STACK EMISSIONS MONITORING REPORT · 2019-01-16 · SOCOTEC UK Job Number: Report Date: Version: 1...

SOCOTEC UK Job Number:Report Date:Version: 1Report By: Adam RussellMCERTS Number: MM 15 1360MCERTS Level: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4

Report Approved By: Andrew O'NeillMCERTS Number: MM 08 985Business Title: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4

Signature:

Sampling Date(s):23rd - 30th August

27th September 2018LEK 11283

Co. LeitrimIreland

Drumsna

Masonite Ireland

Carrick-on-Shannon

Release Point: SO2A

Your contact at SOCOTEC UK LTD

Operator & Address:

Derryoughter

2-4 Langlands PlaceKelvin South Business Park

East KilbrideG75 0YF

Tel: 01355 246 730Fax: 01355 249 669

Permit Reference:IPPC Licence: PO021-02

David HayBusiness Manager - North

Tel: 01355 246 730Email: [email protected]

STACK EMISSIONS MONITORING REPORT

SOCOTEC UK Reporting Template v1 of 51

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EXECUTIVE SUMMARY

Stack Emissions Monitoring Objectives

- Plant

- Operator

- Stack Emissions Monitoring Test House

Emissions Summary

Monitoring Times

Process Details

Monitoring Methods

Analytical Methods

- Sampling Methods with Subsequent Analysis

- On-Site Testing

Sampling Location

- Sampling Plane Validation Criteria

- Duct Characteristics

- Sampling Lines & Sample Points

- Sampling Platform

- Sampling Location / Platform Improvement Recommendations

Sampling and Analytical Method Deviations

APPENDICES

APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team

APPENDIX 2 - Summaries, Calculations, Raw Data and Charts

APPENDIX 3 - Measurement Uncertainty Budget Calculations

CONTENTS

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Masonite IrelandCarrick-on-ShannonSO2A

LEK 11283 / Version 123rd - 30th August

IPPC Licence: PO021-02

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Plant

SO2A

Operator

Masonite Ireland

Derryoughter

Drumsna

Carrick-on-Shannon

Co. Leitrim

Ireland


Stack Emissions Monitoring Test House

SOCOTEC UK - East Kilbride Laboratory2-4 Langlands PlaceKelvin South Business ParkEast KilbrideG75 0YFUKAS and MCERTS Accreditation Number: 1015

Opinions and interpretations expressed herein are outside the scope of UKAS accreditation.MCERTS accredited results will only be claimed where both the sampling and analytical stages are UKAS accredited.This test report shall not be reproduced, except in full, without written approval of SOCOTEC UK LTD.

MONITORING OBJECTIVES

SOCOTEC UK LTD were commissioned by Masonite Ireland to carry out stack emissions monitoring to determine the release of prescribed pollutantsfrom the following Plant under normal operating conditions.

Masonite Ireland operates a first stage fibre drier process at Carrick-on-Shannon which is subject to IPPC Licence PO021-02, under the EPA Act 1992.

EXECUTIVE SUMMARY

The results of these tests shall be used to demonstrate compliance with a set of emission limit values for prescribed pollutants as specified in thePlant's IPPC Licence, PO021-02.

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Parameter Units Result Calculated Uncertainty

Limit

+/-Total Particulate Matter mg/m³ 1.57 0.23 20Particulate Emission Rate kg/hr 0.32 0.05 2.1

Dioxins & Furans (NATO I-TEQ) ng/m³ 0.0084 0.0109 -Dioxins & Furans (NATO I-TEQ) Emission Rate µg/hr 1.2390 1.6095 -Dioxins & Furans (WHO TEQ Humans / Mammals) ng/m³ 0.0076 0.0099 -Dioxins & Furans (WHO TEQ H / M) Emission Rate µg/hr 1.1199 1.4548 -Dioxins & Furans (WHO TEQ Fish) ng/m³ 0.0089 0.0115 -Dioxins & Furans (WHO TEQ Fish) Emission Rate µg/hr 1.3067 1.6974 -Dioxins & Furans (WHO TEQ Birds) ng/m³ 0.0194 0.0252 -Dioxins & Furans (WHO TEQ Birds) Emission Rate µg/hr 2.8583 3.7129 -

Dioxins & Furans (NATO I-TEQ) ng/m³ 0.0075 0.0098 -Dioxins & Furans (NATO I-TEQ) Emission Rate µg/hr 1.1068 1.4378 -Dioxins & Furans (WHO TEQ Humans / Mammals) ng/m³ 0.0060 0.0077 -Dioxins & Furans (WHO TEQ H / M) Emission Rate µg/hr 0.8776 1.1401 -Dioxins & Furans (WHO TEQ Fish) ng/m³ 0.0072 0.0094 -Dioxins & Furans (WHO TEQ Fish) Emission Rate µg/hr 1.0644 1.3826 -Dioxins & Furans (WHO TEQ Birds) ng/m³ 0.0178 0.0231 -Dioxins & Furans (WHO TEQ Birds) Emission Rate µg/hr 2.6160 3.3982 -Formaldehyde mg/m³ 3.57 0.35 12Formaldehyde Emission Rate kg/hr 0.73 0.07 0.8CVOCs mg/m³ 9.14 1.87 100CVOCs Emission Rate kg/hr 1.87 0.38 6.7Total Aldehydes mg/m³ 5.83 1.24 20Total Aldehydes Emission Rate kg/hr 1.09 0.23 2Sulphur dioxide mg/m³ 0.25 0.04 40Sulphur dioxide Emission Rate kg/hr 0.05 0.01 4.3Oxides of Nitrogen (as NO2) mg/m³ 33.4 5.40 200Oxides of Nitrogen (as NO2) Emission Rate kg/hr 7.18 1.16 21.3Carbon Monoxide mg/m³ 12.6 2.91 100Carbon Monoxide Emission Rate kg/hr 2.71 0.63 10.7Oxygen (dry) % v/v 17.1 2.91 - P

Oxygen (Wet) % v/v 14.3 2.44Moisture % 16.0 0.66 - P

Stack Gas Temperature oC 56.0 - -Stack Gas Velocity m/s 10.24 0.24 -Gas Volumetric Flow Rate (Actual) m³/hr 154491 7886 -Gas Volumetric Flow Rate (STP, Wet) m³/hr 129096 6589 -Gas Volumetric Flow Rate (STP, Dry) m³/hr 108472 5537 -Gas Volumetric Flow Rate at Reference Conditions m³/hr 215185 10984 -

P

Reference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.

P

P

P

P

P

P

EXECUTIVE SUMMARY

EMISSIONS SUMMARY

P

ND = None Detected,Results at or below the limit of detection are highlighted by bold italic text.The above volumetric flow rate is calculated using data from the preliminary survey. Mass emissions for non isokinetic tests are calculated using these values. For all isokinetic testing the mass emission is calculated using test specific flow data and not the above values.

P

P

P

P

P

O

O

MCERTS accredited

result

Dioxins & Furans - UPPER Limits

Dioxins & Furans - LOWER Limits

P

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Total Particulate Matter Run 1

Formaldehyde Run 1CVOCs Run 1Total Aldehydes Run 1Sulphur dioxide Run 1Combustion Gases 28 August 2018 60 minutes

60 minutes

28 August 201814:21 - 15:25

Dioxins & Furans Run 160 minutes

30 August 2018 360 minutes11:12 - 17:1723 August 2018 15:35 - 16:38

Sampling TimesSampling Date(s)Parameter

EXECUTIVE SUMMARY

Sampling DurationMONITORING TIMES

23 August 201815:35 - 16:38

28 August 201823 August 2018

60 minutes

15:35 - 16:38 60 minutes

60 minutes

23 August 2018 15:12 -Preliminary Stack Traverse15:31 - 16:3115:40 - 16:45

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Description of process First stage fibre drier

Continuous or batch Continuous

Product Details Door skin manufacturing

Part of batch to be monitored (if applicable) N/A

Normal load, throughput or continuous rating Normal

Fuel used during monitoring N/A

Abatement Scrubber

EXECUTIVE SUMMARY

Process Details

PROCESS DETAILS

Parameter

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Species SOCOTEC UK UKAS Lab MCERTS Limit of CalculatedTechnical Number Accredited Detection MUProcedure Method (LOD) +/- %

TPM AE 104 1015 Yes 0.19 mg/m³ 14.7%PCDD/PCDF AE 109 1015 Yes 0.002 ng/m³ 129.9%

Formaldehyde AE 114 1015 Yes 0.01 mg/m³ 9.9%CVOCs AE112 1015 No 0.02 mg/m³ 20.5%

Total Aldehydes Based on AE114 1015 No 0.08 mg/m³ 21.3%Sulphur dioxide AE 112 1015 Yes 0.01 mg/m³ 16.3%

NOX AE 102 1015 Yes 0.26 mg/m³ 16.2%CO AE 102 1015 Yes 0.14 mg/m³ 23.2%O2 AE 102 1015 Yes 0.01% 17.1%

H2O AE 105 1015 Yes 0.01% 4.13%Velocity AE 154 1015 Yes 5 Pa 2.36%

Volumetric Flow Rate

AE 154 1015 Yes - 5.10%

- - - - - -

SRM - EN 15058:2017

SRM - EN 14790

Monitoring Methods

AM - EN 14789:2017

SRM - EN 1948 - Part 1

MONITORING METHODS

EN 14791

SRM - EN 14792:2017

Standard Reference Method / Alternative Method

The selection of standard reference / alternative methods employed by SOCOTEC UK is determined, wherever possible by the hierarchy of methodselection outlined in Environment Protection Agency Technical Guidance Note (Monitoring) AG2.

