UNIT 4: Stoichiometry (or Baking Cookies)

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UNIT 4: Stoichiometry (or Baking Cookies) Section 1: Percent Composition and Molar Mass Section 2: Empirical Formulas Section 3: Dimensional Analysis Section 4: The Mole Concept Section 5: Avogadro’s Number Section 6: Mole Ratios & Theoretical Yield Section 7: Limiting Reactants Section 8: Percent Yield Section 9: “Other” Stoichiometry Problems

Transcript of UNIT 4: Stoichiometry (or Baking Cookies)

Page 1: UNIT 4: Stoichiometry (or Baking Cookies)

UNIT 4: Stoichiometry (or Baking Cookies)Section 1: Percent Composition and Molar Mass

Section 2: Empirical Formulas

Section 3: Dimensional Analysis

Section 4: The Mole Concept

Section 5: Avogadro’s Number

Section 6: Mole Ratios & Theoretical Yield

Section 7: Limiting Reactants

Section 8: Percent Yield

Section 9: “Other” Stoichiometry Problems

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UNIT 4 SynapsisIn the previous unit we explored chemical reactions and how they must be balanced because of

the law of conservation of mass. We also explored molecules and Ionic compounds and how these substances are often represented using a chemical formula.

In this Unit we will further explore the law of conservation of mass. This time, we will look at it more mathematically.

We will start slowly by looking at the percentage that each element contributes to a substance. After that we will look at reducing molecular formulas.

Next, we will look at one of the fundamental concepts in chemistry; the mole. The mole is the measuring cup of nature, it’s how we determine proportionality in chemical reactions.

The proportionality of chemical reactions and how the mole is used to represent those proportions is the focus of Section 6,7,8, & 9.

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Section 1: Percent Composition & Molar Mass

This part of the Unit is covered on pages 341-342 in your textbook

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Section 1: Percent Composition and Molar Mass / Objectives

“After this lesson I can…

• …calculate the molar mass of a given substance.”

• …determine the percent composition for a given substance when provided it’s chemical formula.”

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Molar Mass• The molar mass is the sum total of all the average atomic masses for all the atoms in a given

substance.

• This is simple and rather incorrect definition for molar mass but it works for now. Later on we will look at the more accurate and more important definition.

• Example #1: C6H12O6

• C: 6 × 12.01 = 72.06

• H: 12 × 1.01 = 12.12

• O: 6 × 16.00 = 96

• (72.06 + 12.12 + 96) = 180.18Molar mass of C6H12O6

• Example #2: Na3PO4

• Na: 3 × 22.99 = 68.97

• P: 1 × 30.97 = 30.97

• O: 4 × 16.00 = 64.00

• (68.97 + 30.97 + 64.00) = 163.94molar mass of Na3PO4

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Practice Problems: Molar Mass Directions: Calculate the molar mass for the following molecules and compounds and do it with a smile!

1) Lithium Nitrate: LiNO3

2) Magnesium Fluoride: MgF2

3) Dinitrogen Tetraoxide: N2O4

4) Iron(III) Carbonate: Fe2(CO3)3

5) Caffeine: C8H10N4O2

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Percent Composition• The percent composition of a molecule or compound is the percentage that each element in the

molecule or compound contributes to the molar mass.

• To find the percent composition of a given substance you just take each elements contribution and divide it by the molar mass. You have to convert the decimal to a percent of coarse.

• Example #1: C6H12O6

• C: 6 × 12.01 = 72.06 / 180.18 = .3999 or 39.99% Carbon

• H: 12 × 1.01 = 12.12 / 180.18 = .0673 or 6.73% Hydrogen

• O: 6 × 16.00 = 96 / 180.18 = .5328 or 53.28% Oxygen

• (72.06 + 12.12 + 96) = 180.18 Molar mass of C6H12O6

• Example #2: Na3PO4

• Na: 3 × 22.99 = 68.97 / 163.94 = .4207 or 42.07% Sodium

• P: 1 × 30.97 = 30.97 / 163.94 = .1889 or 18.89% Phosphorus

• O: 4 × 16.00 = 64.00 / 163.94 = .3904 or 39.04% Oxygen

• (68.97 + 30.97 + 64.00) = 163.94 molar mass of Na3PO4

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Practice Problems: Percent CompositionDirections: Determine the Percent Composition for the following molecules and compounds.

