Mass Transfer Model prosidingrepository.ubaya.ac.id/34329/1/Mass Transfer Model... ·...
35
Transcript of Mass Transfer Model prosidingrepository.ubaya.ac.id/34329/1/Mass Transfer Model... ·...
PUPUK KA1TIM
skkmigas
ISSN : 1693-4393
PROSIDING SEMINAR NASIONAL
TEKNIK KIMIA "KEJUANGAN" 2013
Pengembangan Teknologi Kimia untuk Pengolahan Sumber Daya A/am Indonesia
Yogyakarta, 5 Maret 2013
PROGRAM STUDI TEKNIK KIMIA FAKULTAS TEKNOLOGIINDUSTRI UPN"VETERAN"YOGYAKARTA
Prosiding Seminar Nasional Teknik Kimia "Kejuangan· Pengembangsn Teknologi Kimia untuk Pengo/shan Sumber Daya A/am Indonesia Yogyakarta, 5 Maret 2013
PROSIDING SEMINAR NASIONAL TEKNIK KIMIA "KEJUANGAN" 2013.
Pengemhangan Teknologi Kimia untuk Pengolahan Sumber Daya A/am Indonesia Yogyakarta, 5 Maret 2013
Hak Cipta ada pada Program Studi Teknik Kimia
Teknologi Industri UPN ''Veteran" Y ogyakarta Jl. SWK 104 (Lingkar Utara) Condongcatur, Yogyakarta (55283)
Dilarang mengutip sebagian atau seluruh buku ini atau diperbanyak dengan tujuan komersial dalam bentuk apapun tanpa seijin Program Studi Teknik Kimia Fakultas Tekno1ogi Industri UPN ''Veteran" Yogyakarta, kecuali untuk keperluan penulisan artike1 atau karangan ilmiah dengan menyebutkan buku ini sebagai sumber.
Cetakan I: Maret 2013
ISSN 1693-4393
• Program Studi Teknik Klmia, FTI, UPN "Veteran• Yogyakarta
ISSN 1693-4393
ii
Prosidiog Seminar Nasional Tektlik Kimia "Kejuangan• Pengembangan Teknologi Kimia untuk Pengolahsn Sumber Daya AJam Indonesia Yogyakarta. 5 Maret 2013
Reviewer Seminar Nasional Teknik Kimia "Kejuangan" 2013
ISSN 1693-4393
Program Studi Teknik Kimia, Falrultas Teknologi Industri, UPN "Veteran" Yogyakarta
1. Prof. lr. H. Wahyudi Budi Sediawan, SU, Ph.D (UGM Yogyakarta)
2. lr. Mob. Fahrurrozi, M.Sc., Ph.D (UGM Yogyakarta)
3. Prof. Dr. lr. H. Supranto, SU (UPN "Veteran" Yogyakarta)
Program Sl\ldi Teknik Kimla, FTI, UPN "Veteran• Yogyakarta vii
It Prosiding Seminar Nasional Teknik Kmia "Kejuangan• ISSN 1693-4393 f Pengembangan Teknologi Kimia untuk Pengolahan Sumber Days Alam Indonesia
· Yogyakarta, 5 Maret 2013
Panitia Seminar Nasional Teknik Kimia "Kejuangan" 2013 Prodi Teknik Kimia Ffl UPN "Veteran' Yogyakarta
Peoaoggung Jawab Ir. Nur lndrianti, MT., D.Eng (Dekan Fakultas Teknik Industn)
: Peogarah 1. Ir. Tutik Muji Setyoningrum, MT (Ketua Pro<ii Teknik Kimia)
Ketua Pelaksana
Wakil Ketua Pelaksana
Sekretaris
Bendabara
Koordinator Bidaog Acara dan Persidangan Anggota
Koordinator Bidang Materi dan Prosiding Anggota
Koordinator Seksi Dana dan Promosi Anggota
Koordinator Bidang Publikasi dan Dokumentasi Anggota
Koordinator Konsumsi Anggota
2. Ir. Bambang Sugiarto, MT (Sekretaris Prodi Teknik Kimia) 3. Prof.Dr. Ir. Supranto, SU 4. Prof. Ir. H. Wahyudi Sediawan, SU, Ph.D 5. Ir. Mob. Fahrurrozi, M.Sc., Ph.D
Dr. Eng. Y. deddy Hermawan, ST,MT
Dr. Adi Ilcham, ST, MT
I . Siti Diyar Kholisoh, ST, MT 2. Ir. Tunjung Wahyu Widayati, MT
I. Ir. Purwo Subagyo, MT 2. Ora. Suci Astutiningsih
Ir. Endang Sulistyowati, MT
l. Dr. Ir. Mahreni, MT 2. Ir. Danang Jaya, MT 3. Ir. Harsa Pawignya, MT
Siswanti, ST, MT
Dra. Sri Wahyu Murni, MT
Ir. Sri Sukadarti. MT 1. Dr. Ir.Tjukup Mamoto, MT 2. Dr. Ir. Ramli Sitanggang, MT
Ir. Zubaidi Actunad, MT
1. Ir. Widayati, MT, Ph.D 2. Ir. I KeM Subawa, MT 3. Dr. Ir. M. Syahri, MT
Ir. Faizah Hadi, MT Ir. Dyah Tri Retno, MM
Program Studl Teknik Kimia, FTI. UPN "Veteran' Yogyakarta viii
Prosiding Seminar Nasional Teknik Kimia "Kejuangan· ISSN 1693-4393 Pengembangan Teknologi Kimia untuk Pengolahan Sumber Daya A/am Indonesia Yogyakarta, 5 Maret 2013
Kata Pengantar Sambutan Ketua Pelaksana Sambutan Rektor Sambutan Dekan Reviewer Susunan Paoitia Daftar lsi
Makalab Pembicara Utama
Kode Judul, Penulis dan Alamat
Daftar lsi
MUl Nilai Tambab Sumber Daya Alam tak Terbarukan bagi Pembanguoan Ekonomi Nasional Jr. Farlda Zed, ME, M4 Kepala Biro Kebijakan Energi dan Persidangan, Sekretariat Jenderal Dewan Energi Naional
MU2 Pemaofaatan Gas Bumi Dalam PerspektifPengembangan Industri Kimia SuryaMadya Sekretaris Perusahaan PT Pupuk Kaltim. Bontang Kaltim, Indonesia Alumni Teknik Kimia UPN Veteran Yogyakarta tahun 1981 E-mail: [email protected]
Makalab Slot
Kode Judul, Peoulis dan Ala mat
MS Disain Tata Ketola Migas Paska Putusao MK dan Keeeoderungao lndustri Migas Global Benny Lub/Qntara dan Dldi Sed4rto SKKMigas
Makalah Bidang Kajian
A. Perpindaban Massa dan Panas
Kode Judul, Penulis dan Alamat
iii iv v vi vii viii ix
A 1 Tbe Performance of Controlled Freeze Out Area Double Pipe Heat Exchanger in Removing C02
From C~C02 Gas Mixture lbnu Eka Rahayu, Ardi/Q Hayu Tiwlkrama, Sdiyo Gunawan, dan Gede Wlbawa• Department of Chemical Engineering, Faculty of Industria) Technology Sepuluh Nopember Institute of Technology Kampus ITS Sukolilo Surabaya, 6011. Tel/Fax :+62-31-5946240/+62-31-5999282 • E-mail: [email protected]
A2 Evaluasi Performance lnjeksi Air pada Lapangan Mlnyak "X" Didukung dengan Pelaksanaao SurveU/Qnce dan Perencaoaan Water Injection Plant Sederbana Harlyadf , Nov/on Arlbowo1
Program Studi Teknik Perminyakan, FakuJtas Teknologi Mineral, UPN "Veteran" Yogyakarta Jl. SWK 104 (Lingkar Utara), Condong Catur, Yogyakarta 55283
Program Studi Telcnlk Kirnia. FTI, UPN "Veteran• Yogyakarta ix
at Prosiding Seminar Nasional Teknik Kimia "Kejuangan• ISSN 16934393 1 Pengembangsn Teknologi Kimia untulc Pengo/shan Sumber Days A/am Indonesia
Yogyakarta, 5 Maret 2013
A3 .Kajian Telmologi Dehumidir.er Untuk Pengeringan Obat Herbal Sri Utami HandayanlJ t) Program Dill Teknik Mesin, Fakultas Teknik Universitas Diponegoro 11. Pedalangan, Tembalang Semarang, Telp/Fax. 024 7471379 Email : [email protected]
A4 Evaluasi Proses Debidrasi Gas Alam Menggunakan Trietbylene Glycol (Teg) Anas Pujl Santoso Program Studi Teknik Perminyakan, UPN "Veteran" Yogyakarta
AS Pengarub Isopropyl Alkobol Pada Laju Etsa Silikon (100) dengan Larutan KOH dan TMAH Slamet Wldodo PPET-LIPI, Jl. Saogkuriang Komp. LIPI Bandung 40135, No.Telp/Fax:022-2504660/022-2504659, E-mail: widodo @ppet.lipi.go.id, [email protected]
A6 Studi Etsa Elektrokimia dari Silikon (100) Dengan Larutan CsOH dan KOH Slamet Wldodo PPET-LIPI, Jl. Sangkuriang Komp. LIPI Bandung 40135, No.Telp!Fax:022-2504660/022-2504659, E-mail: widodo @ppet.lipi.go.id, [email protected]
A 7 Mass Transfer Model for Bask Blue Adsorption onto Pillared Bentonite Clay Using Langmuir Equilibrium and Taking into Account the Intra Particle Concentration Gradient .fiqdlqtnl Rlt11 Prlvanlinf·, Walty11dl B11dl Sedlawan•, Rocllmadfand lnunn hasetyo• • Department of Chemical Engineering. University ofSurabaya, Surabaya60292, Indonesia • Department of Chemical Engineering, Gajah Mada University, Yogyakarta 55281 , Indonesia ·Corresponding Author's E-mail: [email protected]
A8 Studi Pemanfaatan Condensate Outlet Steam Trap Sebagai Air Umpan Boiler di PT. Pupuk Sriwidjaja Palembang A/fa Wldyawan 1
• dan William KMsnanto 1
1Departemen Perencanaan dan Pengendalian Produksi, PT. Pupuk Sriwidjaja Palembang J1 Mayor Zen Palembang 30118 • E-mail: [email protected]
B. Termodinamika
Kode Judul, Penulis dan Alamat
C. Teknologi dan Pengendalian Proses
Kode Judul, Penulis dan Alamat
C 1 Ana lisa Pengujian Kualitas, Kompatibllitas, Scaling Tendency dan Mikrobiologi Air lnjeksi untuk Penerapan Waterflooding di Lapangan Minyak Dedy Xrlstanto Program Studi Teknik Perminyakan, Fakultas Teknologi Mineral, UPN "Veteran" Yogyakarta 11. SWK 104 (Lingkar Utara), Condongcatur, Yogyakarta 55283 E-mail: [email protected]
C2 Efek Pencampuran Tepung Peuyeum dan Tepung Singkong Terbadap Tekstur dan Rasa Roti Tawar Andy Chandra, Judy Retti Witono, dan Sabrina Jurusao Teknik Kimia, Fakultas Teknologi Industri, Universitas Katolik Parahyangan Ciumbuleuit 94, Bandung 40141, Telp!Fax. (022)2032700 E-mail: [email protected]
Program Studl Teknlk Kimla, FTI, UPN "Veteran• Yogyakarta X
user
Highlight
~ Prosiding Seminar Nasional Teknik Kimia "Kejuangan•
1 Pengembangen Teknologf Kimia untuk Pengofahsn Sumber Dsys AJBm Indonesia Yogyakarta. 5 Maret 2013
C3 Peniogkatan Perolebao Mioyak Deogao COz Flooding Edgie Yuda Kaestf·, I Putu Suarsanrl·, Dedi Cahyoko Ajt* 1 Jurusan Teknik Perminyakan Fakultas Teknologi Mineral UPN "Veteran" Yogyakarta 2 EOR Pertamina EP 3 Mahasiswa MTG Teknologi Mineral UPN "Veteran" Yogyakarta
