All Squeaky Cleaning, LLC Material Safety Data Sheets (MSDS)allsqueakycleaning.com/MSDS.pdf ·...

All Squeaky Cleaning, LLCMaterial Safety Data Sheets

(MSDS)

Last Updated: 11MAR13

#20430 Page 1 of 7 Issue date 09-Jul-2010

Severe 4Serious 3Moderate 2Slight 1Minimal 0

MATERIAL SAFETY DATA SHEET

.

1. Product and Company Identificationspace

Product Name LYSOL® Brand (Kills 99.9% of Viruses & Bacteria) Multi-Surface Cleaner CompleteClean (Pourable), All Scents

space

UPC CODES Refer to Section 16 space

CAS # Mixturespace

Product use Cleanerspace

Distributed by Reckitt BenckiserMorris Corporate Center IV 399 Interpace Parkway P.O. Box 225 Parsippany, NJ 07054-0225 In Case of Emergency: 1-800-228-4722 Transportation Emergencies: 24 Hour Number:

North America: CHEMTREC: 1-800-424-9300 Outside North America: 1-703-527-3887

space

LEGENDHMIS/NFPA

Health / 2

0Flammability 0

2 0Physical Hazard 0

Personal Protection B .

2. Hazards Identificationspace

Emergency overview This product is regulated by the US EPA as a disinfectant.

PRECAUTIONARY STATEMENTS: Hazards to humans and domestic animals.

CAUTION Causes moderate eye irritation. Avoid contact with eyes, skin or clothing. Washthoroughly with soap and water after handling. If you have sensitive skin wear rubber gloves.

space

Potential short term health effectsRoutes of exposure

KEEP OUT OF REACH OF CHILDREN.

Eye, Skin contact, Inhalation, Ingestion. space

space

space

space

space

Eyes Causes moderate eye irritation. Avoid eye contact.Skin May be irritating to sensitive skin or in the case or prolonged contact with the liquid.

Not expected to be a skin sensitizer. Inhalation None expected during normal conditions of use.Ingestion Health injuries are not known or expected under normal use.

Target organs Skin. Eyes.space

Chronic effects The finished product is not expected to have chronic health effects.space

Signs and symptoms Symptoms may include redness, edema, drying, defatting and cracking of the skin.Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.

.

3. Composition / Information on Ingredientsspace

Ingredient(s) CAS # Percent

Alcohols, C12-16, ethoxylated

Alkyl (50%C14, 40%C12, 10%C16) dimethyl benzyl ammonium chlorides

Ethanol

68551-12-2

68424-85-1

64-17-5

2.5 - 10

1 - 2.5

0.1 - 1

UPC 036241756109


.

4. First Aid Measuresspace

First aid proceduresEye contact

space

Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.

space

space

space

Skin contact Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.

Inhalation Move to fresh air.Ingestion Rinse mouth with water. Contact a physician or poison control center if symptoms

develop. NEVER give an unconscious person anything to ingest. Notes to physician Symptoms may be delayed. Treat patient symptomatically.

space

General advice Avoid contact with eyes and skin. Keep out of reach of children. Immediate medical attention is required. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. If you feel unwell, seek medical advice (show the label where possible).

.

5. Fire Fighting Measuresspace

Flammable properties Not flammable by OSHA criteria.space

Extinguishing media

space

Suitable extinguishing media Treat for surrounding material.

space

Unsuitable extinguishing media Not availableProtection of firefighters

Specific hazards arising from the chemical

Not available space

space

Protective equipment for firefighters

Firefighters should wear full protective clothing including self contained breathing apparatus.

Hazardous combustion products May include and are not limited to: Oxides of carbon. Oxides of nitrogen.space

Explosion dataSensitivity to mechanical impact Not available

space

Sensitivity to static discharge Not available .

6. Accidental Release Measuresspace

Personal precautions Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak.

space

Methods for containment Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas.

space

Methods for cleaning up Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use.

.

7. Handling and Storagespace

Handling CAUTIONCauses moderate eye irritation. Avoid contact with eyes. If you have sensitive skin wear rubber gloves. Use good industrial hygiene practices in handling this material.

space

Storage Store in original container out of reach of small children. Keep securely closed in a cool, well ventilated area. Do not reuse empty container. Rinse and discard or recycle.

It is a violation of Federal law to use this product in a manner inconsistent with its labeling.

UPC 036241756109


.

8. Exposure Controls / Personal Protectionspace

Exposure limitsIngredient(s)


Exposure Limits

ACGIH-TLVNot established OSHA-PELNot established

Alkyl (50%C14, 40%C12, 10%C16) dimethyl benzyl ACGIH-TLVammonium chlorides Not established

OSHA-PELNot established

Ethanol ACGIH-TLV TWA: 1000 ppm STEL: 1000 ppm OSHA-PELTWA: 1000 ppm

space

Engineering controls Provide adequate ventilation. General ventilation normally adequate.space

Personal protective equipment

space

Eye / face protection Safety glasses recommended. Emergency responders should wear full eye and face protection.

space

space

space

Hand protection Impervious gloves. Confirm with reputable supplier first.Emergency responders should wear impermeable gloves.

Skin and body protection As required by employer code.Emergency responders should wear impermeable clothing and footwear when responding to a situation where contact with the liquid is possible.

Respiratory protection No special requirements under normal use conditions.Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid inhalation of vapours generated by this product during a spill or other clean-up operations.

General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.When using do not eat or drink. Washing with soap and water after use is recommended as good hygienic practice to prevent possible eye irritation from hand contact.

.

9. Physical and Chemical Propertiesspace

Appearance Clear.space

Color Variablespace

Form Liquidspace

Odor Characteristicspace

Odor threshold Not availablespace

Physical state Liquidspace

pH 8.5 - 9.5space

Freezing point Not availablespace

Pour point Not availablespace

Boiling point Not availablespace

Flash point > 199.94 °F (> 93.3 °C) Tagliabuespace

Evaporation rate Not availablespace

Flammability limits in air, lower, %by volume

space

Flammability limits in air, upper, %by volume

space

Not available

Not available

Vapor pressure Not availablespace

Vapor density Not availablespace

Specific gravity 1.19 (Water = 1)

UPC 036241756109


space

Octanol/water coefficient Not availablespace

Solubility (H2O) Completespace

Auto-ignition temperature Not available .

10. Stability and Reactivityspace

Chemical stability Stable under recommended storage conditions.space

Conditions to avoid DO NOT MIX WITH BLEACH or use in conjunction with other household products.Exposure to moisture. Excessive heat.

space

Incompatible materials Acids. Oxidizers.space

Hazardous decomposition products May include and are not limited to: Oxides of carbon. Oxides of nitrogen.space

Possibility of hazardous reactions Hazardous polymerization does not occur. .

11. Toxicological Informationspace

Component analysis - LC50Ingredient(s)



LC50

Not available

Not available

Ethanol 31623 ppm rat space

Component analysis - Oral LD50Ingredient(s)



LD50

1380 mg/kg rat

426 mg/kg rat

Ethanol 3450 mg/kg mouse; 7060 mg/kg rat space

Effects of acute exposure

space

Eye Causes moderate eye irritation. Avoid eye contact.

space

space

space

Skin May be irritating to sensitive skin or in the case or prolonged contact with the liquid.Not expected to be a skin sensitizer.

Inhalation None expected during normal conditions of use.Ingestion Health injuries are not known or expected under normal use.

Sensitization The finished product is not expected to have chronic health effects.space

Chronic effects The finished product is not expected to have chronic health effects.space

Carcinogenicity The finished product is not expected to have chronic health effects.ACGIH - Threshold Limit Values - CarcinogensEthanol 64-17-5 A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans IARC - Group 1 (Carcinogenic to Humans)Ethanol 64-17-5 Monograph 96 [in preparation] (in alcoholic beverages)

space

Mutagenicity The finished product is not expected to have chronic health effects.space

Reproductive effects The finished product is not expected to have chronic health effects.space

Teratogenicity The finished product is not expected to have chronic health effects.space

Synergistic Materials Not available .

12. Ecological Informationspace

Ecotoxicity See belowEcotoxicity - Freshwater Fish Species DataEthanol 64-17-5 96 Hr LC50 Oncorhynchus mykiss: 12.0-16.0 ml/L [static]; 96 Hr LC50 Pimephales

promelas: >100 mg/L [static]; 96 Hr LC50 Pimephales promelas: 13400-15100 mg/L [flow-through]

space

Ecotoxicity - Water Flea DataEthanol 64-17-5 48 Hr LC50 Daphnia magna: 9268 - 14221 mg/L; 24 Hr EC50 Daphnia magna: 10800

mg/L; 48 Hr EC50 Daphnia magna: 2 mg/L [Static] Environmental effects Not available

space

Aquatic toxicity Not available

UPC 036241756109


space

Persistence / degradability Not availablespace

Bioaccumulation / accumulation Not availablespace

Partition coefficient Not availablespace

Mobility in environmental media Not availablespace

Chemical fate information Not available .

