Conference 2015 - Scottish Carbon Capture & Storage · PDF file• There is a need for...
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Conference 2015
© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015
Harnessing CO2 The CO2 and the Cement Industry: Uses & Needs
SCCS Conference Edinburgh Michel Gimenez - 28 November 2015
© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015 4
CO2 Emission of a Cement Plant
0,40 t CO2 0,20 t CO2
1,15 t 0,747 t 1 t
0,253 t 0,1 t Fuel
Raw material
Clinker
Cement
Additions
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Combustion
Calcination e.g. ~ 600 kg CO2/tcement
0,60 t CO2
c/k = 1,34
Play on fuels emission factor
and on SHC
Play on clinker factor
Play on calcination ratio
© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015
Breakthrough Levers
• New low CO2 intensive products (cement and concrete):
• Low burning: - 30 % CO2/t
• Mineral carbonation: ~ - 70 % CO2/t
• Carbonated aggregates by
• CO2 applications: we favor direct flue gas capture & uses: • Mineral carbonation: see above + Skyonic example in Texas
• Some chemistry with low concentration CO2?
• High concentration CO2 capture (>99 %) is still expensive = 50-75 €/t and can be used for EOR, high value added applications and geological storage. No business model is established today for CCS
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© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015
Which CO2 Uses in the Cement Industry?
• LafargeHolcim is developing a new type of binder through a collaboration with the start up company SOLIDIA, based in New Jersey (USA)
• Industrial productions, 2 x 5000 t, made year 2014 in USA and in 2015 in Hungary
The birth of a new type of binders
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© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015
Which CO2 Uses in the Cement Industry?
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The birth of a new type of binders
• Many trials have been performed with SOLIDIA at customer sites (concrete precast)
• Market development started in North America and Europe (2015-2016)
• Up to 70 % CO2 reduction is expected by using the SOLIDIA binder as compared to usual Portland cement but…
• … application segments still need to be developed: today non-structural precast only
© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015
Applications
Concrete Block Products
Concrete Pavers / Hardscape Products
AAC Block
Railroad Sleepers
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© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015
CO2 Needs
• The amount of CO2 potentially available in our plants is generally exceeding by far the needs (ratio ~ 1 to 10)
• CO2 source is present in our cement plants but is still very expensive to capture and cost is critical to the business model (50 €/t – 75€/t)
• There is a need for cheap & small size CO2 capture plants i.e. 50,000 t/y – 100 kt/y
• Logistics is critical in most CO2 applications
Capture & logistics
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© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015
Summary Learning on Capture Technologies
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% CO2 Captured
CO2 Capture Cost €/t CO2
DMX™ Solvent (99%vol)
MEA Solvent (99%vol)
Oxycombustion (80%-99%vol)
Separated calcination (80%-99%vol)
CO2 from Flue Gas (15%-25%vol)
[1] From the ACACIA project with IFPEN (2009-2012)
[2] From the ACACIA project with IFPEN (2009-2012)
[3] Estim. by LAFARGE-AL-FLS Oxycomb. Project (2013)
[4] Estim. by LAFARGE IPC-LEC (2013)
[5] Estim. LAFARGE IPC-LEC (2015)
[1] [2]
[3]
[4]
[5]
© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015
CO2 Uses vs CO2 Storage
• Volume of CO2 needed for use is by far smaller than the CO2 emitted
• CO2 uses will not enable storage because the business model are not the same (while the other way round could be true)
• They will develop in parallel and not sequentially
Differences in Business Models
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2015
CO2 Uses
2035
2020
CO2 Capture & Storage
2050
© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015
CO2 Needs
• An average cement plant is emitting 750 kt CO2 per year and the CO2 needs for carbonation might be 75 kt/y, i.e. 10% (70 kt to 100 kt is the standard size CO2 production plant in Europe today)
• We thus need cheap & small-sized CO2 capture plants
• Investing a full-size capture plant and using only 10 % of it is not sound regarding capture cost thus preventing CO2 uses to develop
1st point
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Methane and CO2 cryo-capture in a biogas plant (~ 0,25 t/h)
Credit
© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015
CO2 Needs
● Capturing only part of the CO2 output implies going for post-combustion technologies or using the flue gas straight from the plant without concentrating the CO2
● Small capture plant will be less expensive than full size ones but the
CO2 captured more expensive, both due to size effect ● The more concentrated the CO2 , the cheaper the capture thus,
selected sources of CO2 will be the first concerned e.g. biogas plants, fermentation plants, SMR (when not captured yet)…
● No pipelines are requested for shipping but only refrigerated truck,
and liquid CO2 storage on utilization sites
2nd point
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© LafargeHolcim 2015 SCCS Conference Edinburgh 28-10- 2015
CO2 Uses in the Frame of the Cement Industry
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Progress conclusion
● We do sell minerals ! Therefore, mineralization appears to be the most adapted to our industry; we do close the loop, provided the final product can be sold
● SOLIDIA or Carbon8 experiences are good examples of low CO2
products, even if the final market still needs to be extended to more application segments
● CO2 source is present in our plants but is still very expensive and
critical to the business model ● Logistics is critical in most CO2 applications