INVENTYS RESEARCH CO. PVT. LTD. Intermediates for Pharma...

M/S Inventys Research Co.

Proposed expansion project for manufacturing of Advanced Intermediates for

Pharma Industry, API, Fine chemicals, Agro Actives, and specialty chemicals

Plot No.: SEZ 14 & 15, MIDC Butibori, Nagpur - 441122, Maharashtra Pre-Feasibility Report

PFR for M/s. Inventys Research Company Pvt. Ltd. Prepared by Goldfinch Engineering Systems Pvt. Ltd.

INVENTYS RESEARCH CO. PVT. LTD.

PFR for Environmental Clearance (EC) of proposed new project for manufacturing of Advanced

Intermediates for Pharma Industry, API, Fine chemicals, Agro Actives, and specialty chemicals at Plot

No.: SEZ 14 & 15, MIDC Butibori, Nagpur - 441122, Maharashtra.

© Goldfinch Environmental Engineering Systems Private Limited (‘Goldfinch’), July 2018

This report is released for the use of the M/s. Inventys Research Co. Pvt. Ltd. Regulators and relevant

stakeholders solely as part of the subject EC of Proposed New project of Manufacturing of Advanced

Intermediates for Pharma Industry, API, Fine chemicals, Agro Actives, and specialty chemicals at Plot No.:

SEZ 14 & 15, MIDC Butibori, Nagpur - 441122, Maharashtra. Information provided (unless attributed to

referenced third parties) is otherwise copyrighted and shall not be used for any other purpose without

the written consent of Goldfinch/Inventys.

QUALITY CONTROL

Name of

Publication

Inventys Research Co. Pvt. Ltd. proposed New project to manufacturing of

Advanced Intermediates for Pharma Industry, API, Fine chemicals, Agro

Actives and specialty chemicals at Plot No.: SEZ 14 & 15, MIDC Butibori, Nagpur -

441122, Maharashtra

Project Number GEC/IRCPLB/2017/11/07 Report

No. 1 Version 1 Released July 2018

DISCLAIMER

Goldfinch has taken all reasonable precautions in the preparation of this report as per its auditable

quality plan. Goldfinch also believes that the facts presented in the report are based on information

submitted by Inventys and based on the technical expertise of Goldfinch as on the date it was written.

However, it is impossible to dismiss absolutely, the possibility of errors or omissions. Goldfinch therefore

specifically disclaims any liability of any form resulting from the use or application of the information

contained in this report. The information is not intended to serve as legal advice related to the individual

situation.






Contents

1.0 INTRODUCTION OF THE PROJECT ................................................................... 6

1.1 Introduction of the Project .................................................................................. 6

1.2 Introduction of the Project Proponent ................................................................... 8

1.3 Brief description of nature of the project ............................................................... 9

1.4 Need for the project and its importance to the country and or region ....................... 9

2.0 PROJECT DESCRIPTION ................................................................................... 10

2.1 Type of Project ................................................................................................ 10

2.2 Project Location ............................................................................................... 10

2.3 Details of alternate sites considered and the basis of selecting the proposed site ..... 12

2.4 Size or Magnitude of Operation ........................................................................ 12

2.6 Raw Materials .................................................................................................. 58

2.7 Resource optimization/recycling and reuse envisaged in the project ....................... 58

2.8 Availability of water its source, energy/power requirement and source ................... 58

2.8.1 Water Requirement and Source ....................................................................... 58

2.8.3 Fuel Requirement............................................................................................ 58

2.9 Quantity of wastes to be generated (liquid and solid) and scheme for their

management/disposal ...................................................................................... 59

2.9.1 Gaseous Emissions .......................................................................................... 59

2.9.2 Effluent ......................................................................................................... 59

3.1 Connectivity ................................................................................................... 66

3.2 Land Form, Land use and Land ownership ...................................................... 66

3.3 Topography ................................................................................................... 66

3.5 Soil classification ............................................................................................ 67

3.6 Climatic data from secondary sources .............................................................. 67

3.7 Social Infrastructure Availability ...................................................................... 67

4.0 Planning In Brief ........................................................................................ 68

4.1 Planning Concept ............................................................................................. 68

4.2 Land Use Planning ............................................................................................ 68

4.3 Assessment of Infrastructure Demand (Physical & Social) ..................................... 69

4.4 Amenities/Facilities .......................................................................................... 69

4.5 Population Projection ........................................................................................ 69

5.0 Existing infrastructure ................................................................................ 70






5.1 Industrial area................................................................................................. 70

5.2 Residential Area ............................................................................................... 70

5.3 Green Belt ..................................................................................................... 70

5.4 Social Infrastructure ........................................................................................ 70

5.6 Drinking Water Management ............................................................................ 71

5.7 Sewage System .............................................................................................. 71

5.8 Industrial Water Management ........................................................................... 71

5.9 Solid Waste Management ............................................................................... 71

5.10 Power Requirement & Supply / source ............................................................ 71

6.0 Rehabilitation and Resettlement (R & R) Plan ........................................... 72

6.1 Policy to be adopted (Central/State) in respect of the project affected persons ....... 72

7.0 PROJECT SCHEDULE & COST ESTIMATES ...................................................... 73

7.1 Likely date of start of construction and likely date of completion ........................... 73

7.2 Estimated project cost ..................................................................................... 73

7.3 Economic Viability ...................................................................................... 73

8.0 ANALYSIS OF PROPOSAL (FINAL RECOMMENDATIONS) ........................... 74






EXECUTIVE SUMMARY

Inventys Research Co. Pvt. Ltd. (Inventys) has been promoted by The Multi Group (TMG). TMG

consists of three companies. The first one focuses on producing intermediates (chemicals) for

dyes, pigments, pharmaceuticals, rubber, and various other industry segments. This company

has never made a loss in last 30 years of its existence. Second company produces specialty

chemicals for similar industry segments. Both of these companies are the only companies outside

China, to be able to compete in the global markets in their respective product segments. The

Multi group serves more than 500 companies worldwide. More than 25% of our production is

exported to western European, North America countries and to Japan, Korea, and China. Third

company, Inventys (started in 2005) with a focus on:

Outsourced manufacturing using dedicated plants for large companies from high-cost Countries

Contract research, process scale-up, and process optimization services.

For producing Specialty Intermediates & Fine Chemicals.

Inventys has already demonstrated ability to build manufacturing plant (with DCS automation)

for specialty chemicals, on a fast track. Inventys has now achieved ISO 9000, 14000, and 18000

certifications. Currently it has got one FDA approved plant (GMP certification awaited) and two

non-GMP plants.

Company proposes to expand the manufacturing of products in segments of Pharmaceutical,

Advanced Intermediates for Pharma Industry, API, Agro Actives, Fine chemicals, specialty

chemicals in the Plot No. SEZ 14 & 15, MIDC Industrial area, Butibori, Nagpur, State-

Maharashtra. The proposed project falls under classification 5(b) & 5 (f) of schedules listed in EIA

notification SO1533 dated 14/09/2006. Its appraisal category is A.

Project Synopsis:

Sr. No Parameters Description

1. Category as per EIA Notification 5 (b) & 5 (f) Cat. A

2. Latitude 20°56'44.96"N

3. Longitude 78°57'12.76"E

4. Proposed Production Capacity

Proposed Production Capacity:

Products: 12710 TPA

By Products : 1236 TPA






Sr. No Parameters Description

5. Total Plot Area 69025.55 Sq.m.

6. Green Belt Area 22790 Sq.m

7. Fresh Water Requirement 1452.5 CMD

8. Effluent Quantity

(Trade + Domestic)

Trade Effluent: 580 CMD

Domestic: 44 CMD

9. Trade Effluent Treatment

High COD & TDS stream from process will be treated by Multi Effect Evaporator (MEE). Treated effluent from MEE will be treated with utility blow downs in full-fledged ETP. Treated waste water will be discharged to CETP.

10. Domestic Waste water Treatment Domestic wastewater treatment in proposed STP of

capacity 50 CMD

11. Fuel requirement at full load For Boiler: Coal 72 MT/D or Briquette 88 MT/D

Stack height for boiler: 30 m from ground

For DG: 1600 Lit/Hr

12. Power Requirement Power required: 10 MW

13. Dispersion of emission DG Sets, 4 DG set 1500 KVA each

Stack 30 m each from ground

14. Work Force Total: 1100 Nos.

15. Total Capital Cost the project Total: 110.0 Cr.






1.0 INTRODUCTION OF THE PROJECT

1.1 Introduction of the Project

Inventys Research Co. Pvt. Ltd. (Inventys) has been promoted by The Multi Group (TMG). TMG

consists of three companies. The first one focuses on producing intermediates (chemicals) for

dyes, pigments, pharmaceuticals, rubber, and various other industry segments. This company

has never made a loss in last 30 years of its existence. Second company produces specialty

chemicals for similar industry segments. Both of these companies are the only companies outside

China, to be able to compete in the global markets in their respective product segments. The

Multi group serves more than 500 companies worldwide. More than 25% of our production is

exported to western European, North America countries and to Japan, Korea, and China. Third

company, Inventys (started in 2005) with a focus on:

Outsourced manufacturing using dedicated plants for large companies from high-cost Countries

Contract research, process scale-up, and process optimization services.

For producing Specialty Intermediates & Fine Chemicals.

Inventys started as a third company in The Multi Group (TMG). Inventys built a grass root facility

in 2006-2008, to cater need of its customer. This plant is manufacturing a chiral complex amino

acid exclusively for one large Europe Based Multi-National Corporation (MNC). The Inventys first

built a pilot plant in one large Multi Group Plant. After getting approval of the pilot production

successfully, Inventys was awarded with the contract for set up and produce the product in the

required scale. The manufacturing process has been completely developed and process

optimized/ stabilized over last four years of operation.

Inventys has built a small but efficient and cost effective manufacturing organization in MIDC at

Butibori near Nagpur. Inventys has already demonstrated ability to build manufacturing plant

(with DCS automation) for specialty chemicals, on a fast track. Inventys has now achieved ISO

9000, 14000, and 18000 certifications. One of the Inventys Plants has also received FDA

approval. Inventys plans to get GMP certification for this plant.

In these 10 years of successful operation, Inventys have emerged as trusted partner in High

quality reliable contract manufacturing of specialty chemicals & advanced intermediates. Inventys

has repeatedly demonstrated its world class skills in:

Efficient manufacturing with continuous improvement

While practicing responsible care towards the environment, employees & the society.