13. Disposal Considerationsspace

Waste codes Not availablespace

Disposal instructions Dispose in accordance with all applicable regulations.space

Waste from residues / unused products

space

Not available

Contaminated packaging Not available .

14. Transport Informationspace

UN/ID N.o. Not applicable

U.S. Department of Transportation (DOT): Classification: Not regulated Proper shipping name Not applicable

U.S. DOT Hazard Class Not applicable

Subsidiary Risk Not applicable

Packing group Not applicable

DOT RQ (lbs) Not applicable ERG NO Not applicable

space

Transportation of Dangerous Goods (TDG - Canada): Classification: Not regulated Proper shipping name Not applicable

Status Not applicable Packing group Not applicable

space

IMDG (Marine Transport): Classification: Not regulatedProper shipping name Not applicable

Class Not applicable

Subsidiary Risk Not applicable


IMDG Page Not applicable

Marine pollutant Not applicable

EMS Not applicable

MFAG Not applicable

Maximum Quantity Not applicable

UPC 036241756109


spaceIATA/ICAO (Air): Classification: Not regulated Proper shipping name Not applicable

Class Not applicable

Subsidiary Risk: Not applicable


Maximum Quantity Not applicable

.

15. Regulatory Informationspace

US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.

Product Registration: Registered with EPA, EPA Reg. No. 777-89space

Occupational Safety and Health Administration (OSHA)

space

29 CFR 1910.1200 hazardous chemical

Yes

space

Superfund Amendments and Reauthorization Act of 1986 (SARA)

space

space

Hazard categories

Section 302 extremely hazardous substance

Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No No

space

Section 311 hazardous chemical YesClean Air Act (CAA) Not available

space

Clean Water Act (CWA) Not availablespace

State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm.

U.S. - Massachusetts - Right To Know ListEthanol 64-17-5 Teratogen U.S. - Minnesota - Hazardous Substance ListEthanol 64-17-5 Present U.S. - New Jersey - Right to Know Hazardous Substance ListEthanol 64-17-5 sn 0844 U.S. - Pennsylvania - RTK (Right to Know) ListEthanol 64-17-5 Present U.S. - Rhode Island - Hazardous Substance ListEthanol 64-17-5 Toxic; Flammable

space

Inventory statusCountry(s) or region Inventory name On inventory (yes/no)*United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory YesA "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

UPC 036241756109


.

16. Other Informationspace

Disclaimer This product should only be used as directed on the label and for the purpose intended.To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

space

Further information 19200-81153-8 - LYSOL® Brand (Kills 99.9% of Viruses & Bacteria) Multi-SurfaceCleaner Complete Clean (Pourable), All Scents - 40 oz. - Island Berries™ - 0170877

19200-78631-7 - LYSOL® Brand (Kills 99.9% of Viruses & Bacteria) Multi-Surface Cleaner Complete Clean (Pourable), All Scents - 40 oz. -Lavender Breeze® - 0170875

19200-78626-3 - LYSOL® Brand (Kills 99.9% of Viruses & Bacteria) Multi-Surface Cleaner Complete Clean (Pourable), All Scents - 40 oz. - Lemon Breeze® - 0150144

19200-78625-6 - LYSOL® Brand (Kills 99.9% of Viruses & Bacteria) Multi-Surface Cleaner Complete Clean (Pourable), All Scents - 40 oz. - Orange Breeze® - 0170876

space

19200-78630-0 - LYSOL® Brand (Kills 99.9% of Viruses & Bacteria) Multi-Surface Cleaner Complete Clean (Pourable), All Scents - 40 oz. - Pacific Fresh® - 0170770

Issue date 09-Jul-2010space

Effective date 31-May-2010space

Prepared by Reckitt Benckiser Regulatory Department 800-333-3899space

Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document.

UPC 036241756109


Murphy® Oil Soap Liquid 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ACUTE HEALTH. . . 1 FIRE. . . . . . . . . . . . . 0 REACTIVITY. . . . . . 0 PRODUCT NAME: Murphy® Oil Soap Liquid LABEL CODE: 01101 (16 oz), 01106 (32 oz), 01103 (1 gal) CAS NUMBER: Not applicable - product is a mixture GENERAL USE: A specially formulated, mild, multi-purpose cleaner.

COLGATE-PALMOLIVE COMPANY Institutional Products Division 191 East Hanover Avenue Morristown, NJ 07960-3151

For consumer information: Call (800) 432-8226 EMERGENCY TELEPHONE NUMBER: For emergency involving spill, leak, fire, exposure or accident, call CHEMTREC: (800) 424-9300, day or night.

THE PITTSBURGH POISON CENTER HAS BEEN PROVIDED SPECIFIC INFORMATION FOR USE IN MEDICAL EMERGENCIES INVOLVING THIS PRODUCT: CALL COLLECT: (412) 692-5596.

2. COMPOSITION/INFORMATION ON INGREDIENTS OSHA REGULATED COMPONENTS (present at a concentration > or = 1%): Component CAS # % PEL TLV Potassium 1310-58-3 1-5 None 2 mg/m3 Hydroxide

The following components, present at a concentration > or = 0.1%, are listed as carcinogens or potential carcinogens by either the National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC) or OSHA: Component CAS # % PEL TLV None - not applicable

3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS: EYE CONTACT: Direct exposure to large amounts may cause eye irritation, but no permanent eye injury is expected. SKIN CONTACT: No skin irritation is expected with normal use. However, skin irritation may occur with prolonged or excessive contact. INGESTION: Repeated overexposure may be harmful. INHALATION: No adverse effects expected with normal use. 4. FIRST AID MEASURES EYE CONTACT: Flush eye with large amounts of warm water for 15 minutes. Get medical attention if irritation persists. SKIN CONTACT: Flush skin with large amounts of water for 15 minutes. Get medical attention if irritation occurs. INGESTION: Drink 2-4 ounces of a clear liquid. Get medical attention. INHALATION: Not applicable. 5. FIRE FIGHTING MEASURES Flash Point (Method): Not established. Extinguishing Media: Water spray, CO2, All-purpose dry chemical SPECIAL FIRE FIGHTING PROCEDURES: Self-contained breathing apparatus and protective clothing should be worn when fighting chemical fires. 6. ACCIDENTAL RELEASE MEASURES Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of water. 7. HANDLING AND STORAGE: Store in a cool dry place (40 – 125 degrees F). 8. EXPOSURE CONTROLS/PERSONAL PROTECTION GENERAL CONTROLS: Avoid contact with skin and eyes. PROTECTIVE CLOTHING: Under normal conditions of use, no special precautions or control measures are required. In processing and packaging operations where repeated skin or eye contact are possible, the use of safety goggles and rubber gloves is recommended. SPECIAL PRECAUTIONS: Keep out of the reach of children. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance and odor: Amber, viscous liquid. Citrus odor. Specific Gravity: Approximately 1.0

pH: 11.0 ± 0.6 (1% Solution)

HMIS HAZARD RATING Least=0 Slight=1 Moderate=2 High=3 Extreme= 4

10. STABILITY AND REACTIVITY GENERAL: This product is stable. Hazardous polymerization will not occur. INCOMPATIBLE MATERIALS: Avoid contact with strong oxidizing and reducing agents, acids, alkalis, organic peroxides and easily ignitable materials. Avoid prolonged contact with reactive metals (e.g. aluminum, brass, bronze, etc.). HAZARDOUS DECOMPOSITION: May produce irritating or poisonous gases upon thermal decomposition. 11. TOXICOLOGICAL INFORMATION This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the MSDS. 12. ECOLOGICAL INFORMATION: Not Available. 13. DISPOSAL CONSIDERATIONS Small quantities generated by consumer use may be disposed of in a sanitary sewer with large quantities of water. Empty containers generated by consumer use may be disposed of as conventional waste. Any disposal practice must be in compliance with local, state, and federal laws and regulations (contact local or state government agency for specific rules). Do not dump into sewers, any body of water, or onto the ground. 14. TRANSPORTATION This product is not regulated as a DOT hazardous material. 15. REGULATORY INFORMATION RCRA (40 CFR 261, Subpart D): Not Applicable. CLEAN WATER ACT: Contains potassium hydroxide which is a Section 311 material. CLEAN AIR ACT: Contains ethanol which is a Section 111 material. SARA: Sections 301-304 (Threshold planning quantity – TPQ) 40 CFR 355: The TPQ for this product is 10,000 lbs. Acute health hazard: Irritant Section 313 (Toxic chemical release reporting) 40 CFR 372: The following chemicals must be reported under SARA 313: Not Applicable. CERCLA: Section 102 (Reportable Quantity – RQ) 40 CFR 302: The RQ for this product to the environment is 32,258 lbs. based on the presence of potassium hydroxide (3.1%). Releases greater than or equal to 32,258 lbs. must be reported to The National Response Center (NRC) immediately: 800-424-8802. TSCA Section 8(b) INVENTORY STATUS: All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory.

