Supporting Information - Royal Society of Chemistry · 2013-09-18 · Supporting Information . Mild...
Transcript of Supporting Information - Royal Society of Chemistry · 2013-09-18 · Supporting Information . Mild...
Supporting Information
Mild Catalytic Pyrolysis of Biomass for Production of Transportation Fuels: A Techno-Economic Analysis
Rajeeva Thilakaratne1, 2, Tristan Brown3, Yihua Li4, Guiping Hu4, Robert Brown1, 2, 3
1Department of Mechanical Engineering 2Center for Sustainable Environmental Engineering
3Bioeconomy Institute 4Industrial and Manufacturing Systems Engineering
Iowa State University Ames, IA 50011
Contents
a) Snapshot of the Chemcad model areas and the details of the stream properties and composition
Figure S-1 Pretreatment and pyrolysis area snapshot of the Chemcad model
Figure S-2 Upgrading area snapshot of the Chemcad model
Figure S-3 Hydrogen generation area snaphot of the Chemcad model
Figure S-4 Utilities area snapshot of the Chemcad model
Table S-1 Streams composition and property data of the Chemcad model
b) Snapshots of the heat exchanger network design
Table S-2 Process heat exchangers
Table S-3 Targeted utility streams
Table S-4 Heat exchanger network design
c) Power consumption of the process
Table S-5 Major power consumption breakdown
d) Detailed capital and operational cost breakdown
Table S-6 Operation cost break down
Table S-7 Capital cost break down
Table S-8 Equipment cost source
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Figure S-1. Pretreatment and pyrolysis area
Hammer Mill
Screw feed
100 101
105
106 107
114
115
116
117
118Screw feed
AirPreheater
Air
FlashSeperator
CatalyticPyrolyzer
Dryer
Regenerator
103
Aqueous Waste
Flash Vent
Pyrolysis Offgas toCombustor
AirCompressor
Cyclone 1
Cyclone 2
Bio OilCondensor
ESP
Ash
Screen
Flue GasHeat Recovery
WoodyBiomass
Dryer Exhaust Combustion Air
Bio Oil
Pyrolysis Offgas to H2 Plant
109
111
112
120
122
124
125
127
129
130
131
132133134
135
136
138
139140
142
143
144
146
110
Screw feed
Fludizing Gas Compressor
113
141
102
104108
Global K value model – NRTL
Global enthalpy model - SRK
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Figure S-2. Upgrading area
LP Flash
HP Flash
201
202
204
205
210
214 215
217 218
219 220
221 222
223
208
H2 Compressor 1
H2 to Desulfurification
Hydrotreater 1 Preheater
Hydrotreater 1
Upgraded Oil Cooler
Debutanizer
PSA -Hydroggen Recovery
Bio OIl Pump
H2 RecycleCompressor 1
H2 Recycle Cooler
211
216
209
Hydrotreater 2
Hydrotreater 2 Preheater
H2 RecycleCompressor 2
H2 Compressor 3
H2 Compressor 2
H2 Compressor Cooler 1
H2 Compressor Cooler 2
Fractionator
Aqueous Waste
Fractionator Preheater
Debutanizer Preheater
DieselCooler 1
Gasoline Cooler 1
Bio Oil
Upgrading Offgas to H2 Plant
H2
200
207
213
224
226
227
228229230231
232
235 236 237
238
206
233 234
239
Global K value model – NRTL
Global enthalpy model - SRK
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Figure S-3. Hydrogen generation area
H2 PlantProcess water Pump
Offgas Compressor Cooler 1
Offgas Compressor 1
Offgas Compressor 2
Offgas Compressor 3
H2 PlantWater Preheater
Feed GasPreheater
Desulfurifier
Process Water
Prere formerReformerH2
Water Gas Shift
Gas Cooler
Aqueous Waste
FlashSeperator
PSA -H2 Plant
Offgas
Pyrolysis Offgas
Upgrading Offgas
H2 toUpgrading
300
301
302 303 304 305
307
308
309
310
311312
313
314316
320
322
323
325
327 318
317 315
Offgas Compressor Cooler 2
306
319
Global K value model – NRTL
Global enthalpy model - SRK
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Figure S-4. Utility area
400
401 402
405
407
408
409
410
411
412
413
418
419
420 421
422600
601
Upgrading Aqueous Waste
Hydrogen Plant Aqueous Waste
Boiler Blowdown
Cooling Plant Blowdown
416
To Waste Water Treatment
Boiler Water Pump
Boiler Preheater BoilerCondensor
TurbineStage 1
TurbineStage 3
Turbine Stage 2
Condensate Pump 1
HP SteamHeat Exchangers
Condensate Pump 2
Makeup Water Tank Deareator
BoilerMakeup Water
Condenstate Tank
BoilerBlow Down
Pyrolysis Aqueous Waste
501
502
503
504
505
507
508
Boiler
Blow Down
Windage
Cooling PlantMakeup Water
Cooling PlantWater Pump
CoolingHeat Exchangers
Cooling Tower
500
602
603
604
605
606
607417
Combustion Air
Pyrolysis Offgas
H2 Plant Offgas
Pyrolysis Flash Vent
Dryer Exhaust
Gas Combustor Heat Recovery
Reformer HE
Gas Combustor
Flue Gas
608
609
423
614
615
403
404
610
611
612
613
Cogeneration Offgas combustion
Aqueous waste
Global K value model – NRTL
Global enthalpy model - SRK
Cooling plant
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Table S-1. Streams composition and property data (Continued…)
