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T h e s e s a m p l e s *ere o r i g i n a l l y r e c e i v e d a s l o w c o n c e n t r a t i o n s e d i m e n t s a m p l e s ,but the h i g h c o n c e n t r a t i o n o f c o m p o u n d s in the s a m p l e s made i t nec e s sary toa n a l y z e a l l t h r e e a s "medium" l e v e l s a m p l e s . Once a g a t n l i n s t r u m e n t t i m e w a sl o s t d u e t o t h i s i n c o r r e c t a s s i g n m e n t o f c o n c e n t r a t i o n l e v e l s .T h e V O A f o r s a m p l e 7720 w a s p a r t i c u l a r l y a l a r m i n g , a s i t l o ok ed a l m o s t l i k ea s t a n d a r d m i x , a n d c o n t a i n e d b o t h v i n y l c h l o r i d e a n d a c r o ' i e i n , w h i c h w er a r e l y f i n d . I n t h e b a s e / n e u t r a l f r a c t i o n , N - n i t r o s o d i p h e n y l a m i n e w a s d e t e c t e d( b e l o w t h e d e t e c t i o n l i m i t ) a s d i p h e n y l a m i n e .I t s h o u l d a l s o b e no t ed t h a t a l l o f t h e b a s e / n e u t r a l f r a c t i o n s were c o n c e n t r a c e dt o a f i n a l v o l u m e o f 1 0 m l , ba s ed o n t h e F I D s c r e e n i n g r e s u l t s .

T h e p e s t i c i d e f r a c t i o n h a d h i g h e r d e t e c t i o n l i m i t s ( 1 ^ g / g f o r p e s t i c i d e s ;1 0 f o r P C B ' s ) d u e t o i n t e r f e r e n c e s w h i c h c o u l d n o t b e removed b y t h e d i f f e r e n tc l e a n - u p p r o c e d u r e s .A n i n t e r e s t i n g p o i n t i s t h a t t h e B / H f r a c t i o n o f s a m p l e s 7721 a n d p o s s i b l y 7722a p p e a r e d t o have coal t a r c r e o s o t e s p r e s e n t , t y p i f i e d b y h i g h n a p h t h a l e n e a n dt h e p r e s e n c e o f v a r i o u s p o l y n u c T e a r s .I f th ere a r e a n y q u e s t i o n s , p l e a s e g i v e u s a c a l l .S i n c e r e l y , /

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J - I n d i c a t e s an e s t i m a t e d vaJue «/hich is used when e s t i m a t i n ga c o n c e n t r a t i o n ( o r t e n t a t i v e l y i d e n t i f i e d c o m p o u n d s ; e.g..1 2 0 0 J . I V f o o t n o t e s h o u l d read: 5 - E s t i m a t e d va lue .

Other - O t h e r i p « * c ; l i c I ' U g s a n d f o o t n o t e s n a y b e r e q u i r e d < op r o p e r t y d e f i n e t ! ' " r«3ul«. I f u S e i l . t h e y mult 6 < - f , j , ! yd e s c r i b e d ;n j page a t t o r h i j d to the da ta \ u f n m a / y r e p o r t .

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DIOXINS CJ^.'OI i •

Data R e p o r t i n g Q u a l i f i e r s

F o r r e p - i r r i n f l r p i , , i t ^ t o E P A , r h cD e f i n i t i o n o f luch f U g J must b « e x p l i < J l

. j . . . i h l t . ( . j i < : u ' . n l . f u i u i l s dre encouraged.

VaJue - If the r e s u l t is a v a j u r t grea t er than or equal to thel i m i t , report the value.U

F S

compound **s a n a l y z e d toe but not d e t e c t e d .Report t h e minimum d e t e c t i o n l i r m t v a J u e w i t h t f i e U ,e.g., iOU. rhe f o o t n a t e ihould read: U - Compound*ai ani lyzed for but not d e t e c t e d . The number is theminimum d e t e c t i o n l i m i t .

- If t rw m*5l s p e c t r a l d a t a i n d i c a t e th e p r e s e n t r ,) f 4cort.pound t h a t ' n ^ e i s t h e I ' i c n n l i c . i n o n t r t t c r i a :iutt h e q u a n t i t i t w e r e ^ ; i K i s ( C M than f h f M V M i ( i c . | J i - n - r .lion l i m i t but grea t er than *ero, report rhe r t i - f r c d o nl i r r n l a ^ K , «.&., | O K . T h e l i x m i o t e i J ; o u l d . - c j d : K -A c t u a l « t » l ' i < - , ' f c i l h i n C n ' l i m i t . U u m i o ( ' ^ ' - \ T i i M l i o - f , i ilew than t f - e waiv,c 51* en,

- u t i c jT u n l U j f i p p i . e s t o a n a l y s i s pt:r(*-rnn.-<l h yC a p i l l a r y Coiumn.

