Indian StaadardMETHOD OF CHEMCAT

ANAIYSIS OF TIYDRAT]LIC CEMENT

( First Revision )

F@nhRarrii SEPTETDEi r99z

ACwltE t ) 4

FS*€AU Oi9 tnBlilt s?AtEi;E S

: I

^*w;1?'"9lff#J3l'**( First Rerision )

Alil Condac s@tio!.I comircc'

Raqa*

","*" 3'"',#'*,"#*"**.W,*,x#e1g#"rgi-tWg

-";*t#;*-'-t'i::L;;-*---

d*-*- tt'"t "aifir,.j'* '"1 -

"'F*iifl%.,-. r c-".:"'

Jor odd' I rindr )

"T#:.;i-"*TeBdiii *)

il

srkrdr Ei4&dl4 R4i&h co,e (ctrR),

cdd rur&s Ris&i h,iu! {Gri),

( svD Dre! ) ( !rd,!)

lndian StandardMETHOD OF CHEMICAL

ANALYSIS OF HYDRAUIIC CLMENT

( Fitsl Revision )

O . F O R E W O R D

0.r rhis I'dirn sraidiid (Fnn R.lnioi ) '! idopi.d by 'hc Indiir

c.ftfl and contrd. sdiord Cdn

d*i!t adnnds to rh.

.en.ir rhi5 n drdloKri ndho

tiic rrcn lor Jdermird on ornftior orslrsn6 ltr rhi!E! ! or,,hs?(LDra) ndhods 'lsllop.d by Nd6rL

, FqO ild A ,o" h oldDlrv&'d rov

q s h i l l b c r o u n d < i o I i ' ] a . n \ d . i a r , hrs : r r$0 t r r rc 'd i rd o f s j5 i6c

rRd- G @6rq ird64ir dld ( , ! ! , ) .

1.1 rbjr sbndard sv4 lhc prcedurc for ib. chdjot !mly* of rbcdirdd! ryp6 of lydnulic &@i

r.2 ln rdditio! b rL. rd! ror d@jsl rqnirdob Fddib.d i!difiaer /d.f 'tsrtud'oD, thi :.ior ol Ii* [tu jn Ponhnd edr, pu oldiciry t.* ror Ponlud p@l.n'..dotandndnins16.lqu'oi'y6d!'

tl rn .drLr or rh. errt shIs: r3rtre66' r'd r6c i.leanl skidard spsifcario' for tl| ryp.

!boEsh'||b.lbolfugn|ynikdefocsiDs'

3. RIPRODUCIBTIITY OF RISULTS

3.r Bh ddqdiBrtioi' siaU h. nfu6.j!tbc4D.i.3idlhc.r,fuioIl all q6 cb(L dddEiralioN sir

pqdi ror sili.a,ndalmio.,3.d0.! prrccot for

Thl ditrdae t rq4n cn ct d4@iraliorr bv EDT Ddhod3hau@! dcd 0'2 pcn6r ror shim ond! ,od rasndir, 015 pqcdr Io.

,I, CHf,MICAL ANTLYSF CIMENTS OTggRIIIAN PORTL^ND SLAC CEMENT TND IORTI"IND POZZG

..hrtl b. mploy.d in tns, ,nd dis-iiba du ae ls I l0tH977l ) slnu b. c.d ttd. rh" sc ol -.E.gaEsd i l i d6n .d .of an ylidl H&d FdB 3r? iquirrd (#e Is:226r-le?91 3!d

tspdiddd rd,r@ tu Fd hM-tq !4 ( rdl,tu ).w(M drFndd d bd;&r ldldotu L&n ,xr6)-

lIS:a032-t935

4.r.r.r Iltito.hbn eid- sp Et t-t6 t c@fohtrg b Is : 261r976i )-LLr.t Nihi. o.id-sp st r'42l@\tomiq 6 Is : 25+1976t).4,r.8 &n hrt ada-'p er 1 3. lcorfornj.lioIs :?66-197t).a,r'ra Ptuqttt tid -tp v r.7.4Lr.5 Et*rllutic s.td, 40 rtt6r4tr.6 ,{M@tudE dtund. - sps. cgo,.,Lrt ar.tk dd- gariar.a,|'|.3D|.'hJhd|._Eid'a,r.t.9 Stn lninqn o.td-sotid.a.r.r,tr Ptutua wdodat sotid.

.:. 4.rx, Diu, sotabnt aJ R..t ,r - F.Fr rhl roilom* d'rrk $b-

a.r'i"z Niit cit -t | 1, | | t1lbt tufitu}.-\:r,t rtudnla hfln'td. -rtt 'd l:6(br, rcr@).{rr.. sltlroi crd- I : I ( bJ volue )412.. Pha$hdt ea,t : t tb.! \.\Nr).4,r.tc soa,w bdto'u. ntuioa -. N ( rpFolb'ktl ). lr,oln

i0ror,odi!{ brdaidc,n r00.orlord*ic [$red 4 raup 'o rh.

..rr,7 dterol- r r I (by rcrum ).l : l (b rv . lu tu ) .

r0 Fffi erlrd. wlid 50 s of

1,1,t Stafroa Chht;d. totlt6-Di$orr \0 ! dr *rroB.blor:d.\ . (sicl) ii r00 d or rrdrorbbn. kid and dlrGo dd i!c. x*p !

i <dbbd rirh rh. &hno!,

isFii&!6d6dldl!&).$ F * - i - G ' d ! ! ' d ( d ' . . ) .

a.t.t M.'tu i. chta'\1. sptql;on - PnFc ! $turnc'r $ru'ioi I 5 6 cor ndtunc cnbrde (Hscr,) i

1 ' | ' 1 ' o 4 o ' 4 . ' ' p h l r s a l u a o r

r 7) lnd 6J ml or srlphui. ac'd {sp sr I 11).

pertuigtdc ( KMnor) in on.lit of rv.rr

(NHiNor) i! r00 mt orrat6.

