IGM RESINS B.V.
Transcript of IGM RESINS B.V.
IGM RESINS B.V.P/O VN LOGISTICS B.V.DE PANOVEN 104191 GW GELDERMALSENTHE NETHERLANDS
VN LOGISTICS B.V.PANOVEN 10 VN LOGISTICS B.V.
PANOVEN 10
J. VAN KUIJL
(EMEA) +1 760 476 3961 access code 333 293
1 1
UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one), 9, III MARINE POLLUTANT
S. de Vries
Frimpeks Kimya Ve Etiket San. Tic. A.S.Mermerciler Sanayi Sitesi, Cad. 15 834524 BEYLIKDUZU, ISTANBULTURKIJE
6 CARTON(4G one inner plastic bag) OF 20.000 KG, 120.000 KG NETTO / 131.000 KG GROSS
GELDERMALSEN 20-10-2021 GELDERMALSEN 20-10-2021
IGM RESINS B.V.P/O VN LOGISTICS B.V.DE PANOVEN 104191 GW GELDERMALSENTHE NETHERLANDS
VN LOGISTICS B.V.PANOVEN 10 VN LOGISTICS B.V.
PANOVEN 10
J. VAN KUIJL
(EMEA) +1 760 476 3961 access code 333 293
1 1
UN 3077,ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Methyl 2-benzoylbenzoate), 9,III, marine pollutant.
S. de Vries
Frimpeks Kimya Ve Etiket San. Tic. A.S.Mermerciler Sanayi Sitesi, Cad. 15 834524 BEYLIKDUZU, ISTANBULTURKIJE
10 CARTONS(4G one inner plastic bag) OF 20.000 KG, 200.000 KG NETTO / 222.000 KG GROSS
GELDERMALSEN 20-10-2021 GELDERMALSEN 20-10-2021
IGM RESINS B.V.P/O VN LOGISTICS B.V.DE PANOVEN 10 - PAND 14191 GW GELDERMALSENTHE NETHERLANDS
(EMEA) +1 760 476 3961 ## 333 293
VN LOGISTICS B.V.VN LOGISTICS B.V.
J. VAN KUIJL
UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III.Marine Pollutant
J. VAN LOENEN
Frimpeks Kimya Ve Etiket San. Tic. A.S.Mermerciler Sanayi Sitesi, Cad. 15 834524 BEYLIKDUZU, ISTANBULTURKIJE
1 IBC (3H1) OF 1000 KG. TOTAL NET: 1000.00 KG, TOTAL GROSS: 1059.00 KG
GELDERMALSEN , 20-10-2021 GELDERMALSEN , 20-10-2021
IGM RESINS B.V.P/O VN LOGISTICS B.V.DE PANOVEN 104191 GW GELDERMALSENTHE NETHERLANDS
VN LOGISTICS B.V.PANOVEN 10 VN LOGISTICS B.V.
PANOVEN 10
J. VAN KUIJL
UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide),9,III,(-)
1 1
(EMEA) +1 760 476 3961 access code 333 293
J. VAN LOENEN
Frimpeks Kimya Ve Etiket San. Tic. A.S.Mermerciler Sanayi Sitesi, Cad. 15 834524 BEYLIKDUZU, ISTANBULTURKIJE
3 CARTONS (4G one inner plastic bag) OF 20.000 KG, 60.00 KG NETTO / 66.00 KG GROSS
GELDERMALSEN 21-10-2021 GELDERMALSEN 21-10-2021
IGM RESINS B.V.P/O VN LOGISTICS B.V.DE PANOVEN 10 - PAND 14191 GW GELDERMALSENTHE NETHERLANDS
(EMEA) +1 760 476 3961 ## 333 293
VN LOGISTICS B.V.VN LOGISTICS B.V.
J. VAN KUIJL
UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate, Acrylic acid), 9, III. Marine Pollutant
1
2 IBC'S(31HA1) OF 1000 KG. TOTAL NET: 2000.000 KG, TOTAL GROSS: 2118.000 KG
S. de Vries
Frimpeks Kimya Ve Etiket San. Tic. A.S.Mermerciler Sanayi Sitesi, Cad. 15 834524 BEYLIKDUZU, ISTANBULTURKIJE
GELDERMALSEN , 20-10-2021 GELDERMALSEN , 20-10-2021
SAFETY DATA SHEETThis safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006Commission Regulation (EU) No 2015/830 of 28 May 2015
Issuing Date 09-Jun-2020 Revision date 09-Jun-2020 Revision Number 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier
Product Code(s) 10000161
Product Name Omnirad 379
REACH registration number 01-2120040688-50-0000
EC No 438-340-0
CAS No 119344-86-4
Chemical name 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one
Pure substance/mixture Substance
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use Photoinitiator.
Uses advised against Consumer use.
1.3. Details of the supplier of the safety data sheet
For further information, please contact E-mail address [email protected] 1.4. Emergency telephone number
Emergency Telephone (EMEA) +1 760 476 3961 ## 333 293 Emergency Telephone §45 - (EC)1272/2008 Europe 112
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 Reproductive toxicity Category 2 - (H361) Chronic aquatic toxicity Category 1 - (H410)
2.2. Label elements
SupplierIGM Resins B.V Gompenstraat 49 5145 RM Waalwijk T: +31 (0) 416 316 657 F: +31 (0) 416 564 632
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Signal wordWarning
Hazard statements H361 - Suspected of damaging fertility or the unborn childH410 - Very toxic to aquatic life with long lasting effects
Precautionary Statements - EU (§28, 1272/2008)P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP273 - Avoid release to the environmentP280 - Wear protective gloves/protective clothing/eye protection/face protectionP308 + P313 - IF exposed or concerned: Get medical advice/attentionP391 - Collect spillageP405 - Store locked upP501 - Dispose of contents/ container to an approved waste disposal plant
Additional informationThis product requires tactile warnings if supplied to the general public.
2.3. Other hazards No information available
SECTION 3: Composition/information on ingredients
3.1 Substances
Chemical name EC No CAS No Weight-% Classification according to Regulation (EC) No.
1272/2008 [CLP]
REACH registration
number 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]
butan-1-one
438-340-0 119344-86-4 >95% Repr. 2 (H361)Aquatic Chronic 1 (H410)
01-2120040688-50-XXXX
Chemical name CAS No Specific concentration limit (SCL)
M-Factor M-Factor (long-term)
2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one
119344-86-4 1
Full text of H- and EUH-phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
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General advice Show this safety data sheet to the doctor in attendance.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a doctor. Remove contact lenses, if present and easy to do. Continue rinsing.
Skin contact Wash skin with soap and water. In the case of skin irritation or allergic reactions see a doctor.
Ingestion Clean mouth with water and drink afterwards plenty of water.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms No information available.
4.3. Indication of any immediate medical attention and special treatment needed
Note to doctors Treat symptomatically.
SECTION 5: Firefighting measures 5.1. Extinguishing media
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical.
Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.
5.2. Special hazards arising from the substance or mixture
Specific hazards arising from the chemical
No information available.
Hazardous combustion products Thermal decomposition can lead to release of toxic and corrosive gases/vapours. Carbon monoxide.
5.3. Advice for firefighters
Special protective equipment for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation.
For emergency responders Use personal protection recommended in Section 8.
6.2. Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information.
6.3. Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
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6.4. Reference to other sections
Reference to other sections See section 8 for more information. See section 13 for more information.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Remove contaminated clothing and shoes.
General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and immediately after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions Store in a cool, dry area away from potential sources of heat, open flames, sunlight or other chemicals. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store locked up.
7.3. Specific end use(s)
Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters
Exposure Limits .
Biological occupational exposure limits
Derived No Effect Level (DNEL)
Derived No Effect Level (DNEL) Worker
Derived No Effect Level (DNEL) 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Type Worker Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 1.4 mg/m³
Type Worker Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 0.2 mg/kg bw/d Derived No Effect Level (DNEL) General Population
Derived No Effect Level (DNEL) 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Type Consumer Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 0.35 mg/m³
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Type Consumer Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 0.1 mg/kg bw/d
Type Consumer Long term Systemic health effects Exposure route Oral Derived No Effect Level (DNEL) 0.1 mg/kg bw/d
Predicted No Effect Concentration (PNEC)
.
Predicted No Effect Concentration (PNEC) 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Environmental compartment Predicted No Effect Concentration (PNEC) Microorganisms in sewage treatment 10 mg/l
8.2. Exposure controls
Personal protective equipment
Eye/face protection Eye protection must conform to standard EN 166.
Hand protection Wear suitable gloves. Gloves must conform to standard EN 374.
Gloves Duration of contact PPE - Glove material Glove thickness Break through time
Long term (repeated) Nitrile rubber 0.4 mm 480 minutes Butyl rubber 0.4 mm 4 hours
Skin and body protection Wear suitable protective clothing.
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and immediately after handling the product.
Environmental exposure controls No information available.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state Solid Appearance Powder. Colour light yellow. Odour Not determined. Odour threshold Not determined
Property Values Remarks • Method pH Not determined Melting point / freezing point 68 °C Boiling point / boiling range 270 °C Flash point 178 °C CC (closed cup) Evaporation rate Not determined Flammability (solid, gas) Does not ignite Flammability Limit in Air
Upper flammability or explosive
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9.2. Other information Softening point Not determined Molecular weight Not determined VOC Content (%) No information available Liquid Density Not determined Bulk density Not determined
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity No information available.
10.2. Chemical stability
Stability Stable under normal conditions.
