Benefits of Marine Line Tank Coating

Presenting MarineLine Tank Coating SystemsBenefits - Application - Cleaning - Repair

High Performance Coatings and Linings

GenerateastrongreturnonInvestment(ROI)overthelifeofthetankcoating.

Versatilitywiththeabilitytocarryawiderangeofchemicals,CPPs,PFADs,Bio-Fuels,andMethanol.

Assuranceofproductpurityfromporttoport.

Tankcoatingapplicationandcuringaredonecorrectlyandcertified.

What Shipowners Want From Chemical/Product Tankers


Easytankcleaninganddryingforfastturnaroundwithminimaldowntime.

Minortankrepairsandrusttouch-upscaneasilybedonewithMarineMendrepairkits.

Ongoingtankcoatinginspection/managementforworry-freeperformance.

This presentation will show how MarineLine coating meets these needs.

What Shipowners Want From Chemical/Product Tankers

High Performance Coatings and LiningsEvolution, Application and Benefits of MarineLine Coatings

Introduction

SectionOneContent

EvolutionandCoatingsDevelopment

ChemistryBehindMarineLineCoatings

Application,CuringandInspection

BenefitstotheShipowner

Evolution, Application and Benefits of MarineLine Coatings The Technology Behind MarineLine Coatings

Evolution, Application and Benefits of MarineLine Coatings Introduction

AdvancedPolymerCoatingsisaworld-wideleaderinutilizingorganicpolymertechnologywithhighperformancecapabilities.

Technologyisbasedonapatentedcross-linkedorganic-inorganicpolymerofferinghighheatresistanceandexcellentcorrosionresistance.

Coatingpropertiesarefarsuperiortoothermaterialsonthemarketwithoutcompromisingmaterialflexibility(non-brittle)ortoughness.

APCspolymertechnologyreplacesconventionalepoxyandzincsilicatecoatingsandliningsthattypicallycanhavecorrosivedeficiencies.

APCsspecialtyprotectivecoatingsservemanydifferentindustriesincluding:

Evolution, Application and Benefits of MarineLine Coatings APC Develops New Coatings for Market Applications

chemical storagetanksandterminals petro-chemicalmanufacturing

flooring storage/secondarycontainment powergeneration railandover-the-roadtransportation

Basedonindustrialsuccesses,APCdevelopedMarineLineforliningmaritimechemicaltankers.

FirstshipcoatedwithoriginalMarineLinewasM/T Indra,whichcarriedSuperPhosphoricAcidandothercargoesforyearsofservice.

2004-APCbeganopeningglobalofficestomeetgrowingdemandforMarineLinecoatings.


2006-AtSMM,APCannouncedthe100thchemicaltankercoatedwithMarineLine.

2007-APCcompletedamajorplantexpansioninAvon,Ohio,USA,toenhanceproductioncapacityforgrowingcoatingdemand.

2009-APCannouncedmorethan350shipshadbeencoatedwithMarineLine.

2010-APCgearsuptolaunchanewtankcoating-MarineLineX-engineeredspecificallyfortheoiltankermarket.


PhenolicEpoxiesform3dimensionalscreen-likestructureswithhydroxylformationinsidethecrosslinkstructurewhencured.

Evolution, Application and Benefits of MarineLine CoatingsThe Chemistry Behind MarineLine - Problems with Epoxies

HomopolymerizationofMarineLine

MarineLineiscrosslinkedbyanether(c-o-c)structure,oneofthestrongestbondsinchemistry,meaningtherearenohydroxylgroupsavailableforhydrolysisinMarineLine.

Evolution, Application and Benefits of MarineLine Coatings The Chemistry Behind MarineLine - A Solution Emerges

Thetechnology;Epoxies,andMarineLineform3-dimensionalscreen-likestructureswhencured.


OriginalMarineLinepolymerhad5-functionalitystructureforming25crosslinkswhenheatcuredusingacatalyst,notanaminecuringagent.

