APPENDIX B GROUNDWATER MONITORING … Lagoon/20170810... · GROUNDWATER MONITORING FORMS &...

August 2017 Project No. 1656790

APPENDIX B

GROUNDWATER MONITORING FORMS & ANALYTICAL LABORATORY RESULTS

October 06, 2016

Anne Faeth-BoydGolder Associates820 South Main St.Suite 100St Charles, MO 63301

The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested. Results are expressed as "as received" unless otherwise noted.

QC sample results for this data met EPA or laboratory specifications except as noted in the Case Narrative or as noted with qualifiers in the QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in full unless written approval has been obtained by ALS Environmental. Samples will be disposed in 30 days unless storage arrangements are made.

If you have any questions regarding this report, please feel free to call me.

Sincerely,

ALS Environmental received 6 sample(s) on Sep 29, 2016 for the analysis presented in the following report.

Laboratory Results for: City of Camdenton

Dear Anne,

Work Order: HS16091367

Generated By: Jumoke.Lawal

Dane J. Wacasey

10450 Stancliff Rd. Suite 210 Houston, TX 77099 T: +1 281 530 5656 F: +1 281 530 5887 www.alsglobal.com

Page 1 of 30

Client: Golder Associates

Work Order: HS16091367Project: City of Camdenton SAMPLE SUMMARY

Lab Samp ID Client Sample ID Collection DateMatrix TagNo Date Received Hold

HS16091367-01 28-Sep-2016 11:30 29-Sep-2016 08:20Mulberry Well (437-472) Water





HS16091367-06 28-Sep-2016 00:00 29-Sep-2016 08:20Trip Blank Water

ALS Group USA, Corp 06-Oct-16Date:

Page 2 of 30

Client: CASE NARRATIVE

Work Order:City of CamdentonGolder Associates

Project:HS16091367

GCMS Volatiles by Method SW8260

Batch ID: R282565Sample ID: Mulberry Well (564-598) (HS16091367-02MSD)

Some compounds outside recovery limits on MS/MSD.•

Sample ID: VLCSW-161005cis-1,3-Dichloropropene and Methylcyclohexane exceeded %recovery limits on LCS. Samples are non detect in the batch•

Sample ID: VSTD050Dichlorodifluoromethane, cis-1,3-Dichloropropene and Methylcyclohexane exceeded %D limits on CCV. Samples are non detect•


Page 3 of 30

Client:Project:Sample ID:

Golder AssociatesCity of CamdentonMulberry Well (437-472)

WorkOrder:Lab ID:

Collection Date:

HS16091367HS16091367-01

28-Sep-2016 11:30 Matrix:Water

ANALYTICAL REPORT

ANALYSES RESULT REPORT LIMIT

DILUTION FACTORUNITS

DATE ANALYZEDQUAL MDL

LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: AKP1ug/L 05-Oct-2016 14:300.201,1,1-Trichloroethane 1.0U

1ug/L 05-Oct-2016 14:300.501,1,2,2-Tetrachloroethane 1.0U

1ug/L 05-Oct-2016 14:301.01,1,2-Trichlor-1,2,2-trifluoroethane 1.0U

1ug/L 05-Oct-2016 14:300.301,1,2-Trichloroethane 1.0U

1ug/L 05-Oct-2016 14:300.201,1-Dichloroethane 1.0U

1ug/L 05-Oct-2016 14:300.201,1-Dichloroethene 1.0U

1ug/L 05-Oct-2016 14:300.501,2,4-Trichlorobenzene 1.0U

1ug/L 05-Oct-2016 14:301.01,2-Dibromo-3-chloropropane 1.0U

1ug/L 05-Oct-2016 14:300.201,2-Dibromoethane 1.0U

1ug/L 05-Oct-2016 14:300.501,2-Dichlorobenzene 1.0U


1ug/L 05-Oct-2016 14:300.501,2-Dichloropropane 1.0U



1ug/L 05-Oct-2016 14:300.502-Butanone 2.0U

1ug/L 05-Oct-2016 14:301.02-Hexanone 2.0U

1ug/L 05-Oct-2016 14:300.704-Methyl-2-pentanone 2.0U

1ug/L 05-Oct-2016 14:302.0Acetone 2.0U

1ug/L 05-Oct-2016 14:300.20Benzene 1.0U

1ug/L 05-Oct-2016 14:300.20Bromodichloromethane 1.0U

1ug/L 05-Oct-2016 14:300.40Bromoform 1.0U

1ug/L 05-Oct-2016 14:300.40Bromomethane 1.0U

1ug/L 05-Oct-2016 14:300.60Carbon disulfide 2.0U

1ug/L 05-Oct-2016 14:300.50Carbon tetrachloride 1.0U

1ug/L 05-Oct-2016 14:300.30Chlorobenzene 1.0U

1ug/L 05-Oct-2016 14:300.30Chloroethane 1.0U

1ug/L 05-Oct-2016 14:300.20Chloroform 1.0U

1ug/L 05-Oct-2016 14:300.20Chloromethane 1.0U

1ug/L 05-Oct-2016 14:300.20cis-1,2-Dichloroethene 1.08.2

1ug/L 05-Oct-2016 14:300.10cis-1,3-Dichloropropene 1.0U

1ug/L 05-Oct-2016 14:300.30Cyclohexane 1.0U

1ug/L 05-Oct-2016 14:300.30Dibromochloromethane 1.0U

1ug/L 05-Oct-2016 14:300.30Dichlorodifluoromethane 1.0U

1ug/L 05-Oct-2016 14:300.30Ethylbenzene 1.0U

1ug/L 05-Oct-2016 14:300.30Isopropylbenzene 1.0U

1ug/L 05-Oct-2016 14:300.50m,p-Xylene 2.0U

1ug/L 05-Oct-2016 14:301.0Methyl acetate 1.0U

1ug/L 05-Oct-2016 14:300.20Methyl tert-butyl ether 1.0U

1ug/L 05-Oct-2016 14:300.30Methylcyclohexane 1.0U

06-Oct-16Date: ALS Group USA, Corp

Note: See Qualifiers Page for a list of qualifiers and their explanation.

Page 4 of 30



WorkOrder:Lab ID:

Collection Date:

HS16091367HS16091367-01


ANALYTICAL REPORT




LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: AKP1ug/L 05-Oct-2016 14:301.0Methylene chloride 2.0U

1ug/L 05-Oct-2016 14:300.30o-Xylene 1.0U

1ug/L 05-Oct-2016 14:300.30Styrene 1.0U

1ug/L 05-Oct-2016 14:300.30Tetrachloroethene 1.0U

1ug/L 05-Oct-2016 14:300.20Toluene 1.01.2

1ug/L 05-Oct-2016 14:300.20trans-1,2-Dichloroethene 1.0U

1ug/L 05-Oct-2016 14:300.20trans-1,3-Dichloropropene 1.0U

1ug/L 05-Oct-2016 14:300.20Trichloroethene 1.0140

1ug/L 05-Oct-2016 14:300.30Trichlorofluoromethane 1.0U

1ug/L 05-Oct-2016 14:300.20Vinyl chloride 1.0U

1ug/L 05-Oct-2016 14:300.50Xylenes, Total 3.0U

Surr: 1,2-Dichloroethane-d4 1%REC 05-Oct-2016 14:3098.4 71-125

Surr: 4-Bromofluorobenzene 1%REC 05-Oct-2016 14:3090.0 70-125

Surr: Dibromofluoromethane 1%REC 05-Oct-2016 14:3079.0 74-125

Surr: Toluene-d8 1%REC 05-Oct-2016 14:30104 75-125



Page 5 of 30



WorkOrder:Lab ID:

Collection Date:

HS16091367HS16091367-02


ANALYTICAL REPORT





















1ug/L 05-Oct-2016 12:212.0Acetone 2.0U

1ug/L 05-Oct-2016 12:210.20Benzene 1.0U























Page 6 of 30



WorkOrder:Lab ID:

Collection Date:

HS16091367HS16091367-02


ANALYTICAL REPORT





1ug/L 05-Oct-2016 12:210.30o-Xylene 1.0U

1ug/L 05-Oct-2016 12:210.30Styrene 1.0U


1ug/L 05-Oct-2016 12:210.20Toluene 1.01.8







Surr: 1,2-Dichloroethane-d4 1%REC 05-Oct-2016 12:21100 71-125






Page 7 of 30



WorkOrder:Lab ID:

Collection Date:

HS16091367HS16091367-03


ANALYTICAL REPORT





















1ug/L 05-Oct-2016 14:562.0Acetone 2.0U

1ug/L 05-Oct-2016 14:560.20Benzene 1.0U























Page 8 of 30



WorkOrder:Lab ID:

Collection Date:

HS16091367HS16091367-03


ANALYTICAL REPORT





1ug/L 05-Oct-2016 14:560.30o-Xylene 1.0U

1ug/L 05-Oct-2016 14:560.30Styrene 1.0U


1ug/L 05-Oct-2016 14:560.20Toluene 1.02.8













Page 9 of 30



WorkOrder:Lab ID:

Collection Date:

HS16091367HS16091367-04


ANALYTICAL REPORT





















1ug/L 05-Oct-2016 15:222.0Acetone 2.0U

1ug/L 05-Oct-2016 15:220.20Benzene 1.0U























Page 10 of 30



WorkOrder:Lab ID:

Collection Date:

HS16091367HS16091367-04


ANALYTICAL REPORT





1ug/L 05-Oct-2016 15:220.30o-Xylene 1.0U

1ug/L 05-Oct-2016 15:220.30Styrene 1.0U


1ug/L 05-Oct-2016 15:22J 0.20Toluene 1.00.84













Page 11 of 30



WorkOrder:Lab ID:

Collection Date:

HS16091367HS16091367-05


ANALYTICAL REPORT





















1ug/L 05-Oct-2016 12:472.0Acetone 2.0U

1ug/L 05-Oct-2016 12:470.20Benzene 1.0U










1ug/L 05-Oct-2016 12:470.20cis-1,2-Dichloroethene 1.016













Page 12 of 30



WorkOrder:Lab ID:

Collection Date:

HS16091367HS16091367-05


ANALYTICAL REPORT





1ug/L 05-Oct-2016 12:470.30o-Xylene 1.0U

1ug/L 05-Oct-2016 12:470.30Styrene 1.0U


1ug/L 05-Oct-2016 12:47J 0.20Toluene 1.00.70



10ug/L 05-Oct-2016 14:052.0Trichloroethene 10240














Page 13 of 30


Golder AssociatesCity of CamdentonTrip Blank

WorkOrder:Lab ID:

Collection Date:

HS16091367HS16091367-06


ANALYTICAL REPORT





















1ug/L 05-Oct-2016 15:482.0Acetone 2.0U

1ug/L 05-Oct-2016 15:480.20Benzene 1.0U










1ug/L 05-Oct-2016 15:480.20cis-1,2-Dichloroethene 1.0U













Page 14 of 30


Golder AssociatesCity of CamdentonTrip Blank

WorkOrder:Lab ID:

Collection Date:

HS16091367HS16091367-06


ANALYTICAL REPORT





1ug/L 05-Oct-2016 15:480.30o-Xylene 1.0U

1ug/L 05-Oct-2016 15:480.30Styrene 1.0U


1ug/L 05-Oct-2016 15:480.20Toluene 1.0U



1ug/L 05-Oct-2016 15:480.20Trichloroethene 1.0U










Page 15 of 30

Client:City of CamdentonGolder Associates

WorkOrder:Project:

HS16091367DATES REPORT

Collection Date Prep Date Analysis DateClient Samp IDSample ID TCLP Date DF

Batch ID R282565 Test Name : LOW LEVEL VOLATILES BY SW8260C Matrix: Water

05 Oct 2016 14:30HS16091367-01 28 Sep 2016 11:30 1Mulberry Well (437-472)






05 Oct 2016 15:48HS16091367-06 28 Sep 2016 00:00 1Trip Blank


Page 16 of 30

Client:Project:

Golder AssociatesCity of Camdenton

WorkOrder: HS16091367

QC BATCH REPORT

Batch ID: R282565 Instrument: VOA4 Method: SW8260

Sample ID: VBLKW-161005 Units: ug/L Analysis Date: 05-Oct-2016 11:30

Run ID: VOA4_282565 SeqNo: 3849954 PrepDate: DF: 1

Analyte SPK ValPQLResultSPK Ref

Value %RECControl

LimitRPD Ref

Value %RPDRPD Limit Qual

MBLK

Client ID:

1,1,1-Trichloroethane U 1.0

1,1,2,2-Tetrachloroethane U 1.0

1,1,2-Trichlor-1,2,2-trifluoroethane U 1.0


1,1-Dichloroethane U 1.0

1,1-Dichloroethene U 1.0

1,2,4-Trichlorobenzene U 1.0

1,2-Dibromo-3-chloropropane U 1.0

1,2-Dibromoethane U 1.0

1,2-Dichlorobenzene U 1.0


1,2-Dichloropropane U 1.0



2-Butanone U 2.0

2-Hexanone U 2.0

4-Methyl-2-pentanone U 2.0

Acetone U 2.0

Benzene U 1.0

Bromodichloromethane U 1.0

Bromoform U 1.0

Bromomethane U 1.0

Carbon disulfide U 2.0

Carbon tetrachloride U 1.0

Chlorobenzene U 1.0

Chloroethane U 1.0

Chloroform U 1.0

Chloromethane U 1.0

cis-1,2-Dichloroethene U 1.0

cis-1,3-Dichloropropene U 1.0

Cyclohexane U 1.0

Dibromochloromethane U 1.0

Dichlorodifluoromethane U 1.0

Ethylbenzene U 1.0

ALS Group USA, Corp Date: 06-Oct-16


Page 17 of 30

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Isopropylbenzene U 1.0

m,p-Xylene U 2.0

Methyl acetate U 1.0

Methyl tert-butyl ether U 1.0

Methylcyclohexane U 1.0

Methylene chloride U 2.0

o-Xylene U 1.0

Styrene U 1.0

Tetrachloroethene U 1.0

Toluene U 1.0

trans-1,2-Dichloroethene U 1.0

trans-1,3-Dichloropropene U 1.0

Trichloroethene U 1.0

Trichlorofluoromethane U 1.0

Vinyl chloride U 1.0

Xylenes, Total U 3.0

47.8 50 0 95.6 71 - 1251.0Surr: 1,2-Dichloroethane-d4

44.48 50 0 89.0 70 - 1251.0Surr: 4-Bromofluorobenzene

48.62 50 0 97.2 74 - 1251.0Surr: Dibromofluoromethane

51.05 50 0 102 75 - 1251.0Surr: Toluene-d8



Page 18 of 30

Client:Project:



QC BATCH REPORT


Sample ID: VLCSW-161005 Units: ug/L Analysis Date: 05-Oct-2016 10:13



Value %RECControl

LimitRPD Ref


LCS

Client ID:

1,1,1-Trichloroethane 57.99 50 0 116 75 - 1301.0

1,1,2,2-Tetrachloroethane 43.19 50 0 86.4 74 - 1231.0

1,1,2-Trichlor-1,2,2-trifluoroethane 59.79 50 0 120 70 - 1301.0


1,1-Dichloroethane 53.88 50 0 108 76 - 1201.0

1,1-Dichloroethene 56.45 50 0 113 75 - 1301.0

1,2,4-Trichlorobenzene 51.99 50 0 104 75 - 1261.0

1,2-Dibromo-3-chloropropane 52.09 50 0 104 65 - 1251.0

1,2-Dibromoethane 54.35 50 0 109 80 - 1211.0

1,2-Dichlorobenzene 49.95 50 0 99.9 80 - 1201.0

1,2-Dichloroethane 52.65 50 0 105 76 - 1201.0

1,2-Dichloropropane 51.56 50 0 103 80 - 1201.0

1,3-Dichlorobenzene 52.16 50 0 104 80 - 1201.0


2-Butanone 109.3 100 0 109 60 - 1402.0

2-Hexanone 115.4 100 0 115 60 - 1312.0

4-Methyl-2-pentanone 96.73 100 0 96.7 60 - 1352.0

Acetone 97.46 100 0 97.5 60 - 1402.0

Benzene 55.06 50 0 110 75 - 1221.0

Bromodichloromethane 56.31 50 0 113 75 - 1251.0

Bromoform 53.48 50 0 107 70 - 1301.0

Bromomethane 55.77 50 0 112 60 - 1401.0

Carbon disulfide 112.4 100 0 112 70 - 1302.0

Carbon tetrachloride 54.02 50 0 108 75 - 1251.0

Chlorobenzene 50.85 50 0 102 80 - 1201.0

Chloroethane 54.74 50 0 109 70 - 1301.0

Chloroform 51.61 50 0 103 70 - 1301.0

Chloromethane 55.26 50 0 111 65 - 1301.0

cis-1,2-Dichloroethene 54.71 50 0 109 75 - 1251.0

cis-1,3-Dichloropropene 62.7 50 0 125 79 - 125 S 1.0

Cyclohexane 55.88 50 0 112 70 - 1301.0

Dibromochloromethane 53.14 50 0 106 70 - 1301.0

Dichlorodifluoromethane 60.6 50 0 121 60 - 1401.0

Ethylbenzene 54.83 50 0 110 80 - 1201.0



Page 19 of 30

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Isopropylbenzene 58.67 50 0 117 75 - 1301.0

m,p-Xylene 111.1 100 0 111 80 - 1202.0

Methyl acetate 53.76 50 0 108 76 - 1221.0

Methyl tert-butyl ether 56.73 50 0 113 70 - 1301.0

Methylcyclohexane 66.82 50 0 134 70 - 126 S 1.0

Methylene chloride 50.09 50 0 100 65 - 1332.0

o-Xylene 54.51 50 0 109 80 - 1201.0

Styrene 57.58 50 0 115 78 - 1221.0

Tetrachloroethene 53.84 50 0 108 75 - 1301.0

Toluene 52.73 50 0 105 75 - 1211.0

trans-1,2-Dichloroethene 55.89 50 0 112 75 - 1251.0

trans-1,3-Dichloropropene 50.1 50 0 100 76 - 1251.0

Trichloroethene 55.46 50 0 111 71 - 1251.0

Trichlorofluoromethane 58.05 50 0 116 67 - 1321.0

Vinyl chloride 55.55 50 0 111 70 - 1351.0

Xylenes, Total 165.6 150 0 110 79 - 1243.0




50.96 50 0 102 75 - 1251.0Surr: Toluene-d8



Page 20 of 30

Client:Project:



QC BATCH REPORT


Sample ID: HS16091367-02MS Units: ug/L Analysis Date: 05-Oct-2016 13:13



Value %RECControl

LimitRPD Ref


MS

Client ID: Mulberry Well (564-598)


1,1,2,2-Tetrachloroethane 0.978 50 0 1.96 74 - 123 JS 1.0

1,1,2-Trichlor-1,2,2-trifluoroethane 65.78 50 0 132 70 - 130 S 1.0

1,1,2-Trichloroethane 46.34 50 0 92.7 80 - 1201.0

1,1-Dichloroethane 53.35 50 0 107 76 - 1201.0

1,1-Dichloroethene 62.89 50 0 126 75 - 1301.0

1,2,4-Trichlorobenzene 48.71 50 0 97.4 75 - 1261.0

1,2-Dibromo-3-chloropropane 45.39 50 0 90.8 65 - 1251.0

1,2-Dibromoethane 53.24 50 0 106 80 - 1211.0


1,2-Dichloroethane 51.43 50 0 103 76 - 1201.0


1,3-Dichlorobenzene 51.29 50 0 103 80 - 1201.0


2-Butanone 111.3 100 0 111 60 - 1402.0

2-Hexanone 111.8 100 0 112 60 - 1312.0


Acetone 96.42 100 0 96.4 60 - 1402.0

Benzene 54.77 50 0 110 75 - 1221.0


Bromoform 51.75 50 0 104 70 - 1301.0

Bromomethane 53.88 50 0 108 60 - 1401.0



Chlorobenzene 49.76 50 0 99.5 80 - 1201.0

Chloroethane 54.94 50 0 110 70 - 1301.0

Chloroform 51.92 50 0 104 70 - 1301.0

Chloromethane 55.54 50 0 111 65 - 1301.0

cis-1,2-Dichloroethene 58.44 50 3.228 110 75 - 1251.0

cis-1,3-Dichloropropene 57.43 50 0 115 79 - 1251.0

Cyclohexane 60.91 50 0 122 70 - 1301.0



Ethylbenzene 55.92 50 0 112 80 - 1201.0



Page 21 of 30

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS



m,p-Xylene 112.4 100 0 112 80 - 1202.0

Methyl acetate U 50 0 0 76 - 122 S 1.0


Methylcyclohexane 70.3 50 0 141 70 - 126 S 1.0


o-Xylene 55.27 50 0 111 80 - 1201.0

Styrene 56.49 50 0 113 78 - 1221.0


Toluene 56.2 50 1.767 109 75 - 1211.0


trans-1,3-Dichloropropene 45.63 50 0 91.3 76 - 1251.0

Trichloroethene 155.8 50 52.25 207 71 - 125 S 1.0


Vinyl chloride 61.01 50 0 122 70 - 1351.0

Xylenes, Total 167.7 150 0 112 80 - 1243.0


50.06 50 0 100 70 - 1251.0Surr: 4-Bromofluorobenzene


52.24 50 0 104 75 - 1251.0Surr: Toluene-d8



Page 22 of 30

Client:Project:



QC BATCH REPORT


Sample ID: HS16091367-02MSD Units: ug/L Analysis Date: 05-Oct-2016 13:39



Value %RECControl

LimitRPD Ref


MSD


1,1,1-Trichloroethane 58.28 50 0 117 75 - 130 59.37 1.85 201.0

1,1,2,2-Tetrachloroethane 1.003 50 0 2.01 74 - 123 0.978 2.51 20 S 1.0

1,1,2-Trichlor-1,2,2-trifluoroethane 61.91 50 0 124 70 - 130 65.78 6.06 201.0

1,1,2-Trichloroethane 42.77 50 0 85.5 80 - 120 46.34 8.02 201.0

1,1-Dichloroethane 50.73 50 0 101 76 - 120 53.35 5.02 201.0

1,1-Dichloroethene 64.02 50 0 128 75 - 130 62.89 1.78 201.0

1,2,4-Trichlorobenzene 50.99 50 0 102 75 - 126 48.71 4.56 201.0

1,2-Dibromo-3-chloropropane 49.02 50 0 98.0 65 - 125 45.39 7.68 201.0

1,2-Dibromoethane 49.8 50 0 99.6 80 - 121 53.24 6.67 201.0

1,2-Dichlorobenzene 48.46 50 0 96.9 80 - 120 47.55 1.91 201.0

1,2-Dichloroethane 48.52 50 0 97.0 76 - 120 51.43 5.83 201.0

1,2-Dichloropropane 48.16 50 0 96.3 80 - 120 50.57 4.89 201.0

1,3-Dichlorobenzene 51.67 50 0 103 80 - 120 51.29 0.74 201.0


2-Butanone 112.4 100 0 112 60 - 140 111.3 0.958 202.0

2-Hexanone 113.3 100 0 113 60 - 131 111.8 1.38 202.0

4-Methyl-2-pentanone 94.26 100 0 94.3 60 - 135 94.67 0.436 202.0

Acetone 97.28 100 0 97.3 60 - 140 96.42 0.887 202.0

Benzene 53.35 50 0 107 75 - 122 54.77 2.64 201.0

Bromodichloromethane 50.1 50 0 100 75 - 125 52.46 4.61 201.0

Bromoform 50.91 50 0 102 70 - 130 51.75 1.65 201.0

Bromomethane 52.18 50 0 104 60 - 140 53.88 3.2 201.0

Carbon disulfide 111.8 100 0 112 70 - 130 116.5 4.08 202.0

Carbon tetrachloride 52.86 50 0 106 75 - 125 54.85 3.69 201.0

Chlorobenzene 48.02 50 0 96.0 80 - 120 49.76 3.56 201.0

Chloroethane 54.65 50 0 109 70 - 130 54.94 0.545 201.0

Chloroform 49.98 50 0 100.0 70 - 130 51.92 3.8 201.0

Chloromethane 53.93 50 0 108 65 - 130 55.54 2.94 201.0

cis-1,2-Dichloroethene 56.12 50 3.228 106 75 - 125 58.44 4.05 201.0

cis-1,3-Dichloropropene 56.1 50 0 112 79 - 125 57.43 2.34 201.0

Cyclohexane 58.33 50 0 117 70 - 130 60.91 4.31 201.0

Dibromochloromethane 48.23 50 0 96.5 70 - 130 50.47 4.54 201.0

Dichlorodifluoromethane 63.21 50 0 126 60 - 140 65.02 2.81 201.0

Ethylbenzene 53.84 50 0 108 80 - 120 55.92 3.79 201.0



Page 23 of 30

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD


Isopropylbenzene 58.2 50 0 116 75 - 130 59.79 2.69 201.0

m,p-Xylene 106.6 100 0 107 80 - 120 112.4 5.31 202.0

Methyl acetate U 50 0 0 76 - 122 0 0 20 S 1.0

Methyl tert-butyl ether 53.32 50 0 107 70 - 130 54.17 1.58 201.0

Methylcyclohexane 67.83 50 0 136 70 - 126 70.3 3.58 20 S 1.0

Methylene chloride 48.84 50 0 97.7 65 - 133 50.19 2.74 202.0

o-Xylene 52.13 50 0 104 80 - 120 55.27 5.85 201.0

Styrene 55.03 50 0 110 78 - 122 56.49 2.62 201.0

Tetrachloroethene 54.44 50 0 109 75 - 130 58.34 6.92 201.0

Toluene 53.51 50 1.767 103 75 - 121 56.2 4.89 201.0

trans-1,2-Dichloroethene 55.52 50 0 111 75 - 125 58.01 4.39 201.0

trans-1,3-Dichloropropene 46.07 50 0 92.1 76 - 125 45.63 0.949 201.0

Trichloroethene 151.3 50 52.25 198 71 - 125 155.8 2.94 20 S 1.0

Trichlorofluoromethane 59.81 50 0 120 67 - 132 62.87 4.98 201.0

Vinyl chloride 58.84 50 0 118 70 - 135 61.01 3.62 201.0

Xylenes, Total 158.7 150 0 106 80 - 124 167.7 5.49 203.0

47.76 50 0 95.5 71 - 125 49.59 3.77 201.0Surr: 1,2-Dichloroethane-d4

49.01 50 0 98.0 70 - 125 50.06 2.13 201.0Surr: 4-Bromofluorobenzene

40.32 50 0 80.6 74 - 125 41.81 3.63 201.0Surr: Dibromofluoromethane

51.34 50 0 103 75 - 125 52.24 1.73 201.0Surr: Toluene-d8

The following samples were analyzed in this batch: HS16091367-01 HS16091367-02 HS16091367-03 HS16091367-04 HS16091367-05 HS16091367-06



Page 24 of 30

QUALIFIERS, ACRONYMS, UNITS

Client:Project:WorkOrder:

Golder AssociatesCity of CamdentonHS16091367

Qualifier Description* Value exceeds Regulatory Limit

a Not accredited

B Analyte detected in the associated Method Blank above the Reporting Limit

E Value above quantitation range

H Analyzed outside of Holding Time

J Analyte detected below quantitation limit

M Manually integrated, see raw data for justification

n Not offered for accreditation

ND Not Detected at the Reporting Limit

O Sample amount is > 4 times amount spiked

P Dual Column results percent difference > 40%

R RPD above laboratory control limit

S Spike Recovery outside laboratory control limits

U Analyzed but not detected above the MDL/SDL

Acronym DescriptionDCS Detectability Check Study

DUP Method Duplicate

LCS Laboratory Control Sample

LCSD Laboratory Control Sample Duplicate

MBLK Method Blank

MDL Method Detection Limit

MQL Method Quantitation Limit

MS Matrix Spike

MSD Matrix Spike Duplicate

PDS Post Digestion Spike

PQL Practical Quantitaion Limit

SD Serial Dilution

SDL Sample Detection Limit

TRRP Texas Risk Reduction Program

Unit Reported Descriptionµg/L Micrograms per Liter


Page 25 of 30

CERTIFICATIONS,ACCREDITATIONS & LICENSES

Agency Number Expire Date

Arkansas 16-022-1 27-Mar-2017

California 2919 2016-2018 31-Jul-2018

Illinois 003872 09-May-2017

Kansas E-10352 2015-2016 30-Oct-2016

Kentucky 96 2016-2017 30-Apr-2017

Louisiana 03087 2016-2017 30-Jun-2017

North Carolina 624 - 2016 31-Dec-2016

North Dakota R193 2016-2017 30-Apr-2017

Oklahoma 2016-122 31-Aug-2017

Texas TX104704231-16-17 30-Apr-2017


Page 26 of 30


Work Order: HS16091367Project: City of Camdenton SAMPLE TRACKING

Lab Samp ID Client Sample ID Action Date Person New Location

HS16091367-01 Mulberry Well (437-472) Login 9/29/2016 11:43:32 AM JRM VW-3





HS16091367-06 Trip Blank Login 9/29/2016 11:43:33 AM JRM VW-3


Page 27 of 30

RPG

29-Sep-2016 08:20Date/Time Received:

HS16091367

Golder St Louis

Work Order:

Client Name:

Sample Receipt Checklist

Received by:

Shipping container/cooler in good condition?

Custody seals intact on shipping container/cooler?

Custody seals intact on sample bottles?

Chain of custody present?

Chain of custody signed when relinquished and received?

Chain of custody agrees with sample labels?

Samples in proper container/bottle?

Sample containers intact?

Sufficient sample volume for indicated test?

All samples received within holding time?

Container/Temp Blank temperature in compliance?

Temperature(s)/Thermometer(s):

Cooler(s)/Kit(s):

Date/Time sample(s) sent to storage:

Water - VOA vials have zero headspace?

Water - pH acceptable upon receipt?

pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

1.3c/2.0c UC/C IR11White09/29/2016 11:45

Yes No No VOA vials submitted

Yes No N/A

Yes No N/A

Checklist completed by: Jared R. MakanDateeSignatureDateeSignature

3-Oct-201629-Sep-2016

FedExWater Carrier name:Matrices:

Reviewed by: Dane J. Wacasey

Client Contacted: Date Contacted: Person Contacted:

Contacted By: Regarding:

Comments:

Corrective Action:

Yes

NoYesTX1005 solids received in hermetically sealed vials? N/A


Page 28 of 30

November 07, 2016

Anne Faeth-BoydGolder Associates820 South Main St.Suite 100St Charles, MO 63301

The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested. Results are expressed as "as received" unless otherwise noted.

QC sample results for this data met EPA or laboratory specifications except as noted in the Case Narrative or as noted with qualifiers in the QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in full unless written approval has been obtained by ALS Environmental. Samples will be disposed in 30 days unless storage arrangements are made.

If you have any questions regarding this report, please feel free to call me.

Sincerely,

ALS Environmental received 7 sample(s) on Oct 29, 2016 for the analysis presented in the following report.

Laboratory Results for: City of Camdenton

Dear Anne,

Work Order: HS16101339

Generated By: Jumoke.Lawal

Dane J. Wacasey

10450 Stancliff Rd. Suite 210 Houston, TX 77099 T: +1 281 530 5656 F: +1 281 530 5887 www.alsglobal.com

Page 1 of 47


Work Order: HS16101339Project: City of Camdenton SAMPLE SUMMARY

Lab Samp ID Client Sample ID Collection DateMatrix TagNo Date Received Hold

HS16101339-01 25-Oct-2016 16:30 29-Oct-2016 09:30MWPT-1 Water

HS16101339-02 25-Oct-2016 00:00 29-Oct-2016 09:30DUP-1 Water


HS16101339-04 27-Oct-2016 16:00 29-Oct-2016 09:30FB-1 Water


HS16101339-06 28-Oct-2016 13:05 29-Oct-2016 09:30RB-1 Water

HS16101339-07 25-Oct-2016 00:00 29-Oct-2016 09:30TRIP BLANK Water

ALS Group USA, Corp 07-Nov-16Date:

Page 2 of 47

Client: CASE NARRATIVE

Work Order:City of CamdentonGolder Associates

Project:HS16101339

GCMS Volatiles by Method SW8260

Batch ID: R283946Sample ID: HS16101295-03MS

MS and MSD are for an unrelated sample•

Batch ID: R283975

The test results meet requirements of the current NELAP standards, state requirements or programs where applicable.•