Explosion data Sensitivity to mechanical impact None. Sensitivity to static discharge None.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions None under normal processing.
Hazardous polymerisation Polymerisation can occur.
10.4. Conditions to avoid
Conditions to avoid Extremes of temperature and direct sunlight.
10.5. Incompatible materials
Incompatible materials None known based on information supplied.
10.6. Hazardous decomposition products
Hazardous decomposition products None known based on information supplied.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Information on likely routes of exposure
limits Lower flammability or explosive limits
Vapour pressure < 0.0000013 Pa @ 25 °C Vapour density Relative density 1.160 @ 20 °C Water solubility 0.0028 g/l @ 20 °C Solubility(ies) Not determined. Partition coefficient log Pow = 4.1 @ 25 °C Autoignition temperature Not auto-flammable °C Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic viscosity Not determined
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Product Information .
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms No information available.
Numerical measures of toxicity
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 50,000.00 mg/kg ATEmix (inhalation-dust/mist) 250.50 mg/l
Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50
2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-
yl)phenyl]butan-1-one
> 2000 mg/kg ( Rat ) > 2000 mg/kg ( Rat )
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation Based on available data, the classification criteria are not met. Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Method OECD Test No. 404: Acute Dermal Irritation/Corrosion Species Rabbit Exposure route Dermal Effective dose 0.5 g Exposure time 4 hours Results Erythema 0 edema non-irritant
Serious eye damage/eye irritation Based on available data, the classification criteria are not met. Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Method OECD Test No. 405: Acute Eye Irritation/Corrosion Species Rabbit Exposure route Eye Effective dose 0.1 g Exposure time Single exposure Results non-irritant
Respiratory or skin sensitisation Based on available data, the classification criteria are not met. Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Method OECD Test No. 406: Skin Sensitisation Species Guinea pig Exposure route Dermal Results Not a skin sensitiser
Germ cell mutagenicity Based on available data, the classification criteria are not met. Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Method OECD Test No. 476: In vitro Mammalian Cell Gene Mutation Test Species in vitro
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Results Negative
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Classification based on data available for ingredients.
Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Method OECD Test No. 421: Reproduction/Developmental Toxicity Screening Test Species Rat Results NOEL (No observed effect level) 60 mg/kg bw/d
STOT - single exposure Based on available data, the classification criteria are not met.
STOT - repeated exposure Based on available data, the classification criteria are not met. Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4) Method OECD Test No. 407: Repeated Dose 28-day Oral Toxicity Study in Rodents Species Rat Exposure route Oral Exposure time 28 days Results NOEL (No observed effect level) 15 mg/kg bw/d
SECTION 12: Ecological information
12.1. Toxicity
Ecotoxicity Very toxic to aquatic life with long lasting effects.
Chemical name Algae/aquatic plants Fish Toxicity to microorganisms
Crustacea
2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]
butan-1-one
EC50: > 100 mg/l (72h, Desmodesmus subspicatus)
LC50: > 100 mg/l (96h, Danio rerio)
EC50: > 100 mg/l (3h, Activated sludge)
EC50: > 100 mg/l (48h, Daphnia magna)NOEC = 64 µg/L
(21d,Daphnia Magna)
12.2. Persistence and degradability
Persistence and degradability No information available.
Component Information 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one (119344-86-4)
Method Exposure time Value Results OECD Test No. 301B: Ready
Biodegradability: CO2 Evolution Test (TG 301 B)
28 days Biodegradation -7.4% Not readily biodegradable
12.3. Bioaccumulative potential
Bioaccumulation There is no data for this product.
Bioconcentration factor (BCF) No data available
Component Information
Chemical name Partition coefficient Bioconcentration factor (BCF) 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[ 4.1 689 - 758
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4-(morpholin-4-yl)phenyl]butan-1-one
12.4. Mobility in soil
Mobility in soil No information available.
Chemical name Surface tension Henry’s Law Constant Adsorption coefficient 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]but
an-1-one 119344-86-4
70.4 mN/m @ 20 °C 2.23 x 10 -7 Pa m3/mol log Koc = 3.5
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment
Chemical name PBT and vPvB assessment 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phe
nyl]butan-1-one The substance is not PBT / vPvB
12.6. Other adverse effects
Other adverse effects No information available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste from residues/unused products
Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.
Contaminated packaging Do not reuse empty containers.
SECTION 14: Transport information
IMDG 14.1 UN number UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9 14.4 Packing group III
Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one), 9, III, Marine pollutant
14.5 Marine pollutant Not applicable Environmental hazards Yes
14.6 Special Provisions 274, 335, 966, 967, 969 EmS-No F-A, S-F
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
No information available
RID 14.1 UN number UN3077 14.2 UN proper shipping name
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ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.
_____________________________________________________________________________________________ OR379 - Omnirad 379 Revision date 09-Jun-2020
14.3 Transport hazard class(es) 9 Labels 9
14.4 Packing group III Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.
(2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions None
Classification code M7
ADR 14.1 UN number UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9
Labels 9 14.4 Packing group III
Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 601, 375
Classification code M7
ADN 14.1 UN/ID no UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9
Hazard label(s) 9 14.4 Packing group III
Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 601
IATA 14.1 UN number UN3077 14.2 UN proper shipping name Environmentally hazardous substances, solid, n.o.s. 14.3 Transport hazard class(es) 9 14.4 Packing group III
Description UN3077, Environmentally hazardous substances, solid, n.o.s. (2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions None
ERG Code 9L
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
France Occupational Illnesses (R-463-3, France)
Germany Water hazard class (WGK) slightly hazardous to water (WGK 1)
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European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work
Authorisations and/or restrictions on use:This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)
Persistent Organic PollutantsNot applicable
Dangerous substance category per Seveso Directive (2012/18/EU)E1 - Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1
Named dangerous substances per Seveso Directive (2012/18/EU)
Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable
International Inventories
Chemical name
TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS TCSI NZIoC
2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one 119344-86-4
X X - - - - X X - X X X
Please note that the presence of a substance on an Inventory is not an indication that the substance can be supplied to that country. Additional registration (REACH, K-REACH, ...) might be required.
Legend:
X - Listed TSCA - Toxic Substances Control Act Frank R. Lautenberg Chemical Safety for the 21st Century Act (active rule) DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals TCSI - Taiwan Chemical Substance Inventory
15.2. Chemical safety assessment
Chemical Safety Report A Chemical Safety Assessment has been carried out for this substance
SECTION 16: Other information
Key or legend to abbreviations and acronyms used in the safety data sheet
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Full text of H-Statements referred to under section 3H361 - Suspected of damaging fertility or the unborn child
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H410 - Very toxic to aquatic life with long lasting effects Legend SVHC: Substances of Very High Concern for Authorisation:
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR) U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine's PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organisation for Economic Co-operation and Development Environment, Health, and Safety Publications Organisation for Economic Co-operation and Development High Production Volume Chemicals Programme Organisation for Economic Co-operation and Development Screening Information Data Set RTECS (Registry of Toxic Effects of Chemical Substances) World Health Organization
Issuing Date 09-Jun-2020
Revision date 09-Jun-2020
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value *
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Skin designation
SAFETY DATA SHEETThis safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006Commission Regulation (EU) No 2015/830 of 28 May 2015
Issuing Date 23-Jan-2020 Revision date 23-Jan-2020 Revision Number 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier
Product Code(s) 10000219 10000220 Product Name Omnirad OMBB
REACH registration number 01-2120103325-72-00001
EC No 210-112-3
CAS No 606-28-0
Chemical name Methyl 2-benzoylbenzoate
Pure substance/mixture Substance
Formula C15H12O3
Molecular weight 240.3
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use Photoinitiator.Production of UV inks, coatings and adhesives.For use in industrial installations or professional treatment only.
Uses advised against Consumer use.
1.3. Details of the supplier of the safety data sheet
For further information, please contact E-mail address [email protected] 1.4. Emergency telephone number
Emergency Telephone (EMEA) +1 760 476 3961 ## 333 293
Emergency Telephone - §45 - (EC)1272/2008 Europe 112
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008
SupplierIGM Resins B.V Gompenstraat 49 5145 RM Waalwijk T: +31 (0) 416 316 657 F: +31 (0) 416 564 632
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Specific target organ toxicity — repeated exposure Category 2 - (H373) Chronic aquatic toxicity Category 2 - (H411)
2.2. Label elements
Signal wordWarning
Hazard statements H373 - May cause damage to organs through prolonged or repeated exposureH411 - Toxic to aquatic life with long lasting effects
Precautionary Statements - EU (§28, 1272/2008)P273 - Avoid release to the environmentP314 - Get medical advice/attention if you feel unwellP391 - Collect spillageP501 - Dispose of contents/ container to an approved waste disposal plant
Additional informationThis product requires tactile warnings if supplied to the general public.
2.3. Other hazards No information available
SECTION 3: Composition/information on ingredients
3.1 Substances
Chemical name EC No CAS No Weight-% Classification according to Regulation (EC) No.
1272/2008 [CLP]
REACH registration
number Methyl 2-benzoylbenzoate 210-112-3 606-28-0 > 99% STOT RE 2 (H373)
Aquatic Chronic 2 (H411) 01-2120103325-72
-XXXX
Full text of H- and EUH-phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
General advice Show this safety data sheet to the doctor in attendance.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a doctor. Remove contact lenses, if present and easy to do. Continue rinsing.
Skin contact Wash skin with soap and water. In the case of skin irritation or allergic reactions see a doctor.
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Ingestion Clean mouth with water and drink afterwards plenty of water.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms No information available.
