Kit components PT-CN-CFULL CONTEST Group C Full

Kit components27.11.2020

Product code Description

PT-CN-CFULL CONTEST Group C Full

Components:

PT-CN-C03C 3C - Group C Soil

PT-CN-C05 5 - Group C PAHs

PT-CN-C07A 7a - Group C Phenol

PT-CN-C07B 7b - Group C Phenol

PT-CN-C11 11 - Group C PCBs

PT-CN-C14A 14a - Group C TPH

PT-CN-C14B 14b - Group C TPH

PT-CN-C15 15 - Group C BTEX

PT-CN-C19 19 - Group C Chlorinated Hydrocarbons

PT-CN-C20 20 - Group C SVOCs

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Safety data sheetaccording to 1907/2006/EC, Article 31

Printing date 27.11.2020 Revision: 27.11.2020Version number 1

49.2.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier

· Product name: 3C - Group C Soil

· Part number: PT-CN-C03C

· 1.2 Relevant identified uses of the substance or mixture and uses advised againstNo further relevant information available.

· Application of the substance / the mixture Reference material for laboratory use only

· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:

LGC Limited Tel :+44 (0) 20 8943 7000

Queens Road Fax :+44 (0) 20 8943 2767

Teddington eMail : [email protected]

Middlesex TW11 0LY Web : www.lgcstandards.com

UNITED KINGDOM

· Further information obtainable from:Product safety department

eMail : [email protected]

· 1.4 Emergency telephone number:For Hazardous Materials or Dangerous Goods Incident

Spill, Leak, Fire Exposure, or Accident

Call CHEMTREC:

USA & Canada 1-800-424-9300

Rest of the world +1 703-741-5970

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008

GHS08 health hazard

STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.

· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008

The product is classified and labelled according to the CLP regulation.

· Hazard pictograms

GHS08

· Signal word Warning

· Hazard-determining components of labelling:Quartz (SiO2)

(Contd. on page 2)

GB

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Product name: 3C - Group C Soil

(Contd. from page 1)

49.2.0

· Hazard statementsH373 May cause damage to organs through prolonged or repeated exposure.

· Precautionary statementsP260 Do not breathe dust/fume/gas/mist/vapours/spray.

P314 Get medical advice/attention if you feel unwell.

P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

· 2.3 Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.

· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

· 3.2 Chemical characterisation: Mixtures· Description: Also contains substances at levels not considered to be hazardous.

· Dangerous components:

CAS: 14808-60-7

EINECS: 238-878-4

RTECS: VV 7330000

Quartz (SiO2) STOT RE 2, H373; Acute Tox. 4, H332 >95%

· Additional information: For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

· 4.1 Description of first aid measures· General information:

Symptoms of poisoning may occur even after several hours; therefore medical observation for at least 48

hours after the accident is recommended.

· After inhalation: Supply fresh air; consult doctor in case of complaints.

· After skin contact: Immediately wash with water and soap and rinse thoroughly.

· After eye contact: Rinse opened eye for several minutes under running water.

· After swallowing: Rinse mouth. Do not induce vomiting.

· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.

· 4.3 Indication of any immediate medical attention and special treatment neededNo further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media· Suitable extinguishing agents: Use fire extinguishing methods suitable for surrounding conditions.

· 5.2 Special hazards arising from the substance or mixtureDuring heating or in case of fire poisonous gases are produced.

· 5.3 Advice for firefighters· Protective equipment:

Mouth respiratory protective device.(Contd. on page 3)

GB

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49.2.0

Wear self-contained respiratory protective device.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.

· 6.2 Environmental precautions: Do not allow product to reach sewage system or any water course.

· 6.3 Methods and material for containment and cleaning up:Dispose of contaminated material as waste according to item 13.

Ensure adequate ventilation.

· 6.4 Reference to other sectionsSee Section 7 for information on safe handling.

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handlingEnsure good ventilation/extraction at the workplace.

Store in cool, dry place in tightly closed receptacles.

· Information about fire - and explosion protection: Keep respiratory protective device available.

· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:

Please refer to the manufacturer's certificate for specific storage and transport temperature conditions.

Store only in the original receptacle unless other advice is given on the CoA.

Keep container in a well-ventilated place. Keep away from sources of ignition and heat.

· Information about storage in one common storage facility: Store away from foodstuffs.

· Further information about storage conditions: None.

· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.

· 8.1 Control parameters· Ingredients with limit values that require monitoring at the workplace:

The product does not contain any relevant quantities of materials with critical values that have to be

monitored at the workplace.

· Additional information: Lists used were valid at the time of SDS preparation.

· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:

Keep away from foodstuffs, beverages and feed.

Wash hands before breaks and at the end of work.(Contd. on page 4)

GB

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49.2.0

Store protective clothing separately.

· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure

use self-contained respiratory protective device.

· Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the

degradation

The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the

related standard EN374

Protective gloves

· Material of gloves Fluorocarbon rubber (Viton)

· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to be

observed.

