Newsletter · 2000-06-07 · International WOCE Newsletter, Number 35, June 1999 page 3 One of the...

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News from the WOCE IPO W. John Gould, Director, WOCE IPO and ICPO, Southampton Oceanography Centre, UK. [email protected] Number 35 ISSN 1029-1725 June 1999 Published by the WOCE International Project Office at Southampton Oceanography Centre, UK International WOCE Newsletter IN THIS ISSUE WOCE Tracer Science N. Atlantic exchange with Nordic Seas Seawater Standards for dissolved Nutrients WOCE-AIMS Tracer Workshop WOCE/CLIVAR Data Products Committee Once again the WOCE Newsletter has undergone a slight facelift (reflecting some of the input to our reader survey) and in many ways these changes mirror the constant readjustment that WOCE itself has undergone since it was first conceived as a Global Ocean Circulation Experiment (GOCE) in 1980. As this Newsletter goes to press I am writing my part of the chapter in the WOCE Conference book that will say how WOCE came about and how we did the experiment. I am struck by the foresight that the originators of the GOCE/WOCE concept had and how much progress we have made towards achieving WOCE’s goals. The book will be published later this year by Academic Press. An announcement will be placed in the next Newsletter. It promises to be an important summary of where WOCE-related science stands at the end of the millennium. Two important meetings are coming up. The WOCE North Atlantic Workshop in Kiel (23-27 August) (See NL 34) already has around 100 registered attendees and promises to be an important step towards producing a synthesis in this much-observed and much- modelled basin. In August this year the papers originating from the South Atlantic Workshop will be appearing in JGR(Oceans). In October, the Oceanobs’99 meeting in St Raphael, France, (http://www.BoM.GOV.AU/OCEANOBS99) will take an important step beyond WOCE in seeking to define the various sustained ocean observations that will be needed for climate research in GOOS and CLIVAR. This Conference is forward-looking but its conclusions will owe much to the firm foundation set by WOCE in stimulating a global view of the oceans.

Transcript of Newsletter · 2000-06-07 · International WOCE Newsletter, Number 35, June 1999 page 3 One of the...

Page 1: Newsletter · 2000-06-07 · International WOCE Newsletter, Number 35, June 1999 page 3 One of the major reasons for observing the global ocean is to infer the transport properties

News from the WOCE IPO

W. John Gould, Director, WOCE IPOand ICPO, Southampton OceanographyCentre, UK. [email protected]

Number 35 ISSN 1029-1725 June 1999

Published by the WOCE International Project Office at Southampton Oceanography Centre, UK

International

WOCENewsletter

IN THIS ISSUE

WOCE TracerScience

N. Atlanticexchange with

Nordic Seas

SeawaterStandards for

dissolvedNutrients

WOCE-AIMSTracer Workshop

WOCE/CLIVARData Products

Committee

Once again the WOCE Newsletter has undergone a slight facelift(reflecting some of the input to our reader survey) and in many waysthese changes mirror the constant readjustment that WOCE itself hasundergone since it was first conceived as a Global Ocean CirculationExperiment (GOCE) in 1980.

As this Newsletter goes to press I am writing my part of thechapter in the WOCE Conference book that will say how WOCEcame about and how we did the experiment. I am struck by theforesight that the originators of the GOCE/WOCE concept had andhow much progress we have made towards achieving WOCE’sgoals. The book will be published later this year by Academic Press.An announcement will be placed in the next Newsletter. It promisesto be an important summary of where WOCE-related science standsat the end of the millennium.

Two important meetings are coming up. The WOCE NorthAtlantic Workshop in Kiel (23-27 August) (See NL 34) already hasaround 100 registered attendees and promises to be an important steptowards producing a synthesis in this much-observed and much-modelled basin. In August this year the papers originating from theSouth Atlantic Workshop will be appearing in JGR(Oceans).

In October, the Oceanobs’99 meeting in St Raphael, France,(http://www.BoM.GOV.AU/OCEANOBS99) will take an importantstep beyond WOCE in seeking to define the various sustained oceanobservations that will be needed for climate research in GOOS andCLIVAR. This Conference is forward-looking but its conclusionswill owe much to the firm foundation set by WOCE in stimulating aglobal view of the oceans.

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page 2 International WOCE Newsletter, Number 35, June 1999

The World Ocean Circulation Experiment(WOCE) is a component of the World ClimateResearch Programme (WCRP), which wasestablished by WMO and ICSU, and is carriedout in association with IOC and SCOR.

WOCE is an unprecedented effort byscientists from more than 30 nations to studythe large-scale circulation of the ocean. Inaddition to global observations furnished bysatellites, conventional in-situ physical andchemical observations have been made inorder to obtain a basic description of thephysical properties and circulation of theglobal ocean during a limited period.

The field phase of the project lasted from1990–1997 and is now being followed byAnalysis, Interpretation, Modelling andSynthesis activities. This, the AIMS phase ofWOCE, will continue to the year 2002.

The information gathered during WOCEwill provide the data necessary to make majorimprovements in the accuracy of numericalmodels of ocean circulation. As these modelsimprove, they will enhance coupled models ofthe ocean/atmosphere circulation to bettersimulate – and perhaps ultimately predict –how the ocean and the atmosphere togethercause global climate change over long periods.

WOCE is supporting regional experi-ments, the knowledge from which shouldimprove circulation models, and it is exploringdesign criteria for long-term ocean observingsystem.

The scientific planning and developmentof WOCE is under the guidance of theScientific Steering Group for WOCE, assistedby the WOCE International Project Office(WOCE IPO):• W. John Gould, Director• Peter M. Saunders, Staff Scientist• N. Penny Holliday, Project Scientist• Roberta Boscolo, Project Scientist• Sheelagh Collyer, Publication Assistant• Jean C. Haynes, Administrative Assistant

For more information please visit:http://www.soc.soton.ac.uk/OTHERS/woceipo/ipo.html

About WOCE

Newsletter New Look

Roberta Boscolo, Editor, InternationalWOCE Newsletter, SouthamptonOceanography [email protected]

NOTA BENE: telephone number changes

The Southampton national telephone number 01703 has changedto 023 and six digit local number are prefixed with 80. Forexample the WOCE IPO secretary number becomes:++44 (0)23 8059 6789.

Both new and old numbers can be used to dial Southamptontill April 2000 when the use of 01703 ceases.

Thanks to all of you who spared the time to answer questions inour reader survey and returned the card.

Almost unanimously the feedback was encouraging: theNewsletter is very useful for your work and the kind of informationthat it contains also interests researchers not directly involved inWOCE. However particularly welcomed were your suggestionsfor improvements.

Many of you requested more information on technicalissues, and methods of data analysis. In addition you expressedinterest in including meeting reports and more links to otherrelevant international programmes. We will try to meet thoserequests for future Newsletter issues. Meanwhile some changeshave already taken place.

From this issue the Newsletter presents a new layout: thisgives the opportunity to place some general information aboutWOCE and the IPO which can be useful for new readers and areminder for habitual ones. In addition new web pages have beencreated for the Newsletter:

www.soc.soton.ac.uk/OTHERS/woceipo/acrobat.htmlwhich are easily accessed from the main page of WOCEIPO.

Improvements include the availability in pdf format of therecent past issues – from No. 19 to No. 34 – the list of contentsof all the issues and a link through the WOCE Bibliography tothe list of references of all the articles appeared in the Newsletter.In addition you can find the guidelines for submission (recentlyrevised and more flexible) and the possibility of subscribing on-line in order to receive the hardcopy by surface mail regularly.

We are currently working on making available the rest ofNewsletter issues as pdf files. This involves the scanning ofthose copies that were produced with “scissors and glue”. Weare also hoping to put the complete collection on version 2 of theWOCE Data set CD-ROMs which we anticipate will be publishedin May 2000.

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International WOCE Newsletter, Number 35, June 1999 page 3

One of the major reasons for observing the global ocean isto infer the transport properties of quantities important toclimate, including heat, freshwater, carbon, oxygen, etc.Given the disparate observational techniques which formedthe World Ocean Circulation Experiment, the only feasibleapproach is to combine the data with general circulationmodels (GCMs) to produce the required estimates. Wedemonstrate here preliminary global ocean circulationestimates based on an OGCM constrained by a variety ofglobal data sets. The resulting model state is employed inan offline mode to simulate the ventilation of chloro-fluorocarbon 11 (CFC-11) into the ocean. Through a seriesof experiments, we demonstrate that including the tracerdata itself in the state estimation procedure can provideadditional constraints.

Ocean circulation state estimation

Our estimate of the ocean state is based on the oceancirculation model (MIT OGCM) and its adjoint, whichhave been developed recently at the Massachusetts Instituteof Technology. The “forward” model is derived from theincompressible Navier-Stokes equations on a sphere underthe Boussinesq approximation (Marshall et al., 1997a,b).Alone, the OGCM predicts the ocean state, permittingdetermination of the misfits between model andobservations. The adjoint of theoriginal model produces the misfitgradient relative to uncertain modelparameters, and is then used to bringthe forward component into accordwith the data. Careful coding of theMIT OGCM renders it possible toobtain the adjoint model from theforward code in a semi-automatic wayusing the Tangent Linear and AdjointModel Compiler (TAMC) of Gieringand Kaminski (1999).

Our present focus is theestimation of the time-evolving globalcirculation as it emerges primarilyfrom altimetric measurements and theOGCM. Computations, which areongoing, constrain the MIT OGCMover the six year period 1992 through1997. Data constraints (Fig. 1) includethe absolute and time-varying TOPEX/POSEIDON (T/P) data relative to theEGM-96 geoid model; see Lemoine etal., (1997) from October 1992 throughDecember 1997; surface height

anomalies from the ERS-1 and ERS-2 satellites; monthlymean SST data (Reynolds and Smith, 1994); and the time-varying NCEP re-analysis fluxes of momentum (tau), heat(Hq) and freshwater (Hs). Monthly means of the modelstate are required to remain within assigned bounds of themonthly mean Levitus et al. (1994) climatology, and NSCATestimates of wind stress errors (D. Chelton, pers.communication, 1997) are employed.

Changes in control parameters are used to bring themodel into consistency with the observations. In the presentcomputation, the controls (adjustable model parameters)are the initial condition potential temperature ( )θ andsalinity (S) fields and, the surface forcing fields over theentire six year period. The control vector contains 8 millionelements. The model is currently run on a 2° grid. Becausethe optimisation is not yet complete results presented here,after 30 optimising iterations, are highly preliminary andmay be considered as constrained but not yet optimal(Fig. 2, page 19).

Offline CFC-11 simulations: first results

We use the six year “climatological” annual cycle of thecirculation model to simulate the ventilation of CFC-11into the ocean in an “offline” mode. CFCs are of entirelyanthropogenic origin, with well documented production

Ventilation of CFC-11 in a Global Ocean CirculationModel Constrained by WOCE Data

Mick Follows, Detlef Stammer, and Carl Wunsch, Program in Atmospheres,Oceans and Climate, Massachusetts Institute of Technology, [email protected]

ERS-2 SSHERS-1 SSH

Reynolds SST

tau_ncep

Hq_ncep

Hs_ncep

T_lev

S_lev

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Dat

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mean TP SSH - EGM96

monthly

monthly

monthly

daily TP SSH

Figure 1. Schematic of the ongoing optimisation. While the upper part of the figuresshows the data constraints and their distribution in time, the lower part shows thecontrol parameters.

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page 4 International WOCE Newsletter, Number 35, June 1999

rates. Their atmospheric concentrations, which increasedrapidly from the 1950s to 1990s, have been closely observedsince the 1970s and are well constrained prior to that. CFCsare soluble, and inert in the oceans (see e.g. Weiss et al.,1985).

The governing equation for CFC-11 is

∂∂C

tC K C

V

zC K pC Sp at

c= ⋅ ∇ + ∇ ⋅ ∇ − − +u ( ) ( )∆ 0 (1)

where C is the CFC-11 concentration in water and u is themodel flow field. The parameterisation of subgridscalemixing processes is as used for tracers (T, S) in the OGCM.Vertical convective mixing of tracers, Sc , is achieved in amanner which reproduces the monthly statistics ofconvective mixing in the GCM using a diagnostic“convective index”. Surface exchanges of CFC-11 areparameterised with a wind-speed dependent piston velocity,Vp , following Wanninkhof (1992). ∆z is the depth of thesurface layer and K0 is the temperature and salinitydependent solubility of CFC-11 (Warner and Weiss, 1992).The effects of ice cover are parameterised. The offlineCFC-11 model is initialised with C = 0 and integratedfrom 1950 to 1997, during which time pCat , the atmosphericpartial pressure of CFC-11, is specified according to theobserved atmospheric history.

Comparison of unconstrained andconstrained flow fields

We compare three CFC-11 simulations based on threedifferent circulation state estimates: experiment [i] uncon-strained model, [ii] constrained using initial condition andsurface fluxes as control variables, and [iii] constrainedusing only surface fluxes as control variables. As a result,experiment [ii] exhibits strong surface heat fluxes but asomewhat weaker overturning circulation, relative to [i]. Incontrast, [iii] shows the opposite tendencies.

All three CFC-11 simulations capture the broad

features of the observed global, CFC-11 distribution withsurface concentrations close to saturation, and higherconcentrations in cool waters at high latitudes. We focus onthe modelled CFC-11 distributions in the North Atlanticocean in 1983, and compare them to the observations ofWeiss et al. (1985). The models display elevated CFC-11concentrations at depth in the Labrador Sea in 1983 (Fig. 3a),with some indication of a tongue of elevated CFC-11concentrations associated with the deep western boundarycurrent. Compared to the observations, however, the tongueof CFC-11 is diffuse and does not penetrate far enoughequatorwards. Figs. 3b and 3c show difference maps of theCFC-11 distributions derived from the two constrainedmodels referenced to the unconstrained model (Fig. 3a).The difference maps indicate that each of the optimisedmodels results in an improved simulation, with enhancedCFC-11 ventilation in the western boundary current relativeto the unconstrained model.

The improvement of CFC-11 simulation in experiment[ii] is due to enhanced deep convection (associated withenhanced surface heat fluxes) in the Labrador Sea (Fig. 4),but due to enhanced thermohaline circulation in experiment[iii], where convective activity (and surface fluxes) areweakened relative to the unconstrained experiment (Fig. 4).

Summary and outlook

These preliminary results demonstrate the application ofoptimised flow fields for computing the movement oftracers through the ocean: CFC-11 simulations withoptimised ocean currents do show improved results overthat with the unconstrained model. The improvement canbe brought about by adjustments to convective mixing,deep ocean currents, or both, depending upon the controlvariables of the optimisation. The results show that theinclusion of transient tracers in such an optimisation canprovide added constraints to the circulation state estimate.As we learn to use the tracer data, we expect, among many

40°N

80°W 40° 0° 80°W 40° 0° 80°W 40° 0°

(a) (b) (c)

Figure 3. (a) Modelled CFC-11 concentration (pmol/kg) at 1975 m depth, end of 1983, using [i] (the unconstrained model).Solid contours, 0.2 pmol/kg; dashed contour 0.015 pmol/kg (b) Difference of modelled CFC-11 concentration (pmol/kg)between [ii] and [i], at 1975 m in 1983 ([ii]-[i]). Shaded areas represent a positive difference. ±0.015 pmol/kg contours areoverlain. (c) As (b), but difference of modelled CFC-11 concentration between experiments [iii] and [i].

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International WOCE Newsletter, Number 35, June 1999 page 5

possible applications, to compute property flux divergences,and diagnose oceanic biogeochemical fluxes.

References

Giering, R., and T. Kaminski, 1999: Recipes for adjoint codeconstruction. ACM Trans. on Math. Software, in press.

Lemoine, F., and 17 others, 1997: The development of the NASAGSFC and NIMA Joint Geopotential Model. In: Gravity,Geoid and Marine Geodesy, International Association ofGeodesy Symposia, 117 pp. (ed. Segawa et al.) Springer-Verlag., Berlin-Heidelberg.

Levitus, S., R. Burgett, and T. Boyer, 1994: World Ocean Atlas1994, Vol. 3, Salinity, and Vol. 4, Temperature. NOAAAtlas NESDIS 3 & 4, US Dept. of Comm., Washington,DC.

Marshall, J., A. Adcroft, C. Hill, L. Perelman, and C. Heisey,1997a: A finite-volume, incompressible navier-stokes modelfor studies of the ocean on parallel computers. J. Geophys.Res., 102, 5753–5766.

Marshall, J., C. Hill, L. Perelman, and A. Adcroft, 1997b:Hydrostatic, quasi-hydrostatic and non-hydrostatic oceanmodeling. J. Geophys. Res., 102, 5733–5752.

Reynolds, R. W., and T. M. Smith, 1994: Improved global seasurface temperature analyses using optimum interpolation.J. Clim., 7, 929–948.

Warner, M.J., and R.F. Weiss, 1992: Solubilities ofchlorofluorocarbons 11 and 12 in water and sea water.Deep-Sea Res., 32, 1485–1497.

Wanninkhof, R., 1992: Relationship between wind speed and gasexchange over the ocean. J. Geophys. Res., 97, 7373–7382.

Weiss, R. F., J. L. Bullister, R. H. Gammon, and M. J. Warner,1985: Atmospheric chlorofluoromethanes in the deepequatorial Atlantic. Nature, 314, 608–610.

0

400

800

De

pth

(m

)

80°W 40° 0° 80°W 40° 0° 80°W 40° 0°

(a) (b) (c)

Figure 4. Six year average of convective index at 48°N in the model; (a) unoptimized model, [i], (b) with surface fluxes and initialcondition as control variables, [ii], and (c), with surface fluxes only as control variables [iii]. Convective index varies between0 and 1, with higher values indicating more active mixing.

Elsevier Publisher in collaboration with the co-editors BenSearle (Australian Oceanographic Data Centre, Sydney)and Bill Emery (University of Colorado) is launching a newjournal: Ocean and Atmospheric Data Management.

