HYDROGEN AND FUEL CELL TECHNOLOGY IN...

HYDROGEN AND FUEL CELL HYDROGEN AND FUEL CELL

TECHNOLOGY IN GREECETECHNOLOGY IN GREECE

HY-CO2nd Network Committee Meeting

Prof. Iacovos VasalosGeneral Secretariat for Research and Technology

& Centre for Research & Technology - Hellas

COST Office, BrusselsMarch 16, 2005

THE SETTING UP/INITIATION, THE MANAGEMENT AND THE THE SETTING UP/INITIATION, THE MANAGEMENT AND THE ASSESSMENT OF THEASSESSMENT OF THE HH22FC RD&D PROGRAMS AND SUPPORTING FC RD&D PROGRAMS AND SUPPORTING

ACTIVITIES (THE CHARACTERISTIC MECHANISMS)ACTIVITIES (THE CHARACTERISTIC MECHANISMS)

• No specific program for H2FC• H2FC embedded in several programs • Program content set through a consulting

process with industry, academia• Programs consistent with EU priorities• Funding on a project base • Selection through competitive procedures

BUDGET FOR HBUDGET FOR H22FC RD&D PROGRAMMES AND FC RD&D PROGRAMMES AND SUPPORTING ACTIVITIES IN RELATION TO OTHER SUPPORTING ACTIVITIES IN RELATION TO OTHER

PROGRAMS AND ACTIVITIES (NOT HPROGRAMS AND ACTIVITIES (NOT H22FC)FC)

2000 - 200630 %8,000,000HERON / Placement of PhDs in Greek enterprises

2000 - 200630 %30,700,000AKMON / Support of research centers and univ. labs cooperating with industry (domestic and from abroad)

2000 - 200630 %71,700.000PRAXE / Commercial exploitation of research results (spin-offs)

2000 - 200630 %65,300,000PENED / Reinforcement of human research potential

Funding periodFunded by GSRT (% OF TOTAL)

Size of Funds (€)

Name of programs

THE EXPERIENCE WITH AND EXPECTATION FOR TRANSTHE EXPERIENCE WITH AND EXPECTATION FOR TRANS--NATIONAL COOPERATION, e.g. JOINT H2FC RD&D NATIONAL COOPERATION, e.g. JOINT H2FC RD&D

PROGRAMS AND SUPPORTING ACTIVITIESPROGRAMS AND SUPPORTING ACTIVITIES

• A new program dedicated to H2-FC to begin focus on international cooperation

• Internal consulting process to begin H2-FC program

• Lighthouse project planned

HH22 & FUEL CELL TECHNOLOGIES IN GREECE& FUEL CELL TECHNOLOGIES IN GREECEFunding (2002Funding (2002--2005)2005)

2002 2003 2004 2005 2002-2005FP5 & FP6 (EU) 863.860,01 744.400,82 928.238,03 565.568,73 3.102.067,59Matching Funds 346.781,66 431.834,11 498.670,73 235.206,51 1.512.493,01Structural (GSRT) 15.391,78 137.105,02 251.471,38 265.380,09 669.348,27Industry 0,00 13.210,00 29.735,42 0,00 42.945,42Ministry of Education 2.201,03 3.815,11 170.000,00 40.000,00 216.016,14TOTAL 1.228.234,48 1.330.365,06 1.878.115,56 1.106.155,33 5.542.870,43Funding by GSRT 362.173,44 568.939,13 750.142,11 500.586,60 2.181.841,28

Structural (GSRT)

12%

Matching Funds27% FP5 & FP6

(EU)56%

Ministry of Education

4%Industry1%

PROJECT HIGHLIGHTSPROJECT HIGHLIGHTS

H2RD&D (H2 Production)

H2RD&D (H2 Storage)

H2RD&D (H2 Distribution)

H2RD&D (H2 Use)

HH22 & FUEL CELL TECHNOLOGIES IN GREECE& FUEL CELL TECHNOLOGIES IN GREECEActivitiesActivities


ResearchCPERI/CERTHSolar water splitting

ResearchNTUAMembrane separation

ResearchNTUAWater-Gas-Shift reaction catalysts

ResearchICEHTCatalytic processes and water splitting

ResearchNTUAProduction from waste gases and solid fuels

ResearchUniv. of Patras Univ. of ThessalyAUTHICEHT

Advanced Electrochemical Reactors

DemonstrationCRESHigh pressure electrolysis, utilising wind energy

DemonstrationUniv. of PatrasCPERI/CERTH

Reforming of fuels

StatusInstitutionTechnology



Project examples

Production of clean hydrogen for fuel cells by reforming of bioethanol(BIO-H2)