4.3. Indication of any immediate medical attention and special treatment needed
Note to doctors Treat symptomatically.
SECTION 5: Firefighting measures 5.1. Extinguishing media
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical.
Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.
5.2. Special hazards arising from the substance or mixture
Specific hazards arising from the chemical
No information available.
Hazardous combustion products Thermal decomposition can lead to release of toxic and corrosive gases/vapours. Carbon monoxide.
5.3. Advice for firefighters
Special protective equipment for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas.
Other information Refer to protective measures listed in Sections 7 and 8.
For emergency responders Use personal protection recommended in Section 8.
6.2. Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information.
6.3. Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
6.4. Reference to other sections
Reference to other sections See section 8 for more information. See section 13 for more information.
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SECTION 7: Handling and storage
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7.1. Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions Store in a cool, dry area away from potential sources of heat, open flames, sunlight or other chemicals. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
7.3. Specific end use(s)
Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters
Exposure Limits .
Biological occupational exposure limits
Derived No Effect Level (DNEL)
Derived No Effect Level (DNEL) Worker
Derived No Effect Level (DNEL) Methyl 2-benzoylbenzoate (606-28-0) Type Worker Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 0.367 mg/m³ Safety factor 75
Type Worker Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 0.104 mg/kg bw/d Safety factor 300 Derived No Effect Level (DNEL) General Population
Derived No Effect Level (DNEL) Methyl 2-benzoylbenzoate (606-28-0) Type General Population Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 0.184 mg/m³ Safety factor 150
Type General Population Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 0.052 mg/kg bw/d Safety factor 600
Type General Population Long term Systemic health effects Exposure route Oral
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Derived No Effect Level (DNEL) 0.052 mg/kg bw/d Safety factor 600
Predicted No Effect Concentration (PNEC)
.
Predicted No Effect Concentration (PNEC) Methyl 2-benzoylbenzoate (606-28-0) Environmental compartment Predicted No Effect Concentration (PNEC) Freshwater 9.16 µg/l Marine water 0.916 µg/l Microorganisms in sewage treatment 10 mg/l Freshwater sediment 0.219 mg/kg dry weight Marine sediment 0.022 mg/kg dry weight Soil 0.041 mg/kg dry weight Air No hazard identified
8.2. Exposure controls
Personal protective equipment
Eye/face protection Eye protection must conform to standard EN 166.
Hand protection Gloves must conform to standard EN 374.
Gloves Duration of contact PPE - Glove material Glove thickness Break through time
Nitrile rubber 0.4 mm 4 hours Butyl rubber 0.4 mm 4 hours
Skin and body protection No special protective equipment required.
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls No information available.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state Solid Appearance crystalline, Powder. Colour white, off-white. Odour Odourless. Odour threshold Not determined
Property Values Remarks • Method pH Not applicable Melting point / freezing point 48 - 54 °C Boiling point / boiling range 360 °C @97.2 kPa Flash point 154 °C Evaporation rate Not determined Flammability (solid, gas) Not determined Flammability Limit in Air
Upper flammability or explosive
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9.2. Other information Softening point Not determined Molecular weight 240.3 VOC Content (%) No information available Liquid Density Not determined Bulk density Not determined
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity No information available.
10.2. Chemical stability
Stability Stable under normal conditions.
Explosion data Sensitivity to mechanical impact None. Sensitivity to static discharge None.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions None under normal processing.
Hazardous polymerisation Polymerisation can occur.
10.4. Conditions to avoid
Conditions to avoid Extremes of temperature and direct sunlight.
10.5. Incompatible materials
Incompatible materials None known based on information supplied.
10.6. Hazardous decomposition products
Hazardous decomposition products None known based on information supplied.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Information on likely routes of exposure
Product Information .
limits Lower flammability or explosive limits
Vapour pressure 0 @ 20 °C Vapour density Relative density 1.228 @ 20 °C Water solubility 0.1177 g/L @ 20 °C Solubility(ies) Not determined. Partition coefficient 2.8 Autoignition temperature Not determined Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic viscosity Not determined
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Symptoms related to the physical, chemical and toxicological characteristics
Symptoms No information available.
Numerical measures of toxicity
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document ATEmix (inhalation-dust/mist) 501.00 mg/l
Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50
Methyl 2-benzoylbenzoate > 2000 mg/kg bw (rat) > 2000 mg/kg bw (rat)
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation Based on available data, the classification criteria are not met. Component Information Methyl 2-benzoylbenzoate (606-28-0) Method OECD 439 Species EPISKIN™ Exposure route in vitro Exposure time 4 hours Results non-irritant
Serious eye damage/eye irritation Based on available data, the classification criteria are not met. Component Information Methyl 2-benzoylbenzoate (606-28-0) Method OECD Test No. 405: Acute Eye Irritation/Corrosion Species Rabbit Exposure route Eye Effective dose 0.1 g Exposure time Single exposure Results non-irritant
Respiratory or skin sensitisation Based on available data, the classification criteria are not met. Component Information Methyl 2-benzoylbenzoate (606-28-0) Method OECD Test No. 429: Skin Sensitisation: Local Lymph Node Assay Species Mouse Exposure route Dermal Results Not a skin sensitiser
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
The table below indicates ingredients above the cut-off threshold considered as relevant which are listed as reproductive toxins. Component Information Methyl 2-benzoylbenzoate (606-28-0) Method OECD Test No. 422: Combined Repeated Dose Toxicity Study with the
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Reproduction/Developmental Toxicity Screening Test Species Rat Results Reproductive toxicity NOAEL 500 mg/kg bw/d
STOT - single exposure Based on available data, the classification criteria are not met.
STOT - repeated exposure May cause damage to organs. Component Information Methyl 2-benzoylbenzoate (606-28-0) Method OECD Test No. 422: Combined Repeated Dose Toxicity Study with the
Reproduction/Developmental Toxicity Screening Test Species Rat Exposure route Oral gavage Effective dose 31.25, 125, or 500 mg/kg bw/d Exposure time 30 days Results NOAEL 31.25 mg/kg bw/d
SECTION 12: Ecological information
12.1. Toxicity
Ecotoxicity The environmental impact of this product has not been fully investigated.
Chemical name Algae/aquatic plants Fish Toxicity to microorganisms
Crustacea
Methyl 2-benzoylbenzoate
ErC50 = 29.7 mg/l ErC10 = 12.4 mg/L (72h,
Desmodesmus subspicatus)
LC50 = 9.16 mg/l (96h, Danio rerio)
EC50 = 1000 mg/l EC10 = 100 mg/L (3h,
activated sludge)
EC50 = 26.8 mg/l (48h, Daphnia magna)
12.2. Persistence and degradability
Persistence and degradability No information available.
Component Information Methyl 2-benzoylbenzoate (606-28-0)
Method Exposure time Value Results OECD Test No. 301F: Ready Biodegradability: Manometric Respirometry Test (TG 301 F)
28 days 0 Not readily biodegradable
12.3. Bioaccumulative potential
Bioaccumulation There is no data for this product.
Bioconcentration factor (BCF) No data available
Component Information
Chemical name Partition coefficient Bioconcentration factor (BCF) Methyl 2-benzoylbenzoate 2.8
12.4. Mobility in soil
Mobility in soil No information available.
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Chemical name Surface tension Henry’s Law Constant Adsorption coefficient Methyl 2-benzoylbenzoate
606-28-0 0.001 Pa m³/mol @ 25 °C LogKoc: 2.6
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment
Chemical name PBT and vPvB assessment Methyl 2-benzoylbenzoate The substance is not PBT / vPvB
12.6. Other adverse effects
Other adverse effects No information available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste from residues/unused products
Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.
Contaminated packaging Do not reuse empty containers.
SECTION 14: Transport information
IMDG 14.1 UN number UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9 14.4 Packing group III
Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Methyl 2-benzoylbenzoate), 9, III, Marine pollutant
14.5 Marine pollutant Not applicable Environmental hazards Yes
14.6 Special Provisions 274, 335, 966, 967, 969 EmS-No F-A, S-F
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
No information available
RID 14.1 UN number UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9
Labels 9 14.4 Packing group III
Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Methyl 2-benzoylbenzoate), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions None
Classification code M7
ADR 14.1 UN number UN3077 14.2 UN proper shipping name
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ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.
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14.3 Transport hazard class(es) 9 Labels 9
14.4 Packing group III Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Methyl
2-benzoylbenzoate), 9, III 14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 601, 375
Classification code M7
ADN 14.1 UN/ID no UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9
Hazard label(s) 9 14.4 Packing group III
Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Methyl 2-benzoylbenzoate), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 601
IATA 14.1 UN number UN3077 14.2 UN proper shipping name Environmentally hazardous substances, solid, n.o.s. 14.3 Transport hazard class(es) 9 14.4 Packing group III
Description UN3077, Environmentally hazardous substances, solid, n.o.s. (Methyl 2-benzoylbenzoate), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions None
ERG Code 9L
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
France Occupational Illnesses (R-463-3, France)
Germany Water hazard class (WGK) hazardous to water (WGK 2)
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work
Authorisations and/or restrictions on use:This product contains one or more substance(s) subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)
Persistent Organic PollutantsNot applicable
Dangerous substance category per Seveso Directive (2012/18/EU)E2 - Hazardous to the Aquatic Environment in Category Chronic 2
Named dangerous substances per Seveso Directive (2012/18/EU)
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Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable
International Inventories
Chemical name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS TCSI NZIoC Methyl 2-benzoylbenzoate 606-28-0
X X X X X X X X X
Please note that the presence of a substance on an Inventory is not an indication that the substance can be supplied to that country. Additional registration (REACH, K-REACH, ...) might be required.
