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  • Copyright 2011 - Air Products and Chemicals, Inc.

    Innovations in Natural Gas

    Liquefaction Technology for

    Floating LNG

    Justin Bukowski (Speaker) Yu Nan Liu Stephen Boccella Leo Kowalski

    1

  • Copyright 2011 - Air Products and Chemicals, Inc.

    LNG Prospects

    2

    FLNG

    Land-based

  • Copyright 2011 - Air Products and Chemicals, Inc.

    85 LNG heat exchangers / 40 years 24 turboexpanders Integrated offering with several high

    efficiency refrigeration process cycles

    Air Products LNG Technology

    and Equipment

    3

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Air Products Liquefaction

    Processes for FLNG Applications

    Train Capacity, MTA

    0 1 2 3 4 5+

    N2: AP-NTM

    Pre-Cooled N2: AP-HNTM

    Pre-Cooled MR: AP-C3MRTM

    /AP-DMRTM

    /AP-HMRTM

    MR: AP-SMRTM

    4

  • Copyright 2011 - Air Products and Chemicals, Inc.

    N2 Recycle

    LNG

    Natural Gas Nitrogen

    ~ 1 MTPA

    No HC refrigerant

    All Vapor

    5

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Dual Mixed Refrigerant LNG

    Cold

    Mixed Refrigerant

    MRV

    MRL

    Natural Gas

    Warm

    Mixed

    Refrigerant

    High Efficiency

    High Capacity

    6

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Wound Coil Heat Exchanger

    Natural

    Gas

    LNG

    Tube Bundles

    Natural gas liquefied

    in wound coil tubes

    Refrigerant flows

    down over outside of

    tubes

    7

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Wound Coil Exchangers

    for Safety and Reliability

    Liquefying hydrocarbons can cause high

    thermal stresses due to inherent

    refrigerant/load imbalances

    Wound Coil Exchangers proven to

    withstand thermal stresses

    Dual containment high pressure hydrocarbons

    contained in tubes within a pressure vessel shell.

    Containment important to FLNG safety

    8

  • Copyright 2011 - Air Products and Chemicals, Inc.

    WCHE for Floating LNG

    FLNG vessel subject to motion

    Exchanger design verification

    Mechanical strength

    Process flow effects

    9

  • Copyright 2011 - Air Products and Chemicals, Inc.

    WCHE Mechanical

    Design Verification for FLNG

    Pressure vessel design

    Considered North Sea 100 year storm conditions for strength,

    with 25 year service life for fatigue

    Exchanger design meets fatigue criteria set by DNV

    Design method certified by DNV

    Internal bundle support system

    Tested cyclic loads due to wave motion, based

    on North Sea 100 year storm conditions

    Demonstrated resistance to wear

    or distress that would impair function

    10

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Wound Coil Exchangers

    for FLNG: Process Effects

    Flow through tubes

    Pressure driven, not affected by ship motion

    Liquid flow through shell-side distributors

    Performance insensitive to motion, as verified by computational

    fluid dynamics and experimental testing

    Flow on shell-side of exchanger

    Motion may affect how liquid flows over the tube bundle

    Liquid distribution may affect heat transfer performance

    Effects are mitigated by proper bundle design, using Air

    Products enhanced design tools

    11

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Development of Enhanced

    Wound Coil Exchanger Design Tools

    Fundamental Fluid Flow Experiments & Analysis

    Institute of Thermophysics, Russia

    Enhanced Wound Coil Exchanger

    Design Tools

    12

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Fundamental Fluid Flow Experiments & Analysis

    Laboratory measurements provide inputs to

    hydraulic flow model

    Experiments performed with water,

    water- surfactant mix, and hydrocarbons

    Experiments give hydraulic

    behavior under tilt conditions

    13

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Development of Enhanced

    Wound Coil Exchanger Design Tools

    Fundamental Fluid Flow Experiments & Analysis

    Institute of Thermophysics, Russia

    Enhanced Wound Coil Exchanger

    Design Tools

    Pilot Plant Test Bundle Liquid Flow with Bundle Oscillations

    Heriot-Watt University, Scotland

    Verify

    Model

    14

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Pilot Scale Experiments Liquid Flow with Bundle Oscillations

    Testing performed at Heriot-Watt University in Scotland

    Flow distribution data under static tilt and oscillation (pitch/roll)

    15

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Validation of Model

    Model validated by comparison to

    Heriot-Watt pilot scale data

    16

    High side Low side

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Development of Enhanced

    Wound Coil Exchanger Design Tools

    Fundamental Fluid Flow Experiments & Analysis

    Institute of Thermophysics, Russia

    Enhanced Wound Coil Exchanger

    Design Tools

    Pilot Plant Test Bundle Liquid Flow with Bundle Oscillations

    Heriot-Watt University, Scotland

    Dynamic Simulations & CFD Effect of Motion on Heat Transfer

    Verify

    Model

    17

  • Copyright 2011 - Air Products and Chemicals, Inc.

    FLNG Exchanger Design

    Key Motion Variables

    Static tilt

    Pitch/roll

    Oscillation period

    Exchanger elevation

    Key Design Variables

    Duty and temperatures

    Bundle geometry

    Shell-side flow

    18

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Design for FLNG Motion

    Exchangers are typically designed for full production at

    maximum ship motions expected majority of the year

    (e.g. ~99% occurrence probability)

    Typical design point: Pitch/roll of 3 degrees or less

    For higher ship motion:

    Have analyzed for ship motions up to 6 degrees pitch/roll and

    these can be accommodated with small impact

    At larger motion, heat exchangers continue to operate with

    possible reduction in production or increase in power

    requirement

    19

  • Copyright 2011 - Air Products and Chemicals, Inc.

    0

    20

    40

    60

    80

    100

    120

    0.0 0.2 0.4 0.6 0.8 1.0 1.2

    % L

    NG

    Pro

    du

    ctio

    n,

    Re

    lati

    ve t

    o N

    o-T

    ilt

    Static Tilt Angle, degrees

    Sensitivity to Static Tilt

    20

    Typical

    FLNG

    Vessel

  • Copyright 2011 - Air Products and Chemicals, Inc.

    0

    20

    40

    60

    80

    100

    120

    0 5 10 15 20 25 30 35

    % L

    NG

    Pro

    du

    ctio

    n,

    Re

    lati

    ve t

    o N

    o-T

    ilt

    Period, sec

    Sensitivity to Oscillation Period

    21

    Typical

    FLNG

    Vessel

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Summary

    Air Products offers a robust wound coil exchanger

    design and a selection of process cycles for FLNG

    Air Products has developed a detailed approach to

    understanding impact of motion on the heat exchanger:

    Both experimental and theoretical

    Includes the significant inputs and design parameters

    Effects are quantified

    For typical FLNG motion

    Effects are mitigated by proper bundle design, using Air

    Products enhanced design tools

    22

  • Copyright 2011 - Air Products and Chemicals, Inc.

    Thank You

    23