4.r€ tt /'rrll 0'r F!*rsolurion.

o:rlsk t( NH!), c,o,.H'o I ii o

Rtdtuse Phovtak satrti4 -

( BiCr,.2H,O )i^ oor ritc or v*{.

r < H . o l i 0 0 , d b " ' { . ^ o , l r a o i ' . .i , . d s ru - f rd ' u . . 4 ' l 3bo ' . 0

1.r.r! hiti satdbn - tE 1o - Dir5orv. 70 g or :lmoiun .ilorideii 570 hl orannoird hYdroxide(

x i d ( r . r J M a r . ! p h L h .

r h a , o r u ( : r r

60.c. ndd 50 liB cric.hroceBra

0 0 l N l ' D i J o t k r : [ d . I y g t i g h . d

ril lrhc.olour.h.nes tm 'nr Ed to cl.n blu! Nokrhc volucofEDTA6.d ( /) carcuhr rh.fo

Moh"' of EDra = 'ri-:

Adju{ rhc ror&ily F 0.0r M, jf!4un.d.

Lr,19 Thr\o! Phthat rc,. hltbda1

a.\.rn drtnot Bb. 0 l p.!dr solution in dhvl llcohol ( t///).

. i i . a r b k ( s e o ' . . r . t r r , r b L r J o b .d : ; , o l o o ' 1 1

Pddtlosotr isinio! - tos ii P.jsit x r00

r , . ; . 0 o l . i o n p { . t d L "o . r ' , t ; , i l i ' _io drYeson r sdn.br'h: t l ' ' b l b j 0 d l o

;r LoiDkE Dilut 'ht slttid widolnii{.t nhd ttuou8h mardl*sfrr'rFpq ( wbiEa!No,l0orjt

?qdvslmt), ahl *rh iltr *ruiiled sili.r ( sioj) trD,.ushl) lirf rr'

w d f o ' ; t r n t u j . 0 r b r l o . I 1 1 n d r r h . ; . d l c q . , h 0 0 I ''d of hvdrehrolic rcid r r : t ) rnd hlar rhc $lution on wder balh orho!ebr;. Dil[. tt. loln on $naad *sh rh. smsn ,mond of silio it @obins .i atulbtr rilrd Dr@rR.gv. ihc fltaie lnd hsiiics lor ibc ddmiiiLior or llnbin€d ilF

r u b l . ' D D d d ' F k . ( p p c c

I I00 'o | ,00'c urilrlrc leiahL r.mJins cornrni.

a1,l Trat rba iFit d rcsidr thu onbiied, {hich 'ill conhh sixu

c o a d . h ! i d 4 d " d o F o . * r p r r { . t d I d . n | . ' { r € r " r l / r od@.s. Fdlly na' '}c q'0 'r,dt'o:@laidwach'ol jsnir.d $nplc cpresc rh. amub ot sili6:

Si[ca p.r€n! - ?00 ( ,/t - t1)

% . *.gh .I i:[r - ( ir,olubL 'Epu'rr! rrdc r,

rI-v.jgh'ofinpEnies

r6D rhe Gidu dedrd fron rbe onbin.d DrcciDitrt6 of !luri!! ardGil ic oxid. is irdiBted Bd* 1.3.5.

1,r.3 Add 0 r sof.odiJd or tsrj:h F * phik b 'be fl r.bb rdb i d u o f i n p J i ' : F i d ' o l ' e J n L \ !

@h cooL dlslE L'r rccd m*s in \:E! dd add i. ro rir frltdc rndmrbbE i6ned f6 !h. dd.m;inion ofrho conbin.n snhixa and nidc

4a,r T. rh. 6ltBr r*{!ed in a.3,2 vbich rhdl nav. a volm. ot 4@nr200 d! add a Gw drops or 1be robyl Ed ;disbr, xnd har b b,iiriisiddq z r.v drcF ol btr@i! @

e r o i ' o l f o t d - o d j d n o ' f h oder *i1! aiiuiu hydiojde ( r : I ) dbp br droe udl rh. oloE df r!.

picciDilr. 10 senre ( whicrr shotrld rrdr dc iorc ih$ t ninur.s t flbrF ( w \ ' . i \ o { l o r

i $ q ' d b . L o ' J ! L L r c ' j @ b . '

chrdli. r.id ( r: r). dirub rresorurio! 'd abour r00 br 'nd E o(. oidc'h. hldrord( . s NoE ).

lh Dnr,c elu,ion conbinc dc

ghd pldjih duciuc, ner :loqly

. d n . m . . - d r - * h L b . ! . d ' , a '

1.1.!r C.k4tdbt-ctt$ttt the pE!rla8. oi conbiled f.trkondc rnd i dmnrbr nutdplyirs ihowcish.n,shqs orrh. ilsidue by ?00( 100 divdcd ri $tisbr or s.Lmph Nd l:

R . o | p . E . D l . | Y , i g j n o r . t s i d t r r ' 2 0 0

.*it\l dro.olMtr' abot5dlol

c s r b : e . J . ' ' r ' h " q . i F n P ' w ' .

odr hLod) . b ars B 6.r b . ! " d o k . : d d 0 n d . d dnsor@:'y ,da rr E

. d d d o l t ! o d u i i i ' . v i d m '

v*$l *id wdrr, ahd idd l5 Elo

vnh raldard iolurio! of Fhs5ium

L52 Mdhan 1 \ EDr,l M4rad)

4l.2l P!.pd.6hBb rs si!.r iD 4

4 ' ' 2 ' 2 T s t . ? J ! . faihdiun hydroxid. ( L 6) ti! rura ni'imun amotrr ol dirute hydrocrbric acid ll,101!'d ldd a fc{

3dludoDqlcful]Jtoa@ldglsso!p:ley.l]oalolutoD

r 'n oto 0l M EDTA=0'933 ns ofFcr or

trd ono.{ r.r ch ) Fror 6 --t

/ : volMeotEDTA N.d in nl, xnd

J . s l ' ' . I b . . ' : . J : J q l b L

loud uDi{ 4,a,3,

4,6.1 Mdhod 2 IEDTA tI4ror)-',ftka 2J nl or soluddn csned

da ieD i \ o rL :o Ad I dd !s6dqc

rs: $'- l93s

ph fc rod ( | I Jedd .d 'opo f rnymo lb lu i n ' o t h . t r t r&bn n r l lAdd B tud um r;bb hlDld 6v srinrs url th. coloL, chr F L.m

ih aaLk m .,cr roobm:n rHaeN,;nd.ly 5 H€r rh. blurion b boilrr ro, on. n iruk md 'i.q@1. ^dd l0 ilg ot Ftd al4ol odr& iidsror rnd bndb 'iE.iol ujor dovly 'iln siditrg trD rh6 6lou or lbc orLLior cb! F io by.Uos ror..d. Add z b r ol orbsnu.6 niuat,hdon t ac+. T:rREvirh 0 0r M EDra slul6 i. . d 4p y.rlov6d r.iDr rcd cohu.

