INTERREG III: STARDUST

9
Lille, 18/09/03 INTERREG III: STARDUST January 2003- September 2003 VLIZ

description

INTERREG III: STARDUST. January 2003- September 2003. VLIZ. First joint sampling expedition Rupel River. Sampling site. Intertidal flat: easily sampled at low tide expect relatively contaminated sediments organic rich sediments. Porewater analysis by DGT/DET/coring. Aim. - PowerPoint PPT Presentation

Transcript of INTERREG III: STARDUST

Page 1: INTERREG III: STARDUST

Lille, 18/09/03

INTERREG III: STARDUST

January 2003- September 2003

VLIZ

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Lille, 18/09/03

First joint sampling expedition Rupel River

Sampling site

•Intertidal flat: easily sampled at low tide•expect relatively contaminated sediments•organic rich sediments

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Porewater analysis by DGT/DET/coring•Interlaboratory intercomparison•identify problems•establish protocol for further work

Aim

Methods used•Coring by hand•porewater separation: on field USTL, in lab VUB•cores for DGT and DET transported to the lab

•DGT and DET probes deployed at room temperature for 24h (2 cores)•USTL: DGT diffusive gels 0.8 and 1.2mm

in same core•VUB: DGT diffusive gels 0.8 and 0.8mm

in different cores

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Co DET

-16

-14

-12

-10

-8

-6

-4

-2

0

2

4

0 10 20 30 40

µg/L

de

pth

cm core 1

core 2

USTL

Co DGT VUB

-16

-14

-12

-10

-8

-6

-4

-2

0

2

4

0 5 10

µg/L

core 1

core 2

Co DGT USTL

-12

-10

-8

-6

-4

-2

0

2

4

0 1 2

µg/L

USTL 0.8

USTL 1.2

Mn DET

-16

-14

-12-10

-8

-6

-4

-20

2

4

0 2000 4000 6000

µg/L

de

pth

cm core 1

core 2

USTL

Mn DGT

-16

-14

-12

-10

-8

-6

-4

-2

0

2

4

0 100 200 300

µg/L

core 1

core 2

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Lille, 18/09/03

Fe DET

-16

-14

-12

-10

-8

-6

-4

-2

0

2

4

0 100000 200000 300000 400000 500000

µg/L

de

pth

cm core 1

core 2

Fe DGT

-16

-14

-12

-10

-8

-6

-4

-2

0

2

4

0 5000 10000 15000 20000

µg/L

core 1

core 2

As DET

-16

-14

-12

-10

-8

-6

-4

-2

0

2

4

0 100 200 300

µg/L

de

pth

cm

core 1

core 2

As DGT

-16

-14

-12

-10

-8

-6

-4

-2

0

2

4

0 10 20

µg/L

de

pth

cm

core 1

core 2

DET DGT

Fe

As

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Cd DGT

-15

-10

-5

0

5

0.00 0.10 0.20 0.30

µg/L

de

pth

cm

core 1

core 2Cd

-12

-10

-8

-6

-4

-2

0

2

4

0.00 0.05 0.10

concentration (ppb)

pro

fon

de

ur

(cm

)

0,8 mm

1.2 mm

Cd

-12.00

-10.00

-8.00

-6.00

-4.00

-2.00

0.00

2.00

4.00

0.00 1.00 2.00 3.00 4.00

concentration (ppb)

pro

fon

de

ur

(cm

)

DET

Cd cen

-10

-5

0

5

0 1 2 3

µg/L

de

pth

cm

DGT VUB DGT USTL

centrifugationDET USTL

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Pb DGT

-15

-10

-5

0

5

0 2 4 6

µg/L

de

pth

cm

core 1

core 2

Pb

-12

-10

-8

-6

-4

-2

0

2

4

0.00 0.50 1.00 1.50

concentration (ppb)

pro

fon

de

ur

(cm

)

0,8 mm

1.2 mm

Pb cen

-10

-5

0

5

0 2 4 6 8 10

µg/L

de

pth

cm

DGT VUB DGT USTL

centrifugation

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Ni DGT

-15

-10

-5

0

5

0 2 4 6 8

µg/L

dept

h cm core 1

core 2

Ni

-12

-10

-8

-6

-4

-2

0

2

4

0.00 2.00 4.00

concentration (ppb)

pro

fon

de

ur

(cm

)

0.8 mm

1.2 mm

Cu

-12

-10

-8

-6

-4

-2

0

2

40.00 0.20 0.40 0.60 0.80 1.00

concentration (ppb)

pro

fon

de

ur

(cm

)

0.8 mm

1.2 mm

Cu DGT

-15

-10

-5

0

5

0 1 2 3 4

µg/L

de

pth

cm

core 1

core 2

DGT VUB DGT USTL

Ni

Cu

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Zn DGT

-15

-10

-5

0

5

0 20 40 60 80

µg/L

de

pth

cm core 1

core 2

Zn

-12

-10

-8

-6

-4

-2

0

2

40.00 5.00 10.00 15.00

concentration (ppb)

0,8 mm

1.2 mm

Zn

-12.00

-10.00

-8.00

-6.00

-4.00

-2.00

0.00

2.00

4.00

0.00 100.00 200.00 300.00 400.00 500.00

concentration (ppb)

pro

fon

de

ur

(cm

)

DET

Zn

-10

-5

0

5

0 100 200 300 400

µg/L

de

pth

cm

DGT VUBDGT USTL

centrifugation DET USTL