Vital Products for Your Workflow

Organic Synthesis

Organic Synthesis Vital Products for Your Workflow Visit fishersci.com/organicsynthesis or fishersci.ca/organicsynthesis to learn more.

Enhance Your Organic Synthesis WorkflowEach step in the organic synthesis workflow demands products and tools of exacting quality and reliability. Look to the Fisher Scientific channel as a comprehensive, cost-effective, and dependable source to support your requirements every step of the way. Use our chemical structure search tool to find a match on your molecule of interest.

Count on the Fisher Scientific channel to:

Chemical Structure Search Tool

Offer Chemical Expertise Contact one of our chemical specialists. They can answer specific questions and help you place an order. You can also access the Fisher Scientific Chemical Center. It’s a single source for research and production chemicals supported by a team of specialists.

Visit fishersci.com/chemspecialist or fishersci.ca/chemspecialist to learn more.

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For further information or to contact a Fisher Scientific Sales Representative, call customer service at 1-800-766-7000 in the U.S. or 1-800-234-7437 in Canada.

Search the Fisher Scientific chemical database for an exact or substructure match on your molecule of interest. You can also draw and modify standard organic chemical and organometallic structures.

Visit fishersci.com/structuresearch or fishersci.ca/structuresearch to learn more.

Preparation

You’re ready with lab coats, gloves, and more for safety, and equipment and consumables to handle applications of practically any scale.

Synthesis

From building blocks, catalysts, and solvents to timers, syringes, tubing, and more, you can find what suits your unique requirements.

Purification

Choose from a range of products and equipment to achieve precise purifications and enhance chromatography procedures.

Enhance absorption, chromatography, distillation, extraction, filtration, and more with a flexible choice of instruments, equipment, and supplies.

Analysis

Organic Synthesis Vital Products for Your Workflow Visit fishersci.com/organicsynthesis or fishersci.ca/organicsynthesis to learn more.

Access over 1.7 million products in North America, including the organic synthesis workflow products featured below.

In Canada, visit fishersci.ca/organicsynthesis to shop these categories.

Your One-Stop Shop

Preparation

Synthesis

Purification

Analysis

• Balances

• Heating Mantles

• Thermometers

• Spatulas

• Wash Bottles

• Weighing Dishes

• Fume Hoods

• Biohazardous Containers

• LN2 Storage Equipment

• Gloves

• Goggles

• Lab Coats

• Organic Compounds

• Organometallics

• Solvents

• Connectors & Fittings

• Time Keeping

• TLC Plates

• Chromatography Syringes

• Stoppers

• Film and Foil Wrapping

• General Purpose Wipers

• Tubing

• Desiccants & Drying Agents

• Filtration Products

• Glassware

• Funnels

• Rotary Evaporators

• Freeze Dryers

• Pumps

• Chromatography Consumables

• Flash Chromatography Cartridges

• LC Columns

• Column Packing

• Filter Paper

• Insulated Containers

• Crystallization Microplates

• Melting Point Instruments

• Heating & Drying Ovens

• Thin Layer Chromatography (TLC)

• NMR Tubes

Building Blocks: Explore more than 30,000 chemical building blocks to create a vast array of organic compounds with applications in medicinal chemistry, biochemistry, biotechnology, and more.

Cat. No. Description Quantity

AC157970025 Trimethyl Phosphate, 99% 50 mL, 500 mL, 2.5 L

AC293410500 1,1,1,3,3,3-Hexafluoro-2-Propanol, 99.9%, for Spectroscopy 5 g, 10 g, 25 g, 50 g

AAA10322.AP n-Hexadecane, 99% 100 mL, 500 mL, 2500 mL

AC112315000 1,8-Diaminooctane, 98% 25 g, 100 g, 500 g

AAH33605.06 2,3,5-Tri-O-benzyl-D-ribofuranose, 98% 1 g, 5 g

AAA17056.0B Sodium Salicylate, 99% 250 g, 1000 g

Acros Organics and Alfa Aesar

Organic Synthesis Compounds

Find compounds for each step of your organic synthesis workflow, including a wide variety of Acros Organics™ and Alfa Aesar™ chemicals, catalysts, and reagents.

Whether you’re performing structural analysis and confirmation by NMR or using qualitative techniques, the Acros Organics and Alfa Aesar portfolios can help you effectively complete your synthesis workflow.

Organic Reagents: Choose from our extensive selection of functional reagents, with air- and moisture-sensitive products in AcroSeal™ packaging for performance, convenience, and safety.

