(1)Methodology
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METHODOLOGY
In this chapter, it will discuss the method use for the experiment. There are few tests that need to do by following the sequence.
First is to get the dehydrated and sieved palm shell kernel and followed by pyrolysised bio-solid. This test is to know the
characterizations of the sample in all kinds conditions and to know the composition in the raw sample and also the chemical bonding.
Lastly is the adsorption and desorption rates. This test will be conducted by calculation in order form an equation for the rates.
2.1. Materials
Seasoned kernel sample was obtained from the -- and was crushed to give particle size in the range of 0.10.5 cm [--]. The sample was
dried at 100oC for 24 h prior to the experiments. The kernel contained 18.1 wt%, 59.7 wt%, 22.1 wt% of lignin, cellulose and
hemicellulose, respectively [--]. Elemental analysis has verified the kernel contains 47.89% carbon, 45.41% oxygen and 6.05%
hydrogen[--].
2.2. Dehydrated and sieved
The samples were dehydrated and sieved in four differ sizes. The first kernel was exclusively conducted over 50m in one type of
grind machine. In the second, third and forth methods, kernel were sieved using sieve 0.202mm, 250m and 400m. At the end of the
reaction, the samples were ran for XRF, Nitrogen adsorption, TGA, FTIR and SEM to investigate the chemical bonding and
composition of the unknown compound present in the sieve sample but in the absence of any chemicals .
2.3. Pyrolysis experimental procedure
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The pyrolysis experiments were conducted in a semi-batch stainless steel reactor using the pretreated kernel (30 g). The experimental
system was initially purged with inert nitrogen for approximately 18 min. The reactor was externally heated by an electrical furnace at
a fixed temperature of 550oC, which was monitored by a thermocouple.
2.4. Characterization of bio-solid
The functional groups of bio-solids were analyzed by using Fourier Transform Infrared (FTIR) spectrophotometer. The absorption
frequency spectra were recorded and plotted. The standard IR-spectra of organic compounds were used to identify the functional
groups of the bio-solid. The chemical compositions of the bio-oil were analyzed using (SEM), and the compounds were determined
using (XRF) detector and Nitrogen Adsorption. The yield of kernel conversion and product yield of solid and liquid oils obtained in
the pyrolysis reaction were calculated on weight basis according to equation.
2.5. Adsorption and Desorption rates
The kernels were determined by using Ideal gas equilibrium equation for adsorption and desorption rates. The pyrolysised, calcined
pyrolysised and reduced pyrolysised kernel were compared with standard commercial material so that the equation is the indicator for
the both rates.
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RESULTS AND DISCUSSION
EFB (FESH,DEHYDRATED,SIEVE 250M,REDUCED)
HYDROPHILIC(C6H50H+H2O) HYDROPHOBIC(METHTL ESTER+H2O)
WET IMPREGNATION(BIO OIL+ C6H50H+H2O,DRIED 24HR,100OC) WET IMPREGNATION(BIO OIL+ METHTL ESTER+H2O
DRIED 24HR,100OC)
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CO2 UPTAKE (H2,100ML/MIN,1HR,100OC) CO2 UPTAKE (H2,100ML/MIN,1HR,100
OC)
CO2 DEUPTAKE (H2,100ML/MIN,1HR,100OC) CO2 DEUPTAKE (H2,100ML/MIN,1HR,100
OC)
4000.0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 370.0
0.4884
0.495
0.500
0.505
0.510
0.515
0.520
0.525
0.530
0.535
0.540
0.545
0.550
0.555
0.560
0.565
0.5712
cm-1
A
efb impregnation
3850.28
3444.23
2918.71
2374.67 2080.88
1639.13
1399.13
1239.89
1052.12
670.15
3722.37
1544.39
851.07
412.44531.30
2317.28
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EFB (PYROLYSIS,SIEVE 250M)
REDUCTION(H2,100ML/MIN,1HR,100OC) CO2 UPTAKE (H2,100ML/MIN,1HR,100
OC)
The spectra contain not only the characteristic signals of carbohydrates but also those of
lignin.They are O-H stretching vibration
4000.0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 370.0
1.280
1.30
1.32
1.34
1.36
1.38
1.40
1.42
1.44
1.46
1.48
1.50
1.52
1.54
1.56
1.58
1.590
cm-1
A
efb pyrolysis reduction
3923.79
3770.61
3399.50
2920.65
2149.64
1590.03
1117.59
829.95
1187.82
921.82
4000.0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 370.0
2.09
2.2
2.3
2.4
2.5
2.6
2.7
2.8
2.9
3.0
3.1
3.21
cm-1
A
efb pyrolysis CO2 capture
3837.36
3439.50
2915.85
2514.49
2375.48
1617.14
1489.98
1378.67
1099.37
659.40
556.06
475.06
933.14
2050.99
2980.16
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HYDROPHILIC(C6H50H+H2O) HYDROPHOBIC(METHTL ESTER+H2O)
WET IMPREGNATION(BIO OIL+ C6H50H+H2O) WET IMPREGNATION(BIO OIL+ METHTL ESTER+H2O)
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CO2 UPTAKE (H2,100ML/MIN,1HR,100OC) CO2 UPTAKE (H2,100ML/MIN,1HR,100
OC)
CO2 DEUPTAKE (H2,100ML/MIN,1HR,100OC) CO2 DEUPTAKE (H2,100ML/MIN,1HR,100
OC)
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