USEPA M0011

USEPA M316

SRM - EN ISO 16911-1

Method

SRM - EN ISO 16911-1

EXECUTIVE SUMMARY

-

SRM - EN 14791

SRM - EN 13284-1

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The following tables list the analytical methods employed together with the custody and archiving details:

Species Analytical UKAS Lab Analysis Lab Sample ArchiveProcedure Number Archive Period

Location

TPM AE 106 1015 YesSOCOTEC UK (East Kilbride)

SOCOTEC UK (East Kilbride)

8 Weeks

PCDD/PCDF MSOP1 1549 Yes CLS CLS 8 Weeks

Formaldehyde M103 0605 Yes RPS RPS 8 Weeks

CVOCs Based on AE112 1015 NoSOCOTEC UK -

(Bretby)SOCOTEC UK -

(Bretby)8 Weeks

Total AldehydesASC/SOP/237

Issue 11015 No

SOCOTEC UK - (Bretby)

SOCOTEC UK - (Bretby)

8 Weeks

Sulphur dioxide ASC/SOP/110 1015 YesSOCOTEC UK -

(Bretby)SOCOTEC UK -

(Bretby)8 Weeks

Species Analytical UKAS Lab MCERTS Laboratory Data ArchiveProcedure Number Accredited Archive Period

NOX AE 102 1015 YesSOCOTEC UK (East Kilbride)


5 years

CO AE 102 1015 YesSOCOTEC UK (East Kilbride)


5 years

O2 AE 102 1015 YesSOCOTEC UK (East Kilbride)


5 years

H2O AE 105 1015 YesSOCOTEC UK (East Kilbride)

- -

ON-SITE TESTING

Chemiluminescence

Gravimetric

Zirconia Cell

Spectrophotometry

Gas Chromatography - High Resolution Mass Spectometry

UKAS Accredited Lab Analysis

Non Dispersive Infra Red

SAMPLING METHODS WITH SUBSEQUENT ANALYSISAnalytical Technique

Analytical Methods

Gravimetric

HPLC/Diode Array Detection

Ion Chromatography

UV-Persulphate Oxidation/IR

Analytical Technique

EXECUTIVE SUMMARY

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Sampling Plane Validation Criteria Value Units Requirement Compliant Method

Lowest Differential Pressure 49 Pa >= 5 Pa Yes EN 15259

Lowest Gas Velocity 8.3 m/s - - -

Highest Gas Velocity 11.8 m/s - - -

Ratio of Gas Velocities 1.4 : 1 < 3 : 1 Yes EN 15259

Mean Velocity 10.2 m/s - - -

Maximum angle of flow with regard to duct axis <15 o < 15o Yes EN 15259

No local negative flow Yes - - Yes EN 15259

Value Units Isokinetic

Shape Circular -

Depth 2.31 m Sample port size 4" (Non BSP) 4" (Non BSP)

Width - m Number of lines used 2 1

Area 4.19 m2 Number of points / line 10 1

Port Depth 90 mm Duct orientation Vertical VerticalFiltration - In Stack

In Stack -

General Platform Information

Permanent / Temporary Platform / Ground level / Floor Level / Roof

Inside / Outside

AG1 Platform requirements

Is there a sufficient working area so work can be performed in a compliant manner

Platform has 2 levels of handrails (approximately 0.5 m & 1.0 m high)

Platform has vertical base boards (approximately 0.25 m high)

Platform has removable chains / self closing gates at the top of ladders

Handrail / obstructions do not hamper insertion of sampling equipmentDepth of Platform = >Stack depth / diameter + wall and port thickness + 1.5m

Sampling Platform Improvement Recommendations (if applicable)

Yes

Filtration for TPM

Yes

SAMPLING LINES & POINTS

Yes

Outside

Yes

Yes

DUCT CHARACTERISTICS

EXECUTIVE SUMMARY

Permanent

Yes

The sampling location meets all the requirements as specified in EA Guidance Note M1.

SAMPLING LOCATION

SAMPLING PLATFORM

Non-Iso & Gases

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Sampling Line B

Transfer Line

USEPA M316

USEPA M0011

A transfer line between the first impinger & filter holder was employed due to handrails hampering the insertion of sampling equipment.

Sampling & Analytical Method Deviations

EXECUTIVE SUMMARY

The full number of sampling points could not be completed on sampling line B due to probe overhang (see stack diagram)

Total Aldehyde samples were filtered at the request of Masonite therefore the monitoring does not completely adhere to US EPA Method0011.

Formaldehyde samples were filtered at the request of Masonite therefore the monitoring does not completely adhere to US EPA Method316.

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APPENDICES


CONTENTS

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Species SOCOTEC UK UKAS Lab MCERTSTechnical Number AccreditedProcedure Method

TPM AE 104 1015 Yes 1PCDD/PCDF AE 109 1015 Yes 1Formaldehyde AE 114 1015 Yes 1

CVOCs AE112 1015 No 1Total Aldehydes Based on AE114 1015 No 1Sulphur dioxide AE 112 1015 Yes 1

NOx AE 102 1015 Yes 1CO AE 102 1015 Yes 1O2 AE 102 1015 Yes 1

H2O AE 105 1015 Yes 1Velocity AE 154 1015 Yes 1

Method


SRM - EN 1948 - Part 1

USEPA M0011EN 14791

SRM - EN 15058:2017

Number of Samples

SRM - EN 14791

MONITORING SCHEDULE

SRM - EN 14792:2017

SRM - EN ISO 16911-1SRM - EN 14790

Standard Reference Method / Alternative Method

USEPA M316

AM - EN 14789:2017

SRM - EN 13284-1

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Equipment I.D. Equipment I.D. Equipment I.D.

LEK 9.30 LEK 21-15 LEK 15.21

LEK 9.31 - LEK 20.5

LEK 9.31 - LEK 17.1

LEK 9.31 - -

LEK 17.17 - LEK 16.8

- - -

LEK 6.51 - LEK 2.11

- - LEK 3.15

- - -

- - LEK 29.9

LEK 6.51 - -

- - -

LEK 23.21 LEK 12.10 -

- LEK 8.22 -

- - -

LEK 15.1F - -

- - -

- - LEK 8.22

LEK 24.1 - -

NOTE: If the equipment I.D is represented by a dash (-), then this piece of equipment has not been used for this test.

Cylinder I.D Number

Supplier ppm %Analytical

Tolerance +/- %

Oxygen Fresh Air BOC - 20.9 2.0

Nitric Oxide LEK BOC 200 - 2.0

Carbon Monoxide LEK 163 BOC 166 - 2.0- - - - -

Level Expiry TE1 TE2 TE3 TE4 H&S

Hugh McMahon MM 15 1347MCERTS Level

2Sep-20 Feb-22 May-22 Jul-22 Feb-22 Sep-20

Shane Thompstone

MM 16 1395MCERTS Level

1Oct-21 - - - - Oct-21

Philip Conway MM 18 1474MCERTS Trainee

Mar-23 - - - - Mar-23

Bernath 3006 FID

Tape Measure

STACK EMISSIONS MONITORING TEAM

-

MCERTS Number

TE / H&S Qualifications and Expiry DateMCERTS

Chiller (JCT/MAK 10)Site Balance

5m Heated Line (1)

Small DGM

Heated Line Controller (1)

Site temperature Logger

Inclinometer (Swirl Device)

MONITORING TEAM

Equipment

Laboratory Balance

1m Heated Line (2)

Mass Flow Controller

Thermo FID

Digital Temperature Meter

Servomex

Probe Thermocouple

FT-IR Oven Box

1m Heated Line (3)

Callipers

20m Heated Line (2)

MFC Display module

Probe

Probe Thermocouple

Stackmaster

FTIR Heater Box for Heated Line

Meter Out Thermocouple

Control Box Timer

Stack Thermocouple

1m Heated Line (1)

L-Pitot

Oven Box

Probe JCT Heated Head Filter

Protractor

Digital Micromanometer

Heated Line Controller (2)

Meter In Thermocouple Stopwatch

Extractive Sampling

Control Box DGM

CALIBRATEABLE EQUIPMENT CHECKLIST

Equipment

Anemometer

Horiba PG-250 Analyser


Box Thermocouples

Signal 3030 FID

Instrumental Analyser/s

Personnel

CALIBRATION GASES

S-Pitot

FT-IR Gasmet

Barometer

Equipment

Ecophysics NOx Analyser

Heater Controller

Last Impinger Arm

Gas (traceable to ISO 17025)

Miscellaneous

Dioxins Cond. Thermocouple

10m Heated Line (2)

15m Heated Line (1)

10m Heated Line (1)

20m Heated Line (1)

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Uncertainty Limit Emissionmg/m³ mg/m³ Rate g/hr

0.23 20 322

Blank - - -Reference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.