1) Lithium Nitrate: LiNO3

2) Magnesium Fluoride: MgF2

3) Dinitrogen Tetraoxide: N2O4

4) Iron(III) Carbonate: Fe2(CO3)3

5) Caffeine: C8H10N4O2

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Section 1 Additional Resources & Links…• Tyler Dewitt’s Video: “Percent Composition by Mass”

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Section 2: Empirical Formulas

This part of the Unit is covered on pages 344-350 in your textbook

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Section 2: Empirical Formulas / Objectives

“After this lesson I can…

• …determine the empirical formula of a substance when provided it’s molecular formula.”

• …calculate the empirical formula of a substance when given it’s percent composition.”

• …calculate the empirical formula of a substance when given the masses for the elements in that substance.”

• …determine the molecular formula for an unknown substance when given it’s molar mass and 1 of the following

• Empirical formula

• Percent composition

• Masses of elements”

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Empirical Formula Defined• The chemical formula (a.k.a. molecular formula) of a substance is the number and kinds of atoms

that make up a molecule or ionic compound.

• Empirical formula is a math manipulation of the molecular formula. It is just the molecular formula reduced to it’s lowest whole numbered ratios.

• Examples

• Molecular formula: C5H10 has the empirical formula: CH2

• Molecular formula: C4H8 has the empirical formula: CH2

• Molecular formula: C3N12 has the empirical formula: CN4

• Molecular formula C6H12O6 has the empirical formula: CH2O

• Not all molecular formulas can be reduced. Sometimes a molecular formula is not reducible and so the molecular formula and empirical formula are the same.

• Examples of those include: P3N5 & C5H12

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Practice Problems: Empirical Formula from Molecular FormulaDirections: Determine the empirical formula for the following molecules. If the molecule’s chemical formula cannot be reduced write “cannot be reduced”

1) N2O4

2) C6H12

3) C2H6O

4) C8H10N4O2

5) P2F4

6) P4O10

7) C6H18O3

8) S5N6

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Why Empirical Formulas are Important (or they used to be)• A long time ago, a big part of chemistry was doing experiments to determine what the percent

composition of a given substance was.

• Basically, early chemists were curious what elements made a thing up! They developed a lot of different methods, techniques, and experiments for doing this.

• Once they got the percent composition, they used to it to determine the empirical formula. The empirical formula could then be used to gain additional information about the molecule or compound. When combined with additional experiments, they could often decifer the molecular formula from the empirical one.

• This practice of going from percent composition to empirical formula and then to molecular formula via a series of experiments is totally obsolete. We can get to molecular formula of a pure substance pretty quickly these days using tools and instruments developed specifically for this purpose during the last 50 or so years. Still, they make you do the math exercise (often without doing the actually experiments) in high school chem (sorry).

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Steps to get to Empirical Formula from Percent Composition1) Divide each elements percentage by it’s average atomic mass. Doing this gives you something

called the “moles.” (more on the moles later)

2) Find the mole ratios; Take the lowest number of moles from step 1 and divide the other numbers by it.

3) If the answers from step two are reasonably close to whole numbers, round them to whole numbers. Those are the subscripts for each element. If they are not, multiply to get whole numbers.

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Practice Problems: Empirical Formula from Percent Composition

“Find the empirical formula for a compound which contains 32.8% chromium and 67.2% chlorine?”

“What is the empirical formula for a compound that contains 26.1% carbon, 4.3% hydrogen and 69.6 % oxygen?”

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Why Empirical Formulas are Important (or they used to be)• Some of the earlier techniques for finding empirical formula actually determined how many grams of

each element was in a substance and not the given percentage.

