Lyman Memorial High Shool - lebanonct.org · SCHEDULE Interior Finishes Block Walls Primer:...
Transcript of Lyman Memorial High Shool - lebanonct.org · SCHEDULE Interior Finishes Block Walls Primer:...
Lyman Memorial High ShoolLebanon, CT
LEBANON BOARD OF ED891 EXETER RDLEBANON, CT 062491708
Prepared By:
Anthony TolisanoProfessional Coatings [email protected](860) 985-1430
SCHEDULE
Interior Finishes
Block WallsPrimer: B42W00046 - Heavy Duty Block FillerTopcoat: B70W00211 - Waterbased Catalyzed EpoxyBottom part of walls. 4' down.Topcoat: K46W00151 - Pro Industrial PreCatalyzed Waterbased Semi-Gloss EpoxyTop part of walls. 4' up.
RailingsFirst Coat: B51W00150 - Extreme Bonding PrimerSand and prime all metal substrates with bonding primer, or equivalent.Second Coat: B58W00610 - Macropoxy® 646 Fast Cure EpoxyThird Coat: B65W00651 - Acrolon® 218 HS Polyurethane - Semi-Gloss
Trim and DoorsPrimer: B51W00150 - Extreme Bonding PrimerSand and prime all metal substrates with this bonding primer, or equivalent.Topcoat: B53W01151 - Pro Industrial Waterbased Acrylic Alkyd Urethane Semi Gloss
Bottom Tile TrimPrimer: B51W00150 - Extreme Bonding PrimerLightly sand and apply this bonding primer, or equivalent. Let primer dry 24 hours before top coating.Topcoat-2 Coats: B65W00651 - Acrolon® 218 HS Polyurethane - Semi-Gloss
Galvanized Metal Window TrimPrimer: B66W00310 - Pro Industrial Pro-Cryl® Universal Acrylic PrimerTopcoat: B53W01151 - Pro industrial Waterbased Acrylic Alkyd Urethane Semi Gloss
END OF SECTION
HEAVY DUTY BLOCK FILLER
B42W46
Protective &
MarineCoatings
1.01Revised 5/12
www.sherwin-williams.com/protective
PRODUCT DESCRIPTION
HEAVY DUTY BLOCK FILLER is an acrylic resin block fi ller for use on interior and exterior poured and precast concrete, concrete block, and cinder block.
• Excellent moisture resistance• Excellent fi lling characteristics • Suitable for use in USDA inspected facilities• Resurface spalled and deteriorated concrete walls and
ceilings• Low odor, low VOC
PRODUCT CHARACTERISTICS
Finish: Flat
Color: White
Volume Solids: 53% ± 2%
Weight Solids: 73% ± 2% VOC (EPA Method 24): <50 g/L; 0.42 lb/gal
Recommended Spreading Rate per coat:(varies with application, surface irregularities, and degree of
sealing and fi lling desired.)
Minimum MaximumWet mils (microns) 18.0 (450) 34.0 (850)Dry mils (microns) 10.0 (250) 18.0 (450)~Coverage sq ft/gal (m2/L) 50 (1.2) 88 (8.2)Theoretical coverage sq ft/gal (m2/L) @ 1 mil / 25 microns dft 848 (21)
NOTE: Brush or roll application may require multiple coats to achieve maximum fi lm thickness and uniformity of appearance.
Drying Schedule @ 18.0 mils wet (450 microns):@ 55°F/13°C @ 77°F/25°C @ 95°F/35°C
50% RHTo touch: 1.5 hours 1 hour 30 minutesTo handle: 8 hours 6 hours 1 hourTo recoat:
itself 3 hours 1 hour 30 minuteswater borne 48 hours 18 hours 6 hours
solvent borne 48 hours 48 hours 24 hoursTo cure: 30 days 30 days 10 daysDrying time is temperature, humidity, and fi lm thickness dependent.
Shelf Life: 36 months, unopenedStore indoors at 40°F (4.5°C) to 100°F (38°C)
Flash Point: >200°F (>93°C), PMCCReducer/Clean Up: Water
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RECOMMENDED USES
For use over prepared masonry surfaces in:
• Dairies • Bottling Plants• Mining Industry • Tunnels • Chemical Plants • Paper Mills • Hospitals • Jails• Schools • Power Plants • Equipment Foundations• Water and Sewage Treatment Facilities• Industrial concrete ceilings and walls • Petroleum Refi neries• Acceptable for use in high performance architectural applications
PERFORMANCE CHARACTERISTICS
Substrate*: ConcreteSurface Preparation*: SSPC-SP3System Tested*:
1 ct. Heavy Duty Block Filler @ 10 mils dft/ct*unless otherwise noted below
Test Name Test Method ResultsAdhesion ASTM D4541 200 psiDirect Impact ASTM D2794 6 in. lbs.Dry Heat Resistance ASTM D2485 200°F (93°C)
Flexibility (cold rolled steel)
ASTM D522, 180° bend, 1" mandrel Passes
Moisture Resistance TT-C-555B No failure
Pencil Hardness ASTM D3363 5BThermal Shock ASTM D2246 (5 cycles) ExcellentWinder Driven Rain Resistance TT-C-555b Passes
Wet Heat Resistance Non-immersion 120°F (49°C)
Provides performance comparable to products formulated to federal specifi cation: TT-F-1098D Type 1
1.01
HEAVY DUTY BLOCK FILLER
B42W46
Protective &
MarineCoatings
www.sherwin-williams.com/protective
SURFACE PREPARATION
Surface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.
Refer to product Application Bulletin for detailed surface preparation information.
Minimum recommended surface preparation: Concrete & Masonry: SSPC-SP13/NACE 6,or ICRI No. 310.2, CSP 1-3
Surface Preparation StandardsCondition of Surface
ISO 8501-1BS7079:A1
Swedish Std.SIS055900 SSPC NACE
White Metal Sa 3 Sa 3 SP 5 1Near White Metal Sa 2.5 Sa 2.5 SP 10 2Commercial Blast Sa 2 Sa 2 SP 6 3Brush-Off Blast Sa 1 Sa 1 SP 7 4Hand Tool Cleaning Rusted C St 2 C St 2 SP 2 -
Pitted & Rusted D St 2 D St 2 SP 2 -Power Tool Cleaning Rusted C St 3 C St 3 SP 3 -
Pitted & Rusted D St 3 D St 3 SP 3 -
TINTING
Do not tint.
To provide color as a guide coat, or when color is required for exterior exposure, mix 4 parts by volume of Heavy Duty Block Filler with 1 part by volume of A-100 Exterior Latex Flat, A6 series. For interior exposures, mix 4 parts by volume of Heavy Duty Block Filler with 1 part by volume of ProMar 200 Interior Latex Flat Wall Paint, B30W200 Series.
APPLICATION CONDITIONS
Temperature: 55°F (13°C) minimum, 95°F (35°C) maximum (air, surface, and material) At least 5°F (2.8°C) above dew point
Relative humidity: 85% maximum
PRODUCT CHARACTERISTICS
Packaging: 5 gallon (18.9L) containersWeight: 14.25 ± 0.2 lb/gl 1.71 kg/L
SAFETY PRECAUTIONSRefer to the MSDS sheet before use.
Published technical data and instructions are subject to change without notice. Contact your Sherwin-Williams representative for additional technical data and instructions.
WARRANTYThe Sherwin-Williams Company warrants our products to be free of manufactur-ing defects in accord with applicable Sherwin-Williams quality control procedures. Liability for products proven defective, if any, is limited to replacement of the defec-tive product or the refund of the purchase price paid for the defective product as determined by Sherwin-Williams. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY SHERWIN-WILLIAMS, EXPRESSED OR IMPLIED, STATUTORY, BY OPERATION OF LAW OR OTHERWISE, INCLUDING MER-CHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE.
PRODUCT INFORMATION
RECOMMENDED SYSTEMS Dry Film Thickness / ct. Mils (Microns)Untopcoated, light service Interior:1 ct. Heavy Duty Block Filler 10.0-18.0 (250-450)Exterior:2 cts. Heavy Duty Block Filler 10.0-18.0 (250-450)
Acrylic Finishes:1 ct. Heavy Duty Block Filler 10.0-18.0 (250-450)2 cts. DTM Acrylic Coating 2.5-4.0 (63-100) or Metalatex Semi-Gloss Coating 0.5-4.0 (13-100) or Sher-Cryl HPA 2.5-4.0 (62.5-100)
Alkyd Finishes:1 ct. Heavy Duty Block Filler 10.0-18.0 (250-450)2 cts. Industrial Enamel HS 2.0-4.0 (63-100) or Metalastic DTM 3.0-5.0 (75-125) or Waterbased Industrial Enamel 1.5-3.0 (38-75)
Catalyzed Epoxy, Solvent based:1 ct. Heavy Duty Block Filler 10.0-18.0 (250-450)2 cts. Tile-Clad HS Epoxy 2.5-4.0 (63-100) or Macropoxy 646 5.0-10.0 (125-250)
Catalyzed Epoxy, Water based:1 ct. Heavy Duty Block Filler 10.0-18.0 (250-450)2 cts. Water Based Catalyzed Epoxy 2.5-4.0 (63-100) or Waterbased Tile Clad Epoxy 2.0-4.0 (63-100) or Pro Industrial HB Epoxy 4.0-6.0 (100-150)
Polyurethane:1 ct. Heavy Duty Block Filler 10.0-18.0 (250-450) 1 ct. Macropoxy 646 5.0-10.0 (125-250)2 cts. Hi-Solids Polyurethane 3.0-4.0 (75-100) or Sherthane 2K Urethane 2.0-4.0 (63-100) or Acrolon 218 HS Polyurethane 3.0-6.0 (75-150)
The systems listed above are representative of the product's use, other systems may be appropriate.
DISCLAIMERThe information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative to obtain the most recent Product Data Information and Application Bulletin.
HEAVY DUTY BLOCK FILLER
B42W46
Protective &
MarineCoatings
1.01Revised 5/12
www.sherwin-williams.com/protective
SURFACE PREPARATIONS
Surface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.
Concrete/MasonryNewFor surface preparation, refer to SSPC-SP13/NACE 6, or ICRI No. 310.2, CSP 1-3. Surface must be clean, dry, sound, and offer suf-fi cient profi le to achieve adequate adhesion. Minimum substrate cure is 28 days at 75°F (24°C). Remove all form release agents, curing compounds, salts, effl orescence, laitance, and other foreign matter by sandblasting, shotblasting, mechanical scarifi cation, or suitable chemical means. Refer to ASTM D4260. Rinse thoroughly to achieve a fi nal pH between 6.0 and 10.0. Allow to dry thoroughly prior to coating.
OldFor surface preparation, refer to SSPC-SP13/NACE 6, or ICRI No. 310.2, CSP 1-3. Surface preparation is done in much the same manner as new concrete; however, if the concrete is contaminated with oils, grease, chemicals, etc., they must be removed by clean-ing with a strong detergent. Refer to ASTM D4258. Form release agents, hardeners, etc. must be removed by sandblasting, shot-blasting, mechanical scarifi cation, or suitable chemical means.
Fill all cracks, voids, and bugholes with Steel-Seam FT910.
Follow the standard methods listed below when applicable:ASTM D4258 Standard Practice for Cleaning Concrete.ASTM D4259 Standard Practice for Abrading Concrete.ASTM D4260 Standard Practice for Etching Concrete. ASTM F1869 Standard Test Method for Measuring Moisture Vapor Emission Rate of Concrete. SSPC-SP 13/Nace 6 Surface Preparation of ConcreteICRI No. 310.2
Do not apply over existing coatings.
Surface Preparation StandardsCondition of Surface
ISO 8501-1BS7079:A1
Swedish Std.SIS055900 SSPC NACE
White Metal Sa 3 Sa 3 SP 5 1Near White Metal Sa 2.5 Sa 2.5 SP 10 2Commercial Blast Sa 2 Sa 2 SP 6 3Brush-Off Blast Sa 1 Sa 1 SP 7 4Hand Tool Cleaning Rusted C St 2 C St 2 SP 2 -
Pitted & Rusted D St 2 D St 2 SP 2 -Power Tool Cleaning Rusted C St 3 C St 3 SP 3 -
Pitted & Rusted D St 3 D St 3 SP 3 -
APPLICATION BULLETIN
APPLICATION CONDITIONS
Temperature: 55°F (13°C) minimum, 95°F (35°C) maximum (air, surface, and material) At least 5°F (2.8°C) above dew point
Relative humidity: 85% maximum
APPLICATION EQUIPMENT
The following is a guide. Changes in pressures and tip sizes may be needed for proper spray characteristics. Always purge spray equipment before use with listed reducer. Any reduction must be compliant with existing VOC regulations and compatible with the existing environmental and application conditions.
Reducer/Clean up ...........Water
Airless Spray Pressure.........................2000 psi Hose...............................1/4" - 3/8" ID Tip ...................................028" Filter ...............................30 mesh Reduction .......................not recommended
Conventional Spray Gun ................................Binks 95 Fluid Nozzle ...................67 Air Nozzle.......................67PD Atomization Pressure .....50 psi Fluid Pressure ................20-25 psi Reduction .......................as needed up to 12½% by volume Brush Brush..............................Nylon/Polyester Reduction .......................not recommended
Roller Cover .............................1/2" - 1 1/2" synthetic Reduction .......................not recommended
Squeegee also acceptable
If specifi c application equipment is not listed above, equivalent equipment may be substituted.
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1.01
HEAVY DUTY BLOCK FILLER
B42W46
Protective &
MarineCoatings
www.sherwin-williams.com/protective
APPLICATION BULLETIN
APPLICATION PROCEDURES
Surface preparation must be completed as indicated.
Heavy Duty Block Filler is ready-to-spray (airless) and does not require thinning. Mix material thoroughly to a uniform consis-tency with power agitation and apply by brush, roller, or spray. Follow by squeegee, trowel, or roller, being careful to force mate-rial into pores in order to produce a relatively smooth surface. In severe wet areas, a smooth continuous pinhole-free appearance is necessary for proper protection before topcoating. Two coats will provide the most uniform surface.
Apply paint at the recommended fi lm thickness and spreading rate as indicated below:
Recommended Spreading Rate per coat:(varies with application, surface irregularities, and degree of
sealing and fi lling desired.)
Minimum MaximumWet mils (microns) 18.0 (450) 34.0 (850)Dry mils (microns) 10.0 (250) 18.0 (450)~Coverage sq ft/gal (m2/L) 50 (1.2) 88 (8.2)Theoretical coverage sq ft/gal (m2/L) @ 1 mil / 25 microns dft 848 (21)
NOTE: Brush or roll application may require multiple coats to achieve maximum fi lm thickness and uniformity of appearance.
Drying Schedule @ 18.0 mils wet (450 microns):@ 55°F/13°C @ 77°F/25°C @ 95°F/35°C
50% RHTo touch: 1.5 hours 1 hour 30 minutesTo handle: 8 hours 6 hours 1 hourTo recoat:
itself 3 hours 1 hour 30 minuteswater borne 48 hours 18 hours 6 hours
solvent borne 48 hours 48 hours 24 hoursTo cure: 30 days 30 days 10 daysDrying time is temperature, humidity, and fi lm thickness dependent.
Application of coating above maximum or below minimum recommended spreading rate may adversely affect coating performance.
CLEAN UP INSTRUCTIONS
Clean spills and spatters immediately with soap and warm water. Clean hands and tools immediately after use with soap and warm water. After cleaning, fl ush spray equipment with Mineral Spirits to prevent rusting of the equipment. Follow manufacturer's safety recommendations when using Mineral Spirits.
DISCLAIMERThe information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative to obtain the most recent Product Data Information and Application Bulletin.
PERFORMANCE TIPS
When using spray application, use a 50% overlap with each pass of the gun to avoid holidays, bare areas, and pinholes. If necessary, cross spray at a right angle
Spreading rates are calculated on volume solids and do not in-clude an application loss factor due to surface profi le, roughness or porosity of the surface, skill and technique of the applicator, method of application, various surface irregularities, material lost during mixing, spillage, overthinning, climatic conditions, and excessive fi lm build.
Excessive reduction of material can affect fi lm build, appear-ance, and adhesion.
Make sure material is forced into pores and bugholes in order to provide a pinhole free surface.
Do not use below grade as a hydrostatic waterproofer or in immersion service.
Rolling will provide a textured fi nish. Squeegee will provide a smoother fi nish.
For better fi lling results, apply by airless spray and immediately back roll.
Refer to Product Information sheet for additional performance characteristics and properties.
SAFETY PRECAUTIONSRefer to the MSDS sheet before use.
Published technical data and instructions are subject to change without notice. Contact your Sherwin-Williams representative for additional technical data and instructions.
WARRANTYThe Sherwin-Williams Company warrants our products to be free of manufacturing defects in accord with applicable Sherwin-Williams quality control procedures. Liability for products proven defective, if any, is limited to replacement of the de-fective product or the refund of the purchase price paid for the defective product as determined by Sherwin-Williams. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY SHERWIN-WILLIAMS, EXPRESSED OR IMPLIED, STATUTORY, BY OPERATION OF LAW OR OTHERWISE, INCLUDING MER-CHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE.
SPECIFICATIONS Color: Extra White, Deep Base & Ultradeep Tint Base-wide range of colors available Recommended Spread Rate per coat: Gloss Extra White B70W00211/B60V15 (may vary by base)
wet mils: 6.5 - 8.0 dry mils: 2.5 - 3.0 coverage: 243 - 203 sq ft/gal approximate Theoretical coverage: 609 sq ft/gal @ 1 mil dry Drying Schedule @ 8.0 mils wet, 50% RH: Drying time is temperature, humidity, and film thickness dependent. @ 55°F/12.8°C @ 77°F/25°C @ 120°F/49°C To touch: 2 hours 1 hour 20 minutes Tack free: 4 hours 2 hours 30 minutes Minimum recoat: 28 hours 18-24 hours 4 hours Maximum recoat*: 30 days 30 days 30 days To cure: 20 days 14 days 7 days Pot Life: 48 hours 36 hours 16 hours Sweat-in-time: 60 minutes 30 minutes 30 minutes *If maximum recoat time is exceeded, abrade surface before recoating.
CHARACTERISTICS WATER BASED CATALYZED EPOXY is a two-component water based, catalyzed, acrylic epoxy resin coating formulated for high performance use in industrial and commercial environments. Features: Chemical resistant Impact and abrasion resistance Wash and Scrub resistant Flash rust resistant
For use on properly prepared: Steel, Galvanized & Aluminum Concrete/Masonry Wood Drywall Previously Painted
Recommended for use in: Hospitals, Schools Pharmaceutical houses Institutional kitchens Storage Tanks & Piping & Structural Steel Manufacturing Facilities & New Construction Suitable for use in USDA inspected facilities
Flash Point: N/A Tinting with CCE: Base oz/gal Strength Extra White 0 - 6 SherColor Deep base 4 -14 SherColor Ultradeep 10 -14 SherColor Shelf Life: Part A 36 months,unopened Part B 24 months,unopened Mix Ratio: 2 components, premeasured 4:1 Finish: 60°+@60° Gloss 35-45@60° Semi-Gloss
Gloss Extra White B70W00211/B60V15
(may vary by base) VOC: (mixed less exempt solvents) 143 g/L - 1.19 lb/gal (as per 40 CFR 59.406 and SOR/2009-264, s. 12) Volume Solids: 38 ± 2% Weight Solids: 47 ± 2% Weight per Gallon: 9.67 lb/gal
Gloss Deep Base B70W00213/B60V15 VOC: (mixed less exempt solvents) 168 g/L - 1.40 lb/gal (as per 40 CFR 59.406 and SOR/2009-264, s. 12) Volume Solids: 37 ± 2% Weight Solids: 43 ± 2% Weight per Gallon: 9.14 lb/gal
07/2017 www.sherwin-williams.com continued on back
Steel & Rusted Galvanized, acrylic primer: 1ct. Pro Industrial Pro-Cryl Primer 2cts. Water Base Catalyzed Epoxy Steel alkyd primer: 1ct. Kem Bond HS 2cts. Water Base Catalyzed Epoxy Steel epoxy primer: 1ct. Water Based Tile-Clad Primer 2cts. Water Base Catalyzed Epoxy Aluminum & Galvanized Metal: 2cts. Water Base Catalyzed Epoxy Concrete Block: 1ct. Pro Industrial Heavy Duty Block Filler 2cts. Water Base Catalyzed Epoxy Drywall, Interior: 1ct. ProMar 200 Zero VOC Primer 2cts. Water Base Catalyzed Epoxy
Masonry/Smooth: 2cts. Water Base Catalyzed Epoxy Masonry/Smooth: (Weathered or soft masonry) 1ct. Loxon Concrete and Masonry Primer Or 1ct. Loxon Conditioner 2cts. Water Base Catalyzed Epoxy Wood, Exterior: 1ct. Exterior Oil-Based Wood Primer 2cts. Water Base Catalyzed Epoxy
Wood, Exterior:(For high performance
aesthetics:) 1ct. Exterior Oil-Based Wood Primer 1ct. Water Base Catalyzed Epoxy 1ct: Pro Industrial Water Base Acrolon 100 Wood, Interior: 1ct. Premium Wall & Wood Primer 2cts. Water Base Catalyzed Epoxy
126.01
WATER BASED CATALYZED EPOXY
B70W00211 Extra White B70W00213 Deep Base B70T00204 Ultradeep Base B60V00015 Gloss Hardener B60V00025 Semi-Gloss Hardener
As of 07/25/2017, Complies with: OTC Yes LEED® 09 NC,.CI Yes OTC Phase II Yes LEED® 09 CS Yes SCAQMD No LEED® 09 S Yes CARB Yes LEED® v4 Emissions No CARB SCM 2007 Yes LEED® v4 VOC No Canada Yes MPI
RECOMMENDED SYSTEMS
The systems listed above are representative of the product's use, other systems may be appropriate. Other primers may be appropriate.
System: (unless otherwise indicated) Substrate: Steel Surface Preparation: SSPC-SP6/NACE 3 Finish: Water Based Catalyzed Epoxy– @ 3.0 mils dft/ct (unless otherwise noted)
Abrason Resistance: Method: ASTM D2486 Results: >500 cycles Adhesion1: Method: ASTM D3359 Results: 4B minimum Fineness of Grind2: Result: 6 Hegman minimum Dry Heat Resistance: Method: ASTM D2485 Method A Result: 250°F/121°C
Flexibility: Method: ASTM D522, 180° bend,
1/4" mandrel Result: Passes Scrub Resistance1: Method: ASTM D2486 Result: 4800 scrubs Chemical Resistance: Incidental contact Excellent resistance to: Tap water,10% Acetic Acid, 10% Sodium Hydroxide Great resistance to: Ethanol, Toluene, Mineral Spirits, 10% Sulphuric Acid, Motor Oil Limited resistance to: MEK
1 1 ct. Water Based Epoxy over 1 ct. Pro Industrial Pro-Cryl Universal Prime 2 Standard test based on Certificate of Analysis
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative or visit www.paintdocs.com to obtain the most current version of the PDS and/or an SDS.
