Synthesis, Structural Determination, and Physicochemical Property Studies of Novel
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Synthesis, Structural Determination, and Physicochemical Property Studies of Novel Coordination Polymers Incorporating Kinked and Hydrogen-Bonding Capable Bifunctional Organodiimines Robert L. LaDuca man Briggs College, Michigan State University, East Lansing, MI 488 bonding capable dipyridyl tethering ligands have afforded divalent al dicarboxylate coordination polymers with novel topologies N N H N 4,4'-dipyridylam ine dpa {[Cu 2 (phthalate) 2 (dpa )]•H 2 O} n homochiral septuple [Cu 2 O 2 (dpa)] n fold helices with weak ferromagnetic coupling {[Cd(phthalate)(dpa)(H 2 O)]•4H 2 O} n 3-fold interpenetration of regular (12,3) self-penetrated s connection through phthalate affords 4-connected chiral self-penetrated yyz net (7 4 8 2 topology)
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Synthesis, Structural Determination, and Physicochemical Property Studies of Novel Coordination Polymers Incorporating Kinked and Hydrogen-Bonding Capable Bifunctional Organodiimines. Robert L. LaDuca Lyman Briggs College, Michigan State University, East Lansing, MI 48825. - PowerPoint PPT Presentation
Transcript of Synthesis, Structural Determination, and Physicochemical Property Studies of Novel
Synthesis, Structural Determination, and Physicochemical Property Studies of NovelCoordination Polymers Incorporating Kinked and
Hydrogen-Bonding Capable Bifunctional Organodiimines
Robert L. LaDuca Lyman Briggs College, Michigan State University, East Lansing, MI 48825
Hydrogen-bonding capable dipyridyl tethering ligands have afforded divalent metal dicarboxylate coordination polymers with novel topologies
N
N
H
N
4,4'-dipyridylaminedpa
{[Cu2(phthalate)2(dpa)]•H2O}n
homochiral septuple [Cu2O2(dpa)]n 6-fold helices with weak ferromagnetic coupling
{[Cd(phthalate)(dpa)(H2O)]•4H2O}n3-fold interpenetration of regular (12,3) self-penetrated sublattices,
connection through phthalate affords 4-connected chiral self-penetrated yyz net (7482 topology)
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