MATERIAL SAFETY DATA SHEET NORCROS EPOXY RESIN …

of 27 REVISION DATE: August 2016 REVISION COMMENTS: In accordance with REACH Annexe II (453/2010/EC)

MATERIAL SAFETY DATA SHEET

NORCROS EPOXY RESIN (PART A)

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND THE COMPANY/UINDERTAKING

1.1 PRODUCT IDENTIFIER: Norcros Super Epoxy Grout – Resin (Part A) 1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST: Intended use: PC1 Epoxy resin grout for ceramic wall and floor tiling 1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET: NORCROS ADHESIVES Harewood Street Tunstall Stoke on Trent Staffordshire ST6 5JZ Tel: 01782 524 140 Fax: 01782 524141 E-mail: [email protected] 1.4 EMERGENCY TELEPHONE NUMBER: 44 (0) 1782 524 140 SECTION 2: HAZARDS IDENTIFICATION 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE CLASSIFICATION UNDER CLP: Aquatic Chronic 2: H411 Eye Irritation 2: H319 Skin Irritation 2: H315 Skin Sensitisation 1: H317 MOST IMPORTANT ADVERSE EFFECTS: Causes skin irritation May cause an allergic skin reaction Causes serious eye irritation Toxic to aquatic life with long lasting effects 2.2 LABEL ELEMENTS HAZARD STATEMENTS H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Cause serious eye irritation H411 Toxic to aquatic life with long lasting effects SIGNAL WORDS: Warning


HAZARD PICTOGRAMS GHS07 Exclamation mark GHS09: Environmental

PRECAUTIONARY STATEMENTS P280 Wear protective gloves/ protective clothing/ eye protection/ face protection P273 Avoid release to the environment P305 + 351 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses if + 338: present and easy to do. Continue rinsing P303 +361 IF ON SKIN OR HAIR: Immediately take off all contaminated clothing. Rinse skin with + 353 water/ shower P391 Collect spillage P501 Dispose of to licensed, permitted incinerator, or other thermal destruction device 2.3 OTHER HAZARDS PBT This product is not identified as a PBT/vPvB substance SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2 MIXTURES HAZARDOUS INGREDIENTS: Bisphenol A-(Epichlorhydrin) (Reaction Product)

EINECS CAS PBT/ WEL CLP Classification Percent

500-033-5 25068-38-6 - Eye Irit. 2: H319 Skin Irrit. 2: H315 Skin Sens 1: H317 Aquatic Chronic 2: H411

50-70%

Oxirane, Mono [(C12-14 Alyloxy) Methyl] Derivatives


271-846-8 68609-97-2 - Skin Irrit. 2: H315 Skin Sens 1: H317

10-30%

Bisphenol F Epichlorohydrin Resin with Number Average


- 28064-14-4 - Eye Irit. 2: H319 Skin Irrit. 2: H315 Skin Sens 1: H317 Aquatic Chronic 2: H411

10-30%


SECTION 4: FIRST AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES GENERAL INFORMATION Chemical burns must be treated by a physician. Seek medical attention for all burns, regardless how minor they may seem. AFTER INHALATION: Move affected personnel into fresh air at once. Do not induce vomiting. Keep the

affected person warm and at rest. Seek immediate medical attention. AFTER INGESTION: Immediately rinse mouth thoroughly Do not induce vomiting Provide rest, warmth and fresh air Seek immediate medical attention AFTER CONTACT Remove affected person from source of contamination WITH SKIN Wash off promptly and flush contaminated skin with water

Promptly remove clothing if soaked through and flush with water. Seek medical attention if symptoms occur after washing

AFTER CONTACT Remove affected person from source of contamination WITH EYES Make sure that any contact lenses are removed before rinsing opened eye using

plenty of clean water for at least 15 minutes Continue to rinse for at least 15 minutes and seek medical attention.

