Memorandum To: Adam R. Kaufman, AICP Director of Planning ...
Transcript of Memorandum To: Adam R. Kaufman, AICP Director of Planning ...
One Deans Bridge Road • Somers, New York 10589
914.276.2560 • FAX 914.276.2664
Memorandum
To: Adam R. Kaufman, AICP Director of Planning Town of North Castle 17 Bedford Road Armonk, New York 10504
From: William A. Canavan, PG, LSRP HydroEnvironmental Solutions, Inc. One Deans Bridge Road Somers, New York 10589 Date: December 8, 2017 Re: Oamic Ingredients LLC 6 Labriola Court Armonk, New York
HydroEnvironmental Solutions, Inc. (HES) was retained by the Town of North Castle to review the Oamic Ingredients LLC (Oamic) Application for a proposed food chemical and flavoring warehouse storage facility located at 6 Labriola Court in Armonk, New York. As part of our review process, HES reviewed the following documents provided by the Town and the Applicant:
1. The Applicants Submission of November 6, 2017 which included a summary letter from JMC Site Development Consultants, LLC (JMC), a building architectural plan, a Statement of Oamic’s Statement of Environmental Safety of its Stored Products and information onthe stored products.
2. Site Layout (SP-4) dated 10/11/17 prepared by JMC Consulting. 3. A summary table of chemicals to be stored at the site prepared by JMC. 4. An MSDS Sheet Summary prepared by JMC dated September 25, 2017. 5. A November 17, 2017 letter from the New York City Department of
Environmental Protection (NYCDEP) to Mr. Adam Kaufman, AICP.
Based on our review of the materials provided and our December 1, 2017 site visit and meeting with the Applicant’s engineer, Paull J. Dumont of JMC, we offer the following:
Mr. Adam Kaufman December 8, 2017 Page | 2
Project Background The Applicant proposes to renovate the existing 24,000 (approximately) square
feet warehouse building for the purposes of storing chemical compounds related to food flavoring and preservation. Initially, the Applicant proposed using the facility to store Class I, II and III chemical compounds (according to the International Code Council [ICC] Fire Code Classification) and submitted a site plan and drawings to accommodate this proposal in May and October 2017. However, after appearing before the Town of North Castle Planning and Conservation Boards, and corresponding with the NYCDEP, the Applicant has changed their proposal to only store Class IIIA and Class IIIB combustible liquids and flammable and non-flammable solids.
The site is located immediately adjacent to Bear Gutter Creek and a pond and
wetland that are part of the creek watershed. Bear Gutter Creek is a direct tributary to Kensico Reservoir; therefore, the Town of North Castle and the NYCDEP expressed concerns over the storage of bulk chemicals in very close proximity to an environmentally sensitive watershed. Additionally, the Town of North Castle expressed concerns over the proximity of the facility to sensitive receptors such as restaurants and residential properties. The site location is shown on Figure 1. Regulatory Applicability
As stated by the Applicant, the site is no longer being proposed as a Class I and
II chemical bulk storage facility. Thus, the New York State Department of Environmental Conservation (NYSDEC) Chemical Bulk Storage Regulations, specifically 6 NYCRR Parts 595 through 599 are generally not applicable except for one compound that is proposed to be stored, Benzoic Acid Natural. It should be noted that the chemicals that are proposed for bulk storage on the premises are considered hazardous chemicals by federal regulation under the Occupational Safety and Hazard Administration (OSHA), and several of which are considered hazardous chemicals by the Superfund Amendment and Reauthorization Act (SARA) Parts 311/312. As outlined in the November 17, 2017 NYCDEP letter to the Town, the presence of hazardous chemicals that are stored in bulk in reservoir watersheds are regulated under Rules and Regulations for the Protection from Contamination, Degradation, and Pollution of the New York City Water Supply and its Sources. Therefore, based on the presence of Benzoic Acid Neutral, a NYSDEC regulated hazardous waste, it is HES’ opinion that all applicable NYSDEC Chemical Bulk Storage Regulations and NYCDEP Water Supply Protection Regulations for this compound must be adhered to.
The chemicals that are proposed for bulk storage at the facility are listed on the
attached Table 1. Table 1 lists the twenty-six (26) chemicals the Applicant proposes to store in bulk at the warehouse facility after renovation. As noted on the table, none of the chemicals listed are regulated by the NYCDEP, with the exception of Guaiacol.
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Only one chemical, Benzoic Acid Neutral is regulated by the NYSDEC as a hazardous substance. However, all the chemicals listed on the table are listed as hazardous chemicals by OSHA, and nineteen (19) of twenty-six (26) of the chemicals listed are listed as hazardous under SARA 311/312. Thus the health and safety and handling requirements listed under OSHA and SARA must be followed at all times at the facility.
Safety Data Sheets for Stored Chemicals The Material Safety Data Sheets (MSDS) for the proposed stored chemicals
were provided by the Applicant. It is important to note that as of December 1, 2015, chemical manufacturers are required to provide Safety Data Sheets as MSDS’s are no longer applicable to chemical bulk storage, use, and related health and safety. The Applicant provided MSDS’s that mostly originate from China, the company’s country of origin. The majority of the MSDS’s provided were compiled by Bestally whom is located in Xiamen, China and by Science Lab.com located in Houston, Texas.
As part of the application review process, HES compiled SDSs produced by VIGON
International (VIGON) located in East Stroudsburg, Pennsylvania. The VIGON SDS sheets for all of the chemicals to be stored at the facility are included in Attachments. VIGON SDS were chosen due to the thoroughness, detail, and readability as compared to the majority of the MSDS provided by the Applicant. The Applicant provided MSDS were not uniform. Some of the MSDS did not provide sufficient detailed information related to the chemicals storage and use and health and safety standards as they relate to Regulations and Guidelines in the USA (for example National Institute for Occupational Safety [NIOSH] and OSHA). Based on this information, HES recommends that the Applicant include a comprehensive SDS binder (with uniform SDS) for all proposed chemicals that will be stored at the facility. The Regulations and Guidelines of the USA and its respective agencies must be adhered to for all stored chemicals as they are drastically different than those promulgated in China. Proposed Site Plan
Surrounding Land Use The subject property is immediately surrounded by commercial properties.
These properties include H. Weiss, LLC, a food service equipment and supplies company; Morgan Manhattan Moving and Storage; Standing Ovation Studios and Lighthouse Youth Theatre, performing arts centers; and Gavi Restaurant. Residential neighborhoods exist to the west and northeast of the subject property. Additionally, commercial properties within ¼ mile including restaurants and children’s centers exist to the northeast of the subject property. The subject property location and surrounding land use is shown on Figure 2.
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Sensitive Receptors Bear Gutter Creek, which is situated directly behind the warehouse building,
flows from the northeast to the southwest. The Bear Gutter Creek is tributary to the Kensico Reservoir, which is the “last stop” in the NYCDEP waterway before the water goes to New York City (NYSDEC website). The creek and a small pond that are adjacent to the subject property are shown on Figure 2. According to the VIGON SDS, several of the proposed chemicals are toxic to aquatic life. This information is summarized on Table 1.
From the warehouse building, the land slopes downward to the northeast
towards the pond, and to the northwest and west towards the creek. Additionally, storm drains are located in the asphalt parking lots to the southwest and southeast of the warehouse building. These storm drains likely discharge to Bear Gutter Creek and the associated wetlands. No floor drains were observed in the warehouse building. The surface water flow directions for the site are shown on Figure 1.
Spill prevention and mitigation measures should be taken to avoid the possibility
of potential discharges of chemicals to the exterior of the building, given the surrounding waterways. All VIGON SDS claim the following in Section 6: “Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to the environment. Retain and dispose of contaminated wash water. Contact local authorities in case of spillage to drain/aquatic environment.”
General Recommendations
• All applicable NYSDEC Chemical Bulk Storage Regulations and NYCDEP Water Supply Protection Regulations for Benzoic Acid Natural must be adhered to.
• Health and safety and handling requirements listed under OSHA and SARA must be followed at all times at the facility.
• Spill prevention and mitigation measures should be taken to avoid the possibility of potential discharges of chemicals to the exterior of the building, which could subsequently reach the surrounding waterways. HES recommends that the Applicant compile a Spill Prevention Control and Countermeasure Plan (SPCCP) for the site once it is constructed.
• According to the Oamic Statement (item 8), dated October 30, 2017, Oamic will adopt a procedure to notify the NYCDEP and the North Castle Town Planner of the addition of any new ingredient to the list. HES
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recommends that this statement be expanded to include the required notification of the Town Engineer, Fire Chief, and Building Inspector in case of the addition of new ingredients.
• All Oamic employess that work in the warehouse area of the facility must be properly Health and Safety trained including 40-hour HAZWOPER training. The training must be updated annually in accordance with OSHA requirements.
• The Applicant should compile a comprehensive Health and Safety Plan and maintain it at all times for the facility.
HES would be pleased to meet with the Town and/or the Applicant to discuss this
project in further detail should the need arise. Please contact us at (914) 276-2560 with any questions or should you require any additional information pertaining to this matter.
Oamic Ingredients LLC6 Labriola Court
Armonk, New York
TABLE 1
HydroEnvironmental Solutions, Inc. Page 1 of 1
DEP Regulated DEA RegulatedHazardous Chemical
(6 CRR-NY 597.3)Hazardous Chemical
(OSHA)Hazardous Chemical
(SARA 311/312)Generally Recognized
as Safe (GRAS)Locked Storage
RequiredCombustible Dust Hazard
Explosion Proof Ventilation
Aquatic Toxicity
1 Benzaldehyde No Yes No Yes Yes Yes Yes No Yes Yes2 Furfuryl Alcohol No No No Yes Yes Yes Yes No Yes Yes3 Isovaleric Acid Natural No No No Yes Yes Yes Yes No Yes No4 2-Methylbutyric Acid Natural No No No Yes Yes Yes Yes No Yes No5 Cassia Oil No No No Yes Yes Yes Yes No Yes No6 Benzyl Alcohol Natural No No No Yes Yes Yes No No Yes Yes7 Hexanoic Acid Natural No No No Yes Yes Yes Yes No Yes Yes8 Sulfurol No No No Yes Yes Yes No No Yes No9 Gamma-Decalactone Natural No No No Yes No Yes Yes No Yes Yes
10 Cinnamic Aldehyde Natural No No No Yes Yes Yes Yes No Yes Yes11 Triethyl Citrate Natural No No No Yes No Yes No No Yes No12 Diethyl Succinate No No No Yes No Yes No No Yes No13 Guaiacol Natural Yes No No Yes Yes Yes Yes No Yes Yes14 Alpha Terpineol Natural No No No Yes Yes Yes Yes No Yes No15 Strawberry Furanone No No No Yes Yes Yes No Yes Yes No16 Ethyl Maltol No No No Yes Yes Yes No Yes Yes No17 Phenylacetic Acid Natural No Yes No Yes No Yes Yes Yes Yes No18 Decanoic Acid Natural No No No Yes Yes Yes Yes No Yes Yes19 Methyl Anthranilate Natural No Yes No Yes No Yes Yes No Yes Yes20 Maltol No No No Yes Yes Yes Yes Yes Yes No21 Benzoic Acid Natural No No Yes Yes Yes Yes No Yes Yes Yes22 Vanillin Natural, Ex Clove No No No Yes Yes Yes No Yes Yes Yes23 Methyl Cyclopentenolone Natural No No No Yes No Yes No No Yes No24 Raspberry Ketone Natural No No No Yes Yes Yes No Yes Yes No25 2-Acetylpyrazine No No No Yes No Yes Yes Yes Yes No26 Heliotropin Natural (Piperonal) No Yes No Yes Yes Yes Yes Yes Yes Yes
*All info above taken from Vigon SDS
OAMIC INGREDIENTS LLC6 LABRIOLA COURT
ARMONK, NEW YORK
DECEMBER 2017
AERIAL PHOTOGRAPH SHOWING THESITE LOCATION AND THE SURROUNDING LAND USE
SITE
H. W
eis
s LLC
MORGAN MANHATTANMOVING
STANDING OVATIONSTUDIOS
GAVIRESTAURANT
CO
ND
OM
INIU
MS
BEAR GUTTER CREEK
POND
STREAM
NATIONAL WETLANDSINVENTORY LOCATION
FIGURE 2
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1. IDENTIFICATIONACETYL-2 PYRAZINEProduct Description:22047-25-2CAS #
FEMA Number 3126
Other means of identification500613Vigon Item #Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended use
For Manufacturing Use OnlyRecommended restrictions
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
Manufacturer/Importer/Supplier/Distributor informationManufacturer
Vigon International, Inc.Address 127 Airport RoadCompany name
WebsiteTelephone For information call: 570-476-6300
Emergency phone number INFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
United States
www.vigon.comNot available.
E. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 5Acute toxicity, oralHealth hazardsCategory 2Skin corrosion/irritationCategory 2ASerious eye damage/eye irritationCategory 3 respiratory tract irritationSpecific target organ toxicity, single
exposureNot classified.Environmental hazards
Label elements
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Signal word Warning
Hazard statement May be harmful if swallowed. Causes skin irritation. Causes skin and eye irritation. Causesserious eye irritation. May cause respiratory irritation.
Precautionary statementPrevention Avoid breathing dust. Wash thoroughly after handling. Use only outdoors or in a well-ventilated
area. Wear eye protection/face protection. Wear protective gloves.
Response IF ON SKIN: Wash with plenty of water. IF INHALED: Remove person to fresh air and keepcomfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER/doctor if youfeel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Getmedical advice/attention. Take off contaminated clothing and wash it before reuse.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC)
WARNING! May form combustible dust concentrations in air. Avoid breathing dust.
Supplemental information 100% of the mixture consists of component(s) of unknown long-term hazards to the aquaticenvironment. 100% of the mixture consists of component(s) of unknown acute inhalation toxicity.100% of the mixture consists of component(s) of unknown acute hazards to the aquaticenvironment. 100% of the mixture consists of component(s) of unknown acute dermal toxicity.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS numberCommon name and synonymsChemical name %Ethanone, 1- (2- pyrazinyl) - Pyrazin- 1- ylethan- 1- one1- pyrazin- 2- ylethanonemethyl- 2- pyrazinyl ketone
22047-25-2ACETYL-2 PYRAZINE 100
4. FIRST-AID MEASURESIf breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Inhalation
Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Skin contact
Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Eye contact
Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Ingestion
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Dusts may irritate the respiratory tract, skin and eyes. Skin irritation. May cause rednessand pain.
Most importantsymptoms/effects, acute anddelayed
Not available.Indication of immediate medicalattention and special treatmentneeded
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Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. FIRE-FIGHTING MEASURESWater spray, fog, CO2, dry chemical, or alcohol resistant foam.Suitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing mediaExplosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, andin the presence of an ignition source is a potential dust explosion hazard. Fire may produceirritating, corrosive and/or toxic gases.
Specific hazards arising fromthe chemical
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Special protective equipmentand precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Fire fightingequipment/instructions
Use water spray to cool unopened containers.Specific methodsStatic charges generated by emptying package in or near flammable vapor may cause flash fire.General fire hazards
6. ACCIDENTAL RELEASE MEASURESKeep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Personal precautions, protectiveequipment and emergencyprocedures
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Sweep upand place in a clearly labeled container for chemical waste. Wash contaminated area with water.Use only non-sparking tools. Avoid the generation of dusts during clean-up. This material and itscontainer must be disposed of as hazardous waste. Collect and dispose of spillage as indicated insection 13 of the SDS.
Never return spills in original containers for re-use.
Methods and materials forcontainment and cleaning up
Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
Environmental precautions
7. HANDLING AND STORAGETake precautionary measures against static discharges when there is a risk of dust explosion.Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensurethat dusts do not accumulate on surfaces. Dry powders can build static electricity charges whensubjected to the friction of transfer and mixing operations. Provide adequate precautions, such aselectrical grounding and bonding, or inert atmospheres. Assume that this material is capable ofproducing a dust explosion if ignited as a dust cloud.Do not handle or store near an open flame, heat or other sources of ignition. Take precautionarymeasures against static discharges. Avoid breathing vapor. Avoid breathing dust. Avoid contactwith eyes, skin, and clothing. Avoid prolonged exposure. Wash thoroughly after handling.
Precautions for safe handling
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Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
Conditions for safe storage,including any incompatibilities
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONThis substance has no PEL, TLV, or other recommended exposure limit.Occupational exposure limitsNo biological exposure limits noted for the ingredient(s).Biological limit valuesUse only appropriately classified electrical equipment and powered industrial trucks. It isrecommended that all dust control equipment such as local exhaust ventilation and materialtransport systems involved in handling of this product contain explosion relief vents or anexplosion suppression system or an oxygen-deficient environment. Ensure that dust-handlingsystems (such as exhaust ducts, dust collectors, vessels, and processing equipment) aredesigned in a manner to prevent the escape of dust into the work area (i.e., there is no leakagefrom the equipment). Use explosion-proof ventilation equipment to stay below exposure limits.
Appropriate engineering controls
Individual protection measures, such as personal protective equipmentWear safety glasses with side shields (or goggles).Eye/face protection
Skin protectionChemical resistant gloves.Hand protection
Not available.OtherDust mask.Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. Routinelywash work clothing and protective equipment to remove contaminants.
General hygiene considerations
9. PHYSICAL AND CHEMICAL PROPERTIESRefer to Spec SheetAppearancePowder\Crystal.Physical statePowder. Crystalline powder.FormRefer to Spec SheetColorCharacteristic.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point 170.6 °F (77 °C)
Initial boiling point and boilingrange
374 °F (190 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
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Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure < 1 mm Hg
Vapor density 4.2
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationNot explosive.Explosive properties
Flammability class Combustible IIIB estimated
Molecular formula C6H6N2O
Molecular weight 122.13 g/molNot oxidizing.Oxidizing properties
10. STABILITY AND REACTIVITYThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityMaterial is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous
reactionsKeep away from heat, sparks and open flame. Avoid temperatures exceeding the flash point.Contact with incompatible materials. Minimize dust generation and accumulation.
Conditions to avoid
Strong oxidizing agents.Incompatible materialsNo hazardous decomposition products if stored and handled as indicated.Hazardous decomposition
products
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation Irritating to respiratory system.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion May be harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Dusts may irritate the respiratory tract, skin and eyes. Skin irritation. May cause rednessand pain.
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Information on toxicological effects
Acute toxicity May be harmful if swallowed.
Test ResultsProduct SpeciesACETYL-2 PYRAZINE (CAS 22047-25-2)
LD50 RatOralAcute
> 3000 mg/kg
* Estimates for product may be based on additional component data not shown.Causes skin irritation.Skin corrosion/irritationCauses serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitizationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
US. National Toxicology Program (NTP) Report on CarcinogensNot listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -single exposure
May cause respiratory irritation.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONThe product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
No data is available on the degradability of this product. Persistence and degradabilityNo data available.Bioaccumulative potentialNo data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
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13. DISPOSAL CONSIDERATIONSDo not discharge into drains, water courses or onto the ground. Do not allow this material to draininto sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulationsNot established.Hazardous waste codeEmpty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Waste from residues / unusedproducts
Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.
Contaminated packaging
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
Not regulated as dangerous goods.BULK
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.
US federal regulations
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
SARA 304 Emergency release notificationNot regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
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TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substanceNot listed.
NoSARA 311/312 Hazardouschemical
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Not regulated.Safe Drinking Water Act
(SDWA)
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)NoJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION11-30-2015Issue date
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11-21-2016Revision dateVersion # 03
Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from theManufacturing, Processing, and Handling of Combustible Particulate Solids, for safe handling.
Further information
Health: 2Flammability: 1Physical hazard: 0
HMIS® ratings
Vigon International, Inc. cannot anticipate all conditions under which this information and itsproduct, or the products of other manufacturers in combination with its product, may be used. It isthe user’s responsibility to ensure safe conditions for handling, storage and disposal of theproduct, and to assume liability for loss, injury, damage or expense due to improper use. Theinformation in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
Disclaimer
HAZARD(S) IDENTIFICATION: PreventionHAZARD(S) IDENTIFICATION: Supplemental informationFIRST-AID MEASURES: Most important symptoms/effects, acute and delayedHANDLING AND STORAGE: Precautions for safe handlingPhysical & Chemical Properties: Multiple PropertiesPHYSICAL AND CHEMICAL PROPERTIES: AppearancePHYSICAL AND CHEMICAL PROPERTIES: Oxidizing propertiesPHYSICAL AND CHEMICAL PROPERTIES: Explosive propertiesToxicological Information: Toxicological DataTOXICOLOGICAL INFORMATION: Acute toxicityTOXICOLOGICAL INFORMATION: Symptoms related to the physical, chemical and toxicologicalcharacteristicsECOLOGICAL INFORMATION: Persistence / degradabilityOTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION: References GHS: Classification
Revision information
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1. IDENTIFICATIONProduct Description: BENZALDEHYDE NATURALCAS # 100-52-7
FEMA Number 2127
Other means of identificationVigon Item # 500026
Recommended use Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended restrictions For Manufacturing Use Only
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONCategory 4Flammable liquidsPhysical hazardsCategory 4Acute toxicity, oralHealth hazardsCategory 4Acute toxicity, dermalCategory 4Acute toxicity, inhalationCategory 2Skin corrosion/irritationCategory 2ASerious eye damage/eye irritationCategory 1Sensitization, skinCategory 3 respiratory tract irritationSpecific target organ toxicity, single
exposureCategory 3 narcotic effectsSpecific target organ toxicity, single
exposureCategory 1Hazardous to the aquatic environment,
acute hazardEnvironmental hazards
Category 1Hazardous to the aquatic environment,long-term hazard
Label elements
Signal word Warning
Hazard statementH227 Combustible liquid.H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled.
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H315 Causes skin irritation.H315 + H320 Causes skin and eye irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H335 May cause respiratory irritation.H336 May cause drowsiness or dizziness.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.
Precautionary statementPrevention
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.P261 Avoid breathing mist or vapor.P264 Wash thoroughly after handling.P270 Do not eat, drink or smoke when using this product.P271 Use only outdoors or in a well-ventilated area.P272 Contaminated work clothing should not be allowed out of the workplace.P273 Avoid release to the environment.P280 Wear protective gloves/protective clothing.P280 Wear protective gloves/eye protection/face protection.
ResponseP301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.P302 + P352 IF ON SKIN: Wash with plenty of water.P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P305 + P351 +P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.P312 Call a POISON CENTER/doctor if you feel unwell.P330 Rinse mouth.P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.P337 + P313 If eye irritation persists: Get medical advice/attention.P362 + P364 Take off contaminated clothing and wash it before reuse.P370 + P378 In case of fire: Use appropriate media to extinguish.P391 Collect spillage.
StorageP403 + P233 Store in a well-ventilated place. Keep container tightly closed.P403 + P235 Store in a well-ventilated place. Keep cool.P405 Store locked up.
DisposalP501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwiseclassified (HNOC)
After prolonged contact with highly porous materials, this product may spontaneously combust.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
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CAS number %Chemical name Common name and synonymsPHENYL METHANALBENZENE METHYLALBENZENE CARBONALBENZENE CARBOXALDEHYDEBenzoyl hydride
100-52-7BENZALDEHYDE 100
4. FIRST-AID MEASURESInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Skin contact Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Eye contact Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Ingestion Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Most importantsymptoms/effects, acute anddelayed
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May causerespiratory irritation. Skin irritation. May cause redness and pain. May cause an allergic skinreaction. Dermatitis. Rash.
Indication of immediate medicalattention and special treatmentneeded
Not available.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
5. FIRE-FIGHTING MEASURESSuitable extinguishing media Water spray, fog, CO2, dry chemical, or alcohol resistant foam.Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Specific hazards arising fromthe chemical
Fire may produce irritating, corrosive and/or toxic gases. Porous material such as rags, paper,insulation, or organic clay may spontaneously combust when wetted with this material.
Special protective equipmentand precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Fire fightingequipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Specific methods Use water spray to cool unopened containers.General fire hazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.
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6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures
Keep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Methods and materials forcontainment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Donot allow material to contaminate ground water system. Absorb in vermiculite, dry sand or earthand place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
7. HANDLING AND STORAGEPrecautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. All equipment used
when handling the product must be grounded. Avoid contact with eyes, skin, and clothing. Avoidprolonged exposure. Wash thoroughly after handling. Porous material such as rags, paper,insulation, or organic clay may spontaneously combust when wetted with this material. Mayauto-oxidize with sufficient heat generation to ignite if spread (as a thin film) or absorbed onporous or fibrous material. Take precautionary measures against static discharges. Contaminatedrags and cloths must be put in fireproof containers for disposal. Avoid breathing vapor.
Conditions for safe storage,including any incompatibilities
Do not store in direct sunlight. Keep container closed. Handle containers with care. Open slowly inorder to control possible pressure release. Store in a cool, well-ventilated area. Keep under anitrogen blanket.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits
US. Workplace Environmental Exposure Level (WEEL) GuidesValueMaterial Type
STEL 17.4 mg/m3BENZALDEHYDE (CAS100-52-7)
4 ppmTWA 8.7 mg/m3
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US. Workplace Environmental Exposure Level (WEEL) GuidesValueMaterial Type
2 ppmBiological limit values No biological exposure limits noted for the ingredient(s).Appropriate engineering controls Use explosion-proof ventilation equipment to stay below exposure limits.
Individual protection measures, such as personal protective equipmentEye/face protection Avoid contact with eyes.
Skin protectionHand protection Chemical resistant gloves.
Other Use of an impervious apron is recommended.
Respiratory protection Chemical respirator with organic vapor cartridge and full facepiece.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations When using do not smoke. Keep away from food and drink. Always observe good personalhygiene measures, such as washing after handling the material and before eating, drinking, and/orsmoking. Routinely wash work clothing and protective equipment to remove contaminants.Contaminated work clothing should not be allowed out of the workplace.
9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Refer to Spec Sheet
Physical state Liquid.Form Liquid.Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point -14.8 °F (-26 °C)
Initial boiling point and boilingrange
354.2 °F (179 °C)
Flash point 145.0 °F (62.8 °C) Closed Cup
Evaporation rate Not available.Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
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Vapor pressure 1 mm Hg at 25 °C
Vapor density 3.66
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
1.5
Auto-ignition temperature 377 °F (191.67 °C)
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 1.05 g/cm3 estimated at 15 °C
Dynamic viscosity 1.39 mPa.s
Kinematic viscosity 1.324 mm²/s estimated
Molecular formula C7-H6-O
Molecular weight 106.12 g/mol
Specific gravity 1.04 at 25 °C
10. STABILITY AND REACTIVITYReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Chemical stability Material is stable under normal conditions.Possibility of hazardousreactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Porous material such as rags, paper, insulation, or organic clay may spontaneously combust whenwetted with this material.
Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products if stored and handled as indicated.
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation Harmful if inhaled. May cause drowsiness and dizziness. Headache. Nausea, vomiting.
Skin contact Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction.
Eye contact Causes serious eye irritation.
Ingestion Harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Headache. May cause drowsiness and dizziness. Nausea, vomiting. Severe eye irritation.Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May causerespiratory irritation. Skin irritation. May cause redness and pain. May cause an allergic skinreaction. Dermatitis. Rash.
Information on toxicological effects
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Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness andcentral nervous system effects. Harmful if inhaled. Harmful in contact with skin. Harmful ifswallowed. Narcotic effects. May cause an allergic skin reaction. May cause respiratory irritation.
Test ResultsProduct SpeciesBENZALDEHYDE NATURAL (CAS 100-52-7)
LD50 RabbitDermalAcute
> 1250 mg/kg
LD50 RatOral
1300 mg/kg
* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Causes skin irritation.
Humans: No skin irritation @ 4%Serious eye damage/eyeirritation
Causes serious eye irritation.
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
Skin sensitization May cause an allergic skin reaction.Humans: No senitizing effect @ 4%
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.
Carcinogenicity
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -single exposure
May cause respiratory irritation. May cause drowsiness and dizziness.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONEcotoxicity Very toxic to aquatic life with long lasting effects.
Readily biodegradabilty>90 % BSB/CSB
Product Test ResultsSpeciesBENZALDEHYDE (CAS 100-52-7)
EC50Other 759.3 mg/lActivated sludge, industrial
AquaticEC50Algae 24.9 mg/l, 96 hoursAlgae
EC50Crustacea 50 mg/l, 24 hoursDaphnia magna
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Product Test ResultsSpeciesLC50Fish 0.8 - 1.44 mg/l, 96 hoursBluegill (Lepomis macrochirus)
* Estimates for product may be based on additional component data not shown.
