MATERIAL SAFETY DATA SHEET - Expotech USA · 2018. 8. 18. · P.O. Box 329 - 802 Washington Avenue...

MATERIAL SAFETY DATA SHEETP.O. Box 329 - 802 Washington Avenue Chestertown, MD 21620 - USATELEPHONE # FOR INFORMATION 410 778-310024 HOUR EMERGENCY NUMBER (CHEM-TEL): USA, Canada, Puerto Rico 800-255-3924;

MSDS

Outside North American Continent 813-248-0585 (call Collect)

1. Product Identification

Acid Extracting Solution

Product Code: 6361Product Description:

Manufactured By: LaMotte Company802 Washington AvenueChestertown, MD 21620

TLVPEL

Ceiling 5 ppm (7mg/m³)

None Established

1 mg/m³ (TWA)

%

<3

<2

to 100%

7647-01-0

7664-93-9

7732-18-5

2. Composition/Information On Ingredients

CAS#/Name

Hydrochloric Acid

Sulfuric Acid

Water

Ceiling 2 ppm

0.2 mg/m³ (T) (TWA)

None Established

Hazard

Yes

Yes

No

3. Hazards Overview

Warning! Causes severe eye and skin irritation. Harmful if swallowed.

Primary Route Of Entry: Skin Ingestion

Carcinogenicity: None:

See Section 11, Toxicity.

Other Health Related Comments:

HMIS HazardScale: 4 = Extreme, 3 = High, 2 = Moderate, 1= Slight, 0 = Least

Health: 2 Flammability: 0 Reactivity: 1

1

MATERIAL SAFETY DATA SHEETLaMOTTE COMPANY

P.O. BOX 329 - CHESTERTOWN, MARYLAND 21620TELEPHONE # FOR INFORMATION 410 778-3100

24 HOUR EMERGENCY NUMBER (CHEM-TEL) 800-255-3924

1. PRODUCT IDENTIFICATION

Color Developing ReagentProduct Code: V-6281 Product Description:

TLVPELC 5 mg/cubic m as Mn

N/E

10.000 mg/cubic m

%10

52

2

10034-96-5

12125-02-9

63-74-1

2. HAZARDOUS INGREDIENTS

CAS#/Name

Manganous Sulfate, monhydrate

Ammonium Chloride

Sulfanilamide

C 5 mg/cubic m as Mn

10.000 mg/cubic m

N/E

3. NON-HAZARDOUS INGREDIENTS

NameN-1-naphthylethylenediamine dihydrochloride

Sodium Citrate

CAS # %1465-25-4

68-04-21

35

4. PHYSICAL DATA

Partially

Appearance:

Odor:Solubility In Water: Vapor Pressure:

Melting Point:

Vapor Density:

Boiling Point:pH:

N/A

White Powder

None

N/A

7 (0.1g/10mL water)

N/A

Unknown

5. FIRE & EXPLOSION DATA

HMIS Hazard

Health:

Extinguishing Media:

Special Fire Fighting Procedures:

Flammability:

Flash Point (Method Used):

Scale: 4 = Extreme, 3 = High, 2 = Moderate, 1= Slight, 0 = Least

Reactivity:UEL:

Flammable LimitLEL:

1 0 0

N/A N/A

Unusual Fire & Explosion Hazard:

N/A

Not a fire hazard

N/A

N/A

1

V-6281 Color Developing ReagentProduct Code: Product Description:

6. REACTIVITY DATA

Stable:

Conditions To Avoid:

Incompatibility (Materials To Avoid):

Hazardous Decomposition Products:

True

Heat, moisture, air

Alkalies, metals, concentrated nitric acid or sulfuric acid

COx, ammonia

7. HEALTH HAZARD DATA

Toxicity: orl rat LD50:Primary Route Of Entry:

Other Health Related Comments:Target Organs:

Signs and Symptons of Exposure:

Unknown

Inhalation Skin

Harmful by inhalation, skin contact and if swallowed. Irritating to eyes, skin, and nose.

Carcinogenicity:

Lungs Central Nervous System

None

Manganese investigated as a possible mutagen and reproductive effector.

8. EMERGENCY FIRST AID PROCEDURES

Eye Contact:

Inhalation:

Ingestion:

Skin Contact:

Immediately flush with water for 15 minutes. Consult physician.

Induce vomiting. Drink water. Consult a physician immediately.

Remove to fresh air.

Flush thoroughly with water. Wash with soap and water. Consult physician.

9. SPILL AND DISPOSAL PROCEDURES

Spill and Leak:

Disposal:

Sweep up carefully. Dissolve in water and flush down drain with excess water.

Small quantity: Dissolve in large volume of water and flush down drain with excess water. Large quantity: Dispose as hazardous waste according to federal, state and local regulations.

10. PRECAUTIONARY MEASURES

In Handling:Ventilation:

Work/Hygienic Practices:Other:

Use with adequate ventilation. Do not breathe dust. Avoid contact with skin and clothing.

Gloves Eye Protection Other

Mechanical

Lab Coat

11. SPECIAL PRECAUTIONS

Date: 3/1/2004

N/A

2

1

MSDS Material Safety Data Sheet

PO Box 329 • 802 Washington Avenue • Chestertown, MD 21620 • USA Telephone Number For Information 410-778-3100 24 Hour Emergency Number (CHEM-TEL): USA, Canada, Puerto Rico 800-255-3924; Outside North American continent 813-248-0585 (call collect)

1. Product Identification Manufactured By: LaMotte Company V-6279 Nitrate Reducing Powder 2. Composition/Information on Ingredients Hazardous Name CAS # % OSHA

PEL ACGIH

TLV Yes Ammonium Chloride 12125-02-9 48 10 mg/cubic m

(fume) 10 mg/cubic m

(fume) Yes Sodium Citrate dihydrate 6132-04-3 32 N/E N/E Yes Manganous Sulfate monohydrate 10034-96-5 10 C 5 mg/cubic m

as Mn C 5 mg/cubic m

as Mn Yes Cadmium Powder 7440-43-9 7 5 ug/cubic m

as Cd 0.01 mg/cubic m total dust

Yes Sulfanilamide 63-74-1 2 N/E N/E Yes N-1-naphthylenediamine dihydrochloride 1465-25-4 1 N/E N/E 3. Hazards Overview Primary Route of Entry: Inhalation Skin Danger! Harmful if inhaled, swallowed or absorbed through skin. Irritating to eyes, skin, respiratory system. HMIS Hazard: (Scale: 4 = Extreme, 3 = High, 2 = Moderate, 1 = Slight, 0 = Least) Health: 3 Flammability: 1 Reactivity: 0 Carcinogenicity: Yes: NTP OSHA IARC Warning! This product contains cadmium, a chemical known to the state of California to cause cancer and birth defects or other reproductive harm. Other Health Related Comments: See Section 11. 4. First Aid Measures

Eye Contact: Immediately flush with water for 15 minutes. Skin Contact: Flush with water. Wash with soap and water.

Ingestion: Rinse out mouth. Drink plenty of water. Consult physician immediately. Inhalation: Remove to fresh air. Consult physician.

Product Code: Product Description:

802 Washington AvenueChestertown, MD 21620

3

Product Code: V-6279 Product Description: Nitrate Reducing Powder

5. Fire Fighting Measures Flash Point: N/A LEL: N/A UEL: N/A Fire Rating Extinguishing Media: Dry chemical or CO2 Special Fire Fighting Procedures: Firefighters wear self-contained breathing apparatus Hazardous Combustion and/or Decomposition Products: Ammonia, hydrogen chloride gas Unusual Fire & Explosion Hazard: Emits toxic fumes under fire conditions. 6. Accidental Release Measures Sweep up carefully. Avoid raising/breathing dust. Wear gloves and dust/mist respirator if available. Place waste in plastic bag and enclose in container with lid. Hold for hazardous waste disposal. Ventilate area & wash spill site. 7. Handling & Storage Store tightly closed in cool, dry location, away from incompatible materials. Store away from foods, in secure “poison” area. 8. Exposure Controls/Personal Protection Ventilation A system of local and/or general exhaust is recommended. Prolonged or frequent handling of laboratory reagents containing finely powdered cadmium metal should be done in a fume hood. Protection When Handling Gloves Eye Protection Lab Coat Work/Hygienic Practices: Use with adequate ventilation. Avoid breathing powder. Do not allow powder to contact skin. Wash after handling. 9. Physical & Chemical Properties Appearance: Gray Powder Boiling Point: N/A Melting Point: Unknown pH: 7 (0.1g/10mL water) Odor: slight Vapor Density: N/A Solubility in Water: Partially Vapor Pressure: N/A 10. Stability & Reactivity Stable: Yes Conditions to Avoid: Moisture, heat, flame, and ignition sources Materials to Avoid: Strong acids or bases;other metal powders such as zinc; ammonium nitrate, hydrazoic acid, sodium azide, sulfur Hazardous Decomposition Products: Ammonia, hydrogen chloride gas

4


11. Toxicological Information

Cadmium is a known human carcinogen & reproductive toxicant. It is listed as “Known to Be a Human Carcinogen”(Group 2A) in NTP’s 8th Report on Carcinogens, 1998. The finding is supported by previous IARC studies in experimental animals (IARC- S.7, 1987). In the U.S.A. cadmium and certain cadmium compounds are regulated by OSHA under the Hazard Communication Standard and as chemical hazards in laboratories.

Ammonium chloride: Oral rat LD50: 1650 mg/kg. Investigated as a mutagen. Manganese sulfate monohydrate: Oral rat LD50: 2150 mg/kg; Anhydrous investigated as a tumorigen, mutagen, reproductive effector. Manganese metal has shown reproductive and teratogenic effects in laboratory animals. N-1-naphthylenediamine dihydrochloride: Investigated as a tumorigen and mutagen.

Target Organs: Lungs 12. Ecological Information Information not Available 13. Disposal Considerations

Do not dispose of cadmium-containing waste to sinks and drains. Dispose of as hazardous waste--to incinerator or EPA approved landfill--according to federal, state and local regulations. 14. Transport Information Domestic: Proper Shipping Name: CADMIUM COMPOUNDS International: Proper Shipping Name: CADMIUM COMPOUND Hazard Class/Div: 6.1 UN2570 Packing Group: III 15. Regulatory Information

Chemical Inventory Status USA Europe ---Canada--- Australia Japan Ingredient TSCA EC DSL NDSL

Ammonium Chloride (12125-02-9) Yes Yes Yes No Yes Yes Sodium Citrate, anhydrous (68-04-2) Yes Yes Yes No Yes Yes Manganese Sulfate, anhydrous (7785-87-7)

Yes Yes Yes No Yes Yes

Cadmium (7440-43-9) Yes Yes Yes No Yes Yes Sulfanilamide (63-74-1) Yes Yes Yes No Yes Yes N-1-naphthylenediamine dihydrochloride (1465-25-4)

Yes Yes Yes No Yes No

5


Federal, State, & International Regulations ---SARA 302--- - -------- SARA 313 --------- RCRA TSCA Ingredient RQ TPQ Listed Chemical Category CERCLA 261.33 8(D)

Ammonium Chloride (12125-02-9)

No No No No 1000 No No

Sodium Citrate, anhydrous (68-04-2)

No No No No No No No

Manganese Sulfate, anhydrous (7785-87-7)

No No No Manganese compound

1 No No

Cadmium (7440-43-9) No No Yes Cadmium No No Yes Sulfanilamide (63-74-1) No No No No No No No N-1-naphthylenediamine dihydrochloride (1465-25-4)

No No No No No No No

----------- Australia ----------- ------ SARA 311/312 ------ Hazchem Poison This MSDS is Ingredient Hazard Categories Code Schedule WHMIS Compliant

Ammonium Chloride (12125-02-9)

Acute: Yes Chronic: No Fire: No Pressure: No Reactivity: No

(Pure/Solid)

None allocated

None allocated

Sodium Citrate (6132-04-3) Acute: No Chronic: No Fire: No

Pressure: No Reactivity: No (Pure/Solid)

None allocated

None allocated

Manganese Sulfate, anhydrous (7785-87-7)

Acute: Yes Chronic: Yes Fire: No Pressure: No Reactivity: No

(Pure/Solid)

None allocated

None allocated

Cadmium (7440-43-9) Acute: Yes Chronic: Yes Fire: No

Pressure: No Reactivity: Yes (Pure/Solid)

1[T] None allocated

Sulfanilamide (63-74-1) Acute: Yes Chronic: No Fire: No

Pressure: No Reactivity: No (Pure/Solid)

None allocated

None allocated

N-1-naphthylenediamine dihydrochloride (1465-25-4)

Acute: Yes Chronic: No Fire: No Pressure: No Reactivity: No

(Pure/Solid)

None allocated

None allocated

For #V-6279 product mixture, taken as a whole


1[T] None allocated Yes

6


16. Other Information MSDS Sections Revised: 3, 15, 16 Prepared By: IP Revised: 12/11/08

MATERIAL SAFETY DATA SHEETLaMOTTE COMPANY

P.O. BOX 329 - CHESTERTOWN, MARYLAND 21620TELEPHONE # FOR INFORMATION 410 778-3100

24 HOUR EMERGENCY NUMBER (CHEM-TEL) 800-255-3924

1. PRODUCT IDENTIFICATION

Mixed Acid ReagentProduct Code: V-6278 Product Description:

7558-79-4 2 N/E

TLVPEL10 ppm

10 mg/cubic m

1 mg/cubic m as Cu

%2

<0.1

17

64-19-7

7758-99-8

12125-02-9

2. HAZARDOUS INGREDIENTS

CAS#/Name

Acetic Acid

Copper Sulfate, 5-hydrate

Ammonium Chloride

Sodium Phosphate, Dibasic

25 mg/cubic m

1 mg/cubic m as Cu

10 mg/cubic m

N/E

3. NON-HAZARDOUS INGREDIENTS

NameSodium Chloride

Citric Acid, anhydrous

Water to 100%

CAS # %7647-14-5

77-92-910

4

4. PHYSICAL DATA

Soluble

Appearance:

Odor:Solubility In Water: Vapor Pressure:

Melting Point:

Vapor Density:

Boiling Point:pH:

< 17 @ 20 deg C

Blue-green Clear, light Liquid

Vinegar

<1 (Air=1)

2

> 100 deg C

N/A

1

V-6278 Mixed Acid ReagentProduct Code: Product Description:

5. FIRE & EXPLOSION DATA

HMIS Hazard

Health:

Extinguishing Media:

Special Fire Fighting Procedures:

Flammability:

Flash Point (Method Used):

Scale: 4 = Extreme, 3 = High, 2 = Moderate, 1= Slight, 0 = Least

Reactivity:UEL:

Flammable LimitLEL:

1 0 0

N/A N/A


N/A

Not a fire hazard

Firefighters wear SCBA.

N/A

6. REACTIVITY DATA

Stable:



Hazardous Decomposition Products:

True

Heat

Strong oxidizers, bases, silver compounds, metals

ammonia, hydrogen chloride

7. HEALTH HAZARD DATA

Toxicity: orl rat LD50:Primary Route Of Entry:

Other Health Related Comments:Target Organs:

Signs and Symptons of Exposure:

orl rat LD50: 1650 mg/kg for ammonium chloride, solid

Ingestion Skin

May be harmful if swallowed. May irritate eyes, skin, respiratory tract.

Carcinogenicity: None

8. EMERGENCY FIRST AID PROCEDURES

Eye Contact:

Inhalation:

Ingestion:

Skin Contact:

Flush with water for 15 minutes.

Rinse mouth, drink glass of water. Consult a physician.


Flush thoroughly with water. Wash with soap and water.

2

V-6278 Mixed Acid ReagentProduct Code: Product Description:

9. SPILL AND DISPOSAL PROCEDURES

Spill and Leak:

Disposal:

Neutralize with sodium bicarbonate. Mop up and flush down drain with excess water.

Neutralize and flush down drain with excess water. Dispose according to federal, state and local regulations.

10. PRECAUTIONARY MEASURES

In Handling:Ventilation:

Work/Hygienic Practices:Other:

N/A

Gloves Eye Protection Other

Normal

Lab Coat

11. SPECIAL PRECAUTIONS

Date: 3/1/2004

N/A

3

Revision Number 0

Material Safety Data Sheet

Issuing Date 1/19/2012

Acute ToxicityEyes Severely irritating to eyes. May be abrasive to the eye. May cause redness, itching, and

pain.

Company LaMotte Company, Inc.802 Washington AvenueP.O. Box 329Chestertown, MD 21620USA

Skin Causes irritation. Symptoms can include redness, itching, and pain. May be absorbedthrough the skin in harmful amounts.

1. PRODUCT AND COMPANY IDENTIFICATION

Inhalation May be harmful if inhaled. Irritating to the respiratory system; may cause symptoms thatinclude coughing and shortness of breath.

Synonyms

Ingestion Toxic if swallowed. Causes irritation or burns to the digestive and respiratory tract. Maycause abdominal pain, diarrhea, vomiting.

none

Emergency Telephone Number 24 Hour Emergency Number (CHEM-TEL):USA, Canada, Puerto Rico 1-800-255-3924Outside North American Continent (Call collect) 813-248-0585

Chronic EffectsRepeated ingestion has caused liver and kidney damage in animals

OSHA Regulatory Status

Environmental Hazard Harmful to aquatic organisms.

This material is considered hazardous by the OSHA Hazard Communication Standard (29CFR 1910.1200).

Product Name

2. HAZARDS IDENTIFICATION

Product Code(s)

Potential Health Effects

Recommended Use Test kit reagent. Laboratory chemicals. Industrial (not for food or food contact use).

Principle Routes of Exposure Ingestion, Eye contact, Skin contact, Inhalation.

V-6277

_____________________________________________________________________________________________

SULFATE REAGENT

DANGER!

Emergency OverviewToxic if swallowedToxic by inhalation

May cause adverse cardiovascular effectsSevere eye irritation

Irritating to eyes, respiratory system, and skin

Page 1 / 8

Odor None

Published Date: 20-Jan-2012

Physical State PowderAppearance White

_____________________________________________________________________________________________SULFATE REAGENT Product Code(s) V-6277

Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses andcontinue flushing for at least 15 minutes. Keep eye wide open while rinsing. Call aphysician immediately.

Flash Point Not applicable

General Advice

Ingestion

Suitable Extinguishing Media Water spray, dry chemical, carbon dioxide (CO2), or foam.

Call a physician or Poison Control Center immediately. DO NOT induce vomiting unlessdirected to do so by a physician or poison control center. Never give anything by mouth toan unconscious person. Rinse mouth.

Explosion Data

Consult a physician. Show this safety data sheet to the doctor in attendance. Do not get ineyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapors/spray.

Skin Contact

Protection of First-aiders Use personal protective equipment.

Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Consult a physician.

7. HANDLING AND STORAGE

5. FIRE-FIGHTING MEASURES

4. FIRST AID MEASURES

Inhalation Move to fresh air. Consult a physician. If breathing is irregular or stopped, administerartificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouthresuscitation.

Flammable Properties Not flammable.

NFPA

Citric acid monohydrate

Methods for Containment Dispose according to federal, state, and local regulations. Clean up in a manner that doesnot dispurse dust using a non-sparking shovel and dust pan. Place in a clean dry plasticcontainer with lid. Dispose of as hazardous waste.

5949-29-1

Health Hazard 3

55-65

CAS-No

Methods for Cleaning Up Use personal protective equipment. Keep in suitable and closed containers for disposal.Clean contaminated surface thoroughly. Following product recovery, flush area with water.

Health Hazard 3

Flammability 0

Weight %

Stability 1

Flammability 0

Gum arabic 9000-01-5

Stability 0

1-10

Physical and ChemicalHazards -

Barium chloride dihydrate

6. ACCIDENTAL RELEASE MEASURES

_____________________________________________________________________________________________

10326-27-9 30-40

3. COMPOSITION/INFORMATION ON INGREDIENTS

HMIS

Personal Precautions

Page 2 / 8

Ensure adequate ventilation. Avoid contact with skin, eyes, and clothing. Refer to Section8. Wear protective gloves/clothing and eye/face protection.


Chemical Name


Handling

Incompatible Products Strong oxidizing agents. Acids.

Chemical Name

Engineering Measures ShowersEyewash stationsVentilation systems.

ACGIH TLV

Conditions to Avoid Incompatible products.

OSHA PEL NIOSH IDLH

Wear personal protective equipment. Ensure adequate ventilation. Use only in areaprovided with appropriate exhaust ventilation. Avoid contact with skin, eyes and clothing.Do not eat, drink, or smoke when using this product. Refer to Section 8.

Hazardous Decomposition Products Hydrogen chloride. Carbon oxides (COx). Barium oxides.

Personal Protective Equipment

Storage

Gum arabic 9000-01-5

Hazardous Reactions Contact with acids liberates very toxic gas.

Eye/Face Protection Safety glasses with side-shields.

None Known

Hazardous Polymerization Hazardous polymerization does not occur.

None Known

Skin and Body Protection Wear protective gloves/clothing. Gloves & Lab Coat. Nitrile rubber.

11. TOXICOLOGICAL INFORMATION

None Known

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Respiratory Protection

Acute Toxicity

Use mechanical ventilation (fume hood). When workers are facing concentrations abovethe exposure limit they must use appropriate certified respirators.

Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach ofchildren. Keep away from heat.

Barium chloride dihydrate 10326-27-9

TWA: 0.5 mg/m3

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

TWA: 0.5 mg/m3 TWA: 0.5 mg/m3

Gum arabic 16 g/kg ( Rat ) None Known None Known

10. STABILITY AND REACTIVITY

Citric acid monohydrate 5949-29-1

None Known None Known None Known

Stability Stable.

9. PHYSICAL AND CHEMICAL PROPERTIES

Vapor Pressure No information available

pH 3 (0.1g/10mL water)Autoignition Temperature Not applicable

Vapor Density No information available

Physical State Powder

_____________________________________________________________________________________________

Appearance White


Odor None

Page 3 / 8Published Date: 20-Jan-2012

Not applicableFlammability Limits in Air

_____________________________________________________________________________________________Product Code(s) V-6277SULFATE REAGENT

None Known None Known

Chronic Toxicity Repeated ingestion has caused liver and kidney damage in animals.


Endocrine Disruptor Information .


Chemical Name

Chemical Name EU - Endocrine DisruptersCandidate List

EU - Endocrine Disruptors -Evaluated Substances

Japan - Endocrine DisruptorInformation

ACGIH IARC

Gum arabic None Known None Known None Known

NTP OSHA

Barium chloride dihydrate None Known None Known None Known

None Known

Chronic Toxicity

Citric acid monohydrate None Known None Known None Known

Gum arabic None Known None Known None Known None Known


Barium chloride dihydrate None Known None Known None Known None Known

3000 mg/kg ( Rat )

Citric acid monohydrate None Known None Known None Known None Known

Citric acid monohydrate None Known

Waste Disposal Method This material, as supplied, is a hazardous waste according to federal regulations (40 CFR261). Dispose according to federal, state, and local regulations.