TestFilter & Probe Rinse Number

Filter Start Weight

Filter End Weight

Mass Gained on Filter

Probe Rinse Start Weight

Probe Rinse End Weight

Mass Gained on Probe

Combined Total Mass Gained

g g g g g g gRun 1 AC 9401 0.09337 0.09582 0.00245 202.72680 202.72760 0.00080 0.00325If total mass gained is less than the LOD then the LOD is reported

TestFilter & Probe

NumberFilter Start

WeightFilter End

WeightMass Gained

FilterProbe Start

WeightProbe End

WeightMass Gained

ProbeCombined Total

Mass Gained

g g g g g g gRun 1 AC9157 0.09478 0.09480 0.00002 201.95500 201.95490 -0.00010 0.00023If total mass gained is less than the LOD then the LOD is reported

Acceptable Value

mg/m³

mg/lmg/l

Sampling Times

BLANKS

SAMPLES

2.0 10

FILTER INFORMATION

15:35 - 16:3823 August 2018

1.57

TOTAL PARTICULATE MATTER SUMMARYParameter

0.19

Concentration


Run 1

-

Acetone Blank Value

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ISOKINETIC SAMPLING EQUATIONS - RUN 1 TPM

Absolute pressure of stack gas, Ps Molecular weight of dry gas, Md

Barometric pressure, Pb mm Hg 765.76 CO2 % 2.02Stack static pressure, Pstatic mm H2O -8.97 O2 % 14.33Ps = Pb + (Pstatic) mm Hg 765.10 Total % 16.35

N2 (100 -Total) % 83.65Vol. of water vapour collected, Vwstd Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.90

g 159.2 Molecular weight of wet gas, Ms

Vwstd = (0.001246)(Vlc) m3 0.1983632 Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 27.16Volume of gas metered dry, Vmstd Actual flow of stack gas, Qa

Volume of gas sample through gas meter, Vm m3 1.070 Area of stack, As m2 4.19

Gas meter correction factor, Yd 1.0487 Qa = (60)(As)(Vs) m³/min 2459.6Mean dry gas meter temperature, Tm

oC 23.881 Total flow of stack gas, Q36.132 Conversion factor (K/mm.Hg) 0.3592

Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 1.043 Qstd = (Qa)Ps(0.3592)(1-Bwo) Dry 1723.5 (Ts) +273

Volume of gas metered wet, Vmstw @O2ref 2875.27Vmstw = Vmstd + Vwstd m3 1.2417 (Ts) +273

Qstw = (Qa)Ps(0.3592) Wet 2051.15 (Ts) +273

No Percent isokinetic, %INozzle diameter, Dn mm 7.03

% oxygen measured in gas stream, act%O2 14.3 Nozzle area, An mm2 38.82% oxygen reference condition 17 Total sampling time, q min 60

1.67 %I = (4.6398E6)(Ts+273)(Vmstd) % 108.9 (Ps)(Vs)(An)(q)(1-Bwo)

Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 2.0697 Acceptable isokinetic range 95% to 115% YesMoisture content, Bwo Particulate Concentration, CBwo = Vwstd 0.1598 Mass collected on filter, Mf g 0.00245

% 15.98 Mass collected in probe, Mp g 0.00080Moisture by FTIR % - Total mass collected, Mn g 0.00325Velocity of stack gas, Vs Cwet = Mn mg/m³ 2.617Pitot tube velocity constant, Kp 34.97 Vmstw

Velocity pressure coefficient, Cp 0.871 Cdry = Mn mg/m³ 3.115Mean of velocity heads, DPavg mm H2O 6.50 Vmstd

Mean square root of velocity heads, ÖDP 2.55 Cwet@X%O2 = Mn mg/m³ 1.570Mean stack gas temperature, Ts

oC 57Vs = (Kp)(Cp)(ÖDP)(Ö(Ts + 273)) m/s 9.78 Particulate Emission Rates, E (Ms)(Ps) E = [(Cwet)(Qstw)(60)] / 1000 322.12

O2 Ref = 21.0 - act%O2

21.0 - ref%O2

QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)


Moisture trap weight increase,Vlc

Tm + 273

Vol. of gas metered at O2 Ref. Cond., Vmstd@X%O2

Vmstd + Vwstd

Mean pressure drop across orifice, DH mmH2O

13.6

Is the process burning hazardous waste? (If yes, no favourable oxygen correction)

O2 Reference Factor

Vmstd@X%oxygen

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litre/min litre/min litre/min mm Hg litre/minRun 1 18.70 0.20 0.20 -381 0.37 Yes

% mg/m³ mg/m³Run 1 108.94 Yes Run 1 0.19 1.0 Yes

Acceptable isokinetic range 95% to 115% The above is based on both the Filter and rinse uncertainty

mg/m3 mg/m3 mg/m3 mg/m3

mm °CRun 1 Glass Fibre 47 59

0.19 Yes


5% ELV

LEAK RATE

2.0

Acceptable Isokineticity

FILTERS

°C

Leak Tests Acceptable?

Run

Filter SizeFilter Material

WEIGHING BALANCE UNCERTAINTYISOKINETICITY

Pre-sampling Leak Rate

Maximum Vacuum

Run

Pre-use Filter Conditioning Temperature

Max Filtration Temperature

°C

Blank 1

Mean Sampling Rate

160

Daily Emission Limit Value

Overall Blank Acceptable

Isokinetic Variation

LOD < 5% ELVRun

BLANK VALUE

TOTAL PARTICULATE MATTER QUALITY ASSURANCE CHECKLIST

20

Acceptable Leak Rate

Overall Blank Value

Post-use Filter Conditioning Temperature

Result

Post-sampling Leak RateRun

Run

180

Acceptable Blank Value

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LOD Limit Emissionng/m³ ng/m³ Rate µg/hr

Run 1 0.00242 - 1.24

Field Blanks Run 1 0.00082 - -


Run 1 0.00286 - 1.12



Run 1 0.00320 - 1.31



Run 1 0.00404 - 2.86

Field Blanks Run 1 0.00128 - -Reference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.

Sampling Times

0.00090

ConcentrationTest

Test

Concentration

WHO TEQ (Humans / Mammals)

-

11:12 - 17:17 30 August 2018

ng/m³

Sampling Times ConcentrationWHO TEQ (Fish)

11:12 - 17:17 30 August 2018

Test

ng/m³

0.01943

0.00128

-

Concentration

0.00082

0.00761

Test

-

0.00082

-

NATO I-TEQ

DIOXINS & FURANS SUMMARY - UPPER LIMIT

ng/m³Sampling Times

0.00888

0.00842

11:12 - 17:17 30 August 2018


Sampling Times

WHO TEQ (Birds)

ng/m³

11:12 - 17:17 30 August 2018

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Run 1 - - 1.11

Field Blanks Run 1 - - -


Run 1 - - 0.88



Run 1 - - 1.06



Run 1 - - 2.62

Field Blanks Run 1 - - -Reference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.

-

WHO TEQ (Fish)

0.00000

ConcentrationTest

ng/m³11:12 - 17:17

30 August 2018

-

0.00752

DIOXINS & FURANS SUMMARY - LOWER LIMIT

11:12 - 17:17 30 August 2018

0.01778

Sampling Times Test

Concentration

ConcentrationWHO TEQ (Birds)

0.00723

Test

Concentration

0.00000

ng/m³

-

0.0059611:12 - 17:17

30 August 2018

Test

ng/m³

0.00000

0.00000

Sampling Times

-

WHO TEQ (Humans / Mammals)

NATO I-TEQ


Sampling Times

Sampling Times

11:12 - 17:17 30 August 2018

ng/m³

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Congener Result NATO WHOI-TEQ TEQ Actual Permitted

ng ng ng % %Dioxins2378 Tetra CDD 0.006 0.006 0.006 77 50 - 13012378 Penta CDD < 0.015 0.0075 0.015 49 50 - 130123478 Hexa CDD 0.0094 0.00094 0.00094 114 50 - 130123678 Hexa CDD 0.011 0.0011 0.0011 95 50 - 130123789 Hexa CDD 0.01 0.001 0.0011234678 Hepta CDD 0.06 0.0006 0.0006 63 50 - 130OCDD Octa CDD 0.082 0.000082 0.0000246 106 20 - 150Total -Dioxins 0.1934 0.01722 0.02466Furans2378 Tetra CDF 0.081 0.0081 0.0081 94 50 - 13012378 Penta CDF 0.064 0.0032 0.00192 98 >=5023478 Penta CDF 0.071 0.0355 0.0213 38 50 - 130123478 Hexa CDF 0.048 0.0048 0.0048 100 50 - 130123678 Hexa CDF 0.057 0.0057 0.0057 71 50 - 130234678 Hexa CDF 0.063 0.0063 0.0063 87 50 - 130123789 Hexa CDF < 0.015 0.0015 0.0015 80 >=501234678 Hepta CDF 0.17 0.0017 0.0017 54 20 - 1501234789 Hepta CDF 0.025 0.00025 0.00025 67 >=50OCDF Octa CDF 0.1 0.0001 0.00003 71 20 - 150Total -Furans 0.694 0.06715 0.05160Mean Recoveries (%) 79Total Isomers 0.8874 0.08437 0.07626Total ITEQ (<LOD = 0) 0.07537 0.05976

NOTE: The Total Isomers result includes all isomers below the limit of detection. This gives a "worst case" Dioxins & Furans result.