The OADM aims to facilitate accessibility of data,improve its availability and assist in the generation ofinformation relative to this rapidly evolving discipline. It isintended to provide discussion on the broad spectrum ofmulti-disciplinary marine and atmospheric datamanagement issues, as they are experienced through datacollection, manipulation, storage and dissemination. Inaddition to papers on traditional data management andarchiving issues, the journal will include examples of theinnovative use of data for operations, data assimilation andproduct creation.

OADM will be available on paper and on WWW. Thepaper version will be published quarterly, the web versionwill be updated more regularly and will include pre-printsthus sharing results and discussions at an early opportunity.

Ocean and Atmospheric Data Management becomes a Journal

The complete description of this new journal can befound at:

http://www.elsevier.nl/locate/oadmAuthors interested in submitting a paper and

accompanying data, software or information should registertheir interest with the editors:

Ben Searle (Founder)Head, [email protected] EmeryUniversity of ColoradoBoulder, [email protected] involved in ocean and atmosphere data

management are encouraged to take advantage of this newjournal and submit manuscripts.

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page 6 International WOCE Newsletter, Number 35, June 1999

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The first goal of WOCE is to develop models useful forpredicting climate change and to collect the data necessaryto test them. To this end, WOCE chemical tracer dataprovide a unique set of constraints on ocean circulationmodels that are incorporated into climate prediction systems.In contrast to pre-WOCE ocean modelling, geochemicaltracers are now widely used to assess the simulatedcirculation in models. Tracers that have been used in thiscontext include tritium, chlorofluorocarbons, natural andbomb-produced radiocarbon; and, to a lesser extent, oxygen,

silicate, phosphate, isotopes of organic and inorganic carboncompounds and certain noble gases (e.g., helium and argon).Table 1 includes a list of these tracers along with theirvarious applications and properties in ocean modelassessment (taken from England and Maier-Reimer, 1999).

Natural chemical tracers such as isotopes of carbon,argon, and oxygen are useful for examining the modelrepresentation of old water-masses, such as North Pacificand Circumpolar Deep Water. Anthropogenic or transienttracers, such as tritium, chlorofluorocarbons, and bomb-

WOCE Chemical Tracer Measurements Aid theAssessment of Ocean Climate Models

Matthew H. England, Centre for Environmental Modelling and Prediction(CEMAP), Australia, [email protected]

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International WOCE Newsletter, Number 35, June 1999 page 7

0

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5000-250 -200 -150 -100 -50 0 50

Dep

th (

m)

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(a) North Atlantic

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-250 -200 -150 -100 -50Radiocarbon (per mil)

(d) Southern Ocean

HOR-ZHOR=0.75

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GM=ISOGM=0.5

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ObservedGM-0

GM=ISOGM=0.5

produced 14 C are best suited for analysing model cir-culation over decadal time-scales, such as thermoclineventilation, the renewal of Antarctic Intermediate Water,and the ventilation pathways of North Atlantic Deep Waterand Antarctic Bottom Water. A comprehensive review ofthe use of chemical tracers in assessing ocean models canbe found in England and Maier-Reimer (1999).

The purpose of this note is to highlight the use ofchemical tracers in assessing the circulation and flowpatterns in global and regional ocean models. Crucialinformation can be derived from chemical tracers thatcannot be obtained from traditional hydrographic propertiesalone. For example, temperature-salinity (T-S) can provideonly limited information on model water-mass formationtime-scales, such as indicating the depth of rapid ventilationassociated with surface layer mixing. In addition, T-Stogether determine density which in part controls modelflow patterns, so they do not provide an independentmeasure of model skill. T-S are also themselves controlled

by air-sea heat and freshwater fluxes, which are both poorlyknown and in the case of temperature, partly determined bythe model circulation and convection patterns. This makesT-S less than ideal as validation tracers. Geochemicaltracers, in contrast, can provide detailed information on thepathways and rates of water-mass renewal beneath thesurface mixed layer, and as they do not affect density orcirculation, provide an independent measure of modelperformance. This provides ocean modellers with a powerfultool for assessing simulated ocean circulation patterns.

Long time-scale ventilation processes

The distribution of natural radiocarbon provides thebest measure of deep ocean ventilation rates over longtime-scales; say, century time-scales and beyond. Otherradionuclides have either too rapid a decay rate or are toosparsely observed to be useful in this context. Also, anthro-pogenic compounds such as chlorofluorocarbons (CFCs)

Figure 1. Mean model profiles of radiocarbon in (a) the North Atlantic Ocean (0°–70°N), (b) the Indian Ocean north of theEquator, (c) the North Pacific Ocean (0°–70°N), and (d) the Southern Ocean at the latitude band 55°S–70°S in the experimentsof England and Rahmstorf (1999). The model cases include runs with either Cartesian (HOR), isopycnal (ISO), or Gent andMcWilliams (1990, GM) mixing parameterisations (see Table 2). Scatter plots of basinwide GEOSECS observations areoverlaid for comparison.

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page 8 International WOCE Newsletter, Number 35, June 1999

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are yet to penetrate the ocean in measurable quantitiesbeyond a 50-year time-scale. With biological processesaffecting chemical tracers such as phosphate, oxygen,nitrate and so on, natural radiocarbon is the most obviouschoice for validating model behaviour in regions such asthe deep Indian and Pacific Oceans. Another candidate ismantle helium, which enters the deep ocean in hydrothermalfluids in seafloor volcanoes. However, uncertainty in theinput distribution of helium in hydrothermal fluid remainsrather large (Farley et al., 1995).

To date a number of researchers have exploited radio-carbon as a tracer for assessing circulation and water-massformation in ocean models. Normally radiocarbon issimulated as the deviation of the 14 12C C/ ratio from astandard atmospheric value (denoted ∆14C ), therebyminimising uncertainties associated with isotopic frac-tionation effects and biological conversion processes.Further details of radiocarbon modelling techniques can befound in Toggweiler et al. (1989a,b).

An example of a study employing natural radiocarbonto assess model circulation and water-mass formation isthat of England and Rahmstorf (1999; hereafter ER99),who analyse idealised age and ∆14C in a series ofexperiments with different tracer mixing parameterisations.Fig. 1 shows the mean model profiles of radiocarbon in (a)the North Atlantic Ocean (0°–70°N), (b) the Indian Oceannorth of the Equator, (c) the North Pacific Ocean (0°–70°N), and (d) the Southern Ocean at the latitude band55°S–70°S in ER99. Scatter plots of basinwide GEOSECS14 C observations are included for comparison. Their modelexperiments are run with either Cartesian (HOR), isopycnal(ISO), or Gent and McWilliams (1990, GM) mixingparameterisation (see also Table 2). The goal of their studywas to assess which, if any, mixing scheme results in arealistic simulation of deep ocean ventilation.

Observations of ∆14C show that the North AtlanticOcean is relatively well-ventilated to great depth (Fig. 1a).In contrast, all model experiments of ER99 underestimatethe depth of NADW penetration, with a clear delineationbetween upper well-ventilated NADW and lower ∆14C -depleted waters (par-ticularly under GM).Additional GM experi-ments with an exaggeratedwintertime surface T-Sand/or inclusion of thetopographic stressparameterisation ofHolloway (1992) did notrectify this problem. In thePacific and Indian Oceansthe simulated ventilationtime-scales vary greatlybetween the GM and non-GM runs: typical mid-depth water is far toodepleted in radiocarbon inthe GM runs and too rich

in ∆14C in the HOR/ISO experiments. This turns out to bedue to errors in the simulated circulation patterns in theSouthern Ocean. There, the model equivalent of CDW istoo young in the HOR and ISO cases and too old under GM.GEOSECS ∆14C data indicate a near-uniform SouthernOcean value of -160‰, whereas the HOR and ISO casessimulate radiocarbon to be about -120‰. This is due torapid overturn of ∆14C -rich surface waters at this latitude(see also England and Hirst (1997)). In contrast, all GMcases overestimate the ∆14C depletion of CDW. UnderGM, the model simulates slow downslope flows and weakinterior currents around Antarctica, even with enhancedsurface salinities. This explains the spuriously depletedlevels of interior ∆14C . Overall, no model case consideredby ER99 captures global ocean renewal rates to acceptablelevels of accuracy.

Short time-scale ventilation processes

Shorter time-scale ocean ventilation, say decadal tocentennial, is best assessed using tracers whose atmos-pheric or input history has a distinct transient signal duringthe last few decades, such as CFCs and bomb-producedradionuclides (e.g., tritium/helium, 14 C). Tritium ( )3Hand 14 C were produced by atmospheric nuclear bombtesting in the 1950s and 1960s in an amount greatly exceedingtheir natural abundance. The tritium input function into theWorld Oceans is rather complex; depending on rainfall, airmoisture, geographic location and river input (Weiss andRoether, 1980; Doney et al., 1992). Whilst an entry functionfor tritium into the global oceans has been calculated, thereremains some uncertainty as to the various source terms(see also Heinze et al., 1998). Bomb-produced 14 C entersthe ocean via air-sea gas exchange, and atmospheric historiesare estimated in general as a function of latitude and time(see, e.g., Broecker et al., 1980). Bomb-produced radio-nuclides favour a Northern Hemisphere oceanic uptake.Tritium in particular has a strong Northern Hemisphereinput due to slow mixing of 3H in the troposphere.

Since chlorofluorocarbons are relatively stable and

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quite rapidly mixed in the troposphere, their oceanic inputfunction is reasonably similar for all latitudes. SouthernHemisphere atmospheric concentrations lag NorthernHemisphere values by about 1 year. Air-sea fluxes of CFCsare estimated using an appropriate parameterisation of thegas piston speed, estimates of the atmospheric CFC history,and knowledge of their solubility properties (see, e.g.,England et al., 1994). Sea-ice coverage must also be con-sidered as it can shield the upper ocean from air-sea gasexchange. Technical details of simulating CFCs in oceanGCMs can be obtained from the WWW sitehttp://www.maths.unsw.edu.au/metweb/matthew/cfc.html.

There are numerous ocean modelling studies that

have included CFC uptake forvalidation purposes (see reviewby England and Maier-Reimer,1999). Fig. 2 shows CFCconcentrations for the WOCESR3 section across the SouthernOcean at approximately 150°Ein 1991 compared with themodel of England (1995). Themodel uses traditional horizon-tal/isopycnal mixing and issimilar to ocean models used inclimate studies prior to theemergence of recent tracermixing schemes such as GM.The SR3 CFC section runssouth from Australia to theAntarctic continent. Themeasured CFC shows inter-mediate/mode water pene-tration at about 45°S, sharpvertical gradients of CFC near300-m from about 55°S to 65°S,and a very thin band of recentlyformed AABW adjacent to theAntarctic continental slope.The vertical gradients of CFCin the subpolar waters indicateregions of upwelling of CDWand little surface mixing belowthe seasonal thermocline. Themodel fails to reproduce muchof the observed structure: modewater formation is too shallowat 45°S, erroneously deepsurface layer convectionappears at 55°S to 65°S, andonly a broad weak signal ofAABW is simulated adjacentto Antarctica. These modelproblems turn out to be due tolow horizontal resolution andexcessive diapycnal mixing, aswell as poor treatment of thebottom boundary layer in

z-level models (England and Hirst, 1997, ER99).

Uncertainties, limitations and future work

There are some remaining limitations and uncertainties inusing chemical tracers to assess ocean models, and modelsto interpret observed tracer distributions. Many of theseissues were discussed at the recent WOCE-AIMS TracerWorkshop in Bremen. Future work in a number of areas isrequired to ensure that the utility of the WOCE tracer datasets is maximised in the context of ocean climate modelassessment and development. These issues are brieflysummarised here and will be discussed in the final

Observed Ocean CFC - 11

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Figure 2. Latitude-depth sections of dissolved CFC-11 along WOCE section SR3 across theSouthern Ocean at approximately 150°E during 1991 (a) observed (data provided courtesyof Dr J. L. Bullister), (b) in the model of England (1995). Contour levels are drawn atintervals of 0.5 pmol/kg.

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workshop report.Firstly, input functions and boundary conditions must

be well known for chemical tracers to be used meaningfullyin ocean models. For example, parameterisation of the air-sea gas piston velocity remains a source of uncertainty.Atmospheric histories of gases are generally well known,however, unknown error distributions in globalclimatologies of wind speed and sea-ice coverage can limitour ability to force realistic gas uptake in ocean models.Coupled models might not simulate these propertiesrealistically, confounding the issue of validating climatemodels using internally generated fields for air-sea gasforcing. The input function of tritium is complex to estimateand remains a source of possible error in bomb-tritiumsimulations. Mantle helium sources are very difficult toquantify directly; present estimates have quite large errorbars associated with them. Overall, modellers need errorestimates of these source terms to be able to assess modelskill in a statistically meaningful way.

In a related manner, WOCE and non-WOCE tracerfields contain unknown sampling error distributions - bothspatial and temporal. To directly quantify model skill, forexample, to reject a model solution because it is inconsistentwith tracer data, requires some knowledge of the samplingerror distribution associated with that data (Haine andGray, 1999). This includes measurement error, which isperhaps often small, as well as errors associated with thealiasing of sub-grid scale spatial and temporal variability.Oceanic variability is ubiquitous and evident at manyscales, both in space and time, so we can expect a degree ofaliasing in the WOCE tracer data sets compared to whatmight be simulated in an ocean model.

Other limitations in chemical tracer modelling includethe following:• Measurement density and data products

Transient tracers have ever-evolving interior dis-tributions that must be measured for modellers todevelop the most stringent benchmarks of modelskill. Modellers often seek derived data products,such as integral quantities, column inventories, tracerfields objectively mapped onto isopycnal surfaces,and so on. Yet the temporal/spatial gaps in WOCEtracer data (exacerbated for transient tracers) rendermany derived products difficult to estimate and subjectto unknown error. Some other tracers, for example39 Ar , have ideal properties for ocean modelassessment, yet remain poorly sampled due tomeasurement complexity. Unforeseeable develop-ments in measuring technologies could see such tracersemerge as vital tools for ocean model validation.

• High resolution modelsTracer integration techniques are sometimes used tominimise the cost of running computationallyexpensive models with additional tracers beyondT-S. Examples include simple off-line models, whereinvelocity and T-S fields from a prognostic model areused to advect and mix a chemical tracer withouthaving to rerun the whole model. Uncertainties exist,

however, in the degree to which this technique canalias internal model variability; for example, in surfacelayer convection and in eddy behaviour.

• Regional models and data extrapolation/interpolationSpecifying boundary conditions for chemical tracersin regional ocean models can be problematic,especially for transient tracers. Even if a model domainis selected to have open boundaries that coincide witha WOCE hydrographic section, it is necessary toextrapolate the time-dependent transient tracer contentat this open boundary, which requires assumptionsabout the long-term ocean circulation in particularregions. Adjoint methods combined with appropriateocean models could be useful for extrapolating/interpolating the spatial/temporal gaps in the WOCEtracer data set.

Summary and conclusions

WOCE chemical tracer measurements are greatly assistingin the assessment of ocean models used today in climateprediction systems. Different chemical tracers have differentsource functions and uptake/decay properties, givingmodellers a suite of possible benchmarks to assess modelskill. Future tracer measurement programmes are requiredto realise the full benefits of the WOCE tracer survey, bothin terms of capturing the ever-changing transient tracersignal in the ocean and for determining the represen-tativeness of the WOCE period for the long-term behaviourof the ocean.

The simulation of chemical tracers is strongly recom-mended in model assessment studies and as a tool foranalysing water-mass mixing and transformation in oceanmodels. Because property-property analyses provide amore powerful assessment of ocean model skill than singleproperty assessment, particularly when using propertiesthat give relatively distinct information, multiple tracermodelling is recommended. A cost-effective approach is tosimulate natural radiocarbon to assess long time-scaleprocesses, and CFCs for decadal to interdecadal oceanventilation.

Acknowledgements

I wish to acknowledge the enormous efforts of the tracerobservational community in collecting, analysing,interpreting and disseminating the WOCE tracer data sets.

References

Broecker, W. S., T. H. Peng, and R. Engh, 1980: Modelling thecarbon system. Radiocarbon, 22, 565–598.

Doney, S. C., D. M. Glover, and W. J. Jenkins, 1992: A modelfunction of the global bomb tritium distribution inprecipitation, 1960–1986. J. Geophys. Res., 97, 5481–54982.

England, M. H., V. C. Garcon, and J.-F. Minster, 1994:Chlorofluorocarbon uptake in a World Ocean model, 1.Sensitivity to the surface gas forcing. J. Geophys. Res., 99,25215–25233.

England, M. H., 1995: The age of water and ventilation time-scales in a global ocean model. J. Phys. Oceanogr., 25,2756-2777.

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England, M. H., and A. C. Hirst, 1997: Chlorofluorocarbonuptake in a World Ocean model, 2: Sensitivity to surfacethermohaline forcing and subsurface mixingparameterization. J. Geophys. Res., 102, 15709–15731.

England, M. H., and S. Rahmstorf, 1999: Sensitivity of ventilationrates and radiocarbon uptake to subgrid-scale mixing inocean models. J. Phys. Oceanogr., in press.

England, M. H., and E. Maier-Reimer, 1999: Using chemicaltracers in ocean models. Rev. Geophys., in press.

Farley, K. A., E. Maier-Reimer, P. Schlosser, and W. S. Broecker,1995: Constraints on mantle 3 He fluxes and deep-seacirculation from an ocean general circulation model.J. Geophys. Res., 100, 3829–3839.

Gent, P. R., and J. C. McWilliams, 1990: Isopycnal mixing inocean circulation models. J. Phys. Oceanogr., 20, 150–155.

Haine, T. W. N., and S. L. Gray, 1999: Quantifying meso-scalevariability in ocean transient tracer fields. In preparation.