4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED General Information The severity of the symptoms described will vary dependent of the concentration and length of Exposure

INHALATION Irritation of nose, throat and airway with a feeling of tightness in the chest. Exposure may cause coughing or wheezing

INGESTION: May cause soreness and redness of the mouth SKIN CONTACT: May cause irritation and redness at site of conatct EYE CONTACT: Irritation of eyes and mucous membranes 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED No recommendation given, but first aid may still be required in cases of accidental exposure, inhalation or ingestion of this chemical. If in doubt SEEK MEDICAL ATTENTION PROMPTLY SECTION 5: FIRE FIGHTING MEASURES 5.1 EXTINGUISHING MEDIA Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE In case of fire, toxic gases (CO, CO2, NOx) may be formed


5.3 ADVICE FOR FIRE FIGHTERS Special Fire Fighting Procedures Beware, risk of formation of toxic and corrosive gases. Use supplied air respirator if product is involved in a fire. Protective Equipment for Fire Fighters: Use air-supplied respirator, gloves and protective goggles SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES 6.1.1 For non-emergency personnel Wear suitable protective clothing (including respiratory protection) during removal of spillages in a confined area – refer to section 8. 6.1.2 For emergency personnel Wear suitable protective clothing (including respiratory protection) during removal of spillages in a confined area – refer to section 8. 6.2 ENVIRONMENTAL PRECAUTIONS Avoid material entering drains or water courses or onto the ground. 6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP Wear necessary protective equipment. Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Shovel into dry containers. Cover and move the containers. Flush the area with water. Do not let washing down water contaminate ponds or waterways 6.4 REFERENCE TO OTHER SECTIONS This product contains a substance which is hazardous to aquatic organisms and which may cause long term adverse effects in the aquatic environment. Refer to section 8 of SDS SECTION 7: HANDLING AND STORAGE 7.1 PRECAUTIONS FOR SAFE HANDLING Ensure good ventilation Avoid spilling Avoid skin and eye contact Avoid the formation or spread of mists in the air 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIEs Store in tightly closed original containers Store in dry, well ventilated areas at temperatures of 5 – 32

oC

Protect from frost and damp conditions The floor of the storage room must be impermeable to prevent the escape of liquids 7.3 SPECIFIC END USE(S) The identified uses for this product are detailed in Section 1.2


SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 CONTOL PARAMETERS Workplace Exposure Limits: No data available DNEL/ PNEC: No data available 8.2 EXPOSURE CONTROLS ENGINEERING MEASURES: Provide adequate ventilation including local extraction to ensure

that the defined exposure limit is not exceeded. Provide eyewash station. The floor of the storage room must be impermeable to prevent the escape of liquids

RESPIRATORY EQUIPMENT: If ventilation is insufficient, suitable respiratory protection must

be provided

HAND PROTECTION: Use protective gloves. Breakthrough time of the glove material > 8 hours. Material of gloves for long term application (BTT>480min) must be Nitrile, Butyl, Neoprene or PVC. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material and dexterity. Always seek advice from glove suppliers. Use gloves approved to relevant standards, e.g. EN 374 (Europe), F739 (US)

EYE PROTECTION: Safety glasses/goggles giving complete protection to eyes. Provide

eyewash station

SKIN PROTECTION: Protective clothing ENVIRONMENTAL: Ensure emissions from ventilation or equipment comply with

environmental protection legislation

HYGIENE MEASURES: DO NOT SMOKE IN WORK AREA. Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES

State: Liquid Colour: Yellow Odour: Barely perceptible odour Viscosity: Viscous Boiling Point/range

oC: >100

Relative density: 1.12 Flash Point

oC: >100

pH: Not applicable


9.2 OTHER INFORMATION Not applicable SECTION 10: STABILITY AND REACTIVITY 10.1 REACTIVITY Stable under recommended transport or storage conditions 10.2 CHEMICAL STABILITY Stable under normal temperature conditions and recommended use 10.3 POSSIBILITY OF HAZARDOUS REACTION Hazardous reactions will not occur under normal transport or storage conditions Decomposition may occur on exposure to conditions or materials listed below 10.4 CONDITIONS TO AVOID Heat 10.5 INCOMPATIBLE MATERIALS Strong acids, strong oxidising substances. 10.6 HAZARDOUS DECOMPOSITION PRODUCTS During fire, toxic gases are formed SECTION 11: TOXICOLOGICAL INFORMATION 11.1 INFORMATION ON TOXICOLOGICAL EFFECTS Toxicity Values:

Route Species Test Value Units

ORL - LD50 > 2000 mg/kg

SKIN - LD50 > 2000 mg/kg

HAZARDOUS INGREDIENTS: Bisphenol A-(epichlorhydrin) (Reaction Product)


ORL MUS LD50 15,600 mg/kg

ORL RAT LD50 11,400 mg/kg

SKIN RBT LD50 >20 ml/kg

Oxirane, Mono[(C12-14Alkyoxy)Methyl] Derivatives



Relevant hazards for substance

Hazard Route Basis

Skin corrosion/irritation DRM Hazardous: calculated

Serious eye damage/irritation OPT Hazardous: calculated

Respiratory/Skin sensitisation DRM Hazardous: calculated


SYMPTOMS/ ROUTES OF EXPOSURE SKIN CONTACT: May cause irritation and redness at the site of contact EYE CONTACT: May cause irritation and redness. Eyes may water profusely INGESTION: May cause soreness and redness of the mouth and throat INHALATION: May cause irritation of the throat with a feeling of tightness in the

chest. Exposure may cause coughing or wheezing

DELAYED/ IMMEDIATE Immediate effects can be expected after short term exposure. EFFECTS: SECTION 12: ECOLOGICAL INFORMATION 12.1 TOXICITY ECOTOXICITY Dangerous for the environment if discharged into water courses. The product contains a substance which is harmful to aquatic organisms which may cause long term adverse effects in the aquatic environment. 12.2 PERSISTANCE AND DEGRADABILITY Not biodegradable 12.3 BIOACCUMULATIVE POTENTIAL May accumulate in soil and water systems 12.4 MOBILITY IN SOIL Readily absorbed into soil 12.5 RESULTS OF PBT AND vPvB ASSESSMENT Not identified as a PBT/vPvB substance 12.6 OTHER ADVERSE EFFECTS Toxic to aquatic organisms. Toxic to soil organisms SECTION 13: DISPOSAL CONSIDERATIONS In accordance with local authority regulations. Transfer to a suitable container and arrange for collection by specialised disposal company. 13.1 WASTE TREATMENT METHODS Dispose of waste and residues in accordance with local authority regulations


SECTION 14 TRANSPORT INFORMATION 14.1 UN NUMBER UN No: UN3082 14.2 UN PROPER SHIPPING NAME Environmentally hazardous substance, Liquid, N.O.S 14.3 TRANSPORT HAZARD CLASS(ES) Transport class: 9 Transport Labels:

14.4 PACKING GROUP Packing Group: III 14.5 ENVIRONMENTAL HAZARDS Environmentally Hazardous Substances Marine Pollutant

14.6 SPECIAL PRECAUTIONS FOR USER Special precautions: No special precautions Tunnel code: E Transport category: 3 14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE


SECTION 15: REGULATORY INFORMATION 15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATIONS SPECIFIC FOR THE SUBSTANCE OR MIXTURE 15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATIONS SPECIFIC FOR THE SUBSTANCE OR MIXTURE UK Regulatory References The Control of Substance Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716) Approved Code of Practice Control of Substances Hazardous to Health Approved code of practice Classification and Labelling of Substances and Preparations Dangerous for Supply Guidance Notes Workplace exposure Limits EH40 Introduction to Local Exhaust Ventilation HS(G)37 CHIP for everyone HSG (108) EU Legislation Dangerous Substance Directive 67/548/EEC National Regulations Health and Safety at Work Act (As Amended) 1974 15.2 CHEMICAL SAFETY ASSESSMENT A chemical safety assessment has not been carried out for the substance or the mixture by the supplier. SECTION 16: OTHER INFORMATION This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010 This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010 Abbreviations and acronyms used in the safety data sheet ADR: European Agreement concerning the International Transport of Dangerous Goods by Road RID: Regulations concerning the International Transport of Dangerous Goods by Rail IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association ICAO: International Civil Aviation Organisation GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service DNEL: Derived No Effect Level (REACH) PNEC: Predicted No Effect Concentration (REACH) LC50: Lethal Concentration 50 percent LD50: Lethal Dose: Lethal Dose 50% Information Sources Dangerous Properties of Industrial Materials Report, N.Sax et al. LEGAL DISCLAIMER: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.


