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    Mid Semester Project Report

    MED 421

    On

    Tool Wear Model for Machining Of Titanium Alloy

    Project No: P05

    Submitted by

    Niteesh Verma (Entry No: 2008ME20581)

    Manish Mahi (Entry No: 2008ME20576)

    Supervised by

    Dr. Sudarshan Ghosh

    Examiner

    Prof. P.V Rao

    Mechanical Engineering Department

    Indian Institute of Technology Delhi

    September 2011

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    Contents

    S.No. TOPIC PAGE

    1) List Of Tables 32) Chapter 1: Introduction 4

    3) Chapter 2: Literature Review 8

    4) Chapter 3: Plan Of Work 13

    5) Chapter 4 : Work Schedule 15

    6) References 16

    7) Appendix 17

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    List of Tables

    S.No. Tables Page

    1 Average crater wear rates of various tool materials in turning of Ti-6Al-4V at

    200sfpm

    9

    2 Estimated solubilities of tool materials in titanium at various temperatures 17

    3 Reported solubilities of tool constituents 17

    4 Predicted wear rates from the upper bound Diffusion Model (at 1400K) 18

    5 Predicted Growth of TiC layer on Diamond 18

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    1)Introduction1.1) Titanium

    Titanium (Ti) is a chemical element with atomic number 22. It has a low density and

    is a strong, lustrous, corrosion-resistant transition metal with a silver color. Titanium

    can be alloyed with iron, aluminum, vanadium, molybdenum, among other elements,

    to produce strong lightweight alloys for aerospace (jet engines, missiles, and

    spacecraft), military, industrial process (chemicals and petro-chemicals, desalination

    plants, pulp, and paper), automotive, agri-food, medical prostheses, orthopedic

    implants, dental and endodontic instruments and files, dental implants, sporting

    goods, jewelry, mobile phones, and other applications.

    1.2) Salient Benefits of Using Titanium Alloys

    Due to their high tensile strength to density ratio, high corrosion resistance, and

    ability to withstand moderately high temperatures without creeping, titanium alloys

    are used in aircraft, armor plating, naval ships, spacecraft, and missiles. For these

    applications titanium alloyed with aluminium, vanadium, and other elements is used

    for a variety of components including critical structural parts, fire walls, landing gear,

    exhaust ducts (helicopters), and hydraulic systems. Ti also finds its usage in other

    fields also such as consumer goods, architectural applications, automobile industries

    and various industrial, aerospace, recreational, and emerging markets.

    1.3) Types of Ti alloysTitanium alloys fall into four classes, depending on the structures present alloys,

    near alloys, -alloys and alloys [1]

    alloys contain -stabilizers. The alloy has excellent tensile properties and creepstability at room and elevated temperatures up to 300C.

    Near alloys are highly -stabilized and contain only limited quantities of stabilizing elements. They behave more like alloys and are capable of operating

    at greater temperatures of between 400 and 520C.

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    - alloys contain addition of and stabilizers and they possess microstructuresconsisting of mixtures of and phases.

    alloys contain significant quantities of -stabilizers and are characterized byhigh hardenability, improved forgeability and cold formability, as well as highdensity

    1.4) Machining of titanium alloys

    Although quite a bit of work has been done in machining of hard to machine

    materials, but it has not kept its pace with the advancement of machinability of

    titanium and its alloys due to their high temperature strength, very low thermal

    conductivity, relatively low modulus of elasticity and high chemical reactivity. The

    principle problems associated with machining of titanium alloys are as follows:

    1.4.1) Generation of High cutting temperatureHigh cutting temperature act close to the cutting edge of the tool which is

    principle reason of the rapid tool wear, according to Ezugwu and wang [2] a

    large proportion (about 80%) of the heat generated when machining titanium

    alloy Ti-6Al-4V is conducted into the tool because it cannot be removed with

    the fast flowing chip into the work piece due to low thermal conductivity of

    titanium alloys

    1.4.2) Application of High cutting pressuresThe cutting forces recorded while machining of titanium alloys are similar to

    machining of steels, while much higher mechanical stresses occur at the

    cutting edge when machining titanium alloy. According to konig [3] stresses

    in titanium alloy are three to four times than that in nickel alloy (Nimonic-105). This may be due to unusually small chip tool contact area on the rake

    face. And high resistance of titanium alloy to deformation at elevated

    temperatures which reduces only above 800C may also cause that much

    difference in stresses.