ISSN 1693-4393
C4 Pembeotukan Batubara, Komponen Maseral dan Mineralnya serta Pemanfaatannya Sebagai Eoergi Edy Nursanto'·6·, Arlfudin ldru?, Hendra Amijaytl, Subagyo PTtmU~mJjoyo4, Harli Tantl·' 1Prograrn Doktor, Jurusan Teknik Geologi, Universitas Gadjah Mada, Yogyakarta 2
•3
•4 Jurusan Teknik Geolog~ Fakultas Teknik, UGM-Jalan Grafika No.2 Yogyakarta
s Program Studi Teknik Pertambangan, Universitas Sains dan Teknolog~ Jayapura 6 Program Studi Tekni.k Pertambangan FTM UPN "Veteran" Yogyakarta ·E-mail: [email protected]
C5 Pengolahan Larutan Zat Warna Disperse Red Menggunakao Metode Elektrokoagulasi dengan Elekroda Alumunium Arenst Andreas* dan Aditiyo Ramadhan Jurusan Teknik Kimia, Fakultas Teknologi lndustri, Universitas Katolik Parahyangan, Ciumbuleuit 94 Bandung 40141 Indonesia • E-mail: [email protected]
C6 Optimasi Reaksi Oksidasi Pati Ubi Kayu deogan Proses Ozonasi: Peogaruh pH dan Temperatur Operasi Jsti Pud)lhastuti,Siswo Sumardlono, Edy Supriyo Laboratorium Food Process Engineering, Jur Teknik K.imia. Fak Teknik.Universitas Diponegoro Jl. Prof. Sudharto, SH, Tembalang, Semarang, 50239, Telp/Fax: (024) 7471359 E-mail: [email protected]
C7 Dynamic Study of Bioetbaool Production from Cheese Whey usiDg Kluyveromyces marxianus (DSMZ7239) Akbamingrum Fatmawad·, Rudy Agustrlyanlo Jurusan Teknik Kimia, FT, Universitas Surabaya, Jl Raya Kalirungkut Surabaya 60292
C8 Cydobuaoe Oxidation in a Series of Stirred Tank Reactors Rudy Agustrlyanto, Akbamlngrum Fatmawatl Chemical Engineering Department, Surabaya University , Jalan Raya Kalirungkut Surabaya E-mail: [email protected]
C9 Peoggunaaa Teknologi Hydrothermal Di Daerab Titik Kritis Air Dalam Reaksi Degradasi Gliserol Yuyun Yunlati1
, Sumamo1, Mah/IUf
1 Jurusan Teknik Kimia, ITATS, JLArief Rahman Hakim No.1 00 Surabaya 2 Jurusan Telcnik Kimia, ITS, Kampus ITS Sukolilo, Surabaya E-mail : [email protected]
C 10 Effect of Sonication on the Crystallinity and Hydrolysis Products of Cellulose SultlllTI, Achmad Roesyadi, dan Sumamo3
1.2.3 Jurusan Teknik Kimia, FTI, ITS Surabaya E-mail: Sumari [email protected]
Cll Pengaruh Penggunaan Blowing Agent Methylene Chloride dan Karbondioksida Terhadap Struktur Polyurethane Foam Sojialun Anlsah, Yahma Muhammad Sold, dan Sumamo • Program Studi Teknik Kimia, FTI, Institut Tek:oologi Sepuluh Nopember Surabaya Kampus ITS. n. Teknik Kimia. Sukolilo, Surabaya 60 Ill Telp: 031·5946240 I 031-5922934, Fax: 03 J -5999282 E-mail: [email protected]
Program Sludi Teknik Klmla, m. UPN 'Veteran• Yogyak.a/1a
~ Prosiding Seminar Nasional Teknik Kimia ·Kejuangan· JSSN 1693-4393
1 Pengembsngsn Teknologi Kimis untuk Pengo/shan Sumber Days Alam Indonesia · Yogyakarta, 5 Maret 2013
Cl2 Production of Glycerol Carbonat from by Product Transesterif'lation using Nkkel Catalyst Bambang Poedjojono, Dllllr Agustina PuspiJasarl, S1111ti Dvalr Savilri Jurusan Teknik Kirnia, Fakultas Teknologi, Universitas WR. Supratman, Jl. AriefRachman Hakim No. 14 Surabaya E-mail: [email protected]
Cl3 Performance and Robustness of MultJvariable Feedback Process Systems 1: Principal Gain Analysis Martlren Luther Doko Department of Chemical Engineering, Institut Teknologi Nasional Bandung • Corresponding Author' s E-mail: [email protected]
Cl4 Performance aod Robustness ofMultivariable Feedback Process Systems II: Stability aod Robustness MaTihen Luther Doko Department of Chemical Engineering, lnstitut Teknologi Nasional Bandung ·corresponding Author's E-mail: [email protected]
CIS Degradasi Kitosan Dengan Proses Hldrotermal pada Berbagai Varlasi Konseotrasi Asam Asetat Anllaraklrmi Handarlllrl, Emma Savltrl, dan Sumamo* Program Studi Teknik Kimia, Ffl, Institut Teknologi Sepuluh Nopember Kampus Keputib Sukolilo Surabaya, Jawa Timur E-mail: [email protected]
C 17 Degradation of Leachate from Municipal Solid Waste Final Disposal Using Two Stage Fixed Bed Anaerobk Reacton H. Budltlslllti1*, E. Mulrarl, D. Wldyllbudlnlngslll, M. Glrozall 'Cleaner Production Chemical Engineering Study Program, 2Chemical Analyst Study Program, Chemical Engineering Department, State Polytechnic ofBandung • E-mail: [email protected]
D. Kinetika Reaksi dan Katalisis
Kode Judul, Penulis dan Alamat
01 Pemanfaatan Bijih Besi sebagai Katalis Dalam Pencairao Batubara Har/1 Ta/141
•2
", Hendra Amljaya', Sugeng Sapto Suryono1, I Wayan Warmada1,
Edy Nunanto1.J · 1Jurusan Teknik Geologi, Universitas Gadjah Mada 2Jurusan Teknik Geologi & Pertambangan, Universitas Sains dan Teknologi Jayapura 3Jurusao Teknik Pertambangan UPN yogyakarta *E-mail: tuna [email protected]
02 The Effect of Promotor oo Catalyst Activity to Traosestererificatioo of Palm Oil Sand Dyalr Savitri, Aclrmad Roesyadi Laboratoriuro Teknik Reaksi Kimia Jurusan Teknik Kimia, Fakultas Teknologi Industri, Institut Teknologi Sepuluh Nopember Surabaya
E-mail: [email protected]
03 Traosesterifikasi Minyak Jarak Pagar Menggunakao NaOH dan Ca(OHh sebagai Katalis Din/ Kumlawad· dan Malrfud Laboratorium Teknologi Proses Program Studi Teknik Kimia, FTI, Jnstitus Teknologi Sepuluh Nopember , Karnpus ITS Sukolilo Surabaya, Jawa Timur 60 Ill • E-mail: [email protected]
Program Studi Teknik Kimia, FTI, UPN -veteran' Yogyakarta xii
~ Prosiding Seminar Nasional Teknik Kimia "Kejuangan• ISSN 1693-4393
' . Pengembangan Tel<nologi Kimia untuk Pengofahan Sumber Days A/am Indonesia • Yogyakarta, 5 Maret 2013
E. Bloteknologi
Kode Judul, Penulis dan Alamat
El Validasi Proses Menggunakan Media Fill Anna R", Widyastuti W, Mujinab, Sribastioi, Enny L, Dadaog PRR-BAT AN, Kawasan Puspiptek- Serpong "E-mail : [email protected]
E2 AnaUsis Asam Sianida (HCN) pada Beberapa Genotip Ubi Kayu (Man/hot esculenta, Crantz.) Djumhawan Ratman Pennana1
, Sari Nengsih2, N. Sri Hartatl 1 dan Enny Sudarmonowilli'
1Pusat Penelitian Bioteknologi-LIPI, Cibinong, 2Mahasiswa Program Studi Fannasi, ISTN- Jakarta • E-mail: [email protected]
E3 lsolasi Enzim BromeUn Dalam Bentuk Serbuk dari Buab Nanas Ronny Kurniawan. S.Juhanda, Adllia Nugraha, ltfan Djatnika JW"USan Teknik Kimia, Fakultas Teknologi lndustri ltenas Bandung Jl. PHH. Mustafa No 23 Bandung 40132, Telp (022)727221 5 Fax (022)7202892 E-mail : ron [email protected]
E4 Seleksi In Vitro Tunas Ubi Kayu (Man/hot escu/enta Crantz) Genotip ldiog untuk Ketabaoan Terbadap Kekeringao Meoggunakan Media Polietileo Gllkol (PEG-'000) Dody Prlad/1·, Eka Des/ Lestluf, Rani FitTiani' dan N.S Hartati' 1Pusal Penelitian Biotek.nologi-LIPI, n. Raya Bogor K.m.46 Cibinong 16911 2Departemen Biologi, Fakultas Matematika dan Ilmu Pengetahuan A lam, Universitas Indonesia • E-mail: d [email protected]
ES Multiplikasi Tunas In Vitro Benib Asal Pobon Seogon Unggul Menggunakan Nodal Kotiledon N. Sri Hartati, Dodi Priady and Enny Sudarmonowad Pusat Penelitian Bioteknologi LIPI • • E-mail: [email protected]
E6 Peningkatan Kapasitas Produksi dan Uji Praklinis 1311-MIBG Sebagai Radiofarmaka Diagnosa danTerapi Neuroblastoma Lalumi Andrl A, Purwoko, Sri Aguswarinl, Karyadl, Sri Setyowad, Adang Hardl G. Pusat Radioisotop dan Radiofannaka BAT AN e-mail : [email protected], lakdriti@ya}}oo.co.id
E8 Produksi Protein Sel Tungpl dari Jamur dengan Substrat Kulit Singkoog (Man/hot u.dllsslma) Faizah Hadi 1, Sri Sukadanl 1, lndrlhapstuf, Ritkl Kumlasilr2
1Dosen Program Studi Teknik Kimia,.Fakultas Teknologi Industri 2 Mahasiswa Program Studi Teknik Kimia,Fakultas Teknologi lndustri Universitas Pembangunan Nasional .. Veteran" Yogyakarta Jln :SWK 104 (Lingkar utara ,Condong catur,Yogyakarta,55283 Telp/Fax :0274 486889: E-mail :[email protected]
F. Optimasi Teknologi Pemisaban
Kode Judul, Peaulis dan Alamat
Fl Penuruoan Kadar Garam Dalam Air Laut Deagao Proses Elektroforesis: Kajian Awal M.Syalrrf dan 1Jukup Mamoto2
1•2Program Studi Teknik Kimia, FTI, UPN "Veteran" Yogyakarta
E-mail: [email protected]
Program Studi Teknik Kimia, FTI, UPN "Veteran" Yogyakarta xiii
r' . Pengembangan Teknologi Kimia untuk Pengolahan Sumber Daya A/am Indonesia ~ Prosiding Seminar Nasional Teknik Kimia "Kejuangan• ISSN 1693-4393
Yogyakarta, 5 Maret 2013
F2 Pengarub Drying Agent pada Ekstraksi dan lnaktivasi Eozim Gaultberase Simuftan dari Gandapura (Gaultheria jTagantissima) Priyono Kusumo1
', Mega Kasmiyatun1f dan Mohamad Endy Yulillnto 1'