With Strong IPR adherence

fast effective optimal process scale up

frugal project engineering

safe plant operations

Inventys today employs about 150 people in its current factory in Butibori MIDC near Nagpur. It

plans to recruit 1,100 employees once the operation at this new facility and its head office in

Mumbai. Most of the staff is B.Sc. MSc. and PhD’s in chemistry and Chemical Engineering.

Inventys Butibori site is about 7 acres in size and currently less than 2 acres are occupied.

Inventys has already manufacturing a specialty chemical in the existing manufacturing area. With

this strong background and experience, Inventys is planning to put 8 GMP plants of specialty

chemicals. These plants will be of three storied. Each plant is assigned to manufacture specialty

chemicals/API/Fine chemicals/Bio Pharmaceuticals/ Perfumery chemicals/Chemicals for other

industries. The planned reaction capacity per plant is ~350-400 KL.

List of some of the important processes that shall be included in the plant design are:

PROCESS

Conversion of acid to the corresponding nitriles. Alternately

some of the products can be based on ammoxidation

Alkylation

Hydrogenations (continuous including high pressure)

Acetone based product

Oxidation

Ketones from Carboxylic Acids

Etherification of Phenolics

Glycidisation (Reaction of aromatics/ Aliphatic alcohols with

epichlorohydrin)

Specialty bisphenols (condensation of Phenols with ketones)

Amination

There will also spare reserved to build a Kilo level production can take place. Flexible layout of

the plant shall make the plant multipurpose and the kilo scale as well as pilot plant production

can be taken for variety of products without much plant changes. The plant will be controlled by

an elaborate Automation system to ensure a consistency in production. State of the art effluent

treatment system will supplement the environmental responsibility. The utilities required critical

process steps will be housed in the same or adjoining building in order to avoid transport losses

and spillage in plant area.






Considering this background, Inventys is expanding the customer and product base. This project

envisages setting up a new multi-purpose plants for the manufacture of high value specialty

chemicals and advanced inter mediates to be supplied exclusively to Global Chemical MNCs in the

field of Perfumery, Life Sciences, and Pharmaceuticals. Inventys plans to set up this multipurpose

plant at their existing site in MIDC Butibori, near Nagpur, Maharashtra.

Inventys Research Company has now achieved ISO 9001:2008, 14001:2004, and 18000:OSHAS

management System Accreditation. Inventys is submitting this application for a environmental

permission to manufacture a number of advance intermediates, different API's, Specialty

chemicals, Agro Actives and Fine chemicals. This permission will allow Inventys to change the

product mix as per the requirement of customer for custom manufacturing order.

As per the EIA Notification S.O. 1533 dated 14th September 2006, proposed activity is covered

under Pesticides 5 (b) & Synthetic Organic Chemical 5 (f) and needs prior environmental

clearance. Further, as the proposed industry is under category A. Since it is located in a notified

industrial area the project is exempted from public hearing.

1.2 Introduction of the Project Proponent

List of directors along with their designation is given in Table 1-1






Table 1-1: List of Directors and their designations

Name of Director Designation

Dr. Deepak Birewar Chairman & Managing Director

Shobana Birewar Director

Dr. Neeta Naik Director

1.3 Brief description of nature of the project

Currently Inventys Research Company is producing Specialty Chemicals products sMPGM ((s)-(+)

Methyl Phenyl Glycine Methyl Ester) and 5-Methyl 5- Phenyl Imidazolidine 2, 4-dione. These

products are used in various pharma and agro application.

Company proposes to expand the manufacturing of products in segments of Pharmaceutical,

Advanced Intermediates for Pharma Industry, API, Agro Actives, Fine chemicals, specialty


Maharashtra.

This site is well connected and the project is manageable from production, pollution control and

quality assurance point of view. All necessary infrastructures for this capacity are already

conveniently available.

1.4 Need for the project and its importance to the country and or region

Inventys has been a contract manufacturing company in market of Specialty Chemicals since its

beginning. With its market knowledge and manufacturing experience, Inventys is aware that

there is substantial market potential in Specialty Chemicals, Advanced Intermediates, API and

Agro Actives which can be explored with.

1.5 Demands-Supply Gap

Indian chemical industry has been facing debilitating competition from China for last 15 yrs.

Import duty reduction coupled with government’s unimaginative policies and inefficiencies in core

sector of the Indian economy have resulted in a destruction of chemical business in India at an

alarming rate.

One of the ways to overcome these challenges is to move up the value chain of chemical

business, i.e. to manufacture higher value specialty chemicals. It is also essential to continuously

change the product mix to stay ahead of the global competition. Such knowledge intensive






business practices would be necessary to gain leadership in today's globally competitive business

in such industry segment by concentrating on high value specialty chemicals using state of the

art manufacturing and research intensive business practices. To fulfill this gap, Inventys is

proposing to increase its production capacity to meet the market requirement.

1.6 Imports vs. Indigenous Production

The products manufactured will be sold both in domestic & export markets. There is significant

demand for these products by large MNCs from Europe, America and Japan. Inventys has a

strong position in supplying such products at internationally competitive prices in a sustainable

manner. This has been made possible by developing efficient processes through in-house R&D,

effective and economical plant design, speedy project execution, and building good customer

relationship.

1.7 Domestic /Export Markets

The finished goods will be sold in domestic as well as foreign market as per client demand.

1.8 Employment Generation due to the project

The proposed new product manufacturing facility will generate employment to 1,100 persons at

various skill levels. Inventys will give priority to local population as per the requirement. The

proposed project is a large scale industry it is bound to encourage small scale industries, traders

and transporters and effect considerable indirect employment.

2.0 PROJECT DESCRIPTION

2.1 Type of Project

Inventys Research Company private limited proposes to manufacture new products in segments

of Advanced Intermediates for Pharma Industry, API, Fine chemicals, Agro Actives, and specialty


Maharashtra.

2.2 Project Location

Inventys has a manufacturing unit at Plot SEZ 14 & 15, MIDC Industrial area, Butibori, Nagpur.

Major factories adjacent to the manufacturing unit are CEAT tyres unit on west side, Innovative

Textiles at south side, Spacewood furniture’s on East side and open area on North side. The

proposed site is well connected by road to Nagpur-Chandrapur at distance of 5 Km. Nearest

railway station is at Butibori which is 6 km away from site. The nearest airport is Nagpur at 20

km.






Figure 2-1 : Satelite Image of the Site

Corner Latitude Longitude

A 20°56'47.08"N 78°57'18.67"E

B 20°56'40.10"N 78°57'15.88"E

C 20°56'43.65"N 78°57'6.17"E

D 20°56'50.68"N 78°57'8.93"E

center 20°56'44.96"N 78°57'12.76"E






The project site is situated in MIDC Butibori. It is a notified industrial area where the land

is owned by Maharashtra Industrial Development Corporation (MIDC) and leased to the

Company. The land is meant for industrial activity.

Land Ownership: Land is owned by Maharashtra Industrial Development Corporation

(MIDC) and leased to the Company for 99 years.

2.3 Details of alternate sites considered and the basis of selecting the proposed site

The proposed new project at Plot No. SEZ 14 & 15, MIDC Industrial area, Butibori, Nagpur, State-

Maharashtra. The site is well connected by road as well as by railway and a designated and

approved industrial area for manufacture of chemicals. No alternative site has been considered.

2.4 Size or Magnitude of Operation

The products manufactured and their capacities proposed are shown in below Table

Table 2-1: Proposed Production Capacity

Sr. No.

Product Name Production

Quantity TPA

1 Sucrose octakis(hyrogen sulfate) aluminum complex 300

2 6-Chloro-2-hexanone 500

3 3-(prop-2-en-1-yloxy)-1-benzothiazole 1,1-dioxide 1,000

4 3-Chloroaniline 500

5 2-(3,4-Dimethyl-1-H-pyrazol-1-yl)butanedioic acid 3,000

6 3-ethyl-4-methyl-1,5-dihydro-2-h-pyrrol-2-one 20

7 2-Amino-5-chlorobenzoic acid 100

8 1-Chloro-2-phenoxybenzene 300

9 Decanenitrile 500

10 2-propylpentanoic acid 300

11 Sodium 2-propylpentanoate 100

12 Sodium hydrogen bis(2-propylvalerate) oligomer 100

13 1-Chloro-2-methoxynaphthalene 1,000

14 1-(isoprylamino)-3-(1-naphthyloxy)-2-propanol hydrochloride 30

15 2-Isopropyl-6-methyl-4-pyrimidinol 200

16 5-Phenyl-1,2-oxazol-3-ol 200

17 2-Bromo-6-methoxynaphthalene 1,000

18 2-Phenyl indole 10

19 4-Amino salicylic acid 50

20 2-(diethylamino)2-6,acetoxylidide hydrochloride 50






21 Methyl(2E)-3-(6-chloro-4-oxo-4h-3,1-benzoxazin-2-yl)prop-2-enoate

200

22 1-bromo-3-chloropropane 100

23 Benzyldimethyl[2-[2-[p-(1,1,3,3-tetramethylbutyl)phenoxy]ethoxy]ethyl]ammonium chloride

300

24 5-tert-Butyl-m-Xylene 300

25 4-Methoxy-6-methyl-1,3,5-triazin-2-amine 50

26 2-Chlorothiophene-5-carboxylic acid 100

27 2-hydroxy-5-{(E)-[4-(pyridin-2-ylsulfamoyl)phenyl]diazenyl}benzoic acid

100

28 3,4 DiMethyl Pyrazole 1,000

29 O,O-diethyl O-(5-phenyl-1,2-oxazol-3-yl) phosphorothioate 300

30 5-[4'-(Bromomethyl)-1,1'-biphenyl-2-yl]-1-triphenylmethyl-1-H-Tetraz ole]

500

31 3 (Trifluoromethyl) pyrazine-2-carboxylate 100

32 3-methyl-N-{2-methyl-1-[2-methyl-4-(propan-2-yloxy)phenyl]-1-oxopropan-2-yl}thiophene-2-carboxamide

100

33 3-(trifluoromethyl)aniline 100

34 2,3,4,5-Tetrafluorobenzoic Acid 100

35 2,4,5-Trifluoro-3-methoxybenzyoyl chloride 100

Total 12710

By Products:

Sr. No. By Product name Production Quantity TPA

1 Nacl 234

2 NaBr 565.2

3 NH4Br 64.8

4 toluene 372

Total 1236






2.5 PROCESS DESCRIPTION:

1) Sucrose octakis (hyrogen sulfate) aluminum complex Chemical Reaction:

Process Description:

In suitable reactor , reflux condenser, addition funnel, thermometer pocket & mechanical stirrer

and assembly was mounted on water bath.

