博士後期課程【選択科目】...techniques 授業の目標 Course Objectives By the end...

博士後期課程

【選択科目】

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科目名 Course Title 先端総合化学特論Ⅰ [Modern Trends in Chemical Sciences and Engineering I]

講義題目 Subtitle 総合化学特論Ⅰ [Modern Trends in Physical and Material Chemistry]

責任教員 Instructor 村上洋太 [Yota MURAKAMI] (大学院理学研究院)

担当教員 Other Instructors

開講年度 Year 2019 時間割番号Course Number 095111

期間 Semester １学期（春）単位数 Number of Credits 1

授業形態 Type of Class 講義対象年次 Year of Eligible Students ～

ナンバリングコード Numbering Code CHEM_REQEL 7111

キーワード Key Words

先端物理化学，物質変換化学，光化学，分子理論化学，化学エネルギー変換，分離プロセス工学，プロセス工学，触媒設計，機能解析

化学，ナノフォトニクス材料，無機固体化学、ナノ物質化学，界面電子化学，無機物性化学，電子材料化学，機能固体化学，応用材料化

学

授業の目標 Course Objectives

物理化学・材料化学分野の先端的な化学研究について英語の講義を行う。先端研究を理解する上で必要となる基本的概念について解

説し，専門分野の最新のトレンドについて概観した後，最先端の研究成果を紹介する。化学研究の様々なトピックスについて英語で講

義を受け討議する。

到達目標 Course Goals

物理化学および物質化学の様々な領域の研究に触れ，各自の視野を広げ近接する研究領域と融合した新たな考え方を学ぶとともに，

国際的研究能力の育成を目指す。

授業計画 Course Schedule

固体表面の構造と電子状態，分子軌道理論と分子シミュレーション手法，ナノ粒子・ナノクラスターの機能，触媒化学と物質変換，励起状

態の化学，分子性物質の構造と物性，無機化合物の機能と物性，生体膜の構造と機能など，物理化学および無機分析化学の最新の研

究動向を紹介する。

また，触媒や吸着材等に利用される多孔質材料，化学プロセスのシステム設計法，相平衡の推算方法および拡散分離操作，グリーン合

成の触媒反応設計，メソスコピック系材料の物性設計，無機材料作製法，ナノからミクロンにおける粒子制御による無機材料の機能性，

電極表面の原子配列と熱力学について解説するとともに，無機固体材料の電子構造と物性，セラミックス原料粒子の合成工程，電子材

料化学の基礎概念，セラミック材料の物性と応用例，磁性材料や電池材料などの機能性セラミックスなど，物質化学における幅広い分野

のトピックスを解説する。

準備学習（予習・復習）等の内容と分量 Homework

講義内容についてはその日のうちに復習すること。

成績評価の基準と方法 Grading System

原則として、授業回数の７割以上の出席を成績評価の条件とする。学修態度(20%)および、レポート(80%)によって評価する。レポートは、

各回毎に講師の指示に従って提出する。

テキスト・教科書 Textbooks

なし。適宜資料を配布する。

講義指定図書 Reading List

参照ホームページ Websites

研究室のホームページ Website of Laboratory

備考 Additional Information

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講義題目 Subtitle 総合化学特論Ⅱ [Modern Trends in Organic Chemistry and Biological Chemistry]




期間 Semester １学期（夏）単位数 Number of Credits 1




有機構造化学，高分子機能科学，有機金属化学，有機物性化学，遺伝情報制御化学，疾病制御化学，有機合成化学，生物物理化学，

生合成工学，生命システム工学，生物計測化学，機能性高分子，動物細胞培養工学


有機化学・生物化学分野の先端的な化学研究について英語の講義を行う。先端研究を理解する上で必要となる基本的概念について解




様々な領域の研究に触れ，各自の視野を広げるとともに，国際的研究能力の育成を目指す。


有機金属触媒を用いたクロスカップリング，複雑な構造を有する天然由来低分子有機化合物の合成，高度な分子認識に基づいた機能

制御分子の設計，有機触媒による環境調和型合成法の開発，化学生物学を指向した生物活性分子ライブラリーの構築や機能性高分子

の合成および物性解析など有機化学の最新の研究動向を紹介する。また酵素などによる生体反応や生体機能発現機構の構造生物学

的解析法，バイオインフォマティクスを利用した遺伝子機能の解析，機能改変による高機能化について解説するとともに，遺伝情報の維

持や発現の制御機構，生命原理を制御するシステムの破綻がもたらす病態形成メカニズムなど生物化学における幅広い分野のトピック

スを解説する。


予習は原則として必要ないが、関連項目に関し相当する教科書の内容を確認して授業を受けるのが望ましい。









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科目名 Course Title 先端総合化学特論Ⅱ [Modern Trends in Chemical Sciences and Engineering II]

講義題目 Subtitle Leading and Advanced Molecular Chemistry and Engineering IA - 2019

責任教員 Instructor 村越敬 [Kei MURAKOSHI] (大学院理学研究院)

担当教員 Other Instructors Hogan YU (Simon Fraser University)


期間 Semester 集中単位数 Number of Credits 1




Molecular spectroscopy and microscopy, Bioanalytical Chemistry, Optical biosensors, Electrochemical biosensors, Microfluidic and microarray

techniques


By the end of this course the students will be able to ;

1. understand the basic principle of modern microscopy for imaging microassasys and microarrays.

2. understand the basic principle and state-of-art techniques in surface analysis.

3. understand the basic principles of biosensors and their applications.

4. improve the scientific presentation skills.


By the end of this course, the instructor will be able to

1. provide the students an overview of the modern techniques that are essential for today's bioanalytical and materials chemistry research.

2. improve the students' capability of understanding scientific lectures in English.

3. improve the students' confidents in communicating with the instructor and fellow students.


Lecture I: Modern optical microscopy

Lecture II: Surface analysis: from composition to morphology

Lecture III: DNA microarray biochips to microfluidic techniques

Lecture IV: Electrochemical biosensors

Seminar: Mobile electronics as point-of-care diagnostic tools: from disc player to smartphone


to be announced


Your grade will be determined by how well you demonstrate your achievement of the course goals through

1. Daily course quizzes. 20%

2. Course discussions on specific topics. 40%

3. Short presentations on selected literature. 40%


Lecture notes will be distributed at the class.




http://www.sfu.ca/chemistry/people/profiles/hhyu/

https://wwwchem.sci.hokudai.ac.jp/~pc/



講義題目 Subtitle 総合化学特論Ⅱ [Modern Trends in Organic Chemistry and Biological Chemistry]




期間 Semester １学期（夏）単位数 Number of Credits 1




有機構造化学，高分子機能科学，有機金属化学，有機物性化学，遺伝情報制御化学，疾病制御化学，有機合成化学，生物物理化学，

生合成工学，生命システム工学，生物計測化学，機能性高分子，動物細胞培養工学


有機化学・生物化学分野の先端的な化学研究について英語の講義を行う。先端研究を理解する上で必要となる基本的概念について解




様々な領域の研究に触れ，各自の視野を広げるとともに，国際的研究能力の育成を目指す。


有機金属触媒を用いたクロスカップリング，複雑な構造を有する天然由来低分子有機化合物の合成，高度な分子認識に基づいた機能

制御分子の設計，有機触媒による環境調和型合成法の開発，化学生物学を指向した生物活性分子ライブラリーの構築や機能性高分子

の合成および物性解析など有機化学の最新の研究動向を紹介する。また酵素などによる生体反応や生体機能発現機構の構造生物学

的解析法，バイオインフォマティクスを利用した遺伝子機能の解析，機能改変による高機能化について解説するとともに，遺伝情報の維

持や発現の制御機構，生命原理を制御するシステムの破綻がもたらす病態形成メカニズムなど生物化学における幅広い分野のトピック

スを解説する。


予習は原則として必要ないが、関連項目に関し相当する教科書の内容を確認して授業を受けるのが望ましい。









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講義題目 Subtitle Leading and Advanced Molecular Chemistry and Engineering IB - 2019


担当教員 Other Instructors David LEWIS (Flinders University), 野口秀典(物質・材料研究機構)






nano-cylinders, selective transport of molecules, polymers, solar cell, nano-devices, microwave processing


By the end of this course you will be able to ;

1. understand the basic principle of polymer materials for device applications.

2. understand basic principle and state-of-art techniques on organic electronics

3. understand basic principles of microwave processing of materials.

4. capable of designing a novel polymer materials for enhancing coating and photochromism.


By the end of this course you will be able to

1. write appropriate syllabus with correct understanding.

2. carry out a class incorporating the education technique such as experiment, e-learning, the clicker and so on.

3. present science (or their speciality) knowledge clearly.

4. design an active learning class.