· Eye protection:

Tightly sealed goggles

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties· General Information· Appearance:

Form: Solid

Colour: Brown

· Odour: Odourless

· Odour threshold: Not determined.

· pH-value: Not applicable.

· Change in conditionMelting point/freezing point: 1,713 °C

Initial boiling point and boiling range: 2,230 °C

· Flash point: Not applicable.

· Flammability (solid, gas): Not determined.

· Ignition temperature: Not determined

· Decomposition temperature: Not determined.

(Contd. on page 5)

GB

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49.2.0

· Auto-ignition temperature: Product is not selfigniting.

· Explosive properties: Not determined.

· Explosion limits:Lower: Not determined.

Upper: Not determined.

· Vapour pressure at 1732 °C: 13.5 hPa

· Density at 20 °C: 2.2-2.6 g/cm³

· Bulk density: 1,400 kg/m³

· Relative density Not determined.

· Vapour density Not applicable.

· Evaporation rate Not applicable.

· Solubility in / Miscibility withwater: Insoluble.

· Partition coefficient: n-octanol/water: Not determined.

· Viscosity:Dynamic: Not applicable.

Kinematic: Not applicable.

· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 ReactivityStable under normal conditions.

No further relevant information available.

· 10.2 Chemical stability Stable under normal conditions.

· Thermal decomposition / conditions to be avoided:Formation of toxic gases is possible during heating or in case of fire.

· 10.3 Possibility of hazardous reactions No dangerous reactions known.

· 10.4 Conditions to avoid Heat.

· 10.5 Incompatible materials: Strong oxidizing agents.

· 10.6 Hazardous decomposition products:Formation of toxic gases is possible during heating or in case of fire.

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects· Acute toxicity Based on available data, the classification criteria are not met.

· Primary irritant effect:· Skin corrosion/irritation Based on available data, the classification criteria are not met.

· Serious eye damage/irritation Based on available data, the classification criteria are not met.

· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.(Contd. on page 6)

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· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)· Germ cell mutagenicity Based on available data, the classification criteria are not met.

· Carcinogenicity Based on available data, the classification criteria are not met.

· Reproductive toxicity Based on available data, the classification criteria are not met.

· STOT-single exposure Based on available data, the classification criteria are not met.

· STOT-repeated exposureMay cause damage to organs through prolonged or repeated exposure.

· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

· 12.1 Toxicity· Aquatic toxicity: No further relevant information available.

· 12.2 Persistence and degradability No further relevant information available.

· 12.3 Bioaccumulative potential No further relevant information available.

· 12.4 Mobility in soil No further relevant information available.

· Additional ecological information:· General notes: Not hazardous for water.

· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.


· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods· Recommendation

Must not be disposed of together with household garbage. Do not allow product to reach sewage system.

· European waste catalogueWaste disposal key numbers from EWC have to be assigned depending on origin and processing.

· Uncleaned packaging:· Recommendation: Dispose of in accordance with national regulations.

SECTION 14: Transport information

· 14.1 UN-Number· ADR, IMDG, IATA Not applicable

· ADR, IMDG, IATA Not applicable

· 14.3 Transport hazard class(es)

· ADR, ADN, IMDG, IATA· Class Not applicable

(Contd. on page 7)

GB

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49.2.0

· 14.4 Packing group· ADR, IMDG, IATA Not applicable

· 14.5 Environmental hazards: Not applicable.

· 14.6 Special precautions for user Not applicable.

· 14.7 Transport in bulk according to Annex II ofMarpol and the IBC Code Not applicable.

· UN "Model Regulation": Not applicable

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.

· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

The information in this safety data sheet (SDS) has been prepared with due care and is true and accurate to

the best of our knowledge. The user must determine the suitability of the information for its particular

purpose, ensure compliance with existing laws and regulations, and be aware that other or additional safety

or performance considerations may arise when using, handling and/ or storing the material. The information

in this SDS does not purport to be all inclusive or a guarantee as to the properties of the material supplied,

and should be used only as a guide. LGC makes no warranties or representations as to the accuracy and

completeness of the information contained herein, shall not be held responsible for the suitability of this

information for the user's intended purposes or the consequences of such use, and shall not be liable for any

damage or loss, howsoever arising, direct or otherwise.

· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International

Carriage of Dangerous Goods by Road)

IMDG: International Maritime Code for Dangerous Goods

IATA: International Air Transport Association

GHS: Globally Harmonised System of Classification and Labelling of Chemicals

EINECS: European Inventory of Existing Commercial Chemical Substances

ELINCS: European List of Notified Chemical Substances

CAS: Chemical Abstracts Service (division of the American Chemical Society)

PBT: Persistent, Bioaccumulative and Toxic

vPvB: very Persistent and very Bioaccumulative

Acute Tox. 4: Acute toxicity – Category 4

STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2

· SourcesTables 3.1 and 3.2 from Annex 6 of EC 1272/2008, EC 1907/2006, EH40/2005 as amended 2011, Registry of

Toxic Effects of Chemical Substances (RTECS), The Dictionary of Substances and their Effects, 1st Edition,

IUCLID.