APPLICATION Refer to the SDS sheet before use Temperature: 55°F/12.8°C minimum 100°F/37.8°C maximum (Air, surface, and material) At least 5°F above dew point Relative humidity: 85% maximum The following is a guide. Changes in pressures and tip sizes may be needed for proper spray characteristics. Always purge spray equipment before use with listed reducer. Any reduction must be compatible with the existing environmental and application conditions. Excessive reduction of material can affect film build, appearance, and adhesion. Reducer/Clean Up ............................... Water Airless Spray Pressure ............................................ 2000 psi Hose ..................................................... 1/4" ID Tip .......................................................... .015" Filter ................................................ 100 mesh Reduction . As needed up to 12.5% by volume Brush Brush .................................... Nylon / polyester Reduction .......................... Not recommended Roller Cover .......... 3/8" woven solvent resistant core Reduction ......................... Not recommended If specific application equipment is not listed above, equivalent equipment may be substituted. In order to avoid blockage of spray equipment, clean equipment before use or before periods of extended downtime with soap and water.
CLEANUP INFORMATION Clean spills, spatters, hands and tools immediately after use with soap and warm water. After cleaning, flush spray equipment with compliant cleanup solvent to prevent rusting of the equipment. Follow manufacturer’s safety recommendations when using solvents. HOTW 05/15/2017 B70W211/B60V25 01 143 HOTW 05/15/2017 B70W213/B60V25 01 168 HOTW 05/15/2017 B70T204/B60V25 01 162
SURFACE PREPARATION WARNING! Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. When cleaning the surface per SSPC-SP1, use only an emulsifying industrial detergent, followed by a water rinse. Do not use hydrocarbon solvents for cleaning. Iron & Steel - Minimum surface preparation is Power Tool Clean per SSPC-SP3. Remove all oil and grease from surface by Solvent Cleaning per SSPC-SP1 (recommended preparation is Steam Cleaning). For better performance, use Commercial Blast Cleaning per SSPC-SP6/NACE 3, blast clean all surfaces using a sharp, angular abrasive for optimum surface profile (2 mils). Prime any bare steel within 8 hours or before flash rusting occurs. Aluminum - Remove all oil, grease, dirt, oxide and other foreign material per SSPC-SP1. Galvanizing - Allow to weather a minimum of six months prior to coating. Solvent Clean per SSPC-SP1. When weathering is not possible, or the surface has been treated with chromates or silicates, first Solvent Clean per SSPC-SP1 and apply a test patch. Allow paint to dry at least one week before testing adhesion. If adhesion is poor, brush blasting per SSPC-SP16 is necessary to remove these treatments. Rusty galvanizing requires a minimum of Hand Tool Cleaning per SSPC-SP2, prime the area the same day as cleaned. Concrete Block - Surface should be thoroughly clean and dry. Air, material and surface temperatures must be at least 55°F (12.8°C) before filling. Use Pro Industrial Heavy Duty Block Filler or Loxon Block Surfacer. The filler must be thoroughly dry before topcoating. Masonry - All masonry must be free of dirt, oil, grease, loose paint, mortar, masonry dust, etc. Clean per SSPC-SP13/Nace 6/ ICRI No. 310.2R, CSP 1-3. Poured, troweled, or tilt-up concrete, plaster, mortar, etc. must be thoroughly cured at least 30 days at 75°F. Form release compounds and curing membranes must be removed by brush blasting. Brick must be allowed to weather for one year prior to surface preparation and painting. Prime the area the same day as cleaned. Weathered masonry and soft or porous cement board must be brush blasted or power tool cleaned to remove loosely adhering contamination and to get to a hard, firm surface. Apply one coat Loxon Conditioner, following label recommendations. Previously Painted Surfaces - If in sound condition, clean the surface of all foreign material. Smooth, hard or glossy coatings and surfaces should be dulled by abrading the surface. Apply a test area, allowing paint to dry one week before testing adhesion. If adhesion is poor, additional abrasion of the surface and/or removal of the previous coating may be necessary. Retest surface for adhesion. If paint is peeling or badly weathered, clean surface to sound substrate and treat as a new surface as above. Recognize that any surface preparation short of total removal of the old coating may compromise the service length of the system. Wood - Surface must be clean, dry and sound. Prime with recommended primer. No painting should be done immediately after a rain or during foggy weather. Knots and pitch streaks must be scraped, sanded and spot primed before full coat of primer is applied. All nail holes or small openings must be properly caulked. Primer recommended.
APPLICATION PROCEDURES Apply paint at the recommended film thickness and spreading rate as indicated on front page. Application of coating above maximum or below minimum recommended spreading rate may adversely affect coating performance. Spreading rates are calculated on volume solids and do not include an application loss factor due to surface profile, roughness, or porosity of the surface, skill, and technique of the applicator, method of application, various surface irregularities, material lost during mixing, spillage, over thinning, climatic conditions, and excessive film build.
SAFETY PRECAUTIONS Refer to the SDS sheets before use. FOR PROFESSIONAL USE ONLY Published technical data and instructions are subject to change without notice. Contact your Sherwin-Williams representative for additional technical data and instructions.
PERFORMANCE TIPS Mix contents of each component thoroughly with low speed power agitation. Make certain no pigment remains on the bottom of the can. Then combine four parts by volume of Part A with one part by volume of Part B. Thoroughly agitate the mixture with power agitation. Allow the material to sweat-in as indicated. Re-stir before using. If reducer solvent is used, add only after both components have been thoroughly mixed, after sweat-in. Do not apply the material beyond recommended pot life. Do not mix previously catalyzed material with new. Stripe coat crevices, welds, and sharp angles to prevent early failure in these areas. When using spray application, use a 50% overlap with each pass of the gun to avoid holidays, bare areas, and pinholes. If necessary, cross spray at a right angle. No painting should be done immediately after a rain or during foggy weather. All epoxies will chalk and fade when un-topcoated in exterior environments. Apply appropriate topcoat if aesthetics are required.
WATER BASED CATALYZED EPOXY B70 SERIES
PRO INDUSTRIAL™
113.01
PRE-CATALYZED WATERBASED EPOXY
K45-150 SERIES EG-SHEL K46-150 SERIES SEMI-GLOSS
Block 1 ct. Loxon Block Surfacer 2 cts. Pro Industrial Pre-Catalyzed Epoxy Drywall 1 ct. ProMar 200 Zero VOC Primer 2 cts. Pro Industrial Pre-Catalyzed Epoxy Masonry 1 ct. Loxon Concrete & Masonry Primer 2 cts. Pro Industrial Pre-Catalyzed Epoxy
Steel, Aluminum, Galvanized 1 ct. Pro Industrial Pro-Cryl Primer 2 cts. Pro Industrial Pre-Catalyzed Epoxy Wood 1 ct. Premium Wall and Wood Primer 2 cts. Pro Industrial Pre-Catalyzed Epoxy
System Tested: Substrate: Steel Surface Preparation: SSPC-SP6 Primer: 1 ct. DTM Acrylic Primer Finish: 1 ct. Pro Industrial Pre-Catalyzed Epoxy Eg-Shel
CHARACTERISTICS Pro Industrial Pre-Catalyzed Waterbased Epoxies are single-component pre-catalyzed waterborne acrylic epoxies that offers the adhesion, durability and resistance to stains and most cleaning solvents usually characteristic of two-component waterborne acrylic epoxy products. These products can be applied over a wide variety of primers on properly prepared interior metal, wood, masonry, plaster and drywall. Interior institutional/commercial high
maintenance areas Upgrade surfaces painted with
conventional coatings with a high performance protection system with excellent adhesion
Corrosion and Chemical resistant Hospitals and Schools Institutional dining and kitchen areas Suitable for use in USDA inspected
facilities Color: most colors Recommended Spread Rate per coat: 4.0 mils wet; 1.5 mils dry 350 - 400 sq ft/gal NOTE: Brush or roll application may require multiple coats to achieve maximum film thickness and uniformity of appearance. Drying Time @ 4.0 mils wet, 50% RH, 77°F: temperature and humidity dependent Touch: 1 hour Recoat: 8 hours Drying time is temperature, humidity, and film thickness dependent. If this product dries 72 hours or longer it must be sanded before it is recoated. This product is fully cured in approximately 5 - 7 days. Finish: Eg-Shel 20 - 30 units @ 85° Semi-Gloss 55 - 65 units @ 60° Flash Point: N/A Shelf Life: 36 months, unopened Store indoors at 40°F to 100°F. Tinting with CCE or BAC: Use SherCOLOR Formulation System
K45W00151 VOC (less exempt solvents): 135 g/L; 1.12 lb/gal Volume Solids: 36 ± 2% Weight Solids: 51 ± 2% Weight per Gallon: 10.63 lb ± 0.2 lb
As of 06/24/2015, Complies with: OTC Yes LEED® 09 CI Yes SCAQMD No LEED® 09 NC Yes CARB Yes LEED® 09 CS Yes CARB SCM 2007 Yes NGBS Yes MPI Yes
6/2015 www.sherwin-williams.com continued on back
Adhesion Method: ASTM D3359 Result: 5B 100% Adhesion for light colors; Darker colors require longer cure time for same level of adhesion Block Resistance Lab Assessment Excellent
Pencil Hardness: Method: ASTM D3363 Result: 2B Scrub Resistance Method: ASTM D 2486 Result: 500 - 600cycles with Stiff Bristle Brush and Pumice Scrub Media
RECOMMENDED SYSTEMS
Chemical Resistance ASTM D 1308 Rating: Excellent Resistance • Limited Resistance x Distilled Water (Hot and at Room Temperature) ........ • Ethyl Alcohol ....................................... • Vinegar (3% acetic acid) ..................... • Alkali (10% Sodium Hydroxide) ........... • Acid (10% Sulfuric Acid) ...................... • Soap (10% Fantastik®) ....................... • 50/50 Xylene/Mineral Spirits ............... • Mildew Resistant This coating contains agents which inhibit the growth of mildew on the surface of this coating film.
Stain Resistance ASTM D 3023 Rating: Excellent Resistance • Limited Resistance x Mustard ................................................ • Grape Juice .......................................... • Red Crayon .......................................... x Lipstick, Red ........................................ • Permanent Ink ...................................... x Coffee .................................................. • 10% Sodium Hydroxide (alkali) ............ • Acetic Acid ........................................... •
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative or visit www.paintdocs.com to obtain the most current version of the PDS and/or an SDS.
APPLICATION Refer to the SDS before use. Temperature: 50°F minimum 120°F maximum (Air, surface, and material) At least 5°F above dew point Relative humidity: 85% maximum The following is a guide. Changes in pressures and tip sizes may be needed for proper spray characteristics. Always purge spray equipment before use with listed reducer. Any reduction must be compat ib le wi th the ex is t ing environmental and application conditions. Airless Spray Pressure ........................ 1800 - 2700 psi Hose ............................................ 1/4" ID Tip ...................................... .015" - .021" Filter ......................................... 60 mesh Reduction .................. Not recommended Brush ......................... Nylon / polyester Reduction .................. Not recommended Roller .......................... 1/4 - 1/2" woven Reduction ................. Not recommended If specific application equipment is listed above, equivalent equipment may be substituted.
CLEANUP INFORMATION Clean spills, spatters, hands and tools immediately after use with soap and warm water. After cleaning, flush spray equipment with compliant cleanup solvent to prevent rusting of the equipment. F o l l o w manu fac tu re r ’ s sa fe t y recommendations when using solvents.
CAUTION Not for use on surfaces continuously wet or under water, such as bath tubs, sinks, showers, or countertops. HOTW 06/24/2015 K45W00151 11 135 KOR
SURFACE PREPARATION WARNING! Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. Remove all surface contamination including mildew by washing with an appropriate cleaner, rinse thoroughly and allow to dry. Scrape and sand peeled or checked paint to a sound surface. Sand glossy surfaces dull. Seal stains from water, smoke, ink, pencil, grease, etc. with an appropriate primer/sealer. Iron & Steel - Minimum surface preparation is Hand Tool Clean per SSPC-SP2. Re-move all oil and grease from surface per SSPC-SP1. For better performance, use Commercial Blast Cleaning per SSPC-SP6. Primer recommended for best perform-ance. Aluminum - Remove all oil, grease, dirt, oxide and other foreign material per SSPC-SP1. Galvanizing - Allow to weather a minimum of six months prior to coating. Solvent Clean per SSPC-SP1. When weathering is not possible, or the surface has been treated with chromates or silicates, first Solvent Clean per SSPC-SP1 and apply a test patch. Allow paint to dry at least one week before testing adhesion. If adhesion is poor, brush blasting per SSPC-SP7 is necessary to remove these treatments. Rusty galvanizing requires a minimum of Hand Tool Cleaning per SSPC-SP2, prime the area the same day as cleaned. Concrete and Masonry - For surface preparation, refer to SSPC-SP13/NACE 6 or ICRI 03732, CSP 1-3. Surfaces should be thoroughly cleaned and dry. Surface tem-peratures must be at least 55°F before filling. If required for a smoother finish, use the recommended filler/surfacer. The filler/surfacer must be thoroughly dry before topcoating per manufacturer's recommendations. Weathered masonry and soft or porous cement board must be brush blasted or power tool cleaned to remove loosely adhering contamination and to get to a hard, firm surface. Apply one coat Loxon Conditioner, following label recommendations. Drywall - Fill cracks and holes with patching paste/spackle and sand smooth. Joint compounds must be cured and sanded smooth. Remove all sanding dust. Wood - Sand any exposed wood to a fresh surface. Patch all holes and imperfec-tions with a wood filler or putty and sand smooth. Previously Painted Surfaces - If in sound condition, clean the surface of all foreign material. Smooth, hard or glossy coatings and surfaces should be dulled by abrading the surface. Apply a test area, allowing paint to dry one week before testing adhe-sion. If adhesion is poor, additional abrasion of the surface and/or removal of the previous coating may be necessary. Retest surface for adhesion. If paint is peeling or badly weathered, clean surface to sound substrate and treat as a new surface as above.
PRO INDUSTRIAL™ PRE-CATALYZED WATERBASED EPOXY
CHARACTERISTICS Color: White Base Coverage: 450-500 sq ft/gal (11.04-12.27 m2/L) @ 3.1 mils wet; .9 mils dry Drying Time, @ 77°F(25°C), 50% RH: Drying and recoat times are temperature, humidity and film thickness dependent.
Touch: 30 minutes Recoat: as a primer 1 hour as a stain sealer: 4 hours with a Hi-Performance Finish 24 hours Flash Point: N/A Finish: 0-5 units @ 60° Tinting with CCE only: Base oz/gal Strength White 0 - 2 Sher-Color Vehicle Type: Acrylic
B51W00150
VOC (less exempt solvents): <50 g/L; <0.42 lb/gal As per 40 CFR 59.406 and SOR/2009-264, s.12
Volume Solids: 30 ± 2% Weight Solids: 47 ± 2% Weight per Gallon: 10.93 lb (4.96 kg) Tinting May be tinted with no more than 2 oz. of ColorCast Ecotoner® per gallon. Do not exceed 2 ounces per gallon of total colorant. Check color before use. For best topcoat color development, use the recommended "P"-shade primer. When spot priming on some surfaces, a non-uniform appearance of the final coat may result, due to differences in holdout between primed and unprimed areas. To avoid this, prime the entire surface rather than spot priming. See Exterior Use if priming pre-finished metal surfaces. Must be topcoated within 14 days with oil/alkyd, latex, epoxy, urethane, and lacquer topcoats.
SURFACE PREPARATION WARNING! Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. Remove all surface contamination by washing with an appropriate cleaner, rinse thoroughly and allow to dry. Existing peeled or checked paint should be scraped and sanded to a sound surface. Glossy surfaces should be sanded dull. Recognize that any surface preparation short of total removal of the old coating may compromise the service length of the system. Testing - On hard, slick, glossy, or otherwise hard to paint surfaces, after preparing the surface, apply a test area of this primer, allow to dry properly and test for adhesion. Because of the exceptional adhesion of this product, sanding may not be necessary for most clean, paintable surfaces. Sanding or dulling with an abrasive cleaner is recommended on glossy, extremely hard surfaces for maximum adhesion. Stains from heavy water, smoke, ink, pencil, grease, etc. should be sealed with the appropriate primer/sealer.
CHARACTERISTICS Extreme Bond Primer is a high quality, waterborne, acrylic, primer. Designed for coating hard, slick, glossy surfaces with minimal surface preparation. Because of the exceptional adhesion of this product, sanding may not be necessary for most clean, paintable surfaces.
• Promotes adhesion on hard to paint
surfaces • Tightly bonds to slick and glossy surfaces • Assures uniform appearance of topcoats • One coat application • Fast dry • Universal, will accept Hi-Performance
coatings such as epoxies and urethanes • Assures adhesion of the topcoat to slick,
glossy surfaces Interior & Exterior for use on these surfaces: • PVC Piping • Plastics • Glass • Wall Laminate • Glossy Surfaces • Aluminum • Kitchen Cabinets • Fiberglass • Varnished Woodwork • Ceramic Wall Tile • Previously Painted Surfaces • Glazed Block • Fluoropolymer coatings EXTERIOR USE When priming larger exterior pre-finished metal surfaces where exterior maximum adhesion is needed, use DTM Bonding Primer.
As of 12/08/2016, Complies with: OTC Yes LEED® 09 NC, CI Yes OTC Phase II Yes LEED® 09 CS Yes SCAQMD Yes LEED® 09 H & S Yes CARB Yes LEED® v4 Emissions Yes CARB SCM 2007 Yes LEED® v4 VOC Yes Canada Yes MPI Yes
12/2016 www.sherwin-williams.com continued on back
108.51
EXTREME BOND™ Interior/Exterior Bonding Primer
B51W00150 (US)
B51WQ0150 (Canada)
GREENGUARD PRODUCT CERTIFIED FOR LOW CHEMICAL EMISSIONS UL.COM/GG UL 2818
GOLD
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative or visit www.paintdocs.com to obtain the most current version of the PDS and/or an SDS.
108.51
EXTREME BOND™ Interior/Exterior Bonding Primer
B51W00150 (US)
B51WQ0150 (Canada)
SURFACE PREPARATION Mildew Prior to attempting to remove mildew, it is always recommended to test any cleaner on a small, inconspicuous area prior to use. Bleach and bleaching type cleaners may damage or discolor existing paint films. Bleach alternative cleaning solutions may be advised. Mildew may be removed before painting by washing with a solution of 1 part liquid bleach and 3 parts water. Apply the solution and scrub the mildewed area. Allow the solution to remain on the surface for 10 minutes. Rinse thoroughly with water and allow the surface to dry before painting. Wear protective eyewear, waterproof gloves, and protective clothing. Quickly wash off any of the mixture that comes in contact with your skin. Do not add detergents or ammonia to the bleach/water solution. Do not use hydrocarbon containing solvents such as mineral spirits. When cleaning the surface use only a waterbased emulsifying detergent.
APPLICATION When the air temperature is at 35°F(1.7°C)substrates may be colder; prior to painting, check to be sure the air, surface, and material temperature are above 35°F(1.7°C) and at least 5°F above the dew point. Avoid using if rain or snow is expected within 2-3 hours. Air and surface temperatures must not drop below 35°F(1.7°C) for 48 hours after application. Do not reduce for stain blocking. No reduction necessary. Brush - Use a nylon/polyester brush. Roller - Use a 3/8” nap soft woven roller cover. Spray—Airless Pressure .................................... 2000 psi Tip ......................................... .015"-.021"
CAUTIONS Protect from freezing. Non-photochemically reactive. Do not use this product in areas subject to excessive water, e.g., in showers, around sinks, or on tubs. Not for use on floors. For large exterior pre-finished metal surfaces such as siding, use DTM Bonding Primer. Do not use on large surfaces of exterior wood. Does not adhere to polypropylene, polyethylene, or thermoplastic polyolefins. HOTW 12/08/2016 B51W00150 06 00 SP, FRC
CLEANUP INFORMATION Clean spills, spatters, hands and tools with soap and warm water. After cleaning, flush spray equipment with compliant cleanup solvent to prevent rusting of the equipment. Follow manufacturer's safety recommendations when using solvents.
SURFACE PREPARATION Due to the wide variety of substrates, surface preparation methods, application methods, and environments, one should test the complete system for adhesion, compatibility and performance prior to full scale application. Aluminum and Galvanized Wash to remove any oil, grease, or other surface contamination. All corrosion must be removed with sandpaper, wire brush, or other abrading methods. Ceramic Tile/ Glazed Block and Brick/ Porcelain After removing all surface contamination, the surface should be scuff sanded or scrubbed with an abrasive cleaner to dull the surface for best adhesion. Tile - Tile, laminate, ceramic and plastic tiles, and similar glossy surfaces, must be free of all oil, grease, and soap residue. Glass Apply Extreme Bond directly to glass that has been thoroughly cleaned. CAUTION: Any opaque coating will block light, which then causes an increase in the surface temperature of the glass. Dark colors will get hotter than light colors. In tightly fitted glass, any increase in the temperature of the glass will cause some expansion of the glass, which may cause it to shatter. Plastic/Vinyl/PVC/Fiberglass/ Formica After removing all surface contamination, the surface should be scuff sanded or scrubbed with an abrasive cleaner to dull the surface for best adhesion. Plastic: Due to the diverse nature of plastic substrates, a coating or coating system must be tested for acceptable adhesion to the substrate prior to use in production. Reground and recycled plastics along with various fire retardants, flowing agents, mold release agents, and foaming/blowing agents will affect coating adhesion. Please consult your Sherwin- Williams Representative for system recommendations.
www.sherwin-williams.com/protective Ref: 1101-1 (NA 4.53)
Page 1 of 2
Protective & Marine Coatings PRODUCT DATA SHEET
MACROPOXY® 646
FAST CURE EPOXY
Revised: January, 2018 PRODUCT DESCRIPTION
MACROPOXY 646 FAST CURE EPOXY a high solids, high build, fast drying, polyamide epoxy designed to protect steel and concrete in
industrial exposures. Ideal for maintenance painting and fabrication shop applications. The high solids content ensures adequate protection of sharp edges, corners, and welds. This product can be applied directly to marginally prepared steel surfaces.
INTENDED USES
Recommended for marine applications, refineries, offshore platforms, fabrication shops, chemical plants, tank exteriors, power plants, water treatment plants, and mining and minerals industry
Mill White and Black are acceptable for immersion use for salt water and fresh water, not acceptable for potable water
PRODUCT DATA
Volume Solids: 72% ± 2%, mixed, Mill White
VOC (mixed): Unreduced: <250 g/L; 2.08 lb/gal
Reduced 10%: <300 g/L; 2.50 lb/gal
Finish: Semi-Gloss
Colors: Mill White, Black and a wide range
of colors available through tinting
Typical Thickness:
Recommended Spreading Rate Per Coat
Minimum Maximum
Wet mils (microns) 7.0 (175) 13.5 (338) Dry mils (microns) 5.0* (125) 10.0 (250) ~Coverage sq ft/gal (m2/L) 115 (2.9) 230 (5.8) Theoretical coverage sq ft/gal
(m2/L) @ 1 mil (25 microns) dft 1152 (28.2)
*May be applied at 3.0-10.0 mils (75-250 microns) dft in a multicoat system. NOTE: Brush or roll application may require multiple coats to achieve
maximum film thickness and uniformity of appearance.