Metals by Method M2340 B

Batch ID: R284356


Metals by Method SW7470

Batch ID: 109499Sample ID: HS16110059-01MS

MS and MSD are for an unrelated sample•

Metals by Method SW6020

Batch ID: 109425Sample ID: HS16101322-10MS

MS/MSD and DUPs are for an unrelated sample•

WetChemistry by Method SW9060

Batch ID: R284304


WetChemistry by Method SM2320B

Batch ID: R284076



Page 3 of 47


Golder AssociatesCity of CamdentonMWPT-1

WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-01

25-Oct-2016 16:30 Matrix:Water

ANALYTICAL REPORT





















1ug/L 31-Oct-2016 19:332.0Acetone 2.0U

1ug/L 31-Oct-2016 19:330.20Benzene 1.0U





















07-Nov-16Date: ALS Group USA, Corp


Page 4 of 47



WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-01


ANALYTICAL REPORT





1ug/L 31-Oct-2016 19:330.30o-Xylene 1.0U

1ug/L 31-Oct-2016 19:330.30Styrene 1.0U


1ug/L 31-Oct-2016 19:330.20Toluene 1.0U










Surr: Toluene-d8 1%REC 31-Oct-2016 19:3398.1 75-125HARDNESS, TOTAL AS CACO3 BY SM2340B

Method:M2340 B Analyst: DQ

1mg/L 07-Nov-2016 15:302.00Hardness (As CaCO3) 2.00327

ICP-MS METALS BY SW6020A Method:SW6020 Analyst: JDEPrep:SW3010A / 01-Nov-2016

1mg/L 04-Nov-2016 18:070.000400Arsenic 0.00500U

1mg/L 04-Nov-2016 18:070.00190Barium 0.005000.0489

1mg/L 04-Nov-2016 18:070.000200Cadmium 0.00200U

1mg/L 04-Nov-2016 18:070.0340Calcium 0.50067.6

1mg/L 04-Nov-2016 18:070.000400Chromium 0.00500U

1mg/L 04-Nov-2016 18:07J 0.000600Lead 0.005000.00399

1mg/L 04-Nov-2016 18:070.0100Magnesium 0.20038.5

1mg/L 04-Nov-2016 18:070.00110Selenium 0.00500U

1mg/L 04-Nov-2016 18:070.000200Silver 0.00500U

MERCURY BY SW7470A Method:SW7470 Analyst: JCJPrep:SW7470 / 03-Nov-2016

1mg/L 03-Nov-2016 15:270.0000400Mercury 0.000200U

ALKALINITY BY SM2320B Method:SM2320B Analyst: KMU1mg/L 02-Nov-2016 11:075.00Alkalinity, Bicarbonate (As

CaCO3)5.00324

1mg/L 02-Nov-2016 11:075.00Alkalinity, Carbonate (As CaCO3) 5.00U

1mg/L 02-Nov-2016 11:075.00Alkalinity, Hydroxide (As CaCO3) 5.00U

1mg/L 02-Nov-2016 11:075.00Alkalinity, Total (As CaCO3) 5.00324

TOTAL ORGANIC CARBON BY SW9060A Method:SW9060 Analyst: KMU1mg/L 06-Nov-2016 17:230.500Organic Carbon, Total 1.00U



Page 5 of 47


Golder AssociatesCity of CamdentonDUP-1

WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-02


ANALYTICAL REPORT





















1ug/L 31-Oct-2016 19:582.0Acetone 2.0U

1ug/L 31-Oct-2016 19:580.20Benzene 1.0U























Page 6 of 47


Golder AssociatesCity of CamdentonDUP-1

WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-02


ANALYTICAL REPORT





1ug/L 31-Oct-2016 19:580.30o-Xylene 1.0U

1ug/L 31-Oct-2016 19:580.30Styrene 1.0U


1ug/L 31-Oct-2016 19:580.20Toluene 1.0U










Surr: Toluene-d8 1%REC 31-Oct-2016 19:5898.7 75-125



Page 7 of 47



WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-03


ANALYTICAL REPORT





















1ug/L 31-Oct-2016 20:232.0Acetone 2.0U

1ug/L 31-Oct-2016 20:230.20Benzene 1.0U























Page 8 of 47



WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-03


ANALYTICAL REPORT





1ug/L 31-Oct-2016 20:230.30o-Xylene 1.0U

1ug/L 31-Oct-2016 20:230.30Styrene 1.0U


1ug/L 31-Oct-2016 20:230.20Toluene 1.0U














1mg/L 04-Nov-2016 18:100.000400Arsenic 0.00500U

1mg/L 04-Nov-2016 18:100.00190Barium 0.005000.0476

1mg/L 04-Nov-2016 18:100.000200Cadmium 0.00200U

1mg/L 04-Nov-2016 18:100.0340Calcium 0.50067.8


1mg/L 04-Nov-2016 18:100.000600Lead 0.005000.00531



1mg/L 04-Nov-2016 18:100.000200Silver 0.00500U


1mg/L 03-Nov-2016 15:280.0000400Mercury 0.000200U


CaCO3)5.00326




TOTAL ORGANIC CARBON BY SW9060A Method:SW9060 Analyst: KMU1mg/L 06-Nov-2016 17:550.500Organic Carbon, Total 1.00U



Page 9 of 47


Golder AssociatesCity of CamdentonFB-1

WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-04


ANALYTICAL REPORT





















1ug/L 31-Oct-2016 20:482.0Acetone 2.0U

1ug/L 31-Oct-2016 20:480.20Benzene 1.0U








1ug/L 31-Oct-2016 20:48J 0.20Chloroform 1.00.45

1ug/L 31-Oct-2016 20:480.20Chloromethane 1.01.1

1ug/L 31-Oct-2016 20:480.20cis-1,2-Dichloroethene 1.0U













Page 10 of 47


Golder AssociatesCity of CamdentonFB-1

WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-04


ANALYTICAL REPORT





1ug/L 31-Oct-2016 20:480.30o-Xylene 1.0U

1ug/L 31-Oct-2016 20:480.30Styrene 1.0U


1ug/L 31-Oct-2016 20:480.20Toluene 1.0U



1ug/L 31-Oct-2016 20:480.20Trichloroethene 1.0U







Surr: Toluene-d8 1%REC 31-Oct-2016 20:4895.5 75-125



Page 11 of 47



WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-05


ANALYTICAL REPORT





















1ug/L 31-Oct-2016 21:132.0Acetone 2.0U

1ug/L 31-Oct-2016 21:130.20Benzene 1.0U























Page 12 of 47



WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-05


ANALYTICAL REPORT





1ug/L 31-Oct-2016 21:130.30o-Xylene 1.0U

1ug/L 31-Oct-2016 21:130.30Styrene 1.0U


1ug/L 31-Oct-2016 21:130.20Toluene 1.0U














1mg/L 04-Nov-2016 18:130.000400Arsenic 0.00500U

1mg/L 04-Nov-2016 18:130.00190Barium 0.005000.0489

1mg/L 04-Nov-2016 18:130.000200Cadmium 0.00200U

1mg/L 04-Nov-2016 18:130.0340Calcium 0.50068.0


1mg/L 04-Nov-2016 18:13J 0.000600Lead 0.005000.00415



1mg/L 04-Nov-2016 18:130.000200Silver 0.00500U


1mg/L 03-Nov-2016 15:300.0000400Mercury 0.000200U


CaCO3)5.00324




TOTAL ORGANIC CARBON BY SW9060A Method:SW9060 Analyst: KMU1mg/L 06-Nov-2016 18:13J 0.500Organic Carbon, Total 1.000.510



Page 13 of 47


Golder AssociatesCity of CamdentonRB-1

WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-06


ANALYTICAL REPORT




LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: AKP1ug/L 01-Nov-2016 00:340.201,1,1-Trichloroethane 1.0U

1ug/L 01-Nov-2016 00:340.501,1,2,2-Tetrachloroethane 1.0U

1ug/L 01-Nov-2016 00:341.01,1,2-Trichlor-1,2,2-trifluoroethane 1.0U

1ug/L 01-Nov-2016 00:340.301,1,2-Trichloroethane 1.0U

1ug/L 01-Nov-2016 00:340.201,1-Dichloroethane 1.0U

1ug/L 01-Nov-2016 00:340.201,1-Dichloroethene 1.0U

1ug/L 01-Nov-2016 00:340.501,2,4-Trichlorobenzene 1.0U

1ug/L 01-Nov-2016 00:341.01,2-Dibromo-3-chloropropane 1.0U

1ug/L 01-Nov-2016 00:340.201,2-Dibromoethane 1.0U

1ug/L 01-Nov-2016 00:340.501,2-Dichlorobenzene 1.0U


1ug/L 01-Nov-2016 00:340.501,2-Dichloropropane 1.0U



1ug/L 01-Nov-2016 00:340.502-Butanone 2.0U

1ug/L 01-Nov-2016 00:341.02-Hexanone 2.0U

1ug/L 01-Nov-2016 00:340.704-Methyl-2-pentanone 2.0U

1ug/L 01-Nov-2016 00:342.0Acetone 2.0U

1ug/L 01-Nov-2016 00:340.20Benzene 1.0U

1ug/L 01-Nov-2016 00:340.20Bromodichloromethane 1.0U

1ug/L 01-Nov-2016 00:340.40Bromoform 1.0U

1ug/L 01-Nov-2016 00:340.40Bromomethane 1.0U

1ug/L 01-Nov-2016 00:340.60Carbon disulfide 2.0U

1ug/L 01-Nov-2016 00:340.50Carbon tetrachloride 1.0U

1ug/L 01-Nov-2016 00:340.30Chlorobenzene 1.0U

1ug/L 01-Nov-2016 00:340.30Chloroethane 1.0U

1ug/L 01-Nov-2016 00:34J 0.20Chloroform 1.00.37

1ug/L 01-Nov-2016 00:340.20Chloromethane 1.0U

1ug/L 01-Nov-2016 00:340.20cis-1,2-Dichloroethene 1.0U

1ug/L 01-Nov-2016 00:340.10cis-1,3-Dichloropropene 1.0U

1ug/L 01-Nov-2016 00:340.30Cyclohexane 1.0U

1ug/L 01-Nov-2016 00:340.30Dibromochloromethane 1.0U

1ug/L 01-Nov-2016 00:340.30Dichlorodifluoromethane 1.0U

1ug/L 01-Nov-2016 00:340.30Ethylbenzene 1.0U

1ug/L 01-Nov-2016 00:340.30Isopropylbenzene 1.0U

1ug/L 01-Nov-2016 00:340.50m,p-Xylene 2.0U

1ug/L 01-Nov-2016 00:341.0Methyl acetate 1.0U

1ug/L 01-Nov-2016 00:340.20Methyl tert-butyl ether 1.0U

1ug/L 01-Nov-2016 00:340.30Methylcyclohexane 1.0U



Page 14 of 47


Golder AssociatesCity of CamdentonRB-1

WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-06


ANALYTICAL REPORT




LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: AKP1ug/L 01-Nov-2016 00:341.0Methylene chloride 2.0U