NATO I-TEQ & WHO TEQ (Humans / Mammals)Extraction Recovery

DIOXINS & FURANS ANALYSIS SUMMARY - RUN 1


Humans / Mammals

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Congener Result WHO WHOTEQ TEQ Actual PermittedFish Birds

ng ng ng % %Dioxins2378 Tetra CDD 0.006 0.006 0.006 77 50 - 13012378 Penta CDD < 0.015 0.015 0.015 49 50 - 130123478 Hexa CDD 0.0094 0.0047 0.00047 114 50 - 130123678 Hexa CDD 0.011 0.00011 0.00011 95 50 - 130123789 Hexa CDD 0.01 0.0001 0.00011234678 Hepta CDD 0.06 0.00006 0.00006 63 50 - 130OCDD Octa CDD 0.082 - - 106 20 - 150Total -Dioxins 0.1934 0.02597 0.02174Furans2378 Tetra CDF 0.081 0.00405 0.081 94 50 - 13012378 Penta CDF 0.064 0.0032 0.00064 98 >=5023478 Penta CDF 0.071 0.0355 0.071 38 50 - 130123478 Hexa CDF 0.048 0.0048 0.0048 100 50 - 130123678 Hexa CDF 0.057 0.0057 0.0057 71 50 - 130234678 Hexa CDF 0.063 0.0063 0.0063 87 50 - 130123789 Hexa CDF < 0.015 0.0015 0.0015 80 >=501234678 Hepta CDF 0.17 0.0017 0.0017 54 20 - 1501234789 Hepta CDF 0.025 0.00025 0.00025 67 >=50OCDF Octa CDF 0.1 0.00001 0.00001 71 20 - 150Total -Furans 0.694 0.06301 0.17290Mean Recoveries (%) 79Total Isomers 0.8874 0.08898 0.19464Total ITEQ (<LOD = 0) 0.07248 0.17814


WHO TEQ (Fish) & WHO TEQ (Birds)

DIOXINS & FURANS ANALYSIS SUMMARY - RUN 1

Extraction Recovery


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Congener Result NATO WHOI-TEQ TEQ Actual Permitted

ng ng ng % %Dioxins2378 Tetra CDD < 0.002 0.002 0.002 71 50 - 13012378 Penta CDD < 0.002 0.001 0.002 69 50 - 130123478 Hexa CDD < 0.002 0.0002 0.0002 80 50 - 130123678 Hexa CDD < 0.002 0.0002 0.0002 72 50 - 130123789 Hexa CDD < 0.002 0.0002 0.00021234678 Hepta CDD < 0.0075 0.000075 0.000075 78 50 - 130OCDD Octa CDD < 0.02 0.00002 0.000006 75 20 - 150Total -Dioxins 0.0375 0.00370 0.00468Furans2378 Tetra CDF < 0.0035 0.00035 0.00035 69 50 - 13012378 Penta CDF < 0.0025 0.000125 0.000075 101 >=5023478 Penta CDF < 0.003 0.0015 0.0009 68 50 - 130123478 Hexa CDF < 0.005 0.0005 0.0005 80 50 - 130123678 Hexa CDF < 0.004 0.0004 0.0004 79 50 - 130234678 Hexa CDF < 0.004 0.0004 0.0004 72 50 - 130123789 Hexa CDF < 0.0025 0.00025 0.00025 94 >=501234678 Hepta CDF < 0.05 0.0005 0.0005 78 20 - 1501234789 Hepta CDF < 0.007 0.00007 0.00007 96 >=50OCDF Octa CDF < 0.45 0.00045 0.000135 77 20 - 150Total -Furans 0.5315 0.004545 0.00358Mean Recoveries (%) 79Total Isomers 0.569 0.00824 0.00826Total ITEQ (<LOD = 0) 0.00000 0.00000


DIOXINS & FURANS ANALYSIS SUMMARY - FIELD BLANK RUN 1

Extraction Recovery

Humans / Mammals

NATO I-TEQ & WHO TEQ (Humans / Mammals)


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Congener Result WHO WHOTEQ TEQ Actual PermittedFish Birds

ng ng ng % %Dioxins2378 Tetra CDD < 0.002 0.002 0.002 71 50 - 13012378 Penta CDD < 0.002 0.002 0.002 69 50 - 130123478 Hexa CDD < 0.002 0.001 0.0001 80 50 - 130123678 Hexa CDD < 0.002 0.00002 0.00002 72 50 - 130123789 Hexa CDD < 0.002 0.00002 0.000021234678 Hepta CDD < 0.0075 0.0000075 0.0000075 78 50 - 130OCDD Octa CDD < 0.02 - - 75 20 - 150Total -Dioxins 0.0375 0.00505 0.00415Furans2378 Tetra CDF < 0.0035 0.000175 0.0035 69 50 - 13012378 Penta CDF < 0.0025 0.000125 0.000025 101 >=5023478 Penta CDF < 0.003 0.0015 0.003 68 50 - 130123478 Hexa CDF < 0.005 0.0005 0.0005 80 50 - 130123678 Hexa CDF < 0.004 0.0004 0.0004 79 50 - 130234678 Hexa CDF < 0.004 0.0004 0.0004 72 50 - 130123789 Hexa CDF < 0.0025 0.00025 0.00025 94 >=501234678 Hepta CDF < 0.05 0.0005 0.0005 78 20 - 1501234789 Hepta CDF < 0.007 0.00007 0.00007 96 >=50OCDF Octa CDF < 0.45 0.000045 0.000045 77 20 - 150Total -Furans 0.5315 0.00397 0.00869Mean Recoveries (%) 79Total Isomers 0.569 0.00901 0.01284Total ITEQ (<LOD = 0) 0.00000 0.00000


DIOXINS & FURANS ANALYSIS SUMMARY - FIELD BLANK RUN 1


Extraction RecoveryWHO TEQ (Fish) & WHO TEQ (Birds)

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ISOKINETIC SAMPLING EQUATIONS - RUN 1 Dioxins & Furans

Absolute pressure of stack gas, Ps Molecular weight of dry gas, Md

Barometric pressure, Pb mm Hg 752.26 CO2 % 2.02Stack static pressure, Pstatic mm H2O -8.97 O2 % 14.33Ps = Pb + (Pstatic) mm Hg Total % 16.35

751.60 N2 (100 -Total) % 83.65Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.90

Vol. of water vapour collected, Vwstd Molecular weight of wet gas, Ms

g - Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 27.16Vwstd = (0.001246)(Vlc) m3 - Velocity of stack gas, Vs

Volume of gas metered dry, Vmstd Pitot tube velocity constant, Kp 34.97Velocity pressure coefficient, Cp 0.87

Volume of gas sample through gas meter, Vm m3 5.38 Mean of velocity heads, DPavg mm H2O 4.85

Gas meter correction factor, Yd 1.05 Mean square root of velocity heads, ÖDP 2.20Mean dry gas meter temperature, Tm

oC 29.87 Mean stack gas temperature, TsoC 58

Mean pressure drop across orifice, DH mmH2O 28.78 Vs = (Kp)(Cp)(ÖDP)(Ö(Ts + 273)) m/s 8.54 (Ms)(Ps)

Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 5.05 Actual flow of stack gas, Qa

Area of stack, As m2 4.19Volume of gas metered wet, Vmstw Qa = (60)(As)(Vs) m³/min 2148.7

Total flow of stack gas, QVmstw = Vmstd + Vwstd m3 6.0111 Conversion factor (K/mm.Hg)

Qstd = (Qa)Ps(0.3592)(1-Bwo) Dry 1471.2 (Ts) +273

No @O2ref 2452 (Ts) +273

% oxygen measured in gas stream, act%O2 14.33 Qstw = (Qa)Ps(0.3592) Wet 1751% oxygen reference condition 17 (Ts) +273

O2 Ref = 21.0 - act%O2 1.67 Percent isokinetic, %I 21.0 - ref%O2 Nozzle diameter, Dn mm 7.0

Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 10.02 Nozzle area, An mm2 38.8Moisture content, Bwo Total sampling time, q min 360.0

%I = (4.6398E6)(Ts+273)(Vmstd) % 103.0Bwo = Vwstd 0.1598 (Ps)(Vs)(An)(q)(1-Bwo)

% 15.98Moisture by FTIR % - Acceptable isokinetic range 95% to 115% Yes

O2 Reference Factor

QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)Is the process burning hazardous waste? (If yes, no favourable oxygen correction)

Vmstd + Vwstd




Tm + 273

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litre/min litre/min litre/min mm Hg litre/min litre/min

15.68 0.25 0.25 -381 0.78 Yes

Isokinetic Criterion Compliance

mm °C

Quartz Fibre 47 123

Critical Sampling Requirement

Run 1 Yes Yes

- -

.


