Treatment of resin waste water Ppt

Under the guidance ofDr. B. Prasad

Professor, Dept. of Chemical Engg.IIT Roorkee

TREATMENT OF RESIN MANUFACTURING INDUSTRY

WASTE WATER USING COAGULATION FLOCCULATION

Presented by: Arvind kumar E. No. 14515002

• Introduction

• Literature review

• Objectives

Contents

Resins

• Resins are natural or synthetic compound that begins in a highly viscous

state and hardens with treatment.

• It is soluble in alcohol, but insoluble in water.

• Synthetic resin are produce by polymerization and poly condensation

process.

TYPES OF RESINS AND THEIR USES : resin are two types

• Synthetic resin

• Natural resin

INTRODUCTION LITERATURE REVIEW OBJECTIVES


RESINS USES

Polyacrylonitrile resin Civil and military aircraft , Missiles, Pressure vessels ,Tennis rackets, badminton rackets .

Epoxy resin Adhesives ,carbon fiber Fiberglass, vinyl ester .

Ion-exchange resin Water purification, metal separation Sugar manufacturing, pharmaceuticals .

Phenol formaldehyde resin (Bakelite resin)

Electrical insulators, Radio ,Telephone casings, Kitchenware, Jewelry, Pipe stems .

Ebonite resin Bowling balls ,Electric plugs Smoking pipe ,Fountain pen bodies and nib feeds .

Coagulation

• Coagulation is the destabilization of colloidal by addition of chemical that

neutralize the negative charge .

• Chemical coagulant are higher valance cationic salt ( Al+3 , Fe+3 etc)

• Coagulant dose are used to reduce the electrostatic repulsive force .

• Electrostatic repulsive force reduce by the addition of counter charged ions.

• For determining the optimum coagulant dose jar test is to be done in

laboratory.

Flocculation

Flocculation is the agglomeration of destabilizing particles in to a large size

particle known as flocs .which can be remove by sedimentation or floatation .


Mechanism : There are two major force acting on colloids 1. Electrostatic repulsion2. Intermolecular or vander waals attraction force



Industries Coagulant Remark Author

Sugar Industries (Al2(SO4)3+FeSO4) 77% COD REDUCTION

Khan et al., 2003

Pulp and paper Polyaluminium Chloride (PAC), Bagasse fly ash

(BFA)

COD and colour to 87 % and 95 %,

respectively

Srivastava et al., 2005

Textile Industry Polyaluminium Chloride (PAC)

93.47% COD Sabur et al., 2012

Distillery Industries FeCl3, AlCl3 and PAC 55, 60 and 72% COD reductions and about

83, 86 and 92% colour reductions

Chaudhari et al., 2007

Application of different coagulant in industries


Grease waste water Aluminum sulfate ferric chloride and ferrous sulfate

Aluminium sulphate =90% Ferric

chloride=88% Ferrous sulphate=28%

Ghaly et al., 2006

Synthetic Wastewater Ferric Chloride dye removal 96.3% Moghaddam et al., 2010

Dye waste water Polyferric chlorides (PFCs) COD 55% reduction Yu-li, et al., 2006

Municipal waste wateralum and ferric chloride 50% COD, 90%

phosphoursTassoula et al., 2007

Tannery leather waste water PACF/Ca(OH)2 76% COD and 98%

TSSLofrano et al., 2006

Petroleum waste water PACl, FeCl3 PAC= 885 Color and 72% COD, FeCl3=79 color and 67% COD

Farajnezhad, and Gharbani, 2012

Industries Coagulant Dosing Remark Author


S.No Characteristics Value

1 pH 7.4

2 Sulphate (mg/l) 60

3 Chloride (mg/l) 53

4 TDS (mg/l) 235

5 COD (mg/l) 487

6 BOD (mg/l) 60

7 Phenol (mg/l) 122

RESIN MANUFACTURING INDUSTRY WASTE WATER CHARECTARSTIC

Phenol formaldehyde resin industry waste water characteristics (Rengaraj et al. 2011)


RESIN MANUFACTURING INDUSTRY WASTE WATER CHARECTARSTIC

ABS resin industry waste water charactarstic (Chen, et al. 2000 )

SN. Characteristics Value

1 pH 7.01

2 Temperature 0C 40

3 DO (mg/l) 4.8

4 COD(mg/l) 4125.6-4896.2

5 Acrilonitrile (mg/l) 380.8-449.9

6 Acryleamide (mg/l) 65.7-76.3

7 Acrylic acid(mg/l) 154.1-180.1

8 Ammonia (mg/l) 51.6-53.9

LITERATURE REVIEW

Level in water (ppm) Length of exposure Description of effect

142 1day Death & nervous system disorder

180 10 day Birth defect in rate

Level in water (ppm) Length of exposure Description of effect

35 2 year Premature death in rate

52 60 day Low sperm count

100 19 month Low red blood cell count

200 6 month Ulcer in the throat and premature death

500 220 day Reduce reproductivity capability in rate

Long turm exposure (Greater then 14 year)