• If you have the grams of each element in a given substance, you can find the empirical formula using the exact same set of steps you would use if you had the percentage.

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Practice Problems: Empirical Formula from Mass

“What is the empirical formula for a compound that contains 5.28g of Tin and 3.37g of Fluorine?"

“If a sample of ethyl butyrate is known to contain 0.62069 g of carbon, 0.103448 g of hydrogen and 0.275862 g of oxygen, what is the empirical formula for ethyl butyrate?”

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Why Empirical Formulas are Important (or they used to be)• As mentioned earlier, once a chemist had the empirical formula she could run another experiment or

analysis to determine the molar mass. When she had both the molar mass and the empirical formula she could determine the molecular formula.

• Lets do a few of those problems now.

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Practice Problems: Molecular formula from Empirical & Molar Mass

“A substance is analyzed and found to have the empirical formula CH2. If the molar mass is found to be approximately 84 g/mol, what is the molecular formula?”

“A substance is analyzed and found to have the empirical formula NBr2. If the molar mass is found to be approximately 347.6 g/mol, what is the molecular formula?”

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Practice Problems: Molecular formula from Empirical & Molar Mass

“A substance is analyzed and found to have to be 44.9% Phosphorus & 55.1% Fluorine. If the molar mass is found to be approximately 137.9 g/mol, what is the molecular formula?”

“A substance is analyzed and found to contain 50 mg Carbon, 8.33 mg Hydrogen, & 66.7 mg Oxygen. If the molar mass is found to be approximately 60 g/mol, what is the molecular formula?”

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Empirical Formula & Percent Composition Concept Map

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Section 2 Additional Resources & Links…• Tyler Dewitt’s Video: “Empirical Formula and Molecular Formula Introduction”

• Tyler Dewitt’s Video: “Calculating Molecular Formula from Empirical Formula: Part 2”

• The Organic Chemistry Tutor’s Video: “Empirical Formula Given Grams and & Mass Percent Composition, Molecular Formula Determination”

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Section 3: Dimensional Analysis

This part of the Unit is covered on pages 44-46 in your textbook

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Section 3: Dimensional Analysis / Objectives

“After this lesson I can…

• …identify the conversion factor(s) in a given problem or find the conversion factor(s) in reference materials.”

• …use dimensional analysis to solve single and multi-step problems (particularly mole problems)”

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Dimensional Analysis• Dimensional Analysis is a lot easier than it sounds and if you are familiar with “fence posting” if you

done it already.

• I like to think of dimensional analysis as a technique for converting between units or solving problems.

• This technique is especially useful when more units have to be converted in successive steps, like when you have to go to pounds to kilograms and then to grams.

• Dimensional Analysis is about canceling out units until you arrive at your desired unit (the answer).

• It is also very useful for things like physics and engineering and those of you who go on to take those classes will be re-introduced to the dimensional analysis technique.

• I will teach you the simpliest set of steps to do it. In your math class, you will see a more advanced and more valuable way of doing D.A.

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Steps for Using Dimensional Analysis1) Identify the conversion factors you need to use and write them off to the side using an equal sign.

2) Write down the quantity & unit you are starting with.

3) Next to the quantity you are starting with, draw a number of “fence posts” equal to the number of

conversion factors you are using (example: 3 conversion factors needs 3 fence posts, 5 conversion

factors needs 5 fence posts). Keep in mind some teachers like parenthesis and fractions instead of

fence posts but it’s the same idea.

4) Find the conversion factor you need to cancel out the unit that you started with and then write that

conversion factor as a fraction in the first fence post. Put the canceling unit in the denominator and

the other unit in the numerator (Remember: “Whatever comes up, must come down”)

5) Repeat step 4 with subsequent conversion factors until you have arrived at the unit the question is

asking for.

6) Cancel out units and multiply all fractions.

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Practice Problems: Dimensional Analysis

“The guy at the game store will give you 1 PS4 game for 3 xbox games. How many PS4 games can you get with 15 xbox games?”

