Lecture05 Seawater Chemical Properties

48
ΩΚΕΑΝΟΓΡΑΦΙΑ Δ΄ ΕΞΑΜΗΝΟ Τα φυσικοχημικά χαρακτηριστικά του νερού Μέρος 1ο : Χημεία

description

Seawater Chemical Properties

Transcript of Lecture05 Seawater Chemical Properties

  • 1 :

  • 1.

    2. 2.1.

    2.2.

    3. 3.1.

    3.2.

    3.3.

    4.

  • ;

    :

    ,

    :

    / /

    ( / ) /

    / /

    (C, N, P, S)

    . . (. )

  • . . (. )

    :

  • . . (. )

    :

    / /

    /

    /

    ( CO2)

    CO2, ,

    (C, N, P, S)

  • 1.

    97% (1,37 x 109 km3) , ~ 20% / (12% )

    (2%)

    , 0.003%!!!

    (106km3) (%) 1400 96,96 50 460 890 43,4 2,97 15,3 1,05 0,125 0,009 0,0017 0,0001 0,065 0,0045 0,0155 0,001 0,002 0,0001

    1459 100

  • 1.

  • " "

    1.

    1.1.

  • " "

    ,

    ...

    1.

    1.1.

  • ...

    !!!

    : , , ( , ) ...

    " "

    1.

    1.1.

  • 1.

    1.2.

    =

    425x103 km3/yr1,38x109 km3

    = =

    3.250

  • 2.

    2.1.

    105

    ( ) ( ).

    ( )

    H20

  • 2.

    2.1.

    H2O

  • 2.

    2.1.

    H2O

    :

    :

    :

  • 2.

    2.1.

    fractal

  • 2.

    2.2.

    -

    4 C

    .

    (9% ) 0 C

    ()

    ( )

  • 2.

    2.2.

    -

    - 10 cm

    :

    , .. 0,1 C, , 1 cm

  • 2.

    2.2.

    ( )

  • 2.

    2.2.

    1 g -

    1 g -

  • 2.

    2.2.

    -

    540 cal/g 100 oC

    , .. 20 oC, (585 cal/g)

  • 2.

    2.2.

    -

    80 cal/g 0 oC

  • 2.

    2.2.

  • 2.

    2.2.

    .

    . .

    .

    .

    . .

    . 4 ( -1,90).

    . , .

    .

    , .

    . .

    . , .

    . .

    . .

  • 3.

    3.1.

    , 6 99%

    5 0,9%

    ~90 0,1%

    :

    (50 750 )

    (0,05 50 )

    (0,05 50 nM)

  • 3.

    3.1.

    g/Kg % Cl- 18,980 55,04 Na+ 10,556 30,61 SO2- 2,649 7,68 Mg2+ 1,272 3,69 Ca2+ 0,400 1,16 K+ 0,380 1,10 CO32- 0,140 0,41

    Br- 0,065 0,19 H3BO3 0,026 0,07

    Sr2+ 0,013 0,04 F- 0,001 0,00

    34,482 99,9

  • 3.

    3.1.

  • 3.

    3.1.

  • 3.

    3.1.

    :

    :

    : .

    : .

    :

  • 3.

    3.1.

    ( Marcet)

    William Dittmar HMS Challenger (1872-1876)

    ( ) ( ) ( ),

    :1. 2. 3. 3. 4.

  • 3.

    3.2.

    :

    ;

    :

    !!!

  • 3.

    3.2.

    (1909)

    (g) 1 kg ,

    S = 1.805 Cl + 0.030

    S = 35 Cl = 19.374

    S = 1.8154 Cl

    (g) 1 kg (ppt)

  • 3.

    3.3.

    (1978)

    S = 0,0080 0,1692 R151/2 + 25,3851 RT +14,0941RT3/2 7,0261 RT2 + 2,7081 RT5/2 + S

    :

    S = [(T = [(T - 15) / (1 + 0,0162(T 15))] + 0.005 15))] + 0,005 0,0056 RT-1/2 0,0066 RT 0,0375 RT3/2 + 0,636 RT2 0,0144 RT5/2

    RT = C (S, T, 0) / C (KCl, T, 0)

    C (S, T, 0) , C (KCl, T, 0) KCl 32,4356 g 1 kg .

    : 2 S 42

  • 3.

    3.3.

    : ( )

    :

  • 3.

    3.3.

    :

    : , ,

    : , : , , , ,

    ,, , , ..

  • 3.

    3.3.

  • 3.

    3.3.

  • 3.

    3.3.

    /

    33-38

    10 (brackish) 42 (hypersaline)Great Salt Lake 280 330 39

  • 3.

    3.3.

    ;

  • 3.

    3.3.

    :

  • 3.

    3.3.

    :

    (34,6 34,9 )

  • 3.

    3.3.

  • 3.

    3.3.

    !!!

    ,

    !!!

  • 3.

    3.3.

    :1. ( ) 2. ( )

    :1. ( )2.

  • 3.

    3.3.

  • 3.

    3.3.

    : ( ) ( )

    =

  • 3.

    3.3.

  • 3.

    3.3.

    :

    (1,16%) (30,61%), ( ) ;

    :

    . , .. :

    (Fe) (Al) ~100 (Ca) ~1.000.000 (Na) (Cl)

  • 4.

    .

    .

    Slide Number 1Slide Number 2Slide Number 3Slide Number 4Slide Number 5Slide Number 6Slide Number 7Slide Number 8Slide Number 9Slide Number 10Slide Number 11Slide Number 12Slide Number 13Slide Number 14Slide Number 15Slide Number 16Slide Number 17Slide Number 18Slide Number 19Slide Number 20Slide Number 21Slide Number 22Slide Number 23Slide Number 24Slide Number 25Slide Number 26Slide Number 27Slide Number 28Slide Number 29Slide Number 30Slide Number 31Slide Number 32Slide Number 33Slide Number 34Slide Number 35Slide Number 36Slide Number 37Slide Number 38Slide Number 39Slide Number 40Slide Number 41Slide Number 42Slide Number 43Slide Number 44Slide Number 45Slide Number 46Slide Number 47Slide Number 48