60467219-Ropaque-HP-1096
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Transcript of 60467219-Ropaque-HP-1096
ROPAQUE® HP-1096 The All-Purpose Pigment
Table of Contents
Ropaque® HP-1096 opaque polymer is a non-film-forming synthetic pigment
engineered to improve the economics of waterborne coatings.
Ropaque HP-1096 is a polymer with a large void fraction designed to be used in
coatings where the pigment volume concentration is in the range of 50PVC and higher.
Ropaque HP-1096 contributes similar volume solids to ROPAQUE OP-96, but at
lower weight solids allowing lower raw material cost. This allows formulators to gain
additional savings in paints above the critical pigment volume concentration and at
very low titanium dioxide levels, by further increasing the total pigment volume
concentration over that of Ropaque OP-96 based paints.
Ropaque HP-1096 is not recommended at PVC's below 50 as its relatively large
particle size may decrease gloss and sheen levels. At this lower PVC's Ropaque Ultra is recommended.
Reformulation Protocols
Ropaque HP-1096 is designed for optimum usage closed to above critical pigment
volume concentration (CPVC) water borne paints having Titanium Dioxide levels below 12% pigment volume concentration (PVC).
Reformulation of paints not previously containing ROPAQUE or other
competitive Opaque Polymers :
First calculate the %PVC of pigment and extenders in your formulation, the Total
%PVC should be within the range of 50 to 85%.
TIO2% PVC
For TiO2% PVC's greater than 6%, rev=move 1/2 of the TiO2% PVC. If TiO2 level is below 6% PVC, then remove 1 1/2 % PVC units of TiO2.
High Oil Adsorption Extender
For high oil absorption. extenders such as Kaolinite clays and alumino silicates, maintain an equal level of these materials in the reformulation.
HP-1096 % PVC
Add 8 to 12% PVC of Ropaque HP-1096 to the reformulation
Total % PVC
Increase the total % PVC of the reformulated paint by 5% PVC units by adjusting the low O.A. extender such as calcium carbonate, chlorite, or silica.
Maintain the volume solids of the reformulation equal/higher to that of the original.
Coalescent should be added on the same basis as recommended for the binder used,
however, the amount of Ropaque HP-1096 added should be included in the calculation.
Reformulation of Paints Containing Ropaque OP-96
Replace Ropaque OP-96 on an equal weight basis or, for lowest cost reformulation, follow guidelines below.
First calculate the % PVC of pigment and extenders in your formulation the Total % PVC should be within the range of 50 to 85%.
TiO2 % PVC
Decrease the level of TiO2 by 0.5% PVC units. If the original level of TiO2 is greater
than 12 % PVC, the Ropaque HP-1096 reformulation may be more expensive than
the OP-62 formulation.
High Oil Adsorption Extender
For high oil absorption extenders such as Kaolinite clays and alumino silicates, increase the combined level of these materials in the reformulation by 2 to 3% PVC units.
HP-1096 % PVC
Increase the level of ROPAQUE OPAQUE POLYMER in the reformulation by 4% PVC units.
Total % PVC
Increase the total % PVC of the reformulated paint by 2.5 % PVC units by adjusting the low oil absorption extender such as calcium carbonate, chlorite, or silica.
Maintain the volume solids of the reformulation equal/higher to that of the original.
Coalescent level may be increased to further improve scrub resistance and film formation.
FEATURES AND ADVANTAGES
Maintain properties at lower raw material cost and hence increase profitability Improved properties at little or no cost increase Improved dirt resistance in exterior coatings Improved interior washability Better wet-to-dry color matching Color consistency at every tinting Improved block resistance for interior coatings
TYPICAL PHYSICAL PROPERTIES (These properties are typical and should not be considered
specifications.)
Ropaque® HP-1096
Percent Solids
Weight
28 - 29
pH
8-8.7
Density, lb/gal
Wet
8.55
Bulking Value, gal/lb
Wet
0.1170
Viscosity, cP
80 - 100
Average Particle Size,
Microns
0.55
We recommend Ropaque HP-1096 for exteriorand Interior formulations.
Interactions with Other Paint Ingredients
Ropaque HP-1096 hiding properties depends on the integrity of the hollow sphere in the paint film. As with all polymers, polymers can be affected by solvents.
