I II - US Environmental Protection Agency · I II II II I December 6, 1985 Ms. Linda Haas Boynton...

IIIIIIII

December 6, 1985

Ms. Linda Haas BoyntonSample Management Office300 North Lee Street* Suite 200Alexandria, VA 22314Dear Ms, Boynton:Enclosed please find the analytical results for Dioxin case SAS#1945-Fdata are summarized in several sections in the data package. These

c?or-vO

The samples were extracted as per Region V method, passed through option A cleanup —steps and reconstituted with isooctane. Samples 1945F-1 through 1945F-3, the sampledduplicate and matrix spike, numbers 1945F- 1D and 1945F-3SPK respectively, show thepresence of "grease-like" yellow precipitate upon conconcentration below 1ml andreconstitution with 50ul isooctane. The precipitate dissolves in 1ml hexane.These samples were subjected through an option D cleanup and subsequently analyzedalong with the method blank and samples 1945F-4 through 1945F-6,The samples that were passed through option cleanup step show no surrogate recoveryof 37CL4=2*3,7»8~TCDD and r jCL12-2»3,7,8-TCDF as well as no recovery of the internalstandard ! 3Cj2~2,3,7,8-TCuD. The method blank and sample numbers 1945F-4 through1945F-6 which were not subjected to option D cleanup show good surrogate recoveries.Sample numbers 1945F-4 and 1945F-5 show presence of hexachlorodibenzo-p-dioxins*5 isomers for samples 1945F-4, and 2 isomers for 1945F-5. However, based on our1on ratio criteria for Hexa-CDD, we quantitated on one isomer in each of thesetwo samples.Should you need additional information, please feel free to contact me. *Very truly yours,

GERE ENGINEERS, INC.

Antonio Lo Surdo» Ph .D.GC/MS Group LeaderAL/bppEnclosure

O'Bnsn & Gere Engineers. Inc8ox 4873 /1304 Buckley Road / Syracuse NY 13221 / (315) 451-4700Blue Bell, PA / Boston, MA / Landover. MD / New York, NY / St. touis. MO / White Plains, NY

a 1 enamels GEHBGC/H3 IHJgCTiOH LOGBOOK (CHRONOLOGY)

COLUMN INJECTION VOLUME CASE NO.

08 & C **. EP* NO.** '• t t*£*l

DATANAME

en- ftctl-ficcl-fi

ft***.

75

DATE

w/v/r.

V

\

Tlftf INITIALSI.

L .

L •

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i'

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COHHGJT3

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JCC/HS INJECTION LOGBOOK (CHRONOLOGY)

INJECTION VOLUME CASE NO.

08 A C Ho. £PA NO.3**

DATAHAKE

a

NUM8EK DATE////l T

nt

V

TIME

9'rtto

/7V/

M S /

(N fT iAU;<U

COfWEHTS

58

17H

IIIIIIIII

COLUMN

08 & G Mo

GC/HS INJECTION LflCSOOK (CHfiOHOCOCY)

INJECTION VOLUMI

NO.DATA FILE

NAI€

£>

) •* • • * '

CASE NO.

INITIALS

y

/aft?

M

/r

oo

IIIfil 0BRIENGCERE

8HECTf i - L .

OAT610

. //tf/fi

MQNO

I1 -

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I t

t i

OIX ICASE i

PCDD/PCDF Concent rat ton (PPT) as Dry WeightISOKER

ORIfOMOLQG

2 ,3 ,7 ,G-TCDFtV^M.V.fl-icbF& jtecovery

' 0913^2.3, 7, 8-TCDFAdded

Total TCDFsTotal Penta CDFsTotal Ifexa CDFsTotal Itopta CDFsOCDF2 ,3 ,7 ,B -TCDD3 'C l -2 .3 .7 ,Q-TCDn% Recoveryng3 'CI -2,3 f7 f3-TCOOAdded

Total Tetra CDOsTotal Penta CDDs124579 & 124639tfeCDB

123579 £ 1236(19HfiCOD

123169 HfiCOD1 23170 rifiCOD123670 HfiCDOS23- .67 A 123789lifiCDD

Total HfiCDO'sJ / CS- 123470 i!i;CDD% Recovery

mj37CS- 52321 70H/COD Added123^679 JljCDD12346?0 H?CODTOTAL H?CDDooro^C|-OCDn IRecovfcrync j3?Cl-OCDn Added

DATE: , ALIQUOT WT.////?/^ /<? (g)' [ ^^rF- AWO i ? £COt/ .

/^^

D£TE: / X ALIQUOT WT.////^'5 /S » (g)??4TF-*

NO R^co 1^

fO ^j-

PRECFSfOK ASRPD

PRECIS [ONLIMITS

COMMENTS

#^<J ^ei:^^

^nA/t> K t6^ ^

(t> v-J-

?

V

i 0 0 6 7 1 3

IX

PCDD/PCDF Concentration PPT) as Dry WeightISOMER

OKMOKOLOG

? ,3 ,7 ,8 -TCDFi^-i.V.fl-TCDF"'& Recoveryf lgSQ?2,3,7,8-TCDF

AddedTotal TCDFsTotal Penta COFsTotal Uexa CDFsTotaMlcpta CDFsOCOF2 .3 9 7, f i -TCBD3 'CS-2 .J .7 > e -TCDOt Recovery

ng3 7Cl-2 e3,? ta-TCDOAdded

Total Tetra CDDsTotal Penta OHls1246?9 A !24689HfiCOD

123679 & 123689HfiCOO

523469 ttfiCDD123^78 i!6CDOJ 2 3678 (fgCOnJ23^67 & 123789IfcCDO

Totd} KfiCOD'sJ 'C!-I23^78 H?COD% Recovery

ny 3 7CI- 1232478HfCM Added1231679 II/COO1234678 lf ?CDD •TOTAL h/CDftocon3?q-Gam ^Recoverymj3 'Cl-OCf»D Added |

DATE.v^ i ALIQUOT WT*fr//?/W /? (g)/f^iT-3 '

K/i) ##:<>/./o^J-

DATE: x / ALIQUOT WT.//AV/^i /9 (g)/W$F- *+

It*?*10 *$

PRECfsrOM ASRPD

PRECISIONLIMITS

COMMENTS

MO f i tCO^/

/6 ^Jts%it) ^j-

2/?V£ > Pfr

e

v

; Q 0 6 7 1 4

CASE IPCDD/PCDF Concentration PPT) as Dry Weight

ISOKEROR

HOHOLOG[DATE: , ALIOt/OT WT.I l^yS F —-S"

2 a 3 ; 7 8-TCOF j.& gecovery ^nrtl^/* T-V9 7 7 fl-TfHPl"""C-lV^* **» * »" * * * * * ' 1 iA 1A-4.Added ' »Total TCOFsTotal Pcnta COFs |Total tlexa CDFs (Total Mcpta CDFsOCDF2 .3 , ? , f i -TCDD% Recovery

ng^7CJ-2,3,7 f t f l -TCDDAdded

DATE: . .AL IQUOT WT./?Vi~ F- <*

OrH2 / *tO "v^g-

PRECISION ASRPD

PRECISIONLIMITS

COMMENTS

nt%"to

Tota l Tetra CDDs jTotal Penta CDDs I124679 & ^24689fffCDD

123679 & 123669HfiCDD

123469 HfiCOO123478 tifiCOO123670 1(6CDO123467 i 123709IffiCDL

Total HfiCRD's §i^c3 p^r3 /CI- !2347f l i f ?COD% Recovery 1

n t j i ? C» - 1232470ll;COn Added1 234679 H/CDD1234678 rj/CDDTOTAL lf;CODoc»n^ 'C j -OCOD XRccoverymji'C!-OCIK» Added

1 -, fid?7 7*|6

s

'V

' 0 0 6 7 1 5

IX

PCDO/PCDF Concentration PPT) as Dry heightCASE I 5/?S ft ~ f=

ISOMEROK

KOMOL06g .3 ,7 »0-TCDr.T-IV •.' f. "~*r i i>v

DATE: ALIQUOT WT.(9)

Mr ALIQUOT WT.F- tO

(^ PRECfS ION ASRPD

PRECISIONLFHETS

COMMENTS

.$ RecoveryAdded 10

Total TCDfsTotal Penta CRFsTotal Ifexa COFsTota l i Septa CDFsOCDF2 .3 ,7 > f l -TCDB1 Recovery %Added to

Total Tetra CDDsTotal Penta COOs12 >679 4 124689123679 4 123689IffiCOO

123469 HfiCDDTT fTlTJ23670 ISgCDO123467 £ 123709

% RecoveryItjCDn AddedT234679 H/CW1234678TOTAL H;COD3?C!-OCOf> XRecovcry

' 0 0 6 7 1 6

m mm rat mm OK on mm mm «•*>"•§ « mm mm onCASE *

PCDD/PCDF Concentration (PPT) as Dry HeightISOHER

OKItOHOLOG

2,3 .73-TCDF'S£Jr*.V*&-TttF".£ Recovery

>JI3C,>72.3 j-TCDF

Addedtotal TCbfsTotal Penta CDFsTotal Hexa COFsTotal Mepta COFsOCOF2 .3 , ? , a -TCDD3 ;Cl-2 ,3 .? ,8-TCDD% Recovery

mj 3 'C ) -2 t3,7,a -TCDDAdded

Total Tctra CODsTotal Peata CDDs124679 4 !24f»a9HfiCOO123679 & 1236S9llfiCOD

I231G9 tfsCOOI2347Q IteCDD123570 llgCOf)>23^67 A liJ37ft9JifiCOO

Tota l HfiCDO'sJ / C! - l ?3470 lf7CBD% Recovery

mj J 7Ci-123247BII/CDD Ad*fecf1234679 Jl jCDD12346?0 H?COOTOTAL H;CO&qcun^CI-OCfJD IHecoverymj3;C"r~GCflD AcEdecf

IDATE;^ , y ALIQUOT WT.l*/fi[fr 11 (9)i^^S^F- 3 «rtTT»x iift^

J\^ (R^Co^

to

DATE: ALIQUOT WT.^^ (9)

-PRECISION AS

RPDPRECISIOM

LIMITS

S^S^/W-/2

COMMENTS

MO ft^^l'ft> v-£

^

s

t

:• 0 0 6 7 1 7

III SUBJECT QY DATE JOSNO

IIIIIIII

I

Case No, J>JJ

GC/MS TUNING AND MASS CALIBRATIONDacafluorotrlphenylphosphine (DFTPP)^ Contractor ___ _________ : _____ Contract No.

