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    int. j. remote sensing, 2002, vol. 23, no. 16, 32293249

    Quantication of surface suspended sediments along a river dominated

    coast with NOAA AVHRR and SeaWiFS measurements: Louisiana,

    USA

    S. W. MYINT

    Department of Geography, University of Oklahoma, Norman, OK 73019, USA;e-mail: [email protected]

    and N. D. WALKER

    Coastal Studies Institute/Dept of Oceanography and Coastal Sciences,

    Louisiana State University, Baton Rouge, LA 70803, USA;e-mail: [email protected]

    (Received 22 May 2000; in nal form 8 August 2001 )

    Abstract. The ability to quantify suspended sediment concentrations accuratelyover both time and space using satellite data has been a goal of many environ-mental researchers over the past few decades. This study utilizes data acquiredby the NOAA Advanced Very High Resolution Radiometer (AVHRR) and the

    Orbview-2 Sea-viewing wide eld-of-view ( SeaWiFS) ocean colour sensor, coupledwith eld measurements to develop statistical models for the estimation of near-surface suspended sediments and suspended solids. Ground truth water sampleswere obtained via helicopter, small boat and automatic water sampler within afew hours of satellite overpasses. The NOAA AVHRR atmospheric correctionwas modied for the high levels of turbidity along the Louisiana coast. Modelswere developed based on the eld measurements and reectance/radiance meas-urements in the visible and near infrared Channels of NOAA-14 and Orbview-2SeaWiFS. The best models for predicting surface suspended sediment concentra-tions were obtained with a NOAA AVHRR Channel 1 (580680 nm) cubic model,Channel 2 (7251100 nm) linear model and SeaWiFS Channel 6 (660680 nm)power model. The suspended sediment models developed using SeaWiFS Channel5 (545565 nm) were inferior, a result that we attribute mainly to the atmosphericcorrection technique, the shallow depth of the water samples and absorptioneVects from non-sediment water constituents.

    1. Introduction

    Louisiana coastal waters receive inorganic sediments from the Mississippi River,

    the largest river in North America and sixth largest worldwide in terms of discharge.

    Annual water and sediment discharges average 18 400 m3 s1 and 210106 tons yr1

    (Milliman and Meade 1983) The discharge and sediment load of the Mississippi

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    Figure 1. Map of the study region showing where the Mississippi River and Atchafalaya

    River enter into the northern Gulf of Mexico along the Louisiana coastline.

    River bird-foot delta and the Atchafalaya River delta, 200 km to the west ( gure 1) .

    The Atchafalaya River (including the Red River ow) carries about 30% of the

    volume and 50% of the suspended sediment load of that in the Mississippi River

    (Mossa and Roberts 1990). The low salinity, high turbidity plumes of these two

    rivers are discharged into very diVerent coastal environmental settings. The main

    branch of the Mississippi River ows into the Gulf of Mexico through several passes,

    intersecting a headland that projects about 60 km south of the mainland. The

    Atchafalaya River water and sediments are discharged through Atchafalaya Bay

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    of NOAA AVHRR and radiance measurements of the Orbview-2 SeaWiFS. Satellite-

    acquired reectance measurements can provide valuable information on the distribu-

    tion of river water and sediments on the continental shelf as well as on the circulation

    processes aVecting the fate of river-borne material. The development of better tech-

    niques for quantifying water constituents using satellite reectance measurements

    will lead to major improvements in the understanding and modelling of sedimentre-suspension and transport in river-inuenced coastal environments.

    Many researchers have used optical remote sensing techniques to study the

    spatial extent and temporal changes in suspended sediments of reservoirs, lakes and

    rivers and the coastal ocean (e.g. Goldman et al. 1974, Gagliardini et al. 1984, Rouse

    and Coleman 1976, Curran and Novo 1988, Stumpf 1988, Stumpf and Pennock

    1989, Moeller et al. 1993, Wang et al. 1996, Walker 1996, Walker and Hammack

    2000). Riverine and coastal waters are comprised of a diverse array of living, non-

    living and once living material that vary over time and space. The main constituents

    are suspended inorganic matter, suspended organic matter, phytoplankton , dissolvedorganic matter and detritus (Kondratyev and Filatov 1999). In the coastal zone of

    Louisiana, suspended sediments (inorganic matter) are a large component of the

    in-water substances with sediment loads in the Mississippi and Atchafalaya River

    typically ranging from 100 to 400 mg l1 (Mossa 1990, Walker 1996, Allison et al.