Catalytic monolith reactor for hydrogen generation from solar water splitting (HYDROSOL)


H2RD&D (H2 Distribution)

H2RD&D (H2 Storage)

ResearchCRESStorage technologies

ResearchDemokritosBonded magnets based on nanocrystalline powder


Policy projectNTUAUse of Existing Natural Gas System

Market analysisCRESIntroduction of H2 energy technologies in stand alone systems

Policy projectHIT/CERTHRoadmap for Hydrogen Energy in Europe



ResearchCPERI/CERTHPolymer electrolyte proton conductors

ResearchUniv. of PatrasICEHTCPERI/CERTHAUTH

Design, construction and testing of Proton Exchange Membrane Fuel Cells (PEMFC)

ResearchICEHTUniv. of ThessalyCPERI/CERTHAUTH

Design, construction and testing of Solid Oxide Fuel Cell (SOFC) components

ResearchDemokritosMetallic and metal – oxide contacts

ResearchDemokritosPreparation & characterization of nanostructuredmaterials

ResearchUniv. of PatrasDesign, synthesis and characterization of materials


H2RD&D (H2 Use)


H2RD&D (H2 Use)

Project examples

Realizing Reliable, Durable, Energy Efficient and Cost Effective SOFC Systems (Real-SOFC)

Advanced PEM Fuel Cells (APOLLON)

Fuel cell application in a new configured aircraft (CELINA)

HYDROGEN ISLANDSHYDROGEN ISLANDS

OUTLINEThe Greek H2 R&D community, aiming to “competitively” participate in the Growth Initiative, is working on:

– a major scale project, of national scope– promoting H2 use on a local level

The application will be on a non-grid connected island with: – a high cost of energy likely to earlier transition to H2

economy– potential of H2 production from RES – development of other technologies / pathways

Likely site is Milos of the Cyclades.


GOALSH2 technologies will include:

– production from conventional fuels and RES installations (electricity producing + biofuels)

– storage in gaseous form – distribution through limited pipeline network and filling

stations– use in CHP, land and sea transport applications

Through H2 technologies:– 10% of electrical demand– 5% of energy for heat – 5% of energy for transportwill be covered


Specific project features: – an extra of 3MW of RES producing capacity (wind, PV,

geothermal, landfill gas)– 3MW of electrolysers or reformers producing 1,600,000

Nm3 H2 per annum– 500kW of stationary FCs running on H2 or biofuels– 1 bus, few special vehicles, boats running on H2– accompanying activities (R&D, demo, training,

dissemination, etc)– total budget approx. 20 MEuro


Specific project features: – R&D institutes (CPERI, U. Patras, U. Athens, NTUA, U.

Thessaly, ICE/HT, Demokritos)– Ministry of Development, GSRT – Local authorities (Island of Milos)– Industry developing H2 related hardware– Industry that could implement H2 related hardware– Power industry, RES installation developers– Financing institutions, Regulatory authority – Associations, locals

PRODUCTION OF PRODUCTION OF HYDROGENHYDROGEN VIA BIOVIA BIO--ETHANOL REFORMINGETHANOL REFORMING

Logo of the project: BIO-H2

Outline:

Plant cultivation

(1)

Anaerobic Digestion (7)

Reformationof ethanol (6)

Fuel Cell (11)

BiomassSolid residue

Aqueous broth8-10% ethanol

CH4CO2

45-55% ethanol

CO, H2

CO2

Solar Energy

COH2

Fertilizer

Saccharification /Fermentation (4)

BiogasReformation (8)

Distillation (5)

Shift Reactor (9)

Heat

Heat

Heat

Residues of agroindustries

and cultivations (2)

Heat

Selective COoxidation (10)

Post Combustion

(12)

Municipal solid waste

(organic fraction) (3)

CO2, CO, H2

CO2

CO2, H2

Electricity

Gasification(13)

Heat

Plant cultivation

(1)



Fuel Cell (11)



CH4CO2

45-55% ethanol

CO, H2

CO2

Solar Energy

COH2

Fertilizer



Distillation (5)

Shift Reactor (9)

Heat

Heat

Heat



Heat


Post Combustion

(12)



CO2, CO, H2

CO2

CO2, H2

Electricity

Gasification(13)

Heat

Plant cultivation

(1)



Fuel Cell (11)



CH4CO2

45-55% ethanol

CO, H2

CO2

Solar Energy

COH2

Fertilizer



Distillation (5)

Shift Reactor (9)