NEW JERSEY RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST: This product contains the following components subject to reporting requirements: Potassium hydroxide, ethanol PENNSYLVANIA HAZARDOUS SUBSTANCE LIST: This product contains the following components subject to reporting requirements: Potassium hydroxide MASSACHUSETTS SUBSTANCE LIST: This product contains the following components subject to reporting requirements: Potassium hydroxide, ethanol CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): This product contains the following components subject to reporting requirements: None CANADA: Workplace Hazardous Materials Information System (WHMIS)-listed material. This product contains the following components subject to reporting requirements: Potassium hydroxide

16. OTHER INFORMATION Effective Date: June 29, 2000 Supersedes MSDS dated April 28, 1997 MSDS Status: Revised sections 1, 8, 11 The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate-Palmolive makes no representation, guarantee or warranty, expressed or implied, as to the accuracy, reliability or completeness of the information and assumes no responsibility for injury, damage or loss resulting from the use of the material.

of 2 Personal Care Products, Inc.

MATERIAL SAFETY DATA SHEET PREPARED IN COMPLIANCE WITH OSHA'S HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200

PRODUCT IDENTITY (AS USED ON LABEL AND LIST)

POWERHOUSE OVEN CLEANER

SECTION I – SUPPLIER INFORMATION

PERSONAL CARE PRODUCTS, INC. 32500 TELEGRAPH ROAD, SUITE 202 BINGHAM FARMS, MI 48025-2463

EMERGENCY TELEPHONE NUMBER: 800-535-5053 INFORMATION TELEPHONE NUMBER: 248-258-1555 DATE PREPARED: DECEMBER 15, 2006

SECTION II - HAZARD INGREDIENTS/IDENTITY INFORMATION

HAZARDOUS COMPONENTS (CHEMICAL IDENTITY/COMMON NAME) CAS NO. ACGIH TLV

OTHER SPECIFICATIONS %(OPTIONAL)

BUTANE 106-97-8 N/A N/A 0-4

PROPANE 74-98-6 N/A N/A 0-4

TRIETHANOLAMINE 102-71-6 N/A N/A 0-1

POLYOXYETHYLENE NONYL PHENYL ETHER 26027-38-3 N/A N/A 0-1

ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 N/A N/A 0-2

SODIUM SILICATE 1344-09-8 N/A N/A 0-8

MAGNESIUM ALUMINUM SILICATE 1337-76-4 N/A N/A 0-3

SODIUM HYDROXIDE 1310-73-2 N/A N/A 0-15

SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS

BOILING POINT: N/A SPECIFIC GRAVITY (H2O = 1): N/A

VAPOR PRESSURE (MM HG.): N/A MELTING POINT: N/A

VAPOR DENSITY (AIR = 1): N/A EVAPORATION RATE (ETHER=1): N/A

SOLUBILITY IN WATER: MISCIBLE PH: 12

APPEARANCE AND ODOR: FOAM AEROSOL, WITH A SLIGHT ODOR

SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (METHOD USED): FLAMMABLE LIMITS (LEL): FLAMMABLE LIMITS (UEL):

N/A N/A N/A

EXTINGUISHING MEDIA: FOAM, CARBON DIOXIDE, DRY CHEMICAL POWDER. USE WATER SPRAY OR FOG NOZZLE TO KEEP CYLINDER COOL. MOVE CYLINDER AWAY FROM FIRE IF THERE IS NO RISK.

SPECIAL FIRE FIGHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. DO NOT EXTINGUIS BURNING GAS IF FLOW CANNOT BE SHUT OFF IMMEDIATLEY. USE WATER SPRAY OR FOG NOZZLE TO KEEP CYLINDER COOL. MOVE CYLINDER AWAY FROM FIRE IF THERE IS NO RISK.

UNUSUAL FIRE AND EXPLOSION HAZARDS: VAPOR MAY TARVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND FLASH BACK. CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.

SECTION V - REACTIVITY DATA

STABILITY (STABLE/UNSTABLE): STABLE UNDER NORMAL TEMPERATURES AND PRESSURES

CONDITIONS TO AVOID: N/A

MATERIALS TO AVOID: OXYGEN, PRESSED AIR, HALOGEN AND OXIDIZING AGENTS.

HAZARDOUS DECOMPOSITION OR BYPRODUCTS: N/A

HAZARDOUS POLYMERIZATION (MAY OCCUR/WILL NOT OCCUR): N/A

of 2 Personal Care Products, Inc.

SECTION VI - HEALTH HAZARD DATA

ROUTE(S) OF ENTRY: SKIN INGESTION INHALATION EYES N/A

HEALTH HAZARDS (ACUTE & CHRONIC):

EYES:

INHALATION: MAY IRRITATE THE RESPIRATORY TRACT.

INGESTION:

SKIN

CARCINOGENS: NTP IARC OSHA NONE N/A

SIGNS AND SYMPTOMS OF EXPOSURE:

EYES: CAN CAUSE IRRITATION, EXPERIENCED AS DISCOMFORT OR PAIN

INGESTION: MAY CAUSE CASUE HEADACHE, DIZZINESS, INCOORDINATION, NAUSEA, VOMITING, AND GENERAL WEAKNESS

INHALATION: REMOVE TO FRESH AIR. ADMINISTER OXYGEN IF NEEDED. APPLY ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. GET MEDICAL ATTENTION.

SKIN: PROLONGED CONTACT MAY CAUSE SKIN IRRITATION.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

EMERGENCY AND FIRST AID PROCEDURES:

EYES: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IMEMDIATELY.

INHALATION: REMOVER TO FRESH AIR

INGESTION: TOXIC BY INGESTINO. SEEK MEDICAL ATTENTION IMMEDIATELY. CALL POISON CONTROL CENTER OR DOCTOR FOR TREATMENT ADVICE.

SKIN: IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. IF IRRITATION PERSISTS, CALL A PHYSICIAN.

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: EVACUATE AREA AND KEEP PERSONNEL UPWIND. SHUT OFF ALL SOURCES OF IGNITION. SHUT OFF LEAK IF THERE IS NO RISK. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPELTE.

WASTE DISPOSAL METHOD: CONTACT A LICENSED PROFESSINAL WASTE DISPOSAL SERVICE TO DISPOSE OF THIS MATERIAL. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: PREVET THIS CONTIANER FROM CMING IN CONTACT WITH WATER FOR A PROLONGED PERIOD OF TIME. ALWAYS KEEP CONTIANER IN A COOL, DRY PLACE. STORE AWAY FROM HEAT AND DIRECT SUNLIGHT. AVOID FREEZING.

OTHER PRECAUTIONS: N/A

SECTION VIII - CONTROL MEASURES

RESPIRATORY PROTECTION: WEAR SELF-CONTAINED BREATHING APPARATUS.

VENTILATION: LOCAL EXHAUST MECHANICAL (GENERAL) OTHER N/A

PROTECTIVE GLOVES: HEAVY RUBBER GLOVES

EYE PROTECTION : N/A

OTHER PROTECTIVE CLOTHING: RUBBER BOOTS

WORK/HYGIENIC PRACTICES: N/A

THE INFORMATION CONTAINED IN THIS FORM IS BASED ON DATA FROM SOURCES CONSIDERED TECHNICALLY RELIABLE AND HAS BEEN PREPARED IN GOOD FAITH IN ACCORDANCE WITH THE AVAILABLE MATERIAL. IT IS PROVIDED AS A SERVICE TO PERSONS USING THE PRODUCT BY CONDITION OF USE AND HANDLING MAY INVOLVE OTHER AND ADDITIONAL CONSIDERATIONS BEYOND THE CONTROL OF PERSONAL CARE PRODUCTS, INC. NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE AND PERSONAL CARE PRODUCTS, INC. WILL NOT BE LIABLE FOR ANY DAMAGES, LOSSES, INJURIES OR CONSEQUENTIAL DAMAGES THAT MAY RESULT FROM THE USE OR RELIANCE ON ANY INFORMATION CONTAINED IN THIS FORM. HMIS HEALTH 1 FLAMMABILITY 2 REACTIVITY 2

Material Safety Data Sheet Identity (Trade Name As Used on Label)

PINE GLO PRODUCTS, Inc.