“6 bags of chips can be traded for 4 Gatorades. 24 Gatorades can be traded for 2 pizzas. How many pizzas can you get with 138 bags of chips?”

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Practice Problems: Dimensional Analysis

“A car is travelling at 64 miles per hour. If there is 1.6 km in 1 mile, 3,380 feet in 1 km, and 3.3 feet in 1 yard, how many yards will the car travel in 3.4 hours?”

“Game tokens are 100 for a dollar. The crane game takes 25 tokens. If you play the crane game 2 times you win 5 pieces of candy. It takes 12 pieces of candy to make you sick for 2 hours. How many hours are you going to be

sick if you have 9 dollars?”

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Section 3 Additional Resources & Links…• Tyler Dewitt’s Video: “Understanding Conversion Factors”

• Tyler Dewitt’s Video: “Converting Units using conversion Factors”

• Tyler Dewitt’s Video: ”Converting Units using Multiple Conversion Factors”

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Section 4: The Mole Concept

This part of the Unit is covered on pages 325-340 in your textbook

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Section 4: The Mole Concept / Objectives

“After this lesson I can…

• …convert between grams and moles.”

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Moles• Moles measures the amount of something. A lot of you are used to thinking of grams, pounds, or

volume as how “much” of something you have but really how “much” of something you have is measured in moles.

• It’s moles because moles measures the total number of particles.

• Volume measures the space an object takes up.

• Mass technically measures the object’s resistance to acceleration.

• Moles measures the amount of an object.

• In 1 mole of a thing, there are 602,000,000,000,000,000,000,000 particles of that thing.

• Particles could be molecules if you are dealing with molecules, it could be atoms if you are dealing with a pure element like a block of iron, or it could be “unit cells” of an ionic compound (recall because ionic compounds have a crystal lattice we usually don’t refer to them as molecules)

• Luckily converting between the grams and moles of substance is simple; molar mass is your conversion factor! Molar mass is defined as how many grams there are in one mole.

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Practice Problems: Mole Conversions

“How many moles of Water in 111 grams?”

“How many moles of C6H12O6 in 250 grams of C6H12O6?”

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Practice Problems: Mole Conversions

“Suppose you have 4.3 moles H2O, How many grams is this?”

“Calculate the number grams in .044 moles of CrPO4.”

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Section 4 Additional Resources & Links…• Tyler Dewitt’s Video: “Converting Between Grams and Moles:”

• Tyler Dewitt’s Video: “Converting Between Grams and Moles: Part 2”

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Section 5: Avogadro’s Number

This part of the Unit is covered on pages 320-324 in your textbook

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Section 5: Avogadro’s Number / Objectives

“After this lesson I can…

• …convert between moles and number of particles.”

• …solve multi-step problems involving Avogadro’s number”

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Avogadro’s Number• As previously stated, in one mole of a substance there are 6.02 × 1023 particles of that substance.

• Particles could mean molecules, “formula units” in the case of ionic compounds, or atoms in the case of pure substances.

• The number 6.02 × 1023 is known as Avogadro’s number. It’s named in honor of Ameado Avogadro who did early experiments with gases.

• Usually when doing chemistry you just leave things in moles, but if you want to know how many particles there are in anything, get it into moles and then use the conversion factor:

1 mole = 6.02 × 1023 particles.

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Video Time !!!

• TedEd Video: “How Big is a Mole”

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Practice Problems: Avogadro’s Problems

“How many molecules of Water in 11.45 moles?”

“How many Aluminum atoms in a piece of Aluminum foil that contains 15.1 moles?”

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Practice Problems: Avogadro’s Problems

“How many molecules of Carbon Dioxide in .00045 moles?”

“How many moles of NO2 in 2.22 × 1025 molecules?”

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Practice Problems: Avogadro’s Problems

“Suppose a mineral has 2.22 × 1021 units of CuCO3, How many moles of Copper Carbonate in the mineral?”