    2000). Concentrations of suspended inorganic matter due to river discharge as well

    as from the re-suspension of unconsolidated bottom sediments from wind-waves are

    relatively high (Huh et al. 1991, Moeller et al. 1993, Huh et al. 1996, Walker 1996,

    Allison et al. 2000, Walker and Hammack 2000, Huh et al. 2001). The contribution

    of suspended organic matter may also be relatively high as a result of the high levelsof phytoplankton production (Rabalais et al. 1991) as well as from detritus derived

    from the extensive marshes. SAIC (1989) showed that a major optical property of

    the Louisiana shelf waters is the large amount of yellow substances found in the

    estuarine and river discharges.

    The determination of suspended sediments or total suspended solids from water

    reectance is based on the relationship between the scattering and absorption proper-

    ties of water and its constituents (Maul 1985). Most of the scattering is caused by

    suspended sediments whereas the absorption is controlled by chlorophyll a and

    colored dissolved or particulate matter. The spectral behaviour of sediments isdependant both on the particle size distribution and mineral composition (Maul

    1985, Novo et al. 1989). For any given concentration, ne-grained material contains

    more particles and thus scatters more than would an equal weight of coarse-grained

    material. Sediment type also eVects the relationship between reectance and sus-

    pended sediment concentration due to the unique reectance spectra of diVerent

    sediments. For example, Novo et al. (1989) found that a sample of white clay was

    four times more reective at 600 nm than red silt. Moore (1977) demonstrated that

    the peak in reectance shifts to longer wavelengths as the suspended sediment

    concentration increases (Curran and Novo 1988). The absorptive in-water compon-ents such as chlorophyll a and CDOM have been shown to lower the reectance in

    b i l ( d ) h b i V f

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    later applied by Froidefond et al. (1993) and Walker (1996), among others. The

    modication we present here enables development of statistical models that estimatesuspended sediment concentrations in the highly turbid waters of the Atchafalaya

    River outow region (Walker and Hammack 2000, Walker 2001). The models are

    then applied to independent data collected in subsequent years to evaluate the

    robustness and accuracy of these algorithms under diVerent environmental condi-tions. Statistical models for estimating suspended sediment concentrations are also

    developed for the Orbview-2 SeaWiFS, using the standard NASA atmospheri c

    correction formulation (Gordon and Wang, 1994).

    The primary objectives of this study were:

    (1 ) To develop improved techniques for the quantication of suspended sedi-

    ments in turbid coastal environments (Case 2 waters) using visible and near

    infrared Channels of NOAA AVHRR and Orbview-2 SeaWiFS.

    (2) To apply these models to independent datasets to evaluate the robustness and

    accuracy for estimating suspended sediment concentrations under varyingenvironmental conditions.

    (3 ) To identify and evaluate the main sources of error in model development.

    2. Methodology

    The main steps undertaken were the (a) collection of ground truth measurements

    coincident with clear-sky satellite overpasses, (b) atmospheric correction of the

    satellite data to obtain water reectances, (c) investigation of relationships between

    the in-situ measurements and the satellite-derived water reectances, (d) development

    of statistical models, and (e) application, testing and assessment of the new modelson independent datasets.

    2.1. Satellite data overview

    The satellite data used in this study were received and analysed at the Earth

    Scan Laboratory, Coastal Studies Institute, Louisiana State University. Reectance

    measurements from the NOAA-14 Advanced Very High Resolution Radiometer(AVHRR) were used as they were obtained with the highest sun angle, in mid-

    afternoon. The AVHRR sensor has two Channels appropriate for analysing sus-

    pended material, Channel 1 in the red visible portion from 580 to 680 nm, andChannel 2 in the near infrared from 725 to 1100 nm (Table 1). SeaWiFS radiance

    measurements are obtained in six visible channels and two near infrared channels

    from 402 to 885 nm (Table 1) . The SeaWiFS channels oVer increased radiometric

    Table 1. NOAA-14 AVHRR and SeaWiFS ocean colour scanner spectral Bands/Channels.

