i. EIA report uploaded on the website was finalized in ...
Transcript of i. EIA report uploaded on the website was finalized in ...
To, 11/05/2020
Member Secretory,
Expert Appraisal Committee (Industry-II),
Ministry of Environment, Forest & Climate Change,
New Delhi
Sub: Observation of Committee during presentation and undertaking/
Commitment from PP.
Ref: Proposal No: Proposal Number: IA/GJ/IND2/98969/2019, TORs
letter No. IA-J-11011/81/2019-IA-II(I)
MoM: Minutes of 18th EAC (Industry-2) meeting held during April 13-15,
2020
Respected Sir,
This is regarding Presentation made before Expert Appraisal Committee
(Industry-II) on 13th April 2020. During the presentation, Honorable committee
has suggested some point for compliances and commitments and same was
communicated by above MoM which we are accepting herewith with and submit
following commitment.
i. EIA report uploaded on the website was finalized in March, 2019 as
per title of the Report. PP needs to upload the correct EIA/EMP
Report. The Committee suggested that the Consultant/PP has to read
all the documents before uploading on the Parivesh Portal.
It was mistake in change of Date in title page of uploaded EIA report in Form
2. Otherwise entire report is updated and finalized after PH. Chapter 7 and
CER is also updated in the submitted report. In the revised submitted report
we have included revision history summary in tabular form on the title page.
We have uploaded Final EIA report with above correction and modification in
ADS reply.
ii. PP mentioned that instant site is not located at CPA, the Committee
suggested that PP needs to submit a letter from CPCB or SPCB about
the location of project side in CPA or not.
Our project location does not fall in Critically Polluted Area (CPA) or Severely
Polluted Area (SPA) as per the MoEFCC Office Memorandum dated
31.10.2019. Gujarat Pollution Control Board (GPCB) has issue Office Order for
mechanism of environmental management of CPAs/SPAs of Gujarat State
including Map of respective areas with 10 km radius from the CPA boundary.
The map was prepared by BISAG (Bhaskaracharya Institute for Space
Applications and Geo-Informatics). BISAG is a State level agency by
Government of Gujarat to facilitate to provide services and solutions in
implementing map-based Geo Spatial Information Systems. Copy of same is
enclosed herewith for your ready reference.
Nandesari and PCCI Estate are identified CEPI areas nearest from our project
location, which are around 21 km & 20 km away from the site. Pls. refer Pg.
no. 6 & 7 of Annexure-I. It is self-explanatory that, our industrial area does
not fall in CEPI area or not in close vicinity of boundary of CEPI areas.
iii. PP has not carried out alternate site analysis. Committee is of the
view that as PP shall conduct the alternate site analysis study and
prepare the Report as per Appendix III of the EIA Notification, 2006.
Before finalization of this land for Pharma project, we have carried out
alternate site analysis and finalized land of Site-2 based on maximum criteria
fulfilled by this location. We have covered this detail in chapter 5, section 5.2
of EIA report.
iv. PP in slide number 49 mentioned that there is no schedule-I species
reported, However as per EIA/EMP Report Schedule I species were
reported. The PP needs to prepare the Conservation plan for
protection of schedule-1 species and submit to the CWLW for
approval.
Conservation plan with budgetary allocation for schedule-I spices of the study
area enclosed as Annexure-II with Acknowledgement from Office of Deputy
Conservator of Forest, Wildlife Division, Vadodara.
v. Status of TSDF membership.
We have approach to Bharuch Enviro Projects Pvt. Ltd. Dahej, Bharuch
district) a GPCB approved TSDF site and he informed that they have spare
capacity to accommodate our waste. They inform that after obtain EC from
MoEFCC New Delhi & CTE from GPCB, applied for membership with granted
quantity of waste and deposit respective amount for required membership. We
will immediately obtained TSDF membership after grant of CTE based on EC
grant by MoEFCC.
vi. Land conversion details for industrial purpose needs to be submitted.
Copy of NA order is enclosed as Annexure-III
vii. Revised detailed CER plan @ 5% of project cost and needs to be
submitted.
Please refer Annexure-IV for quick reference for increase the CER amount
from 2.5 % to 5% as suggested by Honorable EAC committee. We have
increase the CER amount from 2.5 % to 5% Modified amount is incorporated
in modified EIA report on section- E: Social Impact Assessment (Page no-7-
45), table no Table 7.12(Page no-7-50)
viii. Details technology/mitigation measure to achieve the Volatile organic
compounds (VOCs)/Fugitive emissions @ 99.997%.
Please refer Annexure-V for quick reference for mitigation measure to
achieve the Volatile organic compounds (VOCs)/Fugitive emissions @
99.997%. We have modified section 10.1.1.1: Measures for Solvent Recovery
in modified EIA report on page no-10.4.
ix. Details of fly ash brick making unit inside the plant for fly ash
disposal.
Unit committed to install and operate fly ash brick making unit inside the
plant for fly ash disposal with capacity of 2000 bricks per hour hydraulic
pressure machine for operate once in a week to utilize fly ash to be
generated from burning of Ago briquette in boiler, HAG and TFH. The criteria
of selection of fly ash brick unit is summarized below.
About 80% fly ash will be used for the production of fly ash bricks. The ratio
of Fly Ash (80%) Gypsum (15%) and sand (5%). Based on the maximum fly
ash generation (4.0 TPD), around 2000 per day *26 =52000 nos /month will
be produce. To considering 4 day production per month (Only Sunday), unit
will require 13000 brick per day capacity of machine. To considering this
aspect unit will purchase semi-automatic machine with capacity of 2000
bricks per hour hydraulic pressure machine.
Above details incorporated in modified EIA report on section 2.9.3 Fly Ash
management, page 2-41.
What is stated/committed above is bounded to comply by us. We humbly
request to process our application and issue us an Environmental Clearance at
your earliest. Our project being Pharma units please take positively.
Thanking You,
For, Reynish Pharmachem Pvt. Ltd.
Director
o
Gujarat Pollution Control BoardParyavaran Bhavan, Sector-1 0-A
Gandhinagar
Office Order
Sub: Mechanism for environmenta! management of critically and severallyPolluted Area and considerations of activities/Projects in such areasin compliance to Hon'ble NGT order dated 2310812019 in the matter ofO.A. No. 1038/2018-reg.
With reference to CPCB letter no. CPCB/IPC-VI|/CEPI/NGT/2019 dated2511012019 mechanism prepared by MoEF&CC for grant Consent toEstablishmenUConsent to Operate to those projects / activities of Red /Orange categories located in CPAsi SPAs which are not covered under theprovisions of the EIA notification,2006 are delineated.
Accordingly, it is required to prescribe the additional conditions deemedfit in the CTE / CTO of the projects / activities of Red/ Orange categories in theCPAs / SPAs of Gujarat.
After detailed discussion with industries associations of the CPA / SPAsof Gujarat and consultation with other stakeholders, it is decided to prescribefollowing additional conditions (deemed fit on case to case basis) consideringthe framework given in the letter of CPCB daled 2511012019.
These additional conditions will be applicable to the following CPAs/ SPAs ofthe Gujarat. Considering the mechanism, the 5 km from the boundary of eachCPA/ SPA should be considered as the area of influence and the additionalconditions stipulated for the new / expansion project will be made applicable toall such projects in this area. Map of the respective areas obtained fromBISAG is enclosed herewith as Annexure-1.
1. Vapi GIDC Estate
2. Sachin & Pandesara GIDC Estate (Considering monitoring carriedout by CPCB in these areas)
3. Ankleshwar Cluster (Ankleshwar and Panoli GIDC estate)
4. Nandesari GIDC & PCC Area (Considering monitoring carried out byCPCB in these areas)
5. Vatva- Narol
Page 1 of 5
a
6. AjiG|DC estate (Rajkot)
7. Chitra GIDC estate (Bhavnagar)
Specific Conditions sti ulated in Criticallv Poll uted Areas CPA)/D (
a
a
Severelv Polluted Areas (SPA).
Additional conditions under Air Act:
a) Unit shall adhere to stringent air pollutants standards i.e. 80 % of existing
flue gas and process emission standards in the CPA.
b) Unit shall adhere to stringent air pollutants standards i.e. 90 % of existing
flue gas and process emission standards in the SPA.
c) Following air pollution control measures shall be provided for the flue gas
emission sources like Boiler, Thermic Fluid Heaters etc. (As Applicable)
Stipulated APCM in Red / Orange category industrialunits of CPA/ SPA
Steam generationcapacity (in TPH)
Type of APCM
Less than 1 Multi Cyclone1to<3 Multi Cyclone
Scrubber+ Water
3to<6 Bag filter + Water Scrubber>6 ESP+ Water Scrubber
d) Unit shall provide at least two stage scrubbing system of appropriate
media for the control of the process gas emission.e) Unit shall install and commission Continuous Emission Monitoring
System- CEMS (as per CPCB guidelines for relevant parameters) which
shall be connected with GPCB/CPCB server (ln case of large and
medium red category industries)f) All common facilities shall install CEMS (as per CPCB guidelines for
relevant parameters) which shall be connected with GPCB/CPCB server
to the Stacks provided with Common Multiple Effect Evaporator (CMEE),
Common Spray Dryer, Common incinerator etc.g) The unit shall adhere to Sector specific guidelines/ SOP published by
GPCB / CPCB from time to time for effective fugitive emission control.(like guidelines for: Stone crushing units, Coal handling units, spent
spent acid management,
Page 2 of 5
solvent handling and management,Decontamination of drums, containers etc.)
h) Unit shall take adequate measures to control odour nuisance from the
industrial activities which may include measures like- use of masking
agent with atomizer System (water curtain), closed / automatic material
handling system, containment of the odour vulnerable areas etc'
Unit shall not use Pet-coke, furnace oil, LSHS as a fuel'
Unit shall adopt sectoral Best Available Technology-BAT (Like Use of
lnduction Furnace, Electric Arc Furnace instead of cupola furnace in
foundry industry, Caustic Recovery System in Cotton Textile units etc')
Unit shall provide green belt ol 40o/o of the plot area, using concept of the
social forestry and development of green belt outside project premises in
adjacent areas.
Unit shall provide wall to wall carpeting in vehicle movement areas
within premises to avoid dusting.
i)
i)
k)
r)
e Add itional conditions under the Water Act:
1 unit shall only use treated effluent for preparation of lime and other slurry
in ETP. No fresh water shall be utilized in ETP.
ln the case, if the lndustry is not a member of CETP and domestic waste
water generation is more than 10 KLPD, industry shall install STP of
adequatecapacityandtreatedSewageshallbereused/recycledtothemaximum extent.
2
3 ln case of Large and Medium Red category industry, the unit shall install
system for continuous monitoring of effluent quality / quantity as per
CPCB guidelines for relevant parameters (like pH, Flow, Temperature'
TOC/COD, NHo-N etc.) and shall be connected to GPCB server' ln case'
if the industry is a member of CETP, unit shall install flow meter'
lf the water consumption of the unit is more than 50 KLPD' Unit shall
submit detailed water harvesting plan (off site).
The unit shall explore Techno-Economic feasibility of Zero Liquid
a.
4
5
Discharge (ZLD) and if feasible, ZLD should be adopted
Page 3 of 5
Rules:
I
2
3
Unit shall strictly carry out handling, storage and disposal of fly-ash' slag'
red-mud, de-inking sludge etc (Uign Volume- Low Effect Wastes) as per
prevailing guidelinls and its disposal at designated locations approved by
L
lndustry shall dispose its hazardous wastes through co-processlng' pre.-
processing to the extent possible prior its disposal to incineration/ landfill
as per provisions of Hazardous and Other Wastes (Management and
Transboundary Movement) Rules, 20'l 6'
lndustry shall strictly comply with all the measures specified in guidelines
for spent solvent management, spent acid m.anagement' and other
g;ioetineslOirections puntLneo from time to time by GPCB and/or CPCB'
the Board.
etc.
Unit shall carry out transportation of hazardous wastes through GPS
mounted vehicles onlY
Other General Conditions:
located in CPAs/ SPAs'
.M ab a
Member Secretary
4
1 Unit shall submit report of compliance of the conditions of EC every year
to the Board prepared by third party'
Unit shall enhance CER fundallocation to at least 1 5 times the slabs
gir"n in the OM dated 01 05 2O18 for SPA and 2 times for CPA in case
of Environmental Clearance'
You are required to prescribe relevant additional conditions as
above henceforth while granting cTE / cTo of Red / orange categories
2
i)
No. GPCB/P- ltcEPt'1zt s-L6 g-s-2'-.--)
To, I
Date: { 1.1{.20{9
1. All Unit HeadsZ. nif n"gional Officers...For necessary action please'
Page 4 of 5
Additional conditions under the Hazardous Waste Management
r-
Copy to:
1. Chairman Office2. Member Secretary Office3. All Vigilance Officers... for necessary action
4. Respective File5. lT Cell-for display on Board Website'
e
a
Page 5 of 5
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Conservation Plan for Peacock or Indian Peafowl (Pavo Cristatus)
Schedule – I Bird Species
Protection Status:
As per IUCN: Classified as Least Concern (LC) on the IUCN Red List (1) and listed
on Appendix II of CITES 3.
Population Trend: Stable
Habitat: Terrestrial
Habitat Type: Forest, Scrubland, Artificial/Terrestrial
Generation Length in Year: 6.1
Movement Patterns: Non Migrant
Indian Peafowl (Pavocristatus)
Scientific classification
Kingdom: Animalia
Phylum: Chordata
Class: Aves
Order: Galliformes
Family: Phasianidae
Genus: Pavo
Species: Pavocristatus
Common Name: Indian Peafowl
Vernacular Name: Mor
Introduction: The Indian Peafowl (Pavo Cristatus) is a resident breeder in the
Indian subcontinent. The bird was declared as the National Bird of and its
widespread distribution in the country. The species is found in dry semi-desert
grasslands, shrub and deciduous forests. It forges and nests on the ground but
roots on top of trees. It eats seeds, insects, fruits, small mammals and reptiles. The
Indian Peafowl is a ground nesting bird and it lays a clutch of 4-8 eggs which take
28 days to hatch. The eggs are light brown and are laid every other day usually in
the afternoon. The male does not assist with the rearing, and is polygamous.
Poaching of Peacock for their feathers and poisoning by feeding on pesticide treated
seeds are known threats to wild birds. Under the law, collection of tail feather is
allowed only when bird sheds them. The Indian peafowl is under various threats
that include the demand for feathers and wild meat, conflict with farmers during
cropping season, increased use of chemical fertilizer and pesticide and habitat
degradation.
Habitat:
The Indian Peafowl is found mainly on the ground in open scrub forest or on land
under cultivation where they forage for berries, grains but will also prey on snakes,
lizards, and small rodents. Their loud calls make them easy to detect, and in forest
areas often indicate the presence of a predator such as a tiger. They forage on the
ground in small groups and will usually try to escape on foot through undergrowth
and avoid flying, though they will fly into tall trees to roost. The bird has a
celebrated status in Indian mythology, and hence protected culturally in India
especially in Gujarat. The Indian Peafowl is listed as Least Concern by IUCN (2014)
Red data.
Photographs of Peafowl
Appearance: The male, known as a peacock, is a large bird with a length from bill
to tail of 100 to 115 cm (40 to 46 inches) and to the end of a fully grown train as
much as 195 to 225 cm (78 to 90 inches) and weigh 4–6 kg. The females, or
peahens, are smaller at around 95 cm (38 inches) in length and weigh 2.75– 4 kg.
Indian Peafowl are among the largest and heaviest representatives of the
Phasianidae family. Their size, colour and shape of crest make them unmistakable
within their native distribution range. The male is metallic blue on the crown, the
feathers of the head being short and curled. The fan shaped crest on the head is
made of feathers with bare black shafts and tipped with blush-green webbing. A
white stripe above the eye and a crescent shaped white patch below the eye are
formed by bare white skin. The sides of the head have iridescent greenish blue
feathers. The back has scaly bronze-green feathers with black and copper
markings. The scapular and the wings are buff and barred in black, the primaries
are chestnut and the secondaries are black. The tail is dark brown and the "train" is
made up of elongated upper tail coverts (more than 200 feathers, the actual tail
has only 20 feathers) and nearly all of these feathers end with an elaborate eye-
spot. A few of the outer feathers lack the spot and end in a crescent shaped black
tip. The underside is dark glossy green shading into blackish under the tail. The
thighs are buff coloured. The male has a spur on the leg above the hind toe.
Peacocks are polygamous, and the breeding season is spread out but appears to be
dependent on the rains. Several males may congregate at a lek site and these
males are often closely related. Males at lek appear to maintain small territories
next to each other and they allow females to visit them and make no attempt to
guard harems. Females do not appear to favour specific males. Peafowl are
omnivorous and eat seeds, insects, fruits, and reptiles. A large percentage of their
food is made up of the fallen berries. Around cultivated areas; peafowl feed on a
wide range of crops such as groundnut, tomato, paddy, etc. Around human
habitations, they feed on a variety of food scraps. In the countryside, it is
particularly partial to crops and garden plants.
Status & impact in the Study Area:
No peacock was sighted in the project site. All the direct sightings of the peacock
were located near the human habitats, villages and agriculture field, of study area.
This species is well adapted to natural village environment setting. Day time they
temporarily move towards the surrounding agriculture areas for feeding while
during night time they roost on the trees present in the village and in the
agriculture hedges.
Since Indian Peafowl is a ground nester, several project activities can have adverse
Impact on their nesting grounds such as pollution, degradation of soil and
vegetation from surrounding area and in the forest areas. Direct disturbance by
presence of people, vehicle their noise, vibration, light etc. can potentially disturb
most of the bird species.
Threats in the Study Area:
No perceptible threats were identified in the study region, as
Village residents are against hunting or poaching of the peafowl, due to
culture and mythology reasons.
Majority villagers follow Hinduism in the region, thus they have high respect
towards peacocks due to mythological reasons, and
Literacy levels are greater than 80% in the study region and people are
aware with the significance of the peacock as the national bird.
Conservation: Following actions for the conservation and protection are suggested
in wildlife conservation action plan to reduce impacts of project related activities on
the species. Based on our field observation on the distribution, behavioural ecology,
conservation need, and envisaged impacts of proposed project.
Conservation through Habitat Improvement and Awareness
Habitat improvement programme can be undertaken through plantation of suitable
tree species in the surrounding villages. While selecting the tree/ shrub species care
shall be provided for beery plants which attract these birds. During summer period,
villagers will be encouraged to use the old earthen pots to fill with water for
drinking these birds.
Seed Distribution among the Villagers:
Summer is the time when these birds are facing shortage of feeds, there by
supplying the feed like Bajri, Juwar, Maize to the surrounding villages with good
population of Indian peafowls will suffix the problem of food shortage.
Conservation Measures with fund allocation:
In consultation of the forest department, following conservation measures will be
adapted for peacock conservation:
1. Increasing the tree cover in the study area which will provide shelter and
roosting to the peacocks. This can be achieved by planting of local tree species
like Neem, Shirish, Khakhro, Haldu, Amli, Banyan, Peepal and Peeper or other
Ficus sp. Vacant places such as edges of agricultural fields, village Gauchar,
Panchayat’s common land, neighbourhood of people inhibiting, road side avenue
tree plantation, open scrubs, ravines, school compounds can be selected for
practicing the plantation activity.
2. School level awareness programmes will be conducted for conservation of
peacocks in the study area by organizing competitions during “Wildlife Week”
and “Van Mahotsav” celebrations by active involvement of local community.
3. Some provision of rewards to informers for the control of poaching and illegal
trade in wildlife.
4. Carrying out census and research projects to know the potential threats and
population status of the species in collaboration of local schools, colleges,
panchayats and forest department.
5. Suggest strategies to minimize negative impacts of changing environment in
nearby area of peacock populations and to promote conservation of peacock
habitats.
6. Another way to help preserve the endangered species is to create society
dedicated to ecological ethics. All the conservation measures will be
implemented with the help of and in the consultation of the district forest
department.
The proponent has proposed a sum of Rs. 220000/- for the “Peacock”
conservation plan under the following heads:
Sr.
No.
Work or Activity Approximate
Cost. Rs.
Village
1 Plantation-350 tree plants (5 feet height
as per the plant species-Cost of sapling
will be changed per year)
70,000/-(@
200/-per
plant)
Dabhasa, Ranu,
Dhobikuwa and
Mahuvad
2 Small water tank–10 nos. @ 10000/-per
tank
1,00,000/-
3 One awareness programme for “Peacock”
conservation
20,000/- Study area
4 3 cash prizes @ 10000 in a year will be
awarded to the informer of poachers.
30,000/-
Total 2,20,000/-
Annexure-IV
Revised CER based on local needs
Need Analysis of the Target Beneficiaries in the Project Area
Various needs were identified during the baseline survey within the study
area. Major problems they are facing are given below.
Poor availability of water for irrigation and drinking purpose
Lack of good medical facilities
Unemployment
Health and sanitation program
Poor educational facilities
In the assessment of socio-economic conditions, few indicators were
identified for further attention and strategic planning as given below:
Target Project Area
Total 53 villages fall within the study area; Out of which unit will give
priorities to 4 villages namely 4 villages (Dabhasa, Ranu, Dhobikuwa
and Mahuvad) for CER activities according to the below mentioned criteria.
Largely affected by industrial growth
Vicinity to the project site
Sourcing of employees from these areas
Low level socio-economic status of the people
Lack of adequate intervention of voluntary organization in the
area
The focus area of comprehensive program includes: health, education,
sanitation, sustainable livelihood & infrastructure development.
Details of expenditure for ESR activities(Revised):
Cost of the proposed project : Rs. 40 Crores
Expenditure earmarked towards ESR : Rs. 2.0 Crore
(5.0 % of the total project cost)
Detailed expenditure break-up for CER activities*
Sr.
No.
Activities Years (Rs. in lakhs) Total
Budget
(Rs. in
Lakhs)
1st 2nd 3rd
1 Educational activities
Computers 6.08 6.08 -- 12.16
Scholarship 12.8 12.8 12.8 38.4
2 Drinking water facilities 12 sets of RO and
water cooler at
Primary school and
village Panchayat of 4
villages
14.0 14.0 14.0 42.0
Operating and
maintenance cost
2.0 2.0 2.0 6.0
3 Public Health and family
welfare
Around 10 camp with
cluster of 5 to 6
villages
4.0 4.0 4.0 12.0
Free Medicines 6.0 6.0 6.0 18.0
4 Provide Sawing and
embroidery machine to
women coming from
BPL family and widow
women.
All 53 villages in the
study area
Onetime 100 nos
Sawing machine
5.0 5.0 5.0 15.0
Onetime 50 no
embroidery Machine
5.0 5.0 2.5 12.5
5 Widening and digging of
four village pond
namely
Dabhasa, Bhoj Ranu
Pond and Dabka and
other as per the
suggestion by local
authorities.
8 village pond 22.0 22.0 -- 44.0
Total 76.88 76.8
8
46.3 200.06
*Increase the CER budget from 2.5% to 5.0% as suggested by EAC
committee (Industry-II). Reduce the estimated utilization fund
within 5 years to 3 years. However, project will completed earlier
then the estimated time then utilize CER fund accordingly.
Quantify CER activities in details
Proposed Activities Selected areas or
villages
Frequency Financial provision
in Lakhs
Educational
Provide the
Computer
Secondary School
and Higher
Secondary school of
4 villages
One time
8 Computer x 4
32 x 38000
Total Rs. 12.16
Scholarship to poor
children around 160
students
(40 on merit basis of
each 4 village
student of Secondary
& Higher secondary
school
Every year up to 3
years
Rs.8000 x 160 x 3
Years
Total Rs.38.4
Drinking water facility
Water Cooler, RO
4 sets of RO and
water cooler at
Primary school of 4
villages
Onetime
350000 x 10
Total Rs.42.0
8 sets of RO and
water cooler at
Village Panchayat of
8 villages
Operating and
maintenance cost
-- Three Years 12 x 0.5
Total Rs.6.0
Public Health and family welfare
Medical camp and
free medicine
Around 10 camp with
cluster of 5 to 6
villages
10 camp up to three
Years during rainy
days
10 x 0.4 x 3 years
Total Rs.12.0
Free Medicines 10 x 0.6 x 3 years
Total Rs.18.0
Women Empowerment & children Development activities
Provide Sawing and
embroidery machine
to women coming
from BPL family and
widow women.
All 53 villages in the
study area
Onetime
100 nos Sawing
machine
100 x 15000
Total Rs.15.0
Onetime
50 no embroidery
Machine
50 x 25000
Total Rs.12.5
Environment Sustainability - Ground water recharging
Widening and digging
of four village pond
namely
Dabhasa, Bhoj Ranu
Pond and Dabka and
other as per the
suggestion of local
authorities.
8 village pond One time
(550000
x 8 =
Total 44.0
Total Rs. 200.06 Lakhs
Annexure-V
Details technology/mitigation measure to achieve the Volatile
organic compounds (VOCs)/Fugitive emissions @ 99.997%.
Unit will use Methanol, Dichloromethane, Isopropyl Alcohol, Ethyl Acetate,
Acetone, Toluene, Chloroform, Hexane and Dimethyl Formamide (DMF) etc.
These are mostly transferred to reactors by means of pumps and their
related pipelines. Pumps are provided with proper mechanical seal, and
pipeline is connected with each other by flanges and gaskets. There will be
practically no emission of solvents in form of VOCs. The leak detector and
emission will be checked by digital transmitter with smart sensor. If the
detection level exceed in the work area of half level of TLV/TWA value,
immediate action will be taken by operator to shut down valve/pump to
prevent the leak and emission of gas. Periodically preventive maintenance
schedule shall also be conducted by team.
Unit will handle following solvent having following physical properties namely
BP oC and FP oC.
Solvent to be used with B.P. and F.P. Sr. No. Name of solvent BP oC FP oC
1 Methanol 64.5 12
2 Dichloromethane 39.75 NA
3 Isopropyl Alcohol 82.5 18.3
4 Ethyl Acetate 77.0 -4.4
5 Acetone 56.2 -20
6 Toluene 110.6 4.44
7 Chloroform 61 NA
8 Hexane 69 -22
9 Dimethyl Formamide (DMF) 153 57.7
Unit will follow following LDAR (Leak Detection and Repair)
Programme.
1. Unit will prepare summary of possible Sources of equipment leaks like;
Pumps, Valves, Joints/ Connectors, Pressure relief devices, Open-
ended lines etc.
2. Regular monitoring to check and repair leaking components, including
valves, pumps, connectors, compressors, and agitators, in order to
minimize the emission of fugitive volatile organic compounds (VOCs).
3. Unit will use VOC meter to detect the VOCs and its source to repairing
any leakages
4. Find the Sources of leakages, its Causes and Control the Leaks by way
of modifying/replacing leaking equipment with “leakless” components.
5. Develop awareness of the benefits of leak detection and repair into the
company’s operating and maintenance program in terms of cost
savings, environmental protection, and worker and community safety.
6. Reducing Product Losses, Increasing Safety for Facility Workers and
Operators, Decreasing Exposure for the Surrounding Community,
Avoiding Enforcement Actions.
7. Install Brine chiller (-10 to -200C chiller) for secondary condenser of
solvent recovery system to achieve VOCs loss practically zero.
8. Use Double seal/mechanical seal for control of VOC.
9. Closed handling system shall be provided for chemicals.
10. Reflux condenser shall be provided over reactor.
11. System of leak detection and repair of pump/pipeline based on
preventive maintenance.
12. The acids shall be taken from storage tanks to reactors through closed
pipeline.
13. Storage tanks shall be. vented through trap receiver and condenser
operated on chilled water
14. The condensers shall be providing with sufficient HTA and residence
time to achieve maximum recovery.
15. Solvents shall be stored in a separate space specified with all safety
measures
16. Proper Earthing shall be providing in all the electrical equipment
wherever solvent handling is done.
17. Entire plant shall be flameproof. The solvent storage tanks shall be
providing with breather valve to prevent losses.
Final Environmental Impact
Assessment Report &
Environment Management Plan
of
Reynish Pharmachem Pvt. Ltd.
Survey No. 504, 505, 507, Village: Dabhasa,
Tehsil: Padra, Dist. Vadodara, Gujarat
Proposed Project for Manufacturing of
Bulk Drugs - 50 MTPM
Project Activity: 5(f), Category: A
[ToR Letter No. F. No. J-11011/194/2018-IA-II(I), dated 13.07.2018]
[Study Period: October, 2018 to December, 2018]
Prepared by
San Envirotech Pvt. Ltd.
(NABET Accreditation No. NABET/EIA/1619/RA0084; Valid till 15.06.2020)
424, Medicine Market, Paldi Cross Road, Ahmedabad-380006, Gujarat
Email: [email protected]
Version History
SAN-EIA-REY-V1 March 2019 Submitted for PH
SAN-EIA-REY-V2 August 2019 Modified after PH, submitted to MOEF&CC for
appraisal
SAN-EIA-REY-V3 May 2020 Modified after 18th EAC (Industry-2)
meeting
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. I
Contents Particulars Page No.
Index I
List of Tables X
List of Figures XIII
List of Annexures XIV
Index Chapter 1 Introduction Page No.
1.1 Preface 1-1
1.2 Purpose of the Report 1-1
1.3 Identification of Project & Project Proponent 1-2
1.4 Importance of the project 1-2
1.5 Brief description of project 1-3
1.6 Applicable environmental regulatory framework 1-4
1.7 Scope of the study 1-5
1.8 Compliance to Terms of Reference 1-5
1.9 Objective of EIA 1-18
1.10 Methodology for EIA 1-18
1.11 List of Industries surrounding project site 1-19
1.12 Structure of report 1-21
Chapter 2 Project Description
2.1 Introduction 2-1
2.2 Location of the Project 2-1
2.3 Size or magnitude of operation 2-4
2.3.1 Land breakup & project site layout 2-4
2.3.2 Project Magnitude 2-5
2.4 Infrastructure Facilities 2-6
2.5 Description of manufacturing process 2-7
2.6 Project Components 2-28
2.7 Input Requirements 2-28
2.8 Generation of pollutants 2-34
2.8.1 Wastewater generation 2-34
2.8.2 Gaseous emission 2-34
2.8.3 Hazardous/ solid waste generation 2-36
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2.8.4 Noise Generation 2-37
2.9 Pollution control strategy 2-37
2.9.1 Effluent management 2-37
2.9.2 Air pollution control measures 2-40
2.9.3 Hazardous/solid waste management 2-41
2.9.4 Noise pollution control measures 2-42
2.10 Rain water harvesting 2-42
2.11 Green Belt Development 2-42
2.12 Occupational health & safety 2-42
Chapter 3 Description of Environment
3.1 General 3-1
3.2 Study area 3-1
3.3 Study Period 3-2
3.4 Source of environmental data generation 3-2
3.5 Methodology 3-3
3.6 Land Environment 3-3
3.6.1 Land use pattern of the Study Area 3-3
3.6.2 Objective of Land Use Studies 3-5
3.6.3 Topography 3-5
3.6.4 Seismicity of the area 3-5
3.7 Meteorology 3-6
3.7.1 Site specific micro-meteorological data 3-6
3.7.2 Wind Rose 3-7
3.8 Ambient air quality 3-7
3.8.1 Introduction 3-7
3.8.2 Design of Network for Ambient Air Quality
Monitoring Stations
3-7
3.8.3 Reconnaissance 3-8
3.8.4 Parameters, Frequency and monitoring
Methodology
3-8
3.8.5 Interpretation of result 3-9
3.9 Water Environment 3-10
3.9.1 Geology 3-10
3.9.2 Hydrogeology 3-11
3.10 Water quality 3-12
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3.10.1 Introduction 3-12
3.10.2 Sampling Frequency, Techniques & Methodology 3-13
3.10.3 Surface Water Quality (Primary data) 3-14
3.10.4 Ground Water Quality 3-14
3.10.5 Interpretation 3-14
3.10.6 Conclusion 3-15
3.11 Noise Environment 3-15
3.11.1 Instrument used for Sampling and Monitoring 3-15
3.11.2 Noise Quality Monitoring Locations 3-16
3.11.3 Ambient Noise Standards 3-16
3.11.4 Results 3-16
3.11.5 Conclusion 3-16
3.12 Soil Environment 3-17
3.12.1 Soil sampling locations 3-17
3.12.2 Methodology 3-18
3.12.3 Corollaries 3-19
3.12.4 Conclusion 3-20
3.13 Biological Environment 3-20
3.13.1 Period of the study 3-20
3.13.2 Study methodology 3-20
3.13.3 Floral species in the study area 3-21
3.13.4 Fauna in the study area 3-21
3.14 Socio Economic Environment 3-23
3.14.1 Objective of the study 3-23
3.14.2 Land use pattern and infrastructure 3-23
3.14.3 Demographic and Socio-Economic Environment 3-24
3.14.4 Living Standard and Infrastructure 3-24
Chapter 4 Anticipated Environmental Impacts &
Mitigation Measures
4.1 General 4-1
4.2 Identification of Impact 4-2
4.2.1 Identification of Impacting Activities 4-2
4.2.2 Identification of Environment Attributes 4-3
4.3 Impact on Topography 4-3
4.4 Impact on Air Environment 4-3
4.4.1 Air Pollution Dispersion modeling of stack 4-4
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4.4.2 Micrometeorology 4-5
4.4.3 Input data 4-6
4.4.4 Receptor Network 4-6
4.4.5 Output of Model (24-hourly GLCs) 4-7
4.4.6 Incremental & cumulative concentration of
pollutants
4-7
4.4.7 Conclusion 4-7
4.5 Impact on Water Environment 4-7
4.6 Impact on Noise Environment 4-9
4.7 Impact on Land Environment 4-10
4.8 Impact on Biological Environment 4-11
4.9 Impact on Socio-Economic Environment 4-14
4.10 Impact on Occupational Health & Safety 4-15
4.11 Impact on Traffic Movement 4-16
Chapter 5 Analysis of Alternatives
5.1 Prologue 5-1
5.2 Site Alternative 5-1
5.3 Process Alternative 5-4
Chapter 6 Environmental Monitoring Program
6.1 Prelude 6-1
6.2 Environment Monitoring Program 6-1
6.3 Objective of Monitoring Plan 6-1
6.4 Schedule for Environment Monitoring 6-2
6.5 Ambient Air Quality Monitoring 6-2
6.6 Water Environment Monitoring 6-3
6.7 Noise Environment Monitoring 6-3
Chapter 7 Additional Studies
(A) HAZARD ANALYSIS & RISK ASSESSMENT 7-1
7.1 Introduction 7-1
7.2 Risk Assessment- Identification of Hazards 7-1
7.3 Hazardous Materials Storage 7-3
7.4 Risk Screening Approach 7-4
7.4.1 Acute Exposure Guideline Levels (AEGLs) 7-7
7.4.2 Emergency Response Planning Guidelines (ERPGs) 7-9
7.5 QRA Approach 7-10
7.6 Thermal Hazards 7-10
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7.7 Damage due to explosion 7-12
7.8 Toxic release 7-12
7.9 Acid/Alkali Hazards 7-13
7.10 Likely Failure Scenarios 7-14
(B) Quantitative Risk Assessment & Consequence
Analysis
7-15
7.11 Preamble 7-15
7.11.1 Weather Effect 7-15
7.12 Incidents Impacts 7-15
7.13 Consequential Impacts 7-18
7.13.1 Thermal and Explosion Hazards 7-18
7.13.2 Toxic Hazards 7-18
7.13.3 Other Hazards 7-19
7.13.4 Other Toxic Hazards 7-19
7.14 Occupational Health 7-19
7.15 Conclusion & Recommendations 7-22
7.16 Action plan for handling & safety system of
chemical
7-23
7.16.1 Safety measures for transportation and unloading
of hazardous chemicals
7-23
7.16.2 Safety measures for storage/handling of hazardous
chemicals
7-23
7.16.3 Safety measures for process units 7-24
7.16.4 Safety measures for preventive maintenance 7-25
7.16.5 Safety measures to prevent spillage/leakage of
toxic chemicals
7-25
7.17 Arrangements for ensuring health & safety of
workers engaged in handling of toxic materials
7-25
(D) Disaster management plan 7-27
7.18 Onsite Emergency plan 7-29
7.18.1 Incident controller 7-29
7.18.1.1 Duties of Incident controller 7-29
7.18.2 Site main controller 7-30
7.18.2.1 Duties of site main controller 7-30
7.18.3 Other key personnel 7-31
7.18.3.1 Emergency response team 7-31
7.18.3.2 Emergency personnel’s responsibilities outside
normal working hours of the factory
7-31
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7.18.3.3 Assembly points 7-32
7.18.4 Emergency control centre 7-32
7.18.4.1 Role of emergency control centre 7-32
7.18.5 Fire & Toxicity control arrangements 7-33
7.18.6 Medical arrangements 7-33
7.18.7 Transport & evacuation, mutual aid arrangements 7-33
7.19 Communication system 7-33
7.19.1 Declaring the emergency 7-33
7.19.1.1 Type of sirens 7-33
7.19.1.2 Location of siren 7-34
7.19.1.3 Raising alarm 7-34
7.19.2 Internal communication 7-35
7.19.2.1 Availability of key personnel outside normal
working hours
7-35
7.19.3 Communication to the authorities 7-35
7.20 Pre emergency activities 7-36
7.21 Post-emergency activities 7-36
7.21.1 Evacuation and transportation 7-36
7.21.2 Safe close down 7-37
7.21.3 Use of mutual aid 7-37
7.21.4 Use of external authorities 7-37
7.21.5 Medical treatment 7-37
7.21.6 Accounting for personnel 7-37
7.21.7 Access to records 7-37
7.21.8 Public relations 7-37
7.21.9 Rehabilitation 7-37
7.22 Causes of emergency 7-38
7.22.1 Risk 7-38
7.22.1.1 Nature 7-38
7.22.1.2 Various emergency actions 7-38
7.22.1.3 Response time-minutes 7-39
7.23 Offsite emergency plan 7-39
7.23.1 Need of the site emergency plan 7-39
7.23.2 Structure of the off-site emergency plan 7-40
7.23.3 Role of the factory management 7-40
7.23.4 Role of emergency co-ordination office (ECO) 7-40
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7.23.5 Role of local authority 7-40
7.23.6 Role of fire authorities 7-40
7.23.7 Role of the police and evacuation authorities 7-40
7.23.8 Role of health authorities 7-41
7.23.9 Role of mutual aid agencies 7-41
7.23.10 Role of factory inspectorate 7-41
7.24 Mock drills and records 7-41
7.24.1 Need of rehearsal & training 7-41
7.24.2 Some check points 7-41
7.24.3 Records and updating the plan 7-41
(D) PUBLIC CONSULTATION 7-42
(E) Social Impact Assessment 7-45
Chapter 8 Project Benefits
8.1 Introduction 8-1
8.2 Improvement in Physical Infrastructure 8-1
8.3 Improvement in Social Infrastructure 8-1
8.4 Employment Potential 8-2
8.5 Other Tangible Benefits 8-2
Chapter 9 Environmental Cost Benefit Analysis 9-1
Chapter 10 Environment Management Plan
10.1 Introduction 10-1
10.2 Environmental Management During Construction
Phase
10-2
10.2.1 Air & Noise Environment 10-2
10.2.2 Water Environment 10-2
10.2.3 Socio-Economic Environment 10-2
10.2.4 Health & Safety 10-2
10.3 Environmental Management during the Operational
Phase
10-3
10.3.1 Air Pollution Management 10-3
10.3.1.1 Source of Air Pollution & Control Measures 10-3
10.3.1.2 Measures for Solvent Recovery 10-4
10.3.1.3 Odour Control Plan 10-6
10.3.2 Water Environment 10-6
10.3.3 Hazardous/Solid waste management 10-7
10.3.4 Noise Control 10-8
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10.3.5 Green Belt Development 10-9
10.3.6 Occupational Health & Safety Plan 10-11
10.3.7 Details of the separate isolated storage area 10-13
10.4 Post Project Environmental Monitoring 10-13
10.4.1 Details of Work Place Air Quality Monitoring Plan 10-15
10.5 Environment Management Budget Allocation 10-15
10.6 Environmental Management Cell 10-15
10.6.1 Hierarchical Structure of Environmental
Management Cell
10-16
10.6.2 Environment Policy 10-16
10.6.3 Reporting System of Non-Compliances/Violations
of Environmental Norms
10-17
10.6.4 Framework for Continual Improvement of
Environmental Performance of Organization
10-18
10.7 Resource Conservation and Cleaner Production 10-18
10.8 Energy conservation programme 10-19
10.9 Socio Economic Activities 10-19
Chapter 11 Summary & Conclusion
11.1 Project Description 11-1
11.1.1 General Introduction 11-1
11.1.2 Brief project description 11-1
11.1.3 Investment of the Project 11-2
11.1.4 List of Products 11-2
11.2 Description of Environment 11-2
11.2.1 Baseline Environmental Study 11-2
11.2.2 Air Environment 11-3
11.2.3 Water Environment 11-4
11.2.4 Noise Environment 11-5
11.2.5 Soil Quality 11-6
11.2.6 Biological Environment 11-6
11.2.7 Socio-Economic Environment 11-6
11.3 Anticipated Environmental Impacts and Mitigation
Measures
11-6
11.3.1 Summary of Impacts on Air Environment 11-6
11.3.2 Summary of Impacts on Water Environment 11-7
11.3.3 Impacts on Noise quality & Mitigation measures 11-8
11.3.4 Summary of Impacts on Land Environment 11-8
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11.3.5 Summary of Impact on Socio Economy 11-9
11.3.6 Summary on Impact on Ecology 11-9
11.4 Environment Monitoring Programme 11-9
11.5 Additional Studies 11-10
11.5.1 Risk Assessment 11-10
11.6 Project Benefits 11-10
11.7 Environmental Management Plan 11-10
11.8 Conclusion 11-12
Chapter-12 Disclosure of Consultant engaged
12.1 Preface 12-1
12.2 Details of EIA Consultant Organization 12-1
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. X
List of Tables
Table No.
Name Page No.
1.1 Salient features of the project 1-3
1.2 Product details 1-4
2.1 Boundary coordinates of the site 2-3
2.2 Land breakup 2-4
2.3 List of products with its capacity 2-5
2.4 List of machineries/equipment 2-6
2.5 Raw Materials Requirement, Availability & of Transport
Mode
2-28
2.6 Breakup of water consumption & w/w generation 2-32
2.7 Details of utilities and fuel consumption 2-34
2.8 Details of stacks 2-35
2.9 Estimated Emission quality of stack 2-35
2.10 Details of solid/Hazardous waste 2-36
2.11 Name and size of ETP units 2-38
2.12 Technical specification of RO 2-39
2.13 Technical Details of MEE 2-40
2.14 Estimated characteristic of untreated and treated effluent 2-40
3.1 Environmental setting of the study area 3-2
3.2 Land use statistics work out based on satellite imaginary 3-5
3.3 Monitoring Methodology of Meteorological Data 3-6
3.4 Meteorological Data for the Monitoring Period 3-7
3.5 Methodology of Ambient Air Monitoring 3-8
3.6 Monitored Parameters and Frequency of Sampling 3-9
3.7 Sampling locations with source & date of sampling 3-13
3.8 Monitoring Methodology of Noise 3-16
3.9 Location of soil sampling 3-18
3.10 Methodology of Soil Sample analysis 3-18
3.11 Ambient Air Quality Monitoring Locations 3-26
3.12 Ambient Air Quality Status 3-27
3.13 Ambient Air Quality Status (PM10) 3-28
3.14 Ambient Air Quality Status (PM2.5) 3-29
3.15 Ambient Air Quality Status (SO2) 3-30
3.16 Ambient Air Quality Status (NOx) 3-31
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3.17 Ambient Air Quality Status (CO, HC (Methane & non-
Methane), VOC, HCl)
3-32
3.18 National Ambient Air Quality Standards 3-33
3.19 Results of Groundwater Quality in the Study Area 3-34
3.20 Surface water analysis of Study Area 3-35
3.21 Indian Standard Specification for Drinking Water 3-36
3.22 Ambient Noise Levels in the Study Area 3-37
3.23 Ambient Air Quality Standards with respect to Noise 3-37
3.24 Soil Analysis of Study area 3-38
3.25 Floral Diversity 3-39
3.26 Faunal Biodiversity 3-41
3.27 Traffic Survey 3-42
3.28 Land Use Pattern 3-43
3.29 Summary of Socio-Economic Status of Study area
(Demography)
3-45
3.30 Summary of Socio-Economic Status of Study area
(Amenities)
3-47
4.1 Input data for air quality modeling 4-17
4.2 Cumulative Concentrations at various locations 4-18
4.3 The 24-hourly average GLC Concentration Values for SPM 4-19
4.4 The 24-hourly average GLC Concentration Values for SO2 4-20
4.5 The 24-hourly average GLC Concentration Values for NOx 4-21
4.6 The 24-hourly average GLC Concentration Values for HCl 4-22
6.1 Environment Monitoring Plan 6-4
7.1 Bulk storage of Hazardous Chemicals 7-3
7.2 Hazard Analysis- Raw materials (stored in bulk) 7-5
7.3 Properties of Hazardous Materials 7-7
7.4 Risk Classification 7-10
7.5 Effects due to Incident Radiation intensity 7-11
7.6 Thermal Radiation Impact to human 7-11
7.7 Tolerable Intensities for various objects 7-11
7.8 Damage due to overpressure 7-12
7.9 Different failure scenarios 7-14
7.10 Hazards scenario impact 7-18
7.11 Points raised during public hearing 7-42
7.12a Detailed expenditure break-up for CER activities 7-50
7.12b Quantify CER activities in details 7-51
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10.1 Details of solvent to be used 10-4
10.2 Environment Monitoring Plan 10-14
10.3 Budget Allocation for Environment Management 10-15
10.4 Budgetary provisions for the social upliftment 10-21
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List of Figures
Figure No.
Name Page No.
2.1 Location of the project site 2-2
2.2 Location of Google map 2-3
2.3 Image showing all boundary coordinates of the site 2-3
2.4 Plant layout 2-5
2.5 Water Balance Diagram 2-33
2.6 Process flow chart of wastewater treatment 2-39
3.1 Land use map 3-4
3.2 Graphical representation of ambient air quality 3-27
3.3 Graphical representation for PM10 3-28
3.4 Graphical representation for PM2.5 3-29
3.5 Graphical representation for SO2 3-30
3.6 Graphical representation for NOx 3-31
3.7 Location of AAQM station 3-54
3.8 Wind Rose Diagram 3-55
3.9 Water sampling Locations 3-56
3.10 Noise monitoring Locations 3-57
3.11 Soil Sampling Locations 3-58
3.12 Topo sheet of location with site location map of 10 km radius (1:50,000 scale)
3-59
4.1 Isopleths for Ground Level Concentration for SPM 4-23
4.2 Isopleths for Ground Level Concentration for SO2 4-24
4.3 Isopleths for Ground Level Concentration for NOx 4-25
4.4 Isopleths for Ground Level Concentration for HCl 4-26
7.1 Methanol Tank BLEVE — Thermal Impact Zone 7-16
7.2 Dichloromethane Tank Leakage — Toxic Impact Zone 7-16
7.3 Ethyl Acetate Tank Leakage Pool Fire —Thermal Impact
Zone
7-17
7.4 Acetone Tank Leakage — Toxic Impact Zone 7-17
7.5 Hydrochloric Acid Tank Leakage – Toxic Impact Zone 7-17
10.1 Environment Management Cell 10-16
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List of Annexures
Sr. No. Annexures Page no.
I. NABET-QCI Certificate A–1
II. Photographs of the Site A–3
III. Land Possession Documents A–4
IV. Material Safety Data Sheet of Chemicals A-9
V. Undertaking from Consultant A–111
VI. Undertaking from Project Proponent A–112
VII. Copy of Terms of Reference (TOR) A–114
VIII. Minutes of Public hearing A–122
IX. Hourly Meteorological data A–153
X. Detailed AAQM, Ground Water, Surface Water, Soil,
Noise Result Tables
A–199
XI. Wildlife Conservation Plan submitted for Schedule I
species Pavo Cristatus
A–215
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Chapter-1
Introduction
1.1 PREFACE
An Environmental Impact Assessment (EIA) is an assessment of the
possible impacts that a proposed project may have on the environment -
consisting of the environmental, social and economic aspects. It is an
assessment and management tool that evaluates the possible impacts,
positive or negative, that a proposed project may have on the
environment. EIA systematically examines both beneficial and adverse
consequences of the project and ensures that these effects are taken into
account during project design. The purpose of the assessment is to
ensure that decision makers consider the ensuing environmental impacts
when deciding to proceed with a project. In India, Ministry of
Environment and Forests has defined elaborated “Environmental
Clearance (EC)” framework along with requirements for preparing
Environmental Impact Assessment (EIA) under the Environmental
(Protection) Act, 1986 (Environmental Impact Assessment Notification,
2006) for establishing/expanding and industry/development projects.
1.2 PURPOSE OF THE REPORT
Industrialization and infrastructure development have increased economic
growth and improved living standards of people in India. However,
development has led to rapid consumption of natural resources and
increased emissions of waste. To control the pollutions from industrial
activity, government has framed regulations which are governed by
Ministry of Environment, Forest & Climate Change in India. Environment
Impact analysis is mandatory as per the Environment Impact Assessment
(EIA) Notification issued by Ministry of Environment, Forest & Climate
Change (MoEF&CC), New Delhi dated 14th September, 2006 and its
subsequent amendment; for setting up a new projects or activities, or
expansion or modernization of existing projects or activities based on
their potential environmental impacts as indicated in the Schedule to the
notification, being undertaken in any part of India, unless prior
environmental clearance has been accorded.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-2
Proposed activity of M/s. Reynish Pharmachem Pvt. Ltd. falls under
the schedule of 5(f) category- Synthetic organic chemicals industry
(dyes & dye intermediates; bulk drugs and intermediates excluding drug
formulations; synthetic rubbers; basic organic chemicals, other synthetic
organic chemicals and chemical intermediates) and categorized under
“A”. Therefore, unit requires prior Environmental Clearance for proposed
project.
EIA Consultant
In view of the above, legal aspect and monitoring work has been carried
out for all the environmental attributes by M/s. San Envirotech Pvt.
Ltd. (SEPL), Ahmedabad. SEPL is accredited as Category-A organization
under the QCI-NABET Scheme for accreditation of EIA consultant
Organizations: Version 3 for preparing EIA-EMP reports in 10 sectors.
Final Environment Impact Assessment (EIA) and Environmental
Management Plan (EMP) have been prepared after obtaining Terms of
References (TORs) from Ministry of Environment, Forests & Climate
Change (MoEF&CC), New Delhi. The public hearing will be conducted by
SPCB based on draft EIA/EMP submitted by project proponent. Final
EIA/EMP report is prepared incorporating to comments of Public hearing
and compliance of the Terms of References.
1.3 IDENTIFICATION OF PROJECT & PROJECT PROPONENT
Project is promoted by young entrepreneur Nishant P. Patel. Reynish
Pharmachem Pvt. Ltd. proposes to set up bulk drugs manufacturing
unit at Survey no. 504, 505, 507, Village: Dabhasa, Ta: Padra, District:
Vadodara, Gujarat. Required facilities like infrastructure, communication,
medical facilities, fuel, water, power, unskilled & skilled manpower, raw
materials, road network etc. are readily available, therefore, no other
optional site or area was considered. There is no Rehabilitation and
Resettlement involved. Nearest city Vadodara is about 20 km away from
the site, which is having connectivity with other parts of the country by
road, rail & air.
1.4 IMPORTANCE OF THE PROJECT
The Indian pharmaceuticals market is the 3rd largest in terms of volume
and 13th largest in terms of value. It accounts for 20% in the volume
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terms and 1.4% in value terms of the Global Pharmaceutical Industry as
per a report by Equity Master. India is the largest provider of generic
drugs globally with the Indian generics accounting for 20% of global
exports in terms of volume. The Indian pharmaceutical market size is
expected to grow to US$ 100 billion by 2025, driven by increasing
consumer spending, rapid urbanization, and raising healthcare insurance
among others. Pharma sector‟s revenues are expected to grow by 9 per
cent year-on-year through fiscal 2020. India having unique blend of low-
cost manufacturing, R&D infrastructure, skilled workforce, as well as
gigantic domestic market and world dominance in generics production,
needs to increase its production capacity of pharmaceuticals.
1.5 BRIEF DESCRIPTION OF PROJECT
Salient features of the project and list of products are given in Table 1.1
and Table 1.2, respectively.
Table 1.1 Salient Features of the Project
Name of the Project Reynish Pharmachem Pvt. Ltd.
Proposed production capacity 50 MTPM
Proposed project cost Rs. 40 Crores
Manpower requirement About 65 persons
Location
Survey No. 504, 505, 507
Village Dabhasa
Tehsil Padra
District Vadodara
State Gujarat
Area 36958 m2
Coordinates Latitude: 22°13'32.76"N
Longitude: 73° 1'13.01"E
Nearest
Railway Station Vadodara Railway Station - 19 km,
Padra Railway station - 7.0 km
Air Port Vadodara Airport, about 24 km
Town Padra, about 7.0 km
City, District Headquarters Vadodara, about 20 km
National Park/Wildlife Sanctuary None, within 10 km radius
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-4
Table 1.2 Product details
Sr.
No.
Name of Products Qty.
(MTPM)
1. Telmisartan 48.0
2. Ondansetron HCl
3. Benfotiamine
4. Albendazole
5. 4-Hexyl resorcinol
6. Zopiclone
7. Tamoxifen citrate
8. Bupropion HCl
9. Anstrozole
10. Theophylline
11. Allantoin
12. Terbinafine Hydrochloride
13. Pregabalin Hydrochloride
14. Rebamipide
15. Valsartan
16. R & D Drugs 2.0
Total 50.0
1.6 APPLICABLE ENVIRONMENTAL REGULATORY FRAMEWORK
The proposed project will abide and function under the purview of the
following Rules, Acts & Regulations which are formulated by the Govt. of
India to protect the environment and development in a sustainable way.
The Water (Prevention & Control of Pollution) Act, 1974
The Air (Prevention & Control of Pollution) Act, 1981
The Environmental (Protection) Act, 1986
Environmental Impact Assessment Notification dated 14th September
2006 and subsequent amendments
The Hazardous & Other Waste (Management and Transboundary
Movement) Rules, 2016
Noise Pollution (Regulation and Control) Rules, 2000 and its
amendments
The Public Liability Insurance Act, 1991
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-5
1.7 SCOPE OF THE STUDY
The scope of the EIA study is based on the guideline provided by Ministry
of Environment, Forests & Climate Change, and Government of India. The
scope of the study broadly includes:
Field sampling of environmental attributes at various representative
locations in the study area to establish the baseline status;
Collect & compile secondary data including socio-economic data;
Identification, assessment and evaluation of the beneficial and
adverse impacts on surrounding environment due to proposed
project activities considering the existing baseline status along with
compilation of other information.
Analysis of project proposal and data analysis.
Assessment of pollution potential due to proposed project.
Predict the incremental levels of pollutants in the study area due to
the proposed project;
Evaluate the predicted impacts on the various environmental
attributes by using scientifically developed and widely accepted
models.
Identification and assessment of risks associated with the proposed
project and their appropriate management through proper Risk
Assessment (RA) and Disaster Management Plan (DMP).
Prepare an Environmental Management Plan (EMP) to mitigate the
predicted impacts; and
Identify critical environmental attributes required to be monitored
during the project execution and to suggest post project monitoring.
The scope also includes all the conditions outlined in the TOR issued by
MoEF&CC and the compliance to the TOR is given below.
1.8 COMPLIANCE TO TERMS OF REFERENCE
The Ministry of Environment, Forest and Climate Change to prescribed
the Standard Terms of Reference (TOR) “IA-J-11011/194/2018-
IA-II(I)” dated 13 July 2018 for undertaking detailed EIA study for
the purpose of obtaining Environmental Clearance in accordance with the
provisions of the EIA Notification, 2006.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-6
Compliance of TORs is as below:
Sr.
No.
Condition Compliance
A. Specific TOR
i Public consultation for obtaining
prior environmental clearance is
prescribed.
The public hearing was conducted
by GPCB on 21.06.2019. Public
hearing proceeding is enclosed as
Annexure-VIII.
5(F) STANDARD TERMS OF REFERENCE FOR CONDUCTING ENVIRONMENT
IMPACT ASSESSMENT STUDY FOR SYNTHETIC ORGANIC CHEMICALS
INDUSTRY (DYES & DYE INTERMEDIATES; BULK DRUGS AND
INTERMEDIATES EXCLUDING DRUG FORMULATIONS; SYNTHETIC
RUBBERS; BASIC ORGANIC CHEMICALS, OTHER SYNTHETIC ORGANIC
CHEMICALS AND CHEMICAL INTERMEDIATES) AND INFORMATION TO BE
INCLUDED IN EIA/EMP REPORT
A STANDARD TERMS OF REFERENCE
1. Executive Summary Enclosed as Chapter-11.
2. Introduction
i. Details of the EIA Consultant
including NABET accreditation.
Details of EIA consultant is given in
Chapter-12 „Disclosure of
Consultant engaged‟.
NABET accreditation certificate is
enclosed as Annexure-I.
ii. Information about the project
proponent.
It is described in Chapter-1,
Section 1.3 (Page no. 1-2).
iii. Importance and benefits of the
project.
Importance of the project is
described in Chapter-1, Section 1.4
(Page no. 1-2).
Benefits of the project are
described in Chapter-8 of EIA
report.
3. Project Description
i. Cost of project and time of
completion.
It is described in Chapter-2,
Section 2.1 (Paragraph 2; Page no.
2-1).
ii. Products with capacities for the
proposed project.
It is described in Chapter-2,
Section 2.3.2 (Page no. 2-5).
iii. If expansion project, details of
existing products with capacities
and whether adequate land is
available for expansion, reference
of earlier EC if any.
Not applicable
(New project proposal).
iv. List of raw materials required and
their source along with mode of
List of raw materials required and
their source along with mode of
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-7
transportation. transportation is given in Table No.
2.5, Page no. 2-28 of Chapter-2.
v. Other chemicals and materials
required with quantities and
storage capacities.
Storage capacity of materials is
mentioned in Chapter 7, Table 7.1
(Page no. 7-3).
vi. Details of Emission, effluents,
hazardous waste generation and
their management.
It is described in Chapter-2,
Section 2.8 (Page no. 2-34).
vii. Requirement of water, power, with
source of supply, status of
approval, water balance diagram,
man-power requirement (regular
and contract).
It is described in Chapter-2,
Section 2.7(b, c, d & e) (Page no.
2-32 to 2-34).
viii. Process description along with
major equipments and
machineries, process flow sheet
(quantities) from raw material to
products to be provided.
It is described in Chapter-2,
Section 2.4 (Page no. 2-6) & 2.5
(Page no. 2-7).
ix. Hazard identification and details of
proposed safety systems.
Hazard identification is described in
Chapter-7, Section 7.2 (Page no. 7-
1); risk screening approach is
covered in Section 7.4 (Page no. 7-
4); details of proposed safety
system are covered in Section 7.16
(Page no. 7-23).
x. Expansion/modernization
proposals:
Not applicable
(New project proposal).
a. Copy of all the Environmental
Clearance(s) including
Amendments thereto obtained for
the project from MOEF/SEIAA shall
be attached as an Annexure. A
certified copy of the latest
Monitoring Report of the Regional
Office of the Ministry of
Environment and Forests as per
circular dated 30th May, 2012 on
the status of compliance of
conditions stipulated in all the
existing environmental clearances
including Amendments shall be
provided. In addition, status of
compliance of Consent to Operate
for the ongoing / existing operation
of the project from SPCB shall be
attached with the EIA-EMP report.
Not applicable
(New project proposal).
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-8
b. In case the existing project has not
obtained environmental clearance,
reasons for not taking EC under the
provisions of the EIA Notification
1994 and/or EIA Notification 2006
shall be provided. Copies of
Consent to Establish/No Objection
Certificate and (Consent to Operate
(in case of units operating prior to
EIA Notification '2006, CTE and
CTO of FY 2005-2006) obtained
from the SPCB shall be submitted.
Further, compliance report to the
conditions of consents from the
SPCB shall be submitted.
Not applicable
(New project proposal).
4. Site Details:
i. Location of the project site
covering village, Taluka/Tehsil,
District and State, Justification for
selecting the site, whether other
sites were considered.
Location of the project site covering
village, Taluka/Tehsil, District and
State is provided in Chapter 1,
Table 1.1 (Page no. 1-3); also
shown in Figure 2.1 to 2.3 (Page
no. 2-2).
Justification for selecting the site is
covered in Chapter 5, Section 5.2
(Page no. 5-1).
ii. A toposheet of the study area of
radius of 10km and site location on
1:50,000/1:25,000 scale on an
A3/A2 sheet. (Including all eco-
sensitive areas and
environmentally sensitive places).
Included in Chapter 3, Figure 3.12
(Page no. 3-59).
iii. Details w.r.t. option analysis for
selection of site.
Justification for site selection is
covered Chapter 5, Section 5.2
(Page no. 5-1).
iv. Co-ordinates (lat-long) of all four
corners of the site.
Included in Chapter 2, Table 2.1
(Page no. 2-3).
v. Google map-Earth downloaded of
the project site.
Included in Chapter 2, as Figure
2.2 and Figure 2.3 (Page no. 2-3).
vi. Layout maps indicating existing
unit as well as proposed unit
indicating storage area, plant area,
greenbelt area, utilities etc. If
located within an Industrial area/
Estate/Complex, layout of
Industrial Area indicating location
of unit within the Industrial area/
Estate.
Included in Chapter 2, Figure 2.4
(Page no. 2-5).
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-9
vii. Photographs of the proposed and
existing (if applicable) plant site. If
existing, show photographs of
plantation/greenbelt, in particular.
Attached as Annexure-II.
viii. Land use break-up of total land of
the project site (identified and
acquired), government/private -
agricultural, forest, wasteland,
water bodies, settlements, etc.
shall be included. (Not required for
industrial area).
Land use breakup is included in
Chapter 2, Table no. 2.2 (Page no.
2-4).
ix. A list of major industries with name
and type within study area (10 km
radius) shall be Incorporated. Land
use details of the study area.
A list of major industries with name
and type within study area is
provided in Chapter 1, Section 1.11
(Page no. 1-19).
Land use details of the study area
are included in Chapter 3, Section
3.6 (Page no. 3-3).
x. Geological features and Geo-
hydrological status of the study
area shall be included.
Geological features and Geo-
hydrological status of the study
area is included in Chapter 3,
Section 3.9 (Page no. 3-10).
xi. Details of Drainage of the project
up to 5 km radius of study area. If
the site is within 1 km radius of
any major river, peak and lean
season river discharge as well as
flood. Occurrence frequency based
on peak rainfall data of the past 30
years. Details of Flood Level of the
project site and maximum Flood
Level of the river shall also be
provided. (mega green field
projects)
Site is not within 1 km of any
major river.
xii. Status of acquisition of land. If
acquisition is not complete, stage
of the acquisition process and
expected time of complete
possession of the land.
Attached as Annexure-III.
xiii. R&R details in respect of land in
line with state Government policy.
No, R & R is involved.
5. Forest and wildlife related issues (if applicable):
i. Permission and approval for the
use of forest land (forestry
clearance), if any, and
recommendations of the State
Not applicable.
(Project does not involve forest
land; and
Site is not located within 10 km of
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-10
Forest Department. (if applicable) the National Parks, Sanctuaries,
Biosphere reserves, Migratory
Corridors of Wild Animals)
ii. Land use map based on High
resolution satellite imagery (GPS)
of the proposed site delineating the
forestland (in case of projects
involving forest land more than 40
ha).
iii. Status of Application submitted for
obtaining the stage I forestry
clearance along with latest status
shall be submitted.
iv. The projects to be located within
10 km of the National Parks,
Sanctuaries, Biosphere Reserves,
Migratory Corridors of Wild
Animals, the project proponent
shall submit the map duly
authenticated by Chief Wildlife
Warden showing these features
vis-à-vis the project location and
the recommendations or comments
of the Chief Wildlife Warden-
thereon.
v. Wildlife Conservation Plan duly
authenticated by the Chief Wildlife
Warden of the State Government
for conservation of Schedule I
fauna, if any exists in the study
area.
Wildlife Conservation Plan
submitted for Schedule I species
Pavo Cristatus is included in
Annexure-XI (Page no. A-215).
vi. Copy of application submitted for
clearance under the Wildlife
(Protection) Act, 1972, to the
Standing Committee of the
National Board for Wildlife.
6. Environmental Status
i. Determination of atmospheric
inversion level at the project site
and site-specific micro-
meteorological data using
temperature, relative humidity,
hourly wind speed and direction
and rainfall.
Briefly covered in Chapter 3,
Section 3.7 (Page no. 3-6).
Hourly meteorological data
including temperature, relative
humidity, hourly wind speed and
direction and rainfall is attached as
Annexure-IX.
ii. AAQ data (except monsoon) at 8
locations for PM10, PM2.5, SO2, NOX,
CO and other parameters relevant
to the project shall be collected.
Briefly covered in Chapter 3,
Section 3.8 (Page no. 3-7) and
monitoring locations, period of
monitoring & address are given in
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-11
The monitoring stations shall be
based CPCB guidelines and take
into account the pre-dominant wind
direction, population zone and
sensitive receptors including
reserved forests.
Chapter-3, Table 3.11 (page no. 3-
26).
iii. Raw data of all AAQ measurement
for 12 weeks of all stations as per
frequency given in the NAQQM
Notification of Nov. 2009 along
with -min., max., average and
98% values for each of the AAQ
parameters from data of all AAQ
stations should be provided as an
annexure to the EIA Report.
Briefly covered in Chapter 3, Table
3.11 to 3.17 (Page no. 3-26).
Detailed AAQM table is attached as
Annexure-X.
iv. Surface water quality of nearby
River (100m upstream and
downstream of discharge point)
and other surface drains at eight
locations as per CPCB/ MoEF&CC
guidelines.
Unit will not discharge in surface
water.
Results of surface water monitoring
at eight locations are covered in
Chapter 3, Table 3.20 (Page no. 3-
35).
v. Whether the site falls near to
polluted stretch of river identified
by the CPCB/ MoEF&CC, if yes give
details.
No, the site doesn‟t falls near to
polluted stretch of the river
identified by CPCB/MoEF&CC.
vi. Ground water monitoring at
minimum at 8 locations shall be
included.
Briefly covered in Chapter 3, Table
3.19 (Page no. 3-34).
vii. Noise levels monitoring at 8
locations within the study area.
Briefly covered in Chapter 3, Table
3.22 (Page no. 3-37).
viii. Soil Characteristic as per CPCB
guidelines.
Briefly covered in Chapter 3, Table
3.24 (Page no. 3-38).
ix. Traffic study of the area, type of
vehicles, frequency of vehicles for
transportation of materials,
additional traffic due to proposed
project, parking arrangement etc.
Briefly covered in Chapter 3, Table
3.27 (Page no. 3-42).
x. Detailed description of flora and
fauna (terrestrial and aquatic)
existing in the study area shall be
given with special reference to
rare, endemic and endangered
species. If Schedule-I fauna are
found within the study area, a
Wildlife Conservation Plan shall be
prepared and furnished.
Briefly covered in Chapter 3, Table
3.25 (Page no. 3-39) & 3.26 (Page
no. 3-41). No endangered floral or
faunal species has been recorded
within the study area.
Wildlife Conservation Plan
submitted for Schedule I species
Pavo Cristatus is included in
Annexure-XI (Page no. A-215).
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-12
xi. Socio-economic status of the study
area.
Briefly covered in Chapter 3,
Section 3.14 (Page no. 3-29); and
Table 3.29 (Page no. 3-45) & 3.30
(Page no. 3-47).
7. Impact and Environment Management Plan
i. Assessment of ground level
concentration of pollutants from
the stack emission based on site-
specific meteorological features. In
case the project is located on a
hilly terrain, the AQIP Modeling
shall be done using inputs of the
specific terrain characteristics for
determining the potential impacts
of the project on the AAQ.
Cumulative impact of all sources of
emissions (including
transportation) on the AAQ of the
area shall be assessed. Details of
the model used and the input data
used for modeling shall also be
provided. The air quality contours
shall be plotted on a location map
showing the location of project site,
habitation nearby, sensitive
receptors, if any.
Assessment of ground level
concentration of pollutant from the
stack emission superimposed on
geographical area map based on
the site specific meteorological
features is covered in Chapter 4,
Figure 4.1 to 4.4 (Page no. 4-23).
The modeling approach is briefly
covered in Chapter 4, Section 4.4.1
(Page no. 4-4).
Input parameters used for
modeling are provided in Table 4.1
(Page no. 4-17), additional inputs -
maximum 50 (24-hr) average
concentration values for SPM, SO2,
NOx & HCl, are given in Table 4.3
to 4.6 (Page no. 4-19).
Cumulative impact of all sources of
emissions on AAQ of the area is
given in Table 4.2 (Page no. 4-18).
ii. Water Quality modeling -in case of
discharge in water body.
Not applicable, as unit will not
discharge in water body.
iii. Impact of the transport of the raw
materials and end products on the
surrounding environment shall be
assessed and provided. In this
regard, options for transport of raw
materials and finished products and
wastes (large quantities) by rail or
rail-cum road transport or
conveyor-cum-rail transport shall
be examined.
Traffic study is provided in Chapter
3, Table 3.27 (Page no. 3-42). The
impact of the transport of raw
material and the end products on
the surrounding environment will
be insignificant, so rail or rail-cum
road transport of conveyor-cum-
rail transport is not required at this
point.
iv. A note on treatment of wastewater
from different plant operations,
extent recycled and reused for
different purposes shall be
included. Complete scheme of
effluent treatment. Characteristics
of untreated and treated effluent to
meet the prescribed standards of
discharge under E(P) Rules.
Treatment on wastewater from
different plant operations, extent
recycled and reuse for different
purposes is briefly described in
Chapter 2, Section 2.9.1 (Page no.
2-37).
Characteristic of untreated and
treated effluent is given in Table
2.14 (Page no. 2-40).
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-13
v. Details of stack emission and
action plan for control of emissions
to meet standards.
Details of stack emission and action
plan for control of emissions to
meet standards are covered in
Chapter 2, Section 2.8.2 (Page no.
2-34) & 2.9.2 (Page no. 2-40).
vi. Measures for fugitive emission
control.
Measures for fugitive emission
control are covered in Chapter 2,
Section 2.9.2 (Page no. 2-41).
vii. Details of hazardous waste
generation and their storage,
utilization and management.
Copies of MOU regarding utilization
of solid and hazardous waste in
cement plant shall also be
included. EMP shall include the
concept of waste-minimization,
recycle/reuse/recover techniques,
Energy conservation, and natural
resource conservation.
Details of hazardous waste
generation and their storage,
utilization and management are
covered in Chapter 2, Section 2.8.3
(Page no. 2-36) & 2.9.3 (Page no.
2-41).
Proponent will explore the
possibility of utilization of solid and
hazardous waste in cement plant.
Concepts of resource & energy
conservation and cleaner
production are covered in Chapter
10, Section 10.7 & 10.8 (Page no.
10-17).
viii. Proper utilization of fly ash shall be
ensured as per Fly Ash Notification,
2009. A detailed plan of action
shall be provided.
A detailed plan of fly ash
management is covered in Chapter
2, Section 2.9.3 (Page no. 2-41).
ix. Action plan for the green belt
development plan in 33 % area i.e.
land with not less than 1500 trees
per ha. Giving details of species,
width of plantation; planning
schedule etc. shall be included. The
green belt shall be around the
project boundary and a scheme for
greening of the roads used for the
project shall also be incorporated.
Layout plan earmarking space for
development of green belt is
provided in Chapter 2, Figure 2.4
(Page no. 2-5). Greenbelt
development plan is provided in
Chapter 10, Section 10.3.5 (Page
no. 10-8).
x. Action plan for rainwater
harvesting measures at plant site
shall be submitted to harvest
rainwater from the roof tops and
storm water drains to recharge the
ground water and also to use for
the various activities at the project
site to conserve fresh water and
reduce the water requirement from
other sources.
Action plan for rainwater harvesting
is provided in Chapter 2, Section
2.10 (Page no. 2-42).
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-14
xi. Total capital cost and recurring
cost/annum for environmental pollution control measures shall be
included.
Total capital cost and recurring
cost/annum for environmental
pollution control measures is
included in Chapter 10, Section
10.5 (Page no. 10-15).
xii. Action plan for post-project
environmental monitoring shall be
submitted.
Action plan for post-project
environmental monitoring is
included in Chapter 10, Section
10.4 (Page no. 10-13).
xiii. Onsite and Offsite Disaster (natural
and Man-made) Preparedness and
Emergency Management Plan
including Risk Assessment and
damage control. Disaster
management plan should be linked
with District Disaster Management
Plan.
Onsite and offsite Disaster (natural
and man-made) Preparedness and
Emergency Management Plan is
included in Chapter 7, Section 7.18
(Page no. 7-29) & Section 7.23
(Page no. 7-39).
8. Occupational health:
i. Plan and fund allocation to ensure
the occupational health & safety of
all contract and casual workers.
Occupational health & safety plan is
given in Chapter 10, Section 10.3.6
(Page no. 10-10); and Chapter 7,
Section 7.14 (Page no. 7-19).
Fund allocation is mentioned in
Chapter 10, Section 10.5 (Page no.