· Data compared to the previous version altered. All sections have been updated. GB

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49.2.0



· Product name: 5 - Group C PAHs

· Part number: PT-CN-C05




LGC Limited Tel :+44 (0) 20 8943 7000

Queens Road Fax :+44 (0) 20 8943 2767



UNITED KINGDOM





Call CHEMTREC:

USA & Canada 1-800-424-9300




GHS02 flame

Flam. Liq. 2 H225 Highly flammable liquid and vapour.

GHS08 health hazard

Repr. 2 H361f Suspected of damaging fertility.


Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.

GHS09 environment

Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.(Contd. on page 2)

GB

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Product name: 5 - Group C PAHs


49.2.0

GHS07

Skin Irrit. 2 H315 Causes skin irritation.

STOT SE 3 H336 May cause drowsiness or dizziness.




GHS02 GHS07 GHS08 GHS09

· Signal word Danger

· Hazard-determining components of labelling:n-Hexane

· Hazard statementsH225 Highly flammable liquid and vapour.

H315 Causes skin irritation.

H361f Suspected of damaging fertility.

H336 May cause drowsiness or dizziness.

H373 May cause damage to organs through prolonged or repeated exposure.

H304 May be fatal if swallowed and enters airways.

H411 Toxic to aquatic life with long lasting effects.

· Precautionary statementsP210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No

smoking.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with

water [or shower].

P405 Store locked up.

P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.


· vPvB: Not applicable. GB

(Contd. on page 3)

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CAS: 110-54-3

EINECS: 203-777-6

RTECS: MN 9275000

n-Hexane

Flam. Liq. 2, H225; Repr. 2, H361f; STOT RE 2, H373; Asp. Tox. 1,H304; Aquatic Chronic 2, H411; Skin Irrit. 2, H315; STOT SE 3, H336

>95%




Immediately remove any clothing soiled by the product.



· After inhalation: In case of unconsciousness place patient in recovery position for transport.

· After skin contact:Immediately wash with water and soap and rinse thoroughly.

If skin irritation continues, consult a doctor.


· After swallowing:Rinse mouth. Do not induce vomiting.

Call for a doctor immediately.




· 5.1 Extinguishing media· Suitable extinguishing agents:

CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

· For safety reasons unsuitable extinguishing agents: Water with full jet



Mouth respiratory protective device.

Wear self-contained respiratory protective device. GB

(Contd. on page 4)

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49.2.0



Wear protective equipment. Keep unprotected persons away.

· 6.2 Environmental precautions:Inform respective authorities in case of seepage into water course or sewage system.

Do not allow to enter sewers/ surface or ground water.

· 6.3 Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Dispose of contaminated material as waste according to item 13.








Open and handle receptacle with care.

Prevent formation of aerosols.

· Information about fire - and explosion protection:Keep ignition sources away - Do not smoke.

Protect against electrostatic charges.

Keep respiratory protective device available.






· Further information about storage conditions:Keep container tightly sealed.

Store in cool, dry conditions in well sealed receptacles.



· Additional information about design of technical facilities: No further data; see item 7.(Contd. on page 5)

GB

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49.2.0

· 8.1 Control parameters

· Ingredients with limit values that require monitoring at the workplace:

CAS: 110-54-3 n-Hexane

WEL Long-term value: 72 mg/m³, 20 ppm




Immediately remove all soiled and contaminated clothing

Wash hands before breaks and at the end of work.


Avoid contact with the skin.

Avoid contact with the eyes and skin.



Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a

NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if

irritation or other symptoms are experienced



degradation



Protective gloves

· Material of gloves Nitrile rubber, NBR


observed.

· Eye protection:


GB

(Contd. on page 6)

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49.2.0



Form: Liquid

Colour: Colourless

· Odour: Petrol-like


· pH-value: Not determined.

· Change in conditionMelting point/freezing point: -95 °C

Initial boiling point and boiling range: 69 °C

· Flash point: -26 °C


· Ignition temperature: 240 °C



· Explosive properties: Product is not explosive. However, formation of explosive air/

vapour mixtures is possible.

· Explosion limits:Lower: 1.2 Vol %

Upper: 7.4 Vol %

· Vapour pressure at 20 °C: 160 hPa

· Density at 20 °C: 0.66 g/cm³


· Vapour density Not determined.

· Evaporation rate Not determined.

· Solubility in / Miscibility withwater at 20 °C: 0.1 g/l


· Viscosity:Dynamic: Not determined.

Kinematic: Not determined.


GB

(Contd. on page 7)

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49.2.0






· 10.3 Possibility of hazardous reactions May form flammable/explosive vapour-air mixture.

· 10.4 Conditions to avoidSources of ignition

Heat.





· LD/LC50 values relevant for classification:


Oral LD50 5,000 mg/kg (rat)

Dermal LD50 3,000 mg/kg (rat)

· Primary irritant effect:· Skin corrosion/irritation

Causes skin irritation.


· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.

· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)Repr. 2

· Germ cell mutagenicity Based on available data, the classification criteria are not met.


· Reproductive toxicitySuspected of damaging fertility.

· STOT-single exposureMay cause drowsiness or dizziness.


· Aspiration hazardMay be fatal if swallowed and enters airways.

GB

(Contd. on page 8)

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49.2.0


· 12.1 Toxicity

· Aquatic toxicity:


EC50/48 h 2.1 mg/l (daphnia)

LC50/96 h 2.5 mg/l (fish)

CAS: 191-24-2 Benzo[ghi]perylene

EC50/48 h 0.000587 mg/l (crustacean)




· Ecotoxicological effects:· Remark: Toxic for fish

· Additional ecological information:· General notes:

Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water

Do not allow product to reach ground water, water course or sewage system.

Danger to drinking water if even small quantities leak into the ground.

Also poisonous for fish and plankton in water bodies.

Toxic for aquatic organisms










· 14.1 UN-Number· ADR, IMDG, IATA UN1208

· ADR 1208 HEXANES, ENVIRONMENTALLY HAZARDOUS

· IMDG HEXANES, MARINE POLLUTANT

(Contd. on page 9)

GB

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49.2.0

· IATA HEXANES


· ADR, IMDG

· Class 3 Flammable liquids.

· Label 3

· IATA


· Label 3

· 14.4 Packing group· ADR, IMDG, IATA II

· 14.5 Environmental hazards: Product contains environmentally hazardous substances:

Naphthalene, n-Hexane

· Marine pollutant: Symbol (fish and tree)

· Special marking (ADR): Symbol (fish and tree)

· 14.6 Special precautions for user Warning: Flammable liquids.

· Danger code (Kemler): 33

· EMS Number: F-E,S-E

· Stowage Category E


· Transport/Additional information:

· ADR· Limited quantities (LQ) 1L

· Excepted quantities (EQ) Code: E2

Maximum net quantity per inner packaging: 30 ml

Maximum net quantity per outer packaging: 500 ml

· Transport category 2

· Tunnel restriction code D/E

· UN "Model Regulation": UN 1208 HEXANES, 3, II , ENVIRONMENTALLY

HAZARDOUS

GB

(Contd. on page 10)

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· Seveso categoryE2 Hazardous to the Aquatic Environment

P5c FLAMMABLE LIQUIDS

· Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t

· Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t

· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3




















LC50: Lethal concentration, 50 percent

LD50: Lethal dose, 50 percent



Flam. Liq. 2: Flammable liquids – Category 2

Skin Irrit. 2: Skin corrosion/irritation – Category 2

Repr. 2: Reproductive toxicity – Category 2

STOT SE 3: Specific target organ toxicity (single exposure) – Category 3


Asp. Tox. 1: Aspiration hazard – Category 1

Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2



IUCLID.


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49.2.0



· Product name: 7a - Group C Phenol

· Part number: PT-CN-C07A




LGC Limited Tel :+44 (0) 20 8943 7000

Queens Road Fax :+44 (0) 20 8943 2767



UNITED KINGDOM





Call CHEMTREC:

USA & Canada 1-800-424-9300




GHS05 corrosion

Skin Corr. 1B H314 Causes severe skin burns and eye damage.

Eye Dam. 1 H318 Causes serious eye damage.




GHS05

· Signal word Danger(Contd. on page 2)

GB

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Product name: 7a - Group C Phenol


49.2.0

· Hazard-determining components of labelling:Sodium hydroxide

· Hazard statementsH314 Causes severe skin burns and eye damage.

· Precautionary statementsP280 Wear protective gloves/protective clothing/eye protection/face protection.


water [or shower].

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER/doctor.



regulations.






CAS: 1310-73-2

EINECS: 215-185-5

RTECS: WB4900000

Sodium hydroxide Skin Corr. 1A, H314; Acute Tox. 4, H302 <5%



· 4.1 Description of first aid measures· General information: Immediately remove any clothing soiled by the product.

· After inhalation: Supply fresh air; consult doctor in case of complaints.


Seek immediate medical advice.

· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.




GB

(Contd. on page 3)

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· 6.2 Environmental precautions:Dilute with plenty of water.



Use neutralising agent.
















· Further information about storage conditions: Keep container tightly sealed.(Contd. on page 4)

GB

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49.2.0






CAS: 1310-73-2 Sodium hydroxide

WEL Short-term value: 2 mg/m³






Avoid contact with the eyes.






degradation



Protective gloves



observed.

· Eye protection:


GB

(Contd. on page 5)

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49.2.0



Form: Liquid

Colour: Colourless

· Odour: Odourless



· Change in conditionMelting point/freezing point: Not determined.

Not determined.








· Explosion limits:Lower: Not determined.

Upper: Not determined.


· Density at 20 °C: 1.00452 g/cm³




· Solubility in / Miscibility withwater: Fully miscible.