Cat. No. Description Quantity

AC157910025 Triethylamine, 99% 5 mL, 100 mL, 1 L, 2.5 L, 10 L

AC171445000 1-(3-Dimethylaminopropyl)-3-Ethylcarbodiimide Hydrochloride, 98+% 1 g, 10 g, 50 g, 100 g, 500 g

AC301600025 Ethylenediaminetetraacetic Acid, Tripotassium Salt Dihydrate, 99+% 100 g, 500 g, 2.5 kg

AC202460010 Hydrogen Peroxide, for Analysis, 35 wt.% Solution in Water, Stabilized 25 mL, 500 mL, 1 L, 2.5 L, 10 L

AC122020020 Imidazole, 99% 5 g, 100g, 500 g, 2 kg, 10 kg

AC213351000 n-Butyllithium, 2.5M Solution in Hexanes 100 mL, 800 mL

Find the Right Organics for Your Workfishersci.com/acros

Search for Chemicals by Structure

fishersci.com/structuresearch

Get Essential Reagents for Chemical Synthesisfishersci.com/synthetic-reagents

Organic Synthesis Vital Products for Your Workflow Visit fishersci.com/organicsynthesis or fishersci.ca/organicsynthesis to learn more.

Precious Metal Compounds and Homogenous Catalysts: Find precious metal salts and solutions manufactured to stringent specifications in varying purities and concentrations, plus homogenous catalysts for chemical transformations.

Cat. No. Description Quantity

AA1141414 Silver Nitrate, ACS, >99.9%, (Metals Basis) 5 g, 25 g, 100 g, 500 g

AA11034.18 Palladium(II) Chloride, 99.9%, (Metals Basis), Pd 59.5% Min 0.5 g, 2 g, 10 g, 50 g

AC441390050 Palladium(II) Acetate, 99.9%, (Trace Metal Basis) 1 g, 5 g

AC202380250 Tetrakis (Triphenylphosphine) Palladium(0), 99% 1 g, 5 g, 25 g, 100 g

AA39741.14 Gold(I) Sodium Thiosulfate Hydrate, 99.9%, (Metals Basis) 1 g, 5 g, 25 g

Purification Chemicals: Explore a range of chemicals for extraction, isolation, and purification after synthesis.

Cat. No. Description Quantity

AC360050010 Silica Gel, for Column Chromatography, Ultra Pure, 40-60μ, 60Å 1 kg, 5 kg, 30 kg

AA33337.36 Magnesium Sulfate, Anhydrous, 99.5% Min 500 g, 2 kg, 10 kg

AC120340025 n-Heptane, 99+% 1 L, 2.5 L, 5 L, 25 L

AC349675000 Celite™ 545 500 g, 2.5 kg, 10 g

AC124260010 Sodium Hydroxide, Pure, 1N Standard Solution 1 L, 5 L, 25 L

Analytical Chemicals: Choose products for analytical chemistry that are recognized for their purity and supported by our dedicated technical and sales teams.

Cat. No. Description Quantity

AC196660010 Bromine, 99.6%, for Analysis 25 mL, 250 mL, 1 L

AC176850250 Toluene, 99.8+%, for Analysis 500 mL, 1 L, 2.5 L, 5 L, 25 L

AC373650025 Potassium Iodide, 99+%, for Analysis 100 g, 500 g, 2.5 kg

AA42562.AE Total Organic Carbon (TOC), Standard Solution 100 mL, 500 mL

AA43804.AE Cyanide, Standard Solution, CN 1000μg/mL 100 mL, 500 mL

AA14652.AE Plasma Standard Solution, Au, Ir, Os, Pd, Pt, Re, Rh, Ru @ 100μg/mL 100 mL, 500 mL

Essential Chemicals: Find extra-dry solvents, bases, and salts to create the right conditions for your reaction, plus solvents and silica for separation and purification.

Cat. No. Description Quantity

AC326971000 Tetrahydrofuran, 99.85%, Extra Dry, Stabilized, AcroSeal Packaging 100 mL, 1 L, 2.5 L

AC388361000 Hydrogen Chloride, 4N Solution in 1, 4-Dioxane, AcroSeal Packaging 100 mL, 800 mL

AAA16973.36 Ammonium Citrate Tribasic, >97%, AcroSeal Packaging 100 g, 500 g

AC326800010 Acetone, 99.8%, Extra Dry 100 mL, 1 L

AC397201000 2-Methyltetrahydrofuran, 99+%, Extra Dry, Stabilizer Free, AcroSeal Packaging 100 mL, 1 L

AC610050040 Dichloromethane, for HPLC 4 L

AC326871000 N,N-Dimethylformamide, 99.8%, Extra Dry, AcroSeal Packaging 100 mL, 1 L, 2.5 L

Organic Synthesis Vital Products for Your Workflow Visit fishersci.com/organicsynthesis or fishersci.ca/organicsynthesis to learn more.