4,5a1 c.tohnbn- ciltular. rhr pade3. of,al Or G b.lor:

! -u1 y '_ ( t 1 t E )

/ = Joll$ of PDT fo! alumin in nL4 - robr wruo. orEDra qd i. rh. riu'uon r mr.v!- volM.of EDIA u.dlb.n@ Ga4,5:2)hml,%- Toral hluc or bisurh nihrc sdlurid B.d n rb.

lihtion in d. udr'- rquiEl4e of l d.f badlib !ir.h olaioD {g.

Nd! t row).l nl ofo{l M EDTA = 0 509r ng orAL o,

Armiuiu qjd. ( Al| o! ) e.@' - :=:-

|/ - Wcisht or rhc spL i! s,

4,1.L M.tttod t lct Etutt t{4had)-acidifr rn @bin.d flriBK de o.dE .M,l rri h,do.llorcorrbou mnL ^ddao dorsrrdrd brolretuhb r!. bd elo@dd jturdilr.ry {dd rmoniu hrdroJd. Ellrho soluio! n tn:t dly

,r!ali!.. Eo rb. sdruridn lor r ninutu d norc. mLirp c{bh lhaihi1 ' e . A r r o q , h r F . i i p i ' k ' . . ' e j

did ( rJr ) .h'r hs be' prBiocry

r . i . d ' 1 J n r d . . d 3 0 n l o f w J n5moiiuD o*Lcr $ldo!.l m o r n n h J d ' o r i d .

r *ilho(d'oirl rtr, couiz rh.d r , r r 0 s h u P l i 6 r . d n - o ' ! h N h . ' , r r h 6 F , N o . 7 o : 4 L i t i r d ,

s, rsid. ri.6lrnr.and esbinB ro! sriDrjns EjFdh.

6 posibre, and tu?lry her vi'h rh. m.Lb,. id{y sdcd in aD defEdsrhr. 0I t 100 ro I ?00rc cel

i i a d d r 6 , . ( , o s L d 1 3o , i d . . ) n d w . i s \ _ \ i 4 r c ' d o ! l

d-" (c o) b' :00 tr00d.vd-d or .n.pfl3br or srbpr. &d ( 0r s ) Iclo FkDl ' '.igbr ot rsidu. x 200

412 rrthoA t tEDTl eiad)- Tard l0 n1 of eruriotr r$ .dudd 45.:.t i! r l lcr otr(h. iaL Add I bl or i r.!Got$ii

e q.u b !djr,, pH b hsr v .t..{il.

car.ru oiid. (crol FBir =

/ - volb.ofEDr usd in !r, fdn - wlish! ot rha Fbplc io s.

4A1 Mth.d I ( e4vn ni n4h.d ) - Acidiay the nhhrd *t sidc

nud bdrcsfr Ph aP! r \ r{ gir)

Add rihrnim hydorid; rrci by droD, while $ni!8 conrdly, udl th.

r€ r ! r ' 1 . , ! l L ' o o i \ e i l ' i o ' ) ,' Lm in1s . Sq ' h . { ' i o1 i d . ro r

No. 41 frk* oa@r q ns .quiv,'rdr vish ib? prsipirdc vnh iEno'imDnftr vtrh sorudon ( r00 srEidniuminue dlsolicd i! *i{. x)0 mrot i morilm hrd ondc ;doed 'd d'u.d to ons Jr.). P' k 1 3J ? L h c d p - U . u T n u c | o ( ' . ! q | J . n

i n r D ' * r ' ' k ' l | ' 0 n ' d l & 0 . c l o o $ ' 1 4 'v.ighhliicq'bbdoabingingp o d ! ! r . r ' h e $ . i $ ' o i r i F R i . r vf r o o r , 0 r d 1 r , - l , [ & ' h ! L o s , s L

43,11 cald,c//o' - Crcuhi. th. p.

z - ghns of 6ide (M3&o'), ald

i f d ( 0 5 3 j 3 1 d m l r , p , . db y l 0 0 ,

.82 vlhod , tEDrA r.,rod)-Tal. r0 ml or solDlion rc$rwdrrdq {.s.?.r. Add 5 ft ol1 :1 lidhaidrmhe rnh b'noi shikiD'

f t d r E i r ' r o m l l f d i l d w r k '

g ' { ' h . . J n o ' ' ( ' n F ' ' d

d.id. k obkinid by $bnadirs 1!. rn( y{le ot Qldm o:idc rdn rh"

.'3.r,r Cd.lrox@r - Clhuhte

{ ' . th lo roo l MEDT0 0 1 0 1 7 , ? 5 , ( y , _ / )--F-

v - volm of IDTA uscd i! cao ddcmirarion in nl,

.d riprolly sdd ro or b/drc.ho'nn ind Find rhc narerid wnh trnd?d

dd or N gltus iod urll jr is .viddt lnd rh? dlMFsnio! of rhe eDn!o r0 n l Dd d ' * i r o , i )mr r ' 6 { i

'dpfl-,rcj6' b.lav boirng I ntr /nd qlh .bc re,dk roroqh.yr FF *nh $c Bi'rE Ditur rhc

LoL b r : r cb to i , r . ( t 00 s t ) o t ,

.' Fera'hrr o,.micr'. r h u e F.ierbr $.ord " wr 'b. . t!. 4)b .FE ip 'Lk tbdo lgn |JP l ' . e lh .

holt irganiis rhmiFn. ai 300 rodsidr.. sd wdd rbc birih 3!rph4. .tuine4

arc'r{. rhc sulphuic alhydride 6tu'. of rb. nddi:t 6letr ror 4e

cahuLG ,h' po.EhgJ or sq q fo[oys]sO. p.rc. = rx 34,

n/ - rcithl or rt.id& ( Brso, ) in r; ardJ4 r- nol*uhr F io or 30, .o &sq tfiOj, EL|1pticd

o .hc , ! .o ru , .o , r r3 b , .d , jE r

cool in r d6ic6&r 3!d *.i*b-

o n d . _ T h i s o . l L d d @ t l b .