“How many moles of Dinitrogen Tetroxide in 2.22 × 1025 molecules?”

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Practice Problems: Avogadro’s Problems

“How many molecules of Water in 250 grams?”

“How many Aluminum atoms in a piece of Aluminum foil that has a mass of 155 grams?”

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Practice Problems: Avogadro’s Problems

““Suppose a mountain has 2.22 × 1027 units of CuCO3, How many grams of Copper Carbonate in the mountain?”

“How many Hydrogen atoms in in 155 grams of CH4?”

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Section 5 Additional Resources & Links…• Tyler Dewitt’s Video: “Converting Between Moles, Atoms and Molecules”

• Tyler Dewitt’s Video: “Converting Between Moles, Atoms, and Molecules Part 2”

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Section 6: Mole Ratios & Theoretical Yield

This part of the Unit is covered on pages 368-378 in your textbook

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Section 6: Mole Ratios & Theoretical Yield / Objectives

“After this lesson I can…

• …use the mole ratios in a balanced chemical equation to calculate theoretical yield when given the grams or moles of reactant.”

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Mole Ratios• The mole ratio is taken from a balanced chemical equation and is simply the ratio of coefficients

between reactants and products.

• Mole ratios are really conversion factors.

• Example: 2 C2H6 + 7 O2 4 CO2 + 6 H2O

• Here are some of the ratios in this problem…

• 2 moles of C2H6 = 4 moles of CO2

• 2 moles of C2H6 = 6 moles of H2O

• 7 moles of O2 = 4 moles of CO2

• 7 moles of O2 = 6 moles of H2O

• These ratios allow us to calculate the amount of products that will form from a given amount of reactants.

• For example if we have 2 moles of C2H6 than 4 moles of CO2 will be produced (assuming there is plenty of O2 for it to react with).

• If we happen to have 4 moles of C2H6 then 8 moles of CO2 will be produced (again, assuming there is enough of O2 for it to react with).

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Theoretical Yield• Theoretical Yield is the maximum amount of product that can form given the amount of reactant that

you are starting with. It is calculated using the mole ratio.

• Sometimes problems ask for theoretical yields in moles, sometimes in grams, and sometimes in liters of a gas. it doesn’t have real world applications, but a problem could even ask for the theoretical yield in the number of particles.

• Theoretical yield is ALWAYS found in moles first. Therefore, if a problem asks for the theoretical yield in something else, you will have to find it in moles first and then convert it to that other thing later on.

• Likewise, you need to have your reactant in moles to find theoretical yield. So if your reactant is given to you in something else, you will have to convert it to moles first.

• These relationships are summarized in a diagram on the next page. You can think of the diagram as a flow chart.

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Stoichiometry Concept Map

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Practice Problems: Theoretical Yield

Suppose 4.35 moles of C8H18 reacts with an excess of Oxygen gas. What is the theoretical yield of CO2 in moles given the reaction:

2 C8H18 + 25 O2 16 CO2 + 18 H2O

“If 4.5 moles of WF6 reacts, how many moles of HF will be produced given the reaction:

WF6 + 3 H2 W + 6 HF

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Practice Problems: Theoretical Yield

Suppose 6.1 moles of C8H18 reacts with an excess of Oxygen gas. What is the theoretical yield of CO2 in grams given the reaction:

2 C8H18 + 25 O2 16 CO2 + 18 H2O

“If 10.4 moles of WF6 reacts, how many grams of HF will be produced given the reaction:

WF6 + 3 H2 W + 6 HF

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Practice Problems: Theoretical Yield

If 65 grams of PdCl2 is used in the reaction, how many grams of KCl will be produced given the reaction:

2 PdCl2 + 4 KNO3 → 2 PdO + 4 KCl + 4 NO2

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Section 6 Additional Resources & Links…• Tyler Dewitt’s Video: “Mole Ratio Practice Problems”

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Section 7: Limiting Reactants

This part of the Unit is covered on pages 379-384 in your textbook

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Section 7: Limiting Reactants / Objectives

“After this lesson I can…

• …Identify the limiting reactant in theoretical yield problems and solve those problems.”

