Leaf Energy Ltd - PPT...Leaf Energy Ltd - PPT Author ALPHA1 Created Date 3/23/2015 1:52:23 PM ...

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Leaf Resources Limited Corporate Presentation October 2014 Glycell™ - An Update on Leaf Resources’ Pretreatment Process for the Conversion of Lignocellulosic Biomass to Fuels and Chemicals Les Edye Bioenergy Australia Meeting, March, 2015

Transcript of Leaf Energy Ltd - PPT...Leaf Energy Ltd - PPT Author ALPHA1 Created Date 3/23/2015 1:52:23 PM ...

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Leaf Resources Limited Corporate Presentation

October 2014

Glycell™ - An Update on Leaf Resources’ Pretreatment Process for the Conversion of

Lignocellulosic Biomass to Fuels and Chemicals

Les Edye Bioenergy Australia Meeting, March, 2015

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Forward Looking Statements

This presentation does not constitute, or form part of, an offer to sell or the solicitation of an offer to subscribe for or buy any

securities, nor the solicitation of any vote or approval in any jurisdiction, nor shall there be any sale, issue or transfer of the

securities referred to in this presentation in any jurisdiction in contravention of applicable law. Persons needing advice should

consult their stockbroker, bank manager, solicitor, accountant or other independent financial advisor.

Certain statements made in this presentation are forward-looking statements. These forward looking statements are not

historical facts but rather are based on Leaf Resources current expectations, estimates and projections about the industry in

which Leaf Resources operates, and its beliefs and assumptions. Words such as "anticipates," "expects," "intends," "plans,"

"believes," "seeks,” "estimates,“ “guidance” and similar expressions are intended to identify forward-looking statements. and

should be considered an at-risk statement. Such statements are subject to certain risks and uncertainties, particularly those

risks or uncertainties inherent in the process of developing technology and in the endeavour of building a business around

such products and services. These statements are not guarantees of future performance and are subject to known and

unknown risks, uncertainties and other factors, some of which are beyond the control of Leaf Resources, are difficult to predict

and could cause actual results to differ materially from those expressed or forecasted in the forward-looking statements. Leaf

Resources cautions shareholders and prospective shareholders not to place undue reliance on these forward-looking

statements, which reflect the view of Leaf Resources only as of the date of this presentation. The forward-looking statements

made in this presentation relate only to events as of the date on which the statements are made. Leaf Resources will not

undertake any obligation to release publicly any revisions or updates to these forward-looking statements to reflect events,

circumstances or unanticipated events occurring after the date of this presentation except as required by law or by any

appropriate regulatory authority.

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Leaf Resources Active participants in the advanced bio-economy

Leaf Resources Limited (ASX:LER) is focused on making sustainable products from plant biomass.

We offer an advanced technology package for breaking down plant derived biomass to useful, sustainable, renewable and biodegradable products.

Leaf Resources’ innovative GlycellTM is a disruptive process technology that can reshape the economics of using large scale biomass resources as a replacement for petroleum derived products.

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Clean sugars feed bio-based chemicals market

Industrial Corrosion inhibitors, dust control, boiler water treatment, gas purification, emission abatement, specialty lubricants, hoses, seals

Transportation Fuels, oxygenates, anti-freeze, wiper fluids molded plastics, car seats, belts hoses, bumpers, corrosion inhibitors Textiles Carpets, Fibers, fabrics, fabric coatings, foam cushions, upholstery, drapes, lycra, spandex Safe Food Supply Food packaging, preservatives, fertilizers, pesticides, beverage bottles, appliances, beverage can coatings, vitamins Environment Water chemicals, flocculants, chelators, cleaners and detergents Communication Molded plastics, computer casings, optical fiber coatings, liquid crystal displays, pens, pencils, inks, dyes, paper products Housing Paints, resins, siding, insulation, cements, coatings, varnishes, flame retardents, adhesives, carpeting Recreation Footgear, protective equipment, camera and film, bicycle parts & tires, wet suits, tapes-CD’s-DVD’s, golf equipment, camping gear, boats Health and Hygiene Plastic eyeglasses, cosmetics, detergents, pharmaceuticals, suntan lotion, medical-dental products, disinfectants, aspirin

GlycellTM process

Low cost clean sugars… faster

Proprietary technology owned by others converts the sugars to

Renewable chemicals and green sustainable products.

Bio-based chemicals: growing 20%pa, exceeding $500b by 2017

Bio-based chemical examples

Zeachem - Acetic Acid, Ethyl Acetate Bioamber - Succinic Acid Myriant - Succinic Acid Avantium - PET replacement Baskem - Polyethylene Renovia - Adipic and Lactic acid Multiple - Ethanol Others - Many uses

Used by companies such as: Toyota Dow Dupont Mitsui Johnson and Johnson Proctor and Gamble Coca-Cola Plus many others

* See announcement 14th July 2014 17

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Glycell™ CS Key objectives Process focus

Key proposition and competitive

advantage

“Produce low cost cellulose at any scale”

Cellulosic sugars Maximise cellulose conversion

to cellulosic sugars

Clean enriched streams

Separate pentose rich and hexose rich liquid products

Funding Model Partnerships for a capital light

approach

Glycerol recovery

Profound effect on cost of sugars

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Design Case

Lignocellulosic biomass is impregnated with sulphuric acid and steam at atmospheric pressure over a period of 10 to 20 minutes. The impregnated biomass is fed into a horizontal screw reactor and crude glycerol is added. The mixture of biomass, acid, water and glycerol is held in the horizontal reactor for 30 minutes at 160 ⁰C and then discharged into a pressafiner (screw press) where the solid and liquid components are separated. The solid component is washed with water and treated with a hydrolysing enzyme cocktail, filtered on a belt filter and the filtrate is concentrated to produce a sugars syrup. The lignin-rich filter cake is dried. The liquid component form the pressafiner containing glycerol, soluble sugars, dissolved lignin and acid is processed by simulated moving bed chromatography to recover components.