Manufacturer MSDS Number*

P.O. Box 429

Address CAS Number

Rolesville, NC 27571 11/18/10

Date Prepared

919 - 556 - 7787

Phone Number (For Information) Prepared By*

919 – 556-7787

Emergency Phone Number Telex*

Health : 1

Flammability : 1

Reactivity : 0 Lonza Formulation DC-103

*************************************************************************************

MATERIAL DATE ISSUED DOT HAZARD CLASSIFICATION

Lonza Formulation DC-103 08/01/07 - Rev. Non-hazardous

DOT SHIPPING NAME

CAS NO. See Section I SUPERCEDES Not regulated

10/20/92 DOT LABEL None

FORMULA Mixture

CHEMICAL NAME Mixture

****************************** I - INGREDIENTS *************************************

APPROXIMATE

WEIGHT % TWA/TLV

Di-N-alkyl(C8-10)dimethylammonium chloride

(CAS No. 68424-95-3) 0.05 None established

Linear primary and/or secondary alcohol ethoxylates

and/or nonyl phenol ethoxylate 0.04 None established

N-Alkyl(C12-16)dimethylbenzylammonium chloride


Tetrasodium ethylenediamine tetraacetate


Sodium metasilicate (CAS No. 6834-92-0) 0.01 None established

Water (CAS No. 7732-18-5) 99.8 None established

Fragrance

Dye

********************** II - PHYSICAL AND CHEMICAL PROPERTIES ***********************

APPEARANCE Clear liquid (color depends

upon optional dye added) pH 11.0

VISCOSITY Not known ODOR Depends upon fragrance added

BOILING POINT Not known MELTING OR FREEZING POINT Not known

VAPOR DENSITY (Air=1) Not known VAPOR PRESSURE (mm Hg) Not known

PERCENT VOLATILE (by weight) 99.8 SOLUBILITY IN WATER Soluble

EVAPORATION RATE (Butyl Acetate=1) Not SPECIFIC GRAVITY (WATER = 1) 1.00 @ 25oC

known

*********************** III - FIRE AND EXPLOSION INFORMATION ***********************

FLASH POINT >200oF AUTO IGNITION TEMPERATURE Not known

MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE: 800-424-9300 (Chemtrec) LOWER EXPLOSION LIMIT (%) Not applicable UPPER EXPLOSION LIMIT (%) Not applicable

EXTINGUISHING MEDIA FOAM X ALCOHOL FOAM CO2 X

DRY CHEMICAL X WATER X OTHER

SPECIAL FIRE FIGHTING PROCEDURES:

Must wear NIOSH/MSHA approved self-contained breathing apparatus and protective

clothing.

*********************** III - FIRE AND EXPLOSION INFORMATION (continued) ***********

UNUSUAL FIRE AND EXPLOSION HAZARDS:

Products of combustion are toxic.

Pine Glo Antibacterial Kitchen & Bathroom Cleaner & Disinfectant

************************ IV - HEALTH EFFECTS INFORMATION ***************************

PRIMARY ROUTES OF ENTRY - SKIN CONTACT X EYE CONTACT X

INHALATION INGESTION

EFFECTS OF OVEREXPOSURE

Based on the available animal toxicity information, it is anticipated that this

material will cause mild or no skin or eye irritation upon direct or prolonged

contact. No human overexposure data is available for this material.

OVEREXPOSURE MAY AGGRAVATE EXISTING CONDITIONS:

No effects indicated.

EMERGENCY AND FIRST AID PROCEDURES:

Eyes: Flush eyes with plenty of water for several minutes. Seek medical attention if

irritation develops.

Skin: Wash affected areas with plenty of water, and soap if available, for several

minutes. Seek medical attention if irritation develops.

Ingestion: If swallowed, give 3-4 glasses of milk (if unavailable, give water), but

DO NOT induce vomiting. If vomiting does occur, give fluids again. Get medical

attention to determine whether vomiting or evacuation of stomach is necessary. Do

not give anything by mouth to an unconscious or convulsing person.

Inhalation: Remove from area to fresh air. Seek medical attention if respiratory

irritation develops or if breathing becomes difficult.

CHEMICALS LISTED AS CARCINOGEN BY: (YES OR NO)

NATIONAL TOXICOLOGY PROGRAM - No

I.A.R.C. MONOGRAPHS - No

OSHA - No

*************************** V - REACTIVITY INFORMATION *****************************

STABILITY: STABLE X CONDITIONS TO AVOID

UNSTABLE None known

HAZARDOUS DECOMPOSITION PRODUCTS

Thermal decomposition may produce toxic vapors/fumes of amines and other organic

materials, and oxides of carbon and nitrogen.

HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID

MAY WILL NOT X None known

OCCUR OCCUR

INCOMPATIBILITY (MATERIALS TO AVOID)

WATER OTHER None known

************************ VI - SPILL AND DISPOSAL INFORMATION ***********************

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED

Caution! Floors may become slippery. Wear appropriate protective equipment and

NIOSH/MSHA approved respirator where mist or vapors of unknown concentrations may be

generated (self-contained breathing apparatus preferred).

Dike and contain spill with inert material (sand, earth, etc.) and transfer the

liquid and solid separately to containers for recovery or disposal. Keep spill out

of sewers and open bodies of water.

WASTE DISPOSAL METHODS

Dispose of in compliance with all Federal, state and local laws and regulations.

Incineration is the preferred method.

CONTAINER DISPOSAL

Triple rinse (or equivalent). Then offer for recycling or reconditioning, or

puncture and dispose of in a sanitary landfill, or incineration, or, if allowed by

state and local authorities, by burning. If burned, stay out of smoke.

*********************** VII - PERSONAL PROTECTION INFORMATION **********************

VENTILATION TYPE

In processes where mists or vapors may be generated, proper ventilation must be

provided in accordance with good ventilation practices.

RESPIRATORY PROTECTION

The information provided herein is compiled form internal reports and data form professional publications. IT IS FURNISHED WITHOUT WARRANTY

OF ANY KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in

the development and implementation of safety precautions and procedures.

Where mist or vapors are generated by the process, a NIOSH/MSHA jointly approved

respirator is advised in the absence of proper environmental controls.

PROTECTIVE GLOVES

Rubber or neoprene, when needed, to prevent skin contact.

EYE PROTECTION

Wear chemical splash goggles where there is a potential for eye contact. Use safety

glasses with side shields under normal use conditions.

OTHER PROTECTIVE EQUIPMENT

Eye wash; safety shower; protective clothing (long sleeves, coveralls or other, as

appropriate), when needed, to prevent skin contact.

*************************** VIII - STORAGE AND HANDLING ****************************

PRECAUTIONS FOR STORAGE AND HANDLING:

Store at temperatures below 140oF. Keep containers closed until used.

Do not contaminate drinking water, food or feed by storage or disposal.

**************************** IX - TOXICITY INFORMATION *****************************

The information below is for Lonza Formulation S-21 diluted 1:64 (2 oz./gal), which

is equivalent to Lonza Formulation DC-103.

- eye irritation (rabbit): non-irritant (primary irritation index = 0.0)

- skin irritation (rabbit): non-irritant (primary irritation index = 0.0)

******************* X - MISCELLANEOUS AND REGULATORY INFORMATION ********************

FEDERAL LEVEL REGULATIONS:

This is an EPA registered pesticide (EPA Registration No. 6836-152).

TOXIC SUBSTANCES CONTROL ACT (TSCA INVENTORY) STATUS:

Found on U.S. EPA TSCA inventory.

