INTERREG III: STARDUST
description
Transcript of INTERREG III: STARDUST
Lille, 18/09/03
INTERREG III: STARDUST
January 2003- September 2003
VLIZ
Lille, 18/09/03
First joint sampling expedition Rupel River
Sampling site
•Intertidal flat: easily sampled at low tide•expect relatively contaminated sediments•organic rich sediments
Lille, 18/09/03
Porewater analysis by DGT/DET/coring•Interlaboratory intercomparison•identify problems•establish protocol for further work
Aim
Methods used•Coring by hand•porewater separation: on field USTL, in lab VUB•cores for DGT and DET transported to the lab
•DGT and DET probes deployed at room temperature for 24h (2 cores)•USTL: DGT diffusive gels 0.8 and 1.2mm
in same core•VUB: DGT diffusive gels 0.8 and 0.8mm
in different cores
Lille, 18/09/03
Co DET
-16
-14
-12
-10
-8
-6
-4
-2
0
2
4
0 10 20 30 40
µg/L
de
pth
cm core 1
core 2
USTL
Co DGT VUB
-16
-14
-12
-10
-8
-6
-4
-2
0
2
4
0 5 10
µg/L
core 1
core 2
Co DGT USTL
-12
-10
-8
-6
-4
-2
0
2
4
0 1 2
µg/L
USTL 0.8
USTL 1.2
Mn DET
-16
-14
-12-10
-8
-6
-4
-20
2
4
0 2000 4000 6000
µg/L
de
pth
cm core 1
core 2
USTL
Mn DGT
-16
-14
-12
-10
-8
-6
-4
-2
0
2
4
0 100 200 300
µg/L
core 1
core 2
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Fe DET
-16
-14
-12
-10
-8
-6
-4
-2
0
2
4
0 100000 200000 300000 400000 500000
µg/L
de
pth
cm core 1
core 2
Fe DGT
-16
-14
-12
-10
-8
-6
-4
-2
0
2
4
0 5000 10000 15000 20000
µg/L
core 1
core 2
As DET
-16
-14
-12
-10
-8
-6
-4
-2
0
2
4
0 100 200 300
µg/L
de
pth
cm
core 1
core 2
As DGT
-16
-14
-12
-10
-8
-6
-4
-2
0
2
4
0 10 20
µg/L
de
pth
cm
core 1
core 2
DET DGT
Fe
As
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Cd DGT
-15
-10
-5
0
5
0.00 0.10 0.20 0.30
µg/L
de
pth
cm
core 1
core 2Cd
-12
-10
-8
-6
-4
-2
0
2
4
0.00 0.05 0.10
concentration (ppb)
pro
fon
de
ur
(cm
)
0,8 mm
1.2 mm
Cd
-12.00
-10.00
-8.00
-6.00
-4.00
-2.00
0.00
2.00
4.00
0.00 1.00 2.00 3.00 4.00
concentration (ppb)
pro
fon
de
ur
(cm
)
DET
Cd cen
-10
-5
0
5
0 1 2 3
µg/L
de
pth
cm
DGT VUB DGT USTL
centrifugationDET USTL
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Pb DGT
-15
-10
-5
0
5
0 2 4 6
µg/L
de
pth
cm
core 1
core 2
Pb
-12
-10
-8
-6
-4
-2
0
2
4
0.00 0.50 1.00 1.50
concentration (ppb)
pro
fon
de
ur
(cm
)
0,8 mm
1.2 mm
Pb cen
-10
-5
0
5
0 2 4 6 8 10
µg/L
de
pth
cm
DGT VUB DGT USTL
centrifugation
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Ni DGT
-15
-10
-5
0
5
0 2 4 6 8
µg/L
dept
h cm core 1
core 2
Ni
-12
-10
-8
-6
-4
-2
0
2
4
0.00 2.00 4.00
concentration (ppb)
pro
fon
de
ur
(cm
)
0.8 mm
1.2 mm
Cu
-12
-10
-8
-6
-4
-2
0
2
40.00 0.20 0.40 0.60 0.80 1.00
concentration (ppb)
pro
fon
de
ur
(cm
)
0.8 mm
1.2 mm
Cu DGT
-15
-10
-5
0
5
0 1 2 3 4
µg/L
de
pth
cm
core 1
core 2
DGT VUB DGT USTL
Ni
Cu
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Zn DGT
-15
-10
-5
0
5
0 20 40 60 80
µg/L
de
pth
cm core 1
core 2
Zn
-12
-10
-8
-6
-4
-2
0
2
40.00 5.00 10.00 15.00
concentration (ppb)
0,8 mm
1.2 mm
Zn
-12.00
-10.00
-8.00
-6.00
-4.00
-2.00
0.00
2.00
4.00
0.00 100.00 200.00 300.00 400.00 500.00
concentration (ppb)
pro
fon
de
ur
(cm
)
DET
Zn
-10
-5
0
5
0 100 200 300 400
µg/L
de
pth
cm
DGT VUBDGT USTL
centrifugation DET USTL