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STATUTORY INSTRUMENTS

1997 No. 1869

MERCHANT SHIPPING

The Merchant Shipping (Prevention of Pollution:Substances Other than Oil) (Intervention) Order 1997

Made - - - - 29th July 1997

Laid before Parliament 6th August 1997

Coming into force - - 1st September 1997

The Secretary of State for Transport, in exercise of the powers conferred by section 138A(1)(a) ofthe Merchant Shipping Act 1995(1), hereby makes the following Order:—

1. This Order may be cited as the Merchant Shipping (Prevention of Pollution: Substances Otherthan Oil) (Intervention) Order 1997 and shall come into force on 1st September 1997.

2. The substances prescribed for the purposes of section 138A of the Merchant Shipping Act 1995(Application of sections 137 and 138 to substances other than oil) are those listed in the Scheduleto this Order.

Signed by authority of the Secretary of State for Transport

29th July 1997

Glenda JacksonParliamentary Under Secretary of State,

Department of the Environment, Transport andthe Regions

(1) 1995 c. 21; section 138A was inserted by the Merchant Shipping and Maritime Security Act 1997 (c. 28), section 3.[DOT 11513]

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SCHEDULE Article 2

LIST OF SUBSTANCES

PART 1NOXIOUS LIQUID SUBSTANCES

Acetone cyanohydrinAcrylonitrileAlachlor technical (90% or more)Alcohol (C6–C17)(secondary) poly(3–6) ethoxylatesAlcohol (C12–C15) poly(1–6) ethoxylatesAlcohol (C6–C17) (secondary) poly(7–12) ethoxylatesAlcohol (C12–C15) poly(7–19) ethoxylatesAlkaryl polyethers (C9–C20)Alkyl (C3–C4) benzenesAlkyl (C5–C8) benzenesAlkyl (C7–C9) nitratesAlkyl acrylate-vinyl pyridine copolymer in tolueneAlkylbenzene, alkylindane, alkylindene mixture (each C12–C17)Allyl alcoholAllyl chlorideAmmonium sulphide solution (45% or less)AnilineBenzene and mixtures having 10% benzene or more*Benzyl chlorideBenzyl alcoholButene oligomerButyl butyrate (all isomers)Butyl benzyl phthalateButyl acrylate (all isomers)Butylamine (all isomers)Butyraldehyde (all isomers)Calcium alkyl (C9) phenol sulphide/Polyolefin phosphorosulphide mixtureCalcium hypochlorite solution (more than 15%)Calcium long-chain alkyl phenate sulphide (C8–C40)Camphor oilCarbolic oilCarbon disulphideCarbon tetrachloride

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Chlorinated paraffins (C10–C13)Chloroacetic acid (80% or less)Chlorobenzeneo-ChloronitrobenzeneChloroformChlorohydrins (crude)2- or 3-Chloropropionic acidm-Chlorotolueneo-Chlorotoluenep-ChlorotolueneChlorotoluenes (mixed isomers)Coal tarCoal tar naphtha solventCoal tar pitch (molten)Cobalt naphthenate in solvent naphthaCreosote (coal tar)Creosote (wood)Cresols (all isomers)Cresylic acid, dephenolizedCresylic acid, sodium salt solutionCrotonaldehyde1,5,9-CyclododecatrieneCyclohexyl acetateCyclohexylamine1,3-Cyclopentadiene dimer (molten)CyclopenteneDecanoic acidDeceneDecyl acetateDecyl alcohol (all isomers)Decyl acrylateDecyloxytetrahydro-thiophene dioxideDi-n-hexyl adipateDi-n-propylamineDibutyl phthalateDibutyl hydrogen phosphonateDibutylamineDichlorobenzene (all isomers)Dichloroethyl ether1,6-Dichlorohexane