Isokinetic Variation

Run 1

Acceptable Leak Rate

Leak Test Results Maximum Vacuum

23

Post-sampling Leak Rate

DIOXINS & FURANS QUALITY ASSURANCE CHECKLIST

Mean Sampling Rate

Pre-sampling Leak Rate

Leak Tests Acceptable

Run 1 103.0

Maximum Filtration

Temperature

Filter Size

Run 1

Yes

Filtration

Acceptable isokinetic range 95% to 115%

Maximum Temperature at Condenser / Adsorber

Acceptable Temperature?

< 20°C < 25°CAcceptance Criteria

Filter Material

Acceptable Temperature?

Maximum Temperature during storage / transit

°C°C

10

%Acceptable Isokineticity

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LOD Limit Emissionmg/m³ mg/m³ Rate g/hr

0.01 12 732.64

Field Blank - - -

Please note figures in bold italic font are at the limit of detectionReference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.

Leak Test Results

l/min l/min l/min l/min

Run 1 18.7 0.02 0.10 0.37 Yes

Filter Material Filter Sizemm

°C °C

Run 1 Glass Fibre 47 161 20 Glass

Parameter Total IMP C Absorptionug ug Efficiency %

7392 - Not Determined Not DeterminedRun 1

-

FORMALDEHYDE SUMMARY

Acceptable leak rate

Run 115:35 - 16:38

23 August 20183.57

0.01

Max. Storage / Transit Temp.

ND - None Detected

Post sampling leak rate

Sampling Times

Acceptable ?


Mean Sampling Rate

mg/m³

FORMALDEHYDE QUALITY ASSURANCE CHECKLIST

Concentration

Acceptable Absorption

Pre sampling leak rate


Absorption EfficiencyEfficiency %

Not Determined

Absorption SolutionsType of Absorbers

FORMALDEHYDE ABSORPTION EFFICIENCY

Max. Filtration Temp.

HPLC Water

Test

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ISOKINETIC SAMPLING EQUATIONS 1 Formaldehyde

Absolute pressure of stack gas, Ps Velocity of stack gas, Vs

Barometric pressure, Pb mm Hg 766 Pitot tube velocity constant, Kp 34.97Stack static pressure, Pstatic mm H2O -9 Velocity pressure coefficient, Cp 0.871Ps = Pb + (Pstatic) mm Hg 765 Mean of velocity heads, DPavg mm H2O 6.50

Mean square root of velocity heads, ÖDP 2.55Vol. of water vapour collected, Vwstd Mean stack gas temperature, Ts

oC 57g -

Vwstd = (0.001246)(Vlc) m3 - Vs = (Kp)(Cp)(ÖDP)(Ö(Ts + 273)) m/s 9.8 (Ms)(Ps)

Volume of gas metered dry, Vmstd Actual flow of stack gas, Qa


Gas meter correction factor, Yd 1.0487 Qa = (60)(As)(Vs) m³/min 2460Mean dry gas meter temperature, Tm

oC 23.88 Dry total flow of stack gas, Qstd

Mean pressure drop across orifice, DH mmH2O 36.13 Conversion factor (K/mm.Hg) 0.3592Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 1.04 Qstd = (Qa)Ps(0.3592)(1-Bwo) m³/min 1723

(Ts) +273Volume of gas metered wet, Vmstw Wet total flow of stack gas, Qstw

Vmstw = Vmstd + Vwstd m3 1.2417 Qstw = (Qa)Ps(0.3592) m³/min 2051 (Ts) +273

Nom³/min 2873

% oxygen measured in gas stream, act%O2 14.33 (Ts) +273% oxygen reference condition 17 Percent isokinetic, %I

O2 Ref = 21.0 - act%O2 1.67 Nozzle diameter, Dn mm 7.03 21.0 - ref%O2 Nozzle area, An mm2 38.82

Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 2.0697 Total sampling time, q min 60Moisture content, Bwo %I = (4.6398E6)(Ts+273)(Vmstd) % 109Bwo = Vwstd 0.1598 (Ps)(Vs)(An)(q)(1-Bwo)

% 15.98 Acceptable isokinetic range 95% to 115% YesMoisture by FTIR % -Molecular weight of dry gas, Md Mass collected , M ug 7392CO2 2.02 Cwet = Mn mg/m³ 5.953O2 14.33 Vmstw

Total 16.35 Cdry = Mn mg/m³ 7.085N2 (100 -Total) 83.65 Vmstd

Cwet@X%O2 = Mn mg/m³ 3.571Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.90Molecular weight of wet gas, Ms Formaldehyde Emission Rates, EMs = Md(1 - Bwo) + 18(Bwo) g/gmol 27.2 E = [(Cwet)(Qstw)(60)] / 1000 g/hr 732.64



Vmstd + Vwstd


Vmstd@X%oxygen

Dry total flow of stack gas at X% O2, QstdO2

Tm + 273

Formaldehyde Concentration, C


O2 Reference Factor


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0.02 100 1875

Field Blank - - -

Please note figures in bold italic font are at the limit of detectionReference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.

Leak Test Results


Run 1 18.7 0.20 0.20 0.37 Yes


°C °C



18920 - Not Determined

CVOCS SUMMARY

Not Determined

Absorption Efficiency

-


HPLC Water

Concentrationmg/m³

Test

15:35 - 16:38 23 August 2018


ND - None Detected

0.03



Mean Sampling Rate

CVOCS QUALITY ASSURANCE CHECKLIST

Acceptable ?

9.14

CVOCS ABSORPTION EFFICIENCY


Sampling Times



Run 1

Absorption Solutions

Efficiency %

Type of Absorbers

Run 1 Not Determined


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ISOKINETIC SAMPLING EQUATIONS 1 CVOCs




oC 57g -









Nom³/min 2873






Cwet@X%O2 = Mn mg/m³ 9.139Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.90Molecular weight of wet gas, Ms CVOCs Emission Rates, EMs = Md(1 - Bwo) + 18(Bwo) g/gmol 27.2 E = [(Cwet)(Qstw)(60)] / 1000 g/hr 1874.68

Tm + 273

Vmstd + Vwstd

CVOCs Concentration, C



Vmstd@X%oxygen

O2 Reference Factor





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0.08 20 1086

Field Blank - - -


Leak Test Results


Run 1 18.1 0.10 0.05 0.36 Yes


°C °C



11518 - Not Determined

Mean Sampling Rate

0.26

Test

14:21 - 15:25 28 August 2018


DNPH Solution

Run 1


Type of Absorbers


TOTAL ALDEHYDES SUMMARY

5.83

-

TOTAL ALDEHYDES ABSORPTION EFFICIENCY

Absorption SolutionsMax. Storage / Transit Temp.

Concentrationmg/m³

TOTAL ALDEHYDES QUALITY ASSURANCE CHECKLIST



Run 1 Not Determined



Acceptable ?

Not Determined

Efficiency %


Sampling Times

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ISOKINETIC SAMPLING EQUATIONS 1 Total Aldehydes




oC 59g -









Nom³/min 2607






Cwet@X%O2 = Mn mg/m³ 5.831Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.90Molecular weight of wet gas, Ms Total Aldehydes Emission Rates, EMs = Md(1 - Bwo) + 18(Bwo) g/gmol 27.2 E = [(Cwet)(Qstw)(60)] / 1000 g/hr 1085.66

O2 Reference Factor

13.6


Vmstd + Vwstd

Vmstd@X%oxygen


Total Aldehydes Concentration, C


Tm + 273




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0.01 40.0 46.7

Field Blank - - -


Leak Test Results


Run 1 17.8 0.10 0.20 0.36 Yes


°C °C

Run 1 Quartz Fibre 47 162 20 Glass


470.7 10.2 98 Yes



SULPHUR DIOXIDE ABSORPTION EFFICIENCY

Absorption Solutions

SULPHUR DIOXIDE QUALITY ASSURANCE CHECKLIST


SULPHUR DIOXIDE SUMMARY

mg/m³Concentration

0.07

0.25


Type of Absorbers


Run 1

Efficiency %


15:40 - 16:4528 August 2018

Test

-

Acceptable ?