Legend:
X - Listed TSCA - Toxic Substances Control Act Frank R. Lautenberg Chemical Safety for the 21st Century Act (active rule) DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals TCSI - Taiwan Chemical Substance Inventory
15.2. Chemical safety assessment
Chemical Safety Report A Chemical Safety Assessment has been carried out for this substance
SECTION 16: Other information
Key or legend to abbreviations and acronyms used in the safety data sheet
Full text of H-Statements referred to under section 3H225 - Highly flammable liquid and vapourH301 - Toxic if swallowedH304 - May be fatal if swallowed and enters airwaysH311 - Toxic in contact with skinH315 - Causes skin irritationH331 - Toxic if inhaledH336 - May cause drowsiness or dizzinessH361d - Suspected of damaging the unborn childH370 - Causes damage to organsH373 - May cause damage to organs through prolonged or repeated exposureH411 - Toxic to aquatic life with long lasting effects
Legend SVHC: Substances of Very High Concern for Authorisation:
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR)
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value * Skin designation
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U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine's PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organisation for Economic Co-operation and Development Environment, Health, and Safety Publications Organisation for Economic Co-operation and Development High Production Volume Chemicals Programme Organisation for Economic Co-operation and Development Screening Information Data Set RTECS (Registry of Toxic Effects of Chemical Substances) World Health Organization
Issuing Date 23-Jan-2020
Revision date 23-Jan-2020
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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SAFETY DATA SHEETThis safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006Commission Regulation (EU) No 2015/830 of 28 May 2015
Issuing Date 12-Aug-2019 Revision date 22-Jul-2020 Revision Number 2.01
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier
Product Code(s) 10000221
Product Name Omnirad TPO
REACH registration number 01-2119972295-29-0000
EC No 278-355-8
CAS No 75980-60-8
Chemical name diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide
Pure substance/mixture Substance
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use Photoinitiator.
Uses advised against None known.
1.3. Details of the supplier of the safety data sheet
For further information, please contact E-mail address [email protected] 1.4. Emergency telephone number
Emergency Telephone (EMEA) +1 760 476 3961 ## 333 293 Emergency Telephone §45 - (EC)1272/2008 Europe 112
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 Skin sensitisation Category 1B - (H317) Reproductive toxicity Category 2 - (H361) Chronic aquatic toxicity Category 2 - (H411)
2.2. Label elements
SupplierIGM Resins B.V Gompenstraat 49 5145 RM Waalwijk The Nederlands T: +31 (0) 416 316 657 F: +31 (0) 416 564 632
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Signal wordWarning
Hazard statements H317 - May cause an allergic skin reactionH361 - Suspected of damaging fertility or the unborn childH411 - Toxic to aquatic life with long lasting effects
Precautionary Statements - EU (§28, 1272/2008)P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP272 - Contaminated work clothing should not be allowed out of the workplaceP273 - Avoid release to the environmentP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of water and soapP308 + P313 - IF exposed or concerned: Get medical advice/attentionP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash it before reuseP391 - Collect spillageP405 - Store locked upP501 - Dispose of contents/ container to an approved waste disposal plant
Additional informationThis product requires tactile warnings if supplied to the general public.
2.3. Other hazards No information available
Important health, safety and environmental informationThe classification as Repr. 2 (H361) is the harmonized classification as mentioned in Annex VI of Regulation (EC) No. 1272/2008. Test data mentioned in section 11 of this SDS however prove that classification as Repr. 1B (H360) is more suitable. IGM has updated the REACH dossier and requested that the Swedish authority start the process of amending the harmonized classification. This SDS was updated according to guidance of the Swedish Chemicals Agency.
SECTION 3: Composition/information on ingredients
3.1 Substances
Chemical name EC No CAS No Weight-% Classification according to Regulation (EC) No.
1272/2008 [CLP]
REACH registration
number Diphenyl(2,4,6-trimethylbenzoyl)phos
phine oxide 278-355-8 75980-60-8 >99% Skin Sens. 1B (H317)
Repr. 2 (H361) Aquatic Chronic 2 (H411)
01-2119972295-29-XXXX
Full text of H- and EUH-phrases: see section 16
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SECTION 4: First aid measures
4.1. Description of first aid measures
General advice Show this safety data sheet to the doctor in attendance.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a doctor. Remove contact lenses, if present and easy to do. Continue rinsing.
Skin contact Wash with soap and water. May cause an allergic skin reaction. In the case of skin irritation or allergic reactions see a doctor.
Ingestion Clean mouth with water and drink afterwards plenty of water.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms Itching. Rashes. Hives.
4.3. Indication of any immediate medical attention and special treatment needed
Note to doctors May cause sensitisation in susceptible persons. Treat symptomatically.
SECTION 5: Firefighting measures 5.1. Extinguishing media
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical.
Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.
5.2. Special hazards arising from the substance or mixture
Specific hazards arising from the chemical
Product is or contains a sensitiser. May cause sensitisation by skin contact.
Hazardous combustion products Thermal decomposition can lead to release of toxic and corrosive gases/vapours. Carbon monoxide.
5.3. Advice for firefighters
Special protective equipment for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.
For emergency responders Use personal protection recommended in Section 8.
6.2. Environmental precautions
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Environmental precautions See Section 12 for additional Ecological Information.
6.3. Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
6.4. Reference to other sections
Reference to other sections See section 8 for more information. See section 13 for more information.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash it before reuse. Remove contaminated clothing and shoes.
General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and immediately after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions Store in a cool, dry area away from potential sources of heat, open flames, sunlight or other chemicals. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store locked up. Keep out of the reach of children.
7.3. Specific end use(s)
Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters
Exposure Limits .
Biological occupational exposure limits
Derived No Effect Level (DNEL)
Derived No Effect Level (DNEL) Worker
Derived No Effect Level (DNEL) Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Type Worker Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 0.822 mg/m³
Type Worker Long term Systemic health effects
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Exposure route Dermal Derived No Effect Level (DNEL) 0.233 mg/kg bw/d Derived No Effect Level (DNEL) General Population
Derived No Effect Level (DNEL) Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Type General Population Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 0.145 mg/m³
Type General Population Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 0.0833 mg/kg bw/d
Type General Population Long term Systemic health effects Exposure route Oral Derived No Effect Level (DNEL) 0.0833 mg/kg bw/d
Predicted No Effect Concentration (PNEC)
.
Predicted No Effect Concentration (PNEC) Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Environmental compartment Predicted No Effect Concentration (PNEC) Freshwater 1.4 µg/l Marine water 0.14 µg/l Freshwater - intermittent 14 µg/l Marine water - intermittent 1.4 µg/l Freshwater sediment 0.115 mg/kg Marine sediment 0.0115 mg/kg Soil 0.0222 mg/kg
8.2. Exposure controls
Personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles). Eye protection must conform to standard EN 166.
Hand protection Wear suitable gloves. Gloves must conform to standard EN 374.
Gloves Duration of contact PPE - Glove material Glove thickness Break through time
Nitrile rubber 0.4 mm 4 hours Butyl rubber 0.4 mm 4 hours
Skin and body protection Wear suitable protective clothing.
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and immediately after handling the product.
Environmental exposure controls No information available.
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SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state Solid Appearance Powder. Colour yellow. Odour Not determined. Odour threshold Not determined
9.2. Other information Softening point Not determined Molecular weight Not determined VOC Content (%) No information available Liquid Density Not determined Bulk density Not determined
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity No information available.
10.2. Chemical stability
Stability Stable under normal conditions.
Explosion data Sensitivity to mechanical impact None. Sensitivity to static discharge None.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions None under normal processing.
Hazardous polymerisation Polymerisation can occur.
10.4. Conditions to avoid
Property Values Remarks • Method pH Not applicable Melting point / freezing point 93 °C Boiling point / boiling range > 200 °C Flash point Not applicable Evaporation rate Not determined Flammability (solid, gas) Not determined Flammability Limit in Air
Upper flammability or explosive limits
unknown
Lower flammability or explosive limits
Vapour pressure 0 hPa @ 20 °C Vapour density Relative density 1.218 @ 20 °C Water solubility 0.0119 g/l @ 20 °C Solubility(ies) Not determined. Partition coefficient log Pow = 3.1 @ 23 °C Autoignition temperature > 400 °C Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic viscosity Not determined
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Conditions to avoid Extremes of temperature and direct sunlight.
10.5. Incompatible materials
Incompatible materials None known based on information supplied.
10.6. Hazardous decomposition products
Hazardous decomposition products None known based on information supplied.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Information on likely routes of exposure
Product Information .
Skin contact May cause sensitisation by skin contact. Specific test data for the substance or mixture is not available. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. (based on components).
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms Itching. Rashes. Hives.
Numerical measures of toxicity
Acute toxicity
Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50
Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide
> 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rat )
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation Based on available data, the classification criteria are not met. Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Species Rabbit Exposure route Dermal Effective dose 0.5 g Exposure time 24 hours Results Erythema 0 edema non-irritant
Serious eye damage/eye irritation Based on available data, the classification criteria are not met. Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Species Rabbit Exposure route Eye Effective dose 0.056 g Exposure time 5 days Results non-irritant
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Respiratory or skin sensitisation May cause sensitisation by skin contact. Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Method OECD Test No. 429: Skin Sensitisation: Local Lymph Node Assay Species Mouse Exposure route Dermal Results Sensitising
Germ cell mutagenicity Based on available data, the classification criteria are not met. Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Method OECD Test No. 471: Bacterial Reverse Mutation Test Species in vitro Results Negative
Method OECD Test No. 473: In vitro Mammalian Chromosome Aberration Test Species in vitro Results Negative
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Classification based on data available for ingredients.