J * I n d i c a t e s an e s t i m a t e d value u / h i c h is used when e s t i m a t i n ga c o n c e n t r a t i o n (or t e n t a t i v e l y i d e n t i f i e d c o m p o u n d s ; e.g.,I 2 C Q J . f h e f o o t n o t e should read: J - E s t i m a t e d value .

Other - Other s p e c n i c f l a g s and f o o t n o t e s may be required top r o p e r l y d e f i n e t h » r e s u l t s . I t nied. they m i j j t b e f u i l yd e s c r . b ed i n j p n f j p a t t a c h e d t o t h e - J a t a n u m m a r y r e p o r t .

*• - Trm fUg a p p l i e s to p e s t i c i d e s parame t e r s *here (he i d c < - t i -, n ' j e e n p e r f o r m e d u i ing t w o column ^ o n f i r n i j t . o nicv* m M e t h o d 60S) but the level u [jo :c>«* : /

n 1.1,' ( l i e compound by »nj.« s p e c t r o m e t r v .CX T h i s f ! . i R i s

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C A S *T E N T A T I V E L Y I D E N T I F I E D C O M P O U N D S

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F u r . ' • • ; ; • * • ' • • ' " • % r c t u l l i 1 0 L P A , l t > C f u i l u w i i ^ . ' • . - i nOf, r,,;. . jr o f such ( l a g s T i u i t (xt e n p l i n r however.

y i u r l < . x J i n o t t i e x p l a i n i n g r e s u l t s t * j e

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If the r e i u j t i t a value greater thande t e c t i on l i m i t , repon th* ^alue. (o the

I n d i c a t e s compound * a j a n a l y z e d f o e t x j t n o t a e ; e c t e d .Report t h e ,-nmimum d e t e c t i o n i i f n i l vaiue witr. t h e U ,e.g., I O U . The f o o t n o t e i h o u J d read: U - Compound*/*3 a n a l y z e d /or t x j t no t d e t e c t e d . The number t s the

de t e cnon h m i t .i f t h e maw s p e c t r a l d a t a i n d i c a t e tne r > ' c s e n t - «compound t h a t "i«ts t h e n J c n t t f i c - i ' i o n . r i t e . - .(he q v ^ n t i t a t j v c f e ^ u i t i s lc"J than the - . o e c i J i e d vil i m i t txit g r e a t e r than j r e r o , rrp->r- ih*

j . i K . e.g.. l O K . T h e t o u t i n j t e iri: ui;| r , ; . n J : K -u d l ^ d l ' ! * 1 , i , , tn:n C - e ( u n i t j t ; . - r n o f ' ! • • . ' n . - t ! u . l , i i

t h a n i f * v j u , c i?i»en.

an e s t i m a t e d value *hich is used when e s t i m a t i n gj i o n r c - i t r . i t i o n ( o r t e n t a t i v e l y i d e n t i M e - d c O f t i p o u n d j ; *.£.,I200J. The (ootno-e should read: 1 - E s t i m a t e d

Other - Other s p e c i f i c ( l a g s and f o o t n o t e s may be required top r o p e r l y t i e / t r i e i > * r e s u l t s . I f u S * d , t h e y mgit b e f j i i yd e s c r : t ) e d in j p a j j i - , i t t - i r h e d 1C th e Ufa s u r n m d r y r e p o r t .

•* - T h i s Mag a p p l i e s 10 p e s t i c i d e s p a r a m e t e r ) *hcre the i d e n t i -f i c a t i o n ! u t been p e r f o r m e d J b i n g t w o co lumn c o n f i r m . i t . o n( a s V L V . d e d . ; n M e t h o d 6 ( J 3 ) O u t i h c l eve l i s t o o ' u a : . j -

f the compound by T i j t s s p c c t r o m e t r y ..vhicMi - ^ . . i c ' l ^ Q indn-; i ;< ' h o s e

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N a m e :QC Report No;

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C A S f

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^ ^ ^ T O E N T I F I E D C O M P O U N D SC O M P O U N D N A M E % Maximum Score AttainedFrac t i on Mass M a t c h i n g R o u t i n e a I n c o s

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F R E N C H L I M I T E DA B A N D O N E DH A Z A R D O U S W A S T E D U M P S f T EC R O S B Y , T E X A S

L o c a t i o n o f S a r n p H n g S i t e sr&rxs as

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