95


Sampling Times

0.3% Hydrogen Peroxide

Run 1


Mean Sampling Rate

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ISOKINETIC SAMPLING EQUATIONS 1 Sulphur dioxide




oC 60g -









Nom³/min 2638






Cwet@X%O2 = Mn mg/m³ 0.248Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.90Molecular weight of wet gas, Ms Sulphur dioxide Emission Rates, EMs = Md(1 - Bwo) + 18(Bwo) g/gmol 27.2 E = [(Cwet)(Qstw)(60)] / 1000 g/hr 46.74

Vmstd@X%oxygen

Tm + 273





Vmstd + Vwstd



Sulphur dioxide Concentration, C

O2 Reference Factor

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0.26 200 7179

0.14 100 2706

LOD%

0.01


Date Chiller Temperature (°C) 2.5

Start Time Requirement < 4°C

End Time Compliant Yes

Gas Range Zero Reading Span Reading Zero Check Zero Check Span Check Response Leak Rate(ppm / %) at analyser at analyser at analyser down line down line Time (Secs) %

NO 250 0.20 197.0 0.00 0.20 199.8 51 -1.42

CO 200 -1.00 161.0 -2.00 0.00 166.0 40 -3.11

O2 25 0.12 20.93 0.10 0.00 20.95 25 -0.10

Date Chiller Temperature (°C) 2.5

Start Time Requirement < 4°C

End Time Compliant Yes

Gas Zero Check Span Check Zero Drift Span Driftdown line down line (%) (%)

NO 1.00 197.0 0.32 -1.44

CO 1.00 170.0 0.50 1.50

O2 0.00 20.91 0.00 -0.16

O2

POST-SAMPLING CALIBRATION DATA

28 August 2018

Test

COMBUSTION GASES SUMMARY

16:51

14:23

Concentration

14.3

28 August 2018

NOx 33.4

CO

Sampling Time and Date Concentrationmg/m³

15:31 - 16:31 28 August 2018

12.6

Sampling Time and Date

15:31 - 16:31 28 August 2018

14:16

%Test

PRE-SAMPLING CALIBRATION DATA

16:39

15:31 - 16:31 28 August 2018


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CARBON MONOXIDE EMISSIONS CHART


OXIDES OF NITROGEN (as NO2) EMISSIONS CHART

0.0

50.0

100.0

150.0

200.0

250.0

15:31

15:33

15:35

15:37

15:39

15:41

15:43

15:45

15:47

15:49

15:51

15:53

15:55

15:57

15:59

16:01

16:03

16:05

16:07

16:09

16:11

16:13

16:15

16:17

16:19

16:21

16:23

16:25

16:27

16:29

16:31

Co

nce

ntr

atio

n m

g/m

³

Time

Oxides of Nitrogen NOx

Limit

0.0

20.0

40.0

60.0

80.0

100.0

120.0

15:31

15:33

15:35

15:37

15:39

15:41

15:43

15:45

15:47

15:49

15:51

15:53

15:55

15:57

15:59

16:01

16:03

16:05

16:07

16:09

16:11

16:13

16:15

16:17

16:19

16:21

16:23

16:25

16:27

16:29

16:31

Co

nce

ntr

atio

n m

g/m

³

Time

Carbon Monoxide CO

Limit

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OXYGEN EMISSIONS CHART

0.0

5.0

10.0

15.0

20.0

25.0

15:31

15:33

15:35

15:37

15:39

15:41

15:43

15:45

15:47

15:49

15:51

15:53

15:55

15:57

15:59

16:01

16:03

16:05

16:07

16:09

16:11

16:13

16:15

16:17

16:19

16:21

16:23

16:25

16:27

16:29

16:31

Co

nce

ntr

atio

n %

v/v

Time

O2

O2

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Test Number Start Weight End Weight Total gain Concentration LOD Uncertainty

kg kg kg % % %

Run 1 2.6353 2.7945 0.1592 16.0 0.01 4.13

Test NumberSampling Duration

Total Volume Sampled

Sampling Rate Start Leak Rate End Leak RateAcceptable Leak Rate

mins l l/min l/min l/min l/min

Run 1 60 1242 18.7 0.20 0.200 0.374 Yes

Stack Diameter / Depth, D 2.31 m

Stack Width, W - m

Stack Area, A 4.19 m2

Average stack gas temperature 56 oC

Stack static pressure -0.088 kPa

Barometric Pressure 102.1 kPa

Component Molar Density Conc Dry Volume Dry Conc Conc Wet Volume Wet ConcMass kg/m3 Dry Fraction kg/m3 Wet Fraction kg/m3

M p % Vol r pi % Vol r pi

CO2 44 1.963059 2.018361 0.020184 0.039622 1.695925 0.016959 0.033292

O2 32 1.427679 17.057500 0.170575 0.243526 14.332545 0.143325 0.204623

N2 28 1.249219 80.924139 0.809241 1.010920 67.996418 0.679964 0.849424

H2O 18 0.803070 - - - 15.975112 0.159751 0.128291

Where: p = M / 22.41 pi = r x p

Determinand

Dry Density (STP), P STD

Wet Density (STP), P STW

Dry Density (Actual), P Actual

Average Wet Density (Actual), P ActualW

Where:

P STD = sum of component concentrations, kg/m3 (not including water vapour) P Actual = P STD x (Ts / Ps) x (Pa / Ta)

P STW = (P STD + pi of H2O) / (1 + (pi of H2O / 0.8036)) P ActualW = P STW x (Ts / Ps) x (Pa / Ta)

PRELIMINARY STACK SURVEY


1.016

kg/m3

Units

Sampling Time and Date

MOISTURE CALCULATIONS


1.2156

kg/m31.2941

kg/m3

Stack Gas Composition & Molecular Weights

Moisture Determination - Isokinetic

Moisture Quality Assurance

1.0813

Stack Characteristics

15:35 - 16:3823 August 2018

Result

kg/m3

Calculation of Stack Gas Densities

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TRAVERSE 1

Traverse Distance DP pt DP pt Temp Velocity O2 Angle

Point into mmH2O Pa oC m/s % of Swirl

duct (m)(average of 3

readings)(average of 3

readings)m³/s Vol o

1 0.06 6.0 59 56 9.1 38.2 - <152 0.19 6.0 59 56 9.1 38.2 - <153 0.34 7.0 69 56 9.8 41.2 - <154 0.52 7.0 69 56 9.8 41.2 - <155 0.79 9.0 88 56 11.2 46.7 - <156 1.52 9.0 88 56 11.2 46.7 - <157 1.79 8.0 78 56 10.5 44.1 - <158 1.97 8.0 78 56 10.5 44.1 - <159 2.12 9.0 88 56 11.2 46.7 - <15

10 2.25 7.0 69 56 9.8 41.2 - <15Mean - 7.6 74 56 10.2 42.8 - -

Traverse Distance DP pt DP pt Temp Velocity O2 Angle

Point into mmH2O Pa oC m/s % of Swirl

duct (m)(average of 3

readings)(average of 3

readings)m³/s Vol o

1 0.06 5.0 49 56 8.3 34.8 - <152 0.19 6.0 59 56 9.1 38.2 - <153 0.34 6.0 59 56 9.1 38.2 - <154 0.52 7.0 69 56 9.8 41.2 - <155 0.79 8.0 78 56 10.5 44.1 - <156 1.52 9.0 88 56 11.2 46.7 - <157 1.79 10.0 98 56 11.8 49.3 - <158 1.97 9.0 88 56 11.2 46.7 - <159 2.12 9.0 88 56 11.2 46.7 - <15

10 2.25 8.0 78 56 10.5 44.1 - <15

Start Value End Value Difference Start Value End Value DifferencePa Pa % Pa Pa %

Run 1 102 102 0.0 Pass 105 105 0.0 Pass

RunStagnation

(Pa)Reference

(Pa)Difference

(Pa)

Outcome(Permitted +/- 10 Pa)

Run 1 90 91 -1.0 Pass

Sampling Line B

15:1223 August 2018

Pre Traverse Leak Rate

To complete a compliant pitot leak check a pressure of over 80 mmH₂O (or 800 Pa) is applied and the pressure drop monitored over 5 mins. A drop of less than 5% must be observed.