Lecture I: Fundamentals of Polymer Materials for Nanodevices & Genetics

Lecture II: Microwave processing of materials

Lecture III: Materials and processes for microelectronic applications

Lecture IV: Ophthalmic lens materials and performance enhancing coatings

Lecture V: Photochromic systems

.......

Seminar: Nanotechnology and Polymer Science; Converting research and ideas into new products and technologies


to be announced





3. Short course proposal & presentation. 50%


to be announced




https://www.flinders.edu.au/people/david.lewis

https://www.nims.go.jp/nanointerface/iecmc_nims/index.html



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講義題目 Subtitle Leading and Advanced Molecular Chemistry and Engineering II - 2019

責任教員 Instructor 伊藤肇 [Hajime ITOH] (大学院工学研究院)

担当教員 Other Instructors Eunsung LEE (POSTECH)






Organometallics, Organic Chemistry, Organofluorine Chemistry, Organic Synthesis, Radiochemistry


Fluorinated compounds have been of great interest for many applications such as pharmaceuticals, agrochemicals, fluoro plastics (Teflon), and

18F-labeled radiopharmaceutical imaging agents because of the benefits from fluorine’s unique properties such as thermal and oxidative stability

and lipophilicity to enhance bioavailability. For example, strong C-F bonds on the fluorine-containing material such as Teflon®, Nafinon, and

PFA (perfluoroalkoxy) enable a low polarity, small surface tension and reflective index, which are desired properties of waterproof and insulating

materials. Approximately 25% of current pharmaceuticals and 30% of agrochemicals contain fluorine. Although there was considerable demand

for facile preparation of fluorinated compounds, the methods have been significantly developed only for the past two decades. From these

lectures, I will discuss the early fluorination history and then move on the recent development including reagent based and transition metal

catalyzed fluorination. In addition, [18F]fluorination methods will be discussed. Finally, the efforts to disconnect the strong C-F bonds will be

described for useful applications.


By the end of this course, you will be able to

1. understand the importance of C-F bonds in many applications.

2. design a new synthetic route for fluorinated organic molecules.

3. have knowledge about radiochemistry.

4. understand different views on C-F bond cleavage.


The first aim is to get advanced knowledge for fluorination of organic compounds.

The second aim is to understand application of organofluorine compounds.

1. Early Fluorination

2. Fluorination Reagents

3. Nucleophilic and Electrophilic Fluorination

4. Aliphatic and Aromatic fluorination

5. Fluorination for Positron-Emission Tomography (PET)

6. Activation and functionalization of C-F bonds


Students need the preparations for discussion about fluorination.

You will be asked to write two pages (A4) of report at the end of each lecture.


Assignment on a specified subject regarding to "Development of Synthesis and Reaction of Organofluorine Compounds " (60%).

In addition, we also consider it as the important factor for assessment how actively students participate in each class (40%).


No textbook required. Handouts will be distributed.


Organotransition Metal Chemistry: From Bonding to Catalysis／John F. Hartwig

The Organometallic Chemistry of the Transition Metals／Robert H. Crabtree


http://ioml.postech.ac.kr/

http://labs.eng.hokudai.ac.jp/labo/organoelement/



講義題目 Subtitle Leading and Advanced Molecular Chemistry and Engineering IB - 2019


担当教員 Other Instructors David LEWIS (Flinders University), 野口秀典(物質・材料研究機構)






nano-cylinders, selective transport of molecules, polymers, solar cell, nano-devices, microwave processing


By the end of this course you will be able to ;

1. understand the basic principle of polymer materials for device applications.

2. understand basic principle and state-of-art techniques on organic electronics

3. understand basic principles of microwave processing of materials.

4. capable of designing a novel polymer materials for enhancing coating and photochromism.



1. write appropriate syllabus with correct understanding.

2. carry out a class incorporating the education technique such as experiment, e-learning, the clicker and so on.

3. present science (or their speciality) knowledge clearly.

4. design an active learning class.


Lecture I: Fundamentals of Polymer Materials for Nanodevices & Genetics

Lecture II: Microwave processing of materials

Lecture III: Materials and processes for microelectronic applications

Lecture IV: Ophthalmic lens materials and performance enhancing coatings

Lecture V: Photochromic systems

.......

Seminar: Nanotechnology and Polymer Science; Converting research and ideas into new products and technologies


to be announced





3. Short course proposal & presentation. 50%


to be announced




https://www.flinders.edu.au/people/david.lewis

https://www.nims.go.jp/nanointerface/iecmc_nims/index.html



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講義題目 Subtitle Leading and Advanced Molecular Chemistry and Engineering III - 2019

責任教員 Instructor 安住和久 [Kazuhisa AZUMI] (大学院工学研究院)

担当教員 Other Instructors 幅﨑浩樹(工学研究院), 忠永清治(工学研究院), 村越敬(理学研究院),

八木一三(地球環境科学研究院), 松島永佳(工学研究院), 髙草木達(触媒科学研究所)






Nanostructure, Functionalization, Catalyst, Fuel cell, Solid battery, Photo-electrochemistry, High-speed atomic level microscopy


Electrochemistry is an one of basic science supporting our modern society in various fields. Advantage in electrochemistry is that chemical

reaction can be controlled via operation of electric parameter as voltage and current. This concept is applied to wide application from basic

engineering such as battery, plating, corrosion and refining to advanced science in atomic level reaction, photo-synthesis, catalysts and

innovative new functions. In this lecture, seven researchers working in electrochemistry-related field present fundamental principle, function,

mechanism and recent topics of selected subject.


By the end of this course, students will be able to

• understand fundamental concept of electrochemistry,

• know how electrochemistry is used in many scenes in our life,

• explain how Li-ion battery and fuel cell work to supply high energy,

• imagine how atomic level phenomena provide macroscopic functions,

• and think about new ideas using advanced electrochemistry for future.


Seven professors will lecture on various topics. In the final lecture, student will discuss about the subject their interest in related to lectures.

• Concept and basics of electrochemistry (Jun.25)

• Controlling nano-scale physico-photo-electro-phenomena (Jun.25)

• Controlling nanostructure of surface to provide new functions (Jun.26)

• Very-fast atomic-scale imaging (Jun.26)

• Exploration into the horizon of catalyst (Jun.27)

• Deep understanding of fuel cell (Jun.27)

• Development of innovative all-solid-state battery (Jun.28)

• General discussion (Jun.28)


Students will be asked to write a report at the end of each lecture.


Grading will be done based on report for each topic.






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講義題目 Subtitle Leading and Advanced Materials Chemistry and Engineering I - 2019

責任教員 Instructor 島田敏宏 [Toshihiro SHIMADA] (大学院工学研究院)

担当教員 Other Instructors Nicolas CLEMENT (CNRS)






ナノテクノロジー、分子素子、電子工学、生体分析


分子スケールの電子回路素子は化学・電子工学の双方において夢のデバイスである。現在ではそのようなデバイスを作り、医学・生物

学に応用することが可能になりつつある。その技術にはトップダウンのリソグラフィープロセスとボトムアップの分子の自己組織化を結合

する必要がある。本講義では、ナノ接合における整流性、バリスティック伝導、トンネル効果や分子認識といった分子スケール素子の物

理と化学の基礎を学ぶ。それから分子スケールのデバイス作製技術の現状を概観する。Prof. Nicolas Clement はこの分野の若手の第一

人者である。応用と将来発展についても議論する。


本講義では以下を習得する。

1. ナノデバイス作製の基本概念。

2. 分子スケールのエレクトロニクスの物理的・化学的背景知識

3. 国際共同研究のノウハウ

4. 生体分析のための分子スケールデバイスの設計の基礎


本講義は分子スケールデバイスの原理と作製法の両方を扱う。

原理の部分では、３コマの講義でナノスケールの電気伝導と分子構造がどのように影響するかを学ぶ。

作製の部分では、リソグラフィと自己組織化について 3 コマの講義を行う。最後に、分析デバイスとしての応用を講義する。

授業計画は以下のとおりである。

1. はじめに：分子エレクトロニクス

2. ナノ・分子接合における電気伝導

3. マイクロ・ナノ流体力学

4. トップダウン微細加工技術

5. ボトムアップ微細加工技術

6. 分子・ナノ流体電子デバイスの生体分析化学への応用

7. ナノ材料合成と評価技術に関するラボツアー

8. Prof. Nicolas Clement によるセミナー


毎回の講義で指定する。


最終レポートで評価するが、毎回のクイズへの回答など授業参加の様子も加味する。




This course will be provided as part of the Hokkaido Summer Institute., For more information (invited lecturers, course details, etc.), please

visit the website below:, https://hokkaidosummerinstitute.oia.hokudai.ac.jp/courses/CourseDetail=G041


http://nicolasclement.blog/

http://www.eng.hokudai.ac.jp/labo/kotai/



講義題目 Subtitle Leading and Advanced Molecular Chemistry and Engineering III - 2019

責任教員 Instructor 安住和久 [Kazuhisa AZUMI] (大学院工学研究院)

担当教員 Other Instructors 幅﨑浩樹(工学研究院), 忠永清治(工学研究院), 村越敬(理学研究院),

八木一三(地球環境科学研究院), 松島永佳(工学研究院), 髙草木達(触媒科学研究所)






Nanostructure, Functionalization, Catalyst, Fuel cell, Solid battery, Photo-electrochemistry, High-speed atomic level microscopy


Electrochemistry is an one of basic science supporting our modern society in various fields. Advantage in electrochemistry is that chemical

reaction can be controlled via operation of electric parameter as voltage and current. This concept is applied to wide application from basic

engineering such as battery, plating, corrosion and refining to advanced science in atomic level reaction, photo-synthesis, catalysts and

innovative new functions. In this lecture, seven researchers working in electrochemistry-related field present fundamental principle, function,

mechanism and recent topics of selected subject.