LD50 7.61 mg/l, 96 hoursPimephales promelas
Persistence and degradability Readily biodegradable> 90%, BSB/CSB
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)1.48
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDisposal instructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.Hazardous waste code Not established.Waste from residues / unusedproducts
Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
14. TRANSPORT INFORMATIONADN
1990UN numberBENZALDEHYDEUN proper shipping name9Transport hazard class(es)-Subsidiary class(es)IIIPacking groupYesEnvironmental hazards9Labels required
ADR1990UN numberBENZALDEHYDEUN proper shipping name9Transport hazard class(es)-Subsidiary class(es)IIIPacking groupYesEnvironmental hazards9Labels required
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RID1990UN numberBENZALDEHYDEUN proper shipping name9Transport hazard class(es)-Subsidiary class(es)IIIPacking groupYesEnvironmental hazards9Labels required
DOT
1990UN numberBULK
BENZALDEHYDEProper shipping name9Hazard classIIIPacking group
YesMarine pollutantEnvironmental hazards
155Packaging exceptions241Packaging bulk9Labels required
DOT
1990UN numberNON-BULK
BENZALDEHYDEProper shipping name9Hazard classIIIPacking group
NoMarine pollutantEnvironmental hazards
155Packaging exceptions203Packaging non bulk9Labels required
IATA1990UN numberBENZALDEHYDEUN proper shipping name9Transport hazard class(es)-Subsidiary class(es)IIIPacking groupNoEnvironmental hazards9Labels required
IMDG1990UN numberBENZALDEHYDEUN proper shipping name9Transport hazard class(es)-Subsidiary class(es)IIIPacking group
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YesMarine pollutantEnvironmental hazards
9Labels requiredNot applicable.Transport in bulk according
to Annex II of MARPOL73/78 and the IBC Code
ADN; ADR; DOT BULK; DOT NON-BULK; IATA; IMDG; RID
Marine pollutant
15. REGULATORY INFORMATIONUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
SARA 304 Emergency release notificationNot regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
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Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes
Delayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substanceNot listed.
SARA 311/312 Hazardouschemical
Yes
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Safe Drinking Water Act(SDWA)
Not regulated.
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))BENZALDEHYDE (CAS 100-52-7) 50 %WV
DEA Exempt Chemical Mixtures Code NumberBENZALDEHYDE (CAS 100-52-7) 8256
Food and DrugAdministration (FDA)
Controlled substance
US state regulationsUS - Minnesota Haz Subs: Hazardous substance
BENZALDEHYDE (CAS 100-52-7) Hazardous substance.US. Massachusetts RTK - Substance List
BENZALDEHYDE (CAS 100-52-7)US. New Jersey Worker and Community Right-to-Know Act
BENZALDEHYDE (CAS 100-52-7)US. Pennsylvania Worker and Community Right-to-Know Law
BENZALDEHYDE (CAS 100-52-7)US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)
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Country(s) or region Inventory name On inventory (yes/no)*YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISIONIssue date 05-18-2016Revision date 05-18-2016Version # 04HMIS® ratings Health: 2*
Flammability: 2Physical hazard: 0
Disclaimer Vigon cannot anticipate all conditions under which this information and its product, or the productsof other manufacturers in combination with its product, may be used. It is the user’s responsibilityto ensure safe conditions for handling, storage and disposal of the product, and to assume liabilityfor loss, injury, damage or expense due to improper use. The information in the sheet was writtenbased on the best knowledge and experience currently available. The above information relatesonly to this product and not to its use in combination with any other material or any particularprocess and is designed only as guidance for the safe handling, use, processing, storage,transportation, disposal, and should not be considered as a guarantee or quality specification. Theabove information is based on data provided by and collected from recognized sources such asdistributors, manufacturers, and technical groups and is considered to be accurate to the best ofVigon’s knowledge as of the date of this document. It is the responsibility of the user to review allsafety information about this product and determine its safety and suitability in their own processesand operations. Appropriate warnings and safe handling procedures should be provided to allhandlers and users, taking into account the intended use and the specific conditions and factorsrelating to such use in accordance with all applicable laws and regulations.
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Revision Information Product and Company Identification: Vigon ValuesPhysical & Chemical Properties: Multiple PropertiesToxicological Information: Toxicological DataTransport Information: Proper Shipping Name/Packing GroupRegulatory Information: United StatesGHS: Classification
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1. IDENTIFICATIONBENZOIC ACID NATURALProduct Description:65-85-0CAS #
FEMA Number 2131
Other means of identification504681Vigon Item #Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended use
For Manufacturing Use OnlyRecommended restrictions
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
Manufacturer/Importer/Supplier/Distributor informationManufacturer
Vigon International, Inc.Address 127 Airport RoadCompany name
WebsiteTelephone For information call: 570-476-6300
Emergency phone number INFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
United States
www.vigon.comNot available.
E. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 4Acute toxicity, oralHealth hazardsCategory 2Skin corrosion/irritationCategory 1Serious eye damage/eye irritationCategory 1Specific target organ toxicity, repeated
exposureCategory 3Hazardous to the aquatic environment,
acute hazardEnvironmental hazards
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Label elements
Signal word Danger
Hazard statement Harmful if swallowed. Causes skin irritation. Causes serious eye damage. Causes damage toorgans through prolonged or repeated exposure. Harmful to aquatic life.
Precautionary statementPrevention Do not breathe dust. Wash thoroughly after handling. Do not eat, drink or smoke when using this
product. Avoid release to the environment. Wear eye protection/face protection. Wear protectivegloves.
Response IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. IF ON SKIN:Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing. Immediately call a POISONCENTER/doctor. If skin irritation occurs: Get medical advice/attention. Take off contaminatedclothing and wash it before reuse.
Storage Store away from incompatible materials.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC)
WARNING! May form combustible dust concentrations in air. Avoid breathing dust.
Supplemental information 100% of the mixture consists of component(s) of unknown long-term hazards to the aquaticenvironment.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS numberCommon name and synonymsChemical name %BENZENE CARBOXYLIC ACIDPHENYL FORMIC ACIDPHENYL CARBOXYLIC ACIDCARBOXYBENZENEBENZENE METHANOIC ACIDBENZENE FORMIC ACIDDRACYLIC ACID
65-85-0BENZOIC ACID 100
4. FIRST-AID MEASURESIf breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Inhalation
Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Skin contact
Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Eye contact
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Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Ingestion
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Permanent eye damage including blindness could result. Dusts may irritate the respiratorytract, skin and eyes. Skin irritation. May cause redness and pain. Prolonged exposure may causechronic effects.
Most importantsymptoms/effects, acute anddelayed
Not available.Indication of immediate medicalattention and special treatmentneeded
Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. FIRE-FIGHTING MEASURESWater spray, fog, CO2, dry chemical, or alcohol resistant foam.Suitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing mediaExplosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, andin the presence of an ignition source is a potential dust explosion hazard. Fire may produceirritating, corrosive and/or toxic gases.
Specific hazards arising fromthe chemical
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Special protective equipmentand precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Fire fightingequipment/instructions
Use water spray to cool unopened containers.Specific methodsStatic charges generated by emptying package in or near flammable vapor may cause flash fire.General fire hazards
6. ACCIDENTAL RELEASE MEASURESKeep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Personal precautions, protectiveequipment and emergencyprocedures
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Sweep upand place in a clearly labeled container for chemical waste. Wash contaminated area with water.Use only non-sparking tools. Avoid the generation of dusts during clean-up. This material and itscontainer must be disposed of as hazardous waste. Collect and dispose of spillage as indicated insection 13 of the SDS.
Never return spills in original containers for re-use.
Methods and materials forcontainment and cleaning up
Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
Environmental precautions
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7. HANDLING AND STORAGETake precautionary measures against static discharges when there is a risk of dust explosion.Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensurethat dusts do not accumulate on surfaces. Dry powders can build static electricity charges whensubjected to the friction of transfer and mixing operations. Provide adequate precautions, such aselectrical grounding and bonding, or inert atmospheres. Assume that this material is capable ofproducing a dust explosion if ignited as a dust cloud.Do not handle or store near an open flame, heat or other sources of ignition. Take precautionarymeasures against static discharges. Avoid breathing vapor. Avoid breathing dust. Avoid contactwith eyes, skin, and clothing. Avoid prolonged exposure. Wash thoroughly after handling.
Precautions for safe handling
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
Conditions for safe storage,including any incompatibilities
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONThis substance has no PEL, TLV, or other recommended exposure limit.Occupational exposure limitsNo biological exposure limits noted for the ingredient(s).Biological limit valuesUse only appropriately classified electrical equipment and powered industrial trucks. It isrecommended that all dust control equipment such as local exhaust ventilation and materialtransport systems involved in handling of this product contain explosion relief vents or anexplosion suppression system or an oxygen-deficient environment. Ensure that dust-handlingsystems (such as exhaust ducts, dust collectors, vessels, and processing equipment) aredesigned in a manner to prevent the escape of dust into the work area (i.e., there is no leakagefrom the equipment). Use explosion-proof ventilation equipment to stay below exposure limits.
Appropriate engineering controls
Individual protection measures, such as personal protective equipmentWear safety glasses with side shields (or goggles). Avoid contact with eyes.Eye/face protection
Skin protectionChemical resistant gloves.Hand protection
Use of an impervious apron is recommended.Other
Chemical respirator with organic dust cartridge.Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. Routinelywash work clothing and protective equipment to remove contaminants.
General hygiene considerations
9. PHYSICAL AND CHEMICAL PROPERTIESRefer to Spec SheetAppearancePowder\Crystal.Physical statePowder. Crystalline powder.FormRefer to Spec SheetColorCharacteristic.Odor
Odor threshold Not available.
pH 2.8 Saturated solution in water
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Melting point/freezing point 251.6 °F (122 °C)
Initial boiling point and boilingrange
480.2 °F (249 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure > 1 mm Hg at 20 °C
Vapor density 4.21
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
1.87
Auto-ignition temperature 1058 °F (570 °C)
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 1.27 g/cm3 estimated at 15 °C
Not explosive.Explosive properties
Flammability class Combustible IIIB estimated
Molecular formula C7-H6-O2
Molecular weight 122.13 g/molNot oxidizing.Oxidizing properties
Surface tension 30 mN/m (266 °F (130 °C))
10. STABILITY AND REACTIVITYThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityMaterial is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous
reactionsKeep away from heat, sparks and open flame. Avoid temperatures exceeding the flash point.Contact with incompatible materials. Minimize dust generation and accumulation.
Conditions to avoid
Strong oxidizing agents.Incompatible materials
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No hazardous decomposition products if stored and handled as indicated.Hazardous decompositionproducts
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. Irritating torespiratory system.
Skin contact Causes skin irritation.
Eye contact Causes serious eye damage.
Ingestion Harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Permanent eye damage including blindness could result. Dusts may irritate the respiratorytract, skin and eyes. Skin irritation. May cause redness and pain.
Information on toxicological effects
Acute toxicity Harmful if swallowed.
Test ResultsProduct SpeciesBENZOIC ACID NATURAL (CAS 65-85-0)
LD50 RabbitDermalAcute
> 5000 mg/kg
LC50 RatInhalation
> 12.2 mg/l, 4 hours
> 0.026 mg/l, 1 Hours
LD50 RatOral
1700 mg/kg
* Estimates for product may be based on additional component data not shown.Causes skin irritation.Skin - rabbit - Mild skin irritation - 24 h - Draize Test
Skin corrosion/irritation
Causes serious eye damage.Eyes - rabbit - Risk of serious damage to eyes. - Draize Test
Serious eye damage/eyeirritation
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitizationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
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US. National Toxicology Program (NTP) Report on CarcinogensNot listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard Not an aspiration hazard.
Chronic effects Causes damage to organs through prolonged or repeated exposure.
12. ECOLOGICAL INFORMATIONHarmful to aquatic life.Ecotoxicity
Product Test ResultsSpeciesBENZOIC ACID (CAS 65-85-0)
AquaticEC50Algae > 10 mg/l, 14 dayGreen algae (Scenedesmus acutus)
* Estimates for product may be based on additional component data not shown.
LC50Fish 180 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis)
No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)1.87
Bioconcentration factor (BCF)5.3
No data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDo not discharge into drains, water courses or onto the ground. Do not allow this material to draininto sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulationsNot established.Hazardous waste codeEmpty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Waste from residues / unusedproducts
Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.
Contaminated packaging
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14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
3077UN numberBULK
ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.OS. (BENZOIC ACID RQ = 5000LBS)
Proper shipping name
9Hazard classIIIPacking group
YesMarine pollutantEnvironmental hazards
155Packaging exceptions240Packaging bulk5000Reportable quantity9Labels required
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
DOT BULK
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Marine pollutant
15. REGULATORY INFORMATIONThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.
US federal regulations
CERCLA Hazardous Substance List (40 CFR 302.4)BENZOIC ACID (CAS 65-85-0) Listed.
SARA 304 Emergency release notificationNot regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substanceNot listed.
YesSARA 311/312 Hazardouschemical
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Hazardous substanceClean Water Act (CWA)
Section 112(r) (40 CFR68.130)
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Not regulated.Safe Drinking Water Act(SDWA)
Total food additiveDirect food additiveGRAS food additive
Food and DrugAdministration (FDA)
US state regulationsUS. Massachusetts RTK - Substance List
BENZOIC ACID (CAS 65-85-0)US. New Jersey Worker and Community Right-to-Know Act
BENZOIC ACID (CAS 65-85-0)US. Pennsylvania Worker and Community Right-to-Know Law
BENZOIC ACID (CAS 65-85-0)US. Rhode Island RTK
BENZOIC ACID (CAS 65-85-0)
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION11-30-2015Issue date11-21-2016Revision date
Version # 02Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from theManufacturing, Processing, and Handling of Combustible Particulate Solids, for safe handling.
Further information
Health: 3*Flammability: 1Physical hazard: 0
HMIS® ratings
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Vigon International, Inc. cannot anticipate all conditions under which this information and itsproduct, or the products of other manufacturers in combination with its product, may be used. It isthe user’s responsibility to ensure safe conditions for handling, storage and disposal of theproduct, and to assume liability for loss, injury, damage or expense due to improper use. Theinformation in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
Disclaimer
This document has undergone significant changes and should be reviewed in its entirety.Revision information
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1. IDENTIFICATIONProduct Description: BENZYL ALCOHOL FCCCAS # 100-51-6
FEMA Number 2137
Other means of identificationVigon Item # 500028
Recommended use Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended restrictions For Manufacturing Use Only
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 4Acute toxicity, oralHealth hazardsCategory 4Acute toxicity, dermalCategory 4Acute toxicity, inhalationCategory 2Skin corrosion/irritationCategory 2ASerious eye damage/eye irritationCategory 2Hazardous to the aquatic environment,
acute hazardEnvironmental hazards
Category 2Hazardous to the aquatic environment,long-term hazard
Label elements
Signal word Warning
Hazard statementH302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled.H315 Causes skin irritation.H315 + H320 Causes skin and eye irritation.H319 Causes serious eye irritation.H401 Toxic to aquatic life.H411 Toxic to aquatic life with long lasting effects.
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Precautionary statementPrevention
P261 Avoid breathing vapors.P264 Wash thoroughly after handling.P270 Do not eat, drink or smoke when using this product.P271 Use only outdoors or in a well-ventilated area.P273 Avoid release to the environment.P280 Wear protective gloves/protective clothing.P280 Wear eye/face protection.
ResponseP301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.P302 + P352 IF ON SKIN: Wash with plenty of water.P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P305 + P351 +P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.P312 Call a POISON CENTER/doctor if you feel unwell.P330 Rinse mouth.P332 + P313 If skin irritation occurs: Get medical advice/attention.P337 + P313 If eye irritation persists: Get medical advice/attention.P362 + P364 Take off contaminated clothing and wash it before reuse.P391 Collect spillage.
Storage Store away from incompatible materials.
DisposalP501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS number %Chemical name Common name and synonymsALPHA-HYDROXYTOLUENEPHENYLCARBINOLPHENYLMETHANOLALPHA-TOLUENOLBenzenemethanolphenylmethanolBenzyl carbinol
100-51-6BENZYL ALCOHOL 100
4. FIRST-AID MEASURESInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
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Skin contact Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Eye contact Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Ingestion Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Most importantsymptoms/effects, acute anddelayed
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Skin irritation. May cause redness and pain.
Indication of immediate medicalattention and special treatmentneeded
Not available.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
5. FIRE-FIGHTING MEASURESSuitable extinguishing media Water spray, fog, CO2, dry chemical, or alcohol resistant foam.Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Specific hazards arising fromthe chemical
Fire may produce irritating, corrosive and/or toxic gases.
Special protective equipmentand precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Fire fightingequipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Specific methods Use water spray to cool unopened containers.General fire hazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.
6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures
Keep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
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Methods and materials forcontainment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Donot allow material to contaminate ground water system. Absorb in vermiculite, dry sand or earthand place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
7. HANDLING AND STORAGEPrecautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Take precautionary
measures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Conditions for safe storage,including any incompatibilities
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits
US. Workplace Environmental Exposure Level (WEEL) GuidesValueMaterial Type
TWA 44.2 mg/m3BENZYL ALCOHOL (CAS100-51-6)
10 ppmBiological limit values No biological exposure limits noted for the ingredient(s).Appropriate engineering controls Use explosion-proof ventilation equipment to stay below exposure limits.
Individual protection measures, such as personal protective equipmentEye/face protection Avoid contact with eyes.
Skin protectionHand protection Chemical resistant gloves.
Other Not available.Respiratory protection Chemical respirator with organic vapor cartridge and full facepiece.
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Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations Keep away from food and drink. Always observe good personal hygiene measures, such aswashing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants.
9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Refer to Spec Sheet
Physical state Liquid.Form Liquid.Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 4.64 °F (-15.2 °C)
Initial boiling point and boilingrange
401.54 °F (205.3 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.09 mm Hg at 25 °C
Vapor density 3.72
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
1.1
Auto-ignition temperature 816.8 °F (436 °C)
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 1.04 g/cm3 estimated
Dynamic viscosity 1.06 mPa.s1.62 mPa.s2.76 mPa.s
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5.47 mPa.s
Dynamic viscositytemperature
212 °F (100 °C)
167 °F (75 °C)122 °F (50 °C)77 °F (25 °C)
Flammability class Combustible IIIB estimated
Kinematic viscosity 1.013 mm²/s estimated
Molecular formula C7-H8-O
Molecular weight 108.14 g/mol
Percent volatile 100 %
Specific gravity 1.04 at 25 °C
VOC (Weight %) 100 % EPA estimated
10. STABILITY AND REACTIVITYReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Chemical stability Material is stable under normal conditions.Possibility of hazardousreactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products if stored and handled as indicated.
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation Harmful if inhaled.
Skin contact Harmful in contact with skin. Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion Harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Skin irritation. May cause redness and pain.
Information on toxicological effects
Acute toxicity Harmful if inhaled. Harmful in contact with skin. Harmful if swallowed.
Test ResultsProduct SpeciesBENZYL ALCOHOL (CAS 100-51-6)
LD50 RabbitDermalAcute
2000 mg/kg
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Test ResultsProduct Species
LC100 RatInhalation
> 200 - < 300 mg/l, 8 Hours
LC50 Rat 11 mg/l, 8 Hours
LD50 RatOral
> 1230 - < 3100 mg/kg Remarks:Behavioral:Somnolence (generaldepressed activity). Behavioral:Excitement.Behavioral:Coma.
* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Causes skin irritation.
Skin - rabbit - Irritating to skin. - 24 hSerious eye damage/eyeirritation
Causes serious eye irritation.
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONEcotoxicity Toxic to aquatic life with long lasting effects.
Product Test ResultsSpeciesBENZYL ALCOHOL (CAS 100-51-6)
AquaticEC50Crustacea 55 mg/l, 24 hoursDaphnia magna
LC50Fish 10 mg/l, 96 hoursBluegill (Lepomis macrochirus)
* Estimates for product may be based on additional component data not shown.
460 mg/l, 96 hoursFathead minnow (Pimephales promelas)
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Persistence and degradability Biodegradability Biotic/AerobicResult: 92 - 96 % - Readily biodegradable.
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)1.1
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDisposal instructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.Hazardous waste code Not established.Waste from residues / unusedproducts
Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
14. TRANSPORT INFORMATIONADN
3082UN numberENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BENZYL ALCOHOL)UN proper shipping name9Transport hazard class(es)-Subsidiary class(es)IIIPacking groupYesEnvironmental hazards9Labels required
ADR3082UN numberENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BENZYL ALCOHOL)UN proper shipping name9Transport hazard class(es)-Subsidiary class(es)IIIPacking groupYesEnvironmental hazards9Labels required
RID3082UN numberENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BENZYL ALCOHOL)UN proper shipping name9Transport hazard class(es)-Subsidiary class(es)IIIPacking group
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YesEnvironmental hazards9Labels required
DOT
3082UN numberBULK
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BENZYL ALCOHOL)Proper shipping name9Hazard classIIIPacking group
YesMarine pollutantEnvironmental hazards
155Packaging exceptions241Packaging bulk9Labels required
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDG3082UN numberENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BENZYL ALCOHOL)UN proper shipping name9Transport hazard class(es)-Subsidiary class(es)IIIPacking group
YesMarine pollutantEnvironmental hazards
9Labels requiredNot applicable.Transport in bulk according
to Annex II of MARPOL73/78 and the IBC Code
ADN; ADR; DOT BULK; IMDG; RID
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Marine pollutant
15. REGULATORY INFORMATIONUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
SARA 304 Emergency release notificationNot regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes
Delayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substanceNot listed.
SARA 311/312 Hazardouschemical
Yes
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Safe Drinking Water Act(SDWA)
Not regulated.
500028 BENZYL ALCOHOL FCCSAFETY DATA SHEET
Version # 02Revision Date: 03-31-2015
Print Date: 12-01-2015Page 11 of 12
US state regulationsUS - Minnesota Haz Subs: Hazardous substance
BENZYL ALCOHOL (CAS 100-51-6) Hazardous substance.US. Massachusetts RTK - Substance List
BENZYL ALCOHOL (CAS 100-51-6)US. New Jersey Worker and Community Right-to-Know Act
Not listed.US. Pennsylvania Worker and Community Right-to-Know Law
BENZYL ALCOHOL (CAS 100-51-6)US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISIONIssue date 01-13-2015Revision date 03-31-2015Version # 02HMIS® ratings Health: 2
Flammability: 1Physical hazard: 0
500028 BENZYL ALCOHOL FCCSAFETY DATA SHEET
Version # 02Revision Date: 03-31-2015
Print Date: 12-01-2015Page 12 of 12
Disclaimer Vigon cannot anticipate all conditions under which this information and its product, or the productsof other manufacturers in combination with its product, may be used. It is the user’s responsibilityto ensure safe conditions for handling, storage and disposal of the product, and to assume liabilityfor loss, injury, damage or expense due to improper use. The information in the sheet was writtenbased on the best knowledge and experience currently available. The above information relatesonly to this product and not to its use in combination with any other material or any particularprocess and is designed only as guidance for the safe handling, use, processing, storage,transportation, disposal, and should not be considered as a guarantee or quality specification. Theabove information is based on data provided by and collected from recognized sources such asdistributors, manufacturers, and technical groups and is considered to be accurate to the best ofVigon’s knowledge as of the date of this document. It is the responsibility of the user to review allsafety information about this product and determine its safety and suitability in their own processesand operations. Appropriate warnings and safe handling procedures should be provided to allhandlers and users, taking into account the intended use and the specific conditions and factorsrelating to such use in accordance with all applicable laws and regulations.
Revision Information Product and Company Identification: Alternate Trade NamesACCIDENTAL RELEASE MEASURES: Methods and materials for containment and cleaning upPhysical & Chemical Properties: Multiple PropertiesToxicological Information: Toxicological DataEcological Information: EcotoxicityOTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION: DisclaimerMaterial Attributes & Uses; Experimental Data: Material Attributes
500454 CASSIA OIL NATURALSAFETY DATA SHEET
Version # 01Revision Date: 12-01-2015
Print Date: 12-01-2015Page 1 of 11
1. IDENTIFICATIONProduct Description: CASSIA OIL NATURALCAS # 8007-80-5
Other means of identificationVigon Item # 500454
Recommended use Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended restrictions For Manufacturing Use Only
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 5Acute toxicity, oralHealth hazardsCategory 3Acute toxicity, dermalCategory 2Skin corrosion/irritationCategory 2ASerious eye damage/eye irritationCategory 1Sensitization, skin
Not classified.Environmental hazards
Label elements
Signal word Danger
Hazard statementH303 May be harmful if swallowed.H311 Toxic in contact with skin.H315 Causes skin irritation.H315 + H320 Causes skin and eye irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.
Precautionary statementPrevention
P261 Avoid breathing mist or vapor.P264 Wash thoroughly after handling.P272 Contaminated work clothing should not be allowed out of the workplace.
500454 CASSIA OIL NATURALSAFETY DATA SHEET
Version # 01Revision Date: 12-01-2015
Print Date: 12-01-2015Page 2 of 11
P280 Wear protective gloves/protective clothing.P280 Wear eye/face protection.
ResponseP302 + P352 IF ON SKIN: Wash with plenty of water.P305 + P351 +P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.P312 Call a POISON CENTER/doctor if you feel unwell.P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.P337 + P313 If eye irritation persists: Get medical advice/attention.P361 + P364 Take off immediately all contaminated clothing and wash it before reuse.
StorageP405 Store locked up.
DisposalP501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS number %Chemical name Common name and synonyms8007-80-5CASSIA OIL 100
4. FIRST-AID MEASURESInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Skin contact Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Eye contact Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Ingestion Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Most importantsymptoms/effects, acute anddelayed
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Skin irritation. May cause redness and pain. May cause an allergic skin reaction.Dermatitis. Rash.
Indication of immediate medicalattention and special treatmentneeded
Not available.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
500454 CASSIA OIL NATURALSAFETY DATA SHEET
Version # 01Revision Date: 12-01-2015
Print Date: 12-01-2015Page 3 of 11
5. FIRE-FIGHTING MEASURESSuitable extinguishing media Water spray, fog, CO2, dry chemical, or alcohol resistant foam.Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Specific hazards arising fromthe chemical
Fire may produce irritating, corrosive and/or toxic gases.
Special protective equipmentand precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Fire fightingequipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Specific methods Use water spray to cool unopened containers.General fire hazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.
6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures
Keep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Methods and materials forcontainment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Donot allow material to contaminate ground water system. Absorb in vermiculite, dry sand or earthand place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
500454 CASSIA OIL NATURALSAFETY DATA SHEET
Version # 01Revision Date: 12-01-2015
Print Date: 12-01-2015Page 4 of 11
7. HANDLING AND STORAGEPrecautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. All equipment used
when handling the product must be grounded. Avoid contact with eyes, skin, and clothing. Avoidprolonged exposure. Wash thoroughly after handling. Take precautionary measures against staticdischarges. Avoid breathing vapor.
Conditions for safe storage,including any incompatibilities
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits No exposure limits noted for ingredient(s).Biological limit values No biological exposure limits noted for the ingredient(s).Appropriate engineering controls Use explosion-proof ventilation equipment to stay below exposure limits.
Individual protection measures, such as personal protective equipmentEye/face protection Wear safety glasses with side shields (or goggles). Face shield is recommended.
Skin protectionHand protection Chemical resistant gloves.
Other Use of an impervious apron is recommended.
Respiratory protection Respiratory protection not required. If ventilation is insufficient, suitable respiratory protection mustbe provided.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations Keep away from food and drink. Always observe good personal hygiene measures, such aswashing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants. Contaminated work clothingshould not be allowed out of the workplace.
9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Refer to Spec Sheet
Physical state Liquid.Form Liquid.Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boilingrange
Not available.
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Flammability (solid, gas) Not applicable.
500454 CASSIA OIL NATURALSAFETY DATA SHEET
Version # 01Revision Date: 12-01-2015
Print Date: 12-01-2015Page 5 of 11
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.1 mm Hg at 20 °C
Vapor density Not available.
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 1.05 g/cm3 estimated at 20 °C
Flammability class Combustible IIIB estimated
Molecular formula Not applicable
Specific gravity 1.05 at 25 °C
10. STABILITY AND REACTIVITYReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Chemical stability Material is stable under normal conditions.Possibility of hazardousreactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products if stored and handled as indicated.
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation No adverse effects due to inhalation are expected.
Skin contact Toxic in contact with skin. Causes skin irritation. May cause an allergic skin reaction.