LC50= 1516 mg/L Lepomismacrochirus 96 h

LC50= 440 mg/L Leuciscusidus 96 h


Chemical Name Toxicity to Algae Toxicity to Fish

Chemical Name RCRA - HalogenatedOrganic Compounds

RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes

Chemical Name Log Pow

Gum arabic - 9000-01-5 None Known None Known None Known None Known

Microtox Daphnia Magna (WaterFlea)

Barium chloride dihydrate -10326-27-9

None Known None Known None Known None Known

Gum arabic None Known

Citric acid monohydrate -5949-29-1


12. ECOLOGICAL INFORMATION

Harmful to aquatic organisms.

Barium chloride dihydrate None Known

Gum arabic None Known

Citric acid monohydrate None Known


_____________________________________________________________________________________________

Ecotoxicity

Barium chloride dihydrate None Known None Known None Known None Known

13. DISPOSAL CONSIDERATIONS



Packing Group III

14. TRANSPORT INFORMATION

Packing Group

IMDG/IMO

III

Proper Shipping Name

Proper Shipping Name BARIUM COMPOUNDS, N.O.S. (30% Barium chloride)

BARIUM COMPOUNDS, N.O.S. (30% Barium chloride)

Hazard Class 6.1UN-No 1564

DOT

IATA

Packing Group III

Hazard Class

UN-No 1564

6.1

_____________________________________________________________________________________________

Proper Shipping Name BARIUM COMPOUNDS, N.O.S. (30% Barium chloride)Hazard Class 6.1

Page 5 / 8

UN-No


1564


Barium chloridedihydrate

10326-27-9 ( 30-40 )

TSCA

SARA 311/312 Hazard Categories

DSL EINECS/ELINCS

Acute Health Hazard Yes

1-79 X

Chronic Health Hazard No

KECL X

Fire Hazard No

X

Sudden Release of Pressure Hazard No

International Inventories

Citric acidmonohydrate

5949-29-1 ( 55-65 )

Reactive Hazard No

TSCA X EINECS/ELINCS

ENCS

Clean Water Act

X KECL

Component CWA - ReportableQuantities

CWA - Toxic Pollutants CWA - Priority Pollutants CWA - HazardousSubstances

X X

Gum arabic 9000-01-5 ( 1-10 )


Component TSCA

Barium chloride dihydrate 10326-27-9 ( 30-40 )


DSL

Citric acid monohydrate 5949-29-1 ( 55-65 )


EINECS/ELINCS

ENCS IECSC

U.S. Federal Regulations

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61).

KECL PICCS

Chemical Name CAS-No Weight % HAPS data VOC Chemicals Class 1 OzoneDepletors

Class 2 OzoneDepletors

AICS

Gum arabic 9000-01-5 1-10 None Known None Known None Known None Known

SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemicalor chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Barium chloridedihydrate

10326-27-9 30-40 None Known None Known None Known None Known

Gum arabic 9000-01-5 ( 1-10 )

Citric acidmonohydrate

5949-29-1 55-65 None Known None Known None Known None Known

Present X

Chemical Name

CERCLA

CAS-No Weight % SARA 313 - ThresholdValues %

X

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs

ENCS

Gum arabic

Gum arabic None Known None Known

9000-01-5 1-10 None Known

X KE-18163


_____________________________________________________________________________________________

10326-27-9 30-40 1.0

X X

Citric acid monohydrate 5949-29-1

Page 6 / 8

55-65


None Known

15. REGULATORY INFORMATION


16. OTHER INFORMATION

Chemical Name Carcinogen Status Exposure Limits


U.S. State Regulations

Gum arabic None Known None Known

Chemical Name

Barium chloride dihydrate None Known Mexico: TWA= 0.5 mg/m3

CAS-No

Citric acid monohydrate None Known None Known

California Prop. 65

None Known

Canada

Gum arabic

Chemical Name Massachusetts New Jersey

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) andthe MSDS contains all the information required by the CPR

Pennsylvania Illinois Rhode Island

9000-01-5

Component WHMIS Hazard Class

None Known

Gum arabic

Gum arabic 9000-01-5 ( 1-10 )

Uncontrolled product according to WHMIS classification criteria

None Known X

Barium chloride dihydrate 10326-27-9 ( 30-40 )

1 %D1B


Citric acid monohydrate 5949-29-1 ( 55-65 )

1 %E

None Known

None Known

Barium chloride dihydrate None Known X X None Known X

Barium chloride dihydrate 10326-27-9

Citric acid monohydrate None Known None Known None Known None Known None Known

None Known

None KnownBarium chloride dihydrate


International Regulations

5949-29-1 None Known

_____________________________________________________________________________________________

California Proposition 65This product does not contain any Proposition 65 chemicals

Mexico - Grade

None Known


U.S. State Right-to-Know Regulations

_____________________________________________________________________________________________Product Code(s) V-6277SULFATE REAGENT

DisclaimerThe information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of itspublication. The information given is designed only as a guide for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered as a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterial or in any process, unless specified in the text.


End of MSDS

Revision Date 20-Jan-2012

Prepared By

Revision Note

Regulatory Affairs Department

Initial Release

_____________________________________________________________________________________________

HMISNFPA PPE Transport Symbol



MSDS



Calcium Hardness Indicator

Product Code: T-5250

Tablets

Product Description:


TLVPEL

15 mg/cubic m (dust)

%

74

<2

7447-40-7

2538-85-4


CAS#/Name

Potassium Chloride

Calcon (1-Napthalenesulfonic acid, 3-Hydroxy-4-[2-hydroxy-1-napthylazo]-, sodium salt)

All other ingredients are proprietary 80100291-5022p

10 mg/cubic m

Hazard

Yes

No

*Ingredients not listed by name are proprietary to LaMotte Co, registered under the state of New Jersey (U.S.A.) trade secret protection law, assigned the NJ Trade Secret Registry # 80100291-5022p and may be disclosed only in a medical emergency.

3. Hazards Overview

May irritate eyes and skin. Ingestion of large quantities may cause gastrointestinal irritation and circulatory problems.

Primary Route Of Entry: Ingestion





1

T-5250TabletsCalcium Hardness IndicatorProduct Code: Product Description:

4. First Aid Measures

Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Flush with water.

Drink water. Consult a physician if symptoms develop.

N/A

Rinse skin. Wash with soap and water.

5. Fire Fighting Measures

Extinguishing Media:Special Fire Fighting Procedures:

Flash Point (Method Used): UEL:LEL: N/A N/A


N/A

Not a fire hazard

N/A

N/A

6. Accidental Release Measures

Sweep up. Dissolve in water and flush down drain with excess water.

7. Handling & Storage

Store in cool, dry, storage area.

2


8. Exposure Controls/Personal Protection

Normal

N/A

Ventilation

Protection When Handling

Avoid handling tablets.Work/Hygenic Practices:

9. Physical & Chemical Properties

Appearance:Solubility In Water:Odor:pH:

NoneSolubleSmall Purple Tablet

7(1 tablet in 10mL water)

Vapor Density: N/AN/AVapor Pressure:

Boiling Point: N/AUnknownMelting Point:

10. Stability & Reactivity

Stable: Yes

Moisture, extreme heat or cold

N/A

N/AHazardous Decomposition Products:




potassium chloride- oral rat LD50: 2600 mg/kg; oral man LDLo: 20 mg/kg

Target Organs: N/A

Pre-Existing Conditions Aggravated By Exposure: Impaired kidneys increase effects of KCl

3


12. Ecological Information

Information Not Yet Available

13. Disposal ConsiderationsDissolve in water. Flush down drain with excess water. Dispose according to federal, state and local regulations.

QRLabel5314. Transportation Information

Not Regulated For Transport

15. Regulatory Information

Ingredient--- Canada ---USA

TSCAEurope EC DSL NDSL Australia Japan

Yes Yes7447-40-7Potassium Chloride

2538-85-4Calcon (1-Napthalenesulfonic acid, 3-Hydroxy-4-[2-hydroxy-1-napthylazo]-, s

Yes No Yes Yes

Hazard

Yes

No

Chemical Inventory Status

Federal, State, & International Regulations

Ingredient TPQRQ--------- SARA 313 ---------

Chemical Category--- SARA 302 ---

CERCLARCRA 261.33

TSCA 8(D)

7447-40-7Potassium Chloride


No No No No No

Listed

No No

4


Ingredient

--- SARA 311/312 ---Hazard Categories

-------- Australia -------Hazchem Code

Poison Schedule

7447-40-7Potassium Chloride


None AllocatedYes None AllocatedNo No No No

Acute Chronic Fire Pressure ReactivityThis MSDS Is WHMIS Compliant

T-5250 No No No No No None Allocated None Allocatedproductas a whole

Yes

16. Other Information

Prepared By:1/17/2006Revised:

IP, Regulatory Affairs Department

5


MSDS



Inhibitor Solution



TLVPEL

10 ppm as H2S

None Established

%

35

to 100%

1313-84-4

7732-18-5


CAS#/Name

Sodium Sulfide, 9-hydrate

Water

(11% as "Sodium sulfide")

C 20 ppm as H2S

None Established

Hazard

Yes

No

3. Hazards Overview

Danger! Corrosive. Can cause severe irritation or burns to eyes, skin, and lungs. Harmful or fatal if swallowed.

Primary Route Of Entry: Eye Skin Ingestion Inhalation


See Section 11.




1

9258 Inhibitor SolutionProduct Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Immediately flush with water for 15 minutes while lifting upper and lower eyelids. Get prompt medical attention.

Do Not Induce Vomiting. Rinse out mouth. Drink large quantity of water. Get prompt medical attention.

Remove to fresh air. Give artificial respiration if breathing has stopped. If breathing is difficult, give oxygen. Get prompt medical attention.

Immediately flush with water for 15 minutes while removing contaminted clothing and shoes. Wash with soap and water. Get prompt medical attention.





Not a fire hazard

May emit toxic, flammable vapors of hydrogen sulfide under fire conditions


Ventilate area. Wear PPE noted in Section 8. Carefully collect spill and place in non-metal container. Hold for proper disposal according to federal, state, and local regulations.


Keep in a tightly closed container. Store in a cool, dry, ventilated area away from heat sources, acids, and other incompatible materials. Protect from light and air. Keep out of reach of children.

2



Mechanical

Eye Protection Gloves Lab Coat

Ventilation


A system of local or general exhaust is recommended. Work in fume hood.

Use with adequate ventilation. Avoid contact with eyes and skin. Wash after handling.Work/Hygenic Practices:



Rotten egg, sulfide odorSolubleClear Colorless Liquid

13 - 14

Vapor Density: UnknownUnknownVapor Pressure:

Boiling Point: UnknownUnknownMelting Point:


Stable: Yes

Contact with acids liberates poisonous gas

Strong oxidizers, acids, metals

Decomposed by acid to hydrogen sulfide gas--highly toxic & combustibleHazardous Decomposition Products:




For anhydrous sodium sulfide-- Oral rat LD50: 208 mg/kg. IPR Mouse LD50: 53 mg/kg. Toxic!

Target Organs: Eyes Heart Lung Skin

Pre-Existing Conditions Aggravated By Exposure: Pre-existing skin or eye problems

3



ENVIRONMENTAL FATE: No information found.ENVIRONMENTAL TOXICITY: Sodium sulfide is dangerous to the environment. Very toxic to aquatic organisms.

13. Disposal ConsiderationsDispose of in accordance to federal, state, and local regulations.




Yes Yes1313-82-2Sodium Sulfide, 9-hydrate

7732-18-5Distilled Water

Yes No Yes Yes


Hazard

Yes

No





CERCLARCRA 261.33

TSCA 8(D)

1313-82-2Sodium Sulfide, 9-hydrate


No No

No No No

No No No

No No

Listed

No

No

No

No

4


Ingredient



Poison Schedule

1313-82-2Sodium Sulfide, 9-hydrate


None Allocated

None AllocatedNo

Yes 2X

None Allocated

No

No

No

No

No No

No No


9258 Yes No No No No 2X None Allocatedproductas a whole

Yes

16. Other InformationKeep out of the reach of children.



5


MSDS



Chloride Reagent 2S



TLVPEL

0.01 mg/m³ (TWA) Silver metal dust/fume as Ag

None Established

%

1

to 100%

7761-88-8

7732-18-5


CAS#/Name

Silver Nitrate

Water

0.01 mg/m³ (TWA) soluble silver compounds as Ag

None Established

Hazard

Yes

No

3. Hazards Overview

Vapors and liquid cause irritation to eyes, skin and respiratory system. Harmful if swallowed.






1

7624 Chloride Reagent 2SProduct Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Immediately flush with water for 15 minutes while lifting upper and lower eyelids. Contact physician immediately.

Induce vomiting immediately as directed by medical personnel. Contact physician immediately.

Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, administer artificial respiration.

Immediately flush with water for 15 minutes while removing affected clothing. Contact physician. Wash clothing prior to reuse.





N/A

Water spray

Wear self contained breathing apparatus and protective clothing to prevent inhalation and contact with eyes.

Silver nitrate reactions may cause explosions


Wear PPE noted in section 8. Collect spill in appropriate container or absorb spill on inert material and containerize. Hold for disposal according to federal, state, and local regulations.


Store in cool, dry ventilated area away from light, heat, and incompatible materials.

2



Normal

face shield

Eye Protection Gloves Lab Coat, apron

Ventilation


A system or local or general exhuast is recommended to keep employees exposure below the permissable exposure limits.

Avoid contact with eyes, skin, and clothing.Work/Hygenic Practices:



OdorlessSolubleClear Colorless Liquid

5

Vapor Density: <1 (Air=1)<17 @20° CVapor Pressure:

Boiling Point: no information foundno information foundMelting Point:


Stable: Yes

Heat, Direct Sunlight, Incompatibles

Alkalies, reducing agents, metals

NOx, toxic metal fumes may form when heated to decompositionHazardous Decomposition Products:




Oral Rat LD50: 1173mg/kg for Silver Nitrate, solid. Std Rabbit Draize: 1mg (SEVERE). Investigated as a tumorigen, mutagen, reproductive effector.

Target Organs: Skin

3




13. Disposal ConsiderationsDispose according to federal, state, and local regulations.






Yes Yes7761-88-8Silver Nitrate


Yes No Yes Yes


Hazard

Yes

No





CERCLARCRA 261.33

TSCA 8(D)

7761-88-8Silver Nitrate


No No

No No No

1 No No

No No

Listed

No

No

Silver comp

No

4


Ingredient



Poison Schedule

7761-88-8Silver Nitrate


S6

None AllocatedNo

Yes 2X

None Allocated

Yes

No

No

No

No Yes

No No


7624 Yes Yes No No No 2X None Allocatedproductas a whole

Yes




5


MSDS



Copper 2



7732-18-5 >99

TLVPEL%

<0.1

<0.1

<0.1

60-00-4

3734-67-6

6359-98-4


CAS#/Name

Ethylenediaminetetraacetic acid

Acid Red 1 (Amido Napthol Red G)

Acid Yellow 17

Water

Hazard

3. Hazards Overview

N/A

Primary Route Of Entry: Skin





1

6613 Copper 2Product Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Flush thoroughly with water for 15 minutes. Contact physician if irritation develops.

Give plenty of water. Consult a physician.

N/A

Flush with water for 15 minutes for 15 minutes. Wash with soap and water. Contact physician if irritation develops.





N/A

Not a fire hazard

N/A

N/A


Absorb spill on inert material, place into a chemical waste container, and hold for disposal. Dispose according to federal, state, and local regulations. If regulations permit, rinse to drain with excess water.


Store in cool, dry, storage area away from incompatible materials.

2



Normal

Eye Protection Lab Coat

Ventilation


N/AWork/Hygenic Practices:



NoneSolubleClear Orange Liquid

8

Vapor Density: <1 (Air=1)<17@20° CVapor Pressure:



Stable: Yes

N/A

N/A





Target Organs: Skin

3




13. Disposal ConsiderationsDispose according to federal, state and local regulations.





TSCAEurope EC DSL NDSL Australia JapanHazard





CERCLARCRA 261.33

TSCA 8(D)Listed

4


Ingredient



Poison ScheduleAcute Chronic Fire Pressure Reactivity

This MSDS Is WHMIS Compliant

6613 No No No No No None Allocated None Allocatedproductas a whole

Yes

16. Other InformationKeep out of reach of children



5


MSDS



CM Indicator Reagent



1787-61-7 <0.1 None Established

TLVPEL

1000ppm TWA (1900 mg/m³)

None Established

200ppm TWA (260 mg/m³)

%

22

1

76

64-17-5

67-56-1

102-71-6


CAS#/Name

Ethanol

Methanol

Triethanolamine

Eriochrome Black T; (Mordant Black)

1000 ppm TWA

200 ppm TWA

5 mg/m³ (TWA)

None Established

Hazard

Yes

Yes

Yes

Yes

3. Hazards Overview

May irritate eyes and skin. Harmful if swallowed.

Primary Route Of Entry: Skin Ingestion Inhalation


See Section 11




1

6522 CM Indicator ReagentProduct Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Immediately flush with water for 15 minutes lifting upper and lower eyelids occasionally. Consult a physician if irritation persists.

Drink large quantity of water. Consult physician immediately.

Remove to fresh air. Consult a physician.

Flush skin with water for 15 minutes while removing affected clothing. Wash skin with soap and water. Consult physician if irritation persists.





N/A

Dry chemical, alcohol-resistant foam, CO2

N/A

N/A


Ventilate area. Eliminate sources of ignition. Absorb on inert material, containerize, and hold for disposal as hazardous waste. Do not flush to sewer!


Keep in a tightly closed container. Store in cool, dry place away from incompatible materials. (Triethanolamine is incompatible with copper, copper alloys, galvanized iron, acids, and oxidizers).

2



Normal


Ventilation


Use with adequate ventilation. Avoid contact with eyes, skin, and clothing.Work/Hygenic Practices:



Slightly fishySolubleDark Blue Liquid

10 - 11

Vapor Density: 3 (Air=1)<1 mm Hg@ 20C (Trolamine)Vapor Pressure:

Boiling Point: >330° C (Trolamine)ca. 21° C (Trolamine)Melting Point:


Stable: Yes

Heat

Acids, metals, strong oxidizers

Toxic fumes of COx or NOx under fire conditions.Hazardous Decomposition Products:




Oral Rat LD50: 7060mg/kg Ethanol. Oral Rat LD50: 4920mg/kg Triethanolamine; Trolamine has been investigated as a tumorigen and a mutagen.

Target Organs: Eyes Skin

3



When released into soil or water, this material is expected to readily biodegrade. Not expected to significantly bioaccumulate.When released into the air this material is expected to be readily removed from the atmosphere by dry and wet decomposition.

13. Disposal ConsiderationsDispose of as hazardous waste. Follow federal, state, and local regulations.






Yes Yes64-17-5Ethanol

67-56-1Methyl Alcohol

102-71-6

1787-61-7Eriochrome Black T (C.I. 14645)

Triethanolamine

Yes No Yes Yes


YesYes

Yes

Yes No Yes

Yes

Yes

NoYes Yes Yes

Hazard

Yes

Yes

Yes

Yes





CERCLARCRA 261.33

TSCA 8(D)

64-17-5Ethanol


102-71-6Triethanolamine


No No

No No

No No

No No No

5000

No

No

No No

No No

U154 No

No No

No No

Listed

No

Yes

No

No

No

Toxic Pollutant

4


Ingredient



Poison Schedule

64-17-5Ethanol




None Allocated

S6

None Allocated

None Allocated

Yes

Yes

No

Yes None Allocated

2PE

None Allocated

None Allocated

Yes

Yes

No

No

Yes

Yes

No

No

No No

No No

No No

No No


6522 Yes No No No No None Allocated None Allocatedproductas a whole

Yes

16. Other InformationKeep out of reach of children.



5


Product Name Copper 1

Product Code(s) 6446

Synonyms none

Recommended Use Laboratory chemicals. Industrial (not for food or food contact use). Chemical additive.Swimming pool chemicals.




OSHA Regulatory Status This product is an article which contains a chemical substance. Safety information is givenfor exposure to the article as sold, but considers exposure to the chemical if user has directeye and skin contact with the chemical.

Potential Health EffectsPrinciple Routes of Exposure Skin contact, Inhalation, Ingestion

Acute ToxicityEyes Irritating to eyes.Skin Irritating to skin.Inhalation Irritating to respiratory system.Ingestion Harmful if swallowed.

Chronic Effects


Chemical Name CAS-No Weight %Ammonium hydroxide 1336-21-6 <4

Diethylcarbamodithioic acid sodium salt trihydrate 20624-25-3 1Toluene 108-88-3 <0.1Water 7732-18-5 to 100%

_____________________________________________________________________________________________


Emergency OverviewHarmful if swallowed

Irritating to eyes, respiratory system and skin

Revision Number 0

Published Date: 04-Mar-2010 Page 1 / 7


Appearance Clear, colorless solution Physical State Liquid Odor Pungent, Ammoniacal

Copper 1

_____________________________________________________________________________________________WARNING! This product contains Toluene, a chemcial know to the State of California to cause birth defects or other reproductiveharm..


General Advice Do not get in eyes, on skin, or on clothing.

Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.Consult a physician.

Skin Contact Wash off immediately with soap and plenty of water for at least 15 minutes while removingall contaminated clothing and shoes. Consult a physician.

Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificialrespiration. Call a physician immediately.

Ingestion Do NOT induce vomiting. Drink plenty of water. Clean mouth with water. Never giveanything by mouth to an unconscious person. Consult a physician.

Protection of First-aiders Use personal protective equipment. See Section 8 for more detail. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration withthe aid of a pocket mask equipped with a one-way valve or other proper respiratory medicaldevice.



Explosion Data


Personal Precautions Refer to Section 8. Avoid contact with skin, eyes and clothing.

Methods for Containment Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth,diatomaceous earth, vermiculite) and place in container for disposal according to local /national regulations (see Section 13).

Methods for Cleaning Up Use personal protective equipment. Contain and collect spillage with non-combustibleabsorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place incontainer for disposal according to local / national regulations (see Section 13). Followingproduct recovery, flush area with water.


Handling Handle in accordance with good industrial hygiene and safety practice. Prevent contact withskin, eyes and clothing. Do not ingest. Do not eat, drink or smoke when using this product.

Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Separate from acidsand alkalis. Keep out of the reach of children.


Chemical Name ACGIH TLV OSHA PEL NIOSH IDLHAmmonium hydroxide

1336-21-6None Established None Established None Established

_____________________________________________________________________________________________

NFPA Physical and ChemicalHazards -

Health Hazard 1


Published Date: 04-Mar-2010

Flammability 0

Page 2 / 7

Stability 0

Copper 1

_____________________________________________________________________________________________Diethylcarbamodithioic acid

sodium salt trihydrate 20624-25-3

None Established None Established None Established

Toluene 108-88-3

TWA: 20 ppm TWA: 200 ppm IDLH: 500 ppmTWA: 100 ppm

TWA: 375 mg/m3

STEL: 560 mg/m3

STEL: 150 ppmWater


Personal Protective EquipmentEye/Face Protection Safety glasses with side-shields.Skin and Body Protection Gloves & Lab Coat.Respiratory Protection Use only with adequate ventilation. In case of insufficient ventilation wear suitable

respiratory equipment.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.



Stability Stable under normal conditions.

Incompatible Products Strong acids. Metals. Chlorine.