4'11.|ko'dkedMo|.li']'leiak 0r? i.qutdl

! l14a,rl12 )lball oluin notmortdio00zopdft'ltokls|kdks3tr|Dbilc'E drcchhti artdlHc\l <r! st 1te ) 6mdtr.d bytuclhin

PctuiM choru. I K.t )rodi@ c,vorr. ( Nacr )

41L1.2 Prcpatatid ot ,ohnhr) cdhi6 chtdtd. sbtk sohtid

of crrciuD erboD4c i. a r r00-nr bekcr. whiL nn*,s jo*t,dd roJ d or byd.ochlfic !cid, cool rh. soturion ri roo4

ro 61 000 ppo( 610 p*e!r )a c trm old..tr) sodih chtond..Pabnin chto'id2 sto.k sotutiar - DB&t$

(bo rhd ' rd . r0 r ro I l 0 " r ro r f . . . ! r ho r ! i , : o . b , . sb ry lin mrr. Dirur to o!. lirrc iD a votum.'ir 8sk aid dix

( o r 0 pc@r ) 6.b or sodim oidc) edndatd \ahtb4 - ?rcarc thr ,

r.61. ( ?-\o.). M.r<u! rr. rqw.,l voui. o. roo{d

c'ro ,oe .r cr btu, od ;iy M

h6 irdicard votuD. 'nd sn

' a h 4 ' $ d ' I b . n ' d . o f l h i ! n . d { . ' l }FlycrbyLa! irviir a wlu lbickn$ of ar l4r oDc lm.

y d rL. rtutrua4! e{{hdyd<rdbt

4r13a Frcinqaf tE turb4t -

{Ndro , . , d ( . o {o re r rN3s sudid s,op.

u l c io racha lk ' l i d i i desba ! !o .

amd(r$ ( ' .. No,c )i

i o 4 q i . , r c o . d i i , b t v ! , b d , ' I . . ' , 4 _ r . L n . r

a.n*dly r-i. JlDJdd sb!!ta(c.dxice,nh rhe.rocedrc Pys b.6;:

r l . F o l e . ' i u r . 1v i , h h - , . f - , L ' a ! . ! . 1 ' d r ( r n n , b i f o l o m , u F !

1 r f l . r . A d j a ! | F r ! r d o { s n o r

( N , ; o r r o r i s - ! i \ q r b s

orEilgd th.p,.vior y d4.m ddv dh- 5djb'@m t. hd-n"r

d ro, 61o b{n.mdr, *ld the roF 6f4 fo. sod.'n did.iGnno '\.d"rdFriior or

i!. Hri@stod!L ro'son ot rh. erJm-e4 soluion ( $lution No. 7 ) 'trd frovfg

n d i d a d w f | t r s l b ( k " N o F j r oof m' m@ krnsi5ion*Ehrsrh slldor i thr piDt Th. sdsirivit @!tdh shouldb . d 6 s b d v - i b o u r e r F G r t

r okr4d d$e 4 6r Ddr@ de ( N.o

1yp. sioniz* rirs 'irh disrilLd

$ LLion No | ( r00 ppo) . d ddjri d"FoF gM d $\ir'q1 ootos b pFqd. tull cL 'qdi'F{ @.6 rdding or rco q 16'0 Fcdt rrbrbitrft. r.

{} AEhk rro&d P!F). Pq itrr' lodB.ouDyd wirh r krorJiNos rbo;; For d,,rud$Rion

' ' . ' d - L . t r R . F | ' h !(r)nd,, m rLnr'd d.i'ni'v q

no rd,amat uc 1.t&,iyud un ( c ihe india&d niqilru tu@jtu€ ) {hd pi!3

rr arol :q ,udd!'d $ 'uoi No.2 ( 75 ptb I !r d rc'e 'h. rr!

{DdiLd .oluuon

niaaud ) 1trd r00t o r d r r t u ' l € b

IS :'1031 _ 1c35

so l i i onnYbe tun r i& r td

prcEdtm dddbcd b G') od(rr u,d r.Lko rbihdftidhi b'bc

lr) Duu@inc xrd5 0 , - , ! . 0 ! p '

j) Rep*r tl'c dthe pro.eduE dH in (b) ro (l') ror pobsumo id . ( ( ! o ) m* i ! 3

4.\r.1.1 Sddian of .q.^t -Ptr@ r 000 + 0 001 g or rh. smlir

,00-dr vorh&d fl6( wrh-s.*{ edl $ l b o i u g l ' W [ h o t { t { '

irrhc soLu'ion rhoro!3hrr (!g NoE

4 . r . 4 . 2 P t a ! . l q d " . F t l q v a l e a u 4 a , k $ , . F -:djsi rrr H:Lffit ror de d.trm

r.di's I f" No( r l

uifg mli&dioi or$. aeE u's rrrbr' rhe orti'ar c,Llbarion poi i5

q @ - . . ; . * - r ' i o ' t - - ! o r 0 i r

a.tt.a ! P x.dr. h, d.r'^nu.h at ph,Ln ovJ. otF \er - d F r e i ' , 1 ' n c i . \ I b " . i . J

lor pors'iumonde rnd sdiun dt

conr.i ol wr{'elublc alhLi or rh

?r0 n dvdd t r.€ Nrc )h i d n d y ' h o u g h a B N h * . 6 t |

6 r - . . b F a J

t s :4032. t93s

Hc l -p F r ' ro ) .

8xsk. Dnr.io 500nI.

v tc a ! r . add q0m. o r r r . ; o r . c c r . d "o ' I b ,m0 pDr . o l. 00 n . a : r , r d o , , u . r L i r r , ,

"

of cmh alkrti ii dc sdluiion in rbc | 00-Di ns!

