Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the...

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Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Transcript of Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the...

Page 1: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

SolutionsSubtopics include: (1) Describing Solutions, (2) Concentrations, (2)

Solubility & (3) the Effects of Solutes on Solutions.

Page 2: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

SolutionsDescribing Solutions

Define: solution, solute, solvent, electrolyte, suspensions, colloidal dispersions.

Explore types of solutions.

Separation of Solutions.

Concentrations Express the concentrations of

solutions in terms of: percent, parts per million, mole fraction, molarity and molality.

Solve problems involving the measurements of concentration

SolubilityDefine: miscible, saturated,

unsaturated, solubility, supersaturation.

Describe Factors that effect solubility.

Use “solubility rules” to predict the solubility of an ionic compound in water.

Effects of Solutes on Solution

Effect of solutes on the boiling point and freezing point of solutions.

Solve problems involving freezing point depressions and boiling point elevation (colligative properties).

Solve problems involving solutions and chemical equations.

Effects of electrolytes on the behavior of the solution.

Page 3: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Describing Solutions Define: solution, solute, solvent, suspensions, colloidal dispersions, distillation filtration &

chromatography.

Explore types of solutions.

Identify homogenous mixtures that are not solutions.

Identify the process of separating solutions: distillation, filtration & chromatography.

Page 4: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Aim: What is a Chemical Solution?

Essential Questions:

1. What is a chemical solution?

2. What are some types of chemical solutions?

3. How do we separate chemical solutions? Explain.

Key Words:

solution, solute,

solvent, suspensions,

colloidal dispersions,

distillation, Filtration,

Chromatography.

Page 5: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Name Some Solutions!

Q: What are some solutions you have encountered today?

Page 6: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Which One is a Solution?

Salt Water

Oil Water A) The Salt

Water

B) The Oil

Water

C) Both

D) Neither

Page 7: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Deduction

Q: Based on the previous example, how can we describe a solution?

Page 8: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Notes

I. Describing SolutionsA. Definitions

1. Solution - homogenous mixture of a solute dissolved in a solvent.

Page 9: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Solutes, Solvents & Solutions

Solute

SolventSolution

Page 10: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Notes

2. Solute –

3. Solvent –

4. Solution –

Page 11: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

What Makes Solutions

Homogenous?

Page 12: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Notes

B. “Like Dissolves Like”1. In a solution, all particles attract each

other with intermolecular forces of similar strength.i. Polar substances dissolve other polar

substances or ionic substances. ii. Nonpolar substances dissolve

nonpolar substances.

Page 13: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.
Page 14: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Gases

Given: Particles of different substances must attract each other with intermolecular forces of similar strength in order to form an even distribution, which is a solution.

Given: There are no intermolecular forces at work between particles in the gaseous phase

Deduction: Do gaseous particles form solutions (an even distribution)?

Strong Intermolecul

ar Forces

Weak Intermolecul

ar Forces

NoIntermolecul

ar Forces

Page 15: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Video

Dissolving Gasseshttp://www.youtube.com/watch?v=wOo5f_kvjFs

Dissolving NaClhttp://www.youtube.com/watch?v=

EBfGcTAJF4o

Page 16: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Notes

2. In gasses there are essentially no intermolecular forces, therefore all mixtures of gasses are solutions.

Page 17: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Can Solutions Exist Between Particles in Different States (Gas,

Liquid, Solid)?

Page 18: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Notes

C. States of Matter & Solutions1. The solute and solvent may be in different

phases as long as the particles are evenly distributed amongst each other.

i. Ex: Solid NaCl dissolved in liquid water.

ii. Ex: Gaseous CO2 is dissolved in liquid soda.

Page 19: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Solutions Among Various Phases of

Matter

Example Phase of Solute Phase of Solvent

Metallic Alloy Solid Solid

Table salt-water Solid Liquid

Ethyl alcohol-water Liquid Liquid

CO2-water (Soda) Gas Liquid

Air Gas Gas

Page 20: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

How Do We Determine Which Substance is a Solute & Which is the

Solvent?

Page 21: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Notes

D. Identification of Solutes vs. Solvents 1. If the solute and solvent are in different

phases, then solute assumes the solvent’s phase.

2. If the solute and solvent are in the same phase, then the solvent is the one that there is more of.

Page 22: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

All solutions are homogenous mixtures,

but not all homogenous mixtures

are solutions. Can you think of an example of a homogenous mixture that is

not a solution?