10-14).
ii. Details of exposure specific health
status evaluation of worker. If the
workers‟ health is being evaluated
by pre designed format, chest x
rays, Audiometry, Spirometry,
Vision testing (Far & Near vision,
color vision and any other ocular
defect) ECG, during pre-placement
and periodical examinations give
the details of the same. Details
regarding last month analyzed data
of above mentioned parameters as
per age, sex, duration of exposure
and department wise.
Occupational health & safety
programme is covered in Chapter
7, Section 7.14 (Page no. 7-19);
and Chapter 10, Section 10.3.6
(Page no. 10-10).
iii. Details of existing Occupational &
Safety Hazards. What are the
exposure levels of hazards and
whether they are within Permissible
Exposure Level (PEL)? If these are
not within PEL, what measures the
company has adopted to keep
them within PEL so that health of
No existing Occupational & Safety
Hazards (as this is a new project
proposal).
Hazard analysis of materials is
provided in Chapter 7, Table 7.2
(Page no. 7-5) & Table 7.3 (Page
no. 7-7). Acute Exposure Guideline
Levels (AEGLS) provided in Section
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-15
the workers can be preserved. 7.4.1 (Page no. 7-7); Emergency
Response Planning Guidelines
(ERPGs) provided in Section 7.4.2
(Page no. 7-9); Immediately
dangerous to life or health air
concentration values (IDLH values)
provided in Section 7.8 (Page no.
7-12).
iv. Annual report of health status of
workers with special reference to
Occupational Health and Safety.
Not applicable
(New project proposal).
9. Corporate Environment Policy
i. Does the company have a well laid
down Environment Policy approved
by its Board of Directors? If so, it
may be detailed in the EIA report.
Yes, It is discussed in Chapter 10,
Section 10.6.2 (Page no. 10-16).
Additionally, company will set up a
separate Environment Management
Cell and the objectives and duties
of it are discussed in Chapter 10,
Section 10.6 (Page no. 10-15).
ii. Does the Environment Policy
prescribe for standard operating
process / procedures to bring into
focus any infringement / deviation
/ violation of the environmental or
forest norms / conditions? If so, it
may be detailed in the EIA.
Yes, It is discussed in Chapter 10,
Section 10.6.3 (Page no. 10-17).
iii. What is the hierarchical system or
Administrative order of the
company to deal with the
environmental issues and for
ensuring compliance with the
environmental clearance
conditions? Details of this system
may be given.
It is discussed in Chapter 10,
Section 10.6.1 (Page no. 10-16).
iv. Does the company have system of
reporting of non-compliances /
violations of environmental norms
to the Board of Directors of the
company and / or shareholders or
stakeholders at large? This
reporting mechanism shall be
detailed in the EIA report.
Yes, It is discussed in Chapter 10,
Section 10.6.3 (Page no. 10-17).
10. Details regarding infrastructure
facilities such as sanitation, fuel,
restroom etc. to be provided to the
labor force during construction as
well as to the casual workers
It is discussed in Chapter 10,
Section 10.2.2 (Page no. 10-2) and
10.2.4 (Page no. 10-2).
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-16
including truck drivers during
operation phase.
11. Enterprise Social Commitment (ESC)
i. Adequate funds (at least 2.5 % of
the project cost) shall be
earmarked towards the Enterprise
Social Commitment based on Public
Hearing issues and item-wise
details along with time bound
action plan shall be included.
Socio-economic development
activities need to be elaborated
upon.
ESR plan for 3 years @ 5.0% of the
project cost is included in Chapter
10, Section 10.9 (Page no. 10-19).
Elaborated Socio-economic
development activities & year wise
break up of budget is discussed in
Chapter 7, Section (E) (Page no. 7-
45) & Table 7.12, Page no. 7-50.
12. Any litigation pending against the
project and/or any direction/order
passed by any Court of Law against
the project, if so, details thereof
shall also be included. Has the unit
received any notice under the
Section 5 of Environment
(Protection) Act, 1986 or relevant
Sections of Air and Water Acts? If
so, details thereof and compliance/
ATR to the notice(s) and present
status of the case.
No pending litigation against the
project and/or any direction/order
passed by any Court of Law against
the project.
13. A tabular chart with index for point
wise compliance of above TORs.
Done.
B SPECIFIC TERMS OF REFERENCE
1 Details on solvent to be used,
measures for solvent recovery and
for emission control.
Covered in Chapter 10, Section
10.3.1.2 (Page no. 10-6).
2 Details of process emission from
the unit and its arrangement to
control.
It is briefly described in Chapter 2,
Section 2.8.2 (Page no. 2-34) &
2.9.2 (Page no. 2-40).
3 Ambient air quality data should
include VOC, other-process-specific
pollutants* like NH3*, chlorine*,
HCl*, HBr*, H2S*, HF*, etc. (*-as
applicable).
Ambient air quality data includes
VOC, and process-specific
pollutants HCl; Included in Table
3.17 (Page no. 3-32).
4 Work zone monitoring
arrangements for hazardous
chemicals.
It is described in Chapter 10,
Section 10.4.1 (Page no. 10-15).
5 Detailed effluent treatment scheme
including segregation of effluent
streams for units adopting „Zero‟
Liquid Discharge.
It is described in Chapter 2, Section
2.9.1 (Page no. 2-37).
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-17
6 Action plan for odour control to be
submitted.
It is described in Chapter 10,
Section 10.3.1.3 (Page no. 10-6).
7 A copy of the Memorandum of
Understanding signed with cement
manufactures indicating clearly
that they co-process organic
solid/Hazardous waste in TSDF if
any.
Unit will consider obtaining such
Memorandum of Understanding
signed with cement manufacturers.
8 Authorization/Membership for the
disposal of liquid effluent in CETP
and solid/hazardous waste in TSDF,
if any.
Unit will perform ZLD with in-house
ETP, RO, MEE setup; hence
membership of CETP is not
required.
Unit will obtain membership of
TSDF before establishment.
9 Action plan for utilization of
MEE/dryers salts.
Being a Pharma unit, no possibility
to utilize utilization of MEE/dryers
salts. Unit will send MEE salts to
TSDF.
It is covered in Chapter 2, Section
2.9.3 (Page no. 2-41).
10 Material Safety Data Sheet for all
the Chemicals are being used/will
be used.
Attached as Annexure-IV.
11 Authorization/Membership for the
disposal of solid/hazardous waste
in TSDF.
Unit will obtain membership of TSDF before establishment.
12 Details of incinerator if to be
installed.
Not applicable
13 Risk assessment for storage and
handling of hazardous chemicals/
solvents. Action plan for handling &
safety system to be incorporated.
Risk assessment for storage and
handling of hazardous chemicals is
covered in Chapter 7, Section 7.3
(Page no. 7-3), Section 7.4 (Page
no. 7-4). Hazard analysis of
materials is provided in Table 7.2
(Page no. 7-5) & Table 7.3 (Page
no. 7-7). Acute Exposure Guideline
Levels (AEGLS) provided in Section
7.4.1 (Page no. 7-7); Emergency
Response Planning Guidelines
(ERPGs) provided in Section 7.4.2
(Page no. 7-9); Immediately
dangerous to life or health air
concentration values (IDLH values)
provided in Section 7.8 (Page no.
7-12).
Quantitative risk assessment &
consequence analysis is covered in
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-18
Section 7.12 (Page no. 7-15) and
Section 7.13 (Page no. 7-18).
Action plan for handling & safety
system is covered in Section 7.16-
7.17 (Page no. 7-23).
14 Arrangements for ensuring health
and safety of workers engaged in
handling of toxic materials.
It is briefly covered in Section 7.17
(Page no. 7-25).
1.9 OBJECTIVE OF EIA
The objectives of the present EIA study are to identify potential source of
pollution, assess the impacts on various environmental components due
to the proposed project activity, and recommend appropriate
environmental management system and environment management plan
for the unit to ensure that the adverse impacts, if any, will be minimized.
1.10 METHODOLOGY FOR EIA
Considering the nature and magnitude of the project, surrounding area
and various guidelines available, an area of 10-km radius from the center
of proposed plant site was considered for the purpose of environmental
impact assessment study. The methodology is briefly reported below,
Baseline data collection:
The baseline data for the impact zone have been generated for the
following environmental parameters.
Ambient Air Quality
Micrometeorology
Noise Level
Surface &Ground Water Quality
Soil Quality
Ecology &Biodiversity
Land use pattern
Socio-Economics
The baseline status of the above environmental parameters has been
worked out based on the rapid monitoring/analysis carried out during the
study period of October, 2018 to December, 2018 supplemented by
data collected from various Govt. Dept., census publications etc. The data
is collected and analyzed as per the standard methods for establishing
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-19
the baseline data and so determine the impact of proposed activity on the
same.
Evaluation of Impact from Project Activities
The Environmental Impact resulting from the various project activities,
have been identified, predicted and evaluated based on the study of
manufacturing process and other project related activities as well as
correlating the same with existing baseline status.
Preparation of Environmental Management Plan
Environmental Management Plan has been prepared covering pollution
prevention measures at source in terms of air and water pollution control
measures, solid waste/hazardous waste management, safety
management, greenbelt development, environmental surveillance and
environmental surveillance and environmental management team.
Finally, the detailed assessment of the resultant environmental impacts
have been made based on the impacts identification and evaluated from
the activities over the baseline status of various environmental
components to reduce the pollution and to delineate a comprehensive
environment management plan along with recommendations and
suggestions to improve environment management system.
1.11 LIST OF INDUSTRIES SURROUNDING PROJECT SITE
List of industries in the study area are shown below.
Sr.
No.
Name of Industry Address Type of Industry
1 Ipca Laboratories At Village: Ranu, Tal. Padra,
Dist: Vadodara
Pharmaceutical
Company
2 Admark Poly Coat
Pvt. Ltd.
Survey No. 207, Vill: Luna,
Taluka: Padra, Dist Vadodara
Resin Manufacturer
3 Ami Life Sciences
Pvt. Ltd.
Block No 82/B , VECL Road,
At & Po - Karakhadi, Padra
Pharmaceutical
Company
4 Amoli Organics Ltd. Block No. 422 to 425, VECL
Road, Vill: Luna
Pharmaceutical
Company
5 Apicore Parma Pvt.
Ltd.
Block No. 252/253,
Vill: Dhobikuwa, Tal: Padra
Pharmaceutical
Company
6 BDR Life Sciences
Pvt. Ltd.
R.S. No. 578, Near VECL
Road, Vill: Luna, Tal: Padra
Pharmaceutical
Company
7 Cadila Healthcare
Ltd.
Plot No. 31, Vill: Dabhasa,
Tal. Padra
Pharmaceutical
Company
8 Gulbrandsen Coastal Highway, Vill.: Fine Chemicals
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-20
Chemical Pvt. Ltd. Mujpur, Tal: Padra
9 Kaival Chemicals
Pvt. Ltd.
Block No. 489, Umraya Road,
Vill: Umraya, Tal. Padra
Pharmaceutical
Intermediates
10 Kronox Lab
Sciences Pvt. Ltd.
Block No 284 Vill: Dabhasa,
Tal. Padra
Fine chemicals
11 Kumar Organics
Ltd.
Plot No. 379, Canal Road,
Vill: Luna, Taluka: Padra
Fine chemicals
12 Lupin Limited Block No. 2100, Vill.
Dabhasa, Tal. Padra
Pharmaceutical
Company
13 Paragon Organics Plot No. 582, VECL Road,
Luna, Padra
Pharmaceutical
Company
14 Philoden Agrochem
Pvt. Ltd.
Block No. 73, B/H, Geb Sub
Station, Karkhadi, Tal. Padra
Dyestuff
15 Piramal Glass Ltd Gajera Road, Uchhad Village,
Jambusar, Dist, Bharuch
Glass manufactures
16 Cadila Healthcare
Ltd.
Block No 162, Vill. Dabhasa,
Tal, Padra
Pharmaceutical
Company
17 Shimmer Chemicals
Pvt. Ltd.
Block No. 338, Coastal
Highway, Vill: Mujpur, Tal.
Padra
Fine Chemicals
18 Shiva Pharmachem
Ltd.
Block No. 528, Vill, Luna, Tal.
Padra
Fine Chemicals
19 Solaris Chemtech
Industries
Karakhadi, Taluka: Padra Fine Chemicals
20 Sun
Pharmaceuticals
Indu Ltd.
Plot No. 817 A, VECL Road,
Vill. Karakhdi, Tal, Padra
Pharmaceutical
Company
21 Synbiotics Ltd. Block No. 570,571, & 576/A,
Vill, Luna, Taluka: Padra
Pharmaceutical
Company
22 Transpek Silox
Industry Ltd.
Survey No. 325/1, Ekalbara,
Tal. Padra
Fine Chemicals
23 Exemed
Pharmaceuticals
Block No. 628 VECL Canal
Road, Vill: Luna, Tal: Padra
Pharmaceutical
Company
24 Parad Chem
Corporation
Plot No. 145, Dabhasa,
Dabhasa- Ekalbara Road, Tal. Padra, Dist Vadodara
Fine Chemicals
25 Zydex Industries
Pvt. Ltd.
Village Gavasad, Tal Padra,
Dist Vadodara
Fine Chemicals
26 Prasad International Pvt.
Ltd.
Plot No. 313/P, Village: Luna
Taluka: Padra, Dist Vadodara
Dyestuff & Pigments
27 Alembic Pharmaceuticals Ltd.
Survey No. 843, Karakhadi
Village, Padra Taluka
Pharmaceutical
Company
28 Sterling Biotech
Ltd.
Village: Masar, Taluka:
Padra, Dist: Vadodara
Pharmaceutical
Company
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-21
29 Colorband Dyestuff
Pvt. Ltd.
Village: Ekalbara, Taluka:
Padra, Dist: Vadodara
Dyestuff
1.12 STRUCTURE OF REPORT
The overall contents of the EIA report is in line with generic structure of
EIA report as per the Appendix III of the EIA Notification, 2006. The
report consists of twelve chapters and the content is briefly described in
this section.
Chapter 1: Introduction
The chapter gives brief outline of the project and its proponent, brief
description nature, size and location of the project, purpose of the EIA
study including the scope of the study, TORs compliance etc. and work
to be covered under each Environmental component.
Chapter 2: Project Description
This chapter includes project details and Infrastructure facilities
including all industrial & environmental aspects of the unit as well as
manufacturing process details. It also gives information about utilities,
raw material, water & wastewater quantitative details, stack details,
hazardous waste generation, storage & disposal facility.
Chapter 3: Description of the Environment
This chapter covers data of existing condition of Valued Environmental
Components like air, water, noise, soil, biological environment and
socio-economic aspects, basic amenities land use pattern. It also gives
details of study area, period of study, component of environment & its
methodology. Various sections of the chapter discuss the existing land
use and drainage pattern, climate and meteorological parameters.
Both primary and secondary data collected for the study are depicted
in this chapter.
Chapter 4: Anticipated Environmental Impacts and Mitigation
Measures
This chapter describes the overall impacts of the project activities on
various environmental components. It predicts the overall impact of
the project activities on different components of the environment viz.
Air, Water, Land, Noise, Biological and Socio-Economic and its
mitigation measures.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-22
Chapter 5: Analysis of Alternatives
This chapter gives details of analysis of alternatives in terms of
technology & site.
Chapter 6: Environmental Monitoring Programme
This chapter describes technical aspects of monitoring (including
measurement methodologies, frequency, location and data analysis,
reporting schedules, emergency procedures, detailed budget and
procurement schedules.
Chapter 7: Additional Studies
This chapter describes Risk assessment and on-site, off-site
emergency plan and occupational health & safety programme.
Chapter 8: Project Benefits
This chapter focuses on benefits of project on improvement in physical
infrastructure, social infrastructure & other tangible benefits.
Chapter 9: Environmental Cost Benefit Analysis
Chapter 10: Environmental Management Plan
This chapter describes Environment Management Plan (EMP) to be
adopted for mitigation of anticipated adverse impacts if any and to
ensure acceptable impacts.
Chapter 11: Summary & Conclusion
It gives brief of the EIA Report and chapters there in. It also describes
about overall justification for implementation of the project and
explanation on various mitigation measures.
Chapter 12: Disclosure of Consultants engaged
This chapter describes the name of the consultant engaged with their
brief nature of consultancy activities.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-1
Chapter 2
Project Description
2.1 INTRODUCTION
M/s. Reynish Pharmachem Pvt. Ltd. is a green field project, proposes
to set up bulk drugs manufacturing unit at Survey no. 504, 505, 507,
Village: Dabhasa, Ta.: Padra, District: Vadodara, Gujarat. Total
production capacity of all the products will be tune around 50 MT/month.
The estimated cost for the proposed project is estimated around Rs. 40.0
Crores. Out of this around Rs. 2.5 Crores will be invested for pollution
control measures as capital cost and Rs. 1.5 Crores as recurring cost per
annum. Time of project completion will be about 1.0 - 1.5 years after
accordance of the EC.
As per the EIA Notification - 2006, Industry falls under the Project or
Activity - 5(f) - Synthetic organic chemicals industry (dyes & dye
intermediates; bulk drugs and intermediates excluding drug formulations;
synthetic rubbers; basic organic chemicals, other synthetic organic
chemicals and chemical intermediates).
Based on the type of project, following are the expected aspects:
Air Emissions,
Waste water generation,
Noise generation,
Hazardous waste generation, and
Occupational health, hazards & safety risk
2.2 LOCATION OF THE PROJECT
The project site is located at Survey no. 504, 505, 507, Village: Dabhasa,
Ta: Padra, District: Vadodara, Gujarat. Locations of the project, Google
map and boundary coordinates of the site are shown in Figure 2.1,
Figure 2.2, and Figure 2.3, respectively. The project site is
approachable by Road via Vadodara-Jambusar Hwy. Nearest railway
station and airport is Vadodara Railway Station at about 19 km, Padra
Railway station at about 7.0 km and Vadodara Airport at about 24 km,
respectively.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-2
Figure 2.1 Location of the project site
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-3
Figure 2.2 Location on Google map
Figure 2.3 Image showing all boundary coordinates of the site
Table 2.1 Boundary coordinates of the site
A 22° 13'34.14"N 73°01'09.11"E
B 22° 13'37.03"N 73°01'14.93"E
C 22° 13'29.17"N 73°01'09.37"E
D 22° 13'31.79"N 73°01'18.09"E
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-4
2.3 SIZE OR MAGNITUDE OF OPERATION
2.3.1 Land Breakup & Project Site Layout
Proposed land area is 36958 m2. Greenbelt will be developed in around
12175 m2 area which is more than 33% of the total project area. The
detailed proposed land break up is given below in Table 2.2, whereas the
site layout map is given in the Figure 2.4.
Table 2.2 Land breakup
Sr. No.
Particular Area (m2)
1. Admin Building & Lab 525
2. Water storage area 800
3. Raw Water treatment area 100
4. Tank farm/solvent storage area 680
5. Raw Materials & Finished goods storage area 1200
6. Manufacturing area 5930
7. Manufacturing plant-2 1200
8. Boiler Shed and utilities area 665
9. ETP, MEE and RO Area 650
10. Parking 900
11. Electrical and Security cabin 310
12. Staff Canteen 225
13. Greenbelt 12175
14. Internal Roads & Margin 4615
15. Open Space for future expansion 6983
Total 36958
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-5
Figure 2.4 Plant Layout
2.3.2 Project Magnitude
Proposed production capacity is given below:
Table 2.3 List of products with its capacity
Sr.
No.
Name of Products Qty.
MTPM
1. Telmisartan 48
2. Ondansetron HCl
3. Benfotiamine
4. Albendazole
5. 4-Hexyl resorcinol
6. Zopiclone
7. Tamoxifen citrate
8. Bupropion HCl
9. Anstrozole
10. Theophylline
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-6
11. Allantoin
12. Terbinafine Hydrochloride
13. Pregabalin Hydrochloride
14. Rebamipide
15. Valsartan
16. R & D Drugs 2.0
Total 50.0
2.4 INFRASTRUCTURE FACILITIES
The list of proposed plant equipments/machineries is given below in
Table 2.4.
Table 2.4 List of major machineries/equipment
Sr.
No.
Name of the
Equipment/Machinery
Capacity Nos.
1. SSR (Reactor) 2000 Lit. 4
3000 Lit. 2
4000 Lit. 4
2. GLR (Reactor) 2000 Lit. 4
3000 Lit. 2
4000 Lit. 4
3. CF (Centrifuge) 36” 5
48” 5
4. SF (Sparkler Filter) 18” 3
24” 3
5. Spin Flash Dryer (SFD)/
Fluid Based Dryer (FBD)
1000 Lit. 3
6. Nauta Dryer 1000 Lit. 3
7. Rotary Vacuum Dryer (RVD) 500 Lit. 2
8. Blender 3500 Lit. 1
9. Hydrogenator (SS 316) 2000 Lit. 1
10. Hydrogenator (SS 316) 4000 Lit. 1
11. DG Set 500 kVA 1
12. Steam Boiler 3.0 TPH 1
13. Thermic Fluid Heater 20 lac Kcal/hr. 1
14. Hot Air Generator 30 lac Kcal/hr. 1
15. RO (Raw Water Treatment) 5.0 Kl/hr. 2
16. RO (Effluent Treatment Plant) 7.5 Kl/hr. 2
17. Cooling tower 250 TR 1
500 TR 1
18. Multiple Effect Evaporator 2500 Lit/hr. 1
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-7
2.5 DESCRIPTION OF MANUFACTURING PROCESS
The company will use the Best Available Process Technology (BAT) for the
production. Manufacturing process of all products, with chemical reactions
& mass balance are summarized below.
1. Telmisartan
Manufacturing Process:
2‐n‐Propyl‐4‐methyl‐6‐(1‐methyl benzimidazole‐2‐yl) benzimidazole is
treated with methyl‐4’‐(bromomethyl)‐biphenyl‐2‐carboxylate in acetone
in the presence of sodium hydroxide to form 4‐[4’‐methyl‐6‐
(1‐methyl‐1H‐benzimidazole‐2‐yl‐2‐propyl‐1H‐benzimidazole‐1‐ylmethyl]
biphenyl‐2‐carboxylic acid methyl ester which is hydrolyzed with sodium
hydroxide in aqueous methanol to give telmisartan which is purified in
dichloromethane and methanol.
Chemical Reaction:
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-8
Mass Balance:
INPUT KG OUTPUT KG
2‐n‐Propyl‐4‐methyl
‐6‐(1‐methyl
benzimidazole‐2‐yl)
benzimidazole
68
methyl‐4’‐
(bromomethyl)‐biphenyl‐2
‐carboxylate
58
Acetone 500 Acetone recovery 490
Water 1600 Wastewater 950
Sodium hydroxide 15 Distillation residue 10
Methanol 750 Methanol recovery 650
Sodium hydroxide 25
Water 525 Wastewater 350
HCl 70
Methanol 450 Methanol recovery 560
Dichloromethane 500 Dichloromethane recovery 490
Distillation residue 34
Charcoal 1.5 Spent carbon 1.5
Hyflo 1 Wastewater 903
Drying loss 25
TELMISARTAN 100
Total 4564 4564
Drying
MASS BALANCE OF TELMISARTAN
Reactor
Reactor
Filteration
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-9
2. Ondansetron HCl:
Manufacturing Process:
1, 3 CHD reacts with phenyl hydrazine in presence of catalyst and water.
Acetic acid is added along with zinc chloride and methanol. And then add
concentrated HCl and stir it for 1 hour to maintain the temperature
between 20-25oC. Then mass is methylized with the help of Di-methyl
sulphate and acetone. Acetone is recovered at the end. Then add DMA
HCl with paraformaldehyde to complete the alkylation. Add 2 methyl-
Imidazole to condensate the mass. Then add concentrated HCl in vessel
under stirring. Salt of Ondensetron Dihydrate HCl is generated. Product
and wastewater are separated through centrifugation and wastewater is
sent to the ETP.
Mass Balance:
INPUT KG OUTPUT KG
1,3-CHD 120
Phenyl hydrazine 181
Water 2120
Acetic acid 72 Methanol Recovery 465
Zinc chloride 252 Solvent residue 12
Methanol 477 Wastewater 2000
Con HCl 53
Dimethyl sulphate 70 Acetone Recovery 420
Acetone 435 Solvent residue 15
Potassium Carbonate 40 Wastewater 165
Acetic acid 450
DMA HCl 72
Paraformaldehyde 27
Water 318
2-Methyl Imidazole 95 Wastewater 1200
Water 530
Con HCl 40
Water 530 Wastewater 1484
Drying loss 21
Ondansetron Dihydrate HCl 100
Total 5882 5882
Centrifuge
Drying
HCl salt formation
MASS BALANCE OF ONDANSETRON HCl
Condensation
reaction
cyclization
Methylation
Reductive
alkylation
Condensation
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-10
3. Benfotiamine:
Manufacturing process:
In a clean and dry Reactor, take Thiamine Monophosphate Chloride (TMP)
at room temperature. Add water and stir well at room temperature. Cool
the reaction mass to 10‐15 oC. Add to reaction mass the first lot of 47%
NaOH solution. Then add to reaction mass the Benzoyl Chloride 20‐25 oC
in 30 min. Then Stir the reaction mass a 1h. After completion of reaction,
add to reaction mixture Conc. HCl. Here pH of reaction mixture should be
4.0 ‐ 4.5. Stir reaction mixture at room temperature for 2 h. Cooled and
chilled the product to 10‐15 oC and stirred at same temperature for 30
min. Centrifuged the product. Dry the weight cake. The Dried white solid
product is obtained.
Chemical Reaction:
Mass Balance:
INPUT KG OUTPUT KG
TMP 122
Caustic 27 Methanol recovery 385
Benzoyl chloride 60 Solvent residue 15
HCl 80
Water 200
Methanol 400
Wastewater 362
Drying loss 27
BENFOTIAMINE 100
Total 889 889
MASS BALANCE OF BENFOTIAMINE
Condensation
reaction
Centrifuge
Drying
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-11
4. Albendazole:
Manufacturing Process:
Charge 3 Chloro 6 nitro acetanilide and add NaOH lye in the reactor. Add
Methanol in the vessel then it is distilled in the chamber. In the residue
add hexane along with Di-isopropyl ether. Then heat up to 50-55oC. Then
the mass is dried. The solid mass is obtained. Then add NaOH in solution
to complete the hydrogenation. Add acetone, methyl chloroform ate and
water in the reactor. Centrifuged the product. The aqueous layer is sent
into ETP and product is obtained at the end.
Mass Balance:
INPUT KG OUTPUT KG
3-Chloro-6-
nitroacetanilide91 Wastewater 1471
Propylmercaptan 44
NaOH lye 77
Water 1370
Methanol 274 Methanol Recovery 260
Hexane 137 Hexane + Ether Recovery 220
Di-isopropylether 137 Distillation Residue 7
Water 822
NASH solution (30%) 274 Wastewater 1182
Con HCl 137
Sodium Hydroxide 343
Cyanamide 26
Acetone 40
Methyl chloroformate 30
Water 274 Wastewater 809
Drying loss 27
Albendazole 100
Total 4076 4076
Centrifuge
Drying
MASS BALANCE OF ALBENDAZOLE
Condensation
reaction
cyclization
Hydrogenation
Reductive
alkylation
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-12
5. 4-Hexyl resorcinol:
Manufacturing Process:
Add Zinc chloride, Caproic acid, resorcinol and water in the reactor. Mass
is condensed. During layer separation Caproic acid is recovered and
aqueous filtrate goes into ETP. Then methanol is added during
crystallization process. Also nickel catalyst and toluene is added with
water. Maintain the right temperature. Stir for 1 hour. At the end catalyst
is recovered and the mass is Centrifuged and 4-Hexyl resorcinol is
obtained.
Mass Balance:
INPUT KG OUTPUT KG
Zinc chloride 77
Caproic acid 190 Wastewater 1400
Resorcinol 110
Water 1400
Ni-catalyst 8 Catalyst 8
Methanol 1335 Methanol Recovery 1300
Toluene 605 Toluene Recovery 590
Distillation residue 50
Water 1200 Wastewater 1446
Drying loss 31
4-Hexyl resorcinol 100
Total 4925 4925
MASS BALANCE OF 4-Hexyl Resorcinol
Condensation
reaction
Crystalization
Centrifuge
Drying
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-13
6. Zopiclone:
Manufacturing Process:
2-Amino-5-chloropyridine and pyrazine-2-carboxylic acid was suspended
in dichloromethane. The suspension was refluxed azeotropically for 60
min. The mixture was cooled to 25-30° C and dimethyl formamide was
added followed by addition of thionyl chloride in 45-60 min at 25-30° C.
The resulting mixture was refluxed till completion of reaction. The
reaction mixture was concentrated to dryness at atmospheric pressure.
Cooled the solid to 25-35° C. and water is added to cooled the slurry to
20-25° C. and stirred for 30 min. Slurry was filtered and washed with
water. The solid was dried at 60-70° C. to obtain the mass. Add aqueous
sodium borohydride solution and water is added in under vigorous
stirring. Reaction mixture was stirred at 0-5° C. for 4 to 5 hrs. After
completion of reaction solid was filtered and washed with water. The
filtered solid was refluxed in dichloromethane for 30 min and cooled to
25-30° C. The solid was filtered and dried at 50-60° C to obtain of title
compound. Mixture of N-methyl piperazine carbomoyl chloride
hydrochloride was cooled to 10-15° C. Calcium oxide and dimethyl amino
pyridine were added to the mixture. Reaction mixture was warmed to 25-
30° C. and stirred till completion of reaction. After completion of reaction,
mixture was filtered and washed with dichloromethane. The
dichloromethane layer was concentrated at atmospheric pressure till
dryness. Methanol was added to residual solid and stirred for 60 min at
25-30° C. Slurry was cooled to 0-5° C. and stirred for 60 min at same
temperature. Solid was filtered, and dried at 50-60° C. to obtain
Zopiclone.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-14
Mass Balance:
INPUT KG OUTPUT KG
2-Amino-5-
chloropyridine111
Toluene 580 Toluene Recovered 550
Con.HCl 65 Distillation Residue 30
Pyrazine-2,3-
dicarboxylic acid anhy65 Wastewater 1220
Water 968
Dichloromethane 548 Dichloromethane Recovery 535
Dimethylformamide 33 Distillation Residue 13
Water 768 Wastewater 857
Thionyl chloride 79 SO2, HCl to scrubber 65
Sodium hydroxide 58
Water 1410 Dichloromethane Recovery 295
Sodiumborohydride 7 Distillation Residue 10
Dichloromethane 305 Wastewater 1418
N-me-piperazine
carbamoyl chloride HCl84
Calcium oxide 35
Dimethylaminopyridine 2
Dimethylformamide 80Dichloromethane + DMF
Recovery700
Dichloromethane 635 Methanol Recovery 345
Methanol 355 Residue 25
Drying loss 25
ZOPICLONE 100
Total 6188 6188
Centrifuge
Drying
MASS BALANCE OF Zopiclone
Condensation
reaction
Chroniation
Reduction
Condensation
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-15
7. Temoxifen Citrate:
Manufacturing Process:
In a Reactor charge POCl3 at cool it for 5-10oC. Then charge 2-
phenylbutanoic acid at 5-10 o C. Stir the reaction mass for 1 h at 5-10oC.
Then charge Phenol and chloride at 5-10o C and maintain temp. 5-10oC
for 30 min. Then rise the temp and stir the reaction mass at 48 hrs. Add
water and soda ash. Maintain the temperature 10-15oC during quenching.
Charge Water, NaOH solution, and Toluene in a Reactor with dean stark
and condenser and start heating for reflux 110o C. Then stop the heating
and cool the reaction mass to 50-55o C. Then Charge TBAB and DMCA
HCl and heat the reaction mass for reflux. Then stop heating and stirring.
Charge water to the reaction mass and stir well. Separate the organic and
aqueous layer. The Organic layer (Toluene layer) take for distillation and
distilled out toluene under vacuum below 70o C. Oily compound observed.
Charge Mg-turning and bromo benzene. Exotherm observed, apply water
bath. Take bromo-benzene, Me-THF and make solution with stirring.
After addition complete maintain the temperature (80-85oC) for 1 h. Then
cool the reaction mass to 10-15o C. Then take NH4Cl and water. Then add
this solution in reaction mass drop wise at 5-10oC. Charge IPA and clear
it on heating. Then cooled it up to 0-5oC and stir it well for 20 min at
same temp. The solid obtained was filter of charge Conc. HCl and heat it
up to 55oC. Maintain this temperature to complete hydrolysis for 18 hrs.
After complete hydrolysis, Charge Chloroform to reaction mass and
separate out it. Take Organic layer and distilled out the solvent Charge
Citric acid and Acetone in a reactor and Stir well. Heat it and clear it at
45o C. Then pass the mass to the centrifuge and waste water sent to the
ETP and then wet cake is formed which is dried and product is recovered.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-16
Chemical Reaction:
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-17
Mass Balance:
INPUT KG OUTPUT KG
Phenol 236
2-Phenyl butanoic acid 144
Phosphorus oxychloride 80
Zinc chloride 45
Water 500
Sodium hydroxide 106
HCL Conc. 120
Dimethylamine HCL 85
Sodium methoxide 105 Toluene Recovery 735
Tetrabutly ammonium
bromide9 Distillation Residue 15
Toluene 750 Waste water 600
Water 200
Soda ash 102
2-Methyl
tetrahydrofuran220
2-Methyl tetra hydrofuran
Recovery215
Bromo benzene 102 Isopropyl alcohol Recovery 282
Magnesium turning 70 Distillation Residue 13
Ammonium chloride 55 Wastewater 650
Iso propyl alcohol 290
Water 800
Conc. HCl 650 Wastewater 2066
Chloroform 600 Chloroform Recovery 590
Citric acid 37 Distillation Residue 10
Acetone 300 Acetone Recovery 290
Distillation Residue 10
Drying loss 30
Temoxifen Citrate 100
Total 5606 5606
Centrifuge
Drying
MASS BALANCE OF Tamoxifen Citrate
Condensation
reaction
Ammination
Reduction
Condensation
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-18
8. Bupropion HCl:
Manufacturing Process:
Take of 3‐Chloropropiophenone in Reactor Charge PTSA (P-Toluene
sulfonic acid) in reaction mass. The reaction mass is Stirred for 10‐15
min. Charge NBS (N-Bromo succinamide) and Di-chloro methane in
reaction mass at 50‐55oC. The reaction mass is cooled up to 30 min.
During Ammination process Tert. butyl amine and Di-chloro methane.
Aqueous filter is sent into ETP and Di-chloro methane is recovered. Add
IPA and IPA HCl to form the Salt of Bupropion HCl. Charge tert. Butyl
amine in reaction mass. Heating started up to reflux for completion of the
reaction. Charge DM water. Separate out layer and aqueous layer is
extracted with MDC Both Organic layers are distilled out under vacuum
below at 50-55oC. The reaction mass is cooled up to 10-15oC. Feed 16%
IPA. HCl drop wise in the reaction mass at 10-15oC up to pH 2-3. Hold
the reaction mass for 30 min at 10-15oC. Filter the material and washed
with chilled IPA then centrifuge the mass. Dry the wet cake and product
is obtained at last.
Chemical Reaction:
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-19
Mass Balance:
INPUT KG OUTPUT KG
3-Chloropropiophenone 57
P-Toluene sulfonic acid 7 Wastewater 1094
N-Bromo succinamide 67
Water 1026
Dichloro methane 171
Tert. Butyl amine 74 Wastewater 1061
Dichloro methane 57 Dichloro methane Recovery 220
Water 993 Distillation Residue 8
Isopropyl alcohol HCl 63
Isopropyl alcohol Recovery 220
Isopropyl alcohol 228 Distillation Residue 8
Drying loss 32
Bupropion HCl 100
Total 2743 2743
Drying
Centrifuge
MASS BALANCE OF Bupropion HCl
Condensation
reaction
Ammination
HCL Salt
Formation
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-20
9. Anastrazole:
Manufacturing Process:
Add 3,5-Bis(bromo methyl) toluene, sodium cynide and ethyle acetate
was added drop wise with vigorous stirring over 1 h. The reaction mixture
was stirred for a further 4 h at room temperature. The organic layer
taken and solvent is recovered in distillation column. Then add sodium
hydride, methyl iodide in reactor to complete the methylation and waste
water is sent into ETP. Add Acetonitrile in the solution along with water
and ethyl acetate. Wastewater is sent into treatment. From organic layer
separation solvents are recovered. Then add Dimethyl Formamide, ethyl
acetate and cyclohexane. After that centrifuge the mass and at the end of
process Anstrazole is generated.
Mass Balance:
INPUT KG OUTPUT KG
3,5-Bis(bromo methyl)
toluene
180
Sodium cynide 55 Methanol Recovery 635
Methanol 650 Ethylacetate Recovery 343
Ethyl acetate 350 Isopropanol Recovery 440
Isopropanol 450 Distillation residue 32
Sodium Hypochlorite solution 150
Sodium hydride 150Dimethylformamide
Recovery245
Methyl iodide 338 Ethylacetate Recovery 441
Dimethyl formamide 250 Distillation residue 14
Ethyl acetate 450 Waste water 380
Water 520
Acetonitrile 450 Acetonitrile Recovery 445
NBS 100 Ethyl acetate Recovery 635
AIBN 20 Distilation Residue 20
Water 1000 Wastewater 850
Ethylaceatate 650
Dimethyl formamide 400 Dimethyl formamide 390
1,2,4-trazole Na salt 27 Ethyl acetate Recovery 540
AIBN 20 Cyclohexane Recovery 440
Ethylaceatate 550 Distilation Residue 30
Cyclohexane 450
Water 650 Wastewater 1851
Drying loss 29
Anastrazole 100
Total 7860 7860
Centrifuge
Drying
MASS BALANCE OF Anastrozole
Cyanation
Reaction
Methylation
Ditillation
Traizole
Reaction
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-21
10. Theophylline:
Manufacturing Process:
Add Uracil, Methanol and potassium hydroxide in the reactor. Add methyl
iodide in the reactor. Keep the temperature between 55-60oC. Methanol
is recovered at the end. Waste water is goes into the ETP. Add nitric acid
and sulphuric acid to complete the nitration process. Add HCl, Iron
powder and Methylene chloride. Tetrahydro furan and Methylene chloride
is recovered at the end. Add Nitric acid, sulphuric acid and formic acid for
purification process. For reflux add ethyl acetate and Dichloromethane.
Solvents are recovered in distillation. Centrifuge the mass and aqueous
layer goes into ETP, dried the mass and product is recovered.
Mass Balance:
INPUT KG OUTPUT KG
Uracil 95
Methanol 516 Methanol Recovery 505
Potassium hydroxide 80 Distillation residue 11
Methyl iodide 55
Nitric acid 87
Sulphuric acid 125 Waste water 1500
Water 2097
Tetrahydro furan 710 Iron Sludge 75
HCL solution 90 Tetrahydro furan
Recovery
700
Iron powder 80 Methylene chloride
Recovery
500
Bicarbonate 115 Distillation residue 26
Methylene chloride 516
Nitric acid 85
Sulphuric acid 95 Wastewater 900
Water 450
Formic acid 25
Glacial acetic acid 3
Ethyl acetate 645 Ethyl acetate Recovery 630
Dichloromethane 645 Dichloromethane
Recovery
630
Bicarbonate 90 Distillation residue 30
Water 958 Wastewater 1922
Drying loss 33
Theophylline 100
Total 7562 7562
Centrifuge
Drying
Purification
MASS BALANCE OF Theophylline
Codentasation
reaction
Nitration
Reaction
Reduction
reaction
Purification
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-22
11. Allantoin
Manufacturing Process:
Add urea, Glyoxylic acid, sodium hydroxide in reactor. Mass is condensed
with water. Catalyst is recovered at the end. Mass is dried and then it is
goes for crystallization. In crystallization add water and NaOH. Then mass
is transfer for centrifugation and waste water is sent into ETP. Then mass
is dried and product is received at the end.
Mass Balance:
INPUT KG OUTPUT KG
Urea 38
Glyoxylic acid 47 Waste water 2090
Catalyst 8 Catalyst 8
Water 2205
Sodium hydroxide 23
NaOH 20
Water 500
Water 1995 Waste water 2605
Drying loss 33
Allantoin 100
Total 4836 4836
MASS BALANCE OF Allantoin
Condensation
reaction
Crystallization/
Purification
Centrifuge
Drying
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-23
12. Terbinafine Hydrochloride
Manufacturing Process:
Add 6,6-Dimethyl-1-Heptene-4-yene-3-ol and Phosphorous oxy chloride.
Mass is condensed with Conc. HCl. Keep it stir for 3 hours. Diisopropyl
ether and Acetonitrile is added in the vessel, which are recovered at the
end of condensation. Add N-Methyl-1-Naphthalene methylamine in the
above dried mass. Add Dimethyl formamide, Di-isopropyl Ether,
Methylene chloride and Sodium carbonate. Solvents are recovered at the
end of distillation process. Then mass is dried and Terbinafine Base is
obtained. In Terbinafine Base acetone and Methylene chloride is added
along with water and centrifuge it. Then mass is dried. Terbinafine
Hydrochloride is obtained at the end.
Mass Balance:
INPUT KG OUTPUT KG
6,6-Dimethyl-1-Heptene-
4-yene-3-ol150 Acetonitrile Recovery
515
Phosphorous oxy chloride 625 Diisopropyl ether Recovery 1470
Acetonitrile 525 Distillation Residue 40
Conc. HCl 125 Waste Water 1310
Diisopropyl ether 1500
Water 725
N-Methyl-1-Naphthalene
methylamine
100 Methylene chloride Recovery 735
Dimethyl formamide 50 Diisopropyl Ether Recovery 860
Sodium carbonate 55 Distillation Residue 30
Methylene chloride 750 Wastewater 535
Diisopropyl Ether 875
Water 225
Methylene chloride 500 Methylene chloride Recovery 480
Acetone 300 Acetone Recovery 290
Distillation Residue 30
Water 200 Waste Water 280
Drying loss 30
TERBINAFINE HCl 100
Total 6705 6705
Drying
MASS BALANCE OF TERBINAFINE HYDROCHLORIDE
Codentasation
reaction
Preperation of
Terbinafine
Purification
Centrifuge
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-24
13. Pregabalin Hydrochloride
Manufacturing Process:
In the reactor charge Isoveraldehyde, ethyl Cyano acetate, Diethyle
malonate and water. Maintain the temperature between 27-32oC. Add HCl
in the vessel and stir it for 1 hour. Then mass is further condensed with
urea and sodium hydroxide solution. Waste water goes into ETP and mass
is dried. Then dried mass is collected in that Phenyl ethylamine and PTSA
is added. Add Concentrated HCl in vessel. Stir it for 3 hrs. Cool it for 1
hour. Then mass is crystallized with IPA. IPA is recovered at the end. Add
HCl in the mass and after that centrifuge the mass. Then dried the mass.
At the end Pregabalin Hydrochloride is obtained.
Mass Balance:
INPUT KG OUTPUT KG
Isoveraldehyde 65
Ethyl cyano acetate 78
Diethyl malonate 93 Heptane Recovery 82
Di-N-Propylamine 8 Distillation residue 5
Water 155
Heptane 87
Conc HCl 543
Urea 47
Sodium Hydroxide 1 Wastewater 350
Conc HCl solution 8
Water 250
Chloroform 543 Chloroform Recovery 525
Ethanol 5 Phenyl ethylamine Recovery 72
Phenyl ethylamine 76 Distillation residue 22
PTSA 4 Wastewater 112
Sodium hydroxide 26
Conc HCl 70
DM Water 101
Sodium Hydroxide 146 Isopropyl alcohol
Recovery
78
Isopropyl alcohol 80 Distillation residue 2
Conc HCl 147
Water 698 Wastewater 1853
Drying loss 30
Pregabaline HCl 100
Total 3231 3231
Centrifuge
Drying
MASS BALANCE OF PREGABALIN HYDROCHLORIDE
Codentasation
reaction
Condensation
reaction
Recimization
Crystallization/
Purification
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-25
14. Rebamipide
Manufacturing Process:
Nitration: Charge Diethyl Malonate in nitric acid and warm reaction and
add water in the reaction. After completion of nitration, Reduction take
place.
Reduction: Charge Dichloromethane along with Catalyst and heat up to
45 to 60oC. At the end of reduction catalyst is recovered.
Condensation: charge 4-Chlorobenzoic acid chloride and Dimethyl
formamide. Add water in it. Methylene Dichloride Filtrate is obtained at
the end. Further mass is condensed with 4 Bromo methyl quinoline and
sodium ethoxide. Add Concentrated HCl in vessel and stir for 1 hr. then
add Ethanol.
Centrifugation: The mass is transfer for centrifugation, waste water
goes into ETP and Ethanol is recovered by distillation process. Mass is
dried and Rebapimide is obtained at the end.
Mass Balance:
INPUT KG OUTPUT KG
Diethyl Malonate 44
Nitric acid 42 Wastewater 153
Water 139
Dichloromethane 278 Catalyst Recovery 7
Catalyst Pd/C 7
4-Chlorobenzoic acid 49 Wastewater 31
Dimethyl formamide 1 Dichloromethane Recovery 270
DM water 28 Distillation residue 8
4-Bromo methyl quinoline 63
Sodium Ethoxide 21 Ethanol Recovery 400
Ethanol 416 Residue 16
Sodium Hydroxide 13
Conc HCl 42
Water 70 Wastewater 198
Drying loss 30
REBAMIPIDE 100
Total 1213 1213
Centrifuge
Drying
MASS BALANCE OF REBAMIPIDE
Nitration
Reduction
Condensation
Condensation
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-26
15. Valsartan
Manufacturing Process:
L‐ Valine is treated with methanol in presence of Thionyl chloride to get L‐
Valine methyl ester which was then neutralized with alkali solution to get
L‐methyl valinate. L‐Methyl valinate is condensed with 4‐bromo methyl
‐2‐cyano biphenyl in presence of potassium carbonate which was then
treated with oxalic acid to isolate the Valsartan oxalate. Valsartan oxalate
is condensed with Valeroyl chloride in presence of potassium, Carbonate
in o‐xylene to get Valeroyl Valsartan. The cyano group of Valeroyl
Valsartan is cyclized in presence of tri butyl tin chloride & sodium azide in
o‐xylene at reflux to get methyl Valsartan. The methyl Valsartan is then
hydrolyzed with sodium hydroxide and isolated with dichloromethane and
cyclohexane to get crude Valsartan. The crude Valsartan is treated with
calcium hydroxide in acetone and D I water and filtered to obtained
calcium salt of Valsartan. Valsartan calcium salt is treated with
hydrochloric acid in ethyl acetate and water. The ethyl acetate layer is
treated with di-isopropyl ether to obtain the pure Valsartan.
Chemical Reaction:
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-27
Mass Balance:
INPUT KG OUTPUT KG
L‐ Valine 45
Methanol 450
Thionyl chloride 35 SO2, HCl to scrubber 28
Water 200 Methanol recovery 440
Toluene 650 Toluene recovery 635
DCM 350 DCM recovery 345
Sodium hydroxide 35 Distillation residue 30
NaCl 15 Wastewater 120
4‐ bromo methyl ‐2 ‐
cyano biphenyl
70
Potassium carbonate 45
Acetonitrile 450 Acetonitrile recovery 442
O-xylene 625 O-xylene recovery 615
Oxalic acid 1 Distillation residue 18
Water 450 Wastewater 400
Valeroyl Chloride 40
Potassium carbonate 25
Water 900
Sodium bicarbonate 28
O-xylene 300
HCl 65
Tri butyl tin chloride 20
Tetra butyl
ammonium bromide
15
Sodium azide 22
Hexane 550 Hexane recovery 540
DCM 300 DCM recovery 295
O-xylene 300 O-xylene recovery 295
Sodium hydroxide 45 Distillation residue 20
Calcium hydroxide 25
Water 900 Wastewater 850
Acetone 450 Acetone recovery 445
Ethyl acetate 400 Ethyl acetate recovery 390
Di isopropyl ether500 Di isopropyl ether
recovery490
Water 100 Distillation residue 20
HCl 10 Wastewater 1873
Drying loss 25
VALSARTAN 100
Total 8416 8416
MASS BALANCE OF VALSARTAN
Reactor
Reactor
Reactor
Drying
Reactor
Reactor
Centrifuge
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-28
2.6 PROJECT COMPONENTS
Components of the project include all facilities required for the operation,
which is summarized below:
a) Input Requirement: Raw materials, Water, Fuel, Power, Manpower
b) Utility requirement: Boilers, D.G. set, Cooling tower, Chilling Plant
and RO/DM Plant.
c) Treatment Facilities:
Water treatment facilities: ETP, RO, & MEE
Air Pollution Control Facilities: Multi Cyclone, Bag filter & water
scrubber for flue gas stacks; and water scrubbers & alkali scrubbers
for process gas stacks.
Hazardous/solid waste disposal facilities: Hazardous waste storage
facility.
d) Other: Greenbelt and rain water harvesting.
2.7 INPUT REQUIREMENTS
a) Raw material requirement:
The details of the raw material requirement with availability and mode of
transport are given in Table 2.5 below. The raw materials will be stored/
inventory will be maintained as per market requirement of the products
and production schedule.
Table 2.5 Raw Materials Requirement, Availability & Mode of Transport
Sr. no.
Name of Products
Name of Raw Material Quantity MT/MT
Availability Mode of Transport
1 Telmisartan 2‐n‐Propyl‐4‐methyl ‐6‐(1‐methyl
benzimidazole‐2‐yl)
benzimidazole
0.68 Indigenous/ Imported
By Road/ Sea
methyl‐4’‐(bromomethyl)‐biphen
yl‐2‐carboxylate
0.58 Indigenous/
Imported
By Road/
Sea
Acetone 0.10 Indigenous By Road
Sodium hydroxide 0.40 Indigenous By Road
Methanol 0.10 Indigenous/ Imported
By Road/ Sea
HCl 0.70 Indigenous By Road
Dichloromethane 0.10 Indigenous By Road
Hyflo 0.01 Indigenous By Road
2 Ondensetron
HCl
1,3-CHD 1.20 Indigenous/ Imported
By Road/ Sea
Phenyl hydrazine 1.81 Indigenous/ Imported
By Road/ Sea
Acetic acid 5.22 Indigenous By Road
Zinc chloride 2.52 Indigenous By Road
Methanol 0.12 Indigenous By Road
Con HCl 0.93 Indigenous By Road
Dimethyl sulphate 0.70 Indigenous By Road
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-29
Acetone 0.15 Indigenous By Road
Potassium Carbonate 0.40 Indigenous By Road
DMA HCl 0.72 Indigenous By Road
Paraformaldehyde 0.27 Indigenous/ Imported
By Road/ Sea
2-Methyl Imidazole 0.95 Indigenous By Road
3 Benfotanamine TMP 1.22 Indigenous/
Imported
By Road/
Sea
Caustic 0.27 Indigenous By Road
Benzoyl chloride 0.60 Indigenous By Road
HCl 0.80 Indigenous By Road
Methanol 0.15 Indigenous By Road
4 Albendazole 3-Chloro-6-nitroacetanilide 0.91 Indigenous/ Imported
By Road/ Sea
Propylmercaptan 0.44 Indigenous/
Imported
By Road/
Sea
NaOH lye 0.77 Indigenous By Road
Methanol 0.14 Indigenous By Road
Hexane 0.03 Indigenous By Road
Di-isopropylether 0.03 Indigenous By Road
NASH solution (30%) 2.74 Indigenous By Road
Con HCl 1.37 Indigenous By Road
Sodium Hydroxide 3.43 Indigenous By Road
Cyanamide 0.26 Indigenous By Road
Acetone 0.40 Indigenous By Road
Methyl chloroformate 0.30 Indigenous By Road
5 4-Hexyl
resorcinol
Zinc chloride 0.77 Indigenous By Road
Caproic acid 1.90 Indigenous By Road
Resorcinol 1.10 Indigenous By Road
Methanol 0.35 Indigenous By Road
Toluene 0.15 Indigenous By Road
6 Zopiclone 2-Amino-5-chloropyridine 1.11 Indigenous/ Imported
By Road/ Sea
Toluene 0.30 Indigenous By Road
Con.HCl 0.65 Indigenous By Road
Pyrazine-2,3-dicarboxylic acid
anhy
0.65 Indigenous By Road
Dichloromethane 0.36 Indigenous By Road
Dimethylformamide 0.35 Indigenous By Road
Thionyl chloride 0.79 Indigenous By Road
Sodium hydroxide 0.58 Indigenous By Road
Sodiumborohydride 0.07 Indigenous By Road
N-me-piperazine carbamoyl chloride HCl
0.84 Indigenous/ Imported
By Road/ Sea
Calcium oxide 0.35 Indigenous By Road
Dimethylaminopyridine 0.02 Indigenous/ Imported
By Road/ Sea
Methanol 0.10 Indigenous By Road
7 Tamoxifen
Citrate
Phenol 2.36 Indigenous By Road
2-Phenyl butanoic acid 1.44 Indigenous/ Imported
By Road/ Sea
Phosphorus oxychloride 0.80 Indigenous/
Imported
By Road/
Sea
Zinc chloride 0.45 Indigenous By Road
Sodium hydroxide 1.06 Indigenous By Road
Conc. HCl 7.70 Indigenous By Road
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-30
Dimethylamine HCl 0.85 Indigenous By Road
Sodium methoxide 1.05 Indigenous By Road
Tetrabutly ammonium bromide 0.09 Indigenous By Road
Toluene 0.15 Indigenous By Road
Soda ash 1.02 Indigenous By Road
2-Methyl tetrahydrofuran 0.05 Indigenous By Road
Bromo benzene 1.02 Indigenous By Road
Magnesium turning 0.70 Indigenous By Road
Ammonium chloride 0.55 Indigenous By Road
Iso propyl alcohol 0.08 Indigenous By Road
Chloroform 0.10 Indigenous By Road
Citric acid 0.37 Indigenous By Road
Acetone 0.10 Indigenous By Road
8
Bupropion HCl 3-Chloropropiophenone 0.57 Indigenous/
Imported
By Road/
Sea
P-Toluene sulfonic acid 0.07 Indigenous/ Imported
By Road/ Sea
N-Bromo Succinamide 0.67 Indigenous/ Imported
By Road/ Sea
Dichloro methane 0.08 Indigenous By Road
Tert. Butyl amine 0.74 Indigenous By Road
Isopropyl alcohol HCl 0.63 Indigenous By Road
Isopropyl alcohol 0.08 Indigenous By Road
9 Anastrazole 3,5-Bis (bromo methyl) toluene 1.80 Indigenous/ Imported
By Road/ Sea
Sodium cynide 0.55 Indigenous By Road
Methanol 0.15 Indigenous By Road
Ethyl acetate 0.07 Indigenous By Road
Isopropanol 0.10 Indigenous By Road
Sodium Hypochlorite solution 1.50 Indigenous By Road
Sodium hydride 1.50 Indigenous By Road
Methyl iodide 3.38 Indigenous By Road
Dimethyl formamide 0.05 Indigenous/ Imported
By Road/ Sea
Ethyl acetate 0.09 Indigenous By Road
Acetonitrile 0.05 Indigenous By Road
NBS 1.00 Indigenous By Road
AIBN 0.40 Indigenous By Road
Ethylaceatate 0.25 Indigenous By Road
Dimethyl formamide 0.10 Indigenous By Road
1,2,4-trazole Na salt 0.27 Indigenous By Road
Cyclohexane 0.10 Indigenous By Road
10 Theophylline Uracil 0.95 Indigenous By Road
Methanol 0.11 Indigenous By Road
Potassium hydroxide 0.80 Indigenous By Road
Methyl iodide 0.55 Indigenous By Road
Nitric acid 0.87 Indigenous By Road
Sulphuric acid 1.25 Indigenous By Road
Tetrahydro furan 0.10 Indigenous By Road
HCl solution 0.90 Indigenous By Road
Iron powder 0.80 Indigenous By Road
Bicarbonate 1.15 Indigenous By Road
Methylene chloride 0.16 Indigenous By Road
Nitric acid 0.85 Indigenous By Road
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-31
Sulphuric acid 0.95 Indigenous By Road
Formic acid 0.25 Indigenous By Road
Glacial acetic acid 0.03 Indigenous By Road
Ethyl acetate 0.15 Indigenous By Road
Dichloromethane 0.15 Indigenous By Road
Bicarbonate 0.90 Indigenous By Road
11 Allantoin Urea 0.38 Indigenous By Road
Glyoxylic acid 0.47 Indigenous By Road
Sodium hydroxide 0.23 Indigenous By Road
NaOH 0.20 Indigenous By Road
12 Terbinafine
Hydrochloride
6,6-Dimethyl-1-Heptene-4-yene-3-ol
1.50 Indigenous/ Imported
By Road/ Sea
Phosphorous oxy chloride 6.25 Indigenous By Road
Acetonitrile 0.10 Indigenous By Road
Conc. HCl 1.25 Indigenous By Road
Diisopropyl ether 0.30 Indigenous By Road
N-Methyl-1-Naphthalene methylamine
1.00 Indigenous/ Imported
By Road/ Sea
Dimethyl formamide 0.50 Indigenous By Road
Sodium carbonate 0.55 Indigenous By Road
Methylene chloride 0.15 Indigenous By Road
Diisopropyl Ether 0.15 Indigenous By Road
Methylene chloride 0.20 Indigenous By Road
Acetone 0.10 Indigenous By Road
13 Pregabalin
Hydrochloride
Isoveraldehyde 0.65 Indigenous/
Imported
By Road/
Sea
Ethyl cyano acetate 0.78 Indigenous/
Imported
By Road/
Sea
Diethyl malonate 0.93 Indigenous/ Imported
By Road/ Sea
Di-N-Propylamine 0.08 Indigenous By Road
Heptane 0.05 Indigenous By Road
Conc HCl 7.68 Indigenous By Road
Urea 0.47 Indigenous By Road
Sodium Hydroxide 1.73 Indigenous By Road
Chloroform 0.18 Indigenous By Road
Ethanol 0.05 Indigenous By Road
Phenyl ethylamine 0.76 Indigenous By Road
PTSA 0.04 Indigenous By Road
Isopropyl alcohol 0.02 Indigenous By Road
14 Rebapimide Diethyl Malonate 0.44 Indigenous By Road
Nitric acid 0.42 Indigenous By Road
Dichloromethane 0.08 Indigenous By Road
4-Chlorobenzoic acid chloride 0.49 Indigenous By Road
Dimethyl formamide 0.01 Indigenous By Road
4-Bromo methyl quinoline 0.63 Indigenous/ Imported
By Road/ Sea
Sodium Ethoxide 0.21 Indigenous By Road
Ethanol 0.16 Indigenous By Road
Sodium Hydroxide 0.13 Indigenous By Road
Conc HCl 0.42 Indigenous By Road
15 Valsartan L‐ Valine 0.45 Indigenous/ Imported
By Road/ Sea
Methanol 0.10 Indigenous By Road
Thionyl chloride 0.35 Indigenous By Road
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-32
Toluene 0.15 Indigenous By Road
DCM 0.05 Indigenous By Road
Sodium hydroxide 0.80 Indigenous By Road
NaCl 0.15 Indigenous By Road
4‐ bromo methyl ‐2 ‐ cyano
biphenyl
0.70 Indigenous/ Imported
By Road/ Sea
Potassium carbonate 0.45 Indigenous By Road
Acetonitrile 0.08 Indigenous By Road
O-xylene 0.20 Indigenous By Road
Oxalic acid 0.01 Indigenous By Road
Valeroyl Chloride 0.40 Indigenous By Road
Potassium carbonate 0.25 Indigenous By Road
Sodium bicarbonate 0.28 Indigenous By Road
HCl 0.75 Indigenous By Road
Tri butyl tin chloride 0.20 Indigenous By Road
Tetra butyl ammonium bromide 0.15 Indigenous/ Imported
By Road/ Sea
Sodium azide 0.22 Indigenous By Road
Hexane 0.10 Indigenous By Road
DCM 0.05 Indigenous By Road
Calcium hydroxide 0.25 Indigenous By Road
Acetone 0.05 Indigenous By Road
Ethyl acetate 0.10 Indigenous By Road
Di isopropyl ether 0.10 Indigenous By Road
b) Water requirement:
Total water requirement (Industrial + Domestic + Greenbelt) will be 253
KLD; out of which 118 KLD will be fresh water requirement & 135 KLD
will be recycle/treated water (RO permeate & MEE condensate). Unit will
satisfy its fresh water requirement from Bore well water supply. Major
water demand will be industrial – mainly process (115 KLD), cooling (30
KLD), boiler (35 KLD), and washing (10 KLD). Detailed break up of each
water consumption and Water balance diagram is given in Table 2.6 and
Figure 2.5, respectively.
Table 2.6 Breakup of water consumption & w/w generation
Sr. No.
Source Water Consumption (KL/day)
W/w Generation (KL/day)
1. Domestic 5.0 4.0
2. Green Belt 50 --
3. Industrial
A Water treatment 22 22
B Process 93 96
C Lab 2.0 2.0
D Scrubber 6.0 1.0
E Cooling 30 6.0
F Boiler 35 4.0
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-33
G Washing 10 10
Total Industrial 198 141
Total (1 +2 + 3) 253 145
Recycle Water 135 --
Fresh water
requirement
118 --
Figure 2.5 Water Balance Diagram
Total Water consumption = 253 KLD (118 fresh KLD + 135 recycle* KLD)
Domestic 5
Lab 2
Washing 10
Greenbelt 50
Cooling 30
2 96
Scrubber 6.0
6.0 Bleed off
Boiler 35
Drying loss 1.0
1.0
Soak-pit 4
ETP 22+96+2.0+1.0+10+4+6 = 141
Permeate 95*
4.0 Blow down
RO 141
Reject
MEE 46
Condensate 40*
Salt 2.0
Loss 4.0
Process 115
W. treatment 115
Process 93
Utilities 65
Water
with RM 4.0
10
HCl 3.0
NaHSO3 2.0
22
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-34
c) Power:
Total power requirement of 1000 kVA will be sourced from MGVCL
(Madhya Gujarat Vij Company Limited). Unit will also install a stand by D.
G. Set of capacity 500 kVA, which will be used only in case of emergency/
power failure from the grid.
d) Fuel:
Unit proposes to use Agro briquette as fuel in proposed boiler, TFH & HAG
at the rate of 37 TPD, respectively. Details of fuel consumption are given
below in Table 2.7.
Table 2.7 Details of Utilities and fuel consumption
Sr.
No.
Name of utility Name of fuel Quantity
of fuel
1 Steam Boiler (3.0 TPH) Agro briquette 12 TPD
2 Thermic fluid heater
(20 lac Kcal/hr.)
Agro briquette 10 TPD
3 Hot air generator
(30 lac Kcal/hr.)
Agro briquette 15 TPD
4 DG Set (500 kVA) Diesel 125 lit/hr
e) Manpower:
Total manpower for proposed project will be 65 nos., which include
manpower at all levels.
2.8 GENERATION OF POLLUTANTS
The sources of generation of pollutants are given below;
2.8.1 Wastewater Generation
Total industrial wastewater generation will be 141 KLD. The main source
of the industrial wastewater generation will be from process including lab
and scrubber (99 KLD), washing (10 KLD), utilities (Water treatment,
Boiler & cooling - 10 KLD), and water treatment (22 KLD). Domestic
wastewater generation will be 4.0 KLD. The details of the wastewater
generation are depicted in Table 2.6. Water balance diagram is given in
Figure 2.5.
2.8.2 Gaseous Emission
Flue gas emission will be from stack attached with boilers, Thermic fluid
heater and Hot air generator where Agro briquette will be used as a fuel;
and standby D.G. Set. Most probable pollutants will be SPM, SO2 and
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-35
NOx. Process emission will be from the reaction vessels and
corresponding pollutants will be HCl and SO2. The details of the flue gas
stacks & process gas stacks and emission quality of Stacks are given in
Table 2.8 and Table 2.9, respectively.
Table 2.8 Details of stacks
Sr.
No.
Stack
attached to
Stack
Height
(m)
Fuel
Used
Fuel
consu-
mption
APC
measure
Pollutants
Flue gas Stack
1 Steam Boiler
(3.0 TPH)
30 Agro
briquette
12 TPD Multi
Cyclone, bag filter &
water scrubber
PM<150
mg/Nm3
SO2<100 ppm
NOx<50 ppm 2 Thermic fluid
heater (20 lac Kcal/hr.)
30 Agro
briquette
10 TPD
3 Hot air
generator (30 lac Kcal/hr.)
30 Agro
briquette
15 TPD
4 DG Set
(500 kVA)
11 Diesel 125
lit/hr.
--
Process Gas Emission
1 Process vessel 11 -- -- Water
scrubber followed by
Alkali
Scrubber
SO2<40
mg/Nm3
HCl<20
mg/Nm3
2 SFD/FBD/RVD
(5 nos.)
11 -- -- Inbuilt Cyclone and
Bag filter
PM<40
mg/Nm3
Table 2.9 Estimated Emission Quality of Stack
Sr.
No.
Stack attached
to
Stack
Height
(m)
Temp.
(K)
Velocity
(m/s)
Dia.
(m)
Concentration
SPM
mg/Nm3
SO2
mg/Nm3
NOx
mg/Nm3
1 Steam Boiler
(3.0 TPH)
30 455 6.0 0.45 80 40 35
2 Thermic fluid
heater
(20 lac Kcal/hr.)
30 455 6.5 0.45 80 40 35
3 Hot air
generator
(30 lac Kcal/hr.)
30 455 6.5 0.45 80 40 35
4 D. G. Set
(500 kVA)
11 485 15.0 0.3 65 30 35
5 Process vessel
stack
11 335 5.0 0.3 SO2 - 30 mg/Nm3
HCl - 18 mg/Nm3
6 SFD/ FBD/ RVD
(5 nos.)
11 335 5.0 0.3 PM - 30 mg/Nm3
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-36
Sources of fugitive emission:
In proposed activities, there will be chances of generation of acid fumes
and VOCs from material handling area, process area, and solvent storage
area. There will be also changes of generation of PM (Dust) from packing/
finishing area.
2.8.3 Hazardous/Solid waste generation
Main source of hazardous waste generation will be ETP sludge (25
MT/month) and MEE salt (50 MT/month) from wastewater treatment.
Other wastes will be distillation residue (15 MT/month), Process sludge
(12 MT/month), spent carbon (0.75 MT/month), spent catalyst (1.0
MT/month), used lubricating oil (40 Lit/month), discarded drums (700
nos./month), containers/liners and liners (0.5 MT/month), whatsoever
generated off-specific product and date expired products. HCl (20-25%) -
75 MT/month and Sodium bisulfite (NaHSO3) - 50 MT/month.
Fly ash generation will be around 4.0 MT/day. The details of
solid/hazardous waste generation with its category and quantity are given
in Table 2.10.
Table 2.10 Details of Hazardous waste
Sr.
No.
Type of Solid
Waste
Schedule Quantity Disposal method
Hazardous waste
1 ETP Sludge
&
MEE Salt
35.3 25
MT/month
50
MT/month
Collection, storage & disposal at
TSDF site approved by GPCB.
2 Distillation
residue
20.3 15
MT/month
Collection, storage & disposal at
CHWIF or Co-processing.
3 Process Waste 28.1 12
MT/month
Collection, storage & disposal at
TSDF site approved by GPCB.
4 Used
Lubricating Oil
5.1 40
liter/month
Collection, storage & use within premises as lubricant/sell to
registered recycler.
5 Discarded
containers/
barrels/
Liners
33.1 700
Nos./month
0.5
MT/month
Collection, storage and reuse
for packing of products or
disposal by selling to approved
recyclers.
6 Spent catalyst 28.2 1.0 MT/month
Collection, storage & return back to supplier for
regeneration.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-37
7 Spent carbon 28.3 0.75 MT/month
Collection, storage & return back to supplier for regeneration
8 Off Specific
Products
28.4 Whatever
generated
Collection, storage & disposal at
CHWIF.
9 Date expired
product
28.5 Whatsoever generated
Collection, storage & disposal at
CHWIF.
10 HCl (20-25%) B(15) 75 MT/month
Collection, Storage,
Transportation, sell to actual
user under Rule-9 of HAZ Rule.
11 Sodium
bisulfite
(NaHSO3)
B(15) 50 MT/month
Collection, Storage,
Transportation, sell to actual
user under Rule-9 of HAZ Rule.
Solid waste
1 Fly ash -- 100 MT/month
Collection, Storage, sell to brick
manufacturers.
2.8.4 Noise generation
Main source of noise generation will be boilers, D.G. set, process plant,
vehicular transportation & other machineries.
2.9 POLLUTION CONTROL STRATEGY
The unit is equally conscious about the pollution control strategy. The
details of pollution control strategy for various parameters are given here
under,
2.9.1 Effluent Management
The main source of the industrial wastewater generation will be from
process, water treatment, washing & utilities. The details of the
wastewater generation are shown in Table 2.6. Unit will built full-fledged
ETP to treat w/w generated from proposed project.
Process effluent (Concentrated stream) along with wastewater of
scrubber, washing and utility will be passed through to RO after primary
and secondary treatment. RO reject will be sent to MEE; RO permeate
and condensate of MEE will be reused. Domestic wastewater will be
disposed to soak pit. Thus, achieving Zero Liquid Discharge (ZLD). ETP
sludge and MEE salt will be disposed to approve TSDF site. Domestic
effluent of 4.0 KLD will be disposed to soak pit.
Effluent treatment scheme:
Wastewater from process, washing Scrubbers etc. will be collected in
equalization/neutralization tank, where it is neutralized, depending upon
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-38
the acidity/alkalinity of influent. Later it will be pumped into primary
settling tank to settle down suspended solid. Later it will be pumped into
aeration tanks for biological treatment, where microorganisms will be
reduced organic load in effluent. Then effluent is allowed to secondary
settling tank. This activated effluent is passed to settling tanks for
settling purpose. Here sludge formed is settled and removed from the
bottom hopper. Then water will be transferred to the pressure sand filter
followed by RO. RO permeate will be reused, and RO reject will be sent to
MEE. Sludge will be transferred to the sludge drying bed. After drying,
the dried sludge will be collected, packed in HDPE bags and stored in
separate storage area and disposed at approved TSDF site. Salt from MEE
will be sent to TSDF site, too.
Specifications of ETP, RO, and MEE are provided in Table 2.11, 2.12,
and 2.13, respectively. Characteristic of untreated and treated effluent is
provided in Table 2.14. Process flowchart of ETP is given in Figure 2.6.
Table 2.11 Name and size of ETP units, Design Capacity-200 KLD
Sr. No. Name of units Size of Unit Capacity (m3)
1 Equalization tank 6.0 m x 6.0 m x 4.0
(3.5 WD)
126
2 Neutralization tank 6.0 m x 6.0 m x 4.0
(3.5 WD)
126
3 Primary Settling tank 8.0 m x 6.0 m x 2.5
(1.5 SWD)
48 m2
Surface area
4 Aeration tank 7.5 m x 7.5 m x 4.5
(4.0 WD)
225
5 Secondary Settling tank 8.0 m x 6.0 m x 2.5
(1.5 SWD)
48 m2
Surface area
6 Sludge sump 3.0 m x 3.0 m x 3.0
(2.5 WD)
22.5
7 Filter press 1 No. 42 plates with
36”x 36” size
--
8 Sludge drying beds-
4 Nos.
5.0 m x 5.0 m x 1.5 25 m2 x 4
Surface area
9 Intermediate sump 5.0 m x 5.0 m x 4.5
(4.0 WD)
100
10 Pressure sand Filter Standard Supply 10 Kl/Hr
filtration rate
11 Treated water collection
sump
5.0 m x 5.0 m x 4.5
(4.0 WD)
100
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-39
12 RO, 2 Nos. (One
standby)
Standard Supply 10 Kl/Hr
filtration rate
13 RO Treated water sump 5.0 m x 5.0 m x 4.5
(4.0 WD)
100
14 Reject Effluent sump 3.5 m x 3.5 m x 4.5
(4.0 WD)
49
15 MEE & ATFD Standard Supply 2.5 Kl/Hr
Figure 2.6 Process flow chart of wastewater treatment (ETP-200 m3/day)
Table 2.12 Technical specification of RO (Capacity: 10 KL/hr.)
Particulars Specification
Type of membrane Thin film composite spiral wound
MOC of membrane Polyamide
MOC of membrane housing FRP
Make of membrane housing Matrix/Equiv
High pressure piping from SS 316
No. of housings Two
No. of membranes 6 nos.