By the end of this course, students will be able to

• understand fundamental concept of electrochemistry,

• know how electrochemistry is used in many scenes in our life,

• explain how Li-ion battery and fuel cell work to supply high energy,

• imagine how atomic level phenomena provide macroscopic functions,

• and think about new ideas using advanced electrochemistry for future.


Seven professors will lecture on various topics. In the final lecture, student will discuss about the subject their interest in related to lectures.

• Concept and basics of electrochemistry (Jun.25)

• Controlling nano-scale physico-photo-electro-phenomena (Jun.25)

• Controlling nanostructure of surface to provide new functions (Jun.26)

• Very-fast atomic-scale imaging (Jun.26)

• Exploration into the horizon of catalyst (Jun.27)

• Deep understanding of fuel cell (Jun.27)

• Development of innovative all-solid-state battery (Jun.28)

• General discussion (Jun.28)


Students will be asked to write a report at the end of each lecture.


Grading will be done based on report for each topic.






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講義題目 Subtitle Leading and Advanced Materials Chemistry and Engineering IIA - 2019

責任教員 Instructor 忠永清治 [Kiyoharu TADANAGA] (大学院工学研究院)

担当教員 Other Instructors Li LU (National University of Singapore),

三浦章(工学研究院), NATALY CAROLINA ROSERO NAVARRO(工学研究院)






Electrochemical devices; Electrolyte; Electrode; Nano-structure; Batteries


Recently, safe, low cost, high energy density, and long-lasting electrochemical devices for energy conversion and energy storage are highly

required for the application to mobile devices, electric vehicles, and energy storage system for the renewable energy. Development of novel

materials and morphology control of these materials are key issues. The aim of this course is to describe the importance of electrochemical

devices and materials science involved in the development of such electrochemical devices.

Fundamental concepts in electrochemical energy conversion and storage are firstly overviewed, and then the materials chemistry for the

electrochemical devices will be described. Preparation process for materials of electrochemical devices, effect of nano-structures in electrodes

for lithium and sodium ion batteries, development of all solid-state lithium secondary batteries are also described.



1. explain and compare the electrochemical energy conversion and storages systems.

2. understand the basic requirements for materials used in electrochemical energy conversion and energy storage devices.

3. explain the effects of nanostructures on the properties of electrochemical devices.

4. understand and discuss materials and electrochemical devices in future energy storage system.


Following topics will be covered during this course.

1. Fundamental concepts about electrochemical energy conversion and storage

2. Introduction of inorganic materials science for electrochemical devices

3. Introduction to defects chemistry – dopants in materials for electrochemical storage

4. Nanostructured materials applied to electrodes for lithium and sodium ion batteries

5. Fundamentals of solid electrolyte

6. All-solid-state lithium/sodium secondary batteries

7. Overview of recent trends in materials for electrochemical devices and future energy storage system

8. Students presentation on topics in electrochemical devices


Students will be expected to download class notes from WEB page and read designated chapter in advance.

Students should read some papers on electrochemical devices during this course and make presentation.


Grade will be determined by how well one’s achievement in this course through

1. a report on nanostructured materials in electrochemical devices (weightage 80%), and

2. a presentation on one’s research or some topics in electrochemical devices (weightage 20%).




"Recent Advances in Energy Storage Materials and Devices", Li Lu edited, Materials Research Forum LLC, ISBN 978-1945291265 (2017).

"Ceramic Electrolytes for All-Solid-State Li Batteries", M. Kotobuki, S. Song, C. Chen, and Li Lu, World Scientific Pub Co Inc ISBN: 978-

9813233881(2018).


http://me.nus.edu.sg/

http://www.eng.hokudai.ac.jp/labo/inorgsyn/


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講義題目 Subtitle Leading and Advanced Materials Chemistry and Engineering IIB - 2019

責任教員 Instructor 加藤昌子 [Masako KATO] (大学院理学研究院)

担当教員 Other Instructors Vivian Wing-Wah YAM (University of Hong Kong)






luminescence, photochemistry, photopysics, supramolecule, metal complexes


This course is designed to acquire basic knowledge in coordination chemistry and photochemistry/photopysics of coordination compounds, and

applications as new materials towards device, photocatalytic, and bio-medicinal fields.


Students will gain not only knowledge of photofunctional coordination and supramolecular chemistry, but also acquire problem-solving ability

for exploring functionality of metal-based materials.


Day 1 Lecture 1: Introduction – Luminescent metal-based materials

Day 1 Lecture 2: Basic concepts and principles of photophysics and photochemistry

Day 2 Lecture 3: Energy transfer and electron transfer processes

Day 2 Lecture 4: Nature of selected excited states

Day 3 Lecture 5: Utilization of luminescent metal-based materials for energy

Day 3 Lecture 6: Utilization of luminescent metal-based materials for biomedical applications

Day 4 Lecture 7: Discussion

Day 4 Lecture 8: Open Seminar


To be announced


Assignment on a specified subject regarding "luminescent metal-based materials" (60%).

Assessment how actively students participate in each class (40%).


Handouts will be distributed.




http://hub.hku.hk/cris/rp/rp00822

https://wwwchem.sci.hokudai.ac.jp/~cc/



講義題目 Subtitle Leading and Advanced Materials Chemistry and Engineering IIA - 2019

責任教員 Instructor 忠永清治 [Kiyoharu TADANAGA] (大学院工学研究院)

担当教員 Other Instructors Li LU (National University of Singapore),

三浦章(工学研究院), NATALY CAROLINA ROSERO NAVARRO(工学研究院)






Electrochemical devices; Electrolyte; Electrode; Nano-structure; Batteries


Recently, safe, low cost, high energy density, and long-lasting electrochemical devices for energy conversion and energy storage are highly

required for the application to mobile devices, electric vehicles, and energy storage system for the renewable energy. Development of novel

materials and morphology control of these materials are key issues. The aim of this course is to describe the importance of electrochemical

devices and materials science involved in the development of such electrochemical devices.

Fundamental concepts in electrochemical energy conversion and storage are firstly overviewed, and then the materials chemistry for the

electrochemical devices will be described. Preparation process for materials of electrochemical devices, effect of nano-structures in electrodes

for lithium and sodium ion batteries, development of all solid-state lithium secondary batteries are also described.



1. explain and compare the electrochemical energy conversion and storages systems.

2. understand the basic requirements for materials used in electrochemical energy conversion and energy storage devices.

3. explain the effects of nanostructures on the properties of electrochemical devices.

4. understand and discuss materials and electrochemical devices in future energy storage system.


Following topics will be covered during this course.

1. Fundamental concepts about electrochemical energy conversion and storage

2. Introduction of inorganic materials science for electrochemical devices

3. Introduction to defects chemistry – dopants in materials for electrochemical storage

4. Nanostructured materials applied to electrodes for lithium and sodium ion batteries

5. Fundamentals of solid electrolyte

6. All-solid-state lithium/sodium secondary batteries

7. Overview of recent trends in materials for electrochemical devices and future energy storage system

8. Students presentation on topics in electrochemical devices


Students will be expected to download class notes from WEB page and read designated chapter in advance.

Students should read some papers on electrochemical devices during this course and make presentation.


Grade will be determined by how well one’s achievement in this course through

1. a report on nanostructured materials in electrochemical devices (weightage 80%), and

2. a presentation on one’s research or some topics in electrochemical devices (weightage 20%).




"Recent Advances in Energy Storage Materials and Devices", Li Lu edited, Materials Research Forum LLC, ISBN 978-1945291265 (2017).