Stream No. 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119Temp C 25.0 25.0 104.4 99.6 99.6 99.6 99.6 99.6 584.3 499.5 499.5 499.5 499.5 499.5 38.0 38.0 38.0 38.0 37.8 37.8Pres bar 1.0 1.4 1.2 1.0 1.0 1.0 1.0 1.4 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2Enth MJ/h -963940.0 -963940.0 -547300.0 -547330.0 -547330.0 -32.7 -547490.0 -547490.0 -2747300.0 -2747300.0 -2077100.0 -670180.0 -6630.3 -663550.0 -822450.0 -502140.0 -320310.0 -27480.0 -529620.0 -478170.0Vapor mass frac. 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 1.0 1.0 0.0 1.0 1.0 1.0 0.5 0.0 1.0 0.0 0.0 0.0Total kg/h 118640.0 118640.0 92592.2 92597.8 92597.8 5.5 92592.2 92592.2 585092.2 585095.0 477833.3 107261.3 3141.2 104120.1 104120.1 48685.0 55435.1 3030.9 51716.0 31471.7Flow rates in kg/hWater 35306.9 35306.9 9259.2 9259.8 9259.8 0.6 9259.2 9259.2 9259.2 31037.5 0 31037.5 0 31037.5 31037.5 29316.6 1720.9 1720.9 31037.5 29735Nitrogen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Oxygen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hydrogen 0 0 0 0 0 0 0 0 164.3 265.1 0 265.1 0 265.1 264.9 0 264.9 0 0 0Carbon Dioxide 0 0 0 0 0 0 0 0 15343.1 24750.6 0 24750.6 0 24750.6 24750.7 10.9 24739.8 0 10.9 9.3Carbon Monoxide 0 0 0 0 0 0 0 0 11124.6 17937.9 0 17937.9 0 17937.9 17938 0.3 17937.7 0 0.3 0.1Methane 0 0 0 0 0 0 0 0 2270.3 3660.8 0 3660.8 0 3660.8 3660.8 0.1 3660.7 0 0.1 0Ethylene 0 0 0 0 0 0 0 0 3597.7 5801.4 0 5801.4 0 5801.4 5801.4 0.4 5801 0 0.4 0.3Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 0 0 0 0 0 0 0 0 0 221.7 0 221.7 0 221.7 221.7 190.8 30.9 30.9 221.7 81.2HydroxyAcetone 0 0 0 0 0 0 0 0 0 2217.5 0 2217.5 0 2217.5 2217.5 2197.1 20.4 20.4 2217.5 973.52-5-Xylenol 0 0 0 0 0 0 0 0 0 5122.5 0 5122.5 0 5122.5 5122.5 5120 2.4 2.4 5122.5 69.3syringol 0 0 0 0 0 0 0 0 0 8249.1 0 8249.1 0 8249.1 8249.1 8249 0.2 0.2 8249.1 559.1N-Heptane 0 0 0 0 0 0 0 0 0 111.1 0 111.1 0 111.1 111.1 0.6 110.5 110.5 111.1 0.6Levoglucosan 0 0 0 0 0 0 0 0 0 44.2 0 44.2 0 44.2 44.2 44.2 0 0 44.2 39.1Toluene 0 0 0 0 0 0 0 0 0 1175 0 1175 0 1175 1175 29.8 1145.1 1145.1 1175 42-Methylnaphthal 0 0 0 0 0 0 0 0 0 2644.2 0 2644.2 0 2644.2 2644.2 2643.6 0.6 0.6 2644.2 0.31-ts-35-3C 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 03-3-5-Trimethylh 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Propylcyclohex 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Mesitylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-Nonene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0MthCyclohexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 0 0 0 0 0 0 0 0 881.7 0 881.7 0 881.7 881.7 881.7 0 0 881.7 0Hybrid poplar 83333 83333 83333 83338 83338 5 83333 83333 83333 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 17833.3 17833.3 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 460000 460000 460000 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 1691.7 0 1691.7 1691.7 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Propane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0I-Butane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 1449.5 0 1449.5 1449.5 0 0 0 0 0 0 0
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Table S-1. Streams composition and property data (Continued…)
Stream No. 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139Temp C 37.8 37.8 37.8 37.8 37.8 38.0 38.0 38.0 38.0 38.0 38.0 59.9 25.0 69.1 200.0 200.0 200.0 200.0 200.0 200.0Pres bar 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.5 1.0 1.5 1.5 1.5 1.5 1.5 1.5 1.5Enth MJ/h -478170.0 -51451.0 -51451.0 -4.2 -4.2 -297510.0 -55093.0 -55093.0 -57908.0 -57908.0 -184510.0 -183670.0 -103.7 19932.0 80038.0 32730.0 20826.0 11903.0 11903.0 47308.0Vapor mass frac. 0.0 0.0 0.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0Total kg/h 31471.7 20243.5 20243.5 0.7 0.7 52404.2 9704.2 9704.2 10200.0 10200.0 32500.0 32500.0 448000.1 448000.1 448000.1 183200.0 116573.2 66626.8 66626.8 264800.1Flow rates in kg/hWater 29735 1302.5 1302.5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen 0 0 0 0 0 0 0 0 0 0 0 0 352128 352128 352128 143995.2 91626.6 52368.6 52368.6 208133Oxygen 0 0 0 0 0 0 0 0 0 0 0 0 95872 95872 95872 39204.8 24946.7 14258.1 14258.1 56667.2Hydrogen 0 0 0 0 0 264.9 49.1 49.1 51.6 51.6 164.3 164.3 0 0 0 0 0 0 0 0Carbon Dioxide 9.3 1.2 1.2 0.4 0.4 24739.8 4581.3 4581.3 4815.4 4815.4 15343.1 15343.1 0 0 0 0 0 0 0 0Carbon Monoxide 0.1 0 0 0.1 0.1 17937.7 3321.7 3321.7 3491.4 3491.4 11124.6 11124.6 0 0 0 0 0 0 0 0Methane 0 0 0 0 0 3660.7 677.9 677.9 712.5 712.5 2270.3 2270.3 0 0 0 0 0 0 0 0Ethylene 0.3 0 0 0.1 0.1 5801 1074.2 1074.2 1129.1 1129.1 3597.7 3597.7 0 0 0 0 0 0 0 0Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 81.2 140.4 140.4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0HydroxyAcetone 973.5 1244 1244 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-5-Xylenol 69.3 5053.2 5053.2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0syringol 559.1 7690 7690 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Heptane 0.6 110.5 110.5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Levoglucosan 39.1 5.1 5.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Toluene 4 1171 1171 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-Methylnaphthal 0.3 2643.9 2643.9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-ts-35-3C 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 03-3-5-Trimethylh 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Propylcyclohex 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Mesitylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-Nonene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0MthCyclohexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 881.7 881.7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Propane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0I-Butane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Table S-1. Streams composition and property data (Continued…)