Pusat Studi Lingkungan Hidup UNT AG Semarang '>.Program Studi Teknik Kimia Sl UNTAG, Jln.Pawiyatan Luhur Gedung G Semarang; 2>.Program Studi Telcnik Kimia 03 UNDIP, Tembalang Semarang Email: [email protected]; [email protected]
F3 Equilibrium In C01 Adsorption Using Strong Base Anion Exchange Resin Anies Mutimi ·, WiTatnf, dan As wad Mlndaryanf 1 Center for Materia] and TechnicaJ Product Ministry of Industry Jl. Sangkuriang No.l4, Bandtmg, 40135, Indonesia 2 Department of Chemical Engineering Gadjah Mada University, Jl. Grafika No.2, Yogyakarta, 55281, Indonesia • E-mail: [email protected]
F4 Penambaban Oksidator NaOCI untuk Peningkatan EfiSiensi Pemisahan "-Tc dari Kolom Generator "Mof""Tc Berbasis PBZ-TEOS KadaT/sman, HeTiina, Abidln, HambaU dan Umi NuT Sho/lklla Pusat Radioisotop dan Radiofannaka - BA TAN Kawasan PUSPIPTEK, Gedtmg II, Serpong, Tangerang Selatan. Banten, Telp./Faks: 021-7563141, E-mail: kadarisman _ [email protected]
F5 Simulasi Model Jaringan dan Fasilitas Permuk.aan Injeksi C01 Sistem Terpusat pad a Lapisan F LapaogaoJ Wlbowo1
· , YuUus Deddy Hermawan1
1Program Studi Teknik Perminyakan, FakuJtas Teknologi Mineral, UPN "Veteran" Yogyakarta Jl. SWK 104 (Lingkar Utara) Condongcatur Yogyakarta 2Prograrn Studi Tekoik Kimia, Fakultas Tekoologi Industri, UPN "Veteran" Yogyakarta Jl. SWK 104 (Lingkar Utara) Condongcatur Yogyakarta • E-mail: wibowo _ [email protected]
F6 Peningkatan Rendemen Min yak Nilam (Pogostemon cablln flenth) dengan Destilasi SolventMlcTowave Kusyanto dan Mahfud" Laboratorium Proses Kimia, Jurusan Teknik Kimia, ITS, Surabaya ·E-mail : [email protected]
F7 Kinerja Membran Ultrafiltrasi Pada Pemisabao Emub(Minyak-Air Indah Prlhadnlngtyas D.s1
·, Nita Aryantf, dan Diyoo lkhsan3
1·2.3Magister Telcnik Kimia, Universitas Diponegoro n. H. Prof. Sudarto, SH, Tembalang Semarang 50239 • &moil: [email protected]
F8 Development Downflow Jet Loop-Fixed Bed Gas-Liquid Contactor Hendrlyana Department of Chemical Engineering Jenderal Achmad Y ani University E-mail: hendriyana200 I @gmaiJ.com
G. Tek.Dologi Partikel
Kode Judul, Peoulis dan Alamat
Program Studi Teknik Kimia, FTI. UPN "Veteran· Yogyakarta xiv
lit Prosiding Seminar Nasional Teknik Kimia "Kejuangan· ISSN 1693-4393 f Pengembangsn Teknologi Kimia untuk Pengolahsn Sumber Daya A/am Indonesia
· Y ogyakarta. 5 Maret 2013
H. Teknologi Pengolaban Limbab
Kode Judul, Penulis dan Alamat
HI Peogolaban Skala Pilot Limbab Cadmium dan Sianida Industri Elektroplating dengan Fotokatalisis UVffi01 Ted/ Hudaya ·~Shirleen Rosemarie, dan Regina Leoni Jurusan Teknik Kimia, Fakultas Teknologi Industri, Universitas Katolik Parahyangan Jalan Ciurnbuleuit 94, Bandung 40141, Telp/Fax: (022)- 2032 700; *E-mail: t [email protected], [email protected]
H2 Pengolaban Skala Pilot Limbab Kromium Heksavalen Industri Elektroplating dengan Fotokatalisis UVffi01 Tedi Hudaya ·,Juan August Naldo dan Leonardo Arief Program Studi Teknik Kimia, Fakultas Tek:nologi Industri, Universitas Katolik Parahyangan Jalan Ciurnbuleuit 94, Bandung 40 I 41 • E-mail: [email protected]; [email protected]
H3 Identifikasi Limbab Pada Proses Batik Lies Susllaning Sri Hastuti Peneliti Balai Besar Kerajinan dan Batik (BBKB) Jl. Kusu.manegara No 7 Yogyakarta E-mail: [email protected]
H4 Penurunan Kekerubao Air Tambang Meoggunakan Larutao Alum Sri Suhenry dan Supranto Program Studi Teknik Kimia, FTI, UPN "Veteran" Yogyakarta Jalan Lingkar Utara SWK 108 Condong Catur Yogyakarta
H5 Utilization oflndustrial Tapioca Wastewl\ter for Making Nata de Cassava as Paper Material Slrln Falrus. Netty K., Arlinda lndreswari, dan Ade Christine Arltonang Jurusan Teknik Kimia Itenas Jl PHH. Mustafa No 23 Bandung
E-mail : [email protected]
H6 Hidrolisis Lim bah Tongkol Jaguog Menjadi Glukosa Mengguoakan Katalis Asam Klorida Emmanud11 M. Wldyanli dlln Rispil111di Teknik Kimia- Politeknik Negeri Bandung, KBK Sistem Proses Jln. Gegerkalong Hilir- Ds. Ciwaruga, Bandung 40012 E-mail : emrilanuela25Yroail.com dan [email protected]
H7 Electrode Dimension Effect to Electrocoagulation Performance Bambang HarL pi• •• and Hendrlyana1
Department of Chemical Engineering, Universitas Jenderal Achmad Y ani Jl. Ters Jend. Sudinnan, PO. BOX 148 Cimahi 40531, Indonesia • [email protected]
H8 Peogolaban Lindi Meojadi Biogas Menggunakao Digester Aoaerobik Dua Tabap Mukhtar Ghozall. Dewi W, A de T.N, //ham F Jurusan Teknik Kimia Politeknik Negeri Baodung (Polban) Jl. Gegerkalong Hilir, Ciwaruga Bandung, Telp./Fax.: 022.2016403 E-mail: muhtar _ [email protected]
H9 Kioerja Flokulan Starch-graft-polyacrylllmlde (St-g-P AM) Terbidrolisis Dalam Peogbilangan Warna Pada Limbah Cair Gilang Agung Prabowo dan Sumamo •
• Jurusan Teknik Kimia, Fakultas Teknologi Industri, Institut Teknologi Sepuluh Nopember (ITS), Kampus ITS. 11. Teknik Kimia, Sukolilo, Surabaya-60 J 1 J "E-mail: [email protected]
Program Studi Teknik Kimia, FTI, UPN "Veteran· Yogyakarta XV
Prosiding Seminar Nasional Telcnik Kimia "Kejuangan· ISSN 1693-4393 Pengembangan Teknologi l(jmia untuk Pengolahan Sumber Daya A/am Indonesia Yogyakarta. 5 Maret 2013
HIO Pengolabao Limbab Cair CN"/Cd1+ dan Cr(VI) Jndustri Elektroplating
Ted/ Hudaya ·,Martin Wijaya KUJuma Magister Teknik Kimia, Program Pascasarjana, Universitas Katolik Parahyangan Jalan Merdeka No. 30, Bandung, Telp/Fax: (022) - 2032 700 ·E-mail: t [email protected]; [email protected]. id
H II Pengarub Oil Sllldge Pertamina Surabaya terhadap Kuat Tekan Keramik Tradbional Adl Rcham1
, Dyah Tri Retno1, Allln Syahputra', M. Novie Aprianto"
1·2.3·4 Program Studi Teknik Kimia, FTI, UPN "Veteran" Yogyakarta
JJ. Lingkar Utara Condoog Catur, Sleman, DIY • E-mail: adi [email protected]
Hl2 Studi Awal Pengolahan Llmbab dengan Behan COD-BOD Tinggi Secara Koagulasi-Fiokulasi. Tunjung Wahyu Widayatf, Mahrenf, Herman1, MuhaltiiiUid Catur S. W 1) Dosen Prodi Telcnilc Kimia, Fakultas Teknologi lndustri, UPN "Veteran" Yogyakarta 2) Mahasiswa Prodi Teknik Kimia, Fakultas Teknologi lndustri, UPN "Veteran" Yogyakarta Jl. SWK. 104. Lingkar Utara Condong Catur Yogyakarta (55283) E-mail: [email protected]
Hl3 Processing Bioc:har from Solid Waste of Arenga Pinoata Flour Industry Susanti Rina Nugrabeoi1
), Agus Prasetya1), and Sihaoa3)
1Program Studi Teknik Kimia, FTI. UPN"Veteran" Yogyakarta Jln. SWK 104 (Lingkar Utara), Condongcatur, Yogyakarta 2Chemical Engineering Department, UGM, Jalan Grafika 2, Kampus UGM, Yogyakarta 3Physics Engineering Department, UGM, Jalan Grafika 2, Kampus UGM, Yogyakarta • E-mail: [email protected]
Hl4 Pengolabao Limbab Cair lndustri Tabu Melalui Proses Anaerobik Sid Diyar Khollsoh, Abdullllh Effendi, Dwi Ratna MayiiSarl. dan Rahma Wulan Febriati Program Studi Teknik Kimia, Fakultas Teknologi lndustri, UPN "Veteran" Yogyakarta Jl. SWK 104 (Lingkar Utara), CondOng Catur, Yogyakarta 55283, Telp/Fax. +62-274-487 I 54 E-mail: [email protected]; [email protected]
I. Energi Baru dan Terbarukao
Kode Judul, Penulb dan Ala mat
I I Preparation of Biodiesel from Kemiri Sunan (A leu rites trlspeTmll) Oil Using Dolomite as Solid Catalyst Nancy Siti Djenar and Nlnlk Lintang Politeknik Negeri Bandung Jln. Gegerkalong-Ds. Ciwaruga Kotak Pos 6468 BDCB Bandung, Telp/Fax: 022-2016403 E-mail :[email protected]
12 Pembuatan Biodiesel Mengguoakan Katalis Lim bah Kulit Telur Herry Santoso*, Ivan Kristlanto, dan Aris Setyadi Jurusan Telcnilc Kimia, Fakuitas Teknologi Industri, Universitas Katolik Parahyangan Jalan Ciumbuieuit No. 94, Bandung 40 I 41 , Indonesia • E-mail: [email protected]
13 Kajian Awal Pembuatan Biodiesel Meogguoakan Katalis Asam Berbaban Dasar Campurao DGiukosa dan Pati Jagung Heny Santoso*, G/orlll Marcello Morgen Wiria, dan Irene Tedjasaputra Jurusan Teknik Kimia, Fakultas Teknologi Industri, Universitas Katolik Parahyangan Jalan Ciumbuleuit No. 94, Bandung 40141, Indonesia • E-mail: [email protected]
Program Studi Teknik Kimia, FTI, UPN 'Veteran· Yogyakarta xvi
Prosiding Seminar Nasional Teknik Kimia "Kejuangan· Pengembsngsn Tekno/ogi Kimis untuk Pengo/shsn Sumber Days Alam Indonesia Yogyakarta, 5 Maret 2013
ISSN 1693-4393