GB

(Contd. on page 6)

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49.2.0













CAS: 1310-73-2 Sodium hydroxide


LD 50 (Intraperitoneal) 40 mg/kg (rat)


Causes severe skin burns and eye damage.

· Serious eye damage/irritationCauses serious eye damage.






· STOT-repeated exposure Based on available data, the classification criteria are not met.



· 12.1 Toxicity· Aquatic toxicity: No further relevant information available.



· 12.4 Mobility in soil No further relevant information available.(Contd. on page 7)

GB

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49.2.0


Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water

Do not allow undiluted product to reach ground water, water course or sewage system.

Must not reach sewage water or drainage ditch undiluted or unneutralised.









· Recommended cleansing agents: Water, if necessary together with cleansing agents.



· ADR 1824 SODIUM HYDROXIDE SOLUTION

· IMDG, IATA SODIUM HYDROXIDE SOLUTION


· ADR, IMDG, IATA

· Class 8 Corrosive substances.

· Label 8

· 14.4 Packing group· ADR, IMDG, IATA III


· 14.6 Special precautions for user Warning: Corrosive substances.


· EMS Number: F-A,S-B

· Segregation groups Alkalis

(Contd. on page 8)

GB

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49.2.0

· Stowage Category A

· Segregation Code SG35 Stow "separated from" SGG1-acids








· Tunnel restriction code E

· UN "Model Regulation": UN 1824 SODIUM HYDROXIDE SOLUTION, 8, III



























(Contd. on page 9)

GB

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49.2.0



Skin Corr. 1A: Skin corrosion/irritation – Category 1A

Skin Corr. 1B: Skin corrosion/irritation – Category 1B

Eye Dam. 1: Serious eye damage/eye irritation – Category 1



IUCLID.


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49.2.0



· Product name: 7b - Group C Phenol

· Part number: PT-CN-C07B




LGC Limited Tel :+44 (0) 20 8943 7000

Queens Road Fax :+44 (0) 20 8943 2767



UNITED KINGDOM





Call CHEMTREC:

USA & Canada 1-800-424-9300




GHS02 flame


GHS06 skull and crossbones

Acute Tox. 3 H301 Toxic if swallowed.

Acute Tox. 3 H311 Toxic in contact with skin.

Acute Tox. 3 H331 Toxic if inhaled.

GHS08 health hazard

STOT SE 1 H370 Causes damage to organs.(Contd. on page 2)

GB

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Product name: 7b - Group C Phenol


49.2.0




GHS02 GHS06 GHS08


· Hazard-determining components of labelling:Methanol


H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled.

H370 Causes damage to organs.


smoking.




water [or shower].



regulations.






CAS: 67-56-1

EINECS: 200-659-6

RTECS: PC1400000

Methanol

Flam. Liq. 2, H225; Acute Tox. 3, H301; Acute Tox. 3, H311; AcuteTox. 3, H331; STOT SE 1, H370

>95%

· Additional information: For the wording of the listed hazard phrases refer to section 16. GB

(Contd. on page 3)

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49.2.0




Remove breathing equipment only after contaminated clothing has been completely removed.

In case of irregular breathing or respiratory arrest provide artificial respiration.

· After inhalation:Supply fresh air or oxygen; call for doctor.

In case of unconsciousness place patient in recovery position for transport.























Ensure adequate ventilation.(Contd. on page 4)

GB

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49.2.0
























CAS: 67-56-1 Methanol

WEL Short-term value: 333 mg/m³, 250 ppm

Long-term value: 266 mg/m³, 200 ppm

Sk






GB

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49.2.0










degradation



Protective gloves

· Material of gloves Butyl rubber, BR


observed.

· Eye protection:




Form: Liquid

Colour: Colourless

· Odour: Alcohol-like





· Flash point: 12 °C

(Contd. on page 6)

GB

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49.2.0







· Explosion limits:Lower: 6 Vol %

Upper: 50 Vol %

· Vapour pressure: Not determined.

· Density at 20 °C: 0.80001 g/cm³
















Heat.

· 10.5 Incompatible materials:Strong oxidizing agents.

Strong acids.

Reducing agents.

Alkali metals.(Contd. on page 7)

GB

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49.2.0



· 11.1 Information on toxicological effects· Acute toxicity

Toxic if swallowed, in contact with skin or if inhaled.



Oral (LD50) 5,630 mg/kg (rat)

Dermal (LD50) 15,800 mg/kg (rabbit)

Inhalative (LC50/4h) 83.9 mg/l (rat)







· STOT-single exposureCauses damage to organs.




· 12.1 Toxicity



LC50/96 h 24,000 mg/l (fish)









· vPvB: Not applicable.(Contd. on page 8)

GB

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49.2.0










· ADR 1230 METHANOL mixture

· IMDG, IATA METHANOL mixture


· ADR


· Label 3+6.1

· IMDG


· Label 3/6.1

· IATA


(Contd. on page 9)

GB

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49.2.0

· Label 3 (6.1)





· EMS Number: F-E,S-D

· Stowage Category B

· Stowage Code SW2 Clear of living quarters.