DateInstrument IDLab ID 0-'m/t ION ABUNDANCE CRITERIA

nmeData Release Authorized By:

^RELATIVE ABUNDANCESI

68

69

70127197

198

1S9

275

365

441

442

•443

3O.0 • 60.0% of mats 138tea th*r> 2.0% of mau 69mau 63 fttativc abundarfe*teii Than 7.0% of nuu 69

40.0 - 60.0% of nuts 198

1*31 than 1.0% of mau 198bate twilc. 100% relative abundance

5.0 * 9.0% of mm 19810.0 -30,a of mats 198

greater than 1.00% of mau 198

prfrunt, fain (en than mast 443

gretttr than 40.0% of mass 19817.0 • 23.0% of maw 442

?£ *o-<**• c r71. tt-7* *•>' (j./)1'V?.-?^ '% '/^,iP •

6-? •/? . £^ •V?-7 •5f^/-?-^ t^)2

Oo

THIS PEflPOftMANCE TUNE APPLIES TO THE FOLLOWINGSAMPLES. BLANKS AND STANDARDS.SAMPLE 10CC3 - ft£C1 -^CC2 - ftca-flCC3~ ftCC j -/ >CC 3-/^

.

LAB 10

"?5X i H$/4<?f$O/r tIS2-)5"3i<r^

. . .

DATE

Value in (U/enthMn is % mats 69.2 Value in parenthesis ii % mast 442

Of ANALYSES

/// / V !TV

«

TIME OF ANALYSIS

H 3.?'iSJfi&J7ni°- jo/s^ /o^,z/ r/

FORM V 7/05

1 — '1t111B1wm

59 . 806 2 . 0 06 3 . 1 065 . 0065. 206 8 . 9 57 0 . 0 57 1 . 0 572 . 957 3 . 9 574. 957 6 . 0 57 6 . 9 57 8 . 0 57 9 . 0 58 0 . 0 58 1 . 1 59 1 . 9 58 3 . 0 58 5 . 0 58 5 . 9 59 0 . 9 59 1 . 9 5

2 . 84. 6 8

2 . 8 41 .4 1

.3779, 1 1

2 . 7 83 . 0 ?2 . 5 96 . 8 2

1 0 . 5 42 . 8 4

5 4 . 4 13 . 3 76. 584. 166 . 3 93 . 4 &6 . 3 84 . 2 5

4 2 . 8 42 . 6 61 . 62

1 1 0 . 0 01 1 1 . 0 01 1 3 . 0 01 1 3 . 201 1 6 . 9 01 18 . 101 2 1 . 9 01 2 3 . 0 0123 .85124 .051 2 6 . 0 5126 .951 2 7 . 9 51 2 8 . 9 51 2 9 . 9 51 3 4 . 0 5134 .351 3 6 . 5 5136 .951 4 0 . 8 51 4 2 . 0 5142 .951 46 . 35

3 4 . 2 16 . 2 61 .44.61

1 3 .27.53

1 . 3 52 . 17

.82

.37

.7149 .96

4 , 8 62 5 . 8 72 . 1 11 . 3 42 . 32

.22

.453 . 4 91 . 1 11 . 2 01 , 62

1 6 6 . 9 0168 . C O174 .00175 .001 7 6 . r O178 .95179.95180.751 8 0 . 9 5184.851 8 6 . 0 5136 .95i 8 8 . 9 51 9 1 . 9 51 9 3 . 0 51 9 5 . 9 5197 .351 9 3 . 9 52 0 2 . 8 52 0 3 . 9 52 0 5 . 0 52 0 5 . 9 02 0 6 . 9 0

5 . 8 43 . 2 21 .252 . 0 21 . 134 . 3 72 . 1 5

.92

. 3 02 . 0 5

1 3 . 3 04 . 9 9

. 8 21 . 6 S1 . 4 72 . 2 6

1 0 0 . 006. SI

.453 . 2 56. 14

2 2 . 3 24 .29

2 2 8 . 9 02 3 6 . 9 5240 .8524 1 .05242 .55242 .95243 .95244.85245 .45245 .65246 .05246 .952 5 3 . 0 52 5 4 . 5 52 5 5 . 8 52 5 6 . 9 5257. 952 6 4 . 8 02 7 2 . 9 02 7 3 . 9 02 7 5 . 0 02 7 5 . 8 02 7 6 . 6 0

.94

.27

.31

.30

.22

.2 19 . 3 91 .3 1

. 371 .47.9 1,22. 19

4 6 . 6 96 . 9 5

.452 . 8 41 . 0 11 . 4 93 .73

1 9 . 6 53 . 2 1

. 5 1

3 1 8 . 7 03 2 2 . 9 03 2 6 . 3 03 2 6 . 5 03 3 3 . 0 03 3 3 . 3 03 3 3 . 9 03 3 5 . 0 03 3 5 . 3 0353.75353 .953 6 4 . 9 537 1 . SO4 0 1 . 9 . 54 0 4 . 7 54 0 6 . 2 54 2 0 . 9 5422 .954 2 3 . 9 04 4 0 . 9 04 4 1 . 9 0442 .904 4 3 . 8 0

. 152 . 2 4

.24

.22

. 15. 19

1 .41.53.48.48.24

2 . 4 11 . 1 4

.48

. 39. 2 5. 5 2

3 . 9 2.70

8 . 6 85 8 . 9 51 1 . 9 61 . 1 5

OCMr—xOoo

I F i l f t >OFT44 50 H66pk fib 10

11C-)

OFTPP TUN ING fiUL 25SUB WRM £NH

: 193100:

50-•80^

70*

£0-

49/ O 3*

& /|IIjj}j

314fOii30q

IS?

ii

} . \Sft-Ji: •10- i1 L I

\

Ui, ,(,^ 50 lio '

6! \1 141

tUjUj l130

*

M\

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,

-

Jl200

255N.

i

ILL

PPM OFTPP STD scan £4?£0.51 M i n .

(-110\i.j-100

'-9Q•-80I

VX1

-70

-60

-SO,

-40:•-30ars t ,

i i ;250

' L*r, I

1 / *** 40£

k

•1C

i.flW^Wf i' f tVi'T f', f,-'! .,.,-> ^ i,'.r>-4^-r>- „300 360 400

IIIIQC/MS TUNING AND MASS CALIBRATIONDecafluorotriphenyiphosphind (DFTPP)

Instrument IDUb I0_j

DateContract No.Tim* — - / , ' „

Ddta Release Authorized By:m/c ION ABUNDANCE CRITERIA ^RELATIVE ABUNDANCE$168

GS

70127197

198

139

275

365

441

442

443

30.0 - 60,0% of mau 198ttti than 2.0% of mau 69matt 69 filativ* abundance!*ii ih*n 2.0% of nun 69

40.0 • 60.0% of mau 198law than 1.0% of mass 198

b*« oaatc, 100% nictive abundance5.0 -9,0% of mitt 19810-0 -30.0% of mats 198greaitr than 1.00% of mau 198pr want, but fttx than mail 443

growr than 40.0% of mail 198

17.0 * 23,0% of mau 442

r^7/ A/J1.^ wo p.5-)l7V- 3< ' -2/£ ( )'s^.-/< 1% 'IfD.tP6 - 9

' — " ——— "T3 — "— ~ —— "~ ——— •**" " —— ™— ——— " —— - •• —

-?'^

?-£C4"-J .i* ' f C/f-02

CM

oo

THIS PERFORMANCE TUNg APPLIES TO THE FOLLOWINGSAMPLES. BLANKS AND STANDARDS.

'Valu* in oarenthesif is % ma» 69.in otrtnthetis « maji 442.

SAMPLE 10

pcCC i-

f\ccl

LAB 10

/

fit /3i.K

FORM v:

DATE Of ANALYSIS TIME OF ANALYSIS

1057

7/85

2 2 1 9 0 0O ^ K> XT CO XT CO m XT ^ -O Q COCK

xr oo

o o o oON *-l f*i -t TH Ki t>- TH C-J O O) TH

J't f*N '•! XT <4N IJS O f\ <T) CO O O CM <N XJ XTI', t--\ I'' XT '1 XT

T-< CM US N? U"1- CD r-t ffN. CD O '1f-4 OI C4 US -H CO CN \0

--4 CO'7 -O O

O i-» COCNI

O O O O O CD O If. liN UNo:« o co — i !£••o CK fx ra UN If • O OCK 03 ON o K <?• co f\XT 1\ Os1N <N CJ XT

CN]CJ CM C-J CM f-J (N CN] CN Csi CM CM 04 CNJ CM

-O T\ 03If" L'<M C C4 CJ

N *N ^ \S\ CM if' O f\ '-0 XT CJ O -O 00

UN <NJ --5T CJ ^H

^ H * H T - l ^ - ( ' - H rHT -4 tH ^ - ! T - l ^ ^ r - t r - < T H (HT - ( T - < » H i - ( T - * < N JCN lCM

CJ C-J O f^UN <NI

ON o

cs

r\ o- r\ r\ r x

NO CJ? NC f\ c-a o XT xr •o co a co c^C-l *-» r\ f-i UN CN r-1

O O O O O O O O W - UNUN^ t (N t f NU' 'cc> o-. o o o K, »-* a- a> o UN if • if-CO 00 (?•

if i UNi>. O

o -rn c^•O ^3 NO

xi us 

U>[N,*u

mo-K5AJ

O-O

,/'-KJ

-OT-!