Eye contact Causes serious eye irritation.
Ingestion May be harmful if swallowed.
500454 CASSIA OIL NATURALSAFETY DATA SHEET
Version # 01Revision Date: 12-01-2015
Print Date: 12-01-2015Page 6 of 11
Symptoms related to thephysical, chemical andtoxicological characteristics
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Skin irritation. May cause redness and pain. May cause an allergic skin reaction.Dermatitis. Rash.
Information on toxicological effects
Acute toxicity Toxic in contact with skin. May be harmful if swallowed. May cause an allergic skin reaction.
Test ResultsProduct SpeciesCASSIA OIL (CAS 8007-80-5)
LD50 RabbitDermalAcute
320 mg/kg
LD50 RatOral
2800 mg/kg
* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Causes skin irritation.Serious eye damage/eyeirritation
Causes serious eye irritation.
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
Skin sensitization May cause an allergic skin reaction.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONEcotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.Persistence and degradability No data is available on the degradability of this product.Bioaccumulative potential No data available.Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
500454 CASSIA OIL NATURALSAFETY DATA SHEET
Version # 01Revision Date: 12-01-2015
Print Date: 12-01-2015Page 7 of 11
13. DISPOSAL CONSIDERATIONSDisposal instructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.Hazardous waste code Not established.Waste from residues / unusedproducts
Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
14. TRANSPORT INFORMATIONADN
2810UN numberTOXIC LIQUID, ORGANIC, N.O.S. (CASSIA OIL)UN proper shipping name6.1(PGIII)Transport hazard class(es)-Subsidiary class(es)IIIPacking groupNoEnvironmental hazards6.1Labels required
ADR2810UN numberTOXIC LIQUID, ORGANIC, N.O.S. (CASSIA OIL)UN proper shipping name6.1(PGIII)Transport hazard class(es)-Subsidiary class(es)IIIPacking groupNoEnvironmental hazards6.1Labels required
RID2810UN numberTOXIC LIQUID, ORGANIC, N.O.S. (CASSIA OIL)UN proper shipping name6.1(PGIII)Transport hazard class(es)-Subsidiary class(es)IIIPacking groupNoEnvironmental hazards6.1Labels required
DOT
2810UN numberBULK
TOXIC LIQUID, ORGANIC, N.O.S. (CASSIA OIL)Proper shipping name6.1(PGIII)Hazard classIIIPacking group
500454 CASSIA OIL NATURALSAFETY DATA SHEET
Version # 01Revision Date: 12-01-2015
Print Date: 12-01-2015Page 8 of 11
NoMarine pollutantEnvironmental hazards
153Packaging exceptions241Packaging bulk6.1Labels required
DOT
2810UN numberNON-BULK
TOXIC LIQUID, ORGANIC, N.O.S. (CASSIA OIL)Proper shipping name6.1(PGIII)Hazard classIIIPacking group
NoMarine pollutantEnvironmental hazards
153Packaging exceptions203Packaging non bulk6.1Labels required
IATA2810UN numberTOXIC LIQUID, ORGANIC, N.O.S. (CASSIA OIL)UN proper shipping name6.1(PGIII)Transport hazard class(es)-Subsidiary class(es)IIIPacking groupNoEnvironmental hazards6.1Labels required
IMDG2810UN numberTOXIC LIQUID, ORGANIC, N.O.S. (CASSIA OIL)UN proper shipping name6.1(PGIII)Transport hazard class(es)-Subsidiary class(es)IIIPacking group
NoMarine pollutantEnvironmental hazards
6.1Labels requiredNot applicable.Transport in bulk according
to Annex II of MARPOL73/78 and the IBC Code
500454 CASSIA OIL NATURALSAFETY DATA SHEET
Version # 01Revision Date: 12-01-2015
Print Date: 12-01-2015Page 9 of 11
ADN; ADR; DOT BULK; DOT NON-BULK; IATA; IMDG; RID
15. REGULATORY INFORMATIONUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
SARA 304 Emergency release notificationNot regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes
Delayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substanceNot listed.
SARA 311/312 Hazardouschemical
Yes
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Safe Drinking Water Act(SDWA)
Not regulated.
500454 CASSIA OIL NATURALSAFETY DATA SHEET
Version # 01Revision Date: 12-01-2015
Print Date: 12-01-2015Page 10 of 11
US state regulationsUS. Massachusetts RTK - Substance List
Not regulated.US. New Jersey Worker and Community Right-to-Know Act
Not listed.US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)NoJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISIONIssue date 12-01-2015Revision date 12-01-2015Version # 01HMIS® ratings Health: 2
Flammability: 1Physical hazard: 0
500454 CASSIA OIL NATURALSAFETY DATA SHEET
Version # 01Revision Date: 12-01-2015
Print Date: 12-01-2015Page 11 of 11
Disclaimer Vigon cannot anticipate all conditions under which this information and its product, or the productsof other manufacturers in combination with its product, may be used. It is the user’s responsibilityto ensure safe conditions for handling, storage and disposal of the product, and to assume liabilityfor loss, injury, damage or expense due to improper use. The information in the sheet was writtenbased on the best knowledge and experience currently available. The above information relatesonly to this product and not to its use in combination with any other material or any particularprocess and is designed only as guidance for the safe handling, use, processing, storage,transportation, disposal, and should not be considered as a guarantee or quality specification. Theabove information is based on data provided by and collected from recognized sources such asdistributors, manufacturers, and technical groups and is considered to be accurate to the best ofVigon’s knowledge as of the date of this document. It is the responsibility of the user to review allsafety information about this product and determine its safety and suitability in their own processesand operations. Appropriate warnings and safe handling procedures should be provided to allhandlers and users, taking into account the intended use and the specific conditions and factorsrelating to such use in accordance with all applicable laws and regulations.
500074 CINNAMIC ALDEHYDE FCCSAFETY DATA SHEET
Version # 02Revision Date: 11-02-2016
Print Date: 11-02-2016Page 1 of 10
1. IDENTIFICATIONCINNAMIC ALDEHYDE FCCProduct Description:104-55-2CAS #
FEMA Number 2286
Other means of identification500074Vigon Item #Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended use
For Manufacturing Use OnlyRecommended restrictions
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
Manufacturer/Importer/Supplier/Distributor informationManufacturer
Vigon International, Inc.Address 127 Airport RoadCompany name
WebsiteTelephone For information call: 570-476-6300
Emergency phone number INFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
United States
www.vigon.comNot available.
E. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 5Acute toxicity, oralHealth hazardsCategory 4Acute toxicity, dermalCategory 2Skin corrosion/irritationCategory 2ASerious eye damage/eye irritationCategory 1Sensitization, skinCategory 3 respiratory tract irritationSpecific target organ toxicity, single
exposureCategory 2Aspiration hazardCategory 2Hazardous to the aquatic environment,
acute hazardEnvironmental hazards
500074 CINNAMIC ALDEHYDE FCCSAFETY DATA SHEET
Version # 02Revision Date: 11-02-2016
Print Date: 11-02-2016Page 2 of 10
Label elements
Signal word Warning
Hazard statement May be harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes skin andeye irritation. May cause an allergic skin reaction. Causes serious eye irritation. May causerespiratory irritation. Toxic to aquatic life.
Precautionary statementPrevention Wear eye/face protection. Avoid breathing mist or vapor. Wash thoroughly after handling. Use
only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed outof the workplace. Avoid release to the environment. Wear protective gloves/protective clothing.
Response IF ON SKIN: Wash with plenty of water. IF INHALED: Remove person to fresh air and keepcomfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER/doctor if youfeel unwell. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists:Get medical advice/attention. Take off contaminated clothing and wash it before reuse.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC)
After prolonged contact with highly porous materials, this product may spontaneously combust.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS numberCommon name and synonymsChemical name %CINNAMAL3- phenylprop- 2- enalPHENYL ACROLEINbenzylidene acetaldehyde3- phenyl acryl aldehyde
104-55-2CINNAMIC ALDEHYDE 100
4. FIRST-AID MEASURESIf breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Inhalation
Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Skin contact
Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Eye contact
Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Ingestion
500074 CINNAMIC ALDEHYDE FCCSAFETY DATA SHEET
Version # 02Revision Date: 11-02-2016
Print Date: 11-02-2016Page 3 of 10
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. May cause respiratory irritation. Skin irritation. May cause redness and pain. May cause anallergic skin reaction. Dermatitis. Rash.
Most importantsymptoms/effects, acute anddelayed
Not available.Indication of immediate medicalattention and special treatmentneeded
Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. FIRE-FIGHTING MEASURESWater spray, fog, CO2, dry chemical, or alcohol resistant foam.Suitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing mediaFire may produce irritating, corrosive and/or toxic gases. Porous material such as rags, paper,insulation, or organic clay may spontaneously combust when wetted with this material.
Specific hazards arising fromthe chemical
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Special protective equipmentand precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Fire fightingequipment/instructions
Use water spray to cool unopened containers.Specific methodsStatic charges generated by emptying package in or near flammable vapor may cause flash fire.General fire hazards
6. ACCIDENTAL RELEASE MEASURESKeep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Personal precautions, protectiveequipment and emergencyprocedures
500074 CINNAMIC ALDEHYDE FCCSAFETY DATA SHEET
Version # 02Revision Date: 11-02-2016
Print Date: 11-02-2016Page 4 of 10
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Donot allow material to contaminate ground water system. Absorb in vermiculite, dry sand or earthand place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Methods and materials forcontainment and cleaning up
Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
Environmental precautions
7. HANDLING AND STORAGEDo not handle or store near an open flame, heat or other sources of ignition. All equipment usedwhen handling the product must be grounded. Avoid contact with eyes, skin, and clothing. Avoidprolonged exposure. Wash thoroughly after handling. Porous material such as rags, paper,insulation, or organic clay may spontaneously combust when wetted with this material. Mayauto-oxidize with sufficient heat generation to ignite if spread (as a thin film) or absorbed onporous or fibrous material. Take precautionary measures against static discharges. Contaminatedrags and cloths must be put in fireproof containers for disposal. Avoid breathing vapor.
Precautions for safe handling
Do not store in direct sunlight. Keep under a nitrogen blanket. Keep container closed. Handlecontainers with care. Open slowly in order to control possible pressure release. Store in a cool,well-ventilated area.
Conditions for safe storage,including any incompatibilities
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONThis substance has no PEL, TLV, or other recommended exposure limit.Occupational exposure limitsNo biological exposure limits noted for the ingredient(s).Biological limit valuesUse explosion-proof ventilation equipment to stay below exposure limits.Appropriate engineering controls
Individual protection measures, such as personal protective equipmentWear safety glasses with side shields (or goggles). Face shield is recommended.Eye/face protection
Skin protectionChemical resistant gloves.Hand protection
Use of an impervious apron is recommended.Other
Respiratory protection not required. If ventilation is insufficient, suitable respiratory protection mustbe provided.
Respiratory protection
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Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Keep away from food and drink. Always observe good personal hygiene measures, such aswashing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants. Contaminated work clothingshould not be allowed out of the workplace.
General hygiene considerations
9. PHYSICAL AND CHEMICAL PROPERTIESRefer to Spec SheetAppearanceLiquid.Physical stateLiquid.FormRefer to Spec SheetColorCharacteristic.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point 18.5 °F (-7.5 °C)
Initial boiling point and boilingrange
487.4 °F (253 °C) 101.325 kPa
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.03 mm Hg at 25 °C
Vapor density 4.6
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 1.05 g/cm3 estimated at 25 °C
Flammability class Combustible IIIB estimated
Molecular formula C9-H8-O
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Molecular weight 132.15 g/mol
Specific gravity 1.05 at 25 °C
10. STABILITY AND REACTIVITYThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityMaterial is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous
reactionsPorous material such as rags, paper, insulation, or organic clay may spontaneously combust whenwetted with this material.
Conditions to avoid
Strong oxidizing agents.Incompatible materialsNo hazardous decomposition products if stored and handled as indicated.Hazardous decomposition
products
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction.
Eye contact Causes serious eye irritation.
Ingestion May be harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. May cause respiratory irritation. Skin irritation. May cause redness and pain. May cause anallergic skin reaction. Dermatitis. Rash.
Information on toxicological effects
Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness andcentral nervous system effects. Harmful in contact with skin. May be harmful if swallowed. Maycause an allergic skin reaction. May cause respiratory irritation.
Test ResultsProduct SpeciesCINNAMIC ALDEHYDE (CAS 104-55-2)
LD50 RabbitDermalAcute
0.59 ml/kg
LD50 RatOral
2200 mg/kg
* Estimates for product may be based on additional component data not shown.Causes skin irritation.Human - 40 mg/48H - SEVERE
Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eyeirritation
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
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May cause an allergic skin reaction.Skin sensitizationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
US. National Toxicology Program (NTP) Report on CarcinogensNot listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -single exposure
May cause respiratory irritation.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONToxic to aquatic life.EcotoxicityNo data is available on the degradability of this product.Persistence and degradabilityNo data available.Bioaccumulative potentialNo data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDo not discharge into drains, water courses or onto the ground. Do not allow this material to draininto sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulationsNot established.Hazardous waste codeEmpty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Waste from residues / unusedproducts
Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
Contaminated packaging
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.
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ADRNot regulated as dangerous goods.
RIDNot regulated as dangerous goods.
DOT
Not regulated as dangerous goods.BULK
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.
US federal regulations
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
SARA 304 Emergency release notificationNot regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substanceNot listed.
YesSARA 311/312 Hazardouschemical
SARA 313 (TRI reporting)Not regulated.
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Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Not regulated.Safe Drinking Water Act
(SDWA)
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION01-15-2015Issue date11-02-2016Revision date
Version # 02Health: 2Flammability: 1Physical hazard: 0
HMIS® ratings
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Vigon International, Inc. cannot anticipate all conditions under which this information and itsproduct, or the products of other manufacturers in combination with its product, may be used. It isthe user’s responsibility to ensure safe conditions for handling, storage and disposal of theproduct, and to assume liability for loss, injury, damage or expense due to improper use. Theinformation in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
Disclaimer
Product and Company Identification: Alternate Trade NamesHAZARD(S) IDENTIFICATION: ResponseACCIDENTAL RELEASE MEASURES: Methods and materials for containment and cleaning upEXPOSURE CONTROLS/PERSONAL PROTECTION: PPE SymbolsPhysical & Chemical Properties: Multiple PropertiesPHYSICAL AND CHEMICAL PROPERTIES: Flammability (solid, gas)Toxicological Information: Toxicological DataTOXICOLOGICAL INFORMATION: Aspiration hazardTOXICOLOGICAL INFORMATION: Eye contactTOXICOLOGICAL INFORMATION: Respiratory sensitizationREGULATORY INFORMATION: US federal regulationsOTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION: ReferencesGHS: Classification
Revision information
500107 DECALACTONE GAMMA NATURALSAFETY DATA SHEET
Version # 01Revision Date: 04-29-2015
Print Date: 11-29-2015Page 1 of 10
1. IDENTIFICATIONProduct Description: DECALACTONE GAMMA NATURALCAS # 706-14-9
FEMA Number 2360
Other means of identificationVigon Item # 500107
Recommended use Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended restrictions For Manufacturing Use Only
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 2Skin corrosion/irritationHealth hazardsCategory 2ASerious eye damage/eye irritationCategory 3 respiratory tract irritationSpecific target organ toxicity, single
exposureCategory 3Hazardous to the aquatic environment,
acute hazardEnvironmental hazards
Category 3Hazardous to the aquatic environment,long-term hazard
Label elements
Signal word Warning
Hazard statementH315 Causes skin irritation.H315 + H320 Causes skin and eye irritation.H319 Causes serious eye irritation.H335 May cause respiratory irritation.H402 Harmful to aquatic life.H412 Harmful to aquatic life with long lasting effects.
Precautionary statementPrevention
500107 DECALACTONE GAMMA NATURALSAFETY DATA SHEET
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P261 Avoid breathing mist or vapor.P264 Wash thoroughly after handling.P271 Use only outdoors or in a well-ventilated area.P273 Avoid release to the environment.P280 Wear protective gloves.P280 Wear eye/face protection.
ResponseP302 + P352 IF ON SKIN: Wash with plenty of water.P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P305 + P351 +P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.P312 Call a POISON CENTER/doctor if you feel unwell.P321 Specific treatment (see this label).P332 + P313 If skin irritation occurs: Get medical advice/attention.P337 + P313 If eye irritation persists: Get medical advice/attention.P362 + P364 Take off contaminated clothing and wash it before reuse.
StorageP403 + P233 Store in a well-ventilated place. Keep container tightly closed.P405 Store locked up.
DisposalP501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS number %Chemical name Common name and synonyms5- hexyloxolan-2-one5-Hexyldihydro-2(3H)-furanoneDecan-4-olideHYDROXYDECANOIC ACID,GAMMA-LACTONE
706-14-9DECALACTONE GAMMA 100
4. FIRST-AID MEASURESInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Skin contact Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Eye contact Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
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Ingestion Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Most importantsymptoms/effects, acute anddelayed
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. May cause respiratory irritation. Skin irritation. May cause redness and pain.
Indication of immediate medicalattention and special treatmentneeded
Not available.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
5. FIRE-FIGHTING MEASURESSuitable extinguishing media Water spray, fog, CO2, dry chemical, or alcohol resistant foam.Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Specific hazards arising fromthe chemical
Fire may produce irritating, corrosive and/or toxic gases.
Special protective equipmentand precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Fire fightingequipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Specific methods Use water spray to cool unopened containers.General fire hazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.
6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures
Keep unnecessary personnel away. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them. Eliminateall sources of ignition. Avoid contact with skin or inhalation of spillage, dust or vapor.
500107 DECALACTONE GAMMA NATURALSAFETY DATA SHEET
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Methods and materials forcontainment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Donot allow material to contaminate ground water system. Absorb in vermiculite, dry sand or earthand place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Retain and disposeof contaminated wash water. Avoid release to the environment. Contact local authorities in case ofspillage to drain/aquatic environment.
7. HANDLING AND STORAGEPrecautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Take precautionary
measures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Conditions for safe storage,including any incompatibilities
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits No exposure limits noted for ingredient(s).Biological limit values No biological exposure limits noted for the ingredient(s).Appropriate engineering controls Use explosion-proof ventilation equipment to stay below exposure limits.
Individual protection measures, such as personal protective equipmentEye/face protection Wear safety glasses with side shields (or goggles).
Skin protectionHand protection Chemical resistant gloves.
Other Not available.Respiratory protection Respiratory protection not required. If ventilation is insufficient, suitable respiratory protection must
be provided.Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the materialand before eating, drinking, and/or smoking. Routinely wash work clothing and protectiveequipment to remove contaminants.
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9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Refer to Spec Sheet
Physical state Liquid.Form Liquid.Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boilingrange
537.8 °F (281 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.01 mm Hg at 20 °C
Vapor density 5.9
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationFlammability class Combustible IIIB estimated
Molecular formula C10H18O2
Molecular weight 170.25 g/mol
Specific gravity 0.95 at 25 °C
10. STABILITY AND REACTIVITYReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Chemical stability Material is stable under normal conditions.
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Possibility of hazardousreactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products if stored and handled as indicated.
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation. Causes mild eye irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to thephysical, chemical andtoxicological characteristics
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Skin irritation. May cause redness and pain. May cause respiratory irritation.
Information on toxicological effects
Acute toxicity May cause respiratory irritation.
Test ResultsProduct SpeciesDECALACTONE GAMMA NATURAL (CAS 706-14-9)
LD50 RabbitDermalAcute
> 5000 mg/kg
LD50 RatOral
> 5000 mg/kg
* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Causes skin irritation.Serious eye damage/eyeirritation
Causes serious eye irritation.
Respiratory or skin sensitizationRespiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -single exposure
May cause respiratory irritation.
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Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not available.
12. ECOLOGICAL INFORMATIONEcotoxicity Harmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected.
Product Test ResultsSpecies
* Estimates for product may be based on additional component data not shown.
DECALACTONE GAMMA (CAS 706-14-9)Aquatic
LC50Fish 17.1 - 19 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Persistence and degradability No data is available on the degradability of this product.Bioaccumulative potential No data available.Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDisposal instructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.Hazardous waste code Not established.Waste from residues / unusedproducts
Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
Not regulated as dangerous goods.BULK
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DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
SARA 304 Emergency release notificationNot regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes
Delayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substanceNot listed.
SARA 311/312 Hazardouschemical
No
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Safe Drinking Water Act(SDWA)
Not regulated.
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US state regulationsUS. Massachusetts RTK - Substance List
Not regulated.US. New Jersey Worker and Community Right-to-Know Act
Not listed.US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISIONIssue date 11-29-2015Revision date 04-29-2015Version # 01HMIS® ratings Health: 2
Flammability: 1Physical hazard: 0
500107 DECALACTONE GAMMA NATURALSAFETY DATA SHEET
Version # 01Revision Date: 04-29-2015
Print Date: 11-29-2015Page 10 of 10
Disclaimer The information in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
500560 CAPRIC ACID NATURAL (DECANOIC ACID)SAFETY DATA SHEET
Version # 01Revision Date: 01-10-2015
Print Date: 12-01-2015Page 1 of 10
1. IDENTIFICATIONProduct Description: CAPRIC ACID NATURAL (DECANOIC ACID)CAS # 334-48-5
FEMA Number 2364
Other means of identificationVigon Item # 500560
Recommended use Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended restrictions For Manufacturing Use Only
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 5Acute toxicity, oralHealth hazardsCategory 2Skin corrosion/irritationCategory 1Serious eye damage/eye irritationCategory 3 respiratory tract irritationSpecific target organ toxicity, single
exposureCategory 3Hazardous to the aquatic environment,
acute hazardEnvironmental hazards
Category 3Hazardous to the aquatic environment,long-term hazard
Label elements
Signal word Danger
Hazard statementH303 May be harmful if swallowed.H315 Causes skin irritation.H318 Causes serious eye damage.H335 May cause respiratory irritation.H402 Harmful to aquatic life.H412 Harmful to aquatic life with long lasting effects.
500560 CAPRIC ACID NATURAL (DECANOIC ACID)SAFETY DATA SHEET
Version # 01Revision Date: 01-10-2015
Print Date: 12-01-2015Page 2 of 10
Precautionary statementPrevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.P264 Wash thoroughly after handling.P271 Use only outdoors or in a well-ventilated area.P273 Avoid release to the environment.P280 Wear protective gloves.P280 Wear eye/face protection.
ResponseP302 + P352 IF ON SKIN: Wash with plenty of water.P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P305 + P351 +P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.P310 Immediately call a POISON CENTER/doctor.P321 Specific treatment (see this label).P332 + P313 If skin irritation occurs: Get medical advice/attention.P362 + P364 Take off contaminated clothing and wash it before reuse.
StorageP403 + P233 Store in a well-ventilated place. Keep container tightly closed.P405 Store locked up.
DisposalP501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS number %Chemical name Common name and synonymscaprynic acidcaprinic acidDECYLIC ACIDDECANOIC ACID1-NONANECARBOXYLIC ACID
334-48-5CAPRIC ACID 100
4. FIRST-AID MEASURESInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Skin contact Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Eye contact Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
500560 CAPRIC ACID NATURAL (DECANOIC ACID)SAFETY DATA SHEET
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Ingestion Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Most importantsymptoms/effects, acute anddelayed
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Permanent eye damage including blindness could result. May cause respiratory irritation.Skin irritation. May cause redness and pain.
Indication of immediate medicalattention and special treatmentneeded
Not available.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
5. FIRE-FIGHTING MEASURESSuitable extinguishing media Water spray, fog, CO2, dry chemical, or alcohol resistant foam.Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Specific hazards arising fromthe chemical
Fire may produce irritating, corrosive and/or toxic gases.
Special protective equipmentand precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Fire fightingequipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Specific methods Use water spray to cool unopened containers.General fire hazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.
6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures
Keep unnecessary personnel away. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them. Eliminateall sources of ignition. Avoid contact with skin or inhalation of spillage, dust or vapor.
500560 CAPRIC ACID NATURAL (DECANOIC ACID)SAFETY DATA SHEET
Version # 01Revision Date: 01-10-2015
Print Date: 12-01-2015Page 4 of 10
Methods and materials forcontainment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Donot allow material to contaminate ground water system. Absorb in vermiculite, dry sand or earthand place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Retain and disposeof contaminated wash water. Avoid release to the environment. Contact local authorities in case ofspillage to drain/aquatic environment.
7. HANDLING AND STORAGEPrecautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Take precautionary
measures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Conditions for safe storage,including any incompatibilities
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits No exposure limits noted for ingredient(s).Biological limit values No biological exposure limits noted for the ingredient(s).Appropriate engineering controls Use explosion-proof ventilation equipment to stay below exposure limits.
Individual protection measures, such as personal protective equipmentEye/face protection Wear safety glasses with side shields (or goggles). Face shield is recommended.
Skin protectionHand protection Chemical resistant gloves.
Other Use of an impervious apron is recommended.
Respiratory protection Respiratory protection not required. If ventilation is insufficient, suitable respiratory protection mustbe provided.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations Keep away from food and drink. Always observe good personal hygiene measures, such aswashing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants.
500560 CAPRIC ACID NATURAL (DECANOIC ACID)SAFETY DATA SHEET
Version # 01Revision Date: 01-10-2015
Print Date: 12-01-2015Page 5 of 10
9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Refer to Spec Sheet
Physical state Solid.Form Solid.Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 88.7 °F (31.5 °C)
Initial boiling point and boilingrange
512.6 - 518 °F (267 - 270 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0 kPa at 25 °C0 kPa at 25 °C15 mm Hg at 25 °C
Vapor density 6
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
4.1
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 0.89 g/cm3 estimated
Dynamic viscosity 4.3 mPa.s
Dynamic viscositytemperature
122 °F (50 °C)
Flammability class Combustible IIIB estimated
Kinematic viscosity 4.832 mm²/s estimated
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Molecular formula C10-H20-O2
Molecular weight 172.27 g/mol
Specific gravity 0.89 at 40 °C
10. STABILITY AND REACTIVITYReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Chemical stability Material is stable under normal conditions.Possibility of hazardousreactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products if stored and handled as indicated.
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact Causes skin irritation.
Eye contact Causes serious eye damage.
Ingestion May be harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Permanent eye damage including blindness could result. Skin irritation. May causeredness and pain. May cause respiratory irritation.
Information on toxicological effects
Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness andcentral nervous system effects. May be harmful if swallowed. May cause respiratory irritation.
Test ResultsProduct SpeciesCAPRIC ACID (CAS 334-48-5)
LD50 RabbitDermalAcute
> 5000 mg/kg
LD50 RatOral
3320 mg/kg
LD50 MouseOther
129 mg/kg intravenous
* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Causes skin irritation.Serious eye damage/eyeirritation
Causes serious eye damage.
500560 CAPRIC ACID NATURAL (DECANOIC ACID)SAFETY DATA SHEET
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Respiratory or skin sensitizationRespiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -single exposure
May cause respiratory irritation.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not available.
12. ECOLOGICAL INFORMATIONEcotoxicity Harmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected.Persistence and degradability No data is available on the degradability of this product.Bioaccumulative potential Not available.
Partition coefficient n-octanol / water (log Kow)4.09
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDisposal instructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.Hazardous waste code Not established.Waste from residues / unusedproducts
Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.
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RIDNot regulated as dangerous goods.
DOT
Not regulated as dangerous goods.BULK
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
SARA 304 Emergency release notificationNot regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes
Delayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substanceNot listed.
SARA 311/312 Hazardouschemical
Yes
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
500560 CAPRIC ACID NATURAL (DECANOIC ACID)SAFETY DATA SHEET
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Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)Not regulated.
Safe Drinking Water Act(SDWA)
Not regulated.
US state regulationsUS. Massachusetts RTK - Substance List
Not regulated.US. New Jersey Worker and Community Right-to-Know Act
Not listed.US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISIONIssue date 12-01-2015Revision date 01-10-2015Version # 01HMIS® ratings Health: 3
Flammability: 1Physical hazard: 0
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Version # 01Revision Date: 01-10-2015
Print Date: 12-01-2015Page 10 of 10
Disclaimer The information in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
500439 DIETHYL SUCCINATESAFETY DATA SHEET
Version # 01Revision Date: 04-07-2017
Print Date: 04-07-2017Page 1 of 9
1. IDENTIFICATIONDIETHYL SUCCINATEProduct Description:123-25-1CAS #
FEMA Number 2377
Other means of identification500439Vigon Item #Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended use
For Manufacturing Use OnlyRecommended restrictions
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
Manufacturer/Importer/Supplier/Distributor informationManufacturer
Vigon International, Inc.Address 127 Airport RoadCompany name
WebsiteTelephone For information call: 570-476-6300
Emergency phone number INFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
United States
www.vigon.comNot available.
E. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 5Acute toxicity, dermalHealth hazardsNot classified.Environmental hazards
Label elementsNone.Hazard symbol
Signal word Warning
Hazard statement May be harmful in contact with skin.
Precautionary statementPrevention Observe good industrial hygiene practices.
Response Call a POISON CENTER/doctor if you feel unwell.
Storage Store away from incompatible materials.
500439 DIETHYL SUCCINATESAFETY DATA SHEET
Version # 01Revision Date: 04-07-2017
Print Date: 04-07-2017Page 2 of 9
Disposal Dispose of waste and residues in accordance with local authority requirements.Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS numberCommon name and synonymsChemical name %Butanedioic acid, diethyl esterDiethyl Butanedioatediethyl butane dioatediethyl ethanedicarboxylatediethyl butane- 1, 4- dioate
123-25-1DIETHYL SUCCINATE 100
4. FIRST-AID MEASURESIf breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Inhalation
Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Skin contact
Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Eye contact
Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Ingestion
Direct contact with eyes may cause temporary irritation.Most importantsymptoms/effects, acute anddelayed
Not available.Indication of immediate medicalattention and special treatmentneeded
Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. FIRE-FIGHTING MEASURESWater spray, fog, CO2, dry chemical, or alcohol resistant foam.Suitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing mediaFire may produce irritating, corrosive and/or toxic gases.Specific hazards arising from
the chemicalFirefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Special protective equipmentand precautions for firefighters
500439 DIETHYL SUCCINATESAFETY DATA SHEET
Version # 01Revision Date: 04-07-2017
Print Date: 04-07-2017Page 3 of 9
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Fire fightingequipment/instructions
Use water spray to cool unopened containers.Specific methodsStatic charges generated by emptying package in or near flammable vapor may cause flash fire.General fire hazards
6. ACCIDENTAL RELEASE MEASURESKeep unnecessary personnel away. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them. Eliminateall sources of ignition. Avoid contact with skin or inhalation of spillage, dust or vapor.
Personal precautions, protectiveequipment and emergencyprocedures
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Donot allow material to contaminate ground water system. Absorb in vermiculite, dry sand or earthand place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Methods and materials forcontainment and cleaning up
Prevent further leakage or spillage if safe to do so. Do not contaminate water. Retain and disposeof contaminated wash water. Avoid release to the environment. Contact local authorities in case ofspillage to drain/aquatic environment.
Environmental precautions
7. HANDLING AND STORAGEDo not handle or store near an open flame, heat or other sources of ignition. Take precautionarymeasures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Precautions for safe handling
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
Conditions for safe storage,including any incompatibilities
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONThis substance has no PEL, TLV, or other recommended exposure limit.Occupational exposure limitsNo biological exposure limits noted for the ingredient(s).Biological limit valuesUse explosion-proof ventilation equipment to stay below exposure limits.Appropriate engineering controls
500439 DIETHYL SUCCINATESAFETY DATA SHEET
Version # 01Revision Date: 04-07-2017
Print Date: 04-07-2017Page 4 of 9
Individual protection measures, such as personal protective equipmentWear safety glasses with side shields (or goggles).Eye/face protection
Skin protectionChemical resistant gloves.Hand protection
Not available.OtherRespiratory protection not required. If ventilation is insufficient, suitable respiratory protection mustbe provided.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Always observe good personal hygiene measures, such as washing after handling the materialand before eating, drinking, and/or smoking. Routinely wash work clothing and protectiveequipment to remove contaminants.
General hygiene considerations
9. PHYSICAL AND CHEMICAL PROPERTIESRefer to Spec SheetAppearanceLiquid.Physical stateLiquid.FormRefer to Spec SheetColorCharacteristic.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boilingrange
422.6 °F (217 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.44 mm Hg at 25 °C
Vapor density 6
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
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Print Date: 04-07-2017Page 5 of 9
Decomposition temperature Not available.
Viscosity Not available.
Other informationFlammability class Combustible IIIB estimated
Molecular formula C8H14O4
Molecular weight 174.19
Specific gravity 1.04 at 25 °C
10. STABILITY AND REACTIVITYThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityMaterial is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous
reactionsAvoid temperatures exceeding the flash point. Contact with incompatible materials.Conditions to avoidStrong oxidizing agents.Incompatible materialsNo hazardous decomposition products if stored and handled as indicated.Hazardous decomposition
products
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation No adverse effects due to inhalation are expected.
Skin contact May be harmful in contact with skin. Causes mild skin irritation.
Eye contact Causes mild eye irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to thephysical, chemical andtoxicological characteristics
Direct contact with eyes may cause temporary irritation.
Information on toxicological effects
Acute toxicity May be harmful in contact with skin.
Test ResultsProduct SpeciesDIETHYL SUCCINATE (CAS 123-25-1)
LD50 RabbitDermalAcute
5000 mg/kg
LD50 RatOral
8530 mg/kg
* Estimates for product may be based on additional component data not shown.Skin - rabbit - Mild skin irritationSkin corrosion/irritationEyes - rat - Mild eye irritationSerious eye damage/eye
irritation
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Respiratory or skin sensitizationRespiratory sensitization Not available.
This product is not expected to cause skin sensitization.Skin sensitizationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
US. National Toxicology Program (NTP) Report on CarcinogensNot listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not available.
12. ECOLOGICAL INFORMATIONThe product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
Product Test ResultsSpecies
* Estimates for product may be based on additional component data not shown.
DIETHYL SUCCINATE (CAS 123-25-1)Aquatic
LC50Fish 140 mg/l, 96 hoursFathead minnow (Pimephales promelas)
No data is available on the degradability of this product.Persistence and degradabilityNo data available.Bioaccumulative potentialNo data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDo not discharge into drains, water courses or onto the ground. Do not allow this material to draininto sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
500439 DIETHYL SUCCINATESAFETY DATA SHEET
Version # 01Revision Date: 04-07-2017
Print Date: 04-07-2017Page 7 of 9
Not established.Hazardous waste codeEmpty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Waste from residues / unusedproducts
Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
Contaminated packaging
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
Not regulated as dangerous goods.BULK
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.
US federal regulations
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
SARA 304 Emergency release notificationNot regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
500439 DIETHYL SUCCINATESAFETY DATA SHEET
Version # 01Revision Date: 04-07-2017
Print Date: 04-07-2017Page 8 of 9
Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substanceNot listed.
NoSARA 311/312 Hazardouschemical
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Not regulated.Safe Drinking Water Act
(SDWA)
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION04-07-2017Issue date04-07-2017Revision date
Version # 01
500439 DIETHYL SUCCINATESAFETY DATA SHEET
Version # 01Revision Date: 04-07-2017
Print Date: 04-07-2017Page 9 of 9
Health: 1Flammability: 1Physical hazard: 0
HMIS® ratings
The information in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
Disclaimer
500414 ETHYL MALTOL (VELTOL PLUS)SAFETY DATA SHEET
Version # 03Revision Date: 11-25-2015
Print Date: 11-25-2015Page 1 of 9
1. IDENTIFICATIONProduct Description: ETHYL MALTOL (VELTOL PLUS)CAS # 4940-11-8
FEMA Number 3487
Other means of identificationVigon Item # 500414
Recommended use Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended restrictions For Manufacturing Use Only
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 4Acute toxicity, oralHealth hazardsNot classified.Environmental hazards
Label elements
Signal word Warning
Hazard statementH302 Harmful if swallowed.
Precautionary statementPrevention
P264 Wash thoroughly after handling.P270 Do not eat, drink or smoke when using this product.
ResponseP301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.P330 Rinse mouth.
Storage Store away from incompatible materials.
DisposalP501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwiseclassified (HNOC)
WARNING! May form combustible dust concentrations in air. Avoid breathing dust.
500414 ETHYL MALTOL (VELTOL PLUS)SAFETY DATA SHEET
Version # 03Revision Date: 11-25-2015
Print Date: 11-25-2015Page 2 of 9
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS number %Chemical name Common name and synonyms4H-Pyran-4-one, 2-ethyl-3-hydroxy-2-Ethyl-3-hydroxy-4-pyrone2-ethyl-3-hydroxypyran-4-one
4H-pyran-4-one, 2-ethyl-3-hydroxy-
4940-11-8ETHYL MALTOL 100
4. FIRST-AID MEASURESInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Skin contact Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Eye contact Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Ingestion Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Most importantsymptoms/effects, acute anddelayed
Dusts may irritate the respiratory tract, skin and eyes.
Indication of immediate medicalattention and special treatmentneeded
Not available.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
5. FIRE-FIGHTING MEASURESSuitable extinguishing media Water spray, fog, CO2, dry chemical, or alcohol resistant foam.Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Specific hazards arising fromthe chemical
Fire may produce irritating, corrosive and/or toxic gases.
Explosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, andin the presence of an ignition source is a potential dust explosion hazard.
Special protective equipmentand precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Fire fightingequipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
500414 ETHYL MALTOL (VELTOL PLUS)SAFETY DATA SHEET
Version # 03Revision Date: 11-25-2015
Print Date: 11-25-2015Page 3 of 9
Specific methods Use water spray to cool unopened containers.General fire hazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.
6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures
Keep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Methods and materials forcontainment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Sweep upand place in a clearly labeled container for chemical waste. Wash contaminated area with water.Use only non-sparking tools. Avoid the generation of dusts during clean-up.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
7. HANDLING AND STORAGEPrecautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Take precautionary
measures against static discharges when there is a risk of dust explosion. Avoid breathing dust.Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Wash thoroughly afterhandling.
Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensurethat dusts do not accumulate on surfaces. Dry powders can build static electricity charges whensubjected to the friction of transfer and mixing operations. Provide adequate precautions, such aselectrical grounding and bonding, or inert atmospheres. Assume that this material is capable ofproducing a dust explosion if ignited as a dust cloud.
Conditions for safe storage,including any incompatibilities
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits No exposure limits noted for ingredient(s).Biological limit values No biological exposure limits noted for the ingredient(s).Appropriate engineering controls Use only appropriately classified electrical equipment and powered industrial trucks. Use
explosion-proof ventilation equipment to stay below exposure limits. It is recommended that alldust control equipment such as local exhaust ventilation and material transport systems involvedin handling of this product contain explosion relief vents or an explosion suppression system or anoxygen-deficient environment. Ensure that dust-handling systems (such as exhaust ducts, dustcollectors, vessels, and processing equipment) are designed in a manner to prevent the escape ofdust into the work area (i.e., there is no leakage from the equipment).
Individual protection measures, such as personal protective equipmentEye/face protection Wear safety glasses with side shields (or goggles).
Skin protectionHand protection Chemical resistant gloves.
500414 ETHYL MALTOL (VELTOL PLUS)SAFETY DATA SHEET
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Print Date: 11-25-2015Page 4 of 9
Other Not available.Respiratory protection Dust mask.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations When using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. Routinelywash work clothing and protective equipment to remove contaminants.
9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Refer to Spec Sheet
Physical state Powder\Crystal.Form Powder. Crystalline powder.Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 194 °F (90 °C)
Initial boiling point and boilingrange
554 °F (290 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0 mm Hg at 25 °C
Vapor density 4.9
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationFlammability class Combustible IIIB estimated
500414 ETHYL MALTOL (VELTOL PLUS)SAFETY DATA SHEET
Version # 03Revision Date: 11-25-2015
Print Date: 11-25-2015Page 5 of 9
Molecular formula C7H8O3
Molecular weight 140.14 g/mol
10. STABILITY AND REACTIVITYReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Chemical stability Material is stable under normal conditions.Possibility of hazardousreactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Keep away from heat, sparks and open flame. Avoid temperatures exceeding the flash point.Minimize dust generation and accumulation. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products if stored and handled as indicated.
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation Irritating to respiratory system.
Skin contact Dust or powder may irritate the skin.
Eye contact Dust may irritate the eyes.
Ingestion Harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Dusts may irritate the respiratory tract, skin and eyes.
Information on toxicological effects
Acute toxicity Harmful if swallowed.
Test ResultsProduct SpeciesETHYL MALTOL (CAS 4940-11-8)
LD50 RabbitDermalAcute
> 5000 mg/kg
LD50 RatOral
1150 mg/kg
* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.Serious eye damage/eyeirritation
Direct contact with eyes may cause temporary irritation.
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
500414 ETHYL MALTOL (VELTOL PLUS)SAFETY DATA SHEET
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Print Date: 11-25-2015Page 6 of 9
Carcinogenicity
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONEcotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.Persistence and degradability No data is available on the degradability of this product.Bioaccumulative potential No data available.Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDisposal instructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.Hazardous waste code Not established.Waste from residues / unusedproducts
Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
Not regulated as dangerous goods.BULK
500414 ETHYL MALTOL (VELTOL PLUS)SAFETY DATA SHEET
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Print Date: 11-25-2015Page 7 of 9
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
SARA 304 Emergency release notificationNot regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes
Delayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substanceNot listed.
SARA 311/312 Hazardouschemical
Yes
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Safe Drinking Water Act(SDWA)
Not regulated.
500414 ETHYL MALTOL (VELTOL PLUS)SAFETY DATA SHEET
Version # 03Revision Date: 11-25-2015
Print Date: 11-25-2015Page 8 of 9
US state regulationsUS. Massachusetts RTK - Substance List
Not regulated.US. New Jersey Worker and Community Right-to-Know Act
Not listed.US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISIONIssue date 11-24-2015Revision date 11-25-2015Version # 03Further information Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the
Manufacturing, Processing, and Handling of Combustible Particulate Solids, for safe handling.HMIS® ratings Health: 1
Flammability: 1Physical hazard: 0
500414 ETHYL MALTOL (VELTOL PLUS)SAFETY DATA SHEET
Version # 03Revision Date: 11-25-2015
Print Date: 11-25-2015Page 9 of 9
Disclaimer Vigon cannot anticipate all conditions under which this information and its product, or the productsof other manufacturers in combination with its product, may be used. It is the user’s responsibilityto ensure safe conditions for handling, storage and disposal of the product, and to assume liabilityfor loss, injury, damage or expense due to improper use. The information in the sheet was writtenbased on the best knowledge and experience currently available. The above information relatesonly to this product and not to its use in combination with any other material or any particularprocess and is designed only as guidance for the safe handling, use, processing, storage,transportation, disposal, and should not be considered as a guarantee or quality specification. Theabove information is based on data provided by and collected from recognized sources such asdistributors, manufacturers, and technical groups and is considered to be accurate to the best ofVigon’s knowledge as of the date of this document. It is the responsibility of the user to review allsafety information about this product and determine its safety and suitability in their own processesand operations. Appropriate warnings and safe handling procedures should be provided to allhandlers and users, taking into account the intended use and the specific conditions and factorsrelating to such use in accordance with all applicable laws and regulations.
Revision Information Product and Company Identification: Alternate Trade NamesPhysical & Chemical Properties: Multiple PropertiesToxicological Information: Toxicological Data
507731 GUAIACOL NATURALSAFETY DATA SHEET
Version # 01Revision Date: 02-15-2017
Print Date: 02-15-2017Page 1 of 10
1. IDENTIFICATIONGUAIACOL NATURALProduct Description:90-05-1CAS #
FEMA Number 2532
Other means of identification507731Vigon Item #Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended use
For Manufacturing Use OnlyRecommended restrictions
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
Manufacturer/Importer/Supplier/Distributor informationManufacturer
Vigon International, Inc.Address 127 Airport RoadCompany name
WebsiteTelephone For information call: 570-476-6300
Emergency phone number INFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
United States
www.vigon.comNot available.
E. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONCategory 4Flammable liquidsPhysical hazardsCategory 4Acute toxicity, oralHealth hazardsCategory 5Acute toxicity, dermalCategory 2Skin corrosion/irritationCategory 2ASerious eye damage/eye irritationCategory 3Hazardous to the aquatic environment,
acute hazardEnvironmental hazards
Category 3Hazardous to the aquatic environment,long-term hazard
507731 GUAIACOL NATURALSAFETY DATA SHEET
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Print Date: 02-15-2017Page 2 of 10
Label elements
Signal word Danger
Hazard statement Combustible liquid. Harmful if swallowed. May be harmful in contact with skin. Causes skinirritation. Causes serious eye damage. May cause drowsiness or dizziness. Harmful to aquatic lifewith long lasting effects.
Precautionary statementPrevention Keep away from heat/sparks/open flames/hot surfaces. No smoking. Avoid breathing mist or
vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Useonly outdoors or in a well-ventilated area. Avoid release to the environment. Wear protectivegloves/eye protection/face protection.
Response IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. IF ON SKIN:Wash with plenty of water. IF INHALED: Remove person to fresh air and keep comfortable forbreathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. Specifictreatment (see this label). If skin irritation occurs: Get medical advice/attention. Take offcontaminated clothing and wash it before reuse. In case of fire: Use appropriate media toextinguish.
Storage Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place.Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS numberCommon name and synonymsChemical name %2- methoxyphenol1- hydroxy- 2- methoxybenzeneortho- methoxyphenolpyrocatechol methyl esterortho- hydroxyanisole
90-05-1GUAIACOL 100
4. FIRST-AID MEASURESIf breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Inhalation
Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Skin contact
Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Eye contact
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Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Ingestion
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eyedamage including blindness could result. Skin irritation. May cause redness and pain.
Most importantsymptoms/effects, acute anddelayed
Not available.Indication of immediate medicalattention and special treatmentneeded
Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. FIRE-FIGHTING MEASURESWater spray, fog, CO2, dry chemical, or alcohol resistant foam.Suitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing mediaFire may produce irritating, corrosive and/or toxic gases.Specific hazards arising from
the chemicalFirefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Special protective equipmentand precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Fire fightingequipment/instructions
Use water spray to cool unopened containers.Specific methodsStatic charges generated by emptying package in or near flammable vapor may cause flash fire.General fire hazards
6. ACCIDENTAL RELEASE MEASURESKeep unnecessary personnel away. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them. Eliminateall sources of ignition. Avoid contact with skin or inhalation of spillage, dust or vapor.
Personal precautions, protectiveequipment and emergencyprocedures
507731 GUAIACOL NATURALSAFETY DATA SHEET
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Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Donot allow material to contaminate ground water system. Absorb in vermiculite, dry sand or earthand place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Methods and materials forcontainment and cleaning up
Prevent further leakage or spillage if safe to do so. Do not contaminate water. Retain and disposeof contaminated wash water. Avoid release to the environment. Contact local authorities in case ofspillage to drain/aquatic environment.
Environmental precautions
7. HANDLING AND STORAGEDo not handle or store near an open flame, heat or other sources of ignition. Take precautionarymeasures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Precautions for safe handling
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
Conditions for safe storage,including any incompatibilities
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONThis substance has no PEL, TLV, or other recommended exposure limit.Occupational exposure limitsNo biological exposure limits noted for the ingredient(s).Biological limit valuesUse explosion-proof ventilation equipment to stay below exposure limits.Appropriate engineering controls
Individual protection measures, such as personal protective equipmentWear safety glasses with side shields (or goggles). Face shield is recommended.Eye/face protection
Skin protectionChemical resistant gloves.Hand protection
Use of an impervious apron is recommended.Other
Respiratory protection not required. If ventilation is insufficient, suitable respiratory protection mustbe provided.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using do not smoke. Keep away from food and drink. Always observe good personalhygiene measures, such as washing after handling the material and before eating, drinking, and/orsmoking. Routinely wash work clothing and protective equipment to remove contaminants.
General hygiene considerations
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9. PHYSICAL AND CHEMICAL PROPERTIESRefer to Spec SheetAppearanceLiquid.Physical stateLiquid.FormRefer to Spec SheetColorCharacteristic.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point 89.6 °F (32 °C)
Initial boiling point and boilingrange
399.2 - 402.8 °F (204 - 206 °C)
Flash point 179.0 °F (81.7 °C) Closed Cup
Evaporation rate Not available.Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 100 mm Hg at 144°C
Vapor density 4.3
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
1.32
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 1.13 g/cm3 estimated at 21 °C
Flammability class Combustible IIIA estimated
Molecular formula C7-H8-O2
Molecular weight 124.13 g/mol
Specific gravity 1.13 at 25 °C
10. STABILITY AND REACTIVITYThe product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
507731 GUAIACOL NATURALSAFETY DATA SHEET
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Material is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous
reactionsAvoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding theflash point. Contact with incompatible materials.
Conditions to avoid
Alkaline metals.Incompatible materialsNo hazardous decomposition products if stored and handled as indicated.Hazardous decomposition
products
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting.
Skin contact May be harmful in contact with skin. Causes skin irritation.
Eye contact Causes serious eye damage.
Ingestion Harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eyedamage including blindness could result. Skin irritation. May cause redness and pain.
Information on toxicological effects
Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness andcentral nervous system effects. Harmful if swallowed. May be harmful in contact with skin.Narcotic effects.
Test ResultsProduct SpeciesGUAIACOL (CAS 90-05-1)
LD50 RabbitDermalAcute
4600 mg/kg
LD50 MouseInhalation
7570 mg/m3
LD50 RatOral
520 mg/kg Remarks: Behavioral:Generalanesthetic.
* Estimates for product may be based on additional component data not shown.Causes skin irritation.Skin - rabbitResult: Severe skin irritation - 24 h(Draize Test)
Skin corrosion/irritation
Causes serious eye damage.Eyes - rabbitResult: Mild eye irritation - 24 h(Draize Test)
Serious eye damage/eyeirritation
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Respiratory or skin sensitizationRespiratory sensitization Not available.
This product is not expected to cause skin sensitization.Skin sensitizationResult: Equivocal evidence.Histidine reversion (Ames)HumanlymphocyteSister chromatid exchange
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
US. National Toxicology Program (NTP) Report on CarcinogensNot listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -single exposure
May cause drowsiness and dizziness.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not available.
12. ECOLOGICAL INFORMATIONHarmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected.Ecotoxicity
Product Test ResultsSpecies
* Estimates for product may be based on additional component data not shown.
GUAIACOL (CAS 90-05-1)Aquatic
EC50Crustacea 25.9 mg/l, 48 hoursWater flea (Daphnia magna)
No data is available on the degradability of this product.Persistence and degradabilityNot available.Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)1.32
No data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
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13. DISPOSAL CONSIDERATIONSDo not discharge into drains, water courses or onto the ground. Do not allow this material to draininto sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulationsNot established.Hazardous waste codeEmpty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Waste from residues / unusedproducts
Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
Contaminated packaging
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
NA1993UN numberBULK
COMBUSTIBLE LIQUID, N.O.S. (GUAIACOL)Proper shipping nameCombustible liqHazard classIIIPacking group
NoMarine pollutantEnvironmental hazards
150Packaging exceptions242Packaging bulk3Labels required
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.
US federal regulations
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CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
SARA 304 Emergency release notificationNot regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substanceNot listed.
YesSARA 311/312 Hazardouschemical
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Not regulated.Safe Drinking Water Act
(SDWA)
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand Inventory
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Country(s) or region Inventory name On inventory (yes/no)*YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION02-15-2017Issue date02-15-2017Revision date
Version # 01Health: 3*Flammability: 2Physical hazard: 0
HMIS® ratings
The information in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
Disclaimer
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1. IDENTIFICATIONHELIOTROPINE NATURALProduct Description:120-57-0CAS #
FEMA Number 2911
Other means of identification500670Vigon Item #Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended use
For Manufacturing Use OnlyRecommended restrictions
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
Manufacturer/Importer/Supplier/Distributor informationManufacturer
Vigon International, Inc.Address 127 Airport RoadCompany name
WebsiteTelephone For information call: 570-476-6300
Emergency phone number INFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
United States
www.vigon.comNot available.
E. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 5Acute toxicity, oralHealth hazardsCategory 2Skin corrosion/irritationCategory 1Sensitization, skinCategory 3Hazardous to the aquatic environment,
acute hazardEnvironmental hazards
Category 3Hazardous to the aquatic environment,long-term hazard
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Label elements
Signal word Warning
Hazard statement May be harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction. Harmfulto aquatic life with long lasting effects.
Precautionary statementPrevention Avoid breathing dust. Wash thoroughly after handling. Contaminated work clothing should not be
allowed out of the workplace. Avoid release to the environment. Wear protective gloves.
Response IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell. If skinirritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash itbefore reuse.
Storage Store away from incompatible materials.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC)
WARNING! May form combustible dust concentrations in air. Avoid breathing dust. Afterprolonged contact with highly porous materials, this product may spontaneously combust.
Supplemental information 100% of the mixture consists of component(s) of unknown acute inhalation toxicity.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS numberCommon name and synonymsChemical name %piperonaldehyde5- FORMYL- 1, 3- BENZODIOXOLEPIPERONAL3, 4 dimethylene dioxybenzaldehyde1, 3- BENZODIOXOL- 5- CARBOXALDEHYDE
120-57-0PIPERONYL ALDEHYDE 100
4. FIRST-AID MEASURESIf breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Inhalation
Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Skin contact
Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Eye contact
Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Ingestion
Dusts may irritate the respiratory tract, skin and eyes. Skin irritation. May cause redness and pain.May cause an allergic skin reaction. Dermatitis. Rash.
Most importantsymptoms/effects, acute anddelayed
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Not available.Indication of immediate medicalattention and special treatmentneeded
Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. FIRE-FIGHTING MEASURESWater spray, fog, CO2, dry chemical, or alcohol resistant foam.Suitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing mediaExplosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, andin the presence of an ignition source is a potential dust explosion hazard. Fire may produceirritating, corrosive and/or toxic gases.
Porous material such as rags, paper, insulation, or organic clay may spontaneously combust whenwetted with this material.
Specific hazards arising fromthe chemical
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Special protective equipmentand precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Fire fightingequipment/instructions
Use water spray to cool unopened containers.Specific methodsStatic charges generated by emptying package in or near flammable vapor may cause flash fire.General fire hazards
6. ACCIDENTAL RELEASE MEASURESKeep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Personal precautions, protectiveequipment and emergencyprocedures
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Sweep upand place in a clearly labeled container for chemical waste. Wash contaminated area with water.Use only non-sparking tools. Avoid the generation of dusts during clean-up. This material and itscontainer must be disposed of as hazardous waste. Collect and dispose of spillage as indicated insection 13 of the SDS.
Never return spills in original containers for re-use.
Methods and materials forcontainment and cleaning up
Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
Environmental precautions
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7. HANDLING AND STORAGETake precautionary measures against static discharges when there is a risk of dust explosion.Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensurethat dusts do not accumulate on surfaces. Dry powders can build static electricity charges whensubjected to the friction of transfer and mixing operations. Provide adequate precautions, such aselectrical grounding and bonding, or inert atmospheres. Assume that this material is capable ofproducing a dust explosion if ignited as a dust cloud.Do not handle or store near an open flame, heat or other sources of ignition. Porous material suchas rags, paper, insulation, or organic clay may spontaneously combust when wetted with thismaterial. May auto-oxidize with sufficient heat generation to ignite if spread (as a thin film) orabsorbed on porous or fibrous material. Take precautionary measures against static discharges.Contaminated rags and cloths must be put in fireproof containers for disposal. Avoid breathingvapor. Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Precautions for safe handling
Do not store in direct sunlight. Keep container closed. Handle containers with care. Open slowly inorder to control possible pressure release. Store in a cool, well-ventilated area. Keep under anitrogen blanket.
Conditions for safe storage,including any incompatibilities
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONThis substance has no PEL, TLV, or other recommended exposure limit.Occupational exposure limitsNo biological exposure limits noted for the ingredient(s).Biological limit values
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Dust, inhalable:Austria: limit value - 8 hours = 10 mg/m³Austria: limit value - short term = 20 mg/m³Belgium: limit value - 8 hours = 10 mg/m³Denmark: limit value - 8 hours = 10 mg/m³Denmark: limit value - short term = 20 mg/m³France: limit value - 8 hours = 10 mg/m³ (restrictive statutory limit value)Germany (AGS): limit value - 8 hours = 10 mg/m³Germany (AGS): limit value - short term = 20 mg/m³Germany (DFG): limit value - 8 hours = 4 mg/m³Hungary: limit value - 8 hours = 10 mg/m³Spain: limit value - 8 hours = 10 mg/m³Sweden: limit value - 8 hours = 10 mg/m³Switzerland: limit value - 8 hours = 10 mg/m³Dust, respirable:Austria: limit value - 8 hours = 5 mg/m³Austria: limit value - short term = 10 mg/m³Belgium: limit value - 8 hours = 3 mg/m³France: limit value - 8 hours = 5 mg/m³ (restrictive statutory limit value)Germany (AGS): limit value - 8 hours = 3 mg/m³Germany (AGS): limit value - short term = 6 mg/m³Germany (DFG): limit value - 8 hours = 1.5 mg/m³Hungary: limit value - 8 hours = 6 mg/m³Spain: limit value - 8 hours = 3 mg/m³Sweden: limit value - 8 hours = 5 mg/m³Switzerland: limit value - 8 hours = 3 mg/m³· Additional information: This sheet is based on the current valid lists.