Stream No. 140 141 142 143 144 145 146 200 201 202 204 205 206 207 208 209 210 211 212 213Temp C 396.2 675.0 675.0 325.0 289.1 117.2 117.2 37.8 40.1 62.6 200.0 200.0 400.0 400.0 40.0 40.0 40.0 38.4 38.4 38.4Pres bar 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 117.0 117.0 117.0 117.0 117.0 117.0 117.0 117.0 117.0 1.5 1.5 1.5Enth MJ/h -2029800.0 -2016100.0 -382770.0 -493650.0 -472830.0 -889470.0 -889470.0 -51451.0 -51190.0 -48882.0 -36466.0 -64508.0 -43821.0 -73073.0 -107410.0 -8635.9 -98775.0 -192.5 -77173.0 -77173.0Vapor mass frac. 1.0 0.0 1.0 1.0 1.0 1.0 1.0 0.0 0.0 0.1 0.2 0.2 0.9 0.9 0.1 1.0 0.0 1.0 0.0 0.0Total kg/h 742634.0 460000.0 282633.2 282633.2 399206.4 425254.1 425254.1 20243.6 20243.6 22655.6 22655.6 22656.1 22656.1 22656.1 22656.1 2658.0 19998.1 37.1 4907.5 4907.5Flow rates in kg/hWater 0 0 0 0 0 26047.7 26047.7 1302.5 1302.5 1302.5 1302.5 3092 3092 4875.4 4875.4 5.5 4869.9 1.1 4865.6 4865.6Nitrogen 208133 0 208133 208133 299759.4 299759.4 299759.4 0 0 0 0 0 0 0 0 0 0 0 0 0Oxygen 56667.2 0 9518 9518 34464.7 34464.7 34464.7 0 0 0 0 0 0 0 0 0 0 0 0 0Hydrogen 0 0 0 0 0 0 0 0 0 2412 2412 1807.7 1807.7 1206.5 1206.5 1205.4 1.1 1.1 0 0Carbon Dioxide 0 0 64982.4 64982.4 64982.4 64982.4 64982.4 1.2 1.2 1.2 1.2 313.7 313.7 624.7 624.7 607.7 16.9 14.6 1.6 1.6Carbon Monoxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Methane 0 0 0 0 0 0 0 0 0 0 0 300.2 300.2 598.9 598.9 598 0.9 0.9 0 0Ethylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 0 0 0 0 0 0 0 140.4 140.4 140.4 140.4 71.1 71.1 1.7 1.7 0 1.7 0 0.6 0.6HydroxyAcetone 0 0 0 0 0 0 0 1244 1244 1244 1244 636.2 636.2 26.8 26.8 0 26.8 0.2 26.1 26.12-5-Xylenol 0 0 0 0 0 0 0 5053.2 5053.2 5053.2 5053.2 2519.7 2519.7 2.4 2.4 0 2.4 0 0.1 0.1syringol 0 0 0 0 0 0 0 7690 7690 7690 7690 3845 3845 16 16 0 16 0 12.1 12.1N-Heptane 0 0 0 0 0 0 0 110.5 110.5 110.5 110.5 313.6 313.6 515.6 515.6 19.4 496.2 0.5 0 0Levoglucosan 0 0 0 0 0 0 0 5.1 5.1 5.1 5.1 2.6 2.6 0.1 0.1 0 0.1 0 0.1 0.1Toluene 0 0 0 0 0 0 0 1171 1171 1171 1171 583.6 583.6 0.2 0.2 0 0.2 0 0 02-Methylnaphthal 0 0 0 0 0 0 0 2643.9 2643.9 2643.9 2643.9 1317.3 1317.3 0 0 0 0 0 0 01-ts-35-3C 0 0 0 0 0 0 0 0 0 0 0 1467.1 1467.1 2926.2 2926.2 1.5 2924.7 0.8 0 03-3-5-Trimethylh 0 0 0 0 0 0 0 0 0 0 0 157 157 312.6 312.6 0.1 312.5 0 0 0N-Propylcyclohex 0 0 0 0 0 0 0 0 0 0 0 1467.1 1467.1 2926.2 2926.2 0.5 2925.7 0.3 0 0Mesitylene 0 0 0 0 0 0 0 0 0 0 0 117.2 117.2 233.8 233.8 1 232.8 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 70.2 70.2 139.9 139.9 0 139.9 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 292.3 292.3 583.1 583.1 0 583.1 0 0 0Cis-Decalin 0 0 0 0 0 0 0 0 0 0 0 482.6 482.6 962.5 962.5 0 962.5 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 675 675 1346.4 1346.4 0 1346.4 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 589 589 1174.9 1174.9 0 1174.9 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 36.3 36.3 72.4 72.4 0 72.4 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 770.3 770.3 1536.5 1536.5 0 1536.4 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 28.4 28.4 56.6 56.6 0 56.6 0 0 01-Nonene 0 0 0 0 0 0 0 0 0 0 0 180.5 180.5 359.9 359.9 0.1 359.8 0 0 0MthCyclohexane 0 0 0 0 0 0 0 0 0 0 0 800.2 800.2 1596.1 1596.1 2.5 1593.6 1.4 0.1 0.1N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 22.5 22.5 44.9 44.9 0 44.9 0 0 0Chrysene 0 0 0 0 0 0 0 881.7 881.7 881.7 881.7 439.3 439.3 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 17833.3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 460000 460000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 0 0 0 0 90.9 90.9 181.4 181.4 181.1 0.3 0.3 0 0Propane 0 0 0 0 0 0 0 0 0 0 0 81.4 81.4 162.5 162.5 24.2 138.3 10.5 0.8 0.8I-Butane 0 0 0 0 0 0 0 0 0 0 0 86.2 86.2 171.9 171.9 11 160.9 5.5 0.3 0.3Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Table S-1. Streams composition and property data (Continued…)
Stream No. 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233Temp C 38.4 100.0 70.0 130.0 210.0 169.5 130.0 221.8 130.0 65.7 40.0 42.4 42.4 40.0 171.2 38.0 150.1 38.0 87.0 175.8Pres bar 1.5 1.5 1.4 1.5 1.5 1.5 1.4 1.6 1.5 1.4 2.0 1.4 1.4 2.0 5.5 5.5 13.3 13.3 13.3 25.0Enth MJ/h -21662.0 -20064.0 -518.8 -18690.0 -12396.0 -11917.0 -15204.0 -2292.3 -3381.1 -711.3 -8870.4 -9581.7 -9581.7 233.2 2292.2 203.1 1963.8 266.4 2230.3 5457.9Vapor mass frac. 0.0 0.0 1.0 0.0 1.0 1.0 0.0 0.0 0.