Study on Solid Adsorbent for CO2-Capture from Post ... · 2nd Post Combustion Capture Conference ....
Transcript of Study on Solid Adsorbent for CO2-Capture from Post ... · 2nd Post Combustion Capture Conference ....
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2nd Post Combustion Capture Conference September 17th-20th, 2013
Takeshi Okumura Kawasaki Heavy Industries, Ltd. (KHI)
Study on Solid Adsorbent for CO2-Capture from
Post Combustion Gases Utilizing Low-Temperature Thermal Energy
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Outline
1.About our Company
2.Basic Technology
3.The KCC System
4.CO2 Capture Performance Test
5.CO2 Capture Energy
6.Feasibility Study of the KCC Application
7.Conclusions
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1. About our Company
Motorcycle& Motorcycle& EnginesEngines
AerospaceAerospace
RollingRolling StockStock
Gas Turbine &MachineryGas Turbine &MachineryPlant & InfrastructurePlant & Infrastructure
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Ship & Ship & Offshore StructureOffshore Structure
9 16
2012FYNet Sales
7
19%20
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OthersOthers
Precision MachineryPrecision Machinery
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Motorcycle& Motorcycle& EnginesEngines
AerospaceAerospace
RollingRolling StockStock
Gas Turbine &MachineryGas Turbine &MachineryPlant & InfrastructurePlant & Infrastructure
10
Ship & Ship & Offshore StructureOffshore Structure
9 16
2012FYNet Sales
7
19%20
10
OthersOthers
Precision MachineryPrecision Machinery
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2.Basic Technology
CO2 Concentration :1000 - 5000 ppm
KCC
Original adsorbent enables selective CO2 adsorption
Technology developed for a closed/semi-closed space
Gases CO2
CO2
CO2
CO2
CO2
CO2
CO2
CO2
CO2
CO2
CO2 free Gas
Original Adsorbent (An amine-coated porous material)
Aircraft cabin Office air-conditioning
Submarine Life Support
Kawasaki CO2 Capture
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3.The KCC System
CO2 desorption at low temperature (e.g., 60 oC)
Applicable use of low-temperature waste heat
CO2
Desorption
Alternately
Steam Adsorption
Flue Gas
(60 oC, 20 kPa) Fixed-bed adsorbent (Our Original)
CO2 CO2
CO2 Free Gas
Alternately adsorb and desorb CO2 by mode switching
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Superior adsorption performance for CO2 concentration between 0.1% and 50% confirmed by lab testing.
Adapted to Wide Range of CO2 Concentration
Application of KCC to Post-Combustion gases
KCC System
Gas Engine
Living Space
Thermal Power Plant
Cement Plant
Chemical Plant 0.1%
5% 13%
20%
50%
CO2
Our target
Our target
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4.CO2 Capture Performance Test Photo of the 10 t CO2/day bench-scale test plant
6.5 m (W)×7.5 m (L)×12 m (H)
Adsorption tower
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System Chart of the Bench-Scale Test Plant
Coal-fired flue gas
Gas heater
Condenser
Stack
Adsorption tower
Water Boiler
Steam generator
CO2
Vacuum pump
Fan CO2 free gas
:Coal-fired flue gas :Steam for CO2 recovery :CO2 free gas :Captured CO2
Bag filter
Steam
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Test Conditions and Measurement Parameters
Case1 Case2 Case3
Flue gas flow rate Nm3/h 960 1700 2000
Concentration of CO2 in the flue gas % 12 13 16
Flue gas temperature oC 40 40 40
Steam temperature oC 60 60 60
<Test Conditions>