"~ ir^v"7.oj *-«

2 3 050 NG DFTPP STONRM £NH

2UL 25

IIIIIIIIIII

i 1 e : > C

~ e, f o c.36 . Q 53? . 0539 . 0540 . 0541 . 054 2 . 1 042 . °04 4 . 0 04 6 . 3 04 3 . 9 05 0 . 0 05 1 . 0 05 1 . 9 05 5 . 1 055 , 905 6 . 9 05 8 . 0 06 0 . 8 06 1 . 9 06 2 . 2 06 3 . 0 064 . 106 5 . 0 06 3 . 0 06 * . 0071 . 3573. 157 7 . 9 57 4 . 9 57 5 . 8 5*?6 . 957 7 . 9 57° . 0575 , 953 0 . 3 53 1 . 8532 . 95S3 . °5

)FT45 =I n t .i .401 . 9 42 . 8 97 . 7 31 . 783 . 5 13 . 4 7

1 6 . 3 31 3 . 3 14 . 7 3

1 9 . 4 41 8 . 7 96 1 . 0 7

2 . 6 63 . 4 9? . 3 66 . 183. 03. 5°. 6 2. 3 3

3 . 1 8. 5 5

1 . 1 31 . 8 6

7 5 . 0 0, 86

1 . 9 76 . 6 99 . 9 22 . 9 5

5 3 . 1 83 . 5 44 . 7 93 . 9 05 . 8 21 . 9-52 . 48

1 4 . 9 7

Scan # :m/z

8 4 . 9 58 5 . 3 58 8 . 0 59 0 . 8 59 2 . 1 5°2 . 9594 .8595. 059 5 . 8 597 , 009 3 . 0 099 . 00

1 0 1 . 0 01 0 2 , 3 01 0 7 . 8 01 0 4 . 9 01 0 5 . 3 01 0 6 . 9 01 0 7 . 9 01 0 9 . 9 01 1 0 . 8 01 1 2 . 0 01 1 5 . 9 01 1 7 . 0 01 1 9 . 9 01 2 1 . 9 01 2 3 . 1 0124 . 0 01 2 4 , 6 51 2 6 . 9 51 2 7 . 9 51 2 b . 9 51 3 1 . 0 51 3 2 . 8 51 3 4 . 9 51 4 0 . ^ 514J .851 4 2 . 3 5

2 3 CI n t .2 . 6 3

1 0 . 5 31 . 2 62, 051 . 5 2' ' . SO

.73

. 2 11 . 0 4

. 2 6? .66« i .972 . 1 41 . 1 32 . 2 81 . 8 1

. 4 61 7 . 6 4

2 . 7 933 . 1 1

4 . 9 4.95

1 .921 3 . 4 9

, .24. 8 0

2 . 0 5. 9 0. 2 4

5 0 . 3 64 . 3 5

2 3 . 2 4. 42. 1 8

1 . 193 . 471 . 2 2

. 6 8

I Re

143 .147.147.148 .148 .14° ,152 .1 5 3 .1 55 ,1 56 .1 57 .1 57 .153 .150 ,1 6 0 .1 6 0 .1 6 3 .1 65 .166 .166 .1 6 3 .170 .172 .173.1?? .175 .175 .1 78 .179 .1 8 0 .185 .186 .1 8 8 .1 9 1 .1 92 .195 .197.1 9 8 .

t n .

7505857s?951590700 00 010700 07020800 01 010900 0909010900 050907595959585^505**£8585

t imeIn t

i.3 ,

t

.

1 .,

2 .2 .,.,

1 .,.

1 .c;2 ....,

2 .,

4.2 .i .

14 .4 .,

1 .,

»k .1 0 0 .

6 .

,

2450425 23 C?4322°20352054337016?913594477412180834112363541420465901736840090

2 0 . -m/

2 0 1 .2 0 3 .2 0 3 .2 0 4 .2 0 5 .2 0 6 .2 0 9 .2 0 9 .2 1 0 .2 1 0 .2 1 0 .213 .2 1 5 .2 1 6 .2 18 .2 2 0 .222 .i •*» *, £. £ •2 2 3 .224 .227 .229 .2 3 0 .23 1 .2 3 6 .24 1 .243 .243 .244.245 .245 .245 .2 5 2 .254 .- >CC-i. s j i2 JS257.2 5 8 .

21525959595C 02050104090•3f f>

909010900 0SO9090000080109555059575052535958595'3575Off,

Int .

. 1 6

. 6 33 , 8 ?5 . 9 8

2 2 . 7 3-* . 14

. 38. 2 0. 2 1. 2 1. 6 5, 2 0. 2 9

7. 1J, 31

5 . 1 0. 6 4

1 . 6 11 3 . 4 2

3 , 2 55 , 1 41 , 4 5

. 2 0

.2 1. 5 1. 1 3. 8 3

9 . 2 0. 6 0. 6 4. 3 1

2 . 4 1. 6 8

46 . 616 . 9 0. 21

3 . 2 S. 2 1

m/264 .267 .273 .2 7 3 .274 .275 .t-, -j^•ti J .2 9 2 .295 .2 9 6 .7 1 4 .3 14 .3 1 * 4 .3 15 .5 2 1 .322 .3 2 3 .327 .3 2 7 .3 3 3 .335 .?41 .3 4 5 .3 5 1 .3 5 3 .3 6 4 .3 7 1 .3 8 3 .3 8 9 .4 0 1 .4 0 2 ,4 2 0 .4 2 2 .441 .- * * * i .442 .^4a .

b

307000so90°0C00 065c c35053565855 090°06090900000Q$25o57590807 0753595950 0°090i 1

i n t .1 . 4 5, 16

1 . 7 64 . 1 4

2 1 . 5 33 . 0 31 . 34

. 2 0.49

5 . 9 3.77. 23. 2 0

i . 17. 2 3. 2 0

2 , 5 0. 2 3.23. 24

1 . 5 8. 23.23, 44. 1 3. 2 8

2 . 5 4.9?. 2 6. 2 0.78. 52. 3 9

4. 198 , 6 1

64. 4 01 2 . 1 5

1 . 0 4

h~-,CMh-\OOO

IIIIII

II

Case No. -

GO/MS TUNING AND MASS CALIBRATIONDecafluorotrfphenylphosphine (DFTPP)

Instrument IDUsb ID «Z^L'

ContractorDate _. n/lift*

Contract No.f.'Time -—!„_

Data Release Authorized By:(ON ABUNDANCE CRITERIA KR6LATIV6 ABUNDANCE

51

€8

63

TOt27>97

198

199

275

3654-41

442443

30.0 -60.0% o* nusi 198

leu than 2.0% of miss 69

masi 69 relative abundancetest thjn 2.0^ of m«i 69

JO.O • 60.0% of ma» 198

let* thin 1.0% of ma» 198

b*w Mate, 100% relative jbundanct

S.O • 9.0% of mm 19810.0 -30-0% of m«s 190

jtenif trun 1.00% of mau 198

OftMnt, but leu than man 443

greater than 40.0% df man 198

17.0 -23.0% of man 442

5£?<^% C 3 1

7V- (^ . ' iV r^-7)15-/-?0*1idb>o7>tW- *-l-Z'f-0t>t'Zto<$ c )2

OO

THIS PERFORMANCE TUNE APPLIES TO THE FOLLOWINGSAMPLES. BLANKS AND STANDARDS. value if oarentrtem is %in parenthesis n *i

matt 69.nui* 44?

SAMPLE 10

-i

LAO IO

/7t>/

v M,H

FORM V

OAT6 Of ArgALYSIS TIME OF ANALYSIS

r/05

' * ' • '. V ' J *•-*-! • I. 1- * t . f c . f . S..1 * • • ' J ' 'fl

fW

o;

a:

tnen

0)3.

^ i- n>^ 3 A>

co \j \j

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Compound- 2 , 3 , 7 , 3 - T C D F 1 '' 2 , 3 . 7 , 9 - T C D F )• 2 . 3 . 7 . 3 - T C D F - )2 , 3 , 7 , 3 - T C D F )2 ,3 ,7 ,3 -TCDF )

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'HEXA-CDD)• HEXA-CDD)^HEXA-CDD)C HEXA-CDD )f. HEXA-CDD)f HEXA-CDD'f HEXA-CDD)(HEXA-CDD)'HEXA-CDD)t HEXA-CDD)(HEXA-CDO)(HEXA-CDO)(HEXA-CDD)(HEXA-CDD': HEXA-CDD)' .HEXA-CDD)(HEXA-COD)(HEXA-CDD)(HEXA-CDD)(HEXA-COD)(HEXA-CDO)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDO)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-COD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)

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- 3 3 3 . 93 3 1 . 97 3 1 . 9331 .93 3 1 . 93 3 1 . 93 3 1 . 93 3 1 . 93 3 1 . 93 3 1 , 93 3 1 . 92 5 7 . 02 5 7 . 02 5 7 . 0257 . 0257 . 025^ . 02 5 7 . 02 5 ^ . 0257. 03 1 9 . 33 1 * . 83 1 9 . 33 1 ° . 33 1 9 . 83 1 ° . 83 1 9 . 33 1 9 . 83 2 1 . 33 2 1 . 83 2 1 . 83 2 1 . 83 2 1 . 83 2 1 . 83 2 7 . 82 4 0 . 92 4 0 . 92 4 0 . 92 4 0 . 92 4 0 . 92 4 0 . 92 4 0 . 92 4 0 . 93 0 3 . 93 0 3 . 93 0 5 . 9

r l 3 C 1 2 - 2 , ? . 7 , 3 - T C D C na ? C 1 2 - 2 . 3 , 7 , a - T C D D )r 1 3 C 1 2 - 2 . 3 . " ? , 9 - "COD '' 1 3 C 1 2 - 2 . 3 . " ' ,3 -TCDD)' 1 3 C 1 2 - 2 , 3 , 7 . 3 - T C D D )• ' 1 3 C 1 2 - 2 . 3 . 7 . 3 - T C D D )< 1 3C 12 -2 , 3 ,7 . J3 - TCDD >' 1 ?C 12 -2 ,3 ,7 , S -TCDD )( 1 3 C 1 2 - 2 . 3 . 7 . 8 - T C D D )' . i 3 C 1 2 - 2 . 3 , 7 l 3 - T C D D ; '' 1 3 C 1 2 - 2 , 3 , 7 . ' 3 - T C D D )