RO feed flow rate 10000 LPH
RO permeate flow rate ~7000LPH
Operating pressure 12-14 kg/cm2
Filter Press & Sludge drying bed
ETP Sludge to TSDF
Equalization/ Neutralization
Tank
Primary Settling
Tank
Pressure sand filter
RO Permeate to reuse
Reject
MEE/ ATFD
Condensate reuse
Reject
Salt to TSDF
Equalization/
Neutralization Tank
Aeration
Tank
Secondary
Settling Tank
Intermediate
sump
Effluent from Plant
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-40
Table 2.13 Technical Details of MEE (Capacity: 2.5 KL/hr)
Description Unit Value
Water Evaporation capacity Kgs/hr ~2125-2050
Feed rate Kgs/hr 2500
Concentrate outlet rate Kgs/hr ~250-300
Total solids in product feed TDS% 3%
Total solids in Concentrate outlet TDS% 30%
Inlet/outlet temp ˚C 185-200
Concentrate outlet temp ˚C 60-65
Cooling water inlet/outlet temp ˚C 32-40
Operating hours Hrs/day 20
Table 2.14 Estimated characteristic of untreated and treated effluent
Parameters Unit Untreated
effluent-
Process
Treated
effluent
RO
Permeate
MEE
Condensate
pH pH Unit 2.0-4.5 7.0-7.5 7.0-7.5 7.0-7.5
Color Co-Pt Unit 25-45 <15.0 -- --
SS mg/L 450-600 75-100 -- --
TDS mg/L 12750-
13500
8750-9500 450-500 50-100
COD mg/L 3500-4500 1500-2000 <50 <150
BOD mg/L 1200-1500 1000-1250 -- --
Oil & Grease mg/L 15-20 5-10 -- --
Ammonical
Nitrogen
mg/L 35-45 10-15 -- --
2.9.2 Air Pollution Control Measures
Flue gas emission is due to the combustion of fuel Agro briquette in
boiler, Thermic Fluid Heater and Hot Air Generator. Multi Cyclone, bag
filter & water scrubber will be installed as APCM for each flue gas
emission source. To control the process emission, water and alkali
scrubber will be provided. Spin flash dryers (SFD)/Fluid Based Dryer
(FBD)/Rotary Vacuum Dryer (RVD) will be equipped with in-built cyclone
and bag filter. Furthermore, adequate stack height and facility for
sampling such as ladder and sampling point will be provided as per the
GPCB guidelines. The details of stacks with their APC measures are given
in Table 2.8.
Operating hours 20 Hrs/day
Recovery 70 % (approx.)
High pressure piping from SS 316
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-41
Fugitive Emission Control
To control fugitive emission, following steps will be implemented:
Entire process will be carried out in closed reactors.
Pneumatically transfer of liquid raw material in rector.
Raw material will be stored in the covered structure.
Regular maintenance of valves, pipes etc.
PPEs will be provided to the workers.
Frequent work area monitoring will be done ensure fugitive
emissions level.
Greenbelt will be developed around the plant to arrest the fugitive
emission.
2.9.3 Hazardous/Solid Waste Management
Entire quantity of hazardous waste will be handled & disposed as per
Hazardous & Other waste (Management & Transboundary Movement)
Rules, 2016. ETP sludge and MEE salt from wastewater treatment and
Process sludge will be disposed of at approved TSDF site. Spent carbon
and spent catalyst will be returned back to supplier for regeneration.
Distillation residue, off specification products and date expired products
will be sent for co-processing or at CHWIF. Used lubricating oil will be
sold to registered recycler. Discarded Drums & containers/Liners will be
sold to actual users. HCl (20-25%) and Sodium bisulfite (NaHSO3) will be
sold to actual user under Rule-9 of HAZ Rule.
The unit will provide isolated area with impervious flooring & roof cover
for the storage of hazardous waste. Details of hazardous waste disposal
methods are given in Table 2.10.
Fly Ash management
Unit committed to install and operate fly ash brick making unit inside the
plant for fly ash disposal with capacity of 2000 bricks per hour hydraulic
pressure machine for operate once in a week to utilize fly ash to be
generated from burning of Ago briquette in boiler, HAG and TFH. The
criteria of selection of fly ash brick unit is summarized below.
About 80% fly ash will be used for the production of fly ash bricks. The
ratio of Fly Ash (80%) Gypsum (15%) and sand (5%). Based on the
maximum fly ash generation (4.0 TPD), around 2000 per day *26
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-42
=52000 nos /month will be produce. To considering 4 day production per
month (Only Sunday), unit will require 13000 brick per day capacity of
machine. To considering this aspect unit will purchase semi-automatic
machine with capacity of 2000 bricks per hour hydraulic pressure
machine.
2.9.4 Noise Pollution Control Measures
The main noise generating sources in the plant will be boiler, D.G. set,
process plant, vehicular transportation & other machineries. All these
sources will generate continuous noise. However, the noise transmitted
outside the plant boundary will be low because most of the noise
generating equipments will be in closed structures provided with acoustic
enclosure. Equipments will be statically and dynamically balanced. Ear
muff, ear plug will be provided to all workers working at noisy area.
Additionally, extensive oiling, lubrication, periodic monitoring and regular
maintenance will be carried out for the machineries and equipments to
reduce noise generation. Moreover, adequate greenbelt will be developed
within premises and around the periphery to prevent the noise pollution.
By taking measures as mentioned, it is anticipated that noise levels in the
plant will be maintained below the permissible limit.
2.10 RAIN WATER HARVESTING
The rain water from the building roofs will be directed through the
drainage to the covered storm water drainage line. All drainage system
will be concreted lined and located along the roads up to rain water
harvesting pit. Roof top rain water will be collected in tanks and reused
after filtration as per requirements. Additional rain water will be recharge
into water recharging well.
2.11 GREEN BELT DEVELOPMENT
Total land area is 36958 m2. The unit will develop greenbelt in area of
12175 m2. Overall greenbelt area will be tuned around 33% of the total
area of the project.
2.12 OCCUPATIONAL HEALTH & SAFETY
The company is concerned with the health, safety and environment
protection. Following key safety measures shall be a part of the Health &
Safety policy and shall be followed after the project implementation:
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 2-43
Safety Training shall be provided to the employees.
Safety Sirens with Alarm System in case of emergency shall be
provided.
Fire Hydrant System shall be installed.
Fire Extinguishers shall be provided.
Mock drills shall be periodically conducted.
First Aid Facility and training shall be provided.
Personnel protective Equipment shall be provided to the employees.
Health check-ups shall be organized at regular intervals.
Safety/Health records and MSDS shall be maintained.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-1
Chapter-3
Description of Environment
3.1 GENERAL
To assess environmental impacts from proposed project at a specific
location, it is essential to monitor the existing environmental quality
prevailing in the surrounding area prior to implementation of the project.
The environmental status within the impact zone could be used for
identification of significant environmental issues to be addressed in the
impact assessment study. Baseline data generation is a part of the
Environmental Impact Assessment (EIA) study and helps to evaluate the
predicted impacts on the various environmental attributes in the study
area by using scientifically developed and widely accepted impact
assessment methodologies. This section contains the description of
baseline studies of 10 km radius surrounding the project site. The
baseline study was carried out to understand following environmental
parameters.
Land Environment
Meteorology
Air Environment
Water Environment
Soil Environment
Noise Environment
Biological Environment
Socio-economic Environment
The data collected has been used to understand the existing environment
scenario around the project site against which the potential impacts of
the proposed project can be assessed.
3.2 STUDY AREA
The unit is located at Survey no. 504, 505, 507, Village: Dabhasa, Ta.:
Padra, District: Vadodara, Gujarat. An area of 10 km radius from the
boundary of the project site is considered as study area for the EIA study
as per the TOR issued by MoEF&CC.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-2
Table 3.1 Environmental setting of the study area
Name of the Project Reynish Pharmachem Pvt. Ltd.
Proposed production capacity 50 MTPM
Proposed project cost Rs. 40 Crores
Manpower requirement About 65 persons
Location
Survey No. 504, 505, 507
Village Dabhasa
Tehsil Padra
District Vadodara
State Gujarat
Area 36958 m2
Coordinates Latitude: 22°13'32.76"N
Longitude: 73° 1'13.01"E
Nearest
Railway Station Vadodara Railway Station – 19.0 km,
Padra Railway station - 7.0 km
Air Port Vadodara Airport, about 24 km
Town Padra, about 7.0 km
City, District Headquarters Vadodara, about 20 km
National Park/Wildlife Sanctuary None, within 10 km radius
3.3 STUDY PERIOD
Baseline environmental quality represents the background scenario of
various environmental components. As part of EIA study, baseline
environmental monitoring was done over a radial distance of 10 km
around the project site during the period of October, 2018 to
December, 2018.
3.4 SOURCE OF ENVIRONMENTAL DATA GENERATION
Baseline information on micrometeorology, ambient air quality, water
quality, noise level, soil quality and ecology (flora-fauna) are generated
by M/s. San Envirotech Pvt. Ltd., Ahmedabad. Apart from these,
secondary data have been collected from census book, revenue records,
soil survey and forest department, meteorological department etc. The
generation of primary as well as collection of secondary data &
information from the site and surrounding was carried out during the
period of October, 2018 to December, 2018.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-3
3.5 METHODOLOGY
The process & methodology adopted for various environmental attributes
in the study is as follows:
To assess the Air environment in the study area, monitoring of the Air
quality was done by setting up reconnaissance. The samples were
collected by installation of combined sampler (with gaseous
attachment) at different locations for monitoring of primary air
pollutants to work out the existing status of air quality.
Ground water samples & surface water samples were analyzed for the
parameters necessary to determine water quality (based on IS:
10500-2012 criteria) and those which are relevant from the point of
view of environmental impacts of the project site.
Soil samples were collected using an Auger and analyzed for relevant
physico-chemical characteristics in order to assess the impact on soil.
The noise level monitoring was done at various locations at different
intervals of time with the help of sound level meter.
Socio-economic data was collected from field studies and secondary
sources like Census of India 2011, Revenue record, etc.
3.6 LAND ENVIRONMENT
Land Cover is the physical material at the surface of the earth (includes
grass, trees, bare ground, water etc.); whereas Land use is the human
use of land. Studies on land use aspects of eco-system play an important
role in identifying susceptible issues and to take appropriate action to
uphold ecological equilibrium in the region. Main objective is to provide a
baseline status of the study area so that temporal changes due to the
proposed activities on the surroundings can be assessed in future.
3.6.1 Land use pattern of the Study Area
The study area of 10-km around the project site is considered in the land
use pattern study. The term land-use indicates the way in which the land
is utilized for different purposes. The land-use distribution of the study
area is given in Table 3.2. Land-use map is given in Figure 3.1.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-4
Figure 3.1 Land use Map
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-5
Table 3.2 Land use statistics work out based on satellite imaginary
Level 1 Level 2 Area (Sq. km.) Area (%)
Agricultural Crop Land 238.3 75.83
Fallow Land 21.37 6.8
Marsh Land 11.96 3.81
Marsh Vegetation 6.98 2.22
Built-up land
Industrial & Commercial 2.69 0.86
Residential 11.47 3.65
Transportation 5.63 1.79
Waste land Barren land 7.29 2.32
Scrub land 3.92 1.25
Water body Canal 1.08 0.34
Reservoirs /Ponds 2.46 0.77
River 1.12 0.36
Total 314.27 100
3.6.2 Objective of Land Use Studies
The objectives of land use studies are (i) to develop land use & land cover
map using land coordinates of the project area, (ii) to identify and mark
important basic features according primary and secondary data, and (iii)
to suggest measures for conservation and sustainable use of land.
3.6.3 Topography
The site area is plain with little undulating at few places. Agriculture and
allied activities are most predominant in this area. Fallow land and barren
lands were less observed near project site. There was no Eco Fragile Zone
or Natural Forest near project site in study area. Toposheet of location
with site location map of 10 km radius at 1:50,000 scale is shown in
Figure 3.12.
3.6.4 Seismicity of the area
The project site falls under seismic zone III. The Seismic Zone Map of
Gujarat is given below.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-6
3.7 METEOROLOGY
Meteorology is the key to understand the air quality. Wind fluctuations
over a very wide range of time, accomplish dispersion and strongly
influence other processes associated with them. The micrometeorological
conditions at the project site will be regulating the transport and diffusion
of air pollutants released into the atmosphere.
3.7.1 Site specific micro-meteorological data
The data on surface meteorological parameters in the study area were
collected from October, 2018 to December, 2018, by setting up
portable weather monitoring station placed at project site. The sensor of
the equipment was kept at sufficient height (about 10 m) from ground
level with free exposure to the atmosphere. The monitoring methodology
is given in Table 3.3 & data collected are presented in Table 3.4.
The following parameters were recorded at hourly intervals during
monitoring period:
• Wind speed & Wind direction
• Temperature
• Relative humidity
• Rainfall
Table 3.3: Monitoring Methodology of Meteorological Data
Sr.
No.
Sampling
Parameters
Sample Collection Total
Sampling
Period
Sampling
Frequency
Methodology
Sampling
Equipment
Sensitivity/
Detection
Limit
1 Wind Speed Anemometer
cup counter
(0 to 65 m/s)
0.25 m/s October,
2018 to
December,
2018
Hourly As per
manufacturer‟s
manual,
Instruments
are
Calibrated
2 Wind
Direction
Wind vane
(0° to 357°)
10
3 Temperature Thermometer
(-40° to 60°)
0.10C
4 Humidity Hygrometer 3%
5 Rainfall Rain gauge 0.5 mm
6 Cloud Cover -- -- 4 Hourly Visual
Inspection by
the observer
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Table 3.4: Meteorological Data for the Monitoring Period
(October, 2018 to December, 2018)
Month Wind
speed
(km/hr.)
Pre
dominant
wind
direction
Temp. (0C) Relative
Humidity
(%)
Rain fall (mm)
Max Min Max Min Max Min 24 hrs.
highest
No. of
rainy days
Oct‟18 21.4 0.0 E 39 26 87 20 No rainfall during
the study period Nov‟18 17.5 0.0 NE 38 20 40 16
Dec‟18 25.1 0.0 E 37 17 53 14
3.7.2 Wind Rose
Wind rose is the diagrammatic representation of wind speed in a specified
direction with its arms representing sixteen directions, each arms give a
clear frequency distribution of wind speed in a particular direction for a
given period of time. It is one of the most important meteorological
parameters and governs dispersion; diffusion & transportation of
pollutants. The % frequencies of wind in 16 directions have been
computed from the recorded data during the study period for 24-hourly
intervals to plot wind rose. The predominant wind directions – NNE, NE,
ENE, E; implying that winds come from these directions for most of the
time during the period. The wind speed class 1-5 kmph occurred for
3.99%, 6-10 kmph about 25.18%, 11-15 kmph 48.1% and above 15
kmph and below 40 kmph occurred for 10.05 % of the study period. Calm
wind during this period is 12.68 %.Wind rose diagram is shown as Figure
3.8.
3.8 AMBIENT AIR QUALITY
3.8.1 Introduction
To quantify the impact of the proposed project on the ambient air quality,
it is necessary to evaluate the existing ambient air quality of the area.
The ambient air quality monitoring with respect to the study area of 10
km radius around the project site was done for the baseline information.
3.8.2 Design Network for Ambient Air Quality Monitoring Stations
The baseline status of the ambient air quality has been assessed through
a scientifically designed ambient air quality monitoring network. The
design of monitoring network is based on the following considerations:
Topography/Terrain of the study area
Populated areas within the region
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Prediction of maximum concentrations and distances of their likely
occurrence under prevailing meteorological conditions
Representation of regional background
Representatives of likely impact areas
Ambient Air Quality Monitoring (AAQM) stations were placed at eight
locations with due consideration to the above mentioned points.
3.8.3 Reconnaissance
Reconnaissance was undertaken to establish the baseline status of air
environment in the study region. The prime objective of the NAAQ
survey, within 10 km radial study area around the proposed project, was
to establish the existing ambient air quality levels. The monitoring
locations (relative directions and distances) are given in Table 3.11 &
shown in Figure 3.7 and results are given in Table 3.12 to 3.17.
3.8.4 Parameters, Frequency and monitoring Methodology
The existing ambient air quality, in terms of Particulate Matter-10 (PM10),
Particulate Matter-2.5 (PM2.5), Sulphur Dioxide (SO2), Oxides of Nitrogen
(NOx), Carbon Monoxide (CO), Hydrocarbons (HC), Volatile Organic
Compounds (VOCs), Hydrochloric acid (HCl) has been measured. It was
ensured that, the equipment was placed at open space free from any
obstacles at a height of at least 3 to 4 m above the ground level at each
monitoring station to avoid the effects of wind-blown ground dust.
Monitoring has been carried out as per the latest CPCB and MoEF & CC
guidelines and notifications. Details of methodology are given in Table
3.5.
Table 3.5 Methodology of Ambient Air Monitoring
Sampling
Parameters
Instrument used Analytical
equipment
Detection
Limit
Test method
PM10 Combined Sampler
(GTI-241)
Electronic Balance 1 μg/m3 Gravimetric IS: 5182
(Part 23) 2006
PM2.5 Combined Sampler
(GTI-241)
Electronic Balance 1 μg/m3 Gravimetric CPCB
Guidelines for Ambient
Air Monitoring
SO2 Gaseous flow
attachment with
Combined sampler
Spectro Photometer 2.5 μg/m3 Colorimetric IS: 5182:
(Part II) 2001
NOx Gaseous flow
attachment with
combined sampler
Spectro Photometer 6.0 μg/m3 Colorimetric IS: 5182:
(Part VI) 2006
HCl Gaseous flow
attachment with
Titrimetric 1 μg/m3 Titrimetric
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combined sampler
CO Bladder & Pump Gas Chromatograph 1 ppm Gas Chromatography
HC Bladder & Pump Gas Chromatograph 1 ppm Gas Chromatography
VOC Bladder & Pump Gas Chromatograph 1 ppm Gas Chromatography
The duration of sampling of PM2.5, PM10, SO2 & NOx was 24-hourly
continuous sampling per day and CO, HC (Methane & non-Methane), VOCs
(benzene, Toluene & Xylene) & HCl were sampled for 8-hours duration. The
monitoring was done for twice a week for three months. Parameters and
frequency of sampling is given in Table 3.6.
Table 3.6 Monitored Parameters and Frequency of Sampling
Parameters Sampling frequency
Fine Particulate Matter (PM2.5) 24 hourly sample twice a week for three months
Respirable Particulate Matter
(PM10)
24 hourly sample twice a week for three months
Sulphur dioxide (SO2) 24 hourly sample twice a week for three months
Oxides of Nitrogen (NOx) 24 hourly sample twice a week for three months
Hydrochloric acid (HCl) 8 hourly sampling
Carbon Monoxide (CO) 8 hourly sampling
Hydro Carbon (HC) 8 hourly sampling
Volatile Organic Compounds
(VOCs)
8 hourly sampling
3.8.5 Interpretation of result
The existing baseline levels with respect to PM10, PM2.5, SO2, NOX, HCl,
CO, VOCs and HC are tabulated in Tables 3.13 to 3.17 & chart is given
as Figure 3.2 to 3.6.
Particulate Matter (PM10)
An average and 98th percentile value of 24-hourly PM10 values at all the
locations are found from 63.7-71.0 g/m3 and 63.7-68.8 g/m3. The
results were found well within the National Ambient Air Quality Standards
(NAAQS-CPCB) of 100 g/m3.
Particulate Matter (PM2.5)
An average and 98th percentile value of 24-hourly PM2.5 values at all the
locations ranges from 37.0– 48.0 g/m3 and 41.4-50.0 g/m3. The values
are well within National Ambient Air Quality Standards (NAAQS-CPCB) of
60 g/m3.
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Sulphur Dioxide (SO2)
An average and 98th percentile value of 24-hourly SO2 value of arithmetic
mean at all the locations ranged from 13.0 – 16.3 g/m3 and 15.8 – 20.8
g/m3 respectively, which are well below National Ambient Air Quality
Standards (NAAQS-CPCB) of 80 g/m3.
Oxides of Nitrogen (NOx)
An average and 98th percentile value of 24 hourly NOx value of arithmetic
mean at all the locations ranged from 15.8-18.1 g/m3 and 19.7-23.6
g/m3 respectively, which are well below the National Ambient Air Quality
Standards (NAAQS-CPCB) of 80 g/m3.
Hydrochloric acid (HCl)
HCl found below detectable limit at all the locations.
Carbon Monoxide (CO)
Minimum & Maximum value of CO at all the locations ranged from 1024 –
1182 g/m3.
Hydro Carbon (HC)
Minimum & Maximum value of Methane HC at all the locations ranged
from 32.2-41.1 g/m3 & non-methane HC ranged from 1028-1185 g/m3.
Volatile Organic Compounds (VOCs)
Minimum & Maximum value of VOC at all the locations ranged from 0.27
g/m3 – 3.41 g/m3.
3.9 WATER ENVIRONMENT
3.9.1 Geology
The rocks of the Vadodara district shows an age from Proterozoic to
Recent but a striking features of the district stratigraphy is the total
absence of Paleozoic, and the development of only the uppermost
Mesozoic rocks. The south westerly extended Precambrian basement of
Peninsular India, the oldest rocks of Proterozoic age, are exposed in
eastern and north eastern part of the district. Post Cretaceous sediments
& major volcanic rocks rest over this south westerly extended
Precambrian basement. Post Cretaceous sediments, Infratrappean and
Intratrappean are exposed as scattered inliers while younger volcanic
rocks unit as Deccan trap is well represented and so are the Tertiary and
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Quaternary, though the Tertiary records are not complete and fully
exposed.
3.9.2 Hydrogeology
In Vadodara district area, groundwater occurs both as unconfined and
confined conditions. Saturated zones of unconsolidated shallow alluvium
and weathered zones, shallow depth jointed and fractured rocks forms
unconfined aquifers, whereas multilayered aquifer below impervious clay
horizons in alluvium formation and interflow zones of basalts, inter-
trappean beds, deep seated fracture zones, shear zones in basalts,
granites and gneisses give rise to semi confined to confined conditions.
Generally the water table follows topographic configuration. The depth to
water is greater in upland areas whereas in valley portion and shallow
grounds, the levels are very close to surface. In hilly terrain of eastern,
north- east and south-east part of the district, spring zones are seen in
stream river section; also along the section of the Mahi, the Narmada and
the Orsang rivers. The piezometric surface, mainly in alluvium areas of
western half the district also follows the gentle gradient corresponding to
subsurface configuration of deep aquifer zones.
In major part of the district, in north and almost in eastern half of the
district, the hard rocks, such as phyllite, schist, granite, gneiss, basalt
and other sediments such as sandstone, limestone etc., form aquifers,
whereas multilayered alluvium deposits form aquifer system in remaining
central, south-central and western half of the district. The weathered
basalts, granite, gneiss etc., covered by soil and the valley fill & piedmont
deposits forms potential aquifer in the vicinity of rivers and on vast
undulating plains adjacent to hilly terrain but their regional continuity and
extent are limited due to heterogeneous nature of deposits with limited
thickness and as such rarely exceed a few square kilometers. Map
showing general hydrogeology of the district is given as figure below.
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Groundwater Condition
As per the GWRDC ground water estimation the Padra Taluka falls in Safe
(White) category.
3.10 WATER QUALITY
3.10.1 Introduction
Water quality assessment is one of the essential components of EIA
study. Such assessment helps in evaluating the existing health of water
body and suggesting appropriate mitigation measures to minimize the
potential impact from development projects. The water quality at the site
and other locations within the 10-km impact zone was monitored during
the study period. The purpose of the study is to:
Assess the water quality characteristics for critical parameters;
Evaluate the impact on agricultural productivity, habitat conditions
recreational resources and aesthetics in the vicinity; and
Predict the likely impacts on water quality due to the project and
related activities.
Reconnaissance survey was undertaken and monitoring locations were
finalized based on:
Location of residential areas representing different activities/likely
impact areas; and
Likely areas, which can represent baseline conditions.
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3.10.2 Sampling Frequency, Techniques & Methodology
Eight surface water and eight groundwater samples were collected during
the study period. Ground water samples were collected from the existing
bore wells, while surface water was collected from ponds by surface
water sampler. These samples were taken as grab samples. Necessary
precautions were taken for preservation of samples. Sampling locations
with source & date of sampling is given in Table 3.7.
The samples collection procedure was adopted from „Standard Methods‟
for the examination of Water and Wastewater published by American
Public Health Association (APHA) and IS 10500-2012.The samples were
analyzed for Physico-chemical parameters to assess the existing water
quality of the area (based on IS: 10500-2012 & APHA/AWWA, 23rd
edition). The water sampling locations marked within the study area and
the result of the analysis (ground water and surface water) is presented
in the Figure 3.9 & Table 3.19 & 3.20 respectively.
Table 3.7 Sampling locations with source & date of sampling
Ground Water Sampling Locations
Sample
Code
Location Coordinates Date of
Sampling
Taluka District
GW1 Project Site 22°13'32.76"N
73° 1'13.01"E
18/12/2018 Padra Vadodara
GW2 Dabhasa 22° 14' 19.54" N
73° 1' 31.97" E
18/12/2018 Padra Vadodara
GW3 Padra 22° 15' 12.83" N
73° 4' 30.43" E
18/12/2018 Padra Vadodara
GW4 Umaraya 22° 15' 42.29" N
73° 1' 50.55" E
18/12/2018 Padra Vadodara
GW5 Dhobikuwa 22° 13' 13.63" N
72° 59' 29.52" E
19/12/2018 Padra Vadodara
GW6 Ranu 22° 13' 19.73" N
73° 1' 8.66" E
19/12/2018 Padra Vadodara
GW7 Bhoj 22° 11' 47.11" N
72° 59' 56.27" E
19/12/2018 Padra Vadodara
GW8 Vishrampura 22° 11' 47.11" N
72° 58' 22.85" E
19/12/2018 Padra Vadodara
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Surface Water Sampling Locations
Sample Code
Location Coordinates Date of Sampling
SW1 Dabhasa Pond 22°14'52.50"N, 73° 2'12.87"E 18/12/2018
SW2 Padra Pond 22°14'29.47"N, 73° 4'59.38"E 18/12/2018
SW3 Bhoj Pond 22°11'57.70"N, 73° 0'16.22"E 19/12/2018
SW4 Ranu Pond 22°12'36.72"N, 73° 1'19.35"E 19/12/2018
SW5 Luna Pond 22°15'47.48"N, 73° 2'50.25"E 19/12/2018
SW6 Dabka Pond 22°14'50.41"N, 72°57'34.74"E 18/12/2018
SW7 Tajpura Pond 22°15'32.56"N, 73° 4'14.73"E 18/12/2018
SW8 Mahi River 22°15'35.19"N, 72°59'38.49"E 19/12/2018
3.10.3 Surface Water Quality (Primary data)
Surface water samples were collected from ponds of Dabhasa, Padra,
Bhoj, Ranu, Luna, Dabka, Tajpur village, and Mahi River. Analysis of the
same is given in Table 3.20. The results have been compared with the
drinking water quality standards specified in IS: 10500-2012. It was
observed that all the physico-chemical parameters and heavy metals
from surface water samples except turbidity are below stipulated drinking
water standards and are suitable for domestic purposes.
3.10.4 Ground Water Quality
The results of the ground water quality monitored during the study period
are given in Table 3.19.
3.10.5 Interpretation
The samples were taken as grab samples and analyzed for various
parameters of ground water. Sampling location is shown in Figure 3.9.
Color: All the samples were found color less meeting desirable norms.
pH: All the samples meet the desirable standards (pH ranges from 7.3-
7.9).
Total Dissolved Solids (TDS): TDS in samples ranges from 1092 mg/L
(Nr. Project Site) to 1923 mg/L (Umaraya). The entire samples meet the
permissible limit of 2000 mg/L TDS.
Calcium: Calcium contents in the water ranges from 44 mg/L
(Dhobikuwa) to 92 mg/L (Umaraya), all the samples meet the permissible
limit of 200 mg/L, (Permissible Limit in the Absence of Alternate Source).
Magnesium: Magnesium content in the water ranges from 40 mg/L
(Bhoj) to 59 mg/L (Dhobikuwa). All the samples meet the permissible
limit of 100 mg/L (Permissible Limit in the Absence of Alternate Source).
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Sulfate: Sulfate content in the water ranges from 58 mg/L (Nr. Project
Site) to 116 mg/L (Dabhasa). All the samples meet the permissible limit
of 400 mg/L(Permissible Limit in the Absence of Alternate Source).
Fluoride: Fluoride content in the water ranges from 0.56 mg/L
(Vishrampura) to 0.70 mg/L (Dhobikuwa). All the samples meet the
permissible limit of 1.5 mg/L (Permissible Limit in the Absence of
Alternate Source).
Total Alkalinity: Total alkalinity in the water samples ranges from 308
mg/L (Dabhasa) to 346 mg/L (Padra). All the samples are within the
permissible limit of 600 mg/L (Permissible Limit in the Absence of
Alternate Source).
Other Parameters: Potassium (ranges from 43 mg/L to 68 mg/L),
Sodium (ranges from 323 mg/L to 592 mg/L) and Chloride (ranges from
512 mg/L to 935 mg/L). All the samples meet permissible limit in the
absence of alternate source.
Heavy metals like cadmium, copper, lead, chromium, iron and zinc are
well below the limit in all samples.
3.10.6 Conclusion
The results have been compared with the drinking water quality
standards specified in IS: 10500-2012 & all parameters meet the
permissible limit set by the authority (BIS). Indian Standard specification
for drinking water is given in Table 3.21.
3.11 NOISE ENVIRONMENT
Noise can be defined as an unwanted sound. The definition of noise as
unwanted sound implies that it has an adverse effect on human beings
and their environment. The noise level variation can be temporal, spatial.
It interferes with speech and hearing and is intense enough to damage
hearing or is otherwise annoying. Noise can also disturb natural wildlife
and ecological system. It is therefore, necessary to measure both the
quality as well as the quantity of noise in and around the proposed site.
3.11.1 Instrument used for Sampling and Monitoring
The intensity of sound energy in the environment is measured in a
logarithmic scale and is expressed in a decibel, dB(A) scale. Sound Level
Meter (SLM) is used for the collection of data at an interval of one hour.
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The day noise levels have been monitored during 6:00 am to 10:00 pm
and night noise levels during 10:00 pm to 6:00 am at all locations. Noise
levels recorded at each station are computed for equivalent noise levels.
Noise monitoring methodology is given in below Table 3.8.
Table 3.8 Monitoring Methodology of Noise
Environment Component
Sampling Location
Test method Instrument used
Make
Ambient Noise level
09 Locations
As per manufacturers Manual
Sound Level Meter
Mextech-SL-4012
3.11.2 Noise Quality Monitoring Locations
The noise survey was conducted to assess the background noise levels in
different zones. Based on the Gazettes Notification (S.O. 123(E)) of MoEF
dated February 14, 2000 on ambient air quality standards, 9 monitoring
locations were selected. Noise level measurements have been made using
Sound Level Meter. The noise monitoring locations & its results are given
in Figure 3.10 & Table 3.22 respectively.
3.11.3 Ambient Noise Standards
Ministry of Environment & Forests (MoEF) has notified the noise
standards vide Gazette Notification dated February 14, 2000 for different
zones viz. industrial, commercial, residential and silence zones under the
Environment Protection Act (1986). These standards are given in Table-
3.23.
3.11.4 Results
The noise levels of various locations are given in Table 3.22. The
monitored noise level in the day time Leq (Ld) varies from 50.7 to 53.7
dB(A) and the night time Leq (Ln) varies from 39.2 to 43.4 dB(A) within
the study area. Higher noise value of 53.7 dB(A) was recorded during day
time at Village 1000 m East from the site & lower noise value of 40.1
dB(A) was recorded during night time at 500 m North from the site.
3.11.5 Conclusion
Based on the observations made during the studies, it is concluded that;
the noise levels recorded at various locations in the study area show
considerable fluctuations because of changes in traffic movement,
commercial and other domestic activities in the study area. Overall the
ambient noise level in the monitored locations was found to be within the
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permissible limits stipulated for residential, industrial areas, silence and
commercial zone.
3.12 SOIL ENVIRONMENT
Soils may be defined as a thin layer of earth‟s crust that serves as a
natural medium for the growth of plants. It is the unconsolidated mineral
matter that has been subjected to and influenced by genetic and
environmental factors. Soils serve as a reservoir of nutrients for plants
and crops and also provide mechanical anchorage and favorable tilth.
The objective of the soil sampling is:
To determine the baseline soil characteristics;
To monitor the impact on soil (pollutant deposition/other) in long
run.
The soils of Vadodara district can be broadly classified into three groups.
They are black soils, alluvial soils and hilly soils. Soil map of the district is
given below.
The above mentioned data has been sourced from District Groundwater
Brochure Vadodara District Gujarat
3.12.1 Soil sampling locations
Soil quality of the study area is one of the important components for
environment impact assessment. The composite soil samples were
collected from the study area from eight locations (Project site, Dabhasa,
Padra, Umaraya, Dhobikuwa, Ranu, Bhoj and Vishrampura) and were
analyzed for different parameters. The location of the monitoring is given
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below in Table 3.9. Results are given in Table 3.24 and depicted in
Figure 3.11.
Table 3.9 Location of soil sampling
Sample
Code
Locations Coordinates Date of
sampling
Tehsil District
S1 Project Site
22°13'35.86"N 73° 1'14.67"E
18/12/2018 Padra Vadodara
S2 Dabhasa 22°14'26.55"N 73° 1'28.67"E
18/12/2018 Padra Vadodara
S3 Padra
22°15'9.75"N
73° 4'19.69"E
18/12/2018 Padra Vadodara
S4 Umaraya 22° 15' 43.56" N 73° 1' 49.41" E
18/12/2018 Padra Vadodara
S5 Dhobikuwa 22° 13' 16.24" N 72° 59' 26.19" E
19/12/2018 Padra Vadodara
S6 Ranu 22° 13' 20.09" N
73° 1' 8.91" E
19/12/2018 Padra Vadodara
S7 Bhoj
22° 12' 2.67" N 72° 59' 56.13" E
19/12/2018 Padra Vadodara
S8 Vishrampura 22° 11' 47.01" N 72° 58' 22.26" E
19/12/2018 Padra Vadodara
3.12.2 Methodology
To understand the soil quality of the study area, analysis of all eight
locations including the project site was conducted by making suspension
of soil sample. The samples were examined for various physical and
chemical characteristics in order to assess the impact on soil. Analysis
was done by using following methodology.
Table 3.10 Methodology of Soil Sample analysis
Sampling
Parameters
Sample
collection
Analytical
Equipment
Methodology Remarks
Porosity
Manual
sample
Collection in
polyethylene
bags using
an Auger
- IS: 2720 Part 7 Trial pit
method
for topsoil
sample
collection;
disturbed
samples
Water holding
capacity
- -
Permeability - IS: 2720 Part 17
Moisture content Electronic Balance IS: 2720 Part 2
Texture - IS: 2720 Part 4
Particle size
Distribution
Glass wares IS: 2720 Part 4 5% Leachate
to
be made and
analyzed as
per
APHA,
“Standard
Methods”
All method
numbers are
as
Cation Exchange
Capacity
Centrifuge IS: 2720 Part 24
(1976)
SAR F. Photometer
(Na, K)
Titration (Ca & Mg)
Calculation
pH pH Meter 4500 H+B
Electrical
Conductivity
Conductivity Meter As per IS 14767 -
2000
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Calcium Glass wares 3500 Ca B per APHA
“Standard
Methods”
(23rdedition)
Magnesium Glass wares 3500 Mg B
Sodium (Na) Flame Photometer 3500 Na B
Potassium Flame Photometer 3500 K B
3.12.3 Corollaries
Physical Parameters
Particle Size: A Particle size of the different constituents (clay, silt, sand
and gravel) controls the porosity and water holding characteristic of the
soil. Clay (size<0.002 mm) amount in the soil samples ranges from 16 %
to 24 %; Silt (size 0.002 to 0.075 mm) in the soil samples is 21 % to 32
% and Sand (size 0.075 to 0.475 mm) in the soil samples is 24 % to 33
%, while Gravel (size>4.75 mm) in the soil samples is 20% to 26%.
Analysis shows that the soil has moderate water holding capacity.
Porosity: Porosity is a measure of space in between soil particles caused
by structural conditions and determined under identical conditions.
Porosity of soil samples of the study area ranges from 40.3 % to 43.7%.
Water Holding Capacity (WHC): Water Holding Capacity (WHC) of soil
samples of the study area ranges from 40.3% to 42.1%.
Bulk Density: Bulk Density of soils in the study area is found to be in the
range from 1.39 to 1.46 g/cm3.
Chemical Parameters
pH: pH of soils in the study area is found to be in the range of 7.2 to 7.9.
Chloride: Chloride content in soils of the study area is found to be in the
range of 622 to 898 mg/kg.
Soluble Calcium: The soluble calcium as CaCO3 in soil samples is found
to be in the range of 363 to 797 mg/kg.
Magnesium: Magnesium content in soil samples of the study area ranges
from 202 to 720 mg/kg.
Total Phosphorus: Available Phosphorus content in soil samples of the
study area ranges from 36 to 188 mg/kg.
Total Nitrogen: Available nitrogen content in soil samples of the study
area is found to be in the range from 9 to 282 mg/kg.
Potassium: Potassium content in soil samples of the study area is found
to be in the range from 126 to 185 mg/kg.
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Sodium: Sodium content in soil samples of the study area is found to be
in the range from 510 to 692 mg/kg.
Total Organic Matter (TOM): Total organic matter content in soil
samples of the study area is found to be in the range of 1.85 to 4.95
mg/kg.
3.12.4 Conclusion
In the study area, variations in the pH value ranging from 7.2 to 7.9
which shows that the soil is slightly alkaline in nature. Organic Matter
ranges from 1.85 to 4.95 mg/kg in the soil samples. Soil of the study
area is known to be good for cultivation. Generally, soils with low bulk
density have favorable physical conditions (porosity and permeability)
whereas those with high bulk density exhibit poor physical conditions for
agriculture crops.
3.13 BIOLOGICAL ENVIRONMENT
An ecological study of the ecosystem is essential to understand the
impact of industrialization and urbanization on existing flora and fauna of
the study area. The biological study was undertaken as a part of the EIA
study report to:
Understand the present status of ecosystem prevailing in the study
area.
Compare it with past condition with the help of available data.
Predict changes in the biological environment as a result of present
activities and to suggest measures for maintaining its health.
The survey was conducted to study the flora & fauna in 10 km radius.
Some of the information was gathered from the local habitants. All the
collected data were classified to interpret the impact of pollution.
3.13.1 Period of the study
The baseline study, for the assessment of the floral and faunal
biodiversity of the terrestrial environment, within 10 km radius from the
site was conducted during October, 2018 to December, 2018.
3.13.2 Study methodology
Survey methodology was based on the flora & fauna species identification
in person, recently recorded and found in the region by the localities.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-21
Sampling of grass species was carried out by quadrat sampling method to
examine the species distribution and its frequency in the region.
Quadrate Sampling Method:
A quadrat (or plot-based) survey is a quantitative examination of species
distribution & abundance. Quadrats are more likely to detect
inconspicuous species because a smaller area is sampled in a
concentrated search. The survey was carried out for the vegetation
ground cover found in the road edges by 1 m2 quadrat and study on the
edge effect due to rapid industrialization and urbanization.
3.13.3 Floral species in the study area
Flora is basically the plant life that is present in a particular region or
habitat at a particular time. List of flora found in the study area is
tabulated in Table 3.25.
3.13.4 Fauna in the study area
Fauna is the animal life that is present in a particular region or habitat at
a particular time. Irrespective of its unfriendly terrain, Gujarat gives
shelter to a variety of animals and birds. They live in smaller herds and
thrive mainly on wild grasses and various types of shrubs. Faunal
biodiversity with their scientific names and common names is presented
in Table 3.26.
Schedule – I Bird Species
Protection Status:
As per IUCN: Pavo cristatus is Classified as Least Concern (LC) on the
IUCN Red List (1) and listed on Appendix II of CITES 3.
Population Trend: Stable
Habitat: Terrestrial
Habitat Type: Forest, Scrubland, Artificial/Terrestrial
Generation Length in Year: 6.1
Movement Patterns: Non Migrant
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-22
Indian Peafowl (Pavo cristatus)
Scientific classification
Kingdom: Animalia
Phylum: Chordata
Class: Aves
Order: Galliformes
Family: Phasianidae
Genus: Pavo
Species: Pavocristatus
Common Name: Indian Peafowl
Vernacular Name: Mor
No peacock was sighted in the project site. All the direct sightings of the
peacock were located near the human habitats, villages and agriculture
field, of study area. This species is well adapted to natural village
environment setting. Day time they temporarily move towards the
surrounding agriculture areas for feeding while during night time they
roost on the trees present in the village and in the agriculture hedges.
Since Indian Peafowl is a ground nester, several project activities can
have adverse Impact on their nesting grounds such as pollution,
degradation of soil and vegetation from surrounding area and in the
forest areas. Direct disturbance by presence of people, vehicle their
noise, vibration, light etc. can potentially disturb most of the bird species.
Threats in the Study Area:
No perceptible threats were identified in the study region, as
Village residents are against hunting or poaching of the peafowl, due
to culture and mythology reasons.
Majority villagers follow Hinduism in the region, thus they have high
respect towards peacocks due to mythological reasons, and
Literacy levels are greater than 80% in the study region and people
are aware with the significance of the peacock as the national bird.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-23
3.14 SOCIO-ECONOMIC ENVIRONMENT
An essential part of environmental study is socio-economic environment
incorporating various facts related to socio-economic conditions in the
area, which deals with the total environment. Socio economic study
includes demographic structure of the area, provision of basic amenities
viz., housing, education, health and medical services, occupation, water
supply, sanitation, communication, transportation as well as feature of
aesthetic significance such as temples, historical monuments etc. at the
baseline level. This would help in visualizing and predicting the possible
impact depending upon the nature and magnitude of the project. Socio-
economic study of an area provides a good opportunity to assess the
socio-economic conditions of an area. This study will possibly make a
change in living and social standards of the particular area benefitted due
to the project. It can undoubtedly be said that this unit will provide direct
and indirect employment and improve the infrastructural facilities and
standards of living of the area.
3.14.1 Objective of the study
The objectives of this socio-economic report consist of:
To conduct socio-economic assessment study in lease Area
To help in providing better living standards.
To know the current socio-economic situation in the region to cover
the sub sectors of education, health, sanitation, water and food.
To provide employment opportunities.
3.14.2 Land use pattern and infrastructure
The land use pattern indicates the manner in which different parts of land
in an area is being utilized or non-utilized. It is an important indicator of
environmental health; human activity and a degree of inter play between
these two. Even though the soil quality, water availability and climate
have strong influence on agriculture and vegetation, the human activity
may alter the natural environment to a large extent to suit human needs.
Unnatural land use often triggers rapid environmental deterioration and
disturbs ecological balance. In census records, major land use
classifications are; Forests, Culturable land, Culturable wasteland and
area not available for cultivation. Culturable land is further classified as:
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-24
irrigated and unirrigated. Area not available for cultivation includes lands
put to non-agriculture uses as well as barren and uncultivable lands.
The main land use in area is for dwellings, infrastructure and related
activities. However, the land use pattern for rural areas is discussed
below. The information is preliminary based on 2011 Census as depicting
in Table 3.28. Total land area is 32540.2 ha, out of that Irrigated area is
16487.3 ha. It constitutes 50.66% of the total land area. 8613.9 ha are
un-irrigated by source and it constitutes 26.47% of total land area. The
study area consist of Cultivable wasteland is 757 ha (2.32%). Area not
available for cultivation is 1549.4 ha & it constitute 4.76%.
3.14.3 Demographic and Socio-Economic Environment
The demographic and Socio-economic details of the study area are
discussed below. These are primarily based on census data of 2011. Data
on number of households, population as well as literacy and employment
pattern in the study area have been presented in Table 3.29. The
employment pattern in the area is indicator of number of persons
employed in various sectors. It also indicates the various categories of
employment flourishing in the area. The Study area in 10 km radius has
53 villages including project site. The total no. of household in the
villages are 37970 and the total population is 185899 (52.16% men &
47.84% women). 70.41% of are literate while literacy rate among women
& men is 62.90% & 77.31% respectively. 54.30% of male population is
part of main worker, while only 12.25% of female population is a part of
main workers. 4.37% of male workers are marginal workers, while 9.55%
of female workers are engaged in such type of activities. 41.33% of male
population and 78.19% of female population are non-workers.
3.14.4 Living Standard and Infrastructure
In India it is not possible to setup a primary standard of living because of
wide variations in terms of income, economic conditions, social custom,
employment opportunity, pattern of spending, etc. However, availability
of amenities like education, medical, water supply, communication, road
network, electricity, etc. significantly reflects the level of development of
the area. Information on available amenities in the study area has been
extracted from census record of 2011. Total numbers of village in study
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-25
area are 53. On the basis of data presented in the Table 3.30, the status
of available amenities is discussed in following sub-sections:
Educational Facilities
As per 2011 census, there are primary school in all 53 villages, 31 Pre-
primary school, 50 Secondary schools, 34 Senior Secondary schools, and
27 Arts, Science and Commerce College.
Medical Facilities
53 villages in the study area have 46 primary health centers, 50 primary
health sub centers, 44 Maternity & Child Welfare Centre, 28 T.B Clinic, 42
Dispensaries, 45 Veterinary hospital, and 40 Family welfare center in
study area of 10 km.
Drinking Water Supply
All the 53 villages in the study area have two or more sources of drinking
water. Most of the villages in study area have tube well water supply in
addition to Tap water (almost all). Moreover all villages have facility of
well water and some villages have hand pump, river and tank water, tube
well or other facilities for water.
Communication and Transport
The main mode of public transport available in the study area is by bus
service. 35 villages have approach to railway station as western railway
meter gauge line is passing through nearby. All of villages in the study
area are connected with pucca road & kutccha road. 47 villages have
water bound macadam facilities, 44 villages are connected with the State
highways and 29 villages are connected with the national highways.
Post and Telegraph
As per 2011 census record out of 53 villages in study area, almost all the
villages have phone facility at doorstep & post office facility. Villages have
facility of Public Call Office service at door step.
Power Supply
As per 2011 census record almost all the villages are getting power
supply for all purposes.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-26
Table 3.11: Ambient Air Quality Monitoring Locations
(Monitoring Period: 1st October, 2018 to 29th December, 2018)
Sr.
No.
Sampling
Location
Direction
w.r.t project
site
Address &
Geographical location
Distance
in km
Type of
Area
1 Project Site
(A1)
-- 22°13'35.86"N
73° 1'14.67"E
0.0 Industrial
2 Dabhasa
(A2)
NNE(UW) Tarak Patel
22°14'26.55"N
73° 1'28.67"E
1.57 Residential
3 Padra (A3) ENE(UW) Parul Patel,
Ujambag, Padra-
Tajpura Road
22°15'9.75"N
73° 4'19.69"E
6.11 Residential
4 Umaraya
(A4)
NNE(UW) Pyarelal Virubhai
22°15'43.56"N
73°1'49.41"E
4.16 Residential
5 Dhobikuwa
(A5)
WSW(DW) Sagabhai Parmar
22°13'16.24"N
72°59'26.19"E
3.10 Residential
6 Ranu (A6) SSW(DW) Jivanbhai Patel
22°13'20.09"N
73°1'8.91"E
0.45 Residential
7 Bhoj (A7) SW(DW) Narshinhbhai
Valand
22°12'2.67"N
72°59'56.13"E
3.56 Residential
8 Vishrampura
(A8)
SW(DW) Ashokbhai Patel
22°11'47.01"N
72°58'22.26"E
5.88 Residential
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-27
Table 3.12: Ambient Air Quality Status
(Monitoring Period: 1st October, 2018 to 29th December, 2018)
Sr.
No.
Sampling
Station
PM10
(g/m3)
PM2.5
(g/m3)
SO2
(g/m3)
NOx
(g/m3)
Average (Min-Max)
1 Project Site (A1) 67.9
(59.9-74.0)
39.9
(35.0-44.5)
15.5
(12.5-18.0)
18.1
(14.4-21.4)
2 Dabhasa (A2) 70.7
(63.7-82.2)
39.8
(28.9-45.8)
15.1
(13.0-17.6)
17.8
(13.5-21.0)
3 Padra (A3) 67.2
(54.3-74.8)
37.0
(29.4-42.7)
13.7
(10.8-15.8)
16.9
(13.3-20.7)
4 Umaraya (A4) 67.1
(59.0-76.3)
41.8
(34.6-51.2)
16.3
(12.9-19.2)
17.4
(14.4-22.2)
5 Dhobikuwa (A5) 71.0
(64.3-76.2)
37.3
(29.4-44.0)
13.6
(11.2-15.9)
16.0
(12.4-20.5)
6 Ranu (A6) 68.9
(61.3-76.0)
37.6
(31.7-47.1)
13.0
(10.2-18.3)
15.8
(11.6-23.1)
7 Bhoj (A7) 69.6
(61.9-77.7)
41.1
(35.2-49.3)
13.8
(11.4-16.9)
15.8
(13.7-20.8)
8 Vishrampura (A8)
70.7
(66.2-76.6)
39.5
(34.3-45.4)
14.9
(11.5-24.2)
16.7
(13.1-26.5)
Figure 3.2 Graphical representation of Ambient Air Quality
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-28
Table 3.13: Ambient Air Quality Status (PM10)
(Monitoring Period: 1st October, 2018 to 29th December, 2018)
Average-24 Hours Unit-g/m3
Station Name Max Min 98th
Percentile
75th
Percentile
50th
Percentile
25th
percentile
Avg. SD
Project Site(A1) 74.0 59.9 73.3 70.9 68.3 66.0 67.9 3.9
Dabhasa(A2) 82.2 63.7 81.2 75.4 71.1 65.3 70.7 5.6
Padra (A3) 74.8 54.3 74.7 71.8 68.1 63.7 67.2 5.6
Umaraya (A4) 76.3 59.0 75.6 69.2 66.9 64.0 67.1 4.4
Dhobikuwa(A5) 76.2 64.3 76.1 73.7 71.6 68.8 71.0 3.7
Ranu (A6) 76.0 61.3 75.7 72.5 68.9 65.6 68.9 4.2
Bhoj (A7) 77.7 61.9 76.4 72.1 69.7 67.0 69.6 3.7
Vishrampura (A8) 76.6 66.2 76.5 72.8 70.6 68.3 70.7 3.0
Figure 3.3 Graphical representation for PM10
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-29
Table 3.14: Ambient Air Quality Status (PM2.5)
(Monitoring Period: 1st October, 2018 to 29th December, 2018)
Average-24 Hours Unit-g/m3
Station Name Max Min 98th
Percentile
75th
Percentile
50th
Percentile
25th
percentile
Avg. SD
Project Site (A1) 44.5 35.0 44.5 41.8 39.6 38.0 39.9 2.7
Dabhasa (A2) 45.8 28.9 45.8 41.5 40.2 37.2 39.8 3.9
Padra (A3) 42.7 29.4 41.4 38.8 37.6 35.9 37.0 2.8
Umaraya (A4) 51.2 34.6 50.0 44.0 41.9 38.9 41.8 4.2
Dhobikuwa (A5) 44.0 29.4 42.6 38.9 37.8 35.9 37.3 3.1
Ranu (A6) 47.1 31.7 46.3 40.0 37.6 33.7 37.6 4.4
Bhoj (A7) 49.3 35.2 47.0 42.6 41.3 39.6 41.1 2.9
Vishrampura (A8) 45.4 34.3 45.0 42.9 38.5 36.2 39.5 3.6
Figure 3.4 Graphical representation for PM2.5
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-30
Table 3.15: Ambient Air Quality Status (SO2)
(Monitoring Period: 1st October, 2018 to 29th December, 2018)
Average-24 Hours Unit-g/m3
Station Name Max Min 98th
Percentile
75th
Percentile
50th
Percentile
25th
percentile
Avg. SD
Project Site(A1) 18.0 12.5 18.0 16.8 15.3 14.7 15.5 1.6
Dabhasa(A2) 17.6 13.0 17.2 15.8 15.3 14.3 15.1 1.2
Padra (A3) 15.8 10.8 15.8 14.8 13.9 12.8 13.7 1.5
Umaraya (A4) 19.2 12.9 19.1 17.6 16.5 14.8 16.3 1.8
Dhobikuwa(A5) 15.9 11.2 15.8 14.9 13.6 12.7 13.6 1.4
Ranu (A6) 18.3 10.2 17.4 13.4 12.6 11.4 13.0 2.0
Bhoj (A7) 16.9 11.4 16.4 14.5 13.7 13.2 13.8 1.2
Vishrampura (A8) 24.2 11.5 20.8 16.1 14.6 13.5 14.9 2.5
Figure 3.5 Graphical representations for SO2
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-31
Table 3.16: Ambient Air Quality Status (NOx)
(Monitoring Period: 1st October, 2018 to 29th December, 2018)
Average-24 Hours Unit-g/m3
Station Name Max Min 98th
Percentile
75th
Percentile
50th
Percentile
25th
percentile
Avg. SD
Project Site(A1) 21.4 14.4 21.1 19.7 18.1 16.8 18.1 1.9
Dabhasa(A2) 21.0 13.5 21.0 19.1 17.7 16.6 17.8 2.0
Padra (A3) 20.7 13.3 20.2 18.3 16.8 16.0 16.9 2.0
Umaraya (A4) 22.2 14.4 21.9 17.8 16.9 16.0 17.4 2.2
Dhobikuwa(A5) 20.5 12.4 20.2 18.2 13.9 14.0 16.0 2.3
Ranu (A6) 23.1 11.6 22.0 16.7 15.3 14.0 15.8 2.7
Bhoj (A7) 20.8 13.7 19.7 16.8 15.3 14.4 15.8 1.8
Vishrampura
(A8)
26.5 13.1 23.6 17.8 16.0 15.1 16.7 2.8
Figure 3.6 Graphical representations for NOx
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-32
Table 3.17: Ambient Air Quality Status
(CO, HC (Methane & non-Methane), VOC, HCl)
(Monitoring Period: 1st October, 2018 to 29th December, 2018)
Station Name CO
(g/m3)
Hydro Carbon
(g/m3)
VOC
(g/m3)
HCl
(g/m3)
Methane Non-
Methane
Benzene Toluene Xylene
Project Site(A1) 1024 32.2 1028 0.42 0.59 0.37 BDL
Dabhasa(A2) 1062 37.6 1123 0.89 0.21 0.29 BDL
Padra (A3) 1131 36.1 1141 1.42 1.63 0.26 BDL
Umaraya (A4) 1087 39.3 1092 0.49 0.36 BDL BDL
Dhobikuwa(A5) 1054 39.5 1063 0.63 0.29 BDL BDL
Ranu (A6) 1075 34.0 1039 0.35 0.21 BDL BDL
Bhoj (A7) 1182 34.9 1109 0.28 0.27 BDL BDL
Vishrampura
(A8)
1073 41.1 1185 0.27 BDL BDL BDL
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-33
Table 3.18: National Ambient Air Quality Standards
(EP, 7th amendment rules-2009)
Pollutants Time-weighted average
Concentration in ambient air
Industrial, Residential, Rural and
others area
Ecologically Sensitive area (Notified by
Central Government)
Method of Measurement
Sulphur Dioxide (SO2), µg/m3
Annual Average*
50 20 Improved west and Gaekemethod
Ultraviolet fluorescence
24 hours** 80 80
Oxides of Nitrogen as (NO2), µg/m3
Annual Average*
40 30 Modified Jacob &Hochheiser
(Na-Arsenate) Chemiluminescence
24 hours** 80 80
Particulate Matter (Size less than 10 µm or PM10, µg/m3
Annual Average*
60 60 Gravimetric TOEM Beta attenuation 24 hours** 100 100
Particulate Matter (Size less than 2.5 µm or PM2.5, µg/m3
Annual Average*
40 40 Gravimetric TOEM Beta attenuation 24 hours** 60 60
Ozone (O3) µg/m3
8 hours ** 100 100 UV photometric Chemiluminescence Chemical Method
1hours** 180 180
Lead (Pb) µg/m3
Annual Average*
0.50 0.50 AAS/ICP method after sampling on EPM 2000 or equivalent filter paper
ED-XRF using Teflon filter
24 hours** 1.0 1.0
CarbonMonoxide
(CO) mg/m3
8 hours** 02 02 Non Dispersive Infra
Red (NDIR) spectroscopy
1 hour** 04 04
Ammonia (NH3) µg/m3
Annual Average*
100 100 Chemiluminescence Indophenol Blue
Method 24 hours** 400 400
Benzene (C6H6) µg/m3
Annual* 05 05 Gas chromatography based continuous analyzer
Adsorption and desorption followed
by GC analysis
Benzo(a) Pyrine (BaP)-particulate
phase only, ng/m3
Annual* 01 01 Solvent extraction followed by HPLC/GC
analysis
Arsenic (As), ng/m3
Annual* 06 06 AAS/ICP method after sampling on EPM 2000 or equivalent
filter paper
Nickel (Ni) ng/m3
Annual* 20 20 AAS/ICP method after sampling on EPM
2000 or equivalent filter paper
* Annual Arithmetic mean of minimum 104 measurements in a year taken twice a week 24 hourly at uniform interval.
** 24 hourly/8 hourly or 01 hourly values, as applicable, shall be complied with 98% of the time in a year. 2% of the time, they may exceed the limits but not two consecutive days of monitoring.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-34
Table 3.19: Results of Groundwater Quality in the Study Area
(Date of Sampling: 18 to 19 December, 2018)
Parameters Unit CONCENTRATION
Nr. Project
Site
(GW1)
Dabhasa
(GW2)
Padra
(GW3)
Umaraya
(GW4)
Dhobikuwa
(GW5)
Ranu
(GW6)
Bhoj
(GW7)
Vishrampura
(GW8)
pH pH Unit 7.6 7.3 7.5 7.7 7.4 7.1 7.3 7.8
Color Co-Pt Unit Color
less
Color
less
Color
less
Color
less
Color
less
Color
less
Color
less
Color
less
Conductivity Micro
mhos/cm
1580 2450 1735 2770 1963 1670 1825 1930
Turbidity NTU 7.2 5.9 6.1 11.9 8.5 10.3 6.9 7.8
TDS mg/L 1092 1690 1209 1923 1372 1156 1270 1342
Total Hardness as CaCO3 mg/L 265 362 313 460 353 393 297 387
Total Alkalinity mg/L 310 308 346 319 328 332 309 314
Sodium as Na+ mg/L 397 528 330 592 449 323 391 403
Potassium as K+ mg/L 68 62 53 66 43 50 68 50
Calcium as Ca+2 mg/L 48 56 51 92 44 85 53 84
Magnesium as Mg+2 mg/L 59 54 45 56 59 44 40 43
Chlorides as Cl- mg/L 516 818 512 935 643 561 567 634
Sulfates as SO4-2 mg/L 58 116 85 112 92 87 72 81
Fluoride as F- mg/L 0.66 0.61 0.59 0.67 0.7 0.64 0.66 0.56
Nitrates as NO3-3 mg/L 17 21 21 18 16 25 18 15
Phenol mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001
Cyanide as CN- mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001
Arsenic as As mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Cadmium as Cd mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Copper as Cu mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Lead as Pb mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Manganese as Mn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Iron as Fe mg/L 0.23 0.26 0.19 0.29 0.25 0.23 0.21 0.23
Zinc as Zn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
% Sodium -- 65.6 72.08 65.2 70.1 70.3 60.4 68.7 65.9
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-35
Table 3.20: Surface Water analysis of study area
(Date of Sampling: 18 to 19 December, 2018)
Parameters Unit CONCENTRATION Method of Test
(Ref. to IS) Dabhasa
Pond
(SW1)
Padra
Pond
(SW2)
Bhoj
Pond
(SW3)
Ranu
Pond
(SW4)
Luna
Pond
(SW5)
Dabka
Pond
(SW6)
Tajpura
Pond
(SW7)
Mahi
River
(SW8)
pH pH Unit 7.3 7.6 7.5 7.2 7.7 7.1 7.4 7.8 3025(Part 11)
Conductivity Micro
mhos/cm
755 502 508 630 560 830 610 1225 ---
Turbidity NTU 15.3 10.9 9.6 11.7 12.5 10.7 7.9 15.6 3025(Part 10)
TDS mg/L 518 342 406 435 385 572 418 842 3025(Part 16)
Dissolved Oxygen mg/L 5.1 6.2 7.5 4.9 6.3 8.4 5.8 6.3 ---
Total Hardness as
CaCO3
mg/L 171 152 196 171 129 170 122 205 3025(Part 21)
Total Alkalinity mg/L 258 286 310 295 276 278 265 338 3025(Part 23)
Sodium as Na+ mg/L 186 123 142 159 141 185 160 295 3025(Part 45)
Potassium K+ mg/L 25 28 21 27 30 28 25 39 3025(Part 45)
Calcium Ca+2 mg/L 29 31 39 32 27 35 21 36 3025(Part 40)
Magnesium Mg+2 mg/L 24 18 24 22 15 20 17 28 3025(Part 46)
Chlorides as Cl- mg/L 203 108 137 155 109 225 152 382 3025(Part 32)
Sulfates as SO4-2 mg/L 28 18 29 32 24 27 31 46 3025(Part 24)
Nitrates as NO3-3 mg/L 9.5 10 11.3 7.8 9.5 10.2 11.3 12.7 3025(Part 34)
Phenol as CH3OH mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 3025(Part 43)
Cyanide as CN- mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 3025(Part 27)
Arsenic as As mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 37)
Cadmium as Cd mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 41)
Copper as Cu mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 42)
Lead as Pb mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 47)
Manganese as Mn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 59)
Iron as Fe mg/L 0.19 0.23 0.17 0.15 0.13 0.21 0.18 0.15 3025(Part 53)
Total Chromium mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 52)
Zinc as Zn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 49)
Total Coliform MPN/ml 142 152 172 98 110 152 148 198 IS: 5401(P-I)
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-36
Table 3.21: Indian Standard Specification for Drinking Water
Sr. No.
Parameters Desirable Limit
Permissible Limit in the
Absence of Alternate
Source
I Essential Characteristics
1. Colour, Hazen Units, Max. 5 25
2. Odour Unobjectionable -
3. Taste Agreeable -
4. Turbidity, NTU, Max. 5 10
5. pH 6.5-8.5 No Relaxation
6. Total Hardness (as CaCO3) mg/l, Max. 300 600
7. Iron (as Fe) mg/l, Max. 0.3 1.0
8. Chlorides (as Cl) mg/l, Max. 250 1000
9. Residual Free Chlorine, mg/l, Min. 0.20* -
II Desirable Characteristics
10. Dissolved Solids, mg/l, Max. 500 2000
11. Alkalinity (as CaCO3), mg/l, Max. 200 600
12. Sulphate (as SO4) mg/l, Max. 200 400
13. Nitrate (as NO3) 45 100
14. Fluoride (as F) mg/l, Max. 1.0 1.5
15. Calcium (as Ca) mg/l, Max. 75 200
16. Magnesium (as Mg) mg/l, Max. 30 100
17. Copper (as Cu) mg/l, Max. 0.05 1.5
18. Manganese (as Mn) mg/l, Max. 0.1 0.3
19. Mercury (as Hg) mg/l, Max. 0.001 No Relaxation
20. Cadmium (as Cd) mg/l, Max. 0.01 No Relaxation
21. Selenium (as Se) mg/l, Max. 0.01 No Relaxation
22. Arsenic (As As) mg/l, Max. 0.05 No Relaxation
23. Cyanide (as CN) mg/l, Max. 0.05 No Relaxation
24. Lead (as Pb) mg/l, Max. 0.05 No Relaxation
25. Zinc (as Zn) mg/l, Max. 5 15
26. Aluminium (as Al) mg/l, Max. 0.03 0.2
27. Boron (as B) mg/l, Max. 1 5
28. Chromium (as Cr) mg/l, Max. 0.05 No Relaxation
29. Phenolic Compounds (as C6H5OH) mg/l,
Max.
0.001 0.002
30. Anionic Detergents (as MBAS) mg/l, Max. mg/l, Max.
0.2 1.0
31. Mineral Oil mg/l, Max. 0.01 0.03
32. Pesticides Absent 0.001
33. Radioactive Materials a. Alpha Emitters, Bq/I, Max.
b. Beta Emitters, Pci/I, Max
-
-
0.1
0.037
Note: * Applicable only when water is chlorinated
Source: IS: 10500, 2012
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-37
Table 3.22: Ambient Noise Levels in the Study Area
(Date of Sampling: 18 to 19 December, 2018)
Sr.
No.
Locations Coordinates Ld/Ln Noise
Level
dB(A)
1 Project site (N1) 22°13'32.76"N
73° 1'13.01"E Ld 52.7
Ln 41.9
2 100 m West from the
site (N2)
22°13'30.48"N
73° 1'5.74"E
Ld 52.7
Ln 43.1
3 250 m South from the
site (N3)
22°13'22.58"N
73° 1'15.97"E
Ld 51.7
Ln 40.8
4 500 m North from the
site (N4)
22°13'51.53"N
73° 1'10.05"E
Ld 50.9
Ln 39.2
5 1000 m East from the
site (N5)
22°13'36.56"N
73° 1'51.78"E
Ld 53.7
Ln 43.4
6 Village Dabhasa (N6) 22°14'38.53"N
73° 2'11.02"E
Ld 52.7
Ln 41.2
7 Nr Bus stop Padra(N7) 22°14'30.19"N
73° 5'7.73"E
Ld 52.9
Ln 41.0
8 Village Ranu (N8) 22°12'30.40"N
73° 1'28.74"E
Ld 50.7
Ln 40.2
9 Village Bhoj (N9) 22°12'1.19"N
73° 0'9.68"E
Ld 51.8
Ln 40.3
Table 3.23
Ambient Air Quality Standards with respect to Noise
Zone Limits Leq, dB(A)
Day Time Night Time
Industrial 75 70
Commercial 65 55
Residential 55 45
Silence 50 40
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-38
Table 3.24: Soil Analysis of Study area
(Date of Sampling: 18 to 19 December, 2018)
Sr.
No.
Parameters Unit Concentration
Project Site
(S1)
Dabhasa
(S2)
Padra
(S3)
Umaraya
(S4)
Dhobi
Kuwa (S5)
Ranu
(S6)
Bhoj
(S7)
Vishrampura
(S8)
1. pH (5%) Solution --- 7.8 7.2 7.9 7.5 7.3 7.5 7.4 7.8
3. Loss of Ignition % 7.5 6.3 6.8 8.9 10.2 9.2 8.5 7.3
4. Particle Size
Clay (<0.002 mm) % 16 20 18 18 20 20 19 24
Silt (0.002 to 0.075 mm) % 32 31 26 30 21 28 32 28
Sand (0.075 - 0.475 mm) % 29 28 32 32 33 27 24 25
Gravel (size > 4.75 mm) % 23 21 24 20 26 25 25 23
5. Water Holding Capacity % 42.1 40.9 40.8 40.3 41.1 40.4 40.6 41.9
6. Permeability cm/hr 2.96 3.12 1.98 3.05 3.14 3.15 3.12 3.15
7. Bulk Density g/cm3 1.43 1.41 1.42 1.43 1.42 1.39 1.44 1.46
8. Porosity % 42.1 42.9 42.5 42.1 42.5 43.7 41.7 40.8
9. Sodium Absorption Ratio Meq/
100 gm
5.99 3.97 4.55 4.2 3.67 5.52 4.95 5.37
10. Sodium mg/kg 629 578 559 510 573 692 589 626
11. Potassium mg/kg 156 163 173 175 142 185 163 126
12. Calcium mg/kg 497 406 615 556 797 629 559 363
13. Magnesium mg/kg 202 720 316 335 629 336 307 398
14. Chlorides mg/kg 678 622 679 689 850 888 795 727
15. Sulphates mg/kg 494S 480 466 428 421 437 494 429
16. Organic Matter mg/kg 4.95 2.07 2.91 2.65 2.33 1.85 2.02 2.42
17. Total Nitrogen mg/kg 282 230 49 214 83 198 193 207
18. Total Phosphorus mg/kg 146 132 36 188 98 134 185 171
19. Iron mg/kg 2.57 2.24 2.38 2.34 2.38 2.16 2.4 2.35
20. Manganese mg/kg 7.42 5.54 7.42 8.12 3.76 5.86 5.86 5.54
21. Cation Exchange Capacity meq/
100 gm
7.3 10.96 8.58 8.24 12.08 9.43 8.33 8.18
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-39
Table 3.25
Floral Diversity
(A) Trees
Scientific Name Family Vernacular Name
Acacia Nilotica Fabaceae Bawal
Acacia Tortilis Fabaceae Israeli Bawal
Ailanthus Excelsa Simaroubiaceae Mahanimb
AlangiumSalvifolium Alangiaceae Ankol
AlbiziaLebbeck Fabaceae Siras
Azadirachtaindica Meliaceae Neem
Borassusflabellifer Arecaceae Tad
Calotropisprocera Asclepiadaceae Akauwa
CommiphoraMukul Burseraceae Guggal
CordiaDichotoma Ehretiaceae Gundi
Delonixelata Caesalpiniaceae Gulmohar
Emblicaofficinalis Euphorbiaceae Amla
Eucalyptus Tereticornis Myrtaceae Nilgiri
Ficusbengalesis Moraceae Vad
Ficusmicrocarpa Moraceae Banyan
Ficusreligiosa Moraceae Pipal
MangiferaIndica Anacardiaceae Ambo
ManilkaraZapota Sapotaceae Chikoo
Moringaoleifera Moringaceae Sargvo
Phoenix Sylvestris Arecaceae Khajoor
Pithecellobiumdulce Fabaceae Gorasamli
Sapindusemarginatus Sapindaceae Aritha
Syzygiumcumini Myrtaceae Jamun
TamarindusIndica Fabaceae Amli
Tectonagrandis Verbenaceae Sagwan
TerminaliaCatappa Combretaceae Almond
ZiziphusMauritiana Rhamnaceae Bor
(B) Shrubs
Scientific Name Family Vernacular Name
Acacia Caesia Fabaceae Palinja
Acacia Catechu Mimosoideae Khair
Adhatodavasica Acanthaceae Adusa
Annonasquamosa Annonaceae Sitafal
AzimaTetracantha Salvadoraceae Piludi
Calotropisprocera Asclepiadaceae Aak
Carica Papaya Caricaceae Papaya
Cassia Auriculata Caesalpiniaceae Anwal
DaturaStramonium Solanaceae Datura
Euphorbia Neriifolia Euphorbiaceae Thor
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-40
LawsoniaInermis Lythraceae Hina
Nariumindicum Apocynaceae Karne
Ocimum Sanctum Lamiaceae Tulsi
Ricinuscommunis Euphorbiaceae Arandi
Rosa Chinensis Rosaceae Rose
SennaAuriculata Fabaceae Avaram
ZizyphusMauritiana Rhamnaceae Bordi
(C) Herbs
Scientific Name Family Vernacular Name
Adhatodavasica Acanthaceae Adusa
AlysicarpusRugosus Fabaceae Chainpea
AmaranthusViridis Amaranthaceae Amaranth
AnisomelesIndica Lamiaceae Indian Catmint
Annonasquamosa Annonaceae Sitafal
BiophytumReinwardii Oxalidaceae Lajwanti
Carica Papaya Caricaceae Papaya
Croton Bonplandianum Euphorbiaceae Tulsi
Daturametel Solanaceae Datura
DesmostachyaBipinnata Poaceae Daabh
EchinopsEchinatus Asteraceae Shuliyo
Euphorbia Tirucalli Euphorbiaceae Saptala
Jatrophagossypifolia Euphorbiaceae Ratanjyot
Lantana Camara Verbenaceae Raimunia
Nariumindicum Apocynaceae Karne
Ocimum Sanctum Lamiaceae Tulsi
Pedalium Murex Pedaliacae KadvaGokhru
PhyllanthusAmarus Euphorbiaceae Jar-Amla
Punicagranatum Puniacaceae Dadam
Ricinuscommunis Euphorbiaceae Arandi
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-41
Table 3.26
Faunal Biodiversity
(A) List of Terrestrial & Aquatic Birds in the Study Area
Scientific Name Common Name
AcridotheresGinginianus Bank Myna
AcridotheresTristis Common Myna
AlcedoAtthis Kingfisher
AnasPoecilorhyncha Duck
CetntropusSinensis Coucal
Columba Livia Rock Pigeon
CorvusCorax Common Raven
CorvusSplendens House Crow
DendrocittaVagabunda Rufoustreepie
DicrurusMacrocercus Black Drongo
EremoptrixGrisea Sparrow-Lark
EudynamysScolopacea Asian Koel
MotacillaMaderaspatensis White-Browed Wagtail
Nectarinia Minima Sunbird
Passer Domesticus Sparrow
PavoCristatus Peafowl
PsittaculaKrameri Parakeet
PycnonotusCafer Bulbul
SaxicoloidesFulicata Indian Robin
SpilopeliaSenegalensis Dove
StreptopeLiachinensis Spotted Dove
TurdoidesCaudatus Babbler
(B) List of Mammals and Reptiles in the Study Area
Scientific Name Common Name
AhaetullaNasuta Green Vine Snake
BungarusCaeruleus Common Krait
CalotesVersicolor Garden Lizard
Canis Lupus Familiaris Indian Pariah Dog
FelisChaus Jungle Cat
FunambulusPennantii Palm Squirrel
HerpestesEdwardsii Mongoose
MusBooduga Field Mouse
NajaNaja Cobra
Presbytis Entellus Monkey
RattusRattus Rat
Semnopithecus Entellus Langur
VulpesBengalensis Fox
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-42
Table 3.27
Traffic Survey
TRAFFIC SHEET
LOCATION Padra-Jambusar Road
TIME 09.00 to 10.00 DATE 21/12/18
TOTAL PCU calculation Total PCU/hr
BUSES/TRUCKS* 52 PCU x 3 156
CARS/VANS 270 PCU x 1 270
MOTORCYCLES / BICYCLES 318 PCU x0.5 159
Total 585
TIME 18.00 to 19.00 DATE 21/12/18
TOTAL PCU calculation Total PCU/hr
BUSES/TRUCKS* 61 PCU x 3 183
CARS/VANS 249 PCU x 1 249
MOTORCYCLES / BICYCLES 342 PCU x0.5 171
Total 603
Note: *Mini-bus, Chartered Bus, School Bus, have been collectively
classified as Buses. Trucks and Tankers have been collectively classified as
Trucks.