    NOAA-14 AVHRR SeaWiFSChannel/band wavelength (nm) Wavelength (nm)

    1 580680 4024222 7251100 4334533 3550 3930 480 500

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    sensitivity over NOAA AVHRR visible and near infrared channels (Stumpf 1992) as

    the sensors primary purpose is to estimate chlorophyll a and ocean productivity

    (OReilly et al. 1998). Both sensors have pixel sizes of approximately 1.1 km at nadir.

    2.2. Field data

    A crucial step in the quantitative use of remote measurements is the collectionof in situ water samples coincident with clear-sky satellite overpasses. It is important

    that the measurements be made as close together in time as possible. Helicopters

    provide an eYcient platform for collection of water samples for several reasons.

    First, one can sample a large area rapidly, enabling the sampling of a range of water

    types. Second, one can locate areas of uniform colour indicating some homogeneity

    in the water mass. Third, if clouds are in the eld of view, one can locate cloud-free

    areas more easily at the elevated altitude. The ground truth data used in this study

    were obtained by helicopter, by high speed boat and by automatic water samplers.

    For the NOAA AVHRR model development, two helicopter trips were performedover the Atchafalaya region on 26 April 1996 and 21 June 1996, with data collection

    lasting about four hours, centred on the satellite overpass time. Additional ground

    truth water samples were obtained by automatic water samplers in West Cote

    Blanche Bay west of Atchafalaya Bay on 26 March and 27 March 1998 within one

    hour of satellite overpass. On 21 March 2001, additional water samples were collected

    by a small fast coastal research vessel in Fourleague Bay and on the inner shelf, east

    of Atchafalaya Bay. Also on 21 March, water samples were collected by a research

    cruise on the inner shelf near the Mississippi bird-foot delta. The water samples

    collected on 21 March 2001 were used to test the NOAA AVHRR models. TheSeaWiFS ground truth data were obtained on 26 April 2000, west of the Mississippi

    River delta, in Barataria Bay and on the inner shelf seaward of the Bay. As of yet,

    additional ground truth data have not been obtained to test the SeaWiFS suspended

    sediment model.

    The 500 ml water samples, obtained from the top 0.5 m of water, were refrigerated

    in the dark and processed within a few days of collection. The concentrations of

    total suspended solids (TSS) were determined by ltering through GF/F glass ber

    lters following the methods described in USGS (1987). Filters were dryed at 60C

    for 12 hours and re-weighed. The inorganic sediment fraction or suspended sediment(SS) was determined by ashing the lters at 500C for 12 h and re-weighing. For the

    water samples analysed, the inorganic fraction contributed 80% or more to the total

    suspended solid (TSS) weight when TSS exceeded 10 mg l 1 . At lower TSS concentra-

    tions, the organic fraction was as much as 50%. Visual examination of the lter

    papers before ashing revealed that the organic material was primarly phytoplankton

    (Walker and Hammack 2000).

    2.3. Atmospheric correction of the data

    The atmospheri c correction of NOAA AVHRR Channel 1 and 2 data wereperformed using a technique described by Stumpf and Pennock (1989) and Stumpf

    ( ) hi h i i i f h i l i di

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    Channel 2 reectances are subtracted from Channel 1 reectances. The purpose of

    this step is to remove contamination from aerosols and sunglint. However, in doingso one assumes that the water reectance in Channel 2 is zero (Gordon and Morel

    1983). Then, a clear-water pixel is identied in the area of interest and the reectance

    value of this pixel is subtracted from the entire scene. This last step removes contam-

    ination due to Rayleigh and aerosol scattering. This technique has been used success-fully in studies of Mobile Bay and Delaware Bay (Stumpf 1992) and the Mississippi

    plume region (Walker 1996). For our study area, the technique required modications

    because the Channel 2 measurements in the Atchafalaya Bay region were non-zero

    (gure 2(b)), thus invalidating the assumption that water reectance in Channel 2 is

    negligible. This problem was solved by modifying the bias correction technique for

    use with Channel 1 alone. In short, step 2 was omitted from the above procedure.

    This modied technique was successful in retaining the water reectance patterns

    within the Atchafalaya and adjacent bays and on the inner shelf. Three new variables

    were created in the atmospheric correction process. The variable created by sub-tracting Channel 2 from Channel 1 is called Ch1-Ch2. The atmospherically corrected

    Channel 1 and 2 variables are called Ch1W and Ch2W.