Conditions to Avoid Excessive heat.

Hazardous Decomposition Products Ammonia. Nitrogen oxides (NOx). Contact with acid can release carbon disulfide..



Acute Toxicity

Chemical Name LD50 Oral LD50 Dermal LC50 InhalationAmmonium hydroxide 350 mg/kg ( Rat ) None Established None Established

Diethylcarbamodithioic acid sodiumsalt trihydrate

1500 mg/kg ( Rat ) None Established None Established

Toluene 636 mg/kg ( Rat ) 8390 mg/kg ( Rabbit ) 12.5 mg/L ( Rat ) 4 h26700 ppm ( Rat ) 1 h

Water 90 mL/kg ( Rat ) None Established None Established

Chronic Toxicity

Chemical Name ACGIH IARC NTP OSHAAmmonium hydroxide None Established None Established None Established None Established

_____________________________________________________________________________________________

Vapor Pressure >20 mmHg @ 20 °C

12

Vapor Density No data available

Boiling Point/Range ca 100 °C


Freezing Point No information available

Odor Pungent, AmmoniacalPhysical State Liquid


Appearance Clear, colorless solution

Page 3 / 7

pH

Copper 1

_____________________________________________________________________________________________Diethylcarbamodithioic acid

sodium salt trihydrateNone Established None Established None Established None Established

Toluene None Established None Established None Established None EstablishedWater None Established None Established None Established None Established




Ammonium hydroxide None Established None Established None EstablishedDiethylcarbamodithioic acid sodium

salt trihydrateNone Established None Established None Established

Toluene None Established None Established None EstablishedWater None Established None Established None Established


EcotoxicityChemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (Water

Flea)Ammonium hydroxide None Established LC50= 8.2 mg/L Pimephales

promelas 96 hNone Established EC50 = 0.66 mg/L 48 h

Diethylcarbamodithioic acidsodium salt trihydrate

None Established None Established None Established None Established

Toluene EC50 > 433 mg/L 96 h LC50= 13 mg/L Lepomismacrochirus 96 h

LC50= 24.0 mg/L Lepomismacrochirus 96 hLC50= 24.0 mg/L

Oncorhynchus mykiss 96 hLC50= 25 mg/L Pimephales

promelas 96 h

EC50 = 19.7 mg/L 30 min EC50 = 11.3 mg/L 48 hEC50 = 310 mg/L 48 h

Water None Established None Established None Established None Established

Chemical Name Log PowAmmonium hydroxide None Established

Diethylcarbamodithioic acid sodium salttrihydrate

None Established

Toluene = 2.65Water None Established


Waste Disposal Method Dispose of in accordance with local regulations.

Chemical NameAmmonium hydroxide -

1336-21-6Diethylcarbamodithioic acid

sodium salt trihydrate -20624-25-3

Toluene - 108-88-3Water - 7732-18-5



Ammonium hydroxide -1336-21-6


Diethylcarbamodithioic acidsodium salt trihydrate -

20624-25-3


_____________________________________________________________________________________________

Page 4 / 7



Copper 1

_____________________________________________________________________________________________Toluene - 108-88-3 None Established None Established Toxic waste; (waste number

F025); Waste description:Condensed light ends, spent

filters and filter aids, andspent desiccant wastes from

the production of certainchlorinated aliphatic

hydrocarbons, by free radicalcatalyzed processes. These

chlorinated

None Established

Water - 7732-18-5 None Established None Established None Established None Established

Chemical Name California Hazardous Waste StatusAmmonium hydroxide Toxic; Corrosive

Toluene Toxic; Ignitable


DOT Not regulated

IATA Not regulated

IMDG/IMO Not regulated



Component TSCA DSL EINECS/ELINCS

ENCS IECSC KECL PICCS AICS

Ammonium hydroxide 1336-21-6 ( <4 )

Present X X 1-314 X KE-01688 X X

Diethylcarbamodithioicacid sodium salt

trihydrate 20624-25-3 ( 1 )

TSCA DSL EINECS/ELINCS

ENCS X KECL X X

Toluene 108-88-3 ( <0.1 )


Water 7732-18-5 ( to 100% )

Present X X ENCS X KE-35400 X X


SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemicalor chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:

Chemical Name CAS-No Weight % SARA 313 - ThresholdValues %

Ammonium hydroxide 1336-21-6 <4 1.0Diethylcarbamodithioic acid sodium salt trihydrate 20624-25-3 1 None Established

Toluene 108-88-3 <0.1 1.0Water 7732-18-5 to 100% None Established

SARA 311/312 Hazard CategoriesAcute Health Hazard YesChronic Health Hazard NoFire Hazard NoSudden Release of Pressure Hazard NoReactive Hazard No

Clean Water Act

_____________________________________________________________________________________________

Page 5 / 7



Copper 1

_____________________________________________________________________________________________Component CWA - Reportable

QuantitiesCWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous

SubstancesAmmonium hydroxide

1336-21-6 ( <4 )1000 lb None Established None Established X

Diethylcarbamodithioic acid sodiumsalt trihydrate

20624-25-3 ( 1 )


Toluene 108-88-3 ( <0.1 )

1000 lb X X X

Water 7732-18-5 ( to 100% )




Ammonium hydroxide 1336-21-6 <4 None Established None Established None Established None EstablishedDiethylcarbamodithioic

acid sodium salttrihydrate

20624-25-3 1 None Established None Established None Established None Established

Toluene 108-88-3 <0.1 Present Group I None Established None EstablishedWater 7732-18-5 to 100% None Established None Established None Established None Established

CERCLA

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQsAmmonium hydroxide 1000 lb None Established

Diethylcarbamodithioic acid sodium salt trihydrate None Established None EstablishedToluene 1000 lb None EstablishedWater None Established None Established


California Proposition 65WARNING! This product contains a chemcial know to the State of California to cause birth defects or other reproductive harm.

Chemical Name CAS-No California Prop. 65Ammonium hydroxide 1336-21-6 None Established

Diethylcarbamodithioic acid sodium salt trihydrate 20624-25-3 None EstablishedToluene 108-88-3 DevelopmentalWater 7732-18-5 None Established

Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode IslandAmmonium hydroxide X X X None Established None Established

Diethylcarbamodithioic acidsodium salt trihydrate

None Established None Established None Established None Established None Established

Toluene X X X X XWater None Established None Established None Established None Established None Established


Mexico - Grade No information available.

Chemical Name Carcinogen Status Exposure LimitsAmmonium hydroxide None Established None Established

Diethylcarbamodithioic acid sodium salt trihydrate None Established None EstablishedToluene None Established Mexico: TWA= 188 mg/m3

Mexico: TWA= 50 ppmWater None Established None Established

Canada

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) andthe MSDS contains all the information required by the CPR.

_____________________________________________________________________________________________


Page 6 / 7Published Date: 04-Mar-2010

Copper 1

_____________________________________________________________________________________________WHMIS Hazard ClassNot determined

Chemical Name NPRIToluene X


Prepared By Regulatory Affairs Department


Revision Date

Revision Note Initial Release.


End of MSDS

_____________________________________________________________________________________________


HMIS PPE


Transport Symbol

Page 7 / 7

NFPA


MSDS



Reducing Reagent



TLVPEL

5 mg/cubic m (mist, resp.)

2 mg/cubic m as Sn

%

>95

1.6

<4

56-81-5

10025-69-1

7732-18-5


CAS#/Name

Glycerol

Stannous Chloride Dihydrate

Water

10 mg/cubic m (mist)

2 mg/cubic m as Sn

Hazard

Yes

Yes

No

3. Hazards Overview

May be irritating to eyes, skin and respiratory tract.

Primary Route Of Entry: Skin


See Section 11, Toxicity.




1

6405 Reducing ReagentProduct Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:


Induce vomiting. Give plenty of water. Consult a physician.

Remove to fresh air. Consult a physician.

Rinse skin thoroughly. Wash with soap and water.





190 deg C-closed cup

Dry chemical, alcohol-resistant foam, CO2

Use water to keep fire-exposed containers cool.

Contact with strong oxidizing agents (such as nitric acid) may cause fire or explosion.


Small spills: Absorb on paper towels or mop up and flush down drain with excess water. Large spills: Ventilate area of spill. Absorb on inert material (vermiculite or other sorbent) or spill pads, place into a clean, dry plastic pail with lid.


Store tightly closed in cool, dry place away from heat, strong oxidizers, alkalis, nitrates, or nitric acid.

2



Normal

Gloves Eye Protection Lab Coat

Ventilation


Avoid contact with skin.Work/Hygenic Practices:



NoneSolubleClear Slightly colored Viscous liquid

N/A

Vapor Density: 3 (Air=1)3mm Hg @ 20 deg CVapor Pressure:

Boiling Point: ca. 180 C20 deg CMelting Point:


Stable: Yes

Heat, open flame, and hot surfaces

Contact with nitric acid or other strong oxidizers

Toxic gases, fumes (acrolein, hydrochloric acid) may be released in a fireHazardous Decomposition Products:




Oral rat LD50: 700 mg/kg for stannous chloride, anhydrous. Both stannous chloride dihydrate and glycerol investigated as mutagens, reproductive effectors.

Target Organs: Skin

3



When released into soil or water glycerol is expected to readily biodegrade. When released into air it may be removed to a moderate extent by rain. It is not expected to significantly bioaccumulate. It is not expected to be toxic to aquatic life.

13. Disposal ConsiderationsSmall quantities may be flushed to drain with water. Large quantities of collected waste should be sent to incinerator. Dispose according to federal, state and local regulations.






Yes Yes56-81-5Glycerol

7772-99-8Stannous Chloride anhydrous


Yes No Yes Yes


YesYes Yes No Yes Yes

Hazard

Yes

Yes

No





CERCLARCRA 261.33

TSCA 8(D)

56-81-5Glycerol



No No

No No

No No

No

No

No No

No No

No No

No No

Listed

No

No

No

No

No

4


Ingredient



Poison Schedule

56-81-5Glycerol



None Allocated

None Allocated

None Allocated

Yes

No

Yes None Allocated

None Allocated

None Allocated

Yes

Yes

No

No

No

No

No No

No No

No No


6405 Yes Yes No No No None Allocated None Allocatedproductas a whole

Yes




5


Product Name Special NF Phosphorus Extracting Solution


Recommended Use Laboratory chemicals. Industrial (not for food or food contact use).





Potential Health EffectsPrinciple Routes of Exposure Ingestion, and, Skin contact

Acute ToxicityEyes May cause irritation.Skin May cause irritation.Inhalation May cause irritation of respiratory tract.Ingestion Harmful if swallowed.

Chronic Effects


Chemical Name CAS-No Weight %Ammonium fluoride 12125-01-8 1.7Hydrochloric acid 7647-01-0 1.4

Water 7732-18-5 to 100%



_____________________________________________________________________________________________


Issuing Date 2/25/2010 Revision Number 0

Published Date: 25-Feb-2010

Emergency OverviewMay cause skin and eye irritation

Harmful if swallowed

Page 1 / 6

Appearance Clear, Colorless Physical State Liquid Odor None

Special NF Phosphorus Extracting Solution

_____________________________________________________________________________________________Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.

Consult a physician.

Skin Contact Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. If skin irritation persists, call a physician.

Inhalation Move to fresh air. If breathing is difficult, give oxygen.

Ingestion Rinse mouth with water and afterwards drink plenty of water or milk. Consult a physician.Never give anything by mouth to an unconscious person.

Notes to Physician Treat symptomatically. See MSDS (material safety data sheet) for additional information.



Flash Point N/A


Explosion Data


Personal Precautions Refer to Section 8.

Methods for Cleaning Up Use personal protective equipment. Use a non-combustible material like vermiculite, sandor earth to soak up the product and place into a container for later disposal. After cleaning,flush away traces with water.



Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reachof children.


Chemical Name ACGIH TLV OSHA PEL NIOSH IDLHAmmonium fluoride

12125-01-8TWA: 2.5 mg/m3 TWA: 2.5 mg/m3 TWA: 2.5 mg/m3

Hydrochloric acid 7647-01-0

None Established None Established IDLH: 50 ppmCeiling: 7 mg/m3

Ceiling: 5 ppmWater


Personal Protective EquipmentEye/Face Protection Safety glasses with side-shields.Skin and Body Protection Wear protective gloves/clothing.Respiratory Protection Maintain adequate ventilation.

_____________________________________________________________________________________________

Health Hazard 1


Flammability 0 Stability 0NFPA Physical and ChemicalHazards -

Published Date: 25-Feb-2010 Page 2 / 6


_____________________________________________________________________________________________

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Wash hands beforebreaks and immediately after handling the product. Do not eat, drink or smoke when usingthis product.




Incompatible Products Alkalis. Metals.

Conditions to Avoid None known.

Hazardous Decomposition Products Hydrogen chloride. Hydrogen fluoride.

Hazardous Reactions None under normal processing.



Acute Toxicity

Product Information Harmful if swallowed.

Irritation May cause skin and eye irritation.

Chemical Name LD50 Oral LD50 Dermal LC50 InhalationAmmonium fluoride None Established None Established None EstablishedHydrochloric acid 700 mg/kg ( Rat ) 5010 mg/kg ( Rabbit ) 3124 ppm ( Rat ) 1 h

Water 90 mL/kg ( Rat ) None Established None Established

Chronic Toxicity

Chemical Name ACGIH IARC NTP OSHAAmmonium fluoride None Established None Established None Established None EstablishedHydrochloric acid None Established None Established None Established None Established





Ammonium fluoride None Established None Established None EstablishedHydrochloric acid None Established None Established None Established

Water None Established None Established None Established

_____________________________________________________________________________________________

LiquidAppearance Clear Colorless

pH

Vapor Pressure No data available

2

Vapor Density <1(Air = 1)

Flash Point N/A Boiling Point/Range 100 °C

Odor None



Page 3 / 6

Physical State


_____________________________________________________________________________________________



Flea)Ammonium fluoride None Established LC50= 364.0 mg/L

Pimephales promelas 96 hNone Established None Established

Hydrochloric acid None Established LC50= 282 mg/L Gambusiaaffinis 96 h

None Established None Established


Chemical Name Log PowAmmonium fluoride None EstablishedHydrochloric acid None Established

Water None Established


Waste Disposal Method This material, as supplied, is not a hazardous waste according to state and Federalregulations (40 CFR 261). This material could become a hazardous waste if it is mixed withor otherwise comes in contact with a hazardous waste, if chemical additions are made tothis material, or if the material is processed or otherwise altered. Consult 40 CFR 261 todetermine whether the altered material is a hazardous waste pursuant to Federalregulations, and the applicable state requirements for the specific area of disposal. Consultthe appropriate state, regional, or local regulations for additional requirements. When incompliance with local regulations; neutralize reagent (to pH 6-7)with dilute base(NaOH/soda ash/slaked lime), then rinse to drain with excess water. .

Chemical NameAmmonium fluoride - 12125-

01-8Hydrochloric acid - 7647-01-

0Water - 7732-18-5



Ammonium fluoride - 12125-01-8


Hydrochloric acid - 7647-01-0



Chemical Name California Hazardous Waste StatusAmmonium fluoride Toxic; CorrosiveHydrochloric acid Toxic; Corrosive; Reactive


DOT Not regulated

IATA Not regulated




_____________________________________________________________________________________________

Page 4 / 6




_____________________________________________________________________________________________Component TSCA DSL EINECS/ELIN

CSENCS IECSC KECL PICCS AICS

Ammonium fluoride 12125-01-8 ( 1.7 )

Present X X 1-14; 1-310; 1-311

X KE-01665 X X

Hydrochloric acid 7647-01-0 ( 1.4 )

T X X X X KE-20189X

X X

Water 7732-18-5 ( to 100% )



SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.


Ammonium fluoride 12125-01-8 1.7 1.0Hydrochloric acid 7647-01-0 1.4 1.0

Water 7732-18-5 to 100% None Established


Clean Water ActComponent CWA - Reportable


SubstancesAmmonium fluoride 12125-01-8 ( 1.7 )

100 lb None Established None Established X

Hydrochloric acid 7647-01-0 ( 1.4 )

5000 lb None Established None Established X

Water 7732-18-5 ( to 100% )




Ammonium fluoride 12125-01-8 1.7 None Established None Established None Established None EstablishedHydrochloric acid 7647-01-0 1.4 Present None Established None Established None Established

Water 7732-18-5 to 100% None Established None Established None Established None Established

CERCLA

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQsAmmonium fluoride 100 lb None EstablishedHydrochloric acid 5000 lb 5000 lb

Water None Established None Established


Chemical Name CAS-No California Prop. 65Ammonium fluoride 12125-01-8 None EstablishedHydrochloric acid 7647-01-0 None Established

Water 7732-18-5 None Established

Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode IslandAmmonium fluoride X X X None Established XHydrochloric acid X X X X X

_____________________________________________________________________________________________


Page 5 / 6Published Date: 25-Feb-2010


_____________________________________________________________________________________________Water None Established None Established None Established None Established None Established



Chemical Name Carcinogen Status Exposure LimitsAmmonium fluoride None Established None EstablishedHydrochloric acid None Established None Established

Water None Established None Established

Canada

WHMIS Hazard ClassNon-controlled




Revision Date



End of MSDS

_____________________________________________________________________________________________

Transport SymbolNFPA


HMISNot regulated


PPE

Revision Number 0



Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.


Synonyms

Chronic Effects

none

Emergency Telephone Number

Chronic exposure causes detriment of thyroid gland function Prolonged skin contact may defat the skin and produce dermatitis

24 Hour Emergency Number (CHEM-TEL):USA, Canada, Puerto Rico 1-800-255-3924Outside North American Continent (Call collect) 813-248-0585


Product Name

Principle Routes of Exposure Ingestion, and, Inhalation.


Product Code(s)

Recommended Use Test kit reagent. Industrial (not for food or food contact use). Laboratory chemicals.

Acute Toxicity

6311


Eyes May cause irritation. May cause redness, itching, and pain.

MANGANESE PERIODATE REAGENT

Skin May cause irritation. Symptoms can include redness, itching, and pain.Inhalation May cause irritation of respiratory tract.


Weight %Sodium metaperiodate 7790-28-5 1-5

Sodium sulfate 7757-82-6 to 100%

WARNING!

_____________________________________________________________________________________________

Emergency OverviewHarmful if swallowedHarmful by inhalation

May cause skin, eye, and respiratory tract irritationIngestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea


Chemical Name CAS-No

Page 1 / 8

Physical State Crystalline, Powder

Published Date: 17-Nov-2011

Appearance White Odor Slight

_____________________________________________________________________________________________MANGANESE PERIODATE REAGENT Product Code(s) 6311

Inhalation

Specific Hazards Arising from the ChemicalThis is a strong oxidizer and will react vigorously or explosively with many materials including fuels.

Move to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a physician.

Do not breathe dust. Do not get in eyes, on skin, or on clothing. Show this safety datasheet to the doctor in attendance.


Eye Contact

Skin Contact Wash off immediately with soap and plenty of water for at least 15 minutes while removingall contaminated clothing and shoes. If irritation develops or persists, consult physician.

Flammable Properties


Not flammable. Non-combustible, substance itself does not burnbut may decompose upon heating to produce corrosive and/ortoxic fumes.

Ingestion DO NOT induce vomiting unless directed to do so by a physician or poison control center.Drink plenty of water. Never give anything by mouth to an unconscious person. Consult aphysician.

Handling Handle in accordance with good industrial hygiene and safety practice. Prevent contactwith skin, eyes, and clothing. Do not ingest. Do not eat, drink, or smoke when using thisproduct.


Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.Consult a physician.

Storage Keep containers tightly closed in a dry, cool, and well-ventilated place. Keep out of thereach of children.



General Advice

Protection of First-aiders

Contains a chemical that is an oxidizer: Sodium metaperiodate

Use personal protective equipment. See Section 8 for more detail. Do not usemouth-to-mouth method if victim ingested or inhaled the substance; induce artificialrespiration with the aid of a pocket mask equipped with a one-way valve or other properrespiratory medical device.

Explosion Data

Flammability 0

Personal Precautions Refer to Section 8. Ensure adequate ventilation. Wear protective gloves/clothing andeye/face protection.

HMIS Flammability 0

Physical and ChemicalHazards OX

Methods for Containment Sweep up in a manner that does not dispurse dust and shovel into suitable containers fordisposal.

Stability 1

_____________________________________________________________________________________________

Health Hazard 1

Stability 1


Methods for Cleaning Up After cleaning, flush away traces with water.

NFPA

Page 2 / 8

Health Hazard 1



Hazardous polymerization does not occur.

None Known


Respiratory Protection Maintain adequate ventilation.


None Known

Acute Toxicity

None Known

Chemical Name

Stability


Stable under normal conditions of use and storage.

ACGIH TLV

Sodium metaperiodate None Known None Known None Known

Hygiene Measures

Sodium sulfate None Known None Known None Known

Handle in accordance with good industrial hygiene and safety practice. Wash hands beforebreaks and immediately after handling the product. Do not eat, drink or smoke when usingthis product.

Incompatible Products Strong reducing agents. Combustible materials. Organic material. Incompatible withstrong acids and bases.

Chronic Toxicity

Sodium metaperiodate 7790-28-5

None Known

Chronic Toxicity Chronic exposure causes detriment of thyroid gland function . Prolonged skin contact maydefat the skin and produce dermatitis.


Conditions to Avoid Heat, flames and sparks. Exposure to air or moisture over prolonged periods.

Chemical Name ACGIH IARC NTP OSHA

None Known

Sodium metaperiodate None Known None Known None Known None Known

None Known

Sodium sulfate None Known None Known None Known None Known

Hazardous Decomposition Products Carbon oxides (COx). Nitrogen oxides (NOx). Sulfur oxides (SOx). Ammonia.

Eye/Face Protection Safety glasses with side-shields. Goggles.

OSHA PEL NIOSH IDLH


Skin and Body Protection Wear protective gloves/clothing.

Sodium sulfate 7757-82-6

Hazardous Polymerization


Appearance White


Odor Slight


pH

_____________________________________________________________________________________________

4 (0.1g/10mL water)Boiling Point/Range No data available


Physical State Crystalline, Powder

Page 3 / 8Published Date: 17-Nov-2011

Flammability Limits in Air Not flammable




Sodium metaperiodate None Known None Known None Known

Endocrine Disruptor Information

Sodium sulfate None Known None Known None Known

.


Persistence and Degradability Based on components, product is expected to be readily biodegradable.

Toxicity to Algae Toxicity to Fish

Contaminated Packaging Dispose of in accordance with local regulations.




May cause long-term adverse effects in the aquatic environment.



Sodium metaperiodate None Known

Sodium metaperiodate -7790-28-5



Sodium sulfate - 7757-82-6 None Known None Known None Known None Known

Sodium sulfate None Known


Ecotoxicity

Sodium sulfate None Known LC50= 13 mg/L Lepomismacrochirus 96 h

None Known EC50 = 2564 mg/L 48 hEC50 = 4547 mg/L 96 h

_____________________________________________________________________________________________


Page 4 / 8

Waste Disposal Method


Dispose of contents/container in accordance with local regulation.