Nrp, ro rbc i!r6r 00l r fouows:

w.s!' d!5.L _ 4,

n ! p e . d ! 4 N i " o r d ! l ! l ! i @ d d l

^ - U a r ,

- !tlrg',e orud-$tubtc sodium oiid. ( N.,o )i

: Fns.Fr nlrion otNa,o in rhe r

- F.d! or wif-$hbk pob$dn djd. ( r{to )j- Fls p.r duon or&o i! the r00-n ns*;

5.1 obid rhr. mdhods or icn ho? bqr d6d'6ed ror dctrrung

5.''|.|Abfulut.'hand_^6s.|||

52.1.2 o!.cg"r - 6rr(d sbrll b

or{rq. rlor.ri slyeror srhlL b. r.e I'onrcid c ofrLd.hydic nrtr.

5.,'1'.PAao]Ph|h.!.hh|]i.k.

shourdbc srishry rlttine (se Norc 1)10$ejDdcro!. lf,l '.sDlvln, is

v h ric *xxdlrd anDolih rcd're s.rurior ar- 5,t.1.5)l'd rbb 3ddn | ' . | u | ' P ' ' , . o ' o d l o ' o d l ' H a '

L n d " o . n . - o .

n l r i . , , , \ ; . . - , o ' a b e ' f o L l . i t . o t . 1 . . I J r b q d . o . ( f di ' t , h 4 b . o r . ' i g h ' | J " ' d ' . ' { d ' ' o L -

m l t d - d - ! d , . r n ( . . 4 , ' + , J i i i r . r o n r a . o 1 d . . . a N o F 2 )

P d d i d i l E r ' ; p s d i L o " ' r

ro r r i r ia rn -0005 s .donoJtlg i Prarie rhd srulio' bydnsokjrs 16s ol crJ5kriDe rnmoDuna@hG {s' Ndc lii on. Jnrd or c

,r 900 ro I00ec1o doosror *eisri, wh€D,he (h;€d cx!.lh oiid.

e ] e [ q ' ' l ' c { c lr , . r a J " 0 r r ,lhc flrk rke Nor r).

cond.Nr{s. Nor.2 ).

@iun rdde blqjon. Rlpke r,:.

co.d.ns.r and 6oil th. soluiion i3(r., Nok r ). shakerhe nrsk ft.q

boilins l hc r txion is conDlde phd' m funhq

n,!k rnd proc.d n rhedxndir(ioi {ee5.!.r.5) thevh.r the conia! olle cdcildoiide n rhesnple do!5ioti4{ar btmln!h!! 00j Frcar dlringrh.l

T h c ' ' ' | . ! h i ] ] b . f u C h o 8 l o p ' i ' ' . o n p | . } | l ' b l o L A h T ! ' ' ' ' ' ' ' ' '

$au, clmn, 7s-fridoi ls snv6. cri!,r $e rsidui D x! rs4c ion{ B!i | i s 6 ' . d o u g h t d

s m p L c n 6 n . s o q h b p ' $ o n p lhiiaor" si{ tor r!. d4dnira!o!.

r ' . 1 b . d o r o d . : " -.n Jhi .F r d .,.r ,t ;

solmioD aaie .ach ol r[. sdy lihuois.

b s h ] k . l h e f l [ k v j g d r c s l ' a l i n l avisorcsly ehih n isdkcoi..dcd tro

' . , 6 . n - i o i o . * 8 r . , . ' s o r o e

r d'opof6e phmlPhrbal.ii indiq

hrr !:rxof50hnidD,diorhs *iy !o

t . ' A . o ' l d a ' A h ' | ' F 4 ' | ", , i l I , , i e d : . . , t r ; - i , . r r d m i r . . 1 . K

wnb sidihr coDrtr$ in ;orher nsk*hi.! eDiiils an srcs ot amoriuD rera&.

n&q add j6r @ough lqnoDium -cd'. ro d\cbr& lh; oinl obu! and

sppcr rhe fask !i$ily. whd ro.ri4 rhc dcrcr

3.2.! .a/d/or'd - CJI! LLk ,h. F

Fre ahiM ond. ( cao ), p.l@r - rtl x 100

cao .quiEtnt of rhd aoooiib

,Yif;"r""-t- "*"".t'5!3fi}uol.c|'!.dnrlidM.l[.d

5. r1e4a, - Tbc tolo{i4 Esdr aE r.4uirtd.33.r.r ph.rctphthohhkditut _rfteaF dc ildioro, as d*cjb.d

5'3.':zclyqol-.|hondlsdhd|_PEFElheso|vdtasdsrtib.dsdcr 5.2r.1. Ei!h* rnl,ydroB briuru.d ra r{cldar. rha otutjoi of tre .rhiu onde. rmhydJ.b boriu

60E j o r { r v - i be fo r Lh !o !6 , i . , . u1 -L4o ( .?sNok r . t . . od , t rnr \ . 0 , , r ' hn co L i "_ s lEu d ,d

tGh / .p ' . p . r rd a r rm o r ide o .adC- r . r ' hc " l ns d f rh . , r .md-

( r@ D r*.c ) 4 &.i &hlo: id. o

e l , r d ( 0 . 2 r t _ P r c o r f ' n daftlatc rs dddihed udd r2.r.5-

l c i u q i d . i d i n k d q P o n h n dc@ni.sd.qib.dsdq516jng.hro d.d rn "dr.r"or (."sr

or t* slcilm ord. doa,d o ft."*by @r than 0.0r Fd.ar duing lbc lrn hou of boi14 (r?. No'? ),

533 Ccr.,rcr,n - Gr.uhre ihl pq@bs. ot frE ahib ord. &

rs: {032- r$5

5J,a x's,r-Thjs ndhod hsa tmddcy b EE bjgld i.slts hrthc idnod d*qib.d ud{ sr.

5,,r &bn@qr.ot Mdr.ds,,rj lne dlyLncsqcol dhod n b 6. B.d o'ly ror *ii{riig fEc

line in lr6h clintd ard frahlt

5.{.2 n a!." - rhc rollowioer<

5,.,2,1 llhyLn. sly@l sneu ror donbn oore tnan d. pendr ol

Td .J0n |o f { l b l .D .3 l j olsoauislrandshal.dinldYalsrurc A sEnnh'blle @lou indi6tB l}e DBdr.f watfr and th.

Irrt.olouft only rabt sa,, n indicr6!h' rh. srd .olrdi it b.low qe pb . l owon .Fc .d , i i 6Dbercmo\ tdb ,d lpd l i onb 'ha l i ng 'h "slyol b l]fc for I .o 2 hou6.