Charged Pyridine at Room Temp, Chlorosulfonic acid added slowly into the reaction mass in 4 to 5 hr at 50 to 55°C.

Add sucrose slowly in 1 hr at 50 to 55°C.

Reaction mass heated to 60 to 65°C over 15 min and maintain for 2.0 hrs.

DM water added and pH of reaction mass adjusted to 7 to 8 byNAOH solution

Pyridine and water distill from reaction mass over period of 4-5 hours.

DM water added and clear solution is charcoal treated for 30 min at 25-35°C.

To filtrate aluminium chlorohydrate solution slowly added in 4 to 5 hrs. at 50 to 55°C

Reaction mass maintain for 2 hours at 60 to 65°C further maintain at 25 to 35°C for 6 hours.

Isolate final product by filtration.

OH

OO

O

OH

OH

OH

OH OH OH

OH

1. Pyridine, ClSO3H, NaOH

2. Aluminum chlorohydrate 50%

OSO 3Al(OH) 2

OO

O

OSO 3Al(OH) 2

(HO) 2AlO3SO

(HO) 2AlO3SO

(HO) 2AlO3SO(HO) 2AlO3SO OSO 3Al(OH) 2

OSO 3Al(OH) 2

sucrose

sucrose octakis(hydrogen sulfate) aluminum complex

Project 1: Sucrose octakis(hydrogen sulfate) aluminum complex

1

8 Al(OH) 3

Balance equation:

C12H22O11

FW: 342.29

+ 8 ClSO3H

FW: 116.52+ +16 NaOH

FW: 40

8 Al2Cl(OH)5

FW:174.45

C12H54Al16O75S8

FW: 2086.75

+ 16 NaCl

FW: 58.44

+ 16 H2O

FW: 18






Flow Diagram:






Material Balance

Sr

Raw Material Purity of raw material Quantity (Kg)

1 Chlorosulfonic acid 100.00% 455.82

2 Sucrose 100.00% 167.38

3 Pyridine 100.00% 502.20

4 DM water 100.00% 489.00

5 Sodium hydroxide (flakes) 100.00% 312.96

6 activated charcoal 100.00% 1.66

7 50% aluminium chorohydrate 50.00% 1364.05

TOTAL 3293.07

Sr

Out Put in Tonne

Product

(Kg)

Byproduct (kg)

Water Air Emission

Haz. Waste

In product/in

waste material/fi

lter cake etc. (Kg)

Waste Water

Reaction

water (kg)

Recycle/

Reuse of

waste/

wash water (Kg)

Total (Kg)

To ETP (Kg)

Process waste Recovered solvent

Grand Total (Kg)

water vapour (Kg)

solvent loss (Kg)

Total

(Kg)

Waste

Water

actual (Kg)

organic

(Kg)

Inorganic (kg)

Residue (Kg)

Spent carbon (Kg)

Total (Kg)

For Sold to authorized party (Kg)

Total (Kg)

Reuse (Kg)

1 1000.

00

1171.15

457.70 140.83 1769.68

19.5 10.02 29.52

0 1.96 1.96

491.93

491.93

3293.09

NaCl Pyridine

Pyridine






2) 3-(prop-2-en-1-yloxy)-1-benzothiazole 1,1-dioxide

Chemical Reaction:


Stage 1

Take a suitable reactor equipped with condenser, addition funnel, thermometer & mechnaical stirrer.

Charge 1H-isoindole-1,3 (2H)-dione and water in reactor

Purge chlorine in the above solution for at room temperature.

Adjust the p.H of the reaction mass to basic using sodium hydroxide.

Warm the reaction mass .

Stirr the reaction mass and maintain it for another 10-12 hours.

Filter out the precipitated solid & take the filtered solid in methanol.

Heat the reaction mass to reflux and maintain it for 8-12 hours.

Recover the methanol solvent by distillation and get the residual oil as a stage 1 product.

purify prodcut by vacuum distillation

Stage 2

Take a suitable RBF equipped with condenser, addition funnel, thermometer & mechnaical stirrer.

Charge water and methayl aminobenzoate to reactor and add hydrochloric acid.

Project 3: 3-(prop-2-en-1-yloxy)-1,3-benzothiazole 1,1-dioxide

NH

S

O

OO

+Cl

CH2

NaOH

N

S

OO

O

CH2

1,2-benzothiazol-3(2H)-one 1,1-dioxide 3-chloroprop-1-ene

3-(prop-2-en-1-yloxy)-1,2-benzothiazole 1,1-dioxide

NH

O

O

1.Cl2 (g), NaOH, water

2. MeOH

O

OMe

NH2

1H-isoindole-1,3(2H)-dione

C8H5NO2

FW: 147.12

Cl2FW: 71

2 NaOH

FW: 40

CH3OHFW: 32

+ + +C8H9NO2

FW: 151.16

2 NaCl H2O CO2+ + +FW: 58.5 FW: 18 FW: 44

Balanced equantion

STEP 1

STEP 2

C7H5NO3S

FW: 183.18+

C3H5Cl + NaOH

FW: 76.52

C10H9NO3S

FW: 223.23+ NaCl H2O

FW: 58.5 FW: 18+

FW: 40

STEP 3

C8H9NO2

FW: 151.16

NaCl

FW: 58.5+ NaNO2 +

SO2 + NH3+ N2C7H5NO3S

FW: 183.18

CH3OH++ +

1. Con HCl, NaNO2, water

2. SO2

2 H2O

+ HCl

FW 68.99 FW 64 FW 17 FW 36.5 FW 28 FW 32FW 18






To this solution, add sodium nitrite solution in water at -5 to 0⁰C

then purge sufur dioxide gas to reaction mass and stir for 5-8 H

then purge ammonia gas gas to reaction mass and stir for2-4 H

add tolune to reaction mass and separate toluen & water layer.

heat separated toluene layer to reflux for 8-10 H.

then cool reaction mass to RT and filter off precipitated stage 2 intermediate.

send filtrate for toluene recovery

Stage 3

Take a suitablereactor equipped with condenser, addition funnel, thermometer & mechnaical stirrer.

Charge satge 2 intermediate and allyl chloride to reactor

To this solution, add sodiun hydroxidesolution in water at RT

heat the reaction mas to reflux till completion of reaction

remove ethylene dichloride by distillation.

cool the reaction mass to RT

filter off precipitated product.






Flow diagram:






Material balance:

Stage 1

Sr

Raw Materials per tonne of product Purity of raw material Quantity (Kg)

1 1H-isoindole-1,3 (2H)-dione 100.00% 1016.81

2 Chlorine 100.00% 490.71

3 Sodium hydroxide flakes 100.00% 552.92

4 Water 100.00% 3050.44

5 Methanol 99.00% 2073.43

Sr

Out Put in Tonne 7184.31

Product (Kg)

Byproduct

To be used in

next batch (kg)

Water

Air Emission

Haz. Waste

Catalyst

To be used

in next batch

Waste Water

Inorganic (kg)

Reaction

water

total (kg)

water with

methanol (kg)

To ETP (Kg)


Grand Total (Kg) Gase

s (Kg)

solvent loss (Kg)

Total (Kg)

Waste Water actual (Kg)

organic (Kg) Residu

e (Kg)

Spent carbon (Kg)

Total (Kg)


Total (Kg) Reuse

(Kg)

1 940.26 808.64 3070.76

124.41 3195.16

-20.73 3174.43

304.10

18.66 322.76

104.50 104.50

1814.25

1814.25

7185.57

NaCl CO2






Stage 2

Sr


1 Methyl-aminobenzoate 100.00% 940.26

2 Sodium nitrite 100.00% 429.14

3 35 % hydrochloric acid 100.00% 648.69

4 sulfur dioxide gas 100.00% 398.10

5 Ammonia gas 100.00% 105.75

6 tolune 100.00% 4354.21

7 Water 100.00% 2488.12

Sr


Product (Kg)

Byproduct

To be used in

next batch (kg)

Water Air Emission

Haz. Waste

Waste Water

Reaction

water

Recycle/

Reuse of

waste/ wash water (Kg)

Total (Kg)

To ETP (Kg)

Process waste Recovered solvent Grand Total (Kg)

Gas (kg)

solvent loss (Kg)

Total (Kg)


organic waste (Kg)

organic (Kg)

Inorganic (kg)

Residue (Kg)

Spent carbon (Kg)

Total (Kg)


Total (Kg) Reuse

(Kg)

1 911.5

5

2909.80

103.2570243

199.05

363.89 223.93 3799.92

3799.92

174.17 43.54 217.71

124.41

124.41

4310.67

4310.67

9364.26

waste MeO

H NaCl

Nitrogen

toluene

toluen

e






Stage 3

Sr


1 stage 3 intermediate 100.00% 911.55

2 allyl chloride 100.00% 380.89

3 Ethylene dichloride 100.00% 2239.92

4 water 100.00% 2239.92

5 Sodium hydroxide 100.00% 199.10

Sr


Product (Kg)

Byproduct

To be used in

next batch (kg)

Water Air Emission

Haz. Waste

Catalyst

To be used in

next batch

Waste Water

Reaction water

Recycle/ Reuse

of waste/ wash water (Kg)

Total (Kg)

To ETP (Kg)


Grand Total (Kg)

Gas

(kg)

solvent loss (Kg)

Total (Kg)


organic (Kg)

Inorganic (kg) Residu

e (Kg)

Spent carbon (Kg)

Total (Kg)


Total (Kg) Reuse

(Kg)

1 1000.0

0

2239.92 110.75

291.19 89.60 2731.46

2731.46

44.80 44.80

0.00 2195.1

2

2195.12

5971.38

NaCl EDC EDC






3) 2-(3,4-Dimethyl-1-H-pyrazol-1-yl)butanedioic acid

Chemical reaction:


Stage 1

Take a suitable RBF euipped with condenser, mechanical stirrer, addition funnel& thermometer.

Charge methnaol at room temp. in to the reaction vessel in 4-5 hrs.

Prepare a solution of 2-butanone & paraformaldehyde and add in reaction mass at 40-50°C in 2-4 hrs.

Add sodium hydroxide in to the reaction mass and maintain thereaction for 10-12 hours at room temperature.