The table below indicates ingredients above the cut-off threshold considered as relevant which are listed as reproductive toxins. Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Method OECD Test No. 414: Pre-natal Development Toxicity Study Species Rat Results Developmental toxicity NOAEL 150 mg/kg bw/d
Method OECD Test No. 421: Reproduction/Developmental Toxicity Screening Test Species Rat Results Reproductive toxicity NOAEL 60 mg/kg bw/d
Method OECD Test No. 421: Reproduction/Developmental Toxicity Screening Test Species Rat Results Developmental toxicity NOAEL 200 mg/kg bw/d
Method OECD Test No. 421: Reproduction/Developmental Toxicity Screening Test Species Rat Results Parental NOAEL 200 mg/kg bw/d
Chemical name European Union Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide Repr. 2
STOT - single exposure Based on available data, the classification criteria are not met.
STOT - repeated exposure Based on available data, the classification criteria are not met. Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8) Method OECD Test No. 408: Repeated Dose 90-Day Oral Toxicity Study in Rodents Species Rat Exposure route Oral Results NOAEL 100 mg/kg bw/d
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SECTION 12: Ecological information
12.1. Toxicity
Ecotoxicity The environmental impact of this product has not been fully investigated.
Chemical name Algae/aquatic plants Fish Toxicity to microorganisms
Crustacea
Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide
EC50 > 2.01 mg/l (72h, Pseudokirchneriella
subcapitata) EC10 = 1.56 mg/l (72h,
Pseudokirchneriella subcapitata)
LC50 = 6.53 mg/l (48h, Oryzias latipes)
EC50 > 1000 mg/l (3h, Activated sludge)
EC50 = 3.53 mg/l (48h, Daphnia magna)
12.2. Persistence and degradability
Persistence and degradability No information available.
Component Information Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (75980-60-8)
Method Exposure time Value Results OECD Test No. 301F: Ready Biodegradability: Manometric Respirometry Test (TG 301 F)
28 days Biodegradation 0 - 10% Not readily biodegradable
12.3. Bioaccumulative potential
Bioaccumulation There is no data for this product.
Bioconcentration factor (BCF) No data available
Component Information
Chemical name Partition coefficient Bioconcentration factor (BCF) Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide 3.1 18 - 72
12.4. Mobility in soil
Mobility in soil No information available.
Chemical name Surface tension Henry’s Law Constant Adsorption coefficient Diphenyl(2,4,6-trimethylbenzoyl)phosp
hine oxide 75980-60-8
0 Pa m³/mol @ 25 °C log Koc = 784.8
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment
Chemical name PBT and vPvB assessment Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide The substance is not PBT / vPvB
12.6. Other adverse effects
Other adverse effects No information available.
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SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste from residues/unused products
Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.
Contaminated packaging Do not reuse empty containers.
SECTION 14: Transport information
IMDG 14.1 UN number UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9 14.4 Packing group III
Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide, Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III, Marine pollutant
14.5 Marine pollutant Not applicable Environmental hazards Yes
14.6 Special Provisions 274, 335, 966, 967, 969 EmS-No F-A, S-F
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
No information available
RID 14.1 UN number UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9
Labels 9 14.4 Packing group III
Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide, Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions None
Classification code M7
ADR 14.1 UN number UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9
Labels 9 14.4 Packing group III
Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide, Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 601, 375
Classification code M7
ADN 14.1 UN/ID no UN3077 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. 14.3 Transport hazard class(es) 9
Hazard label(s) 9
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14.4 Packing group III Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.
(Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide), 9, III 14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 601
IATA 14.1 UN number UN3077 14.2 UN proper shipping name Environmentally hazardous substances, solid, n.o.s. 14.3 Transport hazard class(es) 9 14.4 Packing group III
Description UN3077, Environmentally hazardous substances, solid, n.o.s. (Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide, Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions None
ERG Code 9L
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
France Occupational Illnesses (R-463-3, France)
Germany Water hazard class (WGK) hazardous to water (WGK 2)
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work
Authorisations and/or restrictions on use:This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)
Persistent Organic PollutantsNot applicable
Dangerous substance category per Seveso Directive (2012/18/EU)E2 - Hazardous to the Aquatic Environment in Category Chronic 2
Named dangerous substances per Seveso Directive (2012/18/EU)
Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable
International Inventories
Chemical name
TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS TCSI NZIoC
Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide
X X - X - X X X X X X X
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75980-60-8
Please note that the presence of a substance on an Inventory is not an indication that the substance can be supplied to that country. Additional registration (REACH, K-REACH, ...) might be required.
Legend:
X - Listed TSCA - Toxic Substances Control Act Frank R. Lautenberg Chemical Safety for the 21st Century Act (active rule) DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals TCSI - Taiwan Chemical Substance Inventory
15.2. Chemical safety assessment
Chemical Safety Report A Chemical Safety Assessment has been carried out for this substance
SECTION 16: Other information
Key or legend to abbreviations and acronyms used in the safety data sheet
Full text of H-Statements referred to under section 3H317 - May cause an allergic skin reactionH361 - Suspected of damaging fertility or the unborn childH411 - Toxic to aquatic life with long lasting effects Legend SVHC: Substances of Very High Concern for Authorisation:
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR) U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine's PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organisation for Economic Co-operation and Development Environment, Health, and Safety Publications Organisation for Economic Co-operation and Development High Production Volume Chemicals Programme Organisation for Economic Co-operation and Development Screening Information Data Set
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value *
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Skin designation
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RTECS (Registry of Toxic Effects of Chemical Substances) World Health Organization
Issuing Date 12-Aug-2019
Revision date 22-Jul-2020
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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SAFETY DATA SHEETThis safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006Commission Regulation (EU) No 2015/830 of 28 May 2015
Issuing Date 12-Feb-2021 Revision date 15-Oct-2020 Revision Number 1.01
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier
Product Code(s) 10000222 10000223
Product Name Omnirad TPO-L
REACH registration number 01-2119987994-10-0000
EC No 282-810-6
CAS No 84434-11-7
Chemical name Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate
Pure substance/mixture Substance
Molecular weight 316.4 g/mol
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use Photoinitiator.For use in industrial installations or professional treatment only.
Uses advised against Consumer use.
1.3. Details of the supplier of the safety data sheet
For further information, please contact E-mail address [email protected] 1.4. Emergency telephone number
Emergency Telephone (GB) +44 20 35147487 ## 333 293 TF (UK) 0 800 680 0425 ## 333 293
Emergency Telephone §45 - (EC)1272/2008 Europe 112
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 Skin sensitisation Category 1B - (H317)
SupplierIGM Resins B.V. Gompenstraat 49 5145 RM Waalwijk The Netherlands T: +31 (0) 416 316 657 F: +31 (0) 416 564 632
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Chronic aquatic toxicity Category 2 - (H411)
2.2. Label elements
Signal wordWarning
Hazard statements H317 - May cause an allergic skin reactionH411 - Toxic to aquatic life with long lasting effects
Precautionary Statements - EU (§28, 1272/2008)P272 - Contaminated work clothing should not be allowed out of the workplaceP273 - Avoid release to the environmentP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of water and soapP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash it before reuseP391 - Collect spillageP501 - Dispose of contents/ container to an approved waste disposal plant
2.3. Other hazards No information available
SECTION 3: Composition/information on ingredients
3.1 Substances
Chemical name EC No CAS No Weight-% Classification according to Regulation (EC) No.
1272/2008 [CLP]
REACH registration
number Ethyl
phenyl(2,4,6-trimethylbenzoyl)phosphinate
282-810-6 84434-11-7 >98% Skin Sens. 1B (H317) Aquatic Chronic 2 (H411)
01-2119987994-10-XXXX
Full text of H- and EUH-phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
General advice Show this safety data sheet to the doctor in attendance.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a doctor. Remove contact lenses, if present and easy to do. Continue rinsing.
Skin contact Wash with soap and water. May cause an allergic skin reaction. In the case of skin irritation
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or allergic reactions see a doctor.
Ingestion Clean mouth with water and drink afterwards plenty of water.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms Itching. Rashes. Hives.
4.3. Indication of any immediate medical attention and special treatment needed
Note to doctors May cause sensitisation in susceptible persons. Treat symptomatically.
SECTION 5: Firefighting measures 5.1. Extinguishing media
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical.
Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.
5.2. Special hazards arising from the substance or mixture
Specific hazards arising from the chemical
Product is or contains a sensitiser. May cause sensitisation by skin contact.
Hazardous combustion products Thermal decomposition can lead to release of toxic and corrosive gases/vapours. Carbon monoxide.
5.3. Advice for firefighters
Special protective equipment for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.
For emergency responders Use personal protection recommended in Section 8.
6.2. Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information.
6.3. Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
6.4. Reference to other sections
Reference to other sections See section 8 for more information. See section 13 for more information.