NORCROS EPOXY CURING AGENT (PART B)


1.1 PRODUCT IDENTIFIER: Norcros Super Epoxy Grout – Curing Agent – Part B 1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST: Intended use: PC1 Epoxy resin grout for ceramic wall and floor tiling 1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET: NORCROS ADHESIVES Harewood Street Tunstall Stoke on Trent Staffordshire ST6 5JZ Tel: 01782 524 140 Fax: 01782 524141 E-mail: [email protected] 1.4 EMERGENCY TELEPHONE NUMBER: 44 (0) 1782 524 140 SECTION 2: HAZARDS IDENTIFICATION 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: CLASSIFICATION UNDER CLP Acute Tox. 4: H302 Aquatic Chronic 2: H411 Repr. 2: H361fd Skin Corr 1B. H314 Skin Sens. 1: H317 MOST IMPORTAND ADVERSE EFFECTS: Harmful if swallowed Causes severe skin burns and eye damage May cause an allergic skin reaction Suspected of damaging fertility Suspected of damaging the unborn child Toxic to aquatic life with long lasting effects


2.2 LABEL ELEMENTS: HAZARD STATEMENTS: H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H361fd Suspected of damaging fertility. Suspected of damaging

the unborn child H411 Toxic to aquatic life with long lasting efects

SIGNAL WORDS: Danger HAZARD PICTOGRAMS GHS05: Corrosion GHS07: Exclamation mark GHS08: Health Hazard GHS09: Environmental

PRECAUTIONARY STATEMENTS PREVENTION: P260: Do not breathe dust/fumes/gas/mist/vapours/spray P280: Wear protective gloves/protective clothing/eye protection/face protection P301 + 312: If swallowed call a poison centre/doctor if you feel unwell P301 + 330 + 331: If swallowed rinse mouth. Do not induce vomiting P302 + 352: If on skin wash with plenty of water P303 + 361 + 353: If on skin (or hair) remove all contaminated clothing immediately. Rinse

skin with water/ shower 2.3 OTHER HAZARDS PBT: This product is not identified as a PBT/ vPvB substance


SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2 MIXTURES: HAZARDOUS INGREDIENTS: Benzyl Alcohol


202-859-9 100-51-6 - Acute Tox 4: H332 Acute Tox.4: H302

10-30%

4-Tert-Butylphenol


202-679-0 98-54-4 - Repr. 2: H361f Skin Irrit. 2: H315 Eye Dam. 1: H318

1-10%

4-Nonylphenol, Branched


284-325-5 84852-15-3 - Repr. 2: H361fd Acute Tox. 4: H302 Skin Corr. 1B: H314 Aquatic Chronic 1: H410 Aquatic Acute 1: H400

1-10%

Trimethylexane-1, 6-Diamine


247-134-8 25620-58-0 - Skin Corr. 1B: H314 Aquatic Acute 1: H400

1-10%

3,6,9- Triazaundecamethylenediamine


203-986-2 112-57-2 - Acute Tox. 4: H312 Acute Tox. 4 H302 Skin Corr. 1B: H314 Skin Sens. 1: H317 Aquatic Chronic 2: H411

1-10%

The full text for all R-Phrases and Hazard Statements are displayed in Section 2.


SECTION 4: FIRST AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES AFTER INHALATION: Move affected personnel into fresh air ensuring one’s own safety. Consult a

doctor AFTER INGESTION: Immediately rinse mouth and drink plenty of water. Do not induce vomiting Transfer to hospital as soon as possible AFTER CONTACT Wash off promptly and flush contaminated skin with water WITH SKIN Promptly remove clothing if soaked through and flush with water. Seek medical attention if discomfort continues AFTER CONTACT Make sure that any contact lenses are removed before rinsing opened eye WITH EYES: using plenty of clean water for at least 15 minutes. Seek medical attention if discomfort persists. 4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED General Information The severity of the symptoms described will vary dependent of the concentration and length of Exposure INHALATION Absorption through the lungs can occur causing symptoms similar to those of

ingestion. INGESTION: There may be soreness and redness of the mouth and throat. There may be

difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting. SKIN CONTACT: Prolonged skin contact may cause redness and irritation. EYE CONTACT: There may be irritation and redness Delayed/ immediate effects: Immediate effects can be expected after short-term exposure 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED Not applicable SECTION 5: FIRE FIGHTING MEASURES 5.1 EXTINGUISHING MEDIA Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE Hazardous combustion products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours 5.3 ADVICE FOR FIRE FIGHTERS Special Fire Fighting Procedures Containers close to fire should be removed or cooled with water Wear full protective clothing to prevent contact with skin and eyes. Wear self-contained breating apparatus.


SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES Personal precautions: Refer to section 8 of SDS. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid. 6.2 ENVIRONMENTAL PRECAUTIONS Avoid material entering drains or water courses or onto the ground. Contain spillage using bunding. 6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP Absorb in vermiculite, dry sand or earth and place into containers. Shovel into dry containers. Cover and move the containers. Flush the area with water. Dispose of by an appropriate method 6.4 REFERENCE TO OTHER SECTIONS Sections 8 and 13 should be referred to. See section 11 for additional information on health hazards SECTION 7: HANDLING AND STORAGE 7.1 PRECAUTIONS FOR SAFE HANDLING Avoid the formation or spread of mists in the air. Avoid direct contact with the substance. Suspected cancer causing nitrosamines could be formed. Emergency showers and eye wash stations should be readily accessible. Adhere to work practice rules established by government regulations. Use only in well-ventilated areas. Use personal protective equipment. 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIEs Store in tightly closed original containers Store in dry, well ventilated areas at temperatures of 5 – 32

oC

Protect from frost and damp conditions Do not store in reactive metal containers. 7.3 SPECIFIC END USE(S) The identified uses for this product are detailed in Section 1.2 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 CONTOL PARAMETERS Workplace Exposure Limits (WEL): No data available. DNEL/ PNEC: No data available.


8.2 EXPOSURE CONTROLS ENGINEERING MEASURES: Provide readily accessible eyewash stations and safety showers. Provide natural or explosive-proof ventilation adequate to ensure

concentrations are kept below exposure limits. RESPIRATORY EQUIPMENT: If ventilation is insufficient, suitable respiratory protection must

be provided

HAND PROTECTION: The most suitable gloves must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material

EYE PROTECTION: Safety glasses. Ensure eye bath is to hand. SKIN PROTECTION: Protective clothing. HYGIENE MEASURES: DO NOT SMOKE IN WORK AREA. Wash at the end of each work

shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES STATE: Liquid COLOUR: Yellow-orange ODOUR: Irritating odour VISCOSITY: Non-viscous Boiling point/range

oC: >200

Flash point

oC: >150

Relative density: 0.99 pH: >8 9.2 OTHER INFORMATION No data available


SECTION 10: STABILITY AND REACTIVITY 10.1 REACTIVITY Stable under recommended transport or storage conditions 10.2 CHEMICAL STABILITY Stable under normal temperature conditions and recommended use 10.3 POSSIBILITY OF HAZARDOUS REACTION Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below. 10.4 CONDITIONS TO AVOID Heat 10.5 INCOMPATIBLE MATERIALS Strong oxidising agents. Strong acids. 10.6 HAZARDOUS DECOMPOSITION PRODUCTS Haz. Decomp. Products: In combustion emits toxic fumes. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 INFORMATION ON TOXICOLOGICAL EFFECTS HAZARDOUS INGREDIENTS: Benzyl Alcohol

IVN RAT LD50 53 mg/kg

ORL MUS LD50 1,360 mg/kg


4-Nonylphenol, Branched


SKN RBT LDLO 3,160 mg/kg

3,6,9-Triazaundecamethylenediamine

IPR RAT LD50 205 mg/kg

IVN MUS LD50 320 mg/kg


RELEVANT HAZARDS FOR SUBSTANCE:

Hazard Route Basis

Acute toxicity (ac.tox. 4) ING Hazardous: calculated

Skin corrosion/irritation DRM Hazardous: calculated

Serious eye damage/irritation OPT Hazardous: calculated

Respiratory/skin sensitisation DRM Hazardous: calculated

Reproductive toxicity - Hazardous: calculated


SYMPTOMS/ROUTES OF EXPOSURE SKIN CONTACT: There may be mild irritation at the site of contact EYE CONTACT: There may be irritation and redness INGESTION: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting. INHALATION: Absorption through the lungs can occur causing symptoms similar to those of ingestion. DELAYED/IMMEDIATE Immediate effects can be expected after short-term exposure. EFFECTS: SECTION 12: ECOLOGICAL INFORMATION 12.1 TOXICITY Ecotoxicity values: No data available. 12.2 PERSISTANCE AND DEGRADABILITY Biodegradable. 12.3 BIOACCUMULATIVE POTENTIAL No bioaccumulation potential. 12.4 MOBILITY IN SOIL Readily absorbed into soil. 12.5 RESULTS OF PBT AND vPvB ASSESSMENT This product does not contain any PBT or vPvB substances 12.6 OTHER ADVERSE EFFECTS Negligible ecotoxicity SECTION 13: DISPOSAL CONSIDERATIONS In accordance with local authority regulations 13.1 WASTE TREATMENT METHODS DISPOSAL OPERATIONS: Transfer to a suitable complete container and arrange for collection by

specialised disposal company. N.B. The user’s attention is drawn to the possible existence of regional or national regulations regarding disposal.


SECTION 14 TRANSPORT INFORMATION 14.1 UN NUMBER UN No. ) UN2735 14.2 UN PROPER SHIPPING NAME Polyamines, Liquid, Corrosive, N.O.S. 14.3 TRANSPORT HAZARD CLASS(ES) Transport Class: 8 Transport Labels:

14.4 PACKING GROUP Packing Group: II 14.5 ENVIRONMENTAL HAZARDS Environmentally Hazardous Substances Marine Pollutant

14.6 SPECIAL PRECAUTIONS FOR USER SPECIAL PRECAUTIONS: No special precautions. TUNNEL CODE: E TRANSPORT CATEGORY: 2 14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE


SECTION 15: REGULATORY INFORMATION 15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATIONS SPECIFIC FOR THE SUBSTANCE OR MIXTURE PHRASES USED IN s.2 and S.3: H302: Harmful if swallowed H312: Harmful in contact with skin H314: Causes severe skin burns and eye damage H315: Causes skin irritation H317: May cause an allergic skin reaction H318: Causes serious eye damage H332: Harmful if inhaled H361f: Suspected of damaging fertility H361fd: Suspected of damaging fertility. Suspected of damaging the unborn child H410: Very toxic to aquatic life with long lasting effects H411: Toxic to aquatic life with long lasting effects The Control of Substance Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716) Approved Code of Practice Safety Data Sheets for Substances and Preparations Guidance Notes Workplace Exposure Limits EH40 EU Legislation Dangerous Substance Directive 67/548/EEC National Regulations Workplace Exposure Limits 2005 (EH40) 15.2 CHEMICAL SAFETY ASSESSMENT A chemical safety assessment has not been carried out for the substance or the mixture by the supplier. SECTION 16: OTHER INFORMATION This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010 This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010 Abbreviations and acronyms used in the safety data sheet ADR: European Agreement concerning the International Transport of Dangerous Goods by Road RID: Regulations concerning the International Transport of Dangerous Goods by Rail IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association ICAO: International Civil Aviation Organisation GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service DNEL: Derived No Effect Level (REACH) PNEC: Predicted No Effect Concentration (REACH) LC50: Lethal Concentration 50 percent LD50: Lethal Dose: Lethal Dose 50%


Information Sources Dangerous Properties of Industrial Materials Report, N.Sax et al. LEGAL DISCLAIMER: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.


MATERIAL SAFETY DATA SHEET

NORCROS EPOXY GROUT FILLER BLEND (PART C)


1.1 PRODUCT IDENTIFIER: Norcros Super Epoxy Grout – Filler Blend 1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST: Intended use: PC1 Epoxy resin grout for ceramic wall and floor tiling 1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET: NORCROS ADHESIVES Harewood Street Tunstall Stoke on Trent Staffordshire ST6 5JZ Tel: 01782 524 140 Fax: 01782 524141 E-mail: [email protected] 1.4 EMERGENCY TELEPHONE NUMBER: 44 (0) 1782 524 140 SECTION 2: HAZARDS IDENTIFICATION 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE CLASSIFICATION UNDER CLP: 2.2 LABEL ELEMENTS HAZARD STATEMENTS H372: Causes damage to organs through prolonged or repeated exposure by inhalation. SIGNAL WORDS: Danger HAZARD PICTOGRAMS:

GHS08

PRECAUTIONARY STATEMENT(s) P260: Do not breathe dust P264: Wash hands and exposed skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P314: Get medical advice/ Attention if you feel unwell. P501: Dispose of contents in accordance with local, state or national legislation.