· UN "Model Regulation": UN 1230 METHANOL MIXTURE, 3 (6.1), II




· Seveso categoryH2 ACUTE TOXIC




· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 69








and should be used only as a guide. LGC makes no warranties or representations as to the accuracy and(Contd. on page 10)

GB

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49.2.0





















IUCLID.


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49.2.0



· Product name: 11 - Group C PCBs





LGC Limited Tel :+44 (0) 20 8943 7000

Queens Road Fax :+44 (0) 20 8943 2767



UNITED KINGDOM





Call CHEMTREC:

USA & Canada 1-800-424-9300




GHS02 flame


GHS08 health hazard


GHS09 environment

Aquatic Acute 1 H400 Very toxic to aquatic life.

Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.(Contd. on page 2)

GB

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Product name: 11 - Group C PCBs


49.2.0

GHS07








· Hazard-determining components of labelling:2,2,4-Trimethylpentane

n-Hexane





H410 Very toxic to aquatic life with long lasting effects.


smoking.




water [or shower].



regulations.





(Contd. on page 3)

GB

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49.2.0


CAS: 540-84-1

EINECS: 208-759-1

RTECS: SA 3320000

2,2,4-Trimethylpentane

Flam. Liq. 2, H225; Asp. Tox. 1, H304; Aquatic Acute 1, H400;Aquatic Chronic 1, H410; Skin Irrit. 2, H315; STOT SE 3, H336

>95%



· 4.1 Description of first aid measures· General information: Immediately remove any clothing soiled by the product.













· 5.2 Special hazards arising from the substance or mixtureFormation of toxic gases is possible during heating or in case of fire.

· 5.3 Advice for firefighters· Protective equipment: Wear self-contained respiratory protective device.


· 6.1 Personal precautions, protective equipment and emergency proceduresWear protective equipment. Keep unprotected persons away.






GB

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49.2.0




















· 8.1 Control parameters· Ingredients with limit values that require monitoring at the workplace:

The product does not contain any relevant quantities of materials with critical values that have to be

monitored at the workplace.







Avoid contact with the eyes and skin.(Contd. on page 5)

GB

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49.2.0








degradation



Protective gloves



observed.

· Eye protection:




Form: Liquid

Colour: Colourless









(Contd. on page 6)

GB

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49.2.0






Upper: 6 Vol %






· Solubility in / Miscibility withwater: Not miscible or difficult to mix.












Heat.





(Contd. on page 7)

GB

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49.2.0












· 12.1 Toxicity


CAS: 540-84-1 2,2,4-Trimethylpentane





· Ecotoxicological effects:· Remark: Very toxic for fish






Very toxic for aquatic organisms








(Contd. on page 8)

GB

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49.2.0




· ADR 1262 OCTANES mix ture , ENVIRONMENTALLY

HAZARDOUS

· IMDG OCTANES mixture, MARINE POLLUTANT

· IATA OCTANES mixture


· ADR, IMDG


· Label 3

· IATA


· Label 3



2,2,4-Trimethylpentane





· EMS Number: F-E,S-E



(Contd. on page 9)

GB

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49.2.0








· UN "Model Regulation": U N 1 2 6 2 O C T A N E S M I X T U R E , 3 , I I ,

ENVIRONMENTALLY HAZARDOUS





























(Contd. on page 10)

GB

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49.2.0






Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1




IUCLID.


/11



49.2.0



· Product name: 14a - Group C TPH

· Part number: PT-CN-C14A




LGC Limited Tel :+44 (0) 20 8943 7000

Queens Road Fax :+44 (0) 20 8943 2767



UNITED KINGDOM





Call CHEMTREC:

USA & Canada 1-800-424-9300




GHS02 flame


GHS08 health hazard

Carc. 2 H351 Suspected of causing cancer.

Repr. 2 H361f Suspected of damaging fertility.



GHS09 environment

Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.(Contd. on page 2)

GB

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Product name: 14a - Group C TPH


49.2.0

GHS07








· Hazard-determining components of labelling:n-Hexane

Gasoil : fuels, diesel



H351 Suspected of causing cancer.

H361f Suspected of damaging fertility.


H373 May cause damage to organs through prolonged or repeated exposure.


H411 Toxic to aquatic life with long lasting effects.


smoking.




water [or shower].



regulations.


· vPvB: Not applicable. GB

(Contd. on page 3)

/11





49.2.0


· 3.2 Chemical characterisation: Mixtures· Description: Mixture: consisting of the following components.