( 2 , 3 . 7 , 8 - T C D Q )( 2 , 3 , 7 , 3 - T C D D j( 2 , 3 , 7 , 8 - T C D D )f 2 , 3 , 7 , 8 - T C O D )f. 2 , 3 , 7 . 8 - TCOD )( 2 ' , 3 ,7 ,8 -TCDC >( 2 . 3 , 7 , 3 - T C D D )( 2 . 3 , 7 . 8 - T C D D 'C 2 , 3 , 7 . 3 - T C O C )(2 .3 ,7 .3 -TCDC"( 2 , 3 , 7 , 3 - T C D O i( 2 , 3 , 7 ,3 -TCDD)( 2 , 3 ,7 ' , 3 -TCDD )C2 , 3 ,7 ,8 -TCDD )( 2 , 3 , ? , 8 - T C D D )f 2 ,3 , 7 ,8 - TCDD >( 2 , 3 .7 ,8 -TCDD )( 2 , 3 , 7 , 8 - T C D D )(2 , 3 , 7 . 3- TCDD)( 2 , 3 , 7 , 8 - T C D D )C 2 , 3 ,7 ,8-TCOD)( 2 ,3 ,7 ,8 -TCDD )( 2 , 3 ,7 ,8 -TCDD )

( 37CL4- 2 , 3 , 7 , 8 - TCOO )( 2 , 3 , 7 , 8 - T C D F )( 2 ,3 ,7,8-TCDF)<2 ? 3,7 ,8-TCDF , i( 2 ^ 3 , 7 , 3 - T C D F )( 2 , 3 ,7 ,8-TCDF)(2 ,3 ,7 ,8 -TCDF )(2 ,3 ,7,8-TCOF)^ 2 , 3 , 7 , 3 - T C D F )^ 2 , 3 , 7 ^ 8 - T C O F )( 2 ,3 t? ,8-TCOF)(2 ,3 ,7,8-TCDF)

2 9 .£. ••' .•TO

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1 0 5 oi 3 9 2

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:o00000 3,0o;0.3000 00 00000• 1 0O. i: o0 000o :C OOt<. 0o :0 0o;30Q C0000G O000 000000000000000000 0000000000000

I ' iG-NONONONONO• .0NOMOhONONOMONO• i ONONONONONO; 10NCi iONONO(JOMONONONONONONONONONOMONONONONONONONONONO

-ULCAL ISCAL ISCAL ISC AL 1 8CHL I 3CHL i BCALIBCAL I 3CAL IE:,nLltCALIBCAL i 5CfcL lBCAL 1 3CALIBCALIBCAL IECAL 1 3CHL IBCHL 13CALIB_"AL I BCAL I BCAL IBCAL I BCALI3CALIBCALIBCALIBCALIBCAL IBCALIBCALIBCALIBCAL 1 8CAL 13CALIBCALIBCALIBCALIBCALIBCALIBCALIBCALIB

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IIIIIIIII

IIII

Compound urea i-onc Un i • 2,9 )9 )9 )

1 0 )1 0 )1 0 )12 )12 )12 )12 )12 )12 )12 )1 2 )1 2 )12 )12 )1 2 )12 )12)12 )12 )1 2 )1 2 )13 )13 )

3053053 0 53 153 1531532632o32e32632632632632s32632632632632632632632632632o339389

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.8. 8. 3. 3. 8. 3. 8. 8. 3. 8p. 3. 3. 8. 3. 8. 8

( 2 , 3 . 7 , 8 - T C D F )' 2 , 3 ,7 .8 -TCDF )( 2 , 3 . 7 , 3 - T C D F )( 1 3 C 1 2 - 2 . 3 , 7 , 3 - T C D F >( 1 3 C 1 2 - 2 ; 3 , 7 , 3 = TCDF •U3C 12 -2 , 3 ,7 , 3 -TCDF )( HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD>< HEXA-CDD)(HEXA-CDD)(HEXA-CDO)( HEXA-CDD .'(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)' .HEXA-COD;t HEXA-CDD)' HEXA-CDD>(HEXA-CDD)

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1 17912 131276123*130713 121352136613751390139-140-51426142^1443146-315221532l *3-b1 503

31363096

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MOMOMOMO' iONOf iOMOfidNONOMQNONONONOnoMQNOMOMQHO-0NO•oNO

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HS d a t a f i l e header f r om : - >SXl48Samp l e : D I O X J N STD CC2-A Op e r a t o r : TONY MSMi s c : 2UL CC2-&Sys. ft: 1 MS mode l : 96 SW/HUI rev . : Cft ALS ft : 0

Method f i l e : D I O X I N Tun ing r i l e : r "T9501 N s . o f e x t r a - e c a r d s :Source t e m p . : 200 Analyzer t em p . : 250 Tran s f e r l i n e t em p . :

Chroma t o g r a p h i c t empe r a t u r e s : 70.Chromatographic t imes , m in . : 4.0Chroma tog raph i c r a t e , d e g/m i nJ 2 5 . 0

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QUANT REPORTOp e r a t e - ID : TONYDa t a F i l e : > S X i 4 3 : : H 6Name: O I O X I N STO CC2-AMi s c : 2'J.. CC2-AID F i l e : PCDDT i t l e : CQD/PCDF ID FILELas t C a l i b r a r i a n *

Compound

Quan t T :mei n j e c t e d a t

Oi l u t i o n F^c tor3 5 1 1 1 ? 1 6 : 1 1c5 1U3 i * : ?3

I . 0 0

nrea '- o n c

1 )2)2)2 )3 )3 )5 >3 )3 )3-)3 )4 )4)4 34)4)5 )5 )5 )5 )5 )5 )5 )7)7)7)7)7)7)7)7)8 )8 )8 )8)8)9)9 )9 )9 )

10 )1 0 )10 )10 )1 0 )10 )

* 3 3 3 .33 1 .3 3 L .331 .2 5 7 .25" .257 .2 5 7 .2 5 7 .257 .257 .7 1 9 .3 1 9 .3 1 - .3 1 ? .3 1 9 .3 2 1 .3 2 1 .3 2 1 .3 2 1 .3 2 1 .3 2 1 .3 2 1 .2 4 0 .2 4 0 .2 4 0 .240 .240 .2 4 0 .2 4 0 .2 4 0 .303 .3 0 3 .3 0 3 .3 0 3 .303 ,3 0 5 .3 0 5 .3 0 5 .305 .3 1 5 ,3 1 5 .3 15 ,3 1 5 .3 15 .3 15 ,

9999000000033**•ag398B333899999999999999999999999

U 3 C 1 2 - 2 . 3 , 7 , 8 - T C D D >( 1 3C 12 -2 , ? '7 ,3 -TCDD >' ' 1 3C 12 -2 , 3 , 7 , 8 - T C D O )U ? C 1 2 - 2 , ? , 7 , 3 - T C D O )( 2 , 3 , 7 , 8 - T C D D )f 2 ,3 ,7 ,3-TCDD )(2 . 3 , 7 , S - T C D D )( 2 , 3 , 7 , 8 - T C D D )( 2 , 3 , 7 , 8 - T C D D )C 2 , 3 .7 , S -TCDO . >( 2 . 3 . 7 , 3 - T C D D )( 2 . 5 , 7 , 8 - T C D D )i 2 . 7 , 7 , 8 - T C D D )(2 . 3 ,7 ,3 -TCDD )' '2 ,3 , 7. 3- TCCD)C 2 . 3 , 7 , 8 - T C D D )( 2 , 3 , 7 , 8 - T C D O )( 2 , 3 , 7 , 8 - T C D D )( 2 , 7 ,7 ,8 -TCDD?f 2 , 3 , 7 , 8 - T C D D )

2 , 3 ,7 ,3 -TCDD )t 2 , 3 ,7 ,3 -TCDO)(2 . 3 , 7 , 8 - T C D D )( 2 , 3 ,7 ,8 -TCDF )( 2 . 3 , 7 , 8 - T C D F )f 2 , 3 , 7 , 3 ~ T C D F >( 2 , ? , 7 , 8 - T C D F )( 2 , 3 , 7 , 8 - T C D F )( 2 , 3 , 7 , 8 - T C D F )( 2 , 3 , 7 , 8 - T C D F )<2 , 3 , 7 , 8 - T C D F )(2 ,3 ,7 ,8-TCDF)( 2 , 3 . 7 , 8 - T C D F )(2 ,3 ,7 ,8 -T tDF )( 2 , 3 , 7 , 8 - T C D F )(2 ,3 ,7 ,8-TCDF)( 2 , 3 , 7 , 8 - T C D F )( 2 , 3 ,7 ,8 - TCDF )( 2 , 3 , 7 , 8 - T C D F )(2 ,3 ,7 ,8-TCDF )( 1 3C 12 ~2 , 3 ,7 ,8 -TCDF )< 1 3C 12 -2 , 3 ,7 ,8 - TCDF )C U C 1 2 ~ 2 , 3 , 7 , 8 - T C D F >U3C 12 -2 ,3 ,7 ,3 -TCDF )( 1 3C l2 -2 ) 3 ,7 > a - TCDF )C 1 3 C 1 2 - 2 , 3 , 7 , 3 - T C D F )

2929311 126232930303272i d28282932232829292^32322728232929303031282829313127282831282829303031

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NG/iJLMONONOMONOM3HOnoNONONONOMGr iONCnoNO• - »oNONONOMONONONONOHOMONONQNONONONONONONONOHONONOHOHONOHO

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IIIIII

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Compound R. T. Scan# Area Cone Un i t s11 '1 1 )1 1 )1 2 )12 )12 )1 2 )12 )12)12 )12 )12 )12)12 )12 )12 • >12 )12 )12 )12 )12 )12 )12 )12 )12 )13 )13 )13 )14 )14 -14 )

3 17 .3 1 ™ .3 1 ^ .3 2 6 .3 2 6 .3 2 6 .326 .3 2 6 .32* = .3 2 6 .326 .3 2 6 .326 .326 .326 .32 - = .326 .3 2 6 .3 2 6 .3 2 6 .326 .3 2 6 .326 .3 2 6 .7 2 6 .3 2 6 .389 .3 8 9 .3 8 9 .3 9 1 .3 9 1 .3 9 1 .