CERCLA (Comprehensive Environmental Response, Compensation and Liability Act of

1980 requires notification of the National Response Center

(Telephone 1 -800-424-8802) in the event of a release of quantities of the

following hazardous materials contained in this product, if the release is

equal to or greater than the Reportable Quantities (RQs) listed in

40 CFR 302.4:

Typical Maximum

Chemical Name CAS Number Concentration

None known

SARA Title III, Sections 302/304 (Superfund Amendments and Reauthorization act of

1986) - This act requires emergency planning, including agency notification, for

possible release of the following components of this material, based upon the

Threshhold Planning Quantities (TPQs) and release Reportable Quantities (RQs)

listed for the Components in 40 CFR 355:

Typical Maximum


None known

SARA Title III Sections 311/312 - This act requires reporting under the Community

Right-to-Know provisions due to the inclusion of the following components of this

material in one or more of the five hazard categories listed in 40 CFR 370:

Hazard *)

Chemical Name CAS Number Categories

None known

*) The five hazard categories are as follows: F=FIRE HAZARD; S= SUDDEN RELEASE OF

PRESSURE; R=REACTIVE; A=IMMEDIATE (ACUTE) HEALTH HAZARD; C=DELAYED (CHRONIC)

HEALTH HAZARD

******************* X - MISCELLANEOUS AND REGULATORY INFORMATION (continued) ********

FEDERAL LEVEL REGULATIONS (continued):

SARA Title 313 - This act requires submission of annual reports of releases of the

following components of this material if the threshold reporting quantities,

as listed in 40 CFR 372, are met or exceeded:

Typical Maximum


None known

STATE RIGHT-TO-KNOW REGULATIONS:

CALIFORNIA PROPOSITION 65 - Components present in this material which the State of

California has found to cause cancer, birth defects or other reproductive harm

are as follows:

Typical Maximum


Acetaldehyde 75-07-0 4 ppb

Benzene 71-43-2 100 ppb

Benzyl chloride 100-44-7 200 ppb

1,4-Dioxane 123-91-1 4 ppb

Ethylene oxide 75-21-8 <1 ppb

N-Nitrosodimethylamine 62-75-9 1 ppb

Propylene oxide 75-56-9 20 ppb

Toluene 108-88-3 100 ppb

MASSACHUSETTS Right-to-Know - The following components of this material are included

in the Massachussets Substance List and are present at or above reportable

levels:

Typical Maximum


None known

MICHIGAN Critical Materials - The following components of this material are included

in the Michigan Critical Materials List:

Chemical Name CAS Number

None known

NEW JERSEY Right-to-Know - The following components of this material are included in

the New Jersey Hazardous Substance List and are present at or above reportable

levels:

Typical Maximum


None known

******************* X - MISCELLANEOUS AND REGULATORY INFORMATION (continued) ********

STATE RIGHT-TO-KNOW REGULATIONS (continued):

PENNSYLVANIA Right-to-Know - The following components of this material are included

in the Pennsynvania Hazardous Substance List and are present at or above

reportable levels:

Typical Maximum


None known

The Clorox Company 1221 Broadway Oakland, CA 94612 Tel. (510) 271-7000

Material Safety Data Sheet

I Product: TILEX INSTANT MILDEW REMOVER

Description: CLEAR, FAINT YELLOW LIQUID WITH CHARACTERISTIC BLEACH ODOR

Other Designations Distributor Emergency Telephone Nos.

Tilex Tilex Instant Mildew Stain Remover

Clorox Sales Company

1221 Broadway Oakland, CA 94612

For Medical Emergencies call: (800) 446-1014

For Transportation Emergencies Chemtrac (800) 424-9300

II Health Hazard Data III Hazardous Ingredients Moderate eye irritant. Mild to moderate skin irritant. Occasional clinical reports suggest a low potential for skin sensitization upon exaggerated exposure to sodium hypochlorite if skin damage (e.g., irritation) occurs during exposure. Routine clinical tests conducted on intact skin with this product found no sensitization in the test subjects. Exposure to vapor or mist may irritate eyes, nose, throat, lungs. Harmful if swallowed. May cause nausea and vomiting if swallowed. The following medical conditions may be aggravated by exposure to high concentrations of vapor or mist: heart conditions or chronic respiratory problems such as asthma, emphysema, chronic bronchitis or obstructive lung disease. Under normal consumer-use conditions, the likelihood of any adverse health effects is low. FIRST AID: EYE CONTACT: Remove any contact lenses, and flush eyes thoroughly with water for 15 minutes. If irritation persists, call a physician. SKIN CONTACT: Remove contaminated clothing; wash affected skin with water. IF BREATHING IS AFFECTED: Get fresh air immediately. IF SWALLOWED: Drink a glass of water. Call a physician.

Ingredient Concentration Worker Exposure Limit Sodium hypochlorite 1-5% none established CAS #7681-52-9 Sodium hydroxide 0.5-2% 2 mg/m3, Ceiling-TLV CAS #1310-73-2 2 mg/m3, Ceiling Federal OSHA PEL TLV = Threshold Limit Value Source: ACGIH 1992-1993 PEL = Permissible Exposure Limit Source: OSHA None of the ingredients in this product are on the IARC, OSHA or NTP carcinogen lists.

IV Special Protection and Precautions V Transportation and Regulatory Data Hygienic Practices: Do not get in eyes or on clothing. Avoid prolonged or repeated skin contact. Avoid prolonged breathing of vapor. Use only in well-ventilated areas. Personal Protection: Wear safety glasses. For sensitive skin or repeated/prolonged use, wear gloves. Ventilation: Use general ventilation to minimize exposure to gases or aerosols associated with this product.

U.S. DOT Hazard Class: Not restricted U.S. DOT Proper Shipping Name: n/a EPA CERCLA/SARA TITLE III: Chemical Name CERCLA/304 311/212 312 RQ(lbs.) Sodium hypochlorite 100 No No Sodium hydroxide 1000 Yes No

VI Spill Procedures/Waste Disposal VII Reactivity Data Spill Procedures: Absorb and containerize. Wash down residual to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. Waste Disposal: Dispose of in accordance with all applicable federal, state, and local regulations.

Stable under normal use and storage conditions. Strong oxidizing agent. Reacts with other household chemicals such as toilet bowl cleaners, rust removers, acids or ammonia-containing products to produce hazardous gases, such as chlorine and other chlorinated compounds. Prolonged contact with metal or old porcelain may cause pitting or discoloration.

VIII Fire and Explosion Data IX Physical Data Flashpoint: greater than 200 °F Fire Extinguishing Agents: Water spray, dry chemical or carbon dioxide (CO2). Special Fire-Fighting Procedures: None Unusual Fire and Explosion Hazards: None

Appearance: ...........................................................Clear, faint yellow liquid Odor: ...................................................................Characteristic bleach odor pH: .............................................................................................. 12.4 - 12.8 Solubility in water: ..........................................................Completely soluble Specific gravity (water = 1): ..................................................... 1.04 at 25°C

1963, 1991 THE CLOROX COMPANY DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 10/00

Awesome Products Inc.

6370 Altura Blvd.

Buena Park, CA 90620

1(800)482-2875


SECTION 1 — CHEMICAL PRODUCT & COMPANY IDENTIFICATION

22 oz Awesome Orange All Purpose Cleaner 12/cs

32 oz Awesome All Purpose Cleaner Orange Oxygen 12/cs

40 oz Awesome Strike Orange 12/cs

64 oz Awesome Orange All Purpose Degreaser 6/cs

64 oz Awesome Strike Orange 6/cs

Company:

Awesome Products Inc

6370 Altura Blvd. Buena Park, CA 90620

Date MSDS Prepared

10/22/11

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients Percent

Range CAS Number

Orange Oil Blend < 0.01-1.5 8008-57-9 &111-76-2

Ethoxylated Alcohol < 0.5-2.0 9036-19-5

Disodium Salt < 0.5-1.5 6834-92-0

Tetra Sodium EDTA

Hydroxy Sodium

< 0.5-1.5

< 0.5-0.8

64-02-8

1310-73-2

SECTION 3 — COMPOSITION/INFORMATION ON INGREDIENTS

SECTION 4 — FIRST AID MEASURES

Skin Contact

If adverse effect occurs, rinse skin with water.

Eye Contact

Flush with plenty of water. After 5 minutes of flushing, remove contact lenses, if present. Continue

flushing for at least 10 more minutes. If irritation persists seek medical attention.

Inhalation

If adverse effect occurs, move to fresh air.

Ingestion

Drink plenty of water to dilute.

SECTION 5 — FIRE FIGHTING MEASURES

This formula is stable, non-flammable, and will not burn. No special procedures necessary.

Flammability: Non-flammable

Flash Point: Non-flammable

Suitable Extinguishing Media: Use dry chemical, CO2, water spray.

Extinguishing Media to Avoid: High volume jet water.

Special Exposure Hazards: In event of fire created carbon oxides, oxides of phosphorus may be formed.

Special Protective Equipment: Wear positive self-contained breathing apparatus; wear full protective clothing.