Chemical Name


Packing Group III


Packing Group

IMDG/IMO

III


Proper Shipping Name OXIDIZING SOLID, N. O. S. (3% Sodium metaperiodate)

OXIDIZING SOLID, N. O. S. (3% Sodium metaperiodate)

Hazard Class 5.1UN-No 1479

DOT

IATA

Packing Group III

Hazard Class

UN-No 1479

5.1

_____________________________________________________________________________________________

Proper Shipping Name OXIDIZING SOLID, N. O. S. (3% Sodium metaperiodate)Hazard Class 5.1

Page 5 / 8

UN-No


1479


KE-31609 X

Reactive Hazard Yes

X


Clean Water Act

Component TSCA

.Component CWA - Reportable


Substances

DSL EINECS/ELINCS

Sodium metaperiodate 7790-28-5 ( 1-5 )



Sodium sulfate 7757-82-6 ( to 100% )


ENCS IECSC KECL PICCS


Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product does not contain any HAPs.

AICS




Sodium metaperiodate 7790-28-5 1-5 None Known None Known None Known None Known


Sodium sulfate 7757-82-6 to 100% None Known None Known None Known None Known

Weight % SARA 313 - ThresholdValues %

Present X

CERCLA

Sodium metaperiodate 7790-28-5 1-5 None Known


X 1-444

Sodium metaperiodate None Known None Known

Sodium sulfate 7757-82-6

Sodium sulfate None Known None Known

to 100% None Known

X KE-31572


X X




Acute Health Hazard

Chemical Name CAS-No California Prop. 65

Yes


Present

Chronic Health Hazard Yes

_____________________________________________________________________________________________

X X

Fire Hazard No

1-501 X

Page 6 / 8Published Date: 17-Nov-2011



Revision Date 17-Nov-2011

Revision NoteInitial Release




None Known

None Known

Sodium sulfate


X None Known X None Known


None Known

Sodium metaperiodate


C



7790-28-5


Sodium sulfate


Chemical Name

Mexico - Grade

Massachusetts New Jersey Pennsylvania Illinois


Rhode Island

7757-82-6


NFPA

None Known

None Known

Sodium metaperiodate

Sodium sulfate

HMIS


_____________________________________________________________________________________________

None Known

PPE


Transport Symbol

None Known

Page 7 / 8

Canada




End of MSDS

_____________________________________________________________________________________________

Published Date: 17-Nov-2011 Page 8 / 8


MSDS



Manganese Buffer Reagent



TLVPEL%

26

74

5949-29-1

7558-79-4


CAS#/Name

Citric Acid

Sodium Phosphate, Dibasic

Hazard

3. Hazards Overview

Dust may irritate eyes, skin, respiratory tract.

Primary Route Of Entry: Inhalation





1

6310 Manganese Buffer ReagentProduct Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:


Drink plenty of water. Consult a physician.


Flush with water. Wash with soap and water.





N/A

Not a fire hazard

N/A

N/A


Spray with water to keep dust to minimum. Sweep up, dissolve in water, and flush to drain with excess water.


Store in cool, dry, storage area away from incompatible materials.

2



Normal

Gloves Eye Protection Lab Coat

Ventilation


N/AWork/Hygenic Practices:



NoneSolubleWhite Crystalline powder

6 (0.1g/10ml water)

Vapor Density: N/AN/AVapor Pressure:



Stable: Yes

N/A

N/A





Target Organs: N/A

3




13. Disposal ConsiderationsDissolve and wash down drain with water. Dispose according to federal, state and local regulations.





TSCAEurope EC DSL NDSL Australia JapanHazard





CERCLARCRA 261.33

TSCA 8(D)Listed

4


Ingredient



Poison ScheduleAcute Chronic Fire Pressure Reactivity

This MSDS Is WHMIS Compliant

6310productas a whole




5


MSDS



Tricon Flocculating Solution



TLVPEL

None Established

None Established

%

<0.1

to 100%

9003-05-8

7732-18-5


CAS#/Name

Nonionic Polyacrylamide

Water

None Established

None Established

Hazard

No

No

3. Hazards Overview

N/A

Primary Route Of Entry:





1

5941 Tricon Flocculating SolutionProduct Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Flush thoroughly with water for 15 minutes, lifting eyelids occasionally. If irritation develops consult physician.

Drink several glasses of water. Consult physician.


Flush thoroughly with water. Wash skin with soap. If irritation develops, consult physician.





N/A

Not a fire hazard

N/A

N/A


Absorb spill on inert material, containerize and hold for sanitary disposal. Dispose according to federal, state, and local regulations. If permitted, flush to drain with excess water.


Store in cool, dry, area.

2



Normal

N/A

Ventilation


Work/Hygenic Practices:



NoneSolubleClear Colorless Liquid

6

Vapor Density: Unknown<17 mm Hg @ 20° CVapor Pressure:

Boiling Point: ca. 100° CN/AMelting Point:


Stable: Yes

N/A

N/A





Target Organs: N/A

3



Information not available.





Yes Yes9003-05-8Polyacrylamide polymer


Yes No Yes Yes


Hazard

No

No





CERCLARCRA 261.33

TSCA 8(D)

9003-05-8Polyacrylamide polymer


No No

No No No

No No No

No No

Listed

No

No

No

No

4


Ingredient



Poison Schedule

9003-05-8Polyacrylamide polymer


None Allocated

None AllocatedNo

No None Allocated

None Allocated

No

No

No

No

No No

No No



Yes




5


Product Name Soil Flocculating Reagent


Synonyms none

Recommended Use Laboratory chemicals. Industrial (not for food or food contact use). Test kit reagent.




Potential Health EffectsPrinciple Routes of Exposure Ingestion

Acute ToxicityEyes No known effect based on information supplied.Skin No known effect based on information supplied.Inhalation Not an expected route of exposure.Ingestion No known effect based on information supplied.

Chronic Effects No known effect.

Aggravated Medical Conditions No information available.

Environmental Hazard No information available.


Chemical Name CAS-No Weight %Polyacrylamide (Superfloc N-300 Flocculant) 000 <0.1

Water 7732-18-5 to 100%



_____________________________________________________________________________________________

Revision Number 0



Emergency OverviewKeep out of the reach of children

Published Date: 22-Sep-2010 Page 1 / 6

Physical State Liquid Odor OdorlessAppearance Clear, colorless solution

Soil Flocculating Reagent

_____________________________________________________________________________________________Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.

If irritation persists or develops, contact a physician.

Skin Contact Wash off immediately with soap and plenty of water for at least 15 minutes while removingall contaminated clothing and shoes. If irritation develops or persists, consult physician.

Inhalation Move to fresh air. If breathing is difficult, give oxygen.

Ingestion Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person.

Notes to Physician See MSDS (material safety data sheet) for additional information. Treat symptomatically.

Protection of First-aiders Use personal protective equipment. See Section 8 for more detail.


Flammable Properties Not a fire hazard.


Explosion Data


Personal Precautions Do not get in eyes, on skin, or on clothing.

Methods for Containment Soak up with inert absorbent material, containerize, and hold for disposal.



Handling Handle in accordance with good industrial hygiene and safety practice. Do not ingest. Donot eat, drink or smoke when using this product. Prevent contact with skin, eyes andclothing.

Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Keep from freezing.Keep out of the reach of children.


Chemical Name ACGIH TLV OSHA PEL NIOSH IDLHPolyacrylamide (Superfloc N-300

Flocculant) 000


Water 7732-18-5




_____________________________________________________________________________________________

Odor Odorless

Flammability 0

Physical State Liquid pH 6.0 - 7.0

Stability 0

Boiling Point/Range 100 °C


Health Hazard 0

Published Date: 22-Sep-2010

Appearance

Page 2 / 6

Clear, colorless solution



_____________________________________________________________________________________________


Stability Stable.

Incompatible Products No materials to be especially mentioned.

Conditions to Avoid Do not freeze.

Hazardous Decomposition Products None known based on information supplied.



Acute Toxicity

Product Information Product does not present an acute toxicity hazard based on known or supplied information.

Chemical Name LD50 Oral LD50 Dermal LC50 InhalationPolyacrylamide (Superfloc N-300

Flocculant)None Known None Known None Known

Water 90 mL/kg ( Rat ) None Known None Known

Chronic Toxicity

Chronic Toxicity No known effect.

Carcinogenicity There are no known carcinogenic chemicals in this product.

Chemical Name ACGIH IARC NTP OSHAPolyacrylamide (Superfloc

N-300 Flocculant)None Known None Known None Known None Known

Water None Known None Known None Known None Known




Polyacrylamide (Superfloc N-300Flocculant)


Water None Known None Known None Known



Flea)Polyacrylamide (Superfloc

N-300 Flocculant)None Known None Known None Known None Known


Chemical Name Log PowPolyacrylamide (Superfloc N-300

Flocculant)None Known

_____________________________________________________________________________________________

Essentially the same as water


Vapor Pressure Essentially the same as water


Vapor Density


_____________________________________________________________________________________________Water None Known


Waste Disposal Method Dispose of in accordance with local regulations. Can be disposed as waste water, when incompliance with local regulations.

Chemical NamePolyacrylamide (Superfloc

N-300 Flocculant) - 000Water - 7732-18-5



Polyacrylamide (SuperflocN-300 Flocculant) - 000


Water - 7732-18-5 None Known None Known None Known None Known


DOT Not regulated

IATA Not regulated






Polyacrylamide(Superfloc N-300

Flocculant) 000 ( <0.1 )

TSCA DSL EINECS/ELINCS


Water 7732-18-5 ( to 100% )





Polyacrylamide (Superfloc N-300 Flocculant) 000 <0.1 None KnownWater 7732-18-5 to 100% None Known

SARA 311/312 Hazard CategoriesAcute Health Hazard NoChronic Health Hazard NoFire Hazard NoSudden Release of Pressure Hazard NoReactive Hazard No

Clean Water Act

_____________________________________________________________________________________________


Page 4 / 6Published Date: 22-Sep-2010


_____________________________________________________________________________________________Component CWA - Reportable


SubstancesPolyacrylamide (Superfloc N-300

Flocculant) 000 ( <0.1 )


Water 7732-18-5 ( to 100% )


Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air ActAmendments of 1990.



Polyacrylamide(Superfloc N-300

Flocculant)

000 <0.1 None Known None Known None Known None Known

Water 7732-18-5 to 100% None Known None Known None Known None Known

CERCLA

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQsPolyacrylamide (Superfloc N-300 Flocculant) None Known None Known

Water None Known None Known


Chemical Name CAS-No California Prop. 65Polyacrylamide (Superfloc N-300 Flocculant) 000 None Known

Water 7732-18-5 None Known


Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode IslandPolyacrylamide (Superfloc

N-300 Flocculant)None Known None Known None Known None Known None Known

Water None Known None Known None Known None Known None Known


Mexico - Grade

Chemical Name Carcinogen Status Exposure LimitsPolyacrylamide (Superfloc N-300 Flocculant) None Known None Known


Canada


WHMIS Hazard ClassNon-controlled


_____________________________________________________________________________________________

Page 5 / 6




_____________________________________________________________________________________________



Revision Date



End of MSDS

_____________________________________________________________________________________________


HMISNot regulated

PPE Transport Symbol


NFPA

Page 6 / 6




Chronic Effects

OSHA Regulatory Status While this material is not considered hazardous by the OSHA Hazard CommunicationStandard (29 CFR 1910.1200), this MSDS contains valuable information critical to the safehandling and proper use of the product. This MSDS should be retained and available foremployees and other users of this product.

Recommended Use Test kit reagent. Laboratory chemicals. Industrial (not for food or food contact use).


Potential Health EffectsPrinciple Routes of Exposure Skin and eye contact

Product Name

Product Code(s)

Company

Acute Toxicity

LaMotte Company, Inc.802 Washington AvenueP.O. Box 329Chestertown, MD 21620USA

5638


Eyes Contact with eyes may cause irritation.

Charcoal Suspension


Skin No hazard from product as supplied.Inhalation Not an expected route of exposure.


Ingestion May cause gastrointestinal discomfort if consumed in large amounts.


7732-18-5 to 100%


Chemical Name CAS-No Weight %

Emergency OverviewThe product contains no substances which at their given concentration are considered to be hazardous to health

_____________________________________________________________________________________________

Carbon 7440-44-0 20Water

Page 1 / 7

Odor None

Published Date: 24-Jun-2011

Physical State LiquidAppearance Black particles in suspension

_____________________________________________________________________________________________Charcoal Suspension Product Code(s) 5638

Flash Point


Not applicable

Inhalation Not expected.

Storage Keep containers tightly closed in a dry, cool, and well-ventilated place. Keep out of thereach of children.


Protection of First-aiders Use personal protective equipment. See Section 8 for more detail. Do not usemouth-to-mouth method if victim ingested or inhaled the substance; induce artificialrespiration with the aid of a pocket mask equipped with a one-way valve or other properrespiratory medical device.

Suitable Extinguishing Media

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

Dry chemical, CO2, alcohol-resistant foam or water spray.

Carbon 7440-44-0

None Known TWA: 15 mg/m3

TWA: 5 mg/m3

None Known

Wash off with warm water and soap.

Water 7732-18-5


Explosion Data


Eye Contact




Ingestion

Respiratory Protection None required under normal usage.

Drink plenty of water. If symptoms persist or develop contact physician.

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Ifirritation persists or develops, contact a physician.

Flammable Properties Not a fire hazard.


Skin Contact

HMIS Flammability 0


Methods for Cleaning Up If local regulations permit, rinse liquid portion to drain and solid portion to landfill. Aftercleaning, flush away traces with water.

Stability 0Health Hazard 0

_____________________________________________________________________________________________

Stability 0


NFPA

Health Hazard 0

Flammability 0

Page 2 / 7Published Date: 24-Jun-2011

Personal Precautions Use personal protective equipment. Refer to Section 8. Avoid contact with skin, eyes, andclothing.

_____________________________________________________________________________________________Product Code(s) 5638Charcoal Suspension

Water 90 mL/kg ( Rat ) None Known None Known

Hygiene Measures

Incompatible Products


Chronic Toxicity

Strong oxidizing agents.



Carbon None Known None Known None Known None Known

Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink orsmoke when using this product. Wash hands before breaks and immediately after handlingthe product.


Conditions to Avoid Incompatible products.

Acute Toxicity




Stability Stable under normal conditions of use and storage.

Carbon None Known None Known None KnownWater None Known None Known None Known


Hazardous Decomposition Products


Carbon oxides (COx).

Carbon 10000 mg/kg ( Rat ) None Known None Known


/

Vapor Density <1(Air = 1)

Physical State LiquidAppearance Black particles in suspension

212ca. 100Flash Point Not applicable

Odor

_____________________________________________________________________________________________

°F

None

°C

pH 7

Vapor Pressure <17 mmHg @ 20°C


Boiling Point/Range



Ecotoxicity

Water


None Known

Carbon None Known None Known None Known None KnownWater None Known None Known




DOT Not regulated


Chemical Name


IATA Not regulated

This material, as supplied, is not a hazardous waste according to Federal regulations (40CFR 261). Can be disposed as waste water, when in compliance with local regulations.

Toxicity to Algae


Toxicity to Fish



Carbon

_____________________________________________________________________________________________



None Known

Page 4 / 7

Carbon - 7440-44-0





KE-35400 X

Reactive Hazard No

X


Clean Water Act

Component TSCA

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42).



DSL EINECS/ELINCS

Carbon 7440-44-0 ( 20 )



Water 7732-18-5 ( to 100% )





AICS



Carbon 7440-44-0 ( 20 )

Carbon 7440-44-0 20 None Known None Known None Known None Known




Present X

CERCLA

Carbon 7440-44-0 20 None Known


X ENCS

Carbon None Known None Known

Water 7732-18-5


to 100% None Known

X KE-04671


X X





Water 7732-18-5 ( to 100% )

Present

_____________________________________________________________________________________________


X X

Fire Hazard No

Page 5 / 7

ENCS


X


Revision Date 24-Jun-2011





Canada

None Known X

Carbon



Component

Not regulated

WHMIS Hazard Class


Carbon 7440-44-0 ( 20 )



Water 7732-18-5 ( to 100% )


California Prop. 65


Chemical Name

Water 7732-18-5

Mexico - Grade

Chemical Name Massachusetts New Jersey Pennsylvania


Illinois

NFPA

Rhode Island

Carbon None Known Mexico: TWA= 2 mg/m3

HMIS

None Known

CAS-No

Water

PPE

None Known

_____________________________________________________________________________________________

None Known

Carbon

Transport Symbol

X None Known X


_____________________________________________________________________________________________Product Code(s) 5638Charcoal Suspension


_____________________________________________________________________________________________

End of MSDS

Published Date: 24-Jun-2011 Page 7 / 7


MSDS



Manganese-Magnesium

Product Code: 5145

Test Solution #2



TLVPEL

C 2 mg/m³

None Established

%

15

85

1310-73-2

7732-18-5


CAS#/Name

Sodium Hydroxide

Water

C 2 mg/m³

None Established

Hazard

Yes

No

3. Hazards Overview

Poison! Danger! Corrosive. Liquid and mist cause severe burns to all body tissue. Inhalation may cause coughing, chest pains, damage to lungs. Ingestion may be fatal. Reacts with water, acids, and other materials.

Primary Route Of Entry: Eye Skin Ingestion Inhalation


Sodium hydroxide has been investigated as a mutagen.




1

5145Test Solution #2Manganese-MagnesiumProduct Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Immediately flush with water for 15 minutes while periodically lifting upper and lower eyelids. Contact physician immediately.

DO NOTinduce vomiting. Drink several glasses of water or milk. Contact physician immediately.

Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, begin artificial respiration and seek immediate medical attention.

Flush with water for 15 minutes while removing affected clothing/shoes. Wash. Contact physician. Wash clothing prior to reuse.





N/A

Not a fire hazard

Wear protective equipment.

Can react with metals to produce hydrogen gas which can form an explosive mixture with air.


Wear appropriate PPE and ventilate area. Neutralize spill with 6M hydrochloric (or similar) acid, place into chemical waste container, and hold for disposal. Dispose according to federal, state, and local regulations.


Store in cool, dry, area away from incompatible materials such as strong acids and metals

2



Normal

chemical glovessafety glasses


Ventilation


Avoid all contact with eyes, skin, or clothing. Wash after handling.Work/Hygenic Practices:




14

Vapor Density: Unknown<13 mm @ 20° CVapor Pressure:

Boiling Point: 107° Cca. -10° CMelting Point:


Stable: Yes

Heat

Strong acids, metals





Target Organs: Corrosive to all body parts Eyes Skin

3





14. Transportation Information

Proper Shipping Name:SODIUM HYDROXIDE SOLUTIONDOT:

IATA: SODIUM HYDROXIDE SOLUTION

Hazard Class/Div:

88

IATA:DOT:

UN: 1824

IIPacking Group:




Yes Yes1310-73-2Sodium Hydroxide


Yes No Yes Yes


Hazard

Yes

No





CERCLARCRA 261.33

TSCA 8(D)

1310-73-2Sodium Hydroxide


No No

No No No

1000 No No

No No

Listed

No

No

No

No

4


Ingredient



Poison Schedule



S6

None AllocatedNo

Yes 2R

None Allocated

No

No

No

No

No Yes

No No


5145 Yes Yes No No Yes 2R S6productas a whole

Yes




5


Product Name Aluminum Test Solution


Synonyms none





OSHA Regulatory Status Safety information is given for exposure to the reagent as sold and considers exposure tothe chemical if user has direct eye and skin contact.

Potential Health EffectsPrinciple Routes of Exposure Skin contact, Ingestion, and, Inhalation

Acute ToxicityEyes Irritating to eyes.Skin Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis.Inhalation May cause irritation of respiratory tract. Symptoms of overexposure include dizziness,

headache, drowsiness, cough..Ingestion May cause drowsiness and dizziness. Potential for aspiration if swallowed.

Chronic EffectsAggravated Medical Conditions Hypersensitivity may occur in those with preexisting skin disorders. Preexisting eye

disorders.


Chemical Name CAS-No Weight %Hematein 475-25-2 0.13

Isopropyl alcohol 67-63-0 to 100%

_____________________________________________________________________________________________

WARNING!

Revision Number 0

Emergency OverviewFlammable liquid and vapor

Vapors are heavier than air. Vapor may travel across the ground and reach remote ignition sources causing aflashback fire danger

Vapors may be irritating to eyes, nose, throat, and lungs



Page 1 / 7


Appearance Red, Transparent Physical State Liquid Odor Alcohol

Aluminum Test Solution

_____________________________________________________________________________________________




Skin Contact Wash skin with soap and water. If irritation develops or persists, consult physician.

Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificialrespiration and contact emergency personnel. Call a physician immediately.

Ingestion Do not induce vomiting without medical advice. If accidentally swallowed obtain immediatemedical attention..

Protection of First-aiders Use personal protective equipment. Do not use mouth-to-mouth method if victim ingested orinhaled the substance; induce artificial respiration with the aid of a pocket mask equippedwith a one-way valve or other proper respiratory medical device.


Flammable Properties Flammable.

Flash Point 12 °CMethod Closed cup


Explosion Data



Methods for Containment Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical wastecontainer. Dike far ahead of spill; use dry sand to contain the flow of material. A vaporsuppressing foam may be used to reduce vapors.

Methods for Cleaning Up Soak up with inert absorbent material. Pick up and transfer to properly labeled containers.Minimize the amount spilled and supress resultant vapors.


Handling Handle in accordance with good industrial hygiene and safety practice. Prevent contact withskin, eyes, and clothing. Do not ingest. Do not eat, drink, or smoke when using this product.

Storage Keep containers tightly closed in a dry, cool, and well-ventilated place. Keep away fromheat and sources of ignition. Keep out of the reach of children.


Chemical Name ACGIH TLV OSHA PEL NIOSH IDLHHematein 475-25-2


_____________________________________________________________________________________________


Health Hazard 1



Flammability 3

Page 2 / 7

Stability 0


_____________________________________________________________________________________________Isopropyl alcohol

67-63-0= 400 ppm STELTWA: 200 ppm

TWA: 980 mg/m3

TWA: 400 ppmIDLH: 2000 ppmTWA: 400 ppm

TWA: 980 mg/m3

STEL: 1225 mg/m3

STEL: 500 ppm

NIOSH IDLH: Immediately Dangerous to Life or Health

Engineering Measures Ensure adequate ventilation, especially in confined areas.

Personal Protective EquipmentEye/Face Protection Safety glasses with side-shields.Skin and Body Protection Wear protective gloves/clothing. Repeated or prolonged contact:. Rubber gloves. Incidental

contact/splash protection:. Neoprene gloves.Respiratory Protection Use only with adequate ventilation. In case of insufficient ventilation wear suitable

respiratory equipment.

Hygiene Measures Do not eat, drink or smoke when using this product.




Incompatible Products Strong inorganic acids and oxidizing agents.

Conditions to Avoid Heat, flames and sparks.

Hazardous Decomposition Products Carbon oxides.