CAS: 110-54-3

EINECS: 203-777-6

RTECS: MN 9275000

n-Hexane

Flam. Liq. 2, H225; Repr. 2, H361f; STOT RE 2, H373; Asp. Tox. 1,H304; Aquatic Chronic 2, H411; Skin Irrit. 2, H315; STOT SE 3, H336

>95%

CAS: 68334-30-5

EINECS: 269-822-7

RTECS: -

Gasoil : fuels, diesel

Carc. 2, H351

<2%





















Mouth respiratory protective device.(Contd. on page 4)

GB

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49.2.0




























· 7.3 Specific end use(s) No further relevant information available. GB

(Contd. on page 5)

/11





49.2.0






WEL Long-term value: 72 mg/m³, 20 ppm
















degradation



Protective gloves



observed.(Contd. on page 6)

GB

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49.2.0

· Eye protection:




Form: Liquid

Colour: Colourless














Upper: 7.4 Vol %






· Solubility in / Miscibility withwater at 20 °C: 0.1 g/l


(Contd. on page 7)

GB

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49.2.0











Heat.








Dermal LD50 3,000 mg/kg (rat)





· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)Carc. 2, Repr. 2


· CarcinogenicitySuspected of causing cancer.

· Reproductive toxicitySuspected of damaging fertility.


(Contd. on page 8)

GB

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49.2.0




· 12.1 Toxicity




LC50/96 h 2.5 mg/l (fish)




· Ecotoxicological effects:· Remark: Toxic for fish






Toxic for aquatic organisms









GB

(Contd. on page 9)

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49.2.0



· ADR 1208 HEXANES mix ture , ENVIRONMENTALLY

HAZARDOUS

· IMDG HEXANES mixture, MARINE POLLUTANT

· IATA HEXANES mixture


· ADR, IMDG


· Label 3

· IATA


· Label 3



n-Hexane






· Stowage Category E








(Contd. on page 10)

GB

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49.2.0


· UN "Model Regulation": U N 1 2 0 8 H E X A N E S M I X T U R E , 3 , I I ,

ENVIRONMENTALLY HAZARDOUS


































Carc. 2: Carcinogenicity – Category 2

Repr. 2: Reproductive toxicity – Category 2




(Contd. on page 11)

GB

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49.2.0




IUCLID.


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49.2.0



· Product name: 14b - Group C TPH

· Part number: PT-CN-C14B




LGC Limited Tel :+44 (0) 20 8943 7000

Queens Road Fax :+44 (0) 20 8943 2767



UNITED KINGDOM





Call CHEMTREC:

USA & Canada 1-800-424-9300




GHS02 flame






GHS08 health hazard


GB

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Product name: 14b - Group C TPH


49.2.0




GHS02 GHS06 GHS08







smoking.




water [or shower].



regulations.






CAS: 67-56-1

EINECS: 200-659-6

RTECS: PC1400000

Methanol


>95%


(Contd. on page 3)

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49.2.0



























· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.




GB

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49.2.0



























Sk






GB

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49.2.0










degradation



Protective gloves



observed.

· Eye protection:




Form: Liquid

Colour: Colourless







(Contd. on page 6)

GB

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49.2.0








Upper: 50 Vol %






· Solubility in / Miscibility withwater: Not miscible or difficult to mix.












Heat.


Strong acids.

Reducing agents.


GB

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49.2.0




















· 12.1 Toxicity



LC50/96 h 24,000 mg/l (fish)










GB

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49.2.0












· ADR


· Label 3+6.1

· IMDG


· Label 3/6.1

· IATA


· Label 3 (6.1)

(Contd. on page 9)

GB

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49.2.0

































completeness of the information contained herein, shall not be held responsible for the suitability of this(Contd. on page 10)

GB

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49.2.0




















IUCLID.


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49.2.0



· Product name: 15 - Group C BTEX





LGC Limited Tel :+44 (0) 20 8943 7000

Queens Road Fax :+44 (0) 20 8943 2767



UNITED KINGDOM





Call CHEMTREC:

USA & Canada 1-800-424-9300




GHS02 flame






GHS08 health hazard


GB

/10



Product name: 15 - Group C BTEX


49.2.0




GHS02 GHS06 GHS08







smoking.




water [or shower].



regulations.






CAS: 67-56-1

EINECS: 200-659-6

RTECS: PC1400000

Methanol


>95%


(Contd. on page 3)

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49.2.0































GB

/10





49.2.0



























Sk






GB

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49.2.0










degradation



Protective gloves



observed.

· Eye protection:




Form: Liquid

Colour: Colourless







(Contd. on page 6)

GB

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49.2.0








Upper: 50 Vol %


· Density at 20 °C: 0.79948 g/cm³
















Heat.


Strong acids.

Reducing agents.


GB

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49.2.0




















· 12.1 Toxicity



LC50/96 h 24,000 mg/l (fish)










GB

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49.2.0













· ADR


· Label 3+6.1

· IMDG


· Label 3/6.1

· IATA


(Contd. on page 9)

GB

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49.2.0

· Label 3 (6.1)

































GB

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49.2.0





















IUCLID.