Mix Ratio: 1:1 by volume
Reducer/Clean Up: Reducer R7K15 or R7K58 (California) Reducer R7K111 or Oxsol 100
Flash Point: 91°F (33°C), TCC, mixed
Packaging: Part A: 1 gallon (3.78L) and 5 gallon (18.9L) containers Part B: 1 gallon (3.78L) and 5 gallon (18.9L) containers
Average Drying Times @ 7.0 mils wet (175 microns): 35⁰F (1.7⁰C)
77⁰F (25⁰C) 50% RH
100⁰F (38⁰C)
Touch 4-5 hours 2 hours 1.5 hours Handle 48 hours 8 hours 4.5 hours Recoat
- Minimum - Maximum
48 hours 1 year
8 hours 1 year
4.5 hours 1 year
Cure to Service
- Atmospheric - Immersion
10 days 14 days
7 days 7 days
4.5 hours 4 days
If maximum recoat time is exceeded, abrade surface before recoating. Drying time is temperature, humidity, and film thickness dependent. Paint temperature must be at least 40°F (4.5°C) minimum.
Pot Life 10 hours 4 hours 2 hours Sweat-in-time 30 minutes 30 minutes 15 minutes
Weight: 12.9 ± 0.2 lb/gal ; 1.55 Kg/L mixed, may vary by color
Shelf Life: 36 months, unopened Store indoors at 40°F 4.5°C)
to 110°F (43°C)
SURFACE PREPARATION
Surface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.
Minimum recommended surface preparation: Iron & Steel: Atmospheric: SSPC-SP2/3/ ISO8501-1:2007 St 2 or SSPC-SP WJ-3 / NACE WJ-3L Immersion: SSPC-SP10 / NACE 2/ ISO8501-1:2007 Sa 2.5, 2-3 mil (50-75 micron) profile or SSPC-SP WJ- 2/NACE WJ-2L Aluminum & Galvanizing: SSPC-SP1 Concrete & Masonry: Atmospheric: SSPC-SP13 / NACE 6, or ICRI No. 310.2R, CSP 1-3 Immersion: SSPC-SP13 / NACE 6-4.3.1
www.sherwin-williams.com/protective Ref: 1101-1 (NA 4.53)
Page 2 of 2
MACROPOXY® 646
FAST CURE EPOXY
Protective & Marine Coatings PRODUCT DATA SHEET
APPLICATION APPLICATION CONDITIONS
Airless Spray*
Pump ............................. 30:1 Pressure ....................... 2800 - 3000 psi (193 – 206 bar) Hose .............................. 1/4" ID (6.3 mm) Tip ................................. .017" - .023" (0.43 – 0.58 mm) Filter .............................. 60 mesh Reduction ...................... As needed up to 10% by volume
Conventional Spray*
Gun ............................... DeVilbiss MBC-510 Fluid Tip ........................ E Air Nozzle ...................... 704 Atomization Pressure .... 60 - 65 psi (4.1 – 4.5 bar) Fluid Pressure ............... 10 - 20 psi (0.7 – 1.4 bar)
Brush*
Brush ............................. Nylon/Polyester or Natural Bristle
Roller*
Cover ............................ 3/8" woven with solvent resistant core
Plural Component Spray…..Acceptable
*Reduction ........................ As needed up to 10% by volume
Temperature: Air : 35°F (1.7°C) minimum, 120°F (49°C) maximum Surface: 35°F (1.7°C) minimum, 250°F (120°C) maximum Material: 40°F (4.5°C) minimum
At least 5°F (2.8°C) above dew point Relative humidity: 85% maximum
APPROVALS
• Suitable for use in USDA inspected facilities
• Acceptable for use in Canadian Food Processing facilities, categories: D1, D2, D3 (Confirm acceptance of specific part numbers/rexes with your SW Sales Representative)
• Conforms to AWWA D102 OCS #5
• Conforms to MPI # 108
• This product meets specific design requirements for non-safety related nuclear plant applications in Level II, III and Balance of Plant, and DOE nuclear facilities*
* Nuclear qualifications are NRC license specific to the facility
ADDITIONAL NOTES
Tint Part A with Maxitoners at 150% strength. Five minutes minimum mixing on a mechanical shaker is required for complete mixing of color. Tinting is not recommended for immersion service. Quik-Kick Epoxy Accelerator is acceptable for use. See data page 4.99 for details. Acceptable for Concrete Floors.
When spraying above 120°F, reduce material 10% with R7K100. Spray apply only. Product will produce an orange peel appearance when applied at elevated temperatures.
RECOMMENDED SYSTEMS
Dry Film Thickness / ct. Mils (Microns) Steel, Immersion & Atmospheric
1 Ct. Macropoxy 646 5.0-10.0 (125-250) Steel, Organic Zinc Primer, Atmospheric
1 Ct. Zinc Clad IV (85) 3.0-5.0 (75-125) 1 Ct. Macropoxy 646 5.0-10.0 (125-250) Steel, Inorganic Zinc Primer, Atmospheric:
1 Ct. Zinc Clad II (85) 2.0-4.0 (50-100) 1 Ct. Macropoxy 646 5.0-10.0 (125-250) Steel, Organic Zinc/Epoxy/Urethane Topcoat
1 Ct. Zinc Clad IV (85) 3.0-5.0 (75-125) 1 Ct. Macropoxy 646 5.0-10.0 (125-250) 1 Ct. Acrolon 7300 2.0-4.0 (50-100) Steel, Inorganic Zinc/Epoxy/Urethane Topcoat
1 Ct. Zinc Clad II (85) 2.0-4.0 (50-100) 1 Ct. Macropoxy 646 5.0-10.0 (125-250) 1 Ct. Acrolon 7300 2.0-4.0 (50-100) Steel, Organic Zinc/Epoxy/Polysiloxane Topcoat, Atmospheric 1 Ct. Zinc Clad IV (85) 3.0-5.0 (75-125) 1 Ct. Macropoxy 646 5.0-10.0 (125-250) 1-2 Cts. Sher-Loxane 800 2.0-4.0 (50-100) Concrete/Masonry, Smooth, Immersion & Atmospheric 1 Ct. Macropoxy 646 5.0-10.0 (125-250)
HEALTH AND SAFETY Refer to the SDS sheet before use. Published technical data and instructions are subject to change without
notice. Contact your Sherwin-Williams representative for additional technical
data and instructions. WARRANTY The Sherwin-Williams Company warrants our products to be free of manufacturing defects in accord with applicable Sherwin-Williams quality control procedures. Liability for products proven defective, if any, is limited to replacement of the defective product or the refund of the purchase price paid for the defective product as determined by Sherwin-Williams. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY SHERWIN-WILLIAMS, EXPRESSED OR IMPLIED, STATUTORY, BY OPERATION OF LAW OR OTHERWISE, INCLUDING MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE.
DISCLAIMER The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams
Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of
publication. Consult your Sherwin-Williams representative to obtain the most recent Product Data Sheet.
Revised: September 22, 2017
ACROLON™ 218 HSACRYLIC POLYURETHANE
PART A B65-600 GLOSS SERIES PART A B65-650 SEmI-GLOSS SERIES PART B B65V600 HARdENER
Protective &
MarineCoatings
5.22
www.sherwin-williams.com/protective
Product descriPtion
ACROLON 218 HS is a polyester modified, aliphatic, acrylic polyurethane formulated specifically for in-shop applications. Also suitable for industrial applications. A fast drying, urethane that provides color and gloss retention for exterior exposure.• Can be used directly over organic zinc rich primers (epoxy zinc
primer and moisture cure urethane zinc primer)• Color and gloss retention for exterior exposure• Fast dry• Outstanding application properties
Product characteristicsFinish: Gloss or Semi-GlossColor: Wide range of colors availableVolume Solids: 65% ± 2%, mixed, may vary by colorWeight Solids: 78% ± 2%, mixed, may vary by colorVOC (EPA Method 24): Unreduced: <300 g/L; 2.5 lb/gal mixed Reduced 10% with R7K15: <340 g/L; 2.8 lb/gal mixed Reduced 9% with MEK, R6K10: <340 g/L; 2.8 lb/gal Mix Ratio: 6:1 by volume, 1 gallon or 5 gallon mixes premeasured components
Recommended Spreading Rate per coat:Minimum Maximum
Wet mils (microns) 4.5 (112.5) 9.0 (225)Dry mils (microns) 3.0 (75) 6.0 (150)~Coverage sq ft/gal (m2/L) 175 (4.3) 346 (8.5)Theoretical coverage sq ft/gal (m2/L) @ 1 mil / 25 microns dft 1040 (25.5)
NOTE: Brush or roll application may require multiple coats to achieve maximum film thickness and uniformity of appearance.
Drying Schedule @ 6.0 mils wet (150 microns):@ 35°F/1.7°C @ 77°F/25°C @ 120°F/49°C
50% RHTo touch: 4 hours 30 minutes 20 minutesTo handle: 18 hours 6 hours 4 hoursTo recoat:
minimum: 18 hours 8 hours 6 hoursmaximum: 3 months 3 months 3 months
To cure: 14 days 7 days 5 daysPot Life: 4 hours 2 hours 45 minutes(reduced 5% with Reducer R7K15)Sweat-in-Time: None
If maximum recoat time is exceeded, abrade surface before recoating.Drying time is temperature, humidity, and film thickness dependent.Paint temperature must be at least 40°F (4.5°C) minimum.
Shelf Life: Part A* - 36 months, unopenedPart B - 24 months, unopenedStore indoors at 40°F (4.5°C) to 100°F (38°C).
*Aluminum (Part A, Rex # B65SW655) has a shelf life of 24 months.Flash Point: 55°F (13°C), Seta, mixedReducer/Clean Up:Spray:
Brush / Roll:
Reducer R7K15, MEK R6K10, R7K111, Reducer #58Reducer #132, Reducer #58, R7K111
continued on back
recommended usesSpecifically formulated for in-shop applications.For use over prepared metal and masonry surfaces in industrial environ-ments such as:• Structural steel • Tank exteriors• Rail cars and locomotives • Pipelines• Conveyors • Ships• Bridges • Wind Towers - onshore and offshore• Offshore platforms - exploration and production• Suitable for use in USDA inspected facilities• Conforms to AWWA D102 Outside Coating Systems #4 (OCS-4), #5
(OCS-5) & #6 (OCS-6)• Acceptable for use in high performance architectural applications• Acceptable for use over and/or under Loxon S1 and Loxon H1 Caulking• A component of INFINITANK• Over FIRETEX® hydrocarbon systems• Suitable for use in the Mining & Minerals Industry
Performance characteristics
Substrate*: SteelSurface Preparation*: SSPC-SP10/NACE 2System Tested*:
1 ct. Macropoxy 646 @ 6.0 mils (150 microns) dft1 ct. Acrolon 218 HS Gloss @ 4.0 mils (100 microns) dft
*unless otherwise noted belowTest Name Test Method Results
Abrasion Resistance1
ASTM D4060, CS17 wheel, 1000 cycles, 1 kg load
43 mg loss
Adhesion3 ASTM D4541 1976 psi
Corrosion Weathering3
ASTM D5894, 27 cycles, 9072 hours
Rating 10 per ASTM D610, for rusting; Rating 10 per ASTM D714, for blistering
Direct Impact Resistance1 ASTM D2794 50 in. lb.
Dry Heat Resistance1 ASTM D2485, Method A 200°F (93°C)
Flexibility1 ASTM D522, 180° bend, 1/8" mandrel Passes
Humidity Resistance2 ASTM D4585, 100°F (38°C), 1500 hours
Rating 10 per ASTM D610, for rusting; Rating 10 per ASTM D714, for blistering
Pencil Hardness ASTM D3363 3H
Salt Fog Resistance3 ASTM B117, 15,000 hours
Rating 10 per ASTM D610, for rusting; Rating 10 per ASTM D714, for blistering
Meets the requirements of SSPC Paint No. 36, Level 3 for white and light colors. Dark colors may require a clear coat.
Complies with ISO 12944-5 C5I and C5M requirements.Footnotes:1 Finish coat only tested2 Primer Zinc-Clad II Plus Intermediate Macropoxy 646 Finish Acrolon 218 HS3Primer Zinc-Clad III HS
Revised: September 22, 2017
ACROLON™ 218 HSACRYLIC POLYURETHANE
PART A B65-600 GLOSS SERIES PART A B65-650 SEmI-GLOSS SERIES PART B B65V600 HARdENER
Protective &
MarineCoatings
5.22
www.sherwin-williams.com/protective
surface PreParation
Surface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.Refer to product Application Bulletin for detailed surface prepara-tion information.Minimum recommended surface preparation:* Iron & Steel: SSPC-SP6/NACE 3, 1-2 mil (25-50 micron) profile* Galvanizing: SSPC-SP1* Concrete & Masonry: SSPC-SP13/NACE 6, or ICRI No. 310.2R, CSP 1-3* Primer required
Surface Preparation StandardsCondition of Surface
ISO 8501-1BS7079:A1
Swedish Std.SIS055900 SSPC NACE
White Metal Sa 3 Sa 3 SP 5 1Near White Metal Sa 2.5 Sa 2.5 SP 10 2Commercial Blast Sa 2 Sa 2 SP 6 3Brush-Off Blast Sa 1 Sa 1 SP 7 4Hand Tool Cleaning Rusted C St 2 C St 2 SP 2 -
Pitted & Rusted D St 2 D St 2 SP 2 -Power Tool Cleaning Rusted C St 3 C St 3 SP 3 -
Pitted & Rusted D St 3 D St 3 SP 3 -
tintingTint Part A with Maxitoner Colorants.• Extra white tints at 100% tint strength• Ultradeep base tints at 150% tint strength
Five minutes minimum mixing on a mechanical shaker is required for complete mixing of color.
aPPlication conditionsTemperature: 35°F (1.7°C) minimum, 120°F (49°C) maximum (air and surface) 40°F (4.5°C) minimum, 120°F (49°C) maximum (material) At least 5°F (2.8°C) above dew pointRelative humidity: 85% maximum
Refer to product Application Bulletin for detailed application information.
ordering informationPackaging: 1 gallon (3.78L) mix: 5 gallon (18.9L) mix: Part A: .86 gal (3.25L) 4.29 gal (16.2L) Part B: .14 gal (0.53L) 0.71 gal (2.7L) (premeasured components)Weight: 11.2 ± 0.2 lb/gal ; 1.3 Kg/L mixed, may vary with color
safety PrecautionsRefer to the MSDS sheet before use.
Published technical data and instructions are subject to change without notice. Contact your Sherwin-Williams representative for additional technical data and instructions.
WarrantyThe Sherwin-Williams Company warrants our products to be free of manufactur-ing defects in accord with applicable Sherwin-Williams quality control procedures. Liability for products proven defective, if any, is limited to replacement of the defec-tive product or the refund of the purchase price paid for the defective product as determined by Sherwin-Williams. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY SHERWIN-WILLIAMS, EXPRESSED OR IMPLIED, STATUTORY, BY OPERATION OF LAW OR OTHERWISE, INCLUDING MER-CHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE.
PROdUCT INfORmATION
recommended systems Dry Film Thickness / ct. Mils (Microns)Steel:1 ct. Macropoxy 646 5.0-10.0 (125-250)1-2 cts. Acrolon 218 HS Polyurethane 3.0-6.0 (75-150)
Steel:1 ct. Zinc Clad II Plus 3.0-5.0 (75-125)1 ct. Macropoxy 646 5.0-10.0 (125-250)1-2 cts. Acrolon 218 HS Polyurethane 3.0-6.0 (75-150) Steel:1 ct. Zinc Clad IV 3.0-5.0 (75-125)1-2 cts. Acrolon 218 HS Polyurethane 3.0-6.0 (75-150)
Steel:1 ct. Corothane I-GalvaPac Zinc Primer 3.0-4.0 (75-100)1-2 cts. Acrolon 218 HS Polyurethane 3.0-6.0 (75-150)
Steel:1 ct. Epoxy Mastic Aluminum II 6.0 (150)1-2 cts. Acrolon 218 HS Polyurethane 3.0-6.0 (75-150)
Steel:1 ct. Recoatable Epoxy Primer 4.0-6.0 (100-150)1-2 cts. Acrolon 218 HS Polyurethane 3.0-6.0 (75-150)
Concrete/Masonry: 1 ct. Kem Cati-Coat HS Epoxy 10.0-20.0 (250-500) Filler/Sealer 1-2 cts. Acrolon 218 HS Polyurethane 3.0-6.0 (75-150)
Aluminum/Galvanizing:1 ct. DTM Wash Primer 0.7-1.3 (18-32)1-2 cts. Acrolon 218 HS Polyurethane 3.0-6.0 (75-150)
FIRETEX ONLY:Finish Coat for FIRETEX Hydrocarbon Systems:1 ct. Acrolon 218 HS Polyurethane**Consult FIRETEX PFP Specialist for recommended dft range
The systems listed above are representative of the product's use, other systems may be appropriate.
disclaimerThe information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative to obtain the most recent Product Data Information and Application Bulletin.
Revised: September 22, 2017
ACROLON™ 218 HSACRYLIC POLYURETHANE
PART A B65-600 GLOSS SERIES PART A B65-650 SEmI-GLOSS SERIES PART B B65V600 HARdENER
Protective &
MarineCoatings
5.22
www.sherwin-williams.com/protective
surface PreParations
Surface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.
Iron & SteelRemove all oil and grease from surface by Solvent Cleaning per SSPC-SP1. Minimum surface preparation is Commercial Blast Cleaning per SSPC-SP6/NACE 3. For better performance, use Near White Metal Blast Cleaning per SSPC-SP10/NACE 2. Blast clean all surfaces using a sharp, angular abrasive for optimum surface profile (1-2 mils / 25-50 microns). Prime any bare steel the same day as it is cleaned or before flash rusting occurs.
AluminumRemove all oil, grease, dirt, oxide and other foreign material by Solvent Cleaning per SSPC-SP1. Primer required.
Galvanized SteelAllow to weather a minimum of six months prior to coating. Solvent Clean per SSPC-SP1. When weathering is not possible, or the surface has been treated with chromates or silicates, first Solvent Clean per SSPC-SP1 and apply a test patch. Allow paint to dry at least one week before testing adhesion. If adhesion is poor, brush blasting per SSPC-SP7 is necessary to remove these treatments. Rusty galvanizing requires a minimum of Hand Tool Cleaning per SSPC-SP2, prime the area the same day as cleaned or before flash rusting occurs. Primer required.
Concrete and MasonryFor surface preparation, refer to SSPC-SP13/NACE 6, or ICRI No. 310.2R, CSP 1-3. Surfaces should be thoroughly clean and dry. Concrete and mortar must be cured at least 28 days @ 75°F (24°C). Remove all loose mortar and foreign material. Surface must be free of laitance, concrete dust, dirt, form release agents, moisture curing membranes, loose cement and hardeners. Fill bug holes, air pockets and other voids with Steel-Seam FT910. Primer required.
Follow the standard methods listed below when applicable:ASTM D4258 Standard Practice for Cleaning Concrete.ASTM D4259 Standard Practice for Abrading Concrete.ASTM D4260 Standard Practice for Etching Concrete.ASTM F1869 Standard Test Method for Measuring Moisture Vapor Emission Rate of Concrete.SSPC-SP 13/Nace 6 Surface Preparation of Concrete.ICRI No. 310.2R Concrete Surface Preparation.
Surface Preparation StandardsCondition of Surface
ISO 8501-1BS7079:A1
Swedish Std.SIS055900 SSPC NACE
White Metal Sa 3 Sa 3 SP 5 1Near White Metal Sa 2.5 Sa 2.5 SP 10 2Commercial Blast Sa 2 Sa 2 SP 6 3Brush-Off Blast Sa 1 Sa 1 SP 7 4Hand Tool Cleaning Rusted C St 2 C St 2 SP 2 -
Pitted & Rusted D St 2 D St 2 SP 2 -Power Tool Cleaning Rusted C St 3 C St 3 SP 3 -
Pitted & Rusted D St 3 D St 3 SP 3 -
APPLICATION BULLETIN
aPPlication conditions
Temperature: 35°F (1.7°C) minimum, 120°F (49°C) maximum (air and surface) 40°F (4.5°C) minimum, 120°F (49°C) maximum (material) At least 5°F (2.8°C) above dew point
Relative humidity: 85% maximum
aPPlication equiPment
The following is a guide. Changes in pressures and tip sizes may be needed for proper spray characteristics. Always purge spray equipment before use with listed reducer. Any reduction must be compliant with existing VOC regulations and compatible with the existing environmental and application conditions.
Reducer/Clean Up: Spray..............................Reducer R7K15, MEK, Reducer #58, or
R7K111 Brush/Roll ......................Reducer #132, R7K132, Reducer #58,
or R7K111 If reducer is used, reduce at time of catalyzation.Airless Spray Pressure.........................2500 - 2800 psi Hose...............................3/8" ID Tip ...................................013" - .017" Filter ...............................60 mesh Reduction .......................As needed up to 10% by volume with
R7K15 or R7K111, or up to 9% with MEK, R6K10*
Conventional Spray Gun ................................Binks 95 Cap ................................63P Atomization Pressure .....50 - 70 psi Fluid Pressure ................20 - 25 psi Reduction .......................As needed up to 10% by volume with
R7K15 or R7K111, or up to 9% with MEK, R6K10*
Brush Brush..............................Natural Bristle Reduction .......................As needed up to 10% by volume*
Roller Cover .............................3/8" woven with solvent resistant core Reduction .......................As needed up to 10% by volume*
If specific application equipment is not listed above, equivalent equipment may be substituted.
* Note: Reducing more than maximum recommended level willresult in VOC exceeding 340g/L
continued on back
Revised: September 22, 2017
ACROLON™ 218 HSACRYLIC POLYURETHANE
PART A B65-600 GLOSS SERIES PART A B65-650 SEmI-GLOSS SERIES PART B B65V600 HARdENER
Protective &
MarineCoatings
5.22
www.sherwin-williams.com/protective
APPLICATION BULLETINaPPlication Procedures
Surface preparation must be completed as indicated.
Mix contents of each component thoroughly with low speed power agitation. Make certain no pigment remains on the bottom of the can. Then combine six parts by volume of Part A with one part by volume of Part B (premeasured components). Thoroughly agitate the mixture with power agitation. Re-stir before using.
If reducer is used, add only after both components have been thoroughly mixed.
Apply paint at the recommended film thickness and spreading rate as indicated below:
Recommended Spreading Rate per coat:Minimum Maximum
Wet mils (microns) 4.5 (112.5) 9.0 (225)Dry mils (microns) 3.0 (75) 6.0 (150)~Coverage sq ft/gal (m2/L) 175 (4.3) 346 (8.5)Theoretical coverage sq ft/gal (m2/L) @ 1 mil / 25 microns dft 1040 (25.5)
NOTE: Brush or roll application may require multiple coats to achieve maximum film thickness and uniformity of appearance.