Adjust the p.H of reaction mass by adding sulphuric acid at 25-30°C.

Add hydrazine hydrate in to the reaction mass and maintain reaction for 14-16 hours at 25-

30°C.

Adjust the p.H of reaction mass to basic with sodium hydroxide solution and separate out the oily layer as a

stage 1 product.

stage 1 prodcut was purified by vacuum distillation

Stage 2

Take a suitable RBF equipped with with condenser, mechanical stirrer, addition funnel& thermometer.

Charge stage 1 product in the reaction vessel at room temperature and

add furan-2,5-dione slowly in water for 2-4 hrs. into the reaction vessel.

CH3

CH3

O

+ HCHO + NH2 NH2

1. NaOH (Aq)

2. H2SO4 (Aq)NH

N

CH3CH3

+O

OO

NN

CH3

CH3

O

OH

O

OH

2-butanoneformaldehyde

hydrazine Hydrate3,4-dimethyl-1H-pyrazole

Project 5: 2-(3,4-Dimethyl-1-H-pyrazol-1-yl)butanedioic acid

furan-2,5-dione

2-(3,4-dimethyl-1H-pyrazol-1-yl)butanedioic acid

C4H8O HCHO N2H4 2 NaOH H2SO4C5H8N2

FW: 72.1 FW: 30.02FW: 32.04 FW: 40 FW: 98 FW: 96.13

4 H2O+ + + + + +

FW: 18

2 NaHSO4

FW: 120.06

Balanced equation

STEP 2

C5H8N2

FW: 96.13

C4H2O3

FW: 98.05

C9H12N2O4

FW: 212.20

H2O+ +FW: 18

STEP 1






Heat the reaction mass to 60-70° & maintain the reaction for 12-14 hours.

Then cool the reaction mass to 5-10°C for 5-6 hours.

Isolate the final product by filtration.

Flow Diagram:






Material Balance:

Stage 1

Sr Raw Materials per tonne of product Purity of raw material Quantity (Kg)

1 2-Butanone 100.00% 500.35

2 paraformaldehyde 100.00% 208.33

3 Hydrazine hydrate 80.00% 277.94


5 Methanol 99.00% 1498.98

6 Water 100.00% 2081.92

7 Sulfuric acid 98.00% 1387.94

Sr

Out Put in Tonne Total 6510.64

Product

(Kg)

Byproduct

To be

used in

next

batch (kg)

Water

Air Emission

Haz. Waste

Catalyst

To be

used in

next batch

Waste Water

Reaction

water

Recycle/

Reuse

of

waste/

wash

water

(Kg)

Total

(Kg)

To ETP

(Kg)


Grand

Total

(Kg) Gases

(Kg)

solvent

loss

(Kg)

Total

(Kg) Waste

Water

actual (Kg)

organic

(Kg)

Inorganic

in

aq.(kg) Residue

(Kg)

Spent

carbon

(Kg)

Total

(Kg)

For Sold to

authorized

party (Kg)

Total

(Kg) Reuse

(Kg)

1 466.84 2179.07 1665.53 499.66 4344.27 4344.27 29.98 29.98 201.25 201.25 1469.00 1469.00 6511.34

NaHSO4 MeOH MeOH






Stage 2


1 3,4-diemthyl-1h-pyrazole 99.00% 466.84

2 Furan-2,5-dione 99.00% 476.80

3 water 99.00% 486.29

Sr


Product

(Kg)

Byproduct

To be

used in

next

batch (kg)

Water

Air Emission

Haz. Waste

Catalyst

To be

used in

next batch

Waste Water

Reaction

water

Recycle/

Reuse

of

waste/

wash

water

(Kg)

Total

(Kg)

To ETP

(Kg)


Grand

Total

(Kg) Gases

(Kg)

solvent

loss

(Kg)

Total

(Kg) Waste

Water

actual (Kg)

organic

(Kg)

Inorganic

(kg) Residue

(Kg)

Spent

carbon

(Kg)

Total

(Kg)

For Sold to

authorized

party (Kg)

Total

(Kg) Reuse

(Kg)

1 1000.00 398.76 31.12 429.88

0.00 1429.88






4) 3-ethyl-4-methyl-1,5-dihydro-2-h-pyrrol-2-one

Chemical reaction:


Stage 1

Take a suitable reactor , equipped with condenser, addition funnel, thermometer & mechnaical stirrer.

Charge methanol in the reaction vessel at room temperature.

Add methyl-2-ethylacetoacetate & nitromethane in reaction mass.

Add sodium methoxide slowly in the reaction mass.

Heat the reaction mass to reflux & maintain it for 4-8 hours.

Cool the reaction mass to room temperature.

Add sulphuric acid in to the reaction mixture to adjust the p.H of reaction mass .

Filter off the precipitated salt from the reaction mass.

Concentrate the residual mass to get the stage 1 product.

Stage 2

Take a suitable hydrogenator, equipped with with condenser, addition funnel, thermometer & mechnaical stirrer.

Charge nitro intermediate in to the hydrogenator at roo temerature in 2-4 hrs.

Add catalyst Raney Nickel at RT over a period of 1 hour into the hydrogenator.

Seal the autoclave, heat the reaction mas.

Pressurize the autoclave with hydrogen pressure.

Maintain the reaction temperature and pressure for next 6-12 hous.


Filter the catalyst Raney Nickel & wash with methanol.

CH3 O

OO

CH3

CH3

NH

O

CH3 CH3

methyl-2-ethyl acetoacetate

CH3

O

O

CH3

CH3

OH

O2N

+ CH3

NO2NaOMe, Methanol

3-ethyl-4-methyl-1,5-dihydro-2H-pyrrol-2-one

nitromethane

Project 6: 3-Eethyl-4-methyl-1,5-dihydro-2-H-pyrrol-2-one

1. Pd/C, H2 , NaHCO

3

2. Ethyl acetate

C7H12O3

FW: 144.16

+ C1H3NO2

FW: 61+ NaOCH3

FW: 54

C8H15NO5 + CH3OH

FW: 32FW: 205.2+ 0.5 H2SO4

+ 0.5 Na2SO4

FW: 98 FW: 142

Balance equation

STEP 1

STEP: 2

C8H15NO5

FW: 205.2+ 3 H2

FW: 2

+ NaHCO3 C7H11NO CH3OH+ + 3 H2O + 1 NaHCO3

FW: 125.16 FW: 32 FW: 18FW: 84FW: 84






Concentrate the filter to get residual oil.

Reflux the reaction mass for 8-12 hours in aq. sodium bi carbonate solution .

Extract the stage 2 product with ethyl acetate.

Concentrate the ethyl acetate to get final stage 2 product.

purify stage 2 prodcut by vacuum distilaltion

Flow Diagram:






Material Balance:

Stage 1

Sr


1 methyl-2-ethylacetoacetate 100.00% 2879.51

2 nitromethane 100.00% 1218.44

3 Sodium methoxide 100.00% 1078.62

4 Methanol 99.00% 8638.54

5 Sulfuric acid 98.00% 978.75

TOTAL 14793.86

Sr

Out Put in Tonne

Product (Kg)

Byproduct (kg)

for next batch

Water Air Emission

Haz. Waste

In product/in

waste material/filter cake etc.

(Kg)

Waste Water

Reaction

water (kg)

Recycle/

Reuse of


Total

(Kg)

going back with

Methanol (Kg)


Grand Total (Kg)

Gases (Kg)

solvent loss (Kg)

Total (Kg)

waste

water

actual

(Kg)

organic (Kg)


e (Kg)

Spent carbon (Kg)

Total (Kg)


Total (Kg) Reuse

(Kg)

1 4098.7

5 1418.18

86.39

86.39

-86.39 429.85

429.85

0.00 8845.8

0

8845.80

14792.59

Na2SO4 MeO

H MeOH






Stage 2

Sr


1 nitro intermediate 100.00% 4098.75

2 Raney nickel 100.00% 81.98

3 Hydrogen 100.00% 119.85

4 Sodium bicarbonate 100.00% 1677.85

5 Water 100.00% 11984.66

6 Methanol 100.00% 12296.26

TOTAL 30259.35

Sr

Out Put in Tonne

Product (Kg)

Byproduct (kg)

for next batch

Water Air Emission

Haz. Waste

Catalyst Recovered (Kg)

Waste Water

Reaction

water (kg)

Recycle/

Reuse of


Total (Kg)

To ETP

(Kg)


Grand Total (Kg)

Gases (Kg)

solvent loss (Kg)

Total (Kg)


organic (Kg)

Inorganic (kg)

Residue (Kg)

Spent carbon (Kg)

Total (Kg)


Total (Kg) Reuse

(Kg)

1 1000.

00 1677.85 98.37

12107.62

639.1818

1078.62

12746.80

245.93

245.93

1361.56

1361.56

12050.34

12050.34

30259.46

NaHCO3 Raney Nickel

MeOH MeO

H MeOH






5) 2-Amino-5-chlorobenzoic acid

Chemical reaction:


Stage 1


Charge 1H-isoindole-1,3 (2H)-dione and water in reactor

Purge chlorine in the above solution for 4-8 hours at room temperature.

Adjust the p.H of the reaction mass to basic using sodium hydroxide.

Warm the reaction mass to 35-40°C .

Stirr the reaction mass and maintain it for another 10-12 hours.

Filter out the precipitated solid & take the filtered solid in methanol.

Heat the reaction mass to reflux and maintain it for 8-12 hours.

Recover the methanol solvent by distillation and get the residual oil as a stage 1 product.

purify prodcut by vacuum distillation

O

OH

NH2

Cl

2-amino-5-chlorobenzoic acid

NH

O

O 1. SO2Cl

2, EDC

2. NaOH (Aq)

O

OCH3

NH2

methyl 2-aminobenzoate

1. Cl2, NaOH

2. Methanol

Project 7: 2-Amino-5-clorobenzoic acid

Phthalimide

C8H5NO2

FW: 147.12

Cl2

FW: 71

2 NaOH

FW: 40

CH3OH

FW: 32+ + +

C8H9NO2

FW: 151.16

2 NaCl H2O CO2

+ + +FW: 58.5 FW: 18

FW: 44

Balanced equantion STEP 1

STEP 2

C8H9NO2

FW: 151.16

SO2Cl2 NaOH C7H6ClNO2NaCl CH3OH SO2

FW: 134.96 FW: 40 FW: 171.58 FW: 58.5 FW: 32FW: 64+ + ++ +






Stage 2


Charge ethylene dichloride in the reaction vessel at room temperature.