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2,4-Dichlorophenol2,4-Dichlorophenoxyacetic acid, diethanolamine salt solution2,4-Dichlorophenoxyacetic acid, dimethylamine salt solution (70% or less)2,4-Dichlorophenoxyacetic acid, triisopropanolamine salt solution1,2-Dichloropropane1,3-DichloropropeneDichloropropene/Dichloro- propane mixturesDiethyl sulphateDiethylamineDiethylaminoethanolDiethylbenzeneDiglycidyl ether of bisphenol FDiglycidyl ether of bisphenol ADiisobutyl phthalateDiisobutylamineDiisobutyleneDiisopropylamineDiisopropylbenzene (all isomers)Dimethyl octanoic acidDimethyl adipateDimethyl hydrogen phosphiteDimethylamine solution (greater than 55% but not greater than 65%)Dimethylamine solution (greater than 45% but not greater than 55%)Dimethylamine solution (45% or less)N,N-DimethylcyclohexylamineDinitrotoluene (molten)1,4-DioxaneDiphenylDiphenyl etherDiphenyl ether/Diphenyl phenyl ether mixtureDiphenyl/Diphenyl ether mixturesDiphenylamine, reaction product with 2,2,4-TrimethylpenteneDiphenylamines, alkylatedDiphenylmethane diisocyanateDiphenylol propaneDiphenylol propane- epichlorohydrin resinsDodecene (all isomers)Dodecyl alcoholDodecyl diphenyl ether disulphonate solutionDodecyl phenol

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Dodecylamine/Tetradecylamine mixtureDodecyldimethylamine/Tetradecyldimethylamine mixtureDrilling brines (containing Zinc salts)EpichlorohydrinEthyl acrylateEthylamine solutions (72% or less)EthylamineEthylbenzeneN-EthylbutylamineEthylene dichlorideEthylene dibromideEthylene chlorohydrinEthylene oxide/Propylene oxide mixture with an Ethylene oxide content of not more than 30%in weightEthylene glycol methyl ether acetateEthylenediamine2-Ethylhexyl acrylate2-EthylhexylamineEthylidene norborneneo-Ethylphenol2-Ethyl-3-propylacroleinEthyltolueneFluorosilicic acid (20–30%) in water solutionFormaldehyde solutions (45% or less)Fumaric adduct of rosin, water dispersionFurfuralGlycidyl ester of C10 trialkylacetic acidHeptyl acetateHexamethylenediamine solutionHexyl acetate2-Hydroxyethyl acrylate2-Hydroxy-4-(methylthio) butanoic acidIsophorone diisocyanateIsophoronediamineLactonitrile solution (80% or less)Lauric acidLiquid chemical wastesLong chain polyetheramine in alkyl (C2–C4) benzenesLong chain polyetheramine in aromatic solventLong chain alkaryl polyether (C11–C20)

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Magnesium long chain alkyl salicylate (C11+)Mercaptobenzothiazol, sodium salt solutionMetam sodium solutionMethacrylic resin in Ethylene dichlorideMethyl acrylateMethyl butyl ketone2-Methyl-6-ethyl anilineMethyl heptyl ketoneMethyl methacrylateMethylcyclopentadiene dimerMethyl naphthalene (molten)3-MethylpyridineMethyl salicylatealpha-MethylstyreneMotor fuel anti-knock compounds (containing lead alkyls)Naphthalene (molten)Naphthenic acidsNeodecanoic acidNitrating acid (mixture of sulphuric and nitric acids)Nitrobenzeneo-Nitrophenol (molten)o- or p-NitrotoluenesNonene (all isomers)Nonyl phenolNonyl phenol poly(4- 12) ethoxylatesNoxious liquid, N.F, (1) n.o.s. (trade name . . . , contains . . .) S.T.1, Cat.A*Noxious liquid, F, (2) n.o.s. (trade name . . . , contains . . .) S.T.1, Cat.A*Noxious liquid, N.F, (3) n.o.s. (trade name . . . , contains . . .) S.T.2, Cat.A*Noxious liquid, F, (4) n.o.s. (trade name . . . , contains . . .) S.T.2, Cat.A*Noxious liquid, N.F, (5) n.o.s. (trade name . . . , contains . . .) S.T.2, Cat.B*Noxious liquid, N.F, (6) n.o.s. (trade name . . . , contains . . .) S.T.2, Cat.B*, mpNoxious liquid, F, (7) n.o.s. (trade name . . . , contains . . .) S.T.2, Cat.B*Noxious liquid, F, (8) n.o.s. (trade name . . . , contains . . .) S.T.2, Cat.B*, mpNoxious liquid, N.F, (9) n.o.s. (trade name . . . , contains . . .) S.T.3, Cat.A*Noxious liquid, F, (10) n.o.s. (trade name . . . , contains . . .) S.T.3, Cat.A*Noxious liquid, N.F, (11) n.o.s. (trade name . . . , contains . . .) S.T.3, Cat.B*Noxious liquid, N.F, (12) n.o.s. (trade name . . . , contains . . .) S.T.3, Cat.B*, mpNoxious liquid, F, (13) n.o.s. (trade name . . . , contains . . .) S.T.3, Cat.B*Noxious liquid, F, (14) n.o.s. (trade name . . . , contains . . .) S.T.3, Cat.B*, mpOctene (all isomers)