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0Total kg/h 15053.4 15053.4 249.2 14804.2 14804.2 9691.2 9691.2 5113.1 5113.1 286.3 1573.1 1859.4 1859.4 1084.9 1084.9 1084.9 1084.9 1407.8 2492.7 2492.7Flow rates in kg/hWater 3.2 3.2 0.1 3.1 3.1 3.1 3.1 0 0 1.2 5.5 6.7 6.7 0 0 0 0 0 0 0Nitrogen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Oxygen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hydrogen 0 0 0 0 0 0 0 0 0 1.1 120.5 121.6 121.6 1084.9 1084.9 1084.9 1084.9 1407.8 2492.7 2492.7Carbon Dioxide 0.7 0.7 0.7 0 0 0 0 0 0 15.3 607.7 623 623 0 0 0 0 0 0 0Carbon Monoxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Methane 0 0 0 0 0 0 0 0 0 0.9 598 598.9 598.9 0 0 0 0 0 0 0Ethylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 1.1 1.1 0 1.1 1.1 1 1 0.1 0.1 0 0 0 0 0 0 0 0 0 0 0HydroxyAcetone 0.6 0.6 0 0.6 0.6 0.5 0.5 0 0 0.2 0 0.2 0.2 0 0 0 0 0 0 02-5-Xylenol 2.3 2.3 0 2.3 2.3 1 1 1.4 1.4 0 0 0 0 0 0 0 0 0 0 0syringol 4 4 0 4 4 0 0 4 4 0 0 0 0 0 0 0 0 0 0 0N-Heptane 495.7 495.7 12.3 483.4 483.4 479.4 479.4 4 4 12.8 19.4 32.2 32.2 0 0 0 0 0 0 0Levoglucosan 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Toluene 0.2 0.2 0 0.2 0.2 0.2 0.2 0 0 0 0 0 0 0 0 0 0 0 0 02-Methylnaphthal 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-ts-35-3C 2923.8 2923.8 21.5 2902.3 2902.3 2724 2724 178.3 178.3 22.3 1.5 23.8 23.8 0 0 0 0 0 0 03-3-5-Trimethylh 312.5 312.5 0.3 312.2 312.2 274.7 274.7 37.5 37.5 0.3 0.1 0.4 0.4 0 0 0 0 0 0 0N-Propylcyclohex 2925.4 2925.4 2.2 2923.2 2923.2 2558.1 2558.1 365.1 365.1 2.4 0.5 2.9 2.9 0 0 0 0 0 0 0Mesitylene 232.8 232.8 0 232.8 232.8 198.6 198.6 34.2 34.2 0 1 1 1 0 0 0 0 0 0 0N-ButylCycHexane 139.9 139.9 0 139.9 139.9 106.7 106.7 33.2 33.2 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 583 583 0 583 583 389.5 389.5 193.6 193.6 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 962.4 962.4 0 962.4 962.4 620.6 620.6 341.9 341.9 0 0 0.1 0.1 0 0 0 0 0 0 0N-Tridecane 1346.4 1346.4 0 1346.4 1346.4 15.6 15.6 1330.8 1330.8 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 1174.8 1174.8 0 1174.8 1174.8 320.7 320.7 854.1 854.1 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 72.4 72.4 0 72.4 72.4 0.8 0.8 71.5 71.5 0 0 0 0 0 0 0 0 0 0 0Diphenyl 1536.4 1536.4 0 1536.4 1536.4 0.2 0.2 1536.3 1536.3 0 0 0 0 0 0 0 0 0 0 0Tetralin 56.6 56.6 0 56.6 56.6 28.4 28.4 28.2 28.2 0 0 0 0 0 0 0 0 0 0 01-Nonene 359.8 359.8 0.9 358.9 358.9 327.2 327.2 31.6 31.6 1 0.1 1 1 0 0 0 0 0 0 0MthCyclohexane 1592.2 1592.2 36.6 1555.6 1555.6 1533.3 1533.3 22.3 22.3 37.9 2.5 40.4 40.4 0 0 0 0 0 0 0N-C15-CycloC5 44.9 44.9 0 44.9 44.9 0 0 44.9 44.9 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 0 0 0.3 181.1 181.4 181.4 0 0 0 0 0 0 0Propane 127.1 127.1 104.1 23 23 23 23 0 0 114.5 24.2 138.7 138.7 0 0 0 0 0 0 0I-Butane 155.1 155.1 70.6 84.6 84.6 84.6 84.6 0 0 76.1 11 87.1 87.1 0 0 0 0 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Table S-1. Streams composition and property data (Continued…)
Stream No. 234 235 236 237 238 239 300 301 302 303 304 305 306 307 308 309 310 311 312 313Temp C 35.0 177.9 35.0 88.1 88.1 88.1 38.0 42.4 39.2 181.5 93.3 178.8 110.0 181.9 335.0 88.1 322.8 25.0 25.6 335.0Pres bar 25.0 75.0 75.0 117.0 117.0 117.0 1.2 1.4 1.2 4.8 4.8 10.5 10.5 20.0 20.0 117.0 20.0 1.0 20.0 20.0Enth MJ/h 372.4 5604.3 412.2 2385.4 2308.2 77.2 -57907.0 -9581.9 -67489.0 -64996.0 -66593.0 -65064.0 -66326.0 -65033.0 -61971.0 78.5 -61899.0 -357520.0 -357460.0 -290000.0Vapor mass frac. 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 0.0 0.0 1.0Total kg/h 2492.7 2492.7 2492.7 2492.7 2412.0 80.7 10200.0 1859.5 12059.4 12059.4 12059.4 12059.4 12059.4 12059.4 12059.4 82.0 12134.6 22518.0 22518.0 22518.0Flow rates in kg/hWater 0 0 0 0 0 0 0 6.7 6.7 6.7 6.7 6.7 6.7 6.7 6.7 0 6.7 22518 22518 22518Nitrogen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Oxygen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hydrogen 2492.7 2492.7 2492.7 2492.7 2412 80.7 51.7 121.6 173.3 173.3 173.3 173.3 173.3 173.3 173.3 82 248.5 0 0 0Carbon Dioxide 0 0 0 0 0 0 4815.3 623 5438.4 5438.4 5438.4 5438.4 5438.4 5438.4 5438.4 0 5438.4 0 0 0Carbon Monoxide 0 0 0 0 0 0 3491.4 0 3491.4 3491.4 3491.4 3491.4 3491.4 3491.4 3491.4 0 3491.4 0 0 0Methane 0 0 0 0 0 0 712.5 598.9 1311.4 1311.4 1311.4 1311.4 1311.4 1311.4 1311.4 0 1311.4 0 0 0Ethylene 0 0 0 0 0 0 1129.1 0 1129.1 1129.1 1129.1 1129.1 1129.1 1129.1 1129.1 0 1129.1 0 0 0Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0HydroxyAcetone 0 0 0 0 0 0 0 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0 0.2 0 0 02-5-Xylenol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0syringol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Heptane 0 0 0 0 0 0 0 32.2 32.2 32.2 32.2 32.2 32.2 32.2 32.2 0 32.2 0 0 0Levoglucosan 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Toluene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-Methylnaphthal 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-ts-35-3C 0 0 0 0 0 0 0 23.8 23.8 23.8 23.8 23.8 23.8 23.8 23.8 0 23.8 0 0 03-3-5-Trimethylh 0 0 0 0 0 0 0 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0 0.4 0 0 0N-Propylcyclohex 0 0 0 0 0 0 0 2.9 2.9 2.9 2.9 2.9 2.9 2.9 2.9 0 2.9 0 0 0Mesitylene 0 0 0 0 0 0 0 1 1 1 1 1 1 1 1 0 1 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 0 0 0 0 0 0 0 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0 0.1 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-Nonene 0 0 0 0 0 0 0 1 1 1 1 1 1 1 1 0 1 0 0 0MthCyclohexane 0 0 0 0 0 0 0 40.4 40.4 40.4 40.4 40.4 40.4 40.4 40.4 0 40.4 0 0 0N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 181.4 181.4 181.4 181.4 181.4 181.4 181.4 181.4 0 181.4 0 0 0Propane 0 0 0 0 0 0 0 138.7 138.7 138.7 138.7 138.7 138.7 138.7 138.7 0 138.7 0 0 0I-Butane 0 0 0 0 0 0 0 87.1 87.1 87.1 87.1 87.1 87.1 87.1 87.1 0 87.1 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Table S-1. Streams composition and property data (Continued…)
