Material Safety Data Sheet - unitedlubes.comunitedlubes.com/images/MSDS/Mineral Spirits msds.pdf ·...

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Material Safety Data SheetMSDS ID NO.:Revision date:

0247MAR01909/12/2005

Chemical Family:Formula:

Marathon Non-Exempt Mineral SpiritsMineralSpirits Non-Exempt; Non-Exempt Mineral Spirits; Regular MineralSpirits;Stoddard SolventHydrocarbonSolventMixture

Product name:Synonyms:

.....

Manufacturer:Marathon Petroleum Company LLC539 South Main StreetFindlay OH 45840

Other information:Emergency telephone number:

419-421-3070877-627-5463

Mineral Spirits is a complex mixture of predominantlyaliphatic hydrocarbons (paraffins, and cycloparaffins) having.. hydrocarbonchainlengthspredominantlyin the rangeof C9throughC12.

Product information

Component Information

Notes: The manufacturer has voluntarily elected to reflect exposure limits contained inOSHA's 1989 air contaminants standard in its MSDS's, even though certain of thoseexposure limits were vacated in 1992.

EMERGENCY OVERVIEW

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MSDS ID NO.: 0247MAR019 Product name: Marathon Non-Exempt MineralSpirits

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Name CAS Number Weight % ACGIH Exposure OSHA. Vacated Other:Limits: PELs -Time

Weiahted AveMarathon Non-Exempt Mineral Spirits 8052-41-3 100 -100 ppm TWA =100 ppm TWA

=525 maIm' TWA

Name CAS Number Weight % ACGIH Exposure OSHA -Vacated Other:Limits: PEls -Time

Weiahted AveParaffins Mixture 74-84

Cvcloparaffins Mixture 8-11Aromatic Hvdrocarbons Mixture 8-15

THIS PRODUCT IS A CLEAR, COLORLESS LIQUIDWITH A STRONG HYDROCARBONODOR. THIS PRODUCT ISCONSIDERED TO BE A COMBUSTIBLE LIQUID PER THE OSHA HAZARD COMMUNICATIONSTANDARD ANDSHOULD BE KEPT AWAY FROM HEAT, FLAMEAND SOURCES OF IGNITION. NEVER SIPHON THIS PRODUCTBY MOUTH. IF SWALLOWED,THIS PRODUCT MAY GET SUCKED INTO THE LUNGS (ASPIRATED) AND CAUSELUNG DAMAGE OR EVEN DEATH. PROLONGEDOR REPEATEDSKIN CONTACT CAN CAUSE DEFATTING ANDDRYING OF THE SKIN WHICH MAY PRODUCE SEVERE IRRITATION OR DERMATITIS.

OSHAWARNING LABEL:WARNING.

COMBUSTIBLE LIQUID.ASPIRATION (INADVERTENT SUCTION) OF LIQUID INTO THE LUNGS CAN PRODUCE CHEMICAL PNEUMONIA

OR EVEN DEATH.PRODUCES SKIN IRRITATION UPON PROLONGED OR REPEATED CONTACT.

CONSUMERWARNING LABEL:

A CONSUMERWARNING LABEL IS NOT APPLICABLE FOR THIS PRODUCT.

Ingestion:

Exposure to high vapor concentrations may produce headache, giddiness, vertigo,and anesthetic stupor.

Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.Aspiration (inadvertent suction) of liquid into the lungs must be avoided as evensmall quantities in the lungs can produce chemical pneumonitis, pulmonaryedema/hemorrhageand even death.

Inhalation:

Skin contact: Prolonged and repeated liquid contact can cause defatting and drying of the skin andcan lead to irritation and/or dermatitis.

Eye contact: Eye irritation may result from contact with the liquid or exposure to the vapor atconcentrations above the TLV.

Carcinogenic Evaluation:

Product information

Notes: The InternationalAgency for Researchon Cancer (IARC) has determined that thereis inadequate evidence for the carcinogenicity of aliphatic hydrocarbon solvents inhumans. Therefore, aliphatic hydrocarbon solvents are not classifiable as to theircarcinogenicity to humans (Group 3).