Acute Toxicity

Chemical Name LD50 Oral LD50 Dermal LC50 InhalationHematein None Known None Known None Known

Isopropyl alcohol 4396 mg/kg ( Rat ) 12800 mg/kg ( Rabbit )12800 mg/kg ( Rat )

72.6 mg/L ( Rat ) 4 h

Chronic Toxicity

_____________________________________________________________________________________________

Red TransparentpH Not applicable


Specific Gravity 0.78-0.79 @ 20°C

Flash Point

Water Solubility Completely soluble

12 °C

Vapor Pressure 44 mmHg @ 25°C Vapor Density 2 @ 20°C (Air=1)

Method Closed cup

Odor Alcohol

Autoignition Temperature 425 °C Boiling Point/Range 82-83 °C

Physical State Liquid

Published Date: 27-Jan-2011 Page 3 / 7

Appearance

Lower 2%Upper 12%

Explosion LimitsUpper 12%

Flammability Limits in Air

Lower 2%


_____________________________________________________________________________________________

Chemical Name ACGIH IARC NTP OSHAHematein None Known None Known None Known None Known

Isopropyl alcohol None Known Group 1 None Known X

IARC: (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansOSHA: (Occupational Safety & Health Administration)X - Present




Hematein None Known None Known None KnownIsopropyl alcohol None Known None Known None Known



Flea)Hematein None Known None Known None Known None Known

Isopropyl alcohol EC50 > 1000 mg/L 72 hEC50 > 1000 mg/L 96 h

LC50= 61200 mg/LPimephales promelas 96 h



EC50 = 35390 mg/L 5 min EC50 = 13299 mg/L 48 h

Persistence and Degradability Readily biodegradable.

Bioaccumulation/Accumulation This material is not expected to significantly bioaccumulate.

Mobility Will likely be mobile in the environment due to its water solubility.

Chemical Name Log PowHematein None Known

Isopropyl alcohol = 0.05 25 °C


Waste Disposal Method Should not be released into the environment. Dispose of contents/container in accordancewith local regulation.

Chemical NameHematein - 475-25-2

Isopropyl alcohol - 67-63-0



Hematein - 475-25-2 None Known None Known None Known None KnownIsopropyl alcohol - 67-63-0 None Known None Known None Known None Known

Chemical Name California Hazardous Waste StatusIsopropyl alcohol Toxic, Ignitable


DOTProper Shipping Name ISOPROPANOL

_____________________________________________________________________________________________




_____________________________________________________________________________________________Hazard Class 3UN-No 1219Packing Group II

IATAUN-No 1219Proper Shipping Name ISOPROPANOLHazard Class 3Packing Group II

IMDG/IMOProper Shipping Name ISOPROPANOLHazard Class 3UN-No 1219Packing Group II





Hematein 475-25-2 ( 0.13 )

Present X X 5-3660 IECSC KECL PICCS X

Isopropyl alcohol 67-63-0 ( to 100% )





Hematein 475-25-2 0.13 None KnownIsopropyl alcohol 67-63-0 to 100% 1.0

SARA 311/312 Hazard CategoriesAcute Health Hazard YesChronic Health Hazard YesFire Hazard YesSudden Release of Pressure Hazard NoReactive Hazard No

Clean Water ActThis product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21and 40 CFR 122.42).



Hematein 475-25-2 ( 0.13 )


Isopropyl alcohol 67-63-0 ( to 100% )

None Known None Known None Known x



Hematein 475-25-2 0.13 None Known None Known None Known None KnownIsopropyl alcohol 67-63-0 to 100% None Known None Known None Known None Known

_____________________________________________________________________________________________

Page 5 / 7




_____________________________________________________________________________________________

CERCLA

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQsHematein None Known None Known

Isopropyl alcohol None Known None Known


Chemical Name CAS-No California Prop. 65Hematein 475-25-2 None Known

Isopropyl alcohol 67-63-0 None Known

Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode IslandHematein None Known None Known None Known None Known None Known

Isopropyl alcohol X X X None Known X


Mexico - Grade

Chemical Name Carcinogen Status Exposure LimitsHematein None Known None Known

Isopropyl alcohol None Known Mexico: TWA= 980 mg/m3

Mexico: TWA= 400 ppm

Canada

WHMIS Hazard ClassB2 Flammable liquidD2B - Poisonous and infectious material - Other effects - Toxic

Chemical Name NPRIIsopropyl alcohol X

LegendX - Listed


_____________________________________________________________________________________________

NFPA HMIS



PPE

Page 6 / 7

Transport Symbol


_____________________________________________________________________________________________



Revision Date



End of MSDS

_____________________________________________________________________________________________


Published Date: 27-Jan-2011 Page 7 / 7



Acute ToxicityEyes Corrosive to the eyes and may cause severe damage including blindness.


Skin Corrosive. Contact with skin causes irritation to severe burns. Can cause redness, pain,and severe skin burns . Harmful if absorbed through skin.



Inhalation Poison - may be fatal if inhaled. Inhalation of corrosive mist may cause coughing, choking,headache, dizziness, and weakness for several hours. Pulmonary edema may occur withtightness in the chest, shortness of breath, bluish skin, decreased blood pressure, andincreased heart rate. Depending on exposure, the effects from inhalation of corrosive mistscan vary from mild irritation to serious damage to respiratory tract.

Ingestion Very toxic if swallowed. Average lethal dose for inorganic mercury salts is about 1 gram.Corrosive. Can cause immediate pain and burning in the mouth, throat, esphogus and GItract. May cause nausea, vomiting, and diarrhea, and in severe cases death.

Recommended Use

Chronic Effects

Test kit reagent. Laboratory chemicals. Industrial (not for food or food contact use).


Prolonged exposure may cause chronic effects

OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29CFR 1910.1200). Safety information is given for exposure to the reagent as sold andconsiders exposure to the chemical if user has direct eye and skin contact.

Main Symptoms Prolonged contact has a destructive effect on tissue.

Product Name


Product Code(s)

Principle Routes of Exposure Eye contact, Inhalation, skin contact, and ingestion.


_____________________________________________________________________________________________

4798

AMMONIA NITROGEN REAGENT #2 (NESSLER REAGENT)

DANGER! POISON!

Emergency OverviewMAY BE FATAL IF SWALLOWED

CorrosiveHarmful by inhalation

Harmful in contact with skinLiquid and mist can cause severe burns to all body tissue

Water reactive

Page 1 / 9

Odor Odorless


Physical State LiquidAppearance Clear yellow solution

_____________________________________________________________________________________________AMMONIA NITROGEN REAGENT #2 (NESSLER REAGENT) Product Code(s) 4798

General Advice Do not get in eyes, on skin, or on clothing. Do not breathedust/fume/gas/mist/vapors/spray. Do not delay care and transport of a seriously injuredperson. Show this safety data sheet to the doctor in attendance.


Skin Contact Wash off immediately with soap and plenty of water for at least 15 minutes while removingall contaminated clothing and shoes. Remove and wash contaminated clothing beforere-use. Immediate medical attention is required.


Inhalation


Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificialrespiration and contact emergency personnel. Call a physician immediately.


Eye Contact Immediately flush eyes with gentle stream of water for at least 15 minutes, occasionallylifting upper and lower eyelids. Call a physician immediately.

Suitable Extinguishing Media Use extinguishing measures that are appropriate to localcircumstances and the surrounding environment.

Ingestion DO NOT INDUCE VOMITING. Drink large quantity of water. Immediate medical attentionis required. Never give anything by mouth to an unconscious person.

Explosion Data


Specific Hazards Arising from the ChemicalContact with most metals causes the formation of explosive and flammable hydrogen gas. React vigorously with water.

to 100%

Weight %

Health Hazard 3

NFPA

Flammability 0


Mercuric chloride 7487-94-7

Stability 2

Health Hazard 3

3.4

Flammability 0

Potassium iodide 7681-11-0 5-10

Stability 1

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

_____________________________________________________________________________________________

Potassium hydroxide

Physical and ChemicalHazards W

1310-58-3 15


HMIS


Water 7732-18-5


None Known

Engineering Measures Ensure adequate ventilation, especially in confined areas. ShowersEyewash stationsVentilation systems.


Chemical Name ACGIH TLV


OSHA PEL NIOSH IDLH

Eye/Face Protection Safety glasses with side-shields. If splashes are likely to occur, wear:. Face-shield.

Storage Keep containers tightly closed in a dry, cool, and well-ventilated place. Keep away fromheat, moisture, and incompatibles. Keep away from metals and organic halogens. Ensurethat leaks or spills cannot reach drains, sewers or surface waters. Keep out of the reach ofchildren.

Skin and Body Protection Gloves & Lab Coat. Incidental contact/splash protection:. Chemical resistant apron.


TWA: 0.025 mg/m3

Respiratory Protection When workers are facing concentrations above the exposure limit they must useappropriate certified respirators.

None Known IDLH: 10 mg/m3

Ceiling: 0.1 mg/m3

TWA: 0.05 mg/m3

Handling

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink orsmoke when using this product. Wash hands before breaks and immediately after handlingthe product.

Potassium iodide 7681-11-0

TWA: 0.01 ppm None Known None Known

Handle in accordance with good industrial hygiene and safety practice. Prevent contactwith skin, eyes, and clothing. Do not ingest. Do not eat, drink, or smoke when using thisproduct.

Potassium hydroxide 1310-58-3

None Known None Known Ceiling: 2 mg/m3


Water 7732-18-5


Neutralize spills with acid such as acetic, hydrochloric or sulfuric, absorb with vermiculite orother inert substance, and package in a suitable container for disposal. Prevent productfrom entering drains.

_____________________________________________________________________________________________


Methods for Containment Dike to collect large liquid spills. Do not flush to sewer. Absorb spill with inert material (e.g.dry sand or earth), then place in a chemical waste container.

Ensure adequate ventilation. Avoid contact with skin, eyes and inhalation of vapors. Usepersonal protective equipment. Refer to Section 8.

Page 3 / 9



Methods for Cleaning Up



Excessive heat. Incompatible products.

Chronic Toxicity



Chronic Toxicity Prolonged exposure may cause chronic effects.

Hazardous Decomposition Products Potassium Oxides. Iodine gas.

Carcinogenicity All forms of mercury can cross the placenta to the fetus. Most of what is known has beenlearned from experimental animals. .

Acute Toxicity

Incompatible Products Strong acids. Metals. Water-reactive, reacts vigorously with water.

Chemical Name ACGIH IARC NTP OSHAMercuric chloride None Known None Known None Known None KnownPotassium iodide None Known None Known None Known None Known

Stability

Potassium hydroxide None Known None Known None Known None Known

Hazardous Reactions

Chemical Name


LD50 Oral LD50 Dermal LC50 Inhalation

Reacts violently with water. Contact with metals may evolve flammable hydrogen gas.

Mercuric chloride


1 mg/kg ( Rat ) None Known None Known





Potassium iodide

Mercuric chloride None Known None Known None Known


Conditions to Avoid

Potassium hydroxide 214 mg/kg ( Rat ) None Known 85 mg/L Gambusia affinis 24 hr


Water 90 mL/kg ( Rat )


Liquid

Boiling Point/Range > 100°C/212°F

Appearance Clear yellow solution



14

_____________________________________________________________________________________________

Odor OdorlesspH


Autoignition Temperature Not applicable


Physical State



Potassium iodide None KnownPotassium hydroxide None Known None Known None Known



Chemical Name




Toxicity to Algae Toxicity to Fish

Waste Disposal Method Dispose of in accordance with local regulations. Should not be released into theenvironment.


Persistence and Degradability Based on components product is expected to be poorly eliminated from water and poorlybiodegradable.


This material is expected to be toxic to aquatic life. May cause long-term adverse effects in the environment.



Mercuric chloride None Known

Mercuric chloride -7487-94-7


Bioaccumulation/Accumulation Some components of this material have some potential to bioaccumulate but not all havebeen tested. For Mercury: Has an experimentally-determined BCF (bioconcentration factor)of greater than 100. This material is expected to significantly bioaccumulate.

Potassium iodide -7681-11-0


LC50= 0.16 mg/L Lepomismacrochirus 96 h

None Known

Potassium hydroxide -1310-58-3


EC50 = 0.093 mg/L 48 h



Ecotoxicity

Potassium iodide

Mercuric chloride None Known


Potassium iodide None Known


_____________________________________________________________________________________________

Potassium hydroxide = 0.65= 0.83

Water None Known

Potassium hydroxide

Page 5 / 9

None Known


None Known


UN-No

Subsidiary Class 6.1

2922


Packing Group II

CORROSIVE LIQUIDS, TOXIC, N.O.S. (Potassium hydroxide/Mercuric chloride solution)

Packing Group II

IMDG/IMO

DOT

Proper Shipping Name CORROSIVE LIQUIDS, TOXIC, N.O.S. (Potassium hydroxide/Mercuric chloride solution)

Reportable Quantity (RQ)

Hazard Class 8

1000

Subsidiary Class 6.1

Hazard Class

UN-No 2922

8

Packing Group II

IATAUN-No 2922

Subsidiary Class

_____________________________________________________________________________________________

6.1

Proper Shipping Name CORROSIVE LIQUIDS, TOXIC, N.O.S. (Potassium hydroxide/Mercuric chloride solution)


Page 6 / 9

Hazard Class


8


Mercuric chloride 7487-94-7 3.4 1.0

X X

Potassium iodide 7681-11-0 5-10 None Known


Potassium hydroxide 1310-58-3 15 None Known

Potassium iodide 7681-11-0 ( 5-10 )

Present

Water 7732-18-5 to 100% None Known

X X (1)-439 X


KECL X


X



Potassium hydroxide 1310-58-3 ( 15 )

Fire Hazard No

Present X


X 1-369

Reactive Hazard Yes

X KE-29139 X X

Clean Water Act

Component TSCA

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21and 40 CFR 122.42).

Water 7732-18-5 ( to 100% )

Present



X X

Mercuric chloride 7487-94-7 ( 3.4 )

None Known X None Known None Known

ENCS X



KE-35400 X


1000 lb None Known None Known X

X

DSL

Water 7732-18-5 ( to 100% )


EINECS/ELINCS

ENCS IECSC

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product contains the following HAPs: .

KECL PICCS




AICS

Mercuric chloride 7487-94-7 3.4 Present (includesany unique

chemical substancethat contains

Mercury as part ofits infrastructure)




Present X

_____________________________________________________________________________________________

X 1-226


Page 7 / 9

SARA 313 - ThresholdValues %


X KE-23121


Massachusetts New Jersey Pennsylvania Illinois Rhode Island

1000 lb None Known

Mercuric chloride X X X X None Known

Water 7732-18-5

Potassium iodide None Known None Known None Known None Known None Known

Water None Known

Potassium hydroxide X X X None Known X

None Known

to 100%

Water None Known None Known None Known None Known None Known




None Known

None Known

Mexico - Grade

None Known

California Proposition 65WARNING! This product contains a chemcial know to the State of California to cause birth defects or other reproductive harmMercury


None KnownPotassium iodide

Mercuric chloride None Known Mexico: TWA= 0.05 mg/m3

CERCLA

Potassium iodide None Known None Known

7681-11-0

Chemical Name

Potassium hydroxide None Known None Known

CAS-No California Prop. 65


Potassium hydroxide


Canada

Developmental

1310-58-3 15

Potassium iodide



Chemical Name Hazardous Substances RQs




0.1 %D1A D2B

None Known

Extremely Hazardous Substances RQs


1 %D2A

None Known

Water


1 %D1B E


Water 7732-18-5 ( to 100% )


None Known

Mercuric chloride None Known 500 lb



_____________________________________________________________________________________________

Potassium iodide None Known None Known

5-10

Page 8 / 9

None Known


Potassium hydroxide

Chemical Name





End of MSDS



Revision Date 17-Feb-2012

Transport SymbolHMIS

_____________________________________________________________________________________________

NFPA PPE



MSDS



Ammonia Nitrogen Reagent #1



TLVPEL

N/E

%

50

<0.1

to 100%

6381-59-5

N/A

7732-18-5


CAS#/Name

Potassium Sodium Tartrate,4-Hydrate

Kathon CG/ICP preservative

Water

N/E

Hazard

Yes

No

3. Hazards Overview

Large doses by mouth can cause GI irritation. May irritate eyes andskin.



Large oral doses may cause irritation to the gastrointestinal tract, but solution is non-toxic.




1

4797 Ammonia Nitrogen Reagent #1Product Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:


If large amounts were swallowed, give water to drink and get medical advice.

N/A

Flush with water. Wash with soap and water.





N/A

Not a fire hazard

N/A

N/A


Wash down drain with excess water.


Store in cool, dry, storage area away from such incompatible materials as acids, oxidizers, calcium or lead salts, silver nitrate or magnesium sulfate.

2



Normal


Ventilation


Wash aster handling.Work/Hygenic Practices:




8

Vapor Density: <1 (Air=1)<17 mm Hg @ 20 deg CVapor Pressure:

Boiling Point: > 100 deg CUnknownMelting Point:


Stable: Yes

N/A

Acids, oxidizers

COxHazardous Decomposition Products:




non-toxic

Target Organs: Skin

Pre-Existing Conditions Aggravated By Exposure: HeartDisease(low sodium)more susceptable

3




13. Disposal ConsiderationsWash down drain with excess water. Dispose according to federal, state and local regulations.






Yes Yes304-59-6Potassium Sodium Tartrate, anhydrous


Yes No Yes Yes


Hazard

Yes

No





CERCLARCRA 261.33

TSCA 8(D)

304-59-6Potassium Sodium Tartrate, anhydrous


No No

No No

No

No No

No No

No No

Listed

No

No

No

4


Ingredient



Poison Schedule

304-59-6Potassium Sodium Tartrate, anhydrous


None Allocated

None AllocatedNo

Yes None Allocated

None Allocated

No

No

No

No

No No

No No



Yes




5


Product Name Chloride Reagent #1


Recommended Use Laboratory chemicals. Industrial (not for food or food contact use). Test kit reagent.




Potential Health EffectsPrinciple Routes of Exposure Skin and eye contact, Ingestion

Acute ToxicityEyes Liquid may cause severe irritation and possible eye damage.Skin Contact can cause severe skin irritation. Effects are expected to be less severe than for

exposures to higher concentrations which symtoms include sever burns, pain, redness.Inhalation May cause irritation of respiratory tract. May cause allergy or asthma symptoms or

breathing difficulties if inhaled. Effects are expected to be less severe than for exposure tohigher concentrations which symtoms can include coughing, nausea, vomiting.

Ingestion Harmful if swallowed. May cause adverse kidney effects. May cause adverse liver effects.

Chronic EffectsAggravated Medical Conditions Respiratory disorders.


Chemical Name CAS-No Weight %Potassium chromate 7789-00-6 5

Silver nitrate 7761-88-8 <0.01Water 7732-18-5 to 100%


_____________________________________________________________________________________________


Emergency OverviewSevere eye irritationHarmful if swallowedHarmful by inhalation

Irritating to skin



WARNING!

Odor NoneAppearance Clear, Yellow, Liquid Physical State Liquid

Chloride Reagent #1

_____________________________________________________________________________________________


Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Ifirritation persists or develops, contact a physician.

Skin Contact Wash off immediately with soap and plenty of water for at least 15 minutes while removingall contaminated clothing and shoes. If skin irritation persists, call a physician.


Ingestion Do not induce vomiting without medical advice. Rinse mouth with water and afterwardsdrink plenty of water or milk. Never give anything by mouth to an unconscious person.Consult a physician.



Flash Point Not combustible

Suitable Extinguishing Media Dry chemical, CO2, alcohol-resistant foam or water spray.

Explosion Data


Personal Precautions Ensure adequate ventilation. Use personal protective equipment. Refer to Section 8. Avoidcontact with skin, eyes and inhalation of vapors.

Methods for Containment Soak up with inert absorbent material, containerize, and hold for disposal. Do not flush tosewer.

Methods for Cleaning Up Keep in suitable and closed containers for disposal.



Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Store at roomtemperature. Keep away from direct sunlight. Keep out of the reach of children.


Chemical Name ACGIH TLV OSHA PEL NIOSH IDLHPotassium chromate

7789-00-6TWA: 0.01 mg/m3

TWA: 0.05 mg/m3TWA: 5 µg/m3 IDLH: 15 mg/m3

TWA: 0.001 mg/m3

Silver nitrate 7761-88-8

TWA: 0.01 mg/m3 TWA: 0.01 mg/m3 IDLH: 10 mg/m3

TWA: 0.01 mg/m3

Water 7732-18-5


_____________________________________________________________________________________________

Stability 0NFPA Physical and ChemicalHazards -


Health Hazard 2


Flammability 0

Chloride Reagent #1

_____________________________________________________________________________________________Personal Protective Equipment

Eye/Face Protection Safety glasses with side-shields.Skin and Body Protection Wear protective gloves/clothing. Gloves & Lab Coat.Respiratory Protection When workers are facing concentrations above the exposure limit they must use

appropriate certified respirators.





Incompatible Products Strong reducing agents. Hydrazine.

Conditions to Avoid Excessive heat. Incompatible products. Direct sunlight.



Acute Toxicity

LD50 Oral VALUE (mg/kg) Potassium chromate 180mg/kg (Mouse)

Chemical Name LD50 Oral LD50 Dermal LC50 InhalationPotassium chromate None Known None Known None Known

Silver nitrate 1173 mg/kg ( Rat ) None Known None KnownWater 90 mL/kg ( Rat ) None Known None Known

Chronic Toxicity

Chemical Name ACGIH IARC NTP OSHAPotassium chromate A1 Group 1 Known X

Silver nitrate None Known None Known None Known None KnownWater None Known None Known None Known None Known




Potassium chromate None Known None Known None KnownSilver nitrate None Known None Known None Known



_____________________________________________________________________________________________

Flash Point Not combustible


Boiling Point/Range ca. 101 °C

Odor NonePhysical State LiquidAppearance Clear Yellow Liquid

pH


9



Page 3 / 7

Chloride Reagent #1

_____________________________________________________________________________________________Ecotoxicity

Chemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (WaterFlea)

Potassium chromate None Known None Known None Known None KnownSilver nitrate None Known LC50= 0.0056 mg/L

Pimephales promelas 96 hLC50= 0.006 mg/L

Oncorhynchus mykiss 96 hLC50= 0.0064 mg/L

Pimephales promelas 96 hLC50= 0.00644 mg/L

Poecilia reticulata 96 hLC50= 0.007 mg/L Lepomis

macrochirus 96 hLC50= 0.0085 mg/L Poecilia

reticulata 96 hLC50= 0.0094 mg/L

Pimephales promelas 96 h

EC50 = 0.038 mg/L 24 hEC50 = 0.395 mg/l 15 minEC50 = 0.44 mg/L 30 minEC50 = 0.86 mg/L 15 min

EC50 = 0.0006 mg/L 48 hEC50 = 0.9 µg/L 48 hLC50 = 5 µg/L 96 h


Chemical Name Log PowPotassium chromate None Known

Silver nitrate None KnownWater None Known


Waste Disposal Method Dispose of contents/container in accordance with local regulation.