Fin Nm3/h Flue gas flow rate
Tgin oC Flue gas flow temperature
Cin % Concentration of CO2 in the flue gas
Fout Nm3/h Flow rate of CO2-free gas
Cout % Concentration of CO2 in CO2-free gas
Tvin oC Steam temperature
TS1-TS4 oC
Adsorbent temperature (4 points[A, B, C, and D]on the same plane)
<Main measurement Items> Adsorption tower
Flue gas Fin, Tgin, Cin
Fout, Cout
TS1
TS2
TS3
TS4
CO2 free gas
Adsorbent
TS1A TS1B
TS1C TS1D
90 degrees
CO2
Steam
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0
0.2
0.4
0.6
0.8
1
0 5 10 15 20Adsorpt ion t ime [min]
Ratio
of C
O2
conc
entr
atio
nCo
ut/C
in
Case1Case2Case3
CO2 Adsorption Properties
Close to saturation
Desorption Process
100% adsorption of CO2
<Breakthrough curves, ratio of CO2 concentration>
The KCC adsorbent captures CO2 in the flue gas
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30
40
50
60
70
0 4 8 12Adsorpt ion t ime [min]
Adso
rben
t te
mpe
ratu
re(m
ean
valu
e) [
℃]
Case2 TS1Case2 TS2Case2 TS3Case2 TS4
20
30
40
50
60
70
0 4 8 12Adsorpt ion t ime [min]
Adso
rben
t te
mpe
ratu
re(m
ean
valu
e) [
℃]
Case2 TS2ACase2 TS2BCase2 TS2CCase2 TS2D
Adsorption Temperature <TS1–TS4, mean value>
<TS2A–TS2D>
TS2A TS2B
TS2C TS2D
90 degrees
Adsorption tower
Flue gas Fin, Tgin, Cin
Fout, Cout
TS1
TS2
TS3
TS4
CO2 free gas
Adsorbent
CO2
Steam
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0
2
4
6
0 5 10 15Capacity of CO2 Capture [t/ d]
Ther
mal
Ene
rgy
requ
ired
for
CO2
Capt
ure
[GJ/
t-CO
2]
Thermal Energy Required for CO2 Capture
<Thermal Energy required for CO2 Capture with capacity of CO2 Capture>
Amine solution systems (MEA)
Nearly half
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<KCC Moving-Bed System> <Bench plant>
Target:2016 The Beginning of Commercialization
KCC Moving Bed System
CO2 Free Gas
Steam
CO2
Conveyor
Gas for Adsorption Reactor
Desorption Reactor
Adsorbent Dryer
Drying
5 t-CO2/d
Adsorption Reactor
Desorption Reactor
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CO2
Capture Plants
Thermal Energy Electric Power
Flue Gas
CO2
CO2 Capture Energy
+
Confirmed by Bench-Plant Test
Feasibility Study CO2 Capture Energy (1) Cement Plant (2) Gas Engine
5.CO2 Capture Energy
(Steam, etc.) (Pump or Fan, etc.)
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Clinker Cooler Kiln
Boiler
Exhaust steam
Exhaust gas
Turbine
Clinker:6500 t/d
CO2
CO2:60 t/h
KCC Moving-
Bed System
Electric Power 1.6 GJ/t-CO2
(Primary Energy)
Thermal energy + Electric Power = 1.6 GJ/t-CO2
Waste Heat:Exhaust steam
<The CO2 Capture Energy>
MEA Extraction steam
5.Feasibility Study of KCC Application (1) Cement Plant
60oC
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Fuel Gas
Green Gas Engine
Electric Power
Steam
CO2
Exhaust Gas
Waste Heat
KCC Moving-
Bed System
<Trigeneration System>
・Beverage ・Welding gas ・Dry ice etc.
7800 kW
3.5 t/h
The CO2 Capture Energy:1.3 GJ/t-CO2
3.2 t/h
(2) Gas Engine
Cooling Water (under 100 oC)
CO2 as a commercial product
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7.Conclusion • Our original adsorbents capture CO2 from
post-combustion gas.
• The adsorbent regenerates using 60 oC steam.
• The thermal energy required for CO2 capture by the KCC system is nearly half compared with amine solution systems using MEA.
• From the feasibility study, we find that the CO2 capture energy is 1.6 GJ/t-CO2 for cement plant and 1.3 GJ/t-CO2 for gas engine.
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Thank you for your attention.