Heinze, C., E. Maier-Reimer, and P. Schlosser, 1998: Transienttracers in a global OGCM - source functions and simulateddistributions. J. Geophys. Res., 103, 15903-15922.

Holloway, G., 1992: Representing topographic stress for largescale ocean models. J. Phys. Oceanogr., 22, 1033-1046.

Ledwell, J. R., A. J. Watson, and C. S. Law, 1998: Mixing of atracer in the pycnocline. J. Geophys. Res., in press.

Maier-Reimer, E., 1993a: Design of a 3D biogeochemical tracermodel for the ocean. In: Modelling Oceanic ClimateInteractions (eds. D. Anderson and J. Willebrand), pp. 415-

464, NATO-ASI Series, 111, Springer-Verlag, Berlin.Maier-Reimer, E., 1993b: Geochemical cycles in an ocean general

circulation model; preindustrial tracer distributions. Glob.Biogeochem. Cycles, 7, 645–677.

Peng, T.-H., E. Maier-Reimer, and W. S. Broecker, 1993:Distribution of 32 Si in the World Ocean: model comparedto observation. Glob. Biogeochem. Cycles, 7, 463–474.

Sarmiento, J. L., 1983: A simulation of bomb tritium entry into theAtlantic Ocean. J. Phys. Oceanogr., 13, 1924–1939.

Schmidt, G. A., 1998: Oxygen-18 variations in a global oceanmodel. Geophys. Res. Lett., 25, 1201–1204.

Staneva, J. V., K. O. Buesseler, E. V. Stanev, and H. D. Livingston,1998: Application of radiotracers to study Black Seacirculation: Validation of numerical simulations againstobserved weapon testing and Chernobyl 137 Cs data.J. Geophy. Res., in press.

Toggweiler, J. R., K. Dixon, and K. Bryan, 1989a: Simulations ofradiocarbon in a coarse-resolution world ocean model. I:Steady state prebomb distributions. J. Geophys. Res., 94,8217–8242.

Toggweiler, J. R., K. Dixon, and K. Bryan, 1989b: Simulations ofradiocarbon in a coarse-resolution world ocean model. II:Distributions of bomb-produced carbon 14. J. Geophys.Res., 94, 8243–8264.

Weiss, W., and W. Roether, 1980: The rates of tritium input in theworld ocean. Earth Planet. Sci. Lett., 49, 435–446.

Twenty-one research groups from five Universities andfour Research Institutes have participated in the GermanWOCE Programme. The funding from the DeutscheForschungsgemeinschaft and the Bundesministerium fürBildung und Wissenschaft lasted from October 1989 toMarch 1999. This Programme was formally completed inthe framework of a scientific seminar on 28 April 1999 inBremerhaven.

The meeting was opened by the Parliamentary StateSecretary Mr W.-M. Catenhusen, representing the Ministryof Education and Research. Mr Catenhusen acknowledgedthe German scientific contributions to WOCE andhighlighted the importance of the results in the perspectiveof the better understanding of global climate changes. Healso accentuated the need for a continuation of oceanicresearch and held out the prospect of a future financialsupport of ocean and climate research by his Ministryparticularly with respect to CLIVAR.

In a brief review of the German WOCE activitiesE. Augstein, former chairman of the German WOCECommittee, portrayed the field work in the northern,southern and equatorial Atlantic as well as the equatorialIndian Ocean and he stressed achievements in ocean andclimate modelling. He also emphasised the improved insightinto the role of the polar and subpolar oceans in the renewalof North Atlantic Deep Water and Antarctic Bottom Water.Furthermore, he pointed out that the evidence of oceanicvariations in the decadal periodic range – which seem to beprimarily forced by the atmosphere – give rise to futureoceanic studies under the CLIVAR programme.

G. Siedler discussed the reservoir and transport effectsof the oceans within the climate system. He addressed inparticular new aspects of the large scale oceanic fluxes of

mass and heat which have been revealed from hydrographic,float and tracer measurements.

J. Meincke concentrated on air-sea interactions insubpolar regions with emphasis on the North Atlantic. Hedrew attention to the rather fast response time of the oceaniccirculation and heat transports to variations of atmosphericforcing. He also showed that tracer analyses illustrate asignificant acceleration of the eastward spreading ofLabrador Sea Water in the northern part of the Atlanticduring the last 10 years.

C. Böning demonstrated the high sensitivity ofimproved ocean models to small-scale influences. Hereferred to effects of the bottom topography in the DenmarkStrait and the Faroe Islands Ridge as well as deep convectionin the Labrador Sea on the large-scale oceanic circulation.

Finally, D. Olbers discussed mechanisms causinginstabilities in coupled ocean atmosphere models, whichmay be critical to predicting climate changes. He stressedthis point by the fact that present model experimentsalready suggest remarkable changes of the large-scalethermohaline circulation in response to weak perturbationsof the North Atlantic surface conditions.

Besides these review papers the results of the 21subprojects were displayed on posters. The German WOCEReview Board took these posters into detailed consideration.On the basis of the oral and poster presentations as well asa written final report the Board expressed their fullsatisfaction with the national WOCE activities.

The analysis and the scientific interpretation of thedata are not yet finalised. Therefore, part of WOCEinvestigation will continue under the umbrella of CLIVARuntil 2002. The funding of this work which started in March1999 is fully assured.

German WOCE: Final Scientific Seminar, Bremerhaven, 28 April 1999

Prof. Dr Ernst Augstein, Alfred-Wegener-Institut, Bremerhaven, Germany. [email protected]

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Tracing the uptake and redistribution of chlorofluoro-carbons (CFC) provides a powerful tool to study oceancirculation and the mechanisms of water mass formation,both in the real ocean and in numerical simulations (e.g.Rhein, 1994; England, 1995). The intercomparison of fieldmeasurements and modelled CFC distributions may thusserve as an additional means of assessing the models’capability of describing processes in key regions, such asthe Deep Western Boundary Current (DWBC) regime.

CFCs have been frequently used for this purpose inthe recent literature (e.g. England, 1995; Dixon et al., 1996;Döscher, 1994), mostly with models of rather coarsehorizontal resolutions of about 1° to 2° in latitude andlongitude. In comparing the results of these models withobservations, the question arises: which aspects of themodel solutions can be assumed to be fairly independent ofmodel resolution and/or configuration, and which featuresare likely to change with future generations of models of

higher resolution? This brief report will attempt to provideone example of what can be expected.

The models used in this paper are part of the FLAME(Family of Linked Atlantic Model Experiments)configuration (see also Redler et al., 1998, or FLAMEGroup, 1998 (draft available from the authors)). Thenumerical code is based on the GFDL MOM (Pacanowskiet al., 1995). The model domain covers the North and SouthAtlantic, extending from 70°N to 70°S with open boundariesacross the Antarctic Circumpolar Current in the DrakePassage and south of Africa at 30°E and restoring zones atthe artificially closed boundaries.

There are two model versions, both using an isotropic,Mercator grid in the horizontal, but differing in resolution.One uses an eddy-permitting grid of 1/3°, the other a gridof 4/3°. There are 45 non-equidistant levels in the verticalin both cases. Atmospheric forcing is based on a 3-yearmonthly mean climatology of ECMWF analyses (Barnier

Spreading of CFCs in Numerical Models of DifferingResolution

René Redler, GMD SCAI, Sankt Augustin, Germany; and Joachim Dengg,Institut für Meereskunde, Kiel, Germany. [email protected]

Figure 1. Section along 60°N for the lower water column through the Labrador Sea and Irminger Basin,CFC-12 concentrations in pmol/l are shaded, contour lines indicate the density for the 4/3° model (a)and the 1/3° model (b).

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et al., 1995), and relaxation to surface salinity given byBoyer and Levitus (1997). Air-sea fluxes of CFC-11 andCFC-12 are implemented by a relaxation of surfaceconcentrations to saturation. The relaxation time scalechosen correspond to a constant piston velocity of5.6 cm/h. The CFC simulation starts with atmosphericCFCs in 1950 and continues to 1988. Both modelconfigurations use the bottom boundary layer schemeproposed by Beckmann and Döscher (1997) in combinationwith isopycnal mixing of tracers to maintain the signal ofdense water overflowing the Greenland-Iceland-ScotlandRidge. This leads to overflow signals that follow the deepwestern boundary currents in the overflow regions, ratherthan getting mixed with the surroundings when they crossthe ridges.

To demonstrate the impact of horizontal resolution onthe tracer distributions in 1988, a section along 60°Nthrough the Irminger Sea (Fig. 1) shows the pronouncedCFC-12 signal of the Denmark Strait Overflow Water(DSOW) in the Irminger Basin, located at depths below2000 m at the continental slope of Greenland at about40°W. At the coarser (4/3°) resolution the CFC signal (andthe western boundary current) is much broader (Fig. 1a)than in the 1/3° realisation (Fig. 1b). While the maximumCFC concentration (between 1.0 and 1.5 pmol/l) and density( . )σθ = 28 0 indicating the core of DSOW have nearly thesame values in both models, the location of DSOW differssubstantially in this section. Note that the absolute CFC

values may be underestimated in the present modelrealisations due to insufficient CFC surface flux in thenorthern restoring zone. The 1/3° model produces a core ofDSOW at a depth of around 2500 m with clear slope currentcharacteristics, but in the 4/3° simulation this water isfound at the bottom of the Irminger Basin. The reasons forthis striking difference are presently being investigated.

A second major difference between the two models(possibly closely related to the feature just described) ismanifest further south at 48°N in a cross-section betweenthe Grand Banks of Newfoundland and the Mid-AtlanticRidge (Fig. 2). In the 1/3° model the core of DSOW withinthe DWBC is maintained on its way from the overflowregions to the subtropics. CFC-12 concentrations of morethan 0.5 pmol/l at depths between 3000 and 4000 m agreereasonably well with observations recently published byBulsiewicz et al. (1998). In previous simulations with levelmodels of comparable horizontal resolution (e.g., Döscher,1994), the deep core of high tracer values was absent due tooverly strong mixing in the outflow regime (see also,DYNAMO Group, 1997). The effect of the newparameterisation scheme for near-bottom transport appearsmuch weaker in the 4/3° model, where most of the southwardflowing, CFC-rich overflow water stalls at the bottom in thesubpolar gyre north of 52°N.

To give an impression of the resulting horizontaldistributions and the propagation of the CFC-signal withthe NADW, we show CFC-12 on isopycnal surfaces for

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both models (Fig. 3, page 20). The density level has beenchosen separately for each model as the surface on whichthe CFC-12 maximum is found at the equator (27.86σθunits for the 1/3° model and 27 80. σθ units for the 4/3°model). The path of NADW is roughly similar in bothmodels. However, the NADW signal is much more diffusivein the coarse resolution run than a smoothing of the high-resolution results to the coarse grid would suggest: at 1/3°,the CFC appears to be concentrated in a DWBC while at 4/3° it is spread fairly evenly across the whole subtropicalgyre. Note however, that even in the 1/3° model there isonly a weakly concentrated DWBC between Flemish Capand the Bahama Bank. In this area the CFC-pattern producedat high resolution is in reasonably close agreement withmeasured CFC concentrations published by Smethie (1993).

In addition to the spatial patterns, spreading ratesseem to differ in the two models: the downstream transportof newly formed NADW occurs somewhat faster in thehigh resolution integration. After 38 years of integration,the trailing signature of NADW (defined as a thresholdCFC concentration of 0.01 pmol/l) has propagated wellbeyond the equator in the 1/3° integration. This is contrastedby the 4/3° model, where the trailing edge is found at 5°N.

In conclusion, these preliminary results indicate thatcoarse resolution models are able to produce tracerdistributions that are not inconsistent with the results athigher resolution, but they appear to overestimate the large-scale spatial spreading while underestimating the rates ofpropagation of tracer signals. Even at a “medium” resolutionof about 1° the successful numerical representation ofspreading of tracers in the ocean may be hampered by theiroverly strong lateral mixing in these models. The quantitativeeffect for, e.g., the uptake and redistribution of anthropogenicCO2 , in long-term climate studies still needs to be examined.For climate studies interested in stationary states, this maynot be relevant, but it will be a concern for studies interestedin the variability on timescales of several decades.

Acknowledgement

We express our sincere thanks to Mr Klaus Ketelsen, SGIGermany, for his great support in optimising the numericalcode for use on CRAY T3E systems.

References

Barnier, B., L. Siefridt, and P. Marchesiello, 1995: Thermalforcing for a global ocean circulation model using a three-year climatology of ECMWF analyses. J. Mar. Syst., 6,363–380.

Beckmann, A., and R. Döscher, 1997: A method for improvedrepresentation of dense water spreading over topography ingeopotential-coordinate models. J. Phys. Oceanogr., 27,581–591.

Boyer, T. P., and S. Levitus, 1997: Objective analyses oftemperature and salinity for the world ocean on a 1/4° grid.NOAA Atlas NESDIS 11, US Govt. Printing Office,Washington, DC.

Bulsiewicz, K., H. Rose, O. Klatt, A. Putzka, and W. Roether,1998: A capillary-column chromatographic system forefficient chlorofluorocarbon measurement in ocean waters.J. Geophys. Res., 103, C8, 15959-15970.

Dixon, K. W., J. L. Bullister, R. H. Gammon, and R. J. Stouffer,1996: Examining a coupled climate model using CFC-11 asan ocean tracer. Geophys. Res. Lett., 23, 1957–1960.

Döscher, R., 1994: Die thermohaline zirkulation in einemnumerischen modell des Nordatlantischen Ozeans. PhDThesis, No. 257, Ber. Institut für Meereskunde.

DYNAMO Group, 1997: DYNAMO. Dynamics of North AtlanticModels: Simulation and assimilation with high resolutionmodels. No. 294, 334 pp., Ber. Institut für Meereskunde,Kiel, Germany.

England, M., 1995: Using chlorofluorocarbons to assess oceanclimate models. Geophys. Res. Lett., 22, 3051–3054.

Levitus, S., R. Burgett and T. P. Boyer, 1994: World Ocean AtlasVolume 3: Salinity, and Volume 4: Temperature, NOAAAtlas NESDIS 1. US Dept. of Comm., Washington, DC.

Pacanowski, R., K. Dixon, and A. Rosati, 1995: MOM 2Documentation, User’s Guide and Reference Manual. Tech.Rep. No. 3, GFDL Ocean Group.

Redler, R., K. Ketelsen, J. Dengg, and C. W. Böning, 1998: Ahigh-resolution numerical model for the circulation of theAtlantic ocean. In: Proceedings of the Fourth EuropeanSGI/CRAY MPP Workshop (eds. H. Lederer and FriedrichHertweck), pp. 95–108, Max-Planck-Institut fürPlasmaphysik.

Rhein, M., 1994: The Deep Western Boundary Current: tracersand velocities. Deep-Sea Res., 1, 41(2), 263–281.

Smethie, W. M. Jr., 1993: Tracing the thermohaline circulation inthe Western North Atlantic using chlorofluorocarbons.Prog. Oceanogr., 31, 51–99.

MEETING TIMETABLE 1999/2000

19–30 July 1999 IUGG XXII General Assembly Birmingham, UK

23–27 August 1999 WOCE North Atlantic Workshop Kiel, Germany

23–27 August 1999 2nd Conference on Reanalyses Reading, UK

13–17 September 1999 Modelling of Global Climate and Variability Conference Hamburg, Germany

5–7 October 1999 WOCE-26 (SSG) Meeting La Jolla, CA, USA

18–22 October 1999 The Ocean Observing System for Climate S. Raphael, France

25–27 October 1999 Topex/Poseidon/Jason-1 SWT S. Raphael, France

27–29 October 1999 US WOCE SSC Meeting Irvine, CA, USA

13–17 December 1999 AGU Fall Meeting S. Francisco, CA, USA

24–28 January 2000 AGU Ocean Sciences Meeting S. Antonio, TX, USA

13–17 March 2000 WCRP-JSC XII Tokyo, Japan

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International WOCE Newsletter, Number 35, June 1999 page 15

Man-made transient tracers such as chlorofluorocarbons(CFCs) and tritium play an important role in estimating theocean circulation. These passive, inert substances havereasonably well-known atmospheric distributions and verylong lifetimes in seawater. Their tropospheric origin anddecadal time-scale make them ideal tracers of the circulationthat ventilates the basin-scale ocean. Substantial effortshave been made to develop reliable measurement techniquesand obtain high-quality datasets from the global ocean. Incontrast, there have been relatively few attempts to combinethese observations with general circulation models (GCMs)in order to improve understanding of the ocean circulation(notable exceptions include: Robitaille and Weaver (1995),England (1995), England and Holloway (1998), Heinze etal. (1998). Here we report first results from a systematicinvestigation of this issue.

The general interpretation of passive tracer dis-tributions in terms of ocean circulation is a problem withmany close relatives in geophysics. We cannot directlymeasure the quantity of interest (the large-scale, low-frequency flow) but have observations of a related variable(tracer). Using a prognostic theory (tracer predictions froma GCM) we indirectly derive information about the quantityof interest from the data with an inverse method. In practicethere are two distinct stages: first, we test the hypothesisthat the GCM tracer predictions (and hence the circulationitself) are statistically consistent with the observations. Ifthey are, then the data provide no useful additionalinformation about the circulation. One may conclude thatmore measurements are required at this stage. Alternatively,if the data are inconsistent with the GCM, then the modelledcirculation requires improvement. Once this has beenachieved, we return to the consistency hypothesis andrepeat the procedure. In a certain formal sense, we onlylearn something new about the circulation when thishypothesis is rejected. We cannot claim that the model (andhence the circulation) has been “validated” or “verified”,only that it is demonstrably wrong (Wunsch, 1996; Oreskeset al., 1994; Randall and Wielicki, 1997).