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Octyl aldehydesOlefin mixtures (C5–C15)alpha-Olefins (C6–C18) mixturesOleumOleylaminePalm kernel acid oilPentachloroethanePerchloroethylenePhosphorus, yellow or whitePhthalic anhydride (molten)alpha-Pinenebeta-PinenePoly(2+)cyclic aromaticsPolyethylene polyaminesPolyolefin amide alkeneamine (C28+)Polyolefin amide alkeneamine borate (C28–C250)Polyolefin amide alkeneamine polyolPolyolefinamine in aromatic solventPolyolefinamine in alkyl (C2–C4) benzenesPolyolefin ester (C28–C250)beta-PropiolactonePropionitrilen-PropylaminePropylbenzene (all isomers)Propylene trimerPropylene oxidePropylene tetramerRosin soap (disproportionated) solutionRosinSodium sulphide solution (15% or less)Sodium dichromate solution (70% or less)Sodium hydrogen sulphide (6% or less)/Sodium carbonate (3% or less) solutionSodium hydrosulphide solution (45% or less)Sodium hydrosulphide/Ammonium sulphide solutionSodium petroleum sulfonateSodium nitrite solutionSodium thiocyanate solution (56% or less)Styrene monomerSulpho hydrocarbon long chain (C18+) alkylamine mixtureSulphuric acid

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Sulphuric acid, spentTall oil (crude and distilled)Tall oil fatty acid (resin acids less than 20%)Tall oil soap (disproportionated) solutionTall oil fatty acid, barium saltTetrachloroethaneTetramethylbenzene (all isomers)TolueneToluene diisocyanateToluenediamineo-ToluidineTributyl phosphate1,2,4-TrichlorobenzeneTrichloroethyleneTricresyl phosphate (containing 1% or more ortho-isomer)Tricresyl phosphate (containing less than 1% ortho-isomer)TriethylamineTriethylbenzeneTriethylenetetramineTriethylphosphiteTriisopropylated phenyl phosphatesTrimethylamine solution (30% or less)Trimethylbenzene (all isomers)Trimethylhexamethylene diisocyanate (2,2,4- and 2,4,4-isomers)Trixylyl phosphateTurpentineUndecanoic acid1-UndeceneUndecyl alcoholVinyl neodecanoateVinylidene chlorideVinyltolueneWhite spirit, low (15–20%) aromaticXylenesXylenolZinc alkaryl dithiophosphate (C7–C16)Zinc alkyl dithiophosphate (C3–C14)

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PART 2HARMFUL SUBSTANCES

AldrinAzinphos-ethylAzinphos-methylgamma-BHCBinapacrylBrodifacoumBromophos-ethylCadmium compoundCamphechlorCarbophenothionChlordaneChlorinated paraffin (C10–C13)Chlorophenolates, liquidChlorophenolates, solidChlorpyriphosChlorthiophosCopper cyanideCopper metal powderCoumaphosCresyl diphenylphosphateCupric cyanideCupric sulphate1,5,9-cyclododecatrieneCyhexatinCymenes (ortho-; meta-; para-)CymolCypermethrinDDTDialifosDiazinonDichlofenthionDichlorvosDieldrinDimethoateDiphenylaminechloroarsineDiphenylchloroarsine, liquidDiphenylchloroarsine, solid