Add stage 1 product methyl-aminobenzoate, sulfuryl chloride in the reaction mass at -45 to -40 deg C over 2-3

hrs.

warm the reaction mass to -25 to -10 °C .

Maintain the reaction mass under stirring for 1-2 hours.

add sodium hydroxide solution to reaction mass.

separate layers

Recover the solvent ethylene dichloride by distillation of product under vacuum & get the stage 2 product.

Flow Diagram:






Material Balance:

Stage 1

Sr


1 1H-isoindole-1,3 (2H)-dione 100.00% 1190.89

2 Chlorine 100.00% 574.72


4 Water 100.00% 3572.68

5 Methanol 99.00% 2428.41

Sr


Product (Kg)

Byproduct

To be used in

next batch (kg)

Water

Air Emission

Haz. Waste

Catalyst

To be used

in next batch

Waste Water

Inorganic (kg)

Reaction

water

total (kg)

water with

methanol (kg)

To ETP (Kg)


Grand Total (Kg) Gase

s (Kg)

solvent loss (Kg)

Total (Kg)


organic (Kg) Residu

e (Kg)

Spent carbon (Kg)

Total (Kg)


Total (Kg) Reuse

(Kg)

1 1101.2

4 947.08

3596.48

145.70 3742.18

-24.28 3717.90

356.17

21.86 378.02

122.39 122.39

2123.26

2123.26

8414.17

NaCl CO2






Stage 2:

Sr


1 methyl-aminobenzoate 100.00% 1101.24

2 Sulfuryl chloride 100.00% 983.21

3 ethylene dichloride 100.00% 3303.71

4 sodium hydroxide flakes 100.00% 291.41

5 water 100.00% 2914.09

Sr


Product (Kg)

Byproduct

To be used in

next batch (kg)

Water

to scrubber (Kg)

Air Emission Haz. Waste

Waste Water

Reaction

water

Recycle/

Reuse of


Total (Kg)

To ETP (Kg)


Grand Total (Kg)

solvent loss (Kg)

Total

(Kg)


Organic (Kg)

organic (Kg)


e (Kg)

Spent carbon (Kg)

Total (Kg)


Total (Kg) Reuse

(Kg)

1 1000.0

0

2914.09 250.029

233.13

426.19 3823.44

3823.44

466.25 33.04 33.04

0.00 3270.6

7

3270.67

8593.40

waste MeO

H NaCl SO2 EDC EDC






6) 1-Chloro-2-phenoxybenzene

Chemical reaction:


In suitable reactor reflux condenser, addition funnel, thermometer pocket & mechanical stirrer and

assembly was mounted on oil bath.

Charged 2-chlorophenol, chlorobenzene, NaOH a RT.

Slowly raised the temp of reaction mass to 120-140°C with simultaneous distillation of water over 5-6 over.

Reaction mass maintained for 5-8 hour at 120-140°C.

Cool the reaction mass to room temperature and filter off precipitated solid.

Recover unreacted chlorobenzne by vacuum distillation and purify residue by fractional distillation.

Cl

OH

Cl

+O

Cl

NaOH,

Chlorobenzene1-chloro-2-phenoxybenzene2-chlorophenol

Project 8: 1-Chloro-2-phenoxybenzene

Balacne equation

C6H5ClO + C6H5Cl + NaOH C12H9ClO + NaCl + H2O

FW: 128.55 FW: 112.55 FW": 40 FW: 58.5 FW: 18FW: 204.6






Flow Diagram:






Material Balance:


1 2-Chlorophenol 100.00% 739.54

2 Chlorobenzene 100.00% 3164.10


TOTAL 4133.76

Sr

Out Put in Tonne

Product

(Kg)

Byproduct

(kg)

Water

Air Emission

Haz. Waste

In product/in

waste

material/filter

cake etc. (Kg)

Waste Water

Reaction

water

(kg)

Recycle/

Reuse

of

waste/

wash

water

(Kg)

Total

(Kg)

To ETP

(Kg)

Process waste Recovered solvent Grand

Total

(Kg) Gases

(Kg)

solvent loss

(Kg)

Total

(Kg)

Waste

Water

actual

(Kg)

organic

(Kg)

Inorganic

(kg) Residue

(Kg)

Spent

carbon

(Kg)

Total

(Kg)

For Sold to

authorized

party (Kg)

Total

(Kg) Reuse (Kg)

1 1000.00 336.55

103.55 103.55 103.55 25.14 25.14 177.48 177.48 2491.01 2491.01 4133.73

NaCl

Chlorobenzene waste

residue Chlorobenzene






7) Decanenitrile

Chemical reaction:


Stage 1

Take reactor equipped with overhead reflux condenser, mechanical stirrer, thermometer pocket.

Charge toluene in the reaction vessel at room temperature.

Add decanoic acid and SOCl2 in the reaction mass at 25-30°C over 2-4 hrs. Purge ammonia gas slowly from the top of the vessel in the reaction mass for 1-2 hrs.

Heat the reaction mass to reflux for 3-5 hrs.

Filter out the salt and concentrate the filtrate to get residue as stage 1 product.

Stage 2

Take a suitable reactor equipped with overhead mechanical stirrer, thermometer and

reflux condenser.

Prepare a solution of decanamide and acidic resin in a reaction vessel.

Heat the reaction mass to 100-120 °C .

Stir the reaction mass and maintain heating for 20-25 hours.

Simultaneously distill out water and then cool the recation mass to room temperature.

Filter the reaction mass to separate the acidic resin.

Purify it by fractional distillation of product under vacuum.

decanoic acid

Project 9: Decanenitrile

CH3

COOH

1. SOCl2, Toluene

2. Ammonia gasCH3

CONH 2

Acidic resin

CH3

CN

decanenitrile

Balance equation

C10H20O2

FW: 172.17

SOCl2

FW: 118.97 FW: 17

C10H21NO SO22 NH4Cl

+ + + +FW: 171.27 FW: 64 FW: 53.49

STEP 1

STEP 2

C10H21NO

FW: 171.27

C10H19N H2O

FW: 153.26 FW: 18

3 NH3

+






Flow Diagram:






Material Balance:

Stage 1


1 Decanoic acid 99.00% 1183.69

2 SOCl2 99.00% 817.94

3 Ammonia Gas 99.00% 350.63

4 Toluene 99.00% 3547.58

TOTAL 5899.84

Sr

Out Put in Tonne

Product

(Kg)

Catalyst

(kg)

to be

used in

next

batch

Water

to

scrubber

(Kg)

Air Emission

Haz. Waste

In product/in

waste

material/filter

cake etc. (Kg)

Waste Water

Reaction

water

(kg)

Recycle/

Reuse of

waste/

wash

water

(Kg)

Total

(Kg)

To ETP

(Kg)


Grand Total

(Kg) solvent

loss

(Kg)

Total

(Kg)

Waste

Water

actual

(Kg)

organic

(Kg)

Inorganic

(kg) Residue

(Kg)

Spent

carbon

(Kg)

Total

(Kg)

For Sold to

authorized

party (Kg)

Total

(Kg) Reuse

(Kg)

1 1176.33 735.50 735.50 735.50 440.01 70.95 510.96 0.00 3476.63 3476.63 5899.42

NH4Cl SO2 Toluene Toluene






Stage 2


1 Decanamide 100.00% 1176.33

2 Acidic resin 100.00% 117.63

TOTAL 1293.96

Sr

Out Put in Tonne

Product

(Kg)

Catalyst

(kg)

to be

used in

next

batch

Water

Air Emission

Haz. Waste

In product/in

waste

material/filter

cake etc. (Kg)

Waste Water

Reaction

water

(kg)

Recycle/

Reuse of

waste/

wash

water

(Kg)

Total

(Kg)

To ETP

(Kg)


Grand Total

(Kg) Gases

(Kg)

solvent

loss

(Kg)

Total

(Kg)

Waste

Water

actual

(Kg)

organic

(Kg)

Inorganic

(kg) Residue

(Kg)

Spent

carbon

(Kg)

Total

(Kg)

For Sold to

authorized

party (Kg)

Total

(Kg) Reuse

(Kg)

1 1000.00 117.63 123.63 123.63 123.63 0.00 0.00 52.54 52.54 0.00 1293.80

Acidic

Resin






8) 2-propylpentanoic acid

Chemical Reaction:


Stage 1

In suitable reactor reflux condenser, addtion funnel, thermometer pocket & mechanical stirrer


Charge ethyl cyanoacetate in the reaction vessel at room temperature.

Charge propanol in the reaction vessel at room temperature.

Add sodium propoxide slowly from top of the reaction vessel in the reaction mass.

Heat the reaction mass to 50-60° C add propyl bromide slowly from the top and maintain the reaction for 2-6 hrs.

Reflux the reaction mass for next 6-10 hours.


Filter out the solid sodium bromide as a byproduct.

Concentrate the filtrate to get crude stage 1 product and recover propranol

purify crude stage 1 by vacuum distillation

Stage 2

In suitable reactor reflux condenser, addtion funnel, thermometer pocket & mechanical stirrer


Project 10: 2 -Propylpentanoic acid

EtOCN

OEtO

CNO

C H3

CH3

1. N aO H (A q)

2. - C O2

OH

O

CH3

CH3

Ethyl cyanoacetate

Propyl brom ide, N aO Pr,

propanol

C5H

7NO

22 C

3H

7Br 2 C

3H

7ONa

C11

H19

NO2

2 NaBr 2 C3H

8O

+ ++ +

FW: 113.11 FW: 122.99 FW: 80.07FW: 197.27 FW: 102.89 FW: 60.09

STEP 1

STEP 2

C11

H19

NO2

FW: 197.27

2 H2O

+FW: 18

2-propylpentanoic acid

C2H

5OH

FW: 46

C8H

16O

2

FW: 144.21

CO2

FW: 44

NaCl N H 3

FW: 17+ + +

FW: 58.5

NaOH

FW: 40

HCl

FW: 36.5++

+






Take stage 1 product in water into the reaction vessel at room temperature.

Add sodium hydroxide in the reaction mass.

Heat the reaction mass to reflux for 12-18 hours and cool it to room temperature.

Adjust the p.H by adding hydrochloric acid.Filter out the product.

Place the filter solid in reactor. heat the solid to 120-160⁰C for 4-6 h. Distill out the reaction mass to get the pure product.