113.t Rntuttal yen

in 3od sltrdon. in aquous $luri

t.nos5.4.23 stvn'll hrdtochtoti a.id -o r N-

s-aj.r 1!}. on. san or cedcrrr0o dr 6D,ciry ad add i0 dl ofcr[rLei! dyor. cb{ 6. n.6k qi(h ii srk

drainn o:id. i o sorutio!6d ro 70'C

"d shak. rnc n4L vi

' F t t r t h o n r o r o n gtr riuv %.6 drd .horc.cbl d ed rs ' lJsl ! 't !s ' b iaft' n.(ndi lrcdblrB Moro*. 'h. eddHh'o e8r.dl n 'ur r pu.Nddtn rc8u 6nd.8do! a mtr bsth * 60 to 70'c. Ir ,ht.vdr ot

dom by adding pu'Bt *,krft@ Edh.nol to th..rbyL'.3tr6r ( {t

t 5 c orfom* b r0 e of lafa ) ebd oD boilirs L. o.]bdr rd o!! tou!udd rcdq d? solniion is Eadr ro. ritrrid.

5{c B&nnq l@n.l so filtr PiPdr cldg.nhichd sid scbull No. r97 's.r

ln! .ohiio, I'dm 't.3 r^ qncrb uItd. waih lnc crai o! rlrr P'F

rh. r 'rh a lu d Fn o' orrDcol rIq filrd,ior!sa60 | N hjooJlonc .cid Lrs J dro6 of I pc!6r bromq..lsRn io lbsorrb dohor * iidkro'(x. Nq.).

5..r,33 CoDdd rhlmk deiqni'arior sirh rlom qudnies of€ldM oiid6 by dLolving b slrcdl rd dtriins isrjDn 0 r N lydro-ch ]o ' . e id4b . .o le

s,4,1 C4rnrrcrbn c:b'nac {1. D.

b h - d 1 g o f ! \ D o lsldr L bvol@. ,4d d'R of

6. CHEIIIICAI ANILYSTS OF PORTI,IND ST"{C CEME|irI

se{ii sordioN _ rr.

6r-1.r ,sdrb ,i'n - nE Fed ( by y.ighr ).dt \ b' *ighl ),

6.r-1,3 Ph$ph.n. tE t :l (byvot|s).6.t, t.a a\rc4t@ rtnax t dh. ot4

n:m hrdtud. b'id dDd aiLs .o

094 sorFh$iun Frma,Bmi,. t I(Mno.);n oi! Inrc otRtr Allov

6'1''sldduasodiunThb'llphd.sohlia,.thc 5^ oi 74 s

6.1.1 Sta4datd P.tann lodak sot'd,, - 0'0r N, PEprE a solddon .f

. i ' n i o d d . r k l ) F l i n s . ' d 1 d i r

of vftr and r0 nl dfiydrcchloric icid in i J00.nlnsk. ldd rbor 25 nlnde srdioi ( 00r N ) svnr lhe

litl l io' uni| lh;Llidi (001N) D'iL rhc bluc corotr.

j L ' ' L r " " P " p 4

iunjod]csoluljongl',

phne solulbn Equn.d

slndardk{ioi or rr'. pod,iun iodic$14ior

or orc r ot solubL ihrcn in 9 ml oloforc i or sodih hr&oiid. in l0 frl ot waid, rb.n 3 s of p.rasim

6.1.6 Ahno"ta.ol zhc snlthat. solda, - D&solE 50 3 o f iic sutphat( znsorTlrro ) inFilrd rh. $lurio! lnd allowins n ro nDd for d les 14 hou!

5.rJ )rmnt'c'lco.Lhi@ chltiie r,/,ri,, - Dksolv. 15 s drddun.Lo"G (cdc r ,? lH ,o , r r l o m l o r %ts r . l d r50 n lo t nDon inh y d ' o i j . l . ' F ' | ' f r

6br,rc ( N !co,, 4!d rhc" 0c0 s or sent nior'dc (a,q)i o i 0 0 n l o I { r d ,

aooL it b rom hsa1urc, $8fd to i rct@t:c lsk lnd dilut ilro onc rirs, shndadiz? ihc solutio

.sq Fmdssrlb ( Krtrtro! ) i, '.

Fnmmi r ' 3 r ,1 . add60Tr o f rh .d l . r . n ' r r& rd { | 1 ) "1d 0n lof3:odiun nitit solulio! ( 5 F@1) ro rhd [ek. Eoil th.sluddi

roduD bi$ur\rkitrd I rtr br riude.oied @o-a dto

6,ri.2 cdcnr& the Mlgalic ond. .q nld1 ottnc 'bndard sodiun

- 0.03 x 0236 r 30"-----=-'---

c - @,canic o;& cquirlor dr rh.

.l

o = voh'n. in nl of Fil$iu rst d b y 0 ' 0 r g o r $ d i u d q J l d c ' s d

ite solurion n{uncd }Y r0

6 2 Los or tsdri0n Ld$ cn ieiiior shrll $ ddrnined i! leordrtre

6.r sftr - Th. ndhod 'br de@D

abih dnde srril l bc the sam. rs d6di6cd h !.ar..1| MlLod r( tDta M.,\aa

d v d , 4 r . : . r { i @ , . c r r r q , m J . . o r n 0 1 o n . r d i . p a l d, a L . l i r s ! . t a

o id .ik. K-P \- fl.

o r r ' : ' s . d r m 5 n o i d " h y r , m + ^ d d t o " t o r i \ . , . I

o l f i B t i o n n E l c h e d w h e n d n . t o l w o d . o p ] o f E D T A e h d n a j h 3 l p

6.3.r tdhon r I c,crhen. .ttdr,d ) - rh. mdhod tor dacmjiri!