Existing Traffic Scenario and Level of Services
The road from Padra to Jambusar Road is two track lane with divider, all types of
vehicles move on the road.
Capacity of road = 1500 PCU‟s/hr
Total Volume during Peak Hours = 603
Existing Volume/Capacity ratio = 603/1500= 0.402
The level of service is “C” that is Good
LEVEL OF SERVICE
Sr. No.
Existing Volume/Capacity Ratio
Level of Services
1. 0.0 to 0.2 “A” (Excellent)
2. 0.2 to 0.4 “B” (Very Good)
3. 0.4 to 0.6 “C” (Good)
4. 0.6 to 0.8 “D” (Fair)
5. 0.8 to 1.0 “E” (Poor)
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-43
Table 3.28 Land Use Pattern
Name of Village
Total Area of the
Village (ha)
Irrigated by
source (ha)
Un-irrigated
(ha)
Cultivable waste
(ha)
Area not available for
cultivation (ha)
Jhilod 290.2 140 51 8.2 31
Narpura 191 147.1 0 0 30.2
Sankhyad 409.5 288.4 0 0 96.8
Chamara 940.5 350 42 299 28.4
Jaspur 1575 442.2 533 0 130.4
Raypura 449 80 220 67.2 50
Bamangam 1474.2 1221.5 0 0.6 112.3
Devapura 234 181.1 0 0 27
Gambhira 1567.1 583 712 0 127
Umaraya 539.2 300 20 2 45
Tajpura 332.7 200.4 98 0 2.1
Luna 447.5 200 108.4 1.8 3.2
Ekalbara 593 250 115 0 56
Mujpur 888.8 345 300 0 65
Sultanpura 299 65.3 66.2 0 8.7
Dabka 1906.3 650.8 363.3 150.3 100
Pavda 563.2 250.2 180.4 21.4 5.8
Chokari 1380.1 380.1 98.9 10.3 0
Narsipura 266.9 195 26 2 28
Mahuvad 482.5 390.2 31.1 0 6.4
Dabhasa 1199.1 765.8 216.6 0 39.3
Sangma 329.2 215 68 0 20
Sokhdakhurd 446.8 210.1 220.6 4.1 1.9
Darapura 407.6 300 29.9 0 1.7
Ghayaj 737.5 540 104 10 11
Latipura 350.4 248.2 67.8 0 1.5
Ranu 858 568 194 0 40
Dhobikuwa 196.9 129 50 0 0.2
Vadu 874 480 330.7 2.1 9.2
Somjipura 252.2 197.1 24.1 1.8 1.3
Majatan 456.6 77.8 336.7 0 5.3
Sandha 336.7 280 34 16.6 2.1
Chitral 371.7 229 98 0 3
Lola 119.7 74 24 0 13
Muval 781.1 375 296 9 2
Vishrampura 234.9 170 40 1 0
Karnakuva 152.8 105 33.8 0 10.4
Bhoj 1153 710 306.4 123.2 0
Pipli 399.9 190 163 0 41.9
Sejakuva 369.8 15 171.7 0 40.7
Goriyad 614.4 414.4 92.9 4.2 44.2
Sareja 190.4 40 144.6 0.2 0.6
Saras vani 1089.6 591 356.2 20 7
Amla 1021.6 565.5 375 0 53
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-44
Name of
Village
Total Area
of the Village
(ha)
Irrigated
by source
(ha)
Un-
irrigated (ha)
cultivable
waste (ha)
Area not
available for cultivation
(ha)
Sadhi 1400.1 775 511 0 72
Vadadla 263.6 150 61 0 3
Anti 863.1 453.1 315.6 0 9.8
Rajupura 258.1 132 88 0 28
Jalalpur 426.2 255 110 0 45
Kalyankui 213.8 95 93 0 12
Ambada 761.6 367 302 0 50
Bhadara 384.8 70 260 0 17
Gayapura 195.3 40 130 2 10
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-45
Table: 3.29 Summary of Socio-economic status of Study area (Demography)
Name of
the Village/
Town/Ward
No. of
Occupied
Residential
House
Total Population
(Including
institutional and
houseless
population)
Literates Total main
Workers
Marginal
Workers
Cultivators Agricultur
al Laborer
Non-Worker
P M F M F M F M F M F M F M F
Jhilod 406 2061 1101 960 834 598 562 348 42 166 165 7 292 168 497 446
Narpura 323 1563 830 733 630 406 381 314 17 70 151 3 136 193 432 349
Sankhyad 664 3181 1661 1520 1275 862 821 341 134 379 569 26 170 255 706 800
Chamara 1020 5005 2620 2385 2047 1352 1487 436 108 449 528 20 746 191 1025 1500
Jaspur 1530 7658 3996 3662 3145 2425 2213 522 103 83 546 50 1080 402 1680 3057
Raypura 1085 5619 2879 2740 2380 2126 1530 392 179 75 484 23 416 306 1170 2273
Bamangam 1636 8201 4288 3913 3399 2366 2267 595 276 475 971 34 890 335 1745 2843
Devapura 142 631 335 296 255 177 134 35 73 124 102 4 17 1 128 137
Gambhira 1595 7939 4202 3737 3460 2461 2233 807 273 544 723 26 1111 232 1696 2386
Umaraya 775 4115 2146 1969 1621 1111 1072 45 151 85 237 4 304 25 923 1839
Tajpura 360 1720 897 823 733 597 545 121 25 37 177 2 246 114 327 665
Luna 521 2739 1430 1309 1087 833 849 269 17 42 248 10 261 132 564 998
Ekalbara 917 4435 2308 2127 1770 1386 1160 123 89 106 497 31 396 48 1059 1898
Mujpur 1923 9410 4887 4523 3759 2559 2259 445 538 1571 583 13 1154 347 2090 2507
Sultanpura 167 892 462 430 307 258 175 9 11 5 31 1 134 6 276 416
Dabka 1545 7345 3963 3382 2883 1984 2108 414 141 309 165 18 1528 354 1714 2659
Pavda 453 2113 1130 983 852 609 576 141 107 236 188 5 315 126 447 606
Chokari 1811 8884 4706 4178 3336 2170 2738 239 253 1417 535 25 1776 116 1715 2522
Narsipura 729 3447 1747 1700 1410 1090 1066 481 5 2 233 12 595 451 676 1217
Mahuvad 534 2564 1336 1228 1024 759 635 60 109 32 126 5 198 23 592 1136
Dabhasa 1708 8337 4322 4015 3319 2570 2381 243 163 155 586 13 983 144 1778 3617
Sangma 664 3096 1587 1509 1228 979 879 172 83 54 199 14 413 115 625 1283
Sokhdakhurd 462 2139 1099 1040 955 760 713 127 19 6 207 7 248 90 367 907
Darapura 666 3032 1589 1443 1255 1026 836 163 106 21 93 8 384 128 647 1259
Ghayaj 594 2667 1399 1268 1126 888 878 344 10 5 140 3 425 319 511 919
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-46
Latipura 592 2702 1427 1275 1207 920 855 139 32 81 258 12 372 108 540 1055
Ranu 1188 6092 3208 2884 2365 1792 1809 283 103 383 307 8 1032 240 1296 2218
Dhobikuwa 710 3392 1739 1653 1395 1108 713 76 218 133 232 12 310 45 808 1444
Vadu 1916 9626 5027 4599 3887 3024 2702 335 169 213 1040 36 1073 277 2156 4051
Somjipura 518 2480 1292 1188 1020 742 748 180 4 2 109 9 322 158 540 1006
Majatan 629 3288 1704 1584 1301 972 847 251 91 102 230 28 417 144 766 1231
Sandha 531 2600 1349 1251 1024 740 785 156 10 237 287 2 464 152 554 858
Chitral 351 1728 885 843 683 512 455 59 58 66 128 4 231 49 372 718
Lola 270 1535 805 730 637 471 502 41 8 5 238 10 166 26 295 684
Muval 903 4164 2177 1987 1685 1271 1265 207 8 18 344 18 418 149 904 1762
Vishrampura 606 2997 1538 1459 1242 975 859 375 37 147 238 20 375 199 642 937
Karnakuva 283 1289 667 622 516 372 389 185 7 99 88 2 271 179 271 338
Bhoj 1403 7072 3658 3414 2641 1888 2035 394 90 60 622 9 1198 323 1533 2960
Pipli 406 2046 1051 995 837 659 582 73 2 4 87 4 440 66 467 918
Sejakuva 512 2343 1212 1131 892 653 669 135 16 11 71 6 377 112 527 985
Goriyad 429 1943 1003 940 791 620 601 29 11 256 143 0 205 10 391 655
Sareja 2 10 6 4 2 0 3 0 0 0 0 0 3 0 3 4
Saras vani 511 2305 1195 1110 841 622 748 182 11 7 161 10 401 149 436 921
Amla 449 2129 1063 1066 861 811 570 39 14 2 190 9 281 23 479 1025
Sadhi 819 3794 2007 1787 1601 1190 1086 87 85 30 336 4 503 64 836 1670
Vadadla 503 2303 1194 1109 943 729 674 67 41 8 123 18 177 32 479 1034
Anti 837 5055 2602 2453 2004 1648 1266 139 89 18 415 15 673 106 1247 2296
Rajupura 277 1185 612 573 404 310 405 30 2 1 103 6 240 15 205 542
Jalalpur 434 2069 1064 1005 852 706 668 40 19 40 230 6 294 24 377 925
Kalyankui 141 627 326 301 273 219 132 9 70 42 78 4 2 1 124 250
Ambada 244 1021 561 460 453 263 364 157 4 3 95 1 234 150 193 300
Bhadara 137 730 365 365 286 217 223 21 1 1 80 2 59 13 141 343
Gayapura 139 581 308 273 227 153 199 23 7 85 55 2 113 15 102 165
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-47
Table 3.30: Summary of Socio-economic status of Study area (Amenities)
Name of
Village
Educational
Facility
Medical
Facility
Drinking
Water
Facility
Communication
(Post
or Telegraph)
Transportation
Facility
(Bus etc.)
Approach to
Village
Nearest
town
Power
Supply
Jhilod P None of within 10
Km
T,HP,TW,
TK
PO(5-10),SPO(5-
10),PH,PCO
BS,RS(5-10) PR,KR,FP Anklav EA
Narpura PP(5-
10),P(2),S(5-
10),SS(<5)
PHC(5-10),PHS(5-
10), MCW(5-10),
TBC(5-10),D(5-10),
VH(5-10),FWC(5-10)
T,HP,TW PO(5-10),
SPO(5-
10),PH,PCO
BS,RS(5-10) SH(5-
10),PR,KR(5-
10),WBM(5-
10),FP
Anklav EA
Sankhyad P(3),S(<5) PHS T,HP,TW,
R/C
PO(<5),SPO(<5)
,PH,PCO(5-10)
BS,RS(5-10) PR,KR,FP Anklav EA
Chamara PP(5-
10),P(2),S,SS
(<5),ASC(5-
10)
PHC(5-10), PHS,
MCW(5-10), TBC(5-
10), D(5-10), VH(5-
10), FWC(5-10)
T,W,HP,TW PO(<5),SPO,PH,
PCO
BS,RS(<5) SH(5-
10),PR,KR,W
BM(5-10),FP
Anklav EA
Jaspur PP(5-
10),P,S,SS,A
SC(5-10)
PHC(5-10),PHS,
MCW(5-10),TBC(5-
10),D(5-10),VH(5-
10),FWC(5-10)
T,W,HP,
TW,R/C
PO(5-
10),SPO,PH,PCO
BS,RS(5-10) NH(5-
10),SH(5-
10),PR,KR,W
BM(5-10),FP
Padra EA
Raypur PP(5-
10),P,S(<5),
SS(<5),ASC(
5-10)
PHC(<5),PHS,
MCW(<5),TBC(5-
10), D(5-10), VH(5-
10), FWC(<5)
T,HP,TW PO(<5),SPO,PH(
<5),PCO(<5)
BS,RS(<5) NH(<5),SH(
<5),PR,KR(<
5),WBM(5-
10),FP
Vadodara EA
Bamangam P(6),S,SS PHC,PHS(2) T,HP,TW PO,PH,PCO BS PR,KR,FP Anklav EA
Devapura PP(5-
10),P,S(5-
10),SS(<5)
PHC(5-10), PHS(5-
10), MCW(5-10),
TBC(5-10), D(5-10),
VH(5-10), FWC(5-
10)
T,HP,TW PO(<5),SPO(<5)
,PH,PCO(5-10)
BS,RS(<5) SH,PR,KR(5-
10),WBM(5-
10),FP
Anklav EA
Gambhira P(4),S,SS(2) PHS T,HP,TW PO(<5),SPO,PH,
PCO
BS SH,PR,FP Anklav EA
Umaraya PP(5-
10),P,S(<5),
ASC(5-10)
PHC(5-10),PHS,
MCW(5-10),TBC(5-
10),D(<5),VH(5-10),
FWC(5-10)
T,W,HP,TW
,R/C
PO(5-
10),SPO,PH,PCO
(5-10)
BS PR,KR,
WBM(5-10),
FP
Padra EA
Tajpur PP(<5),P,ASC
(<5)
PHC(<5),PHS,MCW(
<5),TBC(<5),D(<5),
T,TW,TK PO(<5),SPO,PH,
PCO(<5)
BS,RS(<5) NH(5-10),
SH(5-10),
Padra EA
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-48
Name of
Village
Educational
Facility
Medical
Facility
Drinking
Water
Facility
Communication
(Post
or Telegraph)
Transportation
Facility
(Bus etc.)
Approach to
Village
Nearest
town
Power
Supply
VH(<5),FWC(<5) PR,KR(<5),W
BM(<5),FP
Luna PP(<5),P,S(5
-10),SS(5-
10),ASC(<5)
PHC(<5),PHS(<5),M
CW(<5),TBC(<5),
D(<5),VH(<5),
FWC(<5)
T,W,TW,TK PO(<5),SPO,PH,
PCO(<5)
BS NH(5-
10),SH(5-
10),PR,KR(<
5),WBM(<5),
FP
Padra EA
Ekalbara PP(5-
10),P(2),S(<
5),SS(5-
10),ASC(5-
10)
PHC(5-10), PHS(5-
10), MCW(5-10),
TBC(5-10), D,
VH(<5), FWC(<5)
T,HP,R/S,
TK
PO(5-
10),SPO,PH,
PCO(<5)
BS,RS(5-10) SH,PR,KR,W
BM(5-10),FP
Padra EA
Mujpur PP(5-
10),P(2),S(<
5),ASC(5-10)
PHC,PHS, MCW(5-
10), TBC(5-10), D(5-
10), VH(5-10),
FWC(5-10)
T,W,HP,
TW,R/C,TK
PO(5-10),
SPO,PH, PCO
BS SH,PR,
KR(<5),
WBM(<5), FP
Padra EA
Sultanpura P,S(<5),SS(5
-10)
PHC(5-
10),PHS(<5),MCW(5
-10),VH(5-10)
T,W,HP,TW
,R/C,TK
PO(<5),
SPO(<5), PH,
PCO
BS,RS(5-10) SH(5-
10),PR,KR,W
BM(5-10),FP
Padra EA
Dabka P(2),S PHC(5-
10),PHS,MCW(5-
10),VH(5-10)
T,W,HP,
TW,R/C,
SPO,PH,PCO BS SH(5-
10),PR,KR,FP
Padra EA
Pavda P,S(5-10) PHC W,HP,TW,
R/C,TK
PO(<5),SPO(<5)
,PH,PCO
BS,RS(5-10) NH(5-10),
SH(5-10),
PR,KR,WBM,
FP
Padra EA
Chokari PP(5-
10),P(3),S(5-
10)
PHC(5-
10),PHS,MCW(5-
10),D,VH(5-10)
T,W,HP,
TW,R/C,TK
PO(<5),SPO,PH,
PCO
BS PR,KR(5-10),
WBM(5-10),
FP
Padra EA
Narsipura P,S(<5) PHC(<5),PHS(<5),M
CW(<5),D(<5),VH(<
5),FWC(<5)
T,HP,TK SPO BS,RS(5-10) NH(5-10),
SH(5-10),
PR,KR,WBM,
FP
Padra EA
Mahuvad PP,P,S,SS(5-
10),ASC(5-
PHC(<5),PHS,MCW,
TBC(5-10), D(5-
T,W,HP,
TW,R/C
PO(5-10), SPO,
PH,PCO
BS,RS(<5) SH,PR,KR,W
BM(5-10),FP
Padra EA
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-49
Name of
Village
Educational
Facility
Medical
Facility
Drinking
Water
Facility
Communication
(Post
or Telegraph)
Transportation
Facility
(Bus etc.)
Approach to
Village
Nearest
town
Power
Supply
10) 10),VH(<5), FWC(5-
10)
Dabhasa PP(<5),P(2),
S,SS(5-
10),ASC(<5)
PHC(<5)PHS,MCW,T
BC(<5),D(<5),VH(<
5),FWC(<5)
T,W,HP,
TW,TK
PO(<5),SPO,PH,
PCO
BS NH(5-10),
SH,PR,KR,W
BM (<5),FP
Padra EA
Sangma PP(<5),P,S(<
5),SS(<5),AS
C(<5)
PHC(<5),PHS,MCW(
<5),TBC(<5),D(<5),
VH(<5), FWC(<5)
T,W,HP,
TW,R/C,TK
PO(<5),SPO,PH,
PCO
BS,RS(<5) NH(5-10),
SH,PR,
KR(<5),
WBM(<5), FP
Padra EA
Sokhdakhurd PP,P,S(<5),S
S(<5),ASC(<
5)
PHC(<5),PHS,
MCW(<5),TBC(<5),
D(<5),VH(<5), FWC
(<5)
T,W,HP,
TW,TK
PO(<5),SPO(<5)
,PH,PCO
BS NH(<5),SH(
<5),PR,KR(<
5),WBM(<5),
FP
Padra EA
Darapura PP(<5),P(2),
S(2),SS(<5),
ASC(<5)
PHC(<5),PHS(<5),
MCW(<5),TBC(<5),
D(<5),VH(<5),
FWC(<5)
T,W,HP,
TW,TK
PO(<5),SPO,PH,
PCO
BS,RS(<5) NH(<5),SH(
<5),PR,KR,W
BM(<5),FP
Padra EA
Ghayaj PP(<5),P,S(<
5),SS(<5),AS
C(<5)
PHC(<5),PHS(<5),
MCW(<5),TBC(<5),
D(<5),VH(<5),
FWC(<5)
T,W,HP,
TW,R/C,TK
PO(<5),SPO,PH,
PCO
BS,RS(<5) SH,PR,KR,W
BM(<5),FP
Padra EA
Latipura PP(<5),P,S,S
S(<5),ASC(<
5)
PHC(<5),PHS(<5),
MCW(<5),TBC(<5),
D(<5),VH(<5),
FWC(<5)
T,W,HP,TW PO(<5),SPO,PH,
PCO(<5)
BS,RS(<5) SH(<5),PR,K
R,WBM,FP
Padra EA
Ranu PP(5-10),
P(3), S,
SS(5-10),
ASC(5-10)
PHC(5-10),PHS,
MCW(<5), TBC(5-
10), D(5-10),VH(5-
10),FWC(5-10)
T,W,HP,TW PO,SPO(<5),PH,
PCO
BS,RS NH(5-10),
SH(5-10),
PR,KR(<5),W
BM(<5),FP
Padra EA
Dhobikuwa P,S(<5) PHC(<5),PHS(<5),
MCW(<5),
TBC(5-10), D(5-10),
VH(<5),FWC(5-10)
T,W,HP,
TW,R/C
PO(5-
10),SPO(<5),PH,
PCO
BS SH,PR,KR,W
BM(5-10),FP
Padra EA
Vadu PP,P(3),S PHC,PHS,MCW,
D(<5),VH
T,HP,TW SPO,PH,PCO BS,RS(<5) NH(<5), SH,
PR,KR,
Padra EA
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-50
Name of
Village
Educational
Facility
Medical
Facility
Drinking
Water
Facility
Communication
(Post
or Telegraph)
Transportation
Facility
(Bus etc.)
Approach to
Village
Nearest
town
Power
Supply
WBM(<5), FP
Somjipura P,S(<5) PHC(<5),PHS(<5),
MCW(<5),VH(<5)
T,HP,TW,
TK
PH,PCO(5-10) BS NH(5-
10),PR,KR,W
BM(<5),FP
Padra EA
Majatan P,S(<5) PHC(<5),PHS(<5),M
CW(<5),D(<5),
VH(5-10),FWC(5-10)
T,W,HP,
TW,TK
PO(<5),SPO,PH,
PCO(<5)
BS,RS(5-10) NH(5-10),
SH(5-10),
PR, KR(5-
10),WBM(5-
10), FP
Padra EA
Sandha PP(<5),P,S(<
5),SS(<5),AS
C(<5)
PHC(<5),PHS(<5),M
CW(<5),D(5-10),
VH(5-10),FWC(5-10)
T,W,TK PO(5-10),
SPO,PH,PCO
BS,RS(5-10) NH(5-
10),SH(<5),
PR,KR,WBM,
FP
Padra EA
Chitral P(2),S(<5),S
S(<5)
PHC(5-10), PHS,
MCW(<5)
T,HP,TW SPO,PH,PCO(<5) BS,RS(5-10) NH(<5),
SH(<5),PR(<
5),KR(<5),W
BM(<5),FP
Padra EA
Lola P,S(<5) PHC(5-10),PHS(5-
10),MCW(5-10),
D(5-10), VH(5-
10),FWC(5-10)
T,HP,TW,
TK
PO(<5),PH BS,RS(5-10) NH(<5),SH,P
R(<5),KR,WB
M(<5),FP
Padra EA
Muval P(3),S PHC(<5),PHS(<5),D,
VH(5-10),FWC(5-10)
T,W,HP,TW
,TK
PO(<5),SPO,PH,
PCO
BS,RS(<5) PR,KR,FP Padra EA
Vishrampura P,S(<5),SS(5
-10)
PHS, MCW(5-
10),D(5-10),VH(5-
10)
T,TW,TK PO(5-10), SPO,
PH,PCO(5-10)
BS,RS(5-10) SH,PR(5-
10),KR(5-
10),WBM(5-
10),FP
Padra EA
Karnakuva P,S(<5) PHS,MCW(<5),
D(<5),VH(<5),
FWC(<5)
T,HP,TW PO(<5),
SPO(<5), PH,
PCO
BS SH,PR,KR,W
BM,FP
Padra EA
Bhoj P(3),S,SS(5-
10)
PHC(5-10), PHS,
MCW(<5), D(<5),
VH(<5), FWC(<5)
T,HP,TW,
R/C
SPO,PH,PCO BS,RS SH(<5),PR,
KR(<5),
WBM(<5),FP
Padra EA
Pipli PP(5-10), P,
S(<5),
PHC(<5),PHS(<5),
MCW(<5),TBC(5-
T,W,HP,
TW,TK
PO(5-
10),SPO,PH,PCO
BS,RS(<5) NH(5-10),
SH(5-10),
Padra EA
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-51
Name of
Village
Educational
Facility
Medical
Facility
Drinking
Water
Facility
Communication
(Post
or Telegraph)
Transportation
Facility
(Bus etc.)
Approach to
Village
Nearest
town
Power
Supply
SS(<5),
ASC(5-10)
10), D(5-10),
VH(<5), FWC(5-10)
PR,KR(<5),W
BM(5-10),FP
Sejakuva PP(5-
10),P(2),S,
SS, ASC(5-
10)
PHC(<5),PHS,
MCW(<5),TBC(5-
10),D(5-10),VH(5-
10),FWC(5-10)
T,W,TW,TK PO(5-
10),SPO,PH,PCO
BS SH(5-
10),PR,KR,W
BM(5-10),FP
Padra EA
Goriyad PP(<5),P,S(5
-10),SS(5-
10),ASC(<5)
PHC(<5),PHS,MCW(
<5),TBC(<5),D(<5),
VH(<5),FWC(<5)
W,TW,TK PO(<5),SPO,PH,
PCO
BS SH,PR,KR,W
BM(<5),FP
Padra EA
Sareja PP(<5),P(<5)
,ASC(<5)
PHC(<5),PHS(<5),
MCW(<5),TBC(<5),
D(<5),VH(<5),
FWC(<5)
T,W,HP,TW PO(<5),SPO(<5)
,PH,PCO
BS NH(5-10),
SH(5-10),PR,
KR(<5),WBM
(5-10),FP
Padra EA
Saras vani PP(5-
10),P,S,SS(<
5),ASC(5-10)
PHC(<5),PHS,MCW,
TBC(<5),D(<5),
VH(<5),FWC(<5)
T,TW,TK PO(<5),SPO,PH,
PCO(<5)
BS,RS(<5) NH(5-10),
SH,PR,
KR(<5),
WBM(<5),FP
Padra EA
Amla PP(5-
10),P,S(<5),
SS(<5),ASC(
5-10)
PHC(<5),PHS,
MCW(5-10),TBC(5-
10),D(<5),
VH(<5),FWC(5-10)
T,W,HP,
TW,TK
PO(5-
10),SPO,PH,PCO
BS,RS(5-10) PR,KR(5-
10),WBM(5-
10),FP
Padra EA
Sadhi PP(5-
10),P(5),S,SS
,ASC(5-10)
PHC,PHS,MCW,
TBC(5-10),D,VH(5-
10),FWC(5-10)
T,W,HP,
TW,TK
PO(5-
10),SPO,PH,PCO
BS NH(5-
10),SH(5-
10),PR,KR,W
BM(<5),FP
Padra EA
Vadadla PP(5-
10),P,S(5-10)
,SS(5-10),
ASC(5-10)
PHC(5-10),PHS(5-
10),MCW(5-10),
D(5-10),VH(5-
10),FWC(5-10)
T,W,HP,
TW,R/C,TK
PO(5-
10),SPO,PH,PCO
BS,RS(<5) NH(5-
10),SH(5-
10),PR,KR,W
BM(<5),FP
Padra EA
Anti PP(5-10),
P(2), S(<5)
, SS(<5),
ASC(5-10)
PHC(<5),PHS(<5),M
CW(<5),TBC(5-
10),D(5-10),VH(5-
10),FWC(5-10)
T,TK PO(<5),SPO,PH,
PCO
BS,RS(5-10) NH(5-10),
SH(5-10),
PR, KR,
WBM(<5), FP
Padra EA
Rajupura P,S(5-10) D(5-10),VH(5-
10),FWC(5-10)
T,W,HP,
TW,TK
PO(<5),SPO,PH,
PCO
BS,RS(<5) NH(5-10),
SH(5-10),
Padra EA
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-52
Name of
Village
Educational
Facility
Medical
Facility
Drinking
Water
Facility
Communication
(Post
or Telegraph)
Transportation
Facility
(Bus etc.)
Approach to
Village
Nearest
town
Power
Supply
PR(5-10),
KR,
WBM(<5), FP
Jalalpura P,S(5-
10),SS(5-10)
PHC(<5),PHS,MCW(
<5),D(<5),VH(5-
10),FWC(5-10)
T,R/C,TK PO(<5),SPO,PH BS,RS(<5) NH(<5),
SH(<5), PR,
KR,
WBM(<5), FP
Padra EA
Kalyankui P PHS(<5),MCW(<5) T,W,HP,
TW,R/C,TK
PO(<5),SPO(5-
10),PH(<5),
PCO(<5)
BS,RS(<5) NH(5-10),
SH(5-10),
PR, KR,
WBM(<5),FP
Padra EA
Ambada P,S PHC(5-10),PHS,D(5-
10),FWC(5-10)
T,W,HP,
TW,TK
PO(5-
10),SPO,PH,
PCO(<5)
BS,RS(<5) NH(5-10),
SH(5-10),
PR,KR,WBM(
5-10),FP
Padra EA
Bhadara P,S(<5),SS(<
5)
PHC(<5),PHS(<5),D(
5-10),VH(5-
10),FWC(5-10)
T,W,HP,
TW,TK
SPO,PH,PCO BS PR,KR, WBM
(5-10),FP
Padra EA
Gayapura PP(5-10), P,
S(5-10),
SS(5-10),
ASC(5-10)
PHC(5-10), PHS(5-
10), MCW(5-
10),TBC(5-10), D(5-
10),VH(<5), FWC(5-
10)
T,W,HP,TW PO(5-10),
SPO(5-10),PH,
PCO(5-10)
BS,RS(<5) NH(5-10),
SH(5-10),
PR,KR,
WBM(<5),FP
Padra EA
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-53
Abbreviations: Educational
PP - Preprimary School
P - Primary School S - Secondary School
SS - Senior Secondary School ASC - College of Arts, Science & Commerce
Medical Facility PHC - Primary Health Centre PHS - Primary Health Sub-Centre
MCW - Maternity & Child Welfare Centre TBC - T.B Clinic
FWC - Family Welfare Centre
D - Dispensary
VH - Veterinary Hospital Drinking Water
T - Tap Water HP - Hand Pump
TW - Tube well Water W - Well Water
TK - Tank water R/C - River/Canal
Post and Telegraph
PO - Post Office
PH - Telephone Connection SPO - Sub Post Office
PCO - Public Call Office
Transportation BS - Bus
RS - Railway Station
Approach to Village NH - National Highway
SH - State Highway PR - Pucca Road
KR - Kutccha Road WBM - Water bound macadam
FP - Footpath
Power Supply
EA - Electricity for all Purposes
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-54
Figure 3.7
Location of AAQM station
Indicating AAQM stations
Project site
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-55
Figure 3.8
Wind Rose diagram
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-56
Figure 3.9
Water sampling Locations
Indicating Ground Water sampling location
Indicating Surface Water Sampling location
Project site
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-57
Figure 3.10
Noise monitoring locations
Indicating Noise Monitoring location
Project site
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-58
Figure 3.11
Soil Sampling Locations
Indicating locations of Soil sampling
Project site
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 3-59
Figure 3.12 Toposheet of location with site location map of 10 km
radius (1:50,000 scale)
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-1
Chapter-4
Anticipated Environmental Impacts &
Mitigation Measures
4.1 GENERAL
Environmental Impact can be defined as any change in environmental
conditions which may be adverse or beneficial; occurred due to action or
set of actions under consideration. It can be assessed by identifying the
sources of the impact and predicting the same. The identification of
environmental impacts has been made by co-relating the relationship
between project activity and environmental parameters. As a part of
present EIA study, anticipated environmental impacts associated with the
project activity of the unit have been identified. The project activities are
usually divided into two phases: Construction Phase and Operation Phase.
For evaluation of impacts due to proposed activities, baseline data has
been utilized. Changes in the environmental parameters & their impact in
terms of short term or long term, positive or negative, reversible &
irreversible are identified & predicted.
The next step is prediction of impacts, which is an important component
in environmental impact assessment process. Several techniques and
methodologies are in vogue for predicting the impacts due to proposed
industrial development on physical, chemical, biological and socio-
economic components of environment. Such predictions delineate
contribution in existing baseline condition for the proposed project. The
additional impacts due to proposed activities are analyzed by keeping in
mind the baseline status. This helps to assess the assimilative capacity of
the environment and in turn the gravity of the impacts. Based on the
identification & prediction of the nature of impact, it can be evaluated
qualitatively and quantitatively.
In this chapter, the effect due to construction & operational activity of the
proposed project is explained.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-2
4.2 IDENTIFICATION OF IMPACT
This chapter deals with the assessment of project impacts on
environment. Mitigation measures are suggested to minimize the likely
negative impacts. The network method (Cause - effect) was adopted to
identify potential impact of the proposed activity. It includes stepwise
study of relationship between an activity and its environmental
parameters. This method involves in the “Road Map” type of approach to
the identification of second & third order effect. The basic idea is to
account for the project activity & identify the type of impact that could
initially occur followed by the identification of secondary and tertiary
impact.
The project will have impacts of varying magnitude on different
environmental components. These impacts could be categorized as -
Primary impacts, i.e. impacts which occur as a direct result of the
project activities.
Secondary and tertiary impacts, i.e. impacts that occur as a result
of primary impacts.
4.2.1 Identification of Impacting Activities
Various activities involved in the project are divided viz.:
A. Construction phase activities: impacts are immediate, in the vicinity
and sporadic
B. Operation phase activities: impacts are long term, in wide area and
continuous
The activities identified for the project under each phase are:
Construction phase
Excavation
Foundation & Civil work
Transportation of construction materials, equipments & machineries
Installation of equipments & machineries
Operation phase
Plant operation
Material storage & handling
Utilities and services
Green belt development
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-3
4.2.2 Identification of Environment Attributes
There are various types of impacts arise due to the proposed activities
which will be evaluated considering the following environment parameters
in construction and operational phase,
Impact on Topography
Impact on Air Environment
Impact on Water Environment
Impact on Noise Environment
Impact on Land Environment (Hazardous/solid waste generation)
Impact on Biological Environment
Impact on Socio-Economic Environment
Impact on Occupational Health & Safety
4.3 IMPACT ON TOPOGRAPHY
Proposed activities at Reynish Pharmachem Pvt. Ltd. will be carried out in
the new premises at Survey no. 504, 505, 507, Village: Dabhasa, Ta.:
Padra, District: Vadodara, Gujarat. Proposed land is already converted
from agriculture to non-agriculture for industrial purpose. During the
construction, excavated soil will be restored to its original shape. Thus,
the impact during the construction is reversible, for short terms and
insignificant. Construction of plant & building will be carried out for
proposed project. During the operational phase of the project, no major
impact is envisaged on the topography.
4.4 IMPACT ON AIR ENVIRONMENT
a. Construction Phase impact & mitigation measures
During construction phase, there will be chances of dust generation due
to the construction activities to be carried out as per the plant design. It
will be limited up to working area only and not likely to spread in wider
area. To mitigate the impact, regular sprinkling of the water will be done.
Vehicular traffic may lead to increased concentration pollutants through
exhaust gases, affecting the ambient air quality of surrounding areas;
vehicles only with PUC certificates will be allowed. However, this effect
remains localized near to the plant site and during the time of vehicular
movement only. Thus, overall impact is envisaged as short-term negative
& reversible in nature. Hence, looking to the overall facts described
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-4
above, it can be concluded that, the impacts on air due to the
construction & erection activities will be minimum or negligible.
b. Operational phase impact & mitigation measures
Long term impacts on the air quality are anticipated due to operational
activities. It depends on various factors like process technology,
operation & maintenance, raw material, fuel, air pollution control
measures. For the study of impact assessment for air environment, all
probable emissions are studied including fugitive emission. The sources
and expected emission level are described in below section.
Emission from the project
Flue gas emission will be from stack attached with Boiler (3.0 TPH),
Thermic Fluid Heater (20 lac Kcal/hr.) and Hot Air Generator (30 lac
Kcal/hr.) where Agro briquette will be used as a fuel; and standby D.G.
Set. Most probable pollutants will be SPM, SO2 and NOx. Process emission
will be from the stack attached with reaction vessels and vent of Spin
flash dryers (SFD)/Fluid Based Dryer (FBD)/Rotary Vacuum Dryer (RVD).
Pollutants from reaction vessels will be SO2 & HCl and PM will be
generated from SFD/FBD/RVD.
Mitigation measures
Multi Cyclone, bag filter & water scrubber will be installed as APCM for
boiler, Thermic fluid heater and Hot air generator. To control the process
emission, water and alkali scrubber will be provided. SFD/FBD/RVD will
be equipped with in-built cyclone and bag filter. Furthermore, adequate
stack height and facility for sampling such as ladder and sampling point
will be provided as per the GPCB guidelines. The details of all stacks with
their APC measures & height are given in Table 2.8.
4.4.1 Air Pollution Dispersion Modeling of stack
Following sub-section give air dispersion modeling details for prediction of
changes in GLC of pollutants emitted from the above stacks.
Objective: The objective of dispersion modeling is to predict the ground
level concentration during the operation of the project and its impact on
ambient air quality of the area concentrations and compare with
applicable NAAQS.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-5
Model used: The impact on air quality due to emissions from single
source or group of sources is evaluated by use of mathematical models.
The impacts of air pollutants were predicted using Gaussian air dispersion
model, which is selected on the basis of existence of multiple point
sources within the industrial complex and the plain terrain at the project
site. In order to predict the impact of air pollutants on ambient air
quality, ISCST3 model (Industrial Source Complex – Short Term
(ISCST3) dispersion model) of United State Environmental Protection
Agency (USEPA) was used by considering guidelines stipulated by CPCB
for air pollution dispersion modeling. The Gaussian model provides
estimates of pollutant concentrations at various receptor locations.
It is an hour-by-hour steady state Gaussian model which takes into
account the following:
Terrain adjustments
Stack-tip downwash
Gradual plume rise
Buoyancy-induced dispersion, and
Complex terrain treatment and consideration of partial reflection
Plume reflection off elevated terrain
Building down wash
Partial penetration of elevated inversions is accounted for Hourly
source emission rates, exit velocity and stack gas temperature
Only two stability conditions based on the meteorology aspects were used
to calculate the theoretical maximum ground level concentration is
comparing the actual data and data generated from mathematical
modeling, it highlights that the stability condition E & A-B were
predominant in the region.
Following are the assumptions made while using the model:
- No dry and wet depletion of pollutants
- Receptors are on flat terrain
The key emitted pollutants will be SPM, SO2, NOx and HCl.
4.4.2 Micrometeorology
Hourly micrometeorological data collected during the study period
(October, 18 to December, 2018) have been used for modeling. The
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-6
hourly wind speed, solar insolation & total cloudiness during day time and
wind speed & total cloudiness during night time were used to determine
the hourly atmospheric stability classes (defined by Pasquill and Gifford
as A to F, A being most unstable and F being most stable). The hourly
stability classes were determined based on the technique suggested by
Turner.
Turner’s system used for determining the stability classes is as follows:
- For day or night: If total cloud cover (TC) = 10/10 and ceiling
<7000 ft (2134 m), NR=0
- For night-time (defined as period from one hour before sunset to
one hour after sunrise):
a) If TC<4/10, use NR = -2
b) If TC>4/10, use NR = -1
- For daytime: determine isolation class number (IN)
a) If TC<5/10, use NR=IN
b) If TC>5/10, modify IN by the sum of the following applicable
criteria
If ceiling<7000 ft (2134 m), modification = -2
If ceiling>7000 ft but <16000 ft (4877 m), modification = -1
- If TC=10/10 and ceiling>7000 ft, modification = -1 and let modified
value of IN=NR, except for day-time NR cannot be <+1.
During the study period, stability calculated based on above-mentioned
Turner method gives average stability as A-B class during Day time and E
class during Night time.
4.4.3 Input data
Stack emissions data have been used for prediction of incremental GLC
values of SPM, SO2, NOx and HCl using one season meteorological data
during October, 18 to December, 2018. Input data includes
quantitative expected emission levels, temperature, and mixing height
from the stack. Input data is given in Table 4.1.
4.4.4 Receptor Network
Uniform polar grid and ambient air monitoring locations are considered as
discrete Cartesian receptor network for entire study area of 10 km radius.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-7
4.4.5 Output of model (24-hourly GLCs)
The 24-hourly average Ground Level Concentration (GLC) values from
proposed project have been computed for SPM, SO2, NOx and HCl
considering topographical features around the plant & applicable stability
classes. The maximum 50 (24-hr) average concentration values for SPM,
SO2, NOx and HCl are given in Table 4.3 to 4.6. Corresponding Isopleths
for 24-hourly predicted value is generated which is shown in Figure 4.1
to 4.4.
It may be noted from the computed result for the proposed scenario that,
the highest 24-hourly average GLCs values for SPM, SO2, NOx and HCl
from the proposed activity are 3.603 g/m3, 1.902 g/m3, 1.628 g/m3,
and 0.287 g/m3 respectively. These GLCs are expected to occur at a
distance of 1.0 km from the source in W direction. With this, marginal
contribution due to the proposal of the project, the levels of PM10, SO2 &
NOx will remain well below the 24-hourly ambient air quality standards
for SO2 & NOx (80 g/m3), PM10 (100 g/m3), PM2.5 (60 g/m3) prescribed
by CPCB.
4.4.6 Incremental & cumulative concentration of pollutants
The maximum incremental GLCs due to project for SPM, SO2, NOx and
HCl is superimposed on the baseline concentrations recorded during the
study period to arrive at the likely resultant concentrations after
implementation of the proposed plant. The cumulative concentrations
(baseline + incremental) of the project is tabulated at Table 4.2.
4.4.7 Conclusion
The modeling study proved that, the air emissions from the proposed
activities would not likely to cause any significant impact on the ambient
air quality of the study area. The ambient air quality around project site
will remain within the National Ambient Air Quality Standards (NAAQS)
prescribed for residential area.
4.5 IMPACT ON WATER ENVIRONMENT
The main sources of impact on water environment will be due to
withdrawal of fresh water from the ground during construction and
operation phase. These are discussed below.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-8
a. Construction Phase impacts & mitigation measures
The water requirement for various purposes will be met from bore well.
During construction work, water requirement is estimated to be about 10-
25 KLD depending upon nature of construction work. In addition to this,
about 3-5 KLD fresh water will be required for domestic activities of the
construction staff which will also be met through the same source. There
will be no major wastewater generation from the construction work.
Hence, it can be concluded that there will be no adverse impact during
construction phase.
b. Operational Phase impacts & mitigation measures
Total water requirement (Industrial + Domestic + Greenbelt) will be 253
KLD; out of which 118 KLD will be fresh water requirement & 135 KLD
will be recycle/treated water (RO permeate & MEE condensate). Unit will
satisfy its fresh water requirement from Bore well water supply. Major
water demand will be industrial – mainly process (115 KLD), cooling (30
KLD), boiler (35 KLD), and washing (10 KLD).
Total industrial wastewater generation will be 141 KLD. The main source
of the industrial wastewater generation will be from process, lab &
scrubber (99 KLD), washing (10 KLD), utilities (Boiler & cooling - 10
KLD), and water treatment (22 KLD). Domestic wastewater generation
will be 4.0 KLD. Unit will built full-fledged ETP to treat w/w generated
from proposed project.
Process effluent along with wastewater of scrubber, washing and utility
will be taken to RO after primary and secondary treatment. RO reject will
be sent to MEE; RO permeate and condensate of MEE will be reused.
Domestic wastewater will be disposed to soak pit. Thus, achieving Zero
Liquid Discharge (ZLD). ETP sludge and MEE salt will be disposed to
approve TSDF site. Domestic effluent of will be disposed to soak pit.
c. Impact Assessment
As fresh water will be met from Bore well water supply, minor impact
envisage on ground water. However, unit will balance it by recharging
ground water during the monsoon season. For that, industry will develop
rain water harvesting structures nearby project area. So, there will not be
any major impact on the water environment due to proposed activities.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-9
Mitigation Measures:
Minimum use of water will be done for construction phase.
Maximum use of treated water from MEE and RO during operational
phase.
Regular maintenance of rain water harvesting structures shall be
undertaken to have effective recharge.
4.6 IMPACT ON NOISE ENVIRONMENT
Any unwanted sound that creates disturbance in hearing is termed as
Noise. Hence, it is important to assess the present noise quality of the
area in order to predict the potential impact of future noise levels due to
the project.
a. Construction Phase Impact & mitigation measures
During the construction phase at Reynish Pharmachem Pvt. Ltd.,
impacts on noise level will occur due to the noise generation from new
equipments/machineries as well as some impact due to transportation.
Mainly the impacts of increased noise levels during construction are likely
to occur due to increase movement of trucks & other diesel-powered
material handling equipment. The impacts of noise during the
construction would be restricted to the site only and will be temporary.
PPEs like ear muff/ear plug will be provided to the workers. Regular
maintenance & lubrication of machineries will be undertaken to reduce
the noise generation. Thus, it is envisaged that the impacts on noise
during the construction phase would be insignificant after mitigation
measure.
b. Operational Phase Impact & mitigation measures
During operation, noise levels will increase due to operation of boiler, Hot
air generation, D.G. sets, process plant, vehicular transportation & other
machineries. The noise anticipated from the project will be confined only
within plant boundary. Adequate greenbelt will be developed for
prevention of noise propagation outside plant premises. Oiling/lubrication
& preventive maintenance will be done to reduce noise generation at
source to the permissible limit. However, at places where noise levels
may exceed the limit, PPEs will be provided to workers. Adequate noise
control measures such as silencers, anti-vibration pad etc. will be
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-10
provided. All the equipment will be designed/operated in such a way that
the noise level in work place shall not exceed 85 dB(A) as per the OSHA
Standard. During operation, the protective measures like PPEs (ear muff,
ear plug) will be provided & the exposure duration of workers/other
personnel to noise will be managed as per OSHA standard. The results of
baseline monitoring carried out in the region are presented in Chapter-3.
The results are below the standards prescribed for Industrial
environment. It can be concluded that, the impact on noise environment
will be long term but insignificant.
4.7 IMPACT ON LAND ENVIRONMENT
The main source of impact on land and soil environment results due to
construction activities and hazardous waste disposal.
a. Construction Phase Impact & mitigation measures
The construction activities at Reynish Pharmachem like excavation,
clearing, leveling & vehicular movements will entail change in the
landscape, which are expected to be of short duration and insignificant.
Unit will provide sanitation facilities for the staff engaged in construction
work which will prevent the impacts on land. Thus, there will not be any
issue of impacts on land during the construction phase.
b. Operational Phase impact (Solid/Hazardous Waste)
The hazardous wastes are the major source of impacts on land.
Hazardous waste generation from project must be considered to identify
the potential impacts. At Reynish Pharmachem Pvt. Ltd., entire quantity
of the hazardous waste will be stored in the isolated hazardous waste
storage area within premises having impervious platform having RCC
floor, leachate collection system & roof cover and disposed as per the
scientific method. Entire quantity of hazardous waste will be handled &
disposed as per Hazardous & Other waste (Management & Transboundary
Movement) Rules, 2016.
Main source of hazardous waste generation will be ETP sludge (25
MT/month), MEE salt (50 MT/month) from wastewater treatment and
Process waste (12 MT/month) will be disposed of at approved TSDF site.
Spent carbon (0.75 MT/month), and spent catalyst (1.0 MT/month) will
be returned back to supplier for regeneration. Distillation residue (15
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-11
MT/month), off specification products and date expired products will be
sent for co-processing or at CHWIF for incineration. Used lubricating oil
(40 Lit/month) will be sold to registered recycler. Discarded Drums (700
Nos./month) & containers/Liners (0.5 MT/month) will be sold to actual
users. Whatsoever generated off-specific product and date expired
products will be sent to CHWIF for Incineration. HCl (20-25%) - 75
MT/month and Sodium bisulfite (NaHSO3) - 50 MT/month will be sold to
actual user under Rule-9 of HAZ Rule.
Fly ash generation from the unit will be around 4.0 MT/day. Fly ash will
be utilized for brick manufacturing in plant premises. Details of
hazardous waste disposal methods are given in Table 2.10. Hence, no
adverse impact on the land environment is likely to occur, and no
significant negative impact is envisaged on the surrounding soil quality.
4.8 IMPACT ON BIOLOGICAL ENVIRONMENT
a. Construction phase impact & mitigation measures
This is a Greenfield project; hence minor cutting of trees/shrubs will be
done to clean the area. However, it will be balanced by developing
greenbelt within premises and along the roads. Various trees, shrubs and
herbs are found in and around it, a list of which is given in baseline. None
of the plants are in the list of endangered plant species. Also, the trees
are identified for their sensitivity & pollution tolerance capacity. This
concept helps to plan the greenbelt of the area making it less polluted
and a pollution absorber. Thus, it is envisaged that there will not be any
adverse impacts on the ecology/biological environment in construction
phase.
b. Operational phase impact & mitigation measures
There are no protected areas like national park/wildlife sanctuary within
the 10 km radial of the project site, so there will not be any significant
impact on ecology. No endangered floral or faunal species has been
recorded within the study area. Further, unit will develop greenbelt to
enhance the biological feature of the site. Also, the trees are identified for
their sensitivity & pollution tolerance capacity.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-12
Conservation of Schedule-I fauna Pavo Cristatus through Habitat
Improvement and Awareness
No peacock was sighted in the project site. All the direct sightings of the
peacock were located near the human habitats, villages and agriculture
field, of study area. This species is well adapted to natural village
environment setting. Day time they temporarily move towards the
surrounding agriculture areas for feeding while during night time they
roost on the trees present in the village and in the agriculture hedges.
Habitat improvement programme can be undertaken through plantation
of suitable tree species in the surrounding villages. While selecting the
tree/ shrub species care shall be provided for beery plants which attract
these birds. During summer period, villagers will be encouraged to use
the old earthen pots to fill with water for drinking these birds.
(Wildlife Conservation Plan submitted for Schedule I species Pavo
Cristatus is attached as Annexure-XI of the EIA report.)
Seed Distribution among the Villagers:
Summer is the time when these birds are facing shortage of feeds, there
by supplying the feed like Bajri, Juwar, Maize to the surrounding villages
with good population of Indian peafowls will suffix the problem of food
shortage.
Conservation Measures with fund allocation:
In consultation of the forest department, following conservation measures
will be adapted for peacock conservation:
1. Increasing the tree cover in the study area which will provide shelter
and roosting to the peacocks. This can be achieved by planting of local
tree species like Neem, Shirish, Khakhro, Haldu, Amli, Banyan, Peepal
and Peeper or other Ficus sp. Vacant places such as edges of
agricultural fields, village Gauchar, Panchayat’s common land,
neighbourhood of people inhibiting, road side avenue tree plantation,
open scrubs, ravines, school compounds can be selected for practicing
the plantation activity.
2. School level awareness programmes will be conducted for
conservation of peacocks in the study area by organizing competitions
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-13
during “Wildlife Week” and “Van Mahotsav” celebrations by active
involvement of local community.
3. Some provision of rewards to informers for the control of poaching and
illegal trade in wildlife.
4. Carrying out census and research projects to know the potential
threats and population status of the species in collaboration of local
schools, colleges, panchayats and forest department.
5. Suggest strategies to minimize negative impacts of changing
environment in nearby area of peacock populations and to promote
conservation of peacock habitats.
6. Another way to help preserve the endangered species is to create
society dedicated to ecological ethics. All the conservation measures
will be implemented with the help of and in the consultation of the
district forest department.
The proponent has proposed a sum of Rs. 220000/- for the “Peacock”
conservation plan under the following heads:
Sr.
No.
Work or Activity Approximate
Cost. Rs.
Village
1 Plantation-350 tree plants (5 feet height as
per the plant species-Cost of sapling will be
changed per year)
70,000/-(@
200/-per plant)
Dabhasa, Ranu,
Dhobikuwa and
Mahuvad
2 Small water tank–10 nos. @ 10000/-per
tank
1,00,000/-
3 One awareness programme for “Peacock”
conservation
20,000/- Study area
4 3 cash prizes @ 10000 in a year will be
awarded to the informer of poachers.
30,000/-
Total 2,20,000/-
Following is the list of trees which are helpful as pollution absorber and at
the same time pollution sensitive.
Family
Name
Botanical Name Common
Name
Sensitive Tolerant
Anacardiaceae Mangiferaindica Mango Cement dust, Coal dust, SO2
Dust collector
Anonaceae Polyalthialongifolia Asopalav SO2 Dust collector
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-14
Family Name
Botanical Name Common Name
Sensitive Tolerant
Caesalpini-aceae
Cassia fistula Garmalo Cement dust, Poor Dust
collector, SO2
N.A
Delonixregia Gulmohar SO2, Fly ash, Cement dust
N.A
Meliaceae Azadirachtaindica Neem Cement dust SO2
Mimosaceae Pithecellobiumdulce Gorasamli N.A Better Dust collector, SO2
There will not be discharge of effluent from Reynish Pharmachem Pvt.
Ltd. and entire quantity of hazardous waste will be handled & disposed as
per Hazardous & Other waste (Management & Transboundary Movement)
Rules, 2016. Hence there will not be any impact on aquatic ecology of the
surrounding area. GLCs of air pollutants will remain low and hence no
significant impact on terrestrial ecology is expected. Thus, there will not
be any significant impact on ecological environment due to proposed
activities.
4.9 IMPACT ON SOCIO-ECONOMIC ENVIRONMENT
a. Construction Phase Impacts & mitigation measures
During the peak construction phase, construction manpower including
construction workers will be employed. However, to the maximum extent
possible, construction workers will be employed from within the study
area. Since the construction phase of this project will be for short time
period, the socio-economic impact due to construction of this project is
going to be temporary. Around 25 to 75 workers will be employed in the
construction work (upon nature of work). This will increase construction
employment in the study area. As the construction phase for the
proposed project will be few months, the impact would be temporary.
b. Operation Phase Impacts & mitigation measures
The proposed unit will be located in private land, so no displacement of
person is envisaged. Unit will provide employment opportunity to locally
available skilled and un-skilled labors at different level as per the
requirement, which in turn result into a positive impact on prevailing
socio-economic environment. For the proposed activities, 65 nos. of
workers will be employed. In addition, employment will be generated by
the secondary supporting activities e.g. transportation, communication,
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-15
daily utility services. Surrounding area has got good educational facilities
and most of employees will come from the surrounding area. Thus,
overall impacts on socio-economic environment are long term and
positive in nature.
4.10 IMPACT ON OCCUPATIONAL HEALTH & SAFETY
a. Construction Phase Impacts & mitigation measures
In the Construction phase, some effects on occupational health & safety
of the employees working in the site are envisaged. Major health issues
encountered will be physical hazards & accidental Hazard. All plans and
construction schedule will be followed as per relevant laws approved by
competent authority, so as to minimize the occupational health hazards.
Mitigation Measures
Necessary PPEs like helmets, ear plug/ear muff, safety shoes,
goggles etc. will be provided to workers.
Incident/accident reporting system will be developed and all the
employees will be made aware for the same.
Periodic inspection & testing of equipments & machineries will be
done.
b. Operational Phase Impacts & mitigation measures
In operational phase, various effects on occupational health and safety of
the employees working in the plant are envisaged. Major health and
safety issues encountered will be physical hazards, respiratory hazards,
electrical hazards, noise, fire hazards associated while working within the
plant. Preventive safety measures shall be taken to minimize the risk of
accident with respect to chemical handling.
Mitigation Measures
Emergency preparedness plan should be implemented.
First aid/other emergency treatment should be provided.
Workers shall be well equipped with personal protective
equipments. Only authorized persons will be allowed inside the
plant.
A health monitoring program shall be in place to monitor the health
of the persons working on the site to ensure the health status of all
concerned.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-16
Fire hydrant system, fire extinguishers will be installed at different
locations within premises.
Sign boards will be displayed at designated locations indicating
appropriate hazard warnings.
Good house-keeping will be ensured within the factory premises.
4.11 IMPACT ON TRAFFIC MOVEMENT
Raw materials, products & wastes will be transported in covered trucks by
road. The traffic load is to be increased due to proposed project for the
transportation of finished goods and raw materials.
Baseline/ Existing Traffic Scenario & Level of Services
The road from Padra to Jambusar Road is two track lane with divider, all
types of vehicles move on the road.
Capacity of road = 1500 PCU’s/hr
Total Volume during Peak Hours = 603
Existing Volume/Capacity ratio = 603/1500= 0.402
The level of service is “C” that is Good
Traffic Scenario & Level of Services: During Construction
Additional traffic from proposed project construction will be,
(i) Estimated 1 trucks/tanker per hour or 3 PCU/hr and
(ii) One to two cars estimated per hour or 2 PCU/hr.
Traffic Scenario & Level of Services: During operational level
Additional traffic from our project will be estimated 30 PCU/day [10
trucks/tankers (in & out) x 3] and 60 PCU/day from car and motorcycle,
which have insignificant impact on existing traffic load.
Conclusion: Traffic load due to proposed project is negligible compare
with existing traffic, hence insignificant impact on existing traffic
condition.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-17
Table 4.1
Input data for air quality modeling
Sr.
No.
Stack attached to Stack
Height
(m)
Temp.
(K)
Velocity
(m/s)
Dia.
(m)
Concentration
SPM
g/s
SO2
g/s
NOx
g/s
1 Steam Boiler
(3.0 TPH)
30 455 6.0 0.45 0.076 0.038 0.033
2 Thermic fluid heater
(20 lac Kcal/hr.)
30 455 6.5 0.45 0.083 0.041 0.036
3 Hot air generator
(30 lac Kcal/hr.)
30 455 6.5 0.45 0.083 0.041 0.036
4 D. G. Set
(500 kVA)
11 485 15.0 0.3 0.069 0.032 0.037
5 Process vessel stack 11 335 5.0 0.3 SO2 – 0.011 g/s
HCl- 0.006 g/s
6 SFD/FBD/RVD
(5 nos.)
11 335 5.0 0.3 PM-0.011 g/s
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-18
Table 4.2
Cumulative Concentrations at various locations
Station Direction Dist.
(Km)
Baseline
Concentration
(g/m3)
Predicted GLC
(g/m3)
Cumulative
Concentration
(g/m3)
PM SO2 NOx PM SO2 NOx PM SO2 NOx
Project Site (A1) -- 0.0 67.9 15.5 18.1 0.2 0.1 0.1 68.1 15.6 18.2
Dabhasa (A2) NNE(UW) 1.57 70.7 15.1 17.8 0.6 0.2 0.4 71.3 15.3 18.2
Padra (A3) ENE(UW) 6.11 67.2 13.7 16.9 0.2 0.0 0.1 67.4 13.7 17.0
Umaraya (A4) NNE(UW) 4.16 67.1 16.3 17.4 0.2 0.0 0.2 67.3 16.3 17.6
Dhobikuwa (A5) WSW(DW) 3.10 71.0 13.6 16.0 1.4 1.2 1.2 72.4 14.8 17.2
Ranu (A6) SSW(DW) 0.45 68.9 13.0 15.8 0.8 0.3 0.3 69.7 13.3 16.1
Bhoj (A7) SW(DW) 3.56 69.6 13.8 15.8 0.6 0.3 0.3 70.2 14.1 16.1
Vishrampura (A8) SW(DW) 5.88 70.7 14.9 16.7 0.2 0.1 0.1 70.9 15.0 16.8
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-19
Table 4.3 The 24-hourly average GLC Concentration Values for SPM
RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE
1 3.603 ( -1000.00, .00) GC 26 1.821 ( -1000.00, -1000.00) GC
2 3.001 ( -2000.00, .00) GC 27 1.810 ( -2000.00, .00) GC
3 2.880 ( -1000.00, .00) GC 28 1.790 ( -1000.00, -1000.00) GC
4 2.492 ( -1000.00, .00) GC 29 1.750 ( -2000.00, .00) GC
5 2.389 ( -1000.00, -1000.00) GC 30 1.737 ( -1000.00, -1000.00) GC
6 2.360 ( -1000.00, .00) GC 31 1.730 ( -2000.00, .00) GC
7 2.335 ( 1000.00, 1000.00) GC 32 1.720 ( .00, 2000.00) GC
8 2.322 ( -1000.00, .00) GC 33 1.699 ( -1000.00, .00) GC
9 2.269 ( 1000.00, .00) GC 34 1.669 ( -1000.00, -1000.00) GC
10 2.260 ( -1000.00, .00) GC 35 1.664 ( -1000.00, -1000.00) GC
11 2.258 ( .00, 1000.00) GC 36 1.656 ( -2000.00, .00) GC
12 2.202 ( -1000.00, .00) GC 37 1.654 ( -1000.00, .00) GC
13 2.189 ( -3000.00, .00) GC 38 1.652 ( -4000.00, .00) GC
14 2.185 ( -1000.00, .00) GC 39 1.636 ( -1000.00, -1000.00) GC
15 2.176 ( -1000.00, -1000.00) GC 40 1.615 ( -1000.00, .00) GC
16 2.052 ( 2000.00, .00) GC 41 1.605 ( -1000.00, -1000.00) GC
17 2.010 ( -1000.00, .00) GC 42 1.592 ( -1000.00, -1000.00) GC
18 1.994 ( -1000.00, .00) GC 43 1.586 ( -2000.00, .00) GC
19 1.990 ( -2000.00, .00) GC 44 1.561 ( -1000.00, .00) GC
20 1.978 ( -1000.00, -1000.00) GC 45 1.558 ( -2000.00, .00) GC
21 1.958 ( -1000.00, .00) GC 46 1.536 ( 3000.00, .00) GC
22 1.927 ( -1000.00, .00) GC 47 1.535 ( -2000.00, .00) GC
23 1.909 ( -1000.00, .00) GC 48 1.526 ( 1000.00, 1000.00) GC
24 1.888 ( .00, -1000.00) GC 49 1.505 ( -1000.00, .00) GC
25 1.883 ( -1000.00, .00) GC 50 1.499 ( -1000.00, -1000.00) GC
Note: Receptor Types: GC = Grid cart, Concentration in µg/m3
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-20
Table 4.4 The 24-hourly average GLC Concentration Values for SO2
RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE
1 1.902 ( -1000.00, .00) GC 26 0.946 ( -1000.00, -1000.00) GC
2 1.552 ( -2000.00, .00) GC 27 0.936 ( -2000.00, .00) GC
3 1.506 ( -1000.00, .00) GC 28 0.927 ( -1000.00, -1000.00) GC
4 1.304 ( -1000.00, .00) GC 29 0.904 ( -2000.00, .00) GC
5 1.244 ( -1000.00, -1000.00) GC 30 0.903 ( -1000.00, -1000.00) GC
6 1.227 ( -1000.00, .00) GC 31 0.892 ( -2000.00, .00) GC
7 1.213 ( 1000.00, 1000.00) GC 32 0.891 ( .00, 2000.00) GC
8 1.211 ( -1000.00, .00) GC 33 0.889 ( -1000.00, .00) GC
9 1.202 ( 1000.00, .00) GC 34 0.868 ( -1000.00, .00) GC
10 1.186 ( .00, 1000.00) GC 35 0.867 ( -1000.00, -1000.00) GC
11 1.185 ( -1000.00, .00) GC 36 0.865 ( -1000.00, -1000.00) GC
12 1.153 ( -1000.00, .00) GC 37 0.855 ( -2000.00, .00) GC
13 1.151 ( -1000.00, .00) GC 38 0.852 ( -1000.00, -1000.00) GC
14 1.133 ( -1000.00, -1000.00) GC 39 0.847 ( -4000.00, .00) GC
15 1.126 ( -3000.00, .00) GC 40 0.836 ( -1000.00, .00) GC
16 1.064 ( 2000.00, .00) GC 41 0.835 ( -1000.00, -1000.00) GC
17 1.058 ( -1000.00, .00) GC 42 0.828 ( -1000.00, -1000.00) GC
18 1.048 ( -1000.00, .00) GC 43 0.819 ( -2000.00, .00) GC
19 1.029 ( -1000.00, -1000.00) GC 44 0.819 ( -1000.00, .00) GC
20 1.028 ( -1000.00, .00) GC 45 0.804 ( -2000.00, .00) GC
21 1.026 ( -2000.00, .00) GC 46 0.802 ( 1000.00, 1000.00) GC
22 1.011 ( -1000.00, .00) GC 47 0.793 ( -2000.00, .00) GC
23 0.999 ( -1000.00, .00) GC 48 0.791 ( -1000.00, .00) GC
24 0.989 ( -1000.00, .00) GC 49 0.791 ( 3000.00, .00) GC
25 0.969 ( .00, -1000.00) GC 50 0.777 ( -1000.00, -1000.00) GC
Note: Receptor Types: GC = Grid cart, Concentration in µg/m3
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-21
Table 4.5 The 24-hourly average GLC Concentration Values for NOx
RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE
1 1.628 ( -1000.00, .00) GC 26 0.817 ( -1000.00, -1000.00) GC
2 1.342 ( -2000.00, .00) GC 27 0.809 ( -2000.00, .00) GC
3 1.296 ( -1000.00, .00) GC 28 0.801 ( -1000.00, -1000.00) GC
4 1.122 ( -1000.00, .00) GC 29 0.781 ( -2000.00, .00) GC
5 1.072 ( -1000.00, -1000.00) GC 30 0.779 ( -1000.00, -1000.00) GC
6 1.058 ( -1000.00, .00) GC 31 0.773 ( -2000.00, .00) GC
7 1.046 ( 1000.00, 1000.00) GC 32 0.769 ( .00, 2000.00) GC
8 1.042 ( -1000.00, .00) GC 33 0.764 ( -1000.00, .00) GC
9 1.025 ( 1000.00, .00) GC 34 0.748 ( -1000.00, -1000.00) GC
10 1.019 ( -1000.00, .00) GC 35 0.747 ( -1000.00, -1000.00) GC
11 1.014 ( .00, 1000.00) GC 36 0.746 ( -1000.00, .00) GC
12 0.989 ( -1000.00, .00) GC 37 0.740 ( -2000.00, .00) GC
13 0.987 ( -1000.00, .00) GC 38 0.735 ( -4000.00, .00) GC
14 0.977 ( -1000.00, -1000.00) GC 39 0.734 ( -1000.00, -1000.00) GC
15 0.976 ( -3000.00, .00) GC 40 0.722 ( -1000.00, .00) GC
16 0.918 ( 2000.00, .00) GC 41 0.720 ( -1000.00, -1000.00) GC
17 0.908 ( -1000.00, .00) GC 42 0.715 ( -1000.00, -1000.00) GC
18 0.895 ( -1000.00, .00) GC 43 0.709 ( -2000.00, .00) GC
19 0.889 ( -2000.00, .00) GC 44 0.703 ( -1000.00, .00) GC
20 0.888 ( -1000.00, -1000.00) GC 45 0.696 ( -2000.00, .00) GC
21 0.883 ( -1000.00, .00) GC 46 0.686 ( 1000.00, 1000.00) GC
22 0.869 ( -1000.00, .00) GC 47 0.686 ( -2000.00, .00) GC
23 0.860 ( -1000.00, .00) GC 48 0.685 ( 3000.00, .00) GC
24 0.847 ( -1000.00, .00) GC 49 0.679 ( -1000.00, .00) GC
25 0.840 ( .00, -1000.00) GC 50 0.672 ( -1000.00, -1000.00) GC
Note: Receptor Types: GC = Grid cart, Concentration in µg/m3
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-22
Table 4.6 The 24-hourly average GLC Concentration Values for HCl
RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE
1 0.287 ( -1000.00, .00) GC 26 0.097 ( -1000.00, -1000.00) GC
2 0.198 ( 1000.00, .00) GC 27 0.095 ( .00, 1000.00) GC
3 0.185 ( -1000.00, .00) GC 28 0.095 ( 2000.00, .00) GC
4 0.174 ( -1000.00, .00) GC 29 0.092 ( .00, 1000.00) GC
5 0.162 ( .00, 1000.00) GC 30 0.090 ( .00, -1000.00) GC
6 0.162 ( -1000.00, .00) GC 31 0.090 ( .00, -1000.00) GC
7 0.160 ( -1000.00, .00) GC 32 0.088 ( -1000.00, -1000.00) GC
8 0.154 ( -1000.00, .00) GC 33 0.087 ( .00, -1000.00) GC
9 0.147 ( -1000.00, .00) GC 34 0.086 ( -1000.00, -1000.00) GC
10 0.146 ( -1000.00, .00) GC 35 0.086 ( -1000.00, -1000.00) GC
11 0.146 ( -1000.00, .00) GC 36 0.085 ( 1000.00, .00) GC
12 0.140 ( -1000.00, .00) GC 37 0.084 ( 1000.00, .00) GC
13 0.136 ( -1000.00, .00) GC 38 0.083 ( -1000.00, .00) GC
14 0.135 ( -1000.00, .00) GC 39 0.082 ( -1000.00, -1000.00) GC
15 0.132 ( -1000.00, .00) GC 40 0.082 ( -1000.00, .00) GC
16 0.132 ( -2000.00, .00) GC 41 0.080 ( .00, 1000.00) GC
17 0.126 ( -1000.00, -1000.00) GC 42 0.080 ( -2000.00, .00) GC
18 0.120 ( -1000.00, .00) GC 43 0.080 ( .00, -1000.00) GC
19 0.114 ( -1000.00, .00) GC 44 0.080 ( -2000.00, .00) GC
20 0.113 ( -1000.00, .00) GC 45 0.080 ( -1000.00, -1000.00) GC
21 0.109 ( -1000.00, .00) GC 46 0.079 ( -1000.00, .00) GC
22 0.109 ( -1000.00, -1000.00) GC 47 0.079 ( -1000.00, -1000.00) GC
23 0.109 ( -1000.00, .00) GC 48 0.079 ( -1000.00, -1000.00) GC
24 0.109 ( 1000.00, 1000.00) GC 49 0.079 ( -1000.00, -1000.00) GC
25 0.097 ( 1000.00, 1000.00) GC 50 0.079 ( -1000.00, -1000.00) GC
Note: Receptor Types: GC = Grid cart, Concentration in µg/m3
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-23
Figure 4.1: Isopleths for Ground Level Concentrations for SPM
-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000
-10000
-8000
-6000
-4000
-2000
0
2000
4000
6000
8000
10000
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-24
Figure 4.2: Isopleths for Ground Level Concentrations for SO2
-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000
-10000
-8000
-6000
-4000
-2000
0
2000
4000
6000
8000
10000
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-25
Figure 4.3: Isopleths for Ground Level Concentrations for NOx
-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000
-10000
-8000
-6000
-4000
-2000
0
2000
4000
6000
8000
10000
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 4-26
Figure 4.4: Isopleths for Ground Level Concentrations for HCl
-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000
-10000
-8000
-6000
-4000
-2000
0
2000
4000
6000
8000
10000
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 5-1
Chapter-5
Analysis of Alternatives
5.1 PROLOGUE
Alternative analysis is the process of analyzing the proposed locating for
suitability for basic necessities to operate the plant safely, this analysis
also covers the environmental aspect of pollution prevention and
improvement in quality of life nearby the project vicinity. The project
alternative is the course of action in pace of another, that would meet the
same purpose and need, but which would avoid or minimize negative
impacts and enhance project benefits. Such projects may result in
specific impacts which can be avoided or mitigated by adherence to
certain predetermined performance standards, guidelines or design
criteria. Alternative approaches may therefore be more effective in
integrating environmental and social concerns into the project planning
process.
5.2 SITE ALTERNATIVE
M/s. Reynish Pharmachem Pvt. Ltd. is a Greenfield project, proposes
to set up bulk drugs manufacturing unit. Total production capacity of all
products will be tune around 50 MT/month. Before finalization of project
land, unit as carried out following three alternate site study.
Alternative sites examined for the proposed project before
finalization of project location:
The following three alternative sites have been considered for the
proposed Pharma Plant before finalize the site.
Description Site-1 Site-2 Site-3
Location (Village) Survey no 206, 207/2
Village Waghodia, Tal: Waghodia
Dist: Vadodara
Survey no. 504,
505, 507, Village:
Dabhasa, Tal:
Padra, Vadodara
Block No.: 391&
392 Village:
Umaraya, Tal:
Padra, Vadodara
Land Area Insufficient
16692 m2
Sufficient
36958 m2
Considerable
20581 m2
Geographical Coordinates
22°19'6.66"N 73°23'42.91"E
22°13'32.76"N 73° 1'13.01"E
22°15'37.7"N 73°01'34.1"E
Areas falling under the critically polluted areas
No critically polluted areas
No critically polluted areas
No critically polluted areas
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 5-2
(within 10 Kms.
Radius)
Within 10 Kms
Radius
Within 10 Kms
Radius
Within 10 Kms
Radius
National Parks/Wildlife
Sanctuaries/Bird Sanctuaries/Tiger
reserve/Elephant corridors/Migratory routes for Birds/Forest
(within 10 Kms. of the project site)
No National
Parks /Wildlife Sanctuaries /Bird
Sanctuaries Migratory routes for Birds/Forest
within 10 Kms. of the project
site
No National Parks
/Wildlife Sanctuaries /Bird
Sanctuaries Migratory routes for Birds/Forest
within 10 Kms. of the project site
No National
Parks /Wildlife Sanctuaries /Bird
Sanctuaries Migratory routes for Birds/Forest
within 10 Kms. of the project
site
Sensitive Areas with
10 Kms. radius of the site
Outside the ESZ Outside the ESZ Outside the ESZ
Land use pattern Rich agriculture land with surrounding
Agriculture farm
Agriculture non-irrigated land converted for
non-agricultural usage
Agriculture irrigated land
Residential structures within 1 km radius
from the project boundary
Waghodia town
around 0.9 km
No Residential
structures within
1 km
Umraya village
around 0.75 km
Number of schools
within 1 km of site
Waghodia
primary School around 1.1 km
None One primary
school
Major water bodies
within 2.5 km radius
from the project
boundary
Waghodia Pond
around 1.4 km
Ajwa Lake 6.0km
Ranu village Pond
around 1.5 km
Mahi river within
1.7 km
Numbers village within 2.5 km radius from the project boundary
4 villages – [email protected] km
Nava [email protected] km
[email protected] km [email protected] km
2 villages – Ranu@ 1.42km, [email protected] km
4 villages – [email protected] km,
[email protected] km, Luna@ 1.9
km, [email protected] km
Transport – Ranked on the ease of
accessibility and networking of Roads,
Rail, Air, Waterways along with logistic centers and
connectivity to port
Easy accessibility of Road network,
but traffic have to pass through
town of Waghodia. Around 20.0 km
from Vadodara city with national
and international connectivity for business by
Road, Rail Air cargo etc.