Drying Schedule @ 6.0 mils wet (150 microns):@ 35°F/1.7°C @ 77°F/25°C @ 120°F/49°C
50% RHTo touch: 4 hours 30 minutes 20 minutesTo handle: 18 hours 6 hours 4 hoursTo recoat:
minimum: 18 hours 8 hours 6 hoursmaximum: 3 months 3 months 3 months
To cure: 14 days 7 days 5 daysPot Life: 4 hours 2 hours 45 minutes(reduced 5% with Reducer R7K15)Sweat-in-Time: None
If maximum recoat time is exceeded, abrade surface before recoating.Drying time is temperature, humidity, and film thickness dependent.Paint temperature must be at least 40°F (4.5°C) minimum.
Application of coating above maximum or below minimum recommended spreading rate may adversely affect coating performance.
clean uP instructionsClean spills and spatters immediately with Reducer #132, R7K132. Clean tools immediately after use with Reducer #132, R7K132. Follow manufacturer's safety recommendations when using any solvent.
disclaimerThe information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative to obtain the most recent Product Data Information and Application Bulletin.
Performance tiPsStripe coat all crevices, welds, and sharp angles to prevent early failure in these areas.
When using spray application, use a 50% overlap with each pass of the gun to avoid holidays, bare areas, and pinholes. If necessary, cross spray at a right angle.
Spreading rates are calculated on volume solids and do not include an application loss factor due to surface profile, roughness or po-rosity of the surface, skill and technique of the applicator, method of application, various surface irregularities, material lost during mixing, spillage, overthinning, climatic conditions, and excessive film build.
Excessive reduction of material can affect film build, appearance, and adhesion.
Do not apply the material beyond recommended pot life.
Do not mix previously catalyzed material with new.
In order to avoid blockage of spray equipment, clean equipment before use or before periods of extended downtime with Reducer #15, R7K15 or MEK, R6K10.
Mixed coating is sensitive to water. Use water traps in all air lines. Moisture contact can reduce pot life and affect gloss and color.
Quick-Thane Urethane Accelerator is acceptable for use. See data page 5.97 for details.
E-Z Roll Urethane Defoamer is acceptable for use. See data page 5.99 for details.
Refer to Product Information sheet for additional performance characteristics and properties.
safety PrecautionsRefer to the MSDS sheet before use.
Published technical data and instructions are subject to change without notice. Contact your Sherwin-Williams representative for additional technical data and instructions.
WarrantyThe Sherwin-Williams Company warrants our products to be free of manufacturing defects in accord with applicable Sherwin-Williams quality control procedures. Liability for products proven defective, if any, is limited to replacement of the de-fective product or the refund of the purchase price paid for the defective product as determined by Sherwin-Williams. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY SHERWIN-WILLIAMS, EXPRESSED OR IMPLIED, STATUTORY, BY OPERATION OF LAW OR OTHERWISE, INCLUDING MER-CHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE.
PRO INDUSTRIAL™
113.12
WATERBASED ALKYD URETHANE ENAMEL
B53-1050 SERIES GLOSS B53-1150 SERIES SEMI- GLOSS B53-1250 SERIES LOW SHEEN
Steel: 1ct. Pro Industrial Pro-Cryl Primer 2cts. Pro Industrial Waterbased Alkyd
Urethane Aluminum: 1ct. Pro Industrial Pro-Cryl Primer 2cts. Pro Industrial Waterbased Alkyd
Urethane Galvanizing: 1ct. Pro Industrial Pro-Cryl Primer 2cts. Pro Industrial Waterbased Alkyd
Urethane Concrete Block: 1ct. Heavy Duty Block Filler 2cts. Pro Industrial Waterbased Alkyd
Urethane
Concrete/Masonry: 1ct. Loxon Concrete & Masonry Pri-
mer 2cts. Pro Industrial Waterbased Alkyd
Urethane Drywall: 1 ct. ProMar 200 Zero VOC Primer 2 cts. Pro Industrial Waterbased Alkyd
Urethane Wood, Exterior: 1 ct. Exterior Wood Primer 2 cts. Pro Industrial Waterbased Alkyd
Urethane Wood, Interior: 1 ct. Premium Wall & Wood Primer 2 cts. Pro Industrial Waterbased Alkyd
Urethane
System Tested: (unless otherwise indicated) Substrate: Cold Rolled Steel Finish: 1 ct. Pro Industrial Waterbased Alkyd Urethane 4 mils wet
PRODUCT DESCRIPTION Pro Industrial Waterbased Alkyd Urethane Enamel is a premium quality interior/exterior enamel formulated with a urethane modified alkyd resin system for high performance. It provides beauty and durability when applied to interior/exterior surfaces such as properly prepared drywall, wood, masonry and metal. It brings together the convenience and ease of use of a waterborne coating with the performance and coating characteristics of a traditional oil-based enamel.
Excellent washability & flow & leveling
Excellent touch up
Easy application & cleanup
Resistant to yellowing compared to traditional alkyds
Suitable for use in USDA inspected facilities
PRODUCT CHARACTERISTICS Color: most colors
Extra White B53W01051
Recommended Spread Rate per coat: Wet mils: 4.0 - 5.0 Dry mils: 1.4 - 1.7 Coverage: 320 - 400 sq ft/gal (7.85-9.81 m2/L) Approximate spreading rates are calculated on volume solids and do not include any application loss. Note: Brush or roll application may require multiple coats to achieve maximum film thickness and uniformity of appearance.
Drying Time @ 4.0 mils wet 50% RH: @ 77°F To touch: 1-2 hrs To recoat: 4 hrs Drying time is temperature, humidity, and film thickness dependent.
Finish: 75+@ 60° Gloss 55-70 @ 60° Semi-Gloss 15-25 @ 60° Low Sheen Tinting with CCE: Base oz/gal Strength Extra White 0 - 6 SherColor Deep Base 4 -12 SherColor Ultradeep Base 10 -14 SherColor
Extra White B53W01051 (may vary by color and base)
VOC (less exempt solvents): <50 g/L; <0.42 lb/gal As per 40 CFR 59.406 and SOR/2009-264, s.12 Volume Solids: 34 ± 2% Weight Solids: 47 ± 2% Weight per Gallon: 10.28 lb, (4.66kg) Flash Point: N/A Vehicle Type: Urethane modified alkyd
04/2018 www.sherwin-williams.com continued on back
Pencil Hardness: Method: ASTM D3363 Result: 5H Flexibility: Method: ASTM D522, 180° bend, 1/8" mandrel Result: Excellent no cracking Dry Heat Resistance: Method: ASTM D2485 Result: 200°F Block Resistance: Lab assessment Excellent Resistance to Yellowing: Lab assessment Excellent Oil resistance Lanolin: Lab assessment Excellent
RECOMMENDED SYSTEMS
As of 04/04/2018, Complies with: OTC Yes LEED® 09 NC CI Yes OTC Phase II Yes LEED® 09 CS Yes SCAQMD Yes LEED® v4 Emissions No CARB Yes LEED® v4 VOC Yes CARB SCM2007 Yes Canada Yes MPI
The systems listed above are representative of the product's use, other systems may be appropriate.
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative or visit www.paintdocs.com to obtain the most current version of the PDS and/or an SDS.
APPLICATION Refer to the SDS before using. Temperature: 50°F(10°C) minimum 100°F(37.8°C) maximum (Air, surface, and material) At least 5°F above dew point Relative humidity: 85% maximum The following is a guide. Changes in pressures and tip sizes may be needed for proper spray characteristics. Always purge spray equipment before use with listed reducer. Any reduction must be compatible with the existing environmental and application conditions.
Reducer: Water Airless Spray Pressure .................................... 2000 psi Hose ............................................ 1/4" ID Tip ...................................... .013" - .017" Filter ......................................... 60 mesh Reduction .................. Not recommended Brush ......................... Nylon / polyester Reduction .................. Not recommended Roller ............................ 1/4-1/2" woven Reduction ................. Not recommended If specific application equipment is listed above, equivalent equipment may be substituted.
CLEANUP INFORMATION Clean spills, spatters, hands and tools immediately after use with soap and warm water. After cleaning, flush spray equipment with compliant cleanup solvent to prevent rusting of the equipment. Follow manufacturer’s safety recommendations when using solvents. DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations. HOTW 03/28/2018 B53W01051 08 43 KOR,FRC,SP
SURFACE PREPARATION WARNING! Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. Do not use hydrocarbon solvents for cleaning. Iron & Steel - Minimum surface preparation is Hand Tool Clean per SSPC-SP2. Remove all oil and grease from surface per SSPC-SP1. For better performance, use Commercial Blast Cleaning per SSPC-SP6. Prime the area the same day as cleaned. Aluminum - Remove all oil, grease, dirt, oxide and other foreign material per SSPC-SP1. Prime the area the same day as cleaned. Galvanizing - Allow to weather a minimum of six months prior to coating. Solvent Clean per SSPC-SP1. When weathering is not possible, or the surface has been treated with chromates or silicates, first Solvent Clean per SSPC-SP1 and apply a test patch. Allow paint to dry at least one week before testing adhesion. If adhesion is poor, brush blasting per SSPC-SP16 is necessary to remove these treatments. Rusty galvanizing requires a minimum of Hand Tool Cleaning per SSPC-SP2, prime the area the same day as cleaned. Concrete Block - Surface should be thoroughly clean and dry. Air, material and surface temperatures must be at least 50°F (10°C) before filling. Use Heavy Duty Block Filler or Loxon Block Surfacer. The filler must be thoroughly dry before topcoating. Masonry - All masonry must be free of dirt, oil, grease, loose paint, mortar, masonry dust, etc. Clean per SSPC-SP13/Nace 6/ ICRI No. 310.2R, CSP 1-3. Poured, troweled, or tilt-up concrete, plaster, mortar, etc. must be thoroughly cured at least 30 days at 75°F(23.9°C). Form release compounds and curing membranes must be removed by brush blasting. Brick must be allowed to weather for one year prior to surface preparation and painting. Prime the area the same day as cleaned. Weathered masonry and soft or porous cement board must be brush blasted or power tool cleaned to remove loosely adhering contamination and to get to a hard, firm surface. Apply one coat Loxon Conditioner, following label recommendations. Wood - Surface must be clean, dry and sound. Prime with recommended primer. No painting should be done immediately after a rain or during foggy weather. Knots and pitch streaks must be scraped, sanded and spot primed before full coat of primer is applied. All nail holes or small openings must be properly caulked. Previously Painted Surfaces - If in sound condition, clean the surface of all foreign material. Smooth, hard or glossy coatings and surfaces should be dulled by abrading the surface. Apply a test area, allowing paint to dry one week before testing adhesion. If adhesion is poor, additional abrasion of the surface and/or removal of the previous coating may be necessary. Retest surface for adhesion. If paint is peeling or badly weathered, clean surface to sound substrate and treat as a new surface as above. Recognize that any surface preparation short of total removal of the old coating may compromise the service length of the system.
APPLICATION PROCEDURES Apply paint at the recommended film thickness and spreading rate as indicated on front page. Application of coating below minimum recommended spreading rate will adversely affect coating performance.
SAFETY PRECAUTIONS Refer to the Safety Data Sheets (SDSs) before use. FOR PROFESSIONAL USE ONLY. Published technical data and instructions are subject to change without notice. Contact your Sherwin-Williams representative for additional technical data and instructions.
PERFORMANCE TIPS No painting should be done immediately after a rain or during foggy weather. When using spray application, use a 50% overlap with each pass of the gun to avoid holidays, bare areas, and pinholes. Apply coating evenly while maintaining a wet edge to prevent lapping.
PRO INDUSTRIAL WATERBASED ALKYD URETHANE ENAMEL
PRO INDUSTRIAL™
113.05
PRO-CRYL® UNIVERSAL PRIMER
B66W00310 OFF WHITE B66A00310 GRAY B66N00310 RED OXIDE
Waterborne topcoat: 1-2 cts. Pro Industrial Acrylic or Pro Industrial DTM Acrlyic or Pro Industrial Multi-Surface Acrylic or Pro Industrial Pre-Catalyzed Waterbased Epoxy or Pro Industrial Waterbased Acrolon 100 or Pro Industrial Waterbased Catalyzed Epoxy Solventborne topcoat: 1-2 cts. Pro Industrial High Performance Epoxy or Pro Industrial Urethane Alkyd Pro Industrial Pro-Cryl Universal Primer B66W310 Off White is GREENGUARD GOLD certified for low chemical emissions into indoor air during product usage. For more information, visit ul.com/gg.
System Tested: (unless otherwise indicated) Substrate: Steel Surface Preparation: SSPC-SP10 1 ct. Pro Industrial Pro-Cryl Universal Primer 1 ct. Pro Industrial Acrylic
CHARACTERISTICS Pro Industrial Pro-Cryl Universal Primer is an advanced technology, self cross-linking acrylic primer. It is rust inhibitive and designed for commercial, new construction and maintenance applications. It can be used as a primer under water-based or solvent-based high performance topcoats. Rust inhibitive Single component Early moisture resistant Fast dry Low temperature application 40°F Interior and exterior use Suitable for use in USDA inspected
facilities Color: Off White, Gray, Red Oxide Recommended Spread Rate per coat: Wet mils: 5.0 - 10.0 Dry mils: 1.8 - 3.6 ~Coverage: 160 - 320 sq ft/gal Approximate Theoretical coverage sq ft/gal (m2/L) @ 1 mil / 25 microns dft 577sq ft NOTE: Brush or roll application may require multiple coats to achieve maximum film thickness and uniformity of appearance.
Drying Time @ 6.0 mils wet 50% RH: 40°F 77°F 120°F To touch: 2 hrs 40 min 20 min Tack free: 8 hrs 2 hrs 1 hr To recoat: 16 hrs 4 hrs 2 hrs To cure: 45 days 30 days 14 days Drying time is temperature, humidity, and film thickness dependent.
Finish: Low sheen Flash Point: N/A Shelf Life: 36 months, unopened Store indoors at 40°F to 100°F. Tinting: Do not tint
B66W310 (may vary by color) VOC (less exempt solvents): 96 g/L; 0.80 lb/gal As per 40 CFR 59.406 and SOR/2009-264, s.12
Volume Solids: 36% ± 2% Weight Solids: 49% ± 2% Weight per Gallon: 10.23 lb
9/2015 www.sherwin-williams.com continued on back
Adhesion: Method: ASTM D4541 Result: 500 psi Corrosion Weathering: Method: ASTM D5894, 10 cycles,
3360 hours Result: Passes Direct Impact Resistance: Method: ASTM D2794 Result: >140 in. lbs. Dry Heat Resistance*: Method: ASTM D2485 Result: 200°F Flexibility: Method: ASTM D522, 180° bend,
1/4" mandrel Result: Passes
Moisture Condensation Resistance: Method: ASTM D4585, 100°F, 1250
hours Result: Passes Pencil Hardness: Method: ASTM D3363 Result: H Salt Fog Resistance: Method: ASTM B117, 1250 hours Result: Passes Provides performance comparable to products formulated In Lieu of Federal Specification: AA50557 and Paint Specification: SSPC-Paint 23.
RECOMMENDED SYSTEMS
As of 09/11/2015, Complies with: OTC Yes LEED® 09 CI Yes SCAQMD Yes LEED® 09 NC Yes CARB Yes LEED® 09 CS Yes CARB SCM 2007 Yes LEED® 09 S Yes MPI 107,134 NGBS Yes
*Suitable for intermittent dry heat resistance up to 300°F when used as a system with Sher-Cryl HPA
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative or visit www.paintdocs.com to obtain the most current version of the PDS and/or an SDS.
APPLICATION Refer to the SDS before using Temperature: 40°F minimum 120°F maximum (air, surface, and material) At least 5°F above dew point Relative humidity: 85% maximum The following is a guide. Changes in pressures and tip sizes may be needed for proper spray characteristics. Always purge spray equipment before use with listed reducer. Any reduction must be compatible with the existing environmental and application conditions.
Reducer: Water Airless Spray Pressure .................................... 2000 psi Hose ............................................ 1/4" ID Tip ...................................... .015" - .019" Filter ......................................... 60 mesh Reduction .................. Not recommended Conventional Spray Gun .......................................... Binks 95 Fluid Nozzle ........................................ 66 Air Nozzle ...................................... 63PB Atomization Pressure .................... 60 psi Fluid Pressure ............................... 25 psi ReductionAs needed up to 5% by volume Brush ........................... Nylon/Polyester Reduction .................. Not recommended Roller ...................................3/8" woven ReductionAs needed up to 5% by volume If specific application equipment is listed above, equivalent equipment may be substituted.
CLEANUP INFORMATION Clean spills and spatters immediately with soap and warm water. Clean hands and tools immediately after use with soap and warm water. After cleaning, flush spray equipment with compliant cleanup solvent to prevent rusting of the equipment. Follow manufacturer's safety recommendations when using solvents. HOTW 09/11/2015 B66W00310 32 96 KOR, FRC, SP
SURFACE PREPARATION WARNING! Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. Do not use hydrocarbon solvents for cleaning. Iron & Steel - Minimum surface preparation is Hand Tool Cleaning per SSPC-SP2. Remove all oil and grease from the surface per SSPC-SP1. For better performance, use Commercial Blast Cleaning per SSPC-SP6. Aluminum - Remove all oil, grease, dirt, oxide and other foreign material per SSPC-SP1.Prime the area the same day as cleaned. Galvanizing - Allow to weather a minimum of six months prior to coating. Solvent Clean per SSPC-SP1. When weathering is not possible, or the surface has been treated with chromates or silicates, first Solvent Clean per SSPC-SP1 and apply a test patch. Allow paint to dry at least one week before testing adhesion. If adhesion is poor, brush blasting per SSPC-SP16 is necessary to remove these treatments. Rusty galvanizing requires a minimum of Hand Tool Cleaning per SSPC-SP2, prime the area the same day as cleaned. Previously Painted Surfaces - If in sound condition, clean the surface of all foreign material. Smooth, hard or glossy coatings and surfaces should be dulled by abrading the surface. Apply a test area, allowing paint to dry one week before testing adhesion. If adhesion is poor, additional abrasion of the surface and/or removal of the previous coating may be necessary. Retest surface for adhesion. If paint is peeling or badly weathered, clean surface to sound substrate and treat as a new surface as above. Recognize that any surface preparation short of total removal of the old coating may compromise the service length of the system.
APPLICATION PROCEDURES Apply paint at the recommended film thickness and spreading rate as indicated on front page. Application of coating below minimum recommended spreading rate will adversely affect coating performance.
SAFETY PRECAUTIONS Refer to the SDS sheets before use. FOR PROFESSIONAL USE ONLY Published technical data and instructions are subject to change without notice. Contact your Sherwin-Williams representative for additional technical data and instructions.
PERFORMANCE TIPS No painting should be done immediately after a rain or during foggy weather. When using spray application, use a 50% overlap with each pass of the gun to avoid holidays, bare areas, and pinholes. Apply coating evenly while maintaining a wet edge to prevent lapping.
PRO INDUSTRIAL™ PRO-CRYL® UNIVERSAL PRIMER
page 1 of 2
FLASH POINT> 200 °F PMCC
Specific Gravity1.72
Product Weight14.26 lb/gal
42 00 [0487]
ENVIRONMENTAL DATA SHEET(Certified Product Data Sheet)
Date of PreparationJan 18, 2018
PRODUCT NUMBERB42W46
PRODUCT NAMEHeavy Duty Block Filler - Acrylic Block Filler, White
MANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)| Acute | Chronic |
Volatile IngredientsChemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by VolumeWater
7732-18-5 N N N N 26 45
Volatile Organic Compounds - U.S. EPA
A. Coating Density 14.26 lb/gal 1708 g/lB. Total Volatiles 27.7% by wt. 47.5% by vol.C. Federally exempt solvents:
Water 26.2% by wt. 45.0% by vol.D. Organic Volatiles 1.5% by wt. 2.4% by vol.E. Percent Non-Volatile 72.3% by wt. 52.5% by vol.F. VOC Content 0.20 lb/gal 24 g/l total
0.37 lb/gal 45 g/l less exempt solvents0.39 lb/gal 47 g/l of solids0.02 lb/lb 0.02 kg/kg of solids0.0% by wt LVP-VOC
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009)0.03
Volatile Organic Compounds - California
A. Coating Density 14.26 lb/gal 1708 g/lB. Total Volatiles 27.7% by wt. 47.5% by vol.C. Exempt solvents:
Water 26.2% by wt. 45.0% by vol.D. Organic Volatiles 1.5% by wt. 2.4% by vol.E. Percent Non-Volatile 72.3% by wt. 52.5% by vol.F. VOC Content 0.20 lb/gal 24 g/l total
0.37 lb/gal 45 g/l less exempt solvents0.39 lb/gal 47 g/l of solids0.02 lb/lb 0.02 kg/kg of solids0.0% by wt LVP-VOC
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010)0.03
B42W46
page 2 of 2
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
A. Coating Density 14.26 lb/gal 1708 g/lB. Total Volatiles 27.7% by wt. 47.5% by vol.C. Exempt solvents:
Water 26.2% by wt. 45.0% by vol.D. Organic Volatiles 1.5% by wt. 2.4% by vol.E. Percent Non-Volatile 72.3% by wt. 52.5% by vol.F. VOC Content 0.20 lb/gal 24 g/l total
0.37 lb/gal 45 g/l less exempt solvents0.39 lb/gal 47 g/l of solids0.02 lb/lb 0.02 kg/kg of solids0.0% by wt LVP-VOC
Volatile Organic Compounds - EU Directive 2010/75/EU
Total Volatiles 27.1% by wt. 46.3% by vol.VOC Content 0.11 lb/gal 13 g/l
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
Volatile HAPS 0.00 lb/gal 0.000 kg/l0.00 lb/gal 0.000 kg/l of solids0.00 lb/lb 0.00 kg/kg of solids
Air Quality Data
Density of Organic Solvent Blend8.46 lb/gal
Photochemically ReactiveNo
Additional Regulatory Information
US EPA TSCA:Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:Not Applicable
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.
page 1 of 3
FLASH POINT> 200 °F PMCC
Specific Gravity1.17
Product Weight9.69 lb/gal
26 00 [2407]
ENVIRONMENTAL DATA SHEET(Certified Product Data Sheet)
Date of PreparationJan 15, 2018
PRODUCT NUMBERB70W211
PRODUCT NAMEWater Based Catalyzed Epoxy (Part A), Extra White
MANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)| Acute | Chronic |
Volatile IngredientsChemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume2-(2-Butoxyethoxy)-ethanol
112-34-5 N N *** *** 2 2
Ethylene Glycol107-21-1 N Y Y Y 2 3
Water7732-18-5 N N N N 49 57
Regulated CompoundsSARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
*** Glycol Ethers (SARA) N N Y N 2*** Glycol Ethers (HAPS) N N N Y 2
Volatile Organic Compounds - U.S. EPA
A. Coating Density 9.69 lb/gal 1161 g/lB. Total Volatiles 54.2% by wt. 62.9% by vol.
Non-Organic Volatiles:Ammonium Hydroxide 0.1% by wt. 0.2% by vol.