Chemical NamePotassium chromate - 7789-

00-6Silver nitrate - 7761-88-8

Water - 7732-18-5



Potassium chromate - 7789-00-6


Silver nitrate - 7761-88-8 None Known None Known None Known None KnownWater - 7732-18-5 None Known None Known None Known None Known

Chemical Name California Hazardous Waste StatusPotassium chromate Toxic; Corrosive; Ignitable

Silver nitrate Toxic


DOT Not regulated

IATA Not regulated






Potassium chromate 7789-00-6 ( 5 )

R X X 1-661 X KE-29089 X X

_____________________________________________________________________________________________

Page 4 / 7



Chloride Reagent #1

_____________________________________________________________________________________________Silver nitrate

7761-88-8 ( <0.01 )Present X X 1-8 X KE-31281 X X

Water 7732-18-5 ( to 100% )





Potassium chromate 7789-00-6 5 0.1Silver nitrate 7761-88-8 <0.01 1.0


SARA 311/312 Hazard CategoriesAcute Health Hazard YesChronic Health Hazard YesFire Hazard NoSudden Release of Pressure Hazard NoReactive Hazard No

Clean Water ActThis product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21and 40 CFR 122.42).



Potassium chromate 7789-00-6 ( 5 )

10 lb X None Known X

Silver nitrate 7761-88-8 ( <0.01 )

1 lb X None Known X

Water 7732-18-5 ( to 100% )




Potassium chromate 7789-00-6 5 Present (includesany unique

chemical substancethat contains

Chromium as partof its infrastructure)


Silver nitrate 7761-88-8 <0.01 None Known None Known None Known None KnownWater 7732-18-5 to 100% None Known None Known None Known None Known

CERCLA

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQsPotassium chromate 10 lb None Known

Silver nitrate 1 lb None KnownWater None Known None Known


California Proposition 65WARNING! This product contains a chemcial know to the State of California to cause cancer

Chemical Name CAS-No California Prop. 65Potassium chromate 7789-00-6 Carcinogen

Silver nitrate 7761-88-8 None Known

_____________________________________________________________________________________________



Chloride Reagent #1

_____________________________________________________________________________________________Water 7732-18-5 None Known

Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode IslandPotassium chromate X X X X X

Silver nitrate X X X None Known XWater None Known None Known None Known None Known None Known


Mexico - Grade

Chemical Name Carcinogen Status Exposure LimitsPotassium chromate A1 Mexico: TWA= 0.01 mg/m3

Mexico: TWA= 0.05 mg/m3

Mexico: TWA= 0.5 mg/m3

Silver nitrate None Known Mexico: TWA= 0.01 mg/m3


Canada


WHMIS Hazard ClassC Oxidizing materialsD2A - Poisonous and infectious material - Other effects - Very toxic

D2B - Poisonous and infectious material - Other effects - Toxic

Chemical Name NPRIPotassium chromate X

Silver nitrate X



_____________________________________________________________________________________________


PPE Transport SymbolNFPA


HMIS

Page 6 / 7

Not regulated

Chloride Reagent #1

_____________________________________________________________________________________________Issuing Date 9/22/2010

Revision Date



End of MSDS

_____________________________________________________________________________________________

Page 7 / 7




MSDS



Hardness Reagent #7



7732-18-5

None Established<0.17791-18-6

6381-92-6 1 None Established

TLVPEL

None Established

C 2 mg/m³

None Established

%

0-<0.1

<.02

<.04

111-90-0

139-88-8

1310-73-2


CAS#/Name

Diethylene glycol monoethyl ether

7-Ethyl-2-Methyl-4-undecanolsulfate, sodium salt (Tergitol 4)

Sodium Hydroxide

EDTA disodium salt

Magnesium Chloride

Water

None Established

None Established

C 2 mg/m³

None Established

None Established

to 100% None Established None Established

Hazard

Yes

Yes

Yes

Yes

Yes

No

1

4487 Hardness Reagent #7Product Code: Product Description:

3. Hazards Overview

May be harmful if swallowed.

Primary Route Of Entry: Ingestion






Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Flush thoroughly with water for 15 minutes while occassionally lifting uper and lower eyelids. If irritation develops, contact physician.

Give large quantity of water to drink. Contact physician if gastric distress develops.


Flush with water for 15 minutes. Wash with soap and water. If irritation develops, contact physician.





N/A

Not a fire hazard

N/A

N/A


Absorb spill on inert material, place into a chemical waste container, and hold for disposal. Dispose according to federal, state, and local regulations. If permitted, rinse to drain with excess water.

2



Store in cool, dry, storage area.


Normal

Eye Protection

Ventilation


Wash after handling.Work/Hygenic Practices:




4

Vapor Density: <1 (Air=1)<17 mm Hg @ 20° CVapor Pressure:

Boiling Point: ca. 100° CN/AMelting Point:


Stable: Yes

Temperature extremes

N/A




3



Solution is slightly acidic (pH 4), and may cause stomach distress if a large amount is swallowed.

Target Organs: N/A


Information Not Yet Available.







Yes Yes111-90-0Diethylene glycol monoethyl ether

139-88-87-Ethyl-2-Methyl-4-Undecanolsulfate, sodium salt (Niaproof Type 4)

1310-73-2

139-33-3

7786-30-3

EDTA disodium salt, anhydrous

Sodium Hydroxide

Magnesium Chloride, anhydrous


Yes No Yes Yes

Yes Yes Yes No ? ?

YesYes

Yes

Yes

Yes No Yes

Yes

Yes

NoYes

Yes Yes No Yes

Yes

Yes

Yes

Yes Yes No YesYes Yes

Hazard

Yes

Yes

Yes

Yes

Yes

No


4





CERCLARCRA 261.33

TSCA 8(D)

111-90-0Diethylene glycol monoethyl ether



139-33-3EDTA disodium salt, anhydrous

7786-30-3Magnesium Chloride, anhydrous


No No

No No

No No

No No

No No

No No

No

No

No

No

No

No

No 1000

No

No

No No

No No

No No

No No

No No

No No

Listed

Yes

Yes

No

No

No

No

Glycol Ether

No

Ingredient



Poison Schedule

111-90-0Diethylene glycol monoethyl ether



139-33-3EDTA disodium salt, anhydrous

None Allocated

no info

S6

None Allocated

Yes

Yes

Yes


None Allocated


None Allocated

Yes

Yes

No

None Allocated

no info

2R

None Allocated

None Allocated

None Allocated

No

No

No

No

No

No

Yes

No

No

No

No

No

No No

No No

No Yes

No No

No

No

No

No



Yes

5





6



Causes irritation. Ingestion may cause gastrointestinal irritation, nausea, vomiting anddiarrhea.



Chronic Effects

Synonyms none




Principle Routes of Exposure Ingestion, and, Inhalation.

Product Name

Acute Toxicity


Product Code(s)

Eyes Irritating to eyes. Risk of serious damage to eyes.


Skin Irritating to skin.

4451

IRON REAGENT 2 POWDER

Inhalation Irritating to respiratory system.Ingestion

80-90

Emergency OverviewMay be harmful if swallowed

Irritating to eyes, respiratory system, and skinProduct dust may be irritating to eyes, skin and respiratory system

Contains sulfites - may produce allergic reaction in highly sensitive individuals


LaMotte Company proprietary formulation under the State of New Jersey Trade Secret Protection Law, assigned theNJTSRN 80100291-5021p, and may be disclosed only in a medical emergency.

Zinc - 1Sodium sulfite 7757-83-7 1-5

_____________________________________________________________________________________________

2,2`-Bipyridine 366-18-7 5-10


Sodium metabisulfite 7681-57-4

Page 1 / 8

Appearance Gray


Odor Slight, SulphurousPhysical State Powder

_____________________________________________________________________________________________Product Code(s) 4451IRON REAGENT 2 POWDER

Wash off immediately with soap and plenty of water for at least 15 minutes while removingall contaminated clothing and shoes.


Notes to Physician Treat symptomatically.

Explosion Data

General Advice



Inhalation


Move to fresh air. If symptoms arise, call a physician.

Do not get in eyes, on skin, or on clothing. Show this safety data sheet to the doctor inattendance.



Storage Keep containers tightly closed in a dry, cool, and well-ventilated place. Keep away fromheat and incompatibles. Keep out of the reach of children.



Ingestion

Flammable Properties

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

Not a fire hazard.

Drink plenty of water. Clean mouth with water. Never give anything by mouth to anunconscious person. Consult a physician.


Skin Contact

Flammability 0


Methods for Containment Sweep up in a manner that does not dispurse dust and shovel into suitable containers fordisposal. Dispose according to federal, state, and local regulations.

Stability 0Health Hazard 2

Stability 1


Methods for Cleaning Up Use personal protective equipment. Avoid dust formation. After cleaning, flush awaytraces with water.

_____________________________________________________________________________________________

NFPA

Health Hazard 2

Flammability 0

Page 2 / 8



Refer to Section 8.

HMIS

_____________________________________________________________________________________________Product Code(s) 4451IRON REAGENT 2 POWDER

Handle in accordance with good industrial hygiene and safety practice. Wash hands beforebreaks and immediately after handling the product. Do not eat, drink or smoke when usingthis product.

None Known

Conditions to Avoid Excessive heat. Exposure to air or moisture over prolonged periods. Keep away fromchildren.

None Known

Engineering Measures ShowersEyewash stationsVentilation systems.

None Known

Hazardous Decomposition Products Carbon oxides (COx). Sulfur oxides (SOx). Sodium oxides.

None Known

2,2`-Bipyridine 366-18-7

None Known





Eye/Face Protection Safety glasses with side-shields. Goggles.

Zinc


None Known

Skin and Body Protection

Acute Toxicity

Wear protective gloves/clothing.

Sodium metabisulfite 7681-57-4

TWA: 5 mg/m3



Respiratory Protection Maintain adequate ventilation.

Zinc None Known None Known None Known

None Known N/A


Sodium sulfite 7757-83-7

None Known

Hygiene Measures

Incompatible Products Acids. Alkalis. Strong oxidizing agents.


6 (1 tablet in 10mL of water)Autoignition Temperature Not applicable

Freezing Point ca. 150°C / 302°F sodiummetabisulfite

Physical State PowderAppearance Gray

Water Solubility Soluble in water

Boiling Point/Range No information available

_____________________________________________________________________________________________

Flash Point


Not applicable

Odor Slight, Sulphurous

Page 3 / 8

Vapor Density


No information available

pH

_____________________________________________________________________________________________IRON REAGENT 2 POWDER Product Code(s) 4451


1131 mg/kg ( Rat )

Zinc

2,2`-Bipyridine None Known None Known None Known


Sodium metabisulfite None Known None Known None Known



Sodium sulfite None Known None Known None Known None Known

Sodium sulfite 820 mg/kg ( Rat )

2,2`-Bipyridine None Known None Known None Known None Known

2,2`-Bipyridine

Sodium metabisulfite None Known None Known None Known None Known

100 mg/kg ( Rat )

Chronic Toxicity

250 mg/kg ( Rat ) None Known


None Known 22 mg/L ( Rat ) 1 h5.5 mg/L ( Rat ) 4 h

Chemical Name ACGIH




IARC NTP

Zinc None Known None Known None Known

OSHA

Sodium metabisulfite

Sodium sulfite None Known

Toxicity to Fish Microtox Daphnia Magna (WaterFlea)



Harmful to aquatic organisms.

Zinc None Known

Zinc EC50 = 30 µg/L 96 h

Sodium sulfite = -4 25 °C

LC50= 6.4 mg/L Pimephalespromelas 96 h

None Known

2,2`-Bipyridine None Known

EC50 = 5 µg/L 72 h

Sodium metabisulfite = -3.7 25 °C

Ecotoxicity

Sodium sulfite None Known LC50 220 - 460 mg/LLeuciscus idus 96 h

EC50 = 770 mg/L 17 h LC50 = 330 mg/L 24 h

2,2`-Bipyridine None Known None Known

_____________________________________________________________________________________________


Chemical Name

Sodium metabisulfite EC50 = 40 mg/L 96 hEC50 = 48 mg/L 72 h

LC50= 32 mg/L Lepomismacrochirus 96 h

Page 4 / 8

EC50 = 56 mg/L 17 h


EC50 = 89 mg/L 24 h

Toxicity to Algae


Hazard Class 8

Dispose of contents/container in accordance with local regulation. This material, assupplied, is not a hazardous waste according to state and Federal regulations (40 CFR261). This material could become a hazardous waste if it is mixed with or otherwise comesin contact with a hazardous waste, if chemical additions are made to this material, or if thematerial is processed or otherwise altered. Consult 40 CFR 261 to determine whether thealtered material is a hazardous waste pursuant to Federal regulations, and the applicablestate requirements for the specific area of disposal. Consult the appropriate state, regional,or local regulations for additional requirements.

UN-No 3260

2,2`-Bipyridine - 366-18-7 None Known

Packing Group III


IATA


Sodium metabisulfite -7681-57-4

UN-No 3260


Proper Shipping Name CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.(SODIUM DISULPHITE)


Hazard Class 8

Chemical Name

Packing Group III

RCRA - HalogenatedOrganic Compounds

RCRA - P Series Wastes

IMDG/IMO

RCRA - F Series Wastes RCRA - K Series Wastes

Proper Shipping Name CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (SODIUM DISULPHITE)


Hazard Class 8

Zinc - None Known

UN-No 3260



None KnownSodium sulfite - 7757-83-7

_____________________________________________________________________________________________

DOT


Proper Shipping Name CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.(SODIUM DISULPHITE)

Page 5 / 8

None Known


None Known


1-5 None Known


2,2`-Bipyridine 366-18-7 5-10 None Known

Sodium sulfite 7757-83-7 ( 1-5 )

Present

Sodium metabisulfite 7681-57-4 80-90 None Known

X X 1-502 X


KE-31612 X


X



2,2`-Bipyridine 366-18-7 ( 5-10 )

Fire Hazard No

Present X


X 5-3723

Reactive Hazard Yes

X KE-12238 X X

Clean Water Act

Component TSCA

.

Sodium metabisulfite 7681-57-4 ( 80-90 )

Present



X X

Zinc ( 1 )

None Known X X None Known

1-502 X



KE-12701 X

2,2`-Bipyridine 366-18-7 ( 5-10 )


X

DSL



EINECS/ELINCS

ENCS IECSC


KECL PICCS




AICS

Zinc 1 None Known None Known None Known None Known

Sodium sulfite 7757-83-7 1-5 None Known None Known None Known None Known

Zinc ( 1 )


2,2`-Bipyridine 366-18-7 5-10 None Known None Known None Known None Known

Present X

Sodium metabisulfite 7681-57-4 80-90 None Known None Known None Known None Known

X ENCS


_____________________________________________________________________________________________

X KE-35518

Zinc 1 1.0

X

Page 6 / 8

X


Sodium sulfite 7757-83-7



Zinc

Sodium metabisulfite X X X None Known X

Zinc None Known



None Known

Sodium sulfite 7757-83-7 None Known

Mexico - Grade

None Known

1000 lb

2,2`-Bipyridine 366-18-7


None Known

None Known

Zinc None Known None Known


Sodium sulfite None Known None Known


2,2`-Bipyridine None Known None Known

Chemical Name Hazardous Substances RQs

Sodium metabisulfite None Known None Known



Canada

Sodium sulfite None Known


None Known

Extremely Hazardous Substances RQs



CERCLA

Zinc ( 1 )

Not determined

2,2`-Bipyridine

Chemical Name



Massachusetts New Jersey

2,2`-Bipyridine 366-18-7 ( 5-10 )

D1B

Pennsylvania Illinois


1 %Uncontrolled product according to WHMIS classification criteria

Rhode Island

None Known

Zinc X X X None Known X

None Known

Chemical Name

Sodium sulfite

_____________________________________________________________________________________________

None Known None Known None Known None Known None Known

CAS-No California Prop. 65

Page 7 / 8

2,2`-Bipyridine








End of MSDS


Revision Date 02-Feb-2012

XChemical Name NPRI

Transport Symbol

_____________________________________________________________________________________________

HMISNFPA

Zinc

PPE




Acute ToxicityEyes Corrosive to the eyes and may cause severe damage including blindness.


Skin Corrosive. Can cause redness, pain, and severe skin burns . May discolor the skin.Harmful if absorbed through skin.



Inhalation Inhalation of corrosive mist may cause coughing, choking, headache, dizziness, andweakness for several hours. Pulmonary edema may occur with tightness in the chest,shortness of breath, bluish skin, decreased blood pressure, and increased heart rate.

Ingestion Corrosive. Causes burns. May be fatal if swallowed. Can cause immediate pain andburning in the mouth, throat, esphogus and GI tract. May cause nausea, vomiting, anddiarrhea, and in severe cases death.

Recommended Use

Chronic Effects



Chronic exposure to corrosive mists or vapors may cause erosion of the teeth Chronic exposure to mists containing sulfuric acid isa cancer hazard

OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29CFR 1910.1200). Safety information is given for exposure to the reagent as sold andconsiders exposure to the chemical if user has direct eye and skin contact.

Aggravated Medical Conditions Hypersensitivity may occur in those with preexisting skin disorders. Respiratory disorders.Preexisting eye disorders.

Product Name


Product Code(s)

Principle Routes of Exposure Inhalation, skin contact, and ingestion


_____________________________________________________________________________________________

4450

IRON REAGENT 1 SOLUTION

DANGER!

Emergency OverviewCorrosive

Liquid and mist can cause burns to all body tissueHarmful if swallowed

Harmful in contact with skinWater reactive

Page 1 / 8

Odor Odorless

Published Date: 06-Dec-2011

Physical State LiquidAppearance Clear, colorless

_____________________________________________________________________________________________IRON REAGENT 1 SOLUTION Product Code(s) 4450

Inhalation


Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificialrespiration and contact emergency personnel. Call a physician immediately.


Eye Contact Immediately flush eyes with gentle stream of water for at least 15 minutes, occasionallylifting upper and lower eyelids. Call a physician immediately.

Suitable Extinguishing Media Dry chemical or CO2. DO NOT USE WATER.

Ingestion DO NOT INDUCE VOMITING. Drink plenty of water. Clean mouth with water. Call aphysician immediately. Never give anything by mouth to an unconscious person.

Explosion Data


Specific Hazards Arising from the ChemicalContact with most metals causes the formation of explosive and flammable hydrogen gas. React vigorously with water.

General Advice Do not get in eyes, on skin, or on clothing. Do not breathedust/fume/gas/mist/vapors/spray.


Skin Contact Wash off immediately with soap and plenty of water for at least 15 minutes while removingall contaminated clothing and shoes. Excess acid on skin can be neutralized with a 2%solution of sodium bicarbonate in water. Call a physician immediately.


Formula

Chemical Name

HMIS

Personal Precautions Ensure adequate ventilation. Avoid contact with skin, eyes and inhalation of vapors. Usepersonal protective equipment. Refer to Section 8.

NFPA

CAS-No Weight %

Hin H

Methods for Cleaning Up Neutralize spill with alkaline material (sodium bicarbonate), being careful to preventsplattering, then containerize slurry and hold for later disposal. If local regulations permit,dilute slurry with water and rinse to drain with excess water. After cleaning, flush awaytraces with water.

Health Hazard 3

Health Hazard 3

Sulfuric acid

Flammability 0

7664-93-9 3-5

Flammability 0

Stability 1


_____________________________________________________________________________________________

Water

Stability 0

7732-18-5 to 100%

Physical and ChemicalHazards W

Page 2 / 8Published Date: 06-Dec-2011



Handling


Engineering Measures Ensure adequate ventilation, especially in confined areas.


Storage Keep containers tightly closed in a dry, cool, and well-ventilated place. Keep away fromincompatible materials such as cyanides or sulfides. Store away from strong bases ormetals. Do not store near combustible materials. Keep out of the reach of children.


Incompatible Products Water. Strong bases. Metals. Combustible materials. Cyanides. Sulfides.Formaldehyde.


Conditions to Avoid Excessive heat. Incompatible products. Direct sunlight.


OSHA PEL NIOSH IDLH

Hazardous Decomposition Products Hydrogen gas. Sulfur oxides (SOx).



Hazardous Reactions Reacts violently with water. Contact with metals may evolve flammable hydrogen gas.

Respiratory Protection When workers are facing concentrations above the exposure limit they must useappropriate certified respirators.


Sulfuric acid 7664-93-9

TWA: 0.2 mg/m3 TWA: 1 mg/m3


IDLH: 15 mg/m3

TWA: 1 mg/m3



Water 7732-18-5




Not applicablePhysical State Liquid


Appearance Clear, colorless

Boiling Point/Range


No data availableFlash Point

_____________________________________________________________________________________________

Not applicable

Odor OdorlesspH 1

Page 3 / 8

Autoignition Temperature


Flammability Limits in Air Not applicable

_____________________________________________________________________________________________Product Code(s) 4450IRON REAGENT 1 SOLUTION




Chronic exposure to corrosive mists or vapors may cause erosion of the teeth. Chronicexposure to mists containing sulfuric acid is a cancer hazard.

Acute Toxicity

Sulfuric acid None Known None Known None Known

Sulfuric acid


2140 mg/kg ( Rat ) None Known


510 mg/m3 ( Rat ) 2 h

Sulfuric acid A2 Group 1 Known X

Water


90 mL/kg ( Rat ) None Known None Known

ACGIH: (American Conference of Governmental Industrial Hygienists)A2 - Suspected Human CarcinogenIARC: (International Agency for Research on Cancer)Group 1 - Carcinogenic to Humans

Chemical Name

NTP: (National Toxicity Program)Known - Known Carcinogen

Chronic Toxicity

OSHA: (Occupational Safety & Health Administration)X - Present

LD50 Oral LD50 Dermal LC50 Inhalation

Chronic Toxicity

Daphnia Magna (WaterFlea)



The material may be toxic to aquatic life.

Sulfuric acid None Known

Sulfuric acid None Known

Water None Known

LC50> 500 mg/LBrachydanio rerio 96 h

None Known EC50 = 29 mg/L 24 h

Ecotoxicity


_____________________________________________________________________________________________

Chemical Name

Bioaccumulation/Accumulation When released into the soil, this material may leach into ground water. When released intothe air, this material may be removed from the atmosphere to a moderate extent by wet ordry deposition.

Toxicity to Algae

Page 4 / 8

Toxicity to Fish


Microtox


Reportable Quantity (RQ) 1000


IATA

Chemical Name

UN-No 2796

RCRA - HalogenatedOrganic Compounds

RCRA - P Series Wastes

Proper Shipping Name SULPHURIC ACID (<51% ACID)

RCRA - F Series Wastes RCRA - K Series Wastes

Hazard Class 8


Packing Group II


Sulfuric acid - 7664-93-9 None Known

IMDG/IMO

None Known

Proper Shipping Name SULPHURIC ACID (<51% ACID)

None Known

DOT

Hazard Class 8

None Known

UN-No 2796Packing Group II

Proper Shipping Name SULFURIC ACID (< 51% ACID)

Water - 7732-18-5

Hazard Class 8


_____________________________________________________________________________________________

UN-No 2796


Packing Group

Page 5 / 8

II


Dispose according to federal, state, and local regulations. If permitted, neutralize reagentwith sodium bicarbonate/sodium carbonate, add slurry to large volume of water to dilute,rinse to drain with excess water.


