Atomic force microscopy at the picometer length scale · 2015. 1. 23. · Boneschanscher et al, ACS...
Transcript of Atomic force microscopy at the picometer length scale · 2015. 1. 23. · Boneschanscher et al, ACS...
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A.J. Weymouth and F.J. Giessibl
Atomic force microscopy
at the picometer length scale
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Want to probe interaction that is dominated by the
apex atom of the tip and the closest surface atom
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Inspiration for the qPlus
• Measure frequency
• Oscillate with small amplitudes
• Cantilever stiff enough to prevent
snap-to-contact
F.J. Giessibl, Appl. Phys. Lett. 73, 3956 (1998)
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How do “we” “normally” do AFM?
• Approach tip to surface
• Poke, pulse and pray
• Achieve atomic resolution and scan
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Pentacene CO terminated tip
Gross, Mohn, Moll, Liljeroth and Meyer, Science, 325, 1110 (2009)
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De Oteyza et al, Science, 340, 1434 (2013) Pavlicek et al, Phys Rev Lett, 108, 086101 (2012)
Gross et al, Nat Chem, 2, 821 (2010) Van der Lit et al, Nat Comm, 4, 2023 (2013)
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Neu et al, Phys Rev B, 89, 205407 (2014)
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Normal AFM
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Directly measure the lateral forces: Lateral Force Microscopy (LFM)
Giessibl et al, Proc Nat Acad Sci, 99, 12006 (2002) Weymouth et al, Phys Rev Lett, 111, 126103 (2013)
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Characterize CO at the
end of an AFM tip with
CO on the surface
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Lateral force microscopy data
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𝐸𝑆 =1
2 𝜅𝑆𝜃𝑆
2
𝐸𝑇 =1
2 𝜅𝑇𝜃𝑇
2
𝐸𝑀 = 𝐸𝑀(𝑟, 𝐸𝐵, 𝜆, 𝜎)
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𝜅𝑇 = 22 zNm
Weymouth et al, Science 106, 226801 (2014)
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Boneschanscher et al, ACS Nano, 8, 2006 (2014)
CO terminated tip
Gross et al, Science, 325, 1110 (2009)
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Using simultaneous force and current measurements to investigate a phantom force
Taking UHV know-how and moving to ambient
Using lateral force microscopy to probe molecular stiffness
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…a phantom force?
AFM data of silicon
taken with an applied
bias
appears very different
to data without a bias
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Weymouth et al, Phys Rev Lett 106, 226801 (2011)
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Weymouth et al, Phys Rev Lett 106, 226801 (2011)
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Forthcoming: NC-AFM Vol. 3, Ed. S. Morita, Springer, 2015
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Weymouth et al, Appl Phys Lett, 101, 213105 (2012)
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Forthcoming: NC-AFM Vol. 3, Ed. S. Morita, Springer, 2015
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Taking UHV know-how and moving to ambient environments
D. Wastl
Wastl, Weymouth, Giessibl. Phys. Rev. B, 87, 245415 (2013) Wastl, Weymouth, Giessibl. ACS Nano, 8, 5233 (2014)
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Vacuum conditions
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Ambient conditions
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Comparing wet…
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Strong effect of A on images
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Calculate effective quality factor
𝑄 = 2 𝜋 Energy stored
Energy loss= 2 𝜋
12
𝑘𝐴2
𝐸𝑙𝑜𝑠𝑠
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Wastl, et al. Phys. Rev. B, 87, 245415 (2013)
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Wastl, et al. ACS Nano, 8, 5233 (2014)
Applied to graphitic surfaces: graphene and graphite
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4.4 K
UHV
room temperature
UHV
ambient
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