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49.2.0



· Product name: 19 - Group C Chlorinated Hydrocarbons





LGC Limited Tel :+44 (0) 20 8943 7000

Queens Road Fax :+44 (0) 20 8943 2767



UNITED KINGDOM





Call CHEMTREC:

USA & Canada 1-800-424-9300




GHS02 flame






GHS08 health hazard


GB

/10



Product name: 19 - Group C Chlorinated Hydrocarbons


49.2.0




GHS02 GHS06 GHS08







smoking.




water [or shower].



regulations.






CAS: 67-56-1

EINECS: 200-659-6

RTECS: PC1400000

Methanol


>95%


(Contd. on page 3)

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49.2.0































GB

/10





49.2.0



























Sk






GB

/10





49.2.0










degradation



Protective gloves



observed.

· Eye protection:




Form: Liquid

Colour: Colourless







(Contd. on page 6)

GB

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49.2.0








Upper: 50 Vol %


















Heat.


Strong acids.

Reducing agents.


GB

/10





49.2.0




















· 12.1 Toxicity



LC50/96 h 24,000 mg/l (fish)










GB

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49.2.0













· ADR


· Label 3+6.1

· IMDG


· Label 3/6.1

· IATA


(Contd. on page 9)

GB

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49.2.0

· Label 3 (6.1)

































GB

/10





49.2.0





















IUCLID.


/9



49.2.0



· Product name: 20 - Group C SVOCs





LGC Limited Tel :+44 (0) 20 8943 7000

Queens Road Fax :+44 (0) 20 8943 2767



UNITED KINGDOM





Call CHEMTREC:

USA & Canada 1-800-424-9300




GHS08 health hazard

Carc. 2 H351 Suspected of causing cancer.




GHS08

· Signal word Warning

· Hazard-determining components of labelling:Methylene chloride

(Contd. on page 2)

GB

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Product name: 20 - Group C SVOCs


49.2.0

· Hazard statementsH351 Suspected of causing cancer.

· Precautionary statementsP201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.


P308+P313 IF exposed or concerned: Get medical advice/attention.



regulations.




· 3.2 Chemical characterisation: Mixtures· Description: Mixture: consisting of the following components.


CAS: 75-09-2

EINECS: 200-838-9

RTECS: PA8050000

Methylene chloride Carc. 2, H351 >95%



· 4.1 Description of first aid measures· After inhalation: Supply fresh air; consult doctor in case of complaints.

· After skin contact: Immediately wash with water and soap and rinse thoroughly.







· 5.2 Special hazards arising from the substance or mixtureFormation of toxic gases is possible during heating or in case of fire.

(Contd. on page 3)

GB

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49.2.0

· 5.3 Advice for firefighters· Protective equipment: Wear self-contained respiratory protective device.


· 6.1 Personal precautions, protective equipment and emergency procedures Wear protective clothing.

· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.







· 7.1 Precautions for safe handlingStore in cool, dry place in tightly closed receptacles.








· Further information about storage conditions: Keep container tightly sealed.






CAS: 75-09-2 Methylene chloride



BMGV, Sk

(Contd. on page 4)

GB

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49.2.0

· Ingredients with biological limit values:


BMGV 30 ppm

Medium: end-tidal breath

Sampling time: post shift

Parameter: carbon monoxide






· Respiratory protection:Not required.

Use suitable respiratory protective device in case of insufficient ventilation.



degradation



Protective gloves

· Material of gloves Fluorocarbon rubber (Viton)


observed.

· Eye protection: Safety glasses



Form: Liquid

Colour: Colourless

· Odour: Aromatic



(Contd. on page 5)

GB

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49.2.0

· Change in conditionMelting point/freezing point: -95.1 °C









Upper: 22 Vol %


· Density at 20 °C: 1.32987 g/cm³




· Solubility in / Miscibility withwater at 20 °C: 20 g/l












· 10.5 Incompatible materials: Strong oxidizing agents.(Contd. on page 6)

GB

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49.2.0







LD 50 (Intraperitoneal) 916 mg/kg (rat)




· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)Carc. 2


· CarcinogenicitySuspected of causing cancer.






· 12.1 Toxicity



EC50/48 h 1,470 mg/l (crustacean)

LC50/96 h 310 mg/l (fish)










GB

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49.2.0









· ADR 1593 DICHLOROMETHANE

· IMDG, IATA DICHLOROMETHANE


· ADR, IMDG, IATA

· Class 6.1 Toxic substances.

· Label 6.1

· 14.4 Packing group· ADR, IMDG, IATA III


· 14.6 Special precautions for user Warning: Toxic substances.


· EMS Number: F-A,S-A

· Segregation groups Liquid halogenated hydrocarbons

· Stowage Category A


(Contd. on page 8)

GB

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49.2.0







· Tunnel restriction code E

· UN "Model Regulation": UN 1593 DICHLOROMETHANE, 6.1, III




























Carc. 2: Carcinogenicity – Category 2

(Contd. on page 9)

GB

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49.2.0



IUCLID.


Kit components PT-CN-CFULL CONTEST Group C Full

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Transcript of Kit components PT-CN-CFULL CONTEST Group C Full