Exposure guidelines
Use only appropriately classified electrical equipment and powered industrial trucks. It isrecommended that all dust control equipment such as local exhaust ventilation and materialtransport systems involved in handling of this product contain explosion relief vents or anexplosion suppression system or an oxygen-deficient environment. Ensure that dust-handlingsystems (such as exhaust ducts, dust collectors, vessels, and processing equipment) aredesigned in a manner to prevent the escape of dust into the work area (i.e., there is no leakagefrom the equipment). Use explosion-proof ventilation equipment to stay below exposure limits.
Appropriate engineering controls
Individual protection measures, such as personal protective equipmentChemical goggles are recommended.Eye/face protection
Skin protectionChemical resistant gloves.Hand protection
Use of an impervious apron is recommended.Other
Dust mask.Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. Routinelywash work clothing and protective equipment to remove contaminants. Contaminated workclothing should not be allowed out of the workplace.
General hygiene considerations
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9. PHYSICAL AND CHEMICAL PROPERTIESRefer to Spec SheetAppearancePowder\Crystal.Physical statePowder. Crystalline powder.FormRefer to Spec SheetColorCharacteristic.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point 98.6 °F (37 °C)
Initial boiling point and boilingrange
505.4 °F (263 °C) 101.325 kPa
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.01 mm Hg at 25 °C
Vapor density 5.2
Relative density 1.337 ± 0.06 at 20 °C
Solubility(ies)Solubility (water) 0 Insoluble
Partition coefficient(n-octanol/water)
1.05 log Kow
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationNot explosive.Explosive properties
Flammability class Combustible IIIB estimated
Molecular formula C8-H6-O3
Molecular weight 150.13 g/molNot oxidizing.Oxidizing properties
10. STABILITY AND REACTIVITYThe product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
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Material is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous
reactionsPorous material such as rags, paper, insulation, or organic clay may spontaneously combust whenwetted with this material.
Conditions to avoid
Strong oxidizing agents.Incompatible materialsNo hazardous decomposition products if stored and handled as indicated.Hazardous decomposition
products
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation Irritating to respiratory system.
Skin contact Causes skin irritation. May cause an allergic skin reaction.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion May be harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Dusts may irritate the respiratory tract, skin and eyes. Skin irritation. May cause redness and pain.May cause an allergic skin reaction. Dermatitis. Rash.
Information on toxicological effects
Acute toxicity May be harmful if swallowed.
Test ResultsProduct SpeciesPIPERONYL ALDEHYDE (CAS 120-57-0)
LD50 RabbitDermalAcute
> 5000 mg/kg
LD50 RatOral
2700 mg/kg
* Estimates for product may be based on additional component data not shown.Causes skin irritation.May cause irritation by prolonged skin contact.guinea pig - Skin irritation - 48 h
Skin corrosion/irritation
Direct contact with eyes may cause temporary irritation.Fine particles and powder may cause eye irritation by mechanical effect.rabbit - Mild eye irritation - 48 h
Serious eye damage/eyeirritation
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
May cause an allergic skin reaction.Skin sensitizationGenotoxicity in vitro - Human - lymphocyteSister chromatid exchangeGenotoxicity in vitro - Chicken - EmbryoSister chromatid exchange
Germ cell mutagenicity
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Carcinogenicity
IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
US. National Toxicology Program (NTP) Report on CarcinogensNot listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONHarmful to aquatic life with long lasting effects.Ecotoxicity
No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)1.05, log Kow
No data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDo not discharge into drains, water courses or onto the ground. Do not allow this material to draininto sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulationsNot established.Hazardous waste codeEmpty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Waste from residues / unusedproducts
Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.
Contaminated packaging
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.
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ADRNot regulated as dangerous goods.
RIDNot regulated as dangerous goods.
DOT
Not regulated as dangerous goods.BULK
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.
US federal regulations
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
SARA 304 Emergency release notificationNot regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substanceNot listed.
YesSARA 311/312 Hazardouschemical
SARA 313 (TRI reporting)Not regulated.
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Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Not regulated.Safe Drinking Water Act
(SDWA)
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))PIPERONYL ALDEHYDE (CAS 120-57-0) 20 %WV
DEA Exempt Chemical Mixtures Code NumberPIPERONYL ALDEHYDE (CAS 120-57-0) 8750
Controlled substanceFood and DrugAdministration (FDA)
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION04-26-2017Issue date04-26-2017Revision date
Version # 03Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from theManufacturing, Processing, and Handling of Combustible Particulate Solids, for safe handling.
Further information
Health: 2Flammability: 1Physical hazard: 0
HMIS® ratings
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Vigon International, Inc. cannot anticipate all conditions under which this information and itsproduct, or the products of other manufacturers in combination with its product, may be used. It isthe user’s responsibility to ensure safe conditions for handling, storage and disposal of theproduct, and to assume liability for loss, injury, damage or expense due to improper use. Theinformation in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
Disclaimer
This document has undergone significant changes and should be reviewed in its entirety.Revision information
501218 CAPROIC ACID NATURAL (HEXANOIC ACID)SAFETY DATA SHEET
Version # 06Revision Date: 11-03-2016
Print Date: 11-03-2016Page 1 of 11
1. IDENTIFICATIONCAPROIC ACID NATURAL (HEXANOIC ACID)Product Description:142-62-1CAS #
FEMA Number 2559
Other means of identification501218Vigon Item #Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended use
For Manufacturing Use OnlyRecommended restrictions
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
Manufacturer/Importer/Supplier/Distributor informationManufacturer
Vigon International, Inc.Address 127 Airport RoadCompany name
WebsiteTelephone For information call: 570-476-6300
Emergency phone number INFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
United States
www.vigon.comNot available.
E. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 4Acute toxicity, oralHealth hazardsCategory 3Acute toxicity, dermalCategory 1BSkin corrosion/irritationCategory 1Serious eye damage/eye irritationCategory 3Hazardous to the aquatic environment,
acute hazardEnvironmental hazards
Category 3Hazardous to the aquatic environment,long-term hazard
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Label elements
Signal word Danger
Hazard statement Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage.Causes serious eye damage. Harmful to aquatic life with long lasting effects.
Precautionary statementPrevention Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when
using this product. Avoid release to the environment. Wear protective gloves/protectiveclothing/eye protection/face protection.
Response IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take offimmediately all contaminated clothing. Rinse skin with water. IF INHALED: Remove person tofresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call aPOISON CENTER/doctor. Take off immediately all contaminated clothing and wash it beforereuse.
Storage Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS numberCommon name and synonymsChemical name %pentyl formic acidcapronic acidbutyl acetic acid1- pentane carboxylic acid
142-62-1Hexanoic acid 100
4. FIRST-AID MEASURESIf breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Inhalation
Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Skin contact
Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Eye contact
Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Ingestion
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Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage includingblindness could result.
Most importantsymptoms/effects, acute anddelayed
Not available.Indication of immediate medicalattention and special treatmentneeded
Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. FIRE-FIGHTING MEASURESWater spray, fog, CO2, dry chemical, or alcohol resistant foam.Suitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing mediaFire may produce irritating, corrosive and/or toxic gases.Specific hazards arising from
the chemicalFirefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Special protective equipmentand precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Fire fightingequipment/instructions
Use water spray to cool unopened containers.Specific methodsStatic charges generated by emptying package in or near flammable vapor may cause flash fire.General fire hazards
6. ACCIDENTAL RELEASE MEASURESKeep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Personal precautions, protectiveequipment and emergencyprocedures
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains.Absorb in vermiculite, dry sand or earth and place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Methods and materials forcontainment and cleaning up
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Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
Environmental precautions
7. HANDLING AND STORAGEDo not handle or store near an open flame, heat or other sources of ignition. Take precautionarymeasures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Precautions for safe handling
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
Conditions for safe storage,including any incompatibilities
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONThis substance has no PEL, TLV, or other recommended exposure limit.Occupational exposure limitsNo biological exposure limits noted for the ingredient(s).Biological limit valuesUse explosion-proof ventilation equipment to stay below exposure limits.Appropriate engineering controls
Individual protection measures, such as personal protective equipmentWear safety glasses with side shields (or goggles). Face shield is recommended.Eye/face protection
Skin protectionChemical resistant gloves.Hand protection
Use of an impervious apron is recommended.Other
Respiratory protection not required. If ventilation is insufficient, suitable respiratory protection mustbe provided.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Keep away from food and drink. Always observe good personal hygiene measures, such aswashing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants.
General hygiene considerations
9. PHYSICAL AND CHEMICAL PROPERTIESRefer to Spec SheetAppearanceLiquid.Physical stateLiquid.FormRefer to Spec SheetColorCharacteristic.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point 25.88 °F (-3.4 °C)
Initial boiling point and boilingrange
402.44 °F (205.8 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Not applicable.Flammability (solid, gas)
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Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.16 mm Hg at 25 °C
Vapor density 4
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
1.88
Auto-ignition temperature 716 °F (380 °C)
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 0.93 g/cm3 estimated at 20 °C
Dynamic viscosity 3.23 mPa.s (68 °F (20 °C))Not explosive.Explosive properties
Flammability class Combustible IIIB estimated
Kinematic viscosity 3.477 mm²/s estimated
Molecular formula C6-H12-O2
Molecular weight 116.16 g/molNot oxidizing.Oxidizing properties
Specific gravity 0.93 at 25 °C
Surface tension 23.4 mN/m (158 °F (70 °C))
10. STABILITY AND REACTIVITYThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityMaterial is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous
reactionsAvoid temperatures exceeding the flash point. Contact with incompatible materials.Conditions to avoidStrong oxidizing agents.Incompatible materialsNo hazardous decomposition products if stored and handled as indicated.Hazardous decomposition
products
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11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact Toxic in contact with skin. Causes severe skin burns.
Eye contact Causes serious eye damage.
Ingestion Causes digestive tract burns. Harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage includingblindness could result.
Information on toxicological effects
Acute toxicity Toxic in contact with skin. Harmful if swallowed.
Test ResultsProduct SpeciesHexanoic acid (CAS 142-62-1)
LD50 RabbitDermalAcute
630 µL/kg
LD50 RatOral
1990 mg/kg
* Estimates for product may be based on additional component data not shown.Causes severe skin burns and eye damage.Skin corrosion/irritationCauses serious eye damage.Serious eye damage/eye
irritation
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitizationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
US. National Toxicology Program (NTP) Report on CarcinogensNot listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -single exposure
Not classified.
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Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONHarmful to aquatic life with long lasting effects.Ecotoxicity
Product Test ResultsSpecies
* Estimates for product may be based on additional component data not shown.
Hexanoic acid (CAS 142-62-1)Aquatic
LC50Fish 88 mg/l, 96 hoursFathead minnow (Pimephales promelas)
No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)1.88
No data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDo not discharge into drains, water courses or onto the ground. Do not allow this material to draininto sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulationsNot established.Hazardous waste codeEmpty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Waste from residues / unusedproducts
Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.
Contaminated packaging
14. TRANSPORT INFORMATIONADN
2922UN numberCORROSIVE LIQUIDS, TOXIC, N.O.S. (CAPROIC ACID)UN proper shipping name8Transport hazard class(es)6.1(PGIII)Subsidiary class(es)IIIPacking groupNoEnvironmental hazards8,6.1Labels required
ADR2922UN number
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CORROSIVE LIQUIDS, TOXIC, N.O.S. (CAPROIC ACID)UN proper shipping name8Transport hazard class(es)6.1(PGIII)Subsidiary class(es)IIIPacking groupNoEnvironmental hazards8,6.1
Labels required
RID2922UN numberCORROSIVE LIQUIDS, TOXIC, N.O.S. (CAPROIC ACID)UN proper shipping name8Transport hazard class(es)6.1(PGIII)Subsidiary class(es)IIIPacking GroupNoEnvironmental Hazards8, 6.1Labels requiredRead safety instructions, SDS and emergency procedures before handling.Special precautions for user
DOT
2922UN numberBULK
CORROSIVE LIQUIDS,TOXIC, N.O.S. (CAPROIC ACID)
Proper shipping name
8Hazard class6.1(PGIII)Subsidiary hazard classIIIPacking group
NoMarine pollutantEnvironmental hazards
154Packaging exceptions241Packaging bulk8, 6.1Labels required
DOT
2922UN numberNON-BULK
CORROSIVE LIQUIDS,TOXIC, N.O.S. (CAPROIC ACID)
Proper shipping name
8Hazard class6.1(PGIII)Subsidiary hazard classIIIPacking group
NoMarine pollutantEnvironmental hazards
154Packaging exceptions203Packaging non bulk8, 6.1Labels required
IATA2922UN number
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CORROSIVE LIQUIDS,TOXIC, N.O.S. (CAPROIC ACID)
UN proper shipping name
8Transport hazard class(es)6.1(PGIII)Subsidiary class(es)IIIPacking groupNoEnvironmental hazards8, 6.1Labels required
IMDG2922UN numberCORROSIVE LIQUIDS,TOXIC, N.O.S. (CAPROIC ACID)
UN proper shipping name
8Transport hazard class(es)6.1(PGIII)Subsidiary class(es)IIIPacking group
NoMarine pollutantEnvironmental hazards
8, 6.1Labels requiredNot applicable.Transport in bulk according
to Annex II of MARPOL73/78 and the IBC Code
ADN; ADR; DOT BULK; DOT NON-BULK; IATA; IMDG; RID
15. REGULATORY INFORMATIONThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.
US federal regulations
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
SARA 304 Emergency release notificationNot regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
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Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substanceNot listed.
YesSARA 311/312 Hazardouschemical
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Not regulated.Safe Drinking Water Act
(SDWA)
US state regulationsUS. Massachusetts RTK - Substance List
Hexanoic acid (CAS 142-62-1)US. New Jersey Worker and Community Right-to-Know Act
Hexanoic acid (CAS 142-62-1)US. Pennsylvania Worker and Community Right-to-Know Law
Hexanoic acid (CAS 142-62-1)
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
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Country(s) or region Inventory name On inventory (yes/no)*YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION07-02-2013Issue date11-03-2016Revision date
Version # 06Health: 3Flammability: 1Physical hazard: 0
HMIS® ratings
Vigon International, Inc. cannot anticipate all conditions under which this information and itsproduct, or the products of other manufacturers in combination with its product, may be used. It isthe user’s responsibility to ensure safe conditions for handling, storage and disposal of theproduct, and to assume liability for loss, injury, damage or expense due to improper use. Theinformation in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
Disclaimer
This document has undergone significant changes and should be reviewed in its entirety.Revision information
500191 ISOVALERIC ACIDSAFETY DATA SHEET
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1. IDENTIFICATIONProduct Description: ISOVALERIC ACIDCAS # 503-74-2
FEMA Number 3102
Other means of identificationVigon Item # 500191
Recommended use Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended restrictions For Manufacturing Use Only
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONCategory 4Flammable liquidsPhysical hazardsCategory 4Acute toxicity, oralHealth hazardsCategory 3Acute toxicity, dermalCategory 1BSkin corrosion/irritationCategory 1Serious eye damage/eye irritationCategory 3 respiratory tract irritationSpecific target organ toxicity, single
exposureNot classified.Environmental hazards
Label elements
Signal word Danger
Hazard statementH227 Combustible liquid.H302 Harmful if swallowed.H311 Toxic in contact with skin.H314 Causes severe skin burns and eye damage.H318 Causes serious eye damage.H335 May cause respiratory irritation.
Precautionary statementPrevention
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
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P260 Do not breathe mist or vapor.P264 Wash thoroughly after handling.P270 Do not eat, drink or smoke when using this product.P271 Use only outdoors or in a well-ventilated area.P280 Wear protective gloves/protective clothing/eye protection/face protection.
ResponseP301 + P330 +P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.P303 + P361 +P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P305 + P351 +P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.P310 Immediately call a POISON CENTER/doctor.P361 + P364 Take off immediately all contaminated clothing and wash it before reuse.P370 + P378 In case of fire: Use appropriate media to extinguish.
StorageP403 + P233 Store in a well-ventilated place. Keep container tightly closed.P403 + P235 Store in a well-ventilated place. Keep cool.P405 Store locked up.
DisposalP501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS number %Chemical name Common name and synonymsdelphinic acidIsopentanoic acidBETA-METHYLBUTYRIC ACID3-METHYLBUTANOIC ACID
503-74-2ISOVALERIC ACID 100
4. FIRST-AID MEASURESInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Skin contact Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Eye contact Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
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Ingestion Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Most importantsymptoms/effects, acute anddelayed
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage includingblindness could result. May cause respiratory irritation.
Indication of immediate medicalattention and special treatmentneeded
Not available.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
5. FIRE-FIGHTING MEASURESSuitable extinguishing media Water spray, fog, CO2, dry chemical, or alcohol resistant foam.Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Specific hazards arising fromthe chemical
Fire may produce irritating, corrosive and/or toxic gases.
Special protective equipmentand precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Fire fightingequipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Specific methods Use water spray to cool unopened containers.General fire hazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.
6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures
Keep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
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Methods and materials forcontainment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Donot allow material to contaminate ground water system. Absorb in vermiculite, dry sand or earthand place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
7. HANDLING AND STORAGEPrecautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Take precautionary
measures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Conditions for safe storage,including any incompatibilities
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits No exposure limits noted for ingredient(s).Biological limit values No biological exposure limits noted for the ingredient(s).Appropriate engineering controls Use explosion-proof ventilation equipment to stay below exposure limits.
Individual protection measures, such as personal protective equipmentEye/face protection Face shield is recommended. Wear safety glasses with side shields (or goggles).
Skin protectionHand protection Chemical resistant gloves.
Other Use of an impervious apron is recommended.
Respiratory protection Respiratory protection not required. If ventilation is insufficient, suitable respiratory protection mustbe provided.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations When using do not smoke. Keep away from food and drink. Always observe good personalhygiene measures, such as washing after handling the material and before eating, drinking, and/orsmoking. Routinely wash work clothing and protective equipment to remove contaminants.
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9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Refer to Spec Sheet
Physical state Liquid.Form Liquid.Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point -20.74 °F (-29.3 °C)
Initial boiling point and boilingrange
349.7 °F (176.5 °C) 101.325 kPa
Flash point 158.0 °F (70.0 °C) Closed Cup
Evaporation rate Not available.Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.38 mm Hg at 20 °C
Vapor density 3.5
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
1.2
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 0.93 g/cm3 estimated
Flammability class Combustible IIIA estimated
Molecular formula C5-H10-O2
Molecular weight 102.13 g/mol
Specific gravity 0.93 at 25 °C
10. STABILITY AND REACTIVITYReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
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Chemical stability Material is stable under normal conditions.Possibility of hazardousreactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding theflash point. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products if stored and handled as indicated.
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact Toxic in contact with skin. Causes severe skin burns.
Eye contact Causes serious eye damage.
Ingestion Causes digestive tract burns. Harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage includingblindness could result. May cause respiratory irritation.
Information on toxicological effects
Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness andcentral nervous system effects. Toxic in contact with skin. Harmful if swallowed. May causerespiratory irritation.
Test ResultsProduct SpeciesISOVALERIC ACID (CAS 503-74-2)
LD50 RabbitDermalAcute
310 mg/kg
LD50 RatOral
2000 mg/kg
* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Causes severe skin burns and eye damage.Serious eye damage/eyeirritation
Causes serious eye damage.
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
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OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -single exposure
May cause respiratory irritation.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONEcotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.Persistence and degradability No data is available on the degradability of this product.Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)1.16
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDisposal instructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.Hazardous waste code Not established.Waste from residues / unusedproducts
Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
14. TRANSPORT INFORMATIONADN
3265UN numberCORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (ISOVALERIC ACID)UN proper shipping name8Transport hazard class(es)-Subsidiary class(es)IIIPacking groupNoEnvironmental hazards8Labels required
ADR3265UN number
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CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (ISOVALERIC ACID)UN proper shipping name8Transport hazard class(es)-Subsidiary class(es)IIIPacking groupNoEnvironmental hazards8Labels required
RID3265UN numberCORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (ISOVALERIC ACID)UN proper shipping name8Transport hazard class(es)-Subsidiary class(es)IIIPacking groupNoEnvironmental hazards8Labels required
DOT
3265UN numberBULK
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (ISOVALERIC ACID)Proper shipping name8Hazard classIIIPacking group
NoMarine pollutantEnvironmental hazards
154Packaging exceptions241Packaging bulk8Labels required
DOT
3265UN numberNON-BULK
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (ISOVALERIC ACID)Proper shipping name8Hazard classIIIPacking group
NoMarine pollutantEnvironmental hazards
154Packaging exceptions203Packaging non bulk8Labels required
IATA3265UN numberCORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (ISOVALERIC ACID)UN proper shipping name8Transport hazard class(es)-Subsidiary class(es)IIIPacking groupNoEnvironmental hazards8Labels required
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IMDG3265UN numberCORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (ISOVALERIC ACID)UN proper shipping name8Transport hazard class(es)-Subsidiary class(es)IIIPacking group
NoMarine pollutantEnvironmental hazards
8Labels requiredNot applicable.Transport in bulk according
to Annex II of MARPOL73/78 and the IBC Code
ADN; ADR; DOT BULK; DOT NON-BULK; IATA; IMDG; RID
15. REGULATORY INFORMATIONUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
SARA 304 Emergency release notificationNot regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes
Delayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substanceNot listed.
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SARA 311/312 Hazardouschemical
Yes
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Safe Drinking Water Act(SDWA)
Not regulated.
US state regulationsUS. Massachusetts RTK - Substance List
ISOVALERIC ACID (CAS 503-74-2)US. New Jersey Worker and Community Right-to-Know Act
ISOVALERIC ACID (CAS 503-74-2)US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
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16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISIONIssue date 01-01-2015Revision date 03-17-2015Version # 02HMIS® ratings Health: 3
Flammability: 2Physical hazard: 0
Disclaimer Vigon cannot anticipate all conditions under which this information and its product, or the productsof other manufacturers in combination with its product, may be used. It is the user’s responsibilityto ensure safe conditions for handling, storage and disposal of the product, and to assume liabilityfor loss, injury, damage or expense due to improper use. The information in the sheet was writtenbased on the best knowledge and experience currently available. The above information relatesonly to this product and not to its use in combination with any other material or any particularprocess and is designed only as guidance for the safe handling, use, processing, storage,transportation, disposal, and should not be considered as a guarantee or quality specification. Theabove information is based on data provided by and collected from recognized sources such asdistributors, manufacturers, and technical groups and is considered to be accurate to the best ofVigon’s knowledge as of the date of this document. It is the responsibility of the user to review allsafety information about this product and determine its safety and suitability in their own processesand operations. Appropriate warnings and safe handling procedures should be provided to allhandlers and users, taking into account the intended use and the specific conditions and factorsrelating to such use in accordance with all applicable laws and regulations.
Revision Information Product and Company Identification: Vigon ValuesACCIDENTAL RELEASE MEASURES: Methods and materials for containment and cleaning upPhysical & Chemical Properties: Multiple PropertiesOTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION: DisclaimerGHS: Classification
500413 MALTOL (VELTOL) FCCSAFETY DATA SHEET
Version # 02Revision Date: 11-24-2015
Print Date: 11-24-2015Page 1 of 9
1. IDENTIFICATIONProduct Description: MALTOL (VELTOL) FCCCAS # 118-71-8
FEMA Number 2656
Other means of identificationVigon Item # 500413
Recommended use Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended restrictions For Manufacturing Use Only
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 4Acute toxicity, oralHealth hazardsCategory 2Skin corrosion/irritationCategory 2ASerious eye damage/eye irritationCategory 3 respiratory tract irritationSpecific target organ toxicity, single
exposureNot classified.Environmental hazards
Label elements
Signal word Warning
Hazard statementH302 Harmful if swallowed.H315 Causes skin irritation.H315 + H320 Causes skin and eye irritation.H319 Causes serious eye irritation.H335 May cause respiratory irritation.
Precautionary statementPrevention
P261 Avoid breathing dust.P264 Wash thoroughly after handling.P270 Do not eat, drink or smoke when using this product.
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P271 Use only outdoors or in a well-ventilated area.P280 Wear protective gloves.P280 Wear eye/face protection.
ResponseP301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.P302 + P352 IF ON SKIN: Wash with plenty of water.P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P305 + P351 +P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.P312 Call a POISON CENTER/doctor if you feel unwell.P330 Rinse mouth.P332 + P313 If skin irritation occurs: Get medical advice/attention.P337 + P313 If eye irritation persists: Get medical advice/attention.P362 + P364 Take off contaminated clothing and wash it before reuse.
StorageP403 + P233 Store in a well-ventilated place. Keep container tightly closed.P405 Store locked up.
DisposalP501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwiseclassified (HNOC)
WARNING! May form combustible dust concentrations in air. Avoid breathing dust.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS number %Chemical name Common name and synonyms3-HYDROXY-2-METHYL-4-PYRANONE3-Hydroxy-2-methyl-4-pyrone3- hydroxy-2-methylpyran-4-one
2-methyl pyromeconic acid 2-methyl-3-hydroxy-4-pyrone
118-71-8MALTOL 100
4. FIRST-AID MEASURESInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Skin contact Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Eye contact Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
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Ingestion Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Most importantsymptoms/effects, acute anddelayed
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Dusts may irritate the respiratory tract, skin and eyes. Skin irritation. May cause rednessand pain.
Indication of immediate medicalattention and special treatmentneeded
Not available.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
5. FIRE-FIGHTING MEASURESSuitable extinguishing media Water spray, fog, CO2, dry chemical, or alcohol resistant foam.Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Specific hazards arising fromthe chemical
Fire may produce irritating, corrosive and/or toxic gases.
Explosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, andin the presence of an ignition source is a potential dust explosion hazard.
Special protective equipmentand precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Fire fightingequipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Specific methods Use water spray to cool unopened containers.General fire hazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.
6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures
Keep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Methods and materials forcontainment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Sweep upand place in a clearly labeled container for chemical waste. Wash contaminated area with water.Use only non-sparking tools. Avoid the generation of dusts during clean-up.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
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7. HANDLING AND STORAGEPrecautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Take precautionary
measures against static discharges when there is a risk of dust explosion. Avoid breathing dust.Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Wash thoroughly afterhandling.
Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensurethat dusts do not accumulate on surfaces. Dry powders can build static electricity charges whensubjected to the friction of transfer and mixing operations. Provide adequate precautions, such aselectrical grounding and bonding, or inert atmospheres. Assume that this material is capable ofproducing a dust explosion if ignited as a dust cloud.
Conditions for safe storage,including any incompatibilities
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits No exposure limits noted for ingredient(s).Biological limit values No biological exposure limits noted for the ingredient(s).Appropriate engineering controls Use only appropriately classified electrical equipment and powered industrial trucks. Use
explosion-proof ventilation equipment to stay below exposure limits. It is recommended that alldust control equipment such as local exhaust ventilation and material transport systems involvedin handling of this product contain explosion relief vents or an explosion suppression system or anoxygen-deficient environment. Ensure that dust-handling systems (such as exhaust ducts, dustcollectors, vessels, and processing equipment) are designed in a manner to prevent the escape ofdust into the work area (i.e., there is no leakage from the equipment).
Individual protection measures, such as personal protective equipmentEye/face protection Wear safety glasses with side shields (or goggles).
Skin protectionHand protection Chemical resistant gloves.
Other Not available.Respiratory protection Dust mask.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations When using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. Routinelywash work clothing and protective equipment to remove contaminants.
9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Refer to Spec Sheet
Physical state Powder\Crystal.Form Powder. Crystalline powder.Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
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Melting point/freezing point 318.2 - 323.6 °F (159 - 162 °C)
Initial boiling point and boilingrange
544.46 °F (284.7 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0 kPa at 25 °C
Vapor density 3.8
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationMolecular weight 126.11 g/mol
10. STABILITY AND REACTIVITYReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Chemical stability Material is stable under normal conditions.Possibility of hazardousreactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Keep away from heat, sparks and open flame. Avoid temperatures exceeding the flash point.Minimize dust generation and accumulation. Contact with incompatible materials.