    Determination of water column reectance Rd for each Channel was based on

    the following steps:

    Rd#R

    d=R

    c-R

    bias

    where:

    Rc=

    CA( 1)

    T0

    (1)T1

    (1)-

    A(2)

    T0

    (2)T1

    (2)

    D*(1/r

    2)*(1/cosh)

    A(l)=albedo for Channel l, where A=G*C+I (from Kidwell 1998), G and I

    are calibration coeYcients, and C=count value (01023), T0

    (l)=exp.{-(tr(l)/2+

    t0

    (l))/cosh}, T1

    (l)=exp.{-tr(l)/2+t

    0(l)}, ( 1/r2 )={1+0.0167 cos j }2 and j=2

    (3.1416)(D-3)/365, D is the Julian day, cos h=cosine of solar zenith angle at

    scene centre, tr(l)=Rayleigh optical depth for Channel l, t

    0(l)=ozone and water

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    vapor absorption optical depth for Channel l, Rbias=residual reectance dened as

    Rc

    for a clear atmosphere over clear water near the area of interest.

    The SeaWiFS data were atmospherically corrected using the SeaSpace TerascanTMversion of the NASA Goddard SEADAS code based primarily on Gordon and Wang

    (1994). The NASA atmospheric correction software computes water leaving radiance

    for channels 1 to 5 and total radiance for 6 to 8. As in the Stumpf and Pennock(1989) technique, the assumption is made that water leaving radiance in the near IR

    channels is zero and the water leaving radiance in channels 15 is lowered accord-

    ingly. Throughout the paper, NOAA AVHRR data is presented as reectance meas-

    urements in percent and SeaWiFS data is presented as radiance measurements with

    units of mW cm2 mm 1 sr1 . These are the standard outputs of our TerascanTMimage processing software. The reader is referred to Froidefond et al. (1993) for a

    discussion of conversion techniques from NOAA AVHRR reectance to radiance

    values.

    3. Results

    3.1. Model development

    Correlation, linear and nonlinear regression techniques were used to quantify the

    relationships between the NOAA AVHRR satellite measurements and the in situ

    measurements of total suspended solids (TSS) and suspended sediments (SS). The

    SeaWiFS sensor had not been launched at the time of these helicopter over-ights.

    Linear correlations between TSS, SS and the three variables derived from NOAA

    AVHRR reectance data were investigated using the near-simultaneou s measure-

    ments of satellite and eld data collected on 26 April 1996 (table 2) and on 21 June1996 (table 3) . The separate correlation analyses provided information on the

    strength and reliability of the relationships among the variables. Separate analyses

    for 26 and 27 March 1998 were not performed since only a single measurement was

    available for each date.

    Table 2. NOAA-14 correlation matrix of variables using the 26 April 26 1996 eld data.

    TSS SS Ch1Ch2 Ch1W Ch2W

    TSS 1SS 0.999 1Ch1Ch2 0.677 0.680 1Ch1W 0.833 0.836 0.967 1Ch2W 0.939 0.941 0.862 0.963 1

    Notes: Correlations are all signicant at the 0.01 level (Pearson Correlation), N=19.

    Table 3. NOAA-14 correlation matrix of variables using the 21 June 1996 eld data.

    TSS SS Ch1Ch2 Ch1W Ch2W

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    Signicant linear correlations (at the 0.01 level ) were determined between the

    satellite reectances, TSS and SS. The linear correlations were highest between Ch2Wand the TSS/SS on both dates. The correlations were relatively low between the

    Ch1Ch2 variable and the TSS/SS measurements. The linear correlations were

    highest using the eld measurements of 21 June 1996 when the Atchafalaya River

    discharge was relatively high compared with the April 1996 dataset. River dischargeon 21 June was 11 558 m3 s1 and on 26 April it was 5920 m3 s1 .

    The ground truth measurements of TSS and SS are shown in gure 3 (see

    gure 2 for locations). TSS ranged from 5140 mg l1 and SS ranged from 0 to

    120 mg l1, indicating that inorganic sediments dominated the water constituents. A

    similar graph was constructed for the satellite reectance variables (gure 4). The

    Ch1W reectance measurements were higher and exhibited a larger range in values

    than those of Ch2W, a result that would be expected for this shorter wavelength

    Channel. By comparing gures 3 and 4, it is evident that the Ch1Ch2 variable does

    not follow the curves of TSS and SS above concentrations of about 60 mg l1

    . Weattribute this result to the failure of the atmospheric correction scheme at the higher

    levels of TSS and SS.