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SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash it before reuse.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions Store locked up. Keep out of the reach of children. Store in a cool, dry area away from potential sources of heat, open flames, sunlight or other chemicals. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
7.3. Specific end use(s)
Identified Uses Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Derived No Effect Level (DNEL)
Derived No Effect Level (DNEL) Worker
Derived No Effect Level (DNEL) Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Type Worker Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 5.88 mg/m³
Type Worker Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 1.7 mg/kg bw/d Derived No Effect Level (DNEL) General Population
Derived No Effect Level (DNEL) Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Type General Population Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 0.87 mg/m³
Type General Population Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 0.5 mg/kg bw/d
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Type General Population Long term Systemic health effects Exposure route Oral Derived No Effect Level (DNEL) 0.5 mg/kg bw/d
Predicted No Effect Concentration (PNEC)
Predicted No Effect Concentration (PNEC) Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Environmental compartment Predicted No Effect Concentration (PNEC) Freshwater 0.001 mg/l Freshwater - intermittent 0.035 mg/l Marine water 0 mg/l Freshwater sediment 0.24 mg/kg Marine sediment 0.024 mg/kg Soil 0.047 mg/kg
8.2. Exposure controls
Personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles). Eye protection must conform to standard EN 166.
Hand protection Wear suitable gloves. Gloves must conform to standard EN 374.
Gloves Duration of contact PPE - Glove material Glove thickness Break through time
Nitrile rubber 0.4 mm 60 minutes Butyl rubber 0.4 mm 60 minutes
Skin and body protection Wear suitable protective clothing.
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls No information available.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state Liquid Appearance viscous. Colour yellow. Odour Not determined. Odour threshold Not determined
Property Values Remarks • Method pH No data available pH (as aqueous solution) 3.2 - 4.3 solution 35 mg/L Melting point / freezing point -12 °C Boiling point / boiling range 257.4 °C Flash point 144 °C CC (closed cup) Evaporation rate Not determined Flammability (solid, gas) Not determined
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9.2. Other information Softening point Not determined Molecular weight 316.4 g/mol VOC Content (%) No information available Liquid Density Not determined Bulk density Not determined
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity No information available.
10.2. Chemical stability
Stability Stable under normal conditions.
Explosion data Sensitivity to mechanical impact None. Sensitivity to static discharge None.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions None under normal processing.
Hazardous polymerisation Polymerisation can occur.
10.4. Conditions to avoid
Conditions to avoid Extremes of temperature and direct sunlight.
10.5. Incompatible materials
Incompatible materials None known based on information supplied.
10.6. Hazardous decomposition products
Hazardous decomposition products None known based on information supplied.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Flammability Limit in Air Upper flammability or explosive limits Lower flammability or explosive limits
Vapour pressure 0 hPa @ 20 °C Vapour density Relative density 1.13 @ 20 °C Water solubility 0.035 g/L @ 20 °C Solubility(ies) 71.8 g/L.
Organic solvents.
Partition coefficient log Pow = 2.91 @ 25 °C Autoignition temperature 423 °C Decomposition temperature Kinematic viscosity Not determined Dynamic viscosity 1483 mPa s @ 20 °C
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Information on likely routes of exposure
Product Information
Skin contact May cause sensitisation by skin contact. Specific test data for the substance or mixture is not available. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. (based on components).
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms Itching. Rashes. Hives.
Numerical measures of toxicity
Acute toxicity
Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50
Ethyl phenyl(2,4,6-trimethylbenzoyl)p
hosphinate 84434-11-7
> 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rat )
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Component Information Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Method OECD Test No. 404: Acute Dermal Irritation/Corrosion Species Rabbit Exposure route Dermal Effective dose 0.5 mL Exposure time 4 hours Results Erythema edema 0 non-irritant
Serious eye damage/eye irritation Based on available data, the classification criteria are not met.
Component Information Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Method OECD Test No. 405: Acute Eye Irritation/Corrosion Species Rabbit Exposure route Eye Effective dose 0.1 mL Exposure time 24 hours Results non-irritant
Respiratory or skin sensitisation May cause sensitisation by skin contact.
Component Information Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Method OECD Test No. 429: Skin Sensitisation: Local Lymph Node Assay Species Mouse Exposure route Injection Results Sensitising
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Germ cell mutagenicity Based on available data, the classification criteria are not met.
Component Information Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Method OECD Test No. 471: Bacterial Reverse Mutation Test Species in vitro Results Not mutagenic
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
Component Information Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Method OECD Test No. 414: Pre-natal Development Toxicity Study Species Rat Results NOAEL 300 mg/kg bw/d
Developmental toxicity Based on available data, the classification criteria are not met.
STOT - single exposure Based on available data, the classification criteria are not met.
STOT - repeated exposure Based on available data, the classification criteria are not met.
Component Information Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7) Method OECD Test No. 407: Repeated Dose 28-day Oral Toxicity Study in Rodents Species Rat Exposure route Oral Exposure time 28 days Results NOAEL >= 500 mg/kg bw/d
SECTION 12: Ecological information
12.1. Toxicity
Ecotoxicity The environmental impact of this product has not been fully investigated.
Product Information Chemical name Algae/aquatic plants Fish Toxicity to
microorganisms Crustacea
Ethyl phenyl(2,4,6-trimethylben
zoyl)phosphinate
EC50 = 1.01 mg/l (72h, Desmodesmus subspicatus)
LC50 = 1.89 mg/l (96h, Danio rerio)
EC50 > 1000 mg/l (3h, Activated sludge)
EC50 = 2.26 mg/l (48h, Daphnia magna)
EC10 = 1.55 mg/l (48h, Daphnia magna)
12.2. Persistence and degradability
Persistence and degradability No information available.
Component Information
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Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate (84434-11-7)
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Method Exposure time Value Results OECD Test No. 301F: Ready Biodegradability: Manometric Respirometry Test (TG 301 F)
28 days Biodegradation <10% Not readily biodegradable
12.3. Bioaccumulative potential
Bioaccumulation There is no data for this product.
Bioconcentration factor (BCF) No data available
Component Information
Chemical name Partition coefficient Bioconcentration factor (BCF) Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate 2.91
12.4. Mobility in soil
Mobility in soil No information available.
Chemical name Surface tension Henry’s Law Constant Adsorption coefficient Ethyl
phenyl(2,4,6-trimethylbenzoyl)phosphinate
84434-11-7
log Koc = 3.37 @ 26 °C
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment
Chemical name PBT and vPvB assessment Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate The substance is not PBT / vPvB
12.6. Other adverse effects
Other adverse effects No information available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste from residues/unused products
Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.
Contaminated packaging Do not reuse empty containers.
SECTION 14: Transport information
IMDG 14.1 UN number or ID number UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9 14.4 Packing group III
Description
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UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III, Marine pollutant
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14.5 Marine pollutant Not applicable Environmental hazards Yes
14.6 Special Provisions 274, 335, 969 EmS-No F-A, S-F
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
No information available
RID 14.1 UN number UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9
Labels 9 14.4 Packing group III
Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions None
Classification code M6
ADR 14.1 UN number UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9
Labels 9 14.4 Packing group III
Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 601, 375
Classification code M6 Tunnel restriction code (-)
ADN 14.1 UN/ID no UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9
Hazard label(s) 9 14.4 Packing group III
Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 375, 601
IATA 14.1 UN number or ID number UN3082 14.2 UN proper shipping name Environmentally hazardous substances, liquid, n.o.s. 14.3 Transport hazard class(es) 9 14.4 Packing group III
Description UN3082, Environmentally hazardous substances, liquid, n.o.s. (Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions None
ERG Code 9L
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
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Germany Water hazard class (WGK) hazardous to water (WGK 2)
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work
Authorisations and/or restrictions on use:This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)
Persistent Organic PollutantsNot applicable
Dangerous substance category per Seveso Directive (2012/18/EU)E2 - Hazardous to the Aquatic Environment in Category Chronic 2
Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable
International Inventories
Chemical name
AICS DSL NDSL EINECS ELINCS ENCS IECSC KECL NZIoC PICCS TCSI TSCA
Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate 84434-11-7
x X - X - - X X X - X X
Please note that the presence of a substance on an Inventory is not an indication that the substance can be supplied to that country. Additional registration (REACH, K-REACH, ...) might be required.
Legend:
X - Listed CBI - Confidential Business Information EU-LVE - Low Volume exemption < 1T LCP - Low concern polymer PMN - indicates a commenced PMN substance S - indicates a substance that is identified in a final Significant New Use Rule US-LVE - Low volume exemption < 10 T annually of the active substance US-PE - Polymer Exemption
AICS - Australian Inventory of Chemical Substances DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals PICCS - Philippines Inventory of Chemicals and Chemical Substances TCSI - Taiwan Chemical Substance Inventory TSCA - Toxic Substances Control Act Frank R. Lautenberg Chemical Safety for the 21st Century Act (active rule)
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15.2. Chemical safety assessment
Chemical Safety Report A Chemical Safety Assessment has been carried out for this substance
SECTION 16: Other information
Key or legend to abbreviations and acronyms used in the safety data sheet
Legend SVHC: Substances of Very High Concern for Authorisation:
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Classification procedure Classification according to Regulation (EC) No. 1272/2008 [CLP] Method Used Acute oral toxicity Calculation method Acute dermal toxicity Calculation method Acute inhalation toxicity - gas Calculation method Acute inhalation toxicity - Vapour Calculation method Acute inhalation toxicity - dust/mist Calculation method Skin corrosion/irritation Calculation method Serious eye damage/eye irritation Calculation method Respiratory sensitisation Calculation method Mutagenicity Calculation method Carcinogenicity Calculation method Reproductive toxicity Calculation method STOT - single exposure Calculation method STOT - repeated exposure Calculation method Acute aquatic toxicity Calculation method Chronic aquatic toxicity Calculation method Aspiration hazard Calculation method Ozone Calculation method Health hazards not otherwise classified (HHNOC) Calculation method
Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR) U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification Australian National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine's PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organisation for Economic Co-operation and Development Environment, Health, and Safety Publications Organisation for Economic Co-operation and Development High Production Volume Chemicals Programme Organisation for Economic Co-operation and Development Screening Information Data Set RTECS (Registry of Toxic Effects of Chemical Substances) World Health Organization
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value * Skin designation
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Issuing Date 12-Feb-2021
Revision date 15-Oct-2020
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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SAFETY DATA SHEETThis safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006Commission Regulation (EU) No 2015/830 of 28 May 2015
Issuing Date 09-Dec-2019 Revision date 09-Dec-2019 Revision Number 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier
Product Code(s) 10000300 10000301 Product Name Photomer 4012
REACH registration number 01-2119957862-25-XXXX
EC No 227-561-6
CAS No 5888-33-5
Chemical name Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate
Synonyms Isobornyl acrylate (IBOA)
Pure substance/mixture Substance
Molecular weight 208.30 g/mol
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use Monomer.Reactive.Production of UV inks, coatings and adhesives.For use in industrial installations or professional treatment only.