BUCHI chromatography systems, evaporators, and freeze dryers help make purification and other parts of your organic chemical analyses more efficient, effective, and productive.

Organic SynthesisVital Products for Your Workflow

BUCHI Chromatography Systems Safe and Simple to Use

BUCHI Pure Chromatography Systems feature a compact design that can be used without a fume hood. Choose from flash systems or a combination flash/prep HPLC for small- to large-scale purification of complex mixtures.

• Front-access cartridge and column holders • Small-footprint, extra-solvent platform• Integrated UV standard with ELSD optional • Remote control capable from PC, tablet, or smartphone

Cat. No. Description Quantity

05-405-103 Pure C-805, Flash Chromatography, 50 Bar, 725 psi Each

10-987-136 Pure C-810 Flash, Flash/UV, 50 Bar, 725 psi Each

10-987-137 Pure C-815 Flash, Flash/UV/ELSD, 50 Bar, 725 psi Each

10-987-138 Pure C-830 Flash, Prep HPLC/UV-Vis, 300 Bar, 4,350 psi Each

10-987-140 Pure C-850 Flash Prep, Flash/Prep HPLC/UV-Vis/ELSD, 300 Bar, 4,350 psi Each

11C80500ACA Pure C-805 for Academic Research, Flash Chromatography, 50 Bar, 725 psi Each

FlashPure Cartridges Compatible with Pure Chromatography Systems, BUCHI FlashPure cartridges offer high resolution separations and greater loading capacity. Cartridges are available in a wide range of sizes, covering different stationary phases, particle sizes, and geometries.

Organic Synthesis Vital Products for Your Workflow Visit fishersci.com/organicsynthesis or fishersci.ca/organicsynthesis to learn more.

BUCHI Rotary Evaporators Convenient and Versatile

BUCHI Rotavapor™ R-300 Rotary Evaporators offer a modular design that lets you expand to a fully integrated system with a central interface.

• Bath Capacity: 5 L • Bath Range: Up to 220°C• Speed: 10 to 280 rpm• Electrical Requirements: 100/120 V, 50/60 Hz• Certification: CE/CSA

Cat. No. Description Quantity

05-000-461 Rotavapor R-300 Rotary Evaporator, Manual Lift, Cold Trap* Glassware Each

05-000-491 Rotavapor R-300 Rotary Evaporator, Manual Lift, Vertical* Glassware Each

05-000-455 Rotavapor R-300 Rotary Evaporator, Manual Lift, Cold Trap Glassware Each

05-000-485 Rotavapor R-300 Rotary Evaporator, Manual Lift, Vertical Glassware Each

05-000-941 Rotavapor R-300 Rotary Evaporator, Electronic Lift, Cold Trap Glassware Each

05-000-947 Rotavapor R-300 Rotary Evaporator, Electronic Lift, Cold Trap* Glassware Each

05-000-977 Rotavapor R-300 Rotary Evaporator, Electronic Lift, Vertical* Glassware Each

*Safety-Coated Glassware

BUCHI Freeze Dryers Compact and Powerful

The BUCHI Lyovapor™ L-200 Classic Freeze Dryer offers semi-automated lyophilization in a compact design. Its Infinite-Control™ feature includes easy method creation and use, data logging, real-time chart recording, and remote access from mobile devices.

• Condenser Capacity: 6 kg• Drying Manifold or Shelves• Stainless Steel• Temperature Range: -55°C to +25°C• Electrical Requirements: 208/230 V

Cat. No. Description Quantity

05-403-001 Lyovapor L-200 Freeze Dryer, Manifold Rack, 12-Place, Mobile Trolley Each

05-405-430 Lyovapor L-200 Freeze Dryer, Manifold Rack, 12-Place Each

05-405-431 Lyovapor L-200 Freeze Dryer, Manifold Rack, 12-Place, Pfieffer Duo 6 Vacuum Pump Each

05-405-432 Lyovapor L-200 Freeze Dryer, Manifold Rack, 12-Place, Pfieffer Duo 6 Vacuum Pump, Mobile Trolley Each

05-405-433 Lyovapor L-200 Freeze Dryer, Manifold Rack, 12-Place, Edwards nXDS6iC Vacuum Pump Each

05-405-434 Lyovapor L-200 Freeze Dryer, Four Heatable Shelves, Edwards nXDS6iC Vacuum Pump Each

Organic Synthesis Vital Products for Your Workflow Visit fishersci.com/organicsynthesis or fishersci.ca/organicsynthesis to learn more.