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Limiting Reactant• Notice in Section 6 we really only looked at how to calculate the theoretical yield when given the

amount for one of the reactants.

• But what if we are given amounts for two or more reactants? Which one will we used to determine the theoretical yield?

• While we will have to do the same process we have been doing for both reactants, the theoretical yield is ultimately determined by whichever reactant gives us the lesser amount of product. This reactant is called the limiting reactant, because it limits the amount of product that can be made. The other reactant, the non-limiting reactant, has a certain amount that is left over.

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Practice Problems: Limiting Reactant

“Suppose 2.7 moles of C9H20 reacts with 4.6 moles Oxygen gas. What the theoretical yield of CO2 in grams given the reaction:

C9H20(l) + 14 O2(g) 9 CO2(g) + 10 H2O(g)? “

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Practice Problems: Limiting Reactant

• “If you have 130 grams of Iron reacts with 185 grams of HNO3, what is the theoretical yield of Water in grams? What is the limiting reactant?”

3 Fe + 8 HNO3 3 Fe(NO3)2 + 2 NO + 4 H2O

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Practice Problems: Limiting Reactant

“What mass of NaBH4 will results from the reaction of 355 grams of SiO2 with 275 grams of Sodium? You may assume an excess of the other reactants“

Na2B4O7 + 16 Na + 8 H2 + 7 SiO2 4 NaBH4 + 7 Na2SiO3

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A Quick Note on Making Assumptions• If theoretical yield problem that only gives you the amount for one of the reactants, just assume that

reactant is the limiting reactant and that you have an excess of the other reactant(s).

Examples:

• “What the theoretical yield of NO2 in moles if 100 grams of Sulfur reacts?

S + 6 HNO3H2SO4 + 6 NO2 + 2 H2O”

• Assume there is an excess of HNO3

• “How many grams of NaHCO3 can be made if 45 grams of Na2O is used in the following reaction: Na2O + 2 CO2 + H2O 2 NaHCO3”

• Assume there is an excess of CO2 and H2O.

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Section 7 Additional Resources & Links…• Tyler Dewitt’s Video: “Introduction to Limiting reactant and excess reactant”

• Tyler Dewitt’s Video: “Limiting Reactant Practice Problem”

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Section 8: Percent Yield

This part of the Unit is covered on pages 385-388 in your textbook

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Section 8: Percent Yield / Objectives

“After this lesson I can…

• …Distinguish actual yield, theoretical yield, and percent yield”

• …calculate percent yield (problems will require calculating theoretical yield first)”

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Actual Yield• Remember that Theoretical yield is the maximum possible amount of product you can get from a

reaction if you know the amount of reactants you are starting with.

• In the real world, it is virtually impossible to obtain the theoretical yield. Why?

• One common reason is that you lose some of your product when it’s transferred between containers or purified.

• The Actual yield is what you actually recover after the reaction and any purification steps are over.

• Actual yield is always less than the theoretical yield.

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Percent Yield• The percent yield is the actual yield divided by the theoretical yield times 100.

• It’s a percentage of the product you recovered.

• In the business world, the higher the percent yield the better because any product not recovered is essentially money lost.

• Pharmaceutical companies for example will try and fine tune their manufacturing process so they have very high percent yields for the drugs they make.

• It is impossible for percent yield to be greater than 100%, if this happens in the real world (like in a lab you do), there are only two possibilities:

• You made an error when calculating theoretical yield

• The product you recovered is impure; it contains other substances that are adding to the mass like water or left over reactant. Keep in mind water can be present even in substances that appear dry.

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Practice Problems: Percent Yield

Suppose 89 grams of NaOH reacts with an excess of Sodium Iodide and Bromine. If 12 grams of Water are recovered, what is the percent yield?