APCthendevelopedandpatenteda28-functionalitypolymerforMarineLine784,usingthesamecatalystandrequiringheatcuring.

MarineLinehasbeentestedandprovensuperiorvs.conventionalcoatingssuchasinorganiczincs,phenolicepoxies,andstainlesssteel.

MarineLineresists98%ofcorrosiveacids,alkalis,solvents,gassesandmaterialsatvarioustemperatures.

Outside,independenttestinghasalsoverifiedthisperformanceandstrengthensthecaseagainstcompetitivecoatingsandstainlesssteel.


ToensuretheperformanceofMarineLineitisimperativethatAPCprovideinspectionservices.

APCfocusesontheimportanceofgoodsurfacepreparation,correctapplicationandproperheatcure,ina7-Stepapproach.

MarineLinehassetthebenchmarkregardingheatcuring,andthensparktestingtheentiretanksurface.

TheAPCapproachhasprovenverysuccessfulfortankersupto38,000DWT.

Evolution, Application and Benefits of MarineLine Coatings MarineLine 7 Steps for Application, Curing and Inspection

Weld&GrindInspection

Staging

Dehumidification

Ventilation

Evolution, Application and Benefits of MarineLine Coatings MarineLine Success - Step 1- Pre-Blast

RainProtection

SurfaceContaminationTesting

SurfaceProtection

SurfaceProfile

SurfaceCleanliness

EnvironmentalConditions

Cleaning

Evolution, Application and Benefits of MarineLine Coatings MarineLine Success - Step 2 - Blasting

Blasting

VisualBlastInspection

RejectionofBlastQuality

EnvironmentalConditions

MixingThinners

BaseCoat

StripeCoat

Evolution, Application and Benefits of MarineLine Coatings MarineLine Success - Step 3 - Spray Application

TopCoat

TankTopCoating

ApplicationDefects

FiberglassApplication

DFTVisualInspection

InspectionBooklet

SparkTest

Evolution, Application and Benefits of MarineLine Coatings MarineLine Success - Step 4 - Inspection

TopCoat

TankTopCoating

ApplicationDefects

FiberglassApplication

Equipment

Set-up

Evolution, Application and Benefits of MarineLine Coatings MarineLine Success - Step 5 - Heat Cure

Charting

Curing

High Performance Coatings and Liningsz

FinalInspectionandSign-Off

Evolution, Application and Benefits of MarineLine Coatings MarineLine Success - Step 6 - Final Inspection & Sign-Off


Evolution, Application and Benefits of MarineLine Coatings MarineLine Provides Profitable Benefits - ROI

SeaTrial

SpotBlasting

Touch-Up

VacuumBlastMachine

Evolution, Application and Benefits of MarineLine Coatings MarineLine Success - Step 7 - Repairs After Heat Cure


MarineLineisapreferredcoatingformarinecargotanksduetofastreturnoninvestment.

MarineLinecostmoreinmaterial/curing,butthehigherperformanceofthecoatingmeanstheinvestmentisrecoupedfaster-in12-24months.

Opportunitytochargehighercharteringratesformoreaggressivecargoes.

Cleaningbenefitsareachievedthroughnon-absorption,lowsurfaceenergyandsmoothsurface

Evolution, Application and Benefits of MarineLine Coatings MarineLine Provides Profitable Benefits - ROI


MarineLineofferstheownertheabilitytocarryallcargoesontheIMOlist,including:Acrylonitrile,VAM,Methanol,PalmAcid,AceticAcid

Shipscanleavetheyardaftercertificationandloadaggressivecargoesimmediately.

Ownerscancarrycargoesthatwerepreviouslyallottedforstainlesssteeltanksonly.

Evolution, Application and Benefits of MarineLine Coatings MarineLine Provides - Profitable Benefits - Versatility

Evolution, Application and Benefits of MarineLine Coatings MarineLine Provides - Profitable Benefits - ABS


In2009,APCsMarineLinecoatingsystemreceivedProductTypeApprovedstatusfromtheABS.

CertificateNumber:06-HS154871-PDA.