    1.4.3) Chatter During Machining of Titanium AlloysPrincipal cause of the chatter during machining is due to the low modulus of

    elasticity of titanium alloys. When subjected to cutting pressure, titanium

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    deflects nearly twice as much as carbon steel the greater spring-back behind

    the cutting edge resulting in premature flank wear, vibration and higher cutting

    temperature. The appearance of chatter may also be partly attributed to the

    high dynamic cutting forces in the machining of titanium

    1.4.4) High Chemical Reactivity of the Titanium AlloyTitanium and its alloys react chemically with almost all tool materials

    available at cutting temperature in excess of 500C due to their strong

    chemical reactivity. The tendency for chips to pressure weld to cutting tools,

    severe dissolution-diffusion wear, which rises with increasing temperature,

    and this demand additional criteria in the choice of cutting tool materials

    1.5) Project focus

    Considering the extensive use of titanium and its alloys in the aerospace due to its

    excellent combination of high specific strength (strength to weight ratio) which is

    maintained at elevated temperature, its fractional resistant characteristics and its

    exceptional resistance to corrosion. Even a lot of research going on the machinability

    of the titanium alloys from past 60 years, but still there do not exist a reliable tool

    wear/tool life model. So we realized to predict a suitable and close tool wear model

    which would be a phenomenal achievement in the research field of titanium and will

    solve the problem of major industrial giants who are using titanium very extensively

    like G.E, Boeing etc. Due to very ambiguous properties of titanium scientists and

    researchers have tried a lot to derive a tool wear model but practically one or the other

    property of titanium countered the attempts so far. Researchers have selected

    particular tool and workpiece and tried to predict the model although they derived

    mathematical equations but either they given wrong results or they were only

    applicable for a particular tool-workpiece combination and not for any other, unlike in

    the case of nickel alloy machining or HSS machining where scientists have

    successfully come up with a tool wear model way back in past and also applicable for

    wide range of parameters and materials.

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    1.6) Approach

    Since scientists started their research regarding the prediction of tool wear model by

    considering all the properties of titanium and their effect on the tool life and comparedtitanium alloys with different materials and alloys that pertain similar properties and

    tried to get solution out of that comparison. Similarly we will be looking at the

    already proposed tool wear models for nickel alloys or HSS or titanium itself and try

    to consolidate all of them and try to get as close as possible to the tool wear for

    titanium alloys, will propose a model which will account all the parameters and will

    validate the model with the help of set of experiments.

    Our present work was to focus on the behavior of titanium and its alloys, on their

    machinability, understanding various parameters that are related to tool wear or tool

    life and complexity behind it. We understood the development of mathematical model

    for different outputs of turning operations its dependency on basic parameters of

    speed (V), feed (f) and depth of cut (d).

    Friedman and Field [4] suggested a relation which sometimes called as extended

    Taylor`s equation

    T =

    For p independent variables corresponding to wear parameters (properties)

    R = c [ ]

    Where Ej are the natural machining variables, c and j are model parameters and isa multiplicative random error

    The above relation will help in deriving a true mathematical relation considering all

    the machining variables and now the focus is to point out those variables and touch all

    the aspects of machining of titanium which lead to a true or close tool wear model

    which could be a work of great success.

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    2) Literature Review

    The purpose of the present study is to determine the wear mechanisms in titanium

    machining by comparing the predictions from various theoretical models of tool wear

    with experimental results. Generally, WC based compositions employed to machine

    titanium react with the workpiece material to form titanium carbide. This reaction

    layer has high deformation resistance at cutting temperatures and adheres strongly to

    both tool and the chip. The only tool material which was found to both wear resistant

    and more deformation resistant then WC is polycrystalline diamond. Since diamond is

    essentially pure carbon, the formation of TiC layer at the interface is also promoted in

    this case.