999'3B8a88838338q3388838S33338338

C 1 3 C 1 2 - 2 , 3 , 7 , 8 - T C D F )< 1 3 C i 2 - 2 , ? , 7 , 8 - T C O F )U 3 C 1 2 ~ 2 , ? , 7 , 3 - T C D F ;

'HEXA-CDD)'HEXA-CDO;CHEXA-CDD)(HEXA-COO)(HEX A- COO)'HEXA-CDD'CHEXA-CDD)CHEXA-CDP)(HEXA-CDO)CHEXA-CDD >fHEXA-CDD)CHEXA-CDD J' 'NEXA-CDD 1

(HEXA-CDD;CHEXA-CDD tCHEXA-CDD )^HEXA-COD)rH£XA~CDD)CHEXA-CDO J'. HEXA-CDD)'H£XA-CDD<(HEXA-CDD)CHEXA-CDD)fHEXA-CDD)CHEXA-CDD .'CHEXA-CDD)'HEXA-CDD)'HEXA-CDD)

2 8 .28 .3 0 .32 .32 .3 3 .33 .3 3 .33 .34 .34.34 .34 .35 .35 .3 6 .76 .3 6 .J6.5 6 .36 .36 .36 .37 .37.3 3 .3 5 .36 .37 .35 .?5 .37 .

668925637044535467125178313?54061224?942"?!3035127101*•

3110313038

795823992

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NONONONONONONONONONONONONONOHONOr,nNOMONOMONONONONONONONONONONOMC

CMLI3CALIBCALIBCMLISCALI3CALIBCnLlSCAL isCALIBCALIBCAL 16CAL. IBCALiB r^CAL IB "IrtL I 9 ^CALIB I"*C-L 1 3 vO

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MS da t a * i l e header f r omSamo l e : D IOX IN 3TD CC2-A Op e r a t o r : TONY MS IT: 23Sys . it; i HS mode l : 96 3U/HU re^», : CA nLS * : 0

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Chromatograph i c t empe r a t u r e s : 70.Chroma tog raph ic t imes , m i r > . : 4.0Chroma t o d r s p h i c r a t e , deg/min : 2 5 . 0

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r, ^s ir> r\ ftr- u is. o o o o o o o o o o o o o o o o o or-s NT NT xr srCM IN <s <N NT o

O*• e mnj -,- o f

IIIIIIII

I

Compound R. Scam* urea!Jo i r 3

9 '3 )0 t9 )•3 >

10 -1 0 )1 0 )1 0 )10 •1 0 )10 )1 1 )1 1 )12 •1 2 )12 '1 2 )12 >12)1 2 )1 2 )12. '12 )12 )12 )12 )12 .112 )12 )12 )12 )12 )12 )12 >12 )12 )12)12 )1 2 )13)13 )13 )14 )14 )

3 0 7 . 93 "• 7 . 93 0 = . 93 0 * . 9705 . 93 0 ? . 93 1 ? . 931? . 93 1 ^ . 971« . o31? . 93 lc . Q3 1 ^ . 97 1 ~* . 93 1 7 . 93 2 * . 37 2 6 . 83 2 6 . 97 2 ^ . 37 2 6 . 83 2 6 . 35 2 6 . 8? 2 d . 93 2 6 . 93 2 6 . 33 2 6 . 932-- . 372 o . 93 2 6 . 87 2 6 . 83 2 6 . 8326 .33 2 6 , 37 2 6 . 83 2 6 . 83 2 6 . 95 2 6 . 33 2 6 . 8326 .83 2 6 . 83 2 6 . 8399 ,83 8 9 . 83 8 9 . 83 9 1 . 93 9 1 . 8

( 2 , 3 , 7 , 8 - T C D F )C 2 , 3 , ? , 3 - T C D F )'2 V7'8-TCDF)'2, ' ^7, '8-TCOF)U3C 12 -2 . 3 .7 ,8 -TCDF )' i3C12-2 J 3,7 ,8-TCDF)' 1 3 C 1 2 - 2 , 3 . 7 , 8 - T C D F )• 1 3C 12 -2 , 3 . 7 , 3 - T C D F )( 13C12-2 .3 .-%3-TCDF:-f l 3 C 1 2 - 2 , 3 , 7 . 3 - T C D F )C i 3 C 1 2 - 2 , ? . 7 , 3 - T C D F i

' 1 5 C i 2 - 2 , 3 . T ' , 3 - T C D F f HEXA-CDD)C HEXA- CDD >'HEXA-CDD^C HEXA-CDD '(HEXA-CDD)(HEXA-CDD t(HEXA-CDD)(HEXA-CDD 'f HEXA-CDD)(HEXA-CDD)f HEXA-CDD)• HEXA-CDD)'hEXA-CDD)(NEVA- COD)'HEXA-CDD)CHEXA-CDO)(HEXA-CDD)CHEXA-CDD^(HEXA-CQD)C HEXA-CDD)C HEX A- CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)C HEXA-CDD)(HEXA-CDD)(HEXA-CDD)

283127282930?1262627,23 .2 8 ,28 .71 .-1Q6* -J •

2 8 .7 2 .3 2 .3 3 .33 .3 3 .37 .3 7 .3 7 .33 .37 .34 .3* » .7 4 .34.34 .34 .35.3* .36.3o .36 .36 .36 .37 .37.37 .35 .35 .3 6 .35.37 .

. 3 1

. 16, 02.57. 9 1, 0 ?. 16. 0 3. ~*4. 2 6, 2 3,57. 9 0, 0 0, K°*, 3 0. 349116ff -r* »750e?— ~?Q?94i -j22on' A-?5C8?132104091443790244641224992329

3 1 11 103

5<537813 1 1967

1 10746?5550 19~467313 1 0

1 0 8 3-313 1 017 : i

1 72013501371133^17931 ^ 161-4331445144714751^*82* *£ ~X. '1 T T i*

154215431562159?1605170717 1417201756130013291881190615931 6 0 8182516071862

1 3777265

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1743779

20976907633759

1 4036109774

17393~977

1 0 675

22"*102

36'"* 1

°23 1* 1333q1"!;oe

30?3

1 0 C ?15?24339

79"773j.76

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5719592

4116368

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7?? .1 4 0 3 6 .

10 * .7-M.

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1 0 6 .7* .

227 .10 : .?6 .3i .-2 .3 1 .0! .;- ^'3? .

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0 0,'! 0o : -0 00 00 0003 0000 00 00 00 00 000t ' Jo;; Q0 0JO00?00 ;0 0000 000000 030G O0 00000

MONONONONOHOrONQNONCNONO: iONQNOMOiO

NCt-.QNOJ--0rjQNONONONONONONQNCNONONONONONONONOHONOflONONONCNONOno

CAL ISCALIB;:AL 1 3CALIB

CHL. IBCAL IBC^LI3CNL IEC«L ; BCALIBCAL I ECAL I B: : *LISCH._ I BCr-L 'SCnL I Br^L I ej-f i hv 4 _rCAL I Bi_jf-(L i BCAL 1 8CAL ISCAL IBCnL i 3CA>_ IBCnLiSCALIBCAL 1 3CALIBCMLI3CALIBCAL i 5CML IBCHU 1 8CALIBCAL reCALIBCAL reCAL ISCAL 1 8CHLIBCAL ; aCALIBCAL reCALIBCALIB

K^inr-vOOO,-

* Compound is ISTD

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f 1S d a t a - i l e header f r o m :Samo l e : DI OX IN STD CC2-Mr i i sc : 2UL CC2-A*"*£* ^e:M^i: L^r^r.;^ ALr :

f °S-urc. , e m p . : 200 An.l,,.,9,.^; "J^01 ^n.'J.rl^/^f'IChroma t o g r a p h i c t emp e r a t u r e s : 70Chroma tog raph i c t im e s , mm. : 4 QChroma t o g r a p h i c r a t e , d e a/m i n : 2 ? ' 0

1 9 0 . 2 3 0 .1 0 . 0 2 0 . 0

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IIIIIIIII

QUANT REPORT

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Ooe r a t e - ID: TONY

: :N6Name; C I O X I M STD CC2-AM i 3 c : C j .L 002-AID F I I - : PCDDTit le : "DD'-PCO^ ID FILELa * t Ca . ; & r s t i 3n :

Compound

In i ac ted at0 i lu fc ion Fgc tor

85 1 1 1 ?• 3 5 1 1 1 3

1 7 : 1 21 . 0 0

P. T. can 4 '- o n c1 '2 )2 )2 12 ^7 >? )3 )3 )3 >? )4)4 )4 'i*i 15 )5 >5 )6 )6 )6 '7)7)? >7)717 )7)7 )8 )8 )8 )8 )8 )9 )9 )9 )9 )

1 0 )10 )10 )1 0 )10 )1 1 )1 1 )12 )

* 3 r- 5 . «331 . 935: . *3 3 . . 93 3 1 . 9•"> C ~" A

^T . u25" . 0257 . 025-? . 025" . 025" . 07 1 1 ' . ?3 1 * . 331 * . 33 1 - . 33 2 ; . e721.33 2 1 . 33 2 ^ . 832" . 932 ~ > . 32 4 0 . 92 4 0 . 92 4 0 . 92 4 0 . 92 4 0 . 92 4 C . 92 4 0 . 92 4 0 . 93 0 3 . 93 0 3 . 93 0 3 . 93 0 3 . 93 0 3 . 93 0 5 . 93 0 5 . 93 0 5 , 93 0 5 . 93 1 5 . 93 1 5 . 93 1 5 . 93 1 5 . 93 1 5 . 93 17 .9 <3 1 7 . 9 (3 2 6 . 3

1 1 3 C 1 2 - 2 , 3 , 7 t 3 - T C D D >U 3 C 1 2 - 2 , 3 , 7 , 3 - T C D D )1 1 3 C 1 2 - 2 . 7 . 7 . 3 - T C D O J< 1 3 0 1 2 - 2 , 3 . 7 , 9 - 1 0 0 0 )' 1 3 0 1 2 - 2 , 3 , 7 . 9 - T C D O .( 2 , 3 , 7 . 8 ~ T C D D >

