PUBLICATIONS Robert W. Field 1. R. W. Field and T. H ...rwf.mit.edu/group/field_pubs.pdf · 1...

Prof. Robert W. Field's Publication List as of 10 February 2020 MS Word Page #1

PUBLICATIONS Robert W. Field

1. R. W. Field and T. H. Bergeman, “Radio Frequency Spectroscopy and Perturbation Analysis in CS A1∏ (v=0)”, J. Chem. Phys. 54, 2936-2948 (1971). http://dx.doi.org/10.1063/1.1675276

2. B. G. Wicke, R. W.Field, and W. A. Klemperer, “Fine Structure, Dipole Moment, and Perturbation Analysis of a 3∏ CO”, J.

Chem. Phys. 56, 5758-5770 (1972). http://dx.doi.org/10.1063/1.1677113 3. R. W. Field, B. G. Wicke, J. D. Simmons and S. G. Tilford, “Analysis of Perturbations in the a3∏ and A1∏ States of CO”, J.

Mol. Spectrosc. 44, 383-399 (1972). http://dx.doi.org/10.1016/0022-2852(72)90111-7 4. R. W. Field, S. G. Tilford, R. A. Howard, and J. D. Simmons, “Fine Structure and Perturbation Analysis of the a3∏ State of

CO”, J. Mol. Spectrosc. 44, 347-382 (1972). http://dx.doi.org/10.1016/0022-2852(72)90110-5 5. R. W. Field, R. S. Bradford, D. O. Harris, and H. P. Broida, “Microwave Optical Double Resonance Spectroscopy of BaO”,

J. Chem. Phys. 56, 4712-4714 (1972). http://dx.doi.org/10.1063/1.1677923 6. R. W. Field, R. S. Bradford, H. P. Broida, and D. O. Harris, “Excited State Microwave Spectroscopy on the A1∑ State of

BaO”, J. Chem. Phys. 57, 2209-2210 (1972). http://dx.doi.org/10.1063/1.1678554 7. R. W. Field, “The Valence States of NO+”, J. Mol. Spectrosc. 47, 194-203 (1973).

http://dx.doi.org/10.1016/0022-2852(73)90003-9 8. R. W. Field, A. D. English, T. Tanaka, D. O. Harris, and D. A. Jennings, “Microwave Optical Double Resonance

Spectroscopy with a cw Dye Laser: BaO X1∑ and A1∑”, J. Chem. Phys. 59, 2191-2203 (1973). http://dx.doi.org/10.1063/1.1680320

9. T. Tanaka, A. D. English, R. W. Field, D. A. Jennings, and D. O. Harris, “Microwave Optical Double Resonance of NO2

with a Tunable cw Dye Laser”, J. Chem. Phys. 59, 5217-5218 (1973). http://dx.doi.org/10.1063/1.1680749 10. R. W. Field and H. Lefebvre-Brion, “On the Effective Spin-Spin Constants of Some States of Diatomic Molecules.

Application to the CO Molecule”, Acta Hungarica Physica, 35, 51-61 (1974). http://dx.doi.org/10.1007/BF03159741 11. D. O. Harris, R. W. Field, and H. P. Broida, “Microwave Optical Double Resonance Spectroscopy of Metal Oxides”,

Berichte der Bunsengesellschaft für Physikalische Chemie” 78, 146-153 (1974). http://dx.doi.org/10.1002/bbpc.19740780210 12. R. W. Field, “Assignment of the Lowest 3∏ and 1∏ States of CaO, SrO, and BaO”, J. Chem. Phys. 60, 2400-2413 (1974).

http://dx.doi.org/10.1063/1.1681375 13. R. W. Field, C. R. Jones, and H. P. Broida, “Gas-Phase Reaction of Ba with N2O. II. Mechanism of Reaction”, J. Chem.

Phys. 60, 4377-4382 (1974). http://dx.doi.org/10.1063/1.1680914 14. D. O. Harris, R. W. Field, and T. Tanaka, “MODR of NO2 with a Tunable cw Dye Laser. II. Excited State Microwave

Transitions”, J. Chem. Phys. 61, 3401-3407 (1974). http://dx.doi.org/10.1063/1.1682505 15. R. W. Field, G. A. Capelle, and C. R. Jones, “The A′1∏ – X1∑ System of CaO”, J. Mol. Spectrosc. 54, 156-159 (1975).

http://dx.doi.org/10.1016/0022-2852(75)90017-X 16. R. W. Field, T. Tanaka, and D. O. Harris, “CW Dye Laser Excitation Spectroscopy: CaF A2∏r – X2∑+”, J. Mol. Spectrosc.

57, 107-117 (1975). http://dx.doi.org/10.1016/0022-2852(75)90045-4 17. B. G. Wicke, W. A. Klemperer, and R. W. Field, “Lambda Doublings and electric dipole moments of v = 6 and 7 a 3∏

carbon monoxide”, J. Chem. Phys. 62, 3544-3545 (1975). http://dx.doi.org/10.1063/1.430999 18. R. W. Field, Book Review: A Dictionary of Spectroscopy by R.C. Denney, J. Am. Chem. Soc. 98: 5, 1299 (1976).

http://dx.doi.org/10.1021/ja00421a600


19. R. W. Field, M. Revelli, and G. A. Capelle, “Optical-Optical Double Resonance Laser Spectroscopy of BaO”, J. Chem. Phys. 63, 3228-3237 (1975). http://dx.doi.org/10.1063/1.431813

20. R. W. Field, O. Benoist d'Azy, M. Lavollée, R. Lopez-Delgado, and A. Tramer, “Radiative Decay Rates from Deperturbed v

= 0-7 Vibrational Levels of CO A1∏ Measured Using Synchrotron Radiation”, J. Chem. Phys. 78, 2838-2846 (1983). http://dx.doi.org/10.1063/1.445271

21. G. A. Capelle, R. W. Field, and H. P. Broida, “Photon yields of Several Reactions Producing Diatomic Strontium Oxide and

Halides, and SrO(A′ 1∏–X1∑): A New Band System”, J. Chem. Phys. 62, 3131-3136 (1975). http://dx.doi.org/10.1063/1.430859

22. T. Tanaka, R. W. Field, and D. O. Harris, “Microwave Optical Double Resonance and CW Dye Laser Excitation

Spectroscopy of NO2. Rotational Assignment of the K = 0-4 Subbands of the 593 nm Band”, J. Mol. Spectrosc. 56, 188-199 (1975). http://dx.doi.org/10.1016/0022-2852(75)90234-9

23. R. W. Field, C. R. Jones, and H. P. Broida, “Reply to Comment by D. Husain and J. R. Wiesenfeld on 'Gas Phase Reaction of

Ba with N2O. II. Mechanism of Reaction' [J. Chem. Phys. 60, 4377 (1974) http://dx.doi.org/10.1063/1.1680914]”, J. Chem. Phys. 62, 2012-2013 (1975). http://dx.doi.org/10.1063/1.430662

24. R. W. Field, “Long-Lived, Energetic Products of Chemical Reactions: Ba + N2O, A Case Study”, Molecular Spectroscopy:

Modern Research, Volume II, K.N. Rao (editor), pp. 261-274, Academic Press (1976). 25. R. W. Field, R. A. Gottscho and E. Miescher, “Observed and Calculated Interactions between Valence States of the NO

Molecule”, J. Mol. Spectrosc. 58, 394-413 (1975). http://dx.doi.org/10.1016/0022-2852(75)90220-9 26. T. Ikeda, N. B. Wong, D. O. Harris, and R. W. Field, “Argon Ion and Dye Laser Induced MgO B1∑+–X1∑+ and B1∑+–A1∏

Photoluminescence Spectra Analysis of a3∏1 ~ X1∑+ Perturbations”, J. Mol. Spectrosc. 68, 452-487 (1977). http://dx.doi.org/10.1016/0022-2852(77)90247-8

27. R. A. Gottscho, J. B. Koffend, J. R. Lombardi, and R. W. Field, “Optical-Optical Double Resonance Laser Spectroscopy of

BaO. II. New Observations of a3∏ and A′1∏ and Re-examination of the Parkinson Band System”, J. Chem. Phys. 68, 4110-4122 (1978). http://dx.doi.org/10.1063/1.436325

28. T. A. Miller, R. S. Freund and R. W. Field, “The Identification and Characterization of the 4∑+ State of CN”, J. Chem. Phys.

65, 3790-3792 (1976). http://dx.doi.org/10.1063/1.433569 29. R. W. Field, A. Lagerqvist, and I. Renhorn, “A Perturbation Study of the Low Lying SiO Electronic States”, J. Chem. Phys.

66, 868-869 (1977). http://dx.doi.org/10.1063/1.433922 30. R. A. Gottscho and R. W. Field, “Assignment of Extra Lines in a Perturbed Band Spectrum Using power Broadened Line

Widths”, Chem. Phys. Lett. 60, 65-68 (1978). http://dx.doi.org/10.1016/0009-2614(78)85711-X 31. J. B. Koffend, R. Bacis, and R. W. Field, “CW Optically Pumped Iodine Laser. Spectroscopy and Long Range Analysis of

the X1∑+g Ground State of I2”, J. Mol. Spectrosc. 77, 202-212 (1979). http://dx.doi.org/10.1016/0022-2852(79)90102-4

32. R. W. Field, A. Lagerqvist, and I. Renhorn, “The Low Lying States of SiO”, Physica Scripta 14, 298-319 (1976).

http://dx.doi.org/10.1088/0031-8949/14/6/010 33. a) J. R. Lombardi, J. B. Koffend, R. A. Gottscho, and R. W. Field, “Laser Induced Phosphorescence in Gas Phase

Thiophosgene”, J. Mol. Spectrosc. 65, 446-454 (1977). http://dx.doi.org/10.1016/0022-2852(77)90284-3 b) P. F. Bernath, P. G. Cummins, J. R. Lombardi, and R. W. Field, “The Excitation Spectrum of Gas Phase Thiophosgene”, J.

Mol. Spectrosc. 69, 166-167 (1977). http://dx.doi.org/10.1016/0022-2852(78)90036-X 34. K. A. Dick, W. Benesch, H. M. Crosswhite, S. G. Tilford, R. A. Gottscho, and R. W. Field, “High Resolution Spectra of

Bands of the First Negative Group of Ionized Molecular Nitrogen (N+21NG: B2∑+

u→ X2∑+g)”, J. Mol. Spectrosc. 69, 95-108

(1978). http://dx.doi.org/10.1016/0022-2852(78)90031-0


35. a) J. B. Koffend and R. W. Field, “CW Optically Pumped Molecular Iodine Laser”, J. Appl. Phys. 48, 4468-4472 (1977).

http://dx.doi.org/10.1063/1.323457 b) J. B. Koffend, F. J. Wodarczyk, and R. W. Field, pp. 96-109, High Power Lasers and Applications, K.L. Kompa and H.

Walther (editors), Springer Verlag, 1978. 36. J. B. Koffend, R. W. Field, D. R. Guyer, and S. R. Leone, “Pulsed and CW Optically Pumped Lasers for Novel Applications

in Spectroscopy and Kinetics”, pp. 382-393, Laser Spectroscopy III, J. L. Hall and J. L. Carlsten (editors), Springer Verlag, 1977.

37. I. P. Herman, A. Javan, and R. W. Field, “Observation of Infrared-Optical Double Resonance in NO2”, J. Chem. Phys. 68,

2398-2405 (1978). http://dx.doi.org/10.1063/1.436010 38. R. W. Field, “Transitions Near Dissociation Limits by Optical Optical Double Resonance and Optically Pumped Laser

Spectroscopy”, pp. 143-155, Etats Atomiques et Moléculaires Couplés a un Continuum. Atomes et Molécules Hautement Excités, Editions du CNRS No. 273 (1977).

39. R. A. Gottscho, R. W. Field, and H. Lefebvre-Brion, “Ab Initio and Semiempirical Estimates of PN Valence State

Interactions”, J. Mol. Spectrosc. 70, 420-431 (1978). http://dx.doi.org/10.1016/0022-2852(78)90180-7 40. R. A. Gottscho, R. W. Field, K. A. Dick, and W. Benesch, “Deperturbation of the N+

2 First Negative Group B2∑+g - X2∑+

g”, J. Mol. Spectrosc. 74, 435-455 (1979). http://dx.doi.org/10.1016/0022-2852(79)90166-8

41. J. B. Koffend, S. Goldstein, R. Bacis, R. W. Field, and S. Ezekiel, “Doppler-Free Emission Spectroscopy and Secondary

Frequency Standards Using an Optically Pumped Laser”, Phys. Rev. Lett. 41, 1040-1045 (1978). http://dx.doi.org/10.1103/PhysRevLett.41.1040

42. J. B. Koffend, R. Bacis and R. W. Field, “The Electronic Transition Moment of the B0+

u– X1∑+gSystem of I2 Through Gain

Measurements of an I2 Optically Pumped Laser”, J. Chem. Phys. 70, 2366-2372 (1979). http://dx.doi.org/10.1063/1.437744 43. R. W. Field, R. A. Gottscho, J. G. Pruett, and J. J. Reuther, “Barium Oxide: The Questions Unanswered”, pp. 39-59,

Proceedings 14th International Conference on Free Radicals (Eds. Y. Morino, I. Tanaka, and E. Hirota), Sanda, Japan, Yamada Science Foundation, Osaka.

44. J. B. Koffend, R. Bacis, and R. W. Field, “Stimulated Emission Spectroscopy with an Optically Pumped I2 Laser”, Proc. Int.

Conf. Lasers, 168, 240-251 (1979). A1* . R. W. Field, “Tunable Laser Spectroscopy”, Coherent Focus on Science 1, no. 2 (1977). 45. A. J. Kotlar, R. W. Field, J. I. Steinfeld, and J. A. Coxon, “Analysis of Perburbations in the A2∏ – X2∑+ 'Red' System of

CN”, J. Mol. Spectrosc. 80, 86-108 (1980). http://dx.doi.org/10.1016/0022-2852(80)90272-6 46. C. Linton, M. Dulick, and R. W. Field, “Laser Spectroscopy of CeO. Fluorescence of the C1 – X1 and D3 – X3 Systems”, J.

Mol. Spectrosc. 78, 428-436 (1979). http://dx.doi.org/10.1016/0022-2852(79)90069-9 47. M. Dulick, R. W. Field, and J. Cl. Beaufils, “On the Hyperfine Structure of the 0-0 Band in the PrO XVII System”, J. Mol.

Spectrosc. 78, 333-334 (1979). http://dx.doi.org/10.1016/0022-2852(79)90011-0 48. J. B. Koffend, F. J. Wodarczyk, R. Bacis, and R. W. Field, “Collisional Relaxation of Highly Excited Vibrational Levels of

the I2 X1∑+g State Using an I2 Optically Pumped Laser”, J. Chem. Phys. 72, 478-483 (1980).

http://dx.doi.org/10.1063/1.438874 49. P. F. Bernath and R. W. Field, “Optical-Optical Double-Resonance Spectroscopy of CaF: The E2∑+ and E′2∏ States”, J.

Mol. Spectrosc. 82, 339-347 (1980). http://dx.doi.org/10.1016/0022-2852(80)90119-8 * Application Note.


50. R. A. Gottscho, P. S. Weiss, R. W. Field, and J. G. Pruett, “Sub-Doppler Optical-Optical Double-Resonance Spectroscopy of BaO. Electronic Structure in the 4-eV Region”, J. Mol. Spectrosc. 82, 283-309 (1980). http://dx.doi.org/10.1016/0022-2852(80)90117-4

51. R. A. Gottscho, J. B. Koffend, and R. W. Field, “Optical-Optical Double-Resonance Spectroscopy of BaO. The Low Lying

States”, J. Mol. Spectrosc. 82, 310-338 (1980). http://dx.doi.org/10.1016/0022-2852(80)90118-6 52. R. Bacis, S. Churassy, R. W. Field, J. B. Koffend, and J. Vergés, “High Resolution and Sub-Doppler Fourier Transform

Spectroscopy: Iodine Molecular Fluorescence Excited by the 514.5 and 501.7 nm Ar+ Laser Lines”, J. Chem. Phys. 72, 34-42 (1980). http://dx.doi.org/10.1063/1.438855

53. R. A. Gottscho, R. W. Field, R. Bacis, and S. J. Silvers, “Simultaneous Measurement of Rotational and Translational

Relaxation by Sub-Doppler Optical-Optical Double Resonance Spectroscopy: BaO(A1∑+)–Ar and BaO(A1∑+)–CO2”, J. Chem. Phys. 73, 599-611 (1980). http://dx.doi.org/10.1063/1.440159

54. S. J. Silvers, R. W. Field, and R. A. Gottscho, “Collisional Depolarization of State Selected (J,MJ) BaO A 1∑+ Measured by

Optical-Optical Double Resonance”, J. Chem. Phys. 74, 6000-6008 (1981). http://dx.doi.org/10.1063/1.441039 55. M. Dulick, P. F. Bernath, and R. W. Field, “Rotational and Vibrational Analysis of the CaF B2∑+ – X2∑+ System”, Can. J.

