Resin R3XHT_material Safety Data Sheet_Part A

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Product : R3XHT (Part A), Date : 5 January 2013 MSDS No. : 21112012 1 MATERIAL SAFETY DATA SHEET 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product Name: R3XHT (Part A), Date : 5 January 2013 MSDS No. : 21112012 Company: 3X ENGINEERING 9 Av. Albert II 98000 Monaco Tel. : +377 92 05 79 81 Fax : +377 92 05 72 71 (mon. fri. 8 a.m. 5 p.m.) E-mail (questions) : [email protected] Supplier: For Chemical Emergency: ORFILA : 01.45.42.59.59 2. COMPOSITION / INFORMATION ON INGREDIENTS Chemical characterization: Modified epoxide resin on basis Bisphenol-A-Epichlorhydrinresin especially formulated on non-corroding steel-alloy powder and+ AI2O3+ SiC Dangerous components: Bisphenol A-epichlorohydrin resin CAS-Number: 25068-38-6 NLP: 500-033-5 Symbol(s): Xi, N R-phrase(s): 36/38, 43, 51/53 Concentration: > =95 % 3. HAZARDS IDENTIFICATION R 36/38 Irritating to eyes and skin. R 43 May cause sensitisation by skin contact. R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 4. FIRST AID MEASURES General advice: Move out of dangerous area. Take off all contaminated clothing immediately. Eeye contact: Rinse immediately 15 minutes with plenty of water, also under the eyelids. Consult a doctor. Skin contact: If you have skin contact, you must wash off with much water and soap. If irritation persists, consult a doctor. Inhalation : Move to fresh air. Consult a physician after significant exposure. Ingestion: Prevent vomiting if possible. Clean mouth with water and drink afterwardsplenty of water. Call a physician immediately. 5. FIRE-FIGHTING MEASURES Suitable extinguishing agents: Water spray, foam, CO2, extinguishing powder Special hazards during fire fighting: In case of fire toxic gases may be built Protective equipment: In the event of fire, wear self-contained breathing apparatus. Wear personal protective equipment. Additional information Water mist may be used to cool closed containers, risk of bursting. Extinguishing water is to be disposed of in accordance with local authority regulations 6. ACCIDENTAL RELEASE MEASURES Person precautions: Keep unprotected people away. Use personal protective equipment. Avoid contact with skin, eyes and clothing.

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Transcript of Resin R3XHT_material Safety Data Sheet_Part A

  • Product : R3XHT (Part A), Date : 5 January 2013 MSDS No. : 21112012

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    MATERIAL SAFETY DATA SHEET

    1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

    Product Name: R3XHT (Part A),

    Date : 5 January 2013 MSDS No. : 21112012

    Company:

    3X ENGINEERING

    9 Av. Albert II

    98000 Monaco

    Tel. : +377 92 05 79 81 Fax : +377 92 05 72 71

    (mon. fri. 8 a.m. 5 p.m.)

    E-mail (questions) : [email protected]

    Supplier:

    For Chemical Emergency:

    ORFILA : 01.45.42.59.59

    2. COMPOSITION / INFORMATION ON INGREDIENTS

    Chemical characterization: Modified epoxide resin on basis Bisphenol-A-Epichlorhydrinresin especially formulated on

    non-corroding steel-alloy powder and+ AI2O3+ SiC

    Dangerous components: Bisphenol A-epichlorohydrin resin

    CAS-Number: 25068-38-6

    NLP: 500-033-5

    Symbol(s): Xi, N

    R-phrase(s): 36/38, 43, 51/53

    Concentration: > =95 %

    3. HAZARDS IDENTIFICATION

    R 36/38 Irritating to eyes and skin.

    R 43 May cause sensitisation by skin contact.

    R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

    4. FIRST AID MEASURES

    General advice: Move out of dangerous area. Take off all contaminated clothing immediately.

    Eeye contact: Rinse immediately 15 minutes with plenty of water, also under the eyelids. Consult a doctor.

    Skin contact: If you have skin contact, you must wash off with much water and soap. If irritation persists,

    consult a doctor.

    Inhalation : Move to fresh air. Consult a physician after significant exposure. Ingestion: Prevent vomiting if possible. Clean mouth with water and drink afterwardsplenty of water. Call

    a physician immediately.

    5. FIRE-FIGHTING MEASURES

    Suitable extinguishing agents: Water spray, foam, CO2, extinguishing powder

    Special hazards during fire fighting: In case of fire toxic gases may be built

    Protective equipment: In the event of fire, wear self-contained breathing apparatus. Wear personal

    protective equipment.

    Additional information Water mist may be used to cool closed containers, risk of bursting. Extinguishing

    water is to be disposed of in accordance with local authority regulations

    6. ACCIDENTAL RELEASE MEASURES

    Person precautions: Keep unprotected people away. Use personal protective equipment. Avoid

    contact with skin, eyes and clothing.

  • Product : R3XHT (Part A), Date : 5 January 2013 MSDS No. : 21112012

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    Environmental precaution: Do not allow reach sewage system or water bodies. Do not allow to enter the

    ground/soil.