Hazard Rating: Hazard: 4-Very High 1-Health 3-High 0-Flammability 2-Moderate 0- Reactivity 1-Slight 0-Special 0-Insignificant

Potential Health Effects Eye Contact: Mildly irritating. Skin Contact: No adverse effects expected under typical use conditions. Prolonged exposure may cause dryness. Chemically sensitive individuals may experience mild irritation. Ingestion: May cause stomach or intestinal irritation if swallowed. Inhalation: No adverse effects expected under typical use conditions. Adequate ventilation should be present for prolonged usage in small enclosed areas.

SECTION 6 — ACCIDENTAL RELEASE MEASURES

Personal Precautions: See section 8- personal protection. Environmental Precautions: Do not allow into open waterways and ground water system. Method for Clean Up: Dilute with water and rinse into sanitary sewer system or soak up with inert absorbent material

SECTION 7 — HANDLING AND STORAGE

Handling: Keep container tightly closed. Ensure adequate ventilation. Keep out of reach of children.

Storage: Keep in cool dry area.

SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION

Exposure Limit Value: OSHA PEL

Orange Oil Blend TWA 50 ppm (240 mg/m3)

ACGIH TLV

20 ppm (97 mg/m3)

Trisodium Phosphate Exposure Controls: Eye Contact: Use protective glasses if splashing or spray-back is likely. Respiratory: Use in well ventilated areas. Skin Contact: Prolonged exposure or dermal sensitive individuals should use .protective gloves.

5 mg/m3

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES

Appearance:

Various Odor:

Orange

VOC composite Partial Pressure: TBD

VOC <2

Specific Gravity:

1.010+0.010 Density:

8.3 lb./gal; Vapor Pressure (mmHg):

18 mmHg @20°C;25.5mmHg @27°C

Water Solubility:

100%

Boiling Point (° C)

~210 F° (98 °C)

Freezing Point (° C)

~32 F (0 °C)

pH

10.5+0.5

SECTION 10 — STABILITY AND REACTIVITY

Stability: Stable Materials to Avoid: None known Hazardous Decomposition Products: Normal products of combustion –CO, CO2; Oxides of Phosphorous may occur.

SECTION 11 — TOXICOLOGICAL INFORMATION

Acute Toxicity: Oral LD50 (rat) >5g/kg body weight Dermal LD50 (rabbit) >5g/kg body weight Toxicity calculated from ingredients using OECD SERIES ON TESTING AND ASSESMENT Number 33 Carcinogens: No ingredients are listed by OSHA, IARC, or NTP as known or suspected carcinogens.

SECTION 12 — ECOLOGICAL INFORMATION

Hazard to wild mammals: Low, based on toxicology profile

Hazard to avian species: Low, based on toxicology profile

Hazard to aquatic organisms: Low, based on toxicology profile

SECTION 13 — DISPOSAL CONSIDERATIONS

Appropriate Method for Disposal:

Unused Product: *Dilute with water to use concentration and dispose by sanitary sewer.

Used Product: *This product can enter into clarifiers and oil/water separators. Used product may

be hazardous on the cleaning application and resulting contaminants.

Empty Containers: *Triple-rinse with water and offer for recycling if available in your area.

Otherwise, dispose as non-hazardous waste.

*Dispose of used or unused product, and empty containers in accordance with the local, State, Provincial,

and Federal regulations for your location. Never dispose of used degreasing into lakes, streams, and

open bodies of water or storm drains.

SECTION 14 — TRANSPORT INFORMATION

U.S. Department of Transportation (DOT) / Canadian TDG: Not Regulated

IMO/IDMG: Not classified as Dangerous

ICAO/IATA: Not classified as Dangerous

ADR/RID: Not classified as Dangerous

U.N. Number: Not Required Proper Shipping Name: Detergent Solution

Hazard Class: Non-Hazardous Marine Pollutant: No

SECTION 15 — REGULATORY INFORMATION

All components are listed on: EINECS, TSCA, DSL and AICS Inventory.

No components listed under: Clean Air Act Section 112; Clean Water Act 307 & 311

SARA Title lll Orange Oil Blend is subject to the reporting requirements of Section 313 of Title lll of the Superfund

Amendments and Reauthorization Act of 1986 as Category N230- Certain Glycol Ethers.

RCRA Status: Not a hazardous waste CERCLA Status: No components listed

State Right to Know Lists:

Orange Oil Blend Illinois, Massachusetts, New Jersey, Pennsylvania, Rhode Island

WHMIS Classification- Category D, subcategory 2B, eye irritant

Toxic Substances List- Schedule 1- CEPA

Name (Canadian Environmental Protection Act) NPRI Inventory

Orange Oil Blend Yes No

This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the information required by Canada’s Controlled Products Regulation.

Material Safety Data Sheet U. S. Department of Labor May be used to comply with OSHA's Occupational Safety and Health Administration Hazard Communication Standard (Non-Mandatory Form)

29 CFR 1910.1200. Standard must be Form Approved OMB No.

1218-0072 consulted for specific requirements.

IDENTITY (As Used on Label and List) NOTE: Blank spaces are not permitted. If any item is not applicable, or

Bab-O Cleanser

no information is available, the space must be marked to indicate that.

SECTION I Manufacturer's Name Emergency Telephone Number

Fitzpatrick Bros., Inc. (262) 947-3500 X 617

Address (Number, Street, City, State and ZIP Code) Telephone Number for Information

(262) 947-3500 X 617 Date Prepared

625 North Sacramento Boulevard 9/18/2003 Signature of Preparer (optional)

Chicago, Illinois 60612

SECTION II - Hazardous Ingredients/Identity Information Hazardous Components (Specify Chemical Identity: Common Name[s]) OSHA PEL ACGIH TLV Other Limits Recommended % (optional) THIS PRODUCT CONTAINS: Calcium Carbonate (CAS# 1317-65-3)

Sodium Carbonate (CAS# 497-19-8)

Sodium Dodecylbenzene Sulfonate (CAS# 25155-30-0)

These basic materials have been identified as eye, skin, mucous membrane irritants.

SECTION III - Physical/Chemical Characteristics Boiling Point Specific Gravity (H2O = 1)

N/A N/A Vapor Pressure (mm Hg.) Melting Point

N/A N/A Vapor Density (AIR = 1) Evaporation Rate (Butyl Acetate = 1)

N/A N/A Solubility in Water

Partially soluble in water Appearance and Odor

White powder - odor

SECTION IV - Fire and Explosion Hazard Data Flash Point (Method Used) Flammable Limits LEL UEL

SECTION V - Reactivity Data Stability Unstable Stable Conditions to Avoid

X Do not mix with ammonia or other household chemicals Incompatability (Materials to Avoid)

Hazardous Decomposition or Byproducts

Hazardous May Occur Will Not Occur Conditions to Avoid Polymerization

X

SECTION VI - Health Hazard Data Routes of Entry: Inhalation? Skin? Ingestion?

Yes No No Health Hazards (Acute and Chronic)

This material is identified as an irritant to eyes and the respiratory tract.

Scouring powder is not irritating to the skin and is harmful if swallowed.

Carcinogenicity: NTP? IARC Monographs? OSHA Regulated?

Non-carcinogen Signs and Symptoms of Exposure

Eye and mucous membrane irritation

Medical Conditions Generally Aggravated by Exposure

Avoid contact with eyes. Avoid breathing dust. Emergency and First Aid Procedures

In case of contact with eyes, wash with plenty of water for at least 15 minutes.

Get medical attention if excessive inhalation occurs. Remove victim to fresh air.

SECTION VII - Precautions for Safe Handling and Use

N/A N/A N/A N/A Extinguishing Media

Not a fire or explosive hazard Special Fire Fighting Procedures

None Unusual Fire and Explosion Hazards

None

(Reproduce locally) Page 1 OSHA 174, Sept. 1985

Steps to be Taken in Case Material is Released or Spilled

Normal clean-up procedures Waste Disposal Method

Conform to state, federal and local regulations

Precautions to be Taken in Handling and Storing

Store in cool, dry, ventilated area Other Precautions

SECTION VIII - Control Measures Respiratory Protection (Specify Type)

If dusty, wear mask Ventilation Local Exhaust Special

Natural Mechanical (General) Other

Protective Gloves Eye Protection

If needed Wear goggles, if needed

Other Protective Clothing or Equipment

Optional Work/Hygienic Practices

Page 2

SAFETY DATA SHEET

PAGE 1 OF 4

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: Bab-0 Liquid Soft Cleanser with Bleach

MANUFACTURER: Fitzpatrick Bros., Inc. 309 Radio Road Quincy, IL 62305

EMERGENCY PHONE:

800-233-8064 or 262-947-3500 X 617

CHEMICAL NAME: Liquid cleaner with bleach

PRODUCT USE: Household cleanser

SECTION 2: HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW: A thick oqaque cream with a slight chlorine odor. Can irritate or burn the eyes. Irritating to the skin.