"Ceramic Electrolytes for All-Solid-State Li Batteries", M. Kotobuki, S. Song, C. Chen, and Li Lu, World Scientific Pub Co Inc ISBN: 978-

9813233881(2018).


http://me.nus.edu.sg/

http://www.eng.hokudai.ac.jp/labo/inorgsyn/


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講義題目 Subtitle Leading and Advanced Materials Chemistry and Engineering IIC - 2019


担当教員 Other Instructors Fei CHEN (Wuhan University of Technology), 長浜太郎(工学研究院)






セラミックス、傾斜材料、固体電解質、酸化物系全固体電池、エネルギー貯蔵、スピントロニクス


現代社会は材料と化学に関する技術がなければ成り立たない。本講は、セラミックスと酸化物系複合材料を対象とし、中国から Prof. Fei

CHEN を招いて共同で講義を行う。セラミックスの応用はその物性によって制限されるが、セラミックスと他の材料を複合化することによ

って応用が広がる。Prof. Fei CHAN はエネルギー分野に関するセラミックス複合材料の応用について講義を行う。その中には、グリッド

スケールのエネルギー貯蔵技術、全固体電池及び関連するプロセス技術である。Prof. Fei CHEN は MIT で学んだ中国で著名な若手

教授である。島田と長浜は無機系材料の関連物性を講義する。


この講義により、下記のことを習得する。

1. 材料の電子的、力学的性質およびエネルギー応用。

2. セラミックス材料のプロセスに関する物理と化学。

3. 海外での留学と仕事に関する知識。


この講義は材料のプロセスと機能という２つの内容を扱う。プロセスに関しては３コマの講義と、可能ならば実験を含むラボツアーを行

う。材料の機能に関しては４コマの講義を行う。全体として下記を計画している

1. はじめに：現代社会におけるセラミックス

2. 原子スケールでの材料創成における基礎概念：熱力学・速度論と化学の利用

3. グリッドスケールのエネルギー貯蔵を目標とする高エネルギープロセス

4. 半導体回路のための電子的・光学的性質

5. 固体電解質と固体電池のための電気化学

6. スピントロニクス

7. 実験見学：プラズマ CVD、高圧合成、種々の評価手法

8. Prof. Fei CHEN によるセミナー




最終レポートで評価するが、毎回の講義時に課すクイズの解答など、授業参加の様子も加味して判断する。











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講義題目 Subtitle Leading and Advanced Materials Chemistry and Engineering IID - 2019

責任教員 Instructor 幅﨑浩樹 [Hiroki HABAZAKI] (大学院工学研究院)

担当教員 Other Instructors Byungjin CHO (Chungbuk National University), 朱春宇(工学研究院)






Inorganic nanomaterials, nanoporous materials, nanocarbons, energy conversion and storage, nanoelectronics


Diverse inorganic nanomaterials are becoming more and more important in modern technology. In this lecture, we invite Prof. Byungjin Cho

from Chungbuk national University, Korea, who is a leading young scientist in advanced inorganic materials. Th synthesis, characterization,

functionalization and device applications of a range of nanomaterials are briefly introduced to get fundamental knowledge on 1D and 2D

nanomaterials with various functionalities. Basic concepts for electronic and energy applications will be proposed in this lecture.



1. explain the basic concepts for diverse applications of inorganic nanomaterials.

2. explain the synthesis methods of diverse inorganic nanomaterials and their applications.

3. explain the basic chemistry and physics behind the fabrication and characterization of nanomaterials.


This course is focused on fabrication, properties and applications of advanced inorganic materials. The course is organized as follows:

1. Introduction: How inorganic nanomaterials are used in modern technology.

2. Synthesis of 2D nanostructures

3. Characterization methods for physical and chemical properties of nanomaterials

4. Diverse applications of 2D inorganic nanomaterials

5. Fabrication and applications of nanocomposite materials

6. Self-organized fabrication of nanostructured materials and their applications

7. Lab tour, showing various characterization techniques of nanomaterials

8. Seminar by Prof. Byungjin Cho


To be announced


Grading will be based on the final reports submitted some period after the lectures.




Not required. Handouts will be distributed.



https://bjcho6885.wixsite.com/mnlab

http://labs.eng.hokudai.ac.jp/labo/elechem/



講義題目 Subtitle Leading and Advanced Materials Chemistry and Engineering IIC - 2019


担当教員 Other Instructors Fei CHEN (Wuhan University of Technology), 長浜太郎(工学研究院)






セラミックス、傾斜材料、固体電解質、酸化物系全固体電池、エネルギー貯蔵、スピントロニクス


現代社会は材料と化学に関する技術がなければ成り立たない。本講は、セラミックスと酸化物系複合材料を対象とし、中国から Prof. Fei

CHEN を招いて共同で講義を行う。セラミックスの応用はその物性によって制限されるが、セラミックスと他の材料を複合化することによ

って応用が広がる。Prof. Fei CHAN はエネルギー分野に関するセラミックス複合材料の応用について講義を行う。その中には、グリッド

スケールのエネルギー貯蔵技術、全固体電池及び関連するプロセス技術である。Prof. Fei CHEN は MIT で学んだ中国で著名な若手

教授である。島田と長浜は無機系材料の関連物性を講義する。


この講義により、下記のことを習得する。

1. 材料の電子的、力学的性質およびエネルギー応用。

2. セラミックス材料のプロセスに関する物理と化学。

3. 海外での留学と仕事に関する知識。


この講義は材料のプロセスと機能という２つの内容を扱う。プロセスに関しては３コマの講義と、可能ならば実験を含むラボツアーを行

う。材料の機能に関しては４コマの講義を行う。全体として下記を計画している

1. はじめに：現代社会におけるセラミックス

2. 原子スケールでの材料創成における基礎概念：熱力学・速度論と化学の利用

3. グリッドスケールのエネルギー貯蔵を目標とする高エネルギープロセス

4. 半導体回路のための電子的・光学的性質

5. 固体電解質と固体電池のための電気化学

6. スピントロニクス

7. 実験見学：プラズマ CVD、高圧合成、種々の評価手法

8. Prof. Fei CHEN によるセミナー




最終レポートで評価するが、毎回の講義時に課すクイズの解答など、授業参加の様子も加味して判断する。











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講義題目 Subtitle Leading and Advanced Materials Chemistry and Engineering III - 2019

責任教員 Instructor 坂口和靖 [Kazuyasu SAKAGUCHI] (大学院理学研究院)

担当教員 Other Instructors 山浦一成(物質・材料研究機構), 辻本吉廣(物質・材料研究機構)






Solid state chemistry, superconductivity, strongly correlated electrons, magnetic properties


Solid-state chemistry is a common background for developing research fields such as quantum materials, materials engineering, and condensed

matter science. By mastering knowledge of solid-state chemistry and deepening your understanding, you can strengthen research abilities and

activities in the latest fields. This course is designed as an introduction to solid state chemistry useful for materials development for hands-on

properties mostly for superconductivity and correlated electrons properties.



1. present fundamental knowledge of solid state chemistry.

2. carry out a laboratory work for solid-state materials synthesis.

3. reveal the lattice structure and local coordination of solid-state materials by diffraction.

4. explain fundamental magnetic properties and practical functions of solid-state materials.


1. Introduction for solid-state and crystal chemistry

2. Introduction for materials synthesis and phase diagram

3. Structure principles and structure characterization of solid-state compounds

4. Magnetic and electrical properties of solid-state compounds

5. Introduction for superconductivity


No specific requirements for this course, but recommended to read text books for solid state chemistry at undergraduate level.


Written assignment on a specified topic in solid state chemistry or related fields (60%).

Class participation (40%).






https://www.nims.go.jp/research/group/quantum-solid-state/index.html


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講義題目 Subtitle Leading and Advanced Biological and Polymer Chemistry and Engineering IA - 2019

責任教員 Instructor 佐田和己 [Kazuki SADA] (大学院理学研究院)

担当教員 Other Instructors Kostas SARAKINOS (Linkoping University), 角五彰(理学研究院)






Atomic Layer, Crystal Growth, Thin Films, Metal, Epitaxy, Nucleation, Layer-by-Layer, Polymers, Self-assembly, Supramolecular Chemistry,

Organogels, Organic Crystals, Soft Crystals, Kinesin, Tubline, Microtubles


Atomic or molecular level thin films are key materials for modern technology and related science. Learning the thin films should be of

importance for material researchers. In particular, this lecture covers science and technology of both physics and chemistry aspects.

In the former, definition of thin films for surface physics and engineering is provided with reference to specific examples of applications and

devices founded upon thin films. Then, physical- and chemical-vapor deposition techniques used for thin-film synthesis are discussed on a

conceptual level, and film-formation stages. The atomic-scale mechanisms that lead to vapor condensation on solid substrate surfaces are

discussed from the view point of thermodynamics and kinetics. The atomistic theory of nucleation of the thin film is introduced and explained.