Phys. 58, 703-712 (1980). http://dx.doi.org/10.1139/p80-096 56. P. Bernath, R. W. Field, B. Pinchemel, Y. Lefebvre, and J. Schamps, “Laser Spectroscopy of CaBr: A2∏ – X2∑+ and B2∑+

– X2∑+ Systems”, J. Mol. Spectrosc. 88, 175-193 (1981). http://dx.doi.org/10.1016/0022-2852(81)90362-3 57. P. F. Bernath, M. Dulick, R. W. Field, and J. Hardwick, “Laser Excited Fluorescence of CS2”, J. Mol. Spectrosc. 86, 275-285

(1981). http://dx.doi.org/10.1016/0022-2852(81)90280-0 58. C. Linton, M. Dulick, R. W. Field, P. Carette, and R. F. Barrow, “Low Lying Electronic States of CeO”, J. Chem. Phys. 74,

189-191 (1981). http://dx.doi.org/10.1063/1.440870 59. P. C. F. Ip, P. F. Bernath, and R. W. Field, “Optical-Optical Double-Resonance Spectroscopy of BaF: The E2∑+ and F2∏

States”, J. Mol. Spectrosc. 89, 53-61 (1981). http://dx.doi.org/10.1016/0022-2852(81)90159-4 60. O. Appelblad, A. Lagerqvist, I. Renhorn, and R. W. Field, “The Spectrum of CuO: Low Lying Electronic States Observed

by Laser Induced Fluorescence”, Physica Scripta 22, 603-608 (1980). http://dx.doi.org/10.1088/0031-8949/22/6/010 61. P. F. Bernath, P. G. Cummins, and R. W. Field, “Intermodulated Fluorescence Spectroscopy of CaF A2∏ – X2∑+”, Chem.

Phys. Lett. 70, 618-620 (1980). http://dx.doi.org/10.1016/0009-2614(80)80138-2 62. M. Dulick, R. W. Field, and J. Cl. Beaufils, “Rotational and Hyperfine Analysis of the 0, 0 Band of the PrO XX System”, J.

Mol. Spectrosc. 87, 268-277 (1981). http://dx.doi.org/10.1016/0022-2852(81)90094-1 63. M. Dulick, R. W. Field, J. Cl. Beaufils, and J. Schamps, “The Electronic Spectrum of PrO. Energy Linkages, Rotational

Analysis, and Hyperfine Structure for Systems XVII and XXI”, J. Mol. Spectrosc. 87, 278-288 (1981). http://dx.doi.org/10.1016/0022-2852(81)90095-3

64. P. F. Bernath, B. Pinchemel, R. W. Field, K. Möller and T. Törring, “Combined Fitting of Optical and Millimeter Wave

Data: The Linked A2∏ – X2∑+ and B2∑+ – X2∑+ Systems of Ca79Br and Ca81Br”, J. Mol. Spectrosc. 88, 420-423 (1981). http://dx.doi.org/10.1016/0022-2852(81)90191-0

65. D. E. Reisner, P. F. Bernath, and R. W. Field, “Vibration-Rotation and Deperturbation Analysis of the A2∏ – X2∑+ and

B2∑+ – X2∑+ Systems of the CaI Molecule”, J. Mol. Spectrosc. 89, 107-124 (1981). http://dx.doi.org/10.1016/0022-2852(81)90163-6

66. S. Churassy, F. Martin, R. Bacis, J. Vergès, and R. Field, “Rotation-Vibration Analysis of B 0+

u– a 1g and B 0+u– a′ 0+

gElectronic Systems of I2 by Laser-Induced-Fluorescence Fourier-Transform Spectroscopy”, J. Chem. Phys. 75, 4863-4868 (1981). http://dx.doi.org/10.1063/1.441923


67. P. F. Bernath, B. Pinchemel, and R. W. Field, “The Hyperfine Structure of the Calcium Monohalides”, J. Chem. Phys. 74, 5508-5515 (1981). http://dx.doi.org/10.1063/1.440957

68. S. M. Harris, R. A. Gottscho, R. W. Field, and R. F. Barrow, “Valence Sttes of the SiS Molecule: Analysis of (d3∆1, e3∑–,

C1∑–, D1∆) Perturbations in the A1∏–X1∑+ System”, J. Mol. Spectrosc. 91, 35-59 (1982). http://dx.doi.org/10.1016/0022-2852(82)90029-7

69. R. W. Field, “Tunable Laser Electronic Spectroscopy”, Faraday Disc. Am. Chem. Soc. 71, 111-123 (1981).

http://dx.doi.org/10.1039/DC9817100111 70. P. G. Cummins, R. W. Field, and I. Renhorn, “Argon Ion Laser-Induced BaS B1∑+ – A1∑+, A′1∏, a3∏, and X1∑+

Photoluminescence Spectra: Analysis of A~A′ and A~a, and A′ ~a Perturbations”, J. Mol. Spectrosc. 90, 327-352 (1981). http://dx.doi.org/10.1016/0022-2852(81)90131-4

71. D. Cerny, R. Bacis, R. W. Field, and R. A. McFarlane, “Nitrogen B3∏g ! W3∆u Laser Systems. Assignment and Model for

Observed Lasing Lines”, J. Phys. Chem. 85, 2626-2631 (1981). http://dx.doi.org/10.1021/j150618a012 72. C. Kittrell, E. Abramson, J. L. Kinsey, S. McDonald, D. E. Reisner, D. Katayama, and R. W. Field, “Selective Vibrational

Excitation by Stimulated Emission Pumping”, J. Chem. Phys. 75, 2056-2059 (1981). http://dx.doi.org/10.1063/1.442324 73. H. S. Schweda, G. K. Chawla, and R. W. Field, “Highly Excited, Normally Inaccessible Vibrational Levels by Sub-Doppler

Modulated Gain Spectroscopy: The Na2 A1∑+uState”, Opt. Commun. 42, 165-170 (1982).

http://dx.doi.org/10.1016/0030-4018(82)90131-6 74. a) R. F. Marks, R. A. Gottscho, and R. W. Field, “The CaO D,d 1,3∆ – a3∏ System: Sub-Doppler Spectrum, Rotational

Analysis, and Deperturbation”, Physica Scripta 25, 312-328 (1982). http://dx.doi.org/10.1088/0031-8949/25/2/010 b) R. F. Marks, H. S.Schweda, R. A. Gottscho, and R. W. Field, “The Orange Arc Bands of CaO. Analysis of a

D,d 1,3∆ – a 3∏ System”, J. Chem. Phys. 76, 4689-4691 (1982). http://dx.doi.org/10.1063/1.442784 75. E. Abramson, C. Kittrell, J. L. Kinsey,and R. W. Field, “Excitation Spectroscopy of the Acetylene A~ − X~ Transition in the

220 nm Wavelength Region”, J. Chem. Phys. 76, 2293-2295 (1982). http://dx.doi.org/10.1063/1.443301 76. H. Lefebvre-Brion and R. W. Field, “Perturbations in the Spectra of Diatomic Molecules”, Comm. Atomic and Molec. Phys.

11, 37-44 (1981). 77. C. Linton, M. Dulick, R. W. Field, P. Carette, P. C. Leyland, and R. F. Barrow, “Electronic States of the CeO Molecule:

Absorption, Emission and Laser Spectroscopy”, J. Mol. Spectrosc. 102, 441-497 (1983). http://dx.doi.org/10.1016/0022-2852(83)90053-X

78. B. Pouilly, J. M. Robbe, J. Schamps, L. Young, and R. W. Field, “Perturbations in the A1∏ – X1∑+ System of the BeS

Molecule. The a3∏i State”, J. Mol. Spectrosc. 96, 1-55 (1982). http://dx.doi.org/10.1016/0022-2852(82)90213-2 79. R. W. Field, “Diatomic Molecule Electronic Structure beyond Simple Molecular Constants”, Berichte der Bunsengesellschaft

für Physikalische Chemie 86, 771-779 (1982). http://dx.doi.org/10.1002/bbpc.19820860903 80. F. Martin, S. Churassy, R. Bacis, R. W. Field, and J. Vergès, “Long Range Behavior of the Gerade States Near the 2P3/2 +

2P3/2 Iodine Dissociation Limit by Laser-Induced-Fluorescence Fourier-Transform Spectroscopy”, J. Chem. Phys. 79, 3725-3737 (1983). http://dx.doi.org/10.1063/1.446293

81. D. G. Imre, J. L. Kinsey, R. W. Field, and D. H. Katayama,”Spectroscopic Characterization of Repulsive Potential Energy

Surfaces: Fluorescence Spectrum of Ozone”, J. Phys. Chem. 86, 2564-2566 (1982). http://dx.doi.org/10.1021/j100211a004 82. a) D. E. Reisner, P. H. Vaccaro, C. Kittrell, R. W. Field, J. L. Kinsey and H.-L. Dai, “Selective Vibrational Excitation of

Formaldehyde X~1A1 by Stimulated Emission Pumping”, J. Chem. Phys. 77, 573-575 (1982). http://dx.doi.org/10.1063/1.443596


b) E. Abramson, H.-L. Dai, R. W. Field, D. G. Imre, J. L. Kinsey, C. Kittrell, D. E. Reisner, and P. H. Vaccaro, “Laser Population of Highly Excited Vibrational Levels of Molecules,” Reactants and Probes in Chemistry, W.M. Jackson and A.B. Harvey, eds. pp. 393- 404 Howard University Press, 1985.

c) H.-L. Dai, E. Abramson, R. W. Field, D. Imre, J. L. Kinsey, C. L. Korpa, D. E. Reisner, and P. H. Vaccaro, “Single

Eigenstate Polyatomic Molecule Vibrational Spectroscopy at 1-4eV”, Springer Series Opt. Sci. 40, 74-77, (1983). 83. H. J. Vedder, G. K. Chawla, and R. W. Field, “Observation of the Quasibound Energy Levels and Tunnelling Lifetimes in the

Na2 B1∏u State”, Chem. Phys. Lett. 111, 303-308 (1984). http://dx.doi.org/10.1016/0009-2614(84)85511-6 84. P. H. Vaccaro, J. L. Kinsey, R. W. Field, and H.-L. Dai, “Electric Dipole Moments of Excited Vibrational Levels in the X~1A1

State of Formaldehyde by Stimulated Emission Spectroscopy,” J. Chem. Phys. 78, 3659-3664 (1983). http://dx.doi.org/10.1063/1.445140

85. C. Kittrell, S. Cameron, L. Butler, R. W. Field, and R. F. Barrow, “Two-Photon Excitation of the D 1∆ – X 1∑+ Transition in Carbon Monoxide”, J. Chem. Phys. 78, 3623-3624 (1983). http://dx.doi.org/10.1063/1.445190

86. C. Linton, S. McDonald, S. Rice, M. Dulick, Y. C. Liu, and R. W. Field, “Laser Spectroscopy of YbO: Observation and Analysis of Some 0+ – 1∑+ Transitions”, J. Mol. Spectrosc. 101, 332-343 (1983). http://dx.doi.org/10.1016/0022-2852(83)90139-X

87. E. Abramson, R. W. Field, D. Imre, K. K. Innes, and J. L. Kinsey, “Fluorescence and Stimulated Emission S1→ S0 Spectra of Acetylene: Regular and Ergodic Regions,” J. Chem. Phys. 83, 453- 465 (1985). http://dx.doi.org/10.1063/1.449560

88. H. Schall, C. Linton, and R. W. Field, “Laser Spectroscopy of LaF: Determination of the Separation of the Singlet and Triplet State Manifolds”, J. Mol. Spectrosc. 100, 437- 448 (1983). http://dx.doi.org/10.1016/0022-2852(83)90100-5

89. Li Li and R. W. Field, “Direct Observation of High-Lying 3∏g States of the Na2 Molecule by Optical-Optical Double Resonance,” J. Phys. Chem. 87, 3020-3022 (1983). http://dx.doi.org/10.1021/j100239a011

90. Y. C. Liu, H. Schall, R. W. Field, and C. Linton, “Laser Spectroscopy of Holmium Oxide: Examination of the Low-Lying States”, J. Mol. Spectrosc. 104, 72-88 (1984). http://dx.doi.org/10.1016/0022-2852(84)90246-7

91. Li Li, S. F. Rice, and R. W. Field, “Observation of the v = 0-13 Levels of Na2 b3∏u by OODR 3Λg – b3∏u Fluorescence Spectroscopy”, J. Mol. Spectrosc. 105, 344-350 (1984). http://dx.doi.org/10.1016/0022-2852(84)90224-8

92. E. Abramson, R. W. Field, D. Imre, K. K. Innes, and J. L. Kinsey, “Stimulated Emission Pumping of Acetylene: Evidence

for Quantum Chaotic Behavior near 27,900 cm–1 of Excitation?,” J. Chem. Phys. 80, 2298-2300 (1984). http://dx.doi.org/10.1063/1.447006

93. D. E. Reisner, R. W. Field, J. L. Kinsey, and H.-L. Dai, “Stimulated Emission Spectroscopy: A Complete Set of Vibrational

Constants for X~1A1 Formaldehyde”, J. Chem. Phys. 80, 5968-5978 (1984). http://dx.doi.org/10.1063/1.446677 94. H.-L. Dai, R. W. Field, and J. L. Kinsey, “State-Specific Rates of H2CO(S0) → H2 + CO at Energies Near the Top of Barrier:

A Violation of RRKM Theory?”, J. Chem. Phys. 82, 1606-1607 (1985). http://dx.doi.org/10.1063/1.448436 95. H.-L. Dai, R. W. Field, and J. L.Kinsey, “Intramolecular Vibrational Dynamics Including Rotational Degrees of Freedom:

Chaos and Quantum Spectra”, J. Chem. Phys. 82, 2161-2163 (1985). http://dx.doi.org/10.1063/1.448354 96. S. Churassy, G. K. Chawla, and R. W. Field, “Modulated Gain Spectrometer”, J. Opt. Soc. Am. B. 2, 1929-1933 (1985).

http://dx.doi.org/10.1364/JOSAB.2.001929 97. Li Li, S. F. Rice, and R. W. Field, “The Na2 a 3∑+

u State. Rotationally Resolved OODR 3∏g – a 3∑+u Fluorescence

Spectroscopy”, J. Chem. Phys. 82, 1178-1182 (1985). http://dx.doi.org/10.1063/1.448490 98. H. L. Dai, C. L. Korpa, J. L. Kinsey, and R. W. Field, “Rotation Induced Vibrational Mixing in X~1A1 Formaldehyde: Non-

negligible Dynamical Consequences of Rotation”, J. Chem. Phys. 82, 1688-1701 (1985). http://dx.doi.org/10.1063/1.448401


99. S. F. Rice, H. Martin, and R. W. Field, “The Electronic Structure of the Calcium Monohalides. A Ligand Field Approach”, J. Chem. Phys. 82, 5023-5034 (1985). http://dx.doi.org/10.1063/1.448676

100. H. Lefebvre-Brion and R. W. Field, BOOK: Perturbations in the Spectra of Diatomic Molecules, 465 p., Academic Press,

1986. 101. P. H. Vaccaro, R. Redington, J. Schmidt, J. L. Kinsey, and R. W. Field, “Rotational Relaxation in the H2CO A~1A2 State by

Transient Gain Spectroscopy”, J. Chem. Phys. 82, 5755-5756 (1985). http://dx.doi.org/10.1063/1.448564 102. J. A. Gray and R. W. Field, “The Zeeman Effect as an Aid to Electronic Assignment: The NiH A 2∆5/2 State”, J. Chem. Phys.

84, 1041-1042 (1986). http://dx.doi.org/10.1063/1.450588 103. J. A. Gray, S. F. Rice, and R. W. Field, “The Electric Dipole Moment of NiH X2∆5/2 and B2∆5/2”, J. Chem. Phys. 82, 4717-

4718 (1985). http://dx.doi.org/10.1063/1.448682 104. R. L. Sundberg, E. Abramson, J. L. Kinsey, and R. W. Field, “Evidence of Quantum Ergodicity in Stimulated Emission

Pumping Spectra of Acetylene”, J. Chem. Phys. 83, 466-475 (1985). http://dx.doi.org/10.1063/1.449561 105. M. Dulick and R. W. Field, “Electronic Structure of PrO: An Analysis Summary”, J. Mol. Spectrosc. 113, 105-141 (1985).

http://dx.doi.org/10.1016/0022-2852(85)90124-9 106. X. Xie and R. W. Field, “The 6Li2 A1∑+

u~ b3∏u Spin-Orbit Perturbations: Sub-Doppler Spectra and Steady State Kinetic Lineshape Model”, Chem. Phys. 99, 337-345 (1985). http://dx.doi.org/10.1016/0301-0104(85)80130-0

107. a) X. Xie and R. W. Field, “The Bound and Quasibound Levels of 6Li2 a3∑+

u”, J. Chem. Phys. 83, 6193-6196 (1985). http://dx.doi.org/10.1063/1.449565

b) S. F. Rice and R. W. Field, “Perturbation Facilitated OODR Resolved Fluorescence Spectroscopy of the a3∑+

u State of Li2 and Na2”, pp. 389-398, Methods of Laser Spectroscopy (Y. Prior editor, Plenum, New York, 1986).

108. S. F. Rice, X. Xie, and R. W. Field, “The Predissociation of Li2 b3∏u by a3∑+

u”, Chem. Phys. 104, 161-167 (1986). http://dx.doi.org/10.1016/0301-0104(86)80162-8

109. X. Xie and R. W. Field, “Perturbation Facilitated Optical-Optical Double Resonance Spectroscopy of the 6Li2 33∑+

g, 23∏g, 13∆g, b3∏u, and a3∑+

u States”, J. Mol. Spectrosc. 117, 228-244 (1986). http://dx.doi.org/10.1016/0022-2852(86)90152-9 110. Li Li and R. W. Field, “CW Optical-Optical Double Resonance Studies of the 23∏g, 33∏g, 43∑+

g, and 13∆g Rydberg States of Na2”, J. Mol. Spectrosc. 117, 245-282 (1986). http://dx.doi.org/10.1016/0022-2852(86)90153-0

111. H. Schall, J. Gray, M. Dulick, and R. W. Field, “Sub-Doppler Zeeman Spectroscopy of the CeO Molecule”, J. Chem. Phys.