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Cost of Sugars

Inputs and effect on cost of sugars

Feedstock Input Price ($/as is tonne at 50% moisture)

Sugar cost (¢/lb)

85% glycerol recovery

100 12

75 8

55 5

Class 5 conceptual design & costing

Sugars Cost – Marginal cost of combined C5 & C6 sugars production net of lignin revenue less capital cost of production over 20 year plant life

Estimates give ~4c/lb cost of capital (40 tph as is brown field plant)

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Product R&D

Biomass pretreatment technologies

US activities

Australian activities

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Andritz Pretreatment Reactor

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Biomass flexibility

Poplar

Bagasse

Blue gum rough chipped

Oil Palm fibre (EFB)

Eucalyptus

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Pilot Plant

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Eucalyptus

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Laboratory optimisation

A significant reduction of lignin content in the Glycell pretreatment solid fraction.

0

20

40

60

80

100

120

0 % A;0 % G;

4.9;60 min

0.5 % A;0 % G;

4.9;60 min

0 % A;200 % G;

4.9;60 min

0.5 % A;200 % G;

4.9;60 min

0.5 % A;280 % G;

5.7;60 min

0.5 % A;400 % G;

6.9;60 min

0.5 % A;200 % G;

6.9;60 min

0.5 % A;200 % G;

4.9;30 min

Kap

pa N

umbe

r

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C6 sugar yield

The saccarification (digestibility) procedure measures the efficacy of a given pretreatment based on a maximum enzyme loading and is reported as a percentage of the theoretical mass yield. Cellulase enzyme cocktail used was Cellic ® CTec3 (Cellic ® CTec3 is a registered trademark of Novozymes) at 20 FPU/g cellulose at

2% cellulose weight loading applied to all samples.

Cellulose saccharification after enzymatic hydrolysis using the GlycellTM process - C6 Sugar yield as % of theoretical maximum • High cellulose recovery (94%) High sugar conversion • 30% more sugars – boost economics • Minimal degradation products detected • This is commercially significant as many products need “clean sugars”

99.45% 100%

80.31%

98.08%

44.54%

74.94%

6 hrs 24 hrs

Bagasse Glycell treatment Eucalyptus Glycell treatment

Eucalyptus - dilute acid treatment

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Improved saccharification kinetics Significant opportunity to reduce enzyme load and size of reactors

Dilute acid – NREL design target (2013) – 0.9 % acid; 2.3 liquid:solid; 5 min – 90 % hydrolysis of cellulose after 84 hours with enzyme load of10 mg/g cellulose

ca. 5 % conversion of xylan to furfural

Glycell best to date – Hardwood – 0.8 % acid; 160 % glycerol; 2.4 liquid:solid; 30 min

No measurable furfural formation

0

10

20

30

40

50

60

70

80

90

100

0 10 20 30 40 50 60 70 80

Glu

can

co

nve

rsio

n (%

)

Glycell best to date 1.0 % A; 200 % glycerol; 3.0; 30 min Dilute acid no pretreatment

Saccharification optimisation opportunity

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Degradation products

Description Cellobiose

(g/L) Xylitol (g/L)

Formic Acid (g/L)

Acetic Acid

(g/L) Levulinic Acid

(g/L) Ethanol

(g/L) HMF (g/L)

Furfural (g/L)

Bagasse

ND ND ND ND ND ND ND ND

Eucalyptus ND ND ND 1.85 ND ND ND ND

Other than Acetic acid, all typical degradation products were not detected for both bagasse and Eucalypt conditions

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Zeachem Collaboration

Collaboration Agreement with ZeaChem Inc.

The evaluation by ZeaChem and Leaf Resources of the Leaf GlycellTM process for the production of fermentable sugars at ZeaChem’s demonstration plant at Boardman, Oregon.

The trials will use Poplar as a feedstock.

SMB chromatic separator pilot from ARI in Twin Falls, Idaho

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Key competitive advantages

Based on current data, Leaf Energy’s GlycellTM process when compared to other pretreatment processes, such as acid hydrolysis and/or steam explosion:

Produces high yield cellulose with less degradation products;

Excellent enzymatic conversion of cellulose to sugars;

Enzyme kinetics improved on the Glycell™ pretreated biomass allowing quick sugar production, and;

produces clean sugars due to milder conditions.

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The Glycell™ Process Proprietary technology for cellulose production

Simple, innovative, low cost and effective

Uses a biodegradable reagent

Low temperature and low pressure

Continuous Process design

Short processing time

The Glycell ™ process has compelling advantages over traditional methods of cellulose extraction

Product benefits: Economic benefits:

Significantly lower capital costs1

Significantly lower operating costs

Industrially available equipment

Operates at any scale

High Cellulose recovery

High conversion of Cellulose to Sugars2

1 see announcement lodged ASX 7th July 2014 2 See announcement lodges ASX 14th July 2014

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