    Scatter-plots of satellite reectances (independent variables) and the eld measure-

    ments of suspended sediments (dependant variables) demonstrated that the relation-

    ships were non-linear using Ch1W reectances and linear using Ch2W reectances

    (gure 5). Previous algorithms developed using NOAA AVHRR Ch1 measurements

    were also non-linear in form (Stumpf 1992, Walker 1996, Walker and Hammack

    2000).

    The SPSS software package was used to determine the best predictive modelsfor the estimation of suspended sediments and suspended solids from the reectance

    measurements. Both linear and nonlinear regression techniques were investigated.

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    Figure 4. Satellite reectances (%) corresponding to the eld measurements of gure 3.Sample points 121 were obtained in June and 2244 were obtained in April.

    The nonlinear models that were investigated included logarithmic, inverse, quadratic,

    cubic, power, compound, S-curve, logistic, growth and exponential. Initially, models

    were chosen based mainly on the coeYcient of determination (R2 ) values and F-

    ratios. Table 4 depicts the best model results using Ch1W and Ch2W as independent

    variables.

    From the statistical results shown in table 4 and graphical data displays, the

    most robust models were chosen for the estimation of both suspended sediments

    (SS) and total suspended solids (TSS) using Ch1W and Ch2W. In gure 6, the

    predicted concentrations of SS computed from the two diVerent reectance models

    are shown. Table 5 corresponds to gure 6, listing summary statistics for the chosen

    models including R2 , the standard error of the estimate (SEE), root mean square

    error (RMS), F-ratio and the tabled F value.

    The cubic models ( SS1C, TSS1C) yielded the best estimates of suspended sediment

    and suspended solids using Ch1W (table 5, gure 6). The linear models (TSS2L,

    SS2L) gave the best results using Ch2W (table 5, gure 6).

    The equations for the selected predictive models for TSS and SS are given below:

    TSS=-10.26+(14.8288 Ch1W)-(3.1684 (Ch1W)2)+(0.2691 (Ch1W)3)

    SS=-10.746+(12.7179 Ch1W)-(2.7548 (Ch1W)2 )+(0.2353 (Ch1W)3 )

    TSS=-8.1358+(20.0235 Ch2W)

    SS=-9 3438+(17 3593 Ch2W)

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    Figure 5. Scatter-plot of NOAA AVHRR (top panel ) Ch1W reectances (%) and ( bottompanel) Ch2W reectances (%) against suspended sediment (SS) concentrations(mg l1): April/June 1996.

    more similar to the eld measurements, particularly at the higher levels of suspended

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    Table 4. Linear and nonlinear estimations for TSS and SS using Ch1W and Ch2W.

    LIN QUA CUB EXP POW

    TSS Ch1W R2 0.71 0.92 0.95 0.91 0.83F-ratio 96.97 213.63 218.03 393.54 192.99

    SS Ch1W R2 0.70 0.92 0.95 0.83 0.78F-ratio 94.86 217.05 224.38 194.13 140.13

    TSS Ch2W R2 0.91 0.91 0.95 0.83 0.87F-ratio 379.52 207.56 224.77 193.92 268.53

    SS Ch2W R2 0.90 0.91 0.95 0.71 0.76F-ratio 349.14 189.80 233.48 96.92 129.12

    Notes: LIN=Linear model; QUA=Quadratic model; CUB=Cubic model; EXP=Exponential model; and POW=Power model.

    sediment levels were highest. The Ch2W model yielded higher levels of SS in these

    regions. This was also observed in the actual Ch2 reectance measurements ( gure 2 ).

    It is most likely that the diVerence may be attributed to diVerential absorption by

    non-sediment water constituents including gelbstoVe, marsh detrital material and

    phytoplankto n (Wang et al. 1996). Absorption eVects would have impacted Ch1

    more than Ch2, lowering reectance values in Ch1. Additional information on water

    constituents will be needed to clarify the observed diVerences between reectance

    patterns of the two channels.

    3.2. Application and testing of the models

    Water samples were obtained on 21 March 2001 in the Atchafalaya Bay region

    and in the Mississippi River plume, coincident with a clear sky NOAA AVHRR

    image. The Atchafalaya and Mississippi Rivers were in ood with discharges

    of 10214m3 s1 and 24 209 m3 s 1 (http://www.mvn.usace.army.mil), respectively.