Incompatible materials Alkaline metals.Hazardous decompositionproducts
No hazardous decomposition products if stored and handled as indicated.
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation Irritating to respiratory system.
Skin contact Causes skin irritation.
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Print Date: 11-24-2015Page 6 of 9
Eye contact Causes serious eye irritation.
Ingestion Harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Severe eye irritation. Dusts may irritate the respiratory tract, skin and eyes. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause rednessand pain.
Information on toxicological effects
Acute toxicity Harmful if swallowed. May cause respiratory irritation.
Test ResultsProduct SpeciesMALTOL (CAS 118-71-8)
LD50 RabbitDermalAcute
> 5000 mg/kg
LD50 RatOral
1410 mg/kg
* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Causes skin irritation.
Skin - rabbit - Irritating to skin. - 24 hSerious eye damage/eyeirritation
Causes serious eye irritation.
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -single exposure
May cause respiratory irritation.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONEcotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.Persistence and degradability No data is available on the degradability of this product.Bioaccumulative potential No data available.Mobility in soil No data available.
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Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDisposal instructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.Hazardous waste code Not established.Waste from residues / unusedproducts
Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
Not regulated as dangerous goods.BULK
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
SARA 304 Emergency release notificationNot regulated.
500413 MALTOL (VELTOL) FCCSAFETY DATA SHEET
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Print Date: 11-24-2015Page 8 of 9
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes
Delayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substanceNot listed.
SARA 311/312 Hazardouschemical
Yes
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Safe Drinking Water Act(SDWA)
Not regulated.
US state regulationsUS. Massachusetts RTK - Substance List
Not regulated.US. New Jersey Worker and Community Right-to-Know Act
Not listed.US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
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Country(s) or region Inventory name On inventory (yes/no)*YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISIONIssue date 11-24-2015Revision date 11-24-2015Version # 02Further information Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the
Manufacturing, Processing, and Handling of Combustible Particulate Solids, for safe handling.HMIS® ratings Health: 1
Flammability: 1Physical hazard: 0
Disclaimer Vigon cannot anticipate all conditions under which this information and its product, or the productsof other manufacturers in combination with its product, may be used. It is the user’s responsibilityto ensure safe conditions for handling, storage and disposal of the product, and to assume liabilityfor loss, injury, damage or expense due to improper use. The information in the sheet was writtenbased on the best knowledge and experience currently available. The above information relatesonly to this product and not to its use in combination with any other material or any particularprocess and is designed only as guidance for the safe handling, use, processing, storage,transportation, disposal, and should not be considered as a guarantee or quality specification. Theabove information is based on data provided by and collected from recognized sources such asdistributors, manufacturers, and technical groups and is considered to be accurate to the best ofVigon’s knowledge as of the date of this document. It is the responsibility of the user to review allsafety information about this product and determine its safety and suitability in their own processesand operations. Appropriate warnings and safe handling procedures should be provided to allhandlers and users, taking into account the intended use and the specific conditions and factorsrelating to such use in accordance with all applicable laws and regulations.
Revision Information Product and Company Identification: Alternate Trade NamesPhysical & Chemical Properties: Multiple PropertiesToxicological Information: Toxicological Data
501338 METHYL-2 BUTYRIC ACID NATURAL (OPTICALLY ACTIVE)SAFETY DATA SHEET
Version # 02Revision Date: 11-08-2016
Print Date: 11-08-2016Page 1 of 10
1. IDENTIFICATIONMETHYL-2 BUTYRIC ACID NATURAL (OPTICALLY ACTIVE)Product Description:116-53-0CAS #
FEMA Number 2695
Other means of identification501338Vigon Item #Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended use
For Manufacturing Use OnlyRecommended restrictions
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
Manufacturer/Importer/Supplier/Distributor informationManufacturer
Vigon International, Inc.Address 127 Airport RoadCompany name
WebsiteTelephone For information call: 570-476-6300
Emergency phone number INFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
United States
www.vigon.comNot available.
E. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONCategory 4Flammable liquidsPhysical hazardsCategory 4Acute toxicity, oralHealth hazardsCategory 4Acute toxicity, dermalCategory 1BSkin corrosion/irritationCategory 1Serious eye damage/eye irritation
Not classified.Environmental hazards
Label elements
Signal word Danger
501338 METHYL-2 BUTYRIC ACID NATURAL (OPTICALLY ACTIVE)SAFETY DATA SHEET
Version # 02Revision Date: 11-08-2016
Print Date: 11-08-2016Page 2 of 10
Hazard statement Combustible liquid. Harmful if swallowed or in contact with skin. Causes severe skin burns andeye damage. Causes serious eye damage.
Precautionary statementPrevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke whenusing this product. Wear protective gloves/protective clothing/eye protection/face protection.
Response IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take offimmediately all contaminated clothing. Rinse skin with water. IF INHALED: Remove person tofresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call aPOISON CENTER/doctor. Take off contaminated clothing and wash it before reuse. In case offire: Use appropriate media to extinguish.
Storage Store in a well-ventilated place. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information 100% of the mixture consists of component(s) of unknown long-term hazards to the aquaticenvironment. 100% of the mixture consists of component(s) of unknown acute inhalation toxicity.100% of the mixture consists of component(s) of unknown acute hazards to the aquaticenvironment.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS numberCommon name and synonymsChemical name %2- METHYLBUTANOIC ACIDethyl methyl acetic acidmethylethyl acetic acid
116-53-0METHYL-2 BUTYRIC ACID 100
4. FIRST-AID MEASURESIf breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Inhalation
Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Skin contact
Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Eye contact
Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Ingestion
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage includingblindness could result.
Most importantsymptoms/effects, acute anddelayed
Not available.Indication of immediate medicalattention and special treatmentneeded
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Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. FIRE-FIGHTING MEASURESWater spray, fog, CO2, dry chemical, or alcohol resistant foam.Suitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing mediaFire may produce irritating, corrosive and/or toxic gases.Specific hazards arising from
the chemicalFirefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Special protective equipmentand precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Fire fightingequipment/instructions
Use water spray to cool unopened containers.Specific methodsStatic charges generated by emptying package in or near flammable vapor may cause flash fire.General fire hazards
6. ACCIDENTAL RELEASE MEASURESKeep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Personal precautions, protectiveequipment and emergencyprocedures
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains.Absorb in vermiculite, dry sand or earth and place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Methods and materials forcontainment and cleaning up
Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
Environmental precautions
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7. HANDLING AND STORAGEDo not handle or store near an open flame, heat or other sources of ignition. Take precautionarymeasures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Precautions for safe handling
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
Conditions for safe storage,including any incompatibilities
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONThis substance has no PEL, TLV, or other recommended exposure limit.Occupational exposure limitsNo biological exposure limits noted for the ingredient(s).Biological limit valuesUse explosion-proof ventilation equipment to stay below exposure limits.Appropriate engineering controls
Individual protection measures, such as personal protective equipmentWear safety glasses with side shields (or goggles). Face shield is recommended.Eye/face protection
Skin protectionChemical resistant gloves.Hand protection
Use of an impervious apron is recommended.Other
Respiratory protection not required. If ventilation is insufficient, suitable respiratory protection mustbe provided.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using do not smoke. Keep away from food and drink. Always observe good personalhygiene measures, such as washing after handling the material and before eating, drinking, and/orsmoking. Routinely wash work clothing and protective equipment to remove contaminants.
General hygiene considerations
9. PHYSICAL AND CHEMICAL PROPERTIESRefer to Spec SheetAppearanceLiquid.Physical stateLiquid.FormRefer to Spec SheetColorCharacteristic.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boilingrange
349.7 °F (176.5 °C)
Flash point 165.0 °F (73.9 °C) Closed Cup
Evaporation rate Not available.Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
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Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.38 mm Hg at 20 °C
Vapor density 3.5
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationNot explosive.Explosive properties
Flammability class Combustible IIIA estimated
Molecular formula C5H10O2
Molecular weight 102.13 g/molNot oxidizing.Oxidizing properties
Specific gravity 0.93 at 25 °C
10. STABILITY AND REACTIVITYThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityMaterial is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous
reactionsAvoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding theflash point. Contact with incompatible materials.
Conditions to avoid
Strong oxidizing agents.Incompatible materialsNo hazardous decomposition products if stored and handled as indicated.Hazardous decomposition
products
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact Causes severe skin burns. Harmful in contact with skin.
Eye contact Causes serious eye damage.
Ingestion Causes digestive tract burns. Harmful if swallowed.
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Symptoms related to thephysical, chemical andtoxicological characteristics
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage includingblindness could result.
Information on toxicological effects
Acute toxicity Harmful in contact with skin. Harmful if swallowed.
Test ResultsProduct SpeciesMETHYL-2 BUTYRIC ACID NATURAL (OPTICALLY ACTIVE) (CAS 116-53-0)
LD50 RabbitDermalAcute
1367 mg/kg
LD50 RatOral
1750 mg/kg
* Estimates for product may be based on additional component data not shown.Causes severe skin burns and eye damage.Skin corrosion/irritationCauses serious eye damage.Serious eye damage/eye
irritation
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitizationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
US. National Toxicology Program (NTP) Report on CarcinogensNot listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONThe product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
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No data is available on the degradability of this product. Persistence and degradabilityNo data available.Bioaccumulative potentialNo data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDo not discharge into drains, water courses or onto the ground. Do not allow this material to draininto sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulationsNot established.Hazardous waste codeEmpty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Waste from residues / unusedproducts
Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.
Contaminated packaging
14. TRANSPORT INFORMATIONADN
3265UN numberCORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (METHYL-2 BUTYRIC ACID)UN proper shipping name8Transport hazard class(es)-Subsidiary class(es)IIPacking groupNoEnvironmental hazards8Labels required
ADR3265UN numberCORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (METHYL-2 BUTYRIC ACID)UN proper shipping name8Transport hazard class(es)-Subsidiary class(es)IIPacking groupNoEnvironmental hazards8Labels required
RID3265UN numberCORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (METHYL-2 BUTYRIC ACID)UN proper shipping name8Transport hazard class(es)-Subsidiary class(es)IIPacking GroupNoEnvironmental Hazards8Labels requiredRead safety instructions, SDS and emergency procedures before handling.Special precautions for user
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DOT
3265UN numberBULK
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (METHYL-2 BUTYRIC ACID)Proper shipping name8Hazard classIIPacking group
NoMarine pollutantEnvironmental hazards
154Packaging exceptions242Packaging bulk8Labels required
DOT
3265UN numberNON-BULK
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (METHYL-2 BUTYRIC ACID)Proper shipping name8Hazard classIIPacking group
NoMarine pollutantEnvironmental hazards
154Packaging exceptions202Packaging non bulk8Labels required
IATA3265UN numberCORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (METHYL-2 BUTYRIC ACID)UN proper shipping name8Transport hazard class(es)-Subsidiary class(es)IIPacking groupNoEnvironmental hazards8Labels required
IMDG3265UN numberCORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (METHYL-2 BUTYRIC ACID)UN proper shipping name8Transport hazard class(es)-Subsidiary class(es)IIPacking group
NoMarine pollutantEnvironmental hazards
8Labels requiredNot applicable.Transport in bulk according
to Annex II of MARPOL73/78 and the IBC Code
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ADN; ADR; DOT BULK; DOT NON-BULK; IATA; IMDG; RID
15. REGULATORY INFORMATIONThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.
US federal regulations
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
SARA 304 Emergency release notificationNot regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substanceNot listed.
YesSARA 311/312 Hazardouschemical
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Not regulated.Safe Drinking Water Act
(SDWA)
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International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION11-26-2015Issue date11-08-2016Revision date
Version # 02Health: 3Flammability: 2Physical hazard: 0
HMIS® ratings
Vigon International, Inc. cannot anticipate all conditions under which this information and itsproduct, or the products of other manufacturers in combination with its product, may be used. It isthe user’s responsibility to ensure safe conditions for handling, storage and disposal of theproduct, and to assume liability for loss, injury, damage or expense due to improper use. Theinformation in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
Disclaimer
This document has undergone significant changes and should be reviewed in its entirety.Revision information
501274 METHYL ANTHRANILATE NATURALSAFETY DATA SHEET
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1. IDENTIFICATIONMETHYL ANTHRANILATE NATURALProduct Description:134-20-3CAS #
FEMA Number 2682
Other means of identification501274Vigon Item #Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended use
For Manufacturing Use OnlyRecommended restrictions
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
Manufacturer/Importer/Supplier/Distributor informationManufacturer
Vigon International, Inc.Address 127 Airport RoadCompany name
WebsiteTelephone For information call: 570-476-6300
Emergency phone number INFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
United States
www.vigon.comNot available.
E. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 5Acute toxicity, oralHealth hazardsCategory 5Acute toxicity, dermalCategory 2Skin corrosion/irritationCategory 2ASerious eye damage/eye irritationCategory 3 respiratory tract irritationSpecific target organ toxicity, single
exposureCategory 2Hazardous to the aquatic environment,
acute hazardEnvironmental hazards
Category 2Hazardous to the aquatic environment,long-term hazard
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Label elements
Signal word Warning
Hazard statement May be harmful if swallowed or in contact with skin. Causes skin irritation. Causes skin and eyeirritation. Causes serious eye irritation. May cause respiratory irritation. Toxic to aquatic life withlong lasting effects.
Precautionary statementPrevention Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Use only
outdoors or in a well-ventilated area. Avoid release to the environment. Wear eye protection/faceprotection. Wear protective gloves.
Response IF ON SKIN: Wash with plenty of water. IF INHALED: Remove person to fresh air and keepcomfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER/doctor if youfeel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Getmedical advice/attention. Take off contaminated clothing and wash it before reuse. Collectspillage.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS numberCommon name and synonymsChemical name %Methyl 2- aminobenzoateO- CARBOMETHOXYANILINE2- (METHOXYCARBONYL) ANILINEmethyl ortho- aminobenzoate
134-20-3METHYL ANTHRANILATE 100
4. FIRST-AID MEASURESIf breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Inhalation
Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Skin contact
Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Eye contact
Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Ingestion
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Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. May cause respiratory irritation. Skin irritation. May cause redness and pain.
Most importantsymptoms/effects, acute anddelayed
Not available.Indication of immediate medicalattention and special treatmentneeded
Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. FIRE-FIGHTING MEASURESWater spray, fog, CO2, dry chemical, or alcohol resistant foam.Suitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing mediaFire may produce irritating, corrosive and/or toxic gases.Specific hazards arising from
the chemicalFirefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Special protective equipmentand precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Fire fightingequipment/instructions
Use water spray to cool unopened containers.Specific methodsStatic charges generated by emptying package in or near flammable vapor may cause flash fire.General fire hazards
6. ACCIDENTAL RELEASE MEASURESKeep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Personal precautions, protectiveequipment and emergencyprocedures
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains.Absorb in vermiculite, dry sand or earth and place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Methods and materials forcontainment and cleaning up
501274 METHYL ANTHRANILATE NATURALSAFETY DATA SHEET
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Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
Environmental precautions
7. HANDLING AND STORAGEDo not handle or store near an open flame, heat or other sources of ignition. Take precautionarymeasures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Precautions for safe handling
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
Conditions for safe storage,including any incompatibilities
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONThis substance has no PEL, TLV, or other recommended exposure limit.Occupational exposure limitsNo biological exposure limits noted for the ingredient(s).Biological limit valuesUse explosion-proof ventilation equipment to stay below exposure limits.Appropriate engineering controls
Individual protection measures, such as personal protective equipmentWear safety glasses with side shields (or goggles).Eye/face protection
Skin protectionChemical resistant gloves.Hand protection
Not available.OtherRespiratory protection not required. If ventilation is insufficient, suitable respiratory protection mustbe provided.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Keep away from food and drink. Always observe good personal hygiene measures, such aswashing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants.
General hygiene considerations
9. PHYSICAL AND CHEMICAL PROPERTIESRefer to Spec SheetAppearanceSolid.Physical stateSolid.FormRefer to Spec SheetColorCharacteristic.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point 76.1 °F (24.5 °C)
Initial boiling point and boilingrange
492.8 °F (256 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Not available.Flammability (solid, gas)
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Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.12 mm Hg at 20°C
Vapor density 5.2
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 1.17 g/cm3 estimated at 20 °C
Not explosive.Explosive properties
Molecular formula C8-H9-N-O2
Molecular weight 151.16 g/molNot oxidizing.Oxidizing properties
Specific gravity 1.17 at 20 °C
10. STABILITY AND REACTIVITYThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityMaterial is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous
reactionsAvoid temperatures exceeding the flash point. Contact with incompatible materials.Conditions to avoidPeroxides. Phenols.Incompatible materialsNo hazardous decomposition products if stored and handled as indicated.Hazardous decomposition
products
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact May be harmful in contact with skin. Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion May be harmful if swallowed.
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Symptoms related to thephysical, chemical andtoxicological characteristics
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. May cause respiratory irritation. Skin irritation. May cause redness and pain.
Information on toxicological effects
Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness andcentral nervous system effects. May be harmful in contact with skin. May be harmful if swallowed.
Test ResultsProduct SpeciesMETHYL ANTHRANILATE (CAS 134-20-3)
LD50 RatOralAcute
2910 mg/kg
* Estimates for product may be based on additional component data not shown.Causes skin irritation.rabbit - Skin irritation - 24 h
Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eyeirritation
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitizationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
US. National Toxicology Program (NTP) Report on CarcinogensNot listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
Reproductive toxicity - mouse - OralEffects on Fertility: Female fertility index (e.g., # females pregnant per # sperm positive females; #females pregnant per # females mated ).
Reproductive toxicity
Specific target organ toxicity -single exposure
May cause respiratory irritation.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONToxic to aquatic life with long lasting effects.Ecotoxicity
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Product Test ResultsSpeciesMETHYL ANTHRANILATE (CAS 134-20-3)
AquaticEC50Crustacea 18.2 mg/l, 48 hoursDaphnia magna
LC50Fish > 7.98 - < 10.51 mg/l, 96 hoursBluegill (Lepomis macrochirus)
* Estimates for product may be based on additional component data not shown.
NOEC 5 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)
No data is available on the degradability of this product. Persistence and degradabilityNo data available.Bioaccumulative potentialNo data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDo not discharge into drains, water courses or onto the ground. Do not allow this material to draininto sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulationsNot established.Hazardous waste codeEmpty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Waste from residues / unusedproducts
Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.
Contaminated packaging
14. TRANSPORT INFORMATIONADN
3082UN numberENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (METHYL ANTHRANILATE)UN proper shipping name9Transport hazard class(es)-Subsidiary class(es)IIIPacking groupYesEnvironmental hazards9Labels required
ADR3082UN numberENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (METHYL ANTHRANILATE)UN proper shipping name9Transport hazard class(es)-Subsidiary class(es)IIIPacking groupYesEnvironmental hazards
501274 METHYL ANTHRANILATE NATURALSAFETY DATA SHEET
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9Labels requiredRID
3082UN numberENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (METHYL ANTHRANILATE)UN proper shipping name9Transport hazard class(es)-Subsidiary class(es)IIIPacking GroupYesEnvironmental Hazards9Labels requiredRead safety instructions, SDS and emergency procedures before handling.Special precautions for user
DOT
3082UN numberBULK
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (METHYL ANTHRANILATE)Proper shipping name9Hazard classIIIPacking group
YesMarine pollutantEnvironmental hazards
9Labels requiredDOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDG3082UN numberENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (METHYL ANTHRANILATE)UN proper shipping name9Transport hazard class(es)-Subsidiary class(es)IIIPacking group
YesMarine pollutantEnvironmental hazards
9Labels requiredNot applicable.Transport in bulk according
to Annex II of MARPOL73/78 and the IBC Code
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ADN; ADR; DOT BULK; IMDG; RID
Marine pollutant
15. REGULATORY INFORMATIONThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.
US federal regulations
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
SARA 304 Emergency release notificationNot regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substanceNot listed.
NoSARA 311/312 Hazardouschemical
501274 METHYL ANTHRANILATE NATURALSAFETY DATA SHEET
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SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Not regulated.Safe Drinking Water Act
(SDWA)
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))METHYL ANTHRANILATE (CAS 134-20-3) 50 %WT
DEA Exempt Chemical Mixtures Code NumberMETHYL ANTHRANILATE (CAS 134-20-3) 8530
Controlled substanceFood and DrugAdministration (FDA)
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION08-31-2017Issue date08-31-2017Revision date
Version # 02Health: 2Flammability: 1Physical hazard: 0
HMIS® ratings
501274 METHYL ANTHRANILATE NATURALSAFETY DATA SHEET
Version # 02Revision Date: 08-31-2017
Print Date: 08-31-2017Page 11 of 11
Vigon International, Inc. cannot anticipate all conditions under which this information and itsproduct, or the products of other manufacturers in combination with its product, may be used. It isthe user’s responsibility to ensure safe conditions for handling, storage and disposal of theproduct, and to assume liability for loss, injury, damage or expense due to improper use. Theinformation in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
Disclaimer
This document has undergone significant changes and should be reviewed in its entirety.Revision information
504558 METHYL CYCLOPENTENOLONE NATURALSAFETY DATA SHEET
Version # 02Revision Date: 08-10-2015
Print Date: 11-26-2015Page 1 of 9
1. IDENTIFICATIONProduct Description: METHYL CYCLOPENTENOLONE NATURALCAS # 765-70-8
Other means of identificationVigon Item # 504558
Recommended use Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended restrictions For Manufacturing Use Only
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 5Acute toxicity, oralHealth hazardsNot classified.Environmental hazards
Label elementsNone.Hazard symbol
Signal word Warning
Hazard statementH303 May be harmful if swallowed.
Precautionary statementPrevention Observe good industrial hygiene practices.
ResponseP312 Call a POISON CENTER/doctor if you feel unwell.
Storage Store away from incompatible materials.
Disposal Dispose of waste and residues in accordance with local authority requirements.Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
504558 METHYL CYCLOPENTENOLONE NATURALSAFETY DATA SHEET
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CAS number %Chemical name Common name and synonyms1,2-Cyclopentanedione, 3-methyl-3-Methylcyclopentane-1,2-dione
2-hydroxy-3-methyl-2-cyclopenten-1-one methylcyclopentenealcohol ketone
765-70-8METHYL CYCLOPENTENOLONE 100
4. FIRST-AID MEASURESInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Skin contact Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Eye contact Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Ingestion Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Most importantsymptoms/effects, acute anddelayed
Direct contact with eyes may cause temporary irritation.
Indication of immediate medicalattention and special treatmentneeded
Not available.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
5. FIRE-FIGHTING MEASURESSuitable extinguishing media Water spray, fog, CO2, dry chemical, or alcohol resistant foam.Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Specific hazards arising fromthe chemical
Fire may produce irritating, corrosive and/or toxic gases.
Special protective equipmentand precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Fire fightingequipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Specific methods Use water spray to cool unopened containers.General fire hazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.
6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures
Keep unnecessary personnel away. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them. Eliminateall sources of ignition. Avoid contact with skin or inhalation of spillage, dust or vapor.
504558 METHYL CYCLOPENTENOLONE NATURALSAFETY DATA SHEET
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Methods and materials forcontainment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Donot allow material to contaminate ground water system. Absorb in vermiculite, dry sand or earthand place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Retain and disposeof contaminated wash water. Avoid release to the environment. Contact local authorities in case ofspillage to drain/aquatic environment.
7. HANDLING AND STORAGEPrecautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Take precautionary
measures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Conditions for safe storage,including any incompatibilities
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits No exposure limits noted for ingredient(s).Biological limit values No biological exposure limits noted for the ingredient(s).Appropriate engineering controls Use explosion-proof ventilation equipment to stay below exposure limits.
Individual protection measures, such as personal protective equipmentEye/face protection Wear safety glasses with side shields (or goggles).
Skin protectionHand protection Chemical resistant gloves.
Other Not available.Respiratory protection Dust mask.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations Keep away from food and drink. Always observe good personal hygiene measures, such aswashing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants.
504558 METHYL CYCLOPENTENOLONE NATURALSAFETY DATA SHEET
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9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Refer to Spec Sheet
Physical state Powder\Crystal.Form Crystalline powder.Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 221 °F (105 °C)
Initial boiling point and boilingrange
354.2 °F (179 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0 mm Hg at 25 °C
Vapor density 3.9
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationFlammability class Combustible IIIB estimated
Molecular formula C6H8O2
Molecular weight 112.13 g/mol
10. STABILITY AND REACTIVITYReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Chemical stability Material is stable under normal conditions.
504558 METHYL CYCLOPENTENOLONE NATURALSAFETY DATA SHEET
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Possibility of hazardousreactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products if stored and handled as indicated.
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation Irritating to respiratory system.
Skin contact No adverse effects due to skin contact are expected.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion May be harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Direct contact with eyes may cause temporary irritation.
Information on toxicological effects
Acute toxicity May be harmful if swallowed.
Test ResultsProduct SpeciesMETHYL CYCLOPENTENOLONE (CAS 765-70-8)
LD50 RatOralAcute
2500 mg/kg
* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.Serious eye damage/eyeirritation
Direct contact with eyes may cause temporary irritation.
Respiratory or skin sensitizationRespiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Not classified.
504558 METHYL CYCLOPENTENOLONE NATURALSAFETY DATA SHEET
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Aspiration hazard Not likely, due to the form of the product.
12. ECOLOGICAL INFORMATIONEcotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.Persistence and degradability No data is available on the degradability of this product.Bioaccumulative potential No data available.Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDisposal instructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.Hazardous waste code Not established.Waste from residues / unusedproducts
Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
Not regulated as dangerous goods.BULK
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
504558 METHYL CYCLOPENTENOLONE NATURALSAFETY DATA SHEET
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15. REGULATORY INFORMATIONUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
SARA 304 Emergency release notificationNot regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - No
Delayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substanceNot listed.
SARA 311/312 Hazardouschemical
No
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Safe Drinking Water Act(SDWA)
Not regulated.
US state regulationsUS. Massachusetts RTK - Substance List
Not regulated.US. New Jersey Worker and Community Right-to-Know Act
Not listed.US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.US. Rhode Island RTK
Not regulated.
US. California Proposition 65
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US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)NoKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISIONIssue date 02-05-2015Revision date 08-10-2015Version # 02HMIS® ratings Health: 1
Flammability: 1Physical hazard: 0
Disclaimer The information in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
504558 METHYL CYCLOPENTENOLONE NATURALSAFETY DATA SHEET
Version # 02Revision Date: 08-10-2015
Print Date: 11-26-2015Page 9 of 9
Revision Information Product and Company Identification: Vigon ValuesPhysical & Chemical Properties: Multiple PropertiesToxicological Information: Toxicological DataRegulatory Information: United StatesMaterial Attributes & Uses; Experimental Data: Material Attributes
501299 PHENYLACETIC ACID NATURALSAFETY DATA SHEET
Version # 04Revision Date: 04-19-2017
Print Date: 04-19-2017Page 1 of 10
1. IDENTIFICATIONPHENYLACETIC ACID NATURALProduct Description:103-82-2CAS #
FEMA Number 2878
Other means of identification501299Vigon Item #Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended use
For Manufacturing Use OnlyRecommended restrictions
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
Manufacturer/Importer/Supplier/Distributor informationManufacturer
Vigon International, Inc.Address 127 Airport RoadCompany name
WebsiteTelephone For information call: 570-476-6300
Emergency phone number INFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
United States
www.vigon.comNot available.
E. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 5Acute toxicity, oralHealth hazardsCategory 2ASerious eye damage/eye irritation
Not classified.Environmental hazards
Label elements
Signal word Warning
Hazard statement May be harmful if swallowed. Causes serious eye irritation.
501299 PHENYLACETIC ACID NATURALSAFETY DATA SHEET
Version # 04Revision Date: 04-19-2017
Print Date: 04-19-2017Page 2 of 10
Precautionary statementPrevention Wash thoroughly after handling. Wear eye protection/face protection.
Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue rinsing. Call a POISON CENTER/doctor if you feel unwell. If eyeirritation persists: Get medical advice/attention.
Storage Store away from incompatible materials.
Disposal Dispose of waste and residues in accordance with local authority requirements.Hazard(s) not otherwiseclassified (HNOC)
WARNING! May form combustible dust concentrations in air. Avoid breathing dust.