A section of CFC-11 concentration nominally along20°W in the North Atlantic Ocean (Fig. 1, page 20)illustrates these ideas. Fig. 1a shows the observations madein 1993 (Castle et al., 1998) while Fig. 1b is a GCMCFC-11 field from a 4/3° version of the Miami isopycnalmodel (MICOM, see below). Given the inevitable errors inthe data and the air-sea CFC flux a key question is whetherthese two fields are statistically different. This is the issuewe have addressed using a large database of CFC-11 andCFC-12 measurements and a state-of-the-art (non-eddy-resolving) GCM.

Methods and data

The advection-diffusion equation for the passive transienttracer concentration C is

∂∂

κC

tC C+ ⋅ ∇ − ∇ ⋅ ∇ =u ( ) 0 (1)

where C is a function of position x and time t, u is the (non-divergent) three-dimensional flow and κ is the (variable)diffusion coefficient. We solve this problem, without lossof generality, using the Green’s function G associated withthe linear advection-diffusion operator (see Morse andFeshbach, 1953). The solution is

C(x,t) = κ (xst0 )G(x,t;xst0 )o B(xs ,t0 )

where B is the (uncertain) flux of tracer through the seasurface xs and o means integration over all time and overthe surface of the ocean. (This formalism is easily extendedto cover other tracer sources and sinks.)

This Green’s function solution allows us to determineif the tracer data contain information that constrains ourbest-guess North Atlantic circulation (from the GCM). Weallow errors in the tracer measurements and the air/seaexchange and find the optimal tracer boundary flux thatgives the best least-squares-fit of the GCM-predicted tracerto the observations. This optimal tracer flux B̂ is given by

κGdTPdκGd + Pb( )o B̂ = κGd

TPdd + Pb o B1 (2)

where Gd is the Green’s function at the places and times ofthe observations and Pd and Pb are data and boundary-fluxweights, respectively (that is, inverse error covariances).The tracer observations are d and the prior tracer flux intothe ocean is B1. In practice, the optimal tracer flux B̂ isestimated using a discretized version of eq. (2).

A substantial quantity of pre-WOCE and WOCECFC-11 and CFC-12 data in the North Atlantic has beencollated. The cruises span the years 1982–1994 and covermost regions in the North Atlantic during that period. Mostcruises contained full depth measurements of both CFC-11and CFC-12 concentrations (> 5000 samples of each speciesin total). We gratefully acknowledge the assistance andadvice given by the investigators who provided thesemeasurements for our analyses.

We have used the MICOM primitive equation GCMto predict the North Atlantic CFC transient (Bleck andSmith, 1990). The resolution is 4/3° in longitude and 4/3°× cos(latitude) in latitude yielding an isotropic grid (thisconfiguration is described by the DYNAMO (1997). Thereare sponge layers at the open boundaries (including theStraits of Gibraltar) with 20 density layers in the vertical

North Atlantic Ventilation Constrained by CFCObservations

Thomas Haine, University of Oxford, UK; and Suzanne Gray, Departmentof Meteorology, University of Reading, UK. [email protected]

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page 16 International WOCE Newsletter, Number 35, June 1999

and a thermodynamically active mixed layer. The model isforced with monthly climatological fluxes derived from theECMWF analysis (1986-1988) with the sea surface salinityrelaxing to the Levitus 1982 climatology. Sub-grid-scaleprocesses are parameterised using Laplacian diffusion alongdensity surfaces with a small diapycnal mixing. Oursimulations begin from an adjusted flow which is nearly insteady state on annual time-scales. A tracer model to solveeq. (1) and hence derive the Green’s function, is includedin the dynamical code.

To decide if the modelled CFC field is consistent withthe tracer data we require a measure of the expected misfit(that is, the Pd and Pb in eq. (2)) and the prior-guess flux( B1). The data uncertainty arises from instrumental errorand navigational error (uncertainty in geographic position).However, misfits caused by oceanic variability that ismissing from the GCM are substantially greater. Suchvariability is caused by meso-scale eddies, inertia-gravitywaves and three-dimensional turbulence at scales that areunresolved by the GCM. We call this uncertainty a “model-variability error.” While instrumental and navigationalerrors are relatively straightforward to estimate, the model-variability error is a complex, scale-dependent quantity. Itis directly related to the variance spectrum of the tracer inquestion.

Calculations of tracer spectra from eddy-resolvingnumerical experiments suggest that the spectral shapedepends only weakly on the details of the (large-scale)tracer source and sink (Haine and Gray, 1999). Therefore,we have estimated the tracer variance spectrum of potentialtemperature on isopycnals in the North Atlantic oceanusing high resolution hydrographic data. We have thenused this spectrum as a proxy for the CFC spectrum in theNorth Atlantic and hence estimated the data weight Pd ineq. (2). The magnitude of this model-variability error mayreach 50% in regions of strong eddy activity.

In comparison, the CFC flux error is smaller (O(20%)).Although the details of the air/sea exchange are poorlyknown, the net flux B1 in eq. (2) is primarily limited by theventilation of the mixed layer. The prior boundary fluxestimate itself is determined by comparing realistic MICOMCFC simulations that use different air/sea exchangeparameterisations (Asher and Wanninkhof, 1998).

Results

The results from our inverse calculations are that onintermediate and large scales (O(500) km and larger) theMICOM CFC fields are in reasonable agreement with theobservations when we properly include the effects ofunresolved variability. However, at shorter scales there aresignificant discrepancies, especially in the subpolar gyre. Itappears that the subpolar ventilation mechanisms in theGCM do not penetrate deeply enough and are not in thecorrect locations (as Fig. 1 suggests). Heinze et al. (1998)have also recently concluded that CFCs, anthropogenictritium and tritiugenic helium-3 are inconsistent with a 3.5°resolution global GCM. Although our North Atlantic data

seem to be inconsistent with the 4/3° MICOM model thenormalised misfit is not particularly large. There are alsoseveral sources of error in our analysis. In particular, ourestimate of the North Atlantic tracer variance spectrum isuncertain. In this light we take the view that, on balance, thedata are only marginally inconsistent with the GCM. Inother words, we believe that relatively minor changes in themodel circulation would bring the GCM in to statisticalagreement with the data.

To investigate the implications of our results, we haveestimated some ventilation diagnostics based on our best-fit CFC fields. Fig. 2a shows the total inventory of CFC-11

0

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for densities less than σ0327.92kg m= − based on the 4/3°

MICOM model using CFC-11 fluxes fitted to observations.Years 1964, 1974, 1984 and 1994 are shown. (b) Formationrate (10 m /s)6 3 calculated from the CFC inventory and asimple box mixing model. STMW is Sub-tropical ModeWater and SPMW is Sub-polar Mode Water; see text fordetails.

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International WOCE Newsletter, Number 35, June 1999 page 17

in density classes directly ventilated south of the Greenland-Scotland ridge. The tracer is being absorbed in the seasonallymixed surface layers and in the two principal mode watersformed in the North Atlantic: Subtropical Mode Water(STMW, σ0

326 5≈ −. )kgm and Subpolar Mode Water(SPMW, σ0

327 75≈ −. )kgm (Speer and Tziperman, 1992).Taking all the waters lighter than σ0

327 82≈ −. kgm(pressures less than about 2000 db) together, the NorthAtlantic ocean was near 20% saturated with CFC in themid-1990s.

Using a simple box mixing model we can calculatethe corresponding residence time and hence estimate typicalventilation rates. These fluxes, averaged over the last 20–30 years and based on our synthesis of CFC data and theMICOM circulation, are shown in Fig. 2b. The formationof STMW and SPMW with peak rates around 5 Sv is clear.It is also remarkably consistent with the estimates of (Speerand Tziperman, 1992) based on an independent surfacebuoyancy analysis. Interestingly, their analysis suggests noformation between the two mode waters. Our estimate isabout 1.4 Sv at σ0

327 3= −. kgm and may be due toprocesses (such as interior diabatic mixing and lateraltransfers in the mixed layer) which are very hard to estimateusing other methods (see also Sarmiento, 1983).

In conclusion, we have established a foundation forthe systematic interpretation of transient tracer data usingGCMs. Our results are that the CFC measurements aremarginally inconsistent with a good North Atlantic cir-culation model when we include the effects of unresolvedvariability. Using the best-fit CFC fields we have estimatedthe net North Atlantic ventilation rate. We find goodagreement with independent prior results for mode waterformation and interesting disagreement that may be causedby interior water mass transformation mechanisms. We arenow expanding our tracer database, modifying the modelcirculation and investigating the critical processescontrolling the North Atlantic CFC budget.

Acknowledgements

We thank Chantal Andrié, John Bullister, Scott Doney,Rana Fine, Elisabet Fogelqvist, Monika Rhein, Bill Smethie,

Denise Smythe-Wright, Rik Wanninkhof, Mark Warnerand Ray Weiss who kindly provided their tracermeasurements for this study. Yan Li Jia and Kelvin Richardshelped us use the MICOM model. This work was supportedby grant GST/02/1685 of the Natural Environment ResearchCouncil of the UK.

References

Asher, W., and R. Wanninkhof, 1998: Transient tracers and air-sea gas transfer. J. Geophys. Res., 103, 15939–15958.

Bleck, R., and L. T. Smith, 1990: A wind-driven isopycniccoordinate model of the North and Equatorial Atlanticocean. I. Model development and supporting experiments.J. Geophys. Res., 95, 3273–3285.

Castle, R. D., R. H. Wanninkhof, J. L. Bullister, S. C. Doney, R.A. Feely, B. E. Huss, E. Johns, F. J. Millero, K. Lee, D.Frazel, D. Wisegarver, D. Greeley, F. Menzia, M. Lamb, G.Berberian, and L. D. Moore, 1998: Chemical andhydrographic profiles and underway measurements fromthe North Atlantic during July and August of 1993. NOAAdata report ERL AOML-32 (PB98-131865), NOAA/ERL/AOML.

DYNAMO Group, 1997: Final Scientific Report. Technical Report294, 334 pp., Institut für Meereskunde an der UniversitätKiel, Germany.

England, M. H., 1995: Using chlorofluorocarbons to assess oceanclimate models. Geophys. Res. Lett., 22, 3051–3054.

England, M. H., and G. Holloway, 1998: Simulations of CFCcontent and water mass age in the deep North Atlantic.J. Geophys. Res., 103, 15885–15901.

Haine, T. W. N., and S. L. Gray, 1999: Quantifying meso-scalevariability in ocean transient tracer fields. In prep.

Heinze, C., E. Maier-Reimer, and P. Schlosser, 1998: Transienttracers in a global OGCM: Source functions and simulateddistributions. J. Geophys. Res., 103, 15903–15922.

Levitus, S., 1982: Climatological atlas of the world ocean. NOAAProf. Paper 13, 173pp., Technical report, US Department ofCommerce, NOAA.

Morse, P. M., and H. Feshbach, 1953: Methods of theoreticalphysics. McGraw-Hill.

Oreskes, N., K. Shrader-Frechette, and K. Belitz, 1994:Verification, validation, and confirmation of numerical-models in the earth-sciences. Science, 263, 641–646.

Randall, D. A., and B. A. Wielicki, 1997: Measurements, modelsand hypotheses in the atmospheric sciences. Bull. Amer.Meteor. Soc., 78, 399–406.

Robitaille, D. Y., and A. J. Weaver, 1995: Validation of sub-grid-scale mixing schemes using CFCs in a global ocean model.Geophys. Res. Lett., 22, 2917–2920.

Sarmiento, J. L., 1983: A tritium box model of the North Atlanticthermocline. J. Phys. Oceanogr., 13, 1269–1274.

Speer, K., and E. Tziperman, 1992: Rates of water mass formationin the North Atlantic ocean. J. Phys. Oceanogr., 22, 93–104.

Wunsch, C., 1996: The ocean circulation inverse problem.Cambridge University Press, Cambridge, UK, 1st edition.

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page 18 International WOCE Newsletter, Number 35, June 1999

The fundamental circulation pathways in the EquatorialPacific thermocline can be described by a complex systemof predominantly zonal currents, which exhibit significantspatial and temporal variability (Wyrtki, 1967; Wyrtki andKilonsky, 1982). Present within this current system arewaters subducted into the thermocline in the northern andsouthern subtropics and subsequently upwelled at theequator. There is also a possible contribution from sub-thermocline waters, which may be incorporated by processesof diapycnal mixing or upwelling. However, there is stillsome uncertainty as to both the degree of communicationbetween sub-thermocline and thermocline waters in thePacific, and to the relative importance of the northern andsouthern hemispheres in ventilating the equatorialthermocline. The task of accurately quantifying the sourceof waters in the equatorial current system is exacerbated bythe strongly time-varying circulation. It is because of thishigh temporal variability that tracer budgets (which integrateover long time periods) offer great potential for elucidatingthe time-mean contributions of waters subducted in thesubtropics of the northern and southern hemispheres to theequatorial thermocline.

There have been previous tracer-based approaches tothe problem of quantifying the relative contributions ofwaters subducted in the subtropics to the Equatorial Pacificthermocline, most commonly via salinity budgets (e.g.Toole et al., 1988; Tsuchiya et al., 1989; Wijffels, 1993),but also using tritium (Fine et al., 1993). Salinity massbudgets imply that the southern subtropical gyre providesthe main source water to the Equatorial Undercurrent(EUC). This conclusion is supported by various modellingstudies: A study of GCM velocity fields by Blank andRaynaud (1997) implies that the EUC is composed ofalmost 60% water entering through its southern edge, andin a 3.5 layer model study, Lu et al., 1998, show that 63%of southern hemisphere extratropical water is present withinthe EUC.

While the salinity distribution is certainly an excellenttool with which to attack the problem, the definition ofsource waters in light of a strongly time-varying circulationremains problematic. Further, if there is any exchangebetween thermocline and sub-thermocline waters in theequatorial or subtropical regions, this will be an additionalsource of error. The use of a single transient tracer such astritium is problematic because either the dilution of newlyventilated northern hemisphere waters by less well ventilatedthermocline waters, or any mixing with sub-thermoclinewaters, would have a similar imprint on the tritium signatureas advection of southern source waters into the northernhemisphere.

The approach

We here outline a new method for assessing the relativecontributions of waters subducted in high latitudes of thenorthern and southern Pacific to the equatorial thermoclineover the last few decades. We propose that the ratio of twotransient tracers with similar input histories can be used asto formulate a ‘new’ tracer complementary to, and withcertain advantages over steady-state tracers, and over anytransient tracer considered in isolation. The concept is verysimple: this new tracer can be regarded as a pair of ‘dyes’injected into high-latitude northern- and southern-hemisphere surface waters at some time t0 . Some amountof time later (at time t1), the dyes will have reached theequator. If this ‘ventilation time’ ( )t t tv = −1 0 can beconstrained, and if the dye (tracer) concentrations areknown both at time t0 and time t1, then the degree ofmixing between waters originating in the northern andsouthern hemispheres can be deduced. It is suggested thatthe bomb tritium-bomb radiocarbon tracer pair is ideallysuited for answering questions regarding ventilation sourcesin the equatorial Pacific thermocline.

The bomb tests injected both tritium and radiocarboninto the atmosphere, with a peak in the mid-1960s. Bomb-derived tritium has a strongly asymmetric latitudinal inputfunction, and was delivered predominantly to the northernhemisphere oceans via precipitation, water vapour exchangeand river runoff as HTO (tritiated water; Weiss and Roether,1980). Bomb-derived radiocarbon was delivered to thesurface ocean via CO2 exchange, but because it becamewell mixed in the atmosphere before entering the surfaceocean, its input is nearly symmetric about the equator. Dueto the presence of a significant natural background, in orderto estimate the amount of radiocarbon contributed to anygiven water sample as a result of nuclear testing, it isnecessary to ‘separate’ the natural and bomb-producedcomponents of radiocarbon. To do this we used the silicate-based method described by Broecker et al., 1995.

Radiocarbon decays with a half-life of 5730 years,and hence on decadal timescales, the loss due to decay isnegligible. Tritium, however, decays with a much shorterhalf-life of 12.43 years. By converting measured tritium to‘TU81’ units (i.e. by decay-correcting measured tritiumconcentrations to 1 January 1981), the tritium lost to decayis explicitly accounted for, and the tracer ‘TU81’ can bethought of as a passive dye-like tracer with a pulse-likeinput in the high latitudes of the northern hemisphere.

We define the ratio of tritium to bomb radiocarbon asR=25(TU81/bomb14C). The multiplicative factor is simplypresent in order to make the range of the new tracer fall

Assessing the Importance of Subtropical Watersin Ventilating the Equatorial Pacific Thermocline:a Combined Transient-Tracer Approach

S. Peacock, Lamont-Doherty Earth Observatory of Columbia University, USA;W. Jenkins, Southampton Oceanography Centre, UK; R. Key, Princeton University,USA; and W. Broecker, Lamont-Doherty Earth Observatory. [email protected]

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International WOCE Newsletter, Number 35, June 1999 page 19

Follows et al., page 3, Figure 2. (a) The mean sea surface height field relative to the geoid, as it results from the entiresix year optimisation period. This field displays all major known elements of the general circulation but with sharpfrontal structures smoothed owing to the limited spatial resolution. The optimisation has removed erroneous initialfeatures known previously to have resulted from errors in the geoid estimate. These are particularly pronounced in theabsolute circulation of the tropical Atlantic and Pacific Oceans. (b) The optimised mean (over six years) temperatureand velocity field at 112 m depth (cm/s). As in the surface height field, the flow field also contains all major elementsof the general circulation but with the expected spatial smoothing. (c) Same as (b), but from 2500 m depth.

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page 20 International WOCE Newsletter, Number 35, June 1999

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Redler and Dengg, page 12, Figure 3. Horizontal distribution of CFC-12 on isopycnal surfaces corresponding to the NADWin each model. The colour bar indicates CFC-concentrations in pmol/l, contoured is the depth of the isopycnal surfaces.(a) shows results for year 1988 in the 4/3° model, in (b) the corresponding distribution is plotted for the 1/3° model.

