INTRODUCTORY RAMAN SPECTROSCOPY1 .7. Selection Rules for Infrared and Raman Spectra 22 1 .8. Raman...
Transcript of INTRODUCTORY RAMAN SPECTROSCOPY1 .7. Selection Rules for Infrared and Raman Spectra 22 1 .8. Raman...
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INTRODUCTOR Y
RAMAN SPECTROSCOPY
John R. Ferraro
Kazuo Nakamoto
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Preface
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Acknowledgements
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Chapter 1 .
Basic Theory
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1 .1 .
Historical Background of Raman Spectroscopy
1
1 .2 .
Energy Units and Molecular Spectra
2
1 .3 .
Vibration of a Diatomic Molecule
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1 .4 .
Origin of Raman Spectra
1 3
1 .5 .
Factors Determining Vibrational Frequencies
1 81 .6 .
Vibrations of Polyatomic Molecules
1 91 .7 .
Selection Rules for Infrared and Raman Spectra
2 2
1 .8 .
Raman versus Infrared Spectroscopy
2 61 .9 .
Depolarization Ratios
2 7
1 .10 . The Concept of Symmetry
2 91 .11 .
Point Symmetry Elements
3 01 .12 . The Character Table
4 11 .13 . Classification of Normal Vibrations by Symmetry
4 7
1 .14 .
Symmetry Selection Rules
5 1
1 .15 . Resonance Raman Spectra
5 3
1 .16 . Space Group Symmetry
591 .17 .
Normal Vibrations in a Crystal
661 .18 .
Selection Rules for Solids (Factor Group)
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1 .19 .
Polarized Raman Spectra of Single Crystals
7 81 .20 .
Normal Coordinate Analysis
7 91 .21 .
Band Assignments and Isotopic Shifts
8 7References
9 0
Chapter 2 .
Instrumentation and Experimental Techniques
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2 .1 . Major Components
9 52.2 .
Excitation Sources
9 62.3 .
Sample Illumination
10 22.4. The Monochromator
10 42.5 .
Detection
10 72 .6.
Instrument Calibration
11 3
2.7 .
Sampling Techniques
11 82 .8 .
Determination of Depolarization Ratios
12 92 .9.
Raman Difference Spectroscopy
12 9General References
13 2
References
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Chapter 3 .
Special Techniques
13 5
3 .1 . Nonlinear Raman Spectroscopy
13 5
3 .2 . Time-Resolved Raman (TR') Spectroscopy
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3 .3 .
Matrix-Isolation Raman Spectroscopy
14 7
3 .4 . High-Pressure Raman Spectroscopy
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3 .5 . Surface-Enhanced Raman Spectroscopy (SERS)
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3 .6 .
Raman Spectroelectrochemistry
16 5
3 .7 . Raman Microscopy
17 2
3 .8 . FT-Raman Spectroscopy
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3 .9 . New Raman Imaging Spectrometry
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References
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Chapter 4 .
Applications
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4 .1 .
Applications to Structural Chemistry
19 54 .2 .
Applications to Biochemistry, Biology and Medicine
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4 .3 .
Solid State Applications
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4 .4 .
Industrial Applications
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References
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Appendices
30 5Index
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