Heat

Heat

Heat



Heat


Post Combustion

(12)



CO2, CO, H2

CO2

CO2, H2

Electricity

Gasification(13)

Heat


Main goals:– Use of Biofuels for the production of heat and electricity– Reduction of the CO, NOx, SOx, particulates, VOC’s,

halogenated compounds etc. especially in suffering urban areas

– Delocalized energy generation i.e. in remote and out of grid places

– Promotion of sustainable development


Project approach:– Deliberation of the following reaction systems:

• Steam reforming of Ethanol (700-850°C) • Autothermal reforming of Ethanol (700-1000°C) • Water Gas Shift (two stages: 350-420°C and 200-250°C) • Selective CO oxidation (100-120°C )

Heat-Integrated Wall Reactor (HIWAR)

ReformingFeed

Fluegas

combustion catalyst filmreforming catalyst film

heat exchangezone

Combustibles

Reformate

heat exchangezone

reactionzone


ReformingFeed

Fluegas

combustion catalyst filmreforming catalyst filmcombustion catalyst filmreforming catalyst film

heat exchangezone

Combustibles

Reformate

heat exchangezone

reactionzone


ReformingFeed

Fluegas

combustion catalyst filmreforming catalyst film

heat exchangezone

Combustibles

Reformate

heat exchangezone

reactionzone


ReformingFeed

Fluegas

combustion catalyst filmreforming catalyst filmcombustion catalyst filmreforming catalyst film

heat exchangezone

Combustibles

Reformate

heat exchangezone

reactionzone

– Development of highly active and selective catalysts for hydrogen production via bioethanol steam reforming

– Examination of the reaction kinetics so us to understand the reaction network

– Design and development of advanced reactors for the production of hydrogen from bioethanol

HH22 & FUEL CELL TECHNOLOGIES IN GREECE& FUEL CELL TECHNOLOGIES IN GREECEGreek Hydrogen Energy ChainsGreek Hydrogen Energy Chains

ParticipantsE.A. Karabateas, Ministry of Development, GeneralSecretariat of Research and DevelopmentE. Bikou, Air Liquide HellasK. Sardi, Energy Regulatory Authority (RAE)G. Lagios, Tropical S.A. (Greek private company )D. Galanakis, Tema Energy S.A. (working in NG networks and CHP)N. Lymperopoulos, Centre for Renewable Energy Systems (CRES)D. Giannakopoulos, CERTH/HITV. Portouli, CERTH/HITP. Gravouniotis, Imperial College

HH22 & FUEL CELL TECHNOLOGIES IN GREECE& FUEL CELL TECHNOLOGIES IN GREECEEfficiency of Greek HEfficiency of Greek H22 supply chainssupply chains

0%

10%

20%

30%

40%

50%

60%

70%

80%

90%

100%

CentralElectrolysis

Wind / Pipeline/ CGH2 /Mobile

DecentralElectrolysis

(onsite) Wind /CGH2 / Mobile

Central SMR(with CO2-

sequ.) /Pipeline /

CGH2 / Mobile

Central CoalGasification /

GH2 Pipeline /Filling Station /

Mobile

CentralElectrolysis

Wind / Pipeline/ CGH2 /

Stationary


(onsite) Wind /CGH2 /

Stationary

Central SMR(with CO2-sequ.) /Pipeline /CGH2 /

Stationary


GH2 Pipeline /Stationary

Central SMR(with CO2 seq.)/ Mix CGH2 inNG Pipeline /NG CGH2 /Stationary

Chains

Effic

ienc

y

HH22 & FUEL CELL TECHNOLOGIES IN GREECE& FUEL CELL TECHNOLOGIES IN GREECEGHG emissions of Greek HGHG emissions of Greek H22 supply chainssupply chains

0

100

200

300

400

500

600

CentralElectrolysis

Wind / Pipeline/ CGH2 / Mobile


(onsite) Wind /CGH2 / Mobile

Central SMR(with CO2-

sequ.) / Pipeline/ CGH2 / Mobile


GH2 Pipeline /Filling Station /

Mobile

CentralElectrolysis

Wind / Pipeline/ CGH2 /

Stationary


(onsite) Wind /CGH2 /

Stationary

Central SMR(with CO2-sequ.) /

Pipeline / CGH2/ Stationary


GH2 Pipeline /Stationary

Central SMR(with CO2 seq.)/ Mix CGH2 inNG Pipeline /NG CGH2 /Stationary

Chain

Gee

nhou

se G

as E

mis

sion

s [g

/kW

h]

H2 Filling station H2 distributionH2 production Feedstock transportation Feedstock production

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