No

ENCS X


KE-35400 X

Reactive Hazard Yes

X


Clean Water Act

Component TSCA




DSL EINECS/ELINCS

Sulfuric acid 7664-93-9 ( 3-5 )



Water 7732-18-5 ( to 100% )





AICS



Sulfuric acid 7664-93-9 ( 3-5 )

Sulfuric acid 7664-93-9 3-5 None Known None Known None Known None Known




Present X

CERCLA

Sulfuric acid 7664-93-9 3-5 1.0


X 1-430; 1-724

Sulfuric acid 1000 lb 1000 lb

Water 7732-18-5


to 100% None Known

X KE-32570


X X



Acute Health Hazard

_____________________________________________________________________________________________

Yes

Water 7732-18-5 ( to 100% )

Present


X

Page 6 / 8

X


Fire Hazard



Sulfuric acid X X X


X X

Sulfuric acid


Water None Known

Sulfuric acid 7664-93-9 ( 3-5 )

1 %D1A E


Water 7732-18-5 ( to 100% )




7664-93-9 Carcinogen


Chemical Name

Chemical Name NPRI

CAS-No

Sulfuric acid X

Water

Mexico - Grade


California Prop. 65


Chemical Name Massachusetts

Sulfuric acid A2 Mexico: TWA= 1 mg/m3

New Jersey

_____________________________________________________________________________________________

Pennsylvania


Illinois Rhode Island

Page 7 / 8

California Proposition 65Warning! California Proposition 65 has classified "strong inorganic acid mists containing sulfuric acid" as a chemical known to theState of California to cause cancer. This classification applies only to "mists" containing sulfuric acid and not to sulfuric acid orsulfuric acid solutions, as is this solution.


Canada

_____________________________________________________________________________________________Product Code(s) 4450IRON REAGENT 1 SOLUTION



End of MSDS

Revision Date 06-Dec-2011

Prepared By

Revision Note


Initial Release

_____________________________________________________________________________________________

HMISNFPA PPE Transport Symbol

Page 8 / 8Published Date: 06-Dec-2011

1

MateriaPO Box 329 • 802 Washington Avenue • Chestertown, MD 21620 • USA Telephone Number For Information 410-778-3100 24 Hour Emergency Number (CHEM-TEL): USA, Canada, Puerto Rico 800-255-3924; Outside North American continent 813-248-05

1. Product Identification Manufactured By: L 4410 VM Phosphate

PProduc

802 Ches

2. Composition/Information on Ingredients Hazardous Name CAS # % OSHA

PEL Yes Sulfuric Acid 7664-93-9 16 1 mg/cubic Yes Molybdic acid ammonium salt

tetrahydrate 12054-85-2 1.7 5 mg/cubic

soluble compMo

Yes Ammonium metavanadate 7803-55-6 <0.1 C 0.5 mg/cub

resp. dust as V No Water to 100% 7732-18-5 >82% 3. Hazards Overview Primary Route of Entry: Ingestion Skin Poison! Danger! Corrosive. Liquid and vapor cause severe burns to all body tissue. Harmfu HMIS Hazard: (Scale: 4 = Extreme, 3 = High, 2 = Moderate, 1 = Slight, 0 = Least) Health: 3 Flammability: 0 Reactivity: 2 Carcinogenicity: None Other Health Related Comments: Ammonium meta-vanadate is poisonous & increases the hazards of contact with sulfuric acid liquiMolybdic Acid investigated as a possible cancer hazard. (See Section 11.) 4. First Aid Measures

Eye Contact: Immediately flush with water for 15 minutes. Get medical attention immediateSkin Contact: Immediately flush with water for 15 minutes while removing affected clothing

physician. Ingestion: Do not induce vomiting. Rinse out mouth, drink glass of water, and get medica

immediately Inhalation: Remove to fresh air. If breathing is difficult, give oxygen.

MSDS
l Safety Data Sheet
85 (call collect)

aMotte Company Washington Avenuetertown, MD 21620

roduct Code: t Description:

ACGIH TLV

m 1 mg/cubic m

m . as

5 mg/cubic m soluble comp.

respirable,as Mo

ic m 205

C 0.05mg/cubic m resp. dust as V205

l or fatal if swallowed.

d or vapor.

ly. . Consult

l attention

Product Code: 4410 Product Description: VM Phosphate

5. Fire Fighting Measures Flash Point: N/A LEL: N/A UEL: N/A Fire Rating Extinguishing Media: Dry chemical or CO2, not water Special Fire Fighting Procedures: Wear protective equipment and self-contained breathing apparatus. Hazardous Combustion and/or Decomposition Products: SOx, hydrogen gas Unusual Fire & Explosion Hazard: Violent exothermic reaction occurs with water. Can react with metals to produce hydrogen gas, which can form an explosive mixture with air. 6. Accidental Release Measures Wear gloves & eye protection.Cover spill with sodium bicarbonate or sodium carbonate/calcium hydroxide. Mix & add water to form slurry, avoiding spattering and fumes. Small amount--Scoop up & flush to drain with water. Large amount-Send to disposal as hazardous waste 7. Handling & Storage Store in cool, dry, area away from heat and incompatible materials such as bases, metals, combustibles. 8. Exposure Controls/Personal Protection Ventilation Use with adequate ventilation. Protection When Handling Gloves Eye Protection Lab Coat Work/Hygienic Practices: Avoid contact with skin, eyes or clothing. Wash after handling. 9. Physical & Chemical Properties Appearance: Clear yellow liquid Boiling Point: >100 deg C Melting Point: N/A pH: < 1 Odor: None Vapor Density: >1 (Air=1) Solubility in Water: Soluble Vapor Pressure: Unknown 10. Stability & Reactivity Stable: Yes Conditions to Avoid: Heat, moisture Materials to Avoid: Strong bases, reducing agents, metals, cyanides, sulfides, combustibles Hazardous Decomposition Products: SOx; Contact with metal powders can release flammable hydrogen gas.

2


11. Toxicological Information Oral rat LD50: 2140 mg/kg for sulfuric acid Oral rat LD50: 333 mg/kg for ammonium molybdate anhydrous; investigated as a mutagen.

Oral rat LD50: 58 mg/kg for ammonium meta-vanadate; investigated as a mutagen, reproductive effector.

Target Organs: Corrosive to all body parts 12. Ecological Information Information not Available 13. Disposal Considerations

Add slowly to a large volume of soda ash/calcium hydroxide. Small amounts of this neutralized solution may be flushed to drain. Large amounts of #4410 waste should be handled as hazardous waste and sent to an approved facility. The ammonium meta-vanadate component is a toxic, EPA-regulated waste (code P119). 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: Sulfuric Acid (<51% ACID) Hazard Class/Div: 8 UN2796 Packing Group: II International (Air, I.C.A.O.) Proper Shipping Name: Sulphuric Acid (<51% ACID) Hazard Class/Div: 8 UN2796 Packing Group: II 15. Regulatory Information

Chemical Inventory Status USA Europe ---Canada--- Australia Japan Ingredient TSCA EC DSL NDSL

Sulfuric Acid (7664-93-9) YES YES YES NO YES YES Hexammonium Molybdate (anhydrous) 12027-67-7

YES YES YES NO YES YES

Ammonium metavanadate (7803-55-6)

YES YES YES NO YES YES

Water to 100%

3



---SARA 302--- - -------- SARA 313 --------- RCRA TSCA Ingredient RQ TPQ Listed Chemical Category CERCLA 261.33 8(D)

Sulfuric Acid (7664-93-9) 1000 1000 YES 1000 NO NO NO Hexammonium Molybdate (anhydrous) 12027-67-7

NO NO NO NO NO NO NO


NO NO NO NO 1000 P119 NO

Water to 100% ----------- Australia ----------- ------ SARA 311/312 ------ Hazchem Poison This MSDS is Ingredient Hazard Categories Code Schedule WHMIS Compliant

Sulfuric Acid (7664-93-9)

Acute: Yes Chronic: Yes Fire: No Pressure: No Reactivity: Yes

(Pure/Liquid)

2P None allocated

Hexammonium Molybdate (anhydrous) 12027-67-7


(Pure/Solid)

None allocated

None allocated



(Pure/Solid)

1Z None allocated

For product #4410 liquid mixture, as a whole

Acute: Yes Chronic: Yes Fire: No Pressure: No Reactivity: Yes

2P None allocated Yes

16. Other Information Prepared By: IP Revised:12/18/2007

4


MSDS



Sodium Hydroxide Reagent

Product Code: 4259

with Metal Inhibitor



7732-18-5 to 100% None Established

TLVPEL

C 2 mg/m³

None Established

None Established

%

5.4

5.6

<0.1

1310-73-2

102-71-6

7791-18-6


CAS#/Name

Sodium Hydroxide

Triethanolamine; (Trolamine)

Magnesium Chloride

Water

C 2 mg/m³

5 mg/m³ (TWA)

None Established

None Established

Hazard

Yes

Yes

Yes

No

3. Hazards Overview

Warning! Corrosive. Can cause severe irritation or burns to all body tissue. Harmful if swallowed.

Primary Route Of Entry: Skin Ingestion Inhalation


Trolamine is irritating to eyes, respiratory system and skin. Can cause dermatitis. (IARC Catergory 3: Not classifiable as to carcinogenicity in humans).




1

4259with Metal InhibitorSodium Hydroxide ReagentProduct Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Immediately flush with water for 15 minutes while lifting upper and lower eyelids occasionally. Contact physician if irritqation persists.

DO NOT induce vomiting. Give large amounts of water. Seek medical attention.


Immediately flush with water for 15 minutes while removing affected clothing. Contact physician if irritation persists. Wash clothing prior to reuse.



Flash Point (Method Used): UEL:LEL: 1% 8%


TROLAMINE only levels

Not a fire hazard

Wear protective equipment and self-contained breathing apparatus.

Adding water to caustic solutions generates large amounts of heat.


Ventilate. Wear PPE noted in Sec 8. Neutralize with dilute acid (Hydrochloric/Sulfuric), absorb on inert material, & containerize for disposal. Dispose according to federal, state, and local regulations.


Store in cool, dry, ventilated storage area away from sources of heat and incompatible materials, such as nitric acid, metals. Do not store with aluminum or magnesium.

2



Normal


Ventilation


Local or general ventilation is recommended.

Avoid contact with eyes, skin, and clothing. Wash after handling.Work/Hygenic Practices:




13 - 14

Vapor Density: >1 (Air=1)<1 mm Hg @ 20° CVapor Pressure:

Boiling Point: UnknownN/AMelting Point:


Stable: Yes

Heat, light

Strong acids, oxidizers, metal powders.

NOx, COxHazardous Decomposition Products:




Oral rat LD50: 4920mg/kg for Triethanolamine; Sodium hydroxide investigated as a mutagen.

Target Organs: N/A Skin

3










Yes Yes1310-73-2Sodium Hydroxide


7786-30-3


Magnesium Chloride, anhydrous

Yes No Yes Yes


YesYes

Yes

Yes No Yes

Yes

Yes

NoYes Yes Yes

Hazard

Yes

Yes

Yes

No





CERCLARCRA 261.33

TSCA 8(D)





No No

No No

No No

No No No

No

1000

No

No No

No No

No No

No No

No No

Listed

No

No

No

No

No

No

4


Ingredient



Poison Schedule





S6

None Allocated

None Allocated

None Allocated

Yes

Yes

No

Yes 2R

None Allocated

None Allocated

None Allocated

No

No

No

No

No

No

No

No

No Yes

No No

No No

No No


4259 Yes No No No No 2R S5productas a whole

Yes

16. Other InformationKeep out of reach of children



5



Corrosive to the eyes and may cause severe damage including blindness. Vapor maycause irritation.


Skin Contact with skin causes irritation and burns.



Inhalation Inhalation of vapors can cause coughing, choking, inflammation of the upper respiratorytract; in higher concentrations, burns pulmonary edema, and death. Brief exposure to5000ppm can be fatal.

Ingestion May be fatal if swallowed. Swallowing may cause severe burns of mouth, throat, andstomach. Scarring of tissues and death may result. Symptoms may include pain in mouth,chest, abdomen, coughing, vomiting, and collapse.

Recommended Use

Chronic Effects



Repeated exposure may cause damage to the tissues of the mucous membranes, respiratory tract, eyes, and skin

OSHA Regulatory Status Safety information is given for exposure to the reagent as sold and considers exposure tothe chemical if user has direct eye and skin contact.

Aggravated Medical Conditions Respiratory disorders.

Product Name


Environmental Hazard See Section 12 for additional Ecological Information.

Product Code(s)

Principle Routes of Exposure Eye contact, Inhalation, skin contact, and ingestion.


4255

Hardness Buffer Reagent

Acute Toxicity

_____________________________________________________________________________________________

Eyes

DANGER! POISON!

Emergency OverviewCorrosive

Liquid and mist cause severe burns to all body tissueInhalation may cause coughing, chest pains, damage to lungs

May be fatal if inhaled or swallowed

Page 1 / 9


Published Date: 26-Apr-2011

Appearance Clear, colorless Odor Pungent, Ammonia

_____________________________________________________________________________________________Hardness Buffer Reagent Product Code(s) 4255

Specific Hazards Arising from the ChemicalClosed containers may explode when heated.

Remove material from skin immediately. Wash off immediately with soap and plenty ofwater for at least 15 minutes while removing all contaminated clothing and shoes. Removeand wash contaminated clothing before re-use. Seek immediate medical attention/advice.





Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.Seek immediate medical attention/advice.

Flammable Properties Vapors are flammable.

General Advice

Ingestion


DO NOT INDUCE VOMITING. Drink plenty of water. Clean mouth with water. Never giveanything by mouth to an unconscious person. Immediate medical attention is required.

Do not get in eyes, on skin, or on clothing. Do not breathedust/fume/gas/mist/vapors/spray. Take off contaminated clothing and shoes immediately.Immediate medical attention is required.


Skin Contact

Explosion Data

Notes to Physician See MSDS (material safety data sheet) for additional information.

Ammonium hydroxide

Health Hazard 3

Flammability 0

1336-21-6 <57


Stability 1

Flammability 1

Chemical Name

Water, distilled 7732-18-5

Stability 0

to 100%

CAS-No Weight %

Physical and ChemicalHazards N/A

_____________________________________________________________________________________________

Ammonium chloride

HMIS

12125-02-9

NFPA

7

Page 2 / 9Published Date: 26-Apr-2011

Health Hazard 3


None Known


Personal Protective EquipmentEye/Face Protection Safety glasses with side-shields. If splashes are likely to occur, wear:. Face-shield.

Maintain eye wash and quick drench shower facilities in work area.


Skin and Body Protection Wear protective gloves/clothing. Neoprene and nitrile rubber are recommended materials.


Respiratory Protection Use mechanical ventilation (fume hood). If exposure limits are exceeded or irritation isexperienced, NIOSH/MSHA approved respiratory protection with *Ammonia* cartridgesshould be worn.

OSHA PEL NIOSH IDLH

Storage Keep containers tightly closed in a dry, cool, and well-ventilated place. Store below 25°C(77°F). Keep away from heat and incompatibles. Protect from sunlight. Keep out of thereach of children.

Hygiene Measures Use only with adequate ventilation. Wear suitable gloves and eye/face protection. Avoidcontact with skin, eyes and clothing. Wash hands and face before breaks and immediatelyafter handling the product. Handle in accordance with good industrial hygiene and safetypractice.

Ammonium chloride 12125-02-9

= 20 mg/m3 STELTWA: 10 mg/m3

None Known TWA: 10 mg/m3

STEL: 20 mg/m3

Handling

Ammonium hydroxide 1336-21-6


Handle in accordance with good industrial hygiene and safety practice. Prevent contactwith skin, eyes, and clothing. Do not ingest. Do not breathe vapors or spray mist. Do NOTmix with acids.

Water, distilled 7732-18-5



_____________________________________________________________________________________________

Methods for Cleaning Up Use a non-combustible material like vermiculite, sand or earth to soak up the product andplace into a container for later disposal. Keep in suitable and closed containers fordisposal.


Methods for Containment Dike to collect large liquid spills. Contain and collect spillage with non-combustibleabsorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place incontainer for disposal according to local / national regulations (see Section 13). Do notflush to sewer.

Page 3 / 9

Other Information


Ventilate the area.

Use personal protective equipment. Ensure adequate ventilation. Wear respiratoryprotection. If you have not donned special protective clothing approved for this material, donot expose yourself to any risk of this material touching you. Evacuate personnel to safeareas.

_____________________________________________________________________________________________Product Code(s) 4255Hardness Buffer Reagent

Water, distilled None Known None Known None Known


Ignitions sources - heat, sparks and open flames. Direct sunlight. Incompatible products.

Chronic Toxicity

Acute Toxicity

Chronic Toxicity Repeated exposure may cause damage to the tissues of the mucous membranes,respiratory tract, eyes, and skin.



Hazardous Decomposition Products Burning may produce:. Ammonia. Nitrogen oxides (NOx).

Ammonium chloride None Known None Known None Known None Known

Product Information Harmful if swallowed, inhaled, or absorbed through skin.

Ammonium hydroxide None Known None Known None Known None Known

Incompatible Products Strong acids. Metals. Sodium hypochlorite.

Water, distilled None Known None Known None Known None Known

Stability





Chemical Name

Ammonium chloride None Known None Known None Known

LD50 Oral LD50 Dermal

Ammonium hydroxide None Known None Known None Known

LC50 Inhalation


Water, distilled None Known None Known None Known

Ammonium chloride 1410 mg/kg ( Rat ) None Known None Known


Ammonium hydroxide 350 mg/kg ( Rat ) None Known None Known

Conditions to Avoid


Vapor Pressure No data available

Autoignition Temperature 651°C (1204°F) for AmmoniumHydroxide


Vapor Density 0.60 NH3(Air = 1)

Appearance Clear, colorless

Boiling Point/Range ca. 36°C / 97°F for AmmoniumHydroxide


Solubility Soluble

Odor Pungent, Ammonia

Freezing Point

Evaporation Rate No data available

No information available

_____________________________________________________________________________________________

pH 11

Flammability Limits in AirUpper 16%

Page 4 / 9

Lower


25%

For Ammonium Hydroxide


Waste Disposal Method Dispose of in accordance with local regulations. Should not be released into theenvironment.


Bioaccumulation/Accumulation This material is not expected to significantly bioaccumulate.

Ecotoxicity

Contaminated Packaging Dispose of in accordance with local regulations.

Ammonium chloride None Known


LC50= 209 mg/L Cyprinuscarpio 96 h



None Known

Ammonium chloride

Ammonium chloride -12125-02-9


None Known

EC50 = 202 mg/L 24 h

Ammonium hydroxide -1336-21-6


Ammonium hydroxide

Water, distilled - 7732-18-5 None Known None Known None Known None Known

None Known

Ammonium hydroxide

Water, distilled None Known

None Known LC50= 8.2 mg/L Pimephalespromelas 96 h

None Known EC50 = 0.66 mg/L 48 h


Chemical Name

Water, distilled

_____________________________________________________________________________________________



None Known

Toxicity to Algae


Toxicity to Fish



Packing Group III

Packing Group III


IMDG/IMO

AMMONIA SOLUTION (With >10% - <35% AMMONIA)

Proper Shipping Name AMMONIA SOLUTION (With >10% - <35% AMMONIA)

Reportable Quantity (RQ) 1000lb for Ammonium hydroxide, 5000lb Ammonium chloride

Hazard Class 8

DOT

UN-No 2672Packing Group III

Hazard Class

IATA

8

UN-No 2672

_____________________________________________________________________________________________

Proper Shipping Name AMMONIA SOLUTION (With >10% - <35% AMMONIA)

UN-No 2672


Hazard Class 8



X X


1-314 X


KE-01688 X

Fire Hazard No

X



Water, distilled 7732-18-5 ( to 100% )

Reactive Hazard No

Present X X ENCS

Clean Water Act

X KE-35400


X X



Component TSCA

Ammonium chloride 12125-02-9 ( 7 )


DSL



EINECS/ELINCS



ENCS IECSC


KECL


PICCS AICS




Ammonium chloride 12125-02-9 7 None Known None Known None Known None Known


Ammonium hydroxide 1336-21-6 <57 None Known None Known None Known None Known

Present

Water, distilled 7732-18-5 to 100% None Known None Known None Known None Known

X


CERCLA

SARA 313 - ThresholdValues %

X 1-218

Ammonium chloride


12125-02-9 7

Ammonium chloride 5000 lb None Known

1.0

X

Ammonium hydroxide 1000 lb None Known

KE-01645

Ammonium hydroxide 1336-21-6 <57 1.0

X

_____________________________________________________________________________________________

X

Water, distilled 7732-18-5 to 100% None Known




Present



Ammonium chloride None Known Mexico: TWA= 10 mg/m3

California Prop. 65

Ammonium hydroxide None Known None Known

None Known

Water, distilled None Known None Known

Chemical Name Massachusetts New Jersey Pennsylvania

Canada

Illinois Rhode Island

Ammonium chloride 12125-02-9


Ammonium chloride X X X


None Known X


1 %D2B

None Known

Water, distilled


1 %E

Ammonium hydroxide X



X X None Known None Known


Ammonium hydroxide

Water, distilled None Known None Known None Known None Known None Known




Water, distilled 7732-18-5 None Known

Mexico - Grade

_____________________________________________________________________________________________

None Known

Chemical Name

Chemical Name Carcinogen Status

Page 8 / 9

Exposure Limits


CAS-No


Initial Release



End of MSDS


Revision Date 26-Apr-2011

Revision Note

HMISNFPA PPE

_____________________________________________________________________________________________

Transport Symbol



MSDS



Calcium-Magnesium Inhibitor

Product Code: 3922

Solution



TLVPEL

None Established

None Established

%

8

to 100%

63451-33-2

7732-18-5


CAS#/Name

CDTA disodium magnesium salt

Water

None Established

None Established

Hazard

Yes

No

3. Hazards Overview

Large oral doses may cause nausea and diarrhea.

Primary Route Of Entry:





1

3922SolutionCalcium-Magnesium InhibitorProduct Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Flush with water for 15 minutes. If irritation develops, contact physician

Drink large quantity of water to drink. If gastric distress develops, consult physician.

Not applicable.

Flush with water for 15 minutes. Wash with soap and water. If irritation develops, contact physician.





N/A

Not a fire hazard

N/A

N/A


Dispose according to federal, state, and local regulations. If permitted, mop up spill area and rinse to drain with excess water. Clean spill area with water.


Store in cool, dry place.

2



Normal

Eye Protection

Ventilation


Work/Hygenic Practices:




6

Vapor Density: <1 (Air=1)<17mm Hg @ 20° CVapor Pressure:

Boiling Point: >100° CUnknownMelting Point:


Stable: Yes

N/A

N/A





Target Organs: N/A

3




13. Disposal ConsiderationsFlush to drain with excess water. Dispose according to federal, state, and local regulations.






Yes No63451-33-2N,N'-1, 2-Cyclohexanediylbis (N-carboxymethyl)glycine, Magnesium Disodium salt


No No No No


Hazard

Yes

No





CERCLARCRA 261.33

TSCA 8(D)

63451-33-2N,N'-1, 2-Cyclohexanediylbis (N-carboxymethyl)glycine, Magnesium Disodium salt


No No

No No No

No No No

No No

Listed

No

No

No

No

4


Ingredient



Poison Schedule

63451-33-2N,N'-1, 2-Cyclohexanediylbis (N-carboxymethyl)glycine, Magnesium Disodium salt


None Allocated

None AllocatedNo

Yes None Allocated

None Allocated

No

No

No

No

No No

No No



Yes




5


Product Name Potassium TPB Solution


Synonyms none






Potential Health EffectsPrinciple Routes of Exposure Ingestion, and, Skin contact

Acute ToxicityEyes May cause irritation.Skin May cause irritation.Inhalation Not an expected route of exposure.Ingestion Harmful if swallowed.