Easy accessibility of road network,
Around 19.0 km from Vadodara
city with national and international connectivity for
business by Rail, Air etc.
four lane [email protected] km
six lane Railway station-
Easy accessibility of road network,
Around 19.0 km from Vadodara
city with national and international connectivity for
business by Rail, Air etc.
four lane [email protected] km
six lane Railway station-
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 5-3
Two lane road
[email protected] km six lane
Railway station-Vadodara@22 km
Vadodara Airport@ 18.0
km Dahej port
Waterways connectivity for
import/export of raw materials and products.
Vadodara@19 km
Vadodara Airport@ 24.0
Dahej port Waterways
connectivity for import/export of
raw materials and products.
Vadodara@19
km Vadodara
Airport@ 23.0 Dahej port
Waterways connectivity for
import/export of raw materials and products.
Proximity to from raw material source and
market)
Easy available from Vadodara,
Ahmedabad and Ankleshwar
Easy available from Vadodara,
Ahmedabad and Ankleshwar
Easy available from Vadodara,
Ahmedabad and Ankleshwar
Infrastructure – Ranked on basis of
safe ground water blocks
Area falls under the safe zone as
per the CGWA classification.
Area falls under the safe Zone as
per the CGWA classification.
Area falls under the safe Zone as
per the CGWA classification.
Nearby unit No major highly polluting Chemical
industries in vicinity
No major highly polluting Chemical industries in
vicinity
Pigment Color, Dyes and Dye Intermediates
units nearby, may create FDA
approval issues for chances of contamination by
neighboring unit
Water Quality Saline with TDS
level (Around 1550 mg/L) and
Electric Conductivities (2250 Micro
mhos/cm)
Compare to less
saline with TDS level (1092 mg/L)
and Electric Conductivities (1580 Micro
mhos/cm)
Saline with TDS
level (1925 mg/L) and
Electric Conductivities (2770 Micro
mhos/cm )
Major criteria for selection of this site are:
No forest land involved and land is converted into non-agriculture
activity
No Religious and Historic Places or Archaeological Monuments within
10 km radius from the project site.
Other required facilities like infrastructure, communication, medical
facilities, unskilled & skilled manpower, fuel, water, power, and raw
materials, are readily available, too.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 5-4
No prime agricultural land converted into industrial site (Proposed
Land yields poor agriculture productivities due to non-irrigated land
Land area is sufficiently large to provide space for appropriate EMS.
The site boundary is approachable at about 1.0 km from Vadodara to
Jambusar Highway (SH-16).
Required facilities like infrastructure, communication, medical facilities,
fuel, water, power, unskilled & skilled manpower, raw materials, road
network etc. are easily available at this location.
There is no Rehabilitation and Resettlement involved.
Nearest city Vadodara is about 19 km away from the site, which is
having connectivity with other parts of the country by road, rail & air.
Therefore, project proponent has considered this site/location.
Considering above all aspect, location Site # 2 is better than the
Site-1 & Site-3.
5.3 PROCESS ALTERNATIVE
Production Technology
Reynish will have a team of scientists engaged in R&D activities, work on
differentiated medicines for the future. Proposed technology of production
is result of R & D and no alteration is currently with the proponent.
Wastewater Treatment Technology
Process effluent (Concentrated stream) along with wastewater of
scrubber, washing and utility will be taken to RO after primary and
secondary treatment. RO reject will be sent to MEE; RO permeate and
condensate of MEE will be reused. Domestic wastewater will be disposed
to soak pit. Thus, achieving Zero Liquid Discharge (ZLD). Thus proven,
most feasible and best available technology will be used for wastewater
management and no other alternatives are with the proponent.
Air Pollution Control Technology
Flue gas emission is due to the combustion of fuel Agro briquette in
boiler, Thermic Fluid Heater and Hot Air Generator. Multi Cyclone, bag
filter & water scrubber will be installed as APCM for each flue gas
emission source. Process gas emission will be from the stack attached to
process reactors and vent of Spin flash dryers (SFD)/ Fluid Based Dryer
(FBD)/Rotary Vacuum Dryer (RVD). To control the process emission,
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 5-5
water and alkali scrubber will be provided. Spin flash dryers will be
equipped with in-built cyclone and bag filter. Thus proven, most feasible
and best available technology will be used for Air Pollution Control and no
other alternatives are currently with the proponent.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 6-1
Chapter-6
Environmental Monitoring Programme
6.1 PRELUDE
Environment monitoring is the sampling and analysis tool to know the
environment conditions at particular time. The record of environmental
monitoring is most important as the environmental changes are slow in
nature and impact appears after many years. Environmental Monitoring is
the technical heart of assessment of environmental and social impacts
arising due to implementation of the proposed project. An equally
essential element of this process is to develop measures to eliminate,
offset or reduce impacts to acceptable levels during implementation and
operation of projects. The integration of such measures into project
implementation and operation is supported by clearly defining the
environmental requirements within an Environmental Management Plan.
Reynish Pharmachem Pvt. Ltd. proposed to manufacture bulk drugs
with production capacity of 50 MT/month. The environmental monitoring
programme is developed as below.
6.2 ENVIRONMENT MONITORING PROGRAM
The periodically monitoring of Environmental parameters like air, water,
noise, soil and performance of pollution control facilities and safety
measures in the plant are vital for proper Environmental management of
any industrial project. Therefore, the company shall create environmental
monitoring facilities by the environmental and safety department to
monitor air and water pollutants as per the guideline of GPCB & CPCB.
Moreover, air and water quality shall be monitored by outside agencies
authorized by GPCB at regular frequencies. This department shall also
carry out periodical checkup of fire and safety equipments.
6.3 OBJECTIVE OF MONITORING PLAN
The basic objective of implementing a monitoring plan on a regular basis
is as follows:
To know the pollution status within the plant and its vicinity.
Generate data for corrective action in respect of pollution.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 6-2
Correlate the production operations with emission & control
mechanism.
Examine the performance of pollution control system.
Assess the Environmental impacts.
Remedial measures and environment management plant to reverse
the impacts.
6.4 SCHEDULE FOR ENVIRONMENT MONITORING
The environmental monitoring will be scheduled on regular interval to
assess the conditions. The record of these monitoring will be compared
with the baseline study to know the changes in environmental conditions.
The post-project environmental monitoring suggested herewith should be
as per the following guideline.
The highlights of the integrated environmental monitoring plan are:
The stack monitoring facilities like ladder, platform and porthole at all
the stacks will be maintained in good condition.
Regular monitoring of all gaseous emissions from stacks/vents.
The performance of air pollution control equipment evaluated based
on these monitoring results.
Water consumption will be recorded daily.
As far as possible, noise curbed at its source, with the help of
acoustic hoods and other such noise reducing equipment. Regular
noise level monitoring will be carried out.
Greenbelt will be properly maintained and new plantation
programmes will be undertaken frequently.
Continuous environmental awareness programmes will be carried out
for the employees and also in the surrounding villages.
6.5 AMBIENT AIR QUALITY MONITORING
At Reynish Pharmachem Pvt. Ltd., Flue gas emission is due to the
combustion of fuel Agro briquette in boiler, Thermic fluid heater and Hot
air generator. Multi Cyclone, bag filter & water scrubber will be installed
as APCM for each flue gas stack. Process gas emission will be from the
stack attached to process reactors and vents of Spin flash dryers
(SFD)/Fluid Based Dryer (FBD)/Rotary Vacuum Dryer (RVD). To control
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 6-3
the process emission, water and alkali scrubber will be provided.
SFD/FBD/RVD will be equipped with in-built cyclone and bag filter.
Scheme for monitoring ambient air quality, stack emissions and fugitive
emissions are proposed. The ambient air quality monitoring systems are
recommended for monitoring the ground level concentrations and fugitive
emissions around the plant. Unit should install three monitoring stations
around its battery limit (at 1200 as per guideline) for monitoring PM, SO2
and NOx. The combined data will provide overall characteristic and
emission from the industry. Besides this, stack emissions monitoring as
per SPCB guidelines shall be carried out. Proposed monitoring schemes
are mentioned in Table 6.1.
6.6 WATER ENVIRONMENT MONITORING
Total industrial wastewater generation will be 141 KLD. The main source
of the industrial wastewater generation will be from process including lab
and scrubber (99 KLD), washing (10 KLD), utilities (Boiler & cooling - 10
KLD), and water treatment (22 KLD). Domestic wastewater generation
will be 4.0 KLD.
Process effluent (Concentrated stream) along with wastewater of
scrubber, washing and utility will be taken to RO after primary and
secondary treatment. RO reject will be sent to MEE; RO permeate and
condensate of MEE will be reused. Domestic wastewater will be disposed
to soak pit. Thus, achieving Zero Liquid Discharge (ZLD). ETP sludge
and MEE salt will be disposed to approve TSDF site. Domestic effluent of
4.0 KLD will be disposed to soak pit. The detail of water usage and
wastewater generation is provided comprehensively in Chapter 2.
Proposed monitoring schemes are mentioned in Table 6.1.
6.7 NOISE ENVIRONMENT MONITORING
Main source of noise generation at Reynish Pharmachem Pvt. Ltd. will be
boilers, D.G. set, process plant, vehicular transportation & other
machineries. Monitoring of noise levels is essential to assess the efficacy
of maintenance schedules undertaken to reduce noise levels and noise
protection measures. A good quality digital sound pressure level meter is
essential for this purpose. Proposed monitoring schemes are mentioned
in Table 6.1.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 6-4
Table: 6.1 Environment Monitoring Plan
Nature of
Analysis
Frequency of
analysis with its analyzer
Parameters No. of
samples
Method of
Monitoring
Wastewater analysis
Monthly by external agency
pH, TDS, SS, COD, BOD, Oil
& Grease, etc.
2-3 samples APHA-AWWA 23rd edition
Stack Monitoring of
each stack
Monthly by external agency
PM, SO2, NOX, HCl
All stacks Stack monitoring kit
Ambient Air
Quality Monitoring
Monthly for 24
hours or as per the statutory
conditions by external agency
PM10, PM2.5,
SO2, NOX, HCl
3-5 locations RDS, Fine
particulate sampler
Noise level Monthly as per the statutory
conditions by external agency
Noise level 6-8 locations (Nr. Main gate,
Nr. boiler, Nr. D.
G. Set, Process
area etc.)
Sound Level Meter
Work zone fugitive
monitoring
Monthly by external agency
RPM, VOCs, acid mist
2-3 locations Personal sampler, VOC
sampler
Health check-up of
workers
As per the statutory
guideline
All workers ---
**Rs. 3.0 Lakhs per annum are allocated for Environment Monitoring.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-1
Chapter-7
Additional Studies (A) HAZARD ANALYSIS & RISK ASSESSMENT
7.1 INTRODUCTION
Industrial plants deal with materials, which are generally hazardous in
nature by virtue of their intrinsic chemical properties or their operating
temperatures or pressures or a combination of these. Fire, explosion,
toxic release or combinations of these are the hazards associated with
industrial plants using hazardous chemicals. More comprehensive,
systematic and sophisticated methods of Safety Engineering, such as,
Hazard Analysis and Quantitative Risk Assessment have now been
developed to improve upon the integrity, reliability and safety of
industrial plants.
The primary emphasis in safety engineering is to reduce risk to human
life, property and environment. Some of the more important methods
used to achieve this are:
Quantitative Risk Analysis: Provides a relative measure of the
likelihood and severity of various possible hazardous events by
critically examining the plant process and design.
Work Safety Analysis: The technique discerns whether the plant
layout and operating procedures in practice have any inherent
infirmities.
Safety Audit: Takes a careful look at plant operating conditions, work
practices and work environments to detect unsafe conditions.
Together, these three broad tools attempt to minimize the chances of
accidents occurring. Yet, there always exists, no matter how remote,
probability of occurrence of a major accident. If the accident involves
highly hazardous chemicals in sufficiently large quantities, the
consequences may be serious to the plant, to surrounding areas and the
populations residing therein.
7.2 RISK ASSESSMENT-Identification of Hazards
A three „levels‟ risk assessment approach has been adopted for the M/s.
Reynish Pharmachem Pvt. Ltd. for their greenfield project at 504, 505,
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-2
507, Village: Dabhasa, Ta.: Padra, District: Vadodara, Gujarat. The risk
assessment levels are generally consistent with the practices encountered
through various assignments for medium and large chemical complexes.
The brief outline of the three tier approach is given below:
Level 1 – Risk Screening
This is top-down review of worst-case potential hazards/risks, aimed
primarily at identifying plant sites or areas within plant, which pose the
highest risk. Various screening factors considered include:
Inventory of hazardous materials;
Hazardous Materials properties;
Storage conditions (e.g. temperature and pressure);
Location sensitivity (distance to residential areas/populace).
The data/information is obtained from plant. The results provide a
relative indication of the extent of hazards and potential for risk
exposure.
Level 2 – Major Risk Survey (Semi - Quantitative)
The survey approach combines the site inspection with established risk
assessment techniques applied both qualitative as well quantitative
mode. The primary objective is to identify and select major risks at a
specific location in the plant considering possible soft spots/weak links
during operation/maintenance. Aspects covered in the risk usually
include:
Process Hazards;
Process Safety Management Systems;
Fire Protection and Emergency response equipment and programs.
Security Vulnerability;
Impact of hazards consequences (equipment damage, business
interruption, injury, fatalities);
Qualitative risk identification of scenarios involving hazardous
materials;
Risk reduction measures.
Selection of critical scenarios and their potential of damage provide
means of prioritising mitigative measures and allocate the resources to
the areas with highest risks.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-3
Level 3 – Quantitative Risk Assessment (Deterministic)
This is the stage of assessment of risks associated with all credible
hazards (scenarios) with potential to cause an undesirable outcome such
as human injury, fatality or destruction of property. The four basic
elements include:
Hazards identification utilizing formal approach (Level 2, HAZOP etc.);
Frequency Analysis. Based on past safety data (incidents/accidents);
Identifying likely pathway of failures and quantifying the toxic /
inflammable material release;
Hazards analysis to quantify the consequences of various hazards
scenarios (fire, explosion, BLEVE, toxic vapour release etc.).Establish
minimum value for damage (e.g. IDLH, over pressure, radiation flux)
to assess the impact on environment.
Risk Quantification: Quantitative techniques are used considering
effect/impact due to weather data, population data, and frequency of
occurrences and likely hood of ignition/toxic release. Data are
analyzed considering likely damage (in terms of injury/fatality,
property damage) each scenarios is likely to cause.
QRA provides a means to determine the relative significance of a number
of undesired events, allowing analyst and the team to focus their risk
reduction efforts where they will be beneficial most.
Reynish Pharmachem Pvt. Ltd. project is hazardous in nature. The
QRA for this plant is based on Level 1 and Level 2. Table 2.3 in Chapter
2 gives the list of products (and their monthly production capacity) to be
manufactured in the proposed project.
7.3 HAZARDOUS MATERIALS STORAGE
The solid raw materials will be received in bags or drums and will be
stored in chemicals godowns. The bulk storages of hazardous materials
are given in the Table 7.1 below.
Table 7.1: Bulk Storage of Hazardous Chemicals
Sr.
No.
Name of solvent Maximum storage capacity
(KL)
1 Methanol 10 KL tank
2 Dichlo Methane 10 KL tank
3 Iso propyl alcohol 5 KL tank
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-4
4 Ethyl Acetate 5 KL tank
5 Sodium Hydroxide Lye 5 KL tank
6 HCl (30-32%) 10 KL tank
7 Sulphuric Acid 5 KL tank
8 Acetone 5 KL tank
9 Toluene 0.2 KL x 5 Drum=1.0 KL
10 Chloroform 0.2 KL x 5 Drum=1.0 KL
11 Benzoyl chloride 0.2 KL x 5 Drum=1.0 KL
12 Hexane 0.2 KL x 5 Drum=1.0 KL
13 Nitric acid 0.08 KL x 20 Carboys =1.6 KL
14 Dimethyl formamide 0.2 KL x 5 Drum=1.0 KL
7.4 RISK SCREENING APPROACH
Proposed Plant: Risk screening of Reynish plant was undertaken
through process study and study of data/information provided by
Reynish. Data of major/bulk storages of raw materials, intermediates and
other chemicals were collected. MSDS of hazardous chemicals were
studied vis a vis their inventories and mode of storage. Unit will be used
numbers of hazardous chemicals and also producing organic chemicals –
hazardous in nature. The chemicals stored in bulk (liquid or gaseous) and
defined under MSHIC Rule will be considered for detailed analysis.
The solid materials will be kept in bags or drums and will be stored in
chemicals godowns. The products (liquid or solid) will be packed in drums
and stored in product godowns as per market demand. The bulk storages
of hazardous materials are given in the Table 7.1 above. In addition,
Reynish will store fuels mainly Agro briquette for boiler, TFH & HAG and
HSD (in limited quantity) for DG Set (during power failure only). The solid
material-powder or granules spillage can results in polluting small area
only. The damage to personnel can be through ingress-dermal (if
individual come in contact), oral (if individual food gets infected through
fugitive dust) or inhalation (fugitive dust). The main route is fugitive dust
which in covered area will move to short distance only. The risk is
through liquid/gaseous materials which are volatile material. The toxic
vapours due to spillage of such material can travel to some distance (as
they are stored in covered godowns) and cause damage.
Reynish will be producing 15 Bulk Drug products. All Reynish products are
solid (Either simple Solid or crystalline solid or powder). Many of the
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-5
Reynish raw materials are hazardous in nature. However, hazards
potential (for damage) of materials/chemicals to plant personnel,
environment and off-site area is different for different materials. Reynish
will be using a number of raw materials but only 14 are stored in bulk.
The raw materials coming under hazardous category as specified by
MSIHC Rules, 1989 (including subsequent amendments) is given in Table
7.2 below:
Table: 7.2 Hazards Analysis – Raw materials (stored in Bulk)
Sr.
No.
Raw material Sr. No & Threshold
Quantity (TQ in MT) as
per MSHIC Rules
Chemicals Hazards Potential
Sch-1,
Part-II
Sch-2,
Part-I
Sch-3,
Part-I
1. Methanol
CAS No: 67-56-1
UN No: 1230
377 --- --- Highly flammable, Exposure to
excessive vapor causes eye
irritation, head- ache, fatigue and
drowsiness. High concentrations
can produce central nervous
system depression and optic
nerve damage.
2. Dichloromethane
CAS No.: 75-09-2
UN No.: 1593
-- --- --- Very hazardous in case of eye
contact (irritant), of ingestion, of
inhalation. Hazardous in case of
skin contact (irritant, permeator).
Inflammation of the eye is
characterized by redness,
watering, and itching.
3. Iso Propyl alcohol
CAS No: 67-63-0
UN No: 1219
334 --- --- Highly flammable, Vapors cause
mild irritation of eyes and upper
respiratory tract; high
concentrations may be anesthetic.
4. Ethyl acetate
CAS No: 141-78-6
UN No: 1173
247 --- --- Hazardous in case of ingestion, of
inhalation. Slightly hazardous in
case of skin contact (irritant,
permeator), of eye contact
(irritant).
5. Sodium Hydroxide
CAS No: 1310-730-2
UN No: 1823
571 --- --- Not flammable; Corrosive to
metals and tissue. Hazardous.
6. Caustic Lye
CAS No.: 1310-73-2
UN No.: 1824
--- --- --- Very hazardous in case of skin
contact (corrosive, irritant,
permeator), of eye contact
(irritant, corrosive), of ingestion.
Slightly hazardous in case of
inhalation (lung sensitizer).
7. Hydrochloric acid
CAS No: 7647-01-0
UN No: 1789
313 --- --- Inhalation of fumes results in
coughing and choking sensation,
and irritation of nose and lungs.
Liquid causes burns
8. Sulphuric acid
CAS No: 7664-93-9
UN No: 1830
591 --- --- Corrosive to all body tissues.
Inhalation of vapor may cause
serious lung damage. Contact
with eyes may result in total loss
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Sr.
No.
Raw material Sr. No & Threshold
Quantity (TQ in MT) as
per MSHIC Rules
Chemicals Hazards Potential
Sch-1,
Part-II
Sch-2,
Part-I
Sch-3,
Part-I
of vision. Skin contact may
produce severe necrosis.
9. Acetone
CAS No. 67-64-1
UN No: 109
4 --- --- Hazardous in case of skin contact
(irritant), of eye contact (irritant),
of ingestion, of inhalation. Slightly
hazardous in case of skin contact
(permeator).
10. Toluene
CAS No: 108-88-3
UN No: 1294
628 -- --- The substance may be toxic to
blood, kidneys, the nervous
system, liver, brain, central
nervous system (CNS). Repeated
or prolonged exposure to the
substance can produce target
organs damage.
11. Chloroform
CAS No: 67-66-3
UN No: 1888
130 --- --- Toxic by inhalation. Irritating to
respiratory system. Exposure to
decomposition products may
cause a health hazard. Serious
effects may be delayed following
exposure. Toxic if swallowed.
Aspiration hazard if swallowed.
Can enter lungs and cause
damage. Irritating to skin.
12. Benzoyl chloride
CAS No: 98-88-4
UN No: 1736
65 --- --- A colorless fuming liquid with a
pungent odor. Irritating to skin
and eyes. Corrosive to metals and
tissue.
13. Hexane
CAS No: 110-54-3
UN No: 1208
306 --- --- Inhalation causes irritation of
respiratory tract, cough, mild
depression, cardiac arrhythmias.
Aspiration causes severe lung
irritation, coughing, pulmonary
edema; excitement followed by
depression. Ingestion causes
nausea, vomiting, swelling of
abdomen, headache, depression.
14. Nitric Acid
CAS No.: 7697-37-2
UN No.: 2031
423 --- -- Very hazardous in case of skin
contact (corrosive, irritant,
permeator), of eye contact
(irritant, corrosive), of ingestion,
Slightly hazardous in case of
inhalation (lung sensitizer). Liquid
or spray mist may produce tissue
damage particularly on mucous
membranes of eyes, mouth and
respiratory tract.
15. Dimethyl formamide
CAS No.: 68-12-2
UN No.: 2265
--- --- --- Irritation of eyes, skin and nose.
May cause nausea
Note: TQ-I: Threshold quantity (for application of rules 4,5,7 to 9 and 13 to 15)
TQ-II: Threshold quantity (for application of rules 10 to 12)
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Table: 7.3 Properties of Hazardous materials
Chemicals Physical form
BP oC
FP oC
LEL %
UEL %
TLV ppm
LD50 mg/Kg or LC50 mg/l
Vapour Density
Specific Gravity
Methanol Liquid 64.5 12 6 36.5 250 LD50: 5628 LC50:64000
1.11 0.7915
Dichloro methane
Liquid 39.75 NA 12 19 50 LD50: 1600 LC50: --
2.93 1.32
Iso Propyl
alcohol
Liquid 82.5 18.3 2 12.7 400 LD50: 5045
LC50: --
2.07 0.84
Ethyl acetate Liquid 77 -4.4 2.2 9 400 LD50: 5620 LC50:16000
3.04 0.902
Sodium hydroxide
Solid 1388 NA NA NA 2 NA NA 2.13
Caustic Lye Liquid 140 NA NA NA 2 mg/m3
NA 0.62 (Water)
1.53
Hydrochloric acid
Liquid 108.58 NA NA NA 5 LD50: 900 LC50: 3124
1.267 1.1
Sulphuric acid Liquid 270 NA NA NA 3 LD50: 2140
LC50: 510
3.4 1.84
Acetone Liquid 56.2 -20 2.6 12.8 750 LD50: 5800 LC50: 50100
2 0.79
Toluene Liquid 110.6 4.44 1.1 7.1 300 LD50: 636 LC50: 440
3.1 0.8636
Chloroform Liquid 61 NA NA NA 10 LD50: 695 LC50: 47702
4.36 1.484
Benzoyl chloride
Liquid 198 72 1.2 4.9 1 LD50: 1900 LC50: 1870
4.88 1.211
Hexane Liquid 69 -26 1.2 7.5 50 LD50: 25000
LC50: 48000
2.97 0.659
Nitric acid Liquid 121 NA NA NA 4 NA 2.5 1.408
Dimethyl formamide
Liquid 153 58 2.2 15.2 10 LD50: 2800 LC50: 15
0.95 2.51
NA= Not Available
Note:
1. Oral Toxicity (OT) in LD50 (mg/kg)
2. Dermal Toxicity (DT) in LD50 (mg/kg)
3. Inhalation Toxicity in LC50 (mg/l) [4 hrs.]
Sr.
No.
Toxicity Oral toxicity
LD50 (mg/kg)
Dermal
toxicity LD50 (mg/kg)
Inhalation
toxicity LC50(mg/l)
1. Extremely toxic >5 <40 <0.5
2. Highly toxic >5-50 >40-200 <0.5-2.0
3. Toxic >50-200 >200-1000 >2-10
As detailed in the above table out of 14 raw materials stored in bulk,
none are listed in Schedule 2 and 3 of MSIHC Rules. None of the raw
materials are extremely toxic.
7.4.1 Acute Exposure Guideline Levels (AEGLS)
AEGLs estimate the concentrations at which most people - including
sensitive individuals such as old, sick, or very young people - will begin to
experience health effects if they are exposed to a hazardous chemical for
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-8
a specific length of time (duration). For a given exposure duration, a
chemical may have up to three AEGL values, each of which corresponds
to a specific tier of health effects. AEGLs of the materials at Reynish are
as below.
AEGL-3 is “the airborne concentration of a substance above which it is
predicted that the general population, including susceptible individuals,
could experience life-threatening adverse health effects or death.”
10 min 30 min 60 min 4 hr 8 hr Unit
Methanol (67-56-1)
AEGL 1 670 670 530 340 270 ppm
AEGL 2 11000* 4000 2100 730 520 ppm
AEGL 3 40000** 14000* 7200* 2400 1600 ppm
Dichloromethane (75-09-2)
AEGL 1 290 230 200 NR NR ppm
AEGL 2 1700 1200 560 100 60 ppm
AEGL 3 12000 8500 6900 4900 2100 ppm
Hydrogen Chloride (7647-01-0)
AEGL 1 1.8 1.8 1.8 1.8 1.8 ppm
AEGL 2 100 43 22 11 11 ppm
AEGL 3 620 210 100 26 26 ppm
Sulphuric acid (7664-93-9)
AEGL 1 0.20 0.20 0.20 0.20 0.20 mg/m3
AEGL 2 8.7 8.7 8.7 8.7 8.7 mg/m3
AEGL 3 270 200 160 110 93 mg/m3
Acetone (67-64-1)
AEGL 1 200 200 200 200 200 ppm
AEGL 2 9300* 4900* 3200* 1400 950 ppm
AEGL 3 ** 8600* 5700* 2500 1700 ppm
Toluene(108-88-3)
AEGL 1 67 67 67 67 67 ppm
AEGL 2 1400 760 560 310 250 ppm
AEGL 3 10000 5200 3700 1800 1400 ppm
Chloroform (67-66-3)
AEGL 1 NR NR NR NR NR ppm
AEGL 2 120 80 64 40 29 ppm
AEGL 3 4000 4000 3200 2000 1600 ppm
Hexane (110-54-3)
AEGL 1 NR NR NR NR NR ppm
AEGL 2 4000 2900 2900 2900 2900 ppm
AEGL 3 12000 8600 8600 8600 8600 ppm
Nitric acid (7697-37-2)
AEGL 1 0.16 0.16 0.16 0.16 0.16 ppm
AEGL 2 43 30 24 6 3 ppm
AEGL 3 170 120 92 23 11 ppm
NR = Not recommended due to insufficient data * indicates value is 10-49% of LEL. Safety consideration against explosions must be taken into account. ** indicates value is 50-99% of LEL. Extreme safety consideration against explosions
must be taken into account.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-9
AEGL-2 is “the airborne concentration of a substance above which it is
predicted that the general population, including susceptible individuals,
could experience irreversible or other serious, long-lasting adverse
health effects or an impaired ability to escape.”
AEGL-1 is “the airborne concentration of a substance above which it is
predicted that the general population, including susceptible individuals,
could experience notable discomfort, irritation, or certain asymptomatic
no sensory effects.”
7.4.2 Emergency Response Planning Guidelines (ERPGs)
ERPGs estimate the concentrations at which most people will begin to
experience health effects if they are exposed to a hazardous airborne
chemical for 1 hour. (Sensitive members of the public - such as old, sick,
or very young people - aren't covered by these guidelines and they may
experience adverse effects at concentrations below the ERPG values).
ERPGs of the materials at Reynish are as below.
ERPG-1 ERPG-2 ERPG-3 Unit
Acetic acid 5* 35 250 ppm
Chloroform NA 50 5000 ppm
Dimethylamine 0.6* 100 350 ppm
Hydrogen Chloride 3* 20 150 ppm
Methanol 200 1000 5000 ppm
Sodium Hydroxide 0.5 5.0 50 mg/m3
Sulphuric Acid 2 10 120 mg/m3
Dichloromethane 300 750 4000 ppm
Toluene 50* 300 1000 ppm
*indicates that odor should be detectable near ERPG-1;NA=Not Appropriate
The 3 ERPG tiers are defined as follows:
ERPG-3 is "the maximum airborne concentration below which it is
believed that nearly all individuals could be exposed for up to 1 hour
without experiencing or developing life-threatening health effects."
ERPG-2 is "the maximum airborne concentration below which it is
believed that nearly all individuals could be exposed for up to 1 hour
without experiencing or developing irreversible or other serious health
effects or symptoms which could impair an individual's ability to take
protective action."
ERPG-1 is "the maximum airborne concentration below which it is
believed that nearly all individuals could be exposed for up to 1 hour
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without experiencing other than mild transient health effects or
perceiving a clearly defined, objectionable odor."
7.5 QRA APPROACH
Identification of hazards and likely scenarios (based on Level-1 and
Level-2 activities) calls for detailed analysis of each scenario for potential
of damage, impact area (may vary with weather conditions/wind
direction) and safety system in place. Subsequently each incident is
classified according to relative risk classifications provided in Table 7.4.
Table 7.4: Risk Classification
Stage Description
High
(> 10-2/yr.)
A failure which could reasonably be expected to occur within
the expected life time of the plant. Examples of high failure likelihood are process leaks or single
instrument or valve failures or a human error which could result in releases of hazardous materials.
Moderate (10-2 --10-4/yr.)
A failure or sequence of failures which has a low probability of occurrence within the expected lifetime of the plant.
Examples of moderate likelihood are dual instrument or valve failures, combination of instrument failures and human errors,
or single failures of small process lines or fittings.
Low
(<10-4)
A failure or series of failures which have a very low probability
of occurrence within the expected lifetime of plant. Examples of „low‟ likelihood are multiple instruments or valve
failures or multiple human errors, or single spontaneous failures of tanks or process vessels.
Minor Incidents Impact limited to the local area of the event with potent for
„knock – on- events‟
Serious Incident
One that could cause: Any serious injury or fatality on/off site;
Property damage of $ 1 million offsite or $ 5 million onsite.
Extensive
Incident
One that is five or more times worse than a serious incident.
Assigning a relative risk to each scenario provides a means of prioritising
associated risk mitigation measures and planned actions.
7.6 THERMAL HAZARDS
In order to understand the damages produced by various scenarios, it is
appropriate to understand the physiological/physical effects of thermal
radiation intensities. The thermal radiation due to tank fire usually results
in burn on the human body. Furthermore, inanimate objects like
equipment, piping, cables, etc. may also be affected and also need to be
evaluated for damages. Table 7.5, Table 7.6 and Table 7.7,
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respectively give tolerable intensities of various objects and desirable
escape time for thermal radiation. Thermal hazards could be from fires or
explosion. Fire releases energy slowly while explosion release energy very
rapidly (typically in micro seconds). Explosion is rapid expansion of gases
resulting in rapidly moving shock wave. Explosion can be confined (within
a vessel or building) or unconfined (due to release of flammable gases).
BLEVE (boiling liquid expanding vapour explosion) occurs if a vessel
containing a liquid at a temperature above its atmospheric boiling point
ruptures. The subsequent BLEVE is the explosive vaporization of large
fraction of its vapour contents; possibly followed by combustion or
explosion of the vaporized cloud if it is combustible. Thermal hazards
have been considered for various scenarios including- Fire in inflammable
chemicals storage tanks.
Table 7.5: Effects due to Incident Radiation Intensity
Incident Radiation
kW/m2
Damage Type
0.7 Equivalent to Solar Radiation
1.6 No discomfort on long duration
4.0 Sufficient to cause pain within 20 sec. Blistering of
skin (first degree burn are likely).
9.5 Pain threshold reached after 8 sec. Second degree burn after 20 sec.
12.5 Minimum energy required for piloted ignition of wood, melting of plastic tubing etc.
25
Minimum Energy required for piloted ignition of
wood, melting, plastic tubing etc.
37.5 Sufficient to cause damage to process equipment.
62.0 Spontaneous ignition of wood.
Table 7.6: Thermal Radiation Impact to Human
Exposure
Duration
Radiation Energy
{1% lethality;
kW/m2}
Radiation Energy
for 2nd degree
burns; kW/m2
Radiation Energy
for 1st degree
burns; kW/m2
10 sec 21.2 16 12.5
30 9.3 7.0 4.0
Table 7.7: Tolerable Intensities for Various Objects
Sl.
No.
Objects Tolerable Intensities
(kw/m2)
1 Drenched Tank 38
2 Special Buildings (No window, fire proof doors)
25
3 Normal Buildings 14
4 Vegetation 10-12
5 Escape Route 6 (up to 30 secs.)
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6 Personnel in Emergencies 3 (up to 30 secs.)
7 Plastic Cables 2
8 Stationary Personnel 1.5
7.7 DAMAGE DUE TO EXPLOSION
The explosion of a dust or gas (either as a deflagration or detonation)
results in a reaction front moving outwards from the ignition source
preceded by a shock wave or pressure front. After the combustible
material is consumed the reaction front terminates but the pressure wave
continues its outward movement. Blast damage is based on the
determination of the peak overpressure resulting from the pressure wave
impacting on the object or structure. Damage estimates based on
overpressure are given in Table 7.8 below:
Table 7.8: Damage due to Overpressure
Sr.
No.
Overpressure
(psig/bar)
Damage
1. 0.04 Loud Noise/sonic boom glass failure
2. 0.15 Typical pressure for glass failure
3. 0.5 - 1 Large and small windows usually shattered
4. 0.7 Minor damage to house structure
5. 1 Partial demolition of houses, made uninhabitable
6. 2.3 Lower limit of serious structure damage
7. 5 - 7 Nearly complete destruction of houses
8. 9 Loaded train box wagons completely demolished
9. 10 Probable total destruction of houses
10. 200 Limits of crater lip
In Reynish case explosion probability is remote.
7.8 TOXIC RELEASE
Hazardous materials handled and stored in bulk in Reynish complex are
hazardous materials (as detailed in Table 7.1) as defined in MSHIC rules
and indicated in Table 7.2. Some of these chemicals are stored in bulk
(in tank farm). For toxic release the damage criteria considered is IDLH
concentration (if data are available). The Immediately dangerous to life
or health air concentration values (IDLH values) developed by the
National Institute for Occupational Safety and Health (NIOSH)
characterize these high-risk exposure concentrations and conditions and
are used as a component of respirator selection criteria first developed in
the mid-1970s. IDLH values are established (1) to ensure that the worker
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-13
can escape from a given contaminated environment in the event of failure
of the respiratory protection equipment and (2) to indicate a maximum
level above which only a highly reliable breathing apparatus, providing
maximum worker protection, is permitted. IDLH of all the materials
stored in bulk at Reynish are as below.
IDLH Value Unit
Acetic acid 50 ppm
Acetone 2500 ppm
Chloroform 500 ppm
Dichloromethane 2300 ppm
Dimethylamine 500 ppm
Ethyl Acetate 2000 ppm
Hexane 1100 ppm
Hydrochloric acid 50 ppm
Methanol 6000 ppm
Sodium Hydroxide 10 mg/m3
Nitric acid 25 ppm
Sulfuric Acid 15 mg/m3
Isopropyl Alcohol 2000 ppm
7.9 ACID/ALKALI HAZARDS
Various hazards that can occur due to the acid and alkali incidents are-
Skin irritation and corrosive effects after spillage
Spill pool evaporation of sulphuric/hydrochloric acid or Caustic lye
storage tanks catastrophic failure are limited only
Catastrophic failure giving rise to spill pool evaporation dispersion
up to LC50, IDLH and TLV level
The more hazardous scenario likely is if spilled acid comes in contact with
metal and hydrogen is generated resulting in fire/explosion hazards.
Based on the outcome of the risk assessment, following recommendation
has been made to avoid any risk associated with the storage and use of
acids in the plant:
Double drain valve will be provided to sulphuric acid storage tank.
Full body protection will be provided to operator.
Caution note and emergency first aid will be displayed
All employees will be trained for use of emergency first aid.
Safety shower and eye wash will be provided in storage tank area
and plant area.
Total close process will be adopted for Sulphuric acid handling.
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Dyke wall will be provided to storage tank
Tanker unloading procedure will be prepared.
SOP will be prepared for Hydrochloric acid handling.
Training programme will be conducted for safe handling and
emergency handling of Acids.
In storage tank area, reaction with water generating fumes should
be displayed and avoided.
Suitable extinguishing media-Extinguish with dry powder/sand. DO
NOT USE WATER.
7.10 LIKELY FAILURE SCENARIOS
Few likely failure scenarios have been selected after critical appraisal of
raw materials and storage inventories. Failure scenarios selected are as
given in Table 7.9 below:
Table 7.9: Different Failure Scenarios
S. No. Scenario Remark
RM-1 Methanol tank BLEVE Thermal
RM-2 Dichloromethane tank leakage Toxic
RM-3 Ethyl Acetate tank leakage pool fire Thermal
RM-4 Acetone tank leakage Toxic
RM-5 Hydrochloric Acid tank leakage Toxic
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(B) QUANTITATIVE RISK ASSESSMENT & CONSEQUENCE ANALYSIS
7.11 PREAMBLE
In the previous Chapter we have carried out the hazards analysis of the
Reynish complex considering various aspects including bulk storages of
hazardous chemicals, plant process system, plant incidents/accidents
records, critical appraisal and discussion at site for soft spots in the plant
etc. Based on the hazards analysis few critical scenarios have been
selected for QRA and consequence analysis. QRA quantifies vulnerable
zones for a conceived incident with various levels of severity.
Consequence calculations for risk assessment are invariably in terms of
percentage of fatalities but for emergency handling, fatalities are of no
interest saving lives is the main objectives then. The injury criteria have
to be agreed in terms of thermal load or toxic concentration versus
exposure duration in the first instance.
In consequence calculation, use is made of a number of calculation
models to estimate the physical effects of an accident (spill of hazardous
material) and to predict the damage (lethality, injury, material
destruction and other property damage). The risk assessment modelling
can be roughly divided into three groups:
Determination of source strength parameters;
Determination of consequential effects;
Determination of damage or damage distances (with specific severity
rates)
7.11.1 Weather Effect
The effect of ambient conditions on the impact of fire/heat radiation and
GLC of hazardous/toxic material can be beneficial as well as harmful. A
high wind (turbulence) can dilute the toxic material while stable
environment can extend the reach of IDLH or IT (inhalation LC50 rats for
products) concentration to long distance. Any inflammable gas/vapour
release in turbulent weather will soon dilute the hazardous gases below
LEL and thus prevent the disaster.
7.12 INCIDENTS IMPACTS
The identified failure scenarios (Table 7.9) have been analyzed (Using
ALOHA and EFFECT Modules) for the impact zones considering damage
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-16
due to thermal and toxic impacts. Each incident will have Impact on the
surrounding environment which in extreme case may cross plant
boundary. The impact zones for various scenarios are given in Table
7.10.
Figure-7.1 Methanol Tank BLEVE — Thermal Impact Zone
Figure-7.2 Dichloromethane Tank Leakage — Toxic Impact Zone
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-17
Figure-7.3 Ethyl Acetate Tank Leakage Pool Fire —Thermal Impact Zone
Figure-7.4 Acetone Tank Leakage — Toxic Impact Zone
Figure-7.5 Hydrochloric Acid Tank Leakage – Toxic Impact Zone
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-18
Table 7.10: Hazards Scenario Impact
Scenario Impact Zone (m)
Methanol tank
BLEVE
Red : 161 meters --- (10.0 kW/(sq m) = potentially lethal within 60 sec)
Orange: 234 meters --- (5.0 kW/(sq m) = 2nd degree burns within 60 sec)
Yellow: 369 meters --- (2.0 kW/(sq m) = pain within 60 sec)
Dichloromethane
tank leakage
Red : 79 meters --- (6900 ppm = AEGL-3 [60 min])
Orange: 378 meters --- (560 ppm = AEGL-2 [60 min])
Yellow: 739 meters --- (200 ppm = AEGL-1 [60 min])
Ethyl Acetate tank
leakage pool fire
Red : 29 meters --- (10.0 kW/(sq m) = potentially lethal within 60 sec)
Orange: 37 meters --- (5.0 kW/(sq m) = 2nd degree burns within 60 sec)
Yellow: 51 meters --- (2.0 kW/(sq m) = pain within 60 sec)
Acetone tank
leakage
Red : 59 meters --- (5700 ppm = AEGL-3 [60 min])
Orange: 88 meters --- (3200 ppm = AEGL-2 [60 min])
Yellow: 536 meters --- (200 ppm = AEGL-1 [60 min])
Hydrochloric Acid
tank leakage
Red : 14 meters --- (100 ppm = AEGL-3 [60 min])
Note: Threat zone was not drawn because effects of near-field patchiness
make dispersion predictions less reliable for short distances.
Orange: 32 meters --- (22 ppm = AEGL-2 [60 min])
Note: Threat zone was not drawn because effects of near-field patchiness
make dispersion predictions less reliable for short distances.
Yellow: 116 meters --- (1.8 ppm = AEGL-1 [60 min])
7.13 CONSEQUENTIAL IMPACTS
The consequential impacts from each incident scenarios can be though
thermal, over pressure wave and toxic route. The damage can be on
plant personnel (and neighbouring residents in case incident crosses
boundary), property and also loss in production.
7.13.1 Thermal and Explosion Hazards
Incidents involving thermal hazards are mainly due to BLEVE and fire (in
tank farms). The impact (1st degree burn due to Methanol tank BLEVE) is
limited to ~161 m (i.e. within plant boundary and adjoining premises).
However the consequences can go to worse if the incidents lead to
domino effect to other tanks.
7.13.2 Toxic Hazards
Toxic hazards are mainly due to Dichloromethane, Acetone, and
Hydrochloric Acid tank leakage/spillage. The impact (AEGL-3) is limited to
~79 m (i.e. within plant boundary and adjoining premises). However,
their impact can cross the plant boundary and adjoining premises (if not
controlled in time).
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-19
7.13.3 Other Hazards
The other hazards in the plant include (but not limited to):
Other toxic hazards due to acids/other toxic spillages (mainly limited
to spillage area only).
Mechanical hazards due to machines/equipment.
Hazards due to individual soft spots like walking casually and noticing
a pit and falling or colliding/stumbling or slipping (not noticing a wet
place etc.).
7.13.4 Other Toxic Hazards
Acid spillage-its impact will be limited to spillage area. The spillage if
comes in contact with metal parts will produce hydrogen which is highly
flammable gas. Any person moving in area and getting splash will get the
injury. In addition the spillage will cause pollution problem. The spillage is
to be collected and neutralized for toxic contents before disposal.
7.14 OCCUPATIONAL HEALTH
Reynish will have a well-equipped first aid post. It will also have staff
personnel trained in first aid. Injured personnel will be immediately
rushed to hospital after giving first aid. All employees will have regular
medical checkup as per norms. An emergency vehicle/ambulance will
always (round the clock) available for meeting any eventuality.
Treatment of workers affected by accidental spillage of chemicals
There is wide range of chemicals present in the Chemical plants. The safe
cleanup of a chemical spill requires some knowledge of the properties and
hazards posed by the chemical & any added dangers posed by the
location of the spill. Employees must notify their immediate supervisor of
injury by spillage of chemicals or exposure to hazardous materials. All
injuries must be reported. Supervisor is responsible for reporting any
injuries or occupational illnesses to the management.
Following steps will be immediate taken by the Supervisor.
Identify spillage/leakages of hazardous chemicals
Chemical Exposure to Skin:
Immediately flush with cool water for at least 15 minutes. If there are no
visible burns, remove the cloth from burning part of body. Seek medical
attention if exposure/spillages occur major possible problems.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-20
Chemical Exposure to Skin – Serious:
Remove all contaminated clothing. Locate the nearest emergency shower
and soak for at least 15 minutes. Have someone contact the Hospital for
immediate medical attention.
Chemicals in Eyes:
Irrigate eyes for at least 15 minutes with tempered water from
emergency eyewash station. Remove contact lenses if there is. Notify the
management and immediate medical attention.
Acid Fumes:
Anyone overcome by fumes should be removed to fresh air. Never
attempt to enter a location where potentially dangerous fumes might
place you at risk. If someone is down, contact emergency personnel and
let them enter. Self-breathing apparatus is required for persons entering
the affected area. Seek medical attention for exposure as soon as
possible.
Chemical Spills:
The safe clean-up of an acid spill requires some knowledge of the
properties and hazards posed by the acid and any added dangers posed
by the location of the spill. If you believe a spill is beyond your capacity
to clean up, do not attempt to do so by your own, immediately contact to
nearest fire/emergency station. Spill kits with instructions, absorbents,
neutralizing agents if applicable, protective equipment, and sealable
waste buckets should be present in plant area.
Following Steps to be taken for ensuring health and safety of
workers engaged in handling of Hazardous materials
Identify chemicals to be used, amounts required, condition followed as
per the MSDS guideline.
Evaluate the hazards posed by the chemicals and the process
conditions. The evaluation should cover toxic, physical, reactive,
flammable, explosive as well as any other potential hazards posed by
the respective chemicals.
Select appropriate controls to minimize risk, including use of
engineering controls, administrative controls, and personal protective
equipment (PPE) to protect workers from hazards. The controls must
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-21
ensure that OSHA‟s Permissible Exposure Limits (PELs) are not
exceeded.
Avoid Underestimation of Risk of handling and its reaction.
Before working with chemicals, know the facility‟s policies and
procedures for how to handle an accidental spill or fire. Emergency
telephone numbers should be posted in a prominent area. Know the
location of all safety equipment and the nearest fire alarm and
telephone.
Provide popper Ventilation in the plant/process area.
Corrosive chemicals that require vented storage should be stored in
vented cabinets instead of in a chemical hood.
Local exhaust ventilation devices should be appropriate to the
operations in the plant.
Chemicals should be separated and stored according to hazard
category and compatibility.
Antidotes
Antidotes are used to reduce morbidity and mortality in certain
intoxications, but they are unavailable for most toxic agents. Antidotes
may reverse or reduce poisonous effects by a variety of means. They
may prevent absorption, bind and neutralize poisons directly, antagonize
end‐organ effects, or inhibit conversion to more toxic metabolites. The
antidotes considered to be stored at Reynish and/or supplied to nearest
hospital are shown below.
Name of Antidote Usage
Inj. Avil/ Inj. Dexona Allergic/Anaphylaxis Reaction
Inj. Bal Heavy Metal, Mercury, Lead, Arsenic
Inj. Sneak Venom Sneak Bites
Inj. Adrenalin/ Inj. Atropine Poisoning
Inj. Deriphyllin Abnormal Breathing
Inj. Voveran Pain Relief
Milk of Magnesia Gastric Problems
T.T For Tetanus
Calmpose (Diazepam) Convulsion
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-22
7.15 CONCLUSION & RECOMMENDATIONS
The hazard analysis and risk assessment of few possible selected incident
scenarios indicates that such incidents mostly are not limited to plant
battery limits and have impact on adjoining plants. There are possibilities
of domino effect and the secondary scenario not predictable can be worse
than the primary one.
Incidents involving thermal hazards are mainly due to BLEVE and fire (in
tank farms). The impact (1st degree burn due to Methanol tank BLEVE) is
limited to ~161 m (i.e. within plant boundary and adjoining premises).
Toxic hazards are mainly due to Dichloromethane, Acetone, and
Hydrochloric Acid tank leakage/spillage. The impact (AEGL-3) is limited to
~79 m (i.e. within plant boundary and adjoining premises). The direction
of impact will be in down wind direction (wind direction and speed varies
with season).
Some of the recommendations for Tank farm storage system are as given
below:
Provision of flame detectors/ thermal sensors at strategic locations in
the tank farm area.
Auto water deluge system on each bulk storage tank for inflammable
liquids. The system should automatically start taking signal from flame
detectors or thermal relay.
Fixed foam system with adequate capacity.
Regular „Hazard Survey‟ ensures the detection of leakage in the plant. In
house „capability building‟ to attend hazardous scenarios is to be taken up
through mock drills. Train staff in attending such scenarios.
Human Factors: Reynish should have well equipped Toxic and fire
handling system and also safety department – safety practices. Human
factors role in safety cannot be ignored. Odd hours working and over/long
hours work can drain out individual. It shows in lack of efficiency and also
the lack of apt attention the modern chemical complex demand.
„Safety‟ has unique features:
If no accident has happened so far probability of incident/accident
occurring increases.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-23
„No accident‟/good safety record develops complacency inertia/over
confidence in the team. This attitude gives rise to gaps/soft spots in
the system giving chances to incidents/accidents.
Safety requires novelty. Routine training practices get stale with no
positive results. Look for novel scheme of training/ safety practices
to build up fresh impetus in safety. Involvement of employees with
refreshed outlook for safety is to be achieved.
7.16 ACTION PLAN FOR HANDLING & SAFETY SYSTEM OF CHEMICAL
Flammable chemicals will be stored in open area outside the process
plant with all the safety measures. Hazardous chemicals will be stored
and handle in dispensing room for taking out sample from the container
for quality check-up purpose or for the partial use. This activity for
Hazardous material handling will be carried out by using all PPEs with
proper ventilation & under supervision.
7.16.1 Safety Measures for Transportation and Unloading of Hazardous
Chemicals
Solvent unloading standard procedure will in place and will be
implemented for safe unloading of road tanker.
Static earthing provision will be made for tanker unloading.
Drum handling trolleys will be used for transportation of drums up to
plant and internal handling from storage to process area.
Display Boards will be provided on all storage tanks which include the
name of the chemicals and its major hazardous characteristics.
Fire extinguishers will be provided as required.
First aids boxes will also be provided at different places wherever
required.
Water showering system will be provided to the flammable chemicals
storage area.
Area will be declared as “NO SMOKE ZONE”.
7.16.2 Safety Measures for Storage/Handling of Hazardous Chemicals
All Hazardous and flammable chemicals will store separately and away
from the strong oxidant & kept it in well ventilated room. Adequate
firefighting system will be installed. Safety shower and eye washer will be
installed near storage area. Flame proof light fitting will be provided at
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-24
storage area. Sprinkler system will be installed near storage area. Safety
permit system will be followed for loading and unloading. Isolate storage
will be provided with wire fencing under lock and key. Caution note,
hazardous identification board will be provided. Only authorized person
will be permitted in storage area and register will be maintained. “NO
SMOKING” board will be displayed and Wind Indicator and siren will be
provided.
7.16.3 Safety Measures for Process Units
Safety measures are the most important aspect of selection of process
technology to ensure safety in production unit. For the safety in
production area some important critical safety measures will be provided
within the process technology/equipment itself & will put continue efforts
for developing new technology/equipment. Company will ensure such
provision in the technology/equipment/machineries at time of purchase.
The details of the critical safety measures for process unit are as below;
any reaction upsets will be confined to the reaction vessel itself as
defined quantity of raw materials will be issued to the reaction vessel by
metering pumps/load cells. Process parameters control will be provided
as per SOP- Standard Operating Procedures. Materials will be transferred
by pumping through pipeline or by vacuum from drums. All reaction vents
will be connected to vapor condensers system. Hazardous materials will
be transferred by pipelines and in controlled manners. Trained person will
be engaged for handling of hazardous materials. Proper safety
precautions will be taken during handling of hazardous materials. All
solvents and flammable material with required quantity will be charge in
reactor by pump or by gravity. All the vessels will be examined
periodically by a recognized competent person. All the vessels and
equipments will be well earthed appropriately and well protected against
Static Electricity. Temperature indicators will be provided near all reactor
and distillation systems. Flame proof light fittings will be installed in the
plant. All the Plant Personnel will be provided with Personal Protection
Equipments to protect against any adverse health effect during
operations, leakage, spillages or splash. PPE like Helmets, Safety Shoes
and Safety Glasses will be provided to the employees.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-25
7.16.4 Safety Measures for Preventive Maintenance
The safety measures in the form of the general Do's & Don'ts for safety in
process & other plant area are as below:
Do not work on equipments without permission from plant head and
maintenance head.
Make sure equipment is empty and flushed with nitrogen and air.
Check VOC content for flammable and make sure that no flammable
vapour contents.
Keep proper and adequate fire extinguisher near work area.
Use proper PPE.
Do not allow any employment without pre-medical check-up or without
checking fitness.
Work in any equipment must be conducted in presence of supervisor.
Additional safety measures in form of the checklist covering Do's &
Don'ts of preventive maintenance, strengthening of HSE,
manufacturing utility staff for safety related measures will be updated
timely and will be made available to all concern department &
personnel.
7.16.5 Safety measures to prevent spillage/leakage of toxic chemicals
The preventive maintenance will be planned and carried out as per plan
to avoid the failure of valve, pipelines and other component of
transferring line. The spillage will be confined to the dyke area
underneath the vessel. The resultant splash of such chemicals will result
in exposure of toxic chemicals to employees. Decontamination facilities
(Safety shower and eye wash fountains) will be provided in the plant
area, which can be used to decontaminate the affected employees.
Suitable decontamination procedure will be used to decontaminate the
spilled or leaked material. The SOP for decontamination will be available
with all related department.
7.17 ARRANGEMENTS FOR ENSURING HEALTH AND SAFETY OF
WORKERS ENGAGED IN HANDLING OF TOXIC MATERIALS
The significance of Safety & Health in plant has been a vital issue in
achieving productivity and quality standard. Following is an effort for
safety & health of workers working in the plant. Numbers of chemicals
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-26
are used in plant have specific health hazards in nature. Following are
basic fundamental principles properly underlie all the workers working in
the plant. Occupational health and safety is about preventing people from
being harmed by work or becoming ill from work by taking adequate
precautions and providing a safe and healthy work environment.
Consideration of each should be encouraged before beginning work as
part of the culture of safety within the plant.
Plan ahead. Determine the potential hazards associated with
production.
Minimize exposure to chemicals. Do not allow toxic chemicals to
come in contact with skin. Provide proper ventilation devices to
prevent/minimize airborne.
Do not underestimate hazards or risks. Assume that any mixture
of chemicals will be more toxic than its most toxic component. Treat
all the chemicals as toxic substances.
Be prepared for accidents. Before beginning of any batch reaction,
know what specific steps to take which cause to accident if any
hazardous substance release accidently. Proper follow SOP- Standard
Operating procedure to take batch reaction.
Unit will assess is careful examination of what, at work, could cause harm
to workers, accidents and ill health. All risks in the workplace must be
identified and assessed for control measures to be put in place.
Follow the five steps of hazard identification will be taken by unit namely;
Identify the hazards
Decide who might be harmed and how
Evaluate the risks and decide on precaution
Record your findings and implement them
Review your assessment and update if necessary
Following Information workers should know regarding hazardous
chemicals
Unit shall ensure that the employee is adequately trained with regard to:
The contents of the hazardous chemical substances
Potential source exposure to chemicals
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-27
Measures taken by the employer to protect employees against any risk
from exposure
Precautions to be taken by an employee to protect himself against the
health risks associated exposure
Correct use, maintenance of safety equipment, facilities and
engineering controls
Importance of good housekeeping at the workplace & personal hygiene
Safe working procedures
Procedures to be followed in the event of spillages or leakages.
(C) DISASTER MANAGEMENT PLAN (DMP)
Disaster/Emergency Management Plan is essential for a chemical plant as
the processes adopted for manufacturing are classified under Factory Act
as Hazardous due to handling and storage of toxic, flammable and
explosive hazardous materials. DMP is proposed here is to meet the
extremely adverse situations caused by the various hazardous accident
scenarios. Mock drills are to be carried out in association with district
authorities. Any weak points observed during the mock drills are to be
strengthened.
Primarily, DMP is prepared to furnish details which may require at the
time of the emergency, to delegate responsibility, to estimate the
consequences in advance and to prepare ourselves to control any type of
emergency. The plan explains basic requirements as follows:
Definition,
Objectives,
Organization set up,
Communication System,
Action on site,
Link with Off-site Emergency Plan,
Training rehearsal and record aspect.
Definitions
Various definitions on different analogy used on On-site & Off-site
Emergency Plan are as follows:
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-28
Accident: An accident may be defined as “an undesirable and unplanned
event with or without or major damage consequence of life and /or
property.
Major Accident: It is a sudden, unexpected, unplanned event resulting
from uncontrolled developments during an industrial activity, which
causes or has the potential to cause, death or hospitalization to a number
of people, damage to environment, evacuation of local population or any
combination of above effects.
Emergency: This can be defined as any situation, which presents a
threat to safety of person's or/and property. It may require outside help
also.
Major Emergency: Occurring at a work is one that may affect several
departments within and/or may cause serious injuries, loss of life,
extensive damage to properly or serious disruption outside the works. It
will require the use of outside resources to handle it effectively.
Disaster: Disaster is a sudden calamitous event, bringing great damage,
loss or destruction.
Hazards: Hazard may be defined as “the potential of an accident”.
Hazard exists in man and the system of materials and machines.
Chemical Hazards: It is a hazard due to chemical(s) (including its
storage, process, handling, etc.) and it is realized by fire, explosion,
toxicity, corrosively, radiation, etc.
Risk: Risk may be defined as the combination of consequence and
probability or likelihood of an accident being caused in a given man-
material – machine system.
On-Site Emergency plan: It deals with measures to prevent and control
emergencies within the factory and not affecting outside public or
environment.
Off-Site Emergency plan: It deals with measures to prevent and
control emergencies affecting public and the environment outside the
premises.
Objective of the Disaster Management Plan
The DMP document is prepared keeping in view and to confirm the
requirements of the provisions of The Factories Act, 1948, Guidelines
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-29
issued by the MoEF&CC and MSIHC, 1989 amended in 2000, Schedule 11
under Environmental Protection Act, 1986.
Following are the main objectives of the plan to:
Defined and assess emergencies, including hazards and risk
Control and contain incidents.
Safeguard employees and people in vicinity.
Minimize damage to property and/or the environment.
Minimization of risk and impact of event accident.
Preparation of action plan to handle disasters and to contain damage.
Inform employees, the general public and the authority about the
hazards/risk assessed, & role to be played in the event of emergency.
Be ready for 'mutual aid' if need arises to help neighbouring unit.
Inform authorities and mutual aid centres to come for help.
Effect rescue and treatment of casualties.
Effective rehabilitation of the affected persons and prevention of
damage to the property.
Secure the safe rehabilitation of affected areas & to restore normalcy.
Provide authoritative information to the news media.
7.18 ONSITE EMERGENCY PLAN
7.18.1 Incident Controller
Incident Controller‟s role is to control the emergency at the incident site.
7.18.1.1 Duties of Incident Controller
Incident Controller will proceed to the place of emergency after hearing
siren/announcement. He will:
Assess the scale of emergency and decide if a major emergency exists
or is likely, accordingly activate emergency procedure.
Immediately give his feedback to Emergency Control Centre (ECC)
regarding emergency.
Direct all operations within the area with following priorities.
o Secure the safety of personnel
o Minimize damage to plant property and environment.
o Minimize loss of material.
Direct rescue and firefighting operations till the arrival of the outside
Fire Brigade; he will relinquish control to Sr. Officer of Fire Brigade.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-30
Ensure that the affected area is searched for causalities.
Ensure that all non-essential workers in the affected area evacuate to
the appropriate assembly point.
Set up communication point to establish Radio/Telephone/Messenger
contact as with emergency control centre.
Pending arrival of works site controller, assume the duties of the post
in particular to:
o Direct the shutting down and evacuation of plant and areas likely to
be threatened by emergency.
o Ensure that the outside emergency services have been called in.
Ensure that the key personnel have been called in.
Report all significant development to the Site Main Controller.
Provide advice and information, as required to the Senior Officer of the
Fire Brigade.
Preserve evidence that would facilitate any subsequent inquiry into the
cause and circumstances of emergency.
Dy. Incident Controller will carry out above said duties in absence of
Incident Controller.
7.18.2 Site Main Controller
Site Main Controller will be overall in-charge of emergency organization.
7.18.2.1 Duties of Site Main Controller:
Relieve the Incident Controller of responsibility of overall main control.
Co-ordinate ECC or if required, security for raising evacuation siren
and also all clear siren, in case emergency is over.
Declaration of major emergency ensures that outside emergency
services will be called and when required nearby firms will be
informed.
Ensure that key personnel will be called in.
Exercise direct operational control on parts of the works outside the
affected area.
Maintain a speculative continuous review of possible development and
assess these to determine most possible cause of events.
Direct the shutting down and evacuation of plants in consultation with
key personnel.
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Ensure causalities are receiving adequate attention; arrange for
additional help if required. Ensure relatives are advised.
Ensure the accounting of personnel.
Control traffic movement within the work.
Arrange for a chronological record of the emergency to be maintained.
During prolonged emergency, arrange for the relief of the personnel
and provision of catering facilities.
Contact the local office to receive early notification of impending
changes in weather conditions, in case of prolonged emergency.
Issue authorized statements to the news media and informs H.O.
Ensure that proper consideration is given to the preservation of
evidence.
Control rehabilitation of affected areas after control of the emergency.
7.18.3 Other Key Personnel
The key personnel required for taking decision about further action for
shutting down the plant, evacuate the personnel, and carry out
emergency engineering works in consultation with Site Main Controller in
light of the information received. HOD‟s /Senior Managers/ Section Heads
will be responsible for safety, security, fire, gas and pollution control,
spillage control, communication system including telephone, wireless etc.
Also medical services, transport, engineering, production, technical
services, will form part of advising team.
7.18.3.1 Emergency Response Team
The role of Emergency Response Team members is to actually combat
the emergency at the site and control the emergency situation and carry
out rescue operations. All team members will be thoroughly trained to
deal with fires, explosions, chemical spills and atmospheric releases, first
aid. As per priority list during emergency, the activities will be carried
out as per emergency control plan.
7.18.3.2 Emergency Personnel’s Responsibilities outside Normal
Working Hours of the Factory.
The duties of Shift In-charge & team members have been brought out
in emergency control plan. All team members after evacuating the area
shall report to ECC/Incident Place. The non-essential workers shall be
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-32
evacuated from the plants if need arises and this will be determined with
the forcible rate with which incident may escalate. Non-essential workers
shall assemble at the earmarked/specified point of assembly.
7.18.3.3 Assembly Points
At the proposed plant, at least 2 assembly points will be identified and
marked properly.
7.18.4 Emergency Control Centre
It will be headed by Site Main Controller, HOD – PD, HOD- P&A and it is
sited in Office of Site Main Controller in Admin Building & New
security office (after office hours), which is readily accessible & with
minimum risk, equipped with telephone facilities and other
announcements extra communications facilities needed. It has enough
means to receive and transmit information and directions from site main
controller to incident controller and other areas. In emergency control
centre due to its safer location and advantage of easier accessibility, all
necessary personnel protective equipment‟s fire-fighting extinguishers
will be stocked in sufficient quantity.
7.18.4.1 Role of Emergency Control Centre
In case of mishap or accident like fire, toxic gas leakage, explosion in the
factory, The Emergency Control Centre will be Office of Head-Operations.
The plot plan indicating all the activities in the factory premises
including storage‟s utility services, production area, administration, will
be kept for ready reference, showing the location of fire hydrant and
fire-fighting aids.
Normal role of employees, work permits, gate entries and documents
for head count, employees blood group, other information and
addresses will be available.
Stationery required is available in the Control Centre (ECC) and HOD
(P & A) looks after it.
The requirement of personnel protective equipment and other
material, like torches, have been worked out and the quantity required
during emergency will be kept in the Control Room (ECC). The
responsible person for maintaining the said requirement/inventory will
be HOD-HSE.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-33
7.18.5 Fire & Toxicity Control Arrangements
The plant will be well equipped with suitable numbers of fire-fighting and
personnel protective equipment. The staff will be trained regularly to
handle the various emergency situations.
7.18.6 Medical Arrangements
Availability of first aid facilities in sufficient quantity will be always
ensured. In case of emergency arrangements will be made to avail
outside medical help immediately.
7.18.7 Transport & Evacuation, Mutual Aid Arrangements
Emergency Transport & Evacuation and Mutual Aid arrangements will be
available in the factory.
7.19 COMMUNICATION SYSTEM
7.19.1 Declaring the Emergency
In case of any emergency in the plant, speedy and effective
communication of the same to all concerned in least possible time is the
most important aspect of any emergency-handling plan. An early
communication increases the chances of control of emergency in the bud
stage. Blowing siren will be adopted as method of communication of
emergency, to all employees in the plant.
7.19.1.1 Type of Sirens
Three different types of sirens have been identified for communication of
emergency.
Alert Siren: Single Continuous Siren for One Minute. This indicates
that there is some accidental happening in the plant. All have to become
alert. Incident controller will be rush to the site of emergency. Plant area
people have to start safe shut down. Rescue team and other emergency
control teams have to reach at the site of emergency.
Siren for evacuation: wailing & waning siren for three minutes.
This siren indicates that emergency is of serious proportion and
everybody has to leave his work place. All people having their role in
emergency control have to assume their assigned role. All non-essential
workers have to proceed immediately to assembly area and wait for
further instruction.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-34
All clear siren: Long continuous siren for two minutes. This is a sign
of return of normalcy. On hearing this siren everybody should go back to
his or her respective workplace.
7.19.1.2 Location of Siren
Siren will be located in centre of the pant for wide coverage of the whole
campus. Switch for siren will be provided at security gate. The switch at
Security gate should be operated only as a general rule.
Emergency manual call bell will be installed which will be used in case of
total failure of electricity. It is responsibility of HOD (HSE) to maintain the
upkeep of electric call bell and HOD- Security and administration to
maintain manual and Hand operated siren.
7.19.1.3 Raising Alarm
Any person noticing any emergency situation in the plant should
immediately call security gate with following information:
Identify oneself
State briefly the type of emergency i.e. whether fire, explosion, toxic
gas release etc.
Give the location of the incident
Estimated severity of the incident
Security personnel after ensuring genuineness of the call shall raise the
ALERT SIREN. At the same time, he will also contact the incident
controller and ECC in order and inform about the incident. He will keep
the gate open and rush his two security personnel at the site of
emergency with appropriate PPEs. ECC will be located at the office of
Head-Operations on normal working hours and at Security gate after
normal working hours (during night). ECC shall be immediately manned
on hearing alert siren. If the authorized people to handle ECC are not
available, any senior most people out of the available person nearby shall
occupy ECC till authorized person comes. Incident controller, on hearing
alert siren or by any other way of information of the emergency, will
immediately reach at the site of incident and assess the situation. He will
immediately give his feed back to ECC. ECC shall direct security gate to
raise evacuation siren, if the need arise. SIREN FOR EVACUATION shall
be raised on instruction from Site Main Controller or any Manager of the
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-35
plant in the ECC. Security gate person will be authorized to raise ALL
CLEAR SIREN on instruction from Site Main Controller or ECC, after the
emergency is over.
7.19.2 Internal Communication
It shall be responsibility of ECC to communicate to all employees in the
plant. They may take help of telephone operator for such communication.
However, telephone operator can directly communicate information about
emergency to all internal departments, if such message comes from
incident controller or site main controller. Telephone operator will
continue to operate the switchboard advising the callers that staffs are
not available and pass all calls connected with the incident to ECC.
7.19.2.1 Availability of Key Personnel outside Normal Working Hours
The details of key personnel availability after working hours will be made
available at Security Gate, ECC, telephone operator as well as production
units. Security personnel shall call required key personnel from their
residence in case emergency occurs outside normal working hours.
Availability of emergency vehicle/Ambulance will be ensured to fetch the
key personnel residing outside. It will be the responsibility of HOD (P & A)
to maintain it.
To the Outside Emergency Services
Decision to call outside help to deal with emergency like fire brigade,
ambulance, police, etc., shall be taken by Site Main Controller. However,
in absence of Site Main Controller, if the incident controller realizes the
situation going out of control, he may ask for immediate help from
outside. ECC will be responsible for calling help from outside. A list of
emergency services available in the area with their telephone numbers
will be provided at ECC, at Security gate and with telephone operator.
Facilities such as phones, emergency vehicle, and security personnel will
be available to help calling outside emergency services and authorities.
7.19.3 Communication to the Authorities
The emergency will be immediately communicated to the government
officers and other authorities such as SPCB, police, district emergency
authority, Factory Inspectorate, hospital etc. by Emergency Control
Centre.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-36
Communication to Neighboring Firms & the General Public
In case of emergency having its outside impact, public will be cautioned
regarding the same. Co-ordination of police will be sought for speedy
action. This is to be ensured by ECC.
7.20 Pre-emergency activities
Internal Safety survey with regard to identification of hazards, availability
of protective equipment‟s, checking for proper installation of safety
devices will be carried out periodically.
Periodic pressure testing of equipment
Periodic pressure testing of lines
Periodic safety/relief valve testing
Periodic fire hydrant system testing
Mock drill to check up level of confidence, extent of preparedness of
personnel to face emergency is being contemplated
Regular training is being imparted to all personnel to create awareness
Adequate safety equipment will be made available
Periodic check-up of emergency lights
Safer assembly points will be identified
Storage of adequate first aid treatment facilities
7.21 POST-EMERGENCY ACTIVITIES
Following post emergency actions will be carried out to study in detail and
preventive measures to be taken
Collection of records
Inquiries
Insurance claims
Preparation of reports comprising suggestion and modification
Rehabilitation of affected personnel
Normalization of plant
7.21.1 Evacuation and Transportation
In case of emergency, evacuation and transportation of non-essential
workers will be carried out immediately. The affected personnel will be
transported for medical aid.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-37
7.21.2 Safe Close Down
During emergency plant shut down will be carried out if situation
warrants. This will be as per the instruction of site main controller under
guidance of incident controller.
7.21.3 Use of Mutual Aid
Mutual aid agreement with nearby industries will be ensures to provide
help to each other in the emergency,
7.21.4 Use of External Authorities
As and when necessary, statutory authorities, police, pollution control
personnel, medical aid/center, ambulance etc. will be contacted.
7.21.5 Medical Treatment
The affected personnel will be brought to safer place immediately to give
them first aid. Immediate medical attention will be sought.
7.21.6 Accounting for Personnel
Proper accounting for personnel will be laid down in all the shifts. The
number of persons present inside the plant premises, their duty etc. will
be available with the P & A. This record will be regularly updated.
7.21.7 Access to Records
The relatives of affected personnel will be informed. The details regarding
all employees will be made available to Administration building.
7.21.8 Public Relations
In case of emergency, Manager P & A will be available for official release
of information pertaining to the incident.
7.21.9 Rehabilitation
The affected area will be cleared from emergency activities only after
positive ascertaining of the system in all respects. The entry to affected
area will have to be restricted until statutory authorities visit and inspect
the spot of incident. The site main controller will be in charge of the
activities to be undertaken. The plan will cover emergencies, which can
be brought under control by the works with the help of emergency
team/fire services. The DISASTER CONTROL PLAN for gas leak and fire
will be prepared for entire factory.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-38
7.22 CAUSES OF EMERGENCY
7.22.1 Risk
7.22.1.1 Nature
In the plant, the nature of dangerous events could be of the following:
Fire : Chemical/Electrical
Toxic Release : From chemicals
Leakages : Equipment, pipelines, valves, etc.
Improper handling of products (raw materials/finished products)
Large spillage to ground floors resulting in pollution & fire.
Failures of Equipment/Instruments.
Release of safety valves or ruptures of vessels due to excessive
pressures.
7.22.1.2 Various Emergency Actions
a) Onsite
Safe shut down of the plant and utilities
Emergency control measures.
To attempt with the help of trained crew in firefighting to contain the
fire spread up/gas emission and limit within limited space.
To cut off source of oxygen by use of firefighting appliances.
Cut off fall sources of ignition like electrical gadgets.
To protect fire prone area from the fire.
To remove material which can catch fire.
Evacuation of non-essential persons.
b) Medical Facilities/Treatment
The Plant will have a Health centre which is manned with trained male
nurse on continuous basis who can render medical first aid. Doctor will
visit two times a week for two hour each time.
Depending on seriousness the injured person shall be shifted to any
other hospital.
Vehicle will be available round the clock for transportation. Ambulance
will be also made available in the campus on regular basis.
c) In the event of Fatal Accidents
The information shall be given to following authorities:
Inspector of Police
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-39
Inspector of Factories
Mamlatdar
Corporate Office
Regd. Office
Insurance the plant
Regional Officer, SPCB
d) Emergency Siren
Emergency siren shall be blown for announcing the emergency which
shall have different sound for identification/differentiation than the
normally used for commencement of factory working etc.