    Methods for cleaning up: Soak up with inert absorbent material e.g. sand, silica gel, acid binder, uni-versal binder, sawdust

    Additional advice: Inform fire brigade or police if the product has penetrated into water or into

    the sewerage or if soil or plants have been contaminated.

    7. HANDLING AND STORAGE

    Handling

    Safe handling advice: Ensure adequate ventilation, especially in confined areas. Avoid contact with skin and eyes.

    Handle in accordance with good industrial hygiene and safety practice.

    Advice on protection against

    fire and explosion: No special precautions necessary if used correctly

    Requirements for storage

    areas and containers: Keep container tightly closed. Keep in a well-ventilated place.

    Advice on common storage: No materials to be specially mentioned

    8. EXPOSURE CONTROLS PROTECTION

    Additional information on the

    lay-out of technical plant: No special precautions necessary if used correctly

    Components with workplace control parameters

    Components:

    CAS-Number:

    Value:

    Release notes:

    Basis:

    Personal protection equipment

    Respiratory protection: Breathing apparatus only if aerosol or dust is formed. No personal respiratory

    protective equipment normally required.

    Hand protection: Polyvinyl alcohol or nitrile-butil rubber gloves

    Eye protection: safety glasses

    Skin and body protection: Long sleeved clothing, rubber or plastic apron

    Hygiene measures: Avoid contact with skin and eyes. Wash hands before breaks and the end of

    workday. Keep away from food and drink.

    9. PHYSICAL AND CHEMICAL PROPERTIES

    Appearance

    Appearance: pasty or brushable

    Form:

    Colour: grey

    Odour: almost odourless

    Other data

    Boiling point/range: < 200C

    Flash point: > 200C (DIN 53213)

    Ignition temperature: approx. 460C

    Upper explosion limit:

    Lower explosion limit:

    Vapour pressure: at 20C > 0.1 hPa

    Density: at 20C > 2,5 g/cm3

    Solubility/qualitative:

    Water solubility: at 20C >0.1g/l

    pH-value:

    Viscosity, dynamic: 400000 mPa

    10. STABILITY AND REACTIVITY

    Thermal decomposition / conditions

    to be avoided: No decomposition if stored and applied as directed.

    Hazardous reactions: Exothermic reaction with amines and strong acids.

    Hazardous decomposition products: NO decomposition if stored and applied as directed.

    11. TOXICOLOGICAL INFORMATION

    Acute oral toxicity: LD50 rat 10000 mg/kg (for main component)

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    Acute inhalation toxicity:

    Acute dermal toxicity: LD50 rat > 2000 mg/kg

    Skin irritation May cause skin irritation in susceptible persons.

    Eye irritation: Contact with eyes may cause irritation.

    Sensitization: May cause sensitization of susceptible persons by skin contact.

    Further information: This product was not tested itself. The above mentioned values are results

    of a product with comparable formulation.

    Human Experience: Repeated or prolonged skin contact may cause allergic reactions with susceptible

    persons.

    12. ECOLOGICAL INFORMATION

    Elimination information (persistence and degradability)

    Biodegradability: The product has not been tested. Not readily biodegradable.

    Physicochemical removability: Most parts can be separated mechanically in a sewage plant.

    AOX:

    Additional information: Do not allow to reach sewage system or water bodies. Do not allow to enter

    the ground/soil.

    13. DISPOSAL CONSIDERATIONS

    Product: Remove according to local authority recommendations, e.g. convey to a suitable incinerator.

    Package not cleaned: Empty containers should be transported/delivered using a registered waste

    carrier for local recycling or waste disposal.

    14. TRANSPORT INFORMATION

    Land transport: UN-No. 3082

    Proper shipping name 3082 Environmentally hazardous substance, liquid n.o.s. epoxy resin

    Class 9

    Item 11c ADR

    HI Number 90

    Sea transport: UN-No. 3082

    Proper shipping name Environmentally hazardous substance, liquid n.o.s.(epoxide resin)

    Class 9

    Packing group 3

    EmS -

    MFAG

    Marine pollutant P

    Air transport: UN-No. 3082

    Proper shipping name Environmentally hazardous substance, liquid n.o.s. (Epoxy resin)

    Class 9

    Packing group III

    15. REGULATORY INFORMATION

    Labelling according to EEC Directive

    Hazard-determining

    components of labelling: Bisphenol-A-Epichlorhydrinresin

    Symbol(s): Xi Irritant

    N Environment

    R-phrases: R 36/38 Irritation to eyes

    R 43 May cause sensitisation by skin contact

    R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

    environment.

    S-phrases: S 28 In case of contact with skin, rinse immediately with plenty of water and soap, seek medical

    advice

    S 37/39 Wear suitable gloves and eye/face protection

    S 61 Avoid release to the environment. Refer to special instructions/Safety Data Sheets. Contains

    epoxy constituents. See information supplied by the manufacturer.

    16. OTHER INFORMATION

    These information are based on the present state of our knowledge and do therefore not guarantee certain properties. However, it shall not

    constitute a guarantee for any specific product feature and shall not establish a legally valid contractual relationship.