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Haine and Gray,page 15, Figure 1.Sections of CFC-11c o n c e n t r a t i o n(pmol/kg) nominallyalong 20°W in 1993.(a) Field observations(Castle et al., 1998)(dots show the bottlelocations), and,(b) MICOM pre-diction. The upperpanel in each caseshows the top 1000 dbexpanded. See text fordetails of the MICOMconfiguration.

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International WOCE Newsletter, Number 35, June 1999 page 21

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Peacock et al., page 18, Figure 1. R(25(TU81/bomb C))14 at the time of WOCE on selected isopycnal surfaces in the Pacific.The station locations for WOCE P6, P10, P13, P14, P16, P17, P18 and P19 are shown by the black dots. Maps were constructedusing an objective mapping technique. The grey area in the upper right-hand corner is a region in which there is no data. Whiteareas are regions in which the isopycnal surfaces outcrop.

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page 22 International WOCE Newsletter, Number 35, June 1999

Orr, page 24,Figure 1. Section ofnatural ∆14C, thef r a c t i o n a t i o n -corrected 14 12C/ Cratio (in per mil)along(a) the WesternAtlantic GEOSECScruise track(b) as estimated fromobservations by(Broecker et al.,1995), and in the(c) Princeton-GFDL,(d) Hadley,(e) MPI, and(f) IPSL models.

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v v v v v v v v v v v v v v

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0.0

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3.0pmol/kgCFC-11 CFC-11

Salinity Salinity

Wawaruntu et al., page 26, Figure 1. Salinity and CFC-11 sections from Makassar Strait to Flores Sea to Banda Sea(same section as top Fig. 2) during AM93 and AM94.

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International WOCE Newsletter, Number 35, June 1999 page 23

roughly in the range zero to one. In computing R, all datapoints with TU81<0.1 or bomb C14 20< per mil wereeliminated, due to the sensitivity of R to small errors atthese low values.

One advantage of the tritium-bomb C14 tracer pair isthat the time evolution of the end-member concentrationsin surface waters is known fairly well. Further, water addedto the thermocline by isopycnal or diapycnal mixing or byupwelling of older waters will carry zero-concentrations ofbomb-tritium and bomb-radiocarbon. Hence admixture ofthermocline waters with older waters will not change theratio of bomb-tritium to bomb-radiocarbon.

In order to accurately assess the relative importanceof waters originating in the northern and southern subtropicsin ventilating the equatorial Pacific thermocline, one wouldideally need to know the TU bomb C81 14: ratio in waterwhich is now at the equator at the time when it wassubducted. Therefore, some measure of the time taken totransport waters from the high latitude surface to thesubsurface equatorial thermocline is required. One suchmeasure can be obtained by computing the ‘tritium-helium

age’ (Schlosser, 1992; Jenkins, 1996). Thetritium-helium age section constructed byJenkins (see Jenkins, 1996, for details)along P17 (~135°W) shows that, at theequator between roughly σθ 25.5 and26.5, the tritium-helium age lies between15 and 20 years.

Preliminary results

The distribution of R on selected isopycnalsurfaces at the time ( )t1 of WOCE (early1990s) is shown in Fig. 1 (page 21).

We obtain an estimate of the‘ventilation time’, tv , from the WOCEtritium-helium data. Finally, R is estimatedat subduction latitudes at time t t tv0 1= − .While there has been a significant changein the TU bomb C81 14: ratio in northernhemisphere waters over the last 30 years(due primarily to the continued addition ofbomb C14 ), the change in R in high-latitudesouthern hemisphere waters over the sametime period is barely detectable. Asillustrated in Fig. 2. this is due to the verylow initial TU bomb C81 14: ratio in thesouthern subtropics.

A ventilation age of 15 to 20 yearsfor equatorial waters in the lowerthermocline would require that thesewaters be at the surface in the early to mid1970s (which was the period of theGEOSECS surveys). Based on theGEOSECS data, we assign to these watersan initial Rn (the TU bomb C81 14: ratioin high latitudes of the northern hemis-phere) of 1.35, and an initial Rs (theTU bomb C81 14: ratio in high latitudes of

the southern hemisphere) of 0.15. The TU bomb C81 14:ratio in equatorial waters at the time of the WOCE surveysis close to 0.3 on all density surfaces, and shows littlevariation with longitude (see Fig. 1).

By writing a simple budget equation to estimate therelative contributions of northern and southern sourcewaters to the equatorial thermocline, X R X R Rn n s s eq+ = ,and using the values in table 1, the required contributionsfrom the northern and southern subtropics to the equator areas follows: Xs = 88%, Xn = 12% (where Xn = amount ofwater originating in the northern subtropics; Xs = amount

tegdubehtniselbairavotdengissaseulaV.1elbaTnrehtronfosnoitubirtnocfonoitamitseehtrofnoitauqelairotauqeehtotsretawecruosnrehtuosdna

.enilcomreht

Rn(t

0) R

n(t

1) R

s(t

0) R

s(t

1) R

qe(t

1)

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1

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OCE)=0.8

R eq(WOCE)=0.3

SR (GEOSECS) ~ R (WOCE)=0.15S

Bomb14C

R N(G

EOSE

CS)=1

.35

Addition of

bomb14C

with R>RN

Assume no waters

TU

81

Figure 2. Schematic figure to illustrate how R is expected to change with timein the northern and southern subtropics. The uppermost line shows R in thenorthern subtropics at the time of GEOSECS. Continued addition of bomb14Cto the system, but a much smaller input of tritium would cause the ratio to evolvein the manner shown by the horizontal arrows. R in southern tropical waters(R )s would be expected to change by only a small amount between theGEOSECS and WOCE surveys, and hence we have made the assumption thatRs remained roughly constant at 0.15. The dotted line shows R measured on theequator at the time of WOCE.

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page 24 International WOCE Newsletter, Number 35, June 1999

of water originating in the southern subtropics, andX Xn s+ = 1). This implies that equatorial waters in thelower thermocline are made up almost exclusively of waterof southern hemispheric origin. This result is somewhathigher than that from calculations based on salinity budgetsand GCM transports (e.g. Blanke and Raynaud, 1997; Lu etal., 1998; Tsuchiya et al., 1989); but it supports the viewthat the southern subtropical gyre is the dominant source ofwater to the Equatorial Undercurrent.

Discussion

Our findings are best interpreted as upper bounds on theimportance of waters subducted in the southern extra-tropics in ventilating the Equatorial Pacific thermocline. Ifthe tritium-helium based ventilation age or theTU bomb C81 14: ratio at the time of subduction is spuriouslyhigh, or if there is significant downward mixing of overlyingwaters, our estimate of the importance of the southerncomponent will need to be reduced.

The ventilation age obtained from the tritium-heliumpair may be biased high as a result of addition of primordialhelium due to upwelling or upward diapycnal mixing. Asan extreme lower bound on the southern-component, aventilation age of zero can be assumed by usingR t R tn n( ) ( ) .0 1 0 8= = as the northern end-member. Sucha scenario would require Xs = 77%, Xn = 23%.

Another possible source of error may arise from thedifferent time-history of tritium and bomb-radiocarboninput to the ocean. Because the input of tritium was morepulse-like than that of radiocarbon, there has been continuedaddition of bomb radiocarbon to the surface ocean over thelast 30 years, but a much smaller input of tritium. Thereforethe effect of downward mixing would be to preferentiallymix down bomb C14 , leading to a spuriously lowTU bomb C81 14: ratio. Thus this would, again, lead to anover-estimate of the importance of the southern component.We therefore suggest that the result that equatorial watersconsist of roughly 90% southern-derived waters be taken asan uppermost limit.

We have presented preliminary conclusions regardingthe relative importance of waters subducted in the northernand southern subtropics in ventilating the equatorial Pacificthermocline. These conclusions are based on the tritium-bomb C14 pair and on tritium-helium age estimates. It islikely that estimates could be further improved by thesimultaneous consideration of CFC and salinity budgets.

Acknowledgements

Thanks to M. Visbeck and K. Rodgers for useful commentson the manuscript.

References

Blanke, B., and S. Raynaud, 1997: Kinematics of the PacificEquatorial Undercurrent: An Eulerian and Lagrangianapproach from GCM results. J. Phys. Oceanogr., 27, 1038–1053.

Broecker, W., S. Sutherland, W. Smethie, T.-H. Peng, and G.Ostlund, 1995: Oceanic radiocarbon: separation of thenatural and bomb components. Global Biogeochem. Cycles,9, 263–288.

Fine, R., W. Peterson, C. Rooth and H. Ostlund, 1993: Cross-Equatorial tracer transport in the upper waters of the PacificOcean. J. Geophys. Res., 88, 763–769.

Jenkins, W., 1996: Tritium and 3 He in the WOCE PacificProgram. Int. WOCE Newsl., 23, 6–8.

Lu, P., J. McCreary, and B. Klinger, 1998: Meridional Circulationcells and the Source Waters of the Pacific EquatorialUndercurrent. J. Phys. Oceanogr., 28, 72–84.

Schlosser, P., 1992: Tritium-helium dating of waters in naturalsystems. In: Isotopes of noble gases as tracers inenvironmental studies, IAEA.

Toole, J., E. Zou, and R. Millard, 1988: On the circulation of theupper waters in the Western Equatorial Pacific Ocean.Deep-Sea Res., 35, 1451–1482.

Tsuchiya, M., R. Lucas, R. Fine, and E. Lindstrom, 1989: SourceWaters of the Pacific Equatorial Undercurrent. Prog.Oceanogr., 23, 101–147.

Weiss, R., and W. Roether, 1980: The rates of tritium input intothe world oceans. Earth Planet. Sci. Lett., 49, 435–446.

Wijffels, S., 1993: Exchanges between hemispheres and gyres: Adirect approach to the mean circulation of the EquatorialPacific. MIT/WHOI thesis.

Wyrtki, K., 1967: Circulation and water masses in the easternequatorial Pacific Ocean. J. Oceanol. Liminol., 1, 117–147.

Wyrtki, K., and B. Kilonsky, 1982: Transequatorial water structureduring the Hawaii to Tahaiti Shuttle Experiment, Univ.Hawaii. HIG, 77-1, 65pp.

Ocean general circulation models provide the foundationupon which ocean carbon-cycle models are built. Thesuccess of the latter in simulating the distribution of oceaniccarbon and related biogeochemical tracers is closely tied tothe skill of the former in predicting patterns of oceancirculation. For this reason, recent efforts in the oceancarbon-cycle community to compare global-scale modelshave included substantial emphasis toward validatingmodel-predicted patterns of ocean circulation.

The Ocean Carbon-Cycle Model IntercomparisonProject (OCMIP) began in 1995 as an effort to identify theprincipal differences between existing ocean carbon-cyclemodels. This effort was initiated via the Global, Analysis,Interpretation, and Modelling Task Force (GAIM) of theInternational Geosphere Biosphere Programme (IGBP).The first phase of this project (OCMIP-1), included fourgroups (Max Planck Institute of Meteorology, Hamburg;Princeton University/GFDL, Princeton; Hadley Centre,

Ocean Circulation and the Ocean Carbon-CycleModel Intercomparison Project

James C. Orr, LSCE, Unite Mixte CEA-CNRS, CEA Saclay, [email protected]

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International WOCE Newsletter, Number 35, June 1999 page 25

UK Met. Office, Bracknell; and Institute Pierre SimonLaplace, Paris). Emphasis during OCMIP-1 focused bothon the natural and anthropogenic components of oceaniccarbon and radiocarbon (14 C) .

The natural component of 14 C is particularlyinteresting as a tracer of deep-ocean circulation becausehorizontal and vertical gradients are produced in the oceandue largely to its radioactive decay (half-life of 5730 years).Thus natural 14 C provides invaluable time-dependentinformation, unlike other more classical tracers such astemperature and salinity (e.g., see Toggweiler et al., 1989).During OCMIP-1, modellers compared simulated natural14 C with the observed natural component of C-14 asestimated by Broecker et al. (1995) from measurementstaken during GEOSECS.

An example of the utility of 14 C , is shown by theOCMIP-1 comparison along the GEOSECS section in theWestern Atlantic (Fig. 1, page 22). To properly simulatenatural C-14 in the Western Atlantic, a model must obtainthe proper balance between filling of its deep North Atlanticwith NADW from the north, and infiltration of AABWfrom the south. Observations along the Western AtlanticGEOSECS section reveal that the basin north of the equatoris filled with young waters (all less than 500 years old)penetrating from the north. The youngest deep waterpenetrating south is a tongue at mid-depth, centred at2500 m. Antarctic waters have an older signature, despitetheir recent contact with the atmosphere, due to mixingwith the ocean’s oldest waters from the Pacific. AntarcticWaters penetrate northward both along the bottom (AABW)and at intermediate depths (AAIW).

In the GFDL/Princeton model, younger waters fromthe north penetrate southward but they extend no deeperthan 2500 m. The 14 C signature of this problem was firstidentified by Toggweiler et al. (1989). The GFDL model’soldest Atlantic deep waters are found at depth in the north,unlike the observed distribution, which has the oldest deepwaters in the south. In a more realistic fashion, the MPI,Hadley, and IPSL models simulate younger waters whichfill the entire North Atlantic basin. All three of these modelssimulate a tongue of younger water penetrating from thenorth (NADW) confined by “older” water both above(AAIW) and below (AABW). However the skill variesbetween these three models in their ability to reproduce theobserved distribution. For example, the general distributionin the MPI model appears somewhat too smooth, the ageminima in the tongue of NADW in the Hadley modelappear too shallow, and the along-bottom gradient north of40°N in the IPSL model has a vertical instead of a horizontalstructure.

Further analysis of the time information from natural

14 C in the Western Atlantic reveals that the MPI, Hadley,and IPSL models all exhibit inadequate northwardpenetration of AABW. In contrast are 14 C results from theGFDL model which shows excessive northward penetrationof AABW due to lack of a deep component of NADW. Asimilar pattern of inadequate northward penetration ofAABW was found along the Western Pacific GEOSECSsection, in all four models.

These and other large differences between models,particularly in the Southern Ocean, have prompted modellersto launch a second phase of OCMIP. That effort involves 13different models and new simulations for additional tracersof ocean circulation and biogeochemistry. A key componentof OCMIP-2 involves the recent capability to exploitessential new data sets for CFC-11, CFC-12, 14 C , andCO2 , thanks to the collaborative efforts of associatedobservationalists who are leading related WOCE and JGOFSdata synthesis efforts. During the first two phases, OCMIPhas compared simulations run under present climatologicalconditions, where circulation patterns vary only seasonally.A third phase of OCMIP is currently being planned duringwhich model comparison will focus on the impact ofclimate change on air-sea fluxes of CO2 and marineproductivity. Those coupled carbon-climate models will beevaluated by diagnosing their ability to reproduce observedinterannual to decadal variability.

The OCMIP modellers and data specialists havepooled resources and defined a battery of standardisedvalidation tests. These detailed tests are more rigorous,better documented, and thus easier to implement than thosenormally applied by individual groups. Furthermore,OCMIP has also produced a legacy of standard forcingfields, common analysis tools and techniques, and databasesof selected model output and observations, all of whichfacilitate model-data and model-model comparison. Theocean carbon-cycle community now has a growingreference, accessible to both modellers and observationalists,which would not exist had it not been for OCMIP. Theseefforts are leading to accelerated diagnosis and improvementof ocean carbon-cycle models. More information concerningOCMIP can be found on its Web page (http://www.ipsl.jussieu.fr/OCMIP/).

References

Broecker, W. S., S. Sutherland, W. Smethie, T.-H. Peng, and G.Ostlund, 1995: Oceanic radiocarbon: Separation of thenatural and bomb components. Global Biogeochem. Cycles,263–288.

Toggweiler, J., K. Dixon, and K. Bryan, 1989: Simulations ofradiocarbon in a coarse-resolution world ocean model: 1,Steady-state prebomb distributions. J. Geophys. Res, 94,8217–8242.

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page 26 International WOCE Newsletter, Number 35, June 1999

CFC-11 age on σθ = 27.2

CFC-11 age on σθ = 24.5

CFC-11 age on σθ = 27.0

CFC-11 age on σθ = 26.0CFC-11 age on σθ = 26.5

10

20

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C-1

1 ag

e (y

r)

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v v v v v v v v v v v v v v v v 23 24 26 22 21 20 19 18 17 16 15 11 10 9 8 7

km

10

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e (y

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112° 116° 120° 124° 128° 132°E12°S

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Water from the western Pacific flows through the IndonesianSeas following different pathways and is modified byprocesses that vary seasonally and interannually. Theprocesses are studied using data from three cruises in 1993,1994, and 1996. An inverse-model analysis using salinityand CFC-11 data is done for a vertical section along themain path of flow, from the Makassar Strait to the FloresSea and Banda Sea. The model reproduces the seasonal andinterannual variability of the Throughflow and showsreversals of flow in the vertical structure. The modelsolutions suggest strong baroclinic flows during south-east

monsoon (SEM) of 1993 and 1996 and a small, morebarotropic flow during north-west monsoon (NWM) of1994. The water masses observed in the region can beaccounted for by isopycnal mixing of different sourcewaters, backflushing, and by vertical exchanges, which aresignificant in this region.

Introduction

The circulation and transport through the Indonesian Seashave a large annual variation due to the strong monsoonalchange in the wind pattern in this area. Three Arlindocruises were made during different monsoon periods tostudy the change in the circulation pattern and processes inthe Indonesian Seas. The three cruises are Arlindo Mixing1993 (AM93) from 6 August to 12 September 1993 in aSEM period, Arlindo Mixing 1994 (AM94) from 26 Januaryto 28 February 1994 during the NWM, and Arlindo

Circulation 1996 (AC96)from 18 November to15 December 1996 during anintermonsoon between SEMand NWM.