Stream No. 314 315 316 317 318 319 320 321 322 323 324 325 327 400 401 402 403 404 405 406Temp C 327.2 516.2 857.0 857.0 523.8 567.5 40.0 40.0 40.0 40.0 38.0 38.0 38.0 25.0 102.4 104.1 105.9 170.0 450.0 450.0Pres bar 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 13.3 13.3 13.3 4.0 1.7 1.2 60.0 60.0 59.9 59.9Enth MJ/h -351900.0 -351900.0 -325450.0 -284790.0 -311240.0 -311290.0 -386830.0 -244860.0 -244860.0 -141970.0 -142420.0 -142420.0 266.4 -124610.0 -4054700.0 -4065400.0 -4063400.0 -3991200.0 -3316100.0 -99483.0Vapor mass frac. 1.0 1.0 1.0 1.0 1.0 1.0 0.6 0.0 0.0 1.0 1.0 1.0 1.0 0.0 0.0 0.0 0.0 0.0 1.0 1.0Total kg/h 34652.6 34652.8 34652.8 34652.6 34652.6 34652.7 34652.7 15571.7 15571.7 19081.0 17673.2 17673.2 1407.8 7848.5 260722.1 261529.0 261529.0 261529.0 261526.2 7845.8Flow rates in kg/hWater 22524.7 20262.1 20262.1 17225.4 17225.4 15515 15515 15433.8 15433.8 81.2 81.2 81.2 0 7848.5 260722.1 261529 261529 261529 261526.2 7845.8Nitrogen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Oxygen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hydrogen 248.5 312.2 312.2 1373.1 1373.1 1564.4 1564.4 0.3 0.3 1564.2 156.4 156.4 1407.8 0 0 0 0 0 0 0Carbon Dioxide 5438.4 10777 10777 10388.8 10388.8 14567.2 14567.2 72.5 72.5 14494.7 14494.7 14494.7 0 0 0 0 0 0 0 0Carbon Monoxide 3491.4 213.9 213.9 5429.5 5429.5 2770.2 2770.2 0.5 0.5 2769.7 2769.7 2769.7 0 0 0 0 0 0 0 0Methane 1311.4 3063.7 3063.7 171.1 171.1 171.1 171.1 0 0 171 171 171 0 0 0 0 0 0 0 0Ethylene 1129.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0HydroxyAcetone 0.2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-5-Xylenol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0syringol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Heptane 32.2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Levoglucosan 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Toluene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-Methylnaphthal 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-ts-35-3C 23.8 23.8 23.8 64.8 64.8 64.8 64.8 64.6 64.6 0.2 0.2 0.2 0 0 0 0 0 0 0 03-3-5-Trimethylh 0.4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Propylcyclohex 2.9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Mesitylene 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 0.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-Nonene 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0MthCyclohexane 40.4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 181.4 0.1 0.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Propane 138.7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0I-Butane 87.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Table S-1. Streams composition and property data (Continued…)
Stream No. 407 408 409 410 411 412 413 416 417 418 419 420 421 422 423 500 501 502 503 504Temp C 450.0 450.0 450.0 250.0 450.0 207.6 120.3 120.3 120.3 46.0 46.0 46.1 104.8 104.8 104.8 25.0 29.9 30.1 40.2 30.0Pres bar 59.9 59.9 59.9 59.9 59.9 6.5 2.0 2.0 2.0 0.1 0.1 4.3 1.2 1.2 1.7 1.0 1.0 5.0 5.0 5.0Enth MJ/h -99413.0 -3214400.0 -361370.0 -424350.0 -2850900.0 -2949400.0 -2989500.0 -3988.9 -2985500.0 -3065000.0 -3545200.0 -3543800.0 -6732.9 -3926300.0 -3926100.0 -2846100.0 -218610000.0 -218820000.0 -218230000.0 -218600000.0Vapor mass frac. 1.0 1.0 1.0 0.0 1.0 1.0 1.0 1.0 1.0 0.9 0.0 0.0 1.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0Total kg/h 7840.3 253502.0 28500.0 28500.0 224834.5 224834.5 224834.5 300.0 224534.5 224534.5 224534.5 224454.7 506.3 252628.4 252615.4 179263.0 13786885.0 13800400.0 13800400.0 13786707.0Flow rates in kg/hWater 7840.3 253502 28500 28500 224834.5 224834.5 224834.5 300 224534.5 224534.5 224534.5 224454.7 506.3 252628.4 252615.4 179263 13786885 13800400 13800400 13786707Nitrogen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Oxygen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hydrogen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Carbon Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Carbon Monoxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Methane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0HydroxyAcetone 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-5-Xylenol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0syringol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Heptane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Levoglucosan 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Toluene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-Methylnaphthal 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-ts-35-3C 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 03-3-5-Trimethylh 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Propylcyclohex 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Mesitylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-Nonene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0MthCyclohexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Propane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0I-Butane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Table S-1. Streams composition and property data (Continued…)