85, 751-761 (1986). http://dx.doi.org/10.1063/1.451282 112. A. C. LeFloch, F. Launay, J. Rostas, R. W. Field, C.M. Brown, and K. Yoshino, “Reinvestigation of the CO A1∏ State and

its Perturbations: The v = 0 Level”, J. Mol. Spectrosc. 121, 337-379 (1987). http://dx.doi.org/10.1016/0022-2852(87)90056-7

113. G. J. Scherer, Y. Chen, R. L. Redington, J. L. Kinsey, and R. W. Field, “An Unsuspected Fermi Perturbation in the

Acetylene A~1Au 3ν3 Level”, J. Chem. Phys. 85, 6315-6323 (1986). http://dx.doi.org/10.1063/1.451461 114. a) G. Pichler, J. T. Bahns, K. M. Sando, W. C. Stwalley, W. Müller, D. D. Konowalow, Li Li, and R. W. Field, “Electronic

Assignments of the Violet Bands of Sodium”, AIP Conf. Proc. 146,160-162 (1986). http://dx.doi.org/10.1063/1.35889 b) G. Pichler, J. T. Bahns, K. M. Sando, W. C. Stwalley, D. D. Konowalow, Li Li, R. W. Field, and W. Müller, “Electronic

Assignments of the Violet Bands of Sodium”, Chem. Phys. Lett. 129, 425-428 (1986). http://dx.doi.org/10.1016/0009-2614(86)80372-4


115. B. Barakat, R. Bacis, S. Churassy, R. W. Field, J. Ho, C. Linton, S. McDonald, F. Martin, and J. Vergès, “Observation and Analysis of the 21∑+

g State of 7Li2,” J. Mol. Spectrosc. 116, 271-285 (1986). http://dx.doi.org/10.1016/0022-2852(86)90127-X

116. J. P. Pique, Y. Chen, R. W. Field and J. L. Kinsey, “Chaos and Dynamics on 0.5-300-ps Time Scales in Vibrationally Excited

Acetylene: Fourier Transform of Stimulated Emission Pumping Spectrum”, Phys. Rev. Letts. 58, 475-478 (1987). http://link.aps.org/doi/10.1103/PhysRevLett.58.475

a) J.-P. Pique, Y. Chen, R. W. Field, and J. L. Kinsey, Reply to Comment by J. Wilkie and P. Brumer, “Failure of the Fourier

Transform of the Stimulated Emission Pumping Spectrum of Acetylene to Discern Chaotic Behavior,” Phys. Rev. Lett. 69, 2018 (Comment) and 2019 (Reply) 1992. http://dx.doi.org/10.1103/PhysRevLett.69.2018

117. Li Li and R. W. Field, “A Spin-Orbit 21∏g ~ 23∏2g Perturbation in Na2: Hyperfine Splittings, Perturbation Matrix

Elements, and Electronic Structure Implications”, J. Mol. Spectrosc. 123, 237-246 (1987). http://dx.doi.org/10.1016/0022-2852(87)90273-6

118. S. F. Rice and R. W. Field, “The Electric Dipole Moment of the A2∏ State of ScO,” J. Mol. Spectrosc. 119, 331-336 (1986).

http://dx.doi.org/10.1016/0022-2852(86)90028-7 119. C. E. Hamilton, J. L. Kinsey, and R. W. Field, “Stimulated Emission Pumping: New Methods in Spectroscopy and

Molecular Dynamics,” Ann. Rev. Phys. Chem. 37, 493-524 (1986). http://dx.doi.org/10.1146/annurev.pc.37.100186.002425 120. G. K.Chawla, H. J. Vedder, and R. W. Field, “The Potential Energy Barrier of the Na2 B1∏u State,” J. Chem. Phys. 86,

3082-3088 (1987). http://dx.doi.org/10.1063/1.452019 121. G. Chawla, H. S. Schweda, H. J. Vedder, R. W. Field, S. Churassy, A. M. Lyyra, W. T. Luh, and W. C. Stwalley, “Long

Range Potential of the A1∑+u State of Na2 Using Modulated Gain Spectroscopy,” Am. Instit. Phys. Conf. Proc. of Internatl.

Laser Symposium 146, 466-468 (1986). 122. Li Li, R. W. Field, and Q. Zhu, “Hyperfine Interaction of the Triplet Rydberg States of Na2”, Am. Instit. Phys. Conf. Proc. of

Internatl. Laser Symposium, 160, 378-380 (1987). 123. F. Temps, S. Halle, P. H. Vaccaro, R. W. Field, and J. L.Kinsey, “Collisional Energy Transfer in Highly Vibrationally

Excited H2CO (X~1A1)” J. Chem. Phys. 87, 1895-1897 (1987). http://dx.doi.org/10.1063/1.453207 124. H. Schall, M. Dulick, and R. W. Field, “The Electronic Structure of LaF: A Multi-Configuration Ligand Field Calculation”,

J. Chem. Phys. 87, 2898-2912 (1987). http://dx.doi.org/10.1063/1.453078 125. P. H. Vaccaro, F. Temps, S. Halle, J. L. Kinsey, and R. W. Field, “Polarization-Detected Transient Gain Studies of

Relaxation Processes in v4 = 1 A~1A2 Formaldehyde-h2”, J. Chem. Phys. 88, 4819-4833 (1988). http://dx.doi.org/10.1063/1.454694

126. M. Li, J. A.Gray, and R. W. Field, “A Multipass, Magnetically Confined Sputter Source for Absorption-Based Spectroscopy

of Transient Molecules: The Spectrum of NiH”, Chem. Phys. 117, 171-176 (1987). http://dx.doi.org/10.1016/0301-0104(87)80106-4

127. R. L. Redington, Y. Chen, G. J. Scherer, and R. W. Field, “Laser Fluorescence Excitation Spectrum of Jet-Cooled Tropolone:

The A~1B2 – X~1A1 System”, J. Chem. Phys. 88, 627-633 (1988). http://dx.doi.org/10.1063/1.454189 128. F. Temps, S. Halle, P. H. Vaccaro, R. W. Field, and J. L. Kinsey,”Vibrationally Excited Formaldehyde: The Relationship

between Vibrational Structure and Collisional Properties”, Faraday Discussion on Molecular Vibrations, 1987, J. Chem. Soc. Faraday Trans. 2, 84, 1457-1482 (1988). http://dx.doi.org/10.1039/F29888401457

129. a) J.-P. Pique, Y. Chen, R. W. Field, and J. L. Kinsey, “Laser Spectroscopy and Quantum Chaos: An Example Through the

Fourier Transform of a Stimulated Emission Pumping Spectrum of C2H2 at Very High Vibrational Energy”, Conference Laser M2P, 1987, J. de Physique C7, 655-657 (1987). http://dx.doi.org/10.1051/jphyscol:19877158


b) J. P. Pique, Y. Chen, R. W. Field, J. L. Kinsey, and M. Lombardi, “New Order Out of the Chaotic Bath of Highly Excited Vibrational States of C2H2”, Berichte der Bunsengesellschaft für Physikalishe Chemie 92, 422-424 (1988).

130. R. W. Field, “High Resolution Spectroscopy of Small Molecules”, Conference Laser M2P, 1987, J. de Physique C7,17-28

(1987). 131. Y. Chen, D. M. Jonas, C. E. Hamilton, P. G. Green, J. L. Kinsey, and R. W. Field, “Acetylene: Isomerization and

Dissociation,” Berichte der Bunsengesellschaft für Physikalische Chemie, 92 329-336 (1988). 132. J. P. Pique, Y. M. Engel, R. D. Levine, Y. Chen, R. W. Field, and J. L. Kinsey, “Broad Spectral Features in the Stimulated

Emission Pumping Spectrum of Acetylene”, J. Chem. Phys. 88, 5972-5974 (1988). http://dx.doi.org/10.1063/1.454510 133. M. H. Alexander, P. Andresen, R. Bacis, R. Bersohn, F. J. Comes, P. J. Dagdigian, R. N. Dixon, R. W. Field, G. W. Flynn,

K.-H. Gericke, B. J. Howard, J. P. Huber, D. S. King, J. L. Kinsey, K. Kleinermanns, A. C. Luntz, A. J. MacCaffery, B. Pouilly, H. Reisler, S. Rosenwaks, E. Rothe, M. Shapiro, J. P. Simons, R. Vasudev, J. R. Wiesenfeld, C. Wittig, and R. N. Zare, “A Nomenclature for Λ-Doublet Levels in Rotating Linear Molecules”, J. Chem. Phys. 89, 1749-1753 (1988). http://dx.doi.org/10.1063/1.455121

134. S. F. Rice, W.J. Childs, and R. W. Field, “The A′2∆ state of ScO: Analysis of the A′2∆ (v = 3) ~ A2∏ (v = 1) Perturbation”,

J. Mol. Spectrosc. 133, 22-35 (1988). http://dx.doi.org/10.1016/0022-2852(89)90240-3 135. R. W. Field, “A Zero-Order Electronic Structure Model for Ionic Diatomic Molecules”, The Structure of Small Molecules

and Ions, pp. 333-334, Plenum, 1989. 136. M. Li and R. W. Field, “Sideband OODR Zeeman Spectroscopy of NiH: A New Diagnostic for Electronic and Rotational

Assignment”, J. Chem. Phys. 90, 2967-2970 (1989). http://dx.doi.org/10.1063/1.455897 137. R. L. Redington and R. W. Field, “Laser Fluorescence Excitation Band Profiles of Jet-Cooled Tropolone”, Spectrochim. Acta

45A 41-46 (1989). http://dx.doi.org/10.1016/0584-8539(89)80025-X 138. a) X. Xie, R. W. Field, Li Li, A.M. Lyyra, J.T. Bahns, and W.C. Stwalley, “Absolute Vibrational Numbering and Molecular

Constants of the Na2 23∏g State”, J. Mol. Spectrosc. 134, 119-128 (1989). http://dx.doi.org/10.1016/0022-2852(89)90134-3 b) X. Xie, R. W. Field, Li Li, A.M.Lyyra, J. T. Bahns, and W. C. Stwalley, “The Absolute Vibrational Numbering and

Molecular Constants of the Na2 23∏g and 13∆g States”, Opt. Sci. Eng. Series 10, 191, 569-571, ILS- IV, 1989. 139. Li Li, Q. Zhu, and R. W. Field, “Hyperfine Structure of the Na2 13∆g State”, J. Mol. Spectrosc. 134, 50-62 (1989).

http://dx.doi.org/10.1016/0022-2852(89)90127-6 140. Li Li, Q. Zhu, and R. W. Field, “The Hyperfine Structure of the Na2 43∑+

g State”, Mol. Phys. 66, 685-694 (1989). http://dx.doi.org/10.1080/00268978900100431

141. J. B. Norman, K. J. Cross, H. S. Schweda, M. Polak, and R. W. Field, “The CaO c3∑+ – a3∏ (0, 0) Band: The Key to the

Orange System and the Global Electronic Structure of CaO”, Mol. Phys. 66, 235-268 (1989). http://dx.doi.org/10.1080/00268978900100121

142. D. P. Baldwin and R. W. Field, “The C′ 1∑+ – A′ 1∏ (0,0) and (1,1) Bands of CaO”, J. Mol. Spectrosc. 133, 90-95 (1989).

http://dx.doi.org/10.1016/0022-2852(89)90245-2 143. P. H.Vaccaro, A. Zabludoff, M. Carrera-Patiño, J. L. Kinsey, and R. W. Field, “High Precision Dipole Moments in A~1A2

Formaldehyde Determined via Stark Quantum Beat Spectroscopy”, J. Chem. Phys. 90, 4150-4167 (1989). http://dx.doi.org/10.1063/1.455773

144. a) R. W. Field, “Pathologically Complex Spectra of Small Molecules: High Resolution Techniques for Displaying

Vibrational Chaos and Electronic Simplicity”, Conference on Quantum Electronics and Laser Science, 1989 Technical Digest Series, Vol. 12 (Optical Society of America, Washington, DC), pp. 160-162 (Talk THHH2), 1989.


b) R. W. Field, D.P. Baldwin, E.J.Hill, M. Li, and M. C. McCarthy, “Spectroscopy Beyond Molecular Constants”, Symposium on “Future Trends in Spectroscopy”, Pontificiae Academiae Scientiarum Scripta Varia 81, 75-89 (1989), also Spectrochimica Acta Part A, Suppl. 1, 45, 75-89 (1989). http://dx.doi.org/10.1016/S0584-8539(89)80090-X

145. R. W. Field, “Statistical Spectroscopy: Insight or Nonsense?”, ILS-IV, 1988, Am. Instit. of Phys. Conf. Proc. 191, 673-682

(1988). 146. P. G. Green, J. L. Kinsey, and R. W. Field, “A New Determination of the Dissociation Energy of Acetylene”, J. Chem. Phys.

91, 5160-5163 (1989). http://dx.doi.org/10.1063/1.457614

147. F. Temps, S. Halle, P. H. Vaccaro, R. W. Field, and J. L. Kinsey, “Collisional Relaxation of H2CO (A~1A2, v4 = 1, JKa ,Kc

= 132,12 ) by He, Ar, Xe, and N2”, J. Chem. Phys. 91, 1008-1011 (1989). http://dx.doi.org/10.1063/1.457224

148. Y. Chen, D. M. Jonas, J. L. Kinsey, and R. W. Field, “High Resolution Spectroscopic Detection of Acetylene−Vinylidene

Isomerization by Spectral Cross Correlation”, J. Chem. Phys. 91, 3976-3987 (1989). http://dx.doi.org/10.1063/1.456828 149. a) J. V. Auwera, T. R. Huet, M. Herman, C. Hamilton, J. L. Kinsey, and R. W. Field, “The A~1A″ Electronic State of

Monodeuterated Acetylene”, J. Mol. Spectrosc. 137, 381-395 (1989). http://dx.doi.org/10.1016/0022-2852(89)90181-1 b) C. E. Hamilton, R. W. Field, T. R. Huet, and M. Herman, “Low Energy Vibrational Levels in the A~1Au Electronic State of

C2D2”, J. Mol. Spectrosc. 137, 427-429 (1989). http://dx.doi.org/10.1016/0022-2852(89)90184-7 150. R. O. Loo, W. J. Marinelli, P. L. Houston, S. Arepalli, J. R. Wiesenfeld, and R. W. Field, “Multiphoton Ionization of O2

X3∑–g, a 1∆g, and b 1∑+

g via the Two-Photon Resonant nsσg, ndσg, and ndπg Rydberg Levels”, J. Chem. Phys. 91, 5185-5200 (1989). http://dx.doi.org/10.1063/1.457589

151. T. D. Varberg, E. J. Hill, and R. W. Field, “Laser Spectroscopy of CoH: Spin-Orbit Splitting of the Ground State”, J. Mol.

Spectrosc. 138, 630-637 (1989). http://dx.doi.org/10.1016/0022-2852(89)90023-4 152. D. P. Baldwin, J. B. Norman, R. A. Soltz, A. Sur, and R. W. Field, “The e3∑- – a3∏ (0,0) and E1∑- – A′ 1∏ (0,0), (1,1), and

(2,2) Bands of CaO. Multistate Deperturbation of the e3∑- (v = 0) ~ c3∑+ (v = 1)~ E1∑- (v = 0) System, J. Mol. Spectrosc. 139, 39-67 (1990). http://dx.doi.org/10.1016/0022-2852(90)90241-H

153. D. P. Baldwin and R. W. Field, “The F1∏ – A′ 1∏(0,0) and B1∏ – A′ 1∏(1,0) Green-Band Transitions of CaO”, J. Mol.

Spectrosc. 139, 68-76 (1990). http://dx.doi.org/10.1016/0022-2852(90)90242-I 154. D. P. Baldwin and R. W. Field, “Dispersed Laser Fluorescence Spectroscopy of the Perturbation Facilitated B1∏ – b3∑+

(1,1) Band of CaO”, J. Mol. Spectrosc. 139, 77-83 (1990). http://dx.doi.org/10.1016/0022-2852(90)90243-J 155. J. B. Norman and R. W. Field, “Collision-Induced Angular Momentum Reorientation and Rotational Energy Transfer in

CaF(A2∏1/2)-Ar Thermal Collisions”, J. Chem. Phys. 92, 76-89 (1990). http://dx.doi.org/10.1063/1.458431 156. J. A. Gray, M. Li, and R. W. Field, “Zeeman Spectroscopy and Deperturbation of the Low-Lying States of NiH”, J. Chem.

Phys., 92, 4651-4659 (1990). http://dx.doi.org/10.1063/1.457732 157. E. J. Hill and R. W.Field, “Fluorescence-based Intracavity Laser Spectroscopy and the Electronic Structure of NiH”, J.

