Conference 2015 - Scottish Carbon Capture & Storage · PDF file• There is a need for...

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© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015

Harnessing CO2 The CO2 and the Cement Industry: Uses & Needs

SCCS Conference Edinburgh Michel Gimenez - 28 November 2015

© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015

This is a Cement Plant!

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© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015 4

CO2 Emission of a Cement Plant

0,40 t CO2 0,20 t CO2

1,15 t 0,747 t 1 t

0,253 t 0,1 t Fuel

Raw material

Clinker

Cement

Additions

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Combustion

Calcination e.g. ~ 600 kg CO2/tcement

0,60 t CO2

c/k = 1,34

Play on fuels emission factor

and on SHC

Play on clinker factor

Play on calcination ratio

© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015

Breakthrough Levers

•  New low CO2 intensive products (cement and concrete):

•  Low burning: - 30 % CO2/t

•  Mineral carbonation: ~ - 70 % CO2/t

•  Carbonated aggregates by

•  CO2 applications: we favor direct flue gas capture & uses: •  Mineral carbonation: see above + Skyonic example in Texas

•  Some chemistry with low concentration CO2?

•  High concentration CO2 capture (>99 %) is still expensive = 50-75 €/t and can be used for EOR, high value added applications and geological storage. No business model is established today for CCS

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© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015

Which CO2 Uses in the Cement Industry?

•  LafargeHolcim is developing a new type of binder through a collaboration with the start up company SOLIDIA, based in New Jersey (USA)

•  Industrial productions, 2 x 5000 t, made year 2014 in USA and in 2015 in Hungary

The birth of a new type of binders

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© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015

Which CO2 Uses in the Cement Industry?

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The birth of a new type of binders

• Many trials have been performed with SOLIDIA at customer sites (concrete precast)

• Market development started in North America and Europe (2015-2016)

•  Up to 70 % CO2 reduction is expected by using the SOLIDIA binder as compared to usual Portland cement but…

• … application segments still need to be developed: today non-structural precast only

© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015

Applications

Concrete Block Products

Concrete Pavers / Hardscape Products

AAC Block

Railroad Sleepers

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© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015

CO2 Needs

•  The amount of CO2 potentially available in our plants is generally exceeding by far the needs (ratio ~ 1 to 10)

•  CO2 source is present in our cement plants but is still very expensive to capture and cost is critical to the business model (50 €/t – 75€/t)

•  There is a need for cheap & small size CO2 capture plants i.e. 50,000 t/y – 100 kt/y

•  Logistics is critical in most CO2 applications

Capture & logistics

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© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015

Summary Learning on Capture Technologies

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% CO2 Captured

CO2 Capture Cost €/t CO2

DMX™ Solvent (99%vol)

MEA Solvent (99%vol)

Oxycombustion (80%-99%vol)

Separated calcination (80%-99%vol)

CO2 from Flue Gas (15%-25%vol)

[1] From the ACACIA project with IFPEN (2009-2012)

[2] From the ACACIA project with IFPEN (2009-2012)

[3] Estim. by LAFARGE-AL-FLS Oxycomb. Project (2013)

[4] Estim. by LAFARGE IPC-LEC (2013)

[5] Estim. LAFARGE IPC-LEC (2015)

[1] [2]

[3]

[4]

[5]

© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015

CO2 Uses vs CO2 Storage

•  Volume of CO2 needed for use is by far smaller than the CO2 emitted

•  CO2 uses will not enable storage because the business model are not the same (while the other way round could be true)

•  They will develop in parallel and not sequentially

Differences in Business Models

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2015

CO2 Uses

2035

2020

CO2 Capture & Storage

2050

© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015

CO2 Needs

•  An average cement plant is emitting 750 kt CO2 per year and the CO2 needs for carbonation might be 75 kt/y, i.e. 10% (70 kt to 100 kt is the standard size CO2 production plant in Europe today)

• We thus need cheap & small-sized CO2 capture plants

•  Investing a full-size capture plant and using only 10 % of it is not sound regarding capture cost thus preventing CO2 uses to develop

1st point

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Methane and CO2 cryo-capture in a biogas plant (~ 0,25 t/h)

Credit

© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015

CO2 Needs

● Capturing only part of the CO2 output implies going for post-combustion technologies or using the flue gas straight from the plant without concentrating the CO2

● Small capture plant will be less expensive than full size ones but the

CO2 captured more expensive, both due to size effect ● The more concentrated the CO2 , the cheaper the capture thus,

selected sources of CO2 will be the first concerned e.g. biogas plants, fermentation plants, SMR (when not captured yet)…

● No pipelines are requested for shipping but only refrigerated truck,

and liquid CO2 storage on utilization sites

2nd point

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© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015

CO2 Uses in the Frame of the Cement Industry

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Progress conclusion

● We do sell minerals ! Therefore, mineralization appears to be the most adapted to our industry; we do close the loop, provided the final product can be sold

● SOLIDIA or Carbon8 experiences are good examples of low CO2

products, even if the final market still needs to be extended to more application segments

● CO2 source is present in our plants but is still very expensive and

critical to the business model ● Logistics is critical in most CO2 applications

© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015

Thank you for your attention

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Conference  2015