Changes in the flowpattern and transport vari-ability in turn produce changesin the water mass and proper-ties. During different mon-soon seasons, water fromdifferent sources flows to theIndonesian Seas, and the resultcan be seen in the variation ofsalt, temperature, and othertracers from the surface downto the lower thermocline(Fig. 1, page 22) (Gordon andFine, 1996; Ilahude andGordon, 1996). Localprocesses such asprecipitation and coastalupwelling also contribute tothese changes.

Transient tracer dis-tributions are often used todetermine the spreadingpattern of a water mass.CFC-11 distributions duringthe Arlindo cruises indicate amain Throughflow pathwayof North Pacific thermoclinewater flowing through

Spreading and Velocity Patterns of the Indonesian Throughflow

Jorina M. Waworuntu, Rana A. Fine, and Donald B. Olson, Rosenstiel School of Marine andAtmospheric Science, University of Miami, USA; and Arnold L. Gordon, Lamont-DohertyEarth Observatory of Columbia University, USA. [email protected]

Figure 2. CFC-11 derived ages on σθ surfaces along different sections during AC96.

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International WOCE Newsletter, Number 35, June 1999 page 27

Makassar Strait. At intermediate levels, mainly SouthPacific water spreads southward and westward through thechannels east of Sulawesi (Fig. 2).

In many areas in Indonesia, the surface currentsswitch direction following the monsoon wind patterns(Wyrtki, 1961; Mariano et al., 1995). Changes in thedirection of the surface current suggest that the flow ishighly baroclinic. The Pacific to Indian Ocean pressuregradient across the shallow sills surrounding the area andthe change in direction and strength of the wind presumablyforce the baroclinic flow throughout the whole region.Vertical motion could also play an important role in thewater distribution and transformation in this region. Lackof direct and long term measurements make it difficult toget a complete picture of circulation and processes in theregion, especially the vertical distribution of the circulation.

The inverse model

The tracer distribution at a certain location is a result of theadvection and mixing history prior to the observation. Thedistribution is also subject to the different boundaryconditions for each individual tracer. The observed tracerdistribution reflects the dynamics integrated over time. If a

system is stationary and there are enough linearlyindependent tracers, it is possible to obtain an optimalsolution of the circulation field and mixing parameters thatcan produce the observed tracer field.

A steady advective-diffusive equation for aconservative tracer C can be written as

− ∇ + ∇ ∇ =v. .(C K C) 0

A steady advective-diffusive equation for an idealtracer age T can be written as

− ∇ + ∇ ∇ + =v. .( )T K T 1 0

The factor one comes from the increase in age by one perunit time, if we follow a particle from the time it leaves thesurface.

An inverse method similar to that of McIntosh andVeronis (1993) is used to quantify the advective anddiffusive processes in the eastern Indonesian Seas. Themodel is applied to a two-dimensional vertical sectionalong the flow path from Makassar Strait to Flores Sea andBanda Sea (Fig. 1), for 1993, 1994, and 1996. It is assumedthat these Straits and Seas act as a channel, and the flow andtracer fields are uniform across the channel. A quasi steadystate is assumed for the tracer distributions.

The model input is salinity and CFC-11 agedistribution. The model solves the horizontal andvertical velocities. Vertical diffusivity Kv is assumeduniform throughout the channel. There is no horizontaldiffusivity in the model. The optimal solution isobtained by minimising a penalty function andsmoothing the solution field simultaneously.

Fig. 3 shows the optimal solution for horizontalvelocity profiles for K m sv = −10 3 2 / . Other dif-fusivities larger than 10 m /s-5 2 will give very similarvelocity profiles, scaled with the mixing coefficientused.

Discussion

The optimal solutions of the inverse calculation suggestthat strong baroclinic flows occur during AM93 andAC96. On the other hand, a small and more barotropicflow is the optimal solution obtained for the tracerdistribution in AM94. The seasonal flow variabilitygiven by the solution supports the observation that theThroughflow is minimum during the NWM season. Inthe large diffusivity case, the horizontal velocity forthe AM94 (NWM) is about 15% to 20% of the velocityin the AM93 (SEM) and AC96 (end of SEM).

While the pattern of the circulation in theIndonesian Seas strongly depends on the local forcingand the distribution of boundaries, the strength of theThroughflow seems to be more closely related to thepressure difference between the remote Pacific andthe Indian Ocean. The solutions show a relativelystronger flow to the east in the upper thermoclineduring AC96 compared to AM93. This supports theargument that during a La Niña phase, the build-up ofthe warmpool in the western Pacific will strengthen

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3 2= − . The dashed lines are the corresponding residualhorizontal velocity.

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page 28 International WOCE Newsletter, Number 35, June 1999

the Throughflow (Gordon and Fine, 1996; Gordon et al.,1998).

The model solutions show that the eastward flow in1996 is also accompanied by a reversal flow to the west inthe lower thermocline. The strengthening of the pressuregradient in the lower thermocline between the PacificOcean and the Indonesian Seas during a La Niña year couldincrease the flow in the deeper thermocline through theeastern passages.

This study shows marked changes in the Through-flow volume and character seasonally and interannually.The model is also able to estimate the vertical exchangeprocesses that are important to the local weather pattern andproductivity.

References

Gordon, A. L., and R. A. Fine, 1996: Pathways of water betweenthe Pacific and Indian Oceans in the Indonesian Seas.Nature, 379, 146–149.

Gordon, A. L., R. D. Susanto, A. Ffield, and D. Pillsbury, 1998:Makassar Strait transport: Preliminary Arlindo results fromMAK-1 and MAK-2. Int. WOCE Newsl., 33, 30–32.

Ilahude, A. G., and A. L. Gordon, 1996: Thermocline stratificationwithin the Indonesian Seas. J. Geophys. Res., 101, 12401–12409.

Mariano, A. J., E. H. Ryan, B. D. Perkins, and S. Smithers, 1995:The Mariano Global Surface Velocity Analysis 1.0.Technical Report CG-D-34-95, US Coast Guard.

McIntosh, P. C., and G. Veronis, 1993: Solving underdeterminedtracer inverse problems by spatial smoothing and crossvalidation. J. Phys. Oceanogr., 23, 716–730.

Wyrtki, K., 1961: Physical oceanography of the south east Asianwaters. NAGA Report Vol. 2, 195 pp., Scripps Institute ofOceanography, La Jolla, USA.

The WOCE-AIMS Tracer Workshop was held at theUniversity of Bremen, 22–26 February 1999 as one of thetopical workshops arranged by international WOCE tostructure the data evaluations during WOCE-AIMS andpossibly beyond. More than 70 people from 8 countriesattended, and with a few exceptions, all groups active inocean tracer observations and in tracer modelling wererepresented. The workshop started with a series of invitedoverview talks on the role of tracer studies in physical,chemical and biological oceanography to structure thesubsequent discussions. This was followed by workinggroup and plenary meetings focused on various aspects ofthe WOCE tracer data, their evaluation, and subsequentincorporation into numerical models. Individual scientificprojects were presented through an ongoing poster sessionover the week.

The tasks of the workshop had been defined in advanceby the a planning group (W. Roether, S. Doney, W. Jenkins,Y. Watanabe, W. Smethie, C. Böning, and M. England)coordinating with WOCE SSG and WOCE IPO:(1) Further the oceanographic interpretation of the WOCE

tracer data sets(2) Encourage the synthesis, compilation and dis-

semination of tracer data sets.(3) Establish mechanisms for the production of data

products (gridded and derived) for the use of a broadercommunity.

(4) Identify strategies to facilitate assimilation andincorporation of tracer data into models.

(5) Initiate collaboration and interaction between tracergeochemists and modellers.Discussions during the meeting were lively, with a

general consensus that the workshop was timely, providinga good basis for meeting the targets of WOCE-AIMS. Thecompilation and initial interpretations of the WOCE tracerdata set are well underway and considerable scientific

progress is to be expected with the completed WOCE dataset now in hand. There were four major working groupsaddressing(i) physical oceanographic issues and tracers,(ii) biogeochemical issues and tracers,(iii) model—data interaction, and tracer data issues.

A smaller group dealt with assimilation of tracer dataand other modelling issues of a more general character.Future developments of the field were covered a series ofopen ended plenary discussions. The working groups werespecifically tasked to address four issues: the status of theWOCE tracer data set and its evaluation; the scientificachievements of the WOCE era tracer work to date; andcurrent questions/limitations and future directions for thework. The outcome of the working groups and plenarysessions have been synthesised into a set of general workshoprecommendations:• Complete the WOCE tracer data synthesis for both

the primary analysis (basin and global scale merging,quality control and inter-calibration) and thecalculation of appropriate second order statistics andsynthetic data products (e.g. basin inventories,sampling error estimates, gridded fields, and timeadjusted isopycnal surface distributions).

• Quantify and reduce major sources of uncertainty fortracer analysis and modelling. On-going numericalmodelling progress requires further refinement ofsurface and, for regional models, lateral tracerboundary conditions, quantitative estimates ofmesoscale tracer sampling error, and estimates of therepresentativeness of the WOCE tracer data withrespect to seasonal and inter-annual variability.

• Combine the WOCE tracer data synthesis withhistorical and contemporaneous non-WOCE tracerobservations by identifying the relevant data sets,providing broad access through the WHPO when

WOCE-AIMS Tracer Workshop

Scott C. Doney, NCAR, USA; and Wolfgang Roether, Universität Bremen, Germany. [email protected]

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International WOCE Newsletter, Number 35, June 1999 page 29

possible, and encouraging collaborations on thescientific interpretations of the data. Critical datagaps in the WOCE tracer observations, such as in thewestern South Pacific or Southern Ocean, have beenidentified and should be re-adressed either throughanalysis of available non-WOCE data or specificallytargeted field cruises.

• Encourage co-operation between the tracer modellingand observational communities to interpret fieldobservations, evaluate model skill and diagnose modelbehaviour. Specific activities include promoting theincorporation of tracers into high resolution modellingand data assimilation efforts, the public distributionof model results (e.g. simulated tracer data on allWOCE sections), and the development of integralmeasures for comparing observations and modelssuch as basin and water mass inventories andmeridional transports (e.g. silica transport constraints).

• Promote synthesis and modelling research on multi-tracer and multi-variable approaches for evaluatingocean general circulation model skill and behaviour(e.g. property-property plots) and for improving ourunderstanding of specific oceanographic processesthrough a hierarchy of traditional data analysismethods, conceptual models, inverse techniques andocean general circulation models.

• Enhance legacy of WOCE tracer data set as a bench-mark for future ocean change research through thelinking of the WOCE data to long term ocean observ-ational programmes and renewed efforts on inter-national oceanographic chemical reference standards,both to maintain existing efforts (e.g. for CFCs,inorganic carbon) and to develop new ones (e.g. fornutrients).The following recommendation goes beyond the

specific scope of WOCE:• Explore future scientific applications of ocean tracers

to process studies. Natural tracers and in particulartracer release experiments (TREs) have been and willcontinue to be key elements for hypothesis driven

process studies in both ocean physics (e.g. diapycnaland lateral mixing, convection), chemistry (e.g. gasexchange) and biology (e.g. iron fertilisation). Adetailed discussion, in the form of a white paper, forfuture opportunities in this area is required thataddresses the expanding spectrum of scientific issues,the rapid technological developments (e.g.autonomous sensors, moored water samples, newchemical tracers) and the role of process levelmodelling.Moreover the group sees a need for action on the

following items and urges the WOCE SSG to endorse theseitems and to help to translate them into action:• Provide resources for national and international

scientific synthesis activities for the WOCE tracerdata beyond simply the construction of the basin andglobal calibrated and quality controlled data sets.

• Promote strong interactions with relevant, externaloceanographic communities. The WOCE ocean tracerobservations form a natural bridge between WOCEand existing and emerging physical (CLIVAR, polarprogrammes) and biogeochemical programmes(JGOFS, SOLAS), and joint higher level synthesisand modelling activities should be actively pursued.

• Develop a strategic plan outlining the transition to along-term ocean tracer and hydrographic observationalprogramme. Standard analysis techniques andnumerical models, both in the forward and inversesenses, demonstrate a compelling need for on-going,long term tracer measurements building on the WOCEdata. The workshop recommends the formation of acommittee to draft a white paper, to be completed inapproximately one years time, addressing in detailissues of scientific objectives, implementation,sampling strategies (e.g. time series, repeat sections),and technological developments (e.g. sensors,platforms).The complete report from the WOCE-AIMS tracer

workshop is currently being compiled and should beavailable from the WOCE IPO by Fall of 1999.

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page 30 International WOCE Newsletter, Number 35, June 1999

One of the key problems in oceanography is understandinghow the depth of the oceanic pycnocline is set. In the pastfifteen years, work by a number of authors has provided atheoretical framework for understanding the wind-drivenpycnocline. Less progress has been made for the deeppycnocline, however. Munk (1966) proposed a picture inwhich the pycnocline is maintained by a balance betweendownward mixing of heat and upward advection of densewater. By assuming that the total upwelling was equivalentto the total formation of dense water (~30 Sv), he estimateda pycnocline diffusion rate of order 1 2cm s/ . Bryan (1987)extended this work to an idealised three-dimensional domainwith a flat bottom. He showed that the upwelling is consistentwith a deep anticyclonic and surface cyclonic flow. Theboundary current associated with the surface cyclonic flowadvects warm water polewards resulting in a strong polewardheat flux. Bryan then used the assumption first made byStommel (1961) to link the magnitude of the flow in theboundary current to the pressure gradient. He ended up witha scaling in which the sinking of deep dense water in thenorthern hemisphere was proportional to the square of thepycnocline depth D

T g Dn = ′ 2 / ε (1)

where g’ is the reduced gravity between the pycnocline andthe deep ocean and ε is a frictional resistance. Fromobservations, ( ,T Svn =18 D ~ 600 m) one can estimate

′g / ε to be around 50 3m s/ . Tn represents a conversion oflight water to dense water. In order for the oceanic densityfield to be at steady state there must be a counterbalancingconversion of light water to dense water. As shown inFig. 1, this conversion can either take place in the pycnoclineor in the Southern Ocean, where Circumpolar Deep Water

is freshened to become Antarctic Surface Water and thenwarms as it moves northwards. If the conversion of denseto light water within the pycnocline is denoted as Tu and theconversion of dense to light water in the Southern Ocean isdenoted Ts, it is possible to derive a simple theory forpredicting the depth of the pycnocline (Gnanadesikan,1999).

The upwelling flux in the pycnocline can be easilysolved by noting that an advective-diffusive balance(following Munk, 1968) gives

w T A K Du v= =/ / (2)

where A is the area over which low-latitude upwellingoccurs and Kv is the diffusivity within the pycnocline.Then

T K A Du v= / (3)

The ocean area in latitudes lower than 40° is about2 5 1014 2. .× m This means that if D is 600 m and Tu were18 Sv, Kv would have to be about 0 43 2. / .cm s This ismuch larger than microstructure and tracer releaseexperiments have shown (Ledwell et al., 1993).

In a recent paper (Gnanadesikan, 1999) I revisited thisquestion, looking at the effect of adding a Southern Oceanpath for ocean freshening. The upwelling is allowed toeither draw up dense water from below the pycnocline, orto be supplied by relatively light water from mesoscaleeddies. The additional flux of water has the form

T Lxf

A D

Ls xI

y

= −

τρ (4)

where τx is the wind stress in Drake Passage, |f| is theCoriolis force in Drake Passage, Lx is the circumference of

the globe in Drake Passage, AI is anisopycnal mixing coefficient, and Ly isthe meridional length scale over which thepycnocline shallows in the Southern Ocean.When put together with eqns 1 and 3, thisyields a cubic equation in the pycnoclinedepth D. Fig. 2 shows a sample solutionfor A m sI = 1000 2 / . If the effect of windsis neglected, a high value of pycnoclinediffusivity is needed to get a pycnocline ofreasonable depth. However, if SouthernOcean winds are included, very littlemixing at all is required, in accordancewith observations. Gnanadesikan (1999)shows that this model does a qualitativelygood job at predicting the response of thepycnocline to Southern Ocean winds andeddy processes within a large-scale model.

Connecting the Southern Ocean with the Rest of theWorld: Results from Large-Scale Ocean Models

Anand Gnanadesikan, AOS Program, Princeton University, [email protected]

Lys

T

DNorthern

Upwelling

Light WaterLow Latitude

u

n

T

Southern Ocean Northern Oceans

Dense Water

SouthernOcean Surface

Lyn

Ekman flux

Eddy Ts SinkingReturn flow

Figure 1. Basic schematic of the overturning scheme discussed in Gnanadesikan(1999).

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International WOCE Newsletter, Number 35, June 1999 page 31

What does this have to do with WOCE (and CLIVAR)?What I’d like to emphasise in this article is the contrastbetween a world where most dense water upwells throughthe low latitude pycnocline, and one in which most of theconversion of dense water to light water occurs in theSouthern Ocean. Observations such as WOCE could helpus to make sense of which picture is more accurate. If theSouthern Ocean pathway is dominant, this has a number ofimportant implications:1. It places strong limits on the total productivity of the

world ocean. The average silicate content of water at600 m is ~80µmol. If 18–20 Sv of this water upwellsinto the low-latitudes (where surface silicate is low) itwould imply 50 Tmol/yr of biogenic silica wouldhave to sink across depths of 500–1000 m in the lowlatitudes. If the high silicate deep water is brought tothe surface in the Southern Ocean, silica productioncould be far lower.

2. It affects the stability of the climate system. In theabsence of Southern Ocean eddies and pycnoclinediffusivity, the Northern Hemisphere overturning mustsimply equal the Southern Hemisphere Ekmantransport as long as the NADW is denser than the

AAIW. This means that freshening in the NorthAtlantic due to climate change would simply causethe pycnocline to deepen, but would not (in the longrun) cause the Northern Hemisphere sinking to decline(see also Keeling, subm.). Including eddies, howeverdoes cause the overturning to decline slightly.