Chem. Phys. 93, 1-5 (1990). http://dx.doi.org/10.1063/1.459593 158. S. A. Kadavathu, R. Scullman, J. A. Gray, M. Li, and R. W. Field, “New Low-Lying States in NiH: Rotational Analysis with

the Aid of Laser-Induced Dispersed Fluorescence Spectroscopy”, J. Mol. Spectrosc., 140, 126-140 (1990). http://dx.doi.org/10.1016/0022-2852(90)90011-E

159. D. M. Jonas, X. Zhao, K. Yamanouchi, P. G. Green, G. W. Adamson, and R. W. Field, “High Resolution VUV Fluorescence

Excitation Spectrum and Predissociation of A~1A″ HCN”, J. Chem. Phys. 92, 3988-3989 (1990). http://dx.doi.org/10.1063/1.457809


160. T. D. Varberg, R. W. Field, and A. J. Merer, “Hyperfine Structure of the MnH X 7∑+ State: A Large Gas-To-Matrix Shift in the Fermi Contact Interaction”, J. Chem. Phys. 92, 7123-7127 (1990). http://dx.doi.org/10.1063/1.458252

161. R. L. Redington, T. E. Redington, M. A. Hunter, and R. W. Field, “A~1B2 – X~ 1A1 26v

0 Transitions of 18O-Enriched Tropolone”, J.Chem. Phys. 92, 6456-6462 (1990). http://dx.doi.org/10.1063/1.458325

162. S. A. McDonald, S. F. Rice, R. W. Field, and C. Linton, “Laser Spectroscopy of Low-Lying Excited States in YbO: Linkage

of the Yb2+ f13s and f14 Configurations”, J. Chem. Phys. 93 ,7676-7686 (1990). http://dx.doi.org/10.1063/1.459347 163. Y.-T. Chen, D. M. Watt, R. W. Field, and K. K. Lehmann, “Observation of Highly Vibrationally Excited X~1∑+ HCP by

Stimulated Emission Pumping Spectroscopy”, J. Chem. Phys. 93, 2149-2151 (1990). http://dx.doi.org/10.1063/1.459041 164. Y. Chen, S. D. Halle, D. M. Jonas, J. L. Kinsey, and R. W. Field, “Stimulated-Emission Pumping Studies of Acetylene X~1∑+

gin the 11,400-15,700 cm–1 Region: the Onset of Mixing”, J. Opt. Soc. Am. B 7, 1805-1815 (1990). http://dx.doi.org/10.1364/JOSAB.7.001805

165. J. E. Murphy, J. M. Berg, A. J. Merer, N. Harris, and R. W. Field, “Rydberg States and Ionization Potential of Calcium

Monofluoride”, Phys. Rev. Lett. 65, 1861-1864 (1990). http://dx.doi.org/10.1103/PhysRevLett.65.1861 166. D. P. Baldwin, E. J. Hill, and R. W. Field, “Electron Affinity of O– and Diabatic CaO(g) Integer Charge Potential Curves”, J.

Am. Chem. Soc. 112, 9156-9161 (1990). http://dx.doi.org/10.1021/ja00181a019 167. P. Dupré, R. Jost, M. Lombardi, P. G. Green, E. Abramson, and R. W. Field, “Anomalous Behavior of the Anticrossing

Density as a Function of Excitation Energy in the C2H2 Molecule,” Chem. Phys. 152, 293-318 (1991). http://dx.doi.org/10.1016/0301-0104(91)85006-3

168. P. Ip, K. J. Cross, R. W. Field, J. Rostas, B. Bourguignon, and J. McCombie, “The B1∑+ –a3∏i and D1∆–a3∏1

Intercombination Systems of the MgO Molecule”, J. Mol. Spectrosc. 146, 409-436 (1991). http://dx.doi.org/10.1016/0022-2852(91)90016-4

169. Li Li, A. M. Lyyra, W. C. Stwalley, M. Li, and R. W. Field, “The Na2 41∑+

g~ 23∏g ~ 13∆g Triple Perturbation: Deperturbation of the (v∑, v∏, v∆) = (6, 2, 7) and (7, 3, 8) Interactions”, J. Mol. Spectrosc. 147, 215-228 (1991). http://dx.doi.org/10.1016/0022-2852(91)90180-I

170. S. A. Kadavathu, R. W. Field, J. A. Gray, M. Li, and R. Scullman, “Excited States of NiH and NiD in the 15,500-19,000

cm−1 Region: Rotational Analysis with the Aid of Laser-Induced Fluorescence Spectroscopy”, J. Mol. Spectrosc. 147, 448-470 (1991). http://dx.doi.org/10.1016/0022-2852(91)90069-M

171. K. Yamanouchi, N. Ikeda, S. Tsuchiya, D. M. Jonas, J. K. Lundberg, G. W. Adamson, and R. W. Field, “Vibrationally

Highly Excited Acetylene as Studied by Dispersed Fluorescence and Stimulated Emission Pumping Spectroscopy: Vibrational Assignment of the Feature States”, J. Chem. Phys. 95, 6330-6342 (1991). http://dx.doi.org/10.1063/1.461554

172. T. D. Varberg, R. W. Field, and A. J. Merer, “Elucidation of Electronic Structure by the Analysis of Hyperfine Interactions:

The MnH A7∏ – X7∑+ (0,0) Band”, J. Chem. Phys. 95, 1563-1576 (1991). http://dx.doi.org/10.1063/1.461071 173. J. A. Gray, M. Li, Th. Nelis, and R. W. Field, “The Electronic Structure of NiH: The {Ni+3d9 2D} Supermultiplet”, J.

Chem. Phys. 95, 7164-7178 (1991). http://dx.doi.org/10.1063/1.461393 174. M. C. McCarthy and R. W. Field, “The Use of Magnetic Rotation Spectroscopy to Simplify and Presort Spectra: An

Application to NiH and CeF”, J. Chem. Phys. 96, 7237-7244 (1992). http://dx.doi.org/10.1063/1.462428 175. T. D. Varberg, J. A. Gray, R. W. Field, and A. J. Merer, “Reanalysis and Extension of the MnH A7∏–X7∑+ (0, 0) Band:

Fine Structure and Hyperfine-Induced Rotational Branches”, J. Mol. Spectrosc. 156, 296-318 (1992). http://dx.doi.org/10.1016/0022-2852(92)90233-E

176. Li Li, T. An, T.-J. Whang, A. M. Lyyra, W. C. Stwalley, R. W. Field, and R. A. Bernheim, “Hyperfine Splitting of the Triplet

Rydberg State of Li2”, J. Chem. Phys. 96, 3342-3343 (1992). http://dx.doi.org/10.1063/1.461930


177. E. J. Friedman-Hill and R. W. Field, “A Reexamination of the RKR Potential of the a3∑+u State of Na2”, J. Chem. Phys. 96,

2444- 2448 (1992). http://dx.doi.org/10.1063/1.462047 178. E. J. Friedman-Hill and R. W. Field, “Analysis of the [16.0]3∑– –X3∑– and [16.0]3∑– –[4.3]3∏i Band Systems of the NiO

Molecule”, J. Mol. Spectrosc. 155, 259-276 (1992). http://dx.doi.org/10.1016/0022-2852(92)90516-Q 179. D. M. Jonas, S. A. B. Solina, X. Zhao, and R. W. Field, “High Resolution VUV Stark Measurement of the Dipole Moment of

A~1A″ HCN”, J. Chem. Phys. 96, 7209-7217 (1992). http://dx.doi.org/10.1063/1.462425 180. S. L. Coy, S. D. Halle, J. L. Kinsey and R. W. Field, “Pressure-Induced Rotational Energy Transfer in H2CO A~1A2 v4 = 1:

Dipolar M-Dependence with No Single-Collision Elastic Contribution”, J. Mol. Spectrosc. 153, 340-375 (1992). http://dx.doi.org/10.1016/0022-2852(92)90482-4

181. L. A. Kaledin, C.Linton, T. E. Clarke, and R. W. Field, “Laser Spectroscopy of the Lanthanide Monofluorides: The Ground

State Configuration of Holmium Fluoride”, J. Mol. Spectrosc. 154, 417-426 (1992) http://dx.doi.org/10.1016/0022-2852(92)90219-E

182. D. M. Jonas, S. A. B. Solina, R. W. Field, and R. J. Silbey, “Experimental Distinction of Electric and Magnetic Transition

Moments,” J. Chem. Phys. 96, 7189-7190 (1992). http://dx.doi.org/10.1063/1.462525 183. J. K. Lundberg, R. W. Field, C. D. Sherrill, E. T. Seidl, Y. Xie, and H. F. Schaefer III, “Acetylene: Synergy Between Theory

and Experiment,” J. Chem. Phys. 98, 8384-8391 (1993). http://dx.doi.org/10.1063/1.464496 184. J. K. Lundberg, Y. Chen, J.-P. Pique, and R. W. Field, “Ultraviolet-Optical Double Resonance Study of the Predissociated

C~′ 1Ag State of Acetylene,” J. Mol. Spectrosc. 156, 104-122 (1992). http://dx.doi.org/10.1016/0022-2852(92)90097-8 185. R. L. Redington, T. E. Redington, B. Rajaram, and R. W. Field, “Excitation Spectra of 2,5-Dihydroxy-p-Benzoquinone

Monomer and Hydrates,” J. Chem. Phys. 97, 1624-1629 (1992). http://dx.doi.org/10.1063/1.463204 186. D. M. Jonas, S. A. B.Solina, B. Rajaram, R. J. Silbey, R. W. Field, K. Yamanouchi, and S. Tsuchiya, “Intramolecular

Vibrational Relaxation and Forbidden Transitions in the SEP Spectrum of Acetylene,” J. Chem. Phys., 97, 2813-2816 (1992). http://dx.doi.org/10.1063/1.463021

187. D. M. Jonas, S. A. B. Solina, B. Rajaram, S.J. Cohen, R. J. Silbey, R. W. Field, K. Yamanouchi, and S. Tsuchiya,

“Intramolecular Vibrational Relaxation in the SEP Spectrum of Acetylene,” J. Chem. Phys. 99, 7350-7370 (1993). http://dx.doi.org/10.1063/1.465716

188. M. C. McCarthy, R. W. Field, R. Engleman, Jr., and P. F. Bernath,” Laser and Fourier Transform Spectroscopy of PtH and

PtD”, J. Mol. Spectrosc. 158, 208-236 (1993). http://dx.doi.org/10.1006/jmsp.1993.1067 189. J. K. Lundberg, D. M. Jonas, Y. Chen, B. Rajaram, and R. W. Field, “Rotationally Resolved UV-UV Double Resonance

Study of the Nonplanar E~ State of Acetylene,” J. Chem. Phys. 97, 7180-7196 (1992). http://dx.doi.org/10.1063/1.463543 190. J. M. Berg, J. E. Murphy, N. A. Harris, and R. W. Field, “Observation and Analysis of Core-Penetrating Rydberg States of

Calcium Monofluoride”, Phys. Rev. A. 48, 3012-3029 (1993). http://dx.doi.org/10.1103/PhysRevA.48.3012 191. Li Li, Q. Zhu, A. M. Lyyra, T.-J. Whang, W. C. Stwalley, R. W. Field, and M. H. Alexander, “Collision-Induced Transitions

between A 1∑+u and b 3∏u States of Na2: The ‘Gateway’ Effect of Perturbed Levels,” J. Chem. Phys. 97, 8835-8841 (1992).

http://dx.doi.org/10.1063/1.463971 192. a) N. A. Harris and R. W. Field, “The Core-Penetrating Rydberg Series of the CaF Molecule: At the Borderline Between

Valence and Rydberg States,” J. Chem. Phys. 98, 2642-2646 (1993). http://dx.doi.org/10.1063/1.464144 b) C. Gittins, N. Harris, and R. W. Field, “Rydberg States of CaF: Healing a Scar in the ‘s’∑ Series,” Lawrence Berkeley

Laboratory Report #LBL-32305, pp. 57-60, XIV International Symposium on Molecular Beams, 1992.


193. Li Li, Q. Zhu, A. M. Lyyra, T.-J. Whang, W. C. Stwalley, R. W. Field, and M. H. Alexander, “Rotational Energy Transfer in the Na2 b 3∏u State: Propensity Rules for Rotation, Spin-Orbit Component, and e/f-Parity Changing Collisions,” J. Chem. Phys. 98, 8406-8412 (1993). http://dx.doi.org/10.1063/1.465087

194. Li Li, Q. Zhu, A. M. Lyyra, T.-J. Whang, W. C. Stwalley, R. W. Field, and M. H. Alexander, “Rotational Energy Transfer in

the Na2 b 3∏u State: Propensity Rules for Transitions Between Hyperfine Components,” J. Chem. Phys. 98, 8413-8418 (1993). http://dx.doi.org/10.1063/1.464499

195. Z. J. Jakubek and R. W. Field, “Comment on: High Resolution Laser Spectroscopy of the C~2∆ – X~2∑+ Transition of CaOH

and CaOD: Vibronic Coupling and the Renner-Teller Effect”, J. Chem. Phys. 98, 6574-6575 (1993). http://dx.doi.org/10.1063/1.464801

196. X. Zhao, G. W. Adamson, and R. W. Field, “The HCO B~2A′↔X~2A′ System: Fluorescence Excitation and Stimulated

Emission Pumping Spectra”, J. Mol. Spectrosc. 160, 11-38 (1993). http://dx.doi.org/10.1006/jmsp.1993.1154 197. C. M. Gittins, N. A. Harris, R. W. Field, J. Vergès, C. Effantin, A. Bernard, J. d'Incan, W. E. Ernst, P. Bündgen, and B.

Engels, “Analysis and Deperturbation of the C2∏ and D2∑+ States of CaF”, J. Mol. Spectrosc. 161, 303-311 (1993). http://dx.doi.org/10.1006/jmsp.1993.1236

198. R. Liyanage, P. T. A. Reilly, Y. Yang, R. J. Gordon, and R. W. Field, “Evidence of the Indirect Predissociation of the F1∆

State of HCl”, Chem. Phys. Lett. 216, 544-550 (1993). http://dx.doi.org/10.1016/0009-2614(93)90140-V 199. Z. J. Jakubek, N. A. Harris, R. W. Field, J. A. Gardner, and E. Murad, “Ionization Potentials of CaF and BaF,” J. Chem.

Phys. 100, 622-627 (1994). http://dx.doi.org/10.1063/1.466923 200. a) H.-L. Dai and R. W. Field, Molecular Dynamics and Spectroscopy by Stimulated Emission Pumping (book), 1120 pages,

World Scientific, 1995. b) Li Li and R. W. Field, “Continuous Wave Perturbation-Facilitated Optical-Optical Double Resonance Spectroscopy of

Na2 and Li2,” in Molecular Dynamics and Spectroscopy by Stimulated Emission Pumping pp. 251-278 (eds. H.-L. Dai and R. W. Field), World Scientific, 1995.

c) S. L. Coy, D. Chasman, and R. W. Field, “Extracting Dynamical Information from Complex and Congested Spectra:

Statistics, Pattern Recognition and Parsimonious Trees”, in Molecular Dynamics and Spectroscopy by Stimulate Emission Pumping pp. 891-942 (eds. H.-L.Dai and R. W. Field), World Scientific, 1995.

201. Z. J. Jakubek and R. W. Field, “Core-Penetrating Rydberg Series of BaF: s ~ p ~ d ~ f Supercomplexes,” Phys. Rev. Lett.

72, 2167-2170 (1994). DOI: http://dx.doi.org/10.1103/PhysRevLett.72.2167 202. a) K. Yamanouchi, J. Miyawaki, S. Tsuchiya, D. M. Jonas, and R. W. Field, “New Scheme for Extracting Molecular

Dynamics from Spectra: Case Study on Vibrationally Highly Excited Acetylene,” Laser Chemistry, 14, 183-190 (1994). http://dx.doi.org/10.1155/1994/34542

b) K. Yamanouchi and R. W. Field, “Short Time Dynamics of Highly Excited Small Polyatomic Molecules Extracted from

Laser Spectra,” Laser Chemistry 16, 31-41 (1995). http://dx.doi.org/10.1155/1995/36349 c) R. W. Field, “A Trans-Pacific Collaboration: Dynamical Experiments and Experiences”, Laser Chem. 15, 79-80 (1995).

http://dx.doi.org/10.1155/1995/90604 203. M. C. McCarthy, J. C. Bloch and R. W. Field, “Frequency-Modulation Enhanced Magnetic Rotation Spectroscopy: A

Sensitive and Selective Absorption Scheme for Paramagnetic Molecules,” J.Chem. Phys. 100, 6331-6346 (1994). http://dx.doi.org/10.1063/1.467095

204. M. C. McCarthy and R. W. Field, “Frequency-Modulation Enhanced Magnetic Rotation Spectroscopy of PdH, PdD, NiH,

and CuH,” J. Chem. Phys. 100, 6347-6358 (1994). http://dx.doi.org/10.1063/1.467096


205. L. A. Kaledin, J. C. Bloch, M. C. McCarthy, L. V. Gurvich, and R. W. Field, “Laser Spectroscopic Study of Terbium Monofluoride: Ligand Field Assignments of Some f8[7F]sp – f8[7F]s2 Transitions,” Mol. Phys. 83, 881-905 (1994). http://dx.doi.org/10.1080/00268979400101651

206. R. W. Field, S. L. Coy, and S. A. B. Solina, “Pure Sequence Vibrational Spectra of Small Polyatomic Molecules: Feature

State Assignments, Sequential Dynamics, Energy and Time Scaling, and the Bag-of-Atoms Limit,” Progress of Theoretical Physics Supplement, 116, 143-166 (1994). http://dx.doi.org/10.1143/PTP.116.143

207. E. J. Friedman-Hill and R. W. Field, “First Observation and Electronic Structure of the Diatomic Platinum Nitride

Molecule”, J. Chem. Phys. 100, 6141-6152 (1994). http://dx.doi.org/10.1063/1.467078 208. G. M. Schmid, S. L. Coy, R. W. Field, and R. J. Silbey, “Duffing’s Oscillator and the Normal to Local Mode Transition in

AB2 Triatomic Molecules”, Chem. Phys. Lett. 219, 331-338 (1994). http://dx.doi.org/10.1016/0009-2614(94)00115-4 209. G. M. Schmid, S. L. Coy, R. W. Field, and R. J. Silbey, “The Normal to Local Mode Transition in AB2 Triatomic Molecules:

The Susceptibility of Eigenstates to Symmetry Breaking Perturbations”, J. Chem. Phys. 101, 869-875 (1994). http://dx.doi.org/10.1063/1.467739

210. a) J. C. Bloch, R. W. Field, G. E. Hall, and T. J. Sears, “Time-Resolved Frequency Modulation Spectroscopy of

Photochemical Transients,” J. Chem. Phys 101, 1717-1720 (1994). http://dx.doi.org/10.1063/1.467793 b) T. J. Sears, M. Wu, G. E. Hall, B.-C. Chang, G. Hansford, J. C. Bloch, and R. W. Field, “Infrared and Near Infrared

Transient Absorption Spectroscopy of Molecular Free Radicals,” in Laser Techniques for State-Selected and State-to-State Chemistry, Los Angeles, CA, Jan. 27-29, 1994, SPIE Proceedings Series No. 2124, SPIE Press, Washington (1994).