    Twelve surface samples were collected in the Atchafalaya region and six in the

    Missisissippi Plume region ( Locations, gures 8 and 9). The satellite reectance

    values were extracted from individual pixels closest to the location of the watersamples. The models developed in previous secions were then applied to this

    independent set of data.

    The estimates of SS and TSS from the Ch1W and Ch2W models were better

    than expected. RMS errors were lowest using the Ch2W linear algorithm and ranged

    from 5.87.2 mg l1 (table 6). The Ch1W cubic algorithm produced concentration

    estimates with RMS values of 10.610.9 mg l1 . Bias values were negative using

    Ch1W (-22 to -24 mg l1 ) and positive using Ch2W ( 1321 mg l 1). The relatively

    high bias values are attributable to the larger range of SS and TSS encountered on

    21 March 2001.The spatial distribution of surface suspended sediments hindcast using the NOAA

    A d l h f h A h f l i ( ) d f

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    Figure 6. Model estimates of SS concentrations (mg l1 ) using the NOAA AVHRR (top

    panel) Ch1W cubic model and (bottom panel) Ch2W linear model, compared witheld measurements of SS. SS1C and SS2L refer to the suspended sediment predictionsusing the Ch1W cubic model and the Ch2W linear model, respectively.

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    Table 5. Summary statistics for the non linear cubic regression model using NOAA AVHRRCh1W and the linear regression model using NOAA AVHRR Ch2W data.

    Variable Models R2 SEE RMS F-ratio Tabled F0.05

    Ch1W TSS 0.95 9.09 7.69 218.03 4.08

    SS 0.95 6.94 6.60 224.38 4.08Ch2W TSS 0.91 10.38 10.14 379.52 4.08

    SS 0.90 9.38 9.16 349.14 4.08

    Figure 7. Model-estimated regional SS concentrations (mg l 1 ) on 26 April 1996 using (leftpanel) the Ch1W cubic model and (right panel) the Ch2W linear model. Contourintervals of 10, 25, 50 and 100 mg l 1 are shown.

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    Figure 9. Model-estimated regional SS concentrations (mg l1) for the Mississippi deltaregion on 21 March 2001 using (left panel) the Ch1W cubic model and (right panel)the Ch2W linear model. Contour intervals of 10, 25, 50 and 100 mg l1 are shown.The location of ground truth data collection is depicted using dots.

    Table 6. RMS and bias values for the estimation of TSS and SS from NOAA-14 AVHRRCh1W and Ch2W reectance data on 21 March 2001.

    RMS Bias

    TSS Ch1W 10.94 -22.19SS Ch1W 10.57 -24.02TSS Ch2W 7.18 21.07SS Ch2W 5.81 13.44

    Extensive chlorophyll blooms have been previously observed in Vermilion Bay during

    eld sampling, however, water samples were only obtained from Fourleague Bay in

    March 2001. In the Mississippi delta region (gure 9), the surface sediment distribu-

    tion patterns were similar, but somewhat higher using the Ch2W linear algorithm.

    The Ch2W reectance data and predictions were observed to contain more noise

    and more atmospheric contamination in the 21 March 2001 image, compared with

    those of 1996.

    The March 2001 data set provided the opportunity to improve the SS algorithms

    due to the larger range of sediment concentrations encountered in the eld (maximum

    ground truth data was 209 mg l1 in March 2001). Scatter-plots of Ch1W and

    Ch2W reectances with SS are shown in gure 10. The summary statistics for the

    new SS regression models, developed by combining eld and satellite measurements

    from 1996 and 2001, are summarized in table 7. The cubic model using Ch1W yielded

    a coeYcient of determination (R2 ) of 0.9. The linear model using Ch2W yielded a

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    Figure 10. Scatter-plot of NOAA AVHRR ( top panel ) Ch1W reectances (%) and ( bottom

    panel) Ch2W reectances (%) against SS concentrations (mg l 1 ) using all eldmeasurements: 19962001.

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    Table 7. Summary statistics of suspended sediment regression models using all eld datawith NOAA AVHRR Ch1W and Ch2W variables.