    2.1) Tool Wear model Based on Solubility

    2.1.1) Experiment Results:

    Hartung [5] carried out turning tests on Ti-6Al-4V with the conventional C-2 grade

    (Carbloy 820) and C-3(Kennametal k68) grade of cemented carbide at cutting speed

    from 200-400 sfpm. This attributes that crater wear limits the tool life; flank wear is

    stable and does not contribute to tool failure until crater wear weakens the edge in

    plastic deformation of cutting edge causes acceleration of the wear at the flank. At

    400sfpm and more leads to plastic deformation of the cutting edge and is responsible

    for tool failure.

    To determine the relative wear rate various potential tool materials in the machining

    of Ti-6Al-4V, turning tests were performed at 200sfpm. The average crater wears of

    various tool materials are shown in table 1.

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    Tool material Wear rate()ZrC-Coated Kennametal K7H(C8) 56

    HfC coated Kennametal k68 (C2) 52

    Cemented TiC 43CBN 30

    TiC coated WC(carboloy 523) 30

    HfC coated WC 22

    TiN coated WC 11

    Diamond 1.4

    Table1: Average crater wear rates of various tool materials in turning of Ti-6Al-4V at

    200sfpm

    2.1.2) Theoretical analysis:

    Since crater wear is dominant form of tool wear in the machining of titanium alloy,

    the first assumption was that the tool wear might be explained by the chemical

    dissolution of the tool material in titanium. If the mechanism of chip flow is assumed

    to be similar for different tool materials cutting under identical conditions, the relative

    wear rate can be written as

    Relative wear rate= =

    = Wear rate of tool material i

    Vi = Molar volume of tool material i

    Ci= Solubility of tool material i in the work material at the cutting temperature.

    The solubility estimates comes out to be given in Appendix table 2. The value in table

    may be taken as the maximum possible solubilities based on chemical properties

    alone which may be quite accurate when predicted solubilities are small. Otherwise

    when large concentration the physical and geometrical defects become significant, it

    is assumed that the solubility of tool material in titanium will not be greater thansolubility of its least soluble component.

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    Appendix Table 3 lists the solubilities [6] of tool constituents of titanium obtained

    from phase diagrams; comparing table 2 and 3 reveals that most of the tool materials

    have solubilities in titanium greater than that of one of their least soluble component.

    It may be seen that predictions based on solubility argument do not agree well with

    test results. In particular the analysis does not explain the high wear rates of HfC and

    ZrC coated tools related to that of WC. Unlike the HSS and Nickel alloys there was

    not a significant difference in the tool wear property for coated and uncoated tool in

    the case of titanium machining coated tool wore at about 20 times the rate of identical

    uncoated tool and that cant be explained due to the diff. solubilities of the tool

    materials.

    Hence the tool wear in machining of titanium is fundamentally different from that of

    steel and nickel alloys.

    2.2) Upper Bound Calculations of the Diffusion Flux

    It is possible that the diffusion of tool constituent materials within the chip controls

    the wear. It has been assumed that no deformation occurs in the chip as its light across

    the tool chip interface. This model provides an upper bound for the wear rates of the

    tool materials in the machining of titanium due to diffusion.

    = - KC( )

    Where

    = Wear rate of the tool material.

    K= Ratio of molar volumes of tool material and the chip material

    C= Equilibrium conc. of the tool material in the chip.

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    D= Diffusion coefficient of the slowest diffusing tool constituent in the chip.

    t= Time it takes for the chip tool move from the edge of the tool to the centre of the

    crater

    The value of t was estimated from chip thickness measurements and was found to be

    approximately 3.2x sec and the molar volume of titanium is 10.64/mole [7].The predicted wear rates of various potential tool materials are shown in Appendix 1

    table 4.

    Comparison of predicted results with the actual measured wear rates reveals that this

    model not only gives a gross overestimate of wear rate but also does not rank the

    materials properly in order of their wear resistance.