211. P. Dupré, P. G. Green, and R. W. Field, “Quantum Beat Spectroscopic Studies of Zeeman Anticrossings in the A~ 1Au State

of the Acetylene Molecule (C2H2),” Chem. Phys. 196, 211-238 (1995). http://dx.doi.org/10.1016/0301-0104(94)00312-X 212. G. M. Schmid, S. L. Coy, R. W. Field, and R. J. Silbey, “How Robust are Molecular Properties? A Stability Criterion for

Eigenstates,” J. Chem. Phys. 102, 337-345 (1995). http://dx.doi.org/10.1063/1.469407 213. M. C. McCarthy, H. Kanamori, M. Li, and R. W. Field, “Sideband Optical-Optical Double Resonance Zeeman Spectroscopy.

I. Theory of Saturation and Line Shape Behavior” J. Chem. Phys. 102, 8295-8307 (1995). http://dx.doi.org/10.1063/1.468822

214. C. D. Pibel, K. Yamanouchi, J. Miyawaki, S. Tsuchiya, B. Rajaram, and R. W. Field, “The Ω = 1 van der Waals and Ω = 0+

Double Well Potentials of Xe 6s[3/2]01+Kr 1S0 Determined from Tunable Vacuum Ultraviolet Laser Spectroscopy,” J. Chem.

Phys. 101, 10242-10251 (1994). http://dx.doi.org/10.1063/1.468483 215. J. M. Smith, J. C. Bloch, R. W. Field, and J. I. Steinfeld, “Trace Detection of NO2 by Frequency-Modulation-Enhanced

Magnetic Rotation Spectroscopy”, J. Opt. Soc. Am. B 12, 964-969 (1995). http://dx.doi.org/10.1364/JOSAB.12.000964 216. R. W. Field, H. Ishikawa, B. Rajaram, J. Wang, Y. Ohshima, and Y.-T. Chen, “Caught in the Act of Isomerization,” 38th

Welch Conference on Chemical Dynamics of Transient Species, pp. 259-284, 1994. 217. a) S. A. B. Solina, J. P. O'Brien, R. W. Field, and W. F. Polik, “Dispersed Fluorescence Spectrum of Acetylene from the A~

1Au Origin: Recognition of Polyads and Test of Multiresonant Effective Hamiltonian Model for the X~ State,” J. Phys. Chem. 100, 7797-7809 (1996). http://dx.doi.org/10.1021/jp953330s

b) S. A. B. Solina, J. P. O'Brien, R. W. Field, and W. F. Polik, “The Acetylene S0 Surface: From Dispersed Fluorescence

Spectra to Polyads to Dynamics”, Berichte der Bunsengesellschaft für Physikalishe Chemie 99, 555-560 (1995). http://dx.doi.org/10.1002/bbpc.19950990347

218. J. E. Murphy, E. Friedman-Hill and R. W. Field, “A Multichannel Quantum Defect Fit to the n* = 6 – 8 Core-Penetrating

s~p~d Supercomplexes of CaF,” J. Chem. Phys. 103, 6459-6466 (1995). http://dx.doi.org/10.1063/1.470423 219. E. E. Eyler, S. Gangopadhyay, N. Melikechi, J. C. Bloch, and R. W. Field, “Frequency-Modulation Spectroscopy with

Transform-Limited Nanosecond Laser Pulses”, Optics Letters 21, 225-227 (1996). http://dx.doi.org/10.1364/OL.21.000225


220. J. Schamps, M. Bencheikh, C. Barthelat, and R. W. Field, “The Electronic Structure of LaO: Ligand Field vs. ab initio

Calculations”, J. Chem. Phys. 103, 8004-8013 (1995). http://dx.doi.org/10.1063/1.468227 221. R. Liyanage, Y. Yang, S. Hashimoto, R. J. Gordon, and R. W. Field, “Electronic Control of the Spin-Orbit Branching Ratio

in the Photodissociation and Predissociation of HCl,” J. Chem. Phys. 103, 6811 - 6814 (1995). http://dx.doi.org/10.1063/1.470360

222. L. A. Kaledin, J. C. Bloch, M. C. McCarthy, E. A. Shenyavskaya, and R. W. Field, “Laser Spectroscopy of Gadolinium

Monofluoride: Ligand Field Assignments of States in the 0-3 eV Range”, J. Mol. Spectrosc. 176, 148-161 (1996). http://dx.doi.org/10.1006/jmsp.1996.0072

223. H. Ishikawa, Y.-T. Chen, Y. Ohshima, B. Rajaram, J. Wang, and R. W. Field, “Stimulated Emission Pumping Spectroscopy

of HCP near the Isomerization Barrier: EVIB ≤ 25,315 cm−1”, J. Chem. Phys. 105, 7383-7401 (1996). http://dx.doi.org/10.1063/1.472601

224. J. C. Bloch, M. C. McCarthy, R. W. Field, and L. A. Kaledin, “Laser Spectroscopy of Cerium Monofluoride: Ligand Field

Assignments of Some 4f5d6p ← 4f5d6s Transitions”, J. Mol. Spectrosc. 177, 251-262 (1996). http://dx.doi.org/10.1006/jmsp.1996.0139

225. M. C. McCarthy, J. C. Bloch, R. W. Field, and L. A. Kaledin, “Laser Spectroscopy of Dysprosium Monofluoride: Ligand

Field Assignments of States Belonging to the 4 f96s2, 4 f106s, and 4 f96s6p Superconfigurations,” J. Mol. Spectrosc. 179, 253-262 (1996). http://dx.doi.org/10.1006/jmsp.1996.0204

226. M. C. McCarthy, H. Kanamori, T. C. Steimle, M. Li, and R. W. Field, “Sideband Optical-Optical Double Resonance Zeeman

Spectroscopy. II. Studies of NiH, PdD, and PtH,” J. Chem. Phys. 107, 4179-4188 (1997). http://dx.doi.org/10.1063/1.474792 227. A. L. Kaledin, M. C. Heaven, R. W. Field, and L. A. Kaledin, “The Electronic Structure of the Lanthanide Monohalides: A

Ligand Field Approach,” J. Mol. Spectrosc. 179, 310-319 (1996). http://dx.doi.org/10.1006/jmsp.1996.0209 228. Z. Jakubek and R. W. Field, “Core-Penetrating Rydberg Series of BaF: New Electronic States in the n* ≈ 4 Region,” J. Mol.

Spectrosc. 179, 99-124 (1996). http://dx.doi.org/10.1006/jmsp.1996.0189 229. D. J. Nesbitt and R. W. Field, “Vibrational Energy Flow in Highly Excited Molecules: Role of Intramolecular Vibrational

Redistribution,” J. Phys. Chem. 100, 12,735-12,756 (1996). http://dx.doi.org/10.1021/jp960698w 230. J. T. Bahns, C. C. Tsai, B. Ji, J. T. Kim, G. Zhao, W. C. Stwalley, J. C. Bloch, and R. W. Field, “Laser Frequency-Modulated

Spectroscopy of a Laser-Guided Plasma in Sodium Vapor: Line Positions for NaH (A1∑+ – X1∑+), Na (9-13d and 11-14s), and Ar (5p-4s),” J. Mol. Spectrosc. 186, 222-229 (1997). http://dx.doi.org/10.1006/jmsp.1997.7441

231. R. W. Field, J. P. O'Brien, M. P. Jacobson, S. A. B. Solina, W. F. Polik, and H. Ishikawa, “Intramolecular Dynamics in the

Frequency Domain,” Adv. in Chem. Phys. 101, 463-490 (Solvay Conference 1995), 1997. http://dx.doi.org/10.1002/9780470141601.ch19

232. R. W. Field and C.M. Gittins, “Realistic Representation of the Induced Electric Dipole Moment on a Polarizable Ligand: The

Missing Factor in the Rittner Polarization Model,” J. Chem. Phys. 106, 10379-10382 (1997). http://dx.doi.org/10.1063/1.474107

233. a) J. Janni, B. D. Gilbert, R. W. Field, and J. I. Steinfeld, “Infrared Absorption of Explosive Molecule Vapors,”

Spectrochimica ACTA, A 53, 1375-1381 (1997). http://dx.doi.org/10.1016/S1386-1425(97)00053-X b) B. D. Gilbert, J. Janni, D. Moss, M. Kixmoeller, R. W. Field, J. I. Steinfeld, K. Kniepp, Y. Wang, R. R. Dasari, and M. S.

Feld, “Spectroscopic Detection Methods for Explosive Molecules and their Fragmentation Products,” Proc. 5th. Int. Symp. on Analysis and Detection of Explosives, Chantilly, VA, December, 1995.

c) B. D. Gilbert, J. Janni, D. Moss, R. W. Field, J. I. Steinfeld, and A. Mercado, “Raman Techniques for Detection of

Explosive Materials,” Proc. Optical Soc. of Am., Topical Meeting on Laser Applications to Chemical and Environmental Analysis, p. 109-111, Orlando, FL March, 1996.


234. P. J. Dagdigian, D. F. Varley, R. Liyanage, R. J. Gordon, and R. W. Field, “Detection of DCl by Multiphoton Ionization and

Determination of DCl and HCl Internal State Distributions,” J. Chem. Phys. 105, 10251-10262 (1996). http://dx.doi.org/10.1063/1.472954

235. M. C. McCarthy and R. W. Field, “Sideband Optical-Optical Double Resonance Zeeman Spectroscopy. III. Analysis of

Composite Lines and Selective Detection,” J. Chem. Phys. 107, 4189-4193 (1997). http://dx.doi.org/10.1063/1.474793 236. M. A. Temsamani, M. Herman, S. A. B. Solina, J. P. O'Brien, and R. W. Field, “Highly Vibrationally Excited 12C2H2 in the

X~ 1∑+g State: Complementarity of Absorption and Dispersed Fluorescence Spectra,” J. Chem. Phys. 105, 11357-11359

(1996). http://dx.doi.org/10.1063/1.472995 237. S. Drucker, J. P. O'Brien, P. Patel, and R. W. Field, “The Effects of Triplet Perturbers on Photophysical Processes in the A~

1Au State of Acetylene,” J. Chem. Phys. 106, 3423-3426 (1997). http://dx.doi.org/10.1063/1.473073 238. Z. J. Jakubek and R. W. Field, “Core-Penetrating Rydberg Series of BaF: Single-State and Two-State Fits of New Electronic

States in the 4.4 ≤ n* ≤ 14.3 Region,” J. Mol. Spectrosc. 205, 197-220 (2001). http://dx.doi.org/10.1006/jmsp.2000.8264

239. S.-H. Lee, I-C. Chen, G. W. Adamson, and R. W. Field, “The Fluorescence Excitation Spectrum of HCO B~2A′–X~2A′ 000

Band,” J. Mol. Spectrosc. 182, 385-395 (1997). http://dx.doi.org/10.1006/jmsp.1996.7228 240. H. Ishikawa, C. Nagao, N. Mikami, and R. W. Field, “Observation of the ‘Isomerization States’ of HCP by Stimulated

Emission Pumping Spectroscopy: Comparison between Theory and Experiment,” J. Chem. Phys. 106, 2980-2983 (1997). http://dx.doi.org/10.1063/1.473417

241. Z. J. Jakubek and R. W. Field, “Rydberg Series of BaF: Perturbation-Facilitated Studies of Core-Non-Penetrating States,”

Phil. Trans. Roy. Soc. Lond. A 355, 1507-1526 (1997). http://dx.doi.org/10.1098/rsta.1997.0073 242. S. J. Humphrey, C. G. Morgan, A. M. Wodtke, K. L. Cunningham, S. Drucker, and R. W. Field, “Laser Excited Metastable

States of Acetylene in the 5.5–5.7 eV Region,” J. Chem. Phys. 107, 49--53 (1997). http://dx.doi.org/10.1063/1.474351 243. L. A. Kaledin, M. C. Heaven, and R. W. Field, “Thermochemical Properties (D0

0 and IP) of the Lanthanide Monohalides,” J. Mol. Spectrosc. 193, 285-292 (1999). http://dx.doi.org/10.1006/jmsp.1998.7750

244. M. P. Jacobson, S. L. Coy, and R. W. Field, “Extended Cross Correlation: A Technique for Spectroscopic Pattern

Recognition,” J. Chem. Phys. 107, 8349-8356 (1997). http://dx.doi.org/10.1063/1.475035 245. S. L. Coy, M. P. Jacobson, and R. W. Field, “Identifying Patterns in Multicomponent Signals by Extended Cross

Correlation,” J. Chem. Phys. 107, 8357-8369 (1997). http://dx.doi.org/10.1063/1.475036 246. L. A. Kaledin, J. C. Bloch, M. C. McCarthy, and R. W. Field, “Analysis and Deperturbation of the A2∏ and B2∑+ States of

CaF,” J. Mol. Spectrosc. 197, 289-296 (1999). http://dx.doi.org/10.1006/jmsp.1999.7909 247. A. Strizhev, X. Li, R. Liyanage, R. J. Gordon, and R. W. Field, “A Unified Model of the Dynamics and Spectroscopy of the g

3∑–0and E 1∑+ States of Hydrogen Chloride,” J. Chem. Phys. 108, 984-989 (1998). http://dx.doi.org/10.1063/1.475461

248. J. P. O'Brien, M. P. Jacobson, J. J. Sokol, , S. L. Coy, and R. W. Field, “Numerical Pattern Recognition Analysis of

Acetylene Dispersed Fluorescence Spectra,” J. Chem. Phys. 108, 7100-7113 (1998). http://dx.doi.org/10.1063/1.476127 249. Y. Liu, J. Li, H. Gao, D. Chen, Li Li, R. W. Field, and A. M. Lyyra, “Predissociation of the Na2 3 3∏g and Other Triplet

States,” J. Chem. Phys. 108, 2269-2276 (1998). http://dx.doi.org/10.1063/1.475611 250. E. Hirota, R. W. Field, J. P. Maier, and S. Tsuchiya (editors), “Nonlinear Spectroscopy for Molecular Structure

Determination,” 276pp., IUPAC monograph, Blackwell Science Ltd., Oxford, 1998. 251. J. Li, Y. Liu, H. Gao, H. Chen, J. Xian, G. Wu, D. Chen, Li Li, and R. W. Field, “Predissociation of the Na2 4 3∑+

g State,” J. Chem. Phys. 108, 7707-7712 (1998). http://dx.doi.org/10.1063/1.476206


252. M. P. Jacobson, J. P. O'Brien, R. J. Silbey, and R. W. Field, “Pure Bending Dynamics in the Acetylene X~ 1∑+

g State to 15,000 cm−1 of Internal Energy,” J. Chem. Phys. 109, 121-133 (1998). http://dx.doi.org/10.1063/1.476529

253. A. J. Marr, S. W. North, T. J. Sears, L. Ruslen, and R. W. Field, “Laser Transient Absorption Spectroscopy of

Bromomethylene,” J. Mol. Spectrosc. 188, 68-77 (1998). http://dx.doi.org/10.1006/jmsp.1997.7500 254. H. Ishikawa, C. Nagao, N. Mikami, and R. W. Field, “Spectroscopic Investigation of the Generation of ‘Isomerization’

States: Eigenvector Analysis of the Bend-CP Stretch Polyad,” J. Chem. Phys. 109, 492-503 (1998). http://dx.doi.org/10.1063/1.476586

255. F. Wallimann, S. Leutwyler, and R. W. Field, “Resonant Two-Photon Ionization Spectroscopy of the AuKr van der Waals

Complex,” unpublished (1998). 256. Y. Liu, J. Li, H. Chen, D. Chen, Li Li, and R. W. Field, “The 43∏g and 63∏g States of Na2: Observation and Assignment,”

J. Mol. Spectrosc. 192, 32-40 (1998). http://dx.doi.org/10.1006/jmsp.1998.7660 257. R. Liyanage, R. J. Gordon, and R. W. Field, “Diabatic Analysis of the Electronic States of Hydrogen Chloride,” J. Chem.

Phys. 109, 8374-8387 (1998). http://dx.doi.org/10.1063/1.477500 258. I. Dubinsky, K. Rybak, J. I. Steinfeld, and R. W. Field, “Frequency-Modulation-Enhanced Remote Sensing,” Appl. Phys. B.

67, 481-492 (1998). http://dx.doi.org/10.1007/s003400050533 259. M. P. Jacobson, J. P. O'Brien, and R. W. Field, “Anomalously Slow IVR in the Acetylene X~1∑+

g State above 10,000 cm−1 of internal energy,” J. Chem. Phys. 109, 3831 - 3840 (1998). http://dx.doi.org/10.1063/1.476983

260. H. Chen, Li Li, G. Lazarov, X. Wang, A. M. Lyyra, J. Huennekens, and R. W. Field, “Rotational Pattern Difference in

Resolved Fluorescence Spectra with Different Detection Schemes,” J. Mol. Spectrosc. 196, 197-211 (1999). http://dx.doi.org/10.1006/jmsp.1999.7873

261. J. Li, Y. Liu, D. B. Moss, C. M. Gittins, N. Harris, and R. W. Field, “Double-Resonance Spectroscopic Studies of Core-

Penetrating Rydberg States of CaCl,” J. Mol. Spectrosc. 193, 403 - 411 (1999). http://dx.doi.org/10.1006/jmsp.1998.7746 262. J. O. Clevenger, N. A. Harris, R. W. Field, and J. Li, “The Predissociation Mechanism for 2∑+ Rydberg States of CaCl,” J.