The concept of epitaxy, both homo- and heteroepitaxy, is also introduced for film morphological evolution such as 2D and 3D islands. Strategies

for manipulating growth of morphology evolution using surfactants, energetic ions, and temporally modulated vapor fluxes are also discussed.

Finally, revisiting the film-formation stages, the atomic-scale processes that control film morphological evolution are discussed. Film

morphologies are then classified in the framework of the so-called structure zone models (SZMs) which describe the effect of growth temperature

and impurity concentration of fundamental structure-forming processes.

In the latter, starting from the applications of the polymer thin films in the daily life, the fabrication of polymer thin films and layer-by-layer

method fro hybrid polymer thin film are discussed. Then, the topics moves to chemistry of molecular assemblies. Many examples of two

dimmensional crystallization of organic molecules on a substarte are reviewed in relation to formation of organic crystals and fibrious aggregates.

Their formation are discussed from the view point of the nucleartion-growth theory similar to the formar part. The role of the moelcualr

structures and weak intermolecular interactions are also discussed. Finally, one-dimensional biological molecular assemblies such as

microtubles are reviewed.


Atomic or molecular level thin films are key materials for modern technology and related science. Learning the thin films should be of

importance for material researchers. In particular, this lecture covers science and technology of both physics and chemistry aspects.

In the former, definition of thin films for surface physics and engineering is provided with reference to specific examples of applications and

devices founded upon thin films. Then, physical- and chemical-vapor deposition techniques used for thin-film synthesis are discussed on a

conceptual level, and film-formation stages are explained. The atomic-scale mechanisms that lead to vapor condensation on solid substrate

surfaces are discussed from the view point of thermodynamics and kinetics. The atomistic theory of nucleation of the thin film is introduced

and explained. The concept of epitaxy, both homo- and heteroepitaxy, is also introduced, followed by a discussion on shape evolution of

2Dislands and 3D film morphological evolution. Strategies for manipulating growth of morphologicalevolution using surfactants, energetic ions,

and temporally modulated vapor fluxes are also discussed. Finally, revisiting the film-formation stages, the atomic-scale processes that control

morphological evolution in polycrystalline films are discussed. Film morphologies are then classified in the framework of the so-called structure

zone models (SZMs) which describe the effect of growth temperature and impurity concentration on fundamental film structure-forming

processes.

In the latter, starting from the applications of the polymer thin films in the daily life, the fabrication of polymer thin films and layer-by-layer

method fro hybrid polymer thin film are discussed. Then, the topics moves to chemistry of molecular assemblies. Many examples of two

dimmensional crystallization of organic molecules on a substarte are reviewed in relation to formation of organic crystals and fibrious aggregates.

Their formation are discussed from the view point of the nucleartion-growth theory similar to the formar part. The role of the moelcualr

structures and weak intermolecular interactions are also discussed. Finally, one-dimensional biological molecular assemblies such as

microtubles are reviewed.


(Topic I) Thin films, atomic and physical aspcet

Lecture 1: Introduction to inroganic thin-film science and technology

Lecture 2: Thin-film nucleation from the view point of thermodynamics and kinetics

Lecture 3: Growth evolution and growth manipulation of epitaxial films

Lecture 4: Growth and microstructural evolution of polycrystalline films


講義題目 Subtitle Leading and Advanced Materials Chemistry and Engineering III - 2019


担当教員 Other Instructors 山浦一成(物質・材料研究機構), 辻本吉廣(物質・材料研究機構)






Solid state chemistry, superconductivity, strongly correlated electrons, magnetic properties


Solid-state chemistry is a common background for developing research fields such as quantum materials, materials engineering, and condensed

matter science. By mastering knowledge of solid-state chemistry and deepening your understanding, you can strengthen research abilities and

activities in the latest fields. This course is designed as an introduction to solid state chemistry useful for materials development for hands-on

properties mostly for superconductivity and correlated electrons properties.



1. present fundamental knowledge of solid state chemistry.

2. carry out a laboratory work for solid-state materials synthesis.

3. reveal the lattice structure and local coordination of solid-state materials by diffraction.

4. explain fundamental magnetic properties and practical functions of solid-state materials.


1. Introduction for solid-state and crystal chemistry

2. Introduction for materials synthesis and phase diagram

3. Structure principles and structure characterization of solid-state compounds

4. Magnetic and electrical properties of solid-state compounds

5. Introduction for superconductivity


No specific requirements for this course, but recommended to read text books for solid state chemistry at undergraduate level.


Written assignment on a specified topic in solid state chemistry or related fields (60%).

Class participation (40%).






https://www.nims.go.jp/research/group/quantum-solid-state/index.html


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(Topic II) Thin films and related molecular assembly, organic and biological aspect

Lecture 5: Fabrication of polymer thin films basic and applications

Lecture 6: Two-dimensinal crystal growth of organic molecules on the substrate

Lecture 7: Growth of organic crystals and fibrous aggregates

Lecture 8: Fibrous aggregates of biomacromolecules and its applications

PBL(Problem Based Learning) type discussion will be done in the two topics.


Students will read reviews and the primary literature on each topic, and submit questions for instructor after every classes and some written

reports on the topics.


Attendance more than 70% classes is requisite for evaluation of the credit. The grade is evaluated in the following two items;(1) reports on each

class with learning attitude (40%), (3) term examination or paper or PBL presentation (60%).






http://www.ifm.liu.se/materialphysics/nanoeng/

https://wwwchem.sci.hokudai.ac.jp/~matchemS/


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講義題目 Subtitle Leading and Advanced Biological and Polymer Chemistry and Engineering IB - 2019

責任教員 Instructor 山本拓矢 [Takuya YAMAMOTO] (大学院工学研究院)

担当教員 Other Instructors Michael TURNER (University of Manchester), 佐藤敏文(工学研究院)






polymer chemistry; conjugated polymers; organic electronics; OLEDs, OFETs, solar cells


On successful completion of this course students should be able to: (i) Understand how to prepare conjugated polymers with control of the

microstructure; (ii) Understand how the polymer microstructure influences the polymer electronic and optical properties; (iii) Describe the

operation of light emitting diodes, transistors and solar cells and (iv) Understand how the conjugated polymer microstructure and morphology

can influence the performance of organic electronic and optoelectronic devices.


The goals of the course are to: (i) Provide students with a solid underpinning of the synthetic methods used to prepare conjugated polymers;

(ii) Introduce students to the relationship between conjugated polymer structures and electronic/optical properties; (iii) Provide students with

a basic understanding of how OLEDs, OFETs and OPV device operate and (iv) Enable students to relate the structure of conjugated polymers

to the performance of the material in a device.


1st lecture:

• Introduction to course

• Introduction to polymers

• Introduction to bulk electronic properties

• Organic conductors and applications of conducting polymers

2nd lecture

• Organic semiconductors, applications of conjugated polymers

• Organic electroluminescence, conjugated polymers for OLEDs, device efficiencies.

3rd lecture

• Donor acceptor polymers, polymer blends, thin film morphology

• Conjugated polymers for organic photovoltaics, power conversion efficiencies and figures of merit

4th lecture

• Extended conjugation in conjugated polymers

• Organic electronics and conjugated polymers for OFETs, device performance.

Seminar: Conjugated polymers of many shapes and sizes: rings, chains and nanoparticles.


None


Assignment on a specified subject regarding to "Novel Synthesis of π-Conjugated Polymers" (100 %).

We consider it as the important factor for assessment of three short tests (90%) and final report (10%).


Lecture notes in PDF files will be provided.


References suitable for this course:

(1) M.P. Stevens, Polymer Chemistry - An Introduction, OUP

(2) A. R. West, Basic Solid State Chemistry, Wiley.

(3) W. J. Feast, J. Tsibouklis, K. L. Pouwer, L. Groenendaal, and E. W. Meijer, Polymer, 1996, 37, 5017.

(4) R. H. Friend, R. W. Gymer, Holmes, AB, J. H. Burroughes, R. N. Marks, C. Taliani, D. Bradley, D. A. Dos Santos, J. L. Bredas, M.

Logdlund, and W. R. Salaneck, Nature, 1999, 397, 121-128

(5) D. Braun, Materials Today, 2002, 5, 32-39.

(6) C.D. Dimitrakopoulos, D.J. Mascaro, IBM J. Res. & Dev., 2001, 45, 11.

(Topic II) Thin films and related molecular assembly, organic and biological aspect

Lecture 5: Fabrication of polymer thin films basic and applications

Lecture 6: Two-dimensinal crystal growth of organic molecules on the substrate

Lecture 7: Growth of organic crystals and fibrous aggregates

Lecture 8: Fibrous aggregates of biomacromolecules and its applications

PBL(Problem Based Learning) type discussion will be done in the two topics.