Supplemental information 100% of the mixture consists of component(s) of unknown long-term hazards to the aquaticenvironment. 100% of the mixture consists of component(s) of unknown acute inhalation toxicity.100% of the mixture consists of component(s) of unknown acute hazards to the aquaticenvironment.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS numberCommon name and synonymsChemical name %PHENYL ETHANOIC ACIDALPHA- TOLUIC ACIDBENZENACETIC ACID2- phenylacetic acidOMEGA- PHENYLACETIC ACID
103-82-2PHENYLACETIC ACID 100
4. FIRST-AID MEASURESIf breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Inhalation
Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Skin contact
Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Eye contact
Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Ingestion
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Dusts may irritate the respiratory tract, skin and eyes.
Most importantsymptoms/effects, acute anddelayed
Not available.Indication of immediate medicalattention and special treatmentneeded
Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. FIRE-FIGHTING MEASURESWater spray, fog, CO2, dry chemical, or alcohol resistant foam.Suitable extinguishing media
501299 PHENYLACETIC ACID NATURALSAFETY DATA SHEET
Version # 04Revision Date: 04-19-2017
Print Date: 04-19-2017Page 3 of 10
Do not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing mediaExplosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, andin the presence of an ignition source is a potential dust explosion hazard. Fire may produceirritating, corrosive and/or toxic gases.
Specific hazards arising fromthe chemical
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Special protective equipmentand precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Fire fightingequipment/instructions
Use water spray to cool unopened containers.Specific methodsStatic charges generated by emptying package in or near flammable vapor may cause flash fire.General fire hazards
6. ACCIDENTAL RELEASE MEASURESKeep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Personal precautions, protectiveequipment and emergencyprocedures
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Sweep upand place in a clearly labeled container for chemical waste. Wash contaminated area with water.Use only non-sparking tools. Avoid the generation of dusts during clean-up. This material and itscontainer must be disposed of as hazardous waste. Collect and dispose of spillage as indicated insection 13 of the SDS.
Never return spills in original containers for re-use.
Methods and materials forcontainment and cleaning up
Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
Environmental precautions
7. HANDLING AND STORAGETake precautionary measures against static discharges when there is a risk of dust explosion.Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensurethat dusts do not accumulate on surfaces. Dry powders can build static electricity charges whensubjected to the friction of transfer and mixing operations. Provide adequate precautions, such aselectrical grounding and bonding, or inert atmospheres. Assume that this material is capable ofproducing a dust explosion if ignited as a dust cloud.Do not handle or store near an open flame, heat or other sources of ignition. Take precautionarymeasures against static discharges. Avoid breathing vapor. Avoid breathing dust. Avoid contactwith eyes, skin, and clothing. Avoid prolonged exposure. Wash thoroughly after handling.
Precautions for safe handling
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
Conditions for safe storage,including any incompatibilities
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONThis substance has no PEL, TLV, or other recommended exposure limit.Occupational exposure limits
501299 PHENYLACETIC ACID NATURALSAFETY DATA SHEET
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No biological exposure limits noted for the ingredient(s).Biological limit valuesUse only appropriately classified electrical equipment and powered industrial trucks. It isrecommended that all dust control equipment such as local exhaust ventilation and materialtransport systems involved in handling of this product contain explosion relief vents or anexplosion suppression system or an oxygen-deficient environment. Ensure that dust-handlingsystems (such as exhaust ducts, dust collectors, vessels, and processing equipment) aredesigned in a manner to prevent the escape of dust into the work area (i.e., there is no leakagefrom the equipment). Use explosion-proof ventilation equipment to stay below exposure limits.
Appropriate engineering controls
Individual protection measures, such as personal protective equipmentWear safety glasses with side shields (or goggles).Eye/face protection
Skin protectionChemical resistant gloves.Hand protection
Not available.OtherDust mask.Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Keep away from food and drink. Always observe good personal hygiene measures, such aswashing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants.
General hygiene considerations
9. PHYSICAL AND CHEMICAL PROPERTIESRefer to Spec SheetAppearancePowder\Crystal.Physical statePowder. Crystalline powder.FormRefer to Spec SheetColorCharacteristic.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point 169.7 °F (76.5 °C)
Initial boiling point and boilingrange
509.9 °F (265.5 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.01 mm Hg at 25 °C
501299 PHENYLACETIC ACID NATURALSAFETY DATA SHEET
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Vapor density Not available.
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
1.41
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 1.09 g/cm3 estimated at 77 °C
Not explosive.Explosive properties
Flammability class Combustible IIIB estimated
Molecular formula C8-H8-O2
Molecular weight 136.14 g/molNot oxidizing.Oxidizing properties
10. STABILITY AND REACTIVITYThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityMaterial is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous
reactionsAvoid temperatures exceeding the flash point. Contact with incompatible materials.Conditions to avoidStrong oxidizing agents.Incompatible materialsNo hazardous decomposition products if stored and handled as indicated.Hazardous decomposition
products
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation Irritating to respiratory system.
Skin contact Dust or powder may irritate the skin.
Eye contact Causes serious eye irritation.
Ingestion May be harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Dusts may irritate the respiratory tract, skin and eyes.
Information on toxicological effects
Acute toxicity May be harmful if swallowed.
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Test ResultsProduct SpeciesPHENYLACETIC ACID (CAS 103-82-2)
LD50 RabbitDermalAcute
> 5000 mg/kg
LD50 RatOral
2500 mg/kg
* Estimates for product may be based on additional component data not shown.Eyes - rabbit - Moderate eye irritation - 24 h - Draize TestSkin corrosion/irritationCauses serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitizationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
US. National Toxicology Program (NTP) Report on CarcinogensNot listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONThe product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
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Product Test ResultsSpecies
* Estimates for product may be based on additional component data not shown.
PHENYLACETIC ACID (CAS 103-82-2)Aquatic
LC50Fish 1273 mg/l, 96 hoursFish
No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)1.41
No data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDo not discharge into drains, water courses or onto the ground. Do not allow this material to draininto sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulationsNot established.Hazardous waste codeEmpty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Waste from residues / unusedproducts
Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.
Contaminated packaging
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
Not regulated as dangerous goods.BULK
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
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IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.
US federal regulations
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
SARA 304 Emergency release notificationNot regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substanceNot listed.
NoSARA 311/312 Hazardouschemical
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Not regulated.Safe Drinking Water Act
(SDWA)
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))PHENYLACETIC ACID (CAS 103-82-2) 40 %WT
DEA Exempt Chemical Mixtures Code NumberPHENYLACETIC ACID (CAS 103-82-2) 8791
Controlled substanceFood and DrugAdministration (FDA)
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International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION11-23-2015Issue date04-19-2017Revision date
Version # 04Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from theManufacturing, Processing, and Handling of Combustible Particulate Solids, for safe handling.
Further information
Health: 2Flammability: 1Physical hazard: 0
HMIS® ratings
Vigon International, Inc. cannot anticipate all conditions under which this information and itsproduct, or the products of other manufacturers in combination with its product, may be used. It isthe user’s responsibility to ensure safe conditions for handling, storage and disposal of theproduct, and to assume liability for loss, injury, damage or expense due to improper use. Theinformation in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
Disclaimer
501299 PHENYLACETIC ACID NATURALSAFETY DATA SHEET
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HAZARD(S) IDENTIFICATION: Hazard statementHAZARD(S) IDENTIFICATION: DisposalHAZARD(S) IDENTIFICATION: PreventionHAZARD(S) IDENTIFICATION: ResponseHAZARD(S) IDENTIFICATION: StorageFIRST-AID MEASURES: Most important symptoms/effects, acute and delayedEXPOSURE CONTROLS/PERSONAL PROTECTION: PPE SymbolsPhysical & Chemical Properties: Multiple PropertiesToxicological Information: Toxicological DataTOXICOLOGICAL INFORMATION: CorrosivityTOXICOLOGICAL INFORMATION: Skin contactTOXICOLOGICAL INFORMATION: Specific target organ toxicity - single exposureTOXICOLOGICAL INFORMATION: Symptoms related to the physical, chemical and toxicologicalcharacteristicsGHS: Classification
Revision information
502911 RASPBERRY KETONE NATURALSAFETY DATA SHEET
Version # 03Revision Date: 04-29-2015
Print Date: 11-23-2015Page 1 of 9
1. IDENTIFICATIONProduct Description: RASPBERRY KETONE NATURALCAS # 5471-51-2
FEMA Number 2588
Other means of identificationVigon Item # 502911
Recommended use Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended restrictions For Manufacturing Use Only
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 4Acute toxicity, oralHealth hazardsNot classified.Environmental hazards
Label elements
Signal word Warning
Hazard statementH302 Harmful if swallowed.
Precautionary statementPrevention
P264 Wash thoroughly after handling.P270 Do not eat, drink or smoke when using this product.
ResponseP301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.P330 Rinse mouth.
Storage Store away from incompatible materials.
DisposalP501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwiseclassified (HNOC)
WARNING! May form combustible dust concentrations in air. Avoid breathing dust.
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Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS number %Chemical name Common name and synonyms4-(4-Hydroxyphenyl)butan-2-one2-Butanone, 4-(4-hydroxyphenyl)-OXYPHENYLON
5471-51-24-(4-HYDROXYPHENYL)-2-BUTANONE
100
4. FIRST-AID MEASURESInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Skin contact Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Eye contact Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Ingestion Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Most importantsymptoms/effects, acute anddelayed
Dusts may irritate the respiratory tract, skin and eyes.
Indication of immediate medicalattention and special treatmentneeded
Not available.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
5. FIRE-FIGHTING MEASURESSuitable extinguishing media Water spray, fog, CO2, dry chemical, or alcohol resistant foam.Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Specific hazards arising fromthe chemical
Fire may produce irritating, corrosive and/or toxic gases.
Explosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, andin the presence of an ignition source is a potential dust explosion hazard.
Special protective equipmentand precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Fire fightingequipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Specific methods Use water spray to cool unopened containers.
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General fire hazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.
6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures
Keep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Methods and materials forcontainment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Sweep upand place in a clearly labeled container for chemical waste. Wash contaminated area with water.Use only non-sparking tools. Avoid the generation of dusts during clean-up.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
7. HANDLING AND STORAGEPrecautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Take precautionary
measures against static discharges when there is a risk of dust explosion. Avoid breathing dust.Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Wash thoroughly afterhandling.
Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensurethat dusts do not accumulate on surfaces. Dry powders can build static electricity charges whensubjected to the friction of transfer and mixing operations. Provide adequate precautions, such aselectrical grounding and bonding, or inert atmospheres. Assume that this material is capable ofproducing a dust explosion if ignited as a dust cloud.
Conditions for safe storage,including any incompatibilities
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits No exposure limits noted for ingredient(s).Biological limit values No biological exposure limits noted for the ingredient(s).Appropriate engineering controls Use only appropriately classified electrical equipment and powered industrial trucks. Use
explosion-proof ventilation equipment to stay below exposure limits. It is recommended that alldust control equipment such as local exhaust ventilation and material transport systems involvedin handling of this product contain explosion relief vents or an explosion suppression system or anoxygen-deficient environment. Ensure that dust-handling systems (such as exhaust ducts, dustcollectors, vessels, and processing equipment) are designed in a manner to prevent the escape ofdust into the work area (i.e., there is no leakage from the equipment).
Individual protection measures, such as personal protective equipmentEye/face protection Wear safety glasses with side shields (or goggles).
Skin protectionHand protection Chemical resistant gloves.
Other Not available.
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Respiratory protection Dust mask.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations Keep away from food and drink. Always observe good personal hygiene measures, such aswashing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants.
9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Refer to Spec Sheet
Physical state Powder\Crystal.Form Powder. Crystalline powder.Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 181.4 °F (83 °C)
Initial boiling point and boilingrange
> 392 °F (> 200 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0 mm Hg at 20°C
Vapor density 5.7
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationFlammability class Combustible IIIB estimated
Molecular formula C10H12O2
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Molecular weight 164.2 g/mol
10. STABILITY AND REACTIVITYReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Chemical stability Material is stable under normal conditions.Possibility of hazardousreactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products if stored and handled as indicated.
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation Irritating to respiratory system.
Skin contact Causes mild skin irritation.
Eye contact Dust may irritate the eyes. Causes mild eye irritation.
Ingestion Harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Dusts may irritate the respiratory tract, skin and eyes.
Information on toxicological effects
Acute toxicity Harmful if swallowed.
Test ResultsProduct Species4-(4-HYDROXYPHENYL)-2- BUTANONE (CAS 5471-51-2)
LD50 RatOralAcute
1320 mg/kg
* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.Serious eye damage/eyeirritation
Direct contact with eyes may cause temporary irritation.
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
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Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONEcotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.Persistence and degradability No data is available on the degradability of this product.Bioaccumulative potential No data available.Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDisposal instructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.Hazardous waste code Not established.Waste from residues / unusedproducts
Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
Not regulated as dangerous goods.BULK
DOT
Not regulated as dangerous goods.NON-BULK
502911 RASPBERRY KETONE NATURALSAFETY DATA SHEET
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IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
SARA 304 Emergency release notificationNot regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes
Delayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substanceNot listed.
SARA 311/312 Hazardouschemical
Yes
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Safe Drinking Water Act(SDWA)
Not regulated.
US state regulationsUS. Massachusetts RTK - Substance List
Not regulated.
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US. New Jersey Worker and Community Right-to-Know ActNot listed.
US. Pennsylvania Worker and Community Right-to-Know LawNot listed.
US. Rhode Island RTKNot regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISIONIssue date 11-23-2015Revision date 04-29-2015Version # 03Further information Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the
Manufacturing, Processing, and Handling of Combustible Particulate Solids, for safe handling.HMIS® ratings Health: 1
Flammability: 1Physical hazard: 0
502911 RASPBERRY KETONE NATURALSAFETY DATA SHEET
Version # 03Revision Date: 04-29-2015
Print Date: 11-23-2015Page 9 of 9
Disclaimer Vigon cannot anticipate all conditions under which this information and its product, or the productsof other manufacturers in combination with its product, may be used. It is the user’s responsibilityto ensure safe conditions for handling, storage and disposal of the product, and to assume liabilityfor loss, injury, damage or expense due to improper use. The information in the sheet was writtenbased on the best knowledge and experience currently available. The above information relatesonly to this product and not to its use in combination with any other material or any particularprocess and is designed only as guidance for the safe handling, use, processing, storage,transportation, disposal, and should not be considered as a guarantee or quality specification. Theabove information is based on data provided by and collected from recognized sources such asdistributors, manufacturers, and technical groups and is considered to be accurate to the best ofVigon’s knowledge as of the date of this document. It is the responsibility of the user to review allsafety information about this product and determine its safety and suitability in their own processesand operations. Appropriate warnings and safe handling procedures should be provided to allhandlers and users, taking into account the intended use and the specific conditions and factorsrelating to such use in accordance with all applicable laws and regulations.
Revision Information Product and Company Identification: SynonymsHAZARD(S) IDENTIFICATION: Hazard(s) not otherwise classified (HNOC)HANDLING AND STORAGE: Precautions for safe handlingEXPOSURE CONTROLS/PERSONAL PROTECTION: Respiratory protectionPhysical & Chemical Properties: Multiple PropertiesToxicological Information: Toxicological DataTOXICOLOGICAL INFORMATION: Eye contactOTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION: Disclaimer
502784 FURANEOLSAFETY DATA SHEET
Version # 02Revision Date: 02-04-2016
Print Date: 02-04-2016Page 1 of 9
1. IDENTIFICATIONProduct Description: FURANEOLCAS # 3658-77-3
FEMA Number 3174
Other means of identificationVigon Item # 502784
Recommended use Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended restrictions For Manufacturing Use Only
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 4Acute toxicity, oralHealth hazardsCategory 4Acute toxicity, dermal
Not classified.Environmental hazards
Label elements
Signal word Warning
Hazard statementH302 + H312 Harmful if swallowed or in contact with skin.
Precautionary statementPrevention
P264 Wash thoroughly after handling.P270 Do not eat, drink or smoke when using this product.P280 Wear protective gloves/protective clothing.
ResponseP301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.P302 + P352 IF ON SKIN: Wash with plenty of water.P312 Call a POISON CENTER/doctor if you feel unwell.P330 Rinse mouth.P362 + P364 Take off contaminated clothing and wash it before reuse.
Storage Store away from incompatible materials.
502784 FURANEOLSAFETY DATA SHEET
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DisposalP501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwiseclassified (HNOC)
WARNING! May form combustible dust concentrations in air. Avoid breathing dust.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS number %Chemical name Common name and synonymsenhansol2,5-DIMETHYL-4-HYDROXY-3-FURANONEDIMETHYLHYDROXY FURANONE3(2H)-Furanone, 4-hydroxy-2,5-dimethyl-4-Hydroxy-2,5-dimethylfuran-2(3H)-one
3658-77-34- hydroxy- 2,5-dimethylfuran-3-one
100
4. FIRST-AID MEASURESInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Skin contact Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Eye contact Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Ingestion Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Most importantsymptoms/effects, acute anddelayed
Dusts may irritate the respiratory tract, skin and eyes.
Indication of immediate medicalattention and special treatmentneeded
Not available.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
5. FIRE-FIGHTING MEASURESSuitable extinguishing media Water spray, fog, CO2, dry chemical, or alcohol resistant foam.Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Specific hazards arising fromthe chemical
Fire may produce irritating, corrosive and/or toxic gases.
Explosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, andin the presence of an ignition source is a potential dust explosion hazard.
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Special protective equipmentand precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Fire fightingequipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Specific methods Use water spray to cool unopened containers.General fire hazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.
6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures
Keep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Methods and materials forcontainment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Sweep upand place in a clearly labeled container for chemical waste. Wash contaminated area with water.Use only non-sparking tools. Avoid the generation of dusts during clean-up.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
7. HANDLING AND STORAGEPrecautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Take precautionary
measures against static discharges when there is a risk of dust explosion. Avoid breathing dust.Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Wash thoroughly afterhandling.
Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensurethat dusts do not accumulate on surfaces. Dry powders can build static electricity charges whensubjected to the friction of transfer and mixing operations. Provide adequate precautions, such aselectrical grounding and bonding, or inert atmospheres. Assume that this material is capable ofproducing a dust explosion if ignited as a dust cloud.
Conditions for safe storage,including any incompatibilities
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits No exposure limits noted for ingredient(s).Biological limit values No biological exposure limits noted for the ingredient(s).
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Appropriate engineering controls Use only appropriately classified electrical equipment and powered industrial trucks. Useexplosion-proof ventilation equipment to stay below exposure limits. It is recommended that alldust control equipment such as local exhaust ventilation and material transport systems involvedin handling of this product contain explosion relief vents or an explosion suppression system or anoxygen-deficient environment. Ensure that dust-handling systems (such as exhaust ducts, dustcollectors, vessels, and processing equipment) are designed in a manner to prevent the escape ofdust into the work area (i.e., there is no leakage from the equipment).
Individual protection measures, such as personal protective equipmentEye/face protection Wear safety glasses with side shields (or goggles).
Skin protectionHand protection Chemical resistant gloves.
Other Not available.Respiratory protection Dust mask.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations When using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. Routinelywash work clothing and protective equipment to remove contaminants.
9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Refer to Spec Sheet
Physical state Powder\Crystal.Form Powder. Crystalline powder.Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 172.4 - 177.8 °F (78 - 81 °C)
Initial boiling point and boilingrange
Not available.
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.03 mm Hg at 25 °C
Vapor density 3.3
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Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationFlammability class Combustible IIIB estimated
Molecular formula C6H8O3
Molecular weight 128.13 g/mol
10. STABILITY AND REACTIVITYReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Chemical stability Material is stable under normal conditions.Possibility of hazardousreactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Keep away from heat, sparks and open flame. Avoid temperatures exceeding the flash point.Minimize dust generation and accumulation. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products if stored and handled as indicated.
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation Irritating to respiratory system.
Skin contact Harmful in contact with skin. Dust or powder may irritate the skin.
Eye contact Dust may irritate the eyes.
Ingestion Harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Dusts may irritate the respiratory tract, skin and eyes.
Information on toxicological effects
Acute toxicity Harmful in contact with skin. Harmful if swallowed.
Test ResultsProduct Species4- hydroxy- 2,5-dimethylfuran- 3-one (CAS 3658-77-3)
LD50 RabbitDermalAcute
1660 mg/kg
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Test ResultsProduct Species
LD50 RatOral
1860 mg/kg
* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.Serious eye damage/eyeirritation
Direct contact with eyes may cause temporary irritation.
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONEcotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.Persistence and degradability No data is available on the degradability of this product.Bioaccumulative potential No data available.Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDisposal instructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.Hazardous waste code Not established.Waste from residues / unusedproducts
Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
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Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
Not regulated as dangerous goods.BULK
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
SARA 304 Emergency release notificationNot regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes
Delayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substanceNot listed.
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SARA 311/312 Hazardouschemical
Yes
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Safe Drinking Water Act(SDWA)
Not regulated.
US state regulationsUS. Massachusetts RTK - Substance List
Not regulated.US. New Jersey Worker and Community Right-to-Know Act
Not listed.US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
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16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISIONIssue date 02-04-2016Revision date 02-04-2016Version # 02Further information Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the
Manufacturing, Processing, and Handling of Combustible Particulate Solids, for safe handling.HMIS® ratings Health: 1
Flammability: 1Physical hazard: 0
Disclaimer Vigon cannot anticipate all conditions under which this information and its product, or the productsof other manufacturers in combination with its product, may be used. It is the user’s responsibilityto ensure safe conditions for handling, storage and disposal of the product, and to assume liabilityfor loss, injury, damage or expense due to improper use. The information in the sheet was writtenbased on the best knowledge and experience currently available. The above information relatesonly to this product and not to its use in combination with any other material or any particularprocess and is designed only as guidance for the safe handling, use, processing, storage,transportation, disposal, and should not be considered as a guarantee or quality specification. Theabove information is based on data provided by and collected from recognized sources such asdistributors, manufacturers, and technical groups and is considered to be accurate to the best ofVigon’s knowledge as of the date of this document. It is the responsibility of the user to review allsafety information about this product and determine its safety and suitability in their own processesand operations. Appropriate warnings and safe handling procedures should be provided to allhandlers and users, taking into account the intended use and the specific conditions and factorsrelating to such use in accordance with all applicable laws and regulations.
Revision Information Product and Company Identification: Vigon ValuesHAZARD(S) IDENTIFICATION: Hazard(s) not otherwise classified (HNOC)ACCIDENTAL RELEASE MEASURES: Methods and materials for containment and cleaning upHANDLING AND STORAGE: Precautions for safe handlingPhysical & Chemical Properties: Multiple PropertiesToxicological Information: Toxicological DataTOXICOLOGICAL INFORMATION: Eye contactTOXICOLOGICAL INFORMATION: Skin contactOTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION: DisclaimerGHS: Classification
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1. IDENTIFICATIONProduct Description: SULFUROL (BEAN)CAS # 137-00-8
FEMA Number 3204
Other means of identificationVigon Item # 505048
Recommended use Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended restrictions For Manufacturing Use Only
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONCategory 4Flammable liquidsPhysical hazardsCategory 5Acute toxicity, oralHealth hazardsCategory 3Skin corrosion/irritation
Not classified.Environmental hazards
Label elementsNone.Hazard symbol
Signal word Warning
Hazard statementH227 Combustible liquid.H303 May be harmful if swallowed.H316 Causes mild skin irritation.
Precautionary statementPrevention
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.P280 Wear protective gloves/eye protection/face protection.
ResponseP312 Call a POISON CENTER/doctor if you feel unwell.P332 + P313 If skin irritation occurs: Get medical advice/attention.P370 + P378 In case of fire: Use appropriate media to extinguish.
StorageP403 + P235 Store in a well-ventilated place. Keep cool.
DisposalP501 Dispose of contents/container in accordance with local/regional/national/international regulations.
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Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS number %Chemical name Common name and synonyms5-hydroxyethyl-4-methylthiazole4-methyl-5-thiazoleethanol2-(4-methyl-1,3-thiazol-5-yl)ethanol
137-00-82-(4-Methylthiazol-5-yl)ethanol 100
4. FIRST-AID MEASURESInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Skin contact Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Eye contact Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Ingestion Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Most importantsymptoms/effects, acute anddelayed
Direct contact with eyes may cause temporary irritation. Mild skin irritation.
Indication of immediate medicalattention and special treatmentneeded
Not available.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
5. FIRE-FIGHTING MEASURESSuitable extinguishing media Water spray, fog, CO2, dry chemical, or alcohol resistant foam.Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Specific hazards arising fromthe chemical
Fire may produce irritating, corrosive and/or toxic gases.
Special protective equipmentand precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Fire fightingequipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Specific methods Use water spray to cool unopened containers.
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General fire hazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.
6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures
Keep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Methods and materials forcontainment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Donot allow material to contaminate ground water system. Absorb in vermiculite, dry sand or earthand place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
7. HANDLING AND STORAGEPrecautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Take precautionary
measures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Conditions for safe storage,including any incompatibilities
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits No exposure limits noted for ingredient(s).Biological limit values No biological exposure limits noted for the ingredient(s).Appropriate engineering controls Use explosion-proof ventilation equipment to stay below exposure limits.
Individual protection measures, such as personal protective equipmentEye/face protection Wear safety glasses with side shields (or goggles).
Skin protectionHand protection Chemical resistant gloves.
Other Not available.
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Respiratory protection Respiratory protection not required. If ventilation is insufficient, suitable respiratory protection mustbe provided.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations When using do not smoke. Keep away from food and drink. Always observe good personalhygiene measures, such as washing after handling the material and before eating, drinking, and/orsmoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Refer to Spec Sheet
Physical state Liquid.Form Liquid.Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boilingrange
534.2 - 537.8 °F (279 - 281 °C)
Flash point 176.0 °F (80.0 °C) Closed Cup
Evaporation rate Not available.Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0 mm Hg at 25 °C
Vapor density 5
Relative density Not available.
Solubility(ies)Solubility (water) Soluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationFlammability class Combustible IIIB estimated
Molecular formula C6H9NOS
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Molecular weight 143.21 g/mol
Specific gravity 1.2 at 20 °C
10. STABILITY AND REACTIVITYReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Chemical stability Material is stable under normal conditions.Possibility of hazardousreactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding theflash point. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products if stored and handled as indicated.
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation No adverse effects due to inhalation are expected.
Skin contact Causes mild skin irritation.
Eye contact Direct contact with eyes may cause temporary irritation. Causes mild eye irritation.
Ingestion May be harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Mild skin irritation.
Information on toxicological effects
Acute toxicity May be harmful if swallowed.
Test ResultsProduct Species2-(4-Methylthiazol-5-yl)ethanol (CAS 137-00-8)
LD50 RatOralAcute
2450 mg/kg
* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Causes mild skin irritation.Serious eye damage/eyeirritation
Direct contact with eyes may cause temporary irritation.
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
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OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONEcotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.Persistence and degradability No data is available on the degradability of this product.Bioaccumulative potential No data available.Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDisposal instructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.Hazardous waste code Not established.Waste from residues / unusedproducts
Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
NA1993UN numberBULK
COMBUSTIBLE LIQUID, N.O.S. (2-(4-Methylthiazol-5-yl)ethanol)Proper shipping nameCombustible liqHazard class
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IIIPacking group
NoMarine pollutantEnvironmental hazards
150Packaging exceptions241Packaging bulkNoneLabels required
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
DOT BULK
15. REGULATORY INFORMATIONUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
SARA 304 Emergency release notificationNot regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - No
Delayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
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SARA 302 Extremely hazardous substanceNot listed.
SARA 311/312 Hazardouschemical
Yes
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Safe Drinking Water Act(SDWA)
Not regulated.
US state regulationsUS. Massachusetts RTK - Substance List
Not regulated.US. New Jersey Worker and Community Right-to-Know Act
Not listed.US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
505048 SULFUROL (BEAN)SAFETY DATA SHEET
Version # 01Revision Date: 04-20-2015
Print Date: 11-21-2015Page 9 of 9
Country(s) or region Inventory name On inventory (yes/no)*YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISIONIssue date 11-21-2015Revision date 04-20-2015Version # 01HMIS® ratings Health: 1
Flammability: 2Physical hazard: 0
Disclaimer Vigon cannot anticipate all conditions under which this information and its product, or the productsof other manufacturers in combination with its product, may be used. It is the user’s responsibilityto ensure safe conditions for handling, storage and disposal of the product, and to assume liabilityfor loss, injury, damage or expense due to improper use. The information in the sheet was writtenbased on the best knowledge and experience currently available. The above information relatesonly to this product and not to its use in combination with any other material or any particularprocess and is designed only as guidance for the safe handling, use, processing, storage,transportation, disposal, and should not be considered as a guarantee or quality specification. Theabove information is based on data provided by and collected from recognized sources such asdistributors, manufacturers, and technical groups and is considered to be accurate to the best ofVigon’s knowledge as of the date of this document. It is the responsibility of the user to review allsafety information about this product and determine its safety and suitability in their own processesand operations. Appropriate warnings and safe handling procedures should be provided to allhandlers and users, taking into account the intended use and the specific conditions and factorsrelating to such use in accordance with all applicable laws and regulations.