• - 2 . 3 , 7 , 3 - T C C ' D )' 2 , 3 . 7 , 3 - T C D D >f 2 , 3 , 7 , 3 - T C D D >f 2 , 3 , 7 . 9 - T C D D )< 2 , 3 , 7 . 8 - T C D D -r 2 , 3 f 7 , 3 - T C D D )< 2 . 3 , 7 . 3 - T C O D )< 2 , ? . 7 , 3 - T C D D r< 2 , 3 , 7 t 8 - T C D O >< 2 , 3 , 7 , 8 - T C D D . >< 2 , 3 , 7 , 3 - T C D O ;' 2 , 7 , 7 , 8 - T C D Q )

f ^7f"i 4- ? ? ~> ft rrrr-i - ' -»^*» ^ . . , •• , 0 - 1 UL/L' ,'r 3 7 C L 4 - 2 . 3 . 7 . 3 - T C D D i07CL4 -2 ( 3 ,7 ,8 -TCDD i

f 2 , 3 , 7 . 8 - T C D F )5 2 , 3 , 7 , 9 - T C D F : .^ 2 , 3 , 7 . 8 - T C D F )f 2 , 3 , 7 . 8 - T C D F )f '"* ^C ~? O "f i"* r1* P= •*. j. , j , / , g- TLDF .'f 2 , 3 ,7 ,8 "TCDF - .f 2 , 3 , 7 . 8 - T C O F )( 2 , 3 , 7 , 8-TCDF)C 2 . 3 , 7 , 8 - T C D F i' " 2 , 3 , 7 , 9 - T C O F lf 2 , 3 , 7 , 8 - T C O F )( 2 , 3 , 7 , 8 - T C D F )(2 ,3 ,7 ^ -TCOF )^2 , 3 ,7 ,8 -TCOF )( 2 , 3 ,7 ,8 -TCDF )C 2 , 3 , 7 , 8 - T C D F )C 2 , 3 , 7 , 8 - T C D F )C 1 3 C 1 2 - 2 , 3 , 7 , 8 - T C D F >C 1 3 C 1 2 ^ 2 , 3 I 7 , 9 - T C O F )C 1 3 C 1 2 - 2 , 3 J 7 , 8 - T C O F )C 13C 12 ' 2 , 3 ,7 ,8 «TCDF )a3C 12 -2 ,3 .7 ,8 -TCOF i13C 12 -2 ,3 ,7 ,3 -TCDF )1 3C 12 -2 ,3 ,7 ,8 -TCDF )CHEXA-CDD)

2 9 . 2 62 8 . 4 92 9 _ ••> -72 9 . 5 53 1 . 5 " ?2 6 . 3 526 . 34°/s '3"?*.O i J* *>~* CO^^ . ?82 9 , 2 83 0 . ^ 62 3 . 6 573 -J 2— O * • ,1 J2 ^ . 2 8'? Q O x.A ™ . 7 *|2 3 , 8 72 9 . 2 33 2 . 0 423. 052 - 5 . 2 83 0 . 2 21-9 Q •*- .- . r i" *3 39• - t# * J '

2 9 . 2 23 0 . ^ 13 1 . 1 1T? 1 ITJ* 1 . 1 J

3 1 , 2 33 1 . 2 52 8 . 6 62 9 . 3 92 9 . 9 13 0 . 1 03 1 , 2 40*3 "3 jt&S . 742 8 . 6 52 9 , 3 93 1 . 2 42 8 . 6 42 8 . 8 730. 123 0 . 2 431 . 062 8 . 6 42 8 . 3 73 2 , 8 8

3 0 071 130 1333

I06e-465-2 151A7Ô*069023 72""*,«* o^29

"?O3 0 2'— f.^.- •OO755302i* V A

1 12006 03029 1064-*757795'967

1 0 1 31 02210261029

730757875396

1028625729757

1028723755899912

1007728755

1217

^75- i o . 3 0 NG,,,L90 9 0 . 0 0 NO CALIB'~-*'5 i j . 2 - t ° l . j O hO ' -HLI330 so . oo NO CML IB

"3 "3. ; 0 NO - .AL I ai67 16". OC NO CH^ . 19

36 ;6. C. j * iQ ;^LI39? 9 5 . Q ; j NO CAuIBô -3Q. oo r i o C.-*L; =

5315 5 3 1 - . O C NO CAÎB3- 52. )o NO C- *L : =^31 4 8 : . 00 MO CALIB3 0 2 0 - 3 0 2 0 . ; o • ,0 CM: . : *

1 1 556 1 155- . , 00 MO CAL I3-4 34. ;o - 1C :î_;s

1 6Q " * 1 6 0 7 . 0 0 NO Cwi _ IB:4 i c : u i o2 . o o r * o C^L IS142 K J . O : NO CALIB30 ' J Q . 00 MC "ML '3

3-65 776 - . O C NL CAÎB?^ --* . jo NO CKL :S?4 9 ^ . 0 0 UC CALIB

3a82 . " 6 8 2 . 0 0 r -0 C^LIS630 6 8 0 . 0 0 NO CALIB32 - ? 2 . ;0 HO CMLI3^3 63. Oj NO CALIB5 0 90 . 00 NQ CALIB

195 1 9 5 . 00 NO CAL IS-67 2 6 7 . 0 0 NO CAL I3205 2 0 5 . 0 0 HO CALI8

14333 i - . 3 3 3 . D O NO C.-nLlB^4 9 - i . O O NO CALIB

1 14 1 1 4 . 0 0 NO CfrLIS127 127. OC NO CALIS32 3 2 . 0 0 NO CALIB

^ 12 4 1 2 . 0 0 NO CALIB1 83 1 1 1 8 3 1 1 . 0 0 NO CALIS

329 3 2 9 . 0 0 NO CALIS799 7 9 9 . 0 0 NO CALIB

1 ^283 1 4 2 8 8 . 0 0 NO CALIB36 3 6 . 0 0 NO CALIB9? 9 3 , 0 0 MO CALIB33 8 3 . 0 0 NO CAL IB

1055 1 0 5 5 . 0 0 HO CALIB17909 1 7 9 0 9 . 0 0 MO CAL18

105 1 0 5 . 0 0 HO CALIB

r-ir.r-vOOO

IIIIIIIII

I

Compound R . T , Scan* L.onc un i12 )12)12)1 2 )1 2 )12)12)12 )1 2 )12 )12)1 2 )12 )12 )12 )1 2 )12 )12 )12 >12 )12 . '1 2 312 )12 *12 -1 2 )12'-12 >1 3 )13 )14 ^1 4 '}

3 2 6 . 33 2 6 . 83 2 6 . 83 2 6 . 33 2 6 . 332o . 33 2 6 . 83 2 6 . 33 2 6 . 3326 . e3 2 6 . 83 2 6 . 83 2 6 . 33 2 6 . 83 2 6 . 332 * . 932s . 83 2 ^ . 33 2 6 . 33 2 6 . 33 2 6 , 33 2 6 . 3?2c . 33 2 2 . ?3 2 6 . 832o .S3 2 6 . 33 2 6 . 93 8 9 . 333 ^ .33 9 1 . 33 9 1 . 3

C HEXA-CDO)(HEXA-COD)fHEXA-CDD)'HEXA-CDD)<HEXA-CDD: >(HEXA-CDO)fHEXA-CDD)(HEXA-CDD)(HEXA-CDD)fHEXA-CDD)(HEXA-CDD)CHEXA-COO)fHEXA-CDD)fHEXA-CDD)f HEXA-CDO)fHEXA-CDD)•- HEXA-COD)(HEXA-CDD)• . HEXA-CDD)fH£XA-COD)HEXA-CDD)

rH£XA-CDD)•HEXA-CDD)t'HEXA-CDD)fHEXA-CDD?f HEXA-CDO)fHEXA-CDD)(H£XA-CDD)(HEXA-CDO)rHEXA-CDD)fHEXA-CDD)*HEXA-CDD)

33 .33 .33 .34 .34 .34 .34.34 .34 .35 .35 .35 .35 .36 .36.3e> .36 .36 .36 .36 .37 .37.37.37 .37 .37,38.33 .35 .37 .35 .37 .

1222?112^1538291951430566508; 725436330940434•4373"69913262°Q72934

12441256123913591393140714401450145514771495152515361585159116051626Io4316631684169s>173017^11775.77913051327133614 ^4169 314941730

0535

77~>8?34817434

12990

162 110 1

32244L 7 Q3 0

-2 18211ill134

^6-53•* 431' >3

1036-62

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531

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?77.8 5 .3 4 .31 ,34.3* i .:28 .9 . J .

i »21 .10 , .

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Compound is iSTD

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t o g r a p h i c t emp e r a t u r e s : 70.Chroma t o g r a p h i c t im e s , mm- : 4 .0Chroma t o g r a p h i c r a t e , d e g ^ m t n : 2 ? . 0

1 9 0 .10. 03 . 0

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o o o o o o o o o o o o c-' o o o a:1 Cl to

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co co <?• i\ co r\ o f^ c-j INc. o K. co <?• if1- -o &» oo o rs oooa? a- o — i • o. fx o — < •-•) -o oo <7? »? rvCNI r i <••* c -i c i c -i c -i c a c J IN <N

O O O O OO Q Q Q QO O U '_( Ut- »- »-- I- KI 1 I I I •-•rrj 1.0 Q O O O O U O U O O O Q O O Ci O Q O 00 CO 03 CPr\ Q O Q O Q O D a O Q Q O O Q Q Q Q O O

O O Q Q Q OO O Q O Q OU U U U U UI i i I tW l j - l ^ i j L ! j . k . k . iU _ l i _ i j _ LL tLULh- l j _J jLO Q O O Q O O Q O O O O Q n O Q

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i i ! I ) t I I 1 i '1 1 t ) 1 J 1 ) 1 1C-l (M <N r-i (^O* OJ (N—j -^ <—)U U U U O

r-, r . r\ r r\ r- r\ r- r , r\ r\ r\ «N CJ C-l CM' CO C O C O O D C O G O C O C 0 0 3 G O C O C O C O C O C O C O

t i r\ rs r-. rs is r\ i\ rv i\ rs r\ r\ r\ r\ r\ f\K. K _j -J -Ju u u u u

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f J O I\ fS <M CM (N CM O)

CC1 in? CO CO CO CP OP (?• CN O- C?1-4 . < . < r-4 r\ K r i r r\ T\ is r\ a o-

If* tf> If-IK\ c-i c j r-j CML Ip i) tj It —• *JO HJ W •" O •" *0O O Z r *- »- _ !

rs. is r\ ss r\ fs is ir\ fS is co co oo 03 02

IIIIIIIIIIIIIIIII

Comoound . T. Scam* LOrtC •Jn i t 59 )9. i9)* ; <9 >

1 0 )10 .1 0 *10 )1 0 )1 1 )11 '•1 2 )12 )12 -12 )12 t12 )12 >12 )12 -12 )12 >12)12 )12 )12)12 )12 )12)1 2 )12 )12)12 )12 )12)12)12 )13 )13 )1 3 )14 )