6.3.2 u4ttoJ 2 \1Dt A q4hadt,ll ld ' r 'r n. olllo" o, d iro, Drr e ' d

rdd drop by drop l: I rndoliM hydrc:id. wnh @B!nr sh;rins lil la srbidny apFs Add 2 d n, c{6s. Filb rhc rolutio! rhronsh

pdpcr wnb hol wi.r 2 !o l iimd,

! t d e n q i @ i ! , J ' & , ' |

6.0 l60r!tl. Rsid&€rs dso 6.d m 4.r0.

r g v . i \ o t I ) . e . s r { d p Ii , d . r _ . f l t q o r o

75 d or dilukd iitric !.id ( I :4)Add t0 nl sodiun nnric sotmim ( 5 p.rcor )

L r o ! ' o b o t ' . d r r . \ i , t , ,

' r 0 n t € r t . n n . f t n 4 ̂ i , ' 4 _ , , u qThc soluiion sho,nd rave I vorum. ot 100 ro I]5

Fd+,64ds t@d o.:dhrd rqr!

c . : d ( . r . , r h c h

n r i c l . j d ( r : ' r .

yvnh lh. naidxrd $diu 4r,ii.

b ddsf;0aroi or 'n'ain.s, rhe h!{ sbrr b. cri';;r.d rruD .!c

!'balron by rhe ne rod liid dom 'n ir,7.r.

b , b . r rm . r .b , i J r ( 0 ra r j o r ' . i on .adr t i t , .F i q - r ro c ddpretdlbly oydf, i3l'r. Filrerthep*!jpihr Birsryh!6rn No, 42f h(Prp* or ns .quivrlcrip l a i i i b l o l p o t . b ; n o u i b l . , R n

' , l : y c i g h j ' g o . b l i h $ ' l p | n t ' b d

(o143 x r00 )

6,\t.r e$ ccntdas ftotk. r n o n . q b l r , o i r . . . i d .

, 1 i r r o r | . . { f ; q ' i . .

6,rt 2 Prcrt&f, - fl.ce r s nl or !hI Jg. Naic I ) rd 235 ! or sdd i

lh. fid,r $d:[-k rh. tu r 8dr/ 'owcr J'd o'l;cM rh- .!mm' omrlehrt r'i. tp d rh'Iollor nsoDC! | .N ' . l b .P fo 'm .d 'P :d | J rc rvrh. fl!*

"nh rh. funn;r ;d bilrb.

solution ibroulh rh. rdrd .nd shchloric acid ( a,I)rhrouch dc rmid dshakerh.38k. Dui!3 rh6.shrkincs, kep rhe amler clo*d an

3n, oF thc rumel srrt a slo* nrco u rx h .bo 'LT s1 ' t r o

or rh. hdi. aDJ otrntuL nc o-n*or..i6' r o' r E ' ' ' - D on-.6 .h .& rnd \ uR-0d k . r ; h m ihe d r r c , n Le . " , , ' r n c@rrb .5 . r ! . o o ?0 .o 10 .c a r€eNord 40 E l o r h ld o .10 r dc id a l{ . rd rdDo i . i ;EDd .F ouonu

t d - * ' ' d ; r B d " r - - ' d { " - i . r t

6,rzi ctt.utation - calrtArc $c pc(ds$ or s'lphlr a rollo*:

20 = I00 divided by lhc veidr or snple BEd ( 5 3 ).

. ^ b & _ n . l ' h k d & n 4 j J ' ! h d . 1 6

orii ' iu {rpporiLn.rlly I roLr"c ).,)dqui6e i ( ab{r 15,ri )

' o { l J ' . ' ' t ' \ ' ' ' L . i | r 'ovdrrr,rd{!id lolidi.y rs x tr' i i nrerlor rhc iftrid. scr th. *u. bLrrd

Rins otrrh. ousidc of dE (udbrc I or.ft rr

IS: r0rz- !e8 i

7. iEEMrca! aN^r.YsIs or Po

1.tr M.thad r I ctodEki r1dh,l) 1r ni.rrni dr rloruus

dssrbed jn.i,r.iccpr r 3iy iu 7,z,r.l b 7.2,r.3.

- . ' , ' | r w " i s l o '

wc i rLno r iF tud 0 5 ( rm00 p .Fen !s

1.2.t v.th"tt 1|ED lktra.!)-

d d j u D € \ o . , r . o f : 5 0 b l n " 6 l r r " c t . r . D d n n ! . r s 8 , . .

,.3 srllLq;c adydride -T he n rhod ror dermining srlDhuric hydrid.oI Por'r,rd @ol" d ffi.{ .1.Il bdur r\. -mpk Kd )hJLl b. nd',Lk 1e .i

7,,t ldehbl. R.id@-IDslubL rcidr or Ponl,nd pdzolatu (M!sh:l b? dddnincd s sp.cifi€d i! 4.r0'

3, }OZZOLANICTTI TFITTOR PO

3r Plrts* - thc pozoh'icily 16r fo' cn<kin8 pozol ic tufr

orsiddirior, owils td ds {oilibrIne dd rhd rlkiljs prsdt ir the liquid pha& in o xd *irl! rh. prns

3' lddier. - ?doloic rdiviy ddpdds !p.r rh. frxdion ofcr ( oH )i,d.edb,th.hydntionorrbc.cf.hydnb wholc rr4ab Lrcsrs vnLqciy i! 'cr{d b lhpa,rg \- q,r "y I c. ( oH /! nrc.d 'D I

$ i " ' l y d r , d - n , n . $ r h | . q u f i r o Ic J ( o H ) ! r p r b . o ' , i r , . spe2ol,r h G ro., 'h. c, t ori ',

3.at Elrlm6 $ov rLn by 6iig:0 sof ffi6! F r0d nlotyab

o r c . ( o H l n ! ! o d qlCo diuiquial.'$ of $rcne bis ( oH I Fr litrc.

h . o r m d v b ' c b b d i o F ' ' d G ' u )onpl.klyrt@dktbcliq!orh'drcl}si'rlomlh.bindd.

a

3.3.2 Sd otd E dn$htic A.ill - 0a N.&33 ,{,,o,i:,tol,rb, -05 N,3,3.4 ,,rot ' oralar. - in s rd.n sdluiion.

8.3.6 Potuitn P{nnctu Sohnian, O 0t N.337 Abo$ 20 s pr66n wax ( in .4e r slds 6mk n sd I

&4,r cui..] Fksk ar 300 nl i! ilkRl' r.skdnA sLss o. pl.crably inPhdis nl!*b! Nnh ! nopp{ of r

3.42 r/d - vnh vidc a&nr.t,{.r Frkl - r sinrnd slr$.3,4.4 C,r,cal r/o* - or2J0 m1 {ith grotr .e1s5 soppo.3.4.s 'klri - of 250 nt.3!d6 ?-.ii,, ?rdr. - ol r0 rnd 100 nl.3.41 fh{noit.th spft. ar4i + 2'c.