White Spirits and Plasticizers
Avoid the use of white spirits and plasticizing solvents. The aromatic contents of white
spirits and many monomeric plasticizers have similar solubility parameters . This can
soften the polymer shell and cause the collapse of the spheres during film formation.
Alcohol-based coalescents and glycols do not affect Ropaque HP-1096, however,
during paint preparation, they should not be added in concentrated form to Ropaque
HP-1096 to avoid flocculation.
Handling and Storage Information
Some special storage and handling techniques should be observed for Ropaque
Opaque Polymers.
Intermittent agitation during bulk storage (approximately 15 minutes every 12 hours)
is recommended for controlling sedimentation. A two-inch recirculating closed loop,
using a sliding vane design, diaphragm type, or other low-shear pump to transfer
material, is preferred to a top-entering agitator. The recirculating loop should
discharge below the liquid level of the polymer to avoid foam generation.
As with all our emulsions, do not use mild steel, iron, copper, brass, bronze,
aluminum, or zinc-coated lines, valves, plugs, tanks, etc., in the transfer and storage
of opaque polymers. Polymer accumulates on such surfaces, starting a nucleating
process that results in extensive polymer fouling.
Avoid using surfaces that enable the polymer to wick out, as the wicking process
causes the development of nodules of hard material that grow out from these areas
and eventually drop into the polymer. Examples of materials that could result in
wicking are old fiberglass tanks with exposed glass fibers, a coated tank with part of
the coating broken, and drums with pinholes in the lining.
Exposure of opaque polymer to high shear will cause mechanical breakdown and
polymer buildup. Examples of high shear situations include pumping through small mesh filters at high flow rates and use of pumps with close tolerances.
When filtering with absorbent elements, pre-wetting the element reduces binding.
Cartridge filters and bag filters with needle-punched filter bags are examples of filters
with absorbent elements.
Shared transfer lines and other components should be flushed with water before they
are used for opaque polymers. Contact with concentrated glycols, surfactants, and acid
materials, could cause gelling. Compatibility with all new materials should be checked
routinely.
Protect from freezing!
Avoid free fall.
HEALTH AND SAFETY INFORMATION
Material Safety Data Sheets
Opaque polymer is non-toxic in single acute oral, dermal, and inhalation exposure tests. Without proper safety precautions, it can be a mild skin and eye irritant.
Dow Material Safety Data Sheets (MSDS) contain pertinent information that you may
need to protect your employees and customers against any known health or safety
hazards associated with our products.
Under the OSHA Hazard Communication Standard, workers must have access to and
understand MSDS on all hazardous substances to which they are exposed. Thus, it is
important that you provide appropriate training and information to your employees and
make sure they have available to them MSDS on any hazardous products in their
workplace.
Dow Company sends MSDS on non-OSHA hazardous as well as OSHA-hazardous
products to its customers upon initial shipment (including samples) of all its products
(whether or not they are considered OSHA-hazardous). If you do not have access to
one of these MSDS, please contact your local
Dow representative for an additional copy.
Updated MSDS are sent upon revision to all customers of record.
MSDS should be obtained from your suppliers of other materials recommended in this
bulletin.
Dow is a member of the Chemical Manufacturers Association and is committed to CMA’s Responsible Care® Program.
ROPAQUE is a trademark of Dow Company, or of its subsidiaries or affiliates and is intended to designate goods marketed in North and South America; the same goods may be marketed in other countries, generally under other Company trademark designations.
Suggestions for use of our products are based on information we believe to be reliable. They are offered in good faith, but without guarantee, as conditions and methods of use of our products are beyond our control. We recommend that the prospective user determine the suitability of our materials and suggestions before adopting them on a commercial scale. None of these suggestions should be construed as recommending use of our products in violation of any patent or as permission or license to use any patents of Dow Company.
Dow Company maintains Material Safety Data Sheets (MSDS) on all of its products described in this publication. As the MSDS contain pertinent information that you may need to protect your employees and customers against any known health or safety hazards associated with our products, we recommend that you obtain copies of these documents for each product before its use in your facilities. We also suggest that you contact your suppliers of other materials recommended for use with our products for appropriate health and safety precautions prior to their use.