3. It affects the response of the Antarctic CircumpolarCurrent to winds. A substantial portion (~75%) of theCircumpolar Current transport within Drake Passageis due to velocity shears occurring above 2500 m(Whitworth, 1983). These shears arise from densitygradients across the current. This model suggests thatthese north-south density gradients are linked to theSouthern Ocean winds so that increases in the SouthernOcean winds will produce an increase in the strengthof the current. A number of investigations here atPrinceton and GFDL, (Toggweiler and Samuels, 1995;Gnanadesikan and Hallberg, subm.) seem to confirmthis idea.What sorts of light can WOCE cast on this problem?

I would like to highlight two key areas which would putstrong constraints on ocean models:1. We need a better understanding of what happens to

the Antarctic Surface Water after it leaves the Ekmanlayer. How does it get transformed into AntarcticIntermediate Water and what portion of this fluxflows into the North Atlantic?

2. Similarly, we need a better picture of what happens tothe North Atlantic Deep Water. How much of it endsup in the Southern Ocean surface and how muchmoves through the pycnocline? Nutrient based tracerssuch as PO may be extremely useful in this respect.

References

Bryan, F., 1987: Parameter sensitivity of a primitive equationocean general circulation model. J. Phys. Oceanogr., 17,970–985.

Gnanadesikan, A., 1999: A simple predictive model for thestructure of the oceanic pycnocline. Science, 283, 2077–2079.

Gnanadesikan, A., and R. W. Hallberg, 1999: On the response ofthe Circumpolar Current to Southern Ocean winds in large-scale models. J. Phys. Oceanogr., submitted.

Ledwell, J., A. J. Watson, and C. S. Law, 1993: Evidence for slowmixing across the pycnocline from an open-ocean tracerrelease experiment. Nature, 364, 701–703.

Munk, W., 1966: Abyssal recipes. Deep-Sea Res., 13, 306–318.Stommel, H.,1961: Thermohaline convection with two stable

regimes of flow. Tellus, 13, 224–241.Toggweiler, J. R., and B. Samuels, 1995: Effect of Drake Passage

on the global thermohaline circulation. Deep-Sea Res., 42,477–500.

Whitworth, T., 1983: Monitoring the transport of the AntarcticCircumpolar Current at Drake Passage. J. Phys. Oceanogr.,13, 2045–2057.

0 0.05 0.1 0.15 0.2 0.250

0.2

0.4

0.6

0.8

1

Wind Stress (Pa)

Kv

2 (

cm/s

)

Pycnocline Depth (m)

600800 1000

Figure 2. Solutions of the cubic equation in pycnocline depthobtained by setting the northern sinking flux equal to theupwelling flux in the pycnocline plus the net upwelling of deepwater in the Southern Ocean. Note that the observed pycnoclinedepth of around 600 m can be obtained either by having veryhigh vertical diffusion, but low winds, or moderate winds andlow vertical diffusion.

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page 32 International WOCE Newsletter, Number 35, June 1999

The joint WOCE/CLIVAR Data Products Committee (DPC)held its twelfth meeting at the British Oceanographic DataCentre at CCMS/POL in Bidston, UK. The purpose of themeeting was to continue the development of the integratedWOCE data resource, and to advance the planning of aCLIVAR data, information and products system. The DPCcombines both scientists and data managers and for the firsttime was joined by members of the new CLIVAR DataTask Team, thus meeting as a joint WOCE and CLIVARgroup.

Following the enthusiastic reception of Version 1.0of WOCE Global Data on CD-ROMs (May 1998), the DPCis progressing towards the goal of a fully integrated WOCEdata resource by 2002. The next issue of the Global Data(Version 2.0) will be published in mid-2000 and a stepcloser to that goal. Much of the meeting was spent devisingways to achieve closer links between the various data sets,and to make access for users easier and quicker. The mainimprovement planned for Version 2.0 is that the user willbe able to search all data sets on such common parametersas geographical area, date and time. This facility can best beachieved if all data sets are present in a common file typeand only with standardisation of the above headerinformation. There are clear advantages too in stan-dardisation of the variable names.

The DPC discussed the advantages and disadvan-tages of NetCDF as a file format that might prove to be theway to achieve integration of the numerous data types.NetCDF is freely available and popular among manymodellers, ocean, atmosphere and climate researchers andis used by some WOCE data centres already (see P.McIntosh’s article in International WOCE NewsletterNo. 31). The principle advantage of NetCDF for the DPCis that it is self-describing, which in plain language meansthat there is no need to define data formats; each filecontains sufficient information for software to be able toread it without the user specifying the format first. Thereare still concerns about just how practical NetCDF will befor data centres to export data, and for users to access data.Before committing themselves to NetCDF for Version 2.0,the DPC has tasked all the WOCE data centres to make trialdata files which members of the IPO and DIU who havelittle or no experience of NetCDF will use and assess.Before this can happen a working group from the DPC iscompiling a comprehensive list of header information,variable names and units etc. that need to be standard.Despite the possible move to a non-ASCII format, the DPCis still intent on ensuring that the WOCE Global Data are

available to all users. NetCDF files are readable by manyexisting data visualisation and manipulation packages onall platforms, and there exists free software which exportsASCII files from NetCDF.

The future versions of the WOCE Global Data willalso be more complete in terms of the data sets they include.Each data centre continues to work hard to increase theirholdings and obtain permission from the data providers tomake data public. Version 3.0 will be the final archive, anddata which are not available at that stage will not bearchived as a contribution to the WOCE programme.Lowered ADCP data, and temperature and salinity profilesfrom profiling floats do not presently have homes withinthe WOCE data system and the DPC is considering howthese data can be archived for WOCE and the future. TheUS NODC is the WOCE archive centre and is generouslyproviding the resources for the publication of Versions 1.0,2.0 and 3.0 of the WOCE Global Data, and is activelyparticipating in the discussions on how to create theintegrated data resource. NODC is holding continueddiscussions with data centres on how to transfer the dataresource to their databases and archives with all theinformation intact.

One day of the meeting was taken up with CLIVARdata issues which are rather different from WOCE issuesbecause of their broader scope (oceanic, atmospheric andterrestrial) and the emphasis on rapid delivery of data tousers. The Data Task Team must define and develop a datasystem that will ensure the scientific objectives of CLIVARare met; no small task and one which requires vision as wellas an understanding of the modular yet global nature of theprogramme. The committee was given a comprehensiveguide through the acronym-maze of relevant internationalclimate research programmes and their data managementactivities, because it is clear that CLIVAR will not exist inisolation but will draw on the expertise and facilities of itscompanion programmes. As the Task Team defines theobjectives of the CLIVAR data system and outlines amodel of how it may function, they will draw on theirextensive expertise to outline the data streams that make upthe CLIVAR data resource. CLIVAR-type observationsare already being taken and clearly some tracking of suchactivities needs to begin straight away before the datasystem is fully operational.

A list of the DPC terms of reference and members canbe found at http://www.soc.soton.ac.uk/OTHERS/woceipo/coms.html. Details of the CLIVAR Data Task Team can befound at http://www.dkrz.de/clivar/data.html

Developing the WOCE and CLIVAR Data Resources: AReport on the WOCE/CLIVAR Data Products Committeein April 1999

N. Penny Holliday, Southampton Oceanography Centre, [email protected]

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International WOCE Newsletter, Number 35, June 1999 page 33

The inflow of Atlantic Water to the Nordic Seas (NorwegianSea, Iceland Sea, Greenland Sea) across the Greenland-Scotland Ridge is of major importance both for the regionalclimate of the area through its heat import and for the globalthermohaline circulation through its import of water andsalt to the regions of deep and intermediate water formation.The inflow occurs through three branches (Fig. 1), butpreviously only the weakest of these, the inflow west ofIceland, has been systematically monitored by currentmeasurements.

The “Nordic WOCE” programme was established asa joint Nordic component of WOCE which focused on theexchanges across the Greenland-Scotland Ridge. One ofthe main aims of the programme was to measure fluxes ofwater, heat and salt in the Atlantic inflow. The field phaseof the Nordic WOCE programme was finished in mid-1997, but the equipment acquired within the programmehas been used within the MAST-funded VEINS (Variabilityof Exchanges In the Northern Seas) project in a continuingstudy with similar objectives.

Velocity and water mass observations

The Iceland-Scotland region is a heavily fished area. Thishas severely limited previous observational efforts tomeasure the fluxes over the Greenland-Scotland Ridge.

The Nordic WOCE programme therefore has relied uponAcoustic Doppler Current Profilers (ADCPs) which maybe moored at depths below the intensive fishery or inprotected frames on the bottom while still being able tomeasure velocity profiles covering most of the Atlanticwater layer.

As part of the programme, ADCPs have been mooredat 8 semi-permanent sites on two sections that cross the twomain branches of Atlantic water inflow (Fig. 2). Over theScottish slope region, our own observations have beensupplemented by ADCP data obtained from the North-western Approaches Group through a data exchangeagreement.

In addition to the moored equipment, CTD-observations have been carried out by research vesselsfrom the Faroese Fisheries Laboratory and the MarineLaboratory in Aberdeen at least four times a year. Fig. 3shows the average salinity distribution on the two sectionstogether with typical velocity distributions indicating coresover the slopes.

Flux calculations

To estimate the Atlantic water flux through the Iceland-Scotland Gap, each of the two sections in Fig. 3 wasdivided into boxes, each of which was assigned typical

The Atlantic Water Inflow to the Nordic Seas

Bogi Hansen and Karin M. H. Larsen, Fisheries Laboratory, Faroe Islands;Svein Østerhus, Geophysical Institute, Norway; Bill Turrell, Marine Laboratory,Scotland; and Steingrìmur Jónsson, Marine Research Institute and University ofAkureyri, Iceland. [email protected]

4 Sv115 TW

3 Sv130 TW

1 Sv25 TW

1 Sv

9.4 °C35.31

Iceland

Shetland

Faroes

7.4 °C35.12

Faro

e-S

het

lan

d C

han

nel

Iceland- Faroe Ridge

Den

mar

k S

trai

t

Scotland

Green-land

Figure 1. The Greenland-Scotland Ridge separates the Nordic Seas from the North Atlantic and the rest of the World Ocean.Areas shallower than 500 m are lightly shaded. The three Atlantic water inflow branches are indicated by arrows withindication (rounded values) of the flux of Atlantic water (in Sv = 10 m s )6 3 1− and heat (in TW 10 W12= , relative to 0°C) ineach branch together with typical temperature and salinity of the water transported. About 1 Sv from the Iceland-Faroes inflowrecirculates into the Faroe-Shetland Channel and joins the flow along the Scottish slope.

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page 34 International WOCE Newsletter, Number 35, June 1999

values for temperature, salinity, and velocity per-pendicular to the section as determined from theobservations. The content of Atlantic water in eachbox was determined from temperature and salinityby assuming the water to be a mixture of three watermasses: Atlantic water (T>7°C, S>35.1), Deep water(T<0.5°C, S=34.9), and more shallow water fromthe East Icelandic Current (T=2.5°C, S<34.85).From this, the total flux of Atlantic water, its heatflux, average temperature and salinity may bedetermined by summing all the boxes.

The results of the flux calculations have beenadded to Fig. 1 and they indicate that the Iceland-Faroe branch (the Faroe Current) dominates intransporting water while the Faroe-Shetland inflowdominates in terms of heat and salt flux.

Budgets

In addition to the Iceland-Scotland inflow, Fig. 1includes the inflow west of Iceland, based onKristmannsson (1998). This gives a total Atlanticwater inflow to the Nordic Seas around 8 Sv with atotal heat flux around 270 TW (1TW = 1012 W).These estimates are preliminary, awaiting moredetailed analysis of the co-variation between thetemperature and velocity fields and between differentbranches of the inflow as well as additional databeing acquired in the ongoing VEINS programme.They are slightly lower than but not inconsistentwith Worthington’s (1970) conjecture.

SE

SDSC

S02 S03 S04 S05 S06 S07S08 S09S10 S11 S12 S13

1000

900

800

700

600

500

400

300

200

100

0N01N02N03N04N05N06N07N08N09N10N11

NC NB

NA

50 km 34.8

34.9

35.0

35.1

35.2

35.3

35.4Salinity

SA

SBDep

th (

m)

FaroePlateau

Scottishslope

ND

Section N north of the Faroe Islands

5

10

1520

-5

0 5

15

20

25

-5

Section S in the Faroe-Shetland Channel

Figure 3. Salinity and velocity on section N and S (Fig. 2). The shading indicates average salinities from 8 CTD cruises onsection N and 19 cruises on section S. Thick lines indicate typical velocity perpendicular to the section in cm/sec, positivetowards the east (section N) or northeast (section S) based on ADCP observations in the period 1995–1998. Hatched area onsection S (right) indicates negative flow (towards the south-west). Quasi-permanent ADCP sites are indicated by open circles.Black circle indicates a special ADCP deployment (ND) from November 1997 to June 1998.

S

N

Shetland

Iceland

FaroeIslands

10 cm/s

A

A

B

B

C

C

DE

Figure 2. The 8 Nordic WOCE ADCP mooring sites for measuringAtlantic water inflow are marked by circles on the two black linesindicating standard sections N (North) and S (South). The traces goingout from the mooring sites are progressive vector diagrams for onedeployment at each site adjusted for deployment length (4 to 12months) to indicate velocity in the scale shown in the lower right-handcorner.

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International WOCE Newsletter, Number 35, June 1999 page 35

Including a Bering Strait inflow around 1 Sv (Roachet al., 1995), a total of 9 Sv are found to enter the ArcticMediterranean (Nordic Seas + Arctic Ocean). Two thirds ofthis inflow, 6 Sv, return to the Atlantic as deep overflowaccording to the best available evidence (Hansen et al.,1998), leaving about 3 Sv to exit in the upper layers of theEast Greenland Current and through the CanadianArchipelago.

The deep overflows are mainly driven by the densitydistribution set up by the thermohaline processes, formingdeep and intermediate water in the Arctic Mediterranean.They require a compensating inflow which apparentlydominates the total inflow, indicating that thermohalineprocesses dominate over direct wind-forcing in driving theAtlantic inflow. The overflows do not appear to vary

greatly on time-scales shorter than a few years (Hansenet al., 1998); but the in- and outflows have to balanceon short time-scales (weeks), as noted by Worthington(1970).

If these qualitative arguments are valid, onlysmall variations should be expected in the total Atlanticinflow on monthly time-scales. Fig. 4 shows along-slope current velocity at one site close to the core ineach of the two main branches. Both sites do showfairly large monthly (25 days) variations; but there isan indication of a counter-phase relationship in the twobranches. These results are therefore not inconsistentwith a fairly constant total inflow, but with rapid shiftsbetween the branches, perhaps influenced by wind.

Using simple Ekman dynamics, increased south-westerlies (high NAO index) might be expected toconcentrate the inflow more along the continentalslope and this may be one explanation for the highcorrelation found further downstream off the Norwegiancoast between NAO and the width of the Atlantic flow(Blindheim et al., submitted). A more rigorous basis for

assessing these conclusions is the main focus of the ongoingobservational effort.

References

Blindheim, J., V. Borovkov, B. Hansen, S. Aa. Malmberg, W. R.Turrell, and S. Østerhus. Upper layer cooling and fresheningin the Norwegian Sea in relation to atmospheric forcing.Deep-Sea Res., submitted.

Hansen, B., S. Østerhus, W. J. Gould, and L. J. Rickards, 1998:North Atlantic-Norwegian Sea Exchanges, The ICESNANSEN Project. Report No. 225, ICES CooperativeResearch, Copenhagen, Denmark.

Kristmansson, S. S., 1998: Flow of Atlantic Water into thenorthern Icelandic shelf area, 1985–1989. ICES CooperativeResearch Report.

Roach, A. T., K. Aagaard, C. H. Pease, S. A. Salo, T. Weingartner,V. Pavlov, and M. Kulakov, 1995: Direct measurements oftransport and water properties through the Bering Strait.J. Geophys. Res., 100 (C9), 18443–18457.

Worthington, L. V., 1970: The Norwegian Sea as a Mediterraneanbasin. Deep-Sea Res., 17, 77–84.

The Faroe Bank Channel is more than 200 m deeper thanany other passage across the Greenland-Scotland Ridge(Fig. 1). It is therefore the main outlet for the densestoverflow of cold water from the Arctic Mediterranean(Nordic Seas + Arctic Ocean) to the North Atlantic and isestimated to carry about one third of the total overflow fluxacross the ridge (Hansen et al., 1998). Since 1988 theFaroese Fisheries Laboratory has monitored thehydrography of the channel with regular CTD cruises alonga standard section south-east of the sill. Since 1995 the

Nordic WOCE and later the VEINS programmes havemaintained a 75 kHz ADCP (Acoustic Doppler CurrentProfiler) mooring in the channel, located on the sill. Tostudy the cross-sectional variation of velocity, an experimentwas mounted in 1998 where the long-term ADCP mooringwas supplemented by two additional 75 kHz ADCPs, oneon either side, on a section crossing the channel during aspecial deployment period lasting about two months fromJuly to September 1998. This was combined with CTDobservations along the ADCP section on three cruises.

The Overflow Through the Faroe Bank Channel

Svein Østerhus, Geophysical Institute, Norway; Bogi Hansen and Regin Kristiansen,Fisheries Laboratory, Faroe Islands; and Peter Lundberg, Stockholm University, [email protected]

0

10

20

30

40

Cur

rent

vel

ocity

(cm

/sec

)

Nov 97 Jan 98 March 98 May 98

East velocity at site NB

Velocity tow. 38° at site SE

Figure 4. Current velocities at 200 m depth at sites NB and SE(Fig. 3), averaged over 25 days, measured simultaneously in theperiod 30 October 1997 to 11 June 1998.