With more than 60 years of synthesis experience, TCI specializes in organic reagents and products that are hard to find and difficult to synthesize.

Suzuki-Miyaura ReactionsSince its invention, the Suzuki-Miyaura Cross-Coupling Reaction has been one of the most powerful methods used in the formation of C-C bonds. It is also a useful procedure in the construction of the carbon skeletons of many biologically important compounds. TCI™ offers boronic acids, various metal catalysts and ligands, bases, metal scavengers, and other chemicals you need for Suzuki-Miyaura reactions.

Organic SynthesisVital Products for Your Workflow

Visit fishersci.com/suzuki-miyaura or fishersci.ca/suzuki-miyaura to learn more.

Phosphine LigandsPhosphine ligands help stabilize and activate the metal catalyst in Suzuki-Miyaura reactions. TCI offers an extensive line of these ligands for your research needs.

Visit fishersci.com/phosphine-ligands or fishersci.ca/phosphine-ligands to learn more.

Cat. No. Description Quantity

T0519100G Triphenylphosphine, 95.0 25 g, 100 g, 500 g

B20271G 1,1’-Bis(diphenylphosphino)ferrocene, 96.0+% 1 g, 5 g, 25 g

B238325G (+/-)-BINAP, 97.0+% 5 g, 25 g

B113825G 1,3-Bis(diphenylphosphino)propane, 98.0+% 5 g, 25 g

B27091G 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene, 98.0+% 1 g, 5 g, 25 g

B113710G 1,2-Bis(diphenylphosphino)ethane, 97.0+% 10 g, 25 g

T102425G Tri(o-tolyl)phosphine, 97.0+% 5 g, 25 g

T25841G Tri-tert-butylphosphonium Tetrafluoroborate, 98.0+% 1 g, 5 g

B124625G 1,4-Bis(diphenylphosphino)butane, 98.0+% 5 g, 25 g

C2979200MG cBRIDP(regR), 97.0+% 200 mg, 1 g

Organic Synthesis Vital Products for Your Workflow Visit fishersci.com/organicsynthesis or fishersci.ca/organicsynthesis to learn more.

Nickel CatalystsNickel catalysts offer an alternative to more expensive palladium catalysts. They also allow you to extend your Suzuki-Miyaura reaction to aryl fluorides, sulfamates, and other electrophiles.

Cat. No. Description Quantity

B22251G [1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride, 96.0+% 1 g, 5 g, 25 g

B13135G [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride, 98.0+% 5 g, 25 g

N009625G Bis(2,4-pentanedionato)nickel(II) Hydrate, 98.0+% 25 g, 100 g, 500 g

B35341G Bis(tricyclohexylphosphine)nickel(II) Dichloride, 95.0+% 1 g, 5 g

B157110G Bis(triphenylphosphine)nickel(II) Dichloride, 96.0+% 10 g, 100 g

S048750G Skeletal Nickel Catalyst Slurry in Water [Active Catalyst for Hydrogenation] 50 g

B131325G [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride, 98.0+% 5 g, 25 g

N0096100G Bis(2,4-pentanedionato)nickel(II) Hydrate, 98.0+% 25 g, 100 g, 500 g

B35345G Bis(tricyclohexylphosphine)nickel(II) Dichloride, 95.0+% 1 g, 5 g

B1571100G Bis(triphenylphosphine)nickel(II) Dichloride, 96.0+% 10 g, 100 g

Cat. No. Description Quantity

E007725M Ethylenediamine Anhydrous, 98.0+% 25 mL, 500 mL

M197925G 3-Mercaptopropyl Silica Gel (0.5-0.8mmol/g) 25 g

S08655G Si-TMT (=2,4,6-Trimercaptotriazine Silica Gel) (0.2-0.5mmol/g) 5 g

Visit fishersci.com/nickel-catalysts or fishersci.ca/nickel-catalysts to learn more.

Metal ScavengersExcess metal complexes created in reactions can lead to undesirable byproducts. When a metal scavenger is added to the reaction mixture, they bind to the metal complexes to remove them from the reaction mixture.

Visit fishersci.com/metal-scavengers or fishersci.ca/metal-scavengers to learn more.

Green Chemistry and ReusabilityAdvances in Suzuki-Miyaura chemistry allow many reactions to be run in water. Ionic liquids can also be used in certain reactions. These trials indicate that the products of the reaction can be extracted with high yield and the solvents and solutions successfully reused.

Contact your Fisher Scientific Sales Representative to learn more about TCI products for organic

Organic Synthesis Vital Products for Your Workflow Visit fishersci.com/organicsynthesis or fishersci.ca/organicsynthesis to learn more.

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