Chronic Effects


Chemical Name CAS-No Weight %Sodium borate 1303-96-4 2

Borate(1-), tetraphenyl-, sodium 143-66-8 2.5Water 7732-18-5 to 100%


_____________________________________________________________________________________________

Emergency OverviewMay cause skin and eye irritation

Harmful if swallowed

Revision Number 0



Page 1 / 6


Physical State Liquid Odor NoneAppearance Clear, Colorless

Potassium TPB Solution

_____________________________________________________________________________________________General Advice Do not get in eyes, on skin, or on clothing.


Skin Contact Wash off immediately with soap and plenty of water. If skin irritation persists, call aphysician.

Inhalation Not expected.

Ingestion Drink plenty of water. Clean mouth with water. Never give anything by mouth to anunconscious person. Consult a physician.

Notes to Physician Treat symptomatically.




Explosion DataProtective Equipment and Precautions for Firefighters Wear self-contained breathing apparatus and protective suit.



Methods for Cleaning Up Use personal protective equipment. Use a non-combustible material like vermiculite, sandor earth to soak up the product and place into a container for later disposal. After cleaning,flush away traces with water.



Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reachof children.


Chemical Name ACGIH TLV OSHA PEL NIOSH IDLHSodium borate

1303-96-4= 6 mg/m3 STELTWA: 2 mg/m3

None Established TWA: 5 mg/m3

Borate(1-), tetraphenyl-, sodium 143-66-8


Water 7732-18-5


Personal Protective EquipmentEye/Face Protection Safety glasses with side-shields. Goggles.

_____________________________________________________________________________________________

Stability 0NFPA Physical and ChemicalHazards -


Health Hazard 1


Flammability 0

Page 2 / 6


_____________________________________________________________________________________________Skin and Body Protection Wear protective gloves/clothing.Respiratory Protection Maintain adequate ventilation.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Wash hands beforebreaks and immediately after handling the product. Do not eat, drink or smoke when usingthis product.




Incompatible Products Acids. Strong oxidizing agents.

Conditions to Avoid Heat, flames and sparks. Exposure to light.

Hazardous Decomposition Products Carbon oxides. Boron oxides.




Acute Toxicity

Chemical Name LD50 Oral LD50 Dermal LC50 InhalationSodium borate 2660 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) None Established

Borate(1-), tetraphenyl-, sodium 288 mg/kg ( Rat ) None Established None EstablishedWater 90 mL/kg ( Rat ) None Established None Established

Chronic Toxicity

Chemical Name ACGIH IARC NTP OSHASodium borate None Established None Established None Established None Established

Borate(1-), tetraphenyl-,sodium






Sodium borate None Established None Established None EstablishedBorate(1-), tetraphenyl-, sodium None Established None Established None Established

Water None Established None Established None Established


_____________________________________________________________________________________________

Vapor Pressure <17 mmHg @ 20°C

pH 9Boiling Point/Range 100 °C


Odor NonePhysical State


Liquid

Page 3 / 6

Appearance Clear Colorless


_____________________________________________________________________________________________


Flea)Sodium borate EC50 = 158 mg/L 96 h LC50= 340 mg/L Limanda

limanda 96 hNone Established None Established




Chemical Name Log PowSodium borate None Established

Borate(1-), tetraphenyl-, sodium None EstablishedWater None Established


Waste Disposal Method Can be disposed as waste water, when in compliance with local regulations. This material,as supplied, is not a hazardous waste according to state and Federal regulations (40 CFR261). This material could become a hazardous waste if it is mixed with or otherwise comesin contact with a hazardous waste, if chemical additions are made to this material, or if thematerial is processed or otherwise altered. Consult 40 CFR 261 to determine whether thealtered material is a hazardous waste pursuant to Federal regulations, and the applicablestate requirements for the specific area of disposal. Consult the appropriate state, regional,or local regulations for additional requirements.

Chemical NameSodium borate - 1303-96-4

Borate(1-), tetraphenyl-,sodium - 143-66-8Water - 7732-18-5



Sodium borate - 1303-96-4 None Established None Established None Established None EstablishedBorate(1-), tetraphenyl-,

sodium - 143-66-8None Established None Established None Established None Established


Chemical Name California Hazardous Waste StatusSodium borate Toxic


DOT Not regulated

IATA Not regulated






Sodium borate 1303-96-4 ( 2 )

Present X EINECS/ELINCS

ENCS X KE-03483 X X

Borate(1-),tetraphenyl-, sodium

143-66-8 ( 2.5 )


_____________________________________________________________________________________________




_____________________________________________________________________________________________Water

7732-18-5 ( to 100% )Present X X ENCS X KE-35400 X X




Sodium borate 1303-96-4 2 None EstablishedBorate(1-), tetraphenyl-, sodium 143-66-8 2.5 None Established

Water 7732-18-5 to 100% None Established


Clean Water ActComponent CWA - Reportable


SubstancesSodium borate 1303-96-4 ( 2 )


Borate(1-), tetraphenyl-, sodium 143-66-8 ( 2.5 )


Water 7732-18-5 ( to 100% )




Sodium borate 1303-96-4 2 None Established None Established None Established None EstablishedBorate(1-),

tetraphenyl-, sodium143-66-8 2.5 None Established None Established None Established None Established

Water 7732-18-5 to 100% None Established None Established None Established None Established

CERCLA

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQsSodium borate None Established None Established

Borate(1-), tetraphenyl-, sodium None Established None EstablishedWater None Established None Established


Chemical Name CAS-No California Prop. 65Sodium borate 1303-96-4 None Established

Borate(1-), tetraphenyl-, sodium 143-66-8 None EstablishedWater 7732-18-5 None Established

Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode IslandSodium borate X X X None Established X


None Established None Established None Established None Established None Established

Water None Established None Established None Established None Established None Established


_____________________________________________________________________________________________




_____________________________________________________________________________________________


Chemical Name Carcinogen Status Exposure LimitsSodium borate None Established Mexico: TWA= 5 mg/m3

Borate(1-), tetraphenyl-, sodium None Established None EstablishedWater None Established None Established

Canada

WHMIS Hazard ClassTo be determined




Revision Date



End of MSDS

_____________________________________________________________________________________________

Transport SymbolNFPA


HMISNot regulated


PPE



2218

Eyes May cause irritation.

WIDE RANGE INDICATOR

Skin Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis.Inhalation May cause irritation of respiratory tract. May cause central nervous system depression with

nausea, headache, dizziness, vomiting, and incoordination.


Ingestion May cause drowsiness and dizziness. May be fatal or cause blindness if swallowed. Maycause central nervous system depression.


Synonyms

Chronic Effects

none


Ethanol has been shown to be a reproductive toxin only when consumed as an alcoholic beverage Prolonged skin contact maycause skin irritation and/or dermatitis


Environmental Hazard Harmful to aquatic organisms.


Product Name

Principle Routes of Exposure Skin contact, Ingestion, and, Inhalation.


Product Code(s)


_____________________________________________________________________________________________

Acute Toxicity

Emergency OverviewFlammable liquid and vapor

Harmful by inhalation, in contact with skin and if swallowedMay be fatal or cause blindness if swallowed

Affects central nervous systemMay cause skin and eye irritation

POISON! DANGER!

Page 1 / 10

Appearance Dark green


Odor AlcoholPhysical State Liquid

_____________________________________________________________________________________________WIDE RANGE INDICATOR Product Code(s) 2218

Flammable Properties Flammable.


Flash Point 23°C (74°F) CC

General Advice

Ingestion


Drink 1 or 2 glasses of water. Induce vomiting, but only if victim is fully conscious. Call aphysician immediately.

Explosion Data

Do not get in eyes, on skin, or on clothing. Consult a physician.

Skin Contact

Protection of First-aiders Use personal protective equipment. Do not use mouth-to-mouth method if victim ingestedor inhaled the substance; induce artificial respiration with the aid of a pocket mask equippedwith a one-way valve or other proper respiratory medical device.

Wash off immediately with plenty of water for at least 15 minutes. Consult a physician.





CAS-No Weight %

Thymol blue 76-61-9 <0.05Potassium hydroxide 1310-58-3

NFPA


<0.05

Methyl red 493-52-7

2,4-Dinitrophenol

Personal Precautions Refer to Section 8. Ensure adequate ventilation. Remove all sources of ignition.

Health Hazard 1

51-28-5 0.05

<0.05

Methods for Containment Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical wastecontainer. Dispose according to federal, state, and local regulations.

Flammability 3

Methyl alcohol 67-56-1


Stability 0

2

Phenolphthalein


Ethyl alcohol 64-17-5 52

77-09-8

HMIS

<0.05

Water 7732-18-5

_____________________________________________________________________________________________

to 100%

Health Hazard 2


Chemical Name

Flammability 3

Bromothymol blue

Page 2 / 10

76-59-5


<0.05

Stability 0


Keep containers tightly closed in a dry, cool, and well-ventilated place. Keep away fromheat and sources of ignition. Do not store near combustible materials. Keep out of thereach of children.


None Known None Known Ceiling: 2 mg/m3

Chemical Name

2,4-Dinitrophenol 51-28-5


ACGIH TLV OSHA PEL

Methyl alcohol 67-56-1

= 250 ppm STELTWA: 200 ppm

TWA: 200 ppmTWA: 260 mg/m3

IDLH: 6000 ppmTWA: 200 ppm

TWA: 260 mg/m3

STEL: 325 mg/m3

STEL: 250 ppm

NIOSH IDLH

Ethyl alcohol 64-17-5

TWA: 1000 ppm TWA: 1000 ppmTWA: 1900 mg/m3

IDLH: 3300 ppmTWA: 1000 ppm

TWA: 1900 mg/m3

Methyl red 493-52-7

Water 7732-18-5




Handling

Phenolphthalein 77-09-8



Skin and Body Protection Wear protective gloves/clothing. Nitrile rubber. Gloves & Lab Coat.

None Known



Respiratory Protection Use only with adequate ventilation.



Bromothymol blue 76-59-5


Hygiene Measures Do not eat, drink or smoke when using this product.

None Known

Storage

Thymol blue 76-61-9



Flash Point 23°C (74°F) CC

Vapor Density 1.6 @ 20°C (Air=1) for SDA(3A) Ethyl Alcohol

Odor AlcoholpH Not applicableBoiling Point/Range 78.5°C (173.3°F) for SDA (3A)

Ethyl Alcohol

Physical State LiquidAppearance

Vapor Pressure

_____________________________________________________________________________________________

48 mmHg @ 20 °C for SDA (3A)Ethyl Alcohol

Dark green

Upper 19% Ethanol

Lower

Page 3 / 10

3.3% Ethanol


Explosion Limits


Ethanol has been shown to be a reproductive toxin only when consumed as an alcoholicbeverage. Prolonged skin contact may cause skin irritation and/or dermatitis.

Methyl red None Known None Known None Known

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.


Heat, flames and sparks.

Phenolphthalein None Known



Methyl red None Known None Known None Known None KnownPhenolphthalein None Known Group 2B Reasonably Anticipated X

Bromothymol blue None Known

Bromothymol blue None Known None Known None Known None Known


Thymol blue None Known None Known None Known None KnownPotassium hydroxide None Known None Known None Known None Known

Thymol blue None Known

2,4-Dinitrophenol None Known None Known None Known None Known


Methyl alcohol None Known None Known None Known None Known

Incompatible Products

Acute Toxicity

Ethyl alcohol None Known None Known Known None Known

Potassium hydroxide 214 mg/kg ( Rat )


None Known 85 mg/L Gambusia affinis 24 hr2,4-Dinitrophenol 30 mg/kg ( Rat )





Methyl red None Known None Known None Known


Phenolphthalein Group III Chemical None Known None Known

Methyl alcohol 5628 mg/kg ( Rat )

Bromothymol blue None Known None Known None Known

15800 mg/kg ( Rabbit ) 64000 ppm ( Rat ) 4 h83.2 mg/L ( Rat ) 4 h

Thymol blue None Known None Known None Known


Nitric acid. Strong oxidizing agents.

Potassium hydroxide None Known None Known None Known

Ethyl alcohol 1501 mg/kg ( Rat )

2,4-Dinitrophenol None Known None Known None Known

None Known 124.7 mg/L ( Rat ) 4 h

Methyl alcohol None Known None Known None KnownEthyl alcohol None Known None Known None Known

Water 90 mL/kg ( Rat )



Conditions to Avoid

_____________________________________________________________________________________________

Chemical Name LD50 Oral

Chronic Toxicity

LD50 Dermal LC50 Inhalation

Page 4 / 10

Hazardous Decomposition Products


Carbon oxides (COx).

Chronic Toxicity


Potassium hydroxide = 0.65= 0.83

Potassium hydroxide None Known

2,4-Dinitrophenol = 1.54


Methyl alcohol = -0.77

None Known

Ethyl alcohol = -0.32

Ecotoxicity

2,4-Dinitrophenol

Water None Known

None Known LC50= 6.58 mg/LPimephales promelas 96 h


Methyl red None Known

Methyl alcohol None Known LC50= 13200 mg/LOncorhynchus mykiss 96 h


EC50 = 39000 mg/L 25 minEC50 = 40000 mg/L 15 minEC50 = 43000 mg/L 5 min


None Known


Ethyl alcohol

Waste Disposal Method Dispose of in accordance with local regulations.

None Known LC50= 12900 mg/LOncorhynchus mykiss 96 h

LC50= 14.2 mg/LPimephales promelas 96 h

EC50 = 34634 mg/L 30 minEC50 = 35470 mg/L 5 min

EC50 = 10800 mg/L 24 hEC50 = 9268 mg/L 48 h

None Known

Water None Known




Methyl red - 493-52-7 None Known None Known None Known None Known

None Known

Phenolphthalein - 77-09-8 None Known None Known None Known None Known

Phenolphthalein

Bromothymol blue - 76-59-5 None Known None Known None Known None Known


Thymol blue - 76-61-9 None Known None Known None Known None Known

Persistence and Degradability No information available.

Potassium hydroxide -1310-58-3



2,4-Dinitrophenol - 51-28-5 None Known P048 None Known None Known


Methyl alcohol - 67-56-1 None Known None Known None Known None Known

Chemical Name

Bioaccumulation/Accumulation

Ethyl alcohol - 64-17-5 None Known None Known None Known None Known

No information available.

Bromothymol blue



Chemical Name California Hazardous Waste Status


Ethyl alcohol Toxic; Ignitable

None Known

Toxicity to Algae

Methyl red None Known

Toxicity to Fish

Thymol blue

Phenolphthalein None Known

_____________________________________________________________________________________________


Bromothymol blue None Known


Thymol blue

Page 5 / 10

None Known




Packing Group II


Packing Group

IMDG/IMO

II


Proper Shipping Name ETHANOL SOLUTION (Ethyl Alcohol Solution)

ETHANOL SOLUTION (Ethyl Alcohol Solution)

Hazard Class 3UN-No 1170

DOT

IATA

Packing Group II

Hazard Class

UN-No 1170

3

Not regulated

_____________________________________________________________________________________________

Proper Shipping Name ETHANOL SOLUTION (Ethyl Alcohol Solution)Hazard Class 3

Page 6 / 10

UN-No


1170


Ethyl alcohol 64-17-5 ( 52 )


Methyl red 493-52-7 ( <0.05 )

Water 7732-18-5 ( to 100% )


Present X X 5-243 X KE-06693


X X



Phenolphthalein 77-09-8 ( <0.05 )

Present X X


9-1152 X

Methyl red 493-52-7 <0.05 None Known

KE-03234 X

Phenolphthalein 77-09-8 <0.05 None Known

X

Bromothymol blue 76-59-5 <0.05 None Known


Bromothymol blue 76-59-5 ( <0.05 )

Thymol blue 76-61-9 <0.05 None Known

Present X

Potassium hydroxide 1310-58-3 <0.05 None Known

X ENCS

2,4-Dinitrophenol 51-28-5 0.05 1.0

X KE-02744

Methyl alcohol 67-56-1 2 1.0

X X

Ethyl alcohol 64-17-5 52 None Known

Component TSCA


Thymol blue 76-61-9 ( <0.05 )

Present X X


ENCS X


KECL X


X

DSL

Fire Hazard Yes

EINECS/ELINCS

Potassium hydroxide 1310-58-3 ( <0.05 )


Present X

Reactive Hazard No

X 1-369 X KE-29139

Clean Water Act

X X


ENCS IECSC



2,4-Dinitrophenol 51-28-5 ( 0.05 )

Present

Methyl red 493-52-7 ( <0.05 )


X X



3-797 X



KE-11946 X X

KECL PICCS

Methyl alcohol 67-56-1 ( 2 )

_____________________________________________________________________________________________

Present X X 2-201 X KE-23193 X

Page 7 / 10

X


AICS



None Known

1000 lb

Methyl alcohol 67-56-1 2 Present Group IV None Known None Known

None Known

Water 7732-18-5 ( to 100% )

Ethyl alcohol 64-17-5 52 None Known None Known None Known None Known




None Known X

CERCLA



2,4-Dinitrophenol 51-28-5 ( 0.05 )

Methyl red None Known None Known

None Known

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product contains the following HAPs: .

Phenolphthalein None Known None Known

X X

Bromothymol blue None Known None Known

X

Thymol blue None Known None Known

None Known

Chemical Name

Potassium hydroxide 1000 lb None Known

CAS-No Weight %

2,4-Dinitrophenol 10 lb None Known

HAPS data VOC Chemicals

Methyl alcohol 5000 lb None Known



Ethyl alcohol None Known None Known

Thymol blue 76-61-9 ( <0.05 )



Methyl red 493-52-7 <0.05 None Known



None Known

California Proposition 65WARNING! This product contains a chemcial know to the State of California to cause birth defects or other reproductive harmWARNING! This product contains a chemcial know to the State of California to cause cancer

None Known

Phenolphthalein 77-09-8 <0.05

Chemical Name CAS-No California Prop. 65

None Known Group III

Methyl red 493-52-7 None Known


Phenolphthalein 77-09-8 Carcinogen


Bromothymol blue 76-59-5 None Known

Bromothymol blue 76-59-5

Thymol blue 76-61-9 None Known

<0.05 None Known

Potassium hydroxide 1310-58-3 None Known


2,4-Dinitrophenol 51-28-5 None Known

None Known

None Known

Methyl alcohol 67-56-1 None Known


Thymol blue

Ethyl alcohol 64-17-5 Developmental

76-61-9 <0.05

Water 7732-18-5 None Known




None Known

Potassium hydroxide 1310-58-3 <0.05 None Known

_____________________________________________________________________________________________



2,4-Dinitrophenol 51-28-5

Page 8 / 10

0.05


Present Group III




Methyl red None Known None Known

None Known

Pennsylvania


Illinois

Thymol blue

Bromothymol blue None Known None Known


Thymol blue None Known None Known


Potassium hydroxide None Known None Known

None Known

Rhode Island

2,4-Dinitrophenol None Known None Known

Potassium hydroxide

Methyl alcohol None Known Mexico: TWA= 200 ppmMexico: TWA= 260 mg/m3

X X

Ethyl alcohol None Known Mexico: TWA= 1000 ppmMexico: TWA= 1900 mg/m3

X None Known


X

Methyl red

2,4-Dinitrophenol

Canada

X X X X


None Known


Methyl alcohol


X X

Methyl red 493-52-7 ( <0.05 )


X X


Not determined

X

None Known



None Known

Ethyl alcohol

Thymol blue 76-61-9 ( <0.05 )

Not determined

X X


1 %D1B E

X None Known

2,4-Dinitrophenol 51-28-5 ( 0.05 )

0.1 %

X

None Known


1 %B2 D1B D2A D2B

Water


0.1 %B2 D2B


Water 7732-18-5 ( to 100% )



Chemical Name




_____________________________________________________________________________________________

None Known

Massachusetts

Mexico - Grade

New Jersey

Bromothymol blue








End of MSDS


Revision Date 09-Sep-2011

NPRI

PPENFPA

LegendX - Listed

_____________________________________________________________________________________________

Transport Symbol

Methyl alcohol XChemical Name

HMIS


6361 Acid Extracting SolutionProduct Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Flush thoroughly with water for 15 minutes while occasionally lifting upper and lower eyelids. Consult a physician.

Do not induce vomiting. Give large quantity of water or milk to drink. Consult physician.


Flush thoroughly with water for 15 minutes while removing affected clothing. If irritation develops contact physician. Wash clothing prior tore use.





N/A

Not a fire hazard

N/A

Contact with metals may produce flammable hydrogen gas.


Wear PPE (see Section 8) & ventilate area. Neutralize spill with sodium bicarbonate/lime, scoop up slurry, containerize, and hold for disposal. Dispose according federal, state, and local regulations. If permitted, rinse to drain with excess water.


Keep container tightly closed. Store in cool, dry area away from bases, metals, and other incompatible materials.

2



Normal


Ventilation


Avoid contact with eyes, skin, and clothing. Wash after handling.Work/Hygenic Practices:



SlightSolubleClear Colorless Liquid

<1

Vapor Density: >1 (Air=1)<17 mm Hg @ 20 deg CVapor Pressure:

Boiling Point: > 100 deg CN/AMelting Point:


Stable: Yes

Heat

Alkalies, metals

HCl gas, SOx, hydrogen gasHazardous Decomposition Products:




Oral rat LD50: 2140 mg/kg for sulfuric acid, concentrated

Target Organs: Corrosive to all body parts Skin

3





14. Transportation Information

Proper Shipping Name:CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.DOT:

IATA: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.(HYDROCHLORIC/SULPHURIC ACID SOLUTION)

Hazard Class/Div:

88

IATA:DOT:

UN: 3264

IIPacking Group:

(HYDROCHLORIC/SULFURIC ACID SOLUTION)




Yes Yes7647-01-0Hydrochloric Acid

7664-93-9Sulfuric Acid


Yes No Yes Yes



Hazard

Yes

Yes

No


4





CERCLARCRA 261.33

TSCA 8(D)

7647-01-0Hydrochloric Acid



5000 500

1000 1000

No No

1000

5000

No No

No No

No No

No No

Listed

Yes

Yes

No

No

No

Ingredient



Poison Schedule

7647-01-0Hydrochloric Acid



None Allocated

None Allocated

None Allocated

Yes

No

Yes 2R

2P

None Allocated

Yes

Yes

No

No

No

No

No No

No Yes

No No



Yes




5

MATERIAL SAFETY DATA SHEET - Expotech USA · 2018. 8. 18. · P.O. Box 329 - 802 Washington Avenue...

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Transcript of MATERIAL SAFETY DATA SHEET - Expotech USA · 2018. 8. 18. · P.O. Box 329 - 802 Washington Avenue...