Component Information~

Inhalation:

Skin contact:

If affected, move personto fresh air. If breathing is difficult, administer oxygen. If notbreathing or if no heartbeat,give artificial respirationor cardiopulmonaryresuscitation (CPR). Immediatelycall a physician. If symptoms or irritation occur withany exposure, call a physician.

Wash with soap and large amounts of water. Remove contaminated clothing. Ifsymptoms or irritation occur, call a physician. ;:"""'j"'--'~


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Name IARC NTP ACGIH . OSHA. SelectCarcinoaens: Carcinoaens: Carcinoaens: Carcinoaens:

Marathon Non-ExemptMineral Spirits NE8052-41-3

Eye contact:

If swallowed, do not induce vomiting and do not give liquids. Immediatelycall aphysician.

Flush eyes with large amounts of tepid water for at least 15 minutes..If symptomsorirritation occur, call a physician.

Ingestion:

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Medical conditions aggravated by Skin contact could aggravate an existing skin disorder or dermatitis condition.exposure:

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For small fires, Class B fire extinguishing media such asCO2, dry chemical, foam (AFFF/ATC) or water spray can beused. For large fires, water spray, fog or foam (AFFT/ATC)can be used. Fire fighting should be attempted only by thosewho are adequatelytrained and equipped with properprotective equipment.This product has been determined to be a combustible liquidper the OSHA Hazard Communication Standard and shouldbe handled accordingly. For additional fire relatedinformation, see NFPA 30 or the North American EmergencyResponse Guide 128.Avoid using straight water streams. Water spray and foam(AFFF/ATC) must be applied carefully to avoid frothing andfrom as far a distance as possible. Avoid excessivewaterspray application. Keep surrounding area cool with waterspray from a distance and prevent further ignition ofcombustible material. Keep run-off water out of sewers andwater sources.

Suitable extinguishing media:

Specific hazards:

Special protective equipment for firefighters:

'Flash point:Autoignition temperature:Flammable limits in air -lower (%):Flammable limits in air -upper (%):

NFPArating:Health: 2Flammability:2Reactivity:1Other: -

105 F (Min)450-500 F0.96.0

HMIS classification:Health: 2Flammability: 2Reactivity: 1Special: *See Section 8 for guidance in selection ofpersonal protectiveequipment.

Personal precautions: Keep public away. Isolate and evacuate area. Shut off source if safe to do so.Eliminate all ignition sources. Advise authorities and National Response Center (800-424-8802) if substance has entered a watercourse or sewer. Notify local health andpollution control agencies, if appropriate. Contain liquid with sand or soil. Recoverand return free product to proper containers. Use suitable absorbent materialssuchas vermiculite, sand, or clay to clean up residual liquids.

Handling:


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Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate groundingand bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilatedarea. Do not expose to heat, open flames, strong oxidizers or other sources of ignition. Do not cut, drill, grind or weld onempty containers since they may contain explosive residues.

Hydrocarbons are basically non-conductorsof electricity and can becomeelectrostaticallycharged during mixing, filtering,pumping at high flow rates or loadingand transfer operations. If this charge reachesa sufficiently high level, sparks canform that may ignite the vapors of flammable liquids. Sudden release of hot organic chemical vapors or mists fromprocess equipment operating under elevated temperature and pressure, or sudden ingress of air into vacuum equipmentmay result in ignitions without the presenceof obvious ignition sources. Nozzle spouts must be kept in contact with thecontainers or tank during the entire filling operation.

.Never siphon this product by mouth.Avoid repeated and prolonged skin contact. Exercise good personal hygieneincluding removal of soiled clothing and prompt washing with soap and water.

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PERSONAL PROTECTIVEEQUIPMENT

Engineering measures: Local or general exhaust required in an enclosed area or when there is inadequateventilation.

Respiratory protection: Approved organic vapor chemical cartridgeor supplied air respirators should be wornwhen significant vapors are generated. Observe respirator protection factor criteriacited in ANSI Z88.2. Self-containedbreathing apparatus should be used for firefighting.

Neoprene, nitrile, polyvinyl alcohol (PVA), polyvinyl chloride and polyurethane glovesto prevent skin contact.

Skin and body protection:

Eye protection:

Hygiene measures:

No special eye protection is normally required. Where splashing is possible, wearsafety glasses with side shields.