    2.3) Auger Experiment:

    The existence of 100nm thick layer of TiC on the surface of the diamond to suggests

    that the wear rate of the tool might be calculated from the rate of diffusion of carbon

    through the TiC layer.

    Formation of TiC layer on graphite from molten titanium follows a parabolic growth

    law of the form [8]:

    =t

    =0.2 exp (-61800/RT) /sec

    Where

    x= Layer thickness, cm

    = Parabolic Growth constant /sect= Carburization time, sec

    T= Temperature, K

    R= Universal gas constant

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    The rate of growth of TiC layer is predicted at 1300, 1400 and 1500 K under the

    assumption that the parabolic growth law holds at temperature under the melting point

    of titanium.

    Calculation of the wear rate of diamond in the machining of titanium

    = - D = -

    (

    )

    Where

    y=

    = the wear rate of the tool (cm/sec)=the molar Volume of the tool material /mole) = the concentration of carbon in the tool material (moles/mole) = the molar volume of titanium carbide at points i in the titanium carbide reactionlayer ( /mole)Ci= the concentration of carbon at point i in the titanium carbide reaction layer

    (moles/mole)

    b = the reaction layer/chip boundary

    0 = the reaction layer/tool boundary

    D = the diffusion coefficient of carbon in the titanium carbide reaction layer

    (/sec)t = the thickness of the titanium carbide reaction layer (cm)

    The reaction layer thickness, t, was assumed to be 100 nm, which was the

    approximate measured value in the AES study. All concentrations are from phase

    diagram data.

    Putting the Values of above Parameters the predicted Wear rate of diamond agrees

    quite well with test results. The wear rate of WC Predicted at 1300, 1400 and 1500K

    is average out, which also approximately agrees with observed rate of cemented WC.

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    2.4) Tool life model for hastelloy (Nickel based super alloy)

    Tool life can be estimated = CD/Where CD is total cutting distance to reach flank wear criterion of 0.3mm is feedrate in mm/min. for KC520M model tool insert [9], the tool life estimated from therelation

    Tool life = - 44.85 - 0.07461.7711.29 Where This relation is derived from the large experiments conducted, and using regression

    method. This shows tool life decreases with increasing cutting speed, feed rate, and

    axial depth.

    3)Plan of Work Literature review :The first and very important part of our project

    is to review the research being done so far and what was there

    approach and how could we correct them or do better, consolidating

    the previous efforts and efforts which will be put in this project. We

    will look for proposed models for titanium and their drawbacks and try

    to find out the common potential failure mode and then will take a

    preventive action to go in the right direction

    Objective formulation :- Our objective would be to identify asuitable model which will include every parameter that is responsible

    for the ambiguous behavior for the tool wear in machining of titanium

    alloy

    Formulate and modeling: - after identifying a similar model we willtry to formulate it according to our tool and workpiece specification

    and properties, will propose a analytical model.

    Carry out Experiments: - We will carry out experiments On Ti-6Al-4V a - alloy and our tool material TiAlN, and try to support the

    analytical model. It will help us in determining various coefficients and

    constants. Ultimately it will lead to a mathematical tool wear model for

    the specified workpiece-tool material combination.

    Validate the model: - After proposing a mathematical model for Ti-6Al-4V and TiAlN, we carry out series of experiments on the above

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    combination which will find out exact values and try to support the

    proposed model. The experiments help us to rectify problems in model

    and will give us real time data to deal with model accordingly.

    Analysis: - After getting experimental results we will analyze the realtime practical results and try to find its application over the model. If

    they match will be a great success, otherwise we will try to find out the

    major drawback or error in the proposed model

    Conclusion and Modification: - If the proposed model will be wellsupported by the experiments done on the combination mentioned

    above, will conclude our results and proceed, else will try to modify

    the results and conclude after getting a satisfactory model compatible

    with the real time situation.

    Our work deals with computation as well as experimentation, about a half of this

    semester we will be doing analytical calculations and study to come up with a

    mathematical model and will perform few experiments for development, next

    semester will do more experiments to validate the proposed model and modify it.