Mol. Spectrosc. 193, 412 - 417 (1999). http://dx.doi.org/10.1006/jmsp.1998.7755 263. M. P. Jacobson, R. J. Silbey, and R. W. Field, “Local Mode Behavior in the Acetylene Bending System,” J. Chem. Phys. 110,

845 - 859 (1999). http://dx.doi.org/10.1063/1.478052 264. M. P. Jacobson, C. Jung, H. S. Taylor, and R. W. Field, “State-by-State Assignment of the Bending Spectrum of Acetylene at

15,000 cm−1: A Case Study of Quantum-Classical Correspondence,” J. Chem. Phys. 111, 600-618 (1999). http://dx.doi.org/10.1063/1.479341

265. M. P. Jacobson, S. L. Coy, R. W. Field, S. J. Lipson, R. B. Lockwood, D. L. Vititoe, W. A. M. Blumberg, and P. S.

Armstrong, “Numerical Pattern Recognition Analysis of CO Atmospheric Simulation Experiments,” J. Phys. Chem. A 104, 249-257 (2000). http://dx.doi.org/10.1021/jp9924732

266. D. B. Moss, R. Duan, M. P. Jacobson, J. P. O’Brien, and R. W. Field, “Observation of Coriolis Coupling Between ν2 + 4ν4

and 7ν4 in Acetylene X~1∑+g by Stimulated Emission Pumping Spectroscopy,” J. Mol. Spectrosc. 199, 265-274 (1999).

http://dx.doi.org/10.1006/jmsp.1999.7994 267. R. H. Lipson and R. W. Field, “Toward a Global and Causal Understanding of the Unusual Rydberg State Potential Energy

Curves of the Heteronuclear Rare Gas Dimers,” J. Chem. Phys. 110, 10,653 - 10,656 (1999). http://dx.doi.org/10.1063/1.479009

268. H. Ishikawa, R. W. Field, S. C. Farantos, M. Joyeux, J. Koput, C. Beck, and R. Schinke, “HCP→CPH Isomerization: Caught

in the Act!,” Annu. Revs. Phys. Chem. 50, 443-484 (1999). http://dx.doi.org/10.1146/annurev.physchem.50.1.443


269. M. Joyeux, D. Sugny, V. Tyng, M. E. Kellman, H. Ishikawa, R. W. Field, C. Beck, and R. Schinke, “Semiclassical Study of the Isomerization States of HCP,” J. Chem. Phys. 112, 4162-4172 (2000). http://dx.doi.org/10.1063/1.481001

270. M. P. Jacobson and R. W. Field, “Acetylene at the Threshold of Isomerization,” J. Phys. Chem. A (feature article) 104, 3073-

3086 (2000). http://dx.doi.org/10.1021/jp992428u 271. a) S. Yang, M. Canagaratna, S. Witonsky, S. L. Coy, J. I. Steinfeld, R. W. Field, and A. Kachanov, “Intensity Measurements

and Collision-Broadening Coefficients for the Oxygen A Band Measured by Intracavity Laser Absorption Spectroscopy,” J. Mol. Spectrosc., 201, 188-197 (2000). http://dx.doi.org/10.1006/jmsp.2000.8096

b) J. J. Steinfeld, R. W. Field, M. Gardner, M. Canagaratna, S. Yang, A. Gonzalez-Casielles, S. Witonsky, P. Bhatia, B.

Gibbs, B. Wilkie, S. L. Coy, and A. Kachanov, “New Spectroscopic Methods for Environmental Measurement and Monitoring,” Proc. SPIE-Int. Soc. Opt. Eng. (1999), #3853, pp. 28-33. http://dx.doi.org/10.1117/12.372839

272. M. P. Jacobson and R. W. Field, “Visualizing IVR: Expectation Values of Resonance Operators,” Chem. Phys. Lett. 320,

553-560 (2000). http://dx.doi.org/10.1016/S0009-2614(00)00306-7 273. A. F. Ruckstuhl, M. P. Jacobson, R. W. Field, and J. A. Dodd, “Baseline Subtraction Using Robust Local Regression

Estimation,” J. Quant. Spectr. Radiat. Transf. 68, 179-193 (2001). http://dx.doi.org/10.1016/S0022-4073(00)00021-2 274. X. Dai, J. O. Clevenger, Y. Liu, M. Song, J. Shang, D. Chen, R. W. Field, and Li Li, “The 23∆g State of 7Li2,” J. Mol.

Spectrosc. 200, 120-122 (2000). http://dx.doi.org/10.1006/jmsp.1999.8033 275. K. Hoshina, A. Iwasaki, K. Yamanouchi, M. P. Jacobson, and R. W. Field, “The IR-UV Dispersed Fluorescence Spectrum of

Acetylene: New Classes of Bright States,” J. Chem. Phys. 114, 7424 - 7442 (2001). http://dx.doi.org/10.1063/1.1333006 276. C. M. Gittins, N. A. Harris, Ma Hui, and R. W. Field, “Ionization-Detected Optical-Optical Double Resonance Spectroscopic

Studies of Moderate Energy Rydberg States of Calcium Monofluoride,” Canad. J. Phys. 79, 247 - 286 (2001). http://dx.doi.org/10.1139/p00-101

277. H. K. Srivastava, A. Conjusteau, H. Mabuchi, A. Callegari, K. K. Lehmann, G. Scoles, M. L. Silva, and R. W. Field, “Ro-

vibrational Spectroscopy of the v = 6 Manifold in 12C2H2 and 13C2H2,,” J. Chem. Phys. 113, 7376 - 7383 (2000)

http://dx.doi.org/10.1063/1.1310605 278. S. Altunata and R. W. Field, “A statistical approach for the study of singlet–triplet interactions in small polyatomic

molecules,” J. Chem. Phys. 113, 6640-6651 (2000). http://dx.doi.org/10.1063/1.1310614 279. J. M. Brown, R. J. Buenker, A. Carrington, C. di Lauro, R. N. Dixon, R. W. Field, J. T. Hougen, W. Hüttner, K. Kuchitsu, A.

J. Merer, T. A. Miller, M. Quack, D. A. Ramsay, A. J. Stone, and R. N. Zare, “Remarks on the Signs of g-factors in Atomic and Molecular Zeeman Spectroscopy,” Mol. Phys., 98, 1597-1601 (2000). http://dx.doi.org/10.1080/00268970009483366

280. J. Li, Y. Liu, X. Dai, Li Li, and R. W. Field, “Relabeling and Classification of the Rydberg States”, J. Chem. Phys. 114, 7859

- 7865 (2001). http://dx.doi.org/10.1063/1.1361252 281. Li Li, X. Dai, Y. Liu, J. O. Clevenger, R. W. Field, G.-H. Jeung, N. Geum, and A. M. Lyyra, “The Predissociation of the

13∑–g State of 7Li2,” J. Mol. Spectrosc. 205, 139 - 145 (2001). http://dx.doi.org/10.1006/jmsp.2000.8247

282. E. S. Hwang, J. B. Lipson, R. W. Field, and J. A. Dodd, “Detection of OH (X,v″,J″) via the B 2∑+–X 2∏ Transition and

Properties of the B 2∑+ State,” J. Phys. Chem. A 105, 6030 - 6037 (2001). http://dx.doi.org/10.1021/jp010088i 283. M. Silva, R. Jongma, R. W. Field, and A. M. Wodtke, “The Dynamics of ‘Stretched Molecules’: Experimental Studies of

Highly Vibrationally Excited Molecules with Stimulated Emission Pumping,” Ann. Rev. Phys. Chem. 52, 811 - 852 (2001). http://dx.doi.org/10.1146/annurev.physchem.52.1.811

284. S. Altunata and R. W. Field, “An Assumption-Violating Application of the Lawrance-Knight Deconvolution Procedure: A

Retrieval of Electronic Coupling Mechanisms Underlying Complex Spectra,” J. Chem. Phys. 114, 6557 - 6561 (2001). http://dx.doi.org/10.1063/1.1357788


285. S. K. Witonsky, M. R. Canagaratna, S. L. Coy, J. I. Steinfeld, R. W. Field, and A. A. Kachanov, “The 3ν1 Overtone Band of trans-Nitrous Acid: Rotational and Perturbation Analysis and Absolute Intensity,” J. Chem. Phys. 115, 3134 - 3143 (2001). http://dx.doi.org/10.1063/1.1386785

286. Y. Liu, B. Ji, A. S.-C. Cheung, W. C. Stwalley, R. W. Field, and Li Li, “The Hyperfine Structure of the 1 3∆g State of Na2,” J.

Chem. Phys. 115, 3647 - 3656 (2001). http://dx.doi.org/10.1063/1.1388548 287. S. Altunata, K. L. Cunningham, M. Canagaratna, R. Thom and R. W. Field, “The Mechanism of Surface Electron Ejection by

Laser Excited Metastable Molecules,” J. Phys. Chem. A 106, 1122-1130 (2002). http://dx.doi.org/10.1021/jp012219l 288. Li Li, A. Lazoudis, P. Yi, Y. Liu, J. Huennekens, R. W. Field, and A. M. Lyyra, “Hyperfine Structure of the 13∆g, 23∏g, and

33∑+g States of 6Li7Li”, J. Chem. Phys. 116, 10704-10712 (2002). http://dx.doi.org/10.1063/1.1478692

289. J. Qi, F. C. Spano, T. Kirova, A. Lazoudis, J. Magnes, Li Li, L. M. Narducci, R. W. Field, and A. M. Lyyra, “Measurement

of Transition Dipole Moments in Lithium Dimers Using Electromagnetically Induced Transparency,” Phys. Rev. Lett. 88, 173003-1-4 (2002). http://dx.doi.org/10.1103/PhysRevLett.88.173003

290. a) M. L. Silva, M. P. Jacobson, Z. Duan, and R. W. Field, “Unexpected simplicity in the S1 – S0 dispersed fluorescence

spectra of 13C2H2,” J. Chem. Phys. 116, 7939-7947 (2002). http://dx.doi.org/10.1063/1.1469018 b) M. L. Silva, M. P. Jacobson, Z. Duan, and R. W. Field, “Anomalous Simplicity of the A~ → X~ Dispersed Fluorescence

Spectrum of 13C2H2”, J. Mol. Struct. 565 - 566, 87-91 (2001). http://dx.doi.org/10.1016/S0022-2860(00)00780-8 291. S. N. Altunata, J. Cao, and R. W. Field, “Semiclassical Modeling of Rydberg Wave-Packet Dynamics in Diatomic

Molecules: Average Decoupling Theory”, Phys. Rev. A 65, 053415-1-16 (2002). http://dx.doi.org/10.1103/PhysRevA.65.053415

292. J. F. Harrison, R. W. Field, and C. C. Jarrold, “Comparison of CaF, CaO, ZnF, and ZnO, Their Anions and Cations in Their

Ground and Low-Lying Excited States,” pp. 238-259, Chapter 11 in ACS Symposium Series No. 828, Low-Lying Potential Energy Surfaces, 2002.

293. A. P. Mishra, R. L. Thom, S. Altunata, and R. W. Field, “Study of Intramolecular Dynamics of Highly Energized Small

Molecules Using Laser Spectroscopic Techniques,” in Current Developments in Atomic, Molecular, and Chemical Physics with Applications (ed. Man Mohan), 2003, Kluwer, New York.

294. S. N. Altunata and R. W. Field, “Modeling LiH Potential Energy Curves: An Approach Based on Integration in Finite

Space”, Phys. Rev. A. 67, 022507-1-13 (2003). http://dx.doi.org/10.1103/PhysRevA.67.022507 295. Z.-H. Loh and R. W. Field, “Contrasting Origins of the Isomerization Barriers for Vinylidene, Fluorovinylidene, and

Difluorovinylidene,” J. Chem. Phys. 118, 4037-4044 (2003). http://dx.doi.org/10.1063/1.1540625 296. A. J. Merer, N. Yamakita, S. Tsuchiya, J. F. Stanton, Z. Duan, and R. W. Field, “New Vibrational Assignments in the

A~1Au – X~1 Σg+ Electronic Transition of Acetylene”, Mol. Phys. 101, 663-673 (2003).

http://dx.doi.org/10.1080/0026897021000023640 297. A. P. Mishra, R. W. Field, S. V. N. B. Rao, R. D’Souza, and T. K. Balasubramanian, “Absorption Intensities of the

Multipole-Field-Induced Zero-Phonon Transitions in Solid HD, HT, and DT,” Phys. Rev. B. 67, 134305:1-9 (2003). http://dx.doi.org/10.1103/PhysRevB.67.134305

298. A. P. Mishra and R. W. Field, “Absorption Intensities of the Multipole-Field-Induced Double Transitions Involving a

Homonuclear-Heteronuclear Pair of Hydrogen Molecules in Condensed Phase,” Phys. Rev. B. 68, 184303:1-8 (2003). http://dx.doi.org/10.1103/PhysRevB.68.184303

299. Y. Liu, Li Li, G. Lazarov, A. Lazoudis, A. M. Lyyra, and R. W. Field, “Hyperfine Structures of the 2 3∑+

g , 3 3∑+g, and 4 3∑+

g States of Na2,” J. Chem. Phys. 121, 5821-5827 (2004). http://dx.doi.org/10.1063/1.1780162

300. H. Lefebvre-Brion and R. W. Field, “The Spectra and Dynamics of Diatomic Molecules,” Elsevier, 2004.


301. A. P. Mishra, R. L. Thom, and R. W. Field, “New S1 State Vibrational and T3, 2, 1 Spin-Rotational Assignments in the Vicinity

of the Acetylene A~1Au – X~1∑+g V3

0K10 Band,” J. Mol. Spectrosc. 228, 565-579 (2004).

http://dx.doi.org/10.1016/j.jms.2004.08.001 302. J. J. Kay, D. S. Byun, J. O. Clevenger, X. Jiang, V. S. Petrovi´c, R. Seiler, J. R. Barchi, A. J. Merer, and R. W. Field, “

‘Spectrum-Only’ Assignment of Core-Penetrating and Core-Nonpenetrating Rydberg States of Calcium Monofluoride,” Canad. J. Chem. 82, 791-803 (2004). http://dx.doi.org/10.1139/V04-071

303. Z. Duan, N. Yamakita, S. Tsuchiya, and R. W. Field, “Differential Temperature Laser Induced Fluorescence Spectroscopy,”

Chem. Phys. 324, 709-720 (2006). http://dx.doi.org/10.1016/j.chemphys.2005.12.017 304. P. Yi, M. Song, Y. Liu, R. W. Field, Li Li, and A. M. Lyyra, “Experimental Observation of Autler-Townes Splitting of the

Na2 A1 Σu+ ~ b3∏u Mixed Levels,” Opt. Commun. 233, 131-138 (2004). http://dx.doi.org/10.1016/j.optcom.2004.01.025

305. S. Yang, J. Cao and R. W. Field, “A Semiclassical Study of Wave Packet Dynamics in Anharmonic Potentials,” J. Chem.

Phys., 121, 6599-6607 (2004). http://dx.doi.org/10.1063/1.1791131 306. J. W. Taylor, G. Ehlker, H.-H. Carstensen, L. Ruslen, R. W. Field and W. H. Green, “Direct Measurement of the Fast,

Reversible Addition of Oxygen to Cyclohexadienyl Radicals in Nonpolar Solvents,” J. Phys. Chem. A. 108, 7193-7203 (2004). http://dx.doi.org/10.1021/jp0379547

307. S. N. Altunata, S. L. Coy, and R. W. Field, “Properties of Nearly One-Electron Molecules: I. A Green’s Function

Approach”, J. Chem. Phys. 123, 084318-1 - 084318-12 (2005). http://dx.doi.org/10.1063/1.2005017 308. S. N. Altunata, S. L. Coy, and R. W. Field, “Properties of Nearly One-Electron Molecules: Application to the Rydberg

Spectrum of CaF”, J. Chem. Phys. 123, 084319-1 - 084319-12 (2005). http://dx.doi.org/10.1063/1.2005041 309. S. N. Altunata, S. L. Coy, and R. W. Field, “Broad Shape Resonance Effects in CaF Rydberg States,” J. Chem. Phys. 124,

194302-1 - 194302-9 (2006). http://dx.doi.org/10.1063/1.2192518 310. R. W. Field, C. M. Gittins, N. A. Harris, and Ch. Jungen, “Quantum Defect Theory of Dipole and Vibronic Mixing in

Rydberg States of CaF”, J. Chem. Phys. 122, 184314,1-10 (2005) http://dx.doi.org/10.1063/1.1893860 311. B. M. Wong, S. N. Altunata, and R. W. Field, “Analytical Calculations of Molecular Integrals for Multielectron R-Matrix

Methods,” J. Chem. Phys. 124, 014106-1 - 014106-9 (2006). http://dx.doi.org/10.1063/1.2137320 312. A. H. Steeves, H. A. Bechtel, S. L. Coy, and R.W. Field. “Millimeter-wave-detected, Millimeter-wave Optical Polarization

Spectroscopy (mmOPS)” J. Chem. Phys. 123, 141102-1 - 141102-4 (2005). http://dx.doi.org/10.1063/1.2069865 313. B. M. Wong, A. H. Steeves, and R. W. Field, “Electronic Signatures of Large Amplitude Motions: Dipole Moments of

Vibrationally Excited Local-Bend and Local-Stretch States of S0 Acetylene,” J. Phys. Chem. B 110, 18,912-18,920 (2006). http://dx.doi.org/10.1021/jp061924x

314. R. W. Field, O. Pirali and D. W. Tokaryk, “The Spin-Orbit and Rotational Constants for the N2 C″ 5∏ui (v = 3) State,” J.

