New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the...

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Transcript of New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the...

Page 1: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.
Page 2: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

New Area of Focus: Periodic Table of the Elements.

Copyright © 2010 Ryan P. Murphy

Page 3: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

New Area of Focus: Periodic Table of the Elements.

Copyright © 2010 Ryan P. Murphy

Page 4: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

The Periodic Table of the Elements is a…----

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Page 5: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

A chart of all the known elements.

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Page 6: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Is in order of increasing atomic number and mass.

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Page 7: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

H He

Li Be B C N O F Ne

Na Mg Al Si P S Cl Ar

K Ca Sc Ti Ga Ge As Se Br Kr

Atomic Mass and Atomic Number increases as you move across and down.

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Page 8: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

The table puts elements into groups with similar characteristics.

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Page 9: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Allows us to recognize trends over the whole array of elements.

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Page 10: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

• All of the elements in a period have the same number of atomic orbitals.

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IncreaseIn Energy

Page 11: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Please add to the sideEn

erg

y I

ncre

ases

Page 12: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Horizontal row is called a Period. (Same # of electron orbitals)

Vertical column is called a group/family. (Same # of valence electrons)

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Page 13: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

AMU increases from left to right and top to bottom.

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Page 14: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Density of elements increase down a group

Page 15: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

H He

Li Be B C N O F Ne

Na Mg Al Si P S Cl Ar

K Ca Sc Ti Ga Ge As Se Br Kr

AMU increases as you go from left to right, and from top to bottom

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Page 16: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Electronegativity increases from lower left to upper right.

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Moving top to bottom down the periodic table, electronegativity decreases.

Page 17: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

H He

Li Be B C N O F Ne

Na Mg Al Si P S Cl Ar

K Ca Sc Ti Ga Ge As Se Br Kr

Electron negativ

ity

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Page 18: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

• The most strongly electronegative element, Fluorine (F).

• The least electronegative element is Francium (Fr).

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“I want to give away

one electron.”

“I want to gain one electron”

“You guys should get together.”

Page 19: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Electronegativity - chemical property that describes the tendency of an atom to attract electrons towards itself.affected by both its atomic number and the

distance at which its valence electrons reside from the charged nucleus.

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Page 20: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Copyright © 2010 Ryan P. Murphy

Page 21: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

– Electrons with low ionization energies have a low electronegativity because their nuclei do not exert a strong attractive force on electrons.

– Elements with high ionization energies have a high electronegativity due to the strong pull exerted on electrons by the nucleus.

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and Ions)Ionization energy is the energy required to remove an electron. (Gases and Ions)

Increasing Ionization Energies

Page 22: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

The ionization energy (IE) is defined as the amount of energy required to remove electron from the outer shell

- increase as one moves from left to right within a given row (period) due to more electrons being added

- decrease as one moves down a column (group) because the outer electron shell is getting further away from the nucleus

Page 23: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

As atoms get smaller, the valence electrons are closer to the nucleus so the attractive force holding the electrons is stronger and makes it harder to remove

Page 24: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

New Area of Focus: Electron Orbitals

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Page 25: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Valence electrons: Electrons in the outer most shell.

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1 2 1 4 5 1

Total Electrons

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Lewis Dot Structure- atom model that represents the valence electrons only.

- the valence electrons of atoms are the electrons that interact during the formation of compounds

Page 27: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

En

erg

y I

ncre

ases

Page 28: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Drawing the Lewis Dot Structure for the first three rows.

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1 2 3 4 5 67 8

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Ion- an atom that has lost or gained electrons

- if losing electrons, the ion becomes more positive; ex. If it loses 2 electrons, it will have a +2 charge

- if gaining electrons, then the ion becomes more negative; ex. If it gains 2 electrons, it will have a -2 charge

Page 30: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

En

erg

y I

ncre

ases

+1 +2 0-1-2-3

+/- 4

+3Charges +2

or more

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Transition Metals are found in the middle.

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Transition Metals are…-----

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Page 33: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Malleable: To be shaped / made into sheets.

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Page 34: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Ductile: Made into wire.

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Page 36: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Good conductors of electricity.

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Page 37: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

• Copper (Cu) is a good conductor of electricity. – It is malleable and ductile.

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Page 38: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Have a high luster (shine).

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LUSTER

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Conducts heat well.

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Most have a high density.

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Page 41: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Most are solid.Hg (mercury is a liquid metal)

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Page 42: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Metallically bonded.

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Many metals are reactive to chemicals.

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Page 44: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Many metals are reactive to chemicals.

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Page 45: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Many metals are reactive to chemicals.

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Page 46: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Almost 75% of all elements are classified as metals.

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Page 47: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Alloys: Metals are easily combined

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Page 48: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

• Bronze age: Copper and tin

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Page 49: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

•  Continued Metals…

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Page 50: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

• Some of the metals. Use your table….– Actinide Metals, Lanthanide Metals, Alkali Metals,

Alkaline-Earth Metals, Noble Metals, Rare Metals, Rare-Earth Metals, and Transition Metals

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Page 51: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

• Flame test– Can be used to visually determine the identity

of an unknown metal or metalloid ion based on the characteristic color when burned.

– The heat of the flame converts the metal ions into atoms which become excited and emit visible light.

– The characteristic emission spectra can be used to differentiate between some elements.• Learn more at…• http://www.chem.purdue.edu/bcce/Scaling_a_flashy

_demonstration.pdf

Page 52: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Metalloids / Semi metals: Properties of metals and non-metals---

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Page 53: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Semi-conductors

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Brittle

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Can have luster.

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Page 56: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

H He

Li Be B C N O F Ne

Na Mg Al Si P S Cl Ar

K Ca Sc Ti Ga Ge As Se Br Kr

Key: Metalloids / Semimetals

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Page 57: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Non-MetalsNot metals

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Page 58: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

H He

Li Be B C N O F Ne

Na Mg Al Si P S Cl Ar

K Ca Sc Ti Ga Ge As Se Br Kr

Key: Non-metals

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H

Page 59: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Non-metals…-----

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Page 60: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

H and He are non-metals.

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Page 61: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

They are poor conductors.

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Which is a conductor and which is a insulator?

ABInsulator

Conductor

Page 62: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

They are brittle (break when hit).

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Page 63: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Dull in color. (No Luster)

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Page 64: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Poor conductors of heat.

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Page 65: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

They may be transparent or translucent.

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Page 66: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

They exist as a… (s), (l), (g).

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Solid Liquid Gas

SSulfur Br

Bromine

ClChlorine

Page 67: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

Covalently bonded.

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CH4 Methane Electron Negativity Diff.Hydrogen = 2.20Carbon = 2.55 2.55 – 2.20 = .35

Differences 1.7 or greater, the bond is usually ionic, Differences Less than 1.7, the bond is usually covalent,

Unless the difference is less than 0.5 the bond has some degree of polarity Differences of less than 0.5 are considered to be nonpolar.

Nonpolar Covalent

Bond

Page 68: New Area of Focus: Periodic Table of the Elements. New Area of Focus: Periodic Table of the Elements. Copyright © 2010 Ryan P. Murphy.

They have a low density.

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Low or High?