501585 TERPINEOL ALPHA NATURALSAFETY DATA SHEET
Version # 02Revision Date: 02-17-2015
Print Date: 11-24-2015Page 1 of 10
1. IDENTIFICATIONProduct Description: TERPINEOL ALPHA NATURALCAS # 98-55-5
FEMA Number 3045
Other means of identificationVigon Item # 501585
Recommended use Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended restrictions For Manufacturing Use Only
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 5Acute toxicity, oralHealth hazardsCategory 5Acute toxicity, dermalCategory 2Skin corrosion/irritationCategory 2ASerious eye damage/eye irritationCategory 3 respiratory tract irritationSpecific target organ toxicity, single
exposureNot classified.Environmental hazards
Label elements
Signal word Warning
Hazard statementH303 + H313 May be harmful if swallowed or in contact with skin.H315 Causes skin irritation.H315 + H320 Causes skin and eye irritation.H319 Causes serious eye irritation.H335 May cause respiratory irritation.
Precautionary statementPrevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.P264 Wash thoroughly after handling.
501585 TERPINEOL ALPHA NATURALSAFETY DATA SHEET
Version # 02Revision Date: 02-17-2015
Print Date: 11-24-2015Page 2 of 10
P271 Use only outdoors or in a well-ventilated area.P280 Wear protective gloves.P280 Wear eye/face protection.
ResponseP302 + P352 IF ON SKIN: Wash with plenty of water.P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P305 + P351 +P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.P312 Call a POISON CENTER/doctor if you feel unwell.P321 Specific treatment (see this label).P332 + P313 If skin irritation occurs: Get medical advice/attention.P337 + P313 If eye irritation persists: Get medical advice/attention.P362 + P364 Take off contaminated clothing and wash it before reuse.
StorageP403 + P233 Store in a well-ventilated place. Keep container tightly closed.P405 Store locked up.
DisposalP501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS number %Chemical name Common name and synonyms2-(4- methyl-1-cyclohex-3-enyl)propan-2-oldextro,laevo-alpha-terpineol1-methyl-4-isopropyl-1-cyclohexen-8-olP-MENTH-1-EN-8-OL
98-55-5TERPINEOL ALPHA 100
4. FIRST-AID MEASURESInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Skin contact Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Eye contact Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Ingestion Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
501585 TERPINEOL ALPHA NATURALSAFETY DATA SHEET
Version # 02Revision Date: 02-17-2015
Print Date: 11-24-2015Page 3 of 10
Most importantsymptoms/effects, acute anddelayed
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. May cause respiratory irritation. Skin irritation. May cause redness and pain.
Indication of immediate medicalattention and special treatmentneeded
Not available.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
5. FIRE-FIGHTING MEASURESSuitable extinguishing media Water spray, fog, CO2, dry chemical, or alcohol resistant foam.Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.Specific hazards arising fromthe chemical
Fire may produce irritating, corrosive and/or toxic gases.
Special protective equipmentand precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Fire fightingequipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Specific methods Use water spray to cool unopened containers.General fire hazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.
6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures
Keep unnecessary personnel away. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them. Eliminateall sources of ignition. Avoid contact with skin or inhalation of spillage, dust or vapor.
Methods and materials forcontainment and cleaning up
Use a non-combustible material like vermiculite, sand or earth to soak up the product and placeinto a container for later disposal. Clean surface thoroughly to remove residual contamination.Collect and dispose of spillage as indicated in section 13 of the SDS.
Never return spills in original containers for re-use.Environmental precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic
environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Retainand dispose of contaminated wash water.
7. HANDLING AND STORAGEPrecautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Take precautionary
measures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Conditions for safe storage,including any incompatibilities
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
501585 TERPINEOL ALPHA NATURALSAFETY DATA SHEET
Version # 02Revision Date: 02-17-2015
Print Date: 11-24-2015Page 4 of 10
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits No exposure limits noted for ingredient(s).Biological limit values No biological exposure limits noted for the ingredient(s).Appropriate engineering controls Use explosion-proof ventilation equipment to stay below exposure limits.
Individual protection measures, such as personal protective equipmentEye/face protection Wear safety glasses with side shields (or goggles).
Skin protectionHand protection Chemical resistant gloves.
Other Not available.Respiratory protection Respiratory protection not required. If ventilation is insufficient, suitable respiratory protection must
be provided.Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations Keep away from food and drink. Always observe good personal hygiene measures, such aswashing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants.
9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Refer to Spec Sheet
Physical state Solid.Form Solid.Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 95 - 104 °F (35 - 40 °C)
Initial boiling point and boilingrange
424.4 - 429.8 °F (218 - 221 °C) 101.8583 kPa
Flash point 193.0 °F (89.4 °C) Closed Cup
Evaporation rate Not available.Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.03 kPa at 25 °C
Vapor density 5.3
Relative density Not available.
501585 TERPINEOL ALPHA NATURALSAFETY DATA SHEET
Version # 02Revision Date: 02-17-2015
Print Date: 11-24-2015Page 5 of 10
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
3
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 0.93 g/cm3 estimated
Flammability class Combustible IIIA estimated
Molecular formula C10-H18-O
Molecular weight 154.25 g/mol
Specific gravity 0.94 at 25 °C
10. STABILITY AND REACTIVITYReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Chemical stability Material is stable under normal conditions.Possibility of hazardousreactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products if stored and handled as indicated.
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact May be harmful in contact with skin. Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion May be harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Skin irritation. May cause redness and pain. May cause respiratory irritation.
Information on toxicological effects
Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness andcentral nervous system effects. May be harmful if swallowed. May be harmful in contact with skin.May cause respiratory irritation.
501585 TERPINEOL ALPHA NATURALSAFETY DATA SHEET
Version # 02Revision Date: 02-17-2015
Print Date: 11-24-2015Page 6 of 10
Test ResultsProduct SpeciesTERPINEOL ALPHA (CAS 98-55-5)
LD50 RabbitDermalAcute
> 3000 mg/kg
LD50 RatOral
4300 mg/kg
* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Causes skin irritation.Serious eye damage/eyeirritation
Causes serious eye irritation.
Respiratory or skin sensitizationRespiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -single exposure
May cause respiratory irritation.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not available.
12. ECOLOGICAL INFORMATIONEcotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.Persistence and degradability No data is available on the degradability of this product.Bioaccumulative potential Not available.
Partition coefficient n-octanol / water (log Kow)2.98
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
501585 TERPINEOL ALPHA NATURALSAFETY DATA SHEET
Version # 02Revision Date: 02-17-2015
Print Date: 11-24-2015Page 7 of 10
13. DISPOSAL CONSIDERATIONSDisposal instructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.Hazardous waste code Not established.Waste from residues / unusedproducts
Empty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
NA1993UN numberBULK
COMBUSTIBLE LIQUID, N.O.S. (TERPINEOL ALPHA)Proper shipping nameCombustible liqHazard classIIIPacking group
NoMarine pollutantEnvironmental hazards
150Packaging exceptions242Packaging bulk3Labels required
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
501585 TERPINEOL ALPHA NATURALSAFETY DATA SHEET
Version # 02Revision Date: 02-17-2015
Print Date: 11-24-2015Page 8 of 10
DOT BULK
15. REGULATORY INFORMATIONUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
SARA 304 Emergency release notificationNot regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes
Delayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substanceNot listed.
SARA 311/312 Hazardouschemical
Yes
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Safe Drinking Water Act(SDWA)
Not regulated.
501585 TERPINEOL ALPHA NATURALSAFETY DATA SHEET
Version # 02Revision Date: 02-17-2015
Print Date: 11-24-2015Page 9 of 10
US state regulationsUS. Massachusetts RTK - Substance List
Not regulated.US. New Jersey Worker and Community Right-to-Know Act
Not listed.US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISIONIssue date 11-24-2015Revision date 02-17-2015Version # 02HMIS® ratings Health: 2
Flammability: 2Physical hazard: 0
501585 TERPINEOL ALPHA NATURALSAFETY DATA SHEET
Version # 02Revision Date: 02-17-2015
Print Date: 11-24-2015Page 10 of 10
Disclaimer The information in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
Revision Information ACCIDENTAL RELEASE MEASURES: Methods and materials for containment and cleaning upPhysical & Chemical Properties: Multiple PropertiesToxicological Information: Toxicological DataTransport Information: Material Transportation InformationGHS: Classification
504113 TRIETHYL CITRATE NATURALSAFETY DATA SHEET
Version # 02Revision Date: 09-21-2017
Print Date: 09-21-2017Page 1 of 9
1. IDENTIFICATIONTRIETHYL CITRATE NATURALProduct Description:77-93-0CAS #
FEMA Number 3083
Other means of identification504113Vigon Item #Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended use
For Manufacturing Use OnlyRecommended restrictions
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
Manufacturer/Importer/Supplier/Distributor informationManufacturer
Vigon International, Inc.Address 127 Airport RoadCompany name
WebsiteTelephone For information call: 570-476-6300
Emergency phone number INFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
United States
www.vigon.comNot available.
E. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 5Acute toxicity, oralHealth hazardsNot classified.Environmental hazards
Label elementsNone.Hazard symbol
Signal word Warning
Hazard statement May be harmful if swallowed.
Precautionary statementPrevention Observe good industrial hygiene practices.
Response Call a POISON CENTER/doctor if you feel unwell.
Storage Store away from incompatible materials.
504113 TRIETHYL CITRATE NATURALSAFETY DATA SHEET
Version # 02Revision Date: 09-21-2017
Print Date: 09-21-2017Page 2 of 9
Disposal Dispose of waste and residues in accordance with local authority requirements.Hazard(s) not otherwiseclassified (HNOC)
None known.
Supplemental information None.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS numberCommon name and synonymsChemical name %CITRIC ACID TRIETHYL ESTERtriethyl 2- hydroxypropane - 1, 2, 3- tricarboxylateETHYL CITRATE2- Hydroxy- 1, 2, 3- propanetricarboxylic acidtriethyl ester
77-93-0TRIETHYL CITRATE 100
4. FIRST-AID MEASURESIf breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Inhalation
Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Skin contact
Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Eye contact
Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Ingestion
Direct contact with eyes may cause temporary irritation.Most importantsymptoms/effects, acute anddelayed
Not available.Indication of immediate medicalattention and special treatmentneeded
Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. FIRE-FIGHTING MEASURESWater spray, fog, CO2, dry chemical, or alcohol resistant foam.Suitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing mediaFire may produce irritating, corrosive and/or toxic gases.Specific hazards arising from
the chemicalFirefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Special protective equipmentand precautions for firefighters
504113 TRIETHYL CITRATE NATURALSAFETY DATA SHEET
Version # 02Revision Date: 09-21-2017
Print Date: 09-21-2017Page 3 of 9
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Fire fightingequipment/instructions
Use water spray to cool unopened containers.Specific methodsStatic charges generated by emptying package in or near flammable vapor may cause flash fire.General fire hazards
6. ACCIDENTAL RELEASE MEASURESKeep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Personal precautions, protectiveequipment and emergencyprocedures
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb withinert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recoverusing pumps.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Donot allow material to contaminate ground water system. Absorb in vermiculite, dry sand or earthand place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.
Never return spills in original containers for re-use. This material and its container must bedisposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of theSDS.
Methods and materials forcontainment and cleaning up
Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
Environmental precautions
7. HANDLING AND STORAGEDo not handle or store near an open flame, heat or other sources of ignition. Take precautionarymeasures against static discharges. All equipment used when handling the product must begrounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolongedexposure. Wash thoroughly after handling.
Precautions for safe handling
Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
Conditions for safe storage,including any incompatibilities
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONThis substance has no PEL, TLV, or other recommended exposure limit.Occupational exposure limitsNo biological exposure limits noted for the ingredient(s).Biological limit valuesUse explosion-proof ventilation equipment to stay below exposure limits.Appropriate engineering controls
504113 TRIETHYL CITRATE NATURALSAFETY DATA SHEET
Version # 02Revision Date: 09-21-2017
Print Date: 09-21-2017Page 4 of 9
Individual protection measures, such as personal protective equipmentWear safety glasses with side shields (or goggles).Eye/face protection
Skin protectionChemical resistant gloves.Hand protection
Not available.OtherRespiratory protection not required. If ventilation is insufficient, suitable respiratory protection mustbe provided.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Keep away from food and drink. Always observe good personal hygiene measures, such aswashing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants.
General hygiene considerations
9. PHYSICAL AND CHEMICAL PROPERTIESClear. Refer to Spec SheetAppearanceLiquid.Physical stateLiquid.FormRefer to Spec SheetColorCharacteristic.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point -67 °F (-55 °C)
Initial boiling point and boilingrange
561.2 °F (294 °C)
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.0002 mm Hg at 25 °C
Vapor density 9.6
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
504113 TRIETHYL CITRATE NATURALSAFETY DATA SHEET
Version # 02Revision Date: 09-21-2017
Print Date: 09-21-2017Page 5 of 9
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 1.14 g/cm3 at 20 °C
Dynamic viscosity 35.2 mPa.s (77 °F (25 °C))
Flammability class Combustible IIIB estimated
Kinematic viscosity 30.96 mm²/s estimated
Molecular formula C12-H20-O7
Molecular weight 276.29 g/mol
Specific gravity 1.14 at 25 °C
10. STABILITY AND REACTIVITYThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityMaterial is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous
reactionsAvoid temperatures exceeding the flash point. Contact with incompatible materials.Conditions to avoidStrong oxidizing agents.Incompatible materialsNo hazardous decomposition products if stored and handled as indicated.Hazardous decomposition
products
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation No adverse effects due to inhalation are expected.
Skin contact Causes mild skin irritation.
Eye contact Causes mild eye irritation.
Ingestion May be harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Direct contact with eyes may cause temporary irritation.
Information on toxicological effects
Acute toxicity May be harmful if swallowed.
Test ResultsProduct SpeciesTRIETHYL CITRATE NATURAL (CAS 77-93-0)
LD50 RabbitDermalAcute
> 5000 mg/kg
504113 TRIETHYL CITRATE NATURALSAFETY DATA SHEET
Version # 02Revision Date: 09-21-2017
Print Date: 09-21-2017Page 6 of 9
Test ResultsProduct Species
LC50 RatInhalation
1300 ppm, 6 hours Remarks: Lungs,Thorax, or Respiration:Acute pulmonaryedema. Lungs, Thorax, orRespiration:Pleural effusion Lungs, Thorax,or Respiration:Dyspnea.
* Estimates for product may be based on additional component data not shown.Prolonged skin contact may cause temporary irritation.Skin corrosion/irritationDirect contact with eyes may cause temporary irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitizationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
US. National Toxicology Program (NTP) Report on CarcinogensNot listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICAL INFORMATIONThe product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
No data is available on the degradability of this product.Persistence and degradabilityNo data available.Bioaccumulative potentialNo data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
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13. DISPOSAL CONSIDERATIONSDo not discharge into drains, water courses or onto the ground. Do not allow this material to draininto sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulationsNot established.Hazardous waste codeEmpty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Waste from residues / unusedproducts
Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.
Contaminated packaging
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.DOT
Not regulated as dangerous goods.BULK
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.
US federal regulations
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
SARA 304 Emergency release notificationNot regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
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TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substanceNot listed.
NoSARA 311/312 Hazardouschemical
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.Not regulated.Safe Drinking Water Act
(SDWA)Total food additiveDirect food additiveGRAS food additive
Food and DrugAdministration (FDA)
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
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16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION09-21-2017Issue date09-21-2017Revision date
Version # 02Health: 1Flammability: 1Physical hazard: 0
HMIS® ratings
Vigon International, Inc. cannot anticipate all conditions under which this information and itsproduct, or the products of other manufacturers in combination with its product, may be used. It isthe user’s responsibility to ensure safe conditions for handling, storage and disposal of theproduct, and to assume liability for loss, injury, damage or expense due to improper use. Theinformation in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
Disclaimer
This document has undergone significant changes and should be reviewed in its entirety.Revision information
501432 VANILLIN NATURALSAFETY DATA SHEET
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1. IDENTIFICATIONVANILLIN NATURALProduct Description:121-33-5CAS #
FEMA Number 3107
Other means of identification501432Vigon Item #Concentrated aromatic and flavor ingredient which may be used in flavor and fragrancecompounds according to legal and IFRA or FEMA GRAS/FDA guidelines.
Recommended use
For Manufacturing Use OnlyRecommended restrictions
24 Hour Emergency Response InformationINFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
Web Site: www.vigon.comFor information call: 570-476-6300
CompanyVigon International, Inc.127 Airport RoadE. Stroudsburg, PA 18301
Manufacturer/Importer/Supplier/Distributor informationManufacturer
Vigon International, Inc.Address 127 Airport RoadCompany name
WebsiteTelephone For information call: 570-476-6300
Emergency phone number INFOTRAC (ACCT# 78928);1-800-535-5053 WITHIN THE U.S.A.1-352-323-3500 OUTSIDE THE U.S.A.
United States
www.vigon.comNot available.
E. Stroudsburg, PA 18301
2. HAZARD(S) IDENTIFICATIONNot classified.Physical hazards
Category 4Acute toxicity, oralHealth hazardsCategory 2Serious eye damage/eye irritationCategory 3Hazardous to the aquatic environment,
acute hazardEnvironmental hazards
Category 3Hazardous to the aquatic environment,long-term hazard
Label elements
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Signal word Warning
Hazard statement Harmful if swallowed. Causes serious eye irritation. Harmful to aquatic life with long lastingeffects.
Precautionary statementPrevention Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid
release to the environment. Wear eye protection/face protection.
Response IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. IF IN EYES:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Storage Store away from incompatible materials.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC)
WARNING! May form combustible dust concentrations in air. Avoid breathing dust.
Supplemental information 100% of the mixture consists of component(s) of unknown acute inhalation toxicity.
3. COMPOSITION/INFORMATION ON INGREDIENTSSubstances
CAS numberCommon name and synonymsChemical name %4- hydroxy- 3- methoxybenzaldehydebenzaldehyde, 4- hydroxy- 3- methoxy- 4 - formyl- 2- methoxyphenolp- hydroxy- m- methoxybenzaldehyde2- methoxy- 4- formyl phenol3- methoxy- 4- hydroxybenzaldehydevanillic aldehydevanillaldehyde
121-33-5VANILLIN 100
4. FIRST-AID MEASURESIf breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop orpersist.
Inhalation
Take off immediately all contaminated clothing. Get medical attention if irritation develops andpersists. Wash skin thoroughly with soap and water for several minutes.
Skin contact
Remove contact lenses, if present and easy to do. Get medical attention if irritation develops andpersists. Promptly wash eyes with plenty of water while lifting the eye lids.
Eye contact
Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only ifthe person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept lowso that stomach vomit doesn't enter the lungs.
Ingestion
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Dusts may irritate the respiratory tract, skin and eyes.
Most importantsymptoms/effects, acute anddelayed
Not available.Indication of immediate medicalattention and special treatmentneeded
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Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. FIRE-FIGHTING MEASURESWater spray, fog, CO2, dry chemical, or alcohol resistant foam.Suitable extinguishing mediaDo not use a solid water stream as it may scatter and spread fire.Unsuitable extinguishing mediaExplosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, andin the presence of an ignition source is a potential dust explosion hazard. Fire may produceirritating, corrosive and/or toxic gases.
Specific hazards arising fromthe chemical
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protectiveclothing will only provide limited protection. Wear self-contained breathing apparatus with a fullfacepiece operated in the positive pressure demand mode when fighting fires.
Special protective equipmentand precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures andconsider the hazards of other involved materials. Move containers from fire area if you can do sowithout risk. Water runoff can cause environmental damage. Ventilate closed spaces beforeentering them. Keep run-off water out of sewers and water sources. Dike for water control.
Fire fightingequipment/instructions
Use water spray to cool unopened containers.Specific methodsStatic charges generated by emptying package in or near flammable vapor may cause flash fire.General fire hazards
6. ACCIDENTAL RELEASE MEASURESKeep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin orinhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unlesswearing appropriate protective clothing. Ventilate closed spaces before entering them.
Personal precautions, protectiveequipment and emergencyprocedures
Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Sweep upand place in a clearly labeled container for chemical waste. Wash contaminated area with water.Use only non-sparking tools. Avoid the generation of dusts during clean-up. This material and itscontainer must be disposed of as hazardous waste. Collect and dispose of spillage as indicated insection 13 of the SDS.
Never return spills in original containers for re-use.
Methods and materials forcontainment and cleaning up
Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid release to theenvironment. Retain and dispose of contaminated wash water. Contact local authorities in case ofspillage to drain/aquatic environment.
Environmental precautions
7. HANDLING AND STORAGETake precautionary measures against static discharges when there is a risk of dust explosion.Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensurethat dusts do not accumulate on surfaces. Dry powders can build static electricity charges whensubjected to the friction of transfer and mixing operations. Provide adequate precautions, such aselectrical grounding and bonding, or inert atmospheres. Assume that this material is capable ofproducing a dust explosion if ignited as a dust cloud.Do not handle or store near an open flame, heat or other sources of ignition. Take precautionarymeasures against static discharges. Avoid breathing vapor. Avoid breathing dust. Avoid contactwith eyes, skin, and clothing. Avoid prolonged exposure. Wash thoroughly after handling.
Precautions for safe handling
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Keep container closed. Handle containers with care. Open slowly in order to control possiblepressure release. Store in a cool, well-ventilated area.
Conditions for safe storage,including any incompatibilities
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational exposure limits
US. Workplace Environmental Exposure Level (WEEL) GuidesValueMaterial Type
TWA 10 mg/m3VANILLIN (CAS 121-33-5)No biological exposure limits noted for the ingredient(s).Biological limit valuesUse only appropriately classified electrical equipment and powered industrial trucks. It isrecommended that all dust control equipment such as local exhaust ventilation and materialtransport systems involved in handling of this product contain explosion relief vents or anexplosion suppression system or an oxygen-deficient environment. Ensure that dust-handlingsystems (such as exhaust ducts, dust collectors, vessels, and processing equipment) aredesigned in a manner to prevent the escape of dust into the work area (i.e., there is no leakagefrom the equipment). Use explosion-proof ventilation equipment to stay below exposure limits.
Appropriate engineering controls
Individual protection measures, such as personal protective equipmentWear safety glasses with side shields (or goggles).Eye/face protection
Skin protectionChemical resistant gloves.Hand protection
Not available.OtherDust mask.Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. Routinelywash work clothing and protective equipment to remove contaminants.
General hygiene considerations
9. PHYSICAL AND CHEMICAL PROPERTIESRefer to Spec SheetAppearancePowder\Crystal.Physical statePowder. Crystalline powder.FormRefer to Spec SheetColorCharacteristic.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point 176 - 177.8 °F (80 - 81 °C)
Initial boiling point and boilingrange
543.2 - 545 °F (284 - 285 °C) 101.325 kPa
Flash point > 200.0 °F (> 93.3 °C) Closed Cup
Evaporation rate Not available.Not available.Flammability (solid, gas)
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Upper/lower flammability or explosive limitsFlammability limit - lower(%)
Not available.
Flammability limit - upper(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.002 mm Hg at 25 °C
Vapor density 5.2
Relative density Not available.
Solubility(ies)Solubility (water) Insoluble
Partition coefficient(n-octanol/water)
1.37
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other informationDensity 1.06 g/cm3 estimated
Not explosive.Explosive properties
Flammability class Combustible IIIB estimated
Molecular formula C8-H8-O3
Molecular weight 152.15 g/molNot oxidizing.Oxidizing properties
10. STABILITY AND REACTIVITYThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityMaterial is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous
reactionsKeep away from heat, sparks and open flame. Avoid temperatures exceeding the flash point.Contact with incompatible materials. Minimize dust generation and accumulation.
Conditions to avoid
Strong oxidizing agents.Incompatible materialsNo hazardous decomposition products if stored and handled as indicated.Hazardous decomposition
products
11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure
Inhalation Irritating to respiratory system.
Skin contact Dust or powder may irritate the skin.
Eye contact Causes serious eye irritation.
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Ingestion Harmful if swallowed.
Symptoms related to thephysical, chemical andtoxicological characteristics
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredvision. Dusts may irritate the respiratory tract, skin and eyes.
Information on toxicological effects
Acute toxicity Harmful if swallowed.
Test ResultsProduct SpeciesVANILLIN (CAS 121-33-5)
LD50 RabbitDermalAcute
> 5010 mg/kg Remarks:Behavioral:Somnolence (generaldepressed activity). Behavioral:Food intake(animal). Gastrointestinal:Peritonitis.
* Estimates for product may be based on additional component data not shown.Eyes - rabbit - Irritating to eyes. - 72 hSkin corrosion/irritationCauses serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.
Maximisation Test - guinea pig - Directive 67/548/EEC, Annex V, B.6. - Does not cause skinsensitisation.
Skin sensitization
No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
US. National Toxicology Program (NTP) Report on CarcinogensNot listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -single exposure
Not classified.
Specific target organ toxicity -repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
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12. ECOLOGICAL INFORMATIONHarmful to aquatic life with long lasting effects.Ecotoxicity
Product Test ResultsSpeciesVANILLIN (CAS 121-33-5)
AquaticLC50Fish > 53 - < 61.3 mg/l, 96 hoursFathead minnow (Pimephales promelas)
123 mg/l, 96 hoursLeuciscus idus (Golden orfe)
* Estimates for product may be based on additional component data not shown.
EC50Other 1800 mg/l, 49 hoursActivated Sludge
Sturm test, OECD 301-B, (CO2)Results: Readily biodegradable77.6 %
Persistence and degradability
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)1.37
No data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSAL CONSIDERATIONSDo not discharge into drains, water courses or onto the ground. Do not allow this material to draininto sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical orused container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulationsNot established.Hazardous waste codeEmpty containers or liners may retain some product residues. This material and its container mustbe disposed of in a safe manner (see: Disposal instructions).
Waste from residues / unusedproducts
Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.
Contaminated packaging
14. TRANSPORT INFORMATIONADN
Not regulated as dangerous goods.ADR
Not regulated as dangerous goods.RID
Not regulated as dangerous goods.
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Print Date: 05-25-2017Page 8 of 10
DOT
Not regulated as dangerous goods.BULK
DOT
Not regulated as dangerous goods.NON-BULK
IATANot regulated as dangerous goods.
IMDGNot regulated as dangerous goods.
15. REGULATORY INFORMATIONThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.
US federal regulations
CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.
SARA 304 Emergency release notificationNot regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not available.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substanceNot listed.
YesSARA 311/312 Hazardouschemical
SARA 313 (TRI reporting)Not regulated.
Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
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Not regulated.Safe Drinking Water Act(SDWA)
International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION05-25-2017Issue date05-25-2017Revision date
Version # 03Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from theManufacturing, Processing, and Handling of Combustible Particulate Solids, for safe handling.
Further information
Health: 2Flammability: 1Physical hazard: 0
HMIS® ratings
501432 VANILLIN NATURALSAFETY DATA SHEET
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Vigon International, Inc. cannot anticipate all conditions under which this information and itsproduct, or the products of other manufacturers in combination with its product, may be used. It isthe user’s responsibility to ensure safe conditions for handling, storage and disposal of theproduct, and to assume liability for loss, injury, damage or expense due to improper use. Theinformation in the sheet was written based on the best knowledge and experience currentlyavailable. The above information relates only to this product and not to its use in combination withany other material or any particular process and is designed only as guidance for the safehandling, use, processing, storage, transportation, disposal, and should not be considered as aguarantee or quality specification. The above information is based on data provided by andcollected from recognized sources such as distributors, manufacturers, and technical groups andis considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It isthe responsibility of the user to review all safety information about this product and determine itssafety and suitability in their own processes and operations. Appropriate warnings and safehandling procedures should be provided to all handlers and users, taking into account the intendeduse and the specific conditions and factors relating to such use in accordance with all applicablelaws and regulations.
Disclaimer
This document has undergone significant changes and should be reviewed in its entirety.Revision information