14 Kajian Kinerja dan Keekonominan Rancangan Gasijlclltion Stove Berbasis Lim bah Pertanian Suhartono1, War' an Roslltan1, Pujhmd lntan pi, Sllv/Q WulandtJrf 1Jurusan Teknik Kimia, Fakultas Teknik, Universitas Jenderal Achmad Yani 2Jurusan Teknik Mesin, Fakultas Teknik, Universitas Jenderal Achmad Yani Jl. Terusan Jenderal Sudirman PO. BOX 148 Cimahi, Telp. (022) 6642064 Fax. (022) 6642064, e-mail [email protected]
15 Pre-treatmeat Process of Biodiesel Prodadloa From Waste Cooking Oil Putrl Re3tu Dn~atJo~.zJ, Acltmad Halim Purbohandono1J, and Arief Budlnulrr•J 1Program Studi Teknik Kimia, FTI, UPN"Veteran" Yogyakarta Jln. SWK 104 (Lingkar Utara), Condongcatur, Yogyakarta 2Process System Engineering Research Group, Chemical Engineering Department, UGM Jalan Grafika 2, Kampus UGM, Yogyakarta • E-mail: [email protected]
16 Pengarub Delipifikasi Meaggunakao NaOH pada Hidrolisis Jerami Padi Menggunakan Asam Sulfat Eocer Nadlem Anwar, Gillot Trllatsono, Ymi Trlyan#p Evy Nur Afrlyand Program Studi Teknik Kimia Universitas Jenderal Achmad Yani n. Terusan Jenderal Sudinnan-Cimahi E-mail: [email protected]
17 Spedfication and Classification of Bio-lubricaot Base Fluid from Ring Opening of Epoxldized Methyl Oleate Heryokl Yoltanes, Walty11 Bahari Setlanto, Glgilr Atmajl and Wahju Eko Widodo Pusat Teknologi Agroindustri, Badan Pengkajian dan Penerapan Teknologi - BPPT M.H. Thamrin 8, Jakarta l 0340, Indonesia E-mail : [email protected]
J. Teknik Produk
Kode
Jl
J2
J3
14
Judul, Peoulis dan Alamat
Pengarub Konsentrasl Ferosulfat Terbadap Ketuaan dan Ketahanan Warna Hasil Celupan Kaio Batik Katun Dengan Ekstrak Daun Ketapang Dwl Suhnyanto Peneliti pada Balai Besar Kerajinan dan Batik Badan Penelitian dan Pengembangan lndustri - Kementrian Perindustrian RI n Kusumanegara 7 Yogyakarta 55166. Telp. (0274) 546111 Fax (0274) 543582, E-mail: [email protected]
Pengarub Waktu Fennentasi Pada Pembuatan Zat Warna Indigo (Indigo/era Tinctoria) Dwl Suhnyanto Peneliti pada Balai Besar Kerajinan dan Batik Badan Pengkajian Kebijabn lklim Dan Mutu Industri - Kementrian Periodustrian RI Jl. Kusumanegara No 7 Yogyakarta, Telp.(0274) 546111,512456, Fax.(0274) 543582, 512456, E-mai/:[email protected]
Pemanfaatan Resam Untuk Produk Kerajinan Lies Susikuting Sri Hastud Peneliti Balai Besar Kerajinan dan Batik (BBKB), Jl. Kusumanegara No 7 Yogyakarta E-mail: hastuti2121 @gmail.com
Sintesis Garam Mohr (Besi (II) Amonium Sulfat Hid rat : Fe (NII.)l(S04)2.6 H10)] A.fusdnus Ngadn1
, Mentlk Hut.upf, Emmnumuela Mar/11 Wljayantl 1• Prodi Teknik Kimia, Polban, Jl Gegerkalong,Ds.Ciwaruga, Bandung
2Prodi Analis Kimia, Pol ban, Jl.Gegerka1ong hilir, Ds.Ciwaruga, Bandung Email:ngalin_agustinus@yahoo. com
• Program Studi Teknik Kimia, FTl, UPN "Veteran• Yogyakar1a xvii
~ Prosiding Seminar Nasional Teknik Kimia "Kejuangan" ISSN 1693-4393
r : . Pengembangan Teknologi Kimia untuk Pengo/shan Sumber Days A/am Indonesia Yogyakarta, 5 Maret 2013
J5 Karakteristik Ekspansi TermaJ dan EJektrokimia Komposit Katoda Laa~ruCocuFeuOu-SDC Karbonat untuk Solid Oxide Fuel Cell Bersubu Rendab dan Meoengab Jarot Raharjo1
• dan Agustanhakrl Bakrf 1•2Pusat Teknologi Material, Badan Pengkajian dan Penerapan Teknologi
Gedung II BPPT Lantai 22, Jl. MH. Thamrin no.8, Jakarta Pusat, 10340/ Laboratorium Teknologi Material BPPT, Gedung 224 Puspiptek Serpong, Banten, Jawa Barat. • E-mail: [email protected]
J6 Pengarub Subu Pencampuran dalam Proses Pembuatan Kompon terbadap VJSkositas Mooney, Karakteristik Vulkanisasi, Bound Rubber, Degree of CrosslinkinJ dan Sifat Fisik Karet Alam Abu Hasan1
·, Rochmadi, Hary Sulistyo1 • Suharto Honggokusumo
1Jurusan Tekoik Kimia, Politeknik Negeri Sriwijaya, Jl. Srijaya Negara Bukit Besar Palembang Indonesia 30139 2 Jurusan Teknik Kimia. Fakultas Teknik, Universitas Gadjah Mada, JJ. Grafika no. 2 Yogyakarta 55281 3 Gapkindo, Jl. Cideng Barat no 62A Jakarta 10150 • E-mail: abu [email protected]; [email protected].
J7 Peranan Ubi Kayo dalam Pengembangan lndustri Tepung Mokaf Suharwadji Sentana UPT Balai Pengembangan Proses dan Teknologi Kimia. Lembaga Ilmu Pengetahuan Indonesia Jln. Raya Yogya-Wonosari km 32, Gading, Playen. Gunungkidul, DJ. Yogyakarta E-mail: [email protected]; suha020@ lipi.go.id
J8 Pembuatan Arang Aktif dari Campuran Cangkang dan Sera but Sa wit dengan Aktivator Na2C03 Fatmayatl1
• dan Vonny lndab Sari1
1Program Studi Teknik Pengolahan Sawit., Politeknik Kampar Jl. Tengku Muhammad KM.2 Bangkinang, Riau - 28461 • E-mail: [email protected]; [email protected]
J9 Studi Pengarub Subu, Waktu Reaksi dan Perbaodiogan Mol Reaktan Terbadap Konversi Reaksi Sulfonasi Pada Produksi Metil Ester Sulfonat Arlf Andrlanto1
, Suprapto1
Jurusan Tekni.k Kimia FTI - ITS, Kampus ITS Sukolilo, Surabaya E-mail: [email protected]
J I 0 Preparasi Kit Cair Tetrofosmin untuk Deteksi Kanker dan Perfusi Jantung Widyastuti, Sri Setyowati, Cecep Taufik Rusteodi, Yunilda Pusat Radioisotop ~ Radiofannaka, Badan Tenaga Nuklir Nasional (PRR-BATAN), Kawasan Puspiptek, Setu, Tangerang Selatan. Propinsi Banten • E-mail: [email protected]
Jll Pengarub Perbandiogao Umpan dan Subu Pada Pro5es Pelarutan Zirkonium Hidroksida (ZOH) Tundjung lndrad Y, Sudaryadl, Mulyono (Pusat Teknologi Akselerator dan Proses Bahan ,BA TAN)
J12 Kajiao Potensi Pasar Produk Karbon Dan Grafit Menggunakan Bahan Pilch Dan Coke Tunjung Indrali Y Pusat Teknologi Akselerator dan Proses Bahan ,BAT AN
Jl3 Pembuatan dan Aoalisis Sifat Kuliner Mie Instan Keriog Oven dari Komposit Tepung Gandum dan Tepung Gadung Andri Cahyo Kumoro1
', Diah Susetyo Retnowad, Catarina Sri Budiyad dan R.P. Djoku Murwono Jmusan Teknik Kimia, Fakultas Tekni.k, Universitas Diponegoro n. Prof. H. Soedarto, SH- Tembalang, Semarang 50275, Telp. 024-7460058, Faks. 024-76480675, E-mail: [email protected]
• Program Studi TekniX Kimia. FTl, UPN "Veteran• Yogyakarta xviii
~ Prosiding Seminar Nasional Teknik Kimia "Kejuangan·
1 Pengembangan Teknologi Kimia untuk Pengolahan Sumber Daya A/am Indonesia Yogyakarta, 5 Maret 2013
J14 Pembuatao Surfaktao Berbabao Dasar Jerami Padi Sri Wahyu Mumi, Sri Wahyuni Sand R., IGS Budiaman, Ita Perwitasari dan Abdul A)/ Kresna Tri Anggara Program Studi Teknik Kimia, FTI, UPN "Veteran" Yogyakarta Jl SWK 104 (Lingkar Utara) Condong Catur Yogyakarta-55283 • E-mail: [email protected]
lodeks Peoulis Makalab
lodeks Kata Kuoci
Program Studi Tel<nik Kimia, FTI. UPN "Veteran· Yogya+carta
ISSN 1693-4393
xix
Prosiding Seminar Nasional Teknik Kimia "Kejuangan· Pengembangan Teknologi Kimia untuk Pengo/ahan Sumber Daya A/am Indonesia Yogyakarta, 5 Maret 2013
ISSN 1693-4393
Mass Transfer Model for Basic Blue Adsorption onto Pillared Bentonite Clay Using Langmuir Equilibrium and Taking into Account the Intra Particle
Concentration Gradient
Hadiatni Rita Priyantini•·, Wahyudi Budi Sediawan•, Rochmadi8 and Imam Prasetyo•
a• Department of Chemical Engineering, University of Surabaya, Surabaya60292, Indonesia a Department of Chemical Engineering, Gajah Mada University, Yogyakarta 55281, Indonesia
"corresponding Author' s E-mail: [email protected]
Abstract
Bentonite clay from Pacitan, East Java, was made using intercalation and pil/arization method. using cationic surfactant HDTMA-Cl as intercalating agent and NaOH - AICI; mixture with OHIAI ratio was 0,8 as pi/loring agent at BrfC. Furthermore, calcination was done at 50rfC for 4 hours. Adsorption process was done at laboratory scale batch :.ystem with initial Basic Blue 41 dye concentration varied between 100 ppm, 200 ppm, 300 ppm, 400 ppm, and 500 ppm for adsorbent mass ratio was 0, I giL and adsorbent size of 100 mesh. Adsorbent mass ratio was varied 0,/ giL; 0,2 giL; 0,25 giL; 0,35 giL; and 0,4 giL for initial dye concentration of 600 ppm. Adsorption equilibrium was analyzed using Langmuir equilibrium model, and kinetic model was developed with considering convection mass transfer at adsorbent surface and intraparticle dye diffusion. Mathematic model and experimental data was used to calculate dye convective mass transfer and effectivediffusion coefficient using computer program. The result showed that Basic Blue 41 -pil/arizedbentonite clay equilibrium obeyed Langmuir equilibrium model. Developed kinetic model was relatively fitted to experimental data. Maximu,.,; dye removal was 97.947 %. Generally, Basic Blue 41 adsorption kinetic was controlled by film resistance at adsorbent surface and intra-particle diffusion resistance.