C. Federally exempt solvents:Water 49.3% by wt. 57.3% by vol.
D. Organic Volatiles 4.8% by wt. 5.4% by vol.E. Percent Non-Volatile 45.8% by wt. 37.1% by vol.F. VOC Content 0.46 lb/gal 56 g/l total
1.09 lb/gal 131 g/l less exempt solvents1.26 lb/gal 151 g/l of solids0.10 lb/lb 0.10 kg/kg of solids0.1% by wt LVP-VOC
As-Applied < 1.24 lb/gal < 149 g/l by wt less exempt solventsMaximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009)
0.13
B70W211
page 2 of 3
Volatile Organic Compounds - California
A. Coating Density 9.69 lb/gal 1161 g/lB. Total Volatiles 54.2% by wt. 62.9% by vol.
Non-Organic Volatiles:Ammonium Hydroxide 0.1% by wt. 0.2% by vol.
C. Exempt solvents:Water 49.3% by wt. 57.3% by vol.
D. Organic Volatiles 4.8% by wt. 5.4% by vol.E. Percent Non-Volatile 45.8% by wt. 37.1% by vol.F. VOC Content 0.46 lb/gal 56 g/l total
1.09 lb/gal 131 g/l less exempt solvents1.26 lb/gal 151 g/l of solids0.10 lb/lb 0.10 kg/kg of solids0.1% by wt LVP-VOC
As-Applied < 1.24 lb/gal < 149 g/l by wt less exempt solventsMaximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010)
0.13
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
A. Coating Density 9.69 lb/gal 1161 g/lB. Total Volatiles 54.2% by wt. 62.9% by vol.
Non-Organic VolatilesAmmonium Hydroxide 0.1% by wt. 0.2% by vol.
C. Exempt solvents:Water 49.3% by wt. 57.3% by vol.
D. Organic Volatiles 4.8% by wt. 5.4% by vol.E. Percent Non-Volatile 45.8% by wt. 37.1% by vol.F. VOC Content 0.46 lb/gal 56 g/l total
1.09 lb/gal 131 g/l less exempt solvents1.26 lb/gal 151 g/l of solids0.10 lb/lb 0.10 kg/kg of solids0.1% by wt LVP-VOC
As-Applied < 1.24 lb/gal < 149 g/l by wt less exempt solvents
Volatile Organic Compounds - EU Directive 2010/75/EU
Total Volatiles 52.4% by wt. 60.7% by vol.VOC Content 0.28 lb/gal 34 g/l
As-Applied < 0.41 lb/gal < 49 g/l< 52.9% by wt. < 60 % by vol.
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
Volatile HAPS 0.54 lb/gal 0.065 kg/l1.47 lb/gal 0.176 kg/l of solids0.12 lb/lb 0.12 kg/kg of solids
Air Quality Data
Density of Organic Solvent Blend8.53 lb/gal
Photochemically ReactiveNo
Additional Regulatory Information
US EPA TSCA:Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:Not Applicable
B70W211
page 3 of 3
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.
page 1 of 3
FLASH POINTN.A.
Specific Gravity1.24
Product Weight10.31 lb/gal
15 00 [2846]
ENVIRONMENTAL DATA SHEET(Certified Product Data Sheet)
Date of PreparationMar 1, 2018
PRODUCT NUMBERK46W151
PRODUCT NAMEPRO INDUSTRIAL™ Pre-Catalyzed Waterbased Semi-Gloss Epoxy, Extra White
MANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)| Acute | Chronic |
Volatile IngredientsChemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume2-(2-Methoxyethoxy)-ethanol
111-77-3 N N *** *** 2 2
1-(2-Butoxymethylethoxy)-propanol29911-28-2 N N N N 2 3
Water7732-18-5 N N N N 46 57
Regulated CompoundsSARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
*** Glycol Ethers (SARA) N N Y N 2*** Glycol Ethers (HAPS) N N N Y 2
Volatile Organic Compounds - U.S. EPA
A. Coating Density 10.31 lb/gal 1235 g/lB. Total Volatiles 51.2% by wt. 63.9% by vol.
Non-Organic Volatiles:Ammonium Hydroxide 0.3% by wt. 0.5% by vol.
C. Federally exempt solvents:Water 46.1% by wt. 57.2% by vol.
D. Organic Volatiles 4.8% by wt. 6.2% by vol.E. Percent Non-Volatile 48.8% by wt. 36.1% by vol.F. VOC Content 0.49 lb/gal 59 g/l total
1.15 lb/gal 138 g/l less exempt solvents1.36 lb/gal 164 g/l of solids0.09 lb/lb 0.09 kg/kg of solids1.6% by wt LVP-VOC
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009)0.09
K46W151
page 2 of 3
Volatile Organic Compounds - California
A. Coating Density 10.31 lb/gal 1235 g/lB. Total Volatiles 51.2% by wt. 63.9% by vol.
Non-Organic Volatiles:Ammonium Hydroxide 0.3% by wt. 0.5% by vol.
C. Exempt solvents:Water 46.1% by wt. 57.2% by vol.
D. Organic Volatiles 4.8% by wt. 6.2% by vol.E. Percent Non-Volatile 48.8% by wt. 36.1% by vol.F. VOC Content 0.49 lb/gal 59 g/l total
1.15 lb/gal 138 g/l less exempt solvents1.36 lb/gal 164 g/l of solids0.09 lb/lb 0.09 kg/kg of solids1.6% by wt LVP-VOC
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010)0.09
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
A. Coating Density 10.31 lb/gal 1235 g/lB. Total Volatiles 51.2% by wt. 63.9% by vol.
Non-Organic VolatilesAmmonium Hydroxide 0.3% by wt. 0.5% by vol.
C. Exempt solvents:Water 46.1% by wt. 57.2% by vol.
D. Organic Volatiles 4.8% by wt. 6.2% by vol.E. Percent Non-Volatile 48.8% by wt. 36.1% by vol.F. VOC Content 0.49 lb/gal 59 g/l total
1.15 lb/gal 138 g/l less exempt solvents1.36 lb/gal 164 g/l of solids0.09 lb/lb 0.09 kg/kg of solids1.6% by wt LVP-VOC
Volatile Organic Compounds - EU Directive 2010/75/EU
Total Volatiles 48.0% by wt. 59.7% by vol.VOC Content 0.16 lb/gal 19 g/l
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
Volatile HAPS 0.21 lb/gal 0.025 kg/l0.59 lb/gal 0.070 kg/l of solids0.04 lb/lb 0.04 kg/kg of solids
Air Quality Data
Density of Organic Solvent Blend7.80 lb/gal
Photochemically ReactiveNo
Additional Regulatory Information
US EPA TSCA:Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:Not Applicable
K46W151
page 3 of 3
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.
page 1 of 2
FLASH POINTN.A.
Specific Gravity1.32
Product Weight10.93 lb/gal
08 00 [0618]
ENVIRONMENTAL DATA SHEET(Certified Product Data Sheet)
Date of PreparationMar 3, 2018
PRODUCT NUMBERB51W150
PRODUCT NAMEExtreme Bond Primer, White
MANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)| Acute | Chronic |
Volatile IngredientsChemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by VolumeWater
7732-18-5 N N N N 53 70
Volatile Organic Compounds - U.S. EPA
A. Coating Density 10.93 lb/gal 1310 g/lB. Total Volatiles 53.2% by wt. 70.3% by vol.C. Federally exempt solvents:
Water 53.0% by wt. 70.1% by vol.2-Amino-2-Methyl-1-Propanol 0.1% by wt. 0.2% by vol.
D. Organic Volatiles 0.0% by wt. 0.0% by vol.E. Percent Non-Volatile 46.8% by wt. 29.7% by vol.F. VOC Content 0.00 lb/gal 0 g/l total
0.00 lb/gal 0 g/l less exempt solvents0.00 lb/gal 0 g/l of solids0.00 lb/lb 0.00 kg/kg of solids0.0% by wt LVP-VOC
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009)0.00
Volatile Organic Compounds - California
A. Coating Density 10.93 lb/gal 1310 g/lB. Total Volatiles 53.2% by wt. 70.3% by vol.C. Exempt solvents:
Water 53.0% by wt. 70.1% by vol.D. Organic Volatiles 0.1% by wt. 0.2% by vol.E. Percent Non-Volatile 46.8% by wt. 29.7% by vol.F. VOC Content 0.01 lb/gal 1 g/l total
0.05 lb/gal 6 g/l less exempt solvents0.05 lb/gal 6 g/l of solids0.00 lb/lb 0.00 kg/kg of solids0.1% by wt LVP-VOC
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010)0.00
B51W150
page 2 of 2
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
A. Coating Density 10.93 lb/gal 1310 g/lB. Total Volatiles 53.2% by wt. 70.3% by vol.C. Exempt solvents:
Water 53.0% by wt. 70.1% by vol.D. Organic Volatiles 0.1% by wt. 0.2% by vol.E. Percent Non-Volatile 46.8% by wt. 29.7% by vol.F. VOC Content 0.01 lb/gal 1 g/l total
0.05 lb/gal 6 g/l less exempt solvents0.05 lb/gal 6 g/l of solids0.00 lb/lb 0.00 kg/kg of solids0.1% by wt LVP-VOC
Volatile Organic Compounds - EU Directive 2010/75/EU
Total Volatiles 53.2% by wt. 70.3% by vol.VOC Content 0.01 lb/gal 1 g/l
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
Volatile HAPS 0.00 lb/gal 0.000 kg/l0.00 lb/gal 0.000 kg/l of solids0.00 lb/lb 0.00 kg/kg of solids
Air Quality Data
Density of Organic Solvent Blend7.80 lb/gal
Photochemically ReactiveNo
Additional Regulatory Information
US EPA TSCA:Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:Not Applicable
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.
page 1 of 2
FLASH POINT85 °F PMCC
Specific Gravity1.47
Product Weight12.19 lb/gal
26 00 [2867]
ENVIRONMENTAL DATA SHEET(Certified Product Data Sheet)
Date of PreparationOct 16, 2017
PRODUCT NUMBERB58W610
PRODUCT NAMEMACROPOXY® 646 Fast Cure Epoxy (Part A), Mill White
MANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)| Acute | Chronic | Fire |
Volatile IngredientsChemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by VolumeEthylbenzene
100-41-4 N Y Y Y 3 4
Xylene1330-20-7 N Y Y Y 15 25
Volatile Organic Compounds - U.S. EPA
A. Coating Density 12.19 lb/gal 1460 g/lB. Total Volatiles 17.4% by wt. 29.8% by vol.C. Federally exempt solvents:
Water 0.0% by wt. 0.0% by vol.D. Organic Volatiles 17.4% by wt. 29.8% by vol.E. Percent Non-Volatile 82.6% by wt. 70.2% by vol.F. VOC Content 2.11 lb/gal 253 g/l total
2.11 lb/gal 253 g/l less exempt solvents3.01 lb/gal 361 g/l of solids0.21 lb/lb 0.21 kg/kg of solids
17.4% by wt LVP-VOCAs-Applied < 1.87 lb/gal < 225 g/l by wt less exempt solvents
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009)1.20
Volatile Organic Compounds - California
A. Coating Density 12.19 lb/gal 1460 g/lB. Total Volatiles 17.4% by wt. 29.8% by vol.C. Exempt solvents:
Water 0.0% by wt. 0.0% by vol.D. Organic Volatiles 17.4% by wt. 29.8% by vol.E. Percent Non-Volatile 82.6% by wt. 70.2% by vol.F. VOC Content 2.11 lb/gal 253 g/l total
2.11 lb/gal 253 g/l less exempt solvents3.01 lb/gal 361 g/l of solids0.21 lb/lb 0.21 kg/kg of solids
17.4% by wt LVP-VOCAs-Applied < 1.87 lb/gal < 225 g/l by wt less exempt solvents
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010)1.20
B58W610
page 2 of 2
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
A. Coating Density 12.19 lb/gal 1460 g/lB. Total Volatiles 17.4% by wt. 29.8% by vol.C. Exempt solvents:
Water 0.0% by wt. 0.0% by vol.D. Organic Volatiles 17.4% by wt. 29.8% by vol.E. Percent Non-Volatile 82.6% by wt. 70.2% by vol.F. VOC Content 2.11 lb/gal 253 g/l total
2.11 lb/gal 253 g/l less exempt solvents3.01 lb/gal 361 g/l of solids0.21 lb/lb 0.21 kg/kg of solids
17.4% by wt LVP-VOCAs-Applied < 1.87 lb/gal < 225 g/l by wt less exempt solvents
Volatile Organic Compounds - EU Directive 2010/75/EU
Total Volatiles 17.4% by wt. 29.8% by vol.VOC Content 2.11 lb/gal 253 g/l
As-Applied < 1.87 lb/gal < 225 g/l< 14.6% by wt. < 27 % by vol.
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
Volatile HAPS 2.11 lb/gal 0.253 kg/l3.01 lb/gal 0.360 kg/l of solids0.20 lb/lb 0.20 kg/kg of solids
Air Quality Data
Density of Organic Solvent Blend7.12 lb/gal
Photochemically ReactiveYes
Additional Regulatory Information
US EPA TSCA:Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:Not Applicable
Waste Disposal
Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.
page 1 of 3
FLASH POINT55 °F TCC
Specific Gravity1.35
Product Weight11.23 lb/gal
27 00 [0487]
ENVIRONMENTAL DATA SHEET(Certified Product Data Sheet)
Date of PreparationJan 15, 2018
PRODUCT NUMBERB65W651
PRODUCT NAMEACROLON™ 218 HS Polyurethane - Semi-Gloss (Part A), Extra White/Tint Base
MANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)| Acute | Chronic | Fire |
Volatile IngredientsChemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by VolumeEthylbenzene
100-41-4 N Y Y Y 0.1 < 1
Heavy Aromatic Naphtha64742-94-5 N N N N 2 2
Naphthalene91-20-3 N Y Y Y 0.2 < 1
Methyl Ethyl Ketone78-93-3 N Y N N 5 9
Methyl Isobutyl Ketone108-10-1 N Y Y Y 3 5
n-Butyl Acetate123-86-4 N Y N N 8 13
1-Methoxy-2-Propanol Acetate108-65-6 N N N N 5 7
Volatile Organic Compounds - U.S. EPA
A. Coating Density 11.23 lb/gal 1345 g/lB. Total Volatiles 25.6% by wt. 39.4% by vol.C. Federally exempt solvents:
Water 0.0% by wt. 0.0% by vol.D. Organic Volatiles 25.6% by wt. 39.4% by vol.E. Percent Non-Volatile 74.4% by wt. 60.6% by vol.F. VOC Content 2.87 lb/gal 344 g/l total
2.87 lb/gal 344 g/l less exempt solvents4.74 lb/gal 568 g/l of solids0.34 lb/lb 0.34 kg/kg of solids
23.5% by wt LVP-VOCAs-Applied < 2.46 lb/gal < 295 g/l by wt less exempt solvents
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009)0.52
B65W651
page 2 of 3
Volatile Organic Compounds - California
A. Coating Density 11.23 lb/gal 1345 g/lB. Total Volatiles 25.6% by wt. 39.4% by vol.C. Exempt solvents:
Water 0.0% by wt. 0.0% by vol.D. Organic Volatiles 25.6% by wt. 39.4% by vol.E. Percent Non-Volatile 74.4% by wt. 60.6% by vol.F. VOC Content 2.87 lb/gal 344 g/l total
2.87 lb/gal 344 g/l less exempt solvents4.74 lb/gal 568 g/l of solids0.34 lb/lb 0.34 kg/kg of solids
23.5% by wt LVP-VOCAs-Applied < 2.46 lb/gal < 295 g/l by wt less exempt solvents
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010)0.52
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
A. Coating Density 11.23 lb/gal 1345 g/lB. Total Volatiles 25.6% by wt. 39.4% by vol.C. Exempt solvents:
Water 0.0% by wt. 0.0% by vol.D. Organic Volatiles 25.6% by wt. 39.4% by vol.E. Percent Non-Volatile 74.4% by wt. 60.6% by vol.F. VOC Content 2.87 lb/gal 344 g/l total
2.87 lb/gal 344 g/l less exempt solvents4.74 lb/gal 568 g/l of solids0.34 lb/lb 0.34 kg/kg of solids
23.5% by wt LVP-VOCAs-Applied < 2.46 lb/gal < 295 g/l by wt less exempt solvents
Volatile Organic Compounds - EU Directive 2010/75/EU
Total Volatiles 25.6% by wt. 39.4% by vol.VOC Content 2.87 lb/gal 344 g/l
As-Applied < 2.46 lb/gal < 295 g/l< 22.5% by wt. < 33 % by vol.
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
Volatile HAPS 0.37 lb/gal 0.045 kg/l0.62 lb/gal 0.074 kg/l of solids0.04 lb/lb 0.04 kg/kg of solids
Air Quality Data
Density of Organic Solvent Blend7.30 lb/gal
Photochemically ReactiveYes
Additional Regulatory Information
US EPA TSCA:Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:Not Applicable
Waste Disposal
Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
B65W651
page 3 of 3
Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.
page 1 of 2
FLASH POINTN.A.
Specific Gravity1.27
Product Weight10.54 lb/gal
11 00 [1078]
ENVIRONMENTAL DATA SHEET(Certified Product Data Sheet)
Date of PreparationApr 17, 2018
PRODUCT NUMBERB53W1151
PRODUCT NAMEPRO INDUSTRIAL™ Waterbased Alkyd Urethane Semi-Gloss, Extra White
MANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)| Acute | Chronic |
Volatile IngredientsChemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by VolumePropylene Glycol
57-55-6 N N N N 1 1
Water7732-18-5 N N N N 50 64
Volatile Organic Compounds - U.S. EPA
A. Coating Density 10.54 lb/gal 1262 g/lB. Total Volatiles 51.0% by wt. 65.7% by vol.C. Federally exempt solvents:
Water 49.7% by wt. 64.0% by vol.D. Organic Volatiles 1.3% by wt. 1.6% by vol.E. Percent Non-Volatile 49.0% by wt. 34.3% by vol.F. VOC Content 0.13 lb/gal 16 g/l total
0.37 lb/gal 45 g/l less exempt solvents0.39 lb/gal 47 g/l of solids0.02 lb/lb 0.02 kg/kg of solids0.0% by wt LVP-VOC
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009)0.03
Volatile Organic Compounds - California
A. Coating Density 10.54 lb/gal 1262 g/lB. Total Volatiles 51.0% by wt. 65.7% by vol.C. Exempt solvents:
Water 49.7% by wt. 64.0% by vol.D. Organic Volatiles 1.3% by wt. 1.6% by vol.E. Percent Non-Volatile 49.0% by wt. 34.3% by vol.F. VOC Content 0.13 lb/gal 16 g/l total
0.37 lb/gal 45 g/l less exempt solvents0.39 lb/gal 47 g/l of solids0.02 lb/lb 0.02 kg/kg of solids0.0% by wt LVP-VOC
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010)0.03
B53W1151
page 2 of 2
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
A. Coating Density 10.54 lb/gal 1262 g/lB. Total Volatiles 51.0% by wt. 65.7% by vol.C. Exempt solvents:
Water 49.7% by wt. 64.0% by vol.D. Organic Volatiles 1.3% by wt. 1.6% by vol.E. Percent Non-Volatile 49.0% by wt. 34.3% by vol.F. VOC Content 0.13 lb/gal 16 g/l total
0.37 lb/gal 45 g/l less exempt solvents0.39 lb/gal 47 g/l of solids0.02 lb/lb 0.02 kg/kg of solids0.0% by wt LVP-VOC
Volatile Organic Compounds - EU Directive 2010/75/EU
Total Volatiles 51.0% by wt. 65.7% by vol.VOC Content 0.13 lb/gal 15 g/l
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
Volatile HAPS 0.00 lb/gal 0.000 kg/l0.00 lb/gal 0.000 kg/l of solids0.00 lb/lb 0.00 kg/kg of solids
Air Quality Data
Density of Organic Solvent Blend8.28 lb/gal
Photochemically ReactiveNo
Additional Regulatory Information
US EPA TSCA:Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:Not Applicable
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.
page 1 of 3
FLASH POINTN.A.
Specific Gravity1.23
Product Weight10.23 lb/gal
36 00 [0818]
ENVIRONMENTAL DATA SHEET(Certified Product Data Sheet)
Date of PreparationMar 23, 2018
PRODUCT NUMBERB66W310
PRODUCT NAMEPRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic Primer, Off White
MANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)| Acute | Chronic |
Volatile IngredientsChemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume1-(2-Butoxymethylethoxy)-propanol
29911-28-2 N N N N 3 4
Water7732-18-5 N N N N 48 59
Regulated CompoundsSARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Zinc Compound N N Y N 1
Volatile Organic Compounds - U.S. EPA
A. Coating Density 10.23 lb/gal 1225 g/lB. Total Volatiles 51.2% by wt. 63.6% by vol.
Non-Organic Volatiles:Ammonium Hydroxide 0.1% by wt. 0.2% by vol.
C. Federally exempt solvents:Water 47.9% by wt. 59.0% by vol.
D. Organic Volatiles 3.1% by wt. 4.3% by vol.E. Percent Non-Volatile 48.8% by wt. 36.4% by vol.F. VOC Content 0.32 lb/gal 38 g/l total
0.78 lb/gal 93 g/l less exempt solvents0.87 lb/gal 105 g/l of solids0.06 lb/lb 0.06 kg/kg of solids0.3% by wt LVP-VOC
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009)0.05
B66W310
page 2 of 3
Volatile Organic Compounds - California
A. Coating Density 10.23 lb/gal 1225 g/lB. Total Volatiles 51.2% by wt. 63.6% by vol.
Non-Organic Volatiles:Ammonium Hydroxide 0.1% by wt. 0.2% by vol.
C. Exempt solvents:Water 47.9% by wt. 59.0% by vol.
D. Organic Volatiles 3.2% by wt. 4.4% by vol.E. Percent Non-Volatile 48.8% by wt. 36.4% by vol.F. VOC Content 0.32 lb/gal 39 g/l total
0.80 lb/gal 96 g/l less exempt solvents0.90 lb/gal 108 g/l of solids0.06 lb/lb 0.06 kg/kg of solids0.4% by wt LVP-VOC
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010)0.05
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
A. Coating Density 10.23 lb/gal 1225 g/lB. Total Volatiles 51.2% by wt. 63.6% by vol.
Non-Organic VolatilesAmmonium Hydroxide 0.1% by wt. 0.2% by vol.
C. Exempt solvents:Water 47.9% by wt. 59.0% by vol.
D. Organic Volatiles 3.2% by wt. 4.4% by vol.E. Percent Non-Volatile 48.8% by wt. 36.4% by vol.F. VOC Content 0.32 lb/gal 39 g/l total
0.80 lb/gal 96 g/l less exempt solvents0.90 lb/gal 108 g/l of solids0.06 lb/lb 0.06 kg/kg of solids0.4% by wt LVP-VOC
Volatile Organic Compounds - EU Directive 2010/75/EU
Total Volatiles 48.4% by wt. 59.7% by vol.VOC Content 0.03 lb/gal 4 g/l
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
Volatile HAPS 0.00 lb/gal 0.000 kg/l0.00 lb/gal 0.000 kg/l of solids0.00 lb/lb 0.00 kg/kg of solids
Air Quality Data
Density of Organic Solvent Blend7.41 lb/gal
Photochemically ReactiveNo
Additional Regulatory Information
US EPA TSCA:Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:Not Applicable
B66W310
page 3 of 3
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.