Flow Diagram:






Material Balance:

Stage 1

Sr


1 Ethyl cyanoacetate 100.00% 968.32

2 propyl bromide 100.00% 2105.81

3 Sodiumpropoxide 100.00% 1370.94

4 propanol 100.00% 2910.71

TOTAL 7355.79

Sr

Out Put in Tonne

Product Kg

Byproduct Kg

water Air Emission

Haz. Waste

In product/in

waste material/fil

ter cake etc. Kg

Waste Water

Reaction

water Kg

Recycle/

Reuse of

waste/ wash water

Kg

Total Kg

To ETP

Kg


Grand Total

Kg Gases kg

Solvent loss Kg

Total Kg

Waste

Water

actual Kg

organic Kg

Inorganic Kg Residue

Kg

Spent carbon Kg

Total Kg

For Sold to authorized party Kg

Total Kg Reuse

Kg

1 1519.93

1760.98

0 0 29.11 29.11

136.888848

136.888848

3908.91 3908.91

7355.81

NaBr Propanol

Propanol






Stage 2


1 ethyl 2-cyano-2-propylpentanoate 100.00% 1519.93

2 Water 100.00% 2696.68

3 Sodium Hydroxide 100.00% 308.19

4 35% Hydrochloric acid 35.00% 803.50

TOTAL 5328.31

Sr

Out Put in Tonne

Product Kg

Byproduct Kg

water

Air Emission

Haz. Waste

In product/in waste

material/filter cake etc. Kg

Waste Water

Reaction water Kg

Recycle/ Reuse of waste/ wash

water Kg

Total Kg To ETP

Kg


Grand Total Kg Gases

kg solvent loss Kg

Total Kg Waste

Water actual Kg

organic Kg

Inorganic Kg

Residue Kg Spent carbon Kg

Total Kg

For

Sold to authorized party Kg

Total Kg

Reuse Kg

1 1000 2935.53 581.713396 3517.25 3517.25 339.01 339.01 117.652498 117.652498 354.42 354.42 5328.33

NH3+nacl CO2 Ethanol






9) Sodium 2-propylpentanoate

Chemical Reaction:


Take a suitable reactor equipped with condenser,addition funnel, mechanical stirrer & thermometer.

Charge acetonitrile in the reaction vessel at room temperature.

Charge 2-propylpentaoic acid in the reaction vessel at 25-30°C over a period of 4-5 hrs.

Heat the reaction mass and add sodium hydroxide into the reaction mass.

Maintain heating the reaction mass for next 6-10 hours.

Then cool the reaction mass to room temperature.

isolate precipitated product by filtration

recover acetonitrile from filtrate by distillation

Flow Diagram:

OH

O

CH3

CH3

+ NaOHNaO

O

CH3

CH3

+H2O

sodium 2-propylpentanoate

Project 11: Sodium 2-propylpentanoate


Balanced equation

C8H16O2

FW: 144.21

NaOH

FW: 40

C8H15O2Na

FW: 166.19

H2O

FW: 18++






Material Balance:


1 2-propylpentanoic acid 100.00% 867.74


3 Acetonitrile 100.00% 2599.43

TOTAL 3707.86

Sr

Out Put in Tonne

Product

Kg

Byproduct

Kg

water

Air Emission

Haz. Waste

In product/in

waste

material/filter

cake etc. Kg

Waste Water

Reaction

water Kg

Recycle/

Reuse

of

waste/

wash

water

Kg

Total

Kg

To ETP

Kg


Grand

Total

Kg Gases

kg

solvent

loss Kg Total Kg

Waste

Water

actual

Kg

organic

Kg

Inorganic

Kg Residue

Kg

Spent

carbon

Kg

Total

Kg

For Sold to

authorized

party Kg

Total

Kg Reuse Kg

1 1000 108.31 108.31 108.31 25.99 25.99 0.00 2573.44 2573.44 3707.74

Acetonitrile Acetonitrile






10) Sodium hydrogen bis(2-propylvalerate) oligomer

Chemical Reaction:


Take a suitable reactor, equipped with condenser, mechanical stirrer, thermometer and addition funnel.

Prepare a solution of 2-propylpentoic acid in acetonitrile.

Add sodium hydroxide in to the solution.

Heat the reaction mass to reflux at 50-60°C for 12-18 hours.

Cool then reaction mass to room temperature.

Recover acetonitrile by fractional distillation.

Distill out the reaction mass to get final product.

Flow Diagram:

OH

O

CH3

CH3

+ NaOH

2

O-

O

CH3

CH3

2

Na+


Project 12: Sodium hydrogen bis(2-propylvalerate) oligomer

sodium hydrogen bis(2-propylvalerate) oligomer

2 C8H16O2

FW: 144.21

NaOHFW: 40

C16H31O4Na

FW: 310.41

H2O

FW: 18+ +

Balanced equation






Material Balance:

Sr


1 2-propylpentanoic acid 99.00% 929.16



TOTAL 2507.72

Sr

Out Put in Tonne

Product Kg

Byproduct Kg

water Air Emission

Haz. Waste

In product/in

waste material/fil

ter cake etc. Kg

Waste Water

Reaction

water Kg

Recycle/

Reuse of

waste/ wash water

Kg

Total Kg

To ETP Kg


Grand Total

Kg Gases kg

solvent loss Kg

Total Kg

Waste

Water

actual Kg

organic Kg

Inorganic Kg

Residue Kg

Spent carbon Kg

Total Kg

For Sold to authorized party Kg

Total Kg

Reuse Kg

1 1000

57.99 57.99

57.99

14.50 14.50

1435.20 1435.20

2507.68

Acetonitrile

Acetonitrile






11) 1-Chloro-2-methoxynaphthalene

Chemical reaction:


Stage 1:

Take a suitable RBF equipped with reflux condenser, mechanical stirrer, agitator

and thermometer pocket mounted on water bath.

Prepare a solution of naphthalen-2-ol,sodium hydroxide and water in the reaction vessel.

Add dimethyl sulfate in the reaction mass at room temperature over a period of 2-4 hrs.

Add ethyl acetate in the reaction mass.

Heat the reaction mass to 50-60 deg C and maintain stirring & heating for 4-5 hrs.

Cool the reaction mass to room temperature. Separate layer s.

Remove ethyl acetate by fratctional distillation to get stage 1 product.

Stage 2

Take a suitable RBF equipped with reflux condenser, pocket thermometer, mechnaical stirrer and addition funnel mounted on water bath.

Take stage 1 product in the reaction vessel at room temperature.

Add methanol in the reaction mass at RT.

Add 35% Hydrochloric acid in the reaction mass over 1-2 hrs.

Add dropwise H2O2 in the reaction mass in the above reaction mass.

Concentrate the reaction mass and add water at 60-80⁰C

Filter out the final stage 2 product.

OH OCH3

naphthalen-2-ol 2-methoxynaphthalene

OCH3

Cl

1-chloro-2-methoxynaphthalene

+S O

O

O

O

CH3CH3

dimethyl sulfate

NaOH; water

Project 13: 1-Chloro-2-methoxynaphthalene

1. Conc HCl, H2O2

2. MeOH

Balance equation

C10H8O

FW: 144.16

C2H6O4S

FW: 126.13

2 NaOH

FW: 40

C11H10O

FW: 158.19+ + + CH3OH + Na2SO4

H2O+FW: 32 FW: 142 FW: 18

STEP 1

STEP 2

C11H10O

FW: 158.19

+ HCl H2O2

C11H9ClO

FW: 192.64

+ 2 H2O

FW: 18+

FW: 36.5 FW: 34






Flow Diagram:






Material Balance:

Stage 1


1 Naphthalen-2-ol 1000.00% 939.49

2 Dimethyl sulfate 100.00% 821.99

3 Sodium Hydroxide 100.00% 521.36

4 Water 100.00% 2606.81

5 Ethyl Acetate 100.00% 2932.66

Sr


Product (Kg)

Byproduct (kg)

Water

Air Emission

Haz. Waste

Catalyst To be

used in next batch

Waste Water

Reaction water

Recycle/ Reuse


Total (Kg)

To ETP (Kg)


Grand Total (Kg) Gases

(Kg)

solvent loss (Kg)

Total (Kg) Waste

Water actual (Kg)

organic (Kg) Inorganic

(kg) Residue (Kg)

Spent carbon (Kg)

Total (Kg)


Total (Kg) Reuse

(Kg)

1 1000.00

2606.81 31.58 208.5 925.42 117.31 3858.07 3858.07 19.55 19.55 0.00 2913.11 2913.11 7790.73

waste CH3OH Na2SO4 Ethyl Acetate

Ethyl Acetate






Stage 2


1 2-methoxynaphthalene 100.00% 864.39

2 35% HCL 35.00% 569.84

3 30 % H2O2 30.00% 619.28

4 Methanol 100.00% 2595.51

5 Water 100.00% 2732.12

Sr


Product

(Kg)

Byproduct

To be

used in

next

batch (kg)

Water

Air Emission

Haz. Waste

Waste Water

Reaction

water

Recycle/

Reuse

of

waste/

wash

water

(Kg)

Total

(Kg)

To ETP

(Kg)


Grand

Total

(Kg) Gases

(Kg)

solvent

loss

(Kg)

Total

(Kg)

Waste

Water

actual

(Kg)

organic

waste (Kg)

organic

(Kg)

Inorganic

(kg) Residue

(Kg)

Spent

carbon

(Kg)

Total

(Kg)

For Sold to

authorized

party (Kg)

Total

(Kg) Reuse

(Kg)

1 1000.00 3536.24 52.63 259.55 196.71 4045.13 0.00 0.00 2335.96 2335.96 7381.10

waste MeOH MeOH






12) 1-(isoprylamino)-3-(1-naphthyloxy)-2-propanol hydrochloride

Chemical Reaction:


Stage 1

Take a suitable RBF equipped with reflux condenser, mechanical stirrer pocket thermometer, addition funnel mounted on the water bath.

Prepare a solution of naphthale-1-ol & 2-(chloromethyl)oxirane in the reaction vessel.

Heat the reaction mass to 80-100°C for 4-5 hrs.

Reflux the reaction mass and recover the product by fractional distillation.

Stage 2

In suitable Autoclave equipped with S, H and Gas (N2 & H2) inlets.

Prepare a solution of 2-[(naphtalen-1-yloxy)methyl]oxirane and n-benzylpropane-2-amine in methanol.

Heat the reaction mass to reflux for 6-8 hours.

Cool the reaction mass and transfer the reaction mass to hydrogenator vessel.