Location of Siren Above Plant
Type of Siren Industrial Siren
Position of siren switch Located at Main Gate
e) Seeking help from neighboring industries/sources for fire engine
f) Advise for vacation of other areas
Since the effect of fire/gas emission shall be contained within the area
of the plant advice of vacation of other areas is not necessary.
7.22.1.3 Response Time-Minutes
Hazard Fire Fighting Police Medical Services
Fire &
Explosion
Immediate with whatever
facilities available with the plant
10
min.
10 minutes
External Help within 15 minutes
7.23 OFF-SITE EMERGENCY PLAN
7.23.1 Need of the Site Emergency Plan
Depending upon the wind direction and velocity of the effects of accident
in factory may spread to outside its premises. To avert major disaster it
is essential to seek guidance/assistance of statutory authorities, police
and health department. The movement of traffic may have to be
restricted. Required information will be given to the authority and
consultation will be sought for remedial measures.
A purpose of the off-site emergency plan is:
To provide the local/district authorities, police, fire, brigade, doctors,
surrounding industries and public the basic information of risk and
environmental impact assessment and appraise them of the
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-40
consequences and the protection/prevention measures and to seek
their help to communicate with public in case of major emergency.
To assist district authorities for preparing the off-site emergency plan
for district or particular area and to organize rehearsals from time to
time and initiate corrective actions on experience.
7.23.2 Structure of the Off-Site Emergency Plan
Available with concerned authorities.
7.23.3 Role of the Factory Management
The site main controller will provide a copy of action plan to the statutory
authorities in order to facilitate preparedness of district/area off-site
emergency plan.
7.23.4 Role of Emergency Co-ordination Office (ECO)
He will be a senior police or fire officer co-ordination with site main
controller. He will utilize emergency control centre.
7.23.5 Role of Local Authority
Preparation of Off Site Plan lies with local authorities. An Emergency
Planning Officer (EPO) works to obtain relevant information for preparing
basis for the plan and ensures that all those organization involved in
offsite emergency and to know their role and responsibilities.
7.23.6 Role of Fire Authorities
The fire authorities will take over the site responsibility from incident
controller after arrival. They will be familiarized with site of flammable
materials, water and foam applies points, fire-fighting equipment.
7.23.7 Role of the Police and Evacuation Authorities
Senior Police Officer designated, as emergency co-ordination officer shall
take over all control of an emergency. The duties include protection of
life, property and control of traffic movement. Their functions include
controlling standards, evacuating public and identifying dead and dealing
with casualties and informing relatives of dead or injured. There may be
separate authorities/agencies to carry out evacuation and transportation
work. Evacuation depends upon the nature of accident, in case of fire
only neighboring localities shall be alerted. Whole areas have to be
evacuated in case of toxic release.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-41
7.23.8 Role of Health Authorities
After assessing the extent of effect caused to a person the health
authorities will treat them.
7.23.9 Role of Mutual Aid Agencies
Various types of mutual aid available from the surrounding factories and
other agencies will be utilized.
7.23.10 Role of Factory Inspectorate
In the event of an accident, the Factory Inspector will assist the District
Emergency Authority for information and helping in getting Neighbouring
Industries/mutual aid from surrounding factories. Factory Inspector may
wish to ensure that the affected areas are rehabilitated safely.
7.24 MOCK DRILLS AND RECORDS
7.24.1 Need of Rehearsal & Training
Regular training and rehearsal program of emergency procedures shall be
conducted with elaborate discussions & testing of action plan with mock
drill. If needed, the guidance of outside agencies will be sought.
7.24.2 Some Check Points
The extent of realistic nature of incidents.
Adequate assessment of consequences of various incidents.
Availability of sufficient resources such as water, fire-fighting aids,
personnel.
Logical sequences of actions.
The involvement of key personnel in the preparation of plan.
At least 24 hours covers to take account of absences due to sickness
and holiday, minimum shift manning.
Satisfactory co-operation with local emergency services and district or
regional emergency planning offices.
7.24.3 Records and Updating the Plan
All records of various on-site and off-site emergency plans of the factory
will be useful alone with those of the factors by which statutory
authorities draw a detailed plan for the whole area/district. The records of
the activity will be updated regularly.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-42
(D) PUBLIC CONSULTATION
The public hearing was conducted by GPCB on 18.10.2019 on the basis of
the draft EIA/EMP incorporating the Terms of References. Point raised
during the public hearing by participants is summarized below with
reply/action taken by project proponent.
Table 7.11 Points raised during public hearing
Statement of issues raised by the public and response of the project proponent with
action plan is as follows.
Sr.
No.
Name and
Address
Point Represented Reply from
Project
Proponent
Time Bound
Action Plan
proposed
Budgetary
provision
1. Shri Chauhan
Javed
Vill. Dabhasa
Ta. Padra
It was informed that
local people of an
area are poor and
are in dire need of
employment and
therefore
establishment of an
industry in an area is
welcome. He
subsequently,
inquired to know
about the
employment
creation.
Representative of
project proponent,
Dr. Mahendrabhai
Sadaria informed
that local residents
of village :
Dabhasa would be
given preference
and then to an
area covered
within 10 km.
Total manpower
requirements
would be 65. He
further informed
that only in case
of non-availability
of the requisite
qualified persons;
outsider would be
considered over
local people.
Appointment
office staff/
skill/unskilled
employs
start during
construction
and
operational
phase
--
2. Shri Deval
Patel
Vill. Padra
Ta. Padra
He inquired to know
the expected
benefits to the
society due to social
activities by
industry.
Representative of
project proponent,
Dr. Mahendrabhai
Sadaria briefed
about the various
six activities that
would be
considered under
their CER activities
over the five years
with a budgetary
provisions of Rs.
100 Lakhs. He
further informed
that any
suggestions from
the local people or
from the local
district
administration
would be
positively
considered and
CER activities
Immediately
start before
starting of
construction
activities of
project
Rs.100
Lakh
earmark for
CER
activities
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-43
will be
accommodated.
3 Shri Ketal
Patel
Vill. Dabhasa
Ta. Padra
He inquired to know
the management
plan for the air
pollution control.
Representative of
project proponent,
Dr. Mahendrabhai
Sadaria informed
that coal is
proposed to be
used as a fuel and
therefore cyclone
and bag filter with
the adequate
stack height is
proposed to be
provided for the
air pollution
control whereas
water and alkali
scrubber is
proposed to be
provided for the
process gas
emission and
exhausted
scrubbing media
will be reused /
sold to the
authorized actual
users. He further
informed that
APCMs would be
operated
judiciously without
any flexibility.
Immediately
with Plant
operation
Rs. 32 Lakh
as capital
investment
and Rs.5.0
Lakh/Year
as recurring
cost for
installation
and
operating
APCM for
Air Pollution
Control
4 Shri Bhupendrasinh Mohansinh
Mahida
Vill. Chokari –
Sarpanch,
Ta. Padra
He quoted that
industry is to spend
about 2% as per the
legal requirements
for the CSR and
demanded that such
amount shall be
spent in an area
where industries are
not located.
He also demanded to
give preference to
local people for the
employment who are
residing within 10
km radius.
Representative of
project proponent,
Dr. Mahendrabhai
Sadaria welcomed
the suggestion
about the amount
of CSR to be spent
as well as that of
employment to the
local people. He
further added that
adequate care
would be taken
while
implementation.
CER activities
Immediately
start before
starting of
construction
activities of
project
Rs.100
Lakh
earmark for
CER
activities
5 Shri
Manojbhai
Patel,
Vill. Abhor –
Sarpanch,
Ta. Padra.
He opined that
industry shall strive
to use agro based
fuel being generated
from the local
farmers in lieu of
proposed fuel of coal
which may not only
reduce the air
pollution but would
Representative of
project proponent,
Dr. Mahendrabhai
Sadaria welcomed
the suggestion and
recommended to
plan a briquette
manufacturing
plant for their agro
waste being
CER activities
Immediately
start before
starting of
construction
activities of
project
Rs.100
Lakh
earmark for
CER
activities
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-44
in turn also support
the local farmers in
revenue generation
and will result into
building up of inter
relationship. He
informed that sister
concern unit Lakshya
Group is carrying out
good CSR activities
and opined that such
action will further
support the farmers
of an area where
there are no
industries.
generated from an
area. He further
informed that final
EIA report would
be submitted with
agro briquette as
an alternate fuel
to proposed fuel of
coal.
6 Shri
Dhanajibhai
Ratanabhai
Padhiyar
Vill. Ekalbara,
Member –
Gram
Panchayat
Ta. Padra
He inquired to know
the waste water
management plan
and also demanded
to provide
preference to local
for employment.
Representative of
project proponent,
Dr. Mahendrabhai
Sadaria once again
explained the
waste water
treatment scheme
that was already
shown during
presentation and
informed that
industry will aim
at resource
conservation, will
reuse the treated
waste water and
will maintain ZLD.
It was further
informed that
deserving local
people will be
given preference
for the
employment based
on the
requirements.
Immediately
with Plant
operation
Rs.141
Lakh as
capital
investment
and Rs.95
Lakh/Year
as recurring
cost for
installation
and
operating
wastewater
treatment
7 Shri
Jhahirkhan
Pathan
Vill. Ranu
Ta. Padra
He quoted that he
has provided
employment to
around 10 – 12 local
people even though
running a very small
business and
therefore the
estimated
employment of 65
persons seems very
less for an industry
and therefore has an
objection.
He further inquired
to know about the
steps proposed to be
taken by the
Representative of
project proponent,
Dr. Mahendrabhai
Sadaria informed
that requirements
of manpower are a
proprietary
decision of an
industry based on
their requirements
and cannot be
compared.
With regard to foul
smell, he further
informed that it is
proposed to
provide alkali
Immediately
with Plant
operation
Rs. 32 Lakh
as capital
investment
and Rs.5.0
Lakh/Year
as recurring
cost for
installation
and
operating
APCM for
Air Pollution
Control
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-45
industry for the
control of foul smell
being
pharmaceutical
industry.
scrubber for the
scrubbing of the
process emission.
Further opined
that, though
industry is
committed for the
control of pollution
Additionally,
general awareness
would also not
allow industry to
be non-compliant.
(E) Social Impact Assessment
Reynish Pharmachem Pvt. Ltd. is a green field project, proposes to set
up bulk drugs manufacturing unit. Total production capacity of all
products will be tune around 50 MT/month. There will be no
Rehabilitation & Resettlement (R&R) involved. However, preference will
be given to local people for employment and contribute to improve the
physical infrastructure in vicinity of plant. Detailed Social Impact
Assessment (SIA) study is given below:
Introduction
Corporate Environmental Responsibility (CER) refers to a company‟s
duties to withdraw from damaging natural environments. The term
derives from Corporate Social Responsibility (CSR). Also can be referred
as corporate initiative to assess and take responsibility for the company's
effects on the environment and impact on social welfare. The term
generally applies to companies efforts that go beyond what may be
required by regulators or environmental protection groups.
CSR is a way of conducting business, by which corporate entities visibly
contribute to the social good. Socially responsible companies do not limit
themselves to using resources to engage in activities that increase only
their profits. They use CSR to integrate economic, environmental and
social objectives with the company's operations and growth.
Corporate Social Responsibility is not a new concept in India, however,
the Ministry of Corporate Affairs, Government of India has recently
notified the Section 135 of the Companies Act, 2013 along with
Companies (Corporate Social Responsibility Policy) Rules, 2014
"hereinafter CSR Rules" and other notifications related thereto which
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-46
makes it mandatory (with effect from 1st April, 2014) for certain
companies who fulfill the criteria as mentioned under Sub Section 1 of
Section 135 to comply with the provisions relevant to Corporate Social
Responsibility. CSR is generally understood as being the way through
which a company achieves a balance of economic, environmental and
social imperatives ("Triple-Bottom-Line- Approach"), while at the same
time addressing the expectations of shareholders and stakeholders. The
term "Corporate Social Responsibility (CSR)" can be referred as corporate
initiative to assess and take responsibility for the company's effects on
the environment and impact on social welfare. The term generally applies
to companies efforts that go beyond what may be required by regulators
or environmental protection groups.
Purpose of the CER/CSR
Corporate Environment/ social responsibility (CSR) is a broad term used
to describe a company's efforts to improve society in some way. These
efforts can range from donating money to non-profits to implementing
environmentally-friendly policies in the workplace. The group's CSR
activities are rooted in the knowledge that businesses have a duty to
enable all living beings to get a fair share of the planet's resources.
Businesses are powerful constituents of society and the most successful,
respected, and desirable businesses exist to do much more than make
money; they exist to use the power of business to solve social and
environmental problems. Unit will involve in a community development
and environment preservation projects. Social activities relate to health,
primary education, skills training and entrepreneurship, livelihoods and
women empowerment.
Objective of the study
The main objectives are as follows:
1. To assess the impact of the project on agricultural situation;
2. To examine the impact of the project on pattern of demand;
3. To assess the in impact of the project on consumption pattern;
4. To examine employment and income effects of the project;
5. To explore the possibility of local industrialization as an offshoot of the
Project;
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-47
6. To examine the effect of the project on education status of the people
in the study area; and
7. To judge peoples' perception regarding the project
Survey Methodology
The survey aims to document the living conditions, level of socio-
economic development of the region and the socioeconomic profile of
people in the core and buffer zones of the proposed project area. The
survey was organized to collect information on socio-economic variables
at the village level as well as household level. The village level data are
collected from revenue offices, Panchayat office; Censuses while the
household level data are collected through questionnaire method. The
agreed methodology has been followed with the tools of SIA. The
following strategies were adopted for undertaking the study.
Consultation with Representatives of focus area
Close coordination was maintained with concerned Public Representative‟s
Offices, Local representatives and common village people. Assessment of
the area was made by industry representative along with Team of M/s
San Envirotech Pvt. Ltd.
Assessment of studied area
Pre-contract field visit was conducted with assessment of the area and
people interacting with concerned employees and few opinion leaders of
the area. This visit facilitated the strategic plan to complete the study in
stipulated time.
Focus Group Discussion:
A guiding principle was developed to conduct focused group discussion
with different categories of people of the studied villages.
Study of Village Profile
This study includes village level survey of Population, Economics, Land
use Pattern, Employment pattern, Healthcare Facilities, Amenities for
Livelihood. This primary data is statistically validated and the statistical
differences and is interpreted in the light of economic impacts.
Sources of Information
As per the scope of present study, the information on the sociological
aspects like demography, human settlements, social aspects like SC & ST
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-48
population, literacy levels and economic aspects like occupational
structure of workers has been gathered and complied from secondary
sources viz. the District Census Statistical Handbook, 2011 for Vadodara
District as these documents being comprehensive and authentic.
Socio Economic Survey within study area:
1) Educational facility
Literacy is an important indicator for understanding the socio-economic
development of any area. Many villages of the study area have no proper
education facility and literacy rate is very low especially women. Overall
literacy ratio in the study area is 70.41%. The male literacy in the study
area is found to be 52.16% and the female literacy in the study area is
found to be 47.84%. However, the difference in literacy rate between
male and female is found be much wider. The overall study indicates that
the literacy rate in female population is low which can be attributed to the
social structure prevailing in the villages and traditional family trends.
The educational facilities in the study area are good due to the presence
of good infrastructure for basic education like primary schools and high
schools for higher education.
As per 2011 census, there are primary school in all 53 villages, 31 Pre-
primary school, 50 Secondary schools, 34 Senior Secondary schools, and
27 Arts, Science and Commerce College.
Area is an industrial zone and skilled manpower is essential. Unit will
contribute to start give contribution in terms of stipend to unskilled
employs for vocational training or join hands with other industrial group
to start training institute.
2) Drinking water and Sanitation Facilities
All the 53 villages in the study area have two or more sources of drinking
water. Most of the villages have tube well water supply in addition to Tap
water. Moreover, all villages have facility of well water and some villages
have hand pump, river & tank water, tube well or other facilities for
water. Unit proposed to provide drinking water facility in nearby 2 villages
where quality of potable water is poor. Unit will contribute fund towards
storage of drinking water facility at selected villages.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-49
3) Health & Family welfare
In the study area, there are 7 primary health centers, 17 primary health
sub-centers. There is no any Employees' State Insurance (ESI) Hospital
within the study area. Based on above study, it is concluded that heath
and family welfare facility found good in the study area. However unit will
arrange 2-3 health checkup camp during monsoon and provide fee
medicines.
4) Women Empowerment activities
In some cases, women bear larger losses in terms of educational
attainment, employment and wages. In terms of employment, which is a
major determinant of livelihood, Vadodara rural talukas shows lower than
state average in Worker Participation Rates (WPR). There is distinct
Gender disparity in WPR across all talukas, with women substantially
under-represented in main workers category. Thus, unit proposes to
provide education and training to engage more women in employment
opportunities.
Need Analysis of the Target Beneficiaries in the Project Area
Various needs were identified during the baseline survey within the study
area. Major problems they are facing are given below.
Poor availability of water for irrigation and drinking purpose
Lack of good medical facilities
Unemployment
Health and sanitation program
Poor educational facilities
In the assessment of socio-economic conditions, few indicators were
identified for further attention and strategic planning as given below:
Target Project Area
Target Project Area
Total 53 villages fall within the study area; Out of which unit will give
priorities to 4 villages namely 4 villages (Dabhasa, Ranu, Dhobikuwa
and Mahuvad) for CER activities according to the below mentioned
criteria.
Largely affected by industrial growth
Vicinity to the project site
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-50
Sourcing of employees from these areas
Low level socio-economic status of the people
Lack of adequate intervention of voluntary organization in the area
The focus area of comprehensive program includes: health, education,
sanitation, sustainable livelihood & infrastructure development.
Details of expenditure for ESR activities(Revised):
Cost of the proposed project : Rs. 40 Crores
Expenditure earmarked towards ESR : Rs. 2.0 Crore
(5.0 % of the total project cost)
Table 7.12a Detailed expenditure break-up for CER activities*
Sr.
No.
Activities Years (Rs. in lakhs) Total
Budget
(Rs. in
Lakhs)
1st 2nd 3rd
1 Educational activities
Computers 6.08 6.08 -- 12.16
Scholarship 12.8 12.8 12.8 38.4
2 Drinking water facilities 12 sets of RO and
water cooler at
Primary school and
village Panchayat of 4
villages
14.0 14.0 14.0 42.0
Operating and
maintenance cost
2.0 2.0 2.0 6.0
3 Public Health and family
welfare
Around 10 camp with
cluster of 5 to 6
villages
4.0 4.0 4.0 12.0
Free Medicines 6.0 6.0 6.0 18.0
4 Provide Sawing and
embroidery machine to
women coming from BPL
family and widow
women.
All 53 villages in the
study area
Onetime 100 nos
Sawing machine
5.0 5.0 5.0 15.0
Onetime 50 no
embroidery Machine
5.0 5.0 2.5 12.5
5 Widening and digging of
four village pond namely
Dabhasa, Bhoj Ranu
Pond and Dabka and
other as per the
suggestion by local
authorities.
8 village pond 22.0 22.0 -- 44.0
Total 76.88 76.8
8
46.3 200.06
*Increase the CER budget from 2.5% to 5.0% as suggested by EAC
committee (Industry-II). Reduce the estimated utilization fund within 5 years to 3 years. However, project will completed earlier then the
estimated time then utilize CER fund accordingly.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 7-51
Table 7.12b: Quantify CER activities in details
Proposed Activities Selected areas or
villages
Frequency Financial provision
in Lakhs
Educational
Provide the
Computer
Secondary School
and Higher
Secondary school of
4 villages
One time
8 Computer x 4
32 x 38000
Total Rs. 12.16
Scholarship to poor
children around 160
students
(40 on merit basis of
each 4 village
student of Secondary
& Higher secondary
school
Every year up to 3
years
Rs.8000 x 160 x 3
Years
Total Rs.38.4
Drinking water facility
Water Cooler, RO
4 sets of RO and
water cooler at
Primary school of 4
villages
Onetime
350000 x 10
Total Rs.42.0
8 sets of RO and
water cooler at
Village Panchayat of
8 villages
Operating and
maintenance cost
-- Three Years 12 x 0.5
Total Rs.6.0
Public Health and family welfare
Medical camp and
free medicine
Around 10 camp with
cluster of 5 to 6
villages
10 camp up to three
Years during rainy
days
10 x 0.4 x 3 years
Total Rs.12.0
Free Medicines 10 x 0.6 x 3 years
Total Rs.18.0
Women Empowerment & children Development activities
Provide Sawing and
embroidery machine
to women coming
from BPL family and
widow women.
All 53 villages in the
study area
Onetime
100 nos Sawing
machine
100 x 15000
Total Rs.15.0
Onetime
50 no embroidery
Machine
50 x 25000
Total Rs.12.5
Environment Sustainability - Ground water recharging
Widening and digging
of four village pond
namely
Dabhasa, Bhoj Ranu
Pond and Dabka and
other as per the
suggestion of local
authorities.
8 village pond One time
(550000
x 8 =
Total 44.0
Total Rs. 200.06 Lakhs
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 8-1
Chapter-8
Project Benefits
8.1 INTRODUCTION
Project benefit focus on those points which will become beneficial to the
surrounding area or community in terms of infrastructural development,
social development, employment and other tangible benefits due to
project. Proposed project of Reynish Pharmachem Pvt. Ltd. has a
potential for employment of skilled, semi-skilled and unskilled employees
during construction phase as well as operational phase.
8.2 IMPROVEMENT IN PHYSICAL INFRASTRUCTURE
Reynish Pharmachem Pvt. Ltd. has proposed to manufacture bulk drugs
with quantity of 50 MT/month. The project will have requirement of an
infrastructure, so direct benefits of infrastructure development is
anticipated. The project proposes to employ local people which will help
to increase the income of local people & improve their standard of living.
The construction and commissioning phase will require a substantial
manpower and resources. Hence, with the growth in the economic
conditions, the project may lead to growth in the social stature &
improvement of the quality of life in the surrounding area. It will also help
in improvement in local amenities. Thus, the project will have
considerable indirect benefits to the public physical infrastructures.
8.3 IMPROVEMENT IN SOCIAL INFRASTRUCTURE
The company will conduct social welfare activities which include the
funding & contribution for public infrastructure/facilities development,
maintenance & improvement on basis of as & when required. Due to
proposed project activity at Reynish Pharmachem Pvt. Ltd., social
infrastructure will improve by means of civilization, vocational training
and basic amenities.
Civilization: Due to the project, employment and other infrastructural
facilities will boost up income of surrounding people and improve quality
of life. This will indirectly boost up the civilization of the surrounding
people.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 8-2
Vocational Training: Unit will provide vocational training opportunity to
the surrounding people and motivate the education activities that will
lead the change in life style of the surrounding, hence, improving social
infrastructure.
Basic Amenities: Unit will consider providing or improving education
facilities, healthcare, and drinking water facilities in the area, which will
help in uplifting the living standards of local communities.
8.4 EMPLOYMENT POTENTIAL
In the construction phase, direct and indirect manpower will be involved.
Thus temporary and permanent employment will be generated during
construction phase. The proposed manpower requirement during
construction will be 25-75 nos. During the operation phase, 65 nos. of
skilled and unskilled manpower will be required. Moreover, Reynish
Pharmachem Pvt. Ltd. will provide first priority to local workers for the
employment. Further, the indirect employment via increased
transportation, ancillary units & local economic activities will also add in
the employment potential of the project. Thus, the Reynish Pharmachem
will result in considerable benefits in terms of employment.
8.5 OTHER TANGIBLE BENEFITS
In addition to mentioned above, the project will have many employment
& trade opportunities, which will eventually result in appreciable
economic benefits to the local people & businesses/contractors.
Indirectly, the project will help the Government by paying different taxes
from time to time, which is a part of revenue and thus, will help in
developing the area. Additionally, unit will motivate and support to
provide technology to local farmers and small entrepreneurs for
manufacturing of agro waste based briquettes.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 9-1
Chapter-9
Environmental Cost Benefit Analysis
As per EIA Notification 2006, this Chapter of the ‘Environmental Cost Benefit
Analysis’ is applicable only if it is recommended at the Scoping stage. As per
the standard ToR issued by MoEF&CC, New Delhi vide File No. IA-J-
11011/194/2018-IA-II(I)dated 13th July 2018, the Environmental Cost
Benefit Analysis is not applicable and hence has not been prepared.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-1
Chapter-10
Environment Management Plan
10.1 INTRODUCTION
Assessment of environmental and social impacts arising due to
implementation of the project activities is the technical heart of EIA
process. An equally essential element of this process is to develop
measures to eliminate, offset or reduce impacts to acceptable levels
during implementation and operation of projects. The integration of such
measures into project implementation and operation is supported by
clearly defining the environmental requirements within an Environment
Management Plan (EMP).
The EMP of Reynish Pharmachem Pvt. Ltd. has been formulated
considering all necessary mitigation measures to prevent/ minimize/
eliminate environmental impacts associated with the proposed activities.
Reynish Pharmachem will develop an Environment Management Cell to
keep a close watch on the performance of the pollution control
equipments, emissions from the sources and the quality of surrounding
environment in accordance with the monitoring program.
OBJECTIVE OF ENVIRONMENT MANAGEMENT PLAN
The EMP is prepared with the main objective of enlisting all the
requirements to ensure effective mitigation of adverse impacts for all the
components of the proposed project. The key objectives of the
Environment Management Plan are,
To limit/reduce the degree, extent, magnitude or duration of adverse
impacts,
To treat all the pollutants i.e. liquid effluent, air emissions and
hazardous waste with adoption of adequate and efficient technology,
To reduce risk/hazards and design the disaster management plan,
To make budgetary provision and allocation of funds for environment
management system and for timely revision of budgetary provisions.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-2
10.2 ENVIRONMENTAL MANAGEMENT DURING CONSTRUCTION PHASE
Construction phase results in temporary environmental pollution except
for the permanent change in local land use pattern & aesthetics in certain
cases. Such pollution is mainly due to site preparation, civil works,
transportation, storage & handling of construction materials, construction
worker’s sanitation etc. These are usually short-term impacts.
10.2.1 Air and Noise Environment
During construction work at Reynish Pharmachem, air pollution is
expected in the form of increased suspended particulate matter
concentration. Installation work will generate noise and dust, but it will
be within working areas. To mitigate the adverse environment impact due
to the construction phase, following measures will be taken:
Regular sprinkling of the water will be carried out at least twice a day
along with the construction activities to reduce dust emissions,
Regular preventing maintenance of machinery and transportation
vehicles will be carried out to reduce vehicular emissions and noise
pollution,
Provision of silencer to modulate the noise generated by the machine,
if required, and
Provision of personal protective equipment such as earmuffs/earplugs
to workers working in noisy area.
10.2.2 Water Environment
During construction phase, water supply from bore well and/or tankers
and portable sanitation facilities will be provided. Rest room will be
provided for workers as well as truck drivers during operation phase.
Domestic wastewater will be discharged into soak pit.
10.2.3 Socio-Economic Environment
The proposed man power requirement during construction will be 30-50
nos. Reynish Pharmachem gives preference to local people through both
direct and indirect employment.
10.2.4 Health and Safety
Adequate rest area will be provided to the construction workers, casual
workers, and truck drivers. Unit will also supply potable water and
portable sanitation facilities for the construction workers, casual workers,
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-3
and truck drivers. The safety department will supervise the safe working
of the contractor and their employees. Work spots will be maintained
clean, provided with optimum lighting and enough ventilation to eliminate
dust/fumes.
10.3 ENVIRONMENTAL MANAGEMENT DURING THE OPERATIONAL
PHASE
EMP proposed for implementation is detailed under the following heads:
Air Pollution Management
Wastewater Management
Solid/Hazardous Waste Management
Noise Management
Greenbelt Development
Occupational Safety and Health
Implementation of EMP and monitoring programme
10.3.1 Air Pollution Management
10.3.1.1 Source of Air Pollution and Control Measures
Flue gas emission is due to the combustion of fuel Agro Briquettes in
boiler, Thermic Fluid Heater and Hot Air Generator. Most probable
pollutants will be SPM, SO2 and NOx. Multi Cyclone, bag filter & water
scrubber will be installed as APCM for each flue gas emission source.
Process emission will be from the stack attached with reaction vessels
and corresponding pollutants will be HCl and SO2. To control the process
emission, water and alkali scrubber will be provided. Spin flash dryers
(SFD)/Fluid Based Dryer (FBD)/Rotary Vacuum Dryer (RVD) will be
equipped with in-built cyclone and bag filter. Furthermore, adequate
stack height and facility for sampling such as ladder and sampling point
will be provided as per the GPCB guidelines. The details of stacks with
their APC measures are given in Table 2.8 of Chapter-2.
Measures to control fugitive emission
The fugitive pollutants of PM, VOCs & Acid mists are likely to emit from
process area. Unit will adopt following measures,
Adequate scrubbing system to absorb the process gas and
condensing systems,
Entire process will be carried out in closed reactors,
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-4
Pneumatically transfer of liquid raw material in rector,
Raw material will be stored in the covered structure,
Regular maintenance of valves, pipes, etc.,
Greenbelt will be developed around the plant to arrest the fugitive
emission.
PPEs will be provided to the workers, and
Frequent work area monitoring will be done to ensure fugitive
emissions level.
10.3.1.2 Measures for Solvent Recovery
Details technology/mitigation measure to achieve the Volatile
organic compounds (VOCs)/Fugitive emissions @ 99.997%.
Unit will use Methanol, Dichloromethane, Isopropyl Alcohol, Ethyl Acetate,
Acetone, Toluene, Chloroform, Hexane and Dimethyl Formamide (DMF)
etc.
These are mostly transferred to reactors by means of pumps and their
related pipelines. Pumps are provided with proper mechanical seal, and
pipeline is connected with each other by flanges and gaskets. There will
be practically no emission of solvents in form of VOCs. The leak detector
and emission will be checked by digital transmitter with smart sensor. If
the detection level exceed in the work area of half level of TLV/TWA
value, immediate action will be taken by operator to shut down
valve/pump to prevent the leak and emission of gas. Periodically
preventive maintenance schedule shall also be conducted by team.
Unit will handle following solvent having following physical properties
namely BP oC and FP oC.
Solvent to be used with B.P. and F.P. Sr. No. Name of solvent BP oC FP oC
1 Methanol 64.5 12
2 Dichloromethane 39.75 NA
3 Isopropyl Alcohol 82.5 18.3
4 Ethyl Acetate 77.0 -4.4
5 Acetone 56.2 -20
6 Toluene 110.6 4.44
7 Chloroform 61 NA
8 Hexane 69 -22
9 Dimethyl Formamide (DMF) 153 57.7
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-5
Unit will follow following LDAR (Leak Detection and Repair)
Programme.
1. Unit will prepare summary of possible Sources of equipment leaks
like; Pumps, Valves, Joints/ Connectors, Pressure relief devices,
Open-ended lines etc.
2. Regular monitoring to check and repair leaking components, including
valves, pumps, connectors, compressors, and agitators, in order to
minimize the emission of fugitive volatile organic compounds (VOCs).
3. Unit will use VOC meter to detect the VOCs and its source to
repairing any leakages
4. Find the Sources of leakages, its Causes and Control the Leaks by
way of modifying/replacing leaking equipment with “leakless”
components.
5. Develop awareness of the benefits of leak detection and repair into
the company’s operating and maintenance program in terms of cost
savings, environmental protection, and worker and community safety.
6. Reducing Product Losses, Increasing Safety for Facility Workers and
Operators, Decreasing Exposure for the Surrounding Community,
Avoiding Enforcement Actions.
7. Install Brine chiller (-10 to -200C chiller) for secondary condenser of
solvent recovery system to achieve VOCs loss practically zero.
8. Use Double seal/mechanical seal for control of VOC.
9. Closed handling system shall be provided for chemicals.
10. Reflux condenser shall be provided over reactor.
11. System of leak detection and repair of pump/pipeline based on
preventive maintenance.
12. The acids shall be taken from storage tanks to reactors through
closed pipeline.
13. Storage tanks shall be. vented through trap receiver and condenser
operated on chilled water
14. The condensers shall be providing with sufficient HTA and residence
time to achieve maximum recovery.
15. Solvents shall be stored in a separate space specified with all safety
measures
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-6
16. Proper Earthing shall be providing in all the electrical equipment
wherever solvent handling is done.
17. Entire plant shall be flameproof. The solvent storage tanks shall be
providing with breather valve to prevent losses.
10.3.1.3 Odour Control Plan
All solid raw materials shall be charged directly to reactor through special
air lock hopper against slight negative pressure (in water column) so that
no odour is emitted to the environment. Solid charging nozzle in reactor
shall be projected inside so that it directly falls in to the solvent media,
thereby eliminating carrying over of solid to vapour nozzle. Powder
transfer system shall also be used wherever applicable to have zero loss
of powder into the atmosphere. All liquid raw material handled in drum
shall be cooled down before charging so as to minimize its vapour
pressure and control of odour. Alternatively vacuum lock could also be
used in day tank for transfer of liquid from drum (pumping under
vacuum). Proper Personal Protective Equipment (PPEs) will be provided to
the workers who are involved in handling odorous materials.
10.3.2 Water Environment
Unit will satisfy its fresh water requirement from Bore well water supply.
Total water requirement (Industrial + Domestic + Greenbelt) will be 253
KLD; out of which 118 KLD will be fresh water requirement & 135 KLD
will be recycle/treated water (RO permeate & MEE condensate). Total
industrial wastewater generation will be 141 KLD. The main source of the
industrial wastewater generation will be from process including lab and
scrubber (99 KLD), washing (10 KLD), utilities (Boiler & cooling - 10
KLD), and water treatment (22 KLD).
Process effluent along with wastewater of scrubber, washing and utility
will be taken to RO after primary and secondary treatment. RO reject will
be sent to MEE; RO permeate and condensate of MEE will be reused.
Domestic wastewater will be disposed to soak pit. Thus, achieving Zero
Liquid Discharge (ZLD). ETP sludge and MEE salt will be disposed to
approve TSDF site. Domestic effluent of 4.0 KLD will be disposed to soak
pit.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-7
Effluent treatment scheme:
Wastewater from process, washing Scrubbers etc. will be collected in
equalization/neutralization tank, where it is neutralized, depending upon
the acidity/alkalinity of influent. Later it will be pumped into primary
settling tank to settle down suspended solid. Later it will be pumped into
aeration tanks for biological treatment, where microorganisms will be
reduced organic load in effluent. Then effluent is allowed to secondary
settling tank. This activated effluent is passed to settling tanks for
settling purpose. Here sludge formed is settled and removed from the
bottom hopper. Then water will be transferred to the pressure sand filter
followed by RO.
RO permeate will be reused, and RO reject will be sent to MEE/ATFD.
Sludge will be transferred to the sludge drying bed. After drying, the
dried sludge will be collected, packed in HDPE bags and stored in
separate storage area and disposed at approved TSDF site. Salt from
MEE/ATFD will be sent to TSDF site, too.
10.3.3 Hazardous/Solid Waste Management
Entire quantity of hazardous waste will be handled & disposed as per
Hazardous & Other waste (Management & Transboundary Movement)
Rules, 2016. ETP sludge (25 MTPM) and MEE salt (50 MTPM) from
wastewater treatment and Process sludge (12 MTPM) will be disposed of at
approved TSDF site. Spent carbon (0.75 MTPM), and spent catalyst (1.0
MT/Month) will be returned back to supplier for regeneration. Distillation
residue (15 MTPM), off specification products and date expired products
will be sent for co-processing or at CHWIF. Used lubricating oil (40
Lit/month) will be sold to registered recycler. Discarded Drums (700
Nos./month) & containers/ Liners (0.5 MT/month) will be sold to actual
users. HCl (20-25%) - 75 MT/month and Sodium bisulfite (NaHSO3) - 50
MT/month will be sold to actual user under Rule-9 of HAZ Rule.
The unit will provide isolated area with impervious flooring & roof cover for
the storage of hazardous waste. Details of hazardous waste disposal
methods are given in Chapter 2 (Table 2.10).
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-8
Fly Ash management
Unit committed to install and operate fly ash brick making unit inside the
plant for fly ash disposal with capacity of 2000 bricks per hour hydraulic
pressure machine for operate once in a week to utilize fly ash to be
generated from burning of Ago briquette in boiler, HAG and TFH. The
criteria of selection of fly ash brick unit is summarized below.
About 80% fly ash will be used for the production of fly ash bricks. The
ratio of Fly Ash (80%) Gypsum (15%) and sand (5%). Based on the
maximum fly ash generation (4.0 TPD), around 2000 per day *26 =52000
nos /month will be produce. To considering 4 day production per month
(Only Sunday), unit will require 13000 brick per day capacity of machine.
To considering this aspect unit will purchase semi-automatic machine with
capacity of 2000 bricks per hour hydraulic pressure machine.
Above details incorporated in modified EIA report on section 2.9.3 Fly Ash
management, page 2-41.
Storage and Transportation of Solid/Hazardous Waste:
Proper Hazardous waste storage area with impervious flooring and
covered shed is provided for storage of solid/hazardous waste.
Entire quantity of the hazardous waste is stored in the isolated
hazardous waste storage area within premises having leachate
collection system and roof cover. The storage yard shall be properly
labeled for identification of wastes.
Hazardous waste shall not be stored for a period more than 90 days.
Records of the same shall be maintained and make them available for
inspection.
Properly packed & labeled waste shall be transported through
dedicated vehicle to authorized TSDF facility.
10.3.4 Noise Control
Reynish Pharmachem proposes following measures to minimize the
impact of noise on the environment during the operational phase,
Noise suppression measures such as enclosures, buffers and/or
protective measures should be provided, if required (wherever noise
level is more than 90 dB (A)).
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-9
Extensive oiling, lubrication and preventive maintenance will be carried
out for the machineries and equipments to reduce noise generation.
Use of PPE like ear plugs and ear muffs is made compulsory near the
high noise generating machines.
Moreover, the personnel shall be provided breaks in their working
hours, with the continuous exposure not increasing three hours.
The transportation contractor shall be informed to avoid unnecessary
speeding of the vehicles inside the premises.
Acoustic enclosure shall be provided for D.G. set and similar provisions
like noise attenuator wherever suitable/possible.
Areas with high noise levels will be identified and segregated where
possible and will include prominently displayed caution boards.
Adequate greenbelt will be developed within industrial premises and
around the periphery to prevent the noise pollution.
Periodic monitoring of noise levels as per post-project monitoring plan
shall be done on regular basis.
By taking measures as mentioned above, it is anticipated that noise
levels in the plant will be maintained below the permissible limit.
10.3.5 Green Belt Development
Tree plantation is one of the effective remedial measures to control the
air pollution and noise pollution. It also causes aesthetics improvement of
the area as well as sustains and supports the biosphere. Reynish
Pharmachem proposes to do extensive plantation in 12175 m2.Overall
greenbelt area will be more than 33% of the total area of the project.
Design of Green Belt
As far as possible, following guidelines will be considered in greenbelt
development.
The spacing between the trees will be maintained as per SPCB
guideline i.e. 1 tree/4 sqm.
Spaces, so that the trees may grow vertically and slightly increase
the effective height of the greenbelt.
Planting of trees in each row will be in staggered orientation.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-10
The short trees (< 10 m height) will be planted in the first two rows
(towards plant side) of the green belt. The tall trees (> 10 m height)
will be planted in the outer three rows (away from plant side).
Planting methodology
The plantation shall be done in pits. The pit shall be refilled with soil after
the planting. The sampling of healthy, nursery raised, seedlings in
polythene containers shall be transported in baskets. Planting shall be
done after first monsoon showers. The level of soil is about 10 cm above
of ground level. The soil around the plant shall be pressed to form a low
through. About 25 gm chemical fertilizers shall be added. Watering shall
be continued after plantation if any dry spells follows. Planted area shall
be inspected and mortality rate ensured for each species. The dead and
drying plant shall be replaced by fresh seedlings.
Selection of species for greenbelt
For the development of greenbelt, plants having simple big leaves and
native species are preferred to the plants. The plants are suitable for
greenbelt development based on gaseous exchange capacity of foliage
which is ascertained by the following characteristics:
The plant should be fast growing.
It should have thick canopy cover.
It should be perennial and evergreen.
It should have large leaf area index.
It should be indigenous.
It should be efficient in absorbing pollutants without significant effects
on plant growth.
The objectives of the industrial greenbelt are to improve the micro-
environment. The success depends on the type of land available and
selection of suitable tree species for pollution control. Selection of tree
species for industrial areas is influenced by the nature of industry. The
objective should be to ensure a green cover tolerating pollutant gases
and solid particulates present in the atmosphere. It is also advisable to
select suitable tree species and adopt simple techniques which require
minimum investment and care.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-11
Floral species recommended for greenbelt
Azadirachtaindica (Neem), Albizialebbeck (Siris), Pongamiapinnata
(Karanj), Ficusreligiosa (Peepal) are suggested for the greenbelt
development with respect to this particular area. They are mostly
deciduous and evergreen tree types suitable to be grown in the area.
Survival rate of trees and post plantation care
Considering the availability of water and general survey of surrounding
area, the survival rate is expected to be around 70-75%. Moreover, the
wire net guards will be provided to protect the saplings. The same will be
properly manured and watered so that it can grow well.
Protection of plantation site:
Protection from grazing will be done by erecting tree guards around
planted sapling.
Though the tree suggested for plantation will require very less water,
however during the first year watering will be done twice in a day.
There after watering will be done twice in a week.
The manuring will be done when plantation take up. For this purpose,
cow dung will be dump in the pit. No other manuring will require for
plantation. Cow dung is easily available in the study area.
Damaged plants will be replaced with new plants.
Strict surveillance will be made to increase the survival rate of the
trees.
10.3.6 Occupational Health & Safety Plan
To maintain high standard in Health, Safety and Environment, necessary
key mitigation measures & action plan as EMP has been suggested as
described below.
Post-employment health check-up programs will be carried out on
annually and all records & documents related with employee health
check-up program will be maintained.
As per RA report, all risk control & prevention measures in the unit will
be implemented.
Necessary PPEs, safety equipments/materials to ensure healthy & safe
work conditions will be provided to employees.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-12
All employees will be provided with required set of PPEs like ear plug,
ear muff etc. where noise levels in excess of 80 dB(A) are regularly
generated.
It is recommend that Pre-employment health check-up programs shall
be carried out for every new employee and all records & documents
related with employee health check-up program shall be maintained
by the proponent.
Safety documents, procedures, guidelines along with MSDS shall be
provided to the associated/concerned personnel engaged in respective
operational activities.
Training programs & safety audit shall be done on regular basis to
prevent impacts of the operational activities on occupational health as
well as to improve workplace condition & safe work system.
The proponent shall ensure implementation of emergency
management plan with provision of fire-fighting equipment/facilities,
first aid & medical facilities, evacuation procedures etc.
Proponent shall also ensure proper implementation & functioning as
well as assess effectiveness of this safety & emergency system on
regular basis throughout the project operation phase.
Plans for Periodic Medical Checkup
Part time doctor is periodically visited the plant for health check-up of
each employee.
Pre-employment health check-up will be followed by periodical health
check-up with special attention to occupational health.
Medical records of each employee will be maintained in prescribed
format as per Factory Act.
The health check-up will be conducted as per the pre-designed format
which will include chest X-rays, Audiometry, Spirometry, Vision
Testing, ECG, Blood and urine test etc.
The work zone monitoring will be conducted on regular basis.
Monitoring of the Occupational Injury & It’s Impact on workers
The action plan will be prepared to monitor the injury to workers:
Each workplace will be evaluated for the existing work conditions.
Unsafe Act &unsafe Practices will be identified.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-13
Unsafe equipment, unsafe areas, etc., will be identified.
Area will be checked for proper Ventilation and Illumination.
Air-borne concentration of toxic chemicals will be measured and
records will be kept.
Evaluation of training & on the job work.
Impact of the above mentioned unsafe conditions on workers will be
studied and remedial measures for the same will be adopted.
10.3.7 Details of the separate isolated storage area:
Unit will provide isolated storage area for solvent and corrosive
chemicals. Details of storage are given in Table 7.1 of Chapter-7 of EIA
report. All the raw materials are stored in isolated storage area and
containers are tightly closed.The following precautions shall be taken to
avoid foreseeable accident like spillage, fire and explosion hazards and to
minimize the effect of any such accident and to combat the emergency at
site level in case of emergency.
Various emergency spots in plant area will be identified and kept in
sharp and alert watch.
Protective equipment will be regularly checked and will be kept easily
accessible and easily workable during emergency.
Safety installations like available quantity of running water will be
regularly watched.
Fire bucket and hose reels will be provided to withstand the fire or
explosion conditions.
Various types of fire extinguishers such as (Foam type, water CO2
type, CO2 type) will be provided inside the factory premises.
Every pressure vessel will be provided with minimum one or more
pressure relief devices. The design of the valve is made in such a way
that the breakage of any part will not obstruct force discharge of the
liquid under pressure. Moreover, relief valves are tested and a periodic
schedule for their testing shall be maintained. The defective valves will
be removed if found unsafe for the operation.
10.4 POST-PROJECT ENVIRONMENTAL MONITORING
The highlights of the integrated environmental monitoring plan are:
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-14
The stack monitoring facilities like ladder, platform and port-hole of all
the stacks maintained in good condition.
Regular monitoring of all gaseous emissions from stacks &fugitive
emissions in the process areas.
The performance of air pollution control equipment such as cyclones
and scrubbers will be evaluated based on these monitoring results.
Water consumption in the unit recorded daily.
Analysis of untreated and treated effluent will be carried out regularly.
Performance of effluent treatment plant units, RO, and MEE evaluated
based on above analysis results.
As far as possible, noise curbed at its source, with the help of acoustic
hoods and other such noise reducing equipment. Regular noise level
monitoring carried out.
Green belt properly maintained and new plantation programmes
undertaken frequently.
Continued environmental awareness programmes carried out within
the employees and also in the surrounding villages.
Rain water harvesting ponds will be developed within the industrial
premises and encouraged in the surrounding villages too.
Table: 10.2 Environment Monitoring Plan
Nature of
Analysis
Frequency of analysis
with its analyzer
Parameters No. of samples
Wastewater analysis
Monthly by external agency
pH, TDS, SS, COD, BOD, Oil
& Grease, etc.
4-6 samples
Stack Monitoring of each stack
Monthly by external agency
PM, SO2, NOX, HCl
All stacks
Ambient Air Quality
Monitoring
Monthly for 24 hours or as per the statutory
conditions by external agency
PM10, PM2.5, SO2, NOX, HCl
3-5 locations
Noise level Monthly as per the statutory conditions by
external agency
Noise level 6-8 locations (Nr. Main gate, Nr.
boiler, Nr. D. G. Set,
Process area etc.)
Work zone fugitive monitoring
Monthly by external agency
RPM, VOCs, acid mist
2-3 locations
Health check-up
of workers
As per the statutory
guideline
All workers
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-15
10.4.1 Details of Work Place Air Quality Monitoring Plan
Work zone monitoring will be carried out by independent competent third
party every month. Records will be kept in Form No. 37 as per Gujarat
Factories Rules. Location for samplings will be identified. Following
information will be incorporated in the format for maintaining records of
work zone monitoring:
Location/Operation monitored
Identified contaminant
Sampling instrument used
Number of Samples
Range of contaminant concentration as measured in sample
Average concentration
TWA concentration of contaminant
Reference method used for analysis
Number of workers exposed at the location being monitored
Signature of the person taking samples
10.5 ENVIRONMENT MANAGEMENT BUDGET ALLOCATION
Total capital cost and recurring cost/annum earmarked for environment
pollution control measures by Reynish Pharmachem Pvt. Ltd. will be as
under.
Table 10.3: Budget Allocation for Environment Management
Sr.
No.
Particulars Capital Cost (Rs. in
Lakhs)
Recurring Cost per annum
(Rs. in Lakh)
1 Air Pollution Control 32 5.0
2 Water Pollution Control 141 95
3 Noise Pollution Control 1.0 2.0
4 Solid/Hazardous Waste Management
5.5 28
5 Environment Monitoring
and Management
2.5 3.0
6 Occupational Health 15 10
7 Green Belt Development Plan 35 5.0
8 Rain Water Harvesting
System
18 2.0
Total 250 150
10.6 ENVIRONMENTAL MANAGEMENT CELL
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-16
Reynish Pharmachem will set up separate Environment Management Cell.
The major duties & responsibilities of EMC will be as follows:
To implement the Environmental Management Plan,
To ensure regular operation &maintenance of pollution control devices,
To assure regulatory compliance with all relevant rules and
regulations,
To minimize environmental impacts by strict adherence to the EMP,
To initiate environmental monitoring as per approved schedule,
Review & interpretation of monitored results and corrective measures
in case monitored results are above the specified limit,
Maintain documentation of good environmental practices and
applicable environmental laws as ready reference,
Maintain environmental related records,
Coordination with regulatory agencies, external consultants and
monitoring laboratories, and
Maintaining log of public complaints and the action taken
10.6.1 Hierarchical Structure of Environmental Management Cell
The hierarchical structure of Reynish Pharmachem is given below
Figure 10.1: Environment Management Cell
10.6.2 ENVIRONMENT POLICY
Unit will develop Environment Policy. They commit themselves to:
EHS Head
ETP in-charge Safety officer
General Manager
(Operation)
ETP
Operator
ETP
Chemist
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-17
Ensure continuous improvement in environmental performance of our
works through protective Environmental management system.
Comply with applicable legal and other requirements related to
environmental aspects.
Conserve the resources particularly water, power by fixing and
improving consumption norms.
Concept of cleaner production will be adopted.
Ensure involvement of all employees and contractors in effective
implementation of Environment Management System through
training and awareness.
Promote awareness among local surrounding community for
preservation and maintaining clean environment.
10.6.3 Reporting System of Non-Compliances/Violations of
Environmental Norms
Record keeping and reporting of performance is an important
management tool for ensuring sustainable operation of the unit. Records
are maintained for regulatory, monitoring and operational issues. Reynish
Pharmachem Pvt. Ltd. will develop reporting systems of non-
compliances/violations of environmental norms to the Board of Directors.
The mechanism is summarized below:
1. Identify deviation/non-compliance/violation of environmental norms
as lay down in consent to operate and letter of Environmental
clearance. Record to communication/complain received from
plausible stake holder.
2. The EHS manager will identify deviation/non-compliance/violation
from failure to comply with statutory requirements.
3. Respond from EHS manager within reasonable time limit to concern
authorities with c/c mark to Technical head.
4. Technical head will take it in action and give necessary guideline to
comply this deviation/non-compliance/violation of environmental
norms. Parallel arrange budget for necessary action to comply the
condition.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-18
5. Communication received from the EHS manager will be discussed in
technical management meeting.
6. Board discussion, Decision and Action
The chairperson will review the information available and take a
decision depending on the seriousness of the violation.
The decision will be taken to ensure the compliance of non-
compliance/violation of environmental norms and it’s safeguarded.
The decision will be taken by consensus and if no consensus is
arrived at, voting will be conducted.
Enlist measures that would undertake to ensure that deviations/
non-compliance/violations of Environmental norms and take care
not to occur same violation in future.
10.6.4 Framework for Continual Improvement of Environmental
Performance of Organization
10.7 RESOURCE CONSERVATION AND CLEANER PRODUCTION
Steps that are undertaken by the industry are given below:
RO permeate and MEE condensate will be reused to reduce fresh
water demand.
Housekeeping will be regularly maintained. Dedicated staff for the
purpose will be employed.
Solid wastes e.g. powders, spills, etc. in process and packaging are
to be separately collected and disposed of instead of allowing these
EMP
Implementation
Monitoring as
per EMP
requirement
Internal and
External Audits Corrective and
Preventive Actions
Review and revision of EMP
based on Environmental
Performance Evaluation Improvement
Mitigation
measures
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-19
to effluent streams. This will reduce load to treatment and increase
the efficiency of treatment system.
Mechanical seals will be provided to the process vessels having
agitator for reduction of fugitive emissions and leakages.
Rain water harvesting system will be adopted to compensate the
fresh water withdrawal.
10.8 ENERGY CONSERVATION PROGRAMME
Energy conservation measures are often the easiest, quickest and
cheapest way to reduce costs and be environmentally pro-active. The
conservation efforts would consist of the following:
Ensure proper selection fuel-firing equipments - Burners, mechanical
stokers, etc.
Reduce radiation losses from boilers, furnaces and auxiliary equip-
meant by improved thermal insulation. This will also improve the
working conditions within the building and eliminate unnecessary
ventilation,
Schedule process operations to avoid fluctuations in boiler loads,
Keep the heat transfer surfaces clean by preventing excessive scale
formation,
Pressure vessels should be designed with a length to diameter ratio
of roughly three as they are the most economical,
Maximize the use of natural lighting through design,
CFLs or LED lights are used in administration building and plant
premises,
Constant monitoring of energy consumption and defining targets for
energy conservation,
Maximize the use of laptop computers over desktop computers as
Laptops use less energy than desktop and leave a smaller
environmental footprint at end of life,
Adjusting the settings and illumination levels to ensure minimum
energy used for desired comfort levels,
Recycling of water will be done, and
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-20
10.9 SOCIO-ECONOMIC ACTIVITIES
Enterprise Social Commitment (ESC) refers to voluntary actions
undertaken by company/organization to either improve the living
conditions (economically, socially, environmentally) of local communities
or to reduce the negative effects of the project. By definition, voluntary
actions are those that go beyond legal obligations, contracts, and license
agreements. Socio-economic development activities is a concept of
organization whereby organizations serve the interests of society by
taking responsibility for the impact of their activities on customers,
employees, shareholders, communities and the environment in all aspects
of their operations.
Following activities will be under taken as a part of CSR under
different heads:
A. Education
Awarding meritorious school students in SSC & HSC
Science Lab - Equipment & books in libraries for schools
Supports for sport & cultural competitions in schools
B. Health and family welfare
Malaria eradication camps (collection of blood sample & detection of
virus & free medicine distribution, blood donation camp)
Contribution towards primary Health Services depending on local
needs.
Dental & Eye checkup camp
C. Preservation of Environment and Sustainable Development
Water harvesting systems in nearby villages.
Landscaping and greenbelt development in & around the project
site.
Provide sanitation facilities to villagers.
D. Women Empowerment & children Development activities
Providing training and basic facility for self-sustainability of women.
Scholarship for education to children coming from Low Income
family.
Reynish Pharmachem Pvt. Ltd. proposes to allocate Rs. 2.0 Crores
(Increase the CER budget from 2.5% to 5.0% as suggested by EAC
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 10-21
committee (Industry-II) of total project cost i.e. Rs. 40.0 Crores) towards
the Enterprise Social Commitment. Proposed activities with budgetary
allocation are given below.
Table: 10.4 Budgetary Provisions for the Social Upliftment
Sr.
No.
Activities Years (Rs. in lakhs) Total
Budget
(Rs. in
Lakhs)
1st 2nd 3rd
1 Educational activities
Computers 6.08 6.08 -- 12.16
Scholarship 12.8 12.8 12.8 38.4
2 Drinking water facilities 12 sets of RO and
water cooler at
Primary school and
village Panchayat of 4
villages
14.0 14.0 14.0 42.0
Operating and
maintenance cost
2.0 2.0 2.0 6.0
3 Public Health and family
welfare
Around 10 camp with
cluster of 5 to 6
villages
4.0 4.0 4.0 12.0
Free Medicines 6.0 6.0 6.0 18.0
4 Provide Sawing and
embroidery machine to
women coming from BPL
family and widow
women.
All 53 villages in the
study area
Onetime 100 nos
Sawing machine
5.0 5.0 5.0 15.0
Onetime 50 no
embroidery Machine
5.0 5.0 2.5 12.5
5 Widening and digging of
four village pond namely
Dabhasa, Bhoj Ranu
Pond and Dabka and
other as per the
suggestion by local
authorities.
8 village pond 22.0 22.0 -- 44.0
Total 76.88 76.8
8
46.3 200.06
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 11-1
Chapter-11
Summary & Conclusion
11.1 PROJECT DESCRIPTION
11.1.1 General Introduction
M/s. Reynish Pharmachem Pvt. Ltd. is a green field project, proposes
to set up bulk drugs manufacturing unit at Survey no. 504, 505, 507,
Village: Dabhasa, Ta.: Padra, District: Vadodara, Gujarat. Total
production capacity of all products will be tune around 50 MT/month.
Project activity falls under item 5(f) of the Schedule of EIA Notification,
2006 and its subsequent amendments.
11.1.2 Brief project description
Name of the Project Reynish Pharmachem Pvt. Ltd.
Proposed production capacity 50 MTPM
Proposed project cost Rs. 40 Crores
Manpower requirement About 65 persons
Location
Survey No. 504, 505, 507
Village Dabhasa
Tehsil Padra
District Vadodara
State Gujarat
Area 36958 m2
Coordinates Latitude: 22°13'32.76"N
Longitude: 73° 1'13.01"E
Nearest
Railway Station Vadodara Railway Station – 19.0 km,
Padra Railway station - 7.0 km
Air Port Vadodara Airport, about 24 km
Town Padra, about 7.0 km
City Vadodara, about 20 km
National Park/Wildlife Sanctuary None, within 10 km radius
Proposed
Power Requirement 1000 kVA, Source: MGVCL (Madhya Gujarat Vij Company Limited)
Water Requirement Total: 253 KLD;
Fresh water: 118 KLD; Recycle: 135 KLD
Source of raw water: Bore well
Wastewater Generation Industrial: 141 KLD, ZLD
Domestic: 4 KLD
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 11-2
Fuel Requirement Agro Briquettes: 37 TPD Diesel for D.G. Set: 125 lit/hr.
Source of Air Emission Boiler (1 no.), Thermic fluid heater (1 no), Hot air generator (1 no.), D. G. set
(1 no.), process vent (1 no.), SFD/FBD/RVD (5 nos.).
Details of Haz. Waste ETP sludge, MEE Salt, Distillation residue,
spent carbon, spent catalyst, off specific
product, date expired product, Used Oil,
Discarded drums/containers & Liners,
HCl, Sodium bisulfite
11.1.3 Investment of the project
Estimated cost of the proposed project will be around Rs. 40.0 Crores.
Out of this, Rs. 2.5 Crores will be earmarked as capital investment for
EMS and Rs. 1.5 Crores will be recurring/operating cost per annum.
11.1.4 List of products
Product details with its capacity are given in table below.
Sr. No.
Name of Products Qty. MTPM
1. Telmisartan 48.0
2. Ondansetron HCl
3. Benfotiamine
4. Albendazole
5. 4-Hexyl resorcinol
6. Zopiclone
7. Tamoxifen citrate
8. Bupropion HCl
9. Anstrozole
10. Theophylline
11. Allantoin
12. Terbinafine Hydrochloride
13. Pregabalin Hydrochloride
14. Rebamipide
15. Valsartan
16. R & D Drugs 2.0
Total 50.0
11.2 DESCRIPTION OF ENVIRONMENT
11.2.1 Baseline Environmental Study
To predict the impact of the project on the surrounding environment, the
current baseline environmental status was studied by collecting the data
and carrying out monitoring during October, 2018 to December, 2018
in the study area of 10 km radius from project site as per the TOR.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 11-3
11.2.2 Air Environment
The ambient air quality monitoring was carried out at 8 AAQM locations,
to assess the existing sub-regional air quality status during the period of
October, 2018 to December, 2018.
Combined Sampler along with the analytical methods, prescribed by
CPCB was used for carrying out air quality monitoring. At all these
sampling locations; PM10, PM2.5, SO2 and NOx were monitored on 24-
hourly and HCl, CO, HC and VOCs were monitored on 8-hourly basis to
enable the comparison with ambient air quality standards prescribed by
the CPCB. The data on concentrations of various pollutants were
processed for different statistical parameters like arithmetic mean,
standard deviation, minimum and maximum concentration and various
percentile values. The results are summarized below:
Particulate Matter (PM10)
An average and 98th percentile value of 24-hourly PM10 values at all the
locations are found from 63.7 – 71.0 g/m3 and 63.7 – 68.8 g/m3. The
results were found well within the National Ambient Air Quality Standards
(NAAQS-CPCB) of 100 g/m3.
Particulate Matter (PM2.5)
An average and 98th percentile value of 24-hourly PM2.5 values at all the
locations ranges from 37.0 – 48.0 g/m3 and 41.4 – 50.0 g/m3. The
values are well within National Ambient Air Quality Standards (NAAQS-
CPCB) of 60 g/m3.
Sulphur Dioxide (SO2)
An average and 98th percentile value of 24-hourly SO2 value of arithmetic
mean at all the locations ranged from 13.0 – 16.3 g/m3 and 15.8 – 20.8
g/m3 respectively, which are well below National Ambient Air Quality
Standards (NAAQS-CPCB) of 80 g/m3.
Oxides of Nitrogen (NOx)
An average and 98th percentile value of 24 hourly NOx value of arithmetic
mean at all the locations ranged from 15.8-18.1 g/m3 and 19.7-23.6
g/m3 respectively, which are well below the National Ambient Air Quality
Standards (NAAQS-CPCB) of 80 g/m3.
Hydrochloric acid (HCl)
HCl found below detectable limit at all the locations.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 11-4
Carbon Monoxide (CO)
Minimum & Maximum value of CO at all the locations ranged from 1024 –
1182 g/m3.
Hydro Carbon (HC)
Minimum & Maximum value of Methane HC at all the locations ranged
from 32.2 – 41.1 g/m3 and non-methane HC ranged from 1028 – 1185
g/m3.
Volatile Organic Compounds (VOCs)
Minimum & Maximum value of VOC at all the locations ranged from 0.27
g/m3 – 3.41 g/m3.
Conclusion:
The quality of ambient air in the study area is compared with AAQM
Standards prescribed by CPCB & found below the prescribed standards.
11.2.3 Water Environment
Eight surface water & eight ground water samples were collected during
the study period.
Surface Water Quality
Surface water samples were collected from pond of village Dabhasa,
Padra, Bhoj, Ranu, Luna, Dabka, Tajpur and Mahi River. Results of the
same are given in Chapter-3 of EIA report.
Conclusion:
It was observed that all the physico-chemical parameters and heavy
metals from surface water samples except turbidity are below stipulated
drinking water standards and are suitable for domestic purposes.
Ground Water Quality
Ground water samples have been collected Project site, Dabhasa, Padra,
Umaraya, Dhobikuwa, Ranu, Bhoj and Vishrampura villages.
The summary of the analysis is as below:
Color: All the samples were found color less meeting desirable norms.
pH: All the samples meet the desirable standards (pH ranges from 7.3-
7.9).
Total Dissolved Solids (TDS): TDS in samples ranges from 1092 mg/L
(Nr. Project Site) to 1923 mg/L (Umaraya). The entire samples meet the
permissible limit of 2000 mg/L TDS.
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Calcium: Calcium contents in the water ranges from 44 mg/L
(Dhobikuwa) to 92 mg/L (Umaraya), all the samples meet the permissible
limit of 200 mg/L, (Permissible Limit in the Absence of Alternate Source).
Magnesium: Magnesium content in the water ranges from 40 mg/L
(Bhoj) to 59 mg/L (Dhobikuwa). All the samples meet the permissible
limit of 100 mg/L (Permissible Limit in the Absence of Alternate Source).
Sulfate: Sulfate content in the water ranges from 58 mg/L (Nr. Project
Site) to 116 mg/L (Dabhasa). All the samples meet the permissible limit
of 400 mg/L (Permissible Limit in the Absence of Alternate Source).
Fluoride: Fluoride content in the water ranges from 0.56 mg/L
(Vishrampura) to 0.70 mg/L (Dhobikuwa). All the samples meet the
permissible limit of 1.5 mg/L (Permissible Limit in the Absence of
Alternate Source).
Total Alkalinity: Total alkalinity in the water samples ranges from 308
mg/L (Dabhasa) to 346 mg/L (Padra). All the samples are within the
permissible limit of 600 mg/L (Permissible Limit in the Absence of
Alternate Source).
Other Parameters: Potassium (ranges from 43 mg/L to 68 mg/L),
Sodium (ranges from 323 mg/L to 592 mg/L) and Chloride (ranges from
512 mg/L to 935 mg/L). All the samples meet permissible limit in the
absence of alternate source.
Heavy metals like cadmium, copper, lead, chromium, iron and zinc are
well below the limit in all samples.
Conclusion:
The results have been compared with the drinking water quality
standards specified in IS: 10500-2012 & all parameters meet the
permissible limit set by the authority (BIS).
11.2.4 Noise Environment
Noise monitoring has been conducted at nine locations in the study area.
The monitored noise level in the day time Leq (Ld) varies from 50.7 to
53.7 dB(A) and the night time Leq (Ln) varies from 39.2 to 43.4 dB(A)
within the study area. Higher noise value of 53.7 dB(A) was recorded
during day time at Village 1000 m East from the site & lower noise value
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 11-6
of 40.1 dB(A) was recorded during night time at 500 m North from the
site.
11.2.5 Soil Quality
Soil samples were collected from 8 different locations and analyzed to
assess the soil quality prevailing in the study area. Physical
characteristics of soil have been delineated through specific parameters,
viz. particle size distribution (grain size analysis), porosity, water holding
capacity and permeability whereas data for chemical characterization of
soil, viz. pH, electrical conductivity, cation exchange capacity and sodium
absorption ratio have been analyzed.
11.2.6 Biological Environment
Baseline data for flora & fauna has been collected with its family. It was
found that, none of the species of conservation importance exists in the
study area and no endangered species found in the study area.
11.2.7 Socio-Economic Environment
Socio-economic study includes description of demography, available basic
amenities like housing, health care services, transportation, education
facilities. Information on the above said parameters has been collected to
define the socio-economic profile of the study area (10-km radius).
11.3 ANTICIPATED ENVIRONMENTAL IMPACTS AND MITIGATION
MEASURES
Impact identification has been carried out for various activities involved in
construction as well as operational phase of the project and prediction
has been done for significant impacts. The summary of anticipated
adverse environmental impacts due to proposed project and mitigation
measures is given below.
11.3.1 Summary of impacts on Air Environment:
(a) During construction phase & Mitigation measures
Main sources of impact during construction phase are due to movement
of vehicles & construction equipment at site, foundation works,
transportation of construction material etc. Water sprinkling in the vicinity
of the construction area will be done to control dust. PUC certified
vehicles will be used. Temporary barricades will be provided to reduce
spreading of particulates from construction area.
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Final EIA Report of Reynish Pharmachem Pvt. Ltd. 11-7
(b) During operation phase & Mitigation measures
Flue gas emission will be from stack attached with boiler where Agro
Briquettes will be used as a fuel; and standby D.G. Set. Most probable
pollutants will be SPM, SO2 and NOx. Multi Cyclone, bag filter & water
scrubber will be installed as APCM for flue gas stacks. Process emission
will be from the reaction vessels and vent of Spin flash dryers (SFD)/Fluid
Based Dryer (FBD)/Rotary Vacuum Dryer (RVD). Pollutants from reaction
vessels will be SO2 & HCl and PM will be generated from SFD/FBD/RVD.
To control the process emission, water and alkali scrubber will be
provided. SFD/FBD/RVD will be equipped with in-built cyclone and bag
filter.
Prediction of impacts on air environment is quantified using ISCST3
model. Maximum Ground level concentrations of 24-hr average for SPM,
SO2, NOx and HCl from the proposed activity are 3.603 g/m3, 1.902
g/m3, 1.628 g/m3 and 0.287 g/m3 respectively. These GLCs are
expected to occur at a distance of 1.0 km from the source in W direction.
The obtained GLCs are well within the 24-hourly ambient air quality
standards stipulated by CPCB. However, to mitigate the impact due to the
proposed, unit will provide adequate stack height for proper atmospheric
dispersion as per the norms.
11.3.2 Summary of impacts on Water Environment
(a) Impacts during construction phase & Mitigation measures:
Temporary impacts are likely to occur due to water consumption &
sewage generation. It will not be significant as water requirement would
be temporary during construction phase. Proper sanitation facilities with
adequate disposal system will be provided within the operational plant.
(b) Impacts during operation phase & Mitigation measures:
Fresh water requirement of the unit will be satisfied from bore well. Total
water requirement (Industrial + Domestic + Greenbelt) will be 253 KLD;
out of which 118 KLD will be fresh water requirement & 135 KLD will be
recycle/treated water (RO permeate & MEE condensate).
Total industrial w/w generation will be 141 KLD. Process effluent along
with wastewater of scrubber, washing and utility will be taken to RO after
primary and secondary treatment. RO reject will be sent to MEE; RO
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 11-8
permeate and condensate of MEE will be reused. Domestic wastewater
4.0 KLD will be disposed to soak pit. Thus, achieving Zero Liquid
Discharge (ZLD). ETP sludge and MEE salt will be disposed to approve
TSDF site.
11.3.3 Impacts on Noise quality & Mitigation measures
(a) Impacts during construction phase & Mitigation measures:
During construction phase, major sources of noise are vehicle’s
movement & construction activities. High noise producing activities will be
restricted to daytime only. Well maintained equipments will be used to
prevent noise. Usage of PPE by workers will be made compulsory.
(b) Impacts during operation phase & Mitigation measures:
During the operation phase, the noise levels may increase due to the
operation of boilers, reactors, D.G. sets and other machineries. The
impact is found to be insignificant outside the premises. Unit will provide
necessary PPEs like earplugs or earmuffs to all workers where exposure is
85 dB(A) or more. Selection of any new plant equipment will be made
with specification of low noise levels.
11.3.4 Summary of Impacts on Land Environment
(a) Impacts during construction phase & Mitigation measures:
The construction activities like excavation, leveling & vehicular
movements will change the landscape, which are expected to be of short
duration & insignificant. Preliminary activities like proper storage of
construction materials & proper management will be done within the
project area. Therefore, impact will be negligible. Unit will provide
sanitation facilities for the staff engaged in construction work which will
prevent the impacts on land.
(b) Impacts during operation phase & Mitigation measures:
Hazardous wastes will have significant negative impacts if disposed
unsystematically. Unit has provided all required structural facilities like
separate hazardous waste storage room with RCC floor, leachate
collection system, and concrete floors within premises. Hence, no
significant negative impact is envisaged on the land environment.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 11-9
11.3.5 Summary of impact on Socio Economy
(a) Impacts during construction phase & Mitigation measures:
As this is a Greenfield project, workers for the construction work will be
required. Local contractors to be employed for construction, so no other
issues like social conflict are envisaged. Temporary employment
generated during construction of project will have beneficial impacts on
economic environment.
(b) Impacts during operation phase & Mitigation measures:
Project will require about 65 persons for its operation, which result into a
positive impact on prevailing socio-economic environment. Project will
also have potential of indirect employment due to the increase
transportation activities, contractual works as well as opportunity of
trade. Thus, overall impacts on socio-economic environment are long
term and positive in nature.
11.3.6 Summary of impact on Ecology
There are no protected areas like National Park/Wildlife Sanctuary within
the 10 km radial periphery of the project site so there will not be any
significant impact on ecology.
11.4 ENVIRONMENT MONITORING PROGRAMME
The unit will have dedicated Environment Management Cell to monitor
and evaluate the environmental performance and to supervise the EMS.
Below Post-project monitoring programme will be followed.
Environment Monitoring Program
Nature of Analysis
Frequency of analysis with its analyzer
Parameters No. of samples
Wastewater analysis
Monthly by external agency
pH, TDS, SS, COD, BOD, Oil
& Grease, etc.
2-3 samples
Stack Monitoring
of each stack
Monthly by external
agency
PM, SO2, NOX,
HCl
All stacks
Ambient Air
Quality Monitoring
Monthly for 24 hours or
as per the statutory conditions by external
agency
PM10, PM2.5,
SO2, NOX, HCl
3-5 locations
Noise level Monthly as per the statutory conditions by external agency
Noise level 6-8 locations (Nr. Main gate, Nr.
boiler, Nr. D. G. Set,
Process area etc.)
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 11-10
Work zone fugitive
monitoring
Monthly by external agency
RPM, VOCs, acid mist
2-3 locations
Health check-up of workers
As per the statutory guideline
All workers
11.5 ADDITIONAL STUDIES
11.5.1 Risk Assessment
Risk analysis and study have been carried out for identification of
accident hazards, selection of credible scenarios, Risk Mitigation
measures etc. All the hazardous chemicals will be stored and handled as
per MSDS guidelines. The detail study is prescribed in Chapter-7.
11.6 PROJECT BENEFITS
Proposed project has a potential for employment of skilled, semi-skilled &
unskilled employees. The direct employment potential is estimated as 65
persons and many others will be indirectly employed. Indirectly, the
proposed project will help the Government by paying different taxes from
time to time, which is a part of revenue and thus, will help in developing
the area. The company has allocated a budget of Rs. 2.0 Crore for CER
activities, which can lead to improve social infrastructure.
11.7 ENVIRONMENTAL MANAGEMENT PLAN
EMP includes the protection & mitigation measures to be implemented to
reduce the adverse impact on the environment. Management plan of
impacts identified is detailed below:
Air Pollution Management
Multi Cyclone, bag filter & water scrubber will be installed as APCM to
control flue gas emission. To control the process emission, water and
alkali scrubber will be provided. SFD/FBD/RVD will be equipped with in-
built cyclone and bag filter.
Appropriate stack height and SMF will also be provided as per the
guideline. To control the fugitive emissions, unit will adopt following
mitigation measures. • Regular maintenance of valves, pumps and other equipment will be
done to prevent leakages.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 11-11
• Regular maintenance of air pollution control equipments like scrubber
and bag filters keeping its efficiency utmost.