Stream No. 505 506 507 508 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615Temp C 30.0 30.0 30.0 30.0 200.0 38.0 38.0 37.8 30.6 1642.3 1947.6 260.0 117.2 143.2 37.8 38.0 450.0 30.0 30.0 31.5Pres bar 5.0 5.0 5.0 5.0 1.5 1.2 13.3 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 13.3 59.9 5.0 5.0 1.2Enth MJ/h -2527200.0 -312350.0 -312350.0 -215760000.0 11903.0 -55093.0 -142350.0 -4.2 -197650.0 -185740.0 -145090.0 -352650.0 -889470.0 -1242100.0 -478170.0 265.4 -99418.0 -276410.0 -276410.0 -1275400.0Vapor mass frac. 0.0 0.0 0.0 0.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 0.0 1.0 1.0 0.0 0.0 0.0Total kg/h 159385.6 19699.4 19699.4 13607622.0 66626.8 9704.2 17665.0 0.7 27388.0 94014.8 94014.8 94014.8 425254.2 519269.0 31471.7 1402.3 7840.7 17432.3 17432.3 83296.0Flow rates in kg/hWater 159385.6 19699.4 19699.4 13607622 0 0 81.2 0 81 5190.7 5190.7 5190.7 26047.7 31238.4 29734.9 0 7840.7 17432.3 17432.3 80022.2Nitrogen 0 0 0 0 52368.6 0 0 0 0 52368.6 52368.6 52368.6 299759.4 352128.1 0 0 0 0 0 0Oxygen 0 0 0 0 14258.1 0 0 0 0 2152.1 2152.1 2152.1 34464.7 36616.8 0 0 0 0 0 0Hydrogen 0 0 0 0 0 49.1 156.6 0 205 0.5 0.5 0.5 0 0.5 0 1402.3 0 0 0 1402.6Carbon Dioxide 0 0 0 0 0 4581.3 14486.3 0.4 19094.2 34216.1 34216.1 34216.1 64982.4 99198.5 9.3 0 0 0 0 82Carbon Monoxide 0 0 0 0 0 3321.7 2769.4 0.1 6086.2 86.7 86.7 86.7 0 86.7 0.1 0 0 0 0 0.6Methane 0 0 0 0 0 677.9 171.3 0 847.2 0 0 0 0 0 0 0 0 0 0 0.1Ethylene 0 0 0 0 0 1074.2 0 0.1 1074.3 0 0 0 0 0 0.3 0 0 0 0 0.3Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 0 0 0 0 0 0 0 0 0 0 0 0 0 0 81.2 0 0 0 0 81.2HydroxyAcetone 0 0 0 0 0 0 0 0 0 0 0 0 0 0 973.5 0 0 0 0 973.52-5-Xylenol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 69.3 0 0 0 0 69.3syringol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 559.1 0 0 0 0 559.1N-Heptane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.6 0 0 0 0 0.6Levoglucosan 0 0 0 0 0 0 0 0 0 0 0 0 0 0 39.1 0 0 0 0 39.1Toluene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 42-Methylnaphthal 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.3 0 0 0 0 0.31-ts-35-3C 0 0 0 0 0 0 0.2 0 0.2 0 0 0 0 0 0 0 0 0 0 61.23-3-5-Trimethylh 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Propylcyclohex 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Mesitylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-Nonene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0MthCyclohexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Propane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0I-Butane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Table S-1. Process heat exchangers
Table S-2. Targeted utilities
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Table S-3. Heat exchanger network design
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Table S-2. Major power consumption breakdown
Major Power Consumption by Area MW Pretreatment Covered in the feedstock cost Pyrolysis Screw Feed Air Compressor Fluidizing Gas Compressor
0.73 5.57 0.23
Upgrading Bio Oil Pump H2 Compressors H2 Recycle Compressors
0.07 2.88 1.06
H2 Generation Offgas Compressors Feed Water Pump
1.45 0.01
Cogeneration Turbine power generation Feed Water Pump Condensate Pumps
48.05 0.66 0.03
Cooling Plant 1.70 Total -33.73
Table S-6. Operational cost break down
$/gal product
$ million/year
Dry Biomass 1.65 63.4 Catalysts & Chemicals 0.17 6.5 Waste Disposal 0.07 2.9 Electricity and other utilities -0.41 -15.6 Fixed Costs 0.55 21.2 Capital Depreciation 0.50 19.2 Average Income Tax 0.28 10.9 Average Return on Investment 0.87 33.7 Total 3.69 142.1
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Table S-7. Capital cost break down
Equipment Number
Number Required Equipment Name
Max size Scaling Stream
Scaling Stream Flow ,
tpdNew Stream
Flowstream flow
unitsSize Ratio
Original Equip Cost (per unit)
Base Year
COST BASIS:
installed (i) or bare (b)
Total Original Equip Cost (Req'd & Spare) in Base
YearScaling
Ex ponentScaled Cost in
Base Year Installation FactorInstalled Cost in
Base Year Installed Cost in 2011$Scaled Uninstalled
Cost in 2011$ source
CE Index base year
CE Index 2011