Keywords: Adsorption; Basic Blue;Bentonite Clay; Modeling; Pillarization
1. Jntroduction
Bentonite clay, which was composed of alumina-silicate, is a low price commodity, widely available, and considered to be an effective sorbent material having a high added value. Based on the mineral content, the clay can be divided into: smectite (montmorillonite), kaolinite, halloysite, chlorite and illite[Oiphen et al., 1977]. Bentonite is a type of clay which has the ability to adsorb water and its cation exchange power much greater than the ordinary clay. A component of the dominant clay mineral in bentonite ismontmorillonite.Montmorillonite has the chemical formula [NaxAI(2-x)Mgx(Si40 10XOH):zJ.(H20)m.
Montmorillonite clay minerals are a group that has a good ability to adsorb both the metal and the organic molecules. It also has an ability to inflate and deflate (swelling) and an exchangeable cation[Pinnavaia, 1983].Bentonite is a claycomposed of alumina-siJicatewhich consists of 3 layer.>, where a layer containing octahedral aluminum flanked between the other two layers containing tetrahedral silicate. This three layer.> form a sheet structure [Astrology, 2000].
Due to its large porosity, beside its potential as an adsorbent, bentoniteclay is very suitable to be used as catalysts and ion exchange material. However, although bentoniteclay is very useful in many areas of application, it has limitations in maintaining its shape, due to its nature of easy to swell. Clays can swell due to hydration, deflate and even the structure of the clay can be damaged by dehydration and heating. To prevent this deformation, the interlayer region should be supported by a stable pillar. The other purpose of such modification is to create a large pore volume. In addition, it was also addressed to increase its ability of maintaining the porosity of clay despite hydration and dehydration occur. This process is called pillarization[Robert et al., 1999].
0 Program Studi Tekmlc Kimia. FTl. UPN "Veteran• Yogyakarta A7 -1
~• Prosiding seminar Nasional Teknik Kimia •KejuanganH ' . 1 Pengembangon Teknologl Kimia untuk Pengolohan Sumber Doya Atom Indonesia
' Yogyakarta, S Maret 2013
ISSN 1693-4393
Two main steps of the pillarization process were as follows, I). Inserting a pillaring agent to the layer between the clay sheets, 2). Calcining the material to make the pillaring agent incorporated and tied into the solid sheets strongly. The s<Kalled pillaring agent is any substance that can fonn the pillars on sheets of clay, so the clay becomes porous. While, the insertion of these substances into the space between the sheets (interlayer) without changing the structure of the sheet is called intercalation stage. Bentonite that has undergone a process of pilla.riurion is called pillared bentonite clay[Robert et aJ. , 1999].
To fonn a stable pillared bentonite with permanent porosity, the process of heating (calcination) needs a great consideration. The best temperature range for calcination is between 300-500 °C[Barrer et. al, 1978]. Pinnavia described that the calcination process at the temperature range makes the pillaring agent strongly bind to the bentoniteclay sheets. This is indicated by the spectral data A I MAS-NMS on smectite clays pillared with AI (Barrer et at, 1978). After experiencing pillarization, the pillared bentoniteclay has expands vertically compared to prior pillarization, and can not return to the original fonn despite the dehydration happen[Robert et al., 1999].
Besides being able to expand vertically due to dehydration, other characteristics ofi>illared bentonite is having basal spacing at least 0.315 to 0.353 run. The pillaring agent molecules are laterally in the area ofintermelarwhich has porous characteristic. However, the basic criteria of pillared bentonite is having a good thennal and chemical stability and having a good distribution of the pillars in the intennelarregion [Robert et al., 1999].
The aim of this research work is to develop a mass transfer model which is suitable for basic blue adsorption onto pillaredbentoniteclay by taking into account the intra particle concentration gradient and applying tinier equilibrium equation. The suitability of the model was examined by using the data of laboratory experiments and analyzed quantitatively.
2. Theory and Experimental
2.1 Modeling
Since the pillared bentonite clay particles used in this research work is sphere-like shape, it was considered appropiate to assume the shape of pillared bentoniteto be spherical shape, then the mass transfer model was developed using volume element mass balance for sphere:
If q = C + C then f.J
With
Figure l.Vofume element mass balance
m - m =m in O'UI ace
(-D .4,r.r2~ )-(-D .4.u2~ )=4Jf1'2tv!..(c +C) e ~r e ~r+tv ol f.J
!...(r2 oc) = !..(c +c) or or ot f.J
o2c +.!. oc =-'-!..(c +c) a,.2 r iJr D ot f.J
e
i?c 2 oc 1 iJq -+--=--a-2 r 3- D 01 e
0 Progtam Studi Teknik Kimia, FTI, UPN "Veteran· Yogyakarta
(1)
(2)
A7-2
~~
1 · Prosiding Seminar Nasional Teknik Kimia "Kejuangan"
. II Pengembangan Teknologi Kimia untuk Pengolohan Sumber Doyo A/am Indonesia · Yogyakarta, 5 Maret 2013
Solution of the equation (3) is
q =C +C Jl
= _£+C C+P
Cq + fJq = ae + c2 + tx:
c2 +(a+ p-q)C- fJq = 0
C -(a+ p-q)±J(a+ P-q)2 +4/}q I) 2
-(a.p +P- q) ± J(a.p +P-ql+4/Jq C - p p
2c
ISSN 1693-4393
(3)
(4)
Equation (2} is the general form of differential equation for adsorption of solute from liquid phase to solid sphere which was taken into account the intra-particle concentration gradient. Differential equation (2) was solved using finite difference approximation which expressed as:
(i-l)c 2 (i+lf - . .-- .C .. +- . .+q . . = q .. i.M I -I,J M 1,) i.M I+ I,J 1,) l,j+l
M= (t.r'f Dl!J
e
For a certain position in spherical shape, it is necessary to modify the general finite difference equation as follow: At the center of the sphere (i = 0)
6 6 q =--c +-C +q
O, j+l M O,j M l,j O,j
At solid surface (i = N)
D p N,j N-l,j I c AL N,J l c -c k .4JCR2(c -c .)]
q = • + 61+q N,j+l ea (t.r}'! a l'lT N,j
Solute concentration in the liquid phase (CAL) was calculated using the equation:
4nNR 2 CAL . ,=CALO - -Jr qdr
,) + , v 0
(5)
(6)
(7)
(8)
(9)
There are several methods available to solve the finite difference approximation such as explicit (forward),
implicit (backward) and Crank-Nicolson[Wahyudi Budi Sediawan and AgusPrasetya, 1997]. In this research work,
the fmite difference approximation equation was solved using explicit method. The suitability of the model was examined by evaluating the sum of squares of errors (SSE) which wasexpressed as:
SSE== :E (Cmodel - Cexpmmental (10)
2.2Experimeot
Bentonite clay, which was originated from Pacitan, East Java - Indonesia, was treated following intercalation and pillarization method. The measurement of some physical properties such as density, total porosity, macro and micro pore size and surfuce area BET (Brunauer, Emmet, Teller) was conducted afterward. Cationic surfuctant (HDTMA-CI) was used in intercalation while sodium hydroxide and AICh was used during pillarization process. The C. I. Basic Blue 4lunder the trade name T/A Blue RGN-T200% was used as adsorbate.
Intercalation is performed by preparingbentonite suspensions in which the ratio of bentonite/water = I gram/50 ml was appliedand was diluted using distillate water to 1000 ml of total mixing volume.Surfactaot was then added to the bentonite suspension and was stirred for 5 hours at a temperature of 80 °C. The weight ratio of surfactant/bentonite used was I : 25. After being stirred for 5 minutes the solution was cooled briefly and was separated from the filtrate by a vacuum pump and then was dried in a laboratory scale oven at 100°C for 1 hour.