2.3 OTHER HAZARDS PBT: This product is not identified as a PBT/ vPvB substance SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2 MIXTURES: HAZARDOUS INGREDIENTS:

HAZARDOUS INGREDIENT(S)

CAS No. EC No./ REACH No.

%W/W

HAZARD STATEMENT(S)

HAZARD PICTOGRAM(S)

Calcium Carbonate

471-34-1 207-439-9 65-85 Not classified

Cristobalite 14464-46-1 238-455-4 15-35 STOT RE 1 H372 GHS08

The full text for all R-Phrases and Hazard Statements are displayed in Section 2. SECTION 4: FIRST AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES AFTER INHALATION: Seek medical advice if you feel unwell AFTER INGESTION: Immediately rinse mouth and drink plenty of water. Do not induce vomiting Seek medical advice if you feel unwell. AFTER CONTACT Wash off skin with water WITH SKIN Seek medical advice if you feel unwell. AFTER CONTACT Make sure that any contact lenses are removed before rinsing opened eye WITH EYES: using plenty of clean water for at least 15 minutes. Seek medical attention if discomfort persists. 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED Get medical advice/attention if you feel unwell. Treat symptomatically. SECTION 5: FIRE FIGHTING MEASURES 5.1 EXTINGUISHING MEDIA Suitable extinguishing media for the surrounding fire should be used. Unsuitable extinguishing media: none 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE May decompose in a fire giving off toxic fumes. 5.3 ADVICE FOR FIRE FIGHTERS Wear full protective clothing to prevent contact with skin and eyes. Wear self-contained breating apparatus.


SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES Provide adequate ventilation. Avoid dust generation Do not breathe dust Wear suitable protective clothing, gloves and eye/face protection. 6.2 ENVIRONMENTAL PRECAUTIONS The material and its container must be disposed of in a safe way. 6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP Sweep up spilled substance and remove to safe place. Use vacuum equipment for collecting spilt materials, where practicable. 6.4 REFERENCE TO OTHER SECTIONS Sections 8 and 13 should be referred to. See section 11 for additional information on health hazards SECTION 7: HANDLING AND STORAGE 7.1 PRECAUTIONS FOR SAFE HANDLING Wash hands and exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIEs Storage temperature: Ambient Storage life: Stable under normal conditions. Incompatible materials: None known. 7.3 SPECIFIC END USE(S) The identified uses for this product are detailed in Section 1.2 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 CONTOL PARAMETERS OCCUPATIONAL EXPOSURE Limits

Occupational Exposure Limits

Substance

CAS No.

LTEL (8hr TWA ppm)

LTEL (8hr TWA mg/m

3)

STEL (ppm)

STEL (mg/m

3)

Note

Refractory ceramic fibresand special purpose fibres

14464-46-1 0 5 0 0 Carc, (l)

Silica, respirable crystalline

14464-46-1 0 0.1 0 0 -

Region Source

Europe EU Occupational Exposure Limits

United Kingdom Workplace Exposure Limits (WEL)


Remark Notes

Carc (l) Capable of causing cancer and/or heritable genetic damage. See EH40 paragraphs 49-51. 5mg/m

3 (1 fibres/ millilitre

8.2 EXPOSURE CONTROLS ENGINEERING MEASURES: Use with ventilation, local exhaust ventilation or breathing

protection RESPIRATORY EQUIPMENT: If ventilation is insufficient, suitable respiratory protection must

be provided

HAND PROTECTION: Wear appropriate clothing and gloves: Impervious gloves (EN 374)

EYE PROTECTION: Safety glasses with side protection (EN 166). Ensure eye bath is to hand.

SKIN PROTECTION: Wear protective clothing. HYGIENE MEASURES: DO NOT SMOKE IN WORK AREA. Wash at the end of each work

shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke.