A100 Pretreatment & Pyrolysis Cost included in feedstock handling1 Feedstock Handling Equipment Cost included in feedstock handling1 Dryer Cost included in feedstock handling1 Hammer Mill Cost included in feedstock handling1 Hammer Mill Screens Cost included in feedstock handling1 Pyrolyser Feed Screw kg/hr 83,333 83,333 kg/hr 1.00 $162,500 2010 b $162,500 0.6 $162,500 4.28 $695,500 $739,075 $172,681 3 550.8 585.31 Catalytic Pyrolyzer BPSD 60,000 17,122 BPSD 0.29 $22,700,000 2001 i $22,700,000 0.6 $10,697,143 4.28 $10,697,143 $15,879,115 $3,710,074 6 394.3 585.31 Regenerator BPSD 60,000 17,122 BPSD 0.29 $50,000,000 2001 i $50,000,000 0.6 $23,561,989 4.28 $23,561,989 $34,976,024 $8,171,968 6 394.3 585.31 Cyclone Seperators Cost included in catalytic pyrolyzer1 Bio Oil Condensor Cost Included in heat exchanger 1 Condensor Flash Cost Included in heat exchanger 1 Electrostatic Precipitator kg/hr 64,795 96,181 kg/hr 1.48 $883,048 2010 b $883,048 0.6 $1,119,214 4.28 $4,790,234 $5,090,355 $1,189,335 3 550.8 585.31 Air Compressor $3,902,200 2010 b $3,902,200 0.6 $3,902,200 4.28 $16,701,416 $17,747,804 $4,146,683 1 550.8 585.31 Air Preheater Cost Included in heat exchanger 1 Fluidizing Gas Compressor $592,667 2010 b $592,667 0.6 $592,667 4.28 $2,536,615 $2,695,540 $629,799 1 550.8 585.31 Flash Phase Seperator $25,823 2010 b $25,823 0.6 $25,823 4.28 $110,522 $138,167 $32,282 2 468.2 585.3
A100 $78,266,238 $40,061,536 $59,093,420 $77,266,081 $18,052,823Equiment contingency 0% $0 $0
$77,266,081 $18,052,823
A200 Hydroprocessing1 Hydrotreater 1 BPSD 50,000 2,867 BPSD 0.06 $100,000,000 2007 i $100,000,000 0.6 $17,991,593 4.28 $17,991,593 $18,301,430 $4,276,035 2 575.4 585.3 Cost Included in heat exchanger 1 Hydrotreater 2 Preheater1 Hydrotreater 2 BPSD 50,000 2,867 BPSD 0.06 $175,000,000 2002 i $175,000,000 0.6 $31,485,287 4.28 $31,485,287 $32,027,503 $7,483,061 2 575.4 585.3 Cost Included in heat exchanger 1 Hydrotreater 1 Preheater Cost Included in heat exchanger 1 Bio Oil Pump Pump $11,414 2010 b $11,414 0.6 $11,414 4.28 $48,850 $51,911 $12,129 1 550.8 585.31 Hydrogen Recycle Compressor1 $929,196 2010 b $929,196 0.6 $929,196 4.28 $3,976,959 $4,226,126 $987,413 1 550.8 585.31 Hydrogen Recycle Compressor2 $842,118 2010 b $842,118 0.6 $842,118 5.28 $4,446,383 $4,724,961 $894,879 1 550.8 585.31 H2 Compressor 1 $1,211,410 2010 b $1,211,410 0.6 $1,211,410 4.28 $5,184,835 $5,509,679 $1,287,308 1 550.8 585.31 H2 Comp. Cooler 1 Cost Included in heat exchanger 1 H2 Compressor 2 $1,637,310 2010 b $1,637,310 0.6 $1,637,310 4.28 $7,007,687 $7,446,737 $1,739,892 1 550.8 585.31 H2 Comp. Cooler 2 Cost Included in heat exchanger 1 H2 Compressor 3 $886,513 2010 b $886,513 0.6 $886,513 4.28 $3,794,276 $4,031,997 $942,055 1 550.8 585.31 Fractionator $86,445 2010 b $86,445 0.6 $86,445 4.28 $369,985 $549,216 $128,321 6 394.3 585.31 Debutanizer $184,437 2010 b $184,437 0.6 $184,437 4.28 $789,390 $986,838 $230,570 2 468.2 585.31 PSA - Hydrogen Recovery H2 MMscfd 10 10.23 H2 MMscfd 1.02 $1,750,000 2004 i $1,750,000 0.6 $1,773,624 4.28 $1,773,624 $2,337,051 $546,040 2 444.2 585.31 HT Output Cooler Cost Included in heat exchanger 1 HP Flash $33,794 2010 b $33,794 0.6 $33,794 4.28 $144,640 $180,818 $42,247 2 468.2 585.31 LP Flash $14,971 2010 b $14,971 0.6 $14,971 4.28 $64,074 $80,101 $18,715 2 468.2 585.31 Fractionator Reboiler Cost Included in heat exchanger 1 Fractionator Condensor Cost Included in heat exchanger 1 Fractionation Preheater Cost Included in heat exchanger
A200 $2,069,647 $2,093,271 $3,141,713 $137,660,630 $18,588,665Equiment contingency 0% $0 $0
$137,660,630 $18,588,665
A300 Hydrogen Generation1 Hygrogen Plant H2 MMscfd 25 13.141 H2 MMscfd 0.53 $94,527,826 2007 i $94,527,826 0.6 $64,264,734 4.28 $64,264,734 $71,592,564 $16,727,235 6 525.4 585.31 Water Gas Shift Reactor Cost Included in Hydrogen Plant1 Reformer Output Cooler Cost Included in Hydrogen Plant1 H2 Reformer Cost Included in Hydrogen Plant1 H2 Reformer Heater Cost Included in Hydrogen Plant1 Reformer Feed Heater Cost Included in Hydrogen Plant1 Water Gas Shift Output Cooler Cost Included in Hydrogen Plant1 Process Water Pump $6,231 2010 b $6,231 0.6 $6,231 4.28 $26,667 $28,337 $6,621 1 550.8 585.31 Process Water Heater Cost Included in heat exchanger 1 PSA - Hydrogen Plant Cost Included in Hydrogen Plant1 Flash Seperator Cost Included in Hydrogen Plant1 Off Gas Compressor 1 $1,041,010 2010 b $1,041,010 0.6 $1,041,010 4.28 $4,455,523 $4,734,673 $1,106,232 1 550.8 585.31 Off Gas Comp. intercooer 1 Cost Included in heat exchanger 1 Off Gas Compressor 2 $768,605 2010 b $768,605 0.6 $768,605 4.28 $3,289,629 $3,495,733 $816,760 1 550.8 585.31 Off Gas Comp. intercooer 2 Cost Included in heat exchanger 1 Off Gas Compressor 3 $691,568 2010 b $691,568 0.6 $691,568 4.28 $2,959,911 $3,145,357 $734,897 1 550.8 585.31 Off Gas Comp. intercooer 3 Cost Included in heat exchanger
A300 $2,507,414 $2,507,414 $10,731,730 $82,996,665 $19,391,744Equiment contingency 0% $0 $0
$82,996,665 $19,391,744
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Table S-7. Capital cost break down (Continued…)
A400 Co-generation1 Condensate Pump 1 Cost Included in Boiler1 Condensate Pump 2 Cost Included in Boiler1 Boiler Feed Water Pump Cost Included in Boiler1 Deaereator kg/hr 238,686 260,300 kg/hr 1.09 $305,000 2010 b $305,000 0.6 $321,283 4.28 $1,375,093 $1,461,246 $341,413 5 550.8 585.31 Condensate Tank Cost Included in Boiler1 Boiler Condensor 0.6 Cost Included in heat exchanger 1 Boiler & Accessories kg/hr steam 238,686 261,616 kg/hr steam 1.10 $51,300,000 2010 i $51,300,000 0.6 $54,202,607 3.02 $54,202,607 $57,598,545 $19,072,366 4 & 5 550.8 585.3 Scaled using direct installed cost1 Three Stage Turbine MW 42 48.05 MW 1.14 $17,100,000 2010 i $17,100,000 0.6 $18,484,575 3.02 $18,484,575 $19,642,683 $6,504,200 4 & 5 550.8 585.3 Scaled using direct installed cost