EPA standerd for acrylonitrile on human exposure (short turm exposure )

OBJECTIVESINTRODUCTION


Authors Removal of Coagulant Materials Operating Conditions Efficiency

Song et al.2004COD,TSS ,Chromium

Ferric chloride

pH 9.2 COD 3300 mg/l TSS 15000 mg/lCr 16.8 mg/l

TSS 38.46%COD 30-37 %Cr 74-99 %

Amuda et al.2006

COD TSS Total phosphorus (TP)

FeCl3 .6 H2O

Poly electrolyte

pH 9 COD 1750 mg/l TSS 1620 mg/l BOD 894 mg/l

TSS 97%COD 93 %TP 95 %



Wong et al. 2006

COD,TSS ,TurbiditySludge value index (SVI)

Polyacryl amide cations

pH 7.3- 8.3 COD 3087 mg/l TSS 3240 mg/l Turbidity

TSS 99 %COD 93%Turbidity 95 %SVI 14 mg/l

Ahmad et al.2006

COD TSS Turbidity

Alum +Poly aluminium chloride

pH 6.3-8.3 COD 3087 mg/l TSS 5240 mg/l Turbidity

TSS 99.4%COD 91 %Turbidity 99.8%



Rodrigues et al. 2008

COD,Turbidity ,Nitrate , Sulphate

Ferric chloride , chitosan

pH 6 COD 1303 mg/l BOD 146 mg/l Nitrate Phosphate

Nitrate 90.3 %Sulphate 49.63%COD 58%Turbidity 75 %

Suarez et al.2009

Dichlorophanac (DCF),Naproxen (NPX),Ibuprofen (IBP)

Ferric chloride ,Aluminium sulphate ,Sodium carbonate

pH 7.9 COD 2464 mg/l TSS 339 mg/l

TSS 92 % DCF 46%IBP 23 %NPX 42%



Verma et al. 2010

COD Ferric chloride

pH 5.6 COD 2776 mg/l BOD 480 mg/l

COD 75.5%

Ayoub et al.2011

TSS ,Total phosphorus (TP) ,Cromium ,Turbidity

Lime ,Ferric chloride ,Aluminium sulphate

pH 7.28 TSS 97 %TP 87 %Cr 99.7 %Turbidity 99%


Authors Removal of Process used Operating Conditions EfficiencyKenneth et al. 2008

AcrilonitrieAcetonitrileAcrylamide

Wet oxidation process

Temp 315-372 0cPressure 1550-4500 psiAir 50% O2

Residence time 30 min- 2hr

Acrilonitrie 2480 mg/lAcetonitrile 2050 mg/lAcrylamide 1053 mg/l

Acrilonitrile 99%Acetonitrile 99.9%Acrylamide 92.75

Dars et al.2009

COD

Adsorption process

adsorbent use Commercial activated carbon (CAC),Date pits (ADP),Rice husks (ARH)

COD Remove by CAC – 92.5 %ADP - 90.5%ARH - 89%

WORK DONE ON RESIN WASTE WATER


Authors Removal of Process used Operating Conditions Efficiency

Lai et al.2012 COD ,

TOC,

Iminodipropionitrile

(ADN),

Oxydipropionitrile

(ODN) ,

Acetophenone (AP)

Boilogical

activated

carbon

COD 1100-1300

mg/l

ADN 30-35 mg/l

ODN 67-75 mg/l

AP 16-20 mg/l

COD 80 %

TOC 80%

AND 94.4%

ODN 67%

AP 16-20 %

WORK DONE ON RESIN WASTE WATER


Specific objectives of the work are:

• Characterization of waste water obtained from resin manufacturing industry.

• Preparation of composite coagulants and their characterization.

• Removal of acrylonitrile, BOD, COD, TSS and TDS from acrilonitrile

butadiene styrene (ABS) resin waste water employing composite coagulants.

• To study the effect of various parameters such as concentration, pH,

reaction time , temperature and effect of coagulant dose on acrylonitile.

• To optimize the process.

• To analyze the sludge obtained from treatment waste water .

• To carry out the economic evaluation of the process.


Comparison of different systems performance in acrylonitrile-containing wastewater treatment

Li et al. 2007 Adsorption onto poly aluminium chloride (PAC)

Acrylonitrile Acrylic Acid

Removal rate= 0.0074 g. AN/g. VSS. h Max. Ads. Cap.= 36.23 mg/g

Shin et al.2009 Super critical water oxidation (SCWO)

Acrylonitrile, Cooper

Enhanced oxidation of AN due to the formation of nano-catalysts of copper and/or copper oxides

Shin et al.2009 Super critical water oxidation (SCWO) Acrylonitrile

TOC convertion of AN= 97% within 15s at 552ºc

Authors Treatment system Pollutants Results


Authors Treatment system Pollutants Results

Shakerkhatibi et al.( 2010 )