Heavy Duty Block Filler - Acrylic Block FillerWhite
Not available.
Liquid.
US / Canada: (216) 566-2917Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of identificationProduct type
Emergency telephone number of the company
Section 1. Identification:
:
:
:
Manufacturer : THE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
B42W46
B42W46Product code :
Product Information Telephone Number
: US / Canada: (800) 524-5979Mexico: Not Available
Regulatory Information Telephone Number
: US / Canada: (216) 566-2902Mexico: Not Available
Transportation Emergency Telephone Number
: US / Canada: (800) 424-9300Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2ACARCINOGENICITY - Category 1ASPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1
Classification of the substance or mixture
:
Signal word : Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 63.4%Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 63.4%Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 63.4%
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Causes serious eye irritation.Causes skin irritation.May cause cancer.May cause respiratory irritation.Causes damage to organs through prolonged or repeated exposure. (lungs)
:Hazard statements
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/7/2017 Version : 7.01 1/11
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Section 2. Hazards identificationPrecautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.Call a POISON CENTER or physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
: None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.
Supplemental label elements
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure.
:
Section 3. Composition/information on ingredients
Calcium Carbonate 55.6 1317-65-3Kaolin 7.75 1332-58-7Titanium Dioxide 0.82 13463-67-7Crystalline Silica, respirable powder 0.5 14808-60-7
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of identification
: Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/7/2017 Version : 7.01 2/11
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.Get medical attention. If necessary, call a poison center or physician. If unconscious,place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation : May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact : Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughing
No specific data.
Adverse symptoms may include the following:irritationredness
:
:
:
Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/7/2017 Version : 7.01 3/11
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Section 7. Handling and storage
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/7/2017 Version : 7.01 4/11
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Section 7. Handling and storageAdvice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.
:
:
Calcium Carbonate NIOSH REL (United States, 10/2016). TWA: 5 mg/m³ 10 hours. Form: Respirable fraction TWA: 10 mg/m³ 10 hours. Form: TotalOSHA PEL (United States, 6/2016). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust
Kaolin ACGIH TLV (United States, 3/2016). TWA: 2 mg/m³ 8 hours. Form: Respirable fractionNIOSH REL (United States, 10/2016). TWA: 5 mg/m³ 10 hours. Form: Respirable fraction TWA: 10 mg/m³ 10 hours. Form: TotalOSHA PEL (United States, 6/2016). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust
Titanium Dioxide ACGIH TLV (United States, 3/2016). TWA: 10 mg/m³ 8 hours.OSHA PEL (United States, 6/2016). TWA: 15 mg/m³ 8 hours. Form: Total dust
Crystalline Silica, respirable powder OSHA PEL Z3 (United States, 6/2016). TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:Respirable TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form:RespirableOSHA PEL (United States, 6/2016). TWA: 50 µg/m³ 8 hours. Form: Respirable dustACGIH TLV (United States, 3/2016). TWA: 0.025 mg/m³ 8 hours. Form:Respirable fractionNIOSH REL (United States, 10/2016). TWA: 0.05 mg/m³ 10 hours. Form: respirable dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Occupational exposure limits (Canada)
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/7/2017 Version : 7.01 5/11
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
None.
Ingredient name Exposure limits
Environmental exposure controls
:
None.
Ingredient name Exposure limits
Occupational exposure limits (Mexico)
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Not available.Odor
pH
Not available.Color
Flash point Closed cup: 94°C (201.2°F) [Pensky-Martens Closed Cup]
9.5
Not available.Odor threshold
:
:
:
:
:
:
:
Appearance
Boiling point : 100°C (212°F)
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/7/2017 Version : 7.01 6/11
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Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.71
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature Not available.
Not available.
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Not available.
Decomposition temperature : Not available.
Heat of combustion : 0.61 kJ/g
Aerosol product
Molecular weight : Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/7/2017 Version : 7.01 7/11
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Section 11. Toxicological information
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Calcium Carbonate Category 3 Not applicable. Respiratory tract irritation
Name Category
Name Category
Kaolin Category 1 Inhalation lungsCrystalline Silica, respirable powder Category 1 Inhalation Not determined
Aspiration hazard
Not available.
Route of exposure
Target organs
Route of exposure
Target organs
Titanium Dioxide - 2B -Crystalline Silica, respirable powder
- 1 Known to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Information on the likely routes of exposure
Inhalation : May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact : Causes skin irritation.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughing
No specific data.
Adverse symptoms may include the following:irritationredness
:
:
:
Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness
Delayed and immediate effects and also chronic effects from short and long term exposure
: Not available.
Potential acute health effects
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate effects
: Not available.
Long term exposure
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/7/2017 Version : 7.01 8/11
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Not available.
Causes damage to organs through prolonged or repeated exposure.General :
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Potential chronic health effects
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential delayed effects : Not available.
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
: Not available.
Mobility in soil
Not available.
Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/7/2017 Version : 7.01 9/11
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Section 14. Transport information
-
-
-
-
-
-
Not regulated. Not regulated.
- -
DOT Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL and the IBC Code
No. No.
Not available.
:
Proper shipping name :
Ship type : Not available.
Pollution category : Not available.
Not available.
:
TDG Classification
Not regulated.
-
-
-
No.
-
Mexico Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
Section 15. Regulatory informationSARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
Section 16. Other informationHazardous Material Information System (U.S.A.)
1
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/7/2017 Version : 7.01 10/11
B42W46 Heavy Duty Block Filler - Acrylic Block FillerWhite
Section 16. Other information
1/16/2018
History
Date of printing
Date of issue/Date of revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Notice to reader
Date of previous issue
:
:
:
:
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
1/16/2018
9/7/2017
7.01
SKIN CORROSION/IRRITATION - Category 2 Calculation methodSERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation methodCARCINOGENICITY - Category 1A Calculation methodSPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1
Calculation method
Procedure used to derive the classification
Classification Justification
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/7/2017 Version : 7.01 11/11
B42W46 Heavy Duty Block Filler - Acrylic Block FillerWhite
Water Based Catalyzed Epoxy (Part A)Extra White
Not available.
Liquid.
US / Canada: (216) 566-2917Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of identificationProduct type
Emergency telephone number of the company
Section 1. Identification:
:
:
:
Manufacturer : THE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
B70W211
B70W211Product code :
Product Information Telephone Number
: US / Canada: (800) 524-5979Mexico: Not Available
Regulatory Information Telephone Number
: US / Canada: (216) 566-2902Mexico: Not Available
Transportation Emergency Telephone Number
: US / Canada: (800) 424-9300Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
CARCINOGENICITY - Category 2SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the substance or mixture
:
Signal word : Warning
Hazard pictograms :
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing. Do not breathe vapor.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 14.5%Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 17%Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 20.2%
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Suspected of causing cancer.May cause damage to organs through prolonged or repeated exposure.
:Hazard statements
Date of issue/Date of revision : 3/2/2018 Date of previous issue : 1/16/2018 Version : 9 1/11
B70W211 Water Based Catalyzed Epoxy (Part A)Extra White
SHW-85-NA-GHS-US
Section 2. Hazards identificationStorage : Store locked up.Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise classified
: None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.
Supplemental label elements
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.This product must be mixed with other components before use. Before opening the packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Titanium Dioxide ≥10 - ≤25 13463-67-7Ethylene Glycol ≤3 107-21-12-(2-Butoxyethoxy)-ethanol ≤3 112-34-52-Phenoxyethanol (industrial) ≤2.3 122-99-6
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of identification
: Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
No known significant effects or critical hazards.:Eye contact
Potential acute health effects
Date of issue/Date of revision : 3/2/2018 Date of previous issue : 1/16/2018 Version : 9 2/11
B70W211 Water Based Catalyzed Epoxy (Part A)Extra White
SHW-85-NA-GHS-US
Section 4. First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact : No specific data.
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Date of issue/Date of revision : 3/2/2018 Date of previous issue : 1/16/2018 Version : 9 3/11
B70W211 Water Based Catalyzed Epoxy (Part A)Extra White
SHW-85-NA-GHS-US
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Titanium Dioxide ACGIH TLV (United States, 3/2016). TWA: 10 mg/m³ 8 hours.OSHA PEL (United States, 6/2016). TWA: 15 mg/m³ 8 hours. Form: Total dust
Ethylene Glycol ACGIH TLV (United States, 3/2016). C: 100 mg/m³ Form: Aerosol
2-(2-Butoxyethoxy)-ethanol ACGIH TLV (United States, 3/2016). TWA: 10 ppm 8 hours. Form: Inhalable fraction and vapor
2-Phenoxyethanol (industrial) None.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Occupational exposure limits (Canada)
Date of issue/Date of revision : 3/2/2018 Date of previous issue : 1/16/2018 Version : 9 4/11
B70W211 Water Based Catalyzed Epoxy (Part A)Extra White
SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.
Eye/face protection :
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
ethanediol CA British Columbia Provincial (Canada,7/2016). C: 100 mg/m³ Form: Aerosol TWA: 10 mg/m³ 8 hours. Form: Particulate STEL: 20 mg/m³ 15 minutes. Form:Particulate C: 50 ppm Form: VapourCA Ontario Provincial (Canada, 7/2015). C: 100 mg/m³ Form: Aerosol only.CA Saskatchewan Provincial (Canada,7/2013). CEIL: 100 mg/m³ Form: aerosolCA Alberta Provincial (Canada, 4/2009). C: 100 mg/m³CA Québec Provincial (Canada, 1/2014). STEV: 50 ppm 15 minutes. Form: vapour and mist STEV: 127 mg/m³ 15 minutes. Form: vapour and mist
2-(2-butoxyethoxy)ethanol CA Ontario Provincial (Canada, 7/2015). TWA: 10 ppm 8 hours. Form: Inhalable fraction and vapour.
2-Phenoxyethanol (industrial) CA Ontario Provincial (Canada, 7/2015).Absorbed through skin. TWA: 141 mg/m³ 8 hours. TWA: 25 ppm 8 hours.
Ingredient name Exposure limits
Environmental exposure controls
:
ethanediol NOM-010-STPS-2014 (Mexico, 4/2016). CEIL: 100 mg/m³ Form: Only AEROSOL
2-(2-butoxyethoxy)ethanol ACGIH TLV (United States, 3/2016). TWA: 10 ppm 8 hours. Form: Inhalable fraction and vapor
Ingredient name Exposure limits
Occupational exposure limits (Mexico)
Date of issue/Date of revision : 3/2/2018 Date of previous issue : 1/16/2018 Version : 9 5/11
B70W211 Water Based Catalyzed Epoxy (Part A)Extra White
SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protectionHand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Respiratory protection :
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.16
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 94°C (201.2°F) [Pensky-Martens Closed Cup]
Not available.
9
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point : 100°C (212°F)
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Lower: 0.9%Upper: 15.3%
Decomposition temperature : Not available.
Heat of combustion : 2.08 kJ/g
Aerosol product
Molecular weight : Not applicable.
Section 10. Stability and reactivity
The product is stable.Chemical stability :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Date of issue/Date of revision : 3/2/2018 Date of previous issue : 1/16/2018 Version : 9 6/11
B70W211 Water Based Catalyzed Epoxy (Part A)Extra White
SHW-85-NA-GHS-US
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
No specific data.
:
:
Incompatible materials :
Section 11. Toxicological information
Acute toxicity
Ethylene Glycol LD50 Oral Rat 4700 mg/kg -2-(2-Butoxyethoxy)-ethanol LD50 Dermal Rabbit 2700 mg/kg -
LD50 Oral Rat 4500 mg/kg -2-Phenoxyethanol (industrial) LD50 Dermal Rat 14422 mg/kg -
LD50 Oral Rat 1260 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
-
Ethylene Glycol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams
-
Eyes - Mild irritant Rabbit - 1 hours 100 milligrams
-
Eyes - Moderate irritant Rabbit - 6 hours 1440 milligrams
-
Skin - Mild irritant Rabbit - 555 milligrams
-
2-(2-Butoxyethoxy)-ethanol Eyes - Moderate irritant Rabbit - 24 hours 20 milligrams
-
Eyes - Severe irritant Rabbit - 20 milligrams -2-Phenoxyethanol (industrial) Eyes - Moderate irritant Rabbit - 6 milligrams -
Eyes - Severe irritant Rabbit - 24 hours 250 Micrograms
-
Skin - Mild irritant Rabbit - 24 hours 500 milligrams
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Information on toxicological effects
Classification
Titanium Dioxide - 2B -
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision : 3/2/2018 Date of previous issue : 1/16/2018 Version : 9 7/11
B70W211 Water Based Catalyzed Epoxy (Part A)Extra White
SHW-85-NA-GHS-US
Section 11. Toxicological information
Specific target organ toxicity (repeated exposure)
Ethylene Glycol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
2-(2-Butoxyethoxy)-ethanol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
2-Phenoxyethanol (industrial) Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Name Category
Name Category
Ethylene Glycol Category 2 Not determined Not determined2-(2-Butoxyethoxy)-ethanol Category 2 Not determined Not determined2-Phenoxyethanol (industrial) Category 2 Not determined Not determined
Aspiration hazard
Not available.
Route of exposure
Target organs
Route of exposure
Target organs
Not available.
Information on the likely routes of exposure
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
May cause damage to organs through prolonged or repeated exposure.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact : No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
: Not available.
Potential acute health effects
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Date of issue/Date of revision : 3/2/2018 Date of previous issue : 1/16/2018 Version : 9 8/11
B70W211 Water Based Catalyzed Epoxy (Part A)Extra White
SHW-85-NA-GHS-US
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 13329.9 mg/kgDermal 121315 mg/kg
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Product/ingredient name
2-Phenoxyethanol (industrial) - 0.3493 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Ethylene Glycol - - Readily2-(2-Butoxyethoxy)-ethanol - - Readily
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hoursEthylene Glycol Acute LC50 6900000 µg/l Fresh water Crustaceans - Ceriodaphnia
dubia - Neonate48 hours
Acute LC50 41000000 µg/l Fresh water Daphnia - Daphnia magna -Neonate
48 hours
Acute LC50 8050000 µg/l Fresh water Fish - Pimephales promelas 96 hours2-(2-Butoxyethoxy)-ethanol Acute LC50 1300000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours2-Phenoxyethanol (industrial) Acute LC50 344000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
: Not available.
Mobility in soil
Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Date of issue/Date of revision : 3/2/2018 Date of previous issue : 1/16/2018 Version : 9 9/11
B70W211 Water Based Catalyzed Epoxy (Part A)Extra White
SHW-85-NA-GHS-US
Section 14. Transport information
-
-
-
-
-
-
Not regulated. Not regulated.
- -
DOT Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL and the IBC Code
No. No.
Not available.
:
Proper shipping name :
Ship type : Not available.
Pollution category : Not available.
Not available.
:
TDG Classification
Not regulated.
-
-
-
No.
-
Mexico Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
Section 15. Regulatory informationSARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
Section 16. Other informationHazardous Material Information System (U.S.A.)
2
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Date of issue/Date of revision : 3/2/2018 Date of previous issue : 1/16/2018 Version : 9 10/11
B70W211 Water Based Catalyzed Epoxy (Part A)Extra White
SHW-85-NA-GHS-US
Section 16. Other information
3/2/2018
History
Date of printing
Date of issue/Date of revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Notice to reader
Date of previous issue
:
:
:
:
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
3/2/2018
1/16/2018
9
CARCINOGENICITY - Category 2 Calculation methodSPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
Date of issue/Date of revision : 3/2/2018 Date of previous issue : 1/16/2018 Version : 9 11/11
B70W211 Water Based Catalyzed Epoxy (Part A)Extra White
SHW-85-NA-GHS-US
PRO INDUSTRIAL™ Pre-Catalyzed Waterbased Semi-Gloss EpoxyExtra White
Not available.
Liquid.
US / Canada: (216) 566-2917Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of identificationProduct type
Emergency telephone number of the company
Section 1. Identification:
:
:
:
Manufacturer : THE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
K46W151
K46W151Product code :
Product Information Telephone Number
: US / Canada: (800) 524-5979Mexico: Not Available
Regulatory Information Telephone Number
: US / Canada: (216) 566-2902Mexico: Not Available
Transportation Emergency Telephone Number
: US / Canada: (800) 424-9300Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
CARCINOGENICITY - Category 2TOXIC TO REPRODUCTION (Unborn child) - Category 2SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the substance or mixture
:
Signal word : Warning
Hazard pictograms :
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing. Do not breathe vapor.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 22.1%Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 22.1%Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 22.1%
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Suspected of damaging the unborn child.Suspected of causing cancer.May cause damage to organs through prolonged or repeated exposure.
:Hazard statements
Date of issue/Date of revision : 3/1/2018 Date of previous issue : 1/16/2018 Version : 9 1/10
K46W151 PRO INDUSTRIAL™ Pre-Catalyzed Waterbased Semi-Gloss EpoxyExtra White
SHW-85-NA-GHS-US
Section 2. Hazards identificationResponse : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention.
Storage : Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
: None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.
Supplemental label elements
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
:
Section 3. Composition/information on ingredients
Titanium Dioxide ≥10 - ≤25 13463-67-72-(2-Methoxyethoxy)-ethanol ≤3 111-77-3
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of identification
: Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Potential acute health effects
Date of issue/Date of revision : 3/1/2018 Date of previous issue : 1/16/2018 Version : 9 2/10
K46W151 PRO INDUSTRIAL™ Pre-Catalyzed Waterbased Semi-Gloss EpoxyExtra White
SHW-85-NA-GHS-US
Section 4. First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
No known significant effects or critical hazards.:Ingestion
Skin contact : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
:
:
:
Eye contact : No specific data.
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Section 6. Accidental release measuresPersonal precautions, protective equipment and emergency procedures
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
For non-emergency personnel
Date of issue/Date of revision : 3/1/2018 Date of previous issue : 1/16/2018 Version : 9 3/10
K46W151 PRO INDUSTRIAL™ Pre-Catalyzed Waterbased Semi-Gloss EpoxyExtra White
SHW-85-NA-GHS-US
Section 6. Accidental release measures
Environmental precautions
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Titanium Dioxide ACGIH TLV (United States, 3/2016). TWA: 10 mg/m³ 8 hours.OSHA PEL (United States, 6/2016). TWA: 15 mg/m³ 8 hours. Form: Total dust
2-(2-Methoxyethoxy)-ethanol None.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Occupational exposure limits (Canada)
Date of issue/Date of revision : 3/1/2018 Date of previous issue : 1/16/2018 Version : 9 4/10
K46W151 PRO INDUSTRIAL™ Pre-Catalyzed Waterbased Semi-Gloss EpoxyExtra White
SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
None.
Ingredient name Exposure limits
Environmental exposure controls
:
None.
Ingredient name Exposure limits
Occupational exposure limits (Mexico)
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Not available.Odor
pH
Not available.Color
Flash point Closed cup: >93.3°C (>199.9°F)
9.5
Not available.Odor threshold
:
:
:
:
:
:
:
Appearance
Boiling point : 100°C (212°F)
Date of issue/Date of revision : 3/1/2018 Date of previous issue : 1/16/2018 Version : 9 5/10
K46W151 PRO INDUSTRIAL™ Pre-Catalyzed Waterbased Semi-Gloss EpoxyExtra White
SHW-85-NA-GHS-US
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.24
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature Not available.
Not available.
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Lower: 0.6%Upper: 20.4%
Decomposition temperature : Not available.
Heat of combustion : 2.195 kJ/g
Aerosol product
Molecular weight : Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Mutagenicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
-
2-(2-Methoxyethoxy)-ethanol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams
-
Eyes - Moderate irritant Rabbit - 500 milligrams
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Date of issue/Date of revision : 3/1/2018 Date of previous issue : 1/16/2018 Version : 9 6/10
K46W151 PRO INDUSTRIAL™ Pre-Catalyzed Waterbased Semi-Gloss EpoxyExtra White
SHW-85-NA-GHS-US
Section 11. Toxicological informationNot available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
2-(2-Methoxyethoxy)-ethanol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Name Category
Name Category
2-(2-Methoxyethoxy)-ethanol Category 2 Not determined Not determined
Aspiration hazard
Not available.
Route of exposure
Target organs
Route of exposure
Target organs
Classification
Titanium Dioxide - 2B -
Product/ingredient name NTPIARCOSHA
Information on the likely routes of exposure
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
:
:
:
Eye contact : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
: Not available.
Potential acute health effects
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Date of issue/Date of revision : 3/1/2018 Date of previous issue : 1/16/2018 Version : 9 7/10
K46W151 PRO INDUSTRIAL™ Pre-Catalyzed Waterbased Semi-Gloss EpoxyExtra White
SHW-85-NA-GHS-US
Not available.
May cause damage to organs through prolonged or repeated exposure.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Suspected of damaging the unborn child.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Potential chronic health effects
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours2-(2-Methoxyethoxy)-ethanol Acute EC50 >930 ppm Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 7500000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
: Not available.
Mobility in soil
Not available.
Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Date of issue/Date of revision : 3/1/2018 Date of previous issue : 1/16/2018 Version : 9 8/10
K46W151 PRO INDUSTRIAL™ Pre-Catalyzed Waterbased Semi-Gloss EpoxyExtra White
SHW-85-NA-GHS-US
Section 14. Transport information
-
-
-
-
-
-
Not regulated. Not regulated.
- -
DOT Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL and the IBC Code
No. No.
Not available.
:
Proper shipping name :
Ship type : Not available.
Pollution category : Not available.
Not available.
:
TDG Classification
Not regulated.
-
-
-
No.
-
Mexico Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
Section 15. Regulatory informationSARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
Section 16. Other informationHazardous Material Information System (U.S.A.)
2
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Date of issue/Date of revision : 3/1/2018 Date of previous issue : 1/16/2018 Version : 9 9/10
K46W151 PRO INDUSTRIAL™ Pre-Catalyzed Waterbased Semi-Gloss EpoxyExtra White
SHW-85-NA-GHS-US
Section 16. Other information
3/1/2018
History
Date of printing
Date of issue/Date of revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Notice to reader
Date of previous issue
:
:
:
:
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
3/1/2018
1/16/2018
9
CARCINOGENICITY - Category 2 Calculation methodTOXIC TO REPRODUCTION (Unborn child) - Category 2 Calculation methodSPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
Date of issue/Date of revision : 3/1/2018 Date of previous issue : 1/16/2018 Version : 9 10/10
K46W151 PRO INDUSTRIAL™ Pre-Catalyzed Waterbased Semi-Gloss EpoxyExtra White
SHW-85-NA-GHS-US
Extreme Bond PrimerWhite
Not available.
Liquid.