ENVIRONMENTAL EXPOSURE: Avoid release to the environment.


SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Solid Colour: Not known Odour: Odourless Odour Threshold: Not known pH: Not known Melting point/Freezing Not known Point: Initial boiling point and Not applicable Boiling range: Flash Point: Not applicable Evaporation rate: Not known Flammability (solid, gas): Not known Upper/ lowe rflammability or Not known Explosive limits: Vapour pressure: Not known Vapour density: Not known Density (g/ml) Not known Relative density: Not known Solubility(ies): Water: Negligible Other: Hydrofluoric acid Partition coefficient:n- Not known Octanol/water Auto-ignition temperature: Not known Decomposition Temperature Not known (

oC):

Viscosity: Not known Explosive properties: Not known Oxidising properties: Not known 9.2 OTHER INFORMATION No data available SECTION 10: STABILITY AND REACTIVITY 10.1 REACTIVITY Stable under recommended transport or storage conditions 10.2 CHEMICAL STABILITY Stable under normal temperature conditions and recommended use 10.3 POSSIBILITY OF HAZARDOUS REACTION Hazardous reactions will not occur under normal transport or storage conditions. 10.4 CONDITIONS TO AVOID None anticipated 10.5 INCOMPATIBLE MATERIALS Not known 10.6 HAZARDOUS DECOMPOSITION PRODUCTS No hazardous decomposition products known..


SECTION 11: TOXICOLOGICAL INFORMATION 11.1 INFORMATION ON TOXICOLOGICAL EFFECTS Acute toxicity – Ingestion: Low acute toxicity Acute toxicity – Skin Contact: Low acute toxicity Acute toxicity – Inhalation: Low acute toxicity Skin corrosion/irritation: Non-irritant Serious eye damage/irritation: Non-irritant Skin sensitisation data: Not classified Respiratory sensitisation data: Not classified Germ cell mutagenicity: There is no evidence of mutagenic potential Carcinogenicity: No evidence of carcinogenicity Reproductive toxicity: Not classified Lactation: Not classified STOT – single exposure: Not classified STO – repeated exposure: Self classification: causes damage to organs through

prolonged or repeated exposure by inhalation. Aspiration hazard: Not classified SECTION 12: ECOLOGICAL INFORMATION 12.1 TOXICITY Aquatic invertebrates: Low toxicity to invertebrates Fish: Low toxicity to fish Algae: Low toxicity to algae Sediment Compartment: Not classified Terrestrial Compartment: Not classified 12.2 PERSISTANCE AND DEGRADABILITY Not known 12.3 BIOACCUMULATIVE POTENTIAL Not known 12.4 MOBILITY IN SOIL Not known 12.5 RESULTS OF PBT AND vPvB ASSESSMENT Not known 12.6 OTHER ADVERSE EFFECTS Not known


SECTION 13: DISPOSAL CONSIDERATIONS In accordance with local authority regulations SECTION 14 TRANSPORT INFORMATION Not classified as hazardous for transport SECTION 15: REGULATORY INFORMATION 15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATIONS SPECIFIC FOR THE SUBSTANCE OR MIXTURE The Control of Substance Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716) Approved Code of Practice Safety Data Sheets for Substances and Preparations Guidance Notes Workplace Exposure Limits EH40 EU Legislation Dangerous Substance Directive 67/548/EEC National Regulations Workplace Exposure Limits 2005 (EH40) 15.2 CHEMICAL SAFETY ASSESSMENT A chemical safety assessment has not been carried out for the substance or the mixture by the supplier. SECTION 16: OTHER INFORMATION This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010 This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010 Abbreviations and acronyms used in the safety data sheet ADR: European Agreement concerning the International Transport of Dangerous Goods by Road RID: Regulations concerning the International Transport of Dangerous Goods by Rail IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association ICAO: International Civil Aviation Organisation GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service DNEL: Derived No Effect Level (REACH) PNEC: Predicted No Effect Concentration (REACH) LC50: Lethal Concentration 50 percent LD50: Lethal Dose: Lethal Dose 50% Information Sources Dangerous Properties of Industrial Materials Report, N.Sax et al. LEGAL DISCLAIMER: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

MATERIAL SAFETY DATA SHEET NORCROS EPOXY RESIN …

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