S-Type Pitot Stagnation Check

Run OutcomePost Traverse Leak Rate

Sampling Line A

Outcome

PITOT LEAK CHECK


PRELIMINARY STACK SURVEY

Time of Survey


(actual)

Velocity Measurement Device: S-Type Pitot


(actual)

Date of Survey

PRELIMINARY STACK SURVEY QUALITY ASSURANCE CHECKLIST

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EA Technical Guidance Note (Monitoring) M1 Units Requirement Compliant

Lowest Differential Pressure Pa >= 5 Pa Yes

Lowest Gas Velocity m/s - -

Highest Gas Velocity m/s - -

Ratio of Gas Velocities - < 3 : 1 Yes

Maximum angle of flow with regard to duct axis o < 15o Yes

No local negative flow - - Yes

Velocity at Traverse Point, V = Kpt x (1-e) * Ö(2 * DP pt / P ActualW)

Where:Kpt = Pitot tube calibration coefficient(1-e) = Compressibility correction factor, assumed at a constant 0.998

Average Stack Gas Velocity, Va 10.2 m/s

Duct gas flow conditions Actual Reference UnitsTemperature 56 0 oCTotal Pressure 102.012 101.3 kPaOxygen (Wet) 14.3 17 %Moisture 15.98 15.98 %Pitot tube calibration coefficient, Kpt 0.871

Gas Volumetric Flowrate UnitsAverage Stack Gas Velocity (Va) m/sStack Area (A) m2

Gas Volumetric Flowrate (Actual), QActual m3/hr

Gas Volumetric Flowrate (STP, Wet), QSTP m3/hr

Gas Volumetric Flowrate (STP, Dry), QSTP,Dry m3/hr

Gas Volumetric Flowrate (REF), QRef m3/hr

Where:QActual = Va x A x 3600QSTP = Q (Actual) x (Ts / Ta) x (Pa / Ps) x 3600QSTP,Dry = Q (STP) / (100 - (100 / Ma)) x 3600QRef = Q (STP) x ((100 - Ma) / (100 - Ms)) x ((20.9 - O2a) / (20.9 - O2s))

Nomenclature:Ts = Absolute Temperature, Standard Conditions, 273 KPs = Absolute Pressure, Standard Conditions, 101.3 kPaTa = Absolute Temperature, Actual Conditions, KPa = Absolute Pressure, Actual Conditions, kPaMa = Water vapour, Actual Conditions, % VolMs = Water vapour, Reference Conditions, % VolO2a = Oxygen, Actual Conditions, % VolO2s = Oxygen, Reference Conditions, % Vol

108472


Sampling Plane Validation Criteria

<15

8.3

1.4

PRELIMINARY STACK SURVEY (CONTINUED)

Yes

11.8

49

Calculation of Stack Gas Volumetric Flowrate, Q

4.19

Result

129096

215185

Calculation of Stack Gas Velocity, V

154491

10.24

Result

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Value UnitsStack Depth 2.31 m Sampling Distance Distance into UnitsStack Width - m Point (% of Depth) StackArea 4.19 m2 A 50 1.16 m

Sampling Distance Distance into SwirlPoint (% of Depth) Stack (m) o

1 2.6 0.06 < 152 8.2 0.19 < 153 14.6 0.34 < 154 22.6 0.52 < 15

5 34.2 0.79 < 15

6 65.8 1.52 < 15

7 77.4 1.79 < 15

8 85.4 1.97 < 159 91.8 2.12 < 15

10 97.4 2.25 < 15Point Not Used 2.6 0.06 < 15Point Not Used 8.2 0.19 < 15

Point Not Used 14.6 0.34 < 15

Point Not Used 22.6 0.52 < 15Point Not Used 34.2 0.79 < 15

16 65.8 1.52 < 15Isokinetic sampling point 17 77.4 1.79 < 15Isokinetic sampling points not used 18 85.4 1.97 < 15Non Isokinetic/Gases sampling point 19 91.8 2.12 < 15

20 97.4 2.25 < 15

STACK PHOTOS

STACK DIAGRAM

Non-Isokinetic/Gases Sampling

Isokinetic Sampling


1

2

3

4

5

6

7

8

9

10

20

19

14

17 15 13

12

11

18 16

Sampling Line A

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Run Sampled Volume

Sampled Gas Temp

Sampled Gas Pressure

Sampled Gas Humidity

Oxygen Content

Limit of Detection

Leak Uncollected Mass

m³ K kPa % by volume % by volume % by mass % mgMU required < 2% < 2% < 1% < 1% < 10% < 5% of ELV < 2% < 10% of ELVRun 1 0.001 2.0 0.50 1.0 0.1 0.2300 - -as a % 0.10 0.61 0.49 1.0 0.70 0.55562 1.07 0.001compliant? Yes Yes Yes Yes Yes Yes Yes Yes

Run UncollectedMass

m³ mg - mg/m³ mgRun 1 0.87 3.2500 0.6 0.010 0.0001 -MU as mg/m3 0.02 0.1111 0.02 0.010 0.0001 0.12MU as % 1.27 7.0769 - 0.617 0.0041 -

0.23 mg/m³ 14.74 %(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC UK Technical Procedure AE150 Estimation of Uncertainty of Measurement

Combined uncertainty

Volume (STP) Mass of particulate


MEASUREMENT UNCERTAINTY BUDGET - TOTAL PARTICULATE MATTER

O2 Correction

R1 - Uncertainty expressed at a 95% confidence level (where k = 2)

Leak

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Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Leak

m³ K kPa % by volume % by volume %MU required < 2% < 2% < 1% < 1% < 10% < 2%Run 1 0.001 2.0 0.50 1.0 0.1 -as a % 0.02 0.7 0.50 1.0 0.70 1.59compliant? Yes Yes Yes Yes Yes Yes

Run Laboratoryanalysis

m³ - ng ng/m³ -Run 1 5.3600 0.6 0.8874 0.0001 - -MU as ng/m3 0.0001 0.0001 0.0054 0.0001 0.0008 0.0055MU as % 1.2982 - 64.1199 0.9204 10.00 -

R1 - Uncertainty expressed at a 95% confidence level (where k = 2) 0.011 ng/m³ 129.9 %

(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC UK Technical Procedure AE150 Estimation of Uncertainty of Measurement



Leak

MEASUREMENT UNCERTAINTY BUDGET - DIOXINS & FURANS

O2 CorrectionVolume (STP) Mass of Dioxin & Furan

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Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Limit of Detection

Leak

m³ K kPa % by volume % by volume % by mass %MU required <=2% <2.5 k <=1% <=1% <=5% < 5% of ELV <=2%Run 1 2.070 296.9 101.2 1.0 14.33 7.392 -as a % 0.05 0.67 0.49 1.0 0.70 0.19 0.53compliant? Yes Yes Yes Yes Yes Yes Yes

Run LabUncertainty

m³ mg - mg/m³ mgRun 1 1.9018 7.3920 0.5999 0.0110 - -MU as mg/m3

0.0466 0.0228 0.0536 0.0110 0.1607 0.1775MU as % 1.3041 0.6372 1.4998 0.3087 4.5 -

0.36 mg/m³ 9.94 %


MEASUREMENT UNCERTAINTY BUDGET - ISOKINETIC FORMALDEHYDE


O2 Correction


Volume (STP) Mass of Formaldehyde

Leak Combined uncertainty

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Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Limit of Detection

Leak


Run LabUncertainty


0.1192 0.0473 0.1371 0.0564 0.9139 0.9346MU as % 1.3041 0.5177 1.4998 0.6174 10.0 -

1.87 mg/m³ 20.45 %


O2 CorrectionMass of CVOCs

MEASUREMENT UNCERTAINTY BUDGET - ISOKINETIC CVOCS


Volume (STP)


Leak Combined uncertainty

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Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Limit of Detection

Leak


Run LabUncertainty


0.1188 0.2757 0.1371 0.0146 0.9139 0.9717MU as % 1.3001 3.0166 1.4998 0.1597 10.0 -

1.94 mg/m³ 21.27 %



Leak


Mass of Total Aldehydes

Volume (STP)

MEASUREMENT UNCERTAINTY BUDGET - ISOKINETIC TOTAL ALDEHYDES


O2 Correction

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Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Limit of Detection

Leak

m³ K kPa % by volume % by volume % by mass %MU required <=2% <2.5 k <=1% <=1% <=5% < 5% of ELV <=2%Run 1 1.90 302 101.22 1.0 14.33 0.6544 -as a % 0.05 0.66 0.49 1.0 0.70 0.04 1.12compliant? Yes Yes Yes Yes Yes Yes Yes

Run LabUncertainty


0.0032 0.0155 0.0037 0.0016 0.0119 0.0202MU as % 1.2985 6.2548 1.4998 0.6488 4.8 -

0.04 mg/m³ 16.31 %



Volume (STP) O2 Correction


LeakMass of Sulphur dioxide


MEASUREMENT UNCERTAINTY BUDGET - ISOKINETIC SULPHUR DIOXIDE

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Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Leak

m³ K kPa % by volume % by volume %MU required < 2% < 2% < 1% < 1% < 10% < 2%Run 1 0.001 2.0 0.50 1.0 0.1 -as a % 0.10 0.61 0.49 1.0 0.70 1.07compliant? Yes Yes Yes Yes Yes Yes

Run UncollectedMass

m³ mg - mg/m³ mgRun 1 0.87 159200 0.6 942.03 58 -MU as % v/v 0.24 0.01 0.29 0.12 0.007 0.40MU as % 1.27 0.06 1.50 0.62 0.04 -