• Mechanical seals will be provided to all the reactors.
• Regular periodic monitoring of work area to check the fugitive
emission.
Water Pollution Management
• Industrial wastewater will be treated in ETP followed by RO & MEE to
achieve ZLD.
• RO permeate & condensate of MEE will be reused within the premises.
• Domestic sewage will be disposed off into soak pit though septic tank.
• Unit will maintain the records for the total water consumption.
• Regular monitoring of working of ETP, RO & MEE.
• Rain water harvesting will be done.
Hazardous Waste Management
Entire quantity of hazardous waste will be handled & disposed as per
Hazardous & Other wastes (Management & Transboundary Movement)
Rules, 2016. ETP sludge (25 MT/month), MEE salt (50 MT/month) from
wastewater treatment and Process waste (12 MT/month) will be disposed
of at approved TSDF site. Spent carbon (0.75 MT/month), and spent
catalyst (1.0 MT/month) will be returned back to supplier for
regeneration. Distillation residue (15 MT/month), off specific products and
date expired products will be sent for co-processing or at CHWIF for
incineration. Used lubricating oil (40 Lit/month) will be sold to registered
recycler. Discarded Drums (700 Nos./month) & containers/ Liners (0.5
MT/month) will be sold to actual users. HCl (20-25%) - 75 MT/month and
Sodium bisulfite (NaHSO3) - 50 MT/month will be sold to actual user
under Rule-9 of HAZ Rule. The unit will provide isolated area with
impervious flooring & roof cover for the storage of hazardous waste.
There will not be any major impact on the environment due to hazardous
waste management. Fly ash generation will be around 4.0 MT/day. Fly
ash will be sold to brick manufacturers.
Noise Pollution Management
• Extensive oiling, lubrication and regular maintenance will be carried
out for the machineries and equipments to reduce noise generation.
• PPEs will be provided to the workers working in high noise area.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 11-12
• Acoustic enclosure will be provided to D.G. set.
• Greenbelt will be developed within industrial premises to prevent the
noise pollution.
• Periodic monitoring of noise levels will be done.
Green Belt Development
Total land area is 36958 m2. The unit will develop greenbelt in an area of
12175 m2. Overall greenbelt area will be more than 33% of the total area
of the project.
11.8 CONCLUSION
Based on the study it is concluded that-
There will be no major impact on water environment as entire process
wastewater along with other stream of wastewater will be treated into
ETP and will be taken to RO. RO reject will be sent to MEE and unit will
achieve Zero Liquid Discharge (ZLD).
Condensate of MEE and RO permeate will be reused/recycled within
plant premises. Thus, reducing fresh water consumption.
Domestic effluent will be disposed to soak pit though septic tank.
Multi Cyclone, bag filter & water scrubber will be used as pollution
control equipments for control of flue gas emission.
Water scrubber and Alkali scrubber will be installed as pollution control
equipments for process emission from the unit.
SFD/FBD/RVD will be equipped with in-built cyclone and bag filter.
Fugitive emission will be controlled by close material handling system
and proper storage of materials.
For noise control, unit will provide necessary PPEs like earplugs or
earmuffs to all workers and selection of any new plant equipment will
be made with specification of low noise levels.
Entire quantity of hazardous waste will be handled and disposed as per
Hazardous & Other Waste (Management & Transboundary Movement)
Rules, 2016.
Greenbelt will be developed in more than 33% of the total area.
Fire protection and safety measures will be provided.
Direct and indirect employment opportunities will have positive
impact.
San Envirotech Pvt. Ltd., Ahmedabad
Final EIA Report of Reynish Pharmachem Pvt. Ltd. 12-1
Chapter-12
Disclosure of Consultant engaged
12.1 PREFACE
San Envirotech Pvt. Ltd. (SEPL) has been appointed by Reynish
Pharmachem Pvt. Ltd. to carry out this Environmental Impact
Assessment Study as per the EIA notification, 2006 as amended till date.
SEPL is accredited as Category-A organization under the QCI-NABET
Scheme for accreditation of EIA consultant Organizations: Version 3 for
preparing EIA-EMP reports in 10 sectors (Certificate No. NABET/EIA/
1619/RA0084; Valid till 15.06.2020).
12.2 DETAILS OF EIA CONSULTANT ORGANIZATION
San Envirotech Pvt. Ltd. has started its work in 1990 to serve the
environment as a trustee of next generation with a small infrastructure
under the dynamic leadership of Dr. Mahendra Sadaria. SEPL has wide
spectrum of national and multinational clients covering the industries -
Bulk Drugs and Pharmaceuticals, Dyes and Dye Intermediates, Pesticides,
Fertilizers, Chemicals, Cement, Mining, and Infrastructure. During last
two decades, SEPL has been taking care of client’s unique problems and
concerns in order to develop cost effective strategies to meet their
regulatory obligations. SEPL focuses on strategic planning and
comprehensive solutions to address both short and long term needs of
the clients.
SEPL has in-house multi-disciplinary analytical testing laboratory that is
MoEFCC approved under EP Act. SEPL is also a recognized schedule-II
Environmental Auditor appointed by Gujarat Pollution Control Board as
per the directives of the Honorable High Court of Gujarat. SEPL is also an
ISO 9001:2008, 14001:2008 and OHSAS 18001 certified company. SEPL
team consists of qualified & experienced personnel. Experts involved in
the preparation of this EIA/EMP report are given in EIA report as
‘declaration by experts’.
Photographs of the proposed site
The project site is located at Survey no. 504, 505, 507, Village: Dabhasa, Ta.:
Padra, District: Vadodara, Gujarat.
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A-8
Product: Acetone Revision Date: 12/03/2012 1/8
Acetone MSDS Effective Date: December 03, 2012 24 Hour Emergency Contact: ChemTel: (800)255-3924 www.pioneerforensics.com
1. PRODUCT AND COMPANY IDENTIFICATION Product: Acetone Product Number(s): PF003 CAS#: 67-64-1 Synonyms: Dimethylketal; 2-Propanone; Dimethyl ketone Manufacturer: Pioneer Forensics, LLC
804 E. Eisenhauer Blvd. Loveland, CO 80537 Ph: (970) 292-8487
Emergency Number: (800) 255-3924 (CHEM-TEL) Customer Service: (970) 292-8487
2. HAZARDS IDENTIFICATION Emergency Overview: DANGER! Extremely flammable liquid and vapor. Vapor may cause flash fire. Easily
ignited by heat, spark or flames. Causes eye irritation. Harmful if swallowed. May enter lungs if swallowed or vomited. Prolonged or repeated skin contact may cause drying, cracking, or irritation. High vapor concentrations may cause drowsiness and irritation of the eyes or respiratory tract.
Safety Ratings: Health: 2, Moderate Reactivity: 0, None
Flammability: 3, Severe Contact: 2, Moderate OSHA Regulatory Status: This product is considered a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200. Potential Acute Health Effects:
Routes of Exposure: Inhalation, ingestion, skin contact, eye contact Inhalation: May cause irritation to the mucous membranes and upper respiratory tract. In high
concentrations, vapors and aerosol mists have a narcotic effect and may cause headache, fatigue, dizziness and nausea.
Ingestion: Irritating. May cause nausea, stomach pain and vomiting. Aspiration (breathing) of vomitus
into lungs must be avoided as even small quantities may result in aspiration pneumonitis. Skin Contact: Prolonged or repeated contact with skin may cause redness, itching, irritation and
eczema/chapping. Eye Contact: Causes irritation. High vapor/aerosol concentrations may cause eye irritation.
A-9
Product: Acetone Revision Date: 12/03/2012 2/8
Target Organs: Skin, respiratory system, eyes, central nervous system Chronic Health Effects: Frequent or prolonged contact may defat and dry the skin, leading to discomfort and
dermatitis. Aggravation of Repeated or prolonged exposure to the substance can produce target organs damage. Medical Conditions: Persons with pre-existing skin disorders or eye problems may be more susceptible to the
effects of the substance. Potential Environmental Not classified as environmentally hazardous, however, this does not exclude the possibility Effects: that large or frequent spills can have harmful or damaging effects on the environment. 3. COMPOSITION AND INFORMATION ON INGREDIENTS Chemical Formula % by Components CAS# Formula Weight Hazardous Weight Acetone 67-64-1 C3H6O 58.08 Yes >99.5
4. FIRST AID MEASURES First Aid Procedures:
Inhalation: Remove to fresh air. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Get medical attention if symptoms persist.
Ingestion: Do not induce vomiting. If vomiting occurs, keep head low so that vomit does not enter
lungs. Never give anything by mouth to an unconscious person. GET MEDICAL ATTENTION IMMEDIATELY.
Skin Contact: Wash affected area with soap and water. Remove contaminated clothing and shoes. Wash
clothing before reuse. Get medical attention if symptoms occur.
Eye Contact: Check for and remove contact lenses. Immediately flush eyes with gentle but large stream of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention.
General Advice: In the case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible). Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.
Notes to Physician: Treat symptomatically. Keep victim under observation.
5. FIRE FIGHTING MEASURES NFPA Ratings: Health: 2 Flammability: 3 Reactivity: 0 Flammable Properties: HIGHLY FLAMMABLE! Vapors may cause a flash fire or ignite explosively. Vapors may
travel considerable distance to a source of ignition and flash back. Heat may cause sealed containers to explode.
Flash Point: -20° C (-4° F) Closed Cup
Auto-ignition Temp: 465° C (869° F)
A-10
Product: Acetone Revision Date: 12/03/2012 3/8
Flammable Limits in Lower Explosion Limit: 2.6% Air (% by volume): Upper Explosion Limit: 12.8%
Suitable Extinguishing Media: Water spray, dry powder, alcohol resistant foam, carbon dioxide Unsuitable Extinguishing Media: Do not use a solid (straight) water stream as it may scatter and spread fire. Hazardous Combustion Carbon monoxide, carbon dioxide Products: Specific Hazards: Can be ignited easily by heat, sparks, or flame and burns vigorously. Above flash point,
vapor-air mixtures are explosive within flammable limits noted above. Sealed containers may explode when heated or involved in fire. Vapor may accumulate in container headspace resulting in flammability hazard. Material is sensitive to static discharge.
Special Protective Equipment As in any fire, wear MSHA/NIOSH approved (or equivalent) self-contained positive pressure For Firefighters: or pressure-demand breathing apparatus and full protective gear. Specific Methods: Use water spray to cool unopened containers. Cool containers exposed to flames with
flooding quantities of water until well after the fire is out. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. Move containers from fire area if you can do so without risk. Some of these materials, if spilled, may evaporate leaving a flammable residue. In the event of fire and/or explosion do not breathe fumes.
6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Ventilate area of leak or spill. Isolate hazard area and keep unnecessary and unprotected
personnel away from the area of the leak or spill. Keep upwind. Keep out of low areas. Wear appropriate personal protective equipment as specified in the Exposure Control and Personal Protection Section 8. Avoid contact with eyes, skin, and clothing. Pay attention to flashback. Take precautionary measures against static discharges.
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid
discharge into drains, water courses or onto the ground. In case of large spill, dike if needed.
Methods for Containment: Remove all sources of ignition. Stop the flow of material, if this is without risk. Prevent
entry into waterways, sewer, basements or confined areas. Dike the spilled material, where this is possible.
Methods for Cleaning Up: Use spark-proof tools and explosion-proof equipment. All equipment used when handling
the product must be grounded. Absorb spill with an inert material (e.g. vermiculite, dry sand, earth, cloth, fleece), and place in a suitable non-combustible container for reclamation or disposal. Do not use combustible materials, such as sawdust. Clean contaminated surface thoroughly. Never return spills in original containers for re-use. Clean up in accordance with all applicable regulations.
7. HANDLING AND STORAGE Handling: Do not handle or open near flame, sources of heat, or sources of ignition. Protect material
from direct sunlight. Wear personal protective equipment (see section 8). Use only in well-ventilated areas. Provide sufficient air exchange and/or exhaust in work rooms. Avoid contact with skin, eyes and clothing. Do not breathe vapors or spray mist. Do not ingest. When using, do not eat, smoke, or drink. Take precautionary measures against static discharge. Keep away from incompatible materials. Handle in accordance with good
A-11
Product: Acetone Revision Date: 12/03/2012 4/8
industrial hygiene and safety practice. Wash thoroughly after handling. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquids). Observe all warnings and precautions listed for the product
Storage: Store in a cool, dry, ventilated area. Store away from flame, sources of ignition, heat, and
incompatible materials. Store in original container. Keep containers tightly closed and upright. Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children. Ground container and transfer equipment to eliminate static electric sparks. Comply with all national, state, and local codes pertaining to the storage, handling, dispensing, and disposal of flammable liquids.
8. EXPOSURE CONTROL AND PERSONAL PROTECTION Exposure Limits: ACGIH: TWA: 500 ppm
STEL: 750 ppm BEL: 50mg/L
OSHA: PEL: 1000 ppm 2400 mg/m3
Engineering Controls: Ensure adequate ventilation. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Explosion proof exhaust ventilation should be used.
Personal Protective Equipment: Eye/Face Protection: Wear safety glasses with side shields or goggles and a face shield.
Skin Protection: Wear appropriate chemical resistant clothing (with long sleeves) and appropriate chemical resistant gloves.
Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended
exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Respirator type: Chemical respirator with organic vapor cartridge. Use a positive-pressure air-supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air-purifying respirators may not provide adequate protection.
General Hygiene Avoid contact with skin, eyes and clothing. When using, do not eat, drink or smoke. Always Considerations: observe good personal hygiene measures, such as washing after handling the material and
before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Provide eyewash station and safety shower.
9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Appearance: Transparent Color: Colorless Odor: Sweet, mint-like Molecular Formula: C3H6O
Molecular Weight: 58.08 pH: No information found Specific Gravity: 0.79 Freezing/Melting Point: -94.7 °C (-139 °F)
A-12
Product: Acetone Revision Date: 12/03/2012 5/8
Boiling Point: 56.1 °C (132.8 °F) Flash Point: -20° C (-4° F) Closed Cup Auto Ignition Temperature: 465° C (869° F) Flammable Limits in Air (% by Volume): Upper: 12.8% Lower: 2.6% Solubility: Miscible with water Vapor Pressure: 30.93 kPa at 25°C Vapor Density: 2 Odor threshold (ppm): 62-140 ppm Evaporation Rate: 5.6 BuAc Partition Coefficient (n-octanol/water): -0.24
10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to Avoid: Heat, flames, sparks, ignition sources, incompatibles Incompatible Materials: Oxidizing agents, acids, alkalis, peroxides Hazardous Decomposition Carbon dioxide and carbon monoxide may form when heated to decomposition. Products: Possibility of Hazardous Can react vigorously, violently or explosively with incompatible materials listed above. Reactions: Hazardous Polymerization: Will not occur. 11. TOXICOLOGICAL INFORMATION Toxicological Data: Oral Rat LD50: 5800 mg/kg Skin Rabbit LD50: 20000 mg/kg Inhalation Rat LC50: 76 mg/L 4H Acute Effects: Harmful if swallowed. May enter lungs if swallowed or vomited. Local Effects: Causes eye irritation. Prolonged or repeated skin contact may cause drying, cracking, or
irritation. High vapor concentrations may cause drowsiness and irritation of the eyes or respiratory tract.
Sensitization: Not a skin sensitizer. Chronic Effects: Frequent or prolonged contact may defat and dry the skin, leading to discomfort and
dermatitis. Carcinogenic Effects: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. ACGIH: A4 – Not classifiable as a human carcinogen Skin Corrosion/Irritation: Defatting, drying, and cracking of the skin. Epidemiology: No epidemiological data is available for this product.
A-13
Product: Acetone Revision Date: 12/03/2012 6/8
Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
Neurological Effects: High vapor/aerosol concentrations (attainable only at elevated temperatures) may cause
central nervous system effects such as dizziness, drowsiness or headaches. Reproductive Effects: Contains no ingredient listed as toxic to reproduction. Teratogenic Effects: No data available to indicate product or any components present at greater than 0.1% may
cause birth defects. Target Organs and Symptoms: Moderate eye and/or upper respiratory tract irritation. Drowsiness and dizziness.
12. ECOLOGICAL INFORMATION Ecotoxicological Data: EC50 Water flea (Daphnia magna): 10294 mg/L 48 H
LC50 Fathead minnow (Pimephales promelas): > 100 mg/L 96 H Ecotoxicity: The product components are not classified as environmentally hazardous, however, this
does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Environmental Effects: Ecological injuries are not known or expected under normal use. Persistence and Degradability: Expected to be readily biodegradable. Partition Coefficient -0.24 (n-octanol/water): 13. DISPOSAL INFORMATION Disposal Instructions: Dispose of this material and its container to hazardous or special waste collection point.
Incinerate the material under controlled conditions in an approved incinerator. All wastes must be handled in accordance with local, state and federal regulations.
Contaminated Packaging: Since emptied containers retain product residue, follow label warnings even after container
is emptied. Residual vapors may explode on ignition; do not cut, drill, grind, or weld on or near this container. Offer rinsed packaging material to local recycling facilities.
Waste Codes: US RCRA Hazardous Waste U List: Acetone: U002
14. TRANSPORT INFORMATION DOT: UN Number: UN1090 Proper Shipping Name: Acetone Hazard Class: 3 Packaging Group: II ERG Number: 127
A-14
Product: Acetone Revision Date: 12/03/2012 7/8
15. REGULATORY INFORMATION U.S. Federal Regulations:
OSHA: This product is considered a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
TSCA Inventory: Acetone
U.S. EPCRA (SARA Title III):
Sections 311/312: Hazard Categories List (Yes/No)____ Section 311 – Hazardous Chemical Yes
Immediate Hazard Yes Delayed Hazard No Fire Hazard Yes Pressure Hazard No Reactivity Hazard No CERCLA: Acetone: 5000 lbs
International Inventories: Country(s) or Region Inventory Name On Inventory (Yes/No)*
Australia Australian Inventory of Chemical Yes Substances (AICS)
Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Yes Substances in China (IECSC)
Europe European Inventory of Existing Commercial Yes Chemical Substances (EINECS)
Europe European List of Notified Chemical No Substances (ELINCS)
Japan Inventory of Existing and New Chemical Yes Substances (ENCS)
Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Yes
Chemical Substances (PICCS) *A "Yes" indicates that the listed component(s) of this product comply with the inventory requirements administered by the governing country(s)
16. OTHER INFORMATION Product Use: Laboratory and/or field reagent Disclaimer: Pioneer Forensics LLC provides the information in this Material Safety Data Sheet in the
belief that it is reliable but assumes no responsibility for its completeness or accuracy. The physical properties reported in this MSDS are obtained from the literature and do not constitute product specifications. Pioneer Forensics LLC makes and gives no representations or warranties with respect to the information contained herein or the product to which it refers, whether express, implied, or statutory, including without limitation, warranties of accuracy, completeness, merchantability, non-infringement, performance, safety, suitability, stability, and fitness for a particular purpose. No warranty against
A-15
Product: Acetone Revision Date: 12/03/2012 8/8
infringement of any patent, copyright or trademark is made or implied. This MSDS is intended only as a guide to the appropriate handling of the material by a properly trained person. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. Accordingly, Pioneer Forensics LLC assumes no liability whatsoever for the use of or reliance upon this information including results obtained, incidental or consequential damages, or lost profits.
Issue Date: 12/03/2012 Reason for Revision: Not applicable
A-16
SAFETY DATA SHEET
Revision Date 18-Jan-2018 Revision Number 3
1. IdentificationProduct Name 3-Nitrobenzoyl chloride
Cat No. : AC155840000; AC155840050; AC155841000; AC155845000
CAS-No 121-90-4
Synonyms m-Nitrobenzoyl chloride.
Recommended Use Laboratory chemicals.
Uses advised against Not for food, drug, pesticide or biocidal product use
Details of the supplier of the safety data sheet
Emergency Telephone Number For information US call: 001-800-ACROS-01 / Europe call: +32 14 57 52 11
Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99
CHEMTREC Tel. No.US:001-800-424-9300 / Europe:001-703-527-3887
2. Hazard(s) identificationClassification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label Elements
Signal WordDanger
Hazard StatementsToxic in contact with skinCauses severe skin burns and eye damageMay cause respiratory irritation
Company Fisher ScientificOne Reagent LaneFair Lawn, NJ 07410Tel: (201) 796-7100
Acros OrganicsOne Reagent LaneFair Lawn, NJ 07410
Acute dermal toxicity Category 3Skin Corrosion/irritation Category 1Serious Eye Damage/Eye Irritation Category 1Specific target organ toxicity (single exposure) Category 3Target Organs - Respiratory system.
______________________________________________________________________________________________
Page 1 / 7
A-17
______________________________________________________________________________________________3-Nitrobenzoyl chloride Revision Date 18-Jan-2018
Precautionary StatementsPreventionWear protective gloves/protective clothing/eye protection/face protectionDo not breathe dust/fume/gas/mist/vapors/sprayWash face, hands and any exposed skin thoroughly after handlingUse only outdoors or in a well-ventilated area
ResponseImmediately call a POISON CENTER or doctor/physician
InhalationIF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
SkinWash contaminated clothing before reuseIF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
EyesIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
IngestionIF SWALLOWED: Rinse mouth. DO NOT induce vomiting
StorageStore locked upStore in a well-ventilated place. Keep container tightly closed
DisposalDispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC) None identified
3. Composition/Information on Ingredients
Component CAS-No Weight %
Benzoyl chloride, 3-nitro- 121-90-4 98
4. First-aid measures
Eye Contact Immediate medical attention is required. Rinse immediately with plenty of water, also underthe eyelids, for at least 15 minutes.
Skin Contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Immediate medical attention is required.
Inhalation Remove from exposure, lie down. Move to fresh air. If breathing is difficult, give oxygen. Ifnot breathing, give artificial respiration. Obtain medical attention.
Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Drinkplenty of water. Call a physician immediately. If possible drink milk afterwards.
Most important symptoms andeffects
Causes burns by all exposure routes. Product is a corrosive material. Use of gastriclavage or emesis is contraindicated. Possible perforation of stomach or esophagus shouldbe investigated: Ingestion causes severe swelling, severe damage to the delicate tissueand danger of perforation
Notes to Physician Treat symptomatically
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A-18
______________________________________________________________________________________________3-Nitrobenzoyl chloride Revision Date 18-Jan-2018
5. Fire-fighting measuresSuitable Extinguishing Media Carbon dioxide (CO 2). Dry chemical. Chemical foam.
Unsuitable Extinguishing Media No information available
Flash Point > 112 °C / > 233.6 °F
Method - No information available
Autoignition Temperature No information available
Explosion LimitsUpper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the ChemicalKeep product and empty container away from heat and sources of ignition.
Hazardous Combustion ProductsHydrogen chloride gas Nitrogen oxides (NOx) Carbon monoxide (CO) Carbon dioxide (CO2) Phosgene
Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fullprotective gear.
NFPA
6. Accidental release measuresPersonal Precautions Ensure adequate ventilation. Use personal protective equipment.
Environmental Precautions See Section 12 for additional ecological information.
Methods for Containment and CleanUp
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder,sawdust). Keep in suitable, closed containers for disposal.
7. Handling and storageHandling Avoid contact with skin and eyes. Do not breathe dust. Do not breathe vapors or spray mist.
Use only in area provided with appropriate exhaust ventilation.
Storage Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Corrosivesarea.
8. Exposure controls / personal protectionExposure Guidelines This product does not contain any hazardous materials with occupational exposure
limitsestablished by the region specific regulatory bodies.
Health3
Flammability1
Instability0
Physical hazardsN/A
Engineering Measures Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment
Eye/face Protection
______________________________________________________________________________________________
Page 3 / 7
Wear appropriate protective eyeglasses or chemical safety goggles as described byOSHA's eye and face protection regulations in 29 CFR 1910.133 or European StandardEN166.
A-19
______________________________________________________________________________________________3-Nitrobenzoyl chloride Revision Date 18-Jan-2018
9. Physical and chemical propertiesPhysical State Solid
Appearance Brown
Odor pungent
Odor Threshold No information available
pH No information available
Melting Point/Range 30 - 35 °C / 86 - 95 °F
Boiling Point/Range 275 - 278 °C / 527 - 532.4 °F @ 760 mmHg
Flash Point > 112 °C / > 233.6 °F
Evaporation Rate No information available
Flammability (solid,gas) No information available
Flammability or explosive limitsUpper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density No information available
Specific Gravity 1.420
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity No information available
Molecular Formula C7 H4 Cl N O3
Molecular Weight 185.57
10. Stability and reactivity
Reactive Hazard None known, based on information available
Stability Stable under normal conditions. Moisture sensitive.
Conditions to Avoid Incompatible products.
Incompatible Materials Water, Strong bases, Alcohols
Hazardous Decomposition Products Hydrogen chloride gas, Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide(CO2), Phosgene
Hazardous Polymerization No information available.
Hazardous Reactions None under normal processing.
11. Toxicological informationAcute Toxicity
Product Information No acute toxicity information is available for this product
Component InformationComponent LD50 Oral LD50 Dermal LC50 Inhalation
Benzoyl chloride, 3-nitro- LD50 = 2460 µL/kg ( Rat ) LD50 = 790 µL/kg ( Rabbit ) Not listed
Toxicologically Synergistic No information available
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airlinerespirator in the positive pressure mode with emergency escape provisions.
Hygiene Measures
______________________________________________________________________________________________
Page 4 / 7
Handle in accordance with good industrial hygiene and safety practice.
A-20
______________________________________________________________________________________________3-Nitrobenzoyl chloride Revision Date 18-Jan-2018
ProductsDelayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component CAS-No IARC NTP ACGIH OSHA Mexico
Benzoyl chloride,3-nitro-
121-90-4 Not listed Not listed Not listed Not listed Not listed
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure Respiratory system
STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute anddelayed
Product is a corrosive material. Use of gastric lavage or emesis is contraindicated.Possible perforation of stomach or esophagus should be investigated: Ingestion causessevere swelling, severe damage to the delicate tissue and danger of perforation
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.
12. Ecological informationEcotoxicity Do not empty into drains.
Persistence and Degradability No information available
Bioaccumulation/ Accumulation No information available.
Mobility No information available.
13. Disposal considerationsWaste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, andnational hazardous waste regulations to ensure complete and accurate classification.
14. Transport informationDOT
UN-No UN3261
Hazard Class 8
Packing Group II
TDG UN-No UN3261
Hazard Class 8
Packing Group II
IATA UN-No 1759
______________________________________________________________________________________________
Page 5 / 7
A-21
______________________________________________________________________________________________3-Nitrobenzoyl chloride Revision Date 18-Jan-2018
Proper Shipping Name CORROSIVE SOLID, N.O.S.*
Hazard Class 8
Packing Group II
IMDG/IMO UN-No 1759
Proper Shipping Name CORROSIVE SOLID, N.O.S.
Hazard Class 8
Packing Group II
15. Regulatory information
International Inventories
Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL
Benzoyl chloride, 3-nitro- X X - 204-505-9 - X X - X -Legend:X - ListedE - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designatedpolymer made with any free-radical initiator regardless of the amount used.P - Indicates a commenced PMN substanceR - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.S - Indicates a substance that is identified in a proposed or final Significant New Use RuleT - Indicates a substance that is the subject of a Section 4 test rule under TSCA.XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data BaseProduction and Site Reports (40 CFR 710(B).Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactantsthat comprises one of the eligibility criteria for the exemption rule.
U.S. Federal Regulations
TSCA 12(b) Not applicable
SARA 313 Not applicable
SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act) Not applicable
Clean Air Act Not applicable
OSHA Occupational Safety and Health AdministrationNot applicable
CERCLA Not applicable
California Proposition 65 This product does not contain any Proposition 65 chemicals
U.S. State Right-to-KnowRegulations
Not applicable
U.S. Department of Transportation
Reportable Quantity (RQ): NDOT Marine Pollutant NDOT Severe Marine Pollutant N
U.S. Department of Homeland SecurityThis product does not contain any DHS chemicals.
Other International Regulations
______________________________________________________________________________________________
Page 6 / 7
A-22
______________________________________________________________________________________________3-Nitrobenzoyl chloride Revision Date 18-Jan-2018
Mexico - Grade No information available
16. Other informationPrepared By Regulatory Affairs
Thermo Fisher ScientificEmail: [email protected]
Revision Date 18-Jan-2018
Print Date 18-Jan-2018
Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standardreplacing the current legislation under 29 CFR 1910.1200 to align with the GloballyHarmonized System of Classification and Labeling of Chemicals (GHS).
DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at thedate of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text
End of SDS
______________________________________________________________________________________________
Page 7 / 7
A-23
Chloroform
Trichloromethane
CX1050
Other non-specified industry: Analytical reagent.
EMD Chemicals Inc.480 S. Democrat Rd.Gibbstown, NJ 08027856-423-6300 Technical ServiceMonday-Friday: 8:00 -5:00 PM
800-424-9300 CHEMTREC (USA)613-996-6666 CANUTEC (Canada)24 Hours/Day: 7 Days/Week
Material Safety Data Sheet
Product name
Supplier
Synonym
Material uses
Product code
Validation date
In case of emergency
Product and company identification
Chloroform
:
:
:
:
:
:
:
1 .
4/2/2009.
Dermal contact. Eye contact. Inhalation. Ingestion.
Emergency overview
Hazards identification
Routes of entry
Potential acute health effects
Toxic by inhalation. Irritating to respiratory system. Exposure to decomposition productsmay cause a health hazard. Serious effects may be delayed following exposure.
Irritating to eyes.
Toxic if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage.Irritating to skin.
Eyes
Skin
Inhalation
Ingestion
Physical state Liquid. [Colorless.]
See toxicological information (section 11)
Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing.Use only with adequate ventilation. Keep container tightly closed and sealed until readyfor use. Wash thoroughly after handling.
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Medical conditionsaggravated by over-exposure
Pre-existing disorders involving any target organs mentioned in this MSDS as being atrisk may be aggravated by over-exposure to this product.
:
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard(29 CFR 1910.1200).
2 .
Potential chronic health effects
Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.No known significant effects or critical hazards.:Mutagenicity
Teratogenicity : No known significant effects or critical hazards.No known significant effects or critical hazards.:Developmental effects
Fertility effects : No known significant effects or critical hazards.May cause damage to the following organs: kidneys, liver, heart, skin, eyes, centralnervous system (CNS).
:Target organs
WARNING: This product contains a chemical known to the State of California to causecancer.
HARMFUL IF INHALED OR SWALLOWED.CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION.SUSPECT CANCER HAZARD - MAY CAUSE CANCER.MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: KIDNEYS, LIVER, HEART,SKIN, EYES, CENTRAL NERVOUS SYSTEM.
WARNING!
Continued on next page A-24
2/8CX1050Chloroform
Composition/information on ingredients
Name CAS number % by weight
3 .
Chloroform 67-66-3 100
Wash out mouth with water. Do not induce vomiting unless directed to do so by medicalpersonnel. Never give anything by mouth to an unconscious person. Get medicalattention immediately.
Check for and remove any contact lenses. Immediately flush eyes with plenty of waterfor at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medicalattention immediately.In case of contact, immediately flush skin with plenty of water for at least 15 minuteswhile removing contaminated clothing and shoes. Wash clothing before reuse. Cleanshoes thoroughly before reuse. Get medical attention immediately.Move exposed person to fresh air. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attentionimmediately.
First aid measuresEye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
4 .
Use an extinguishing agent suitable for the surrounding fire.
Emits very toxic fumes when heated to decomposition.
Fire-fighting measures
Extinguishing media
Special remarks on firehazards
Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining.
In a fire or if heated, a pressure increase will occur and the container may burst.
Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
:
5 .
Special exposure hazards :
None known.:
Hazardous thermaldecomposition products
: Decomposition products may include the following materials:carbon dioxidecarbon monoxidehalogenated compoundscarbonyl halides
Flammability of the product :
Not suitable :
No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Do not breathe vapor or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation isinadequate. Put on appropriate personal protective equipment (see section 8).
Environmental precautions
Accidental release measures
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).
Personal precautions :
6 .
Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Prevent entry into sewers, water courses, basements or confined areas.Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,vermiculite or diatomaceous earth and place in container for disposal according to localregulations (see section 13). Dispose of via a licensed waste disposal contractor.Contaminated absorbent material may pose the same hazard as the spilled product.Note: see section 1 for emergency contact information and section 13 for wastedisposal. Dilute with water and mop up if water-soluble or absorb with an inert drymaterial and place in an appropriate waste disposal container.
Spill :
Methods for cleaning up
Continued on next page A-25
3/8CX1050Chloroform
Store in accordance with local regulations. Store in original container, protected fromdirect sunlight. Keep container tightly closed and sealed until ready for use. Containersthat have been opened must be carefully resealed and kept upright to prevent leakage.
Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest.Use only with adequate ventilation. Wear appropriate respirator when ventilation isinadequate. Keep in the original container or an approved alternative made from acompatible material, kept tightly closed when not in use. Empty containers retainproduct residue and can be hazardous. Do not reuse container.
Handling and storage
Handling
Storage
:
:
7 .
Chloroform ACGIH (United States, 1996). TWA: 49 mg/m³OSHA (United States, 1989). TWA: 9.78 mg/m³ACGIH TLV (United States, 1/2008). TWA: 10 ppm 8 hour(s). TWA: 49 mg/m³ 8 hour(s).OSHA PEL 1989 (United States, 3/1989). TWA: 2 ppm 8 hour(s). TWA: 9.78 mg/m³ 8 hour(s).NIOSH REL (United States, 6/2008). STEL: 2 ppm 60 minute(s). STEL: 9.78 mg/m³ 60 minute(s).OSHA PEL (United States, 11/2006). CEIL: 50 ppm CEIL: 240 mg/m³
Exposure controls/personal protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.
Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts. Recommended: splash gogglesPersonal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.Recommended: lab coat
Personal protection
Eyes
Skin
Respiratory
Consult local authorities for acceptable exposure limits.
:
:
:
Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary. Recommended: Viton
Hands :
8 .
Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.
Environmental exposurecontrols
: Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will benecessary to reduce emissions to acceptable levels.
Ingredient Exposure limits
Continued on next page A-26
4/8CX1050Chloroform
60.5°C (140.9°F)
Liquid. [Colorless.]
100% (v/v)
Not available.
-63°C (-81.4°F)
1.49
4.1 [Air = 1]22.3 kPa (167 mm Hg)
Partially soluble in the following materials: water
205 ppm
263.3°C (505.9°F)
119.37 g/molePleasant. Ethereal.Colorless.
Boiling/condensation point
Melting/freezing point
10.2 (Butyl acetate. = 1)
Physical and chemical properties
Physical state
Molecular weight
pH
Critical temperature
Relative density
Vapor pressure
Vapor density
Volatility
Odor threshold
Evaporation rate
Solubility
Odor
Color
CHCl3Molecular formula
100 (%)VOC
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9 .
The product is stable.
Reactive or incompatible with the following materials: oxidizing materials, metals andalkalis.
Under normal conditions of storage and use, hazardous polymerization will not occur.
Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.
Avoid exposure - obtain special instructions before use. Do not swallow.
Stability and reactivity
Chemical stability
Conditions to avoid
Materials to avoid
Hazardous decompositionproducts
Hazardous polymerization
:
:
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:
10 .
Emits very toxic fumes when heated to decomposition.Conditions of reactivity :
Possibility of hazardousreactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Toxicological information11 .
Acute toxicity
Chloroform LD50Intraperitoneal
Rat 894 mg/kg
LD50 Oral Rat 695 mg/kgLD50 Oral Rat 300 mg/kgLD50 Oral Mouse 36 mg/kgLD50 Dermal Rabbit >20 g/kgLD50 Oral Rat 1250 mg/kgLDLo Oral Man 2514 mg/kgLDLo Oral Rabbit 500 mg/kgTDLo Oral Rat 0.5 mL/kgTDLo Oral Rat 14.9 mg/kgTDLo Oral Rat 119.37 mg/kgTDLoIntraperitoneal
Rat 0.5 mL/kg
TDLoIntraperitoneal
Rat 180 mg/kg
LC50 InhalationVapor
Rat 6000 mg/m3
LC50 Inhalation Rat 47702 mg/m3
Product/ingredient name Test Route Species Result
Continued on next page A-27
5/8CX1050Chloroform
Toxicological information11 .VaporLC50 InhalationVapor
Rat 47702 mg/m³
Carcinogenicity
Mutagenicity
Teratogenicity
Classification
Chloroform A3 2B - + Possible -Product/ingredient name ACGIH EPA NIOSH NTPIARC OSHA
No known significant effects or critical hazards.
No known significant effects or critical hazards.
May cause cancer. Risk of cancer depends on duration and level of exposure.
Ecological information12 .
Aquatic ecotoxicity
Chloroform Acute EC50 950 mg/L Algae 48 hoursAcute EC50 560 mg/L Algae 48 hoursAcute LC50 81.5 to 106mg/L Marine water
Crustaceans - Northern pinkshrimp - Penaeus duorarum- 35 to 50 mm
48 hours
Acute LC50 65.7 mg/LFresh water
Daphnia - Water flea -Daphnia magna
48 hours
Acute LC50 17.1 mg/L Fish 96 hoursAcute LC50 16.2 mg/L Fish 96 hoursAcute LC50 15.1 mg/L Fish 96 hoursAcute LC50 13.3 mg/L Fish 96 hoursAcute LC50 17.1 ppmFresh water
Fish - Rainbowtrout,donaldson trout -Oncorhynchus mykiss
96 hours
Acute LC50 16.2 ppmFresh water
Fish - Bluegill - Lepomismacrochirus
96 hours
Acute LC50 15.1 ppmFresh water
Fish - Rainbowtrout,donaldson trout -Oncorhynchus mykiss
96 hours
Acute LC50 13.3 ppmFresh water
Fish - Bluegill - Lepomismacrochirus
96 hours
Acute LC50 13300 ug/LFresh water
Fish - Bluegill - Lepomismacrochirus - 17.1 cm -126.4 g
96 hours
Acute LC50 758000 to850000 ug/L Fresh water
Daphnia - Water flea -Daphnia magna - Young -<=24 hours
48 hours
Acute LC50 353000 to512000 ug/L Fresh water
Daphnia - Water flea -Daphnia magna - Neonate -<12 hours
48 hours
Acute LC50 290000 to512000 ug/L Fresh water
Daphnia - Water flea -Ceriodaphnia dubia -Neonate - <12 hours
48 hours
Acute LC50 66800 to71900 ug/L Fresh water
Daphnia - Water flea -Daphnia magna - Neonate
48 hours
Acute LC50 66500 to78500 ug/L Fresh water
Daphnia - Water flea -Daphnia magna - Neonate
48 hours
Acute LC50 16200 ug/LFresh water
Fish - Bluegill - Lepomismacrochirus - 16.9 cm -129.9 g
96 hours
Acute LC50 63800 to Daphnia - Water flea - 48 hours
Product/ingredient name SpeciesResult Exposure
Continued on next page A-28
6/8CX1050Chloroform
Ecological information12 .
Environmental effects : No known significant effects or critical hazards.
78000 ug/L Fresh water Daphnia magna - NeonateAcute LC50 15100 to22100 ug/L Fresh water
Fish - Rainbowtrout,donaldson trout -Oncorhynchus mykiss
96 hours
Acute LC50 29000 to47000 ug/L Fresh water
Daphnia - Water flea -Daphnia magna - <24 hours
48 hours
Acute LC50 15100 ug/LFresh water
Fish - Rainbowtrout,donaldson trout -Oncorhynchus mykiss -Juvenile (Fledgling,Hatchling, Weanling) - 11.5cm - 16.8 g
96 hours
Acute LC50 17100 ug/LFresh water
Fish - Rainbowtrout,donaldson trout -Oncorhynchus mykiss -Juvenile (Fledgling,Hatchling, Weanling) - 8.8cm - 7.6 g
96 hours
Acute LC50 13300 to20800 ug/L Fresh water
Fish - Bluegill - Lepomismacrochirus
96 hours
Other adverse effects : No known significant effects or critical hazards.
The information presented only applies to the material as supplied. The identification based on characteristic(s) or listingmay not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator todetermine the toxicity and physical properties of the material generated to determine the proper waste identification anddisposal methods in compliance with applicable regulations. Disposal should be in accordance with applicable regional,national and local laws and regulations.
Disposal considerations13 .
Transport information
6.1
6
POISON
DOT Classification CHLOROFORM III
Regulatoryinformation
UN number Proper shippingname
Classes PG* Label Additionalinformation
UN1888
14 .
PG* : Packing group
Reportable quantity10 lbs. (4.54 kg)
Toxic materialIrritating materialCarcinogenTarget organ effects
HCS Classification
Regulatory information
U.S. Federal regulations United States inventory (TSCA 8b): This material is listed or exempted.TSCA 8(d) H and S data reporting: Chloroform : 1987
Clean Water Act (CWA) 307: ChloroformClean Water Act (CWA) 311: Chloroform
SARA 302/304/311/312 extremely hazardous substances: ChloroformSARA 302/304 emergency planning and notification: ChloroformSARA 302/304/311/312 hazardous chemicals: ChloroformSARA 311/312 MSDS distribution - chemical inventory - hazard identification:Chloroform : Immediate (acute) health hazard, Delayed (chronic) health hazard
:
:
United States
15 .
TSCA (Toxic Substance Control Act): This product is listed on the TSCA Inventory.
Continued on next page A-29
7/8CX1050Chloroform
Regulatory information15 .
WARNING: This product contains a chemical known to the State of California to cause cancer.
Clean Air Act (CAA) 112 accidental release prevention: ChloroformClean Air Act (CAA) 112 regulated flammable substances: No products were found.Clean Air Act (CAA) 112 regulated toxic substances: Chloroform
CEPA Toxic substances: This material is not listed.Canadian ARET: This material is not listed.Canadian NPRI: This material is listed.Alberta Designated Substances: This material is not listed.Ontario Designated Substances: This material is not listed.Quebec Designated Substances: This material is not listed.
WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (Toxic).Class D-2A: Material causing other toxic effects (Very toxic).Class D-2B: Material causing other toxic effects (Toxic).
:
SARA 313
Canada
Product name CAS number Concentration
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shallinclude copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
Chloroform Yes. No. 20 μg/day (ingestion)40 μg/day (inhalation)
No.
Ingredient name Cancer Reproductive No significant risklevel
Maximumacceptable dosagelevel
R40- Limited evidence of a carcinogenic effect.R22- Harmful if swallowed.R48/20/22- Harmful: danger of serious damage to health by prolonged exposure throughinhalation and if swallowed.R38- Irritating to skin.
Risk phrases
EU regulations
:
Hazard symbol or symbols :
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and theMSDS contains all the information required by the Controlled Products Regulations.
Chloroform 67-66-3 100
Chloroform 67-66-3 100
Form R - Reportingrequirements
Supplier notification
:
:
Canadian lists :
California Prop. 65
CEPA DSL / CEPA NDSL : This material is listed or exempted.
DEA List I Chemicals(Precursor Chemicals)
: Not listed
DEA List II Chemicals(Essential Chemicals)
: Not listed
Massachusetts Substances : This material is listed.
New Jersey HazardousSubstances
: This material is listed.
New York AcutelyHazardous Substances
: This material is listed.
Pennsylvania RTKHazardous Substances
: This material is listed.
Continued on next page A-30
8/8CX1050Chloroform
Regulatory information15 .
Australia inventory (AICS): This material is listed or exempted.China inventory (IECSC): This material is listed or exempted.Japan inventory (ENCS): This material is listed or exempted.Japan inventory (ISHL): Not determined.Korea inventory (KECI): This material is listed or exempted.New Zealand Inventory of Chemicals (NZIoC): This material is listed or exempted.Philippines inventory (PICCS): This material is listed or exempted.
International regulations
International lists :
S2- Keep out of the reach of children.S36/37- Wear suitable protective clothing and gloves.
Safety phrases :
Contains stabilizer. (<1% wt/wt)
Other information
Other specialconsiderations
00
2
National Fire ProtectionAssociation (U.S.A.)
Health
Special
Instability
Flammability
Notice to reader
The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable,are offered for information purposes only and as a guide to the appropriate precautionary and emergency handlingof the material by a properly trained person having the necessary technical skills. Users should consider thesedata only as a supplement to other information gathered by them and must make independent determinations ofsuitability and completeness of information from all sources to assure proper use, storage and disposal of thesematerials and the safety and health of employees and customers and the protection of the environment. EMDCHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED,INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATIONHEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
:
:
16 .
A-31
SAFETY DATA SHEET
Creation Date 27-Jan-2010 Revision Date 17-Jan-2018 Revision Number 6
1. IdentificationProduct Name Methylene chloride
Cat No. : D37-1; D37-4; D37-20; D37-200; D37-200LC; D37-500; D37FB-19;D37FB-50; D37FB-115; D37FB-200; D37POP-19; D37POPB-50;D37POPB-200; D37RB-19; D37RB-50; D37RB-115; D37RB-200;D37RS-19; D37RS-28; D37RS-50; D37RS-115; D37RS-200; D37SK-4;D37SK-4LC; D37SS-28; D37SS-50; D37SS-115; D37SS-200;D37SS-1350; D37RS1000ASME; NC1485726; D37RE200ASME;NC1568702
CAS-No 75-09-2
Synonyms Dichloromethane; DCM
Recommended Use Laboratory chemicals.
Uses advised against Food, drug, pesticide or biocidal product use
Details of the supplier of the safety data sheet
Emergency Telephone Number
CHEMTRECÒ, Inside the USA: 800-424-9300
CHEMTRECÒ, Outside the USA: 001-703-527-3887
2. Hazard(s) identificationClassification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label Elements
Company Fisher ScientificOne Reagent LaneFair Lawn, NJ 07410Tel: (201) 796-7100
Skin Corrosion/irritation Category 2Serious Eye Damage/Eye Irritation Category 2Carcinogenicity Category 1BSpecific target organ toxicity (single exposure) Category 3Target Organs - Central nervous system (CNS).Specific target organ toxicity - (repeated exposure) Category 2Target Organs - Liver, Kidney, Blood.
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______________________________________________________________________________________________Methylene chloride Revision Date 17-Jan-2018
Signal WordDanger
Hazard StatementsCauses skin irritationCauses serious eye irritationMay cause drowsiness or dizzinessMay cause cancerMay cause damage to organs through prolonged or repeated exposure
Precautionary StatementsPreventionObtain special instructions before useDo not handle until all safety precautions have been read and understoodUse personal protective equipment as requiredWash face, hands and any exposed skin thoroughly after handlingWear eye/face protectionDo not breathe dust/fume/gas/mist/vapors/sprayUse only outdoors or in a well-ventilated area
ResponseIF exposed or concerned: Get medical attention/advice
InhalationIF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
SkinIF ON SKIN: Wash with plenty of soap and waterIf skin irritation occurs: Get medical advice/attentionTake off contaminated clothing and wash before reuse
EyesIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingIf eye irritation persists: Get medical advice/attention
StorageStore locked upStore in a well-ventilated place. Keep container tightly closed
DisposalDispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
WARNING. Cancer - https://www.p65warnings.ca.gov/.
3. Composition/Information on Ingredients
Component CAS-No Weight %
Methylene chloride 75-09-2 >99.5
4. First-aid measures
General Advice If symptoms persist, call a physician.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Getmedical attention.
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Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists,call a physician.
Inhalation Move to fresh air. If not breathing, give artificial respiration. Get medical attention ifsymptoms occur.
Ingestion Clean mouth with water and drink afterwards plenty of water.
Most important symptoms andeffects
None reasonably foreseeable. Inhalation of high vapor concentrations may causesymptoms like headache, dizziness, tiredness, nausea and vomiting
Notes to Physician Treat symptomatically
5. Fire-fighting measuresSuitable Extinguishing Media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable Extinguishing Media No information available
Flash Point No information available
Method - No information available
Autoignition Temperature 556 °C / 1032.8 °F
Explosion LimitsUpper 23 vol %
Lower 13 vol %
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the ChemicalThermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat andsources of ignition.
Hazardous Combustion ProductsCarbon monoxide (CO) Carbon dioxide (CO2) Hydrogen chloride gas Phosgene
Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fullprotective gear.
NFPA
6. Accidental release measuresPersonal Precautions Use personal protective equipment. Ensure adequate ventilation.
Environmental Precautions Should not be released into the environment.
Methods for Containment and CleanUp
Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.
7. Handling and storageHandling Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Avoid
ingestion and inhalation. Ensure adequate ventilation.
Storage Keep containers tightly closed in a dry, cool and well-ventilated place.
8. Exposure controls / personal protectionExposure Guidelines
Health2
Flammability1
Instability0
Physical hazardsN/A
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______________________________________________________________________________________________Methylene chloride Revision Date 17-Jan-2018
9. Physical and chemical propertiesPhysical State Liquid
Appearance Colorless
Odor sweet
Odor Threshold No information available
pH No information available
Melting Point/Range -97 °C / -142.6 °F
Boiling Point/Range 39 °C / 102.2 °F
Flash Point No information available
Evaporation Rate No information available
Flammability (solid,gas) Not applicable
Flammability or explosive limitsUpper 23 vol %
Lower 13 vol %
Vapor Pressure 350 mbar @ 20°C
Vapor Density 2.93 (Air = 1.0)
Specific Gravity 1.33
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature 556 °C / 1032.8 °F
Decomposition Temperature No information available
Viscosity No information available
Molecular Formula C H2 Cl2
Molecular Weight 84.93
10. Stability and reactivity
Reactive Hazard None known, based on information available
Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA)
Methylene chloride TWA: 50 ppm (Vacated) TWA: 500 ppm(Vacated) STEL: 2000 ppm
(Vacated) Ceiling: 1000 ppmTWA: 25 ppm
STEL: 125 ppm
IDLH: 2300 ppm TWA: 100 ppmTWA: 330 mg/m3
STEL: 500 ppmSTEL: 1740 mg/m3
Legend
ACGIH - American Conference of Governmental Industrial HygienistsOSHA - Occupational Safety and Health AdministrationNIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health
Engineering Measures Use only under a chemical fume hood. Ensure that eyewash stations and safety showersare close to the workstation location.
Personal Protective Equipment
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described byOSHA's eye and face protection regulations in 29 CFR 1910.133 or European StandardEN166.
Skin and body protection Long sleeved clothing.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European StandardEN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator ifexposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
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______________________________________________________________________________________________Methylene chloride Revision Date 17-Jan-2018
Stability Stable under normal conditions.
Conditions to Avoid Incompatible products. Excess heat.
Incompatible Materials Strong oxidizing agents, Strong acids, Amines
Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Hydrogen chloride gas, Phosgene
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.
11. Toxicological informationAcute Toxicity
Product InformationComponent Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
Methylene chloride > 2000 mg/kg ( Rat ) > 2000 mg/kg ( Rat ) 53 mg/L ( Rat ) 6 h76000 mg/m3 ( Rat ) 4 h
Toxicologically SynergisticProducts
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation Irritating to eyes and skin
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component CAS-No IARC NTP ACGIH OSHA Mexico
Methylene chloride 75-09-2 Group 2A ReasonablyAnticipated
A3 X A3
IARC: (International Agency for Research on Cancer) IARC: (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansGroup 2A - Probably Carcinogenic to HumansGroup 2B - Possibly Carcinogenic to Humans
NTP: (National Toxicity Program) NTP: (National Toxicity Program)Known - Known CarcinogenReasonably Anticipated - Reasonably Anticipated to be a HumanCarcinogen
ACGIH: (American Conference of Governmental IndustrialHygienists)
A1 - Known Human CarcinogenA2 - Suspected Human CarcinogenA3 - Animal CarcinogenACGIH: (American Conference of Governmental Industrial Hygienists)
Mexico - Occupational Exposure Limits - Carcinogens Mexico - Occupational Exposure Limits - CarcinogensA1 - Confirmed Human CarcinogenA2 - Suspected Human CarcinogenA3 - Confirmed Animal CarcinogenA4 - Not Classifiable as a Human CarcinogenA5 - Not Suspected as a Human Carcinogen
Mutagenic Effects Mutagenic effects have occured in microorganisms.
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure Central nervous system (CNS)
STOT - repeated exposure Liver Kidney Blood
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______________________________________________________________________________________________Methylene chloride Revision Date 17-Jan-2018
Aspiration hazard No information available
Symptoms / effects,both acute anddelayed
Inhalation of high vapor concentrations may cause symptoms like headache, dizziness,tiredness, nausea and vomiting
Endocrine Disruptor Information No information available
Other Adverse Effects Tumorigenic effects have been reported in experimental animals.
12. Ecological informationEcotoxicity .
Component Freshwater Algae Freshwater Fish Microtox Water Flea
Methylene chloride EC50:>660 mg/L/96h Pimephales promelas:LC50:193 mg/L/96h
EC50: 1 mg/L/24 hEC50: 2.88 mg/L/15 min
EC50: 140 mg/L/48h
Persistence and Degradability Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation No information available.
Mobility Will likely be mobile in the environment due to its volatility.
Component log Pow
Methylene chloride 1.25
13. Disposal considerationsWaste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, andnational hazardous waste regulations to ensure complete and accurate classification.
Component RCRA - U Series Wastes RCRA - P Series Wastes
Methylene chloride - 75-09-2 U080 -
14. Transport informationDOT
UN-No UN1593
Proper Shipping Name DICHLOROMETHANE
Hazard Class 6.1
Packing Group III
TDG UN-No UN1593
Proper Shipping Name DICHLOROMETHANE
Hazard Class 6.1
Packing Group III
IATA UN-No UN1593
Proper Shipping Name Dichloromethane
Hazard Class 6.1
Packing Group III
IMDG/IMO UN-No UN1593
Proper Shipping Name Dichloromethane
Hazard Class 6.1
Packing Group III
15. Regulatory information
All of the components in the product are on the following Inventory lists: X = listed
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______________________________________________________________________________________________Methylene chloride Revision Date 17-Jan-2018
International Inventories
Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL
Methylene chloride X X - 200-838-9 - X X X X XLegend:X - ListedE - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designatedpolymer made with any free-radical initiator regardless of the amount used.P - Indicates a commenced PMN substanceR - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.S - Indicates a substance that is identified in a proposed or final Significant New Use RuleT - Indicates a substance that is the subject of a Section 4 test rule under TSCA.XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data BaseProduction and Site Reports (40 CFR 710(B).Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactantsthat comprises one of the eligibility criteria for the exemption rule.
U.S. Federal Regulations
TSCA 12(b)
SARA 313
Component CAS-No Weight % SARA 313 - ThresholdValues %
Methylene chloride 75-09-2 >99.5 0.1
SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act)
Component CWA - HazardousSubstances
CWA - ReportableQuantities
CWA - Toxic Pollutants CWA - Priority Pollutants
Methylene chloride - - X X
Clean Air Act
Component HAPS Data Class 1 Ozone Depletors Class 2 Ozone Depletors
Methylene chloride X -
OSHA Occupational Safety and Health Administration
Component Specifically Regulated Chemicals Highly Hazardous Chemicals
Methylene chloride 125 ppm STEL12.5 ppm Action Level
25 ppm TWA
-
CERCLA This material, as supplied, contains one or more substances regulated as a hazardoussubstance under the Comprehensive Environmental Response Compensation and LiabilityAct (CERCLA) (40 CFR 302)
Component Hazardous Substances RQs CERCLA EHS RQs
Methylene chloride 1000 lb 1 lb -
California Proposition 65 This product contains the following proposition 65 chemicals
Component CAS-No California Prop. 65 Prop 65 NSRL Category
Methylene chloride 75-09-2 Carcinogen 200 µg/day50 µg/day
Carcinogen
U.S. State Right-to-KnowRegulations
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
Methylene chloride X X X X X
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______________________________________________________________________________________________Methylene chloride Revision Date 17-Jan-2018
U.S. Department of Transportation
Reportable Quantity (RQ): YDOT Marine Pollutant NDOT Severe Marine Pollutant N
U.S. Department of Homeland SecurityThis product does not contain any DHS chemicals.
Other International Regulations
Mexico - Grade No information available
16. Other informationPrepared By Regulatory Affairs
Thermo Fisher ScientificEmail: [email protected]
Creation Date 27-Jan-2010
Revision Date 17-Jan-2018
Print Date 17-Jan-2018
Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standardreplacing the current legislation under 29 CFR 1910.1200 to align with the GloballyHarmonized System of Classification and Labeling of Chemicals (GHS).
DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at thedate of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text
End of SDS
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He a lt h
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P e r s o n a lP r o t e c t io n
2
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0
H
Material Safety Data SheetN,N-Dimethylformamide MSDS
Section 1: Chemical Product and Company Identification
Product Name: N,N-Dimethylformamide
Catalog Codes: SLD4261, SLD3331
CAS#: 68-12-2
RTECS: LQ2100000
TSCA: TSCA 8(b) inventory: N,N-Dimethylformamide
CI#: Not applicable.
Synonym: DMF; Dimethyl Formamide
Chemical Name: N,N-Dimethylformamide
Chemical Formula: HCON(CH3)2
Contact Information:
Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396
US Sales: 1-800-901-7247International Sales: 1-281-441-4400
Order Online: ScienceLab.com
CHEMTREC (24HR Emergency Telephone), call:1-800-424-9300
International CHEMTREC, call: 1-703-527-3887
For non-emergency assistance, call: 1-281-441-4400
Section 2: Composition and Information on Ingredients
Composition:
Name CAS # % by Weight
{N,N-}Dimethylformamide 68-12-2 100
Toxicological Data on Ingredients: N,N-Dimethylformamide: ORAL (LD50): Acute: 2800 mg/kg [Rat]. 2900 mg/kg [Mouse].5000 mg/kg [Rabbit]. DERMAL (LD50): Acute: 4720 mg/kg [Rabbit].
Section 3: Hazards Identification
Potential Acute Health Effects: Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion,of inhalation.
Potential Chronic Health Effects:CARCINOGENIC EFFECTS: 3 (Not classifiable for human.) by IARC. MUTAGENIC EFFECTS: Mutagenic for mammaliansomatic cells. Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Classified POSSIBLE for human.DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE].The substance is toxic to kidneys, liver, central nervous system (CNS). The substance may be toxic to blood, the nervoussystem. Repeated or prolonged exposure to the substance can produce target organs damage.
Section 4: First Aid Measures
Eye Contact:
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Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelidsopen. Cold water may be used. Get medical attention.
Skin Contact:In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminatedclothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medicalattention.
Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medicalattention.
Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention.
Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It maybe hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious orcorrosive. Seek medical attention.
Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: Flammable.
Auto-Ignition Temperature: 445°C (833°F)
Flash Points: CLOSED CUP: 57.778°C (136°F). (Tagliabue.) OPEN CUP: 67°C (152.6°F).
Flammable Limits: LOWER: 2.2% UPPER: 15.2%
Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
Fire Hazards in Presence of Various Substances:Flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available.
Fire Fighting Media and Instructions:Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards:A mixture of triethylaluminum and DMF explodes when heated. DMF + potassium permanganate may explode.
Section 6: Accidental Release Measures
Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill:
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Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confinedareas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDSand with local authorities.
Section 7: Handling and Storage
Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Donot ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wearsuitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids.
Storage:Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed andsealed until ready for use. Avoid all possible sources of ignition (spark or flame).
Section 8: Exposure Controls/Personal Protection
Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.
Exposure Limits:TWA: 10 (ppm) from ACGIH (TLV) [United States] TWA: 30 (mg/m3) from ACGIH (TLV) [United States] Consult localauthorities for acceptable exposure limits.
Section 9: Physical and Chemical Properties
Physical state and appearance: Liquid.
Odor: Amine like. (Slight.)
Taste: Not available.
Molecular Weight: 73.09 g/mole
Color: Colorless to light yellow.
pH (1% soln/water): Not available.
Boiling Point: 153°C (307.4°F)
Melting Point: -61°C (-77.8°F)
Critical Temperature: 374°C (705.2°F)
Specific Gravity: 0.949 (Water = 1)
Vapor Pressure: 0.3 kPa (@ 20°C)
Vapor Density: 2.51 (Air = 1)
Volatility: Not available.
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Odor Threshold: 100 ppm
Water/Oil Dist. Coeff.: The product is more soluble in water; log(oil/water) = -1
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, diethyl ether, acetone.
Solubility:Easily soluble in cold water, hot water. Soluble in diethyl ether, acetone. Miscible organic solvents. Soluble in benzene, andchloroform.
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Heat, ignition sources (sparks, flames), incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents, acids.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:Can react vigorously with oxidizing agents, halogenated hydrocarbons, and inorganic nitrates. Incompatible with carbontetrachloride, alkyl aluminums, sodium tetrahydroborate, nitrates, chromic acid, diisocyanatomethane, triethylaluminum,sodium hydride, lithium azide, metallic sodium, bromine, magnesium nitrate, potassium permanganate, nitric acid, chromiumtrioxide, borohydrides, phosphorus trioxide, diborane, octafluoroisobutyrate, sodium nitrite, perchloryl fluoride, postassiummethyl 4,4'-dinitrobutyrate. Reaction with inorganic acid chlorides, such as phosphorous oxychloride and thionyl chloride, mayform dimethylcarbamoyl, a suspect carcinogen. May release dimethylamine and carbon monoixde if heated above 350 C (662F).
Special Remarks on Corrosivity:Pure dimethylformamide is essentially non-corrosive to metals. However copper, tin and their alloys should be avoided.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 2800 mg/kg [Rat]. Acute dermal toxicity (LD50): 4720 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 94001 hours [Mouse].
Chronic Effects on Humans:CARCINOGENIC EFFECTS: 3 (Not classifiable for human.) by IARC. MUTAGENIC EFFECTS: Mutagenic for mammaliansomatic cells. Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Classified POSSIBLE for human.DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE].Causes damage to the following organs: kidneys, liver, central nervous system (CNS). May cause damage to the followingorgans: blood, the nervous system.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals:Lowest Published Lethal Dose: LCL[Rat] - Route: Inhalation; Dose: 5000 ppm/6H
Special Remarks on Chronic Effects on Humans:May affect genetic material. May cause adverse reproductive effects(paternal and maternal) and birth defects. Embryotoxicand/or foetotoxic in animal. Passes through the placental barrier in animal. May cause cancer although IARC evidence forcancer in humans shows inadequate data.
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Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes skin irritation with itching, burning, redness, swelling, or rash. It may be absorbedthrough the skin in toxic amounts and cause systemic effects similar to that of ingestion. It may facilitate the absorptionof other chemical substances through the skin. If there is significant potential for skin contact, monitoring should be doneto measure the level of DMF metabolites in urine specimans at the end of the shift. It is common practice to limit end-of-shift metabolites at or below 40 ppm expressed as n-monomethylformamide or a single individual or at or below 20 ppmMMF for several workers doing the same job. Eyes: Causes eye irritation (possibly severe) with tearing pain or blurredvision. Inhalation: May cause respiratory tract irritation. Short-term overexposure by inhalation may affect behavior/centralnervous system (convulsions, muscle weakness and other symptoms similar to that of acute ingestion), respiration (dyspnea).Ingestion: It can cause gastrointestinal tract irritation with heartburn, abdominal pain, nausea, vomiting or diarrhea. It may alsoaffect the cardiovascular system (hypertension, tachycardia, ECG abnormalities), blood (elevated white blood cell counts), andliver damage (hepatomegaly, jaundice, altered liver enzymes, fatty liver
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
DOT Classification: CLASS 3: Flammable liquid.
Identification: : N,N-Dimethylformamide UNNA: 2265 PG: III
Special Provisions for Transport: Not available.
Section 15: Other Regulatory Information
Federal and State Regulations:Illinois toxic substances disclosure to employee act: N,N-Dimethylformamide Illinois chemical safety act: N,N-Dimethylformamide New York release reporting list: N,N-Dimethylformamide Rhode Island RTK hazardous substances: N,N-Dimethylformamide Pennsylvania RTK: N,N-Dimethylformamide Minnesota: N,N-Dimethylformamide Massachusetts RTK:N,N-Dimethylformamide Massachusetts spill list: N,N-Dimethylformamide New Jersey: N,N-Dimethylformamide New Jerseyspill list: N,N-Dimethylformamide Louisiana spill reporting: N,N-Dimethylformamide California Director's List of HazardousSubstances: N,N-Dimethylformamide TSCA 8(b) inventory: N,N-Dimethylformamide TSCA 8(d) H and S data reporting: N,N-Dimethylformamide: 12/19/95 SARA 313 toxic chemical notification and release reporting: N,N-Dimethylformamide CERCLA:Hazardous substances.: N,N-Dimethylformamide: 100 lbs. (45.36 kg)
Other Regulations:OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on theEuropean Inventory of Existing Commercial Chemical Substances.
Other Classifications:
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WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-2A: Material causingother toxic effects (VERY TOXIC).
DSCL (EEC):R20/21- Harmful by inhalation and in contact with skin. R36- Irritating to eyes. R61- May cause harm to the unborn child.S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S53- Avoidexposure - obtain special instructions before use.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 2
Reactivity: 0
Personal Protection: h
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 2
Reactivity: 0
Specific hazard:
Protective Equipment:Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Splash goggles.
Section 16: Other Information
References: Not available.
Other Special Considerations: Not available.
Created: 10/09/2005 05:12 PM
Last Updated: 11/01/2010 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assumeno liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.
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SAFETY DATA SHEET
Creation Date 13-October-2009 Revision Date 18-January-2018 Revision Number 5
1. IdentificationProduct Name Ethyl acetate
Cat No. : BP1125-1; BP1125-4
CAS-No 141-78-6
Synonyms Acetic acid ethyl ester
Recommended Use Laboratory chemicals.
Uses advised against Not for food, drug, pesticide or biocidal product use
Details of the supplier of the safety data sheet
Emergency Telephone Number
CHEMTRECÒ, Inside the USA: 800-424-9300
CHEMTRECÒ, Outside the USA: 001-703-527-3887
2. Hazard(s) identificationClassification
WHMIS 2015 Classification Classified as hazardous under the Hazardous Products Regulations (SOR/2015-17)
Label Elements
Signal WordDanger
Hazard StatementsHighly flammable liquid and vaporCauses serious eye irritationMay cause drowsiness and dizzinessProlonged or repeated contact may dry skin and cause irritation or cracking
Company Importer/DistributorFisher Scientific112 Colonnade Road,Ottawa, ON K2E 7L6,CanadaTel: 1-800-234-7437
ManufacturerFisher ScientificOne Reagent LaneFair Lawn, NJ 07410Tel: (201) 796-7100
Serious Eye Damage/Eye Irritation Category 2
Specific target organ toxicity (single exposure) Category 3Target Organs - Central nervous system (CNS).
Health Hazards Not Otherwise Classified Category 1Prolonged or repeated contact may dry skin and cause irritation or cracking
Flammable liquids
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Category 2
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______________________________________________________________________________________________Ethyl acetate Revision Date 18-January-2018
Precautionary StatementsPreventionKeep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smokingKeep container tightly closedGround/bond container and receiving equipmentUse explosion-proof electrical/ventilating/lighting/equipmentUse only non-sparking toolsTake precautionary measures against static dischargesDo not breathe dust/fumes/gas/mist/vapours/sprayWash face, hands and any exposed skin thoroughly after handlingUse only outdoors or in a well-ventilated areaWear protective gloves/protective clothing/eye protection/face protection
ResponseIF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ showerIF INHALED: Remove person to fresh air and keep comfortable for breathingIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingCall a POISON CENTER/ doctor if you feel unwellIn case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish
StorageStore in a well-ventilated place. Keep container tightly closedStore locked up
DisposalDispose of contents/container to an approved waste disposal plant
3. Composition/Information on Ingredients
Component CAS-No Weight %
Ethyl acetate 141-78-6 >95
4. First-aid measures
General Advice If symptoms persist, call a physician.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Getmedical attention.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists,call a physician.
Inhalation Move to fresh air. If not breathing, give artificial respiration. Get medical attention ifsymptoms occur.
Ingestion Clean mouth with water and drink afterwards plenty of water.
Most important symptoms/effects Breathing difficulties. May cause central nervous system depression: Inhalation of highvapor concentrations may cause symptoms like headache, dizziness, tiredness, nauseaand vomiting
Notes to Physician Treat symptomatically
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______________________________________________________________________________________________Ethyl acetate Revision Date 18-January-2018
5. Fire-fighting measuresSuitable Extinguishing Media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable Extinguishing Media Water may be ineffective, Do not use a solid water stream as it may scatter and spread fire
Flash Point -4 °C / 24.8 °F
Method - Closed cup
Autoignition Temperature 427 °C / 800.6 °F
Explosion LimitsUpper 11.5 vol %
Lower 2.0 vol %
Oxidizing Properties Not oxidising
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the ChemicalFlammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.Containers may explode when heated.
Hazardous Combustion ProductsCarbon monoxide (CO) Carbon dioxide (CO2)
Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fullprotective gear.
NFPA
6. Accidental release measuresPersonal Precautions Use personal protective equipment. Ensure adequate ventilation.
Environmental Precautions Should not be released into the environment. See Section 12 for additional ecologicalinformation.
Methods for Containment and CleanUp
Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.
7. Handling and storageHandling Ensure adequate ventilation. Wear personal protective equipment. Do not get in eyes, on
skin, or on clothing. Avoid ingestion and inhalation.
Storage Flammables area. Keep away from heat and sources of ignition. Keep container tightlyclosed in a dry and well-ventilated place.
8. Exposure controls / personal protectionExposure Guidelines
Component Alberta BritishColumbia
Ontario TWAEV Quebec ACGIH TLV OSHA PEL NIOSH IDLH
Ethyl acetate TWA: 400 ppmTWA: 1440
mg/m3
TWA: 150 ppm TWA: 400 ppm TWA: 400 ppmTWA: 1440
mg/m3
TWA: 400 ppm (Vacated) TWA:400 ppm
(Vacated) TWA:1400 mg/m3
TWA: 400 ppm
IDLH: 2000 ppmTWA: 400 ppm
TWA: 1400mg/m3
Health2
Flammability3
Instability0
Physical hazardsN/A
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______________________________________________________________________________________________Ethyl acetate Revision Date 18-January-2018
TWA: 1400mg/m3
Legend
ACGIH - American Conference of Governmental Industrial Hygienists
OSHA - Occupational Safety and Health Administration
NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health
Engineering MeasuresEnsure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting/equipment. Ensure thateyewash stations and safety showers are close to the workstation location.Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process orequipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted tocontrol hazardous materials at source
Personal protective equipment
Eye Protection Goggles
Hand Protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by thesupplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatability,Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific localconditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination.
Respiratory ProtectionNo protective equipment is needed under normal use conditions.
Environmental exposure controlsNo information available.
Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Donot eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use. Wash hands beforebreaks and at the end of workday.
9. Physical and chemical propertiesPhysical State Liquid
Appearance Colorless
Odor sweet
Odor Threshold 50 ppm
pH No information available
Melting Point/Range -83.5 °C / -118.3 °F
Boiling Point/Range 75 - 78 °C / 167 - 172.4 °F
Flash Point -4 °C / 24.8 °F
Method - Closed cup
Evaporation Rate 6.2
Flammability (solid,gas) Not applicable
Flammability or explosive limitsUpper 11.5 vol %
Lower 2.0 vol %
Glove material Breakthrough time Glove thickness Glove comments
Butyl rubberNitrile rubber
> 120 minutes< 200 minutes
0.5 - 0.7 mm
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Permeation rate 8 µg/cm2/minAs tested under EN374-3
Determination of Resistance toPermeation by Chemicals
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______________________________________________________________________________________________Ethyl acetate Revision Date 18-January-2018
Vapor Pressure 103 mbar @ 20°C
Vapor Density 3.04
Specific Gravity 0.902
Solubility Slightly soluble in water
Partition coefficient; n-octanol/water No data available
Autoignition Temperature 427 °C / 800.6 °F
Decomposition Temperature No information available
Viscosity 0.45 cP @ 20 °C
Molecular Formula C4 H8 O2
Molecular Weight 88.11
Surface tension 24 mN/m @ 20°C
10. Stability and reactivity
Reactive Hazard None known, based on information available
Stability Stable under normal conditions.
Conditions to Avoid Incompatible products. Keep away from open flames, hot surfaces and sources of ignition.
Incompatible Materials Strong oxidizing agents, Strong acids, Amines, Peroxides
Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2)
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.
11. Toxicological informationAcute Toxicity
Product InformationComponent Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
Ethyl acetate 10,200 mg/kg ( Rat ) > 20 mL/kg ( Rabbit )> 18000 mg/kg ( Rabbit )
58 mg/l (rat; 8 h)
Toxicologically SynergisticProducts
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation Irritating to eyes
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component CAS-No IARC NTP ACGIH OSHA Mexico
Ethyl acetate 141-78-6 Not listed Not listed Not listed Not listed Not listed
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure Central nervous system (CNS)
STOT - repeated exposure None known
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______________________________________________________________________________________________Ethyl acetate Revision Date 18-January-2018
Aspiration hazard No information available
Symptoms / effects,both acute anddelayed
May cause central nervous system depression: Inhalation of high vapor concentrations maycause symptoms like headache, dizziness, tiredness, nausea and vomiting
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.
12. Ecological informationEcotoxicity Do not empty into drains.
Component Freshwater Algae Freshwater Fish Microtox Water Flea
Ethyl acetate EC50 = 3300 mg/L/48h Fathead minnow: LC50: 230mg/l/ 96h
Gold orfe: LC50: 270mg/L/48h
EC50 = 1180 mg/L 5 minEC50 = 1500 mg/L 15 minEC50 = 5870 mg/L 15 min
EC50 = 7400 mg/L 2 h
EC50 = 717 mg/L/48h
Persistence and Degradability Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation No information available.