Chem. Phys. 124, 081103-1 - 081103-3 (2006). http://dx.doi.org/10.1063/1.2172919 315. F. Xie, D. Li, Li Li, R. W. Field and S. Magnier, “Infrared-Infrared Double Resonance Spectroscopy of 39K2: The 1 3∆g

State,” Chem. Phys. Lett. 431, 267-271 (2006). http://dx.doi.org/10.1016/j.cplett.2006.10.002 [INCORRECT DOI] 316. H. A. Bechtel, A. H. Steeves, and R. W. Field, “Laboratory Measurements of the Hyperfine Structure of H14N12C and

D14N12C,” Astrophys. J. Lett. 649, L53-L56 (2006). http://dx.doi.org/10.1086/508272 317. B. M. Wong, R. L. Thom, and R. W. Field, “Accurate Inertias for Large-Amplitude Motions: Improvements on Prevailing

Approximations,” J. Phys. Chem. A 110(23), 7406-7413 (2006). http://dx.doi.org/10.1021/jp057504+ 318. M. A. Flory, R. W. Field, and L. M. Ziurys, “The Pure Rotational Spectrum of CrCN (X 6∑+): An Unexpected Geometry and

Unusual Spin Interactions,” Mol. Phys. 105, 585-597 (2007). http://dx.doi.org/10.1080/00268970601146872


319. R. L. Thom, B. M. Wong, R. W. Field, and J. F. Stanton, “Studies of Intersystem Crossing Dynamics in Acetylene,” J. Chem. Phys. 126, 184307/1-7 (2007). http://dx.doi.org/10.1063/1.2730832

320. B. H. Layne, L. M. Duffy, H. A. Bechtel, A. H. Steeves, and R. W. Field, “Beam Action Spectroscopy via Inelastic

Scattering,” J. Phys. Chem. A 111, 7398-7403 (2007). http://dx.doi.org/10.1021/jp0708650 321. P. Qi, J. Bai, E. Ahmed, A. M. Lyyra, S. Kotochigova, A. J. Ross, C. Effantin, P. Zalicki, J. Vigué, G. Chawla, R. W. Field,

T.-J. Whang, W. C. Stwalley, H. Knöckel, E. Tiemann, J. Shang, L. Li, and T. Bergeman, “New Spectroscopic Data, Spin-Orbit Functions, and Global Analysis of Data on the A 1∑+

u and b 3∏u States of Na2,” J. Chem. Phys., 127, 044301/1-17 (2007). http://dx.doi.org/10.1063/1.2747595

322. W. Bryan Lynch, H. A. Bechtel, A. H. Steeves, J. J. Curley, and R. W. Field, “Observation of the A~1A″ State of Isocyanogen,” J. Chem. Phys., 126, 244307/1-4 (2007). http://dx.doi.org/10.1063/1.2745295

323. J. J. Kay, S. N. Altunata, S. L. Coy, and R. W. Field, “Resonance between Electronic and Rotational Motions in Rydberg

States of CaF,” Mol. Phys., 105, 1661-1673 (2007). http://dx.doi.org/10.1080/00268970701549371 324. W. L. Virgo, K. L. Bittinger, A. H. Steeves, and R. W. Field, “Contrasting Singlet-Triplet Dynamical Behavior of Two

Vibrational levels of the Acetylene S1 2131B2 Polyad,” J. Phys. Chem. A 111, 12534-12537 (2007). http://dx.doi.org/10.1021/jp0760399

325. A. H. Steeves, A. J. Merer, H. A. Bechtel, A. R. Beck and R. W. Field, “Direct Observation of the Symmetric Stretching

Modes of A1Au Acetylene by Pulsed Supersonic Jet Laser Induced Fluorescence,” Mol. Phys. 106, 1867-1877 (2008). http://dx.doi.org/10.1080/00268970802353327

326. V. S. Petrovic and R. W. Field, “Polarization Dependence of Transition Intensities in Double Resonance Experiments:

Unresolved Spin Doublets,” J. Chem. Phys. 128, 014301/1-014301/8 (2008). http://dx.doi.org/10.1063/1.2816105 327. M. de Groot, R. W. Field, and W. J. Buma, “Interference in Acetylene Intersystem Crossing Acts as the Molecular Analog of

Young’s Double-Slit Experiment,” Proc. Nat. Acad. Sci. 106, 2510-2514 (2009). http://dx.doi.org/10.1073/pnas.0809159106 328. H. A. Bechtel, A. H. Steeves, B. M. Wong, and R. W. Field, “Evolution of Chemical Bonding during HCN↔HNC

Isomerization as Revealed Through Nuclear Quadrupole Hyperfine Structure,” Angewandte Chemie 47, 2969-2972 (2008). http://dx.doi.org/10.1002/anie.200705399

329. J. J. Kay, S. L. Coy, V. S. Petrovic, B. M. Wong, and R. W. Field, “Separation of Long-Range and Short-Range Interactions

in Rydberg States of Diatomic Molecules,” J. Chem. Phys. 128, 194301/1-20, (2008). http://dx.doi.org/10.1063/1.2907858

330. S. Zhou, D. Xie, D. Xu, H. Guo, and R. W. Field, “Theoretical Emission Spectra of HNC (~A1A″) on a New ab initio Potential Energy Surface,” Chem. Phys. Lett. 455, 145-150 (2008). http://dx.doi.org/10.1016/j.cplett.2008.02.064

331. A. J. Merer, N. Yamakita, S. Tsuchiya, A. H. Steeves, H. Bechtel, and R. W. Field, “Darling-Dennison Resonance and

Coriolis Coupling in the Bending Overtones of the ~A1Au State of Acetylene, C2H2,” J. Chem. Phys. 129, 054304/1-19 (2008). http://dx.doi.org/10.1063/1.2939246

332. E. H. Ahmed, P. Qi, B. Beser, J. Bai, R. W. Field, J. P. Huennekens and A. M. Lyyra, “Experimental Mapping of the

Absolute Magnitude of the Transition Dipole Moment Function, µe(R), of the Na2 A1 ∑u

+ −X1 ∑g

+ Transition,” Phys. Rev. A 77, 053414/1-7, (2008). http://dx.doi.org/10.1103/PhysRevA.77.053414

333. L. C. O’Brien, B. A. Borchert, A. Farquhar, S. Shaji, J. J. O’Brien and R. W. Field, “Intracavity Laser Absorption

Spectroscopy of AuO: Identification of the B2∑– - X2∏3/2 transition,” J. Mol. Spec. 252, 136-142 (2008). http://dx.doi.org/10.1016/j.jms.2008.07.006

334. J. J. Kay, Ch. Jungen, B. M.Wong, S. L. Coy, and R. W. Field, “A Quantum Defect model for the s, p, d and f Rydberg series

of CaF,” J. Chem. Phys. 134, 114313/1-21 (2011) http://dx.doi.org/10.1063/1.3565967 335. Publishers Note: J. J. Kay, Ch. Jungen, B. M.Wong, S. L. Coy, and R. W. Field, “A Quantum Defect model for the s, p, d

and f Rydberg series of CaF,” J. Chem. Phys. 136, 089903 (2012). http://dx.doi.org/10.1063/1.3685477


336. A. H. Steeves, H. A. Bechtel, A. J. Merer, N. Yamakita, S. Tsuchiya and R. W. Field, “Stretch-bend Combination Polyads in

the ~A1Au State of Acetylene, C2H2,” J. Mol. Spectros. 256, 256-278 (2009). http://dx.doi.org/10.1016/j.jms.2009.05.005 337. R. Vallon, S. H. Ashworth, P. Crozet, R. W. Field, D. Forthomme, H. Harker, C. Richard and A. J. Ross, “A Room-

Temperature Metal-Hydride Discharge Source, with Observations on NiH and FeH”, J. Phys. Chem. A 113, 13159-13166 (2009). http://dx.doi.org/10.1021/jp9033968

338. A. J. Merer, Z. Duan, J. K. G. Watson, and R. W. Field, “Perturbations in the 4ν3 Level of the A~ 1Au State of Acetylene, C2H2,” Canad. J. Phys. 87, 437-441 (2009). http://dx.doi.org/10.1139/P08-084

339. R. W. Field, J. Baraban, S. H. Lipoff and A. R. Beck, “Effective Hamiltonians” in Handbook of High-Resolution

Spectroscopies, M. Quack and F. Merkt, editors, John Wiley & Sons (2010). 340. V. Petrovic, J. J. Kay, S. Coy and R. W. Field, “The Stark effect in Rydberg states of a highly polar diatomic molecule: CaF,”

J. Chem. Phys. 131, 064301/1-14 (2009). http://dx.doi.org/10.1063/1.3179942 341. K. L. Bittinger and R. W. Field, “Deconvolution of spectral data using a doorway-coupling model Hamiltonian,” J. Chem.

Phys. 132, 134302/1-9 (2010). http://dx.doi.org/10.1063/1.3357311 342. H. J. Kulik, A. H. Steeves and R. W. Field, “Ab initio investigation of high multiplicity ∑+ – ∑+ optical transitions in the

spectra of CN and isoelectronic species,” J. Mol. Spectros. 258, 6-12 (2009). http://dx.doi.org/10.1016/j.jms.2009.08.008 343. R. W. Field, “Autobiography”, J. Phys. Chem. A 113, 13045-13075 (2009). http://dx.doi.org/10.1021/jp909444e 344. A. Ross, R. W. Field, and A. Adam, “Tribute: Biography of Colan Linton,” Can. J. Phys. 87(5), viii – xii (2009).

http://dx.doi.org/10.1139/P09-906 345. K. L. Bittinger, W. Virgo, and R. W. Field, “Time-Dependent Center-of-Gravity Metric Determines Key Dynamical Features

of Doorway-Mediated Intersystem Crossing,” J. Phys. Chem. Lett. 1, 2144-2148 (2010). http://dx.doi.org/10.1021/jz100526g 346. S. Soorkia, N. Shafizadeh, J. Lievin, M.-A. Gaveau, C. Pothier, J.-M. Mestdagh, B. Soep and R. Field, “Determination of the

Ground Electronic State in Transition Metal Halides: ZrF”, J. Phys. Chem. A 115, 9620-9632 (2011). http://dx.doi.org/10.1021/jp2004997

347. J. H. Baraban, A. R. Beck, A. H. Steeves, J. F. Stanton and R. W. Field, “Reduced dimension discrete variable representation

study of cis-trans isomerization in the S1 state of C2H2,” J. Chem. Phys. 134, 244311 (2011). http://dx.doi.org/10.1063/1.3570823

348. A. J. Merer, A. H. Steeves, J. H. Baraban, H. A. Bechtel and R. W. Field, “Cis-trans isomerization in the S1 state of

acetylene: identification of cis-well vibrational levels,” J. Chem. Phys. 134(24):244310 (2011). http://dx.doi.org/10.1063/1.3599091

349. K. L. Bittinger, W. L. Virgo and R. W. Field, “Spectral Signatures of Inter-System Crossing Mediated by Energetically

Distant Doorway Levels: Examples from the Acetylene S1 State,” J. Phys. Chem. A (feature article) 115, 11921-11943 (2011). http://dx.doi.org/10.1021/jp2037894

350. S. Fleischer, Y. Zhou, R. W. Field and K. A. Nelson, “Molecular Orientation and Alignment by Intense Single-Cycle THz

Pulses,” Phys. Rev. Lett. 107, 163603 (2011). http://dx.doi.org/10.1103/PhysRevLett.107.163603 351. K. Kuyanov-Prozument, A. Colombo, Y. Zhou, G. B. Park, V. S. Petrovic, S. L. Coy and R. W. Field, “Rydberg Chirped-

Pulse Millimeter-Wave Spectroscopy of Rydberg-Rydberg Transitions,” Phys. Rev. Lett 107, 143001 (2011). http://dx.doi.org/10.1103/PhysRevLett.107.143001

352. G. B. Park, A. H. Steeves, K. Kuyanov-Prozument, J. L. Neill and R. W. Field, “Design and evaluation of a pulsed-jet

chirped-pulse millimeter wave spectrometer for the 70-102 GHz region,” J. Chem. Phys. 135(2), 024202 (2011). http://dx.doi.org/10.1063/1.3597774

353. H. Loh, J. Wang, M. Grau, T. S. Yahn, R. W. Field, C. H. Greene and E. A. Cornell, “Laser-Induced Fluorescence Studies of

HfF+ produced by autoionization”, J. Chem. Phys. 135, 154308-1-7 (2011). http://dx.doi.org/10.1063/1.3652333 354. K. C. Cossel, D. N. Gresh, L. C. Sinclair, T. Coffey, L. V. Skripnikov, A. N. Petrov, N. S. Mosyagin, A. V. Titov, R. W.


Field, E. R. Meyer, E. A. Cornell and J. Ye, “Broadband velocity modulation spectroscopy of HfF+: towards a measurement of the electron electric dipole moment,” Chem. Phys. Lett. 546, 1-10 (2012). http://dx.doi.org/10.1016/j.cplett.2012.06.037

355. H. Loh, R. P. Stutz, T. S.Yahn, H. Looser, R. W. Field and E. A. Cornell, “REMPI Spectroscopy of HfF,” J. Mol. Spectrosc.

276-277, 49-56 (2012). http://dx.doi.org/10.1016/j.jms.2012.06.014

356. J. Baraban, P. Changala, A. Merer, A. Steeves, H. Bechtel and R. W. Field, “The ~A 1Au state of acetylene: ungerade vibrational levels in the region 45800 – 46550 cm–1,” Mol. Phys. 110, 2707-2723 (2012). http://dx.doi.org/10.1080/00268976.2012.706329

357. J. Baraban, J. Stanton, A. Merer and R. W. Field, “Anharmonic force fields of cis- and trans-S1 C2H2” Mol. Phys. 110, 2725-

2733 (2012). http://dx.doi.org/10.1080/00268976.2012.706328 358. N. Bartels, T. Schäfer, J. Hühnert, R. W. Field, and A. M. Wodtke, “Production of a beam of highly vibrationally excited CO

using perturbations,” J. Chem. Phys. 136, 214201 (2012). http://dx.doi.org/10.1063/1.4722090 359. S. Fleischer, R. W. Field and K. A. Nelson, “Commensurate Two-Quantum Coherences Induced by Time-Delayed THz

Fields,” Phys. Rev. Lett. 109, 123603 (2012). http://dx.doi.org/10.1103/PhysRevLett.109.123603 360. M. L. Niu, E. J. Salumbides, D. Zhao, N. de Oliveira, D. Joyeux, L. Nahon, R. W. Field and W. Ubachs, “High resolution

spectroscopy and perturbation analysis of the CO A1∏—X1∑+ (0,0) and (1,0) bands,” Mol. Phys. 111, 2163-2174 (2013). http://dx.doi.org/10.1080/00268976.2013.793889

361. A. Colombo, Y. Zhou, K. Prozument, S. L. Coy and R. W. Field, “Chirped-pulse millimeter-wave spectroscopy: Spectrum,

dynamics, and manipulation of Rydberg-Rydberg transitions” J. Chem. Phys. 138, 014301 (2013). http://dx.doi.org/10.1063/1.4772762

362. M. Gharaibeh, D. Clouthier, A. Kalemos, H. Lefebvre-Brion and R. W. Field, “A New, Definitive Analysis of a Very Old

Spectrum: The Highly Perturbed A2∏3/2u — X2∏3/2g Band System of the Chlorine Cation Cl2+( ) ” J. Chem. Phys. 137, 194317

(2012). http://dx.doi.org/10.1063/1.4765334 363. H. Lee, J. Baraban, R. W. Field and J. F. Stanton, “High-Accuracy Estimates for the Vinylidene-Acetylene Isomerization

Energy and the Ground State Rotational Constants of :C=CH2,” J. Phys. Chem. A 117, 11679-11683 (2013). http://dx.doi.org/10.1021/jp400035a

364. K. Prozument, R. G. Shaver, M. A. Ciuba, J. S. Muenter, G. B. Park, J. F. Stanton, H. Guo, B. M. Wong, D. S. Perry and R.