US / Canada: (216) 566-2917Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of identificationProduct type
Emergency telephone number of the company
Section 1. Identification:
:
:
:
Manufacturer : THE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
B51W150
B51W150Product code :
Product Information Telephone Number
: US / Canada: Not AvailableMexico: Not Available
Regulatory Information Telephone Number
: US / Canada: (216) 566-2902Mexico: Not Available
Transportation Emergency Telephone Number
: US / Canada: (800) 424-9300Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
CARCINOGENICITY - Category 1ASPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1
Classification of the substance or mixture
:
Signal word : Danger
Hazard pictograms :
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 21.8%Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 21.8%Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 21.8%
General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
May cause cancer.Causes damage to organs through prolonged or repeated exposure. (lungs)
:Hazard statements
Date of issue/Date of revision : 3/1/2018 Date of previous issue : 1/16/2018 Version : 10 1/11
B51W150 Extreme Bond PrimerWhite
SHW-85-NA-GHS-US
Section 2. Hazards identificationResponse : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention.
Storage : Store locked up.Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise classified
: None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.
Supplemental label elements
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure.
:
Section 3. Composition/information on ingredients
Talc ≤10 14807-96-6Titanium Dioxide ≤10 13463-67-7Kaolin ≤10 1332-58-7Calcium Carbonate ≤5 1317-65-3Mica ≤5 12001-26-2Crystalline Silica, respirable powder <1 14808-60-7
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of identification
: Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
:
:
:
Description of necessary first aid measures
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Section 4. First aid measuresWash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion :
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact : No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
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Talc NIOSH REL (United States, 10/2016). TWA: 2 mg/m³ 10 hours. Form: Respirable fractionACGIH TLV (United States, 3/2016). TWA: 2 mg/m³ 8 hours. Form: Respirable fraction
Titanium Dioxide ACGIH TLV (United States, 3/2016). TWA: 10 mg/m³ 8 hours.OSHA PEL (United States, 6/2016). TWA: 15 mg/m³ 8 hours. Form: Total dust
Kaolin ACGIH TLV (United States, 3/2016). TWA: 2 mg/m³ 8 hours. Form: Respirable fractionNIOSH REL (United States, 10/2016). TWA: 5 mg/m³ 10 hours. Form: Respirable fraction TWA: 10 mg/m³ 10 hours. Form: TotalOSHA PEL (United States, 6/2016). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust
Calcium Carbonate NIOSH REL (United States, 10/2016). TWA: 5 mg/m³ 10 hours. Form: Respirable fraction TWA: 10 mg/m³ 10 hours. Form: TotalOSHA PEL (United States, 6/2016). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust
Mica ACGIH TLV (United States, 3/2016). TWA: 3 mg/m³ 8 hours. Form: Respirable fractionNIOSH REL (United States, 10/2016). TWA: 3 mg/m³ 10 hours. Form: Respirable fractionOSHA PEL Z3 (United States, 6/2016). TWA: 20 mppcf 8 hours.
Crystalline Silica, respirable powder OSHA PEL Z3 (United States, 6/2016). TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:Respirable TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form:RespirableOSHA PEL (United States, 6/2016). TWA: 50 µg/m³ 8 hours. Form: Respirable dustACGIH TLV (United States, 3/2016). TWA: 0.025 mg/m³ 8 hours. Form:Respirable fractionNIOSH REL (United States, 10/2016). TWA: 0.05 mg/m³ 10 hours. Form: respirable dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
None.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Environmental exposure controls
:
None.
Ingredient name Exposure limits
Occupational exposure limits (Mexico)
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Not available.Odor
pH
White.Color
Evaporation rate 0.09 (butyl acetate = 1)
Flash point Closed cup: >93.3°C (>199.9°F)
8.8
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
Boiling point : 100°C (212°F)
Flammability (solid, gas) : Not available.
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Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.31
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Auto-ignition temperature Not available.
Not available.
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
Lower and upper explosive (flammable) limits
: Not available.
Decomposition temperature : Not available.
Heat of combustion : 0.555 kJ/g
Aerosol product
Molecular weight : Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Irritation/Corrosion
Talc Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
-
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
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Section 11. Toxicological information
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Calcium Carbonate Category 3 Not applicable. Respiratory tract irritation
Name Category
Name Category
Talc Category 1 Inhalation lungsKaolin Category 1 Inhalation lungsMica Category 1 Inhalation lungsCrystalline Silica, respirable powder Category 1 Inhalation Not determined
Aspiration hazard
Not available.
Route of exposure
Target organs
Route of exposure
Target organs
Talc - 3 -Titanium Dioxide - 2B -Crystalline Silica, respirable powder
- 1 Known to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Not available.
Information on the likely routes of exposure
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact : No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
: Not available.
Potential acute health effects
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
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Causes damage to organs through prolonged or repeated exposure.General :
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
: Not available.
Mobility in soil
Not available.
Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
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Section 14. Transport information
-
-
-
-
-
-
Not regulated. Not regulated.
- -
DOT Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL and the IBC Code
No. No.
Not available.
:
Proper shipping name :
Ship type : Not available.
Pollution category : Not available.
Not available.
:
TDG Classification
Not regulated.
-
-
-
No.
-
Mexico Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
Section 15. Regulatory informationSARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
Section 16. Other informationHazardous Material Information System (U.S.A.)
3
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
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Section 16. Other information
3/1/2018
History
Date of printing
Date of issue/Date of revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Notice to reader
Date of previous issue
:
:
:
:
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
3/1/2018
1/16/2018
10
CARCINOGENICITY - Category 1A Calculation methodSPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1
Calculation method
Procedure used to derive the classification
Classification Justification
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MACROPOXY® 646 Fast Cure Epoxy (Part A)Mill White
Not available.
Liquid.
US / Canada: (216) 566-2917Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of identificationProduct type
Emergency telephone number of the company
Section 1. Identification:
:
:
:
Manufacturer : THE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
B58W610
B58W610Product code :
Product Information Telephone Number
: US / Canada: (800) 524-5979Mexico: Not Available
Regulatory Information Telephone Number
: US / Canada: (216) 566-2902Mexico: Not Available
Transportation Emergency Telephone Number
: US / Canada: (800) 424-9300Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 3ACUTE TOXICITY (inhalation) - Category 4SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1SKIN SENSITIZATION - Category 1CARCINOGENICITY - Category 2SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -Category 3SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs, skin) -Category 1ASPIRATION HAZARD - Category 1
Classification of the substance or mixture
:
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 61.2%Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 39.3%Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 61.2%
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
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Section 2. Hazards identificationSignal word : Danger
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED:Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise classified
: None known.
Flammable liquid and vapor.Harmful if inhaled.Causes serious eye damage.Causes skin irritation.May cause an allergic skin reaction.Suspected of causing cancer.May be fatal if swallowed and enters airways.May cause respiratory irritation.May cause drowsiness or dizziness.Causes damage to organs through prolonged or repeated exposure. (lungs, skin)
:Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.
Supplemental label elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. This product must be mixed with other components before use. Before opening the packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Other means of identification
: Not available.
Substance/mixture
CAS number/other identifiers
: Mixture
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Section 3. Composition/information on ingredients
Titanium Dioxide ≥25 - ≤50 13463-67-7Phenol, isobutylenated methylstyrenated ≥10 - ≤25 68457-74-9Xylene ≥10 - ≤25 1330-20-7Polyamide ≥10 - ≤25 68410-23-1Talc ≤10 14807-96-6Ethylbenzene ≤3 100-41-4Triethylene Tetramine <1 112-24-3
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician.
Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.
:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye damage.:Eye contact
Over-exposure signs/symptoms
Potential acute health effects
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Section 4. First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughingnausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness
Adverse symptoms may include the following:stomach painsnausea or vomiting
Adverse symptoms may include the following:pain or irritationrednessblistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:painwateringredness
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
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Titanium Dioxide ACGIH TLV (United States, 3/2016). TWA: 10 mg/m³ 8 hours.OSHA PEL (United States, 6/2016). TWA: 15 mg/m³ 8 hours. Form: Total dust
Phenol, isobutylenated methylstyrenated None.Xylene ACGIH TLV (United States, 3/2016).
TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes.OSHA PEL (United States, 6/2016). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours.
Polyamide None.Talc NIOSH REL (United States, 10/2016).
TWA: 2 mg/m³ 10 hours. Form: Respirable fractionACGIH TLV (United States, 3/2016). TWA: 2 mg/m³ 8 hours. Form: Respirable fraction
Ethylbenzene ACGIH TLV (United States, 3/2016). TWA: 20 ppm 8 hours.NIOSH REL (United States, 10/2016). TWA: 100 ppm 10 hours. TWA: 435 mg/m³ 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m³ 15 minutes.OSHA PEL (United States, 6/2016). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours.
Triethylene Tetramine AIHA WEEL (United States, 10/2011).Absorbed through skin. TWA: 1 ppm 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Xylene CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 100 ppm 8 hours. 15 min OEL: 651 mg/m³ 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m³ 8 hours.CA British Columbia Provincial (Canada,7/2016). TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes.CA Québec Provincial (Canada, 1/2014). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m³ 15 minutes.CA Ontario Provincial (Canada, 7/2015). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours.CA Saskatchewan Provincial (Canada,7/2013). STEL: 150 ppm 15 minutes.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
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Section 8. Exposure controls/personal protection
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Eye/face protection :
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
TWA: 100 ppm 8 hours.
Ethylbenzene CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 100 ppm 8 hours. 8 hrs OEL: 434 mg/m³ 8 hours. 15 min OEL: 543 mg/m³ 15 minutes. 15 min OEL: 125 ppm 15 minutes.CA British Columbia Provincial (Canada,7/2016). TWA: 20 ppm 8 hours.CA Ontario Provincial (Canada, 7/2015). TWA: 20 ppm 8 hours.CA Québec Provincial (Canada, 1/2014). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 125 ppm 15 minutes. STEV: 543 mg/m³ 15 minutes.CA Saskatchewan Provincial (Canada,7/2013). STEL: 125 ppm 15 minutes. TWA: 100 ppm 8 hours.
Triethylene Tetramine CA Ontario Provincial (Canada, 7/2015).Absorbed through skin. TWA: 3 mg/m³ 8 hours. TWA: 0.5 ppm 8 hours.
Environmental exposure controls
:
Xylene NOM-010-STPS-2014 (Mexico, 4/2016). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours.
Ethylbenzene NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 20 ppm 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Mexico)
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Section 8. Exposure controls/personal protectionHand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Respiratory protection :
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
:
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.46
3.66 [Air = 1]
0.95 kPa (7.1 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.8 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 29°C (84.2°F) [Pensky-Martens Closed Cup]
Not available.
Not available.
Viscosity Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point : 136°C (276.8°F)
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Lower: 1%Upper: 7%
Decomposition temperature : Not available.
Heat of combustion : 5.585 kJ/g
Aerosol product
Molecular weight : Not applicable.
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Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Phenol, isobutylenated methylstyrenated
LD50 Dermal Rabbit >20000 mg/kg -
Xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hoursLD50 Oral Rat 4300 mg/kg -
Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -LD50 Oral Rat 3500 mg/kg -
Triethylene Tetramine LD50 Dermal Rabbit 805 mg/kg -LD50 Oral Rat 2500 mg/kg -
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
-
Xylene Eyes - Mild irritant Rabbit - 87 milligrams -Eyes - Severe irritant Rabbit - 24 hours 5
milligrams-
Skin - Mild irritant Rat - 8 hours 60 microliters
-
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
-
Skin - Moderate irritant Rabbit - 100 Percent -Talc Skin - Mild irritant Human - 72 hours 300
Micrograms Intermittent
-
Ethylbenzene Eyes - Severe irritant Rabbit - 500 milligrams
-
Skin - Mild irritant Rabbit - 24 hours 15 milligrams
-
Triethylene Tetramine Eyes - Moderate irritant Rabbit - 24 hours 20 milligrams
-
Eyes - Severe irritant Rabbit - 49 milligrams -Skin - Severe irritant Rabbit - 24 hours 5
milligrams-
Skin - Severe irritant Rabbit - 490 milligrams
-
Product/ingredient name Result Score Exposure ObservationSpecies
Information on toxicological effects
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Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Sensitization
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Phenol, isobutylenated methylstyrenated Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Xylene Category 3 Not applicable. Respiratory tract irritation
Ethylbenzene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Name Category
Name Category
Phenol, isobutylenated methylstyrenated Category 2 Not determined skinXylene Category 2 Not determined Not determinedTalc Category 1 Inhalation lungsEthylbenzene Category 2 Not determined Not determined
Aspiration hazard
Name Result
Phenol, isobutylenated methylstyrenated ASPIRATION HAZARD - Category 1Xylene ASPIRATION HAZARD - Category 1Ethylbenzene ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Route of exposure
Target organs
Classification
Titanium Dioxide - 2B -Xylene - 3 -Talc - 3 -Ethylbenzene - 2B -
Product/ingredient name NTPIARCOSHA
Information on the likely routes of exposure
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.
:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye damage.:Eye contact
: Not available.
Potential acute health effects
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Not available.
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General :
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughingnausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness
Adverse symptoms may include the following:stomach painsnausea or vomiting
Adverse symptoms may include the following:pain or irritationrednessblistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:painwateringredness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 9289.9 mg/kgDermal 4527.4 mg/kgInhalation (gases) 13148.1 ppmInhalation (vapors) 163.6 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Product/ingredient name
Xylene - 8.1 to 25.9 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Xylene - - ReadilyEthylbenzene - - Readily
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hoursXylene Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes
pugio48 hours
Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hoursEthylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella
subcapitata72 hours
Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata
96 hours
Acute EC50 6530 µg/l Fresh water Crustaceans - Artemia sp. -Nauplii
48 hours
Acute EC50 2930 µg/l Fresh water Daphnia - Daphnia magna -Neonate
48 hours
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hoursTriethylene Tetramine Acute EC50 3700 µg/l Fresh water Algae - Pseudokirchneriella
subcapitata96 hours
Acute LC50 33900 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
: Not available.
Mobility in soil
Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
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Section 14. Transport information
PAINT
3
III
PAINT
3
III
UN1263 UN1263
- Emergency schedules F-E, S-E
DOT Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL and the IBC Code
No. No.
Not available.
:
Proper shipping name :
Ship type : Not available.
Pollution category : Not available.
Not available.
:
TDG Classification
UN1263
PAINT
3
III
No.
Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3).
Mexico Classification
UN1263
PAINT
3
III
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
IATA
UN1263
PAINT
3
III
No.
-
128
ERG No.
128 128
ERG No. ERG No.
Section 15. Regulatory informationSARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
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Section 16. Other information
3/2/2018
History
Date of printing
Date of issue/Date of revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
Notice to reader
Date of previous issue
:
:
:
:
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
3/2/2018
10/16/2017
11
Hazardous Material Information System (U.S.A.)
3
3
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
FLAMMABLE LIQUIDS - Category 3 On basis of test dataACUTE TOXICITY (inhalation) - Category 4 Calculation methodSKIN CORROSION/IRRITATION - Category 2 Calculation methodSERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Calculation methodSKIN SENSITIZATION - Category 1 Calculation methodCARCINOGENICITY - Category 2 Calculation methodSPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs, skin) -Category 1
Calculation method
ASPIRATION HAZARD - Category 1 Calculation method
Procedure used to derive the classification
Classification Justification
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Section 16. Other informationdetermine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
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ACROLON™ 218 HS Polyurethane - Semi-Gloss (Part A)Extra White/Tint Base
Not available.
Liquid.
US / Canada: (216) 566-2917Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of identificationProduct type
Emergency telephone number of the company
Section 1. Identification:
:
:
:
Manufacturer : THE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
B65W651
B65W651Product code :
Product Information Telephone Number
: US / Canada: (800) 524-5979Mexico: Not Available
Regulatory Information Telephone Number
: US / Canada: (216) 566-2902Mexico: Not Available
Transportation Emergency Telephone Number
: US / Canada: (800) 424-9300Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 2SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2ASKIN SENSITIZATION - Category 1CARCINOGENICITY - Category 1ASPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
Classification of the substance or mixture
:
Signal word : Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 31.3%Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 34.3%Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 50.3%
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
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Section 2. Hazards identification
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Do not breathe vapor.Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
: None known.
Highly flammable liquid and vapor.Causes serious eye irritation.Causes skin irritation.May cause an allergic skin reaction.May cause cancer.Causes damage to organs through prolonged or repeated exposure.
:Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.
Supplemental label elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. This product must be mixed with other components before use. Before opening the packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS. Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure.
:
Section 3. Composition/information on ingredients
Titanium Dioxide 21.8 13463-67-7n-Butyl Acetate 8.49 123-86-4Crystalline Silica, respirable powder 8 14808-60-71-Methoxy-2-Propanol Acetate 5.39 108-65-6Methyl Ethyl Ketone 5.15 78-93-3Amorphous Precipitated Silica 4.32 112926-00-8Methyl Isobutyl Ketone 3.01 108-10-1Medium Aromatic Hydrocarbons 1.51 64742-94-5Naphthalene 0.23 91-20-3Bis(pentamethyl-4-piperidyl)sebacate 0.22 41556-26-7
Ingredient name CAS number% by weight
Other means of identification
: Not available.
Substance/mixture
CAS number/other identifiers
: Mixture
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Section 3. Composition/information on ingredientsUV Light Absorber 0.12 104810-48-2Benzotriazole Hydroxyphenyl Polymer 0.11 104810-47-1Ethylbenzene 0.1 100-41-4
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:irritationredness
:
:
:
Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
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Section 4. First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Specific treatments : No specific treatment.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxides
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
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Section 6. Accidental release measuresStop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill :
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Titanium Dioxide ACGIH TLV (United States, 3/2016). TWA: 10 mg/m³ 8 hours.OSHA PEL (United States, 6/2016). TWA: 15 mg/m³ 8 hours. Form: Total dust
n-Butyl Acetate NIOSH REL (United States, 10/2016). TWA: 150 ppm 10 hours. TWA: 710 mg/m³ 10 hours. STEL: 200 ppm 15 minutes. STEL: 950 mg/m³ 15 minutes.OSHA PEL (United States, 6/2016). TWA: 150 ppm 8 hours. TWA: 710 mg/m³ 8 hours.ACGIH TLV (United States, 3/2016). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
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Section 8. Exposure controls/personal protection
Crystalline Silica, respirable powder OSHA PEL Z3 (United States, 6/2016). TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:Respirable TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form:RespirableOSHA PEL (United States, 6/2016). TWA: 50 µg/m³ 8 hours. Form: Respirable dustACGIH TLV (United States, 3/2016). TWA: 0.025 mg/m³ 8 hours. Form:Respirable fractionNIOSH REL (United States, 10/2016). TWA: 0.05 mg/m³ 10 hours. Form: respirable dust
1-Methoxy-2-Propanol Acetate AIHA WEEL (United States, 10/2011). TWA: 50 ppm 8 hours.
Methyl Ethyl Ketone ACGIH TLV (United States, 3/2016). TWA: 200 ppm 8 hours. TWA: 590 mg/m³ 8 hours. STEL: 300 ppm 15 minutes. STEL: 885 mg/m³ 15 minutes.NIOSH REL (United States, 10/2016). TWA: 200 ppm 10 hours. TWA: 590 mg/m³ 10 hours. STEL: 300 ppm 15 minutes. STEL: 885 mg/m³ 15 minutes.OSHA PEL (United States, 6/2016). TWA: 200 ppm 8 hours. TWA: 590 mg/m³ 8 hours.
Amorphous Precipitated Silica NIOSH REL (United States, 10/2016). TWA: 6 mg/m³ 10 hours.
Methyl Isobutyl Ketone ACGIH TLV (United States, 3/2016). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes.NIOSH REL (United States, 10/2016). TWA: 50 ppm 10 hours. TWA: 205 mg/m³ 10 hours. STEL: 75 ppm 15 minutes. STEL: 300 mg/m³ 15 minutes.OSHA PEL (United States, 6/2016). TWA: 100 ppm 8 hours. TWA: 410 mg/m³ 8 hours.
Medium Aromatic Hydrocarbons None.Naphthalene ACGIH TLV (United States, 3/2016).
Absorbed through skin. TWA: 10 ppm 8 hours. TWA: 52 mg/m³ 8 hours.NIOSH REL (United States, 10/2016). TWA: 10 ppm 10 hours. TWA: 50 mg/m³ 10 hours. STEL: 15 ppm 15 minutes. STEL: 75 mg/m³ 15 minutes.OSHA PEL (United States, 6/2016). TWA: 10 ppm 8 hours. TWA: 50 mg/m³ 8 hours.
Bis(pentamethyl-4-piperidyl)sebacate None.UV Light Absorber None.Benzotriazole Hydroxyphenyl Polymer None.Ethylbenzene ACGIH TLV (United States, 3/2016).
TWA: 20 ppm 8 hours.
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Section 8. Exposure controls/personal protectionNIOSH REL (United States, 10/2016). TWA: 100 ppm 10 hours. TWA: 435 mg/m³ 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m³ 15 minutes.OSHA PEL (United States, 6/2016). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours.
n-Butyl Acetate CA Alberta Provincial (Canada, 4/2009). 15 min OEL: 200 ppm 15 minutes. 15 min OEL: 950 mg/m³ 15 minutes. 8 hrs OEL: 150 ppm 8 hours. 8 hrs OEL: 713 mg/m³ 8 hours.CA British Columbia Provincial (Canada,7/2016). TWA: 20 ppm 8 hours.CA Ontario Provincial (Canada, 7/2015). TWA: 150 ppm 8 hours. STEL: 200 ppm 15 minutes.CA Québec Provincial (Canada, 1/2014). TWAEV: 150 ppm 8 hours. TWAEV: 713 mg/m³ 8 hours. STEV: 200 ppm 15 minutes. STEV: 950 mg/m³ 15 minutes.CA Saskatchewan Provincial (Canada,7/2013). STEL: 200 ppm 15 minutes. TWA: 150 ppm 8 hours.
Crystalline Silica, respirable powder CA British Columbia Provincial (Canada,7/2016). TWA: 0.025 mg/m³ 8 hours. Form:RespirableCA Québec Provincial (Canada, 1/2014). TWAEV: 0.1 mg/m³ 8 hours. Form:Respirable dust.CA Ontario Provincial (Canada, 7/2015). TWA: 0.1 mg/m³ 8 hours. Form: Respirable fraction.CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 0.025 mg/m³ 8 hours. Form:Respirable particulateCA Saskatchewan Provincial (Canada,7/2013). TWA: 0.05 mg/m³ 8 hours. Form: respirable fraction
Methyl Ethyl Ketone CA Alberta Provincial (Canada, 4/2009). 15 min OEL: 300 ppm 15 minutes. 8 hrs OEL: 200 ppm 8 hours. 8 hrs OEL: 590 mg/m³ 8 hours. 15 min OEL: 885 mg/m³ 15 minutes.CA British Columbia Provincial (Canada,7/2016). TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes.CA Ontario Provincial (Canada, 7/2015). TWA: 200 ppm 8 hours. STEL: 300 ppm 15 minutes.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
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Section 8. Exposure controls/personal protectionCA Québec Provincial (Canada, 1/2014). TWAEV: 50 ppm 8 hours. TWAEV: 150 mg/m³ 8 hours. STEV: 100 ppm 15 minutes. STEV: 300 mg/m³ 15 minutes.CA Saskatchewan Provincial (Canada,7/2013). STEL: 300 ppm 15 minutes. TWA: 200 ppm 8 hours.