No special protective clothing is normally required. Select protective clothingdepending on industrial operations. Use mechanicalventilation equipment that isexplosion-proof.

Appearance:Physical state (Solid/Liquid/Gas):Substance type (Pure/Mixture):Color:Odor:Molecular weight:pH:Boiling point/range (5-95%):Melting point/range:Decomposition temperature:Specific gravity:Density:Bulk density:Vapor density:Vapor pressure:Evaporation rate:Solubility:Solubility in other solvents:Partition coefficient (n-octanol/water):VOCcontent(%):MSDS ID NO.: 0247MAR019

Colorless LiquidLiquidMixtureColorless

Slight Hydrocarbon130-140Neutral310-400 FNot determined.

Not applicable.0.77-0.80

6.4-6.7Ibs/galNo data available.4-6Not determined.No data available.Not determinedNo data available.4.2-6.7No data available.-

Product name: Marathon Non-ExemptMineralSpirits

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- --. -- - - -- -- --- - - - - -- -.. --..-

Viscosity: No data available.

..:.

" : '~~..stability: The material is stable at 70 F, 760 mm pressure.

Polymerization:

Hazardous decomposition products:

Will not occur.

Materials to avoid:

Combustion produces carbon monoxide,aldehydes,aromatic and other hydrocarbons.

Strong oxidizers such as nitrates, chlorates, peroxides.

Conditions to avoid: Sources of heat or ignition.

Acute toxicity:

CAS Number8052-41-3

Some components of this product, have been shown to produce a species specific, sex hormonal dependent kidneylesion in male rats from repeated oral or inhalationexposure. Subsequent research has shown that the kidney damagedevelops via the formation of a alpha-21J-globulin,a mechanism unique to the male rat. Humans do not form alpha-21J-globulin, therefore, the kidney effects resultingfrom this mechanism are not relevant in humans. .

Ninety day and two year inhalation studies of mineral spirits (stoddard solvent) were conducted in mice and rats at~oncentrationsof 138, 275, 550, 1,100and 2,200 mg/m3.In the 90 day studies, no significant toxicity was observed in ratsexcept for nasel irritation at the highest dose and the previously noted effects in the male rat kidney. No significanttoxicity was observed in mice except for slight effects in the spleen of female mice. No evidence of carcinogenic activitywas observed in male mice or female rats chronically exposed to stoddard solvent. There was equivocal evidence thatstoddard solvent produced benign liver tumors in female mice (an effect associated with increased body weight) andsome evidence that stoddard solvent produced adrenal tumors in male rats. This latter effect is believed to be asecondary response to the kidney disease mediated by alpha-21J-microglobulin.

Ecotoxicity effects: The 96 hour LC50 of a water accomadated fraction (WAF) of mineral spirits is >1,000mg/I in rainbow trout.

Cleanup Considerations: This product as produced is not specifically listed as an EPARCRA hazardous waste according to federal regulations (40CFR 261). However, when discarded or disposed of, it maymeet the criteria of an "characteristic" hazardous waste. Thismaterial could become a hazardous waste if mixed or

contaminated with a hazardous waste or other substance(s).It is the responsibility of the user to determine if disposalmaterial is hazardous according to federal, state and localregulations.


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49 CFR 172.101:

DOT:Transport Information: This material when transported via US commerce would be regulated by DOT

Regulations.

Proper shipping name:UN/ldentification No:Hazard Class:Packing group:DOTreportable quantity (Ibs):

Petroleum Distillates,N.O.S. (Naphtha)UN 12683IIINotapplicable.

TDG (Canada):Proper shipping name:UN/Identification No:Hazard Class:Packing group:Regulated substances:

Petroleum Distillates,N.O.S. (Naphtha)UN 12683IIINotapplicable.

Federal Regulatory Information:

US TSCA Chemical Inventory Section 8(b): This product and/or its components are listed on the TSCAChemical Inventory.

This product has been evaluated and determined to behazardous as defined in OSHA's Hazard CommunicationStandard.