POTENTIAL HEALTH EFFECTS

EYES: Can irritate the eyes. Burns can occur in the abscence of prompt first aid.

SKIN: Can irritate or burn the skin.

INGESTIONS: Can cause irritation and stomach distress.

INHALTION: May cause irritation to the respiratory tract.

CHRONIC HAZARDS: Crystalline silica impurity when inhaled above safe exposure limits can cause respiratory system injury and potentially cancer.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

Dermatitis

CARCINOGENICITY

Ingredient Name OSHA ACGIH NTP IARC

Crystalline Silica

--- Suspect human carcinogen

Known carcinogen Human carcinogen

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENT NAME CAS NO. %WT

Calcium Carbonate 1317-65-3 20 - 40 Crystalline Silica, quartz (impurity) 14808-60-7 0.1 – 1.0 Lauralmethylamine oxide 1643-20-5 1 – 5 Sodium Hydroxide 1310-73-2 0.5 – 1.5 Sodium Chlorite 7758-19-2 0.5 – 1.5 Water 7732-18-5 40 – 70

SECTION 4: FIRST AID MEASURES

EYES: Wash with plenty of water for at least 15 minutes. If wearing contact lenses, remove first. If irritation persists, get medical attention.

SKIN: Wash with plenty of water. If irritation persists, get medical attention.

INGESTION: If conscious, drink several glasses of water. Do not induce vomiting. Consult a physiciam or poison control center.

INHALTION: Remove victim to fresh air. Get medical attention if excessive inhalation occurs.

SECTION 5: FIRE-FIGHTING MEASURES

FLASH POINT: Not flammable

FLASH POINT METHOD: Not applicable

SAFETY DATA SHEET

PAGE 2 OF 4

AUTOIGNITION TEMPERATURE: Not flammable

EXTINGUISHING MEDIA: Use any standard agent appropriate for the surrounding fire.

SPECIAL FIRE FIGHTING PROCEDURES:

Wear self contained breathing apparatus.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

None

HAZARDOUS DECOMPOSITION PRODUCTS:

Traces of carbon monoxide and carbon dioxide are potential thermal decomposition materials.

SECTION 6: ACCIDENTAL RELEASE MEASURES

ACCIDENTAL RELEASE MEASURES: Wear proper personal protective equipment. Absorb with rags or other means and place into container for disposal..

SECTION 7: HANDLING AND STORAGE

HANDLING AND STORAGE: Avoid Contact with eyes. Store in cool, dry ventilated area. Do not breathe mists from cleaner.

OTHER PRECAUTIONS: None indicated

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: Use local exhaust ventilation when handling liquid product in large quantities.

VENTILATION : Not normally required.

RESPIRATORY PROTECTION: A NIOSH approved dust or mistrespirator should be worn in areas where product mists are encountered.

EYE PROTECTION: Wear safety glasses or googles,

SKIN PROTECTION: For sensitive skin or prolonged use, wear work gloves.

OTHER PROTECTIVE CLOTHING OR EQUIPMENT:

A source of running water in the work area is advisable for first aid purposes.

EXPOSURE GUIDELINES:

Ingredient Name OSHA ACGIH

Calcium Carbonate 15 mg/m3 Total Dust (TWA)

5 mg/m3 Respirable Dust (TWA)

None established

Crystalline Silica, quartz (impurity) (10 mg/m3)/(%Si02 + 2) Respirable

dust (TWA) 30 mg/m

3)/(%Si02 + 2) Total dust

(TWA)

0.05 mg/m3 Respirable dust (TWA)

Sodium hydroxide 2 mg/m3 (TWA) 2 mg/m

3 (ceiling)

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Thick opaque cream

ODOR: Slight chlorine odor.

PHYSICAL STATE: Cream like liquid

pH (10% aq.): 12 ± 1.5

BOILING POINT Not determined

MELTING POINT: Not determined

FREEZING POINT: Not determined

VAPOR PRESSURE (mmHg): Not determined

VAPOR DENSITY (AIR = 1): Not determined

SPECIFIC GRAVITY (H2O = 1) 1.3 ± 0.2

EVAPORATION RATE: Not determined

SAFETY DATA SHEET

PAGE 3 OF 4

VOLATILE ORGANIC COMPOUNDS (VOC):

< 2%

VISCOSITY: Not determined

SOLUBILITY IN WATER: Emulsifiable in wqter

PERCENT SOLIDS BY WEIGHT: ~ 30 – 35 %

PERCENT VOLATILE: ~ 65 – 70 %

SECTION 10: STABILITY AND REACTIVITY

STABILITY: Stable under anticipated storage and use conditions.

CONDITIONS TO AVOID (STABILITY): Do not mix with ammonia or other house chemicals as this releases toxic gases.

INCOMPATIBILITY (MATERIAL TO AVOID):

None anticipated

HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:

None anticipated

HAZARDOUS POLYMERIZATION: Will not occur

SECTION 11: TOXICOLOGICAL INFORMATION

Acute Not tested as a mixture. Oral toxicity estimated to be low and not toxic under consumer regulations.

Chronic Crystalline silica impurity can cause decreased pulmonary function and/or lung cancer when inhaled above established safe limits over a prolonged perioid of time.

SECTION 12: ECOLOGICAL INFORMATION

ECOLOGICAL INFORMATION: Data not available.

SECTION 13: DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: Conform to state, federal and local regulations.

RCRA HAZARD CLASS: Not a RCRA Hazardous waste if discarded.

The information listed in section 13 is for the product as shipped.

SECTION 14: TRANSPORT INFORMATION

U.S. DOT HAZARD CLASS: Not regulated in surface transporation

PROPER SHIPPING NAME: Bab-0 Liquid Soft Cleanser with bleach (non-hazardous goods)

SECTION 15: REGULATORY INFORMATION

TOXIC SUBSTANCE CONTROL ACT (TSCA):

All ingredients are listed on the TSCA inventory.

SARA TITLE III (CERCLA): No RQs or TPQs

311/312 HAZARD CATEGORIES: Immediate, Delayed

Ingedient Name RQ TPQ SARA 313 Reportable Ingredient

Calcium Carbonate None None No Crystalline Silica, quartz (impurity) None None No Lauralmethylamine oxide None None No Sodium hydroxide 1000 None No Sodium chlorite None None No

SAFETY DATA SHEET

PAGE 4 OF 4

CALIFONRIA PROPOSITION 65: This product contains impurity known to the State of California to cause cancer (crystalline silica).

WHMIS CLASSIFICATION (CANADA): Class D2A, D2B This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

CANADIAN CHEMICAL INVENTORY Ingredients listed on Domestic Substances List (DSL)

SECTION 16: OTHER INFORMATION

NFPA HAZARD CLASSIFICATION: Health: 2 Flammability: 0 Instability: 0 Other: Not Applicable

HMIS HAZARD CLASSIFICATION: Health: 2* Flammability: 0 Physical Hazard: 0

CURRENT ISSUE DATE: 04/20/2010

PREVISOUS ISSUE DATE: 02/24/2010

CHANGES FROM PREVIOUS ISSUE: Reformated to ANSI Z129.1-2004 format and updated text throughtout SDS

DISCLAIMER: The information contained on this Safety Data Sheet is believed to be reliable and acuurate, but is provided without warranty regarding its accuracy. Users must

determine safe conditions for use and assume liability for any loss, injury, demage or

expense resulting from use of this product.


SECTION1 – PRODUCT IDENTIFICATION

Identity: Miracle Cleaning Eraser Brands: Hazard Rating: 1 Health: 0 4 = Extreme Flammability: 1 3 = High Reactivity: 0 2 = Moderate 1 = Slight

SECTION II – COMPOSITION AND INGREDIENTS

Ingredients/Chemical Name: Formaldehyde-Melamine-Sodium Bisulfite Copolymer Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200., and/or WHMIS under HPA:

SECTION III – HAZARDS IDENTIFICATION

Health Hazards (Acute and Chronic): This product is considered to be non-toxic Ingestion: Blockage of the gastrointestinal tract may occur if swallowed Eye Contact: N/A Skin: N/A Inhalation: N/A Signs and Symptoms of Exposure: Ingestion: May cause irritation and/or blockage of the gastrointestinal track. Eye Contact: Dust from foam may cause mechanical irritation. Skin: Dust from foam may cause mechanical irritation. Inhalation: Dust from foam may cause irritation of the respiratory track.