Pillaring agent was made by mixing NaOH and AICI3, in which the ratio ofOH/AI was 0.8, at a temperature of 80°C and was stirred until homogeneous mixing was reached. Intercalated bentonite suspensions was stirred and heated until the temperature reaches 80°C. After that pillaring agent, ratio of Allbentonite = 10 mmollgram,was
0 Program Studi Teknil< Kimia, FTI, UPN "Veteran" Yogyakarta A7 - 3
m :•midi"" ""''"" NM"""I T .. olk Om I• ··~"'"""' 11 Pengembongon Teknolog/l(imio untuk Pengolohon Sumber Dayo A/om Indonesia ' Yogyakarta, 5 Maret 2013
ISSN 1693-4393
added gradually to a suspension of intercalated bentonite and stirred for 5 hours at 80°C. After 5 hours. bentonitewas separated from the filtrate using a vacuum pump and dried in an oven at I 00 °C for I hour. Finally the bentonite was calcined at 500°C in a laboratory scale furnace for 4 hours with a gradual increase to the calcination temperature every 15 minutes to avoid a collapse in the structure of pillared bentonite. To ensure uniformity, cool pillared bentonite powder then passed to a I 00 mesh sieve prior the analysis of surface area BET and other physical and chemical characterization. Pore radius. pore surface area and pore volume was analyzed using NOV A Data Analysis Package Ver. 2.00. Quaotachrome Corporation.
Adsorption test of AI pillared bentonitepowder was performed using an artificial waste which was prepared by dissolve a basic blue dye in 500 ml distiJied water. Experiments were conducted by varying the intial dye concentration andbentonite weight /solution volume ratio. During the batch experiment,the dye concentration changes in liquid phase was detected by taking samples and measure the concentration using an UV spectrophotometer.
3. Results aod Discussion
The scanning electron microscope (SEM) image of original and pillared bentonite wasshown on Figure 2 and Figure 3. respectively. The effect of the pillarization treatment was shown by the different surface appearance ofthe two images. The pillared bentonite image showed clearly the formation of basal spacing and area of intermelar where the pillaring agent molecules are laterally distributed.
The result of the composition analysis of the original and pillared bentonite was shown on Table I. It could be seen from the table that the mass fraction of aluminum oxide increased to some significant extent, i.e. from 18.23 %w to54.16 %w. The increasing aluminum oxide content isdue. to the infiltration of pillaring agent AICh. Then, it indicated that the pillarization process has strongly incorporated and tied the pillaring agent into the bentonitesolid sheets. While the mass fraction of some components including silicon dioxide, calcium oxide and ferro oxide decreased as consequent of increasing the aluminum oxide content.
Larger pore volume was detected on pillared bentonite which reflects increasing the surface area after pillarization. Accumulated pore volume and pore surface area were presented on Figure 4 and Figure 5, respectively. The figures showed clearly that the pillarization increased pore volume and pore surface, significantly. There has been a tremendous shift of pore size distribution dominates, from 0-20 Angstroms for the original bentonite to 20-500 Angstrom for pillared bentonite.
Figure 6 and Figure 1 displays basic blue concentration in the liquid phase by comparing the experimental data to the calculated value from the model for variations in the initial concentration. While Figure 8 and Figure 9 displays the same thing for variations in the ratio ofmass of bentonite to volume of solution.
The parameters associated with the calculation of dye concentration, which include the distribution constant, '· external mass transfer coefficient and diffusivity coefficient., generated during solving the finite differenceapproximationwere presented in Table 2 and Table 3.
Figure 2: Scanning electron microscopeimage of original bentoniteat magnification 1 OOOx
0 Program Studi Teknik Kimia, FTI, UPN "Veteran• Yogyakarta A7-4
Bt• Presiding Seminar Nasional Teknik Kimia •Kejuangan• 1 • Pengembongon Telcnologi Kimio untuk Pengolohon Sumber Doyo A/om Indonesia
' Yogyakarta, 5 Maret 2013
ISSN 1693-4393
Figure 3: Scanning electron microscope imageof pillared bentonite at magnification I 000 x
Table 1: Composition of Original and Pillared Bentonite
Original Pilar red Component
bentonite, •;.w bentonite , %w
Na20 0,05 0.54 MgO 3.70 2.32 AhOJ 18.23 54. 16 Si02 68.69 40.91 CaO 3.90 0.06 Ti02 0.59 0.16 FeO 4.83 1.85
Analysi~ methode : SNI 0449-20 I 0
0 200 400 Pore Radius (Angstrom)
Figure 4: Accumulated pore volumeversus pore radius of original and pillared bentonite clay.
0 Program Studi Teknik Kimia, Fll, UPN 'Veteran• Yogyakarta A7-5
n:, . '\!l!7, Presiding seminar Nasional Teknik Kimia "Kejuangan"
1 j , Pengembongon Teknologi Kimlo untuk Pengolohon Sumber Doya Atom Indonesia
' Yogyakarta, 5 Maret 2013
ISSN 1693-4393
20000 cc .-I ••• • 0 0 16000 • 0 • -... •
~ ~
2 12000 I ~ • Pillared "' cc • ~ c: <( • -... 8000 • ,... r • c:
• r:; p 4000 _Lt?:riginal <{ CJ
0 0... 0 · -{) ... - - ·
0 200 400 Pore Radius (Angstrom}
Figure 5: Accumulated pore surface area versus pore radius of original and pillared bentonite clay.
1
0 .9
0.8
0 .7
'~ 0.6
J 0
0.4
0.3 • 0 .2
0.1 -
0 ... -·
0 so . 100 ttme(sec)
150
Figure6: Basic blue concentration ratio in liquid phase versus time. The experimental data symbol for related initial concentration: •I 00 ppm, 0 200 ppm, i300 ppm, o 400 ppn, + 500 ppm.The curved line expressed the calculated result from the modei.The mass ratio ofbentonitelsolu!ion: 0.10 g/100 mi.
600
500
l 400 . r;:' ~ 0 Q; '0 0 E 200 ... f)
100
0
0 200 400 600
Cu. experimental (xJO'll), fll~
Figure 7: Basic blue concentration in liquid phase, model versus experimental data. The experimental data symbol for related initialconcentration: • 100 ppm, 0200 ppm, i 300 ppm, o 400 ppn, + 500 ppm.The mass ratio of bentonite/solution: 0.10 g/100 mi.
G Program Studi Tel<.nik Kimia, FTI. UPN ·veteran· Yogyal<.arta A7-6
~.Prosiding Seminar Nasion a I Teknik Kimia "Kejuangan•
I Pengembongon Tekno/ogi Kimio untuk Pengofohon Sumber Dayo Afom Indonesia ' · Yogyakarta, S Maret 2013
ISSN 1693-4393
Distribution constants for dye adsorption by bentonite was apparently not affected by the dye concentration in solution, while an increase in the ratio of bentonite/solution slightly lowering the distribution constant value as was shown on Table 2 and Table 3. It wasn't found a clear correlation between the external mass transfer coefficient and the initial dye concenn-ation as well as the bentonite/solution ratio.
Varying the initial concentration of dye at constant bentonite/solution ratio and varying the bentonite/solution ratio at constant initial dye concentration mean varying the dye concentration during the batch adsorption process.
While vaJue of the external mass transfer coefficient calculated from the same experimental data source vary, as shown in Table 2 and Table 3. It mean that a change of dye concentration might be result in a change of an eddy diffusivity and/or the thickness of liquid phase interface film, since an external mass transfer coefficient depend on both the ed dydiffusivity and thet hickness of liquid phase interface film.
1 0.9 0.8 0.7
J 0.6 0.5 .
-~ 0.4 ._, 0.3 • 0.2 0.1
0 ...
0 200 400 600 BOO
time(sec)
. Figure 8: Basic blue concentration ratio in liquid phase versus time. The experimental data symbol for related bentonite/solut.ion ratio: • 0.20 g/1 00 ml, o 0.25 g/1 00 ml, j 0.35 g/1 00 ml, + 0.40 g/1 00 mi. The curved line expressed the calculated result from the model. The initial concentration of basic blue was 600 ppm.
GOO
l 500
l>(· 400 .::' 0 --!::! -.. ~ 200
:3 100
0
0 200 400 600
Figure 9: Basic blue concentration in liquid phase,model versus experimental data. The experimental data symol for related bentonjte/solution ratio: • 0.20 g/100 ml, o 0.25 g/100 ml, A 0.35 g/100 ml, + 0.40 g/100 mi. The curved line expressed the calculated result from the model. The initial concentration of basic blue was 600 ppm.
0 Program Studi Teknik Kimia. FTI, UPN Veteran• Yogyakarta A7 - 7
~~ ~
Prosiding Seminar Nasional Teknik Kimia "Kejuangan· Pengembangan Teknologi Kimia untuk Pengolahan Sumber Daya AJam Indonesia Yogyakarta, 5 Maret 2013
Table 2: Equilibrium, kinetic parameter, and SSE at various initial dye concentration for bentoniteld~e solution ratio 0.1 g/1 00 ml
CALO a ~ kc De SSE
ppm (Umg) (Umg) cmls cm21s 100 2.5 56.35 5.5 6.6 1004 6.7 w·11
200 2.5 80.84 2.8 7.0 10-4 1.8 10"15
300 2.5 145.5 2.5 7.0 10-4 ) .5 JO· IS
400 2.5 101 .2 2.7 6.6 10-4 5.7 w-u 500 2.5 67.90 5.5 6.6 10-4 2.7 w-•s
Table 3: Equilibrium, kinetic parameter, and SSE at various bentonite/dye solution ratio for initial dye concentration 600 ppm
BID IJ kc De
g/100 a SSE
mL (lJmg) ~lJmg) cm/s cm2/s
0.2 1.2 39 8.0 t.4 10·3 5.5 10"15
0.25 1.5 38 5.0 7.0 10'3 5.) 10-IS
0.35 1.5 34 0.9 8 .0 10·3 2.2 w-rs
0.4 59.2 101 17.0 1.5 to·3 6.5 w·'7
ISSN 1693-4393
The sum of squares of errors which was used to examine the suitability of the developed model was presented in Table 2 for initial dye concentration variation and in Table 3 for bentonite/solution ratio variation. Thevalue were in the range of 6.510'17
- 5.710'15.This low value of SSE indicates that the developed mass transfer model is suitable for basic blue adsorption onto pillared bentonite clay.
4. Conclusion
The effect of the bentonitepillarization was shown by the different surface appearance which was found on the scanning electron microscope images. The formation of basal spacing and area of interrnelar was identified in the pillared bentonite.
After pillarization, the mass fraction of aluminum oxide increased to some significant extent, i.e. from 18.23 %w to 54.16 %w. The increasing aluminum oxide content is due to the infiltration of pillaring agent AICh. It indicated that the pillarization process has strongly incorporated and tied the pillaring agent into the bentonite solid sheets.
Larger pore volume was indicated by pillared bentonite which reflects increasing the surface area after pillarization.There has been a tremendous shift of pore size distribution dominates, from 0-20 Angstroms for the original bentonite to 20-500 Angstrom for pillared bentonite.
This research work has proven that the developed mass transfer model are suitable for basic blue adsorption onto pillared bentonite clay.
Acknowledgements
The authors wish to thank The Technological And Professional Skills Development Sector Project (TPSDP) ADB Loan No: 1792 - INO for providing the scholarship. Financial support from The University ofSurabaya is gratefully acknowledged.