Add Pd/C carefully in the reaction mass.

Pressurize autoclave up to 5.0 bar of H2 gas and gradually heat reaction up to 75-80⁰C

Maintain the heating for 6-8hrs.

Remove the reaction mass from hydrogenator.

Filter out the catalyst and use for next batch.

Distill out the methanol and add acetonitrile in the reaction mass.

Pass 1 mole of HCl gas.

Filter out the stage 2 product.

send filtrate for acetonitrile recovery

OH

naphthalen-1-ol

+ Cl O

2-(chloromethyl)oxirane

O

O

2-[(naphthalen-1-yloxy)methyl]oxirane

+

NH

CH3 CH3O

OH

NH2Cl

CH3

CH3

N-benzylpropan-2-amine

1. methanol

2. Pd/C, H2 (g), Methanol

3. HCl (g), acetonitrile

Project 14: 1-(isoprylamino)-3-(1-naphthyloxy)-2-propanol hydrochloride

Balance equation

STEP 1

C10H8O

FW: 144.16

C3H3ClO

FW: 92.52

C13H12O2HCl

+FW: 200 FW: 36.5

+

C13H12O2

FW: 200

C10H15N

FW: 149.23

+ + H2

FW: 2

HCl FW: 36.5

C16H22ClNO2

FW: 295.8

C7H8

FW: 92.1

++

STEP 2






Flow Diagram:

Stage 1






Material Balance:

Stage 1


1 naphthalen-1-ol 100.00% 716.70

2 2-(chloromethyl)oxirane 100.00% 459.97

3

Sr


Product (Kg)

Byproduct To be

used in next

batch (kg)

Water

To scrubber

(Kg)

Air Emission

Haz. Waste

Catalyst To be

used in next batch

Waste Water

Reaction water

Recycle/ Reuse


Total (Kg)

To ETP (Kg)


Grand Total (Kg)

solvent loss (Kg)

Total (Kg) Waste

Water actual (Kg)

organic (Kg)

Inorganic (kg) Residue

(Kg)

Spent carbon (Kg)

Total (Kg)


Total (Kg) Reuse

(Kg)

1 795.45

181.46 199.757388 199.76 0.00 1176.67

HCl






Stage 2


1 2-[(naphtalen-1-yloxy)methyl]oxirane 99.00% 795.45

2 n-benzylpropane-2-amine 99.00% 593.53

3 Pd/C 99.00% 7.95

4 Methanol 99.00% 2386.35


6 H2 Gas 99.00% 7.95

7 HCl Gas 99.00% 145.17

Sr


Product

(Kg)

Byproduct

To be

used in in

other

prodduct

(kg)

Water

Air Emission

Haz. Waste

Catalyst

To be

used in

next

batch

Waste Water

Reaction

water

Recycle/

Reuse

of

waste/

wash

water

(Kg)

Total

(Kg)

To ETP

(Kg)

Process waste Recovered solvent Grand

Total

(Kg) Gases

(Kg)

solvent

loss (Kg)

Total

(Kg)

Waste

Water

actual

(Kg)

organic

(Kg)

Inorganic

(kg) Residue

(Kg)

Spent

carbon

(Kg)

Total

(Kg)

For for reuse

acetonitrile

Total

(Kg) Reuse

(Kg)

1 1000.00 366.30 9.55 0.00 47.73 47.73 174.20 174.20 2362.49 2362.49 4724.97 6322.75

Toluene Pd/C

Methanol

+

acetonitrile

Methanol






2.6 Raw material required along with estimated quantity, likely source, marketing area of final

Product/s, mode of transport of raw material and finished product Raw Materials: The detailed raw

material list for proposed products as per selected capacity is detailed below for all reactants, solvents

and support chemicals.

Source for Raw Material Procurement:

Raw Materials are easily available in the local market.

Mode of Transport of Raw Materials: Raw Material and finished goods will be transported through

Trucks/ Tankers.

Storage at the site: Raw Materials will be stored in storage yard at the project site. Location of storage

yard is demarcated in Layout Plan.

2.7 Resource optimization/recycling and reuse envisaged in the project

Most energy efficient technology is selected. In proposed new project, domestic waste water will be

treated in proposed STP of capacity 50 CMD and this treated water will be used for gardening.

2.8 Availability of water its source, energy/power requirement and source

2.8.1 Water Requirement and Source

Total fresh water requirement for proposed new project (domestic and industrial activity) during operation

phase will be 1452.5 CMD for first day and afterwards it will be reduced to 1408.5 CMD. The water supply

is from MIDC.

2.8.2 Power Requirement

Power requirement of proposed project will be made available through State Electricity Board. Power

requirement of proposed plant is as below:

Power requirement: 10 MW

2.8.2.1 Emergency power

4 numbers of D. G. sets of 1500 KVA each will be provided to supply power in case of MSEDCL power shut down.






2.8.3 Fuel Requirement

Sr. No. Item Quantity Capacity Type Fuel Quantity

1 Boiler 1 30 TPH Coal/Briquette 72 TPD/86 TPD

2 D G Set 4 1500 KVA HSD 1600 Lit. /hr.

2.9 Quantity of wastes to be generated (liquid and solid) and scheme for their

management/disposal

2.9.1 Gaseous Emissions

Details of gaseous emissions from Process and Flue gas are given in Table 2-5

Table 2-5: Details of emissions from process and flue gas

Attached to Boiler DG KVA

Capacity 30 TPH 1500 KVA x 4 Nos.

Fuel type Coal/Briquette HSD

Fuel Quantity 72 TPD/86 TPD 1600 Lit/hr

MOC MS MS

Shape Round Round

Gas temperature 135oC 150oC

Stack Height 30 m 30 m

Mitigation Measures Multicyclone

followed by Bag filter and stack

Combined Stack of adequate height

2.9.2 Effluent

The quantity of effluent generated proposed project is given in Table 2.7






Table 2-7: Details of Water Consumption & Effluent Generation

Water Balance:

Sr. No.

Particulars Consumption (CMD) Loss / Gain (CMD) Effluent (CMD)

Water requirement

1 Industrial process 117 (+)52 169

2 Cooling Tower 1070 (-)713 357

3 Boiler 80 (-)40 40

4 Drum and Reactor washing 1.5 (-)0.5 1

5 Floor washing 14 (-)1.0 13

6 Gardening 115 (-)115 0

7 Domestic 55 (-)11 44

Total 1452.5 828.5 624






A) Multiple Effect Evaporator

Parameters Unit Inlet to MEE Outlet from MEE

Flow m3/day 169 169+42.25=211.67

pH ---- 5-6 7-7.5

COD mg/L 160000-170000 7000-8000

TDS mg/L 80000-90000 <100

B) ETP treatment (Form condensate from MEE along with utility blow down & other washings)

Parameters Unit Inlet to

primary Inlet to

Secondary Inlet to tertiary

Outlet from Tertiary

Flow m3/day 411+211.67=

622.67 622.67 622.67 622.67

pH ---- 7-7.5 7-7.5 7-7.5 7-7.5

COD mg/L 4000-5000 3500-4000 350-400 <250

BOD3, 27°C mg/L 2000-2500 1750-2000 50-100 <100

TDS mg/L 1000-1500 1100-1600 1100-1600 <2100

TSS mg/L 200-300 <100 <100 <100






Standard Operating Procedure of Effluent Treatment Plant

Multi Effect Evaporator (MEE) – For high COD & TDS stream from process (169 CMD) will be fed to MEE

(capacity 200.00 CMD) where the effluent will be concentrated up to 50 % w/w by evaporating the water

with the high pressure steam. The condensate of the evaporator will be fed to ETP for removal of volatile

organics that will get carried away in the condensate. The concentrated liquor will be pumped to the

centrifuge for the removal of solids. Thus the dissolved solids will be completely removed from the liquor

and it will also reduce the concentration of other polluting parameters. The solids recovered from

centrifuge will be sent for disposal to CHWTSDF. The condensate of MEE will be pumped to the Effluent

Treatment Plant for the removal of organics.

Effluent Treatment Plant:

Primary Treatment

The system will be designed to treat 623.00 CMD of waste water. Wastewaters from cooling tower and

boiler blow downs etc. will be collected in the equalization tank and air stripped. This effluent will then be

pumped to the Flash Mixer where it will be dosed with PAC for coagulation. Flash Mixer will be followed

by a flocculator where poly will be dosed for bigger flock formation. This effluent will overflow into the

settling tank where the solids will settle down and will be removed.

Secondary (Aerobic) Treatment:

The neutralized effluent will enter the bioreactor along with domestic effluent. In the bio reactor,

dissolved organic material is degraded by the micro–organisms present in the bio reactor. Oxygen

required for the oxidation of organic matter will be provided by means of proposed diffuser aeration

system which will mix the contents of the bioreactor also. The mixed liquor will overflow into Secondary

Settling Tank (SST).

In the secondary settling tank, solid-liquid separation takes place and solids i.e. biomass will settle at the

bottom of the tank. Settled biomass will be recycled to the bio reactor for maintaining the MLVSS

concentration by using proposed sludge recycle pumps and excess biomass will be wasted periodically to

the sludge sump. Two stage treatments are proposed where the overflow from the 1st stage clarifier will

enter the 2nd stage bioreactor where the non-degraded organics from the 1st stage bioreactor will be

treated. The clear overflow from the 2nd stage Secondary Settling Tank will be collected in the

intermediate sump.

Tertiary Treatment:

The clear effluent from the intermediate sump will be pumped by tertiary Feed pumps through the

pressure sand filter (PSF) & activated carbon filters. The final treated effluent will be collected in the final

collection tank from where it will discharge to CETP.






Sludge Handling:

Primary sludge, excess biomass from the secondary treatment and backwash water from PSF will be

collected in the sludge collection tank. From the sludge collection tank it will be pumped to the filter

press for dewatering. The solid cake from filter press will be sent for disposal to Hazardous waste disposal

site. The filtrate from the filter press will be drained to the equalization tank.

Treatment Scheme for Domestic Wastewater

Domestic sewage will be treated in proposed STP of 50 CMD. Treated water will be reused for gardening.

2.9.3 Details of Hazardous and Non Hazardous wastes

The types of Hazardous wastes generated from the project, method of disposal is shown in table

below:

Table 2-7: Details of Proposed Solid waste along with the Category and disposal method

Hazardous Wastes

Sr. No.