1ug/L 01-Nov-2016 00:340.30o-Xylene 1.0U

1ug/L 01-Nov-2016 00:340.30Styrene 1.0U

1ug/L 01-Nov-2016 00:340.30Tetrachloroethene 1.0U

1ug/L 01-Nov-2016 00:340.20Toluene 1.0U

1ug/L 01-Nov-2016 00:340.20trans-1,2-Dichloroethene 1.0U

1ug/L 01-Nov-2016 00:340.20trans-1,3-Dichloropropene 1.0U

1ug/L 01-Nov-2016 00:340.20Trichloroethene 1.0U

1ug/L 01-Nov-2016 00:340.30Trichlorofluoromethane 1.0U

1ug/L 01-Nov-2016 00:340.20Vinyl chloride 1.0U

1ug/L 01-Nov-2016 00:340.50Xylenes, Total 3.0U

Surr: 1,2-Dichloroethane-d4 1%REC 01-Nov-2016 00:3496.3 71-125

Surr: 4-Bromofluorobenzene 1%REC 01-Nov-2016 00:3490.9 70-125

Surr: Dibromofluoromethane 1%REC 01-Nov-2016 00:3475.6 74-125

Surr: Toluene-d8 1%REC 01-Nov-2016 00:3498.7 75-125



Page 15 of 47


Golder AssociatesCity of CamdentonTRIP BLANK

WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-07


ANALYTICAL REPORT




LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: AKP1ug/L 01-Nov-2016 00:090.201,1,1-Trichloroethane 1.0U

1ug/L 01-Nov-2016 00:090.501,1,2,2-Tetrachloroethane 1.0U

1ug/L 01-Nov-2016 00:091.01,1,2-Trichlor-1,2,2-trifluoroethane 1.0U

1ug/L 01-Nov-2016 00:090.301,1,2-Trichloroethane 1.0U


1ug/L 01-Nov-2016 00:090.201,1-Dichloroethene 1.0U

1ug/L 01-Nov-2016 00:090.501,2,4-Trichlorobenzene 1.0U

1ug/L 01-Nov-2016 00:091.01,2-Dibromo-3-chloropropane 1.0U

1ug/L 01-Nov-2016 00:090.201,2-Dibromoethane 1.0U



1ug/L 01-Nov-2016 00:090.501,2-Dichloropropane 1.0U



1ug/L 01-Nov-2016 00:090.502-Butanone 2.0U

1ug/L 01-Nov-2016 00:091.02-Hexanone 2.0U

1ug/L 01-Nov-2016 00:090.704-Methyl-2-pentanone 2.0U

1ug/L 01-Nov-2016 00:092.0Acetone 2.0U

1ug/L 01-Nov-2016 00:090.20Benzene 1.0U

1ug/L 01-Nov-2016 00:090.20Bromodichloromethane 1.0U

1ug/L 01-Nov-2016 00:090.40Bromoform 1.0U

1ug/L 01-Nov-2016 00:090.40Bromomethane 1.0U

1ug/L 01-Nov-2016 00:090.60Carbon disulfide 2.0U

1ug/L 01-Nov-2016 00:090.50Carbon tetrachloride 1.0U

1ug/L 01-Nov-2016 00:090.30Chlorobenzene 1.0U

1ug/L 01-Nov-2016 00:090.30Chloroethane 1.0U

1ug/L 01-Nov-2016 00:090.20Chloroform 1.0U

1ug/L 01-Nov-2016 00:090.20Chloromethane 1.0U

1ug/L 01-Nov-2016 00:090.20cis-1,2-Dichloroethene 1.0U

1ug/L 01-Nov-2016 00:090.10cis-1,3-Dichloropropene 1.0U

1ug/L 01-Nov-2016 00:090.30Cyclohexane 1.0U

1ug/L 01-Nov-2016 00:090.30Dibromochloromethane 1.0U

1ug/L 01-Nov-2016 00:090.30Dichlorodifluoromethane 1.0U

1ug/L 01-Nov-2016 00:090.30Ethylbenzene 1.0U

1ug/L 01-Nov-2016 00:090.30Isopropylbenzene 1.0U

1ug/L 01-Nov-2016 00:090.50m,p-Xylene 2.0U

1ug/L 01-Nov-2016 00:091.0Methyl acetate 1.0U

1ug/L 01-Nov-2016 00:090.20Methyl tert-butyl ether 1.0U

1ug/L 01-Nov-2016 00:090.30Methylcyclohexane 1.0U



Page 16 of 47


Golder AssociatesCity of CamdentonTRIP BLANK

WorkOrder:Lab ID:

Collection Date:

HS16101339HS16101339-07


ANALYTICAL REPORT




LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: AKP1ug/L 01-Nov-2016 00:091.0Methylene chloride 2.0U

1ug/L 01-Nov-2016 00:090.30o-Xylene 1.0U

1ug/L 01-Nov-2016 00:090.30Styrene 1.0U

1ug/L 01-Nov-2016 00:090.30Tetrachloroethene 1.0U

1ug/L 01-Nov-2016 00:090.20Toluene 1.0U

1ug/L 01-Nov-2016 00:090.20trans-1,2-Dichloroethene 1.0U

1ug/L 01-Nov-2016 00:090.20trans-1,3-Dichloropropene 1.0U

1ug/L 01-Nov-2016 00:090.20Trichloroethene 1.0U

1ug/L 01-Nov-2016 00:090.30Trichlorofluoromethane 1.0U

1ug/L 01-Nov-2016 00:090.20Vinyl chloride 1.0U

1ug/L 01-Nov-2016 00:090.50Xylenes, Total 3.0U

Surr: 1,2-Dichloroethane-d4 1%REC 01-Nov-2016 00:0997.5 71-125

Surr: 4-Bromofluorobenzene 1%REC 01-Nov-2016 00:0990.1 70-125

Surr: Dibromofluoromethane 1%REC 01-Nov-2016 00:0978.1 74-125

Surr: Toluene-d8 1%REC 01-Nov-2016 00:0997.6 75-125



Page 17 of 47

WEIGHT LOG

HS16101339City of CamdentonGolder Associates

WorkOrder:Project:Client:

Batch ID: 109425 Method: ICP-MS METALS BY SW6020A 3010APrep:

ContainerSampIDSample Wt/Vol

Final Volume

Prep Factor

HS16101339-01 1 50 50 (mL) 1HS16101339-03 1 50 50 (mL) 1HS16101339-05 1 50 50 (mL) 1

Batch ID: 109499 Method: MERCURY BY SW7470A HG_WPRPrep:

ContainerSampIDSample Wt/Vol

Final Volume

Prep Factor

HS16101339-01 1 40 40 (mL) 1HS16101339-03 1 40 40 (mL) 1HS16101339-05 1 40 40 (mL) 1


Page 18 of 47

Client:City of CamdentonGolder Associates

WorkOrder:Project:

HS16101339DATES REPORT

Collection Date Prep Date Analysis DateClient Samp IDSample ID TCLP Date DF

Batch ID 109425 Test Name : ICP-MS METALS BY SW6020A Matrix: Water

01 Nov 2016 10:00 04 Nov 2016 18:07HS16101339-01 25 Oct 2016 16:30 1MWPT-1



Batch ID 109499 Test Name : MERCURY BY SW7470A Matrix: Water





31 Oct 2016 19:33HS16101339-01 25 Oct 2016 16:30 1MWPT-1

31 Oct 2016 19:58HS16101339-02 25 Oct 2016 00:00 1DUP-1

31 Oct 2016 20:23HS16101339-03 27 Oct 2016 16:00 1MWPT-3

31 Oct 2016 20:48HS16101339-04 27 Oct 2016 16:00 1FB-1

31 Oct 2016 21:13HS16101339-05 28 Oct 2016 11:30 1MWPT-4


01 Nov 2016 00:34HS16101339-06 28 Oct 2016 13:05 1RB-1

01 Nov 2016 00:09HS16101339-07 25 Oct 2016 00:00 1TRIP BLANK

Batch ID R284076 Test Name : ALKALINITY BY SM2320B Matrix: Water

02 Nov 2016 11:07HS16101339-01 25 Oct 2016 16:30 1MWPT-1

02 Nov 2016 11:14HS16101339-03 27 Oct 2016 16:00 1MWPT-3

02 Nov 2016 11:36HS16101339-05 28 Oct 2016 11:30 1MWPT-4

Batch ID R284304 Test Name : TOTAL ORGANIC CARBON BY SW9060A Matrix: Water

06 Nov 2016 17:23HS16101339-01 25 Oct 2016 16:30 1MWPT-1

06 Nov 2016 17:55HS16101339-03 27 Oct 2016 16:00 1MWPT-3

06 Nov 2016 18:13HS16101339-05 28 Oct 2016 11:30 1MWPT-4

Batch ID R284356 Test Name : HARDNESS, TOTAL AS CACO3 BY SM2340B Matrix: Water

07 Nov 2016 15:30HS16101339-01 25 Oct 2016 16:30 1MWPT-1

07 Nov 2016 15:30HS16101339-03 27 Oct 2016 16:00 1MWPT-3

07 Nov 2016 15:30HS16101339-05 28 Oct 2016 11:30 1MWPT-4


Page 19 of 47

Client:Project:



QC BATCH REPORT

Batch ID: 109425 Instrument: ICPMS05 Method: SW6020

Sample ID: MBLK-109425 Units: mg/L Analysis Date: 04-Nov-2016 12:13

Run ID: ICPMS05_284197 SeqNo: 3881608 PrepDate: 01-Nov-2016 DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Arsenic U 0.00500

Barium U 0.00500

Cadmium U 0.00200

Calcium U 0.500

Chromium U 0.00500

Lead U 0.00500

Magnesium U 0.200

Selenium U 0.00500

Silver U 0.00500

Sample ID: LCS-109425 Units: mg/L Analysis Date: 04-Nov-2016 12:16



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Arsenic 0.04997 0.05 0 99.9 80 - 1200.00500

Barium 0.05018 0.05 0 100 80 - 1200.00500

Cadmium 0.05127 0.05 0 103 80 - 1200.00200

Calcium 5.215 5 0 104 80 - 1200.500

Chromium 0.04782 0.05 0 95.6 80 - 1200.00500

Lead 0.04895 0.05 0 97.9 80 - 1200.00500

Magnesium 5.512 5 0 110 80 - 1200.200

Selenium 0.05048 0.05 0 101 80 - 1200.00500

Silver 0.04885 0.05 0 97.7 80 - 1200.00500

ALS Group USA, Corp Date: 07-Nov-16


Page 20 of 47

Client:Project:



QC BATCH REPORT


Sample ID: HS16101322-10MS Units: mg/L Analysis Date: 04-Nov-2016 12:25



Value %RECControl

LimitRPD Ref


MS

Client ID:

Arsenic 0.05765 0.05 0.01165 92.0 80 - 1200.00500

Barium 0.2219 0.05 0.1563 131 80 - 120 S 0.00500

Cadmium 0.04517 0.05 0.000343 89.7 80 - 1200.00200

Calcium 130.7 5 120 215 80 - 120 SO 0.500

Chromium 0.08394 0.05 0.02858 111 80 - 1200.00500

Lead 0.05531 0.05 0.01085 88.9 80 - 1200.00500

Magnesium 17.46 5 12.78 93.6 80 - 1200.200

Selenium 0.04625 0.05 0 92.5 80 - 1200.00500

Silver 0.04424 0.05 0.000243 88.0 80 - 1200.00500

Sample ID: HS16101322-10MSD Units: mg/L Analysis Date: 04-Nov-2016 12:28



Value %RECControl

LimitRPD Ref


MSD

Client ID:

Arsenic 0.05727 0.05 0.01165 91.2 80 - 120 0.05765 0.668 200.00500

Barium 0.2265 0.05 0.1563 140 80 - 120 0.2219 2.07 20 S 0.00500

Cadmium 0.04618 0.05 0.000343 91.7 80 - 120 0.04517 2.2 200.00200

Calcium 131.1 5 120 223 80 - 120 130.7 0.312 20 SO 0.500

Chromium 0.08595 0.05 0.02858 115 80 - 120 0.08394 2.36 200.00500

Lead 0.05525 0.05 0.01085 88.8 80 - 120 0.05531 0.0977 200.00500

Magnesium 18.05 5 12.78 105 80 - 120 17.46 3.32 200.200

Selenium 0.04575 0.05 0 91.5 80 - 120 0.04625 1.08 200.00500

Silver 0.04361 0.05 0.000243 86.7 80 - 120 0.04424 1.44 200.00500



Page 21 of 47

Client:Project:



QC BATCH REPORT


Sample ID: HS16101322-10BS Units: mg/L Analysis Date: 04-Nov-2016 12:31



Value %RECControl

LimitRPD Ref


PDS

Client ID:

Arsenic 0.104 0.1 0.01165 92.4 75 - 1250.00500

Barium 0.2504 0.1 0.1563 94.1 75 - 1250.00500

Cadmium 0.09216 0.1 0.000343 91.8 75 - 1250.00200

Calcium 129.9 10 120 99.8 75 - 125 O 0.500

Chromium 0.1112 0.1 0.02858 82.6 75 - 1250.00500

Lead 0.1017 0.1 0.01085 90.8 75 - 1250.00500

Magnesium 21.52 10 12.78 87.4 75 - 1250.200

Selenium 0.09148 0.1 0 91.5 75 - 1250.00500

Silver 0.08748 0.1 0.000243 87.2 75 - 1250.00500

Sample ID: HS16101322-10 DIL SX Units: mg/L Analysis Date: 04-Nov-2016 12:22



Value %RECControl

LimitRPD Ref

Value %D%D Limit Qual

SD

Client ID:

Arsenic 0.01162 0.01165 0 10 J 0.0250

Barium 0.1571 0.1563 0.503 100.0250

Cadmium U 0.000343 0 100.0100

Calcium 119.9 120 0.058 102.50

Chromium 0.02974 0.02858 4.04 100.0250

Lead 0.01143 0.01085 0 10 J 0.0250

Selenium U 0 0 100.0250

Silver U 0.000243 0 100.0250

Sample ID: HS16101322-10 DIL SX Units: mg/L Analysis Date: 04-Nov-2016 16:58



Value %RECControl

LimitRPD Ref

Value %D%D Limit Qual

SD

Client ID:

Magnesium 13.99 12.63 10.7 10 R 1.00

The following samples were analyzed in this batch: HS16101339-01 HS16101339-03 HS16101339-05



Page 22 of 47

Client:Project:



QC BATCH REPORT

Batch ID: 109499 Instrument: HG03 Method: SW7470

Sample ID: MBLK-109499 Units: mg/L Analysis Date: 03-Nov-2016 15:16

Run ID: HG03_284160 SeqNo: 3880458 PrepDate: 03-Nov-2016 DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Mercury U 0.000200

Sample ID: LCS-109499 Units: mg/L Analysis Date: 03-Nov-2016 15:17



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Mercury 0.00494 0.005 0 98.8 80 - 1240.000200




Value %RECControl

LimitRPD Ref


MS

Client ID:

Mercury 0.00115 0.005 -0.000011 23.2 80 - 124 S 0.000200




Value %RECControl

LimitRPD Ref


MS

Client ID:

Mercury 0.00499 0.005 -0.000004 99.9 80 - 1240.000200




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Mercury 0.00118 0.005 -0.000011 23.8 80 - 124 0.00115 2.58 20 S 0.000200




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Mercury 0.00492 0.005 -0.000004 98.5 80 - 124 0.00499 1.41 200.000200




Page 23 of 47

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:















2-Butanone U 2.0

2-Hexanone U 2.0


Acetone U 2.0

Benzene U 1.0


Bromoform U 1.0

Bromomethane U 1.0



Chlorobenzene U 1.0

Chloroethane U 1.0

Chloroform U 1.0

Chloromethane U 1.0



Cyclohexane U 1.0



Ethylbenzene U 1.0



Page 24 of 47

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:


m,p-Xylene U 2.0





o-Xylene U 1.0

Styrene U 1.0


Toluene U 1.0










49.8 50 0 99.6 75 - 1251.0Surr: Toluene-d8



Page 25 of 47

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:


1,1,2,2-Tetrachloroethane 40 50 0 80.0 74 - 1231.0

1,1,2-Trichlor-1,2,2-trifluoroethane 49.81 50 0 99.6 70 - 1301.0


1,1-Dichloroethane 51.01 50 0 102 76 - 1201.0

1,1-Dichloroethene 53.57 50 0 107 75 - 1301.0



1,2-Dibromoethane 53.8 50 0 108 80 - 1211.0


1,2-Dichloroethane 49.8 50 0 99.6 76 - 1201.0




2-Butanone 97.1 100 0 97.1 60 - 1402.0

2-Hexanone 86.04 100 0 86.0 60 - 1312.0


Acetone 93.08 100 0 93.1 60 - 1402.0

Benzene 52.91 50 0 106 75 - 1221.0


Bromoform 55.35 50 0 111 70 - 1301.0

Bromomethane 49.8 50 0 99.6 60 - 1401.0



Chlorobenzene 49.58 50 0 99.2 80 - 1201.0

Chloroethane 46.57 50 0 93.1 70 - 1301.0

Chloroform 50.25 50 0 100 70 - 1301.0

Chloromethane 45.39 50 0 90.8 65 - 1301.0



Cyclohexane 46.7 50 0 93.4 70 - 1301.0


Dichlorodifluoromethane 48.1 50 0 96.2 60 - 1401.0

Ethylbenzene 52.77 50 0 106 80 - 1201.0



Page 26 of 47

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:


m,p-Xylene 102.6 100 0 103 80 - 1202.0

Methyl acetate 45.94 50 0 91.9 76 - 1221.0


Methylcyclohexane 47.3 50 0 94.6 61 - 1581.0


o-Xylene 53.09 50 0 106 80 - 1201.0

Styrene 56.63 50 0 113 78 - 1221.0


Toluene 51.68 50 0 103 75 - 1211.0





Vinyl chloride 49.09 50 0 98.2 70 - 1351.0

Xylenes, Total 155.6 150 0 104 79 - 1243.0




49.66 50 0 99.3 75 - 1251.0Surr: Toluene-d8



Page 27 of 47

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID:

1,1,1-Trichloroethane 565.2 500 0 113 75 - 13010

1,1,2,2-Tetrachloroethane 366.9 500 0 73.4 74 - 123 S 10

1,1,2-Trichlor-1,2,2-trifluoroethane 546.2 500 25.83 104 70 - 13010

1,1,2-Trichloroethane 471.5 500 0 94.3 80 - 12010

1,1-Dichloroethane 495.7 500 0 99.1 76 - 12010

1,1-Dichloroethene 545.9 500 0 109 75 - 13010

1,2,4-Trichlorobenzene 420 500 0 84.0 75 - 12610

1,2-Dibromo-3-chloropropane 380.4 500 0 76.1 65 - 12510

1,2-Dibromoethane 497.8 500 0 99.6 80 - 12110

1,2-Dichlorobenzene 443.4 500 0 88.7 80 - 12010

1,2-Dichloroethane 481.5 500 0 96.3 76 - 12010

1,2-Dichloropropane 513.1 500 0 103 80 - 12010



2-Butanone 872.4 1000 0 87.2 60 - 14020

2-Hexanone 706.2 1000 0 70.6 60 - 13120

4-Methyl-2-pentanone 786.3 1000 0 78.6 60 - 13520

Acetone 852.7 1000 0 85.3 60 - 14020

Benzene 523.6 500 0 105 75 - 12210

Bromodichloromethane 522.6 500 0 105 75 - 12510

Bromoform 505.5 500 0 101 70 - 13010

Bromomethane 475.7 500 0 95.1 60 - 14010

Carbon disulfide 1056 1000 0 106 70 - 13020

Carbon tetrachloride 543.8 500 0 109 79 - 12010

Chlorobenzene 477.8 500 0 95.6 80 - 12010

Chloroethane 454 500 0 90.8 70 - 13010

Chloroform 503 500 0 101 70 - 13010

Chloromethane 412.1 500 0 82.4 65 - 13010

cis-1,2-Dichloroethene 521.1 500 6.033 103 75 - 12510

cis-1,3-Dichloropropene 494.6 500 0 98.9 79 - 12510

Cyclohexane 482.2 500 0 96.4 70 - 13010

Dibromochloromethane 505 500 0 101 70 - 13010

Dichlorodifluoromethane 363 500 0 72.6 60 - 14010

Ethylbenzene 526.9 500 0 105 80 - 12010



Page 28 of 47

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID:

Isopropylbenzene 556.3 500 0 111 75 - 13010

m,p-Xylene 1034 1000 0 103 80 - 12020

Methyl acetate 416 500 0 83.2 76 - 12210

Methyl tert-butyl ether 548.2 500 48.09 100 70 - 13010

Methylcyclohexane 490.1 500 0 98.0 61 - 15810

Methylene chloride 504.7 500 0 101 65 - 13320

o-Xylene 517.3 500 0 103 80 - 12010

Styrene 549.9 500 0 110 78 - 12210

Tetrachloroethene 563.5 500 0 113 75 - 13010

Toluene 515.6 500 0 103 75 - 12110

trans-1,2-Dichloroethene 529 500 0 106 75 - 12510

trans-1,3-Dichloropropene 498.8 500 0 99.8 76 - 12510

Trichloroethene 1183 500 638.3 109 71 - 12510

Trichlorofluoromethane 564.8 500 0 113 67 - 13210

Vinyl chloride 473.2 500 0 94.6 70 - 13510

Xylenes, Total 1551 1500 0 103 80 - 12430

455.7 500 0 91.1 71 - 12510Surr: 1,2-Dichloroethane-d4

487.2 500 0 97.4 70 - 12510Surr: 4-Bromofluorobenzene

493.1 500 0 98.6 74 - 12510Surr: Dibromofluoromethane

488.2 500 0 97.6 75 - 12510Surr: Toluene-d8



Page 29 of 47

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID:

1,1,1-Trichloroethane 585.9 500 0 117 75 - 130 565.2 3.6 2010

1,1,2,2-Tetrachloroethane 397.5 500 0 79.5 74 - 123 366.9 8 2010

1,1,2-Trichlor-1,2,2-trifluoroethane 569.4 500 25.83 109 70 - 130 546.2 4.15 2010