W. Field, “A New Approach Toward Transition State Spectroscopy,” Farad. Disc. 163, 33-57 (2013). DOI: http://dx.doi.org/10.1039/C3FD20160K

365. P. Bryan Changala, J. H. Baraban, J. F. Stanton, A. J. Merer and R. W. Field, “Reduced dimension rovibrational variational

calculations of the S1 state of C2H2. II. The S1 rovibrational manifold and the effects of isomerization”, J. Chem. Phys. 140, 024313 (2014). http://dx.doi.org/10.1063/1.4859876

366. Y. Zhou, D. Grimes, T. Barnum, D. Patterson, S. Coy, E. Klein, J. Muenter, and R. W. Field, “Direct detection of Rydberg-

Rydberg millimeter-wave transitions in a buffer gas cooled molecular beam,” Chem. Phys. Lett. 640, 124-136 (2015). http://dx.doi.org/10.1016/j.cplett.2015.10.010

367. C. C. Womack, K. N. Crabtree, L. McCaslin, O. Martinez Jr., R. W. Field, J. F. Stanton and M. C. McCarthy, “Gas-phase

structure determination of dihydroxycarbene, the smallest stable singlet carbene”, Angewandte Chemie 53(16), 4089-4092 (2014).http://dx.doi.org/10.1002/anie.201311082

368. A. H. Steeves, H. A. Bechtel, J. H. Baraban, and R. W. Field, “Communication: Observation of local-bender eigenstates in

acetylene,” J. Chem. Phys. 143, 071101/1-4 (2015). http://dx.doi.org/10.1063/1.4928638 369. J. Jiang, J. H. Baraban, M. L. Clark, and Robert W. Field “Laser-Induced Fluorescence Study of the S1 State of Doubly-

Substituted 13C Acetylene and Harmonic Force Field Determination,” J. Phys. Chem. A 117, 13696-13703 (2013). http://dx.doi.org/10.1021/jp407755m

370. K. Prozument, G. B. Park, R. G. Shaver, A.K. Vasiliou, J. M. Oldham, D. E. David, J. S. Muenter, J. F. Stanton, A. G. Suits,

G. B. Ellison, and Robert W. Field, “Chirped-Pulse Millimeter-Wave Spectroscopy for Dynamics and Kinetics Studies of Pyrolysis Reactions,” Phys. Chem. Chem. Phys. 16, 15739-15751 (2014). http://dx.doi.org/10.1039/C3CP55352C


371. G. B. Park, J. Baraban and R. W. Field, “Full Dimensional Franck-Condon Factors for the Acetylene A

1Au − X1∑g

+ Transition. II. Vibrational Overlap Factors for Levels Involving Excitation in Ungerade Modes” J. Chem. Phys. 141(13), 134305/1-14 (2014). http://dx.doi.org/10.1063/1.4896533

372. A. Velian, M. Nava, M. Temprado, Y. Zhou, R. W. Field and C. C. Cummins, “A Retro Diels-Alder Route to Diphosphorous

Chemistry: Molecular Precursor Synthesis, Kinetics of P2 Transfer to 1,3-Dienes, and Detection of P2 by Molecular Beam Mass Spectrometry,” J.A.C.S. 136(39), 13586-13589 (2014). http://dx.doi.org/10.1021/ja507922x

373. J. Oldham, C. Abeysekera, B. Joalland, L. Zack, K. Kuyanov-Prozument, I. Sims, G. B. Park, R. W. Field, and A.Suits, “A

Chirped-Pulse Fourier-Transform Microwave /Pulsed Uniform Flow Spectrometer: I. The Low-Temperature Flow System,” J. Chem. Phys. 141(15), 154202/1-154202/7 (2014). http://dx.doi.org/10.1063/1.4897979

374. G. B. Park, A. H. Steeves, J. H. Baraban and R. W. Field, “A Simplified Cartesian Basis Model for Intrapolyad Emission

Intensities in the Bent-to-linear Electronic Transition of Acetylene,” J. Phys. Chem. A 119(5), 857-865 (2015).http://dx.doi.org/10.1021/jp5113608

375. K. Prozument, Y. V. Suleimanov, B. Buesser, J. M. Oldham, W. H. Green, A. G. Suits and R. W. Field, “A Signature of

Roaming Dynamics in the Thermal Decomposition of Ethyl Nitrite: Chirped Pulse Rotational Spectroscopy and Kinetic Modeling” J. Phys. Chem. Lett. 5(21), 3641-3648 (2014). http://dx.doi.org/10.1021/jz501758p

376. C. E. Liekhus-Schmaltz, I. Tenney, T. Osipov, A. Sanchez-Gonzalez, N. Berrah, R. Boll, C. Bomme, C. Bostedt, J. D. Bozek,

S. Carron, R. Coffee, J. Devin, B. Erk, K. R. Ferguson, R. W. Field, L. Foucar, L. J. Frasinski, J. M. Glownia, M. Gühr, A. Kamalov, Jacek Krzywinski, H. Li, J. P. Marangos, T. J. Martinez, B. K. McFarland, S. Miyabe, B. Murphy, A. Natan, D. Rolles, A. Rudenko, M. Siano, E. R. Simpson, L. Spector, M. Swiggers, D. Walke, S. Wang, T. Weber, P. H. Bucksbaum, and V. S. Petrovic, “Ultrafast isomerization initiated by X-ray core ionization,” Nat. Comm. 6, 8199 (2015). http://dx.doi.org/10.1038/ncomms9199

377. C. C. Womack, M.-A. Martin-Drumel, G. G. Brown, R. W. Field, and M. C. McCarthy, “Observation of the smallest Criegee

intermediate CH2OO in the gas phase ozonolysis of ethylene”, Science Advances 1(2), e1400105 (2015) http://dx.doi.org/10.1126/sciadv.1400105.

378. C. Abeysekera, L. Zack, G. B. Park, B. Joalland, J. Oldham, K. Prozument, N. Ariyasingha, I. Sims, R. Field, and A. Suits, A

Chirped-Pulse Fourier-Transform Microwave /Pulsed Uniform Flow Spectrometer: II. Performance and applications for reaction dynamics,” J. Chem. Phys. 141(21), 214203/1-214203/9 (2014). http://dx.doi.org/10.1063/1.4903253

379. C. Abeysekera, B. Joalland, N. Ariyasingha, L. N. Zack, I. R. Sims, R. W. Field and A. G. Suits, “Product branching in the

low temperature reaction of CN with propyne by chirped-pulse microwave spectroscopy in uniform supersonic flows,” J. Phys.Chem. Lett. 6(9), 1599-1604 (2015). http://dx.doi.org/10.1021/acs.jpclett.5b00519

380. G. B. Park and R. W. Field, “Edge effects in chirped-pulse Fourier transform microwave spectra,” J. Mol. Spectrosc. 312, 54-

57 (2015). http://dx.doi.org/10.1016/j.jms.2015.03.010 381. G. Barratt Park, C. C. Womack, A. R. Whitehill, J. Jiang, S. Ono and R. W. Field, “Millimeter-wave optical double

resonance schemes for rapid assignment of perturbed spectra, with applications to the C! 1B2 state of SO2”, J. Chem. Phys. 142, 144201-1 – 144201-12 (2015). http://dx.doi.org/10.1063/1.4916908

382. J. H. Baraban, P. Bryan Changala, G. C. Mellau, J. F. Stanton, A. J. Merer and R. W. Field, “Spectroscopic Characterization

of Transition states”, Science 350, 1338-1342 (2015). http://dx.doi.org/10.1126/science.aac9668 383. R. W. Field, “Spectra and Dynamics of Small Molecules, Alexander von Humboldt Lectures” Spring Heidelberg, 2015.

http://dx.doi.org/10.1007/978-3-319-15958-4 384. R. Fernando, C. Qu, J. Bowman, R. W. Field, and A. Suits, “Does Infrared Multiphoton Dissociation of Vinyl Chloride Yield

Cold Vinylidene?,” J. Phys. Chem. Lett. 6, 2457-2462 (2015). http://dx.doi.org/10.1021/acs.jpclett.5b01031 385. M. Niu, E. J. Salumbides, A. N. Heays, N. de Oliveira, R. W. Field, and W. Ubachs, “Spectroscopy and perturbation analysis

of the CO A1∏–X1∑+ (2,0), (3,0) and (4,0) bands,” Mol. Phys. 114, 627-636 (2016). http://dx.doi.org/10.1080/00268976.2015.1108472

386. R. Hakalla, M. L. Niu, R. W. Field, E. J. Salumbides, A. N. Heays, G. Stark, J. R. Lyons, M. Eidelsberg, J. L. Lemaire, S. R.


Federman, M. Zachwieja, W. Szajna, P. Kolek, I. Piotrowska, M. Ostrowska-Kopec, R. Kepa, N. de Oliveira and W. Ubachs, “VIS and VUV spectroscopy of 12C17O and deperturbation analysis of the A1∏, v = 1–5 levels,” RSC Adv. 6, 31588-31606 (2016). http://dx.doi.org/10.1039/C6RA01358A

387. P. Bryan Changala, J. H. Baraban, A. J. Merer, and R. W. Field, “Probing cis-trans Isomerization in the S1 State of Acetylene

via H-Atom Action and Hot Band-Pumped IR-UV Double Resonance Spectroscopies,” J. Chem. Phys. 143, 084310/1-5 (2015). http://dx.doi.org/10.1063/1.4929588

388. G. B. Park, J. Jiang, C. A. Saladrigas, and R. W. Field, “Observation of b2 symmetry vibrational levels of the SO2 C~1B2 state:

Vibrational level staggering, Coriolis interactions, and rotation-vibration constants,” J. Chem. Phys. 144, 144311 (2016). http://dx.doi.org/10.1063/1.4944924

389. J. Jiang, G. B. Park, and R. W. Field, “The rotation-vibration structure of the SO2 C~1B2 state explained by a new internal

coordinate force field,” J. Chem. Phys. 144, 144312 (2016). http://dx.doi.org/10.1063/1.4945621

390. G. B. Park, J. Jiang, and R. W. Field, “The origin of unequal bond lengths in the C~1B2 state of SO2: Signatures of high-lying potential energy surface crossings in the low-lying vibrational structure,” J. Chem. Phys. 144, 144313/1-7 (2016). http://dx.doi.org/10.1063/1.4945622

391. H. C. Schewe, D. Zhang, G. Meijer, R. W. Field, B. G. Sartakov, G. C. Groenenboom, A. van der Avoird, and N. Vanhaecke,

“Stark-interference of electric and magnetic dipole transitions in the A – X band of OH,” Phys. Rev. 116, 153001/1-5 (2016). http://dx.doi.org/10.1103/PhysRevLett.116.153001

392. G. B. Park and R. W. Field, “Perspective: The first ten years of broadband chirped pulse Fourier transform microwave

spectroscopy,” J. Chem. Phys. 144, 200901/1-10 (2016). http://dx.doi.org/10.1063/1.4952762 393. W. Transue, A. Velian, M. Nava, M.-A. Martin-Drumel, C. Womack, J. Jiang, G.-L. Hou, X.-B. Wang, M. McCarthy, R. W.

Field, and C. Cummins, “A Molecular Precursor to Phosphaethyne and its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion,” J.A.C.S. 138, 6731-6734 (2016). http://dx.doi.org/10.1021/jacs.6b03910

394. S. L. Coy, D. D. Grimes, Y. Zhou, R. W. Field, and B. M. Wong, “Electric Potential Invariants and Ions-in-Molecules

Effective Potentials for Molecular Rydberg States,” J. Chem. Phys. 145, 234301/1-20 (2016). http://dx.doi.org/10.1063/1.4968228

395. G. Ch. Mellau, A. A. Kyuberis, O. L. Polyansky, N. Zobov and R. W. Field, “Saddle Point Localization of Molecular

Wavefunctions,” Sci. Rep. 6, 33068/1-11 (2016). http://dx.doi.org/10.1038/srep33068 396. C. Faust, J. Jones, J. Huennekens, and R. W. Field, “Experimental Studies of the NaCs 12(0+) [71∑+] State: Spin-Orbit and

Non-Adiabatic Interactions and Quantum Interference in the 12(0+) [71∑+] and 11(0+) [3∏0] Emission Spectra,” J. Chem. Phys. 146, 104302/1-19 (2017). http://dx.doi.org/10.1063/1.4976630

397. D. D. Grimes, S. L. Coy, T. J. Barnum, Y. Zhou, S. F. Yelin, and R. W. Field, “Direct Single-Shot Observation of Millimeter

Wave Superradiance in Rydberg-Rydberg Transitions,” Phys. Rev. A 95, 043818/1-8 (2017). https://doi.org/10.1103/PhysRevA.95.043818

398. R. Hakalla, M. L. Niu, R. W. Field, A. N. Heays, E. J. Salumbides, G. Stark, J. R. Lyons, M. Eidelsberg, J. L. Lemaire, S. R.

Federman, N. de Oliveira, and W. Ubachs, “Fourier-Transform Spectroscopy of13C17O and Deperturbation Analysis of the A1∏ (v = 0–3) Levels,” J. Quant. Spectros. & Rad. Trans. 189, 312-328 (2017). http://dx.doi.org/10.1016/j.jqsrt.2016.12.012

399. T. M. Trivikram, R. Hakalla, A. N. Heays, M. L. Niu, S. Scheidegger, E. J. Salumbides, N. de Oliveira, R. W. Field and W.

Ubachs, “Perturbations in the A1∏, v = 0 state of 12C18O Investigated via Different spectroscopic Techniques,” Mol. Phys. 115, 3178-3191 (2017). http://dx.doi.org/10.1080/00268976.2017.1356477

400 J. A. DeVine, M. L. Weichman, B. Laws, J. Chang, M. C. Babin, G. Balerdi, C. Xie, C. L. Malbon, W. C. Lineberger, D. R.

Yarkony, R. W. Field, S. T. Gibson, J. Ma, H. Guo, and D. M. Neumark, “Encoding of Vinylidene Isomerization in its Anion Photoelectron Spectrum,” Science 358, 336-339 (2017). http://dx.doi.org/10.1126/science.aao1905

401. D. D. Grimes, T. J. Barnum, Y. Zhou, A. P. Colombo, and R. W. Field, “Coherent Laser-Millimeter-Wave Interactions en


route to Coherent Population Transfer,“ J. Chem. Phys. 147, 144201/1-11 (2017). http://dx.doi.org/10.1063/1.4997624 402. R. Hakalla, T. Trivikram, A. Heays, E. J. Salumbides, N. de Oliveira, R. W. Field, and W. Ubachs, “Precision Spectroscopy

and Comprehensive Analysis of Perturbations in the A1∏(v = 0) state of 13C18O”, Mol. Phys. 117(1), 79-96 (2019). http://dx.doi.org/10.1080/00268976.2018.1495848

403. J. Jiang, C. A. Saladrigas, T. J. Erickson, C. L. Keenan, and R. W. Field, “Probing the Predissociated Levels of the S1 State of

Acetylene via H-atom Fluorescence and Photofragment Fluorescence Action Spectroscopy,” J. Chem. Phys. 149(17), 174309/1-29 (2018). https://dx.doi.org/10.1063/1.5045046

404. Y. Zhou, K. B. Ng, L. Cheng, D. N. Gresh, R. W. Field, J. Ye and E. A. Cornell, “Visible and Ultraviolet Laser Spectroscopy

of ThF,” J. Mol. Spectros.358, 1-16 (2019). https://dx.doi.org/10.1016/j.jms.2019.02.006 405. C. E. Gunthardt, C. J. Wallace, G. E. Hall, R. W. Field, and S. W. North, “Anomalous intensities in the 2+1 REMPI

Spectrum of the E 1∏ – X1∑+ Transition of CO,” J. Phys. Chem. A 123(13), 2780-2788 (2019). https://dx.doi.org/10.1021/acs.jpca.9b00109

406. J. Jiang, Z. Du, and R. W. Field, “Determination of the Sign of the Population Difference in a Two-Level System by

Frequency-Modulation Spectroscopy,” Mol. Phys. (published online 2019). http://dx.doi.org/10.1080/00268976.2019.1660007

407. J. Jiang, A. K. Muthike, T. J. Erickson, and R. W. Field, “One-color (212-220 nm) Resonantly-Enhanced (S1-S0) Multi-

Photon Dissociation of Acetylene,” J. Mol. Spectrosc. 361, 24-33 (2019) http://dx.doi.org/10.1016/j.jms.2019.05.006 408. J. Jiang, T. Barnum, S. Coy, and R. W. Field, “Analysis of Vibrational Autoionization of CaF Rydberg States,” J. Chem.

Phys. 150(15), 154305/1-11 (2019). http://dx.doi.org/10.1063/1.5091526 409. K. Bergmann, H.-C. Nägerl, C. Panda, G. Gabrielse, E. Miloglyadov, M. Quack, G. Seyfang, G. Wichmann, S. Ospelkaus, A.

Kuhn, S. Longhi, A. Szameit, P. Pirro, B. Hillebrands, X.-F. Zhu, J. Zhu, M. Drewsen, W. K. Hensinger, S. Weidt, T. Halfmann, H.-L. Wang, G. S. Paraoanu, N. V. Vitanov, J. Mompart, T. Busch, T. Barnum, D. Grimes, R. W. Field, M. G. Raizen, E. Narevicius, M. Auzinsh, D. Budker, A. Pálffy and C. H. Keitel, “Roadmap on STIRAP Applications,” J. Phys. B: At. Mol. Opt. Phys. 52, 202001/1-55 (2019). http://dx.doi.org/10.1088/1361-6455/ab3995

410. Y. Park, H. Kang, R. W. Field, and H. Kang, “The Frequency-Domain IR Spectrum of Ammonia Encodes Changes in

Molecular Dynamics Caused by a DC Electric Field,” Proc. Nat. Acad. Sci. 116, 23444-23447 (2019). https://dx.doi.org/10.1073/pnas.1914432116

411. B. A. Laws, S. T. Gibson, B. R. Lewis, and R. W. Field, “The Dicarbon Bonding Puzzle, Viewed with Photoelectron

Imaging,” Nat. Comm. (submitted). http://dx.doi.org/10.1038/s41467-019-13039-y 412. K. Prozument, J. H. Baraban, P. B. Changala, G. B. Park, R. G. Shaver, J. S. Muenter, S. J. Klippenstein, V. Y. Chernyak and

R. W. Field, “Vinyl Cyanide Photodissociation: Transition States Characterized by Chirped-Pulse Millimeter-Wave Measurement of HCN and DCN Vibrational Population Distributions,” Proc. Nat. Acad. Sci. 117, 146-151 (2020). DOI: http://dx.doi.org/10.1073/pnas.1911326116

413. J. Jiang, Z. Du, J. Liévin and R. W. Field, “One-Color (~220 nm) Resonance-Enhanced (S1–S0) Multi-Photon Dissociation of

Acetylene: Probe of the C2 A1∏u — X1∑+g band by Frequency Modulation Spectroscopy,” Mol. Phys.

https://doi.org/10.1080/00268976.2020.1724340.

PUBLICATIONS Robert W. Field 1. R. W. Field and T. H ...rwf.mit.edu/group/field_pubs.pdf · 1...

Documents

Transcript of PUBLICATIONS Robert W. Field 1. R. W. Field and T. H ...rwf.mit.edu/group/field_pubs.pdf · 1...