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page 36 International WOCE Newsletter, Number 35, June 1999

Scotland

Norway

30

20

Arctic Ocean

Svalbard

Barents Sea

GreenlandNorway

Iceland

Scot-land

North Sea

Ireland

Jan Mayen

0

200

400

600

800

Denmark Strait Iceland-Faroe Ridge

Gre

enla

nd

Sco

tlan

d

Far

oe

Isla

nd

s

Icel

and Faroe Bank

ChannelWyville-Thomson Ridge

Far

oe

Ban

k

Dep

th (

m )

1000

100 km

FaroeBankChannel

Figure 1. Map of the bottom topography (left). Inserted map shows region around the Faroe Bank Channel and ADCP mooringsites indicated by circles. On both maps, areas shallower than 500 m are lightly shaded. Arrows indicate the path of the overflowthrough the channel. Section below follows the crest of the Greenland-Scotland Ridge along the trace shown on the map.

Vertical profiles

Fig. 2 shows the average velocity profiles from four ADCPdeployments at the central mooring site of the channelcovering a period of almost three years as well as a sampletemperature profile from that site obtained during thespecial deployment period. Cold water dominates thedeepest 200–300 m of the channel and at the central site thiscold water flows north-westwards in a current with averagevelocities exceeding 1 m/sec in the core, centred about120 m above the bottom.

Cross-sectional variation

The cross-sectional variation is shown in a velocity sectionacross the channel for the July-September 1998 specialdeployment period in Fig. 3. This figure shows the highspeed core to be located on the south-western side of thechannel along the slope of the Faroe Bank. On that side ofthe channel, the overflow current only extended a littlemore than 200 m above the sill. On the Faroe side of thechannel, the velocities in the bottom core were smaller, butthe flow extended much higher onto the slope of the FaroePlateau. Fig. 3 also shows the temperature distribution

across the channel on one occasion. To a largeextent the isotherms followed the velocity field.

Flux calculations

To utilise the long-term observations at the centralADCP site, the flux of the deep water through thechannel has been calculated by dividing the cross-sectional area of the channel into a number ofboxes, each of which is assumed to have the samealong-channel velocity as one of the 25 m bins(depth intervals) measured by the ADCP at thecentral site. The flux calculations have been doneboth with horizontal boxes (no cross-sectionalvariation) and with boxes designed on the basis ofFig. 3.

The total water transport through the depthsof the channel is of some interest, but moreimportant is the flux of specific water masses. Thewater in the cold core may be classified into twodifferent water masses (Hansen et al., 1998):Norwegian Sea Deep Water (NSDW) colder than

Northwestward flow (cm/s)0 50 100

400

500

600

700

800

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th (

m)

0 5-1

Temperature at central ADCP site 3 July 1998

Nov.95 - May 96

June 96 - May 97

June 97 - June 98

July 98 - Sep.98

Temperature (°C)

Figure 2. Vectorially averaged velocity profiles along theaxis of the channel (towards 304°) for four ADCPdeployments in the middle of the Faroe Bank Channel.Each filled circle indicates the average velocity in a 25 mlayer (bin) from measurements every 15 or 20 minutes. Thecontinuous curve shows the temperature profile from aCTD cast at this site.

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International WOCE Newsletter, Number 35, June 1999 page 37

-0.5°C, and Norwegian Sea Arctic Intermediate Water(NSAIW) between -0.5°C and +0.5°C. In the literature,water colder than 3°C is often termed “Iceland-ScotlandOverflow Water” (ISOW).

The content of each water mass in the boxes associatedwith each ADCP bin can be determined from thetemperature. Figs. 2 and 3 indicate a relationship betweenthe temperature field and the velocity field. Further study isrequired to clarify on what timescales these two fields co-vary. In this preliminary calculation we have tried both aconstant watermass distribution and one that co-varies withthe velocity distribution.

Long-term fluxes of the overflow

Using the almost three year long series from the centralADCP site, average fluxes have been calculated to 2.5 Svfor the total volume flux below 450 m depth, 1.9 Sv forISOW, and 1.5 Sv of water colder than +0.5°C (NSDW +NWSAIW).

These estimates are preliminary, since a detailedanalysis of the data sets has not been carried out; but theywere not found to depend critically on assumptions ofcross-sectional variation or the coupling of the velocity andtemperature fields. They are therefore not expected to bedrastically revised by the more refined analysis in progress.These estimates are largely consistent with previous, lessdata intensive, estimates (Borenäs and Lundberg, 1988;Saunders, 1990).

The temporal variation of the core velocity at thecentral ADCP site and of the transport of Iceland-ScotlandOverflow water (ISOW) throughout the period are shownin Fig. 4. On a monthly timescale, fairly large variations areseen, but no systematic seasonal signal is obvious in thedata. The figure also has a slight indication of a decreasingtrend in ISOW transport. This would be consistent withlong-term trends that have been reported for the region(Østerhus and Gammelsrød, in press; Turrell et al., in press)and for the Faroe Bank Channel itself (Hansen andKristiansen, in press), but as yet the ADCP measurementsin the Faroe Bank Channel are of too short duration to allowany conclusions on this important question.

References

Borenäs, K. M., and P. A. Lundberg, 1988: On the deep-waterflow through the Faroe Bank Channel. J. Geophys. Res., 93(C2), 1281–1292.

Hansen, B., and R. Kristiansen, 1999: Variations of the FaroeBank Channel overflow. Rit Fiskideildar, to be published.

Hansen, B., S. Østerhus, H. D. Dooley, W. J. Gould, and L. J.Rickards, 1998: North Atlantic-Norwegian Sea Exchanges,The ICES NANSEN Project. Report No. 225, ICESCooperative Research.

Saunders, P. M., 1990: Cold outflow from the Faroe BankChannel. J. Phys. Oceanogr., 20, 28–43.

Turrell, W. R., G. Slesser, R. D. Adams, R. Payne, and P. A.Gillibrand, 1999: Decadal variability in the composition ofFaroe Shetland Channel bottom water. Deep-Sea Res., to bepublished.

Østerhus, S. and T. Gammelsrød, 1999: The abyss of the NordicSeas is warming. J. Clim., to be published.

0

1

2

1995 1996 1997 1998

Core velocity (m/s)

ISOW flux (Sv)

Figure 4. Monthly averaged along-channel velocity at thecore, 117 m above the bottom, at the central ADCP site andthe volume flux of ISOW water through the Faroe BankChannel from November 1995 to September 1998 assumingconstant cross-sectional velocity variation and temperaturefield.

10 km

0

100

200

300

400

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>1.1 m/s 1 m/s

0.9 m/s

0.4 m/s

0.2

m/s

Special ADCP deploymentsouthwestern site

Special ADCP deploymentnortheastern site

ADCP

T<0°C0°T<8°C

Figure 3. A section across the channel in the sill region withaverage along-channel velocity distribution (solid lines)from the special deployment period and temperaturedistribution (dashed lines) from a CTD section obtained atthe end of that period. Water colder than 0°C is darklyshaded while water between 0°C and 8°C is more lightlyshaded. Circles indicate ADCPs.

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page 38 International WOCE Newsletter, Number 35, June 1999

Quality assurance is an essential part of any chemicalanalysis. The measurement of nutrients in seawater hasposed a number of difficulties particularly in terms ofmatrix interference and calibration. Ocean ScientificInternational, who produce the IAPSO seawater standardsfor Practical Salinity, have been working for some years todevelop seawater calibration standards for dissolvednutrients. This article describes that development and thecurrent availability of reference materials and standards.

Certified reference materials

The International Council for Exploration of the Seas(ICES) has expressed an urgent need for the developmentof certified reference seawater for dissolved nutrients.Unfortunately, this expression took place almost a decadeago at the meeting of the IOC-IAEA-UNEP Group ofExperts on Standards and Reference Materials (GESREM)and no such material has appeared to date.

A certified reference material (CRM) is a material orsubstance, one or more properties of which, are sufficientlywell established and certified to be used for the calibrationof an apparatus. In many laboratories, a CRM is analysed,as a sample, to determine the accuracy of analysis as part ofa quality assurance scheme. In the case of nutrients, theideal CRM would be a natural seawater which has beenanalysed, by more than one method, for dissolved nutrients,with confidence limits provided for the determinands.

One of the main problems encountered in theproduction of a CRM, has been the stability of the product.Biological and chemical activity can lead to changes in thenutrient concentrations in short periods of time. Variousforms of chemical preservatives have been used whichinclude organic solvents, formalin, potassium cyanide,sodium fluoride, various acids and mercuric chloride (seeKirkwood, 1992).

The use of additives is generally undesirable as itchanges the matrix of the reference. In addition, mercuricchloride, the most commonly used poison, is known todegrade the efficiency of the cadmium reduction columnson some nitrate analysers. There are also problems associatedwith the handling and transport of solutions containingsuch toxic elements. As a result, some workers haveinvestigated the use of heat as a means of preserving thenutrient concentrations in seawater (Aminot and Kerouel,1991). Uncertified reference materials have been producedfor dissolved nutrients in seawater by the QuasimemeProject (see Topping, 1997). These materials whichcomprise seawaters, spiked with nutrient salts, are providedas part of a laboratory performance study. The QuasimemeProject preserves mixed nutrients in seawater by autoclavingthe samples.

Although reference materials are important in qualityassurance, the preparation of working standards is afundamental component of any chemical analysis. OceanScientific International Ltd. (OSIL) studied the feasibilityof producing commercially available working standardsfor nutrients in seawater. A number of products werealready available from other sources, but none offerednatural seawater matrix at salinity 35.

The need for nutrient standards

The need for seawater nutrient standards has intensified inrecent years, with international programmes such as WOCE,requiring high-quality nutrient data to be collected at sea.Most shipboard analyses are carried out using automatedchemistry systems which measure nutrients colorimetrically.The kinetics, and often the ultimate colour intensities of thechemistry of these techniques, are generally affected by thepresence of seawater matrix salts. Elimination of these salteffects requires that working calibration solutions areprepared in natural low nutrient seawater (LNS) rather thanin demineralised water. The WOCE protocol produced byGordon et al. (1992) stated a preference for the productionof working standards in natural low nutrient seawater(LNS), but recognised that artificial seawater may sufficewhen LNS was unavailable. In continuous-flow analysis,LNS can also be used as a refractive-index blank. This is tocorrect for a false positive absorbance signal, generated bythe refractive effects within the flow cell when salinesamples are run with a demineralised water baseline andinter-sample wash.

Low nutrient seawater

The first requirement of a standard for nutrients in seawater,is the seawater matrix itself. It must be significantly lowerin nutrients than the required standard concentration. Thisis particularly difficult for open ocean measurements whereanalyte levels can be lower than 1_Molar as a result of thesurface-water depletion by plankton. Low Nutrient Seawater(LNS) can be prepared naturally or artificially. OSILregularly collects relatively large quantities of seawaterfrom the mid-Atlantic Ocean for operation of the IAPSOStandard Seawater Service and investigated methods fordepleting the nutrient content. Chemical removal, using co-precipitation techniques with iron and aluminiumcompounds, were found to be effective in terms of nutrientdepletion, but the subsequent removal of the precipitateproved difficult and costly. Biological depletion using aninoculum of plankton to create an artificial ‘bloom’ in thebulk seawater was occasionally successful but was unreliabledue to the difficulty in controlling the conditions for growth.

The Development of Seawater Standards for Dissolved Nutrients

P. S. Ridout, Ocean Scientific International Ltd., UK. [email protected]

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International WOCE Newsletter, Number 35, June 1999 page 39

stiKdradnatStneirtuNeniraM.1elbaT

edoC etylanA xirtaMnoitartnecnoC

)M_(

OPSSN etahpsohP retaWdesinoieD 001

INSSN etirtiN " 001

ANSSN etartiN " 0001

ISSSN etaciliS " 0001

SNL stneirtunllA retaWnaecO 53=SM_1<

As a result, OSIL has now standardised on a practice ofmeasuring each batch of bulk seawater for dissolved nutrientsand reserving the very low measuring batches for bottling.This LNS has the advantage of being naturally depletedwhich, combined with our processing/bottling regime, givesrise to a very stable product. The LNS fulfils all the needsof a seawater matrix for the preparation of standards, carriersolution and RI blank.

Standards preparation

Initial attempts to produce ‘mixed’ nutrient standards inLNS gave rise to the problems of preservation. Although wewere able to stabilise the product using mercuric chloride,this was considered undesirable, by many users, for thereasons described earlier. Another problem, which arose,was defining the most useful working concentration of thenutrients. It became obvious that it would be commerciallyuneconomical to produce the wide range of standardsnecessary to meet all user needs.

The problems described above led to the production ofa range of marine nutrient standard kits (MNSK). Thesecomprise concentrates of single nutrients in deionised water,together with bottles of Low Nutrient Seawater (LNS) -(Table 1).

The user dilutes the concentrate with the LNS toprovide working standards. This method overcomes prob-lems of preservative as the concentrates of single nutrients

in deionised water and the LNS, are stable for long periods.However, once diluted, the working standards should beused immediately after preparation. The concentrate methodalso allows the users to define their own workingconcentration range, thereby overcoming the need for awide range of products. Although a confidence is given forthe nutrient levels in the concentrates and the LNS, the finalworking standard concentration is dependent on the dilutionmade by the user.

Performance evaluation

Although our standards may be used as working calibrationstandards, many laboratories make up their own standardsusing nutrient salts and incorporate our standards as qualityassurance (QA) samples. As a result of user requests, wenow offer Performance Evaluation (PE) samples fordissolved nutrients and salinity. These PE samples aresupplied, ‘unknown’, to analysts who include them in anormal analysis run. After analysis, the measured value foreach PE sample is forwarded to our laboratory where acertificate is issued showing the true value and the analyticalerror.

The need for a certified reference material still existsfor nutrients in seawater. However data quality for marinenutrients can be improved by the careful selection ofstandards, carrier solutions and performance evaluationsamples. Further information may be obtained by contactingOSIL ([email protected]).

References

Aminot, A., and Kerouel, R., 1991: Autoclaved sea water as areference material for the determination of nitrate andphosphate in seawater. Anal. Chim. Acta, 248, 227–283.

Gordon, L. I., Jennings, Jnr., J. C., Ross, A. A., and Krest, J. M.,1992: A suggested protocol for continuous flow automatedanalysis of seawater nutrients. Methods Manual, WHPO,USA.

Kirkwood, D. S., 1992: Stability of solutions of nutrient saltsduring storage. Mar. Chem., 38, 151–164.

Topping, G. (Ed), 1997: Quasimeme quality measurement formarine monitoring. Review of the EU Project 1993–1996.Mar. Poll. Bull., 31, 1–6.

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The WOCE International Newsletter ispublished by the WOCE InternationalProject Office.

Editor:Roberta Boscolo

Compilation and layout:Sheelagh Collyer

The International WOCE Newsletter isdistributed free-of-charge upon requestthanks to the funding contributions fromFrance, Japan, UK, and WCRP.

This Newsletter provides a means ofrapid reporting of work in progressrelated to the Goals of WOCE asdescribed in the WOCE Scientific andImplementation Plan.

Permission to use any scientific material(text as well as figures) published in thisNewsletter should be obtained from theauthors. The reference should appearas follows:AUTHORS, year. Title. InternationalWOCE Newsletter, No., pp.(Unpublished manuscript).

Requests to be added to the mailing listand changes of address should be sentto:WOCE IPOSouthampton Oceanography CentreEmpress DockSouthampton SO14 3ZHUnited KingdomTel. +44 23 8059 6205Fax. +44 23 8059 6204e-mail: [email protected]

Contents of past issues together with theelectronic PDF version can be found at:http://www.soc.soton.ac.uk/OTHERS/woceipo/acrobat.html

Articles, letters, announcements andreviews are welcome and should beaddressed to the editor.

Printed by Technart Ltd.Southern RoadSouthampton SO15 1HGUnited Kingdom.

If undelivered please return to:

WOCE IPOSouthampton Oceanography CentreEmpress DockSouthampton SO14 3ZHUnited Kingdom.

CONTENTS OF THIS ISSUE

❐ News from the IPO W. John Gould 1

❐ Newsletter New Look Roberta Boscolo 2

❐ Tracers

Ventilation of CFC-11 in a Global Ocean Circulation ModelConstrained by WOCE Data Mick Follows, et al. 3

WOCE Chemical Tracer Measurements Aid theAssessment of Ocean Climate Models Matthew H. England 6

Spreading of CFCs in Numerical Models ofDiffering Resolution René Redler et al. 12

North Atlantic Ventilation Constrainedby CFC Observations Thomas Haine and Suzanne Gray 15

Assessing the Importance of Subtropical Watersin Ventilating the Equatorial Pacific Thermocline:a Combined Transient-Tracer Approach S. Peacock et al. 18

Ocean Circulation and the Ocean Carbon-Cycle ModelIntercomparison Project James C. Orr 24

Spreading and Velocity Patterns of theIndonesian Throughflow Jorina M. Waworuntu et al. 26

❐ Other Science

Connecting the Southern Ocean with theRest of the World: Results from Large-Scale Ocean Models

Anand Gnanadesikan 30

The Atlantic Water Inflow to the Nordic SeasBogi Hansen et al. 33

The Overflow Through the Faroe Bank ChannelSvein Østerhus et al. 35

The Development of Seawater Standards forDissolved Nutrients P. S. Ridout 38

❐ Miscellaneous

Ocean and Atmospheric Data Managementbecomes a Journal 5

German WOCE: Final Scientific Seminar,Bremerhaven, 28 April 1999 Ernst Augstein 11

Meeting Timetable 1999/2000 14

WOCE-AIMS Tracer WorkshopScott C. Doney and Wolfgang Roether 28

Developing the WOCE and CLIVAR Data Resources:A Report on the WOCE/CLIVAR Data Products Committeein April 1999 N. Penny Holliday 32