3.s,r ni d+a @niol shs flBk is used, od ih. iosidcofth. tas!'nb rbour 20g orr.!!d pr'si rix. Fhnlyarrdwrh.sqlusro$lidiry

3.5,2 Wiih a pipdq inrodlcr 100 !n ofdisrirr?d wierin ih. drst xidiito r rhcnoii '1 40.c

hpqd're ir Eicbed ( abour r hour I.&fi rhm p.nr inro rhc onior fm

l0 0o + o.0r g of!n. eodi i. bi r1 20 . i nd \b o rde ' o Fsc , t I h .

ro . tu ,do .Fn . r r tmnsi r { ) " c ,qq r ln -L ino J .

4!'C qu(r'J 6kl ' c lioud6 h l r o 1 c o o | L | ' " n q . | . E o e d .

3,5'5 Pipdk oui 50 nl.f rh? frrni.del.riin.lh. bhl.lrifi iny rglinn nandrd hydr..hbnc Gid{0I N),

r o . L r p r a ! h . e u x o n . i q i , h . . - k( o H ) F r u e \ o q

Tnnt1h.olciumon|nle

3.6 R6rlh - E4rcs rh. iohl .lxxhny od rie otdm oxidc 6d.ir' n l i ' o l l ' F l ' ,,L_- qo i Fe'6dros 'hc

lc''Aolinsitlidb.lowll'dsotuhilityircthfim'

Ju.'q foutud dr! ln rh.i ( .r 'oq br16lp.zolanjcacliril,lh.l6tbc@

9. STINTNC TIST FOR MISONRI CEME|II ( DM'RMINATIONO[ WATIR'SOT,UILI 1IIAI-I )

9-r.1 To 150 3 of snpL dt rilotrry e.dr in . !mo-'l bek{. add?50 n'r ot disriUed *xrd.

Firk. 'h oLgh ' Bshrfl ru n.t trJ1lrd rh.' n $ e b L L l b b e . i g i l

drifrclh.i'so|obleftn.islir, h @ ' s r l y , ; ' t u d r 0 D n i r o o T F f F ; , ' q r , d . u r e i ' F r r

wah rhe ru.el rnh r00 dl or dtri0.d {a&r inb rhe bRk r 6.eiiimi .he iEolrblc nds. sft rhqo4hly, rer ndd30 niidrcom&nF

Firr! * ibvc. Acidifv rlr fih4tc {irb I El oto(ol. Ed lvdrochroft idd( H.

a00 n. c@l o rconLdpd'u ( drd

"!,3.n q*di trh\ D 'T i l G f t '

" i o . q . t 4 D r o I r h i r c l q r c n r o , , o . @

r b . F r a h l - v d ! r @ ( e s . r r ! ! $

a

E E r

; ,

rP Dr*bu . Sn.@un dc(on , ^ m,

e,r.? Dd.hinc $diud oxid. aid

t y .1 , f l , r , 2 0 ) I iPb rb r r00 .nun .iide orbnr of rbi solurili .o

tur.slubh rlkdi riedih oxide ( N"o) b ib. ie'idr o 0r a: lollows:

, -B l t500c -D1 t500

ToEl *6iorubL rltdi:,{+,

i \

!

, -,cr6bs. ol ftla-slubt sdiur oridc ( Na:o ),i - partt pd & ion of Noro iu rtu $lurim i! the l00-bl

lct ('a 9.1.1),c = Frd&cc or mtd-solunh Do63i@ oiid. ( Kro ),, - N E oilrionot (,o i! d. $ruiotr in rh. i0dDl

dL&!L (Ee.r.r i. hd -

, -pddbgcof Nqo.quiv .i o dr(:o.

c.mst sub.onnnie, BDC ?: I

R-4M3 oEu { cddn

{ MbLrry dhtuq ), N.w Ddtri

ciryreiu,(Rsh?q). rrklbi D+'m{,, c@.hh4' d

11

U s,, q B,.rroh,1. (rrhi.)!nn,{Ei:id i:R-o\r 6ir,.. \rd,'

Ad rloc Ptrn.l tor co$idsinl EDTA v6hod ot Araryskud coloindrh AnlyJr !l ccn

h i 'iil,,i'-,

L

dld,N s o€'. s 375! 4e w

l k b n ] b * , s ' E 9 e N l d e o u 4 h f f i E a 5 r y b f u l E e [ e @ 6

'sdB otu t4scwhd'*&po*

l * ! o e E d b l y c i b B c l Jted 6e u df Bd. uiiv Bu6ru. N{6hh{!!a sqs..

lcmDn b d otunId9b

PGIFk'NuNbdsMbkq'ss

6d*d6r9k'56Fcd'gebefu

fudsrBu6s'dfoAuEdlFod'colMaArchE&l@

$ s ' L N a u p b f u q N l @ l y s b | qE*. ciuola Mrs. oscbm6 TATFUF om1l'4131'savd4aN@'uNPuFa&c

h*bro d Ei!ri46 ( @ ) &rdie s4 stroa! N4 PUNE.flos

AMENDMENT NO. 1 MAY I99ET10

lS ,1032 | l9at MFI|OD OE CqEMICALANALYSTS o!'. IIYDRAULIC CDMENI

( nta fJvt:toat

(?.s.4.r,6.r):h.nu.rolto*iryr!Nob ulJ:' |t6-^!!rLd\tnd!cDdDrtbrb'do! 'rdqr.b4h ldu ( E E tru.Net) ux nr eo@@r @ ! d ( G R r e ' l t i l o r c b d d h o r F ( s 6 r r r r , 'te.0..)r'q'dL[Lddr{ tu h*dcird!di4ed!.tdddq{.dr.d.lE!sdd

(Pq. a,rdd) - IFln ronodn8 s ro.lmb d rlt.nd:

1L'wa.;lu*tya"ur*"r'drhftqpro Fdqeb@hir Mdonq'r!drr,ndk€G"x.Mt@&.dhdE*ldltdl'JElh9@d'

&|@P|'UdL16,N4Btr|6