1,1,2-Trichloroethane 489.1 500 0 97.8 80 - 120 471.5 3.65 2010

1,1-Dichloroethane 515.3 500 0 103 76 - 120 495.7 3.89 2010

1,1-Dichloroethene 569.1 500 0 114 75 - 130 545.9 4.17 2010

1,2,4-Trichlorobenzene 487.3 500 0 97.5 75 - 126 420 14.8 2010

1,2-Dibromo-3-chloropropane 446 500 0 89.2 65 - 125 380.4 15.9 2010

1,2-Dibromoethane 527.1 500 0 105 80 - 121 497.8 5.72 2010

1,2-Dichlorobenzene 474.5 500 0 94.9 80 - 120 443.4 6.79 2010

1,2-Dichloroethane 484.4 500 0 96.9 76 - 120 481.5 0.596 2010

1,2-Dichloropropane 521.2 500 0 104 80 - 120 513.1 1.57 2010

1,3-Dichlorobenzene 513.2 500 0 103 80 - 120 472.4 8.28 2010

1,4-Dichlorobenzene 493.4 500 0 98.7 80 - 120 449.8 9.25 2010

2-Butanone 938.4 1000 0 93.8 60 - 140 872.4 7.29 2020

2-Hexanone 844.3 1000 0 84.4 60 - 131 706.2 17.8 2020

4-Methyl-2-pentanone 840.9 1000 0 84.1 60 - 135 786.3 6.71 2020

Acetone 923.9 1000 0 92.4 60 - 140 852.7 8.02 2020

Benzene 533.5 500 0 107 75 - 122 523.6 1.87 2010

Bromodichloromethane 536.7 500 0 107 75 - 125 522.6 2.67 2010

Bromoform 534.8 500 0 107 70 - 130 505.5 5.64 2010

Bromomethane 487.7 500 0 97.5 60 - 140 475.7 2.5 2010

Carbon disulfide 1086 1000 0 109 70 - 130 1056 2.81 2020

Carbon tetrachloride 555.1 500 0 111 75 - 125 543.8 2.06 2010

Chlorobenzene 502.2 500 0 100 80 - 120 477.8 4.98 2010

Chloroethane 469.9 500 0 94.0 70 - 130 454 3.45 2010

Chloroform 507 500 0 101 70 - 130 503 0.793 2010

Chloromethane 427.6 500 0 85.5 65 - 130 412.1 3.69 2010

cis-1,2-Dichloroethene 538.7 500 6.033 107 75 - 125 521.1 3.33 2010

cis-1,3-Dichloropropene 508.9 500 0 102 79 - 125 494.6 2.84 2010

Cyclohexane 496.6 500 0 99.3 70 - 130 482.2 2.93 2010

Dibromochloromethane 522.6 500 0 105 70 - 130 505 3.41 2010

Dichlorodifluoromethane 354.7 500 0 70.9 60 - 140 363 2.32 2010

Ethylbenzene 547.7 500 0 110 80 - 120 526.9 3.88 2010



Page 30 of 47

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID:

Isopropylbenzene 580.7 500 0 116 75 - 130 556.3 4.28 2010

m,p-Xylene 1083 1000 0 108 80 - 120 1034 4.66 2020

Methyl acetate 464.5 500 0 92.9 76 - 122 416 11 2010

Methyl tert-butyl ether 582.3 500 48.09 107 70 - 130 548.2 6.03 2010

Methylcyclohexane 501.8 500 0 100 61 - 158 490.1 2.34 2010

Methylene chloride 515.4 500 0 103 65 - 133 504.7 2.11 2020

o-Xylene 536 500 0 107 80 - 120 517.3 3.54 2010

Styrene 575 500 0 115 78 - 122 549.9 4.46 2010

Tetrachloroethene 591.2 500 0 118 75 - 130 563.5 4.8 2010

Toluene 531 500 0 106 75 - 121 515.6 2.94 2010

trans-1,2-Dichloroethene 549.1 500 0 110 75 - 125 529 3.74 2010

trans-1,3-Dichloropropene 517.7 500 0 104 76 - 125 498.8 3.71 2010

Trichloroethene 1190 500 638.3 110 71 - 125 1183 0.566 2010

Trichlorofluoromethane 573.6 500 0 115 67 - 132 564.8 1.55 2010

Vinyl chloride 495.6 500 0 99.1 70 - 135 473.2 4.62 2010

Xylenes, Total 1619 1500 0 108 80 - 124 1551 4.29 2030

462.1 500 0 92.4 71 - 125 455.7 1.39 2010Surr: 1,2-Dichloroethane-d4

485.3 500 0 97.1 70 - 125 487.2 0.395 2010Surr: 4-Bromofluorobenzene

494.1 500 0 98.8 74 - 125 493.1 0.199 2010Surr: Dibromofluoromethane

502.7 500 0 101 75 - 125 488.2 2.93 2010Surr: Toluene-d8

The following samples were analyzed in this batch: HS16101339-01 HS16101339-02 HS16101339-03 HS16101339-04 HS16101339-05



Page 31 of 47

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:















2-Butanone U 2.0

2-Hexanone U 2.0


Acetone U 2.0

Benzene U 1.0


Bromoform U 1.0

Bromomethane U 1.0



Chlorobenzene U 1.0

Chloroethane U 1.0

Chloroform U 1.0

Chloromethane U 1.0



Cyclohexane U 1.0



Ethylbenzene U 1.0



Page 32 of 47

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:


m,p-Xylene U 2.0





o-Xylene U 1.0

Styrene U 1.0


Toluene U 1.0










49.76 50 0 99.5 75 - 1251.0Surr: Toluene-d8



Page 33 of 47

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:





1,1-Dichloroethane 53.13 50 0 106 76 - 1201.0

1,1-Dichloroethene 56.49 50 0 113 75 - 1301.0



1,2-Dibromoethane 54.61 50 0 109 80 - 1211.0


1,2-Dichloroethane 52.41 50 0 105 76 - 1201.0




2-Butanone 104 100 0 104 60 - 1402.0

2-Hexanone 91.56 100 0 91.6 60 - 1312.0


Acetone 101.8 100 0 102 60 - 1402.0

Benzene 54.38 50 0 109 75 - 1221.0


Bromoform 56.2 50 0 112 70 - 1301.0

Bromomethane 52 50 0 104 60 - 1401.0



Chlorobenzene 49.31 50 0 98.6 80 - 1201.0

Chloroethane 49.1 50 0 98.2 70 - 1301.0

Chloroform 51.5 50 0 103 70 - 1301.0

Chloromethane 48.47 50 0 96.9 65 - 1301.0



Cyclohexane 50.08 50 0 100 70 - 1301.0



Ethylbenzene 52.59 50 0 105 80 - 1201.0



Page 34 of 47

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:


m,p-Xylene 103.8 100 0 104 80 - 1202.0

Methyl acetate 50.72 50 0 101 76 - 1221.0


Methylcyclohexane 50.2 50 0 100 61 - 1581.0


o-Xylene 53.15 50 0 106 80 - 1201.0

Styrene 56.88 50 0 114 78 - 1221.0


Toluene 51.58 50 0 103 75 - 1211.0





Vinyl chloride 52.36 50 0 105 70 - 1351.0

Xylenes, Total 157 150 0 105 79 - 1243.0



50.27 50 0 101 74 - 1251.0Surr: Dibromofluoromethane

49.08 50 0 98.2 75 - 1251.0Surr: Toluene-d8



Page 35 of 47

Client:Project:



QC BATCH REPORT


Sample ID: HS16101336-02MS Units: ug/L Analysis Date: 01-Nov-2016 01:49



Value %RECControl

LimitRPD Ref


MS

Client ID:





1,1-Dichloroethane 54.2 50 0 108 76 - 1201.0

1,1-Dichloroethene 58.54 50 0 117 75 - 1301.0



1,2-Dibromoethane 52.62 50 0 105 80 - 1211.0


1,2-Dichloroethane 48.61 50 0 97.2 76 - 1201.0




2-Butanone 97.16 100 0 97.2 60 - 1402.0

2-Hexanone 81.47 100 0 81.5 60 - 1312.0


Acetone 89.4 100 0 89.4 60 - 1402.0

Benzene 55.4 50 0 111 75 - 1221.0


Bromoform 53.85 50 0 108 70 - 1301.0

Bromomethane 49.15 50 0 98.3 60 - 1401.0



Chlorobenzene 49.73 50 0 99.5 80 - 1201.0

Chloroethane 48.54 50 0 97.1 70 - 1301.0

Chloroform 53.64 50 0 107 70 - 1301.0

Chloromethane 44.25 50 0 88.5 65 - 1301.0



Cyclohexane 51.88 50 0 104 70 - 1301.0


Dichlorodifluoromethane 37.84 50 0 75.7 60 - 1401.0

Ethylbenzene 54.77 50 0 110 80 - 1201.0



Page 36 of 47

Client:Project:



QC BATCH REPORT


Sample ID: HS16101336-02MS Units: ug/L Analysis Date: 01-Nov-2016 01:49



Value %RECControl

LimitRPD Ref


MS

Client ID:


m,p-Xylene 105.9 100 0 106 80 - 1202.0

Methyl acetate 47.52 50 0 95.0 76 - 1221.0


Methylcyclohexane 49.79 50 0 99.6 61 - 1581.0


o-Xylene 54.34 50 0 109 80 - 1201.0

Styrene 56.77 50 0 114 78 - 1221.0


Toluene 53.01 50 0 106 75 - 1211.0


trans-1,3-Dichloropropene 51 50 0 102 76 - 1251.0



Vinyl chloride 49.94 50 0 99.9 70 - 1351.0

Xylenes, Total 160.2 150 0 107 80 - 1243.0



50.72 50 0 101 74 - 1251.0Surr: Dibromofluoromethane

49.02 50 0 98.0 75 - 1251.0Surr: Toluene-d8



Page 37 of 47

Client:Project:



QC BATCH REPORT


Sample ID: HS16101336-02MSD Units: ug/L Analysis Date: 01-Nov-2016 02:14



Value %RECControl

LimitRPD Ref


MSD

Client ID:


1,1,2,2-Tetrachloroethane 39.7 50 0 79.4 74 - 123 37.88 4.68 201.0

1,1,2-Trichlor-1,2,2-trifluoroethane 56.06 50 0 112 70 - 130 56.8 1.3 201.0


1,1-Dichloroethane 54.35 50 0 109 76 - 120 54.2 0.279 201.0

1,1-Dichloroethene 60.27 50 0 121 75 - 130 58.54 2.91 201.0

1,2,4-Trichlorobenzene 49.66 50 0 99.3 75 - 126 44.08 11.9 201.0

1,2-Dibromo-3-chloropropane 46.07 50 0 92.1 65 - 125 39.97 14.2 201.0

1,2-Dibromoethane 54.62 50 0 109 80 - 121 52.62 3.73 201.0


1,2-Dichloroethane 51.07 50 0 102 76 - 120 48.61 4.93 201.0

1,2-Dichloropropane 55.6 50 0 111 80 - 120 53.7 3.48 201.0

1,3-Dichlorobenzene 51.56 50 0 103 80 - 120 48.96 5.18 201.0


2-Butanone 101.9 100 0 102 60 - 140 97.16 4.76 202.0

2-Hexanone 93.18 100 0 93.2 60 - 131 81.47 13.4 202.0

4-Methyl-2-pentanone 87.98 100 0 88.0 60 - 135 85.92 2.37 202.0

Acetone 92.82 100 0 92.8 60 - 140 89.4 3.75 202.0

Benzene 57.37 50 0 115 75 - 122 55.4 3.51 201.0

Bromodichloromethane 56.08 50 0 112 75 - 125 54.54 2.79 201.0

Bromoform 55.59 50 0 111 70 - 130 53.85 3.18 201.0

Bromomethane 51.24 50 0 102 60 - 140 49.15 4.16 201.0

Carbon disulfide 113.3 100 0 113 70 - 130 112.4 0.811 202.0

Carbon tetrachloride 58.39 50 0 117 75 - 125 56.63 3.06 201.0

Chlorobenzene 50.59 50 0 101 80 - 120 49.73 1.72 201.0

Chloroethane 49.76 50 0 99.5 70 - 130 48.54 2.48 201.0

Chloroform 53.68 50 0 107 70 - 130 53.64 0.0751 201.0

Chloromethane 45.1 50 0 90.2 65 - 130 44.25 1.91 201.0

cis-1,2-Dichloroethene 57.17 50 0 114 75 - 125 55.52 2.92 201.0

cis-1,3-Dichloropropene 53.01 50 0 106 79 - 125 50.21 5.42 201.0

Cyclohexane 52.01 50 0 104 70 - 130 51.88 0.25 201.0

Dibromochloromethane 53.7 50 0 107 70 - 130 52.67 1.93 201.0

Dichlorodifluoromethane 37.03 50 0 74.1 60 - 140 37.84 2.17 201.0

Ethylbenzene 55.17 50 0 110 80 - 120 54.77 0.729 201.0



Page 38 of 47

Client:Project:



QC BATCH REPORT


Sample ID: HS16101336-02MSD Units: ug/L Analysis Date: 01-Nov-2016 02:14



Value %RECControl

LimitRPD Ref


MSD

Client ID:

Isopropylbenzene 59.68 50 0 119 75 - 130 57.6 3.54 201.0

m,p-Xylene 109.3 100 0 109 80 - 120 105.9 3.21 202.0

Methyl acetate 47.28 50 0 94.6 76 - 122 47.52 0.498 201.0

Methyl tert-butyl ether 56.47 50 0 113 70 - 130 53.98 4.51 201.0

Methylcyclohexane 50.47 50 0 101 61 - 158 49.79 1.35 201.0

Methylene chloride 53.4 50 0 107 65 - 133 54.46 1.97 202.0

o-Xylene 55.67 50 0 111 80 - 120 54.34 2.41 201.0

Styrene 59 50 0 118 78 - 122 56.77 3.85 201.0

Tetrachloroethene 59.82 50 0 120 75 - 130 58.23 2.7 201.0

Toluene 54.42 50 0 109 75 - 121 53.01 2.64 201.0

trans-1,2-Dichloroethene 57.52 50 0 115 75 - 125 56.88 1.11 201.0

trans-1,3-Dichloropropene 52.75 50 0 106 76 - 125 51 3.39 201.0

Trichloroethene 61.07 50 0 122 71 - 125 57.39 6.22 201.0

Trichlorofluoromethane 60.04 50 0 120 67 - 132 59.59 0.76 201.0

Vinyl chloride 51.83 50 0 104 70 - 135 49.94 3.7 201.0

Xylenes, Total 165 150 0 110 80 - 124 160.2 2.94 203.0

45.9 50 0 91.8 71 - 125 45.58 0.702 201.0Surr: 1,2-Dichloroethane-d4

48.26 50 0 96.5 70 - 125 48.21 0.0971 201.0Surr: 4-Bromofluorobenzene

49.26 50 0 98.5 74 - 125 50.72 2.92 201.0Surr: Dibromofluoromethane

49.45 50 0 98.9 75 - 125 49.02 0.884 201.0Surr: Toluene-d8

The following samples were analyzed in this batch: HS16101339-06 HS16101339-07



Page 39 of 47

Client:Project:



QC BATCH REPORT

Batch ID: R284076 Instrument: ManTech01 Method: SM2320B

Sample ID: WBLKW1-161102 Units: mg/L Analysis Date: 02-Nov-2016 10:16

Run ID: ManTech01_284076 SeqNo: 3878729 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Alkalinity, Bicarbonate (As CaCO3) U 5.00

Alkalinity, Carbonate (As CaCO3) U 5.00

Alkalinity, Hydroxide (As CaCO3) U 5.00

Alkalinity, Total (As CaCO3) U 5.00

Sample ID: LCS-ALK1-161102 Units: mg/L Analysis Date: 02-Nov-2016 10:25



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Alkalinity, Carbonate (As CaCO3) 1030 1000 0 103 80 - 1205.00

Alkalinity, Total (As CaCO3) 1056 1000 0 106 80 - 1205.00

Sample ID: LCSD-ALK1-161102 Units: mg/L Analysis Date: 02-Nov-2016 10:34



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Alkalinity, Carbonate (As CaCO3) 1021 1000 0 102 80 - 120 1030 0.911 205.00

Alkalinity, Total (As CaCO3) 1048 1000 0 105 80 - 120 1056 0.729 205.00

Sample ID: HS16101161-01DUP Units: mg/L Analysis Date: 02-Nov-2016 10:49



Value %RECControl

LimitRPD Ref


DUP

Client ID:

Alkalinity, Bicarbonate (As CaCO3) 108.8 110.8 1.77 205.00

Alkalinity, Carbonate (As CaCO3) U 0 0 205.00

Alkalinity, Hydroxide (As CaCO3) U 0 0 205.00

Alkalinity, Total (As CaCO3) 108.8 110.8 1.77 205.00




Page 40 of 47

Client:Project:



QC BATCH REPORT

Batch ID: R284304 Instrument: TOC_02 Method: SW9060

Sample ID: WBLKW1-110616 Units: mg/L Analysis Date: 06-Nov-2016 16:35

Run ID: TOC_02_284304 SeqNo: 3883060 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Organic Carbon, Total U 1.00

Sample ID: WLCSW1-110616 Units: mg/L Analysis Date: 06-Nov-2016 16:52



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Organic Carbon, Total 9.639 10 0 96.4 80 - 1201.00

Sample ID: WLCSDW1-110616 Units: mg/L Analysis Date: 06-Nov-2016 17:07



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Organic Carbon, Total 9.613 10 0 96.1 80 - 120 9.639 0.27 201.00




Value %RECControl

LimitRPD Ref


MS

Client ID: MWPT-1

Organic Carbon, Total 9.797 10 0.449 93.5 80 - 1201.00




Page 41 of 47

QUALIFIERS, ACRONYMS, UNITS

Client:Project:WorkOrder:

Golder AssociatesCity of CamdentonHS16101339

Qualifier Description* Value exceeds Regulatory Limit

a Not accredited

B Analyte detected in the associated Method Blank above the Reporting Limit

E Value above quantitation range

H Analyzed outside of Holding Time

J Analyte detected below quantitation limit

M Manually integrated, see raw data for justification

n Not offered for accreditation

ND Not Detected at the Reporting Limit

O Sample amount is > 4 times amount spiked

P Dual Column results percent difference > 40%

R RPD above laboratory control limit

S Spike Recovery outside laboratory control limits

U Analyzed but not detected above the MDL/SDL

Acronym DescriptionDCS Detectability Check Study

DUP Method Duplicate

LCS Laboratory Control Sample

LCSD Laboratory Control Sample Duplicate

MBLK Method Blank

MDL Method Detection Limit

MQL Method Quantitation Limit

MS Matrix Spike

MSD Matrix Spike Duplicate

PDS Post Digestion Spike

PQL Practical Quantitaion Limit

SD Serial Dilution

SDL Sample Detection Limit

TRRP Texas Risk Reduction Program

Unit Reported Descriptionµg/L Micrograms per Liter


Page 42 of 47

CERTIFICATIONS,ACCREDITATIONS & LICENSES

Agency Number Expire Date

Arkansas 16-022-1 27-Mar-2017

California 2919 2016-2018 31-Jul-2018

Illinois 003872 09-May-2017

Kansas E-10352 2016-2017 31-Jul-2017

Kentucky 96 2016-2017 30-Apr-2017

Louisiana 03087 2016-2017 30-Jun-2017

North Carolina 624 - 2016 31-Dec-2016

North Dakota R193 2016-2017 30-Apr-2017

Oklahoma 2016-122 31-Aug-2017

Texas TX104704231-16-17 30-Apr-2017


Page 43 of 47


Work Order: HS16101339Project: City of Camdenton SAMPLE TRACKING

Lab Samp ID Client Sample ID Action Date Person New Location

HS16101339-01 MWPT-1 Out 11/1/2016 3:34:37 PM PVL METPREP



HS16101339-01 MWPT-1 Return 11/1/2016 3:35:00 PM PVL 19A



HS16101339-01 MWPT-1 Out 11/3/2016 9:55:43 AM JCJ METPREP



HS16101339-01 MWPT-1 Return 11/3/2016 9:55:57 AM JCJ 19A




Page 44 of 47

PMG

29-Oct-2016 09:30Date/Time Received:

HS16101339

Golder St Louis

Work Order:

Client Name:

Sample Receipt Checklist

Received by:

Shipping container/cooler in good condition?

Custody seals intact on shipping container/cooler?

Custody seals intact on sample bottles?

Chain of custody present?

Chain of custody signed when relinquished and received?

Chain of custody agrees with sample labels?

Samples in proper container/bottle?

Sample containers intact?

Sufficient sample volume for indicated test?

All samples received within holding time?

Container/Temp Blank temperature in compliance?

Temperature(s)/Thermometer(s):

Cooler(s)/Kit(s):

Date/Time sample(s) sent to storage:

Water - VOA vials have zero headspace?

Water - pH acceptable upon receipt?

pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.0/2.7 uc/c 112483310/29/2016 01:30pm

Yes No No VOA vials submitted

Yes No N/A

Yes No N/A

Checklist completed by: Cesar A. LiraDateeSignatureDateeSignature

31-Oct-201629-Oct-2016

FedExWater Carrier name:Matrices:

Reviewed by: Dane J. Wacasey

Client Contacted: Date Contacted: Person Contacted:

Contacted By: Regarding:

Comments:

Corrective Action:

Yes

NoYesTX1005 solids received in hermetically sealed vials? N/A


Page 45 of 47

APPENDIX B GROUNDWATER MONITORING … Lagoon/20170810... · GROUNDWATER MONITORING FORMS &...

Documents

Transcript of APPENDIX B GROUNDWATER MONITORING … Lagoon/20170810... · GROUNDWATER MONITORING FORMS &...