Students will read reviews and the primary literature on each topic, and submit questions for instructor after every classes and some written

reports on the topics.


Attendance more than 70% classes is requisite for evaluation of the credit. The grade is evaluated in the following two items;(1) reports on each

class with learning attitude (40%), (3) term examination or paper or PBL presentation (60%).






http://www.ifm.liu.se/materialphysics/nanoeng/

https://wwwchem.sci.hokudai.ac.jp/~matchemS/


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(7) H. Sirringhaus, Adv. Mater., 2014, 26, 1319-1335.

(8) I. Osaka and R.D. McCullough, Acc. Chem. Res., 2008 41 (9), 1202-1214.

(9) I. McCulloch, M. Heeney, et al. Nat Mater, 2006, 5, 328-333

(10) C. B. Nielsen, M. Turbiez, and I. McCulloch, Adv. Mater., 2013, 25, 1859-1880.

(11) X. Guo, A. Facchetti, and T. J. Marks, Chem. Rev., 2014, 114, 8943-9021.

(12) J. Mei, Y. Diao, A. L. Appleton, L. Fang, and Z. Bao, J. Am. Chem. Soc., 2013, 135, 6724-6746.



https://www.research.manchester.ac.uk/portal/michael.turner.html

http://cma.eng.hokudai.ac.jp/index.html


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講義題目 Subtitle Leading and Advanced Biological and Polymer Chemistry and Engineering IIA - 2019


担当教員 Other Instructors Jianxin LI (Nanjing University), 村上洋太(理学研究院)






Interdiscipline; Natural Products; Bioactivity; Chemical Biology; Drug Target; Discovery


The outline includes an introduction:

1. The main types and major biological activities of natural products.

2. New drugs and drug targets.

3. The intersection of chemistry and biology.

4. The objectives and tasks of chemistry and biology.

5. Examples of bioactive natural products and target discovery.


1. To understand the basics of natural products and the importance of drug discovery.

2. To master the characteristics of chemical biology and its role in human health.

3. To learn the importance of bioactive natural products in the discovery of new drug targets.


Day 1: The bioactive natural products and the importance.

• Introduction of importance of natural products.

• Main types and main bioactivity of natural products.

• Famous natural products closely related to human survival.

Day 2: Chemical biology and drug discovery.

• Basic knowledge on chemical biology.

• The main process of drug discovery.

• Drug target discovery and the relations with human health.

Day 3: The natural product based drug discovery.

• Interactions between bioactive natural products and protein.

• The main method of discovering biological proteins that interact with natural products.

• Drug target validation.

Day 4 & 5: Important samples.

Introduce typical and important examples on natural products and novel drug target discovery.


Scan through a few of the articles in the reading list.


Problem-based learning and assignment on a specific topics of this course (60%).




1. Nature, 561, 189-194, 2018.

2. Biotechnology Advances, 36(6), 1559-1562, 2018.


http://chem.nju.edu.cn/english/facultylr.asp?fln=LI,Jianxin

https://wwwchem.sci.hokudai.ac.jp/~biochem/

http://wwwchem.sci.hokudai.ac.jp/~bo/reseach/


(7) H. Sirringhaus, Adv. Mater., 2014, 26, 1319-1335.

(8) I. Osaka and R.D. McCullough, Acc. Chem. Res., 2008 41 (9), 1202-1214.

(9) I. McCulloch, M. Heeney, et al. Nat Mater, 2006, 5, 328-333

(10) C. B. Nielsen, M. Turbiez, and I. McCulloch, Adv. Mater., 2013, 25, 1859-1880.

(11) X. Guo, A. Facchetti, and T. J. Marks, Chem. Rev., 2014, 114, 8943-9021.

(12) J. Mei, Y. Diao, A. L. Appleton, L. Fang, and Z. Bao, J. Am. Chem. Soc., 2013, 135, 6724-6746.



https://www.research.manchester.ac.uk/portal/michael.turner.html

http://cma.eng.hokudai.ac.jp/index.html


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講義題目 Subtitle Leading and Advanced Biological and Polymer Chemistry and Engineering IIB - 2019

責任教員 Instructor 佐藤敏文 [Toshifumi SATOH] (大学院工学研究院)

担当教員 Other Instructors Guey-Sheng LIOU (National Taiwan University)






functional high-performance polymers, polyimides/metal oxides hybrids, triphenylamine (TPA), optical, electrochromic, and optoelectronic

applications.


This course aims to be a comprehensive, authoritative, and general interest to the polymer chemistry and provides the understanding on (i)

high-performance polymers and their representative nanocomposites (ii) specific functionality and its relations to molecular structures, and

characterization skills of these advanced functional polymers.


Get knowledge on (1) How to prepare and characterize the high-performance polymers and their hybrid films via sol-gel approaches and their

related application; (2) A variety of strategies and approaches for obtaining the high-performance polymers with different specific functions; (3)

The characterizations and relationships between the structural units and functions in the polymer chains and the investigation of some advanced

applications in terms of their unique functionality. Overall, to build up the background in polymer chemistry and related polymeric physical

chemistry.


1st lecture: Highly transparent polyimide hybrids for optoelectronic applications

1. Preparation and modification of polyimides.

2. Functional organic-inorganic hybrid nanocomposites via sol-gel reaction.

3. Titania-, Zirconia-based nanocomposites and AgNws/polymers hybrid film.

2nd lecture: Recent advances in triphenylamine-based electrochromic derivatives and polymers

Triphenylamine-containing electrochromic materials revealing significant color changes by electrochemically induced redox reactions are

attractive with great potential for low energy-consumption displays, light-adapting mirrors in vehicles, and smart window applications. These

materials have experienced an exponential growth of research interests and have rapidly developed into an emerging field. In this lecture, the

newly developed triphenylamine-based derivatives and polymers in the past few years are summarized, with emphasis on the synthetic

approaches as well as their potential applications.

3rd lecture: Triphenylamine-based Materials for Electrofluorochromic Devices

The term "electrofluorochromism (EFC)", which deals with the electrically driven reversible optical changes in the fluorescence, has only

recently been coined by combination of two functions of electrochromism and photoluminescence in one molecular chain. How to design the

materials with both electroactive and PL-active characters are necessary for such interesting application.

4th lecture: Solution-processable triarylamine-based high-performance polymers for polymeric memory devices

By carefully designing the polymeric structures based on the switching mechanisms, different types and memory characteristics can be produced,

and these memory properties show extremely high endurance during long-term operation, which makes these high-performance polymers very

suitable materials for memory applications.

Seminar: Design and Preparation of Triphenylamine-based Polymeric Materials Towards Emergent Optoelectronic Applications


Three short tests and final report


Assignment on a specified subject regarding to "high-performance polymers for advanced applications".




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Recent advances in triphenylamine-based electrochromic derivatives and polymers (Polym. Chem., 2018, 9, 3001-3018)

Highly transparent polyimide hybrids for optoelectronic applications (React. Funct. Polym., 2016, 108, 2-30)

Triarylamine-based high-performance polymers for resistive switching memory devices (Polymer Journal, 2016, 48, 117-138)



http://homepage.ntu.edu.tw/~gsliou/FPML/main.htm

http://poly-ac.eng.hokudai.ac.jp/index.html



講義題目 Subtitle Leading and Advanced Biological and Polymer Chemistry and Engineering IIB - 2019

責任教員 Instructor 佐藤敏文 [Toshifumi SATOH] (大学院工学研究院)

担当教員 Other Instructors Guey-Sheng LIOU (National Taiwan University)






functional high-performance polymers, polyimides/metal oxides hybrids, triphenylamine (TPA), optical, electrochromic, and optoelectronic

applications.


This course aims to be a comprehensive, authoritative, and general interest to the polymer chemistry and provides the understanding on (i)

high-performance polymers and their representative nanocomposites (ii) specific functionality and its relations to molecular structures, and

characterization skills of these advanced functional polymers.


Get knowledge on (1) How to prepare and characterize the high-performance polymers and their hybrid films via sol-gel approaches and their

related application; (2) A variety of strategies and approaches for obtaining the high-performance polymers with different specific functions; (3)

The characterizations and relationships between the structural units and functions in the polymer chains and the investigation of some advanced

applications in terms of their unique functionality. Overall, to build up the background in polymer chemistry and related polymeric physical

chemistry.


1st lecture: Highly transparent polyimide hybrids for optoelectronic applications

1. Preparation and modification of polyimides.

2. Functional organic-inorganic hybrid nanocomposites via sol-gel reaction.

3. Titania-, Zirconia-based nanocomposites and AgNws/polymers hybrid film.

2nd lecture: Recent advances in triphenylamine-based electrochromic derivatives and polymers

Triphenylamine-containing electrochromic materials revealing significant color changes by electrochemically induced redox reactions are

attractive with great potential for low energy-consumption displays, light-adapting mirrors in vehicles, and smart window applications. These

materials have experienced an exponential growth of research interests and have rapidly developed into an emerging field. In this lecture, the

newly developed triphenylamine-based derivatives and polymers in the past few years are summarized, with emphasis on the synthetic

approaches as well as their potential applications.