Methyl Isobutyl Ketone CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 205 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. 15 min OEL: 75 ppm 15 minutes. 15 min OEL: 307 mg/m³ 15 minutes.CA British Columbia Provincial (Canada,7/2016). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes.CA Ontario Provincial (Canada, 7/2015). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes.CA Québec Provincial (Canada, 1/2014). TWAEV: 50 ppm 8 hours. TWAEV: 205 mg/m³ 8 hours. STEV: 75 ppm 15 minutes. STEV: 307 mg/m³ 15 minutes.CA Saskatchewan Provincial (Canada,7/2013). STEL: 75 ppm 15 minutes. TWA: 50 ppm 8 hours.
Naphthalene CA Alberta Provincial (Canada, 4/2009).Absorbed through skin. 15 min OEL: 15 ppm 15 minutes. 8 hrs OEL: 10 ppm 8 hours. 8 hrs OEL: 52 mg/m³ 8 hours. 15 min OEL: 79 mg/m³ 15 minutes.CA British Columbia Provincial (Canada,7/2016). Absorbed through skin. TWA: 10 ppm 8 hours. STEL: 15 ppm 15 minutes.CA Ontario Provincial (Canada, 7/2015).Absorbed through skin. TWA: 10 ppm 8 hours. STEL: 15 ppm 15 minutes.CA Québec Provincial (Canada, 1/2014). TWAEV: 10 ppm 8 hours. TWAEV: 52 mg/m³ 8 hours. STEV: 15 ppm 15 minutes. STEV: 79 mg/m³ 15 minutes.CA Saskatchewan Provincial (Canada,7/2013). Absorbed through skin. STEL: 15 ppm 15 minutes. TWA: 10 ppm 8 hours.
Ethylbenzene CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 100 ppm 8 hours. 8 hrs OEL: 434 mg/m³ 8 hours. 15 min OEL: 543 mg/m³ 15 minutes. 15 min OEL: 125 ppm 15 minutes.CA British Columbia Provincial (Canada,7/2016).
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Section 8. Exposure controls/personal protection
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection :
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
TWA: 20 ppm 8 hours.CA Ontario Provincial (Canada, 7/2015). TWA: 20 ppm 8 hours.CA Québec Provincial (Canada, 1/2014). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 125 ppm 15 minutes. STEV: 543 mg/m³ 15 minutes.CA Saskatchewan Provincial (Canada,7/2013). STEL: 125 ppm 15 minutes. TWA: 100 ppm 8 hours.
Environmental exposure controls
:
n-Butyl Acetate NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 150 ppm 8 hours. STEL: 200 ppm 15 minutes.
Crystalline Silica, respirable powder NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 0.025 mg/m³ 8 hours. Form:Respirable fraction
Methyl Ethyl Ketone NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 200 ppm 8 hours. STEL: 300 ppm 15 minutes.
Methyl Isobutyl Ketone NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. STEL: 75 ppm 15 minutes.
Naphthalene NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 10 ppm 8 hours. STEL: 15 ppm 15 minutes.
Ethylbenzene NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 20 ppm 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Mexico)
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Section 8. Exposure controls/personal protectionHand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Respiratory protection :
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
:
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.35
2.48 [Air = 1]
12.1 kPa (90.6 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 5.6 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 13°C (55.4°F) [Tagliabue Closed Cup]
Not available.
Not available.
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point : 78°C (172.4°F)
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Lower: 0.8%Upper: 13.1%
Decomposition temperature : Not available.
Heat of combustion : 8.423 kJ/g
Aerosol product
Molecular weight : Not applicable.
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Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
n-Butyl Acetate LD50 Dermal Rabbit >17600 mg/kg -LD50 Oral Rat 10768 mg/kg -
1-Methoxy-2-Propanol Acetate
LD50 Dermal Rabbit >5 g/kg -
LD50 Oral Rat 8532 mg/kg -Methyl Ethyl Ketone LD50 Dermal Rabbit 6480 mg/kg -
LD50 Oral Rat 2737 mg/kg -Methyl Isobutyl Ketone LD50 Oral Rat 2080 mg/kg -Naphthalene LD50 Dermal Rabbit >20 g/kg -
LD50 Oral Rat 490 mg/kg -Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
-
n-Butyl Acetate Eyes - Moderate irritant Rabbit - 100 milligrams
-
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
-
Methyl Ethyl Ketone Skin - Mild irritant Rabbit - 24 hours 14 milligrams
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Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
-
Methyl Isobutyl Ketone Eyes - Moderate irritant Rabbit - 24 hours 100 microliters
-
Eyes - Severe irritant Rabbit - 40 milligrams -Skin - Mild irritant Rabbit - 24 hours 500
milligrams-
Medium Aromatic Hydrocarbons
Skin - Mild irritant Rabbit - 24 hours 500 microliters
-
Naphthalene Skin - Mild irritant Rabbit - 495 milligrams
-
Skin - Severe irritant Rabbit - 24 hours 0.05 -
Product/ingredient name Result Score Exposure ObservationSpecies
Information on toxicological effects
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Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
MililitersEthylbenzene Eyes - Severe irritant Rabbit - 500
milligrams-
Skin - Mild irritant Rabbit - 24 hours 15 milligrams
-
Sensitization
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
n-Butyl Acetate Category 3 Not applicable. Narcotic effectsMethyl Ethyl Ketone Category 3 Not applicable. Respiratory tract
irritation and Narcotic effects
Methyl Isobutyl Ketone Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Medium Aromatic Hydrocarbons Category 3 Not applicable. Narcotic effectsNaphthalene Category 3 Not applicable. Respiratory tract
irritation and Narcotic effects
Ethylbenzene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Name Category
Name Category
Crystalline Silica, respirable powder Category 1 Inhalation Not determinedMethyl Ethyl Ketone Category 2 Not determined Not determinedMethyl Isobutyl Ketone Category 2 Not determined Not determinedNaphthalene Category 2 Not determined Not determinedEthylbenzene Category 2 Not determined Not determined
Aspiration hazard
Route of exposure
Target organs
Route of exposure
Target organs
Classification
Titanium Dioxide - 2B -Crystalline Silica, respirable powder
- 1 Known to be a human carcinogen.
Amorphous Precipitated Silica
- 3 -
Methyl Isobutyl Ketone - 2B -Naphthalene - 2B Reasonably anticipated to be a human carcinogen.Ethylbenzene - 2B -
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/5/2017 Version : 12.02
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Section 11. Toxicological informationName Result
Medium Aromatic Hydrocarbons ASPIRATION HAZARD - Category 1Naphthalene ASPIRATION HAZARD - Category 1Ethylbenzene ASPIRATION HAZARD - Category 1
Not available.
Information on the likely routes of exposure
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General :
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:irritationredness
:
:
:
Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 20634.4 mg/kgInhalation (vapors) 181.4 mg/l
Route ATE value
Acute toxicity estimates
: Not available.
Potential acute health effects
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/5/2017 Version : 12.02
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Product/ingredient name
Medium Aromatic Hydrocarbons
- 99 to 5780 high
Naphthalene - 36.5 to 168 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
n-Butyl Acetate - - ReadilyMethyl Ethyl Ketone - - ReadilyMethyl Isobutyl Ketone - - ReadilyEthylbenzene - - Readily
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hoursn-Butyl Acetate Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 hours
Acute LC50 18000 µg/l Fresh water Fish - Pimephales promelas 96 hoursMethyl Ethyl Ketone Acute EC50 >500000 µg/l Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 5091000 µg/l Fresh water Daphnia - Daphnia magna -Larvae
48 hours
Acute LC50 3220000 µg/l Fresh water Fish - Pimephales promelas 96 hoursMethyl Isobutyl Ketone Acute LC50 505000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 daysChronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas -
Embryo33 days
Naphthalene Acute EC50 1600 µg/l Fresh water Daphnia - Daphnia magna -Neonate
48 hours
Acute LC50 2350 µg/l Marine water Crustaceans - Palaemonetes pugio
48 hours
Acute LC50 213 µg/l Fresh water Fish - Melanotaenia fluviatilis -Larvae
96 hours
Chronic NOEC 0.5 mg/l Marine water Crustaceans - Uca pugnax - Adult 3 weeksChronic NOEC 1.5 mg/l Fresh water Fish - Oreochromis mossambicus 60 days
Ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata
72 hours
Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata
96 hours
Acute EC50 6530 µg/l Fresh water Crustaceans - Artemia sp. -Nauplii
48 hours
Acute EC50 2930 µg/l Fresh water Daphnia - Daphnia magna -Neonate
48 hours
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
: Not available.
Mobility in soil
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/5/2017 Version : 12.02
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Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
PAINT
3
II
PAINT
3
II
UN1263 UN1263
- Emergency schedules F-E, S-E
DOT Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL and the IBC Code
No. No.
Not available.
:
Proper shipping name :
Ship type : Not available.
Pollution category : Not available.
Not available.
:
TDG Classification
UN1263
PAINT
3
II
No.
Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3).
Mexico Classification
UN1263
PAINT
3
II
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
IATA
UN1263
PAINT
3
II
No.
-
128
ERG No.
128 128
ERG No. ERG No.
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/5/2017 Version : 12.02
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Section 15. Regulatory informationSARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
Section 16. Other information
1/16/2018
History
Date of printing
Date of issue/Date of revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
Notice to reader
Date of previous issue
:
:
:
:
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
1/16/2018
9/5/2017
12.02
Hazardous Material Information System (U.S.A.)
2
3
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
FLAMMABLE LIQUIDS - Category 2 On basis of test dataSKIN CORROSION/IRRITATION - Category 2 Calculation methodSERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation methodSKIN SENSITIZATION - Category 1 Calculation methodCARCINOGENICITY - Category 1A Calculation methodSPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Calculation method
Procedure used to derive the classification
Classification Justification
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/5/2017 Version : 12.02
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B65W651 ACROLON™ 218 HS Polyurethane - Semi-Gloss (Part A)Extra White/Tint Base
Section 16. Other informationof the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Date of issue/Date of revision : 1/16/2018 Date of previous issue : 9/5/2017 Version : 12.02
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B65W651 ACROLON™ 218 HS Polyurethane - Semi-Gloss (Part A)Extra White/Tint Base
PRO INDUSTRIAL™ Waterbased Alkyd Urethane Semi-GlossExtra White
Not available.
Liquid.
US / Canada: (216) 566-2917Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of identificationProduct type
Emergency telephone number of the company
Section 1. Identification:
:
:
:
Manufacturer : THE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
B53W1151
B53W1151Product code :
Product Information Telephone Number
: US / Canada: (800) 524-5979Mexico: Not Available
Regulatory Information Telephone Number
: US / Canada: (216) 566-2902Mexico: Not Available
Transportation Emergency Telephone Number
: US / Canada: (800) 424-9300Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
CARCINOGENICITY - Category 2SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1
Classification of the substance or mixture
:
Signal word : Danger
Hazard pictograms :
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 23.8%Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 23.8%Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 23.8%
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Suspected of causing cancer.Causes damage to organs through prolonged or repeated exposure. (lungs)
:Hazard statements
Date of issue/Date of revision : 4/17/2018 Date of previous issue : 3/16/2018 Version : 9 1/11
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SHW-85-NA-GHS-US
Section 2. Hazards identificationResponse : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention.
Storage : Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.
This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow this product to enter drains, sewers, wastewater treatment systems, groundwater, streams,lakes or ponds. See Environmental Data Sheet (EDS) for additional details.
Hazards not otherwise classified
: DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,metal container. Dispose of in accordance with local fire regulations.
Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.
Supplemental label elements
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
:
Section 3. Composition/information on ingredients
Titanium Dioxide ≥10 - ≤25 13463-67-7Kaolin ≤5 1332-58-7Propylene Glycol ≤3 57-55-6
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of identification
: Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Date of issue/Date of revision : 4/17/2018 Date of previous issue : 3/16/2018 Version : 9 2/11
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SHW-85-NA-GHS-US
Section 4. First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact : No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Section 6. Accidental release measuresPersonal precautions, protective equipment and emergency procedures
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
For non-emergency personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Date of issue/Date of revision : 4/17/2018 Date of previous issue : 3/16/2018 Version : 9 3/11
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SHW-85-NA-GHS-US
Section 6. Accidental release measuresEnvironmental precautions
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow this product to enter drains, sewers, wastewater treatment systems, groundwater,streams, lakes or ponds. See Environmental Data Sheet (EDS) for additional details.
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Titanium Dioxide ACGIH TLV (United States, 3/2017). TWA: 10 mg/m³ 8 hours.OSHA PEL (United States, 6/2016). TWA: 15 mg/m³ 8 hours. Form: Total dust
Kaolin ACGIH TLV (United States, 3/2017). TWA: 2 mg/m³ 8 hours. Form: Respirable fractionNIOSH REL (United States, 10/2016).
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Date of issue/Date of revision : 4/17/2018 Date of previous issue : 3/16/2018 Version : 9 4/11
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SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection TWA: 5 mg/m³ 10 hours. Form: Respirable fraction TWA: 10 mg/m³ 10 hours. Form: TotalOSHA PEL (United States, 6/2016). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust
Propylene Glycol AIHA WEEL (United States, 10/2011). TWA: 10 mg/m³ 8 hours.
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.
Eye/face protection
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow this product to enter drains, sewers, wastewater treatment systems, groundwater,streams, lakes or ponds. See Environmental Data Sheet (EDS) for additional details.
None.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Environmental exposure controls
:
None.
Ingredient name Exposure limits
Occupational exposure limits (Mexico)
Date of issue/Date of revision : 4/17/2018 Date of previous issue : 3/16/2018 Version : 9 5/11
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SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protectionBased on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Respiratory protection :
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.26
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
White.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >93.3°C (>199.9°F)
Not available.
8.8
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point : 100°C (212°F)
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Lower: 2.6%Upper: 12.5%
Decomposition temperature : Not available.
Heat of combustion : 0.479 kJ/g
Aerosol product
Molecular weight : Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Date of issue/Date of revision : 4/17/2018 Date of previous issue : 3/16/2018 Version : 9 6/11
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SHW-85-NA-GHS-US
Section 11. Toxicological information
Acute toxicity
Propylene Glycol LD50 Dermal Rabbit 20800 mg/kg -LD50 Oral Rat 20 g/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
-
Propylene Glycol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams
-
Eyes - Mild irritant Rabbit - 100 milligrams
-
Skin - Moderate irritant Child - 96 hours 30 Percent continuous
-
Skin - Mild irritant Human - 168 hours 500 milligrams
-
Skin - Moderate irritant Human - 72 hours 104 milligrams Intermittent
-
Skin - Mild irritant Woman - 96 hours 30 Percent
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
Kaolin Category 1 Inhalation lungs
Aspiration hazard
Not available.
Route of exposure
Target organs
Information on toxicological effects
Classification
Titanium Dioxide - 2B -
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision : 4/17/2018 Date of previous issue : 3/16/2018 Version : 9 7/11
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SHW-85-NA-GHS-US
Not available.
Information on the likely routes of exposure
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact : No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
: Not available.
Potential acute health effects
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Section 12. Ecological informationToxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hoursPropylene Glycol Acute EC50 >110 ppm Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 1020000 µg/l Fresh water Crustaceans - Ceriodaphnia dubia
48 hours
Acute LC50 710000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Date of issue/Date of revision : 4/17/2018 Date of previous issue : 3/16/2018 Version : 9 8/11
B53W1151 PRO INDUSTRIAL™ Waterbased Alkyd Urethane Semi-GlossExtra White
SHW-85-NA-GHS-US
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Propylene Glycol - - Readily
Soil/water partition coefficient (KOC)
: Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow this product to enter drains, sewers, wastewater treatment systems, groundwater,streams, lakes or ponds. See Environmental Data Sheet (EDS) for additional details.
Section 14. Transport information
-
-
-
-
-
-
Not regulated. Not regulated.
- -
DOT Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
No. No.
TDG Classification
Not regulated.
-
-
-
No.
-
Mexico Classification
Not regulated.
-
-
-
No.
-
IATA
Not regulated.
-
-
-
No.
-
Date of issue/Date of revision : 4/17/2018 Date of previous issue : 3/16/2018 Version : 9 9/11
B53W1151 PRO INDUSTRIAL™ Waterbased Alkyd Urethane Semi-GlossExtra White
SHW-85-NA-GHS-US
Section 14. Transport informationSpecial precautions for user
Transport in bulk according to Annex II of MARPOL and the IBC Code
Not available.
:
Proper shipping name :
Ship type : Not available.
Pollution category : Not available.
Not available.
: Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
Section 15. Regulatory informationU.S. Federal regulations :
SARA 313
TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone
TSCA 5(a)2 final significant new use rules: Pentaoxapentadecane
This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow this product to enter drains, sewers, wastewater treatment systems, groundwater, streams,lakes or ponds. See Environmental Data Sheet (EDS) for additional details.
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
Section 16. Other information
4/17/2018
History
Date of printing
Date of issue/Date of revision
Version
Date of previous issue
:
:
:
:
4/17/2018
3/16/2018
9
Hazardous Material Information System (U.S.A.)
3
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
CARCINOGENICITY - Category 2 Calculation methodSPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1
Calculation method
Procedure used to derive the classification
Classification Justification
Date of issue/Date of revision : 4/17/2018 Date of previous issue : 3/16/2018 Version : 9 10/11
B53W1151 PRO INDUSTRIAL™ Waterbased Alkyd Urethane Semi-GlossExtra White
SHW-85-NA-GHS-US
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Notice to reader
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
Date of issue/Date of revision : 4/17/2018 Date of previous issue : 3/16/2018 Version : 9 11/11
B53W1151 PRO INDUSTRIAL™ Waterbased Alkyd Urethane Semi-GlossExtra White
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PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic PrimerOff White
Not available.
Liquid.
US / Canada: (216) 566-2917Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of identificationProduct type
Emergency telephone number of the company
Section 1. Identification:
:
:
:
Manufacturer : THE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
B66W310
B66W310Product code :
Product Information Telephone Number
: US / Canada: (800) 524-5979Mexico: Not Available
Regulatory Information Telephone Number
: US / Canada: (216) 566-2902Mexico: Not Available
Transportation Emergency Telephone Number
: US / Canada: (800) 424-9300Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2ACARCINOGENICITY - Category 2
Classification of the substance or mixture
:
Signal word : Warning
Hazard pictograms :
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing. Wash hands thoroughly after handling.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 22.4%Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 22.4%Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 22.4%
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Causes serious eye irritation.Causes skin irritation.Suspected of causing cancer.
:Hazard statements
Date of issue/Date of revision : 3/22/2018 Date of previous issue : 3/2/2018 Version : 10 1/11
B66W310 PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic PrimerOff White
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Section 2. Hazards identificationResponse : IF exposed or concerned: Get medical attention. IF ON SKIN: Wash with plenty of
soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store locked up.Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise classified
: None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.
Supplemental label elements
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
:
Section 3. Composition/information on ingredients
Calcium Carbonate ≥10 - <20 1317-65-3Titanium Dioxide ≤10 13463-67-7Mineral Spirits 140-Flash ≤0.3 64742-88-7
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of identification
: Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Date of issue/Date of revision : 3/22/2018 Date of previous issue : 3/2/2018 Version : 10 2/11
B66W310 PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic PrimerOff White
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Section 4. First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:irritationredness
:
:
:
Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Section 6. Accidental release measuresPersonal precautions, protective equipment and emergency procedures
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
For non-emergency personnel
Date of issue/Date of revision : 3/22/2018 Date of previous issue : 3/2/2018 Version : 10 3/11
B66W310 PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic PrimerOff White
SHW-85-NA-GHS-US
Section 6. Accidental release measures
Environmental precautions
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.Avoid breathing vapor or mist. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Calcium Carbonate NIOSH REL (United States, 10/2016). TWA: 5 mg/m³ 10 hours. Form: Respirable fraction TWA: 10 mg/m³ 10 hours. Form: TotalOSHA PEL (United States, 6/2016). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Date of issue/Date of revision : 3/22/2018 Date of previous issue : 3/2/2018 Version : 10 4/11
B66W310 PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic PrimerOff White
SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protectionTitanium Dioxide ACGIH TLV (United States, 3/2016).
TWA: 10 mg/m³ 8 hours.OSHA PEL (United States, 6/2016). TWA: 15 mg/m³ 8 hours. Form: Total dust
Mineral Spirits 140-Flash OSHA PEL (United States, 6/2016). TWA: 100 ppm 8 hours. TWA: 400 mg/m³ 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
None.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Environmental exposure controls
:
None.
Ingredient name Exposure limits
Occupational exposure limits (Mexico)
Date of issue/Date of revision : 3/22/2018 Date of previous issue : 3/2/2018 Version : 10 5/11
B66W310 PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic PrimerOff White
SHW-85-NA-GHS-US
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.23
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >93.3°C (>199.9°F)
Not available.
8.7
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point : 100°C (212°F)
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Lower: 0.6%Upper: 20.4%
Decomposition temperature : Not available.
Heat of combustion : 1.488 kJ/g
Aerosol product
Molecular weight : Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Irritation/Corrosion
Information on toxicological effects
Date of issue/Date of revision : 3/22/2018 Date of previous issue : 3/2/2018 Version : 10 6/11
B66W310 PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic PrimerOff White
SHW-85-NA-GHS-US
Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Calcium Carbonate Category 3 Not applicable. Respiratory tract irritation
Mineral Spirits 140-Flash Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Name Category
Name Category
Mineral Spirits 140-Flash Category 1 Not determined Not determined
Aspiration hazard
Name Result
Mineral Spirits 140-Flash ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Route of exposure
Target organs
Classification
Titanium Dioxide - 2B -
Product/ingredient name NTPIARCOSHA
Information on the likely routes of exposure
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : Causes skin irritation.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness
: Not available.
Potential acute health effects
Date of issue/Date of revision : 3/22/2018 Date of previous issue : 3/2/2018 Version : 10 7/11
B66W310 PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic PrimerOff White
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Not available.
No known significant effects or critical hazards.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:irritationredness
:
:
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
: Not available.
Mobility in soil
Not available.
Date of issue/Date of revision : 3/22/2018 Date of previous issue : 3/2/2018 Version : 10 8/11
B66W310 PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic PrimerOff White
SHW-85-NA-GHS-US
Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
-
-
-
-
-
-
Not regulated. Not regulated.
- -
DOT Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL and the IBC Code
No. No.
Not available.
:
Proper shipping name :
Ship type : Not available.
Pollution category : Not available.
Not available.
:
TDG Classification
Not regulated.
-
-
-
No.
-
Mexico Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
Section 15. Regulatory informationSARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
Date of issue/Date of revision : 3/22/2018 Date of previous issue : 3/2/2018 Version : 10 9/11
B66W310 PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic PrimerOff White
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WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
Section 16. Other information
3/22/2018
History
Date of printing
Date of issue/Date of revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Notice to reader
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Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
3/22/2018
3/2/2018
10
Hazardous Material Information System (U.S.A.)
2
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
SKIN CORROSION/IRRITATION - Category 2 Calculation methodSERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation methodCARCINOGENICITY - Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
Date of issue/Date of revision : 3/22/2018 Date of previous issue : 3/2/2018 Version : 10 10/11
B66W310 PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic PrimerOff White
SHW-85-NA-GHS-US