INTRODUCTION
POLYPHENYLENE SULFIDE
SK Group
SK Group is a Fortune 65th, 3rd largest conglomerate in Korea, GDP 10.3% & Export 10% SK Group has built up a strong global network with 210 corporations, 83 subsidiaries in 42 countries
Energy & Chemicals
- Petroleum - Gas - Petro Chemicals - Specialty Chemicals - Life Science & Pharmacy
Telecommunications
- Mobile Communication - Semiconductor - International-Communication - IT Consulting - System Integration
Trading & Services
- Trading - Engineering-Construction - Hotel & Duty-free shop - Securities
2007
76.5
3.52.1
4.0
5.5
2.6
99.188.9
104.4
134.1
2008 2009 2010 2011
Financial Highlight (Bil.USD)
51.4%Energy & Chemicals25 Companies
17.7 %Telecommunications
24 Companies
30.8 %Trading & Services
27 Companies
134.1 Bil. USD (2011)
SK Chemicals
65 %Green Chemicals Business
35 %Life Science Business
Sales
We care for the futureHealthcare, Earthcare
Global Leading Solution Provider in Eco-friendly Materials
And Total Healthcare
Revenue (Trillion KRW)
1.55 trillion KRW = US$ 1.3 billion, 2011(1,150 KRW/USD)
2007 2008 2009 2010 2011
1.01 1.091.28 1.33
1.55
SK Chemicals
What SK chemicals
provides
Specialty Polymer Business
Composite Business
High Performance Plastic Business
Bio- based Materials & Energy Business
SKYPET(PET)
SKYFLEX(Composite) ECOPRIME(Bio diesel) ECOPLAN(PLA)
ECOTRAN(PPS) SKYBON(TPEE)SKYGREEN(PETG)
ECOZEN(Bio-based Copolyester)
PURATAN(PCT)
ECOTRAN Introduction1
ECOTRAN Properties2
ECOTRAN Applications3
ECOTRAN Technical Support4
INTRODUCTION
High PerformancePolymers
Relative Temperature Index. & Performance
Relative Temperature Index, C
Heat Deflection Temperature, C
EngineeringPolymers
Commodities
Amorphous Semi Crystalline
PEEK
LCP
PPSPPA PCT
PA 46
PPSU
PES
PSU PEI
PC PC-ABSPA 66
PET
PBT
PPPOM
PA 6
PPO
ABSPMMA
PS
PVCSAN
LLDPE HDPE
LDPE
200180
100
120
140
160
180
200
220
240
260
220 240 260 280 300
PPS
PHENOLIC
PBT
PA 6/6
PCT
PA 4/6
PPAPEI
INTRODUCTION
Sn
ExcellentChemical ResistanceNo known solvent below 200 C
Exceptional Thermal StabilityUL Temperature Index 200 - 240 CHDT > 260 C
Inherent Non-Flammability UL 94 : V0 /5 VA rating
Superior MechanicalPropertiesHigh Tensile & Flexural StrengthHigh StiffnessProperties Retention at Elevated Temperatures
Excellent DimensionalStabilityTight Molding TolerancesLow WarpageLow Creep
INTRODUCTION
SK PPS is produced using differentiated & innovative process technology
No by-product (NaCl) Low Impurities (Ions, Oligomers..)No Solvent
Chlorine FreeLow Outgas (Low boiling point oligomers) Better Flowability(30~50% higher)
Conventional Process
SK Process
INTRODUCTION
SK PPS is free from restricted hazardous substances.
Halogens RoHS-6
PFOS
INTRODUCTION
History & Time Schedule
2005~2006 SK PPS had own polymerization technology developed in beaker scale2007~2008 Unit process optimized and process design completed by operation of bench scale2009~2010 Operation of pilot plant began and feasibility for scale-up verified2010~2011 BEDP(Basic Engineering Design Package) for commercial plant completed. 30 patents in Korea and 101 patents in Overseas filed2011~2012 As of Nov. 2012, 21 patents registered
2005.4PPS R&DLaunching
2009.1PilotStart-upCapa. : 30 kg/Bx
2009.3QOn-Spec.
2012.3QSmall Scale- Commercial PlantCapa. : 100 Ton /yr
2012.4QCommercial PlantInvestmentCapa. : 12,000 Ton/yrLocation : Ulsan Korea
2015.3QCommercial plantStart-up
2006.12BenchStart-up
PROPERTIES
Compounding Grade
Base Resin Grade
Glass ReinforcedCompounds
Glass & Mineral filled Compounds
Super Tough Compounds
Ecotran 1040G General purpose, Good flow, low flash, low off-gasEcotran 1040S High strength, low off-gas
Ecotran 0302 Use for CompoundingEcotran 0502 Use for CompoundingEcotran 0703 Use for FilmEcotran 0704 Use for Fiber, Extrusion
Ecotran 5060G General purpose, Good Dimensional stability, low off-gas
Ecotran T2000 Un-filled GradeEcotran T2130 High Toughness GradeEcotran T2150 High Toughness Grade, High Flow
PROPERTIES
Data Sheet
PropertyGF40%1040G
170
1.3
270
14,000
9
40
265
210
2.05
280
14,429
12
41
265
128
1.3
223
19,399
9
33
262
60
15.9
88
2,428
8.8
NB
88
152
2.36
198
9,136
10
58
248
158
1.58
223
9,995
7.5
27
263
GF40% HS1040S
GF/MF 65%5060G
Super tough un-filled
T2000
Super toughGF30%T2130
Super toughGF50%T2150
Tensile Strength (MPa)
Elongation at break (%)
Flexural Strength (MPa)
Flexural Modulus (MPa)
Charpy Impact Notched (KJ/m2)
Charpy Impact Un-notched (KJ/m2)
HDT ( C)
This is representative data only. Updated data will be changed after grade evaluation.
APPLICATION
Automotive
HEV/EV Battery
Coolant Systems
Lighting
Brake Systems Fuel Systems
Engine Component
Electrical Systems
APPLICATION
Automotive
Bobbins
MWO
Coffee Maker
Hot water systems HDD
Connectors
Optical Device
E/E & Appliance
TECHNICAL SUPPORT
Tool Design Support- Based on Mold Flow Data- Tool Steel, Machine Requirements- Vents- Economical Number of Cavities- Molding Trials
Generate Data- Including Development Tailor Made Test- Structural Analysis- Evaluate Design Alternatives- No Costly Proto Types- Aids Compound Selection- Define Grade to be Used
Mold Flow Analysis- Filling pattern
- Temperature Distribution- Pressure Requirements
- Weld Line & Air Trap Locations- Cycle Time
- Cooling Requirements- Gate Location & Number of Gates
SolutionProvider
Product Development, Processing Consideration
CAE (Computer Aided Engineering)
Technical Service
CAEService