Page 23: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

SuspensionsE. Suspensions – suspensions are formed by

the physical homogenous mixture of large particles. (Solutions are made by the chemical mixture of smaller particles).1. Suspensions will settle in time (solutions will

not).2. A light beam passing through a suspension

mixture will be visible (in a solution, it will not).

3. Ex. Sand + Water

Page 24: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Colloidal DispersionF. Colloidal Dispersion – formed when particles larger than those in solution but smaller than those in suspensions are dispersed in a medium

1. The terms dispersed substance vs dispersed medium are used for colloidal dispersion instead of solute and solvent.

2. A colloidal dispersion will not settle. 3. Tyndall effect: a light beam passing through a colloidal

dispersion will be clearly visible. 4. Ex. Whipped cream, mayonnaise, paint, gelatin &

marshmallow.

Page 25: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Tyndall Effect

Page 26: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Our Chemistry class has run out of salt and

we want to make a new batch from

collected sea water.

How do I separate the salt from the water?

Page 27: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

G. Separating Solutions

1. Evaporation Separates dissolved SOLUTE from

SOLUTIONEx. Separating salt from water

2. Simple distillation

Separates SOLVENT from SOLUTIONEx. Obtaining pure water from sea water

3. Fractional distillation Separates one liquid from a mixture

of different liquids using differences in boiling points.Ex. Obtaining alcohol from wine or

oxygen/nitrogen from air.

Page 28: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

4. Filtration

Separates dissolved SOLUTE from SOLUTION

Ex. Filtration of blood in kidneys

5. Chromatography

Separates mixtures into their constituents by preferential adsorption by a solid.

Ex. Separating ink dyes using paper chromatography.

Cont’d

Page 30: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

Learning Check1) The solvent is the part of the solution that

A. gets dissolved B. does the dissolving C. changes phase

2) Two homogenous mixtures not known as solutions are

_______________________ and _______________________.

3) What is a chemical solution?

4) What are some types of chemical solutions?

5) How do we separate chemical solutions? Explain.

Page 31: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

NotesDescribing & Separating Solutions

Page 32: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

I.Describing SolutionsA. Definitions

1. Solution - homogenous mixture of a solute dissolved in a solvent.2. Solute – substance dissolved.3. Solvent – substance that does the dissolving.4. Solution – A homogenous mixture composed on tiny particles.

B. “Like Dissolves Like”1. In a solution, all particles attract each other with intermolecular forces of

similar strength.i. Polar molecules dissolve other polar molecules and ionic compounds. ii. Nonpolar molecules dissolve nonpolar molecules.

2. In gasses there are essentially no intermolecular forces, therefore all mixtures of gasses are solutions.

C. States of Matter & Solutions1. The solute and solvent may be in different phases as long as the particles are

evenly distributed amongst each other.

i. Ex: Solid NaCl dissolved in liquid water.

ii. Ex: Gaseous CO2 is dissolved in liquid soda.

D. Identification of Solutes vs. Solvents 1. If the solute and solvent are in different phases, then solute assumes the

solvent’s phase. 2. If the solute and solvent are in the same phase, then the solvent is the one

that there is more of.

Page 33: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

E. Suspensions – suspensions are formed by the physical homogenous mixture of large particles. (Solutions are made by the chemical mixture of smaller particles).1. Suspensions will settle in time (solutions will not).

2. A light bean passing through a suspension mixture will be visible (in a solution, it will not).

3. Ex. Sand + Water

F. Colloidal Dispersion – formed when particles larger than those in solution but smaller than those in suspensions are dispersed in a medium

4. The terms dispersed substance vs dispersed medium are used for colloidal dispersion instead of solute and solvent.

5. A colloidal dispersion will not settle.

6. Tyndall effect: a light beam passing through will be clearly visible.

7. Ex. Whipped cream, mayonnaise, paint, gelatin & marshmallow.

Page 34: Solutions Subtopics include: (1) Describing Solutions, (2) Concentrations, (2) Solubility & (3) the Effects of Solutes on Solutions.

G. Seperating Solutions

1. Evaporation – separates dissolved SOLUTE from SOLUTION.i. Ex. Separating salt from water

2. Simple distillation – separates solvent from solutioni. Ex. Obtaining pure water from sea water

3. Fractional distillation – separates one liquid from a mixture of different liquids that have different boiling points.i. Ex. Obtaining ALCOHOL from wine or oxygen/nitrogen

from air.