Uses advised against Consumer use.Nail polish/lacquer.Skin contact.
1.3. Details of the supplier of the safety data sheet
For further information, please contact E-mail address [email protected] 1.4. Emergency telephone number
Emergency Telephone (EMEA) +1 760 476 3961 ## 333 293
Emergency Telephone - §45 - (EC)1272/2008 Europe 112
SECTION 2: Hazards identification
SupplierIGM Resins B.V Gompenstraat 49 5145 RM Waalwijk T: +31 (0) 416 316 657 F: +31 (0) 416 564 632
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2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 Skin corrosion/irritation Category 2 - (H315) Serious eye damage/eye irritation Category 2 - (H319) Skin sensitisation Category 1 - (H317) Specific target organ toxicity — single exposure Category 3 - (H335) Acute aquatic toxicity Category 1 - (H400) Chronic aquatic toxicity Category 1 - (H410)
2.2. Label elements
Signal wordWarning
Hazard statements H315 - Causes skin irritationH317 - May cause an allergic skin reactionH319 - Causes serious eye irritationH335 - May cause respiratory irritationH410 - Very toxic to aquatic life with long lasting effects
Precautionary Statements - EU (§28, 1272/2008)P264 - Wash face, hands and any exposed skin thoroughly after handlingP271 - Use only outdoors or in a well-ventilated areaP272 - Contaminated work clothing should not be allowed out of the workplaceP273 - Avoid release to the environmentP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of water and soapP304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathingP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingP312 - Call a POISON CENTER or doctor if you feel unwellP332 + P313 - If skin irritation occurs: Get medical advice/attentionP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP337 + P313 - If eye irritation persists: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash it before reuseP391 - Collect spillageP403 + P233 - Store in a well-ventilated place. Keep container tightly closedP405 - Store locked upP501 - Dispose of contents/ container to an approved waste disposal plant
2.3. Other hazards No information available
SECTION 3: Composition/information on ingredients
3.1 Substances
Chemical name EC No CAS No Weight-% Classification according to Regulation (EC) No.
REACH registration
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1272/2008 [CLP] number Exo-1,7,7-trimethylbicyclo[2.2.1]hept-
2-yl acrylate 227-561-6 5888-33-5 > 98% Skin Irrit. 2 (H315)
Eye Irrit. 2 (H319)Skin Sens. 1 (H317)STOT SE 3 (H335)
Aquatic Acute 1 (H400)Aquatic Chronic 1 (H410)
01-2119957862-25-XXXX
Full text of H- and EUH-phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
General advice Show this safety data sheet to the doctor in attendance.
Inhalation Remove to fresh air. IF exposed or concerned: Get medical advice/attention. Get medical attention immediately if symptoms occur.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Do not rub affected area.
Skin contact May cause an allergic skin reaction. In the case of skin irritation or allergic reactions see a doctor. Wash off immediately with soap and plenty of water for at least 15 minutes.
Ingestion Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Call a doctor.
Self-protection of the first aider Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section 8).
4.2. Most important symptoms and effects, both acute and delayed
Symptoms Itching. Rashes. Hives. Burning sensation.
4.3. Indication of any immediate medical attention and special treatment needed
Note to doctors May cause sensitisation in susceptible persons. Treat symptomatically.
SECTION 5: Firefighting measures 5.1. Extinguishing media
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical.
Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.
5.2. Special hazards arising from the substance or mixture
Specific hazards arising from the chemical
Product is or contains a sensitiser. May cause sensitisation by skin contact.
Hazardous combustion products Thermal decomposition can lead to release of toxic and corrosive gases/vapours. Carbon monoxide.
5.3. Advice for firefighters
Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
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fire-fighters gear. Use personal protection equipment.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.
Other information Refer to protective measures listed in Sections 7 and 8.
For emergency responders Use personal protection recommended in Section 8.
6.2. Environmental precautions
Environmental precautions Prevent further leakage or spillage if safe to do so.
6.3. Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
6.4. Reference to other sections
Reference to other sections See section 8 for more information. See section 13 for more information.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash it before reuse. Avoid breathing vapours or mists.
General hygiene considerations Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product. Avoid contact with skin, eyes or clothing.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions Store in a cool, dry area away from potential sources of heat, open flames, sunlight or other chemicals. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store locked up. Keep out of the reach of children.
7.3. Specific end use(s)
Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters
Exposure Limits .
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Derived No Effect Level (DNEL)
Derived No Effect Level (DNEL) Worker
Derived No Effect Level (DNEL) Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Type Worker Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 4.9 mg/m³
Type Worker Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 1.39 mg/kg bw/d Derived No Effect Level (DNEL) General Population
Derived No Effect Level (DNEL) Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Type General Population Long term Systemic health effects Exposure route Inhalation Derived No Effect Level (DNEL) 1.45 mg/m³
Type General Population Long term Systemic health effects Exposure route Dermal Derived No Effect Level (DNEL) 0.83 mg/kg bw/d
Type General Population Long term Systemic health effects Exposure route Oral Derived No Effect Level (DNEL) 0.83 mg/kg bw/d
Predicted No Effect Concentration (PNEC)
.
Predicted No Effect Concentration (PNEC) Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Environmental compartment Predicted No Effect Concentration (PNEC) Freshwater 0.007 mg/l Marine water 0 mg/l Microorganisms in sewage treatment 2 mg/l Freshwater sediment 0.145 mg/kg dry weight Marine sediment 0.015 mg/kg dry weight Soil 0.029 mg/kg dry weight
8.2. Exposure controls
Personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles). If splashes are likely to occur, wear safety glasses with side-shields. Eye protection must conform to standard EN 166.
Hand protection Wear suitable gloves. Impervious gloves. Gloves must conform to standard EN 374.
Skin and body protection Wear suitable protective clothing. Long sleeved clothing.
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
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General hygiene considerations Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product. Avoid contact with skin, eyes or clothing.
Environmental exposure controls No information available.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state Liquid Colour colourless. Odour Ester. Odour threshold Not determined
9.2. Other information Softening point Not determined Molecular weight 208.30 g/mol VOC Content (%) No information available Liquid Density Not determined Bulk density Not determined
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity No information available.
10.2. Chemical stability
Stability Stable under normal conditions.
Explosion data Sensitivity to mechanical impact None. Sensitivity to static discharge None.
Property Values Remarks • Method pH Not determined Melting point / freezing point < -20 °C Boiling point / boiling range 275 °C Flash point 104 °C Pensky-Martens Closed Cup (PMCC) Evaporation rate Not determined Flammability (solid, gas) Not determined Flammability Limit in Air
Upper flammability or explosive limits Lower flammability or explosive limits
Vapour pressure 0.013 hPa @ 20 °C Vapour density Relative density 0.99 @ 25 °C Water solubility 19.8 mg/l @ 20 °C Solubility(ies) Not determined. Partition coefficient 4.52 Autoignition temperature 375 °C @10088 kPa Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic viscosity 7.5 - 9.5 mPa s
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@ 20 °C
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10.3. Possibility of hazardous reactions
Possibility of hazardous reactions None under normal processing.
Hazardous polymerisation Polymerisation can occur.
10.4. Conditions to avoid
Conditions to avoid None known based on information supplied.
10.5. Incompatible materials
Incompatible materials Strong acids. Strong bases. Strong oxidising agents.
10.6. Hazardous decomposition products
Hazardous decomposition products None known based on information supplied.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available. May cause irritation of respiratory tract.
Eye contact Specific test data for the substance or mixture is not available. Irritating to eyes. (based on components). Causes serious eye irritation.
Skin contact May cause sensitisation by skin contact. Specific test data for the substance or mixture is not available. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. (based on components). Causes skin irritation.
Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms Itching. Rashes. Hives. Redness. May cause redness and tearing of the eyes.
Numerical measures of toxicity
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 4,964.50 mg/kg ATEmix (dermal) 5,081.20 mg/kg
Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50
Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate
= 4350 mg/kg ( Rat ) > 3000 mg/kg ( Rabbit )
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation Classification based on data available for ingredients. Irritating to skin.
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Serious eye damage/eye irritation Classification based on data available for ingredients. Causes serious eye irritation.