3rd lecture: Triphenylamine-based Materials for Electrofluorochromic Devices

The term "electrofluorochromism (EFC)", which deals with the electrically driven reversible optical changes in the fluorescence, has only

recently been coined by combination of two functions of electrochromism and photoluminescence in one molecular chain. How to design the

materials with both electroactive and PL-active characters are necessary for such interesting application.

4th lecture: Solution-processable triarylamine-based high-performance polymers for polymeric memory devices

By carefully designing the polymeric structures based on the switching mechanisms, different types and memory characteristics can be produced,

and these memory properties show extremely high endurance during long-term operation, which makes these high-performance polymers very

suitable materials for memory applications.

Seminar: Design and Preparation of Triphenylamine-based Polymeric Materials Towards Emergent Optoelectronic Applications


Three short tests and final report


Assignment on a specified subject regarding to "high-performance polymers for advanced applications".




-122-


講義題目 Subtitle Leading and Advanced Biological and Polymer Chemistry and Engineering IIC - 2019

責任教員 Instructor 及川英秋 [Hideaki OIKAWA] (大学院理学研究院)

担当教員 Other Instructors Tao YE (Peking University)






Natural Products, Organic Synthesis, Stereochemistry, Drug Discovery


Natural products can be broadly defined as the set of small molecules derived from the environment that are not involved in primary metabolism.

Many of today’s small molecule therapeutics trace their origins to natural products, estimated variably as providing or inspiring the development

of between 50–70% of all agents in clinical use today. Although nature provides us with many natural products that have interesting medicinal

properties, the amounts of these compounds that is isolated is usually quite low, making their development into useful medicinal agents very

difficult. The total chemical synthesis of these compounds is therefore important and has been a key tool in drug discovery and development.

The synthesis allows verification of the primary structure proposed on the basis of studies of the marine natural product, and can be employed

to study and address some of shortcomings of natural products through manipulation of pharmacological properties, structure activity

relationship studies, and the preparation of drug candidates for mechanistic studies.



1. understand advanced retrosynthesis principles for the synthesis of complex molecules.

2. have an advanced knowledge about synthetic strategies.

3. make a new synthetic plan for target molecule using selective transformations.

4. understand key principles behind enantio- and diastereoselectivity, and asymmetric approaches.


The aim is to get advanced knowledge for synthesis of natural products.

Retro-synthesis and synthesis of different classes of natural products important for their structure and/or bioactivity. Complex natural products

are chosen to illustrate the evolution of the state-of-the-art of the field.


No required textbooks. Handouts will contain reference to the primary literature. Students need the preparations for discusion about organic

synthesis.

Students will be asked to choose two total synthesis papers on the same natural product. Analyse each route, identify the key steps, and write

a report explaining important aspects of these syntheses.


Assignment on a specified topic regarding to "Total Synthesis of Natural Products" (60%).





Organic Synthesis: The Disconnection Approach, 2nd Edition

Workbook for Organic Synthesis: Strategy and Control

Classics in Total Synthesis: Targets, Strategies, Methods

Classics in Total Synthesis II: More Targets, Strategies, Methods

Classics in Total Synthesis III: Further Targets, Strategies, Methods


http://web.pkusz.edu.cn/ye/

https://wwwchem.sci.hokudai.ac.jp/~yuhan/


-123-


講義題目 Subtitle Leading and Advanced Biological and Polymer Chemistry and Engineering IID - 2019

責任教員 Instructor 松本謙一郎 [Kenichiro MATSUMOTO] (大学院工学研究院)

担当教員 Other Instructors Sudesh KUMAR (Universiti Sains Malaysia)






biobased plastics, biodegradable materials, biosynthesis, biomass


Development of bio-based materials is important and urgent research target as an essential piece of the sustainable social system. Tropical

area plays important role in the biomass production due to its huge capacity of the production. It should be noted that large portion of the

biomass is used for human foods and animal feed, which is also indirectly used for the human food production. In fact, the increasing demand of

animal protein is a serious issue in terms of global food problem. Recently insects attract research interest as a potent solution of the problem.

Based on the background, we should know about the components of edible and non-edible biomass for better design of bio-based material

production. For practical use of the materials, their physical properties are a critical issue. The physical properties of the polymer materials are

determined by structure of the molecules. Thus, fine regulation of synthetic system is required. On the other hand, it should be noted that

biomass is complex mixture and normally is not suitable as starting substance for chemical synthesis. Thus, biological process plays an important

role in the conversion of biomass into useful materials. This lecture focuses on bacterial polyester polyhydroxyalkanote (PHA). PHAs are

processed into film and fiber with pliable property and used as bio-based and biodegradable plastic. In industrial scale production, the cost of

downstream process greatly contributes to the total cost of the production. This course aims to study broad range of field involved in PHA

including feedstock, a basic mechanism of biosynthesis, downstream processes, and polymer chemistry.


1. Know the global problems of food, energy and materials

2. Learn about the biomass production

3. Learn the biological and chemical methods to utilize biomass resources

4. Understand the basic biology and chemistry of polyhydroxyalkanoates

5. Know about the latest technology using insects


1. Introduction to the concept of sustainability

2. Life: from microbe (single cell) to human and impact on resources (food, energy, materials)

3. Single cell protein (SCP) and other sources of protein

4. Problems caused by plastics

5. Introduction to PHA: synthesis and properties

6. Challenges in the large scale production of PHA

7. Applications of PHA (environment, medical, diagnostics, cosmetics)

8. Sustainable production of PHA


Students will be expected to download class notes using ELMS and read designated chapter in advance.

You will be asked to write a page (A4) of essay at the end of each lecture.


Your grade will be determined by how well you demonstrate your achievement of the course goals in the report.





https://bio.usm.my/staff/k-sudesh-kumar-professor/

https://labs.eng.hokudai.ac.jp/labo/seika/



講義題目 Subtitle Leading and Advanced Biological and Polymer Chemistry and Engineering IIC - 2019

責任教員 Instructor 及川英秋 [Hideaki OIKAWA] (大学院理学研究院)

担当教員 Other Instructors Tao YE (Peking University)






Natural Products, Organic Synthesis, Stereochemistry, Drug Discovery


Natural products can be broadly defined as the set of small molecules derived from the environment that are not involved in primary metabolism.

Many of today’s small molecule therapeutics trace their origins to natural products, estimated variably as providing or inspiring the development

of between 50–70% of all agents in clinical use today. Although nature provides us with many natural products that have interesting medicinal

properties, the amounts of these compounds that is isolated is usually quite low, making their development into useful medicinal agents very

difficult. The total chemical synthesis of these compounds is therefore important and has been a key tool in drug discovery and development.

The synthesis allows verification of the primary structure proposed on the basis of studies of the marine natural product, and can be employed

to study and address some of shortcomings of natural products through manipulation of pharmacological properties, structure activity

relationship studies, and the preparation of drug candidates for mechanistic studies.



1. understand advanced retrosynthesis principles for the synthesis of complex molecules.

2. have an advanced knowledge about synthetic strategies.

3. make a new synthetic plan for target molecule using selective transformations.

4. understand key principles behind enantio- and diastereoselectivity, and asymmetric approaches.


The aim is to get advanced knowledge for synthesis of natural products.

Retro-synthesis and synthesis of different classes of natural products important for their structure and/or bioactivity. Complex natural products

are chosen to illustrate the evolution of the state-of-the-art of the field.


No required textbooks. Handouts will contain reference to the primary literature. Students need the preparations for discusion about organic

synthesis.

Students will be asked to choose two total synthesis papers on the same natural product. Analyse each route, identify the key steps, and write

a report explaining important aspects of these syntheses.


Assignment on a specified topic regarding to "Total Synthesis of Natural Products" (60%).