    Experiments will be performed together in our group and the analytical calculation

    and formulation we will do independently with the supervision on each other and

    consolidate our work to reach a common conclusion.

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    4)GANTT CHARTWork\Week 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16

    Literature review

    Objective formulation

    Formulate and modeling

    Carry out Experiments

    Validate the model

    Analysis

    Conclusion and

    Modification

    Work\Week 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32

    Literature reviewObjective formulation

    Formulate and modeling

    Carry out Experiments

    Validate the model

    Analysis

    Conclusion and

    Modification

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    References

    [1] LB. Borradile, R.H. Jeal, Titanium and Titanium Alloys, vols. I-3, 1981.

    [2] E.O Ezugwo and Z.M Wang Journal of Materials processing technology 68 (1997)

    262-274, School of Engineering Systems and Design, South Bank University,

    London SEI OAA, UK

    [3]W. Konig, Proc. 47th Meeting of AGARD Structural and Materials Panel,

    Florence, Sept. 1978, AGARD, CP256, London, 1979, pp. 1.1-1.10.

    [4] M. Y. FRIEDMAN and M. FIELD, Building of tool life models for use in a

    Computerized numerical machining data bank. Proc. Int. Conf. Prod. Enono.,

    Tokyo, Part 1 (1974).

    [5] P. D. Hartung, Tool Wear in Titanium Machininq, S.M. Thesis, Department of

    Mechanical Engineering, M.I.T., June 1981.

    [6] W. G. Moffatt, The HandDook of Binary Phase Diagrams, General Electric

    Company, Schenectady, New York, 1981.

    [7]B. M. Kramer, Ph.D. Thesis, Department of Mechanical Engineering, M.I.T.1979.

    [8] L. M. Adelsberg and L. H. CadofE, "The Reactions of Liquid Titanium and

    Hafnium with Carbon," Transactions of the Metallurgical Society of -AIME,

    Volume 239, June 1967, pp. 933-935.

    [9] I.A. Choudhurya, M.A. El-Baradie, Machinability assessment of inconel 718 by

    factorial design of experiment coupled with response surface methodology, J.

    Mater. Process. Technol. 95 (1999) 3039.

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    Appendix:

    Table2: Estimated solubilities of tool materials in titanium at various temperatures

    Tool material Solubility (mole %)

    1300K 1400K 1500K

    HfC 1.27 1.41 1.53

    TiC 7.75 7.75 7.75

    WC * * *

    ZrC 4.23 4.42 4.58

    HfN 10.92 12.80 13.35

    . 0.033 0.076 0.16*= chemical reaction occurs

    Table3:Reported solubilities of tool constituents

    Tool constituent Solubility

    1300K 1400K 1500K

    Al 15 19 28

    Hf * * *

    N 23.6 23.5 23.2

    Ta * * *

    Ti 100 100 100

    W * * *

    Zr * * *

    *= these constituents are soluble over a wide range of temperature and conc.

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    Table4: Predicted wear rates from the upper bound Diffusion Model (at 1400K)

    Tool

    material

    Ratio of molar

    volumes*

    Diffusion

    coefficients+()Solubility

    (mole %)

    Predicted

    wear rate

    (m/min)

    Diamond 0.321 2.28x 0.6 176TiC 1.147 4.83x 0.6 28.8WC 1.165 1.05x 0.6 9.48ZrC 1.472 1.40x 0.6 63TiN 1.080 4.82x 23.5 1063

    Table5: Predicted Growth of TiC layer on Diamond.

    Temperature

    (K)

    Parabolic growth

    constant(cm2/sec)

    Time(min) Layer

    thickness

    Time for layer

    thickness of

    500A 750A 1000A

    1300 9.51*(-12) 1/20 0.239/1.068 2.63 5.92 10.52

    1400 5.19*(-11) 1/20 0.358/2.497 0.48 1.08 1.93

    1500 2.26*(-10) 1/20 1.165/5.210 0.11 0.25 0.44