OSHA Hazard Communication Standard:

EPA Superfund Amendment & Reauthorization Act (SARA):

SARA Section 302: This product contains the following component(s)that have been listed on EPA'sExtremely Hazardous Substance (EHS) List:

SARA Section 304: This product contains the following component(s) identified either as an EHS or aCERCLA Hazardous substance which in case of a spill or release may be subject toSARAreportingrequirements: ~

SARA Section 311/312: The following EPA hazard categories apply to this product:

Acute Health HazardFire Hazard

SARA Section 313: This product contains the following component(s)that may be subject to reporting on,,;;";'the Toxic Release Inventory (TRI) From R: '-':'r" i

MSDS ID NO.: 0247MAR019 Product name: Marathon Non-ExemptMineralSpirits

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Name CERCLAISARA-Section302ExtremelyHazardousSubstances and TPQsParaffins NA

Cycloparaffins NAAromaticHydrocarbons NA

Name CERCLAISARA-Hazardous Substances and their Reportable QuantitiesParaffins NA

Cvcloparaffins NAAromaticHvdrocarbons NA

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'il':~;\State and Community Right-To-Know Regulations:The following component(s) of this material are identified on the regulatory lists below:

Paraffins

Louisiana Right-To-Know:California Proposition 65:New Jersey Right-To-Know:Pennsylvania Right-To-Know:Massachusetts Right-To Know:Florida substance List:

Rhode Island Right-To-Know:Michigan critical materials register liSt:Massachusetts Extraordinarily HazardousSubstances:

California - Regulated Carcinogens:Pennsylvania RTK-Special HazardousSubstances:New Jersey -Special Hazardous Substances:New Jersey - EnvironmentalHazardousSubstances List:Illinois- ,ToxicAirContaminantsNew York - Reporting of Releases Part 597 -Listof Hazardous Substances:

CycloparaffinsLouisiana Right-To-Know:CaliforniaProposition 65:New Jersey Right-To-Know:Pennsylvania Right-To-Know:Massachusetts Right-ToKnow:Floridasubstance List:Rhode Island Right-To-Know:Michigancriticalmaterials register list:Massachusetts ExtraordinarilyHazardousSubstances:California - Regulated Carcinogens:Pennsylvania RTK - Special HazardousSubstances:New Jersey - Special Hazardous Substances:New Jersey - Environmental HazardousSubstances List:Illinois - Toxic Air ContaminantsNew York - Reporting of Releases Part 597 -Listof Hazardous Substances:

AromaticHydrocarbonsLouisiana Right-To-Know:CaliforniaProposition 65:New Jersey Right-To-Know:Pennsylvania Right-To-Know:Massachusetts Right-ToKnow:Floridasubstance List:Rhode Island Right-To-Know:Michigancriticalmaterialsregisterlist:

MSDSID NO.: 0247MAR019

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Product name: Marathon Non-Exempt MineralSpirits

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Name CERCLAISARA 313 Emission reportina:Paraffins None

CvcloDaraffins NoneAromatic Hvdrocarbons - None

Massachusetts Extraordinarily HazardousSubstances:

California - Regulated Carcinogens:Pennsylvania RTK - Special HazardousSubstances:

New Jersey - Special Hazardous Substances:New Jersey - Environmental HazardousSubstances List:Illinois - Toxic Air Contaminants

New York - Reporting of Releases Part 597 -List of Hazardous Substances:

Canadian Regulatory Information:

Not Listed

Not ListedNot Listed --',

1Not ListedNot Listed


Canada DSUNDSL Inventory: This product and/or its components are listed either on the Domestic Substances List(DSL) or the Non Domestic Substance List (NDSL).

Additional Information: No data available.

Craig M. Parker Manager, Toxicology and Product SafetyPrepared by:

The information and recommendationscontained herein are based upon tests believed to be reliable. However,Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of thisinformation constitute a warranty, whether expressedor implied, as to the safety of the goods, the merchantability of thegoods, or the fitness of the goods for a particular purpose. Adjustment to conformto actual conditions of usage maybe

-required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lostprofits arising from the use of these data. No warranty against infringementof any patent, copyright or trademark is madeor implied.

End of Safety Data Sheet

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MSDS ID NO.: 0247MAR019

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Product name: Marathon Non-Exempt MineralSpirits

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