- » < • * • — • -•*3 «j •? . 93 G 5 . 93 G 5 . Q

3 G f . 9? : = .971r . *3 1 5 . 93 1 5 . 93 1 5 . 93 1 5 . 93 1T .93 1 ^ . 932-; . 332^ .33 2 6 . 3726 .33 2 6 . 332 ^ . 33 2 6 . 87 2 * . 33 2 6 . 33 2 6 . 851": .33 2 ^ . 83 2 6 . 33 2 ^ . 33 2 6 . 83 2 6 . S3 2 6 . 33 2 6 . 37 2 6 . 3326 . 33 2 6 . 33 2 6 . 83 2 6 . 33 2 6 . 33 2 6 , 83 2 6 . 8389 . 33 8 9 . 83 3 9 . 33 9 1 . 8

( 2 , 3 , 7 . 3 - T C O F ;(2 ,3 , ^ , 3 -TCDF )• '2 ,3 ,7 ,9-TCDF)' 2 , 3 , 7 . 3 - T C D F )f 2 , ? ,? , 3-TCDF:<a3Ci2- * ,3 ,7 ,3-TCDFJf l 3 C 1 2 ~ 2 , 3 , 7 , 3 - T C D F 'r l 3C 12 -2 ,3 .7 ,3 -TCDF )' 1 3C 12 -2 . 3 ,7 1 3 -TCOF >' 1 3 C 1 2 - 2 . 7 , 7 , 3 - T C D F

• l ?C 12 -2 .3 ,7 . a -TCOF >a?C12-2 ,3 ,7 ,8-TCDF j{- H£XA-CDD^

(H£XA-CDO ••HEXA-CDD'• HEXA-CDD)' HEXA-CDD >< HEXA-CDO)<HEXA-tOD>'HEXA-CDD)'HEXA-CQDJf .HEXA-CDD)< HEXA-CDO)rHEXA-CDCO( HEXA-CDD)f HEXA-CDD JfHEXrt-CDD '( HEXA-CDO)(HEXA-CDO •(HEXA-CDO)•'HEXA-CDD,''HEXA-COD)(HEXA-CDO)^HEXA-CDO)fHEXA-CDD)(HEX A -COD)(HEXA-CDD'fHEXA-CDO)•HEXA-COO)(HEXA-CDD)f HEXA-CDO)CHEXA-COD)

26 .23 .23 .23 .7 1 .2e> .26 .23 .28.T *

29 .23 .3 3 .3 7 .73 .3 3 .3 3 .3^4 .34 .3 4 .34 .34 .34 .74 .3 4 .3* * .35 .35 ,75 .36.36 .36 .36 .36 .37 .37.37.37 ,35 .35 ,37 .35 .

406170352 '3443061340361340 3648993031015293139677499.J-U2e3624303765310531436105260324

-»??728"38755

102647851 *72 S754

1 0 0 6?27754

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1438933

77917753

12 1573

1 7<i 1 93 1

5 *3106

53; ?3121

351 19i'~i4- 14.0535

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1- iO1722

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106-3-*3 "^7Q51

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( 1 3 C 1 2 - 2 , 3 . 7 , 8 - T C D F )( 1 3C 12 ~2 , 3 ,7 ,8 -TCDF )( 1 3C 12 -2 ,3 ,7 ,Q -TCDF )

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(2 .3 ,7 ,8-TCOD)C2. . " , 7 ,8 -TCDD -• 2 . 3 . 7 . 8 - T C D D ?' 2 ' . 7 f 7 , 3 - T C D D )(2 , 3 , 7 . 3 - T C D D >(2 . 7 . 7,8-TCDD)' 2 , 3 . 7 . 3 - . T C D D >( 2 , 3 , 7 ,8 -TCDD , 'f 2 , 3 . 7 . 8-TCOD)r 2 . 3 . ? , 8 - T C O D >(2 ,3 .7 .8-TCDD. i

' 77CL4-2 . ? , 7 . 9 - T C D D i( 3 7 C L 4 - 2 . 3 , 7 . 8 - T C D D '• *37CL«-r ,7 ,7,3-TCDDi' 37CL^ -2 t 3 , 7 , 3 - T C D D <(77CL4-2 ,3 ,7 ,8 =TCDD>(2 , ? . 7 , g ~ T C D F >< 2 . 3 , 7 , 8 - T C D F >

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Use r name : TON'.'Run Type: S I M , GC. E l

Sp e c t r om e t e r ?'1ode 1 tf 5996Data P i l e : 3X1oS

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( 1 3C 12 -2 . 3 .7 .8 - TCOD >( 1 3 C 1 2 - 2 , 3 ( 7 t 8 - T C D D J( 1 3 0 1 2 - 2 , 3 , 7 . a -TCDO:-1 1 3 C 1 2 - 2 , 3 . 7 , 3~TCDD- !

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t 2 .7 ,7 .8 -TCO&)(2 .3 ,7 ,8 -TCOD '< 2. 3, 7. 8- TCDO'( 2 , 3 , 7 , 8 - T C D D )<2 ,? , 7 ,8 - TCDO J( 2 , 3 , 7 , 8 - T C D O )< 2 , 3 , 7 , 8 ~ T C D D >(2 ,3 ,7 ,8-TCDD:(2 , 3 ,7 ,8 -TCDD >( 2 , 3 , 7 . 3 - T C D D >( 2 ,3 ,7 ,8 -TCDD)(2 , 3 , 7 , 3-TCDD)( 2 . ? ' , 7 > S -TCDD3( 2 , 3 , 7 , 8 - T C D D )( 2 , 3 . 7 ,8~TCDQ)(5 ,3 ,7 ,8-TCDD)( 2 ,3 ,7 ,8 -TCDD )( 2 , 3 ,7 ,8 -TCDD )( 2 , 3 , 7 , 8 - T C D D )(2 ,3 ,7 ,8-TO>D >( 2 . 3 ,7 ,8 -TCDD )(2 ,3 ,7 ,8 -TCDD )( 2 , 3 ,7 ,8 -TCDD l( 2 , 3 ,7 ,8 -TCDD )(2 ,3 ,7 ,8-TCDD)(2 ,3 ,7,8-TCDD)( 2 , 3 , 7 , 8 - T C D D )( 2 , 3 , 7 , 8 - T C D D )(2 ,3 ,7 ,8-TCDD)(2 ,3 ,7,8-TCOD)

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< 1 3 C 1 2 ~ 2 , 3 , 7 , 3 - T C D F . 'U3C12-2 ,3 ,7 ,8-TCDF >f ! 3 C 1 2 - 2 , 3 , 7 , 3-TCDF 1 'a ?C 12 -2 , 3 ,7 ,9 -TCDF )• ' 1 30 12 -2 ,3 ,7 , 8~7CQF'>' 1 3 C 1 2 - 2 . 3 . 7 . 8 - T C D F )a 3 C 1 2 - 2 , 3 , 7 , 3 ~ T C D F )( 13C l2-2 ,3 ,7 ,8-TCDF)' 1 3 C i 2 - 2 . 3 , 7 , 3 - T C D F " 'U 3 C 1 2 - 2 , 3 , 7 , 8 - T C D F )( 1 3C 12 -2 ,3 ,7 J 8-TCOF )

C HEXA-CDO)(HEXA-CDD)(HEXA-CDD)(HEXA-CDO)(H £XA-CDO<i HEXA-CDO)' HEXA-CDD)' HEXA-CDO ''HEXA-CDO)'HEXA-COD)(HEX A- COD)C HEXA-COD)(HEXA-CDO)(HEXA-CDO)(HEXA-CDD)f HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)'HEXA-CDD)(HEXA-CDD)'HEXA-CDO)< HEXA-CDD)(HEXA-CDO)(HEXA-CDD)(HEXrt-CDO)(HEXA-CDD)(HEXA-CDD)C HEXA-CDD)C HEXA-CDD)(HEXA-CDD)(HEXA-CDD)C HEXA-CDD)*• HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDO)(HEXA-CDD*f HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-COD)(HEXA-CDD)(HEXA-CDO)

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* 37CLf 2 , 31 2 . 3' 2 , 3' 2 , 3= 2 ,3• 2 3^ , ' 2 , 3i 2 .?: 2 , 3( 2 ?? 2 . 3( 2 , 3;' 2 ?( 2 ^ 3' 2 , 3< 2 72 * 3

' - 2 , 3' 2 . 3• ' - 2 . 3' 2 . 3^2 ' . 3' 2 , 3^ 2 , 3

4 - 2 , 3 , 7 . 3 - T C O D ), ^ , 3 -TCOF ).7 ,8 -TCDF ), ^ . 3 -TCDF ). 7 ,8 -TCDF )^ . S -TCDF ), ^ . 3 -TCDF ), 7 , 3 - T C D F ), ^ ,3 -TCDF ),7 ,8 - TCDF ), ^ , 3 -TCDF ), "^ ,3 -TCDF), ~ * . 3 -TCDF ), 7 , 9 - T C D F ). " . 3 - TCOF ). ^ , 3 - TCDF ), ^ ,3 -TCDF ).7 ,8 -TCDF ),7 . 3 -TCDF )~" o Trritr ii . . O~ ! L,Ur J

, 7 ,8 -TCDF ' ., 7 , 5 - T C D F ). 7 , 8 - T C D F ),7 ,3 -TCDF : >, 7 .8 -TCDF ; .f 2 , 3 , x ,a- i uuh .'