SECTION IV – FIRST AID INFORMATION

Emergency and First Aid Procedures: Ingestion: If the sponge is ingested, contact a physician or veterinarian immediately.

Intestinal blockage may be life threatening to some household pets Eye Contact: In case of eye irritation, flush thoroughly with water for 15 minutes. If

irritation persists, seek medical advice. Skin: In case of skin irritation, flush affected area thoroughly with water and apply

a cold compress. If irritation persists, seek medical advice. Inhalation: If respiratory irritation occurs, move from the site of exposure to an area with

fresh air. If irritation persists, seek medical advice. Other: Consumer product packages have a caution statement: keep out of reach of children and to avoid accidental ingestion.


SECTION V – FIRE FIGHTING INFORMATION Flash Point: 580 C/1076 F Explosive Limits: LEL: Method Used: UEL: Extinguishing Media: Regular dry chemical, carbondioxide, water, regular foam. Large fires: Use regular foam of flood with fine water spray. Special Fire Fighting Procedures: Unusual Fire Hazards: Dust/air mixture may explode Stability Unstable: Conditions to Avoid: Stable: Incompatibility (Materials to Avoid):

SECTION VI – ACCEDENTAL RELEASE MEASURES Personal Precautions: Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. Steps To Be Taken in Case Material is Released or Spilled: Collect spilled material in appropriate container for disposal. Keep out of water supplies and sewers. Keep unnecessary people away, isolate hazard are and deny entry.

SECTION VII – HANDING AND STORAGE Precautions To Be Taken in Handling and Storing: Store and handle in accordance with all current regulations and standards. Store in a cool, dry place. Store in a well-ventillated area. Store with bases. Keep from incompatible substances. Use methods to minimize dust. Other Precautions:

SECTION VIII – EXPOSURE CONTROLS, PERSONAL PROTECTION This Section Only Applies To The Product When Used In An Industrial Setting.

Respiratory Protection (Specify Type): Under conditions of frequent use or heavy exposure, respiratory protection may be needed. (Any chemical cartridge respirator with organic vapour cartridge(s) and dust and mist filter(s). Ventilation: Local Exhaust: Provide local ventilation system. Special: Mechanical (General): Other: Eye Protection: Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Protective Gloves: Other Protective Equipment:

SECTION IX – PHYSICAL AND CHEMICAL PROPERTIES Boiling Point (° F): Not Applicable Specific Gravity (H²O=1): <0.01 Vapor Pressure (mm Hg): Not Applicable Percent Volatile by Volume (%): Not Applicable Vapor Density (Air=1): Not Applicable Evaporation Rate (nBuOAc=1): Not Applicable Odor Threshold: Not Applicable Freezing Point: Not Applicable Coefficient of Water/Oil Distribution: N/A pH : 8.0 – 10.0 Viscosity: Not Applicable Reserve : Not Applicable Density: 10g/L approximate Solubility in Water: Not Applicable Appearance and Odor: White, Odourless Physical State: Solid (foam)

SECTION X – STABILITY AND REACTIVITY Possible Hazardous Reactions/Conditions: Stable at normal temperatures and pressure. Conditions to Avoid: Avoid heat, flames, sparks and other sources of ignition. Avoid contact with

incompactible materials. Materials to Avoid: Oxidizing materials. Hazardous Decomposition Products: Oxides of carbon, oxides of nitrogen, oxides of sulfur,

aromatic compounds, formaldehyde, hydrogen cyanide.

SECTION XI – TOXICOLOGICAL INFORMATION Rat, oral LD50 > 5000 mg/kg Rat, inhalation LC50 > 5.6 mg/L (4 hr, dust) Rabbit, primary skin irritation: Non-irritant

SECTION XII – ECOLOGICAL INFORMATION Not Available

SECTION XIII – DISPOSAL CONSIDERATIONS

Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.

SECTION XIV – TRANSPORT INFORMATION

U.S. Department of Transportation: No classification assigned. Canadian Transportation of Dangerous Goods: No classification assigned. Land (ADR/RID), Air (IATA/ICAO) and Maritime (IMDG) Transportation: No Classification assigned.

SECTION XV – ADDITIONAL REGULATORY INFORMATION

U.S. Regulations: OSHA process Safety (29CFR1910.119): Not Regulated. U.S. Inventory (TASCA): Listed on inventory. State Regulations: California Proposition 65: Not Regulated.

Ameriplus Material Safety Data Sheet 535 S. Hercules Ave. #201 Issue date: 10/13/07 Clearwater, FL 33764 Product Name: Home Store Glass Cleaner With Ammonia- Formula 55-519 SECTION I – EMERGENCY CONTACT: Info Trac 1-800-535-5053 SECTION II –HAZARDOUS INGREDIENTS: Component CAS # TLV (ppm) % (in prod.) 2-propanol 67-63-0 400 <2 SECTION III – HEALTH HAZARD: Acute Effects of Overexposure: Skin: Irritant. May cause irritation and redness Eyes: Irritant. Inflammation is characterized by redness, watering and itching. Inhale: Overexposure may cause respiratory irritation. Ingest: Can cause nausea and irritation to mouth, throat and stomach. Existing skin diseases may be aggravated by overexposure. Chronic Effects of Overexposure: Repeated or prolonged exposure may produce defatting of the skin HMIS Codes: Health 1; Flam. 0: React. 1; Pers. Protection B Carcinogenic effects: None of the ingredients are listed as carcinogens by IARC, NTP, or OSHA SECTION IV – FIRST AID MEASURES First aid procedures: Skin: Wash contaminated area with soap or mild detergent. Get medical attention if irritation develops. Eyes: Check for and remove contact lens. Immediately flush with plenty of water for at least 15 minutes. If irritation develops consult a physician. Inhale: This route of exposure is not likely due to the nature of this product.

Ingest: If product is swallowed, do not induce vomiting. If vomiting occurs keep head lower than hips to help prevent aspiration. If individual is alert, give plenty of water to drink. Never give anything by mouth to an unconscious person. SECTION V– FIRE AND EXPLOSION DATA: Flash Point (F) None Flammable Limits: LEL: NA UEL NA Fire Fighting Procedure: use water vapor, foam or fog. Firefighters should ware proper protective equipment. Fire Hazard: NA SECTION VI – ACCIDENTAL RELEASE MEASURES: Spill Clean Up: Wear appropriate protective equipment. Absorb with an inert material and put spilled material in appropriate waste disposal. SECTION VII – HANDLING AND STORAGE PROCEEDURES: Handling: Avoid contact with eyes. Keep container closed. Wash thoroughly after handling. Storage: Keep container in cool well ventilated area. Keep container tightly closed. Store away from incompatible materials. Keep out of the reach of children. SECTION VIII EXPOSURE CONTROLS, PERSONAL PROTECTION: Eye Protection: No special protection is required. Protective Clothing: No special protection is required. Respiratory: No special protection is required. SECTION IX – PHYSICAL AND CHEMICAL DATA: Boiling Point (F) 212 Specific Gravity: 0.995 – 1.00 pH: 11.2 – 12 VOC content (%) <2 Evaporation Rate (Bu acetate=1) NA vap. Pressure (mm Hg) NA Vap. Density NA Solubility in Water: soluble Appearance and Odor: clear thin blue liquid with slight ammonia odor SECTION X – REACTVITY DATA: Stability: Stable Incompatibility: strong oxidizing agents, acids Polymerization: Will not occur Hazardous Decomposition: carbon monoxide, carbon dioxide and other organic materials. SECTION XI TOXOLOGICAL INFORMATION Toxicity to animals Oral (LD50) acute: not available

Dermal (LD50) acute: not available SECTION XII Ecological Information - not available Biodegradable/OECD – not available SECTIION XIII DISPOSAL CONSIDERATIONS Waste Disposal Method: Liquid wastes are not permitted in landfill. Consult local, state, and federal agencies for proper disposal in your area. Classification: non-hazardous waste SECTION XIV TRANSPORT INFORMATION Proper shipping name NA DOT classification not a DOT controlled material UN number NA SECTION XV REGULATORY INFORMATION SARA 313 toxic chemical notification and release reporting - No products found Clean Water Act (CWA) regulated substance – no product found Clean Air Act (CAA) 112 regulated toxic substances - no product found SECTION XVI OTHER INFORMATION To the best of our knowledge information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

All Squeaky Cleaning, LLC Material Safety Data Sheets (MSDS)allsqueakycleaning.com/MSDS.pdf ·...

Documents

Transcript of All Squeaky Cleaning, LLC Material Safety Data Sheets (MSDS)allsqueakycleaning.com/MSDS.pdf ·...