NaI + 4 Br2 + 10 NaOH Na3H2IO6 + 8 NaBr + 4 H2O

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Practice Problems: Percent Yield

The reaction below is run using 27 grams of HNO3 and 50 grams if Pb(NO3)2 are produced. Find the percent yield.

Pb3O4 + 4 HNO3 PbO2 + 2 Pb(NO3)2 + 2 H2O

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Practice Problems: Percent Yield

Suppose 90 grams of Na2O reacts with an excess of Carbon Dioxide and Water according to the reaction below. If 189 grams of NaHCO3 are recovered, what is the percent yield?

Na2O + 2 CO2 + H2O 2 NaHCO3

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Practice Problems: Percent Yield

“Suppose 2.6 grams of Na3PO4 reacts with 3.5 grams of CaCl2 according to the reaction below. If .55 grams of Ca3(PO4)2 are recovered, what is the percent yield?”

2 Na3PO4 + 3 CaCl2 Ca3(PO4)2 + 6 NaCl

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Section 8 Additional Resources & Links…• Fuse School Video: “Percent Yield”

• The Organic Chemistry Tutor Video: “How to Calculate Theoretical Yield and Percent Yield”

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Section 9: “Other” Types Stoichiometry Problems

This part of the Unit is covered on pages 368-384 in your textbook

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Section 9: “Other” Types of Stoichiometry Problems / Objectives

“After this lesson I can…

• …Solve stoichiometry problems that ask for amounts of reactants instead of products.

• …Solve stoichiometry problems that ask for how much of a reactant you need to completely react with another reactant.

• …Solve stoichiometry problems that ask for how much a non-limiting reactant is left over.

• …Create an ‘ICE chart’ for stoichiometery problems.”

Page 75: UNIT 4: Stoichiometry (or Baking Cookies)

“Other” Types of Stoichiometry Problems• You might encounter Stoichiometry problems that ask for something besides theoretical yield.

• One type of problem might ask for you to calculate the amount of reactant needed to form a desired amount of product.

• Another type of problem might ask how much of a reactant you might need to “completely react” with another reactant. In these types of problems it is as if the problem is asking you to insure there is not a limiting reactant; that both reactants are used up completely.

• Once again you will rely on mole ratios to solve these problems. If you are using Dimensional Analysis these problems should not be too difficult. The math is done exactly the same, your just solving for something else besides the product.

Page 76: UNIT 4: Stoichiometry (or Baking Cookies)

Practice Problems: “Other” Stoichiometry Problems

“If you want to synthesis 22 grams of H3PO3, how many moles of Tetraphosphorus Hexaoxide will you need?”

P4O6 + 6 H2O 4 H3PO3

Page 77: UNIT 4: Stoichiometry (or Baking Cookies)

Practice Problems: “Other” Stoichiometry Problems

“If you want to synthesis 25 grams of Ammonia, how many grams of N2 will you need?”

N2(g) + 3 H2(g) 2 NH3(g)

Page 78: UNIT 4: Stoichiometry (or Baking Cookies)

Practice Problems: “Other” Stoichiometry Problems

How many grams of S8 do you need to completely react with 22 grams of Cl2?

S8(s) + 4 Cl2(g) 4 S2Cl2(l)

Page 79: UNIT 4: Stoichiometry (or Baking Cookies)

Practice Problems: “Other” Stoichiometry Problems

How many moles of Selenium and how many moles of HNO3 are required to react with 94 grams of water?

3 Se + 4 HNO3 + H2O 3 H2SeO3 + 4 NO

Page 80: UNIT 4: Stoichiometry (or Baking Cookies)

Section 7,8, & 9 Additional Resources & Links…• Tyler Dewitt’s Video: “Limiting Reactant Practice Problem (Advanced)”

• The Organic Chemistry Tutor Video: “Theoretical, Actual, Percent Yield & Error - Limiting Reagent and Excess Reactant That Remains”

• The Organic Chemistry Tutor Video: “Excess Reactant Stoichiometry, Left Over, Limiting Reactant, Theoretical & Percent Yield Practice”