Evolution, Application and Benefits of MarineLine Coatings MarineLine Provides - Profitable Benefits - ABS


#1-RealWorldExampleofCargoSequencingProvidedbyaShipOwner


Location CargoRafnes LoadedcausticsodaandEDCRotterdam CausticsodaandEDCdischargedAntwerp LoadedPGI,latexandMEGRotterdam LoadedVAM,2ethylhexanol,LAB,

styrenemonomerBarcelona DischargedVAM,2ethylhexanolLavrion DischargedstyrenemonomerGebze DischargedPGI,latexandMEGYuzhny Loadedfullcargoofmethanol


Evolution, Application and Benefits of MarineLine Coatings MarineLine Provides Profitable Benefits - Product Purity



#2-RealWorldExampleofCargoSequencingProvidedbyaShipOwner

Location CargoAlgeciras LoadedTDI,xylene,whitespirit,

hexaneandtolueneGebze Dischargedtoluene,whitespiritand

hexaneSines LoadedpygasAntwerp DischargedTDIandxyleneRotterdam Dischargedpygasandloadedslack

waxHamburg DischargedslackwaxandloadedEDC,

trichloroethaneandmethylenechloride

z

MarineLinecross-linkedstructuremeansthecoatingwillnotabsorbthecargo,thusensuringproductpurity,fromporttoport.

Products Tested: tests certified or performed by

DNV, Verwey Labs and other independent labs.

Evolution, Application and Benefits of MarineLine Coatings MarineLine Provides Profitable Benefits - Product Purity

100

80

60

40

20

050%

Phosphoric Acid 50%

Caustic Acid

80% Acetic Acid 96%

Sulphuric Acid

Ethylene Dichloride

(EDC) Virgin Naptha

Premium Gasoline

Acrylon-itrile

Styrene

Palm Oil

Purity Purity Before After

(Purity Measured to 0.001PPM)


z

APCsseven-stepapproachprovidesassurancethattankcoatingapplicationandcuringaredonecorrectlyandcertified.

Evolution, Application and Benefits of MarineLine Coatings MarineLine Provides Profitable Benefits - Application Assurance

5. HeatCure

6. FinalInspection

7. FinalRepairs

1. Pre-Blast

2. Blasting

3. SprayApplication

4. Inspection

z

Evolution, Application and Benefits of MarineLine Coatings MarineLine Provides Profitable Benefits - Application Assurance

MarineLineServicesisdesignedtoprovideshipownerswithasolutionformanagementoftheirmostvaluableassets-thecargotankcoating.

Thiswillbeprovidedthrough:

Annualinspections

Maintenancetrainingtothecrew

Cleaningconsultation(reducedcosttohire)

Maintenanceprogramevaluation

This program will be unveiled later in 2010.

Evolution, Application and Benefits of MarineLine Coatings MarineLine Provides Profitable Benefits - Ongoing Management


MarineLine Tank Cleaning OverviewIntroduction

SectionTwoContent

CleaningBenefits

LimitationsofZincSilicateCoatings

LimitationsofEpoxyCoatings

LimitationsofStainlessSteel

IndependentTestingofMarineLineCoatings

Extremelysmoothsurfacemakescleaningfast

Lessslops

Lesscleaningchemicalsneeded

Cleaningbenefitsareachievedthroughnon-absorption,lowsurfaceenergyandsmoothsurface

Lesslimitationsthanconventionalcoatingsandstainlesssteel

MarineLine Tank Cleaning OverviewCleaning Benefits of MarineLine

MarineLine Tank Cleaning OverviewCleaning - Limitations with Zinc Silicate Coatings

Conventionalcoatingssuchaszincsilicatesandphenolicepoxieshavelimitationsincargoesandcleaningrequirements.Theselimitationsarebasedupontheirchemicalstructureandabilitytoabsorbcargoes.

Traditionalcleaningchemicalscandestroyzincsilicatecoatingswhencleaningfromadyedgasoline,gasoil,orvegetableoiltoMethanolorMEG.Inadditionittakesanextensiveamountoftimeandefforttogetthetanksclean.