$0A400 $68,705,000 $73,008,465 $74,062,274 $78,702,473 $25,917,978
Equiment contingency 0% $0 $0$78,702,473 $25,917,978
A500 Cooling plantE500 1 Cooling Tow er kg/hr 10,037,820 13,800,000 kg/hr 1.37 $1,375,000 2010 b $1,375,000 0.6 $1,664,357 4.28 $7,123,448 $7,569,751 $1,768,633 4 & 5 550.8 585.3 Scaled using Aspen energy analyserE501 1 Cooling Water Pump kg/hr 10,982,556 13,800,000 kg/hr 1.26 $283,671 2010 b $567,342 0.6 $650,654 4.28 $2,784,801 $2,959,276 $691,420 5 550.8 585.3
A600 $1,942,342 $2,315,011 $9,908,249 $10,529,027 $2,460,053Equiment contingency 0% $0 $0
$10,529,027 $2,460,053
A600 Other1 Off Gas Combustor Cost Included in Hydrogen Plant1 Gas Combustor Heat Recovery Cost Included in heat exchanger 1 Regenerator Heat Recovery Cost Included in heat exchanger 1 Scrubber Cost Included in Boiler1 Process to Process HE $2,840,000 2010 i $2,840,000 0.6 $2,840,000 4.28 $2,840,000 $2,888,908 $674,979 4 575.4 585.3 From HEN 1 LP steam Not required1 MP steam Not required1 HP steam $206,000 2010 i $206,000 0.6 $206,000 4.28 $206,000 $209,548 $48,960 4 575.4 585.3 From HEN 1 Cooling HE $3,748,200 2010 i $3,748,200 0.6 $3,748,200 4.28 $3,748,200 $3,812,749 $890,829 4 575.4 585.3 From HEN 1 HP Steam Generation Included in the Boiler cost1 Process Water Tank kg/hr 250,000 304,000 kg/hr 1.22 $250,000 2009 b $250,000 0.6 $281,125 4.28 $1,203,217 $1,349,404 $315,281 5 521.9 585.31 Bio oil Buffer Check Tank kg/hr 65,000 152,000 kg/hr 2.34 $200,000 2009 b $200,000 0.6 $332,957 4.28 $1,425,056 $1,598,195 $373,410 5 521.9 585.31 Bio oil Check Tank kg/hr 65,000 152,000 kg/hr 2.34 $200,000 2009 b $200,000 0.6 $332,957 4.28 $1,425,056 $1,598,195 $373,410 5 521.9 585.31 Torch Oil Tank kg/hr 65,000 128,000 kg/hr 1.97 $200,000 2009 b $200,000 0.6 $300,336 4.28 $1,285,440 $1,441,616 $0 5 521.9 585.31 Product Storage Tank kg/hr 65,000 300,000 kg/hr 4.62 $200,000 2009 b $200,000 0.6 $500,674 4.28 $2,142,883 $2,403,236 $561,504 5 521.9 585.31 Product Storage Tank kg/hr 65,000 240,000 kg/hr 3.69 $200,000 2009 b $200,000 0.6 $437,934 4.28 $1,874,358 $2,102,086 $491,142 5 521.9 585.31 Product Storage Tank kg/hr 65,000 100,000 kg/hr 1.54 $200,000 2009 b $200,000 0.6 $258,989 4.28 $1,108,475 $1,243,151 $290,456 5 521.9 585.31 Product Storage Tank kg/hr 65,000 644,000 kg/hr 9.91 $200,000 2009 b $200,000 0.6 $791,796 4.28 $3,388,888 $3,800,627 $887,997 5 521.9 585.31 Emergency Flare kg/hr 393,100 205,288 kg/hr 0.52 $32,955 2010 b $32,955 0.6 $22,317 4.28 $95,517 $101,502 $23,715 5 550.8 585.31 Fire Water Pump kg/hr 83,333 83,333 kg/hr 1.00 $15,000 2009 b $15,000 0.6 $15,000 4.28 $64,200 $72,000 $16,822 5 521.9 585.31 Plant Air Compressor mptd 2,000 2,000 mptd biomass 1.00 $87,922 2007 b $87,922 0.6 $87,922 4.28 $376,306 $419,215 $97,947 7 525.4 585.31 Hydraulic Truck Dump w ith Scale mptd 2,000 2,000 mptd 1.00 $80,000 1998 b $80,000 0.6 $80,000 4.28 $342,400 $514,531 $120,218 8 389.5 585.31 Diesel Pump mptd 2,000 2,000 mptd biomass 1.00 $3,842 2007 b $3,842 0.6 $3,842 4.28 $16,444 $18,319 $4,280 7 525.4 585.31 Instrument Air Dryer mptd 2,000 2,000 mptd biomass 1.00 $8,349 2002 b $8,349 0.6 $8,349 4.28 $35,734 $52,870 $12,353 8 395.6 585.31 Plant Air Receiver mptd 2,000 2,000 mptd biomass 1.00 $21,005 2007 b $21,005 0.6 $21,005 4.28 $89,901 $100,152 $23,400 7 525.4 585.31 Firew ater Storage Tank mptd 2,000 2,000 mptd biomass 1.00 $229,900 2007 b $229,900 0.6 $229,900 4.28 $983,972 $1,096,170 $256,115 7 525.4 585.31 Waste w ater treatment plant Cost included in the operating cost
A600 $8,923,173 $22,652,047 $24,822,473 $5,462,817Equiment contingency 0% $0 $0
$24,822,473 $5,462,817
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Table S-8. Equipment cost source
1 Chemcad model 2 S. Jones, J. Holladay, C. Valkenburg, D. Stevens, C. Walton, C. Kinchin, D. Elliott and S. Czernik, Production of Gasoline and Diesel from
Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: a design case, Report PNNL-18284, Pacific Northwest National Laboratory, USA, 2009.
3 M. M. Wright, D. E. Daugaard, J. A. Satrio and R. C. Brown, Fuel, 2010, 89, S2-S10. 4 Aspen Energy Analyser using Chemcad model energy balances 5 D. Humbird, R. Davis, L. Tao, C. Kinchin, D. Hsu, A. Aden, P. Schoen, J. Lukas, B. Olthof, M. Worley, D. Sexton and D. Dudgeon,
Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol, Report NREL/TP-5100-47764, National Renewable Energy Laborotary, USA, 2011.
6 R. A. Meyer, in Handbook of Petroleum Refining Processes, McGraw Hill, New York, 3rd edn. 7 Dutta A, Talmadge M, Hensley J, Worley M, Dudgeon D, Barton D, et al. Techno-economics for conversion of lignocellulosic biomass to
ethanol by indirect gasification and mixed alcohol synthesis. Environmental Progress & Sustainable Energy. 2012;31(2):182-90. 8 Phillips SD. Technoeconomic Analysis of a Lignocellulosic Biomass Indirect Gasification Process To Make Ethanol via Mixed Alcohols
Synthesis. Industrial & Engineering Chemistry Research. 2007;46(26):8887-97.
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Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013