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9 •66338<ii8333393833338:*833838

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1540 176 1 7 o . O Ol HEXA-CDD)(HEXA-CDD)• 'HEXA-CDD)' HEXA-CDD)= HEXA-CDD)r HEXA-CDD)<: HEXA-CDD)* HEXA-CDD)• : HEXA-CDD)(HEXA-CDD)i HEXA-CDD J? HEXA-CDD)(HEXA-CDD)r HEXA-CDD)iHEXA-CDD -C HEXA-CDD)CHEXA-COD)(HEXA-CDD)f HEXA-CDD;(HEXA-CDD)(HEXA-CDD)•: HEXA-CDD)( HEXA-CDD)r HEXA-CDO)

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' 1 3 C 1 2 - 2 . ? , 7 , 8 - T C O O )• 1 3 C 1 2 - 2 , 3 , 7 , 8 - T C D D >a 3 C 1 2 - 2 , 3 , 7 . 8 - T C D D >t 1 3 C 1 2 - 2 , 3 , 7 . 8 - T C D D >' 1 3 C 1 2 - 2 , 3 , 7 , 8 - T C D D . '< 1 3 C 1 2 - 2 , 3 . 7 , 9 - T C D O '• 1 3 C 1 2 - 2 , 3 , 7 , 8 - T C D D . '' i 3 C l 2 ~ 2 . 3 , 7 , 3 ~ T C D D >• ' 1 3C12-2 .3 .7 . S -TCDO)

( 2 , 3 , ^ ^3 -TCOD)• 2 , 3 , 7 , 9 - T C D D )( 2 , 3 , 7 ,3 -TCDD)( 2 , 3 , 7 , 8 - T C D D )( 2 , 3 , 7 . 8 - T C D D )^ 2 , 3 , 7 , 8 - T C D D )C 2 , 3 , 7 . 3 - T C Q D >( 2 , 3 , ^ . 3 - TCDD )^2 , 3 ,7 ,8 - TCDD )' 2 , 3 , 7 . 8 - T C D D )( 2 , 3 , 7 , 9 - T C O O )( 2 , ? , 7 , 8 - T C D D >C2 ,3 ,7 , 3-TCDD)' 2 . 3 . 7 , 3 - T C O D )( 2 , 3 , 7 , 8 - T C D O )C2 , 3 ,7 ,8-TCDD)( 2 , 3 , 7 , 8 - T C O O )( 2 , 3 , 7 , 8 - T C D D )C 2 , 3 , 7 , 8 - T C O D )( 2 , 3 , 7 , 8 - T C D D )( 2 , 3 , 7 , 8 - T C D O )( 2 , 3 , 7 , 8 - T C O D )C 2 , 3 ,7 ,8 -TCDD )( 2 , 3 , 7 , 8 - T C D O )( 2 , 3 , 7 , 8 - T C D D )(2 ,3 ,7 ,8-TCOD)( 2 , 3 , 7 , 8 - T C O O )( 2 , 3 , 7 , 8 - T C D O )( 2 , 3 , 7 , 8 - T C D O )( 2 , 3 , 7 , 8 - T C O D )( 2 , 3 , 7 , 8 - T C D O )( 2 , 3 , 7 , 8 - T C D D )( 2 , 3 , 7 , 8 - T C D D )

(37CL4-2 ,3 ,7 ,8 -TCDD >C37CL4-2 ,3 ,7 ,8 »TCDD)( 37CL4-2 , 3 ,7 , 8-TCDD )( 37CL4-2 ,3 ,7 ,3 -TCDD)

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^ ? 7 C L 4 - 2 , 3 , 7 , 8 - T C D O >2 , 3 , 7 , 8 - T C O F )2 , 3 , 7 , 8 - T C D F )2 , 3 ,7 ,3 -TCDF )2 , 3 , ^ , 3 - T C D F )2 , 3 , 7 , 3 - T C D F ;2 ,3 ,7 ,8 -TCDF )2 . 3 , 7 . 3 - T C D F )2 , 3 , 7 . 8 - T C D F )

' ' 2 , 3 . 7 . 8 - T C D F >2 .3 , ^ ,8 -TCDF )

' 2 , 3 . 7 , 8 - T C D F )^ 2 , 3 , 7 , 8 - T C D F )C 2 , 3 , ? , 8 - T C D F )• ' 2 , 3 , 7 , 8 - T C D F )• 2 , 3 . 7 . 3 - T C D F )^ 2 , 3 , 7 , 8 - T C D F )r 2 , 3 ,7 ,8 - TCDF )( 2 , 3 , 7 , 3 - T C D F )• 2 , 3 . 7 . S ~ T C D F )• ' 2 , 7 , 7 , 9 - T C O F Jf2 , 3 , 7 , 3 - T C D F )• 2 , 3 , -\S-TCDF)"2 . 3 , 7 , 3 - T C D F )• 2 , 3 , 7 ) 8 - T C Q F : >( : ^3 ,7 ,S " - rCDF )' C . ? , 7 , 3 - T C D F )( 2 , 3 . 7 . 8 - T C O F )' 2 , 3 , 7 , 8 - T C D F )f 2 . 3 , 7 , 3 - T C D F )f 2 , 3 , ^ . 3 - T C D F ' .' 2 , 3 , 7 . 8-TCDF)• 2 , 3 , 7 , 3 - T C O F )f? , 3 , 7 . 3 - T C D F )' 2 , 3 , 7 , 8 - T C D F )' • 2 , 3 .7 .3 -TCDF ; .( 2 , 3 , ^ , 8 - T C O F )< 2 , 3 , 7 , 8 - T C D F )f2 ,3 ,7 ,8 -TCDF )' 2 , 3 , 7 . 3 - T C D F )( 2 , 3 . 7 , 3 - T C D F )C 2 , 3 , 7 . 8 - T C D F )( 2 , 3 ,7 ,8 -TCDF )( 2 , 3 , 7 , 8 - T C D F )( 2 , 3 , 7 , 8 - T C D F )( 2 , 3 , 7 , 8 - T C D F )( • 2 , 3 , 7 , 8 - T C D F )( 1 3 C 1 2 ^ 2 , 3 , 7 , 8 - T C D F )U3C 12 -2 ,3 ,7 ,8 -TCDF )( 13C12-2 ,3 ,7 ,8-TCDF)U3C 12 -2 , 3 ,7 ,8 -TCDF )( 1 3C 12 -2 , 3 .7 ,8 - TCDF )C l 3 C 1 2 - 2 , 3 , 7 , 8 - T C D F )( 1 3 C 1 2 - 2 , 3 , 7 , 3 » T C D F )

( 1 3 C 1 2 - 2 , 3 , 7 , 8 - T C D F )U3C 12 -2 ,3 ,7 ,8 -TCDF )(HEXA-CDD)(HEXA-CDD)

3125252626262626262626262727272727272723282323282829292929292 9 ,293 0 ,3 0 ,3 0 ,3 0 ,3 0 .3 0 .3 0 .3 0 .3 1 .3 1 .31 .3 1 .28 .29 .2 6 .26 ,27.3 0 .3 1 .3 1 .3 1 .3 1 .2 8 .29 .33,33 .

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r^•c*^»jCDvOOO

II Compound R. Scan3 ! : Cone Un i ts£2)1?!™2 )J.2 )• 2)™2 )12)

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(-» fn n ru i n r*

(HEXA-CDO)(HEXA-CDO)C HEXA-CDD)'HEXA-CDD)f HEXA-CDD)'HEXA-CDO)f HEXA-CDD)' HEX A- COD)( HEXA-CDD)(HEXA-CDD)' HEXA-CDD)(HEXA-CDD)(HEXA-CDOC HEXA-CDD)fHEXA-COD>'HEXA-CDD)-HEXA-CDD. '•: HEXA-CDD •\* 15TH

7 3 .3 3 .33 .33 .34.3 4 .34 .35 .35 .35 .35 .36 .56 .57 .37 .37.37 .37.

646771751923391526547903741017378293

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006851

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MS d a t a r i l e header f r om : -SX i s lSamp l e : D IOX IN $66509 Op e r a t o r : TQNY MS i>-"l«Mis c : 2UL 0 6 6 5 0 9 SASft 1945-FSys. ft: 1 MS mod e l : 96 SW/HW r e v . : Crt nLS ^ : 0

Method f i l e : O IOX IN Tun ing f i l e : MT9501 Ho . o f - s x t r a r e co rd sSource t em p . : 200 Ana lyzer t e m p . : 250 Tran s f e r l ine t emo .

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Chromatog i raph i c t empe r a t u r e s : 70 . 1 9 0 , 2 3 0 . 0 .Chroma t og r ap h i c t i m e s , m m . : 4 . 0 1 0 . 0 2 0 . 0 0 . 0Chroma tograph i c ra t e f deg/min: 2 5 . 0 3 .0 0 .3 0 .0

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< - 2 . 3 , 7 , 8 - T C D F >' 2 , 3 , 7 . 3-TCDF)1 2 ,: , "%3-TCDF -( 2 , 3 , 7 . 9 - T C D F i^2 ,3 , "7 ,9-TCDF>' 2 , 3 , 7 , 9 - T C D F J< 2 , 3 , 7 . 3 - T C D F )( 1 3 C i 2 - 2 , 3 , 7 ,3-TCDF )U3C12 -2 ,3 .7 ,8 -TCDF >• 1 3 C 1 2 - 2 , 3 , 7 , 8 - T C O F i( 13 C 12-2 , 3 ,7 ,8-TCDF)U3C12-2 , 3 . 7 , 3 - T C D F )f 1 3C 12 -2 , 3 ' , 7 . 8 - T C D F )' 1 3 C 1 2 - 2 . 3 . 7 . 3 - T C D F j' 1 3 C 1 2 - 2 . 7 , , 3 -TCDF )U 7 C 1 2 - 2 , 3 , 7 , 3 - T C D F : <( 1 3 C i 2 - 2 . ' 3 i 7 . 3 - T C D F .U3C12-2 ,3 ,7 ,6 -TCDF >< 1 3 C 1 2 - 2 , 3 , 7 , 9 - T C D F .< 1 3 C 1 2 - 2 , 3 , 7 ,3-TCDF' tU 3 C 1 2 - 2 . 3 , 7 , 8 - T C D F <U3C12-2 .3 ,7 ,8 -TCDF )( 1 3 C 1 2 - 2 f 3 , 7 . 8 - T C D F >

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(HEXA-COD)(HEXA-CDD)

' (HEXA-COD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD^(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDO)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)f HEXA-CDD)(HEXA-CDD)(HEXA-CDD)(HEXA-CDD)

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I II - US Environmental Protection Agency · I II II II I December 6, 1985 Ms. Linda Haas Boynton...

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Transcript of I II - US Environmental Protection Agency · I II II II I December 6, 1985 Ms. Linda Haas Boynton...