Waste Name Unit Category Quantity Disposal Method

Hazardous Waste

1 Chemical Sludge from ETP T/A 35.3 175

CHWTSDF

2 MEE solids T/A 35.3 5475

3 Spent Carbon from ETP T/A 35.3 170

4 Spent Carbon from Process T/A 28.3 588

5 Process Residue T/A 28.1 2160

6 Discarded drums and containers Nos./A 33.1 2500 MPCB authorized

party for reuse

Other Wastes

1 E-waste T/A - 0.5 Sale to MPCB

authorized party

2 Battery Waste T/A - 0.5 Sale to MPCB

authorized party






Non Hazardous Wastes

Sr. No.

Waste Name Unit Quantity Disposal Method

Non-Hazardous Waste

1 Coal Ash T/A 2244.0 Sale to brick

manufacturer

2 Waste paper, Sweeping material, Etc. T/A 1.0 Scrap sale

3 Pallet T/A 2.5 Scrap sale






2.10 Schematic representations of the feasibility drawing which give information of EIA purpose.

Project Identification What environmental impacts are normally associated with such type of projects being

proposed?

Pre-feasibility Analysis Is the Project feasible from an environment point of view?

Project Design

(a) What negative environmental impacts could arise if the proposed project is implemented with proposed design?

(b) Is there alternative design with less environmental impacts?

Project Appraisal Have all the environmental concerns associated with the project been eliminated?

Project Implementation What environmental concerns might arise at the implementation phase of the project?

Preparation of an Environment Monitoring and Evaluation Plan (a) What environment monitoring indicators are required to ensure that the implementation of components of the project will be executed within environmentally

sound limits? (b) What is required to ensure that the recommended environmental control

measures will be implemented and enforced? (c)

(Prepare a comprehensive environment monitoring and management plan)

Post EIA Monitoring and Environment Audit

(a) Is the implementation of components of the project being executed in an environmentally sound manner?

(b) Are all the recommended environmental control measures being implemented and enforced?

(d) Are there any environmental impacts that were earlier not anticipated when EIA was done? ( Identify gaps and corrective action )






3.0 SITE ANALYSIS

3.1 Connectivity

Proposed unit is planned at Plot No. SEZ 14 & 15, MIDC Butibori, Nagpur, Maharashtra.

The nearest city from the site is Butibori at a distance of 5 Km.

The nearest railway station is Butibori at 6 Km

The nearest airport is at Nagpur at 20 km.

Site is well connected to Chandrapur- Nagpur highway (NH 44).

3.2 Land Form, Land use and Land ownership

The proposed land is situated in approved chemical zone of MIDC where land use is industrial. Land is

owned by MIDC and is leased for 99 years.

3.3 Topography

The industry is located at Latitude – 20°56'44.96"N and Longitude- 78°57'12.76"E. Toposheet of the

site is shown below. The study area (10 km radius) around the project site exhibits flat terrain.

Figure 3.1: Toposheet Showing Project site and 10Km of surrounding area






3.4 Existing land use pattern (agriculture, non-agriculture, forest, water bodies (including area

under CRZ), shortest distances from the periphery of the project to periphery of the forests, national

park, wild life sanctuary, eco sensitive areas, water bodies (distance from HFL of the river), CRZ.

The proposed land for setting new unit located in Notified Industrial Estate. The land is acquired by

Inventys. The proposed site is an undeveloped land which does not include agricultural, forestry, water

bodies (including CRZ) etc

3.5 Soil classification

Nagpur lies on the Deccan plateau of the Indian Peninsula and has a mean altitude of 310.5

meters above sea level. The underlying rock strata are covered with alluvial deposits resulting from

the flood plain of the Kanhan River. In some places these give rise to granular sandy soil. In low -lying

areas, which are poorly drained, the soil is alluvial clay with poor permeability characteristics. In the

eastern part of the city, crystalline such as gneiss, schist and granites are found, while in the northern

part yellowish sand stones and clays of the lower formations are found.

3.6 Climatic data from secondary sources

As Nagpur is located at the center of the, far from the Bay of Bengal and the Arabian Sea, it has

tropical wet and dry climate with dry conditions prevailing for most of the year.

Temperature: Summers are extremely hot, lasting from March to June, with May being the

hottest month. Winter lasts from November to January, during which temperatures can drop

below 10 °C (50 °F). The highest recorded temperature in the city was 48.6 °C on 29 May 2012,

while the lowest was 3.9 °C.

Rainfall: It receives an annual rainfall of 1,205 mm (47.44 inches) from monsoon rains during

June to September. The highest recorded daily rainfall was 304 mm.

3.7 Social Infrastructure Availability

Key infrastructure such as hospitals, schools, bank, places of worship and social/ community

facilities such as park, market, playground etc. education, health care, community development,

income distribution, employment and social welfare are available in nearby area of Maharashtra

Industrial Estate.






4.0 Planning in Brief

4.1 Planning Concept

Proposed plant activities will be started after getting statutory clearance from related authorities. The project

will be completed within 6-8 months. Further proposed project activities will take care of all the rules and

regulation of statutory authority and provide the control measure and devices to achieve the standard norms.

Further proposed project activities will take care of all the rules and regulation of statutory authority and

provide the control measure and devices to achieve the standard norms.

4.2 Land Use Planning

Existing land is undeveloped and located in a notified industrial area. The total plot area is

69025.55 sq.m.

Table 4-2: Land Use Break Up

Sr. No. Particular Area in Sq.m

1 Area For Manufacturing 14080

2 RM & Product storages area 1403

3 Utility area 1677

4 Office Building, security 950

5 Water tank and fire fighting 1879

6 Hydrogen Trolly area 535

7 ETP & MEE 1321

8 Tank farm & fuel storage 4272

9 Open area & Internal road 11834.55

10 Green belt area (33% of total plot area) 22790

11 Parking area 8284

Total 69025.55






4.3 Assessment of Infrastructure Demand (Physical & Social)

Key infrastructure such as hospitals, schools, bank, places of worship and social/ community

facilities such as park, market, playground etc. education, health care, community development,

income distribution, employment and social welfare are available in nearby area of Maharashtra

Industrial Estate.

4.4 Amenities/Facilities

In proposed site many basic facilities like uninterrupted water supply, Power and Road

Network & solids disposal facility if feasible are available. This site is inside the campus of the MIDC

and means safe transportation, less need of utilities, less constructing buildings and roads, less fuel,

less water with optimization of infrastructure and networking with CHWSTDF (Common Hazardous

Waste Storage Treatment and Disposal facility), in vicinity established with support of MIDC and

MPCB.

All nearby villages are provided with drinking water from wells or Government Water Supply

Schemes RWS. Hence we do not encroach upon their supply.

4.5 Population Projection

Population plays a key role in the development of the agriculture of the region. Like other districts of

Maharashtra, Nagpur is essentially a district of villages. In 2011, Nagpur had population of 4,653,171 of

which male and female were 2,388,558 and 2,264,613 respectively. In 2001 census, Nagpur had a

population of 4,067,637 of which males were 2,105,314 and remaining 1,962,323 were females. In 2011, the

average literacy rate of Nagpur was 82.81 %.






5.0 Proposed infrastructure

5.1 Industrial area

Industrial Area (Processing area)

Utilities

Cooling tower

ETP

STP

Non- Processing Area

Administrative Cabins

Security cabins

Workers restroom

Water reservoirs

Temporary storage sites

Works block etc.

5.2 Residential Area

There is no residential area proposed at Site.

5.3 Green Belt

The project is built on an MIDC plot with plot area of 69025.55 Sq.m and green belt area is 22790

Sq.m. will be developed to fulfill the statutory requirement (33% of plot area as Green Belt). Around

3000 nos. of trees and shrubs will planted at the site and details will be provided in EIA report.

5.4 Social Infrastructure

The basic amenities within the study area include primary schools, dispensaries, water supply, electric

supply, public telephones, hotels, banks, post offices, petrol pumps, bus services, technical training

institute and entertainment etc.






5.5 Connectivity

Proposed unit is planned at Plot No. SEZ 14 & 15, MIDC Butibori, Nagpur, Maharashtra.

The nearest city from the site is Butibori at a distance of 5 Km.

The nearest railway station is Butibori at 6 Km

The nearest airport is at Nagpur at 20 km.

Site is well connected to Chandrapur- Nagpur highway (NH 44).

5.6 Drinking Water Management

The source of water supply is from MIDC Butibori.

5.7 Sewage System

Domestic sewage will be treated in proposed STP of 50 CMD. Treated water will be reused for gardening.

5.8 Industrial Water Management

Water requirement is fulfilled through MIDC. Total water required for the proposed project will be 1452.5

CMD out of which 44 CMD water will be recycled. From 2ndday onward the total water requirement will be

1408.5 CMD. Treated effluent will be send to CETP for disposal.

5.9 Solid Waste Management

Hazardous solid waste generated from the process and from ETP will be collected, stored, transported

and sent to CHWTSDF as per Hazardous waste (Management, Handling and Transboundry Movement)

Rules 2008.

5.10 Power Requirement & Supply / source

Power requirement of proposed project will be made available through State Electricity Board. Power

requirement of proposed plant is as below:

Power requirement: 10 MW

04 nos. of D. G. sets of capacity 1500 KVA each, will be proposed to meet emergency power requirement of

the plant.






6.0 Rehabilitation and Resettlement (R & R) Plan

6.1 Policy to be adopted (Central/State) in respect of the project affected persons including home

oustees, land oustees and landless.

Rehabilitation and Resettlement (R&R) plan is not applicable for the proposed project as the proposed project

will be in notified MIDC.






7.0 PROJECT SCHEDULE & COST ESTIMATES

7.1 Likely date of start of construction and likely date of completion

The New activity is likely to start after getting Environmental Clearance and NOC/CTE from the

authorized committee.

7.2 Estimated project cost along with analysis in terms of economic viability of the project

The total investment envisaged is Rs. 110 Cr with the break-up as given below Error! Reference s

ource not found.

7.3 Economic Viability

The project has been conceived assuming that there will be a growth in demand for the proposed

products, leading to a reasonable rate of return in the medium term. The project is considered

‘bankable’.






8.0 ANALYSIS OF PROPOSAL (FINAL RECOMMENDATIONS)

Proposed activity will provide benefits to the local people in terms of financial and social welfare.

Local people will get direct financial benefit by way of employment.

Local people will get some contract of supply and services to get indirect income.

Company will contribute in improving education and health facilities in nearby area.






Annexure –I: Plant Layout

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