0.79 % v/v 4.13 %

MEASUREMENT UNCERTAINTY BUDGET - MOISTURE

Volume (STP) Leak


Mass Gained O2 Correction



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200 mg/m3

33.4 mg/m3

410 mg/m3

513 mg/m3

Value MU Met?51 Yes60 -60 -60 -

0.11 Yes0.1 Yes

-0.40 Yes0.32 Yes-1.44 Yes0.25 Yes0.25 Yes0.25 Yes3.00 Yes0.27 YesN/A -0.27 Yes

UncertaintyU r = S r

U lof

U d,z

U d,s

U t,z

U t,s

U p

U fit

U v

U i

U adj

33.36 mg/m3

2.70 mg/m3

5.40 mg/m3

2.7 % ELV

5.4 mg/m3

16.2 % value

Performance characteristic

<2 % range

Units

< 2% of value

Cal gas conc

MEASUREMENT UNCERTAINTY BUDGET - OXIDES OF NITROGEN

<2 % range

Logger sampling interval

Repeatability at zero-

specification

short term zero drift 0.185

% of value

Response time

Analyser Full Scale

% of full scale/3 kPa <2 % / 3 kPa

<2% range / 24hr

% of full scale/2 kPa

0.173

% full scale

Measurement uncertainty (Concentration Measured)

Combined Interfence

<2% range/24hr

-

0.004Uncertainty of Cal gas 2.000

<3% range / 10 K

short term span drift

Deviation from linearity

% full scale

% full scale/10V<4% of Range

Measurement period

<3% / 2 kPaambient temperature dependence zero / span

% of upper limit of Cal range

Number of readings in measurement

seconds

repeatability-0.2310.004

Developed for the STA by R Robinson, NPL

influence of sample gas pressure

Span drift

minutes

Expanded uncertainty expressed with a level of confidence of 95%

% range

% full scale

<2%

Combined interference

180

1.575influence of Ambient Temp at Span

0.000

% full scaleRepeatability at span level

losses in the line (leak) % of value

% full scale/10K


Value of uncertainty quantity

0.000

0.088

Combined uncertaintyExpanded at a 95% confidence interval

influence of supply voltageinfluence of sample gas flow


lack of fit

seconds

< 0.1%vol /10 volt

Limit value

Influence of Vibrationdependence on voltage

<1 % range

-0.831

Concentration @ Ref conditions

-


influence of Ambient Temp at Zero

-

volume or pressure flow dependenceatmospheric pressure dependence

Zero drift

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100 mg/m3

12.6 mg/m3

207.5 mg/m3

250 mg/m3

Value MU Met?40 Yes60 -60 -60 -0.1 Yes0.2 Yes

0.61 Yes0.50 Yes1.50 Yes0.2 Yes

0.44 Yes1 Yes

0.03 Yes-0.70 YesN/A N/A-0.03 Yes1.00 Yes

N/A - Horiba's are not effected by Vibration


U lof

U d,z U d,s

U t,z

U t,s

U p

U fit

U v

U i

U adj

24.7 mg/m3

2.9 mg/m3

5.7 mg/m3

5.7 % ELV

5.7 mg/m3

23.2 % value

Number of readings in measurement--

specification

% full scale

% full scale/10V

Span drift

<2 % range

minutes

% full scale

180

-

Units

<3% range / 10 KCombined interferencedependence on voltage

<2 % range

secondsLogger sampling interval

Analyser Full Scale

Limit value

MEASUREMENT UNCERTAINTY BUDGET - CARBON MONOXIDE

% of Range0.36

% full scale

Deviation from linearity

volume or pressure flow dependence<2% range/24hr

-<1 % rangeRepeatability at zero

Concentration @ Ref conditions

Measurement period


secondsPerformance characteristicsResponse time


Zero drift <2% range / 24hr% full scale

% of upper limit of Cal rangelosses in the line (leak)

<2 % / 3 kPa

< 0.1%vol /10 volt<4% of Range

0.12


Influence of Vibration

atmospheric pressure dependenceambient temperature dependence zero / span

repeatability


<2%

<3% / 2 kPa


0.29

% of value < 2% of value< 2% of value

lack of fitshort term zero drift



0.35

Combined Interfence

influence of sample gas pressure0.13

Uncertainty of calibration gas

-2.310.14

% of value

Performance characteristic0.003

influence of sample gas flow

influence of Ambient Temp span

Repeatability at span level

Cal gas conc

% of value

0.35

influence of Ambient Temp zero

Reference – SOCOTEC UK Technical Procedure AE150 Estimation of Uncertainty of Measurement


0.00influence of supply voltage

Combined uncertaintyExpanded uncertainty

1.34Uncertainty of Cal gas 0.83



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17 %vol17.06 %vol20.9 %vol25 %vol

Value MU Met?25 Yes60 -60 -60 -

0.25 Yes0.15 Yes0.13 Yes0.00 Yes-0.16 Yes0.03 Yes0.05 Yes-0.08 Yes0.14 Yes0.01 Yes0.14 Yes0.1 Yes


U lof

U d,z

U d,s

U t,z

U t,s

U p

U fit

U v

U i

U adj

17.06 %0.18 %0.35 %

0.3 %

0.06 % vol

0.0173

% full scale/10V < 0.1%vol /10 volt

0.1045

% of valuedependence on voltage

<2% range/24hr


0.0000

0.0751


% range <4% of Range

< 2% of value% of value


influence of supply voltageCombined Interfence

0.0083


seconds

Reference

Units

% of full scale/3 kPavolume or pressure flow dependence

4.5 <3% range / 10 K

lack of fit




0.0485

minutesMeasurement period -

MEASUREMENT UNCERTAINTY BUDGET - OXYGEN

Reported ConcentrationCalibration gas

Span drift % full scale

Deviation from linearityRepeatability at span level

% of value

% full scale

Response time 180

Number of readings in measurement

specification

seconds

Analyser Full Scale

Logger sampling interval

<3% / 2 kPa

0.0000-0.0924

atmospheric pressure dependence

short term zero drift

Expanded uncertainty

Combined interference

Uncertainty of Cal gas

0.0006

influence of Ambient Temp at Zeroinfluence of Ambient Temp at Span

ambient temperature dependence

0.06300.0000

< 2% of value

Performance characteristicrepeatability

influence of sample gas pressureinfluence of sample gas flow

<2% range / 24hr


losses in the line (leak)Uncertainty of calibration gas


Zero drift % full scale

<2 % / 3 kPa

% full scale <2 % rangeRepeatability at zero

-

-

<2 % range

<1 % range-

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10.2 m/s154491 m³/hr

Performance Characteristics & Source of Value Units Values Requirement CompliantUncertainty of Local Gas Velocity Determination

Uncertainty of pitot tube coefficient - 0.010

Uncertainty of mean local dynamic pressures - 0.35

Factor loading, function of the number of measurements. 3 readings 0.591 minimum 3 Yes

Range of measurment device pa 1000

Resolution pa 1.00

Calibration uncertainty pa 3.06<1% of Value or 20

Pa whichever is greater

Yes

Drift % range 0.10

Linearity % range 0.06 <2% of value Yes

Uncertainty of gas density determination

Uncertainty of molar mass determination kg/mol 0.00002Uncertainty of temperature measurement K 1.68 <1% of value Yes

Uncertainty of absolute pressure in the duct pa 520

Uncertainty associated with the estimate of density - 0.008

Uncertainty associated with the measurement of local velocity - 0.0001Uncertainty associated with the measurement of mean velocity - 0.0001

m/s0.120.24

%1.202.36

m³/hr40237886

%2.605.10

Reference – SOCOTEC UK Technical Procedure AE150 Estimation of Uncertainty of Measurement


Note - The expanded uncertainty uses a coverage factor of k = 2.


MEASUREMENT UNCERTAINTY BUDGET - VELOCITY & VOLUMETRIC FLOW RATE

Expanded Measurement Uncertainty of Volumetric Flow Rate at a 95% Confidence IntervalExpressed as a % of the Measured Volumetric Flow RateExpanded uncertainty at a 95% Confidence Interval

Measured Velocity at Actual Conditions Measured Volumetric Flow rate at Actual Conditions

Measurement Uncertainty - VelocityCombined uncertaintyExpanded uncertainty at a 95% Confidence Interval

Note - The expanded uncertainty uses a coverage factor of k = 2.

Expanded Measurement Uncertainty of Velocity at a 95% Confidence IntervalExpressed as a % of the Measured VelocityExpanded uncertainty at a 95% Confidence Interval

Measurement Uncertainty Volumetric Flow Rate

Expanded uncertainty at a 95% Confidence Interval

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END OF REPORT

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STACK EMISSIONS MONITORING REPORT · 2019-01-16 · SOCOTEC UK Job Number: Report Date: Version: 1...

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Transcript of STACK EMISSIONS MONITORING REPORT · 2019-01-16 · SOCOTEC UK Job Number: Report Date: Version: 1...