    LIN QUA CUB EXP POW

    Ch1W R2 0.64 0.88 0.90 0.81 0.73

    F-ratio 104.07 206.39 174.15 242.18 154.56Ch2W R2 0.93 0.94 0.94 0.66 0.73

    F-ratio 816.15 436.11 285.79 110.22 156.55

    Notes: LIN=Linear model; QUA=Quadratic model; CUB=Cubic model; EXP=Exponential model; and POW=Power model.

    to the interior of the bay (gure 11). Two additional samples were obtained to the

    east of the line within the central bay region. The samples in the vicinity of the tidal

    pass were excluded from the analysis as they were too close to land to be valid with

    the nominal 1.1 km pixels of SeaWiFS. The correlation matrix obtained for theradiance values, SS and TSS is shown in table 8. The concentration of suspended

    sediments (SS) and total suspended solids (TSS) were found to be highly correlated

    (0.998 ). Channel 6 ( 670 nm) was more highly correlated with SS and TSS than was

    Channel 5 (555 nm). Correlation coeYcients between Ch 6 radiances, TSS and SS

    were 0.85 (table 8). Correlation coeYcients between the Ch 5 and TSS/SS were only0.460.47. The relatively high correlations with Channel 6 were not unexpected as

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    Table 8. Correlation matrix showing the relationship between TSS, SS, SeaWiFS 555 nmand SeaWiFS 670 nm radiances on 26 April 2000.

    TSS SS SeaWiFS-555 SeaWiFS-670

    TSS 1

    SS 0.998** 1SeaWiFS-555 0.456* 0.468* 1SeaWiFS-670 0.845** 0.853** 0.552* 1

    Notes: **Correlation is signicant at the 0.01 level (Pearson Correlation), N=20.*Correlation is signicant at the 0.05 level (Pearson Correlation), N=20.

    it is most similar to NOAA AVHRR Ch1 measurements. The relatively poor perform-

    ance of Channel 5 may be partially attributed to over-correction for the atmosphere

    by the standard NASA algorithm, although SS concentrations were not as high as

    in the Atchafalaya region (maximum of 48 mg l1 ). Another source of error may

    have been the use of water samples from the upper 0.5 m of the water column, if the

    Ch5 radiances represented an integration over a deeper water column.

    Statistical models were then developed using the radiance values of the 555 nm

    and 670 nm Channels (table 9 ). For estimation of SS, the power model out-performed

    other models. Only the model using the 670 nm Channel is considered a reasonable

    approximation of the surface suspended sediment levels (gure 12) . The model-

    estimates of suspended sediment concentrations are compared with actual values in

    gure 13. The RMS error for this model was 8.24 mg l 1 .

    4. Discussion and conclusions

    The technique of ground truthing satellite data via helicopter and high speed

    boat proved very eVective for obtaining water samples close in time to the satellite

    reectance measurements. This is of great importance in coastal regions where

    reectance patterns change rapidly as a result of water movements due to tidal and

    wind-driven currents, mixing and re-suspension processes.

    The near simultaneous acquisition of eld measurements and regional synoptic

    satellite data enabled the development and testing of statistical models for estimating

    near-surface total suspended solids (TSS) and suspended sediments (SS) in surface

    Table 9. Summary statistics of the selected regression models using SeaWiFS 555 and 670 nmChannel data.

    LIN QUA CUB EXP POW

    TSS 555 nm R2 0.21 0.56 0.56 0.37 0.52F-ratio 4.73 10.73 6.91 10.49 19.42

    SS 555 nm R2

    0.22 0.56 0.57 0.42 0.58F-ratio 5.04 10.98 7.14 13.01 24.90

    TSS 670 R2 0 72 0 72 0 72 0 79 0 83

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    S. W. Myint and N. D. Walker3246

    Figure 12. Scatter-plot of satellite-derived normalized radiances (670 nm) and SSconcentrations (mg l1 ) along transect line shown in gure 11.

    Figure 13. Model estimates of SS concentrations (mg l1 ) using the SeaWiFS 670 nm powermodel compared with eld measurements of SS.

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    Quantication of suspended sediments from satellite 3247

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    years later.

    The NOAA AVHRR Ch1W non-linear model and the Ch2W linear model yielded

    R2 values from 0.90.95 for SS and TSS. Subsequent testing with an independent

    dataset yielded acceptable RMS values (

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    S. W. Myint and N. D. Walker3248

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