0 Program Studi Teknlll Kimia, FTI. UPN 'Veteran• Yogyakarta A7-8
~Presiding Seminar Nasional Teknik Kimia "Kejuangan"
I Pengembongan Teknofogi Kimio untuk Pengofahan Sumber Daya A/am Indonesia
Yogyakarta, 5 Maret 2013
Nomenclature
BID CAL CALo
kc Min Mout M.acc N R r
bentonite/dye soultion ratio (g I I 00 ml) solut concentration in liquid phase (mollml) initial solut concentration in liquid phase (mollml) solut concentration in liquid phase interface (mollml) solut concentration at position i at time j solut concentration in solid (gig solid) diffusivity coefficient (cm2/s) Volume Solution {m/) external mass transfer coefficient (cm/s) rate of mass inflow (molls) rate of mass outflow (molls) rate of mass accumulated (moVs) total number of particle sphere radius (em) distance from the sphere center in radial direction (em) time(s)
Greek letters e particle porosity Pad• adsorbent density (glml) a , ~konstanta Langmuir (Umg)
References
I. Astrology (2000). Clay-Catalyzed RNA Polymerization Activity, New York.
ISSN 1693-4393
2. Barrer, R.M., F.R.S. (1978). Zeolites and Clay Minerals as Sorbents and Molecular Sieves, Academic Press, London.
3. Olphen, H.V. (1977). An Introduction to Clay Colloid Chemistry for Clay Technologist. Geologist and Soil Scientist. 2nct Edition. A. Willey-lnterscience-Publication, Canada.
4. Pinna via, T J . ( 1983). Intercalated Clays Catalyst Science220, 4595: 365-371. 5. Robert A. Schoonheydt, Tom Pinnavaia, Gerhard Lagaly and Nick Gangas (I 999). Pillared Clays and
Pillared Layered Soilds. 6. Wahyudi Budi Sediawan and Agus Prasetya (1997). Pemodelan Matematis dan Penyelesaian Numeris
Dalam Teknik Kimia. Penerbit ANDI, Yogyakarta.
0 Program Studi Teknik Kimia, FTI, UPN "Veteran• Yogyakar1a A7-9
~Prosiding Seminar Nasionat Teknik Kimia " Kejuangan•
i · Pengembangorr Teknolagi Kimia untuk Pengolohan Svmber Doyo A/om Indonesia ' Yogyakarta, 5 Maret 2013
ISSN 1693-4393
1. Penanya
Pertanyaan
Jawaban
2. Penanya
Pertanyaan
Jawaban
3. Penanya
Pertanyaan
Jawaban
Lembar Tanya Jawab Moderator: Tjukup Marnoto
Mujahid (Teknik Kimia, UPN "Veteran" Yogyakarta)
Selain AI apakab dapat digunakan Jogam yang lain?
Selain AI, dapat digunakan Zn, sSemua logam dapat dipakai. Untuk minyak atsiri dipakai Fe. Untuk zat warna dipakai AI 95,6%.
Dinda TriG. (Teknik Kimia, UPN "Veteran" Yogyakarta)
Mengapa menggunakan bentonit?
Adsorben yang murah bermacam-macam, karena dipasaran banyak bentonit yang tidak terpakai. Dulu untuk menyerap minyak atsiri dan zat warna basa lainnya.
Dr. Ir. Tjukup Mamoto, MT (Teknik Kimia, UPN "Veteran" Yogyakarta)
Bagaimana jika pori berpori lagi?
Pori ada riga macam: makropori, mesopori dan mikropori. Jadi dari data BET menggunakan mesopori .
• Program Stud! Teknik Kimia, FTI, UPN "Ve~~tran• Yogyakarta A7 -10
Prosiding Seminar Nasional Teknik Klmia "Kejuangan• Pengembangan Tekno/ogi Kimis untulc Pengolahen Sumber Days A/am Indonesia Yogyakarta, 5 Maret 2013
lndeks Penulis Makalah
Peoulis Kode Makalab Peoulis
Abdul Aji Kresna Tri Anggara 114 Diah Susetyo Retnowati
Abdullah Effendi Hl4 Didi Setiarto
Abidin F4 Dini Kurniawati
Abu Hasan J6 Diyoo Ikhsan Achmad Halim Purbobandono 15 Djumhawan Ratman Permana
Achmad Roesyadi CIO,D2 Dody Priadi
Adang Hardi G E6 Dwi Ratna Mayasari
Ade Christine Aritonang H5 Dwi Suheryanto
AdeT.N H8 Dyah Tri Retno
Adi llcham Hll E. Muhari
Aditia Nugraha E3 Edgie Yuda Kaesti
Aditiyo Ramadhan C5 EdyNwsanto
Agus Prasetya Hl3 Edy Supriyo
Agustanhakri Bakri 15 Eka Desi Lestari
Agustinus Ngatin 14 Emma Savitri
Akbarningrum Fatmawati C7,C8 Emmanuela M. Widyanti
Alan Syahputra Hll Emmmanuela Maria Wijayanti
Alfa Widyawan A8 EnnyL
Anas Puji Santoso A4 Enny Sudarmonowati
Andri Cahyo Kumoro Jl3 Evy Nur Afiiyanti
Andy Chandra C2 FaizahHadi
Anies Mutiari f3 Fabnayati
Anitarakhmi Handaratri Cl5 Gatot Trilaksooo
AnnaR El GedeWibawa
Ardila Hayu Tiwikrama Al Gigih Abnaji
Arenst Andreas C5 Gilang Agung Prabowo
Arief Budiman 15 Gloria Marcella Morgen Wiria
Arif Andrianto 19 H. Budiastuti
Arifudin ldrus C4 Hadiatni Rita Priyantini
Aris Setyadi 12 Hambali
Arlinda Indreswari H5 Hani Fitriani
Aswati Mindaryani F3 Hariyadi
Bambang Hari. P H7 Harli Talla
Bambang Poedjojono Cl2 Hary Sulistyo
Benny Lubiantara MS Hendra Amijaya
Catarina Sri Budiyati dan Jl3 Hendra Amijaya
Cecep Taufik Rustendi JlO Hendriyana
D. Widyabudiningsih Cl7 Herlina
Dadang El Herman
Dedi Cahyoko Aji C3 Heny Santoso
Dedy Kristanto Cl Heryoki Yobanes
DewiW H8 I Putu Suarsana
Diah Agustina Puspitasari C12 I Wayan Wannada
• Program Studf Teknik Klmia, m , UPN "Veteran• Yogylkarta
ISSN 1693-4393
Kode Makalab
113
MS
D3
F7
E2
E4,E5
Hl4
Jl,12
HJl Cl7
C3
C4,Dl
C6
E4
Cl5
H6
14 El
E2,E5
16
E8 18 16
AI
17
H9
13
Cl7
A7
F4
E4
A2 C4,Dl
16 C4
Dl
F8,H7
F4
H12
12, 13
17
C3
Dl
lndeks- 1
Prosiding Seminar Nasional Teknik Kimia "Kejuangan· Pengembangan Tekno/ogi Kimia untuk Pengo/shan Sumber Days A/am Indonesia Yogyakarta, 5 Maret 2013
Peoulis Kode Makalab Peoulis
Ibnu Eka Rahayu Al Pujianti lntan P
IGS Budiaman Jl4 Purwoko
lka Perwitasari J14 Putri Restu Dewati
llham F HS R.P. Djoko Murwooo
Imam Prasetyo A7 Rahma Wulan Febriati
Indah Prihatiniogtyas D.S F7 Regina Leoni
Indrihapsari ES Rispiandi
Irene Tedjasaputra l3 Rizki Kurniasih
lrfan Djatnika E3 Roclunadi
Isti Pudjihastuti C6 Ronny Kurniawan
Ivan Kristianto 12 Rudy Agustriyanto
Jarot RahaJjo J5 S.Juhanda
Juan August Naldo H2 Sabrina
Judy Retti Witono C2 Santi Dyah Savitri
Kadarisman F4 Sari Nengsih
Karyadi E6 Setiyo Gunawan
Kusyanto F6 Shirleen Rosemarie
Laksmi Andri A E6 Sihana
Leonardo Arief H2 Silvia Wulandari
Lies Susilaning Sri Hastuti H3,J3 Sirin Fairus
M. Ghozali C17 Siswo Sumardiono
M. Novie Aprianto Hll Siti Diyar Kholisoh
M.Syahri Fl • Slamet Widodo
Mahfud C9, D3,F6 Sofiatun Anisah Mahreni H12 Sri Wahyu Murni
Marthen Luther Doko CI3, Cl4 Sri Aguswarini
Martin Wijaya Kusuma HlO Sri Setyowati
Mega Kasmiyatun F2 Sri Suhenry
Mentik Hulupi J4 Sri Sukadarti Mohamad Eody Ytilianto F2 Sri Utami Handayani
Muhammad Catur S. W Hl2 Sri Wahyuni Santi R
Mujinah El Srihastini
Mukhtar Ghozali HS Subagyo Pramumijoyo
Mulyono 111 Sudaryadi
N. Sri Hartati E2,E5 Sugeng Sapto Suryono
N.S Hartati E4 Suharto Honggokusumo
Nadiem Anwar 16 Suhartono
Nancy Siti Djenar II Suharwadji Sentaoa
NettyK H5 Sumari
Ninik Liotaog II Sumarno
Nita Aryanti F7 Supranto
Novian Aribowo A2 Suprapto
Priyono Kusumo F2 SuryaMadya
• Program Stucli Teknik Kimla, FTI, UPN 'Veteran• Yogyakarta
ISSN 1693-4393
Kode Makalab
14
E6
15
113
H14
HI
H6
ES A7, J6
E3
C7,C8
E3
C2
Cl2, 02 E2
AI
HI
Hl3
14
H5
C6
Hl4
A5, A6
Cll
114
E6
E6, 110
H4
ES A3
114
El
C4
111 Dl
J6
14
J7
ClO
C9, ClO, C l l, Cl5, H9
H4
J9
MU2
lndeks- 2
Prosiding Seminar Nasional Teltnik Kimia "Kejuangan• Pengembangan Teknologi Kimia untuk Pengo/shan Sumber Days A/am Indonesia Yogyakarta, 5 Maret 2013
Peoulis Kode Makalah Penulls
Susanti Rina Nugraheni Hl3 Wibowo TediHudaya HI, H2, HIO Widyastuti Tjukup Mamoto Fl Widyastuti W Tundjuog lndrati Y Jll,Jl2 William Kusnanto
Tuojuog Wahyu Widayati Hl2 Wiralni Umi Nur Sbolikba F4 Y ahma Muhammad Sakti Vonny Indah Sari J8 Y eni Triyani Wahju Eko Widodo 17 Yulius Deddy Hermawan Wahyu Bahari Setianto 17 Yunilda Wahyudi Budi Sediawan A7 Yuyun Yuniati Waran Rosiban 14
• Program Studi Teknik Kimia, FTI, UPN "Veteran" Yogyakerta
ISSN 1693-4393
Kode Makalah
FS
JIO El
AS F3
Cll
16 FS JIO
C9
lndeks • 3
Prosiding Seminar Nasional Teknik Kimia "Kejuangan· Pengemb8ng811 Teknologi Kimis untuk Pengo/shan Sumber Days A/am Indonesia Yogyakarta, 5 Maret 2013
Indeks Kata Kunci
Kata Kuoci Kode Makalab Kata Kunci 99Mo F4 carbon 99Mof9"'Tc generator F4 Carbon Dioxide 99mTc yicld F4 carboxyl group
99mTc-tetrofosmin JIO cassava (Manihot esculenta, Crantz.)