Respiratory or skin sensitisation May cause sensitisation by skin contact. Component Information Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Method OECD Test No. 429: Skin Sensitisation: Local Lymph Node Assay Species Mouse Exposure route Dermal Results Sensitising
Germ cell mutagenicity Based on available data, the classification criteria are not met. Component Information Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Method OECD Test No. 471: Bacterial Reverse Mutation Test Species in vitro Results Not mutagenic
Method OECD Test No. 476: In vitro Mammalian Cell Gene Mutation Test Species in vitro Results Not mutagenic
Method OECD Test No. 487: In Vitro Mammalian Cell Micronucleus Test Species in vitro Results Not mutagenic
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
Component Information Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Method OECD Test No. 422: Combined Repeated Dose Toxicity Study with the
Reproduction/Developmental Toxicity Screening Test Species Rat Results Parental NOAEL 100 mg/kg bw/d
Method OECD Test No. 415: One-Generation Reproduction Toxicity Study Species Rat Results NOAEL 300 mg/kg bw/d
STOT - single exposure May cause respiratory irritation.
STOT - repeated exposure Based on available data, the classification criteria are not met. Component Information Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5) Method OECD Test No. 422: Combined Repeated Dose Toxicity Study with the
Reproduction/Developmental Toxicity Screening Test Species Rat Exposure route Oral Effective dose 25/100/500 mg/kg bw/d Results NOAEL 100 mg/kg bw/d
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SECTION 12: Ecological information
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12.1. Toxicity
Ecotoxicity Very toxic to aquatic life with long lasting effects.
Chemical name Algae/aquatic plants Fish Toxicity to microorganisms
Crustacea
Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate
EC50 = 1.98 mg/L (72h, Pseudokirchneriella
subcapitata) NOEC = 0.405 mg/L
(72h, Pseudokirchneriella subcapitata)
LC50 = 0.704 mg/L (96h, Danio rerio)
- NOEC = 0.092 mg/L (21d, Daphnia magna)
12.2. Persistence and degradability
Persistence and degradability No information available.
Component Information Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate (5888-33-5)
Method Exposure time Value Results OECD Test No. 310: Ready
Biodegradability - CO2 in Sealed Vessels (Headspace Test)
28 days 57% Biodegradation Not readily biodegradable
12.3. Bioaccumulative potential
Bioaccumulation There is no data for this product.
Bioconcentration factor (BCF) No data available
Component Information
12.4. Mobility in soil
Mobility in soil No information available.
Chemical name Surface tension Henry’s Law Constant Adsorption coefficient Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2
-yl acrylate 5888-33-5
23.3 Pam³/mole at 25°C Koc at 20°C = 3.71
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment
Chemical name PBT and vPvB assessment Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate The substance is not PBT / vPvB
12.6. Other adverse effects
Other adverse effects No information available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
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Waste from residues/unused products
Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.
Contaminated packaging Do not reuse empty containers.
SECTION 14: Transport information
IMDG 14.1 UN number UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9 14.4 Packing group III
Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate, acrylic acid), 9, III, Marine pollutant
14.5 Marine pollutant Not applicable Environmental hazards Yes
14.6 Special Provisions 274, 335, 969 EmS-No F-A, S-F
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
No information available
RID 14.1 UN number UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9
Labels 9 14.4 Packing group III
Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate, acrylic acid), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions None
Classification code M6
ADR 14.1 UN number UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9
Labels 9 14.4 Packing group III
Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate, acrylic acid), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 601, 375
Classification code M6
ADN 14.1 UN/ID no UN3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. 14.3 Transport hazard class(es) 9
Hazard label(s) 9 14.4 Packing group III
Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions 274, 335, 375, 601
IATA 14.1 UN number UN3082
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14.2 UN proper shipping name Environmentally hazardous substances, liquid, n.o.s. 14.3 Transport hazard class(es) 9 14.4 Packing group III
Description UN3082, Environmentally hazardous substances, liquid, n.o.s. (Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate, acrylic acid), 9, III
14.5 Environmental hazards Yes 14.6 Special Provisions None
ERG Code 9L
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
Germany Water hazard class (WGK) hazardous to water (WGK 2)
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work
Authorisations and/or restrictions on use:This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)
Persistent Organic PollutantsNot applicable
Dangerous substance category per Seveso Directive (2012/18/EU)E1 - Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1
Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable
International Inventories
Chemical name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS TCSI NZIoC Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate 5888-33-5
X X X X X X X X
Please note that the presence of a substance on an Inventory is not an indication that the substance can be supplied to that country. Additional registration (REACH, K-REACH, ...) might be required.
Legend:
X - Listed TSCA - Toxic Substances Control Act Frank R. Lautenberg Chemical Safety for the 21st Century Act (active rule) DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances
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_____________________________________________________________________________________________ PH4012 - Photomer 4012 Revision date 09-Dec-2019
KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals TCSI - Taiwan Chemical Substance Inventory
15.2. Chemical safety assessment
Chemical Safety Report A Chemical Safety Assessment has been carried out for this substance
SECTION 16: Other information
Key or legend to abbreviations and acronyms used in the safety data sheet
Full text of H-Statements referred to under section 3H226 - Flammable liquid and vapourH302 - Harmful if swallowedH312 - Harmful in contact with skinH314 - Causes severe skin burns and eye damageH315 - Causes skin irritationH317 - May cause an allergic skin reactionH319 - Causes serious eye irritationH332 - Harmful if inhaledH335 - May cause respiratory irritationH400 - Very toxic to aquatic lifeH410 - Very toxic to aquatic life with long lasting effects
Legend SVHC: Substances of Very High Concern for Authorisation:
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR) U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine's PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organisation for Economic Co-operation and Development Environment, Health, and Safety Publications Organisation for Economic Co-operation and Development High Production Volume Chemicals Programme Organisation for Economic Co-operation and Development Screening Information Data Set RTECS (Registry of Toxic Effects of Chemical Substances) World Health Organization
Issuing Date 09-Dec-2019
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value *
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Skin designation
_____________________________________________________________________________________________ PH4012 - Photomer 4012 Revision date 09-Dec-2019
Revision date 09-Dec-2019
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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236 Kap isolierte chemisch einheitliche organische 13,122.00 KgUN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, VG III M6 2 Pallet 2118kgUN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, VG III M7 4 Bag (on 3 Carton ) 66kgUN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, VG III M6 1 Pallet 1059kgUN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, VG III M7 4 Bag (on 10 Carton ) 222kgUN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, VG III M7 4 Bag (on 6 Carton ) 131kg HSCODE = 29144090Ekipman Adet Spanzet 23 Stange 3 Sunta (OSB) 2 Konteyner Stangesi 2
CMR
6 7 8 9 10 11Marka ve Numara Parça Adedi Ambalaj Cinsi Malın Cinsi İstatistik No Brüt Kg HacimMarks and No Number of Pacakges Method of Packing Nature of the goods Statistical number Gross weight Volume in m312
1 Gönderen Sender
2 Alıcı Consignee
3 Malların teslim alındığı yer ve gün Collection Place and Date
4 Malların gönderildiği yer Delivery Place
5 Ek Dökümanlar Attached document
16 Diğer Nakliyeci Successive Carrier
17-18 Özel Talimatlar Special Instructions
21
IGM RESINS BVGOMPENSTRAAT 49NL-5145 RM WAALWIJK - TAX:Supplier Nr:
FRİMPEKS KİMYA VE ETİKET SANAYİ TİCARET AŞMERMERCİLER SANAYİ SİTESİ 8 CADDE NO 15TR-34520 BEYLİKDÜZÜ / İSTANBUL VKN:3880603783EORI Nr: Plant Nr:
NL-4191 GW GELDERMALSEN 21/10/2021
TR-34555 ARNAVUTKÖY / İSTANBUL -
1 ATR(O);1 IMO(C);1 EX-1(O);1 Fatura(C);1 Çeki Liste(C);
Our : 12110960 348264943PO14686; 2000010501; 80022695Your :Dokuman No :0012014667
FCA - Freight Collect
EKOE 597197-7
INTERNATIONAL CONSIGNMENT NOTEBu taşıma karşılıklı birsözleşme olsa bile karayolu ile eşya taşımacılığı(CMR)şartlatına tabidir.
ULUSLARARASI HAMULA SENEDİCMR convention for the internationalcarraige of goods by road is bindingfor this consignment, howeverthe agrement can be bilateral.
Delivery Address19-20 Teslim AdresiCustoms Clearance13 Gümrükleme Adresi
14 Navlunun ödenmesi için talimatlar Instruction as to payment carriage 15 Teslimatta ödenecek meblağReimboursement/cash on delivery
Established inTanzim TR-34149 BAKIRKÖY / İSTANBUL 22/10/2021
SIL
A
24 Mallar teslim alındıGoods received TarihOn
--------------/---------------
Signature and stamp of consigneeMal cinsi ve ambalaj gönderenin muhteviyatına göre yazılmıştır.Condition and nature of the goods and the content of the packagesare as per sender's declaration
Malın sigortasından, kalitesinden tahmilTahliyesi ve Gümrüklemesinden Ambalaj İstifHatasından Nakliyeci Mesul Değildir.Süreyi aşan hergün için 180 EUR karşılığı TL tahsil edilir
Malı gönderenin imzası ve kaşesiSignature and stamp of the sender Nakliyeci kaşesiSignature and stamp of the carrier
22 23
CUSTOMS CLEARANCE :DOUANE KANTOOR VENLO ABCOLUMBUSWEG 57NL-5928 LA VENLODELIVERY ADDRESS :LOTUS ANTREPO LOJİSTİK VE TAŞIMACILIK HİZMETLERİ DIŞYEŞİLBAYIR MAHALLESİ YAPI CADDESİ NO:21/ATR-34555 ARNAVUTKÖY / İSTANBUL
DELIVERED TOAlıcının imzası ve kaşesi
04/11/2021Lotus Yanýcý Antrepo
TRANSPORTER HAS NOT COUNTED THE UNITS