Organic Synthesis: The Disconnection Approach, 2nd Edition

Workbook for Organic Synthesis: Strategy and Control

Classics in Total Synthesis: Targets, Strategies, Methods

Classics in Total Synthesis II: More Targets, Strategies, Methods

Classics in Total Synthesis III: Further Targets, Strategies, Methods


http://web.pkusz.edu.cn/ye/

https://wwwchem.sci.hokudai.ac.jp/~yuhan/


-124-


講義題目 Subtitle Leading and Advanced Biological and Polymer Chemistry and Engineering III - 2019


担当教員 Other Instructors 小松﨑民樹(電子科学研究所), 髙橋正行(理学研究院), 清水洋平(理学研究院),

高橋幸裕(理学研究院), 小門憲太(理学研究院), 吉田将己(理学研究院)






生化学, 生物物理学, 分子生物学, 有機化学, 物理化学, 錯体化学, 高分子化学


1) エレクトロニクスのための機能素材の合成法を知る。

2) 温度応答性ポリマーの基本知識・分子デザイン・応用を知る。

3) 可逆的刺激応答性を示す金属錯体の詳細を知る。

4) 機能性ディスオーダー・分子個性として知られる、一分子生物学の最先端の成果を知る。

5) 新規分子変換における触媒の可能性を知る。

6) 細胞運動の分子基盤と非筋細胞ミオシンⅡの細胞運動における機能を知る。

7) ゲノムにおけるエピジェネティク制御の基礎と iPS 細胞作成・細胞がん化における役割を知る。


この講義の終了時には以下の事を理解することを目標とする。

1. 有用な分子や素材を作るための化学的基礎

2. 生細胞内での反応の分子機構と生体分子の動きを研究するための方法

3. 構造有機化学の基礎と展開


１日目

新規分子変化のための触媒（清水洋平）

２日目

温度応答性ポリマーの基礎理論と分子設計（小門憲太）

エレクトロニクスのための機能素材の合成法（高橋幸裕）

３日目

化学的刺激応答性を示す金属錯体（吉田将己）

細胞運動の分子基盤と非筋ミオシンⅡのアイソフォームの異なる機能（高橋正行）

４日目

一分子生物学の最先端：機能性ディスオーダーと分子個性（小松﨑民樹）

ゲノムのエピジェネテック制御の基礎と iPS 細胞や細胞がん化での機能（村上洋太）

５日目

総合討論（村上洋太）


N/A


二つの講義に関するレポート (100%)








推奨講義（この講義とともにとることを推奨する）

Leading and Advanced Biological and Polymer Chemistry and Engineering IA, IB

Leading and Advanced Biological and Polymer Chemistry and Engineering IIA, IIB, IIC, IID

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科目名 Course Title 総合化学特別研究第二 [Research in Chemical Sciences and Engineering II]

講義題目 Subtitle




期間 Semester 通年不定期単位数 Number of Credits 1




物理化学，無機分析化学，有機化学，生物化学，物質化学，有機プロセス工学，生物機能高分子


外国人を主体とした研究者（ゲストスピーカー）よる主に英語での最先端の専門領域研究についての講演を講義に取り入れ，国際的な

研究活動を行うために必要な能力を養う。


複数の外国人ゲストスピーカーに化学の様々な分野における最先端の研究成果を英語で紹介してもらうことにより，化学研究における

国際的感覚を養う。英語で討議を行うことにより，国際会議等におけるディスカッション能力を養う。


以下に示す化学の幅広い分野において，先端的な研究を展開している外国人研究者より直接英語で講義を受け，広い視野を身につけ

る。各講義において英語によるディスカッションを行い，国際研究発表の場において相手の考えを理解し，自分の考えを論理的に説明

する能力を身につける。

１．物理化学領域（理論化学，表面科学，分光学，電気化学，触媒化学，クラスター化学）

２．無機分析化学領域（希土類，アクチノイド，光化学，錯体化学）

３．有機化学領域（有機構造化学，合成化学，天然物化学，有機金属化学，生物活性天然物）

４．生物化学領域（タンパク質の機能と制御，生命現象の分子機構，生物物理化学）

５．物質化学領域（セラミックス，炭素材料，複合材料の設計，エネルギー材料）

６．有機プロセス工学領域（有機材料，有機工業化学，化学工学，反応工学）

７．生物機能高分子領域（生物工学，機能化学，動物細胞工学，バイオテクノロジー）


講演内容について疑問を残さないように、講演終了後に講師に質疑を行う。


原則として、学修態度(20％)、レポート(80％)によって評価する。







講義題目 Subtitle Leading and Advanced Biological and Polymer Chemistry and Engineering III - 2019


担当教員 Other Instructors 小松﨑民樹(電子科学研究所), 髙橋正行(理学研究院), 清水洋平(理学研究院),

高橋幸裕(理学研究院), 小門憲太(理学研究院), 吉田将己(理学研究院)






生化学, 生物物理学, 分子生物学, 有機化学, 物理化学, 錯体化学, 高分子化学


1) エレクトロニクスのための機能素材の合成法を知る。

2) 温度応答性ポリマーの基本知識・分子デザイン・応用を知る。

3) 可逆的刺激応答性を示す金属錯体の詳細を知る。

4) 機能性ディスオーダー・分子個性として知られる、一分子生物学の最先端の成果を知る。

5) 新規分子変換における触媒の可能性を知る。

6) 細胞運動の分子基盤と非筋細胞ミオシンⅡの細胞運動における機能を知る。

7) ゲノムにおけるエピジェネティク制御の基礎と iPS 細胞作成・細胞がん化における役割を知る。


この講義の終了時には以下の事を理解することを目標とする。

1. 有用な分子や素材を作るための化学的基礎

2. 生細胞内での反応の分子機構と生体分子の動きを研究するための方法

3. 構造有機化学の基礎と展開


１日目

新規分子変化のための触媒（清水洋平）

２日目

温度応答性ポリマーの基礎理論と分子設計（小門憲太）

エレクトロニクスのための機能素材の合成法（高橋幸裕）

３日目

化学的刺激応答性を示す金属錯体（吉田将己）

細胞運動の分子基盤と非筋ミオシンⅡのアイソフォームの異なる機能（高橋正行）

４日目

一分子生物学の最先端：機能性ディスオーダーと分子個性（小松﨑民樹）

ゲノムのエピジェネテック制御の基礎と iPS 細胞や細胞がん化での機能（村上洋太）

５日目

総合討論（村上洋太）


N/A


二つの講義に関するレポート (100%)








推奨講義（この講義とともにとることを推奨する）

Leading and Advanced Biological and Polymer Chemistry and Engineering IA, IB

Leading and Advanced Biological and Polymer Chemistry and Engineering IIA, IIB, IIC, IID

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科目名 Course Title 総合化学研究・指導法 [Research in Chemical Sciences and Engineering III]

講義題目 Subtitle

責任教員 Instructor 武次徹也 [Tetsuya TAKETSUGU] (大学院理学研究院)

担当教員 Other Instructors 担当は主任指導教員


期間 Semester 通年単位数 Number of Credits 2

授業形態 Type of Class 演習対象年次 Year of Eligible Students 1～3



実験法の改良・開発実験指導法成果とりまとめとプレゼンテーション技法論文執筆化学英語


博士研究を遂行するにあたって必要となる実験手法・技法の改良や開発、研究成果の取りまとめとプレゼンテーション法、英語による論

文執筆の進め方等を系統的に学習し、実験・研究指導者となるための実践的知識と能力を養う。


博士学位取得者として備えるべき研究開発能力やプレゼンテーション能力、成果取りまとめ能力、分野開拓能力等を実践的に養う。


博士課程における各学年において、大学院生の研究・学習の進捗状況に応じて適宜、以下の指導を行うことにより、授業の目標を達成

する。

１）研究テーマに関する研究計画、計画を遂行するための実験手法の改良・開発に関する課題を与え、その取り組み状況に応じて適切

なアドバイスを与え、より大きな成果が上がるよう指導する。必要に応じ、適宜、レポート提出を求めるとともに、実験・研究指導を行う。

２）研究結果の取りまとめ、プレゼンテーション法の技術的・科学的指導を行う。特に、論理的に研究成果をまとめ、その成果を客観的か

つ明確にプレゼンテーションする技法の指導を行う。

３）英文を含めた論文執筆法の指導を行う。研究成果を論理的に整理し、適切な取りまとめを通して、科学技術論文として発表を行うこと

のできる能力を養う。日本語・英語ともに、適切な論文取りまとめができる能力を養う指導を行う。

このような取り組みを通して、博士取得者としての新たな実験法の開発能力や総合的な問題解決能力・指導力を涵養する。


与えられた課題に対し、次の実験・研究段階に進むための十分な準備学習。


日常的な取り組みと定期的なレポート作成（50％）、取り組みの成果等（50％）を総合的に評価する。






博士後期課程【選択科目】...techniques 授業の目標 Course Objectives By the end...

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Transcript of 博士後期課程【選択科目】...techniques 授業の目標 Course Objectives By the end...

博 士 後 期 課 程 【選択科目】...techniques 授業の目標 Course Objectives By the end...

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Transcript of 博 士 後 期 課 程 【選択科目】...techniques 授業の目標 Course Objectives By the end...

博士後期課程【選択科目】...techniques 授業の目標 Course Objectives By the end...

Transcript of 博士後期課程【選択科目】...techniques 授業の目標 Course Objectives By the end...