a mixture of palm shells and J8 cassava flour
fibers
Aceptic El cassava peel
acetic acid Cl5 cassava starch
Acid Catalyst 13 catalyst
Acid value 17 cellulose
activated carbon J8 ceramic
Adsorption A7,F3 cheese whe
adsorption power of activated J8 chemical activation
carbon to the iod solutions
AI electrodes cs Chemical Laboratory
alum solvent H4 cbitosan
Anaerobic digester H8, Hl4 C02 Flooding
animal manure Hl4 C02 injection
anyaman J3 C02 removal
Arenga pinata waste Hl3 Coagulation
Basic Blue A7 coal
batik process H3 Coal liquefaction
Bentonite Clay A7 coconut shell
biochar H14 color fastness
Biodiesel 02, 03, II, 12, 13, 15 Compatibility
bioethanol C7 Composite
biogas H8,Hl4 compressive strength
blowing agent Cll concentration
boWtd rubber J6 consumer acceptance
bread C2 Conversion
bromelain E3 Cooking Oil
bubble column photoreactor H2 corncob
Ca(OH)2 catalysts 03 Com Starch
cadmium HI cotyledon node
cadmium-cyanide HIO CsOH
Calcinated Waste Eggshell 12 culinary properties
Catalyst
• Program Studi Teknit( Klmia, FTI, UPN "Veteran• Yogyakarta
ISSN 1693-4393
Kode Makalab
JJ2
AI
C6
E2, E4
C2
E8
C6
Dl,H6
ClO
Hll
C7
J8
Hl2
Cl5
C3
FS
F3 Hl2
C4
Dl
14
Jl
Cl
JS
Hll
F6
Jl3
J9
12
H6, 14
13
E5
A6
Jl3
lndeks -4
~ Presiding Seminar Nasional Teknik Klmia "Kejuangan· ISSN 1693-4393
d Pengembsngsn Teknologi Kimis untuk Pengofshsn Sumber Days A/em Indonesia Yogyakarta. 5 Maret 2013
Kata Kuoci Kode Makalah Kata Kuoci Kode Makalah
cyanide HJ flocculation HJ2
Cyclobexane cs flood balancing A2
degradation C9, CIS flow-rate HS
degree of crosslinking J6 gadung flour JJ3
Dehumidifier A3 gandapura F2
delignification H6 gasification stove 14
delignified 16 gaultherin F2
dew point A4 genotype E2
D-Glucose 13 ginger drying A3
diagnosis JIO glucose CIO, H6
dimension electrode H7 gluten C2
dissolution Jll glycerol C9, Cl2
Dolomite It glycerol carbonat CI2
Double Pipe Heat Exchanger AI glycol losses A4
double promotor D2 graphite Jl2
drought stress E4 heat loss AS
drying A3 heat pump dryer A3
dye binding by alkali J2 hexavalent
H2,Hl0 chromium
Dye solution CS hole scavenger H2
dyes H9 Hydrogen cyanide
E2 (HCN)
Dynamic stud C7 Hydrolysis EIO, H6, H9, 16
Eshape H7 hydrothermal C9, CIS
Electrochemical JS 1-131 E6
Electrocoagulation CS,H7 lAA ES
electroplating HI , H2, HJO indigo leaves J2
Elektroforesis Fl Injection Water
CJ Quality Elektrokimia A6 injeksi C3
emulsion 114 instant noodle 113
emulsion oil in water F7 intensity Jl
Energy A3,C4 IPA AS
enhance oil recovery FS iron ore OJ
enzyme gaultherase F2 iron powder J4
Equilibbrium F3 isolation, E3
esterification IS Jatropha curcas oil 03
Etch stop A6 Jet-loop fixed bed FS
Etsa A6 Kem.iri Sunan II
Etsa Anisotropik AS KOH AS, A6
faktor gesekan (fc) Fl Lactic Acid
J1 Bacteria
Fermentation C7, ES, J2 Leachate Cl7, HS
ferosulphate Jl leaf ketapang
Jl extract
• Program Studi Teknlk l<imia, FTI, UPN "Veteran• Yogyalcarta lndeks- 5
lit Presiding Seminar Nasional Teknik Kimia "Kejuangan· ISSN 1693-4393 Pengembsngan Teknologi Kimia untuk Pengo/shan Sumber Daya A/am Indonesia Yogyakarta, 5 Maret 2013
Kata Kunci Kode Makalab Kata Kunci Kode Makalab
lignin Jl4 PBZ-TEOS F4
lignosulfonate Jl4 Pemanfaatan )3
LT-ITSOFC J5 Peng-Robinson EOS AI
Lubricant 17 Perfonnance and C13, Cl4 Robustness maceral C4 peuyewn flour C2
mass transfer F8 Pillarization A7
Media Fill El pineapple E3
Membrane F7 pollution H3
methane gas C17 Polycrylamide H9
methyl ester J9 polyethylene glycol (PEG-E4 6000)
MIBG E6 polyols Cll
Microbiology Cl polyurethane foam Cll
microwave F6 potential market Jl2
mine water H4 powder morphology Jll
mineral C4 precipitation E3 mixing temperature J6 precursor Jl2
mocaf characteristics J7 Principal Gain Analysis Cl3, Cl4
mocaf flour industries J7 process condition, J4
mocaf utilization J7 pyrolysis Hl3
Modeling A7 quality standard H4
Mohr salt J4 radiochemical purity JlO
mordant Jl radiopharmaceutical E6
myocardial perfusion JlO Radiopharmaceutical El
NaOCl F4 rate of steam condensation AS
NaOH 03 reactor C8
nata de cassava H5 reducing sugar 16
Natural Gas AI rendement F6 natural gas dehydration A4 Res am J3 process
natural rubber J6 reservoir pressure A2
network model F5 Response Surface C5 Methodology neuroblastoma E6 rice straw 16
Ni/yAl203 Cl2 Ring opening esterification 17 oil sludge Hll ROmembrane HlO
oligosaccharides CIO Scaling Tendency Cl oxidation C6,C8 scaling up E6
Oxirane content 17 shoot induction E5
P. Falcataria E5 Si (100) A6
palm oil 02 Silikon (Si) AS paper H5 simulation C8,F5
patchouli alcohol F6 single cell protein ES
• Program Studi Telcnlk Klmia, FTI, UPN "Veteran• Yogyakarta lndeks-6
Prosiding Seminar Nasional Teknik Kimia "Kejuangan· Pengembsngsn Teknologi Kimia untuk Pengolahsn Sumber Days Alsm lndon6sis Yogyakarta. 5 Maret 2013
Kata Kunci Kode Makalah Kata Kunci
Singular Value Cl3, Cl4 traditional
Decomposition (SVD)
sintesis 14 Transesterification
soil amendment Hl3 treatment efficiency
solubility C6 triethylene glycol
solvent F6 turbidity
Starch H9 two stage fixed bed anaerobic reactor
Starch graft Polyacryamide H9 Ultrafiltration
steam condensate AS ultrasonic
stedy state time 111 urea
Sterile El utilization
Strong Base Anion Exchange F3
UVffi02 Resin photocatalysis
sulfonation 19 Validation
sulfuric acid 16, 14 value chain
support 02 Vegetable oil
surface facilities FS waste
surfactant 19,114 Waste Cooking Oil
Surveillance A2 Waste water
swelling power C6 Water injection
tapioca wastewater H5 water injection plant
TDZ ES Waterflooding
temperature variable Hl3 wheat flour
textile waste water H7 wheat flour substitution
thermal efficiency 14 yield
Thermal E?'pansion 15 zirconium hydroxide
TMAH AS zirconium oxychloride
tofu liquid waste Hl4
• Program Studi Tetalik l<lmla, FTI, UPN "Vetefan" Yogyakarta
ISSN 1693-4393
Kode Makalab
Hll
03, II
Cl7
A4
H4
Cl7
E3,F7
ClO
Cl2
AS
HI, H2, HIO
El
112
17
H3,Hll
13,15
Hl2
A2
A2
Cl
113
J7
02
Jll
111
lndeks -7
YAYASAN KEJUANGAN PANGLIMA BESAR SUDIRMAN
UPN "VETERAN" YOGYAI<ARTA Jl. SWK 104 (Lingkar Utara) Condongcatur, Vogyakarta 55283 Telp. (0274)486188, 486733, 486402 Fac. (0274)486400
Jl. Babarsari 2, Tambakbayan, Vo~akarta 55281 Telp.(0274)485268, 486991
PROGRAM PASCA SARJANA PROGRAM STUDI 1. Magister Manajemen Agribisnis 2. Magister Teknik Pertambangan
3. Magister Teknik Geologi
4. Magister Manajemen
5. Magister Ekonomi Pembangunan
6. Magister Teknik lndustri
FAKULTAS EKONOMI 1 . Program Studi Manajemen 2. Program Studi Akuntansi 3. Program Studi Ekonomi Pembangunan
FAKULTAS PERTANIAN
1. Program Studi Agribisnis 2. Program Studi Agroteknologi
FAKULTAS TEKNOLOGI INDUSTRI 1. Program Studi Teknik lndustri 2. Program Studi Teknik lnformatika 3. Program Studi Dill Teknik Kimia
BIDANG KONSENTRASI - Manajemen Sumberdaya Manusia - Teknik Pengolahan Sumberdaya Mineral - Teknik Lingkungan Pertambangan - Teknik Eksplorasi Sumberdaya Mineral - Pengembangan Wilayah - Teknik Sumberdaya Air Tanah - Manajemen Keuangan - Manajemen Pemasaran - Pembangunan Daerah - Keuangan Daerah - Manajemen Aset dan Penilaian Properti - Teknik lndustri
FAKULTAS TEKNOLOGI MINERAL 1. Program Studi Teknik Geologi 2. Program Studi Teknik Pertambangan 3. Program Studi Teknik Perminyakan 4. Program Studi Teknik Lingkungan 5. Program Studi Teknik Geofisika
FAKULTAS TEKNOLOGI INDUSTRI 1. Program Studi Teknik Kimia
F AKUL T AS SOSIAL DAN ILMU POLITIK 1. Program Studi llmu Hubungan lnternasional 2. Program Studi llmu Administrasi Bisnis 3. Program Studi llmu Komunikasi