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DodecylphenolEndosulfanEndrinEPNEsfenvalerateEthionFenbutatin oxideFenitrothionFenpropathrinFenthionFentin acetateFentin hydroxideFonofosHeptachlorHexachlorobutadieneHexachloro-1,3-butadiene1,3-hexachlorobutadieneIsopropyltolueneIsopropyltoluolIsoxathionLindaneMercuric acetateMercuric ammonium chlorideMercuric arsenateMercuric benzoateMercuric bisulphateMercuric bromideMercuric chlorideMercuric cyanideMercuric gluconateMercuric nitrateMercuric oleateMercuric oxideMercuric oxycyanide, desensitisedMercuric potassium cyanideMercuric sulphateMercuric thiocyanateMercurolMercurous acetateMercurous bisulphate

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Mercurous bromideMercurous chlorideMercurous nitrateMercurous salicylateMercurous sulphateMercury acetateMercury ammonium chlorideMercury-based pesticide, liquid, flammable, toxic, flashpoint less than 23°C c.c.Mercury-based pesticide, liquid, toxicMercury-based pesticide, liquid, toxic, flammable, flashpoint between 23°C and 61°C c.c.Mercury-based pesticide, solid, toxicMercury benzoateMercury bichlorideMercury bisulphateMercury bromidesMercury compound, liquid, n.o.s.Mercury compound, solid, n.o.s.Mercury(ii) (mercuric) compounds or Mercury(i) (mercurous) compoundsMercury cyanideMercury gluconateMercury nucleateMercury oleateMercury oxideMercury oxycyanide, desensitisedMercury potassium cyanideMercury potassium iodideMercury salicylateMercury sulphateMercury thiocyanateMethylpropylbenzenesMevinphosNickel carbonylNickel cyanideNickel tetracarbonylOrganotin compound, liquid, n.o.s.Organotin compound, solid, n.o.s.Organotin compounds(pesticides)Organotin pesticide, liquid, flammable, toxic, flashpoint less than 23°C c.c.Organotin pesticide, liquid, toxic

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Organotin pesticide, liquid, toxic, flammable, flashpoint between 23°C and 61°C c.cOrganotin pesticide, solid, toxicOsmium tetroxideParathionParathion-methylPCB'sPentachlorophenolPentachlorophenolPhenarsazine chloridePhenthoatePhenylmercuric acetatePhenylmercuric compound, n.o.s.Phenylmercuric hydroxidePhenylmercuric nitratePhoratePhosalonePhosphamidonPhosphorus, white, dryPhosphorus, white, moltenPhosphorus, white, under waterPhosphorus, yellow, dryPhosphorus, yellow, moltenPhosphorus, yellow, under waterPolychlorinated biphenylsPolyhalogenated biphenyls, liquidPolyhalogenated biphenyls, solidPolyhalogenated ter-phenyls, liquidPolyhalogenated ter-phenyls, solidPotassium cuprocyanidePotassium cyanocupratePotassium cyanomercuratePotassium mercuric iodidePyrazophosQuizalofopQuizalofop-p-ethylSodium copper cyanide, solidSodium copper cyanide, solutionSodium cuprocyanide, solidSodium cuprocyanide, solutionSodium pentachlorophenate

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SulprophosWhite phosphorus, dryWhite phosphorus, wetYellow phosphorus, dryYellow phosphorus, wetTerbufosTetrachlorvinphos

PART 3RADIOACTIVE MATERIALS

Radioactive materials

PART 4LIQUEFIED GASES

AcetaldehydeAnhydrous ammoniaChlorineDimethylamineEthyl chlorideEthylene oxideHydrogen chloride, anhydrousHydrogen fluoride, anhydrousMethyl bromideMethyl ChlorideSulphur dioxideVinyl chloride monomer

EXPLANATORY NOTE

(This note is not part of the Order)

This Order prescribes substances other than oil, the threat of pollution from which (following ashipping casualty) triggers the Secretary of State’s powers of intervention under section 137 of theMerchant Shipping Act 1995 in accordance with section 138A of that Act.The Order gives effect to the Protocol relating to Intervention on the High Seas in Cases of MarinePollution by Substances other than Oil 1973 (Cmnd. 6038) (“the 1973 Protocol”).

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The substances are listed in the Schedule. They are the substances enumerated in the Annex to the1973 Protocol, as amended in 1997.

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