Mobility Will likely be mobile in the environment due to its volatility.
Component log Pow
Ethyl acetate 0.6
13. Disposal considerationsWaste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, andnational hazardous waste regulations to ensure complete and accurate classification.
Component RCRA - U Series Wastes RCRA - P Series Wastes
Ethyl acetate - 141-78-6 U112 -
14. Transport informationDOT
UN-No UN1173
Proper Shipping Name ETHYL ACETATE
Hazard Class 3
Packing Group II
TDG UN-No UN1173
Proper Shipping Name ETHYL ACETATE
Hazard Class 3
Packing Group II
IATA UN-No UN1173
Proper Shipping Name ETHYL ACETATE
Hazard Class 3
Packing Group II
IMDG/IMO UN-No UN1173
Proper Shipping Name ETHYL ACETATE
Hazard Class 3
Packing Group II
15. Regulatory information
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______________________________________________________________________________________________Ethyl acetate Revision Date 18-January-2018
All of the components in the product are on the following Inventory lists: X = listed
International Inventories
Component DSL NDSL TSCA EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL
Ethyl acetate X - X 205-500-4 - X X X X X
Canada
SDS in compliance with provisions of information as set out in Canadian Standard - Part 4, Schedule 1 and 2 of the HazardousProducts Regulations (HPR) and meets the requirements of the HPR (Paragraph 13(1)(a) of the Hazardous Products Act (HPA)).
Component Canada - National PollutantRelease Inventory (NPRI)
Canadian EnvironmentalProtection Agency (CEPA)- List of Toxic Substances
Canada's Chemicals ManagementPlan (CEPA)
Ethyl acetate Part 5, Individual Substances
16. Other informationPrepared By Regulatory Affairs
Thermo Fisher ScientificEmail: [email protected]
Creation Date 13-October-2009
Revision Date 18-January-2018
Print Date 18-January-2018
Revision Summary This document has been updated to comply with the requirements of WHMIS 2015 to alignwith the Globally Harmonised System (GHS) for the Classification and Labelling ofChemicals.
DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at thedate of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text
End of SDS
______________________________________________________________________________________________
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MATERIAL SAFETY DATA SHEET
HYDROCHLORIC ACID 33%
SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT IDENTIFIER: HYDROCHLORIC ACID 33% SOLUTION RECOMMENDED USAGE:
Steel pickling and Scale Removal Ore Refining Hydrolyzing Agent Food Processing Activation of Petroleum Wells Catalyst in Organic Process Removal of Heavy metal from Carbon Black and Activated Carbon Leaching alumina from Crystalline Zeolities Manufacturing of Chlorine Dioxide Water Treatment
MANUFACTURER:
PT ASAHIMAS CHEMICAL Ds Gunung Sugih, Jalan Raya Anyer Km-122 Cilegon 42447 Banten - Indonesia Tel: +62 254 601252 Fax: +62 254 602027 Contact Department: CVT Department
EMERGENCY PHONE NUMBER: +62 254 601252 SECTION 2 HAZARDS IDENTIFICATION GHS Classification: Health Environmental Physical Acute Toxicity - Category 3 Eye Corrosion - Category 1A Skin Corrosion - Category 1A Skin Sensitization - Category 1 Mutagenicity - Category 1A Carcinogenicity - Category 1B Reproductive/Developmental - Category 1A Target Organ Toxicity (Repeated) - Category 1
Aquatic Toxicity: Acute 1 Chronic 1
Substance which in contact with water emit flammable gasses - Category 1
GHS Label: Symbols: skull and crossbones, corrosion, health hazard Hazard Statements DANGER! EXTREMELY CORROSIVE Fatal if inhaled.
Precautionary Statements Causes eye and skin burns Keep container tightly closed. Wear protective gloves and eye/face protection.
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MATERIAL SAFETY DATA SHEET
HYDROCHLORIC ACID 33%
Avoid to swallowed. Causes severe skin burns and eye damage. Can cause blindness, permanent scarring and death. Toxic if swallowed and in contact with skin Suspected of damaging the unborn child. Suspected of causing genetic defects. May cause damage to cardiovascular, respiratory, nervous, and gastrointestinal systems and liver and blood through prolonged or repeated exposure. Harmful to aquatic life. Possible sensitizer. Hygroscopic
Store container tightly closed in cool/ well-ventilated place. Wash thoroughly after handling.
SECTION 3 COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name Percent EINECS/ELINCS
7647-01-0 Hydrogen chloride 33 231-595-7 7732-18-5 Water 67 231-791-2
Synonyms: Muriatic acid; Chlorohydric acid; Hydrogen chloride; Spirits of salt Hazard Symbols: C Risk Phrases: 34 SECTION 4 FIRST AID MEASURES INHALATION: Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. SKIN CONTACT: Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. EYE CONTACT: Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). SPEEDY ACTION IS CRITICAL! INGESTION: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. NOTES TO PHYSICIAN: Do NOT use sodium bicarbonate in an attempt to neutralize the acid. ANTIDOTE: Do NOT use oils or ointments in eye. SECTION 5 FIRE FIGHTING MEASURES - GENERAL INFORMATION: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Not flammable, but reacts with most metals to form flammable hydrogen gas. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Containers may explode when heated. - SUITABLE EXTINGUISTING MEDIA: For large fires, use water spray, fog, or alcohol-resistant foam. Substance is non combustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water
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MATERIAL SAFETY DATA SHEET
HYDROCHLORIC ACID 33%
inside containers. Do NOT use straight streams of water. Most foams will react with the material and release corrosive/toxic gases. Cool containers with flooding quantities of water until well after fire is out. For small fires, use carbon dioxide (except for cyanides), dry chemical, dry sand, and alcohol-resistant foam. SECTION 6 ACCIDENTAL RELEASE MEASURES - PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT & EMERGENCY PROCEDURES: Use proper personal protective equipment as indicated in Section 8. - METHODS & MATERIALS FOR CONTAINMENT & CLEANING UP SPILLS / LEAKS: Large spills may be neutralized with dilute alkaline solutions of soda ash, or lime. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors. Cover with dry earth, dry sand, or other non-combustible material followed with plastic sheet to minimize spreading and contact with water. SECTION 7 HANDLING AND STORAGE - PRECAUTIONS FOR SAFE HANDLING: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Contents may develop pressure upon prolonged storage. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes. Use caution when opening. Keep from contact with moist air and steam. - PRECAUTIONS FOR SAFE STORAGE (including any incompatibilities): Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Do not store in metal containers. Store protected from moisture. Do not store near flammable or oxidizing substances (especially nitric acid or chlorates). SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION - CONTROL PARAMETERS: OCCUPATIONAL EXPOSURE LIMIT or BIOLOGICAL LIMIT VALUE: NFPA Rating: (estimated) Health: 3; Flammability: 0; Reactivity: 1 Explosion Limits Value: Lower: Not available. Upper: Not available.
Chemical Name ACGIH NIOSH OSHA - Final PELs Hydrogen chloride C 5 ppm 50 ppm IDLH C 5 ppm; C 7 mg/m3
Water none listed none listed none listed OSHA Vacated PELs: Hydrogen chloride: C 5 ppm; C 7 mg/m3 Water: No OSHA Vacated PELs are listed for this chemical. - APPROPRIATE ENGINEERING CONTROLS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible
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MATERIAL SAFETY DATA SHEET
HYDROCHLORIC ACID 33%
exposure limits. PERSONAL PROTECTIVE EQIPMENT Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear neoprene or polyvinyl chloride gloves to prevent exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE:
PHYSICAL STATE: Clear liquid COLOR: colorless to slight yellow CHANGE IN APPEARANCE: Not available
ODOR: strong, pungent ODOR THRESHOLD: Not available Molecular Formula: HCl Molecular Weight: 36.46 pH: 0.01 FREEZING/MELTING POINT: -74 deg C BOILING POINT: 81.5-110 deg C @ 760 mmHg FLASH POINT: Not applicable. EVAPORATION RATE: > 1.00 (N-butyl acetate) FLAMMABILITY (solid, gas): Not available VAPOR PRESSURE: 5.7 mm Hg @ 0 deg C VAPOR DENSITY: 1.26 SPECIFIC GRAVITY/DENSITY: 1.0-1.2 VISCOSITY: Not available. SOLUBILITY IN WATER: VERY soluble SOLVENT SOLUBILITY:
Soluble: Miscible Insoluble: Not available
PARTITION COEFICIENT n-octanol / water: Not available AUTO IGNITION TEMPERATURE: Not applicable. DECOMPOSITION TEMPERATURE: Not available. SECTION 10 STABILITY AND REACTIVITY - CHEMICAL STABILITY: Stable under normal temperatures and pressures. - CONDITIONS TO AVOID: Mechanical shock, incompatible materials, metals, excess heat, exposure to moist air or water, bases.
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MATERIAL SAFETY DATA SHEET
HYDROCHLORIC ACID 33%
- INCOMPATIBILITIES WITH OTHER MATERIALS: Bases, acetic anhydride, alkali metals, aluminum, amines, copper, copper alloys, fluorine, iron, sodium hydroxide, steel, sulfuric acid, vinyl acetate, zinc, potassium permanganate, cesium acetylene carbide, rubidium acetylene carbide, rubidium carbide, sodium, chlorosulfonic acid, oleum, carbonates, perchloric acid, calcium phosphide, metal oxides, acetates, cesium carbide, beta-propiolactone, ethyleneimine, propylene oxide, lithium silicides, alcohols + hydrogen cyanide, 2-aminoethanol, ammonium hydroxide, calcium carbide, 1,1-difluoroethylene, ethylene diamine, magnesium boride, mercuric sulfate, silver perchlorate + carbon tetrachloride, uranium phosphide. - HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, hydrogen gas. - HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION RTECS#: CAS# 7647-01-0: MW4025000 CAS# 7732-18-5: ZC0110000 LD50/LC50: CAS# 7647-01-0: Inhalation, mouse: LC50 = 1108 ppm/1H; Inhalation, rat: LC50 = 3124 ppm/1H; Oral, rabbit: LD50 = 900 mg/kg;<BR. CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg;<BR. Carcinogenicity: CAS# 7647-01-0: IARC: Group 3 carcinogen CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. Epidemiology: Experimental reproductive effects have been reported. Teratogenicity: Embryo or Fetus: Stunted fetus, Inhalation, rat TCL0=450 mg/m3/1H Specific Developmental Abnormalities: homeostatis, Inhalation, rat TCL0=450 mg/m3/1H (female 1 days pre-mating). Reproductive Effects: No information available. Neurotoxicity: No information available. Mutagenicity: Cytogenetic analysis: Hamster, lung = 30 mmol/L.; Cytogenetic analysis: Hamster, ovary = 8 mmol/L. Target Organs: Teeth, circulatory system. POTENTIAL HEALTH EFFECTS Inhalation: May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Exposure to the mist and vapor may erode exposed teeth. Causes corrosive action on the mucous membranes. Ingestion: May cause circulatory system failure. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract. May be harmful if swallowed. Skin: May be absorbed through the skin in harmful amounts. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Contact with liquid is corrosive and causes severe burns and ulceration. Eye: May cause irreversible eye injury. Vapor or mist may cause irritation and severe burns. Contact with liquid is corrosive to the eyes and causes severe burns. May cause painful sensitization to light. Chronic: Prolonged or repeated skin contact may cause dermatitis. Repeated exposure may cause erosion of teeth. May cause fetal effects. Laboratory experiments have resulted in mutagenic effects. Prolonged exposure may cause conjunctivitis, photosensitization, and possible blindness.
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MATERIAL SAFETY DATA SHEET
HYDROCHLORIC ACID 33%
SECTION 12 ECOLOGICAL INFORMATION ECOTOXICITY: Fish: Bluegill/Sunfish: 3.6 mg/L; 48Hr; Lethal (unspecified) Bluegill/Sunfish: LC50; 96 Hr; pH 3.0-3.5 No data available. ENVIRONMENTAL: Rapidly hydrolyzes when exposed to water. Will exhibit extensive evaporation from soil surfaces. Upon transport through the soil, hydrochloric acid will dissolve some of the soil materials (especially those with carbonate bases) and the acid will neutralize to some degree. PHYSICAL: No information available. SECTION 13 DISPOSAL CONSIDERATIONS
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed.
SECTION 14 TRANSPORT INFORMATION
US DOT IATA RID/ADR IMO Canada TDG
Shipping Name: HYDROCHLORIC ACID HYDROCHLORIC
ACID Hazard Class: 8 8(9.2) UN Number: UN1789 UN1789
Packing Group: II II SECTION 15 REGULATORY INFORMATION US FEDERAL TSCA CAS# 7647-01-0 is listed on the TSCA inventory. CAS# 7732-18-5 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. SARA Section 302 (RQ)
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MATERIAL SAFETY DATA SHEET
HYDROCHLORIC ACID 33%
CAS# 7647-01-0: final RQ = 5000 pounds (2270 kg) Section 302 (TPQ) CAS# 7647-01-0: TPQ = 500 pounds; RQ = 5000 pounds (does not meet toxicity criteria but because of high production volume and recognized toxicity is considered a chemical of concern) SARA Codes CAS # 7647-01-0: acute. Section 313 This material contains Hydrogen chloride (CAS# 7647-01-0, 36 38%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. Clean Air Act: CAS# 7647-01-0 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletory. This material does not contain any Class 2 Ozone depletory. Clean Water Act: CAS# 7647-01-0 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: CAS# 7647-01-0 is considered highly hazardous by OSHA. STATE CAS# 7647-01-0 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts. CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 7647-01-0: 1 CAS# 7732-18-5: No information available. Canada CAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. This product has a WHMIS classification of D2A, E. CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List. CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List. Exposure Limits CAS# 7647-01-0: OEL-AUSTRALIA:TWA 5 ppm (7 mg/m3) OEL-AUSTRIA:TWA 5 ppm (7 mg/m3) OEL-BELGIUM:STEL 5 ppm (7.7 mg/m3) OEL-DENMARK:STEL 5 ppm (7 mg/m3) OEL-FINLAND:STEL 5 ppm (7 mg/m3);Skin OEL-FRANCE:STEL 5 ppm (7.5 mg/m3) OEL-GERMANY:TWA 5 ppm (7 mg/m3) OEL-HUNGARY:STEL 5 mg/m3 OEL-JAPAN:STEL 5 ppm (7.5 mg/m3) OEL-THE NETHERLANDS:TWA 5 ppm (7 mg/m3) OEL-THE PHILIPPINES:TWA 5 ppm (7 mg/m3) OEL-POLAND:TWA 5 mg/m3 OEL-RUSSIA:STEL 5
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MATERIAL SAFETY DATA SHEET
HYDROCHLORIC ACID 33%
ppm (5 mg/m3) OEL-SWEDEN:STEL 5 ppm (8 mg/m3) OEL-SWITZERLAND:TWA 5 ppm (7.5 mg/m3);STEL 10 ppm (15 mg/m3) OEL-THAILAND:TWA 5 ppm (7 mg/m3) OEL-TURKEY:TWA 5 ppm (7 mg/m3) OEL-UNI TED KINGDOM:TWA 5 ppm (7 mg/m3);STEL 5 ppm (7 mg/m3) OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV SECTION 16 OTHER INFORMATION Revise: 4 Date: August 20, 2009 MSDS SUMMARY OF CHANGES Change of ASC LOGO Licensed to: Supplier to make unlimited paper copies for ASC customer only.
The information in this MSDS was believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall PT ASC be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if PT ASC has been advised of the possibility of such damages.
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Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name Hexane
Cat No. BP2615-100; H291-4; H291-20; H291-200; H291-500; H291FB-19; H291FB-50; H291FB-200; H291RB-19; H291RB-50; H291RB-115; H291RB-200; H291RS-19; H291RS-28; H291RS-50; H291RS-115; H291RS-200; H291S-4; H291SS-28; H291SS-50; H291SS-115; H291SS-200; H300-4; H302-1; H302-4; H302-4LC; H302N-119; H302N-119LC; H302N-219; H302POP-19; H302POP-50; H302RS-19; H302RS-28; H302RS-50; H302RS-115; H302RS-200; H302SK-1; H302SK-4; H302SS-19; H302SS-28; H302SS-50; H302SS-115; H302SS-200; H303-1; H303-4; H303-4LC; H303RS-19; H303RS-28; H303RS-50; H303RS-115; H303RS-200; H303SK-4; H303SS-19; H303SS-28; H303SS-50; H303SS-115; H303SS-200; H307-4; H334-1; H334-4; N3-20; N3-200; O3386-20
Synonyms n-Hexane with < 5% various methyl pentanes; Ligroine; Naphtha Solvent (Anhydrous/Certified ACS/Pesticide/HPLC/OPTIMA/GC Resolv/Spectranalyzed/Technical/Laboratory)
Recommended Use Laboratory chemicals
2. HAZARDS IDENTIFICATION
Target Organs Skin, Respiratory system, Eyes, Central nervous system (CNS), Heart, Blood, Liver,
Reproductive System
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Emergency Telephone NumberCHEMTREC®, Inside the USA: 800-424-9300CHEMTREC®, Outside the USA: 703-527-3887
DANGER!
Revision Number 1
Emergency Overview
Creation Date 26-Oct-2009 Revision Date 26-Oct-2009
Extremely flammable liquid and vapor. Inhalation may cause central nervous system effects. Irritating to eyes and skin. May cause irritation of respiratory tract. Aspiration hazard if swallowed - can enter lungs and cause damage. Danger of
serious damage to health by prolonged exposure. Possible risk of impaired fertility. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
CompanyFisher ScientificOne Reagent LaneFair Lawn, NJ 07410Tel: (201) 796-7100
Appearance Colorless Physical State Liquid odor Petroleum distillates
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Potential Health Effects
Acute Effects Principle Routes of Exposure
Eyes Irritating to eyes.
Skin Irritating to skin. May be harmful in contact with skin.
Inhalation Inhalation may cause central nervous system effects. May cause irritation of respiratory tract. May be harmful if inhaled.
Ingestion Aspiration hazard. May be harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Chronic Effects Tumorigenic effects have been reported in experimental animals.. Experiments have shown reproductive toxicity effects on laboratory animals. Possible risk of impaired fertility. Danger of serious damage to health by prolonged exposure. May cause adverse liver effects.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system disorders. Preexisting eye disorders. Skin disorders.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Haz/Non-haz
Component CAS-No Weight %
Hexane 110-54-3 >95
4. FIRST AID MEASURES
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain
medical attention.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention.
Inhalation Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with a respiratory medical device. Obtain medical attention.
Ingestion Do not induce vomiting. Call a physician or Poison Control Center immediately.
Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Flash Point -22°C / -7.6°F
Method No information available.
Autoignition Temperature 223°C / 433.4°F
Explosion Limits Upper 7.5 vol %
Lower 1.1 vol %
Suitable Extinguishing Media CO2, dry chemical, dry sand, alcohol-resistant foam. Cool closed containers exposed to fire with water spray.
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Revision Date 26-Oct-2009Thermo Fisher Scientific - Hexane
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Unsuitable Extinguishing Media Water may be ineffective. This material is lighter than water and insoluble in water. The fire could easily be spread by the use of water in an area where the water cannot be contained..
Hazardous Combustion Products No information available.
Sensitivity to mechanical impact No information available.
Sensitivity to static discharge No information available.
Specific Hazards Arising from the ChemicalFlammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated.
Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Use personal protective equipment. Remove all sources of ignition. Take precautionary
measures against static discharges.
Environmental Precautions Should not be released into the environment.
Methods for Containment and Clean Up
Soak up with inert absorbent material. Keep in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.
7. HANDLING AND STORAGE
Handling Use only under a chemical fume hood. Wear personal protective equipment. Do not get in
eyes, on skin, or on clothing. Do not breathe vapors or spray mist. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. Use explosion-proof equipment. Take precautionary measures against static discharges.
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition. Flammables area.
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Instability 0 Physical hazards N/A NFPA
Thermo Fisher Scientific - Hexane
Health 1 Flammability 3
Revision Date 26-Oct-2009
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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Measures Use only under a chemical fume hood. Use explosion-proof
electrical/ventilating/lighting/equipment. Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location.
Exposure Guidelines
Component ACGIH TLV OSHA PEL NIOSH IDLH
Hexane TWA: 50 ppm Skin
(Vacated) TWA: 180 mg/m3 (Vacated) TWA: 50 ppm
TWA: 500 ppm TWA: 1800 mg/m3
IDLH: 1100 ppm TWA: 180 mg/m3
TWA: 50 ppm
Component Quebec Mexico OEL (TWA) Ontario TWAEV
Hexane TWA: 176 mg/m3 TWA: 50 ppm
Skin
TWA: 176 mg/m3 TWA: 50 ppm
TWA: 176 mg/m3 TWA: 50 ppm
NIOSH IDLH: Immediately Dangerous to Life or Health
Personal Protective Equipment Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's
eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State Liquid
Appearance Colorless
odor Petroleum distillates
Odor Threshold No information available.
pH No information available. Vapor Pressure 160 mbar @ 20 °C
Vapor Density 2.97 (Air = 1.0)
Viscosity 0.31 mPa s at 20 °C
Boiling Point/Range 69°C / 156.2°F@ 760 mmHg
Melting Point/Range -95°C / -139°F
Decomposition temperature No information available.
Flash Point -22°C / -7.6°F
Evaporation Rate No information available.
Specific Gravity 0.659
Solubility Insoluble in water
log Pow No data available
Molecular Weight 86.18
Molecular Formula C6 H14
10. STABILITY AND REACTIVITY
Stability Stable under normal conditions.
Conditions to Avoid Incompatible products. Heat, flames and sparks. Exposure to light.
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Thermo Fisher Scientific - Hexane Revision Date 26-Oct-2009
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Incompatible Materials Strong oxidizing agents, Halogens
Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2)
Hazardous Polymerization Hazardous polymerization does not occur
Hazardous Reactions . None under normal processing.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
Hexane 25 g/kg ( Rat ) 3000 mg/kg ( Rabbit ) 48000 ppm ( Rat ) 4 h
Irritation Irritating to eyes and skin
Toxicologically Synergistic Products
No information available.
Chronic Toxicity
Carcinogenicity There are no known carcinogenic chemicals in this product
Sensitization No information available.
Mutagenic Effects Mutagenic effects have occurred in experimental animals.
Reproductive Effects Experiments have shown reproductive toxicity effects on laboratory animals.
Developmental Effects Developmental effects have occurred in experimental animals.
Teratogenicity Teratogenic effects have occurred in experimental animals..
Other Adverse Effects Tumorigenic effects have been reported in experimental animals.. See actual entry in RTECS for complete information.
Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Component Freshwater Algae Freshwater Fish Microtox Water Flea
Hexane Not listed Not listed Not listed EC50: 3.87 mg/L/48h
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Persistence and Degradability No information available
Bioaccumulation/ Accumulation No information available
Mobility .
Component log Pow
Hexane 4.11
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.
14. TRANSPORT INFORMATION
DOT
UN-No UN1208
Proper Shipping Name Hexanes
Hazard Class 3
Packing Group II
TDG
UN-No UN1208
Proper Shipping Name HEXANES
Hazard Class 3
Packing Group II
IATA
UN-No UN1208
Proper Shipping Name Hexanes
Hazard Class 3
Packing Group II
IMDG/IMO
UN-No UN1208
Proper Shipping Name Hexanes
Hazard Class 3
Packing Group II
15. REGULATORY INFORMATION
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Thermo Fisher Scientific - Hexane Revision Date 26-Oct-2009
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15. REGULATORY INFORMATIONInternational Inventories
Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS CHINA KECL
Hexane X X - 203-777-6
- X X X X KE-18626
X
Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule.
U.S. Federal Regulations
TSCA 12(b) Not applicable
SARA 313
Component CAS-No Weight % SARA 313 - Threshold
Values %
Hexane 110-54-3 >95 1.0
SARA 311/312 Hazardous Categorization Acute Health Hazard No
Chronic Health Hazard No
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
Clean Water Act Not applicable
Clean Air Act
Component HAPS Data Class 1 Ozone Depletors Class 2 Ozone Depletors Hexane X -
OSHA Not applicable
CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Component Hazardous Substances RQs CERCLA EHS RQs
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Component Hazardous Substances RQs CERCLA EHS RQs
Hexane 5000 lb -
California Proposition 65 This product does not contain any Proposition 65 chemicals.
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
Hexane X X X X X
U.S. Department of Transportation Reportable Quantity (RQ): YDOT Marine Pollutant NDOT Severe Marine Pollutant N
U.S. Department of Homeland Security This product does not contain any DHS chemicals.
Other International Regulations
Mexico - Grade Serious risk, Grade 3
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
WHMIS Hazard ClassB2 Flammable liquidD2A Very toxic materials D2B Toxic materials
16. OTHER INFORMATION
Prepared By Regulatory Affairs
Thermo Fisher ScientificTel: (412) 490-8929
Creation Date 26-Oct-2009
Print Date 26-Oct-2009
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Thermo Fisher Scientific - Hexane Revision Date 26-Oct-2009
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Revision Summary "***", and red text indicates revision
Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
End of MSDS
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Isopropyl Alcohol (2-Propanol) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 11/14/2013 Revision date: 01/26/2018 Supersedes: 09/29/2015 Version: 1.2
01/26/2018 EN (English US) Page 1
SECTION 1: Identification
1.1. Identification Product form : Substance Substance name : Isopropyl Alcohol (2-Propanol) CAS-No. : 67-63-0 Product code : LC15750 Formula : C3H8O Synonyms : 1-methylethanol / 1-methylethyl alcohol / 2-hydroxypropane / dimethyl carbinol / ethyl carbinol /
hydroxypropane / IPA / i-propanol / isoethylcarbinol / propan-2-ol / sec-propanol
1.2. Recommended use and restrictions on use Use of the substance/mixture : Disinfectant
Solvent
1.3. Supplier LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 [email protected] - www.labchem.com
1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification Flammable liquids Category 2
H225 Highly flammable liquid and vapour
Serious eye damage/eye irritation Category 2A
H319 Causes serious eye irritation
Specific target organ toxicity (single exposure) Category 3
H335 May cause respiratory irritation
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) :
GHS02
GHS07
Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapour
H319 - Causes serious eye irritation H335 - May cause respiratory irritation
Precautionary statements (GHS-US) : P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical, lighting, ventilating equipment P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P261 - Avoid breathing mist, vapors, spray. P264 - Wash exposed skin thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear eye protection, face protection, protective clothing, protective gloves. P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
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Isopropyl Alcohol (2-Propanol) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/26/2018 EN (English US) 2/9
lenses, if present and easy to do. Continue rinsing P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P337+P313 - If eye irritation persists: Get medical advice/attention. P370+P378 - In case of fire: Use dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2) to extinguish P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container to comply with local, state and federal regulations P235 - Keep cool. If inhaled: Remove person to fresh air and keep comfortable for breathing
2.3. Other hazards which do not result in classification Other hazards not contributing to the classification
: None.
2.4. Unknown acute toxicity (GHS US) Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances Substance type : Mono-constituent
Name Product identifier % GHS-US classification Isopropyl Alcohol (2-Propanol) (Main constituent)
(CAS-No.) 67-63-0 100 Flam. Liq. 2, H225 Eye Irrit. 2A, H319 STOT SE 3, H335
Full text of hazard classes and H-statements : see section 16
3.2. Mixtures Not applicable
SECTION 4: First-aid measures
4.1. Description of first aid measures First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory
arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with labored breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. Never give alcohol to drink.
First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. First-aid measures after skin contact : Rinse with water. Soap may be used. Do not apply (chemical) neutralizing agents. Take victim
to a doctor if irritation persists. First-aid measures after eye contact : Rinse immediately with plenty of water. Do not apply neutralizing agents. Take victim to an
ophthalmologist if irritation persists. First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce
vomiting. Give activated charcoal. Call Poison Information Centre (www.big.be/antigif.htm). Consult a doctor/medical service if you feel unwell. Ingestion of large quantities: immediately to hospital. Doctor: gastric lavage.
4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Coughing. Dry/sore throat. Central nervous
system depression. Dizziness. Headache. Narcosis. Symptoms/effects after skin contact : Dry skin. Symptoms/effects after eye contact : Irritation of the eye tissue. Symptoms/effects after ingestion : AFTER ABSORPTION OF LARGE QUANTITIES: Central nervous system depression.
Headache. Dilation of the blood vessels. Low arterial pressure. Nausea. Vomiting. Abdominal pain. Disturbed motor response. Disturbances of consciousness. FOLLOWING SYMPTOMS MAY APPEAR LATER: Body temperature fall. Slowing respiration.
Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin. Dry skin. Itching. Cracking of the skin. Skin rash/inflammation. Impaired memory.
4.3. Immediate medical attention and special treatment, if necessary No additional information available
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SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Water spray. Polyvalent foam. Alcohol-resistant foam. BC powder. Carbon dioxide. Unsuitable extinguishing media : Solid water jet ineffective as extinguishing medium.
5.2. Specific hazards arising from the chemical Fire hazard : DIRECT FIRE HAZARD. Highly flammable. Gas/vapor flammable with air within explosion
limits. INDIRECT FIRE HAZARD. May be ignited by sparks. Gas/vapor spreads at floor level: ignition hazard.
Explosion hazard : DIRECT EXPLOSION HAZARD. Gas/vapour explosive with air within explosion limits. INDIRECT EXPLOSION HAZARD. may be ignited by sparks. Reactions with explosion hazards: see "Reactivity Hazard".
Reactivity : Upon combustion: CO and CO2 are formed. Violent to explosive reaction with (strong) oxidizers. Prolonged storage/in large quantities: may form peroxides.
5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to
heat. Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective goggles. Protective clothing. Large spills/in enclosed spaces: compressed
air apparatus. See "Material-Handling" to select protective clothing. Emergency procedures : Keep upwind. Mark the danger area. Consider evacuation. Seal off low-lying areas. Close
doors and windows of adjacent premises. Stop engines and no smoking. No naked flames or sparks. Spark- and explosion-proof appliances and lighting equipment. Keep containers closed. Wash contaminated clothes.
6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Do not breathe gas, fumes, vapor or spray. Emergency procedures : Stop leak if safe to do so. Ventilate area. If a major spill occurs, all personnel should be
immediately evacuated and the area ventilated.
6.2. Environmental precautions Prevent spreading in sewers.
6.3. Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Consult "Material-handling" to
select material of containers. Plug the leak, cut off the supply. Dam up the liquid spill. Try to reduce evaporation. Measure the concentration of the explosive gas-air mixture. Dilute/disperse combustible gas/vapour with water curtain. Provide equipment/receptacles with earthing. Do not use compressed air for pumping over spills.
Methods for cleaning up : Take up liquid spill into absorbent material, e.g.: dry sand/earth/vermiculite or powdered limestone. Scoop absorbed substance into closing containers. See "Material-handling" for suitable container materials. Damaged/cooled tanks must be emptied. Do not use compressed air for pumping over spills. Carefully collect the spill/leftovers. Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.
6.4. Reference to other sections No additional information available
SECTION 7: Handling and storage
7.1. Precautions for safe handling Precautions for safe handling : Comply with the legal requirements. Remove contaminated clothing immediately. Clean
contaminated clothing. Handle uncleaned empty containers as full ones. Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Do not use compressed air for pumping over. Use spark-/explosionproof appliances and lighting system. Take precautions against electrostatic charges. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Observe normal hygiene standards. Keep container tightly closed. Measure the concentration in the air regularly. Work under local exhaust/ventilation.
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Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities Incompatible products : Ammonia. Strong acids. Strong oxidizers. Incompatible materials : Direct sunlight. Heat sources. Sources of ignition. Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources. ignition sources. Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. strong acids. (strong) bases. amines.
halogens. Storage area : Store in a cool area. Store in a dry area. Ventilation at floor level. Fireproof storeroom. Provide
for an automatic sprinkler system. Provide for a tub to collect spills. Provide the tank with earthing. May be stored under nitrogen. Meet the legal requirements.
Special rules on packaging : SPECIAL REQUIREMENTS: closing. with pressure relief valve. dry. clean. correctly labelled. meet the legal requirements. Secure fragile packagings in solid containers.
Packaging materials : SUITABLE MATERIAL: stainless steel. monel steel. carbon steel. copper. nickel. bronze. glass. Teflon. polyethylene. polypropylene. zinc. MATERIAL TO AVOID: steel with rubber inner lining. aluminium.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters Isopropyl Alcohol (2-Propanol) (67-63-0) ACGIH ACGIH TWA (ppm) 200 ppm (2-propanol; USA; Time-weighted average
exposure limit 8 h; TLV - Adopted Value) ACGIH ACGIH STEL (ppm) 400 ppm (2-propanol; USA; Short time value; TLV -
Adopted Value) OSHA OSHA PEL (TWA) (mg/m³) 980 mg/m³
OSHA OSHA PEL (TWA) (ppm) 400 ppm
IDLH US IDLH (ppm) 2000 ppm
NIOSH NIOSH REL (TWA) (mg/m³) 980 mg/m³
NIOSH NIOSH REL (TWA) (ppm) 400 ppm
NIOSH NIOSH REL (STEL) (mg/m³) 1225 mg/m³
NIOSH NIOSH REL (STEL) (ppm) 500 ppm
8.2. Appropriate engineering controls Appropriate engineering controls : Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure. Provide adequate general and local exhaust ventilation.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Safety glasses. Gloves. Protective clothing. Face shield. High gas/vapor concentration: gas mask with filter type A.
Materials for protective clothing:
GIVE EXCELLENT RESISTANCE: butyl rubber. nitrile rubber. viton. polyethylene/ethylenevinylalcohol. GIVE GOOD RESISTANCE: neoprene. GIVE LESS RESISTANCE: PVC. neoprene/natural rubber. GIVE POOR RESISTANCE: natural rubber. polyethylene. PVA
Hand protection:
Gloves
Eye protection:
Safety glasses
Skin and body protection:
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Protective clothing
Respiratory protection:
Wear gas mask with filter type A if conc. in air > exposure limit
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state : Liquid
Appearance : Liquid. Color : Colourless
Odor : Alcohol odour Stuffy odour Mild odour
Odor threshold : 3 - 610 ppm 8 - 1499 mg/m³
pH : No data available
Melting point : -88 °C
Freezing point : No data available
Boiling point : 82 °C (1013 hPa)
Critical temperature : 235 °C Critical pressure : 47600 hPa Flash point : 12 °C
Relative evaporation rate (butyl acetate=1) : 2.3
Relative evaporation rate (ether=1) : 21 Flammability (solid, gas) : No data available
Vapor pressure : 44 hPa (20 °C)
Vapor pressure at 50 °C : 60.2 hPa (25 °C) Relative vapor density at 20 °C : 2.1
Relative density : 0.79
Relative density of saturated gas/air mixture : 1.05 Specific gravity / density : 785 kg/m³ Molecular mass : 60.1 g/mol Solubility : Soluble in water. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in oils/fats.
Soluble in chloroform. Water: Complete Ethanol: Complete Ether: Complete Acetone: soluble
Log Pow : 0.05 (Weight of evidence approach; Other; 25 °C)
Auto-ignition temperature : 399 °C
Decomposition temperature : No data available
Viscosity, kinematic : 2.5316 mm²/s (25 °C)
Viscosity, dynamic : 0.002 Pa.s (25 °C)
Explosion limits : 2 - 13 vol % 50 - 335 g/m³
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information Minimum ignition energy : 0.65 mJ Specific conductivity : 5.8 µS/m Saturation concentration : 106 g/m³ VOC content : 100 % Other properties : Gas/vapour heavier than air at 20°C. Clear. Volatile.
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SECTION 10: Stability and reactivity
10.1. Reactivity Upon combustion: CO and CO2 are formed. Violent to explosive reaction with (strong) oxidizers. Prolonged storage/in large quantities: may form peroxides.
10.2. Chemical stability Stable under normal conditions.
10.3. Possibility of hazardous reactions May react violently with oxidants.
10.4. Conditions to avoid Direct sunlight. High temperature. Incompatible materials. Open flame. Sparks.
10.5. Incompatible materials Ammonia. Strong acids. Strong oxidizers.
10.6. Hazardous decomposition products Carbon dioxide. Carbon monoxide.
SECTION 11: Toxicological information
11.1. Information on toxicological effects Likely routes of exposure : Inhalation; Skin and eye contact
Acute toxicity : Not classified
Isopropyl Alcohol (2-Propanol) (67-63-0) LD50 dermal rabbit 12870 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; 16.4; Rabbit) LC50 inhalation rat (mg/l) 73 mg/l/4h (Rat) ATE US (oral) 5045 mg/kg body weight ATE US (dermal) 12870 mg/kg body weight ATE US (vapors) 73 mg/l/4h ATE US (dust, mist) 73 mg/l/4h
Skin corrosion/irritation : Not classified Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified
Isopropyl Alcohol (2-Propanol) (67-63-0) IARC group 3 - Not classifiable
Reproductive toxicity : Not classified Specific target organ toxicity – single exposure : May cause respiratory irritation.
Specific target organ toxicity – repeated exposure
: Not classified
Aspiration hazard : Not classified
Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Coughing. Dry/sore throat. Central nervous system depression. Dizziness. Headache. Narcosis.
Symptoms/effects after skin contact : Dry skin. Symptoms/effects after eye contact : Irritation of the eye tissue. Symptoms/effects after ingestion : AFTER ABSORPTION OF LARGE QUANTITIES: Central nervous system depression.
Headache. Dilation of the blood vessels. Low arterial pressure. Nausea. Vomiting. Abdominal pain. Disturbed motor response. Disturbances of consciousness. FOLLOWING SYMPTOMS MAY APPEAR LATER: Body temperature fall. Slowing respiration.
Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin. Dry skin. Itching. Cracking of the skin. Skin rash/inflammation. Impaired memory.
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SECTION 12: Ecological information
12.1. Toxicity Ecology - general : Not classified as dangerous for the environment according to the criteria of Directive
67/548/EEC. Not classified as dangerous for the environment according to the criteria of Regulation (EC) No 1272/2008.
Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). Not included in the list of substances which may contribute to the greenhouse effect (Regulation (EC) No 842/2006). TA-Luft Klasse 5.2.5.
Ecology - water : Ground water pollutant. Not harmful to fishes (LC50(96h) >1000 mg/l). Not harmful to invertebrates (Daphnia). Not harmful to algae (EC50 (72h) >1000 mg/l). Inhibition of activated sludge.
Isopropyl Alcohol (2-Propanol) (67-63-0) LC50 fish 2 9640 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Flow-
through system; Fresh water; Experimental value) EC50 Daphnia 2 13299 mg/l (EC50; Other; 48 h; Daphnia magna) Threshold limit algae 1 > 1000 mg/l (EC50; UBA; 72 h; Scenedesmus subspicatus)
12.2. Persistence and degradability Isopropyl Alcohol (2-Propanol) (67-63-0) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No test data on mobility of the substance available. Biochemical oxygen demand (BOD) 1.19 g O₂/g substance Chemical oxygen demand (COD) 2.23 g O₂/g substance ThOD 2.4 g O₂/g substance
12.3. Bioaccumulative potential Isopropyl Alcohol (2-Propanol) (67-63-0) Log Pow 0.05 (Weight of evidence approach; Other; 25 °C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
12.4. Mobility in soil Isopropyl Alcohol (2-Propanol) (67-63-0) Surface tension 0.021 N/m (25 °C)
12.5. Other adverse effects No additional information available
SECTION 13: Disposal considerations
13.1. Disposal methods Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not
be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Recycle by distillation. Remove to an authorized waste incinerator for solvents with energy recovery. Do not discharge into surface water. Obtain the consent of pollution control authorities before discharging to wastewater treatment plants.
Additional information : LWCA (the Netherlands): KGA category 03. Hazardous waste according to Directive 2008/98/EC.
SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : UN1219 Isopropyl alcohol, 3, II
UN-No.(DOT) : UN1219 Proper Shipping Name (DOT) : Isopropyl alcohol Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
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Packing group (DOT) : II - Medium Danger Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 202 DOT Packaging Bulk (49 CFR 173.xxx) : 242 DOT Special Provisions (49 CFR 172.102) : IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling.
DOT Packaging Exceptions (49 CFR 173.xxx) : 4b;150 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.
Other information : No supplementary information available.
SECTION 15: Regulatory information
15.1. US Federal regulations Isopropyl Alcohol (2-Propanol) (67-63-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 SARA Section 311/312 Hazard Classes Physical hazard - Flammable (gases, aerosols, liquids, or solids)
Health hazard - Serious eye damage or eye irritation Health hazard - Specific target organ toxicity (single or repeated exposure)
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory
Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. Isopropyl Alcohol (2-Propanol) CAS-No. 67-63-0 100%
15.2. International regulations CANADA No additional information available
EU-Regulations No additional information available
National regulations No additional information available
15.3. US State regulations
California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm
SECTION 16: Other information
Revision date : 01/26/2018
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Full text of H-phrases: see section 16: ------
H225 Highly flammable liquid and vapour
------
H319 Causes serious eye irritation
------
H335 May cause respiratory irritation
NFPA health hazard : 1 - Materials that, under emergency conditions, can cause significant irritation.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions.
NFPA reactivity : 0 - Material that in themselves are normally stable, even under fire conditions.
Hazard Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above 100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives.
Personal protection : H H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US LabChem Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application.
A-78
Product: Methyl Alcohol Revision Date: 02/27/2015 1/8
Product Identifier: Methyl Alcohol
Product Code(s): NC-6832, NC-3495, M1008, M1025, M1027, M1036
Synonyms: Methanol; Carbinol; Wood Alcohol
Recommended Use: For manufacturing, industrial, and laboratory use only. For use as a solvent or as a cleaning agent.
Uses Advised Against: Not for food, drug, or household use.
Supplier: The Science Company
7625 W Hampden Ave #14, Lakewood, CO 80227 Phone: (303) 777-3777 Fax: (303) 777-3331
Emergency Phone Number: (800) 255-3924 (CHEM-TEL)
Hazard Classifications: Acute Toxicity – Oral: Category 3 Acute Toxicity – Dermal: Category 3 Acute Toxicity – Inhalation: Category 3 Specific Target Organ Toxicity (Single Exposure): Category 1 Flammable Liquids: Category 2
Signal Word: DANGER
Hazard Statements: Toxic if swallowed.
Toxic in contact with skin. Toxic if inhaled. Causes damage to organs. Highly flammable liquid and vapor.
Pictograms:
Precautionary Statements:
SDS
Safety Data Sheet
1. IDENTIFICATION
2. HAZARDS IDENTIFICATION
The Science Company SDS 7625 W Hampden Ave, #14 Lakewood CO 80227 Ph: 303-777-3777
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Product: Methyl Alcohol Revision Date: 02/27/2015 2/8
Prevention: Wash thoroughly after handling. Do not eat, drink, or smoke when using this product. Wear protective gloves, protective clothing, eye protection, and face protection. Do not breathe fumes, mists, vapors, or spray. Use only outdoors or in a well-ventilated area. Keep away from heat, sparks, open flames, and hot surfaces. – No smoking. Keep container tightly closed. Ground container and receiving equipment. Use explosion-proof electrical, ventilating, lighting, and transportation equipment. Use only non-sparking tools. Take precautionary measures against static discharge.
Response: If swallowed: Immediately call a poison center or doctor. Rinse mouth.
If on skin (or hair): Wash with plenty of water. Call a poison center or doctor if you feel unwell. Take off immediately all contaminated clothing and wash it before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor. If exposed: Call a poison center or doctor. In case of fire, use water spray, dry powder, alcohol resistant foam, or carbon dioxide to extinguish.
Storage: Store locked up.
Store in a well-ventilated place. Keep container tightly closed. Keep cool.
Disposal: Dispose of contents and container in accordance with local, regional, national, and international regulations.
Hazards Not Otherwise This product is toxic to humans. Primates are especially susceptible to the toxic effects of Classified: methanol, which are not reflected through toxicity data (see Section 11).
May cause adverse reproductive effects.
Toxicity Statement: Not applicable.
Component Common Name / Synonyms CAS# Chemical Formula % by Weight Methyl Alcohol Methanol 67-56-1 CH3 OH ≥ 99.8
Trade Secret Statement: Not applicable.
First Aid Procedures:
Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. WARNING! It may be hazardous to the person providing aid to give mouth-to- mouth resuscitation when the inhaled or ingested material is toxic, infectious, or corrosive. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a poison center or doctor.
Ingestion: Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
keep head low so that vomit does not enter lungs. Never give anything by mouth to an unconscious person. Immediate medical attention is required. Call a physician or poison control center immediately.
3. COMPOSITION AND INFORMATION ON INGREDIENTS
4. FIRST AID MEASURES
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Product: Methyl Alcohol Revision Date: 02/27/2015 3/8
Skin Contact: Remove contaminated clothing and shoes. Wash skin with plenty of water for at least 15 minutes. Wash clothing before reuse. Get medical attention if symptoms occur.
Eye Contact: Check for and remove contact lenses if present and easy to do. Immediately flush eyes with
gentle but large stream of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention if irritation persists.
General Advice: Poison information centers in each state can provide additional assistance for scheduled
poisons. Ensure that medical personnel and those providing first aid are aware of the material(s) involved and take precautions to protect themselves.
Symptoms and Effects: May cause irritation to eyes, skin, respiratory tract, and gastrointestinal tract. Absorption
through skin may cause visual disturbances and metabolic acidosis. Inhalation of vapors may cause dizziness, suffocation, nervous system effects, and cardiovascular effects. May affect the blood, brain, urinary system, liver, spleen, and eyes. Ingestion may cause nausea, vomiting, diarrhea, abdominal pain, constipation, nervous system effects, blindness, and respiration effects. May affect the blood, liver, kidneys, cardiovascular system, brain, pancreas, and eyes.
Immediate Medical Care/ If you feel unwell or are concerned, call a physician or poison control center immediately. Special Treatment: Treat symptomatically.
Suitable Extinguishing Media: Water spray, dry powder, alcohol resistant foam, carbon dioxide.
Unsuitable Extinguishing Media: Do not use a solid (straight) water stream as it may scatter and spread fire.
Hazardous Combustion Carbon oxides. Products:
Specific Hazards: Highly flammable. Vapors may case flash fire or ignite explosively. Can be ignited easily by
heat, sparks, or flames and burns vigorously. Material may burn with an invisible flame. Sealed containers may explode when heated or involved in fire. Material is sensitive to static discharge. Vapors may travel considerable distance to source of ignition and flash back. Vapor from the solvent may accumulate in container headspace resulting in flammability hazard. High vapor concentration in air may cause an explosion hazard.
Special Protective Equipment/ As in any fire, wear MSHA/NIOSH-approved (or equivalent), self-contained, positive- Precautions for Firefighters: pressure or pressure-demand breathing apparatus and full protective gear. Use water spray
to cool unopened containers. Move containers from fire area, if you can do so without risk. This material may evaporate if spilled and leave a flammable residue. In the event of fire and/or explosion, do not breathe fumes.
Personal Precautions and Ventilate area of leak or spill. Isolate hazard area and keep unnecessary and unprotected Protective Equipment: personnel away from the area of the leak or spill. Keep upwind. Keep out of low areas.
Wear appropriate personal protective equipment (see Section 8). Remove all sources of ignition. Pay attention to flashback. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use spark-proof tools and explosion-proof equipment. Avoid contact with eyes, skin, and clothing.
Emergency Procedures: In case of chemical emergency, or if unsure how to address an accidental release, consult a
professional (see Section 1).
5. FIREFIGHTING MEASURES
6. ACCIDENTAL RELEASE MEASURES
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Product: Methyl Alcohol Revision Date: 02/27/2015 4/8
Methods for Containment: Eliminate all sources of ignition. Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer, basements, or confined areas. Dike the spilled material, where this is possible. Product should not be released to the environment. Contain and recover liquid when possible.
Methods for Cleanup: Absorb spill with an inert material (e.g. vermiculite, dry sand, earth, cloth, or fleece) and
place in a noncombustible container for reclamation or disposal. Do not flush to sewer. Clean contaminated surface thoroughly. Never return spills in original containers for reuse. Clean up in accordance with all applicable regulations.
Handling: Do not handle, store, or open near an open flame, sources of heat, or sources of ignition. Wear personal protective equipment (see Section 8). Use only in well-ventilated areas. Provide sufficient air exchange and/or exhaust in work areas. Avoid contact with skin, eyes, and clothing. Do not breathe vapors or spray mist. Do not ingest. When using, do not eat, drink, or smoke. Take precautionary measures against static discharge. To avoid ignition of vapors by static electricity discharge, all metal parts of equipment must be grounded. Keep away from incompatible materials (see Section 10). Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Containers of this material may be hazardous when empty, as they retain product residues (vapors, liquids). Observe all warnings and precautions listed for this product.
Storage: Store in a cool, dry, ventilated area. Store in a segregated and approved area away from
incompatible materials (see Section 10). Store in original container. Keep containers tightly closed and upright. Keep away from food, drink, and animal foodstuffs. Keep out of the reach of children. Ground container and transfer equipment. Comply with all national, state, and local codes pertaining to the storage, handling, dispensing, and disposal of this product.
Exposure Limits: ACGIH: TWA: 200 ppm STEL: 250 ppm BEL: 15 mg/L
OSHA: PEL: 200 ppm 260 mg/m3
Engineering Controls: Ensure adequate ventilation. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
Personal Protective Measures:
Eye/Face Protection: Wear safety glasses with side shields or goggles and a face shield. Maintain approved
eyewash station and accessible rinse facilities in work area.
Skin Protection: Wear appropriate chemical resistant clothing (with long sleeves) and appropriate chemical resistant gloves.
Respiratory Protection: An air-purifying, NIOSH-approved respirator with appropriate cartridge or canister may be
permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Use a positive-pressure, air-supplied respirator if there is any potential for an uncontrolled release, if exposure levels are unknown, or if any other circumstances exist where air-purifying respirators may not provide adequate protection.
7. HANDLING AND STORAGE
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
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Product: Methyl Alcohol Revision Date: 02/27/2015 5/8
Specific Requirements Ensure that glove material is compatible with this product. This information is available from for Personal Protective glove manufacturers. Equipment:
Appearance: Colorless, transparent liquid.
Odor: Pungent, alcoholic.
Odor Threshold: 100 ppm
Formula Weight: 32.04
pH: No information found.
Melting/Freezing Point: -97.8 °C
Boiling Point/Range: 64.7 °C
Decomposition Temperature: No information found.
Flash Point: 9.7 °C
Auto-ignition Temperature: 455 °C
Flammability: Explosive as vapor; flammable as liquid.
Flammability/Explosive Limits: Lower: 6% by volume Upper: 36% by volume
Solubility: Miscible with water, alcohol, ether, benzene, chloroform.
Vapor Pressure: 97.7 mmHg at 20 °C; 410 mmHg at 50 °C
Vapor Density: 1.11 (Air = 1)
Specific Gravity: 0.791 (Water = 1)
Evaporation Rate: 5.2 (Ether = 1)
Viscosity: No information found.
Partition Coefficient -0.77 (n-octanol/water):
Reactivity Data: Highly flammable. See Section 9.
Chemical Stability: Stable under normal conditions.
Conditions to Avoid: Heat, flames, sparks, sources of ignition, incompatible materials.
Incompatible Materials: Oxidizing agents, metals, reducing agents, acids.
Hazardous Decomposition Carbon oxides. Products:
Possibility of Hazardous May react vigorously, violently, or explosively if exposed to extreme thermal conditions or in Reactions: contact with the incompatible materials listed above.
Hazardous Polymerization: Will not occur.
9. PHYSICAL AND CHEMICAL PROPERTIES
10. STABILITY AND REACTIVITY
A-83
Product: Methyl Alcohol Revision Date: 02/27/2015 6/8
Routes of Exposure: Inhalation, ingestion, skin contact, eye contact.
Acute Effects: Harmful or fatal if swallowed, inhaled, or absorbed through the skin or eyes. Causes irritation to the eyes, skin, respiratory tract, and gastrointestinal tract. May cause visual disturbances or blindness if absorbed into the blood stream. May affect the blood, brain, urinary system, liver, spleen, eyes, kidneys, cardiovascular system, and pancreas.
Chronic Effects: May cause central nervous system effects. May cause damage to eyesight. Prolonged or
repeated exposure may cause liver, kidney, brain, cardiovascular system, blood, spleen, and heart damage as well as adverse reproductive effects, birth defects, mutagenic effects, and dermatitis.
Toxicological Data: LD50 Oral, Rat: 5628 mg/kg
LC50 Inhalation, Rat: 87.6 mg/L 6 h LD50 Dermal, Rabbit: 15,800 mg/kg LDL Oral, Human: 143 mg/kg Toxic to reproduction based on animal data.
Symptoms of Exposure: Irritation, unconsciousness, visual disturbances, metabolic acidosis, drowsiness, dizziness,
suffocation, shortness of breath, nervous system effects, cardiovascular effects, cough, nausea, vomiting, diarrhea, abdominal pain, constipation, blindness, and respiration effects.
Carcinogenic Effects: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Ecotoxicological Data: EC50 Water Flea (Daphnia magna): > 10,000 mg/L 48 h LC50 Fathead Minnow (Pimephales promelas): > 100 mg/L 96 h
Persistence and Degradability: Expected to be readily biodegradable.
Bioconcentration Factor: 1.0
Environmental Effects: Not expected to be hazardous to the environment. However, the possibility of an environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Partition Coefficient (n-octanol/water): -0.77
Disposal Instructions: All wastes must be handled in accordance with local, state, and federal regulations. Minimize exposure to product waste (see Section 8). Do not dispose unused waste down drains or into sewers.
Contaminated Packaging: Because emptied containers retain product residue, follow label warnings even after
container is emptied. Residual vapors may explode on ignition; do not cut, drill, grind, or weld on or near product container. Offer rinsed packaging material to local recycling facilities.
Waste Codes: U154 (US RCRA Hazardous Waste U List – Ignitable waste)
11. TOXICOLOGICAL INFORMATION
12. ECOLOGICAL INFORMATION
13. DISPOSAL INFORMATION
A-84
Product: Methyl Alcohol Revision Date: 02/27/2015 7/8
DOT:
UN Number: UN1230
Proper Shipping Name: Methanol
Hazard Class: 3
Packing Group: II
ERG Number: 127
Other Transport Precautions: Reportable Quantity: 5000 lb
U.S. Federal Regulations:
OSHA: This product is considered a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
TSCA Inventory: All components of this product are on the U.S. TSCA Inventory.
U.S. EPCRA (SARA Title III):
Section 302: No information found.
Sections 311/312:
Section 313: Methanol
CERCLA Reportable Quantities: Methanol: 5000 lb
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Hazard Category List (Yes/No) Section 311 – Hazardous Chemical Yes Immediate Hazard Yes Delayed Hazard Yes Fire Hazard Yes Pressure Hazard No Reactivity Hazard No
A-85
Product: Methyl Alcohol Revision Date: 02/27/2015 8/8
International Inventories:
Country or Region Inventory Name On Inventory (Yes/No)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Yes Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes
*A "Yes" indicates that the listed component(s) of this product comply with the inventory requirements administered by the governing country(s)
Disclaimer: The Science Company provides the information in this Safety Data Sheet in the belief that it is reliable but assumes no responsibility for its completeness or accuracy. The physical properties reported in this SDS are obtained from literature and do not constitute product specifications. The Science Company makes and gives no representations or warranties with respect to the information contained herein or the product to which it refers, whether express, implied, or statutory, including without limitation, warranties of accuracy, completeness, merchantability, non-infringement, performance, safety, suitability, stability, and fitness for a particular purpose. No warranty against infringement of any patent, copyright or trademark is made or implied. This SDS is intended only as a guide to the appropriate handling of the material by a properly trained person. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. Accordingly, The Science Company assumes no liability whatsoever for the use of or reliance upon this information including results obtained, incidental or consequential damages, or lost profits.
Issue Date: February 27, 2015
Reason for Revision: Update of Section 2 over 01/29/2014 version.
16. OTHER INFORMATION
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Version: 1.0
November 2017 EN (English US) 1/10
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY Product Identifier Product Name: Concentrated Nitric Acid, 98% Synonyms: Hydrogen Nitrate, Aqua Fortis, White Fuming Nitric Acid Intended Use of the Product Not available Name, Address, and Telephone of the Responsible Party
Company El Dorado Chemical Company 4500 North West Ave. P.O. Box 231 El Dorado, AR 71731 T (870) 863-1400 - F (870)-863-1126
Emergency Telephone Number Emergency number : (870) 863-1400, (800) 424-9300 (CHEMTREC, 24 hours)
SECTION 2: HAZARDS IDENTIFICATION
Classification of the Substance or Mixture Classification (GHS-US) Ox. Liq. 3 H272 Met. Corr. 1 H290 Skin Corr. 1A H314 Eye Dam. 1 H318
Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) :
GHS03
GHS05
Signal Word (GHS-US) : Danger Hazard Statements (GHS-US) : H272 - May intensify fire; oxidizer
H290 - May be corrosive to metals H314 - Causes severe skin burns and eye damage H318 - Causes serious eye damage
Precautionary Statements (GHS-US) : P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking. P220 - Keep/Store away from extremely high or low temperatures, ignition sources, combustible materials, incompatible materials. P221 - Take any precaution to avoid mixing with incompatible materials, ignition sources, combustible materials. P234 - Keep only in original container. P260 - Do not breathe vapors, mist, spray. P264 - Wash hands, forearms, and other exposed areas thoroughly after handling. P280 - Wear protective gloves, protective clothing, eye protection, face protection, respiratory protection. P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER or doctor/physician.
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P321 - Specific treatment (see section 4). P363 - Wash contaminated clothing before reuse. P370+P378 - In case of fire: Use appropriate media for extinction. P390 - Absorb spillage to prevent material damage. P405 - Store locked up. P406 - Store in corrosive resistant container with a resistant inner liner. P501 - Dispose of contents/container to local, regional, national, territorial, provincial, and international regulations.
Other Hazards Other Hazards Not Contributing to the Classification: Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. May cause or intensify fire; oxidizer. When heated to decomposition, emits toxic fumes. Contact with metals may evolve flammable hydrogen gas. Unknown Acute Toxicity (GHS-US) Not available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Mixture
Name Product identifier % (w/w) Classification (GHS-US)
Nitric acid (CAS No) 7697-37-2 97.5 - 100 Ox. Liq. 3, H272 Met. Corr. 1, H290 Skin Corr. 1A, H314 Eye Dam. 1, H318
Full text of H-phrases: see section 16 SECTION 4: FIRST AID MEASURES Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
Inhalation: When symptoms occur: go into open air and ventilate suspected area. Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call for medical assistance.
Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Immediately call for medical assistance. Wash contaminated clothing before reuse.
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call for medical assistance.
Ingestion: Rinse mouth. Do NOT induce vomiting. Immediately call for medical assistance.
Most Important Symptoms and Effects Both Acute and Delayed General: Causes severe skin burns and eye damage. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
Inhalation: Inhalation may cause immediate severe irritation progressing quickly to chemical burns.
Skin Contact: Causes severe irritation which will progress to chemical burns.
Eye Contact: Causes serious eye damage.
Ingestion: Contact may cause immediate severe irritation progressing quickly to chemical burns. Ingestion is likely to be harmful or have adverse effects.
Chronic Symptoms: May cause erosion of the teeth, or chronic bronchitis.
Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention.
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SECTION 5: FIREFIGHTING MEASURES
Extinguishing Media
Special Hazards Arising From the Substance or Mixture
Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Fight fire remotely due to the risk of explosion. Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Nitrogen oxides. Acrid vapors. Corrosive vapors. Other information: Do not allow run-off from fire fighting to enter drains or water courses. Contact with metals may evolve flammable hydrogen gas. Use water spray to disperse vapors. Reference to Other Sections Refer to section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Do NOT breathe (vapors, mist, spray). Avoid all contact with skin, eyes, or clothing. Keep away from heat/sparks/open flames/hot surfaces. – No smoking. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area.
Environmental Precautions Prevent entry to sewers and public waters.
Methods and Material for Containment and Cleaning Up For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Cautiously neutralize spilled liquid with crushed limestone, soda ash or lime. CAUTION : Neutralization can produce vigorous reaction, boiling and fumes. Use extreme caution in clean-up procedure. As an immediate precautionary measure, isolate spill or leak area in all directions. Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Absorb spillage to prevent material damage. Cautiously neutralize spilled liquid with crushed limestone, soda ash or lime. CAUTION : Neutralization can produce vigorous reaction, boiling and fumes. Use extreme caution in clean-up procedure. Contact competent authorities after a spill.
Reference to Other Sections See section 8, Exposure Controls and Personal Protection.
SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling Additional Hazards When Processed: May be corrosive to metals. When heated to decomposition, emits toxic fumes. Corrosive vapors are released. Contact with metals may evolve flammable hydrogen gas. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Do no eat, drink or smoke when using this product. Wash hands and forearms thoroughly after handling.
Suitable Extinguishing Media: Water spray, fog, carbon dioxide, foam, dry chemical. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire.
Fire Hazard: May intensify fire; oxidizer. Will burn if exposed to heat, and in addition, will accelerate the burning of other combustibles, resulting in more rapid spread of fire. Explosion Hazard: Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. In contact with metals, emits flammable/explosive gas. May cause fire or explosion; strong oxidizer. Reactivity: Thermal decomposition generates : toxic/corrosive vapors. Can react explosively with reducing agents, metal powders, Hydrogen sulfide, nitrate, and organic materials. Contact with metals may evolve flammable hydrogen gas.
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Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof electrical, ventilating, and lighting equipment. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep in fireproof place. Keep/Store away from extremely high or low temperatures, direct sunlight, heat, ignition sources, combustible materials, incompatible materials. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Finely divided metals. Hydrogen sulfide. Reducing agents. Organic materials. Specific End Use(s) Not available SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters
Nitric acid (7697-37-2)
Mexico OEL TWA (mg/m³) 5 mg/m³ Mexico OEL TWA (ppm) 2 ppm Mexico OEL STEL (mg/m³) 10 mg/m³ Mexico OEL STEL (ppm) 4 ppm USA ACGIH ACGIH TWA (ppm) 2 ppm USA ACGIH ACGIH STEL (ppm) 4 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 2 ppm USA NIOSH NIOSH REL (TWA) (mg/m³) 5 mg/m³ USA NIOSH NIOSH REL (TWA) (ppm) 2 ppm USA NIOSH NIOSH REL (STEL) (mg/m³) 10 mg/m³ USA NIOSH NIOSH REL (STEL) (ppm) 4 ppm USA IDLH US IDLH (ppm) 25 ppm Alberta OEL STEL (mg/m³) 10 mg/m³ Alberta OEL STEL (ppm) 4 ppm Alberta OEL TWA (mg/m³) 5.2 mg/m³ Alberta OEL TWA (ppm) 2 ppm
British Columbia OEL STEL (ppm) 4 ppm British Columbia OEL TWA (ppm) 2 ppm Manitoba OEL STEL (ppm) 4 ppm Manitoba OEL TWA (ppm) 2 ppm New Brunswick OEL STEL (mg/m³) 10 mg/m³ New Brunswick OEL STEL (ppm) 4 ppm New Brunswick OEL TWA (mg/m³) 5.2 mg/m³ New Brunswick OEL TWA (ppm) 2 ppm Newfoundland & Labrador OEL STEL (ppm) 4 ppm Newfoundland & Labrador OEL TWA (ppm) 2 ppm Nova Scotia OEL STEL (ppm) 4 ppm Nova Scotia OEL TWA (ppm) 2 ppm Nunavut OEL STEL (mg/m³) 10 mg/m³ Nunavut OEL STEL (ppm) 4 ppm Nunavut OEL TWA (mg/m³) 5.2 mg/m³ Nunavut OEL TWA (ppm) 2 ppm Northwest Territories OEL STEL (mg/m³) 10 mg/m³ Northwest Territories OEL STEL (ppm) 4 ppm Northwest Territories OEL TWA (mg/m³) 5.2 mg/m³ Northwest Territories OEL TWA (ppm) 2 ppm Ontario OEL STEL (ppm) 4 ppm
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Ontario OEL TWA (ppm) 2 ppm Prince Edward Island OEL STEL (ppm) 4 ppm Prince Edward Island OEL TWA (ppm) 2 ppm Québec VECD (mg/m³) 10 mg/m³ Québec VECD (ppm) 4 ppm Québec VEMP (mg/m³) 5.2 mg/m³ Québec VEMP (ppm) 2 ppm Saskatchewan OEL STEL (ppm) 4 ppm Saskatchewan OEL TWA (ppm) 2 ppm Yukon OEL STEL (mg/m³) 10 mg/m³ Yukon OEL STEL (ppm) 4 ppm Yukon OEL TWA (mg/m³) 5 mg/m³ Yukon OEL TWA (ppm) 2 ppm
Exposure Controls Appropriate Engineering Controls: Ensure adequate ventilation, especially in confined areas. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use explosion-proof equipment. Ensure all national/local regulations are observed. Alarm detectors should be used when toxic gases may be released. Gas detectors should be used when flammable gases/vapors may be released.
Personal Protective Equipment: Gloves. Respiratory protection of the dependent type. Protective goggles. Protective clothing.
Materials for Protective Clothing: Chemically resistant materials and fabrics. Corrosion-proof clothing. Wear fire/flame resistant/retardant clothing.
Hand Protection: Wear chemically resistant protective gloves. Acid-resistant protective gloves.
Eye Protection: Chemical goggles or face shield.
Skin and Body Protection: Wear suitable protective clothing.
Respiratory Protection: Use NIOSH-approved air-purifying or supplied-air respirator where airborne concentrations of vapor or mist are expected to exceed exposure limits.
Other Information: When using, do not eat, drink or smoke.
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on Basic Physical and Chemical Properties Physical State : Liquid
Appearance : Colorless,light brown
Odor : Acrid
Odor Threshold : Not available
pH : < 1
Relative Evaporation Rate (butylacetate=1) : > 1
Melting Point : Not available
Freezing Point : -41.1 °C (-42°F)
Boiling Point : 83.9 °C (183°F)
Flash Point : Not available
Auto-ignition Temperature : Not available
Decomposition Temperature : Not available
Flammability (solid, gas) : Not available
Lower Flammable Limit : Not available
Upper Flammable Limit : Not available
Vapor Pressure : 51 mm Hg @25°C (77°F)
Relative Vapor Density at 20 °C : >1
Relative Density : Not available
Specific Gravity : 1.51
Solubility : Miscible.
Viscosity : 1 cp @20°C (68°F)
Volatility : 100% Explosion Data – Sensitivity to Mechanical Impact : Not available
Explosion Data – Sensitivity to Static Discharge : Not available
SECTION 10: STABILITY AND REACTIVITY
Reactivity: Thermal decomposition generates : toxic/corrosive vapors. Can react explosively with reducing agents, metal powders, Hydrogen sulfide, nitrate, and organic materials. Contact with metals may evolve flammable hydrogen gas.
Chemical Stability: May intensify fire; oxidizer.
Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Overheating. Open flame. Incompatible materials. Adding water to acid should be avoided.
Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Metals. May be corrosive to metals. Reducing agents. Amines.
Hazardous Decomposition Products: Thermal decomposition generates : Corrosive vapors. Nitrogen oxides. Explosive hydrogen gas. Toxic vapors.
SECTION 11: TOXICOLOGICAL INFORMATION
Information on Toxicological Effects - Product
LD50 and LC50 Data: Not available
Skin Corrosion/Irritation: Causes severe skin burns and eye damage. pH: < 1
Serious Eye Damage/Irritation: Causes serious eye damage. pH: < 1
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Teratogenicity: Not available
Carcinogenicity: Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Reproductive Toxicity: Not classified
Acute Toxicity: Not classified.
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Specific Target Organ Toxicity (Single Exposure): Not classified
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: Inhalation may cause immediate severe irritation progressing quickly to chemical burns.
Symptoms/Injuries After Skin Contact: Causes severe irritation which will progress to chemical burns.
Symptoms/Injuries After Eye Contact: Causes serious eye damage.
Symptoms/Injuries After Ingestion: Contact may cause immediate severe irritation progressing quickly to chemical burns. Ingestion is likely to be harmful or have adverse effects.
Chronic Symptoms: May cause erosion of the teeth, or chronic bronchitis. Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data:
Nitric acid (7697-37-2)
LC50 Inhalation Rat (mg/l) 0.13 mg/l (Exposure time: 4 h)
LC50 Inhalation Rat (ppm) 67 ppm/4h
SECTION 12: ECOLOGICAL INFORMATION Toxicity Not classified Persistence and Degradability Concentrated Nitric Acid
Persistence and Degradability Not established. Bioaccumulative Potential
Concentrated Nitric Acid
Bioaccumulative Potential Not established.
Nitric acid (7697-37-2)
Log Pow -2.3 (at 25 °C)
Mobility in Soil Not available Other Adverse Effects Other Information: Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial and international regulations.
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SECTION 14: TRANSPORT INFORMATION
14.1 In Accordance with DOT Proper Shipping Name : NITRIC ACID other than red fuming, with more than 70% nitric acid Hazard Class : 8
Identification Number : UN2031 Label Codes : 8,5.1 Packing Group : I
ERG Number : 157 14.2 In Accordance with IMDG Proper Shipping Name : NITRIC ACID Hazard Class : 8 Identification Number : UN2031 Packing Group : I Label Codes : 8,5.1
EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-Q 14.3 In Accordance with IATA Proper Shipping Name : NITRIC ACID Packing Group : I Identification Number : UN2031
Hazard Class : 8 Label Codes : 8,5.1 ERG Code (IATA) : 8X 14.4 In Accordance with TDG Proper Shipping Name : NITRIC ACID Packing Group : I Hazard Class : 8
Identification Number : UN2031 Label Codes : 8,5.1 SECTION 15: REGULATORY INFORMATION US Federal Regulations
Nitric acid (7697-37-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 302 (Specific toxic chemical listings) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 302 Threshold Planning Quantity (TPQ) 1000 SARA Section 313 - Emission Reporting 1.0 %
US State Regulations
Nitric acid (7697-37-2)
U.S. - California - SCAQMD - Toxic Air Contaminants - Non-Cancer Acute U.S. - California - SCAQMD - Toxic Air Contaminants With Proposed Risk Values U.S. - California - Toxic Air Contaminant List (AB 1807, AB 2728) U.S. - Connecticut - Hazardous Air Pollutants - HLVs (30 min) U.S. - Connecticut - Hazardous Air Pollutants - HLVs (8 hr)
Concentrated Nitric Acid
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Reactive hazard Fire hazard
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U.S. - Delaware - Accidental Release Prevention Regulations - Sufficient Quantities U.S. - Delaware - Accidental Release Prevention Regulations - Threshold Quantities U.S. - Delaware - Accidental Release Prevention Regulations - Toxic Endpoints U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs) U.S. - Idaho - Occupational Exposure Limits - TWAs U.S. - Illinois - Toxic Air Contaminants U.S. - Louisiana - Reportable Quantity List for Pollutants U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 2 U.S. - Massachusetts - Oil & Hazardous Material List - Reportable Quantity U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 2 U.S. - Massachusetts - Right To Know List U.S. - Massachusetts - Toxics Use Reduction Act U.S. - Michigan - Occupational Exposure Limits - STELs U.S. - Michigan - Occupational Exposure Limits - TWAs U.S. - Michigan - Polluting Materials List U.S. - Michigan - Process Safety Management Highly Hazardous Chemicals U.S. - Minnesota - Chemicals of High Concern U.S. - Minnesota - Hazardous Substance List U.S. - Minnesota - Permissible Exposure Limits - STELs U.S. - Minnesota - Permissible Exposure Limits - TWAs U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - 24-Hour U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - Annual U.S. - New Jersey - Discharge Prevention - List of Hazardous Substances U.S. - New Jersey - Environmental Hazardous Substances List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - New Jersey - Special Health Hazards Substances List U.S. - New Jersey - TCPA - Extraordinarily Hazardous Substances (EHS) U.S. - New York - Occupational Exposure Limits - TWAs U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances U.S. - North Carolina - Control of Toxic Air Pollutants U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 1-Hour U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 8-Hour U.S. - Ohio - Accidental Release Prevention - Threshold Quantities U.S. - Ohio - Extremely Hazardous Substances - Threshold Quantities U.S. - Oregon - Permissible Exposure Limits - TWAs U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Rhode Island - Air Toxics - Acceptable Ambient Levels - 1-Hour U.S. - South Carolina - Toxic Air Pollutants - Maximum Allowable Concentrations U.S. - South Carolina - Toxic Air Pollutants - Pollutant Categories U.S. - Tennessee - Occupational Exposure Limits - STELs U.S. - Tennessee - Occupational Exposure Limits - TWAs U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term U.S. - Vermont - Permissible Exposure Limits - STELs U.S. - Vermont - Permissible Exposure Limits - TWAs U.S. - Washington - Permissible Exposure Limits - STELs U.S. - Washington - Permissible Exposure Limits - TWAs U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 25 Feet to Less Than 40 Feet
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U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 40 Feet to Less Than 75 Feet U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 75 Feet or Greater U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights Less Than 25 Feet U.S. - Wyoming - Process Safety Management - Highly Hazardous Chemicals
Canadian Regulations
Nitric acid (7697-37-2)
Listed on the Canadian DSL (Domestic Substances List) inventory. Listed on the Canadian Ingredient Disclosure