Aerated submerged fixed film reactor (ASFFR)

Acrylonitrile 99% AN removal at HRT=4 h and OLR= 2.4 kg.COD/m3.d

Chang et al. 2006 Aerated submerged membrane bio reactor (ASMBR)

COD > 92% removal at HRT=18-30 h and OLR= 2 kg.BOD/m3.d

Kumar et al. 2008 Adsorption onto bio gas fly ash ( BFA)

Acrylonitrile Max. Ads. Cap.= 84.47 mg/g at 30ºc

Ramakrishna et al 1989

Powered activated carbon (PAC-AS)

COD 95% CN removal at CN in= 15-20 mg/L 88% COD removal at COD in=25000mg/L

Comparison of different systems performance in acrylonitrile-containing wastewater treatment

INTRODUCTION LITERATURE REVIEW REFERENCES

• Ahmadia, Amiric, Martinezd, Treatment of phenol-formaldehyde resin manufacturing wastewater by the electrocoagulation process a Environmental Technology Research Center, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran

• Amuda and Ibrahim, “Industrial wastewater treatment using natural material as adsorbent”, African Journal of Biotechnology vol 5, 2006.

• Arutchelvan, Kanakasabai , Nagarajan , Muralikrishnan ,Isolation and identification of novel high strength phenol degrading bacterial strains from phenol-formaldehyde resin manufacturing industrial wastewater Journal of Hazardous Materials (2005)

• Akyol, “Treatment of paint manufacturing wastewater by electrocoagulation”, Desalination 2012.• Amokrane, A., Comel, C. and Veron, J., Landfill Leachates Pre-Treatment by Coagulation Flocculation.

Water Res., (1997).• Aghaie, khani and Choobeh, “Utilization Soya Bean Fatty Acid for Synthesis of Alkyd Resin and

Comparation of Properties with Other Vegetable Oils”, Journal of Nano Chemical Agriculture (JNCA), Islamic Azad University, Saveh Branch, 2012.

• Dars, Bakr, Adel M. E. Gabre , Reduction of COD in Resin Production Wastewater Using Three Types of Activated Carbon Enviro. Treat. Tech. ISSN: 2309-1185

• Hassan, Souabi, Yaacoubi and Baudu, “Improvement of paint effluents coagulation using natural and synthetic coagulant aids”, J. Hazard. Mater. 2006

• Hanafy and Elbary , Effluent waste water treatment for a resin based paint plant (case study) Ninth International Water Technology Conference, IWTC9 2005, Sharm El-Sheikh, Egypt

• Hassan, Li, and Noor, coagulation and flocculation treatment of wastewater in textile industry using chitosan. J. Chem. Nat. Resour. Eng.(2009).

• Katal and Pahlavanzadeh, Influence of different combinations of aluminum and iron electrode on electrocoagulation efficiency, Application to the treatment of paper mill wastewater, Desalination, (2011).

INTRODUCTION LITERATURE REVIEW REFERENCES

• Koohestanian, Hosseini, and Abbasian, The Separation Method for Removing of Colloidal Particles from Raw Water. American-Eurasian J. Agric. & Environ. Sci.(2008).

• Lai, Zhou, and Yanga, Treatment of wastewater from acrylonitrile butadiene- styrene (ABS) resin manufacturing by biological activated carbon (BAC) (2013)

• Luenloi, Chalermsinsuwan, Sreethawong and Hinchiranan, Photodegradation of phenol catalyzed by TiO2 coated on acrylic sheets: Kinetics and factorial design analysis, Desalination, (2011)

• Malakootian, Almasi and Hossaini, “Pb and Co removal from paint industries effluent using wood ash”, Int. J. Environ. Sci. Tech. Vol 5(2), 2008.

• Prado , Veiga, and Kennes , Removal of formaldehyde, methanol, dimethyl ether and carbon monoxide from waste gases of synthetic resin-producing industries University of La Coruna, Alejandro Sota, La Coruna, Spain

• Pan, Huang, Chen, and Chung, Evaluation of a Modified Chitosan Biopolymer for Coagulation of Colloidal Particles. Colloids and Surfaces (1999).

• Rajkumar and Palanivelu, Electrochemical treatment of industrial wastewater, J. Hazard. Mater., (2004) .• Rengaraj , Moona, Sivabalan , Arabindoo , Murugesan Removal of phenol from aqueous solution and resin

manufacturing industry wastewater using an agricultural waste: rubber seed coat Oryong dong, Puk-gu, Kwangju 500712, South Korea

• Tahar and Savall, Electrochemical degradation of phenol in aqueous solution on bismuth doped lead dioxide: a comparison of the activities of various electrode formulations, J. Appl. Electrochem(1999) .

• Wyatt and Knowles , Microbial the Degradation of Effluents and Condensates from the Manufacture of Acrylonitrile International Biodeterioration & Biodegradation (1995) .

OBJECTIVES

THANKS

Treatment of resin waste water Ppt

Engineering

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