MarineLine Tank Cleaning OverviewCleaning - Limitations with Zinc Silicate Coatings

MarineLine Tank Cleaning OverviewCleaning - Limitations with Epoxy Coatings

Epoxycoatingshaveveryhighabsorptionproperties,especiallywithaproductsuchasMethanol,andhavehighrestrictionsforcleaningandcargoloading.

MarineLine Tank Cleaning OverviewCleaning - Limitations with Epoxy Coatings

MarineLine Tank Cleaning OverviewCleaning - Limitations with Stainless Steel

Stainlesssteeltankshaveahighinitialcostofconstruction,andongoingcostsofmaintainingtankconditionsthroughpassivationandcleaning.Passivationofthetanksisexpensiveanddangerous,howeverisnecessaryatvariouspointsthroughoutthecargotankslifecycle.

Stainlesssteelhasinherentproblemswithchlorideattack,thusmakingcleaningthetankscostlybecausefreshwaterortreatedseawaterisneeded;additionallytheinherentproblemswithchloridesalsolimitsitsabilitytocarrycertaincargoes.

MarineLine Tank Cleaning OverviewCleaning - Limitations with Stainless Steel

MarineLine Tank Cleaning OverviewIndependent Testing of MarineLine Coatings

In2008MarinspecAssociates(MA),anindependenttestinglab,investigatedtheabsorptionandretentionofchemicalcargoesinorganiccargotankcoatingspriortothecarriageofvegetableoilcargoes.

In2009,MAcomparedtransmissioncharacteristicsofMarineLine784andMarineLineXagainstatypicalzincsilicatecoating,atypicalepoxyphenolic,andstainlesssteel.Thefollowingfivesurfaceswereevaluated:

#1-4MildsteelcoatedwithaEthylZincSilicatecoating,aEpoxyPhenoliccoating,andMarineLine784andMarineLineXcoatings

#5Stainlesssteel,grade304


MAinvestigatedthecargoabsorption(andretention)characteristicsofeachofthe5surfacesunderthesameoperationalconditionswithaviewtocomparingthecontaminationthreateachsurfaceposed,afterexposuretoStyreneMonomer(SM)andEthyleneDicholoride(EDC),tosubsequentlyloadedambienttemperatureandhighmeltingpointvegetableoils.

TheobjectivewastocompareMarineLinecoatingsagainststainlesssteelandinorganiccoatingsundertheInternationalIndustryRulesforthecarriageofEdibleOilsinshipscargotanks.(egEU,FOFSA,NIOPetc).


Theconclusionwasclear;MarineLineout-performedthephenolicepoxyandmatchedtheperformanceofstainlesssteelandinorganiccoatinginensuringedibleoilpuritywhentestedrespectivelywithStyreneMonomerandEDCasimmediatelastcargoes.


MarineLine Tank Cleaning OverviewGeneral Information

P&AManualShipssystem

Removalofwastes

-AnnexIIuseofcleaningadditivesasperMEPC2Circ

-NonAnnexIIsubstances


Tankcleaning/gasfreeingsystemsfixed/portablemachines

Underwaterdischargerestriction

Tankcleanpumpcapacity

Boilercapacityforheating

Freshwaterwashingsystem

Generatorcapacity

High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings


Deckaircompressortypeandcapacity

Diwatersystem/HPwashing

Tankcleaningheatercapacity

Portablemachinecapacityandthrowdistance,cycletime

Fixedmachinesandthrowdistance,cycletime

High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings


TankCleaningMachines

Location

Capacity

Continuousmonitoring

Fixedmachinessingle,dualnozzles

High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings


Cycletimes,throwdistances,shadowarea

Portablemachinesanddrops

Heatercapacity

AnnexIIunderwaterdischargeflowrestrictions

High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings


Crewskillandexperience

Ancillaryequipment

-Wildenpumpsforeducting

-Chemicalspraypump,chemicalresistantHPhosesandsprayguns

-Sparesforportableandfixedmachines

High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings


Pre-Cleaning,TankCleaningandGasFreeing

Tankcleaning

-Industrialrequirements

Useofsurfactants,emulsifiers,wetting,absorptionagentsanddetergents

MEPC2Circ,GESAMPassessedcleaningchemicals

SOLASrestrictionsontankcleaningmachinescapacityforchemicaltankerscarryingAnnexIIcargoeswithoutinerting

High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings


Vegetableoils-dryingandnondrying

Fattyacidsandoleochemicals

CPPcargoes,lubeoils

Inertgascontamination

BTX

Wallwashcargoes

High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings


CleaningbyVentilation

CleaningbyventilationAnnexII

-Vaporpressure>50mb(absolute)

-CheckPandAmanualifpermittedforvessel

-Flammabilityandtoxicity

-IBCCodeCh8

-NotsuitableforinhibitedcargoesSMetc.

High Performance Coatings and Linings High Performance Coatings and Linings


PreviousCargo

Watersoluble?Ifthecargoisreasonablysolubleinwaterthenchemicalcleaningagentsareunnecessaryinmostcases.

Willanincreasedcleaningtemperaturecauseabeneficialreductionofcargoviscosityandlowersurfacetensionor...

Coulditcausetheopposite,thatcargoresiduespolymerizeoroxidize(dry)?

Polymerizationanddryingmustbeavoided,thereforethefirstcleaningoperationmustbecarriedoutcold.



PreviousCargo

Willtheproductbeaffectedbyalkalies?Causticsodaisarelativelycheapandeasilyavailablealkalinechemical.

Willtheproductdissolveinothereasilyavailableproductsbywhichthetankwallscanbetreated?(Successivelyupgradingorfloatationmethods).

High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings


Willcargoresiduesvaporizewithoutleavinganytraces?

Inertgascontaminationofcargotankcoating.

Cancargoresiduesbesafelymixedwiththecargotobeloaded?

High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings


PipeLineCleaning

Droplines

Strippinglines

Cargomanifolds

Drains,plugs

Blindsectionsofpipings

High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings High Performance Coatings and Linings


Steaming

Avoidsteamingasfaraspossible

Usehotfreshwaterforchlorideremoval,recirculationwithfreshwater

Diwaterspraying



OverCleaning?Lastcargo:

MTBE

Methanol

MEG

SM



MarineLineCoating

Cleaningisfasterthanconventionalcoatings

Ambientwash

Hotwash

Cleaningchemicals-useminimal



INNOVATEDonotgiveuporwaitforanswerfromshore

Tryotherchemicalsonboardtocleanspray,soak,wash/scrubtofindoptimumcleaningmethod

Getinsidetank

Washtankquicklyafterrecirculation

Usehotfreshwater


MarineLine Repair Using MarineMend Repair KitIntroduction

SectionThreeContent

SafetyObservance

SurfacePreparation

UsingtheMarineMendRepairKit

RepairProcedureswiththeMarineMendKit


MarineLine Repair Using MarineMend Repair KitIntroduction and Safety Observance

ThefollowingprocedureclearlyexplainswhatmustbedoneinordertorepairaMarineLinetankforservice.TherepairprocedureshouldbeusedwhentheMarineLinecoatinghasbeenmisapplied,damaged,orcontainsholidays(pinholes).

ObserveALLsafetyrequirementsduringthisprocedure,includingwearingallappropriatepersonalprotectiveequipmentasdetailedinMaterialSafetyDataSheets.


SteelplatecoatedwithMarineLine,priortomechanicaldamagewithahammer.

Damagedplate.

MarineLine Repair Using MarineMend Repair KitPre-Surface Preparation

MarineLine Repair Using MarineMend Repair KitMechanical Damage of MarineLine


Pre-Surfacepreparationincludesadetergentwashandchemicalcleaningofallsurfacestoberepaired.

Allsurfacesmustthenbedried.

MarineLine Repair Using MarineMend Repair KitPre-Surface Preparation


Ifthedamagedareasaresmallandindependent(separate)fromeachother,thesmalldamagedareasmaybehandsandedwithamediumgritaluminumoxidesandpaper.

Sandthetopcoat(grey)oftheMarineLinecoating,andremoveanyrustspots.

MarineLine Repair Using MarineMend Repair KitSurface Preparation


Close-upvisualofdamagedMarineLinecoating



Forareasthatarelarger,adisksanderwithamediumgritaluminumoxidediskshouldbeused.Removetopcoat(grey)oftheMarineLinecoating,andanyrustspots,downtoanearwhitemetal.Note:Allareassandeddowntoanearwhitemetal,musthaveanareaof25mmarounditsperiphery.MarineLinecoatingtopcoat(grey)shouldberemovedtoafeatherededge.



Maskedarea25mmperiphery



OrbitalSander



Sandmaskedarea.

Featheredgethesandedareasothatnolooseorsharpedgesofexistingcoatingareobservable.



High Performance Coatings and LiningsMarineLine Repair Using MarineMend Repair Kit

Surface Preparation

Theareashouldbevacuumedthoroughlytoremovealldustparticlesandwashedwithsolvent(MEKorAcetone)toremoveallcontaminants.


CleantheareatoberepairedwithAcetone.Note:Alwaysusecleanwhitecloth.Donotuseshoprags.



Finishedsurfacepreparation,priortorecoating.



MarineLine Repair Using MarineMend Repair KitMarineMend Repair Kit


PartB

PartA


EachMarineMendRepairSystemKitconsistsof:

MarineLine784BaseCoatComponents(NOTE:BesuretomixMarineLine784PartAwithMarineLine784PartB)

1jarMarineLine784(PartA)1bottleMarineLine784Basecoathardener(PartB)MarineMendTopCoatComponents(NOTE:BesuretomixMarineMendPartAwithMarineMendPartB)

1jarMarineMend(PartA)1bottleMarineMendTopcoathardener(PartB)


BaseCoatMarineLine784Mixing

Whenallpreparationworkiscompleted,pourtheentirecontentsofMarineLine784PartBcatalystbottleintoPartAcontainer.Mixthoroughlyfor2to3minutesbeforeapplyingtopreparedsurfaces.Note:ThepotlifeoftheMarineLine784basecoatkitis30minutesmaximum@20C.

Makesureallsurfacepreparationiscompletelyfinishedbeforemixingthekit.


CoatingtheRepairSpotsUseasmallbrushorrollertoapplythemixedcomponentsoftheMarineLine784basecoattotheproperlypreparedsurface.

Applyawetfilmthicknessof160-200microns.


MarineLine784appliedwithbrush.


CoatingtheRepairSpotsAllowbasecoattoB-stagewithgoodventilationuntilcoatinghastackedupbutreleasedallsolvent(coatingleavesafingerprintbutdoesNOTcomeuponfinger.Thismaytakeupto24hoursdependingontemperatureandairflow.


MixingtheMarineMendTopCoatWhenthebasecoathasreachedproperB-stage,pourtheentirecontentsofMarineMendCatalystPartBintothepartAcontainer,thenmixthoroughlyfor2-3minutes.

Applyonecoatinwetfilmthicknessof160-180microns.Note:ThepotlifeoftheMarineMendRepairKitis15minutesmaximum@20C.

Makesureallsurfacepreparationiscompletelyfinishedbeforemixingthekit.


MarineMendappliedwithbrush.


FinishedMarineMendpatch


CuringRequirementsPostcureMarineMendsystemwithsteamcoilsataminimumsubstratetemperature60Cfor24hours.

MarineLine Repair Using MarineMend Repair KitMarineMend Repair Kit Thank You!

ThankyouforyourinterestinMarineLine.

Wearepleasedtoansweryourquestions.

www.adv-polymer.com

Thank You!

Benefits of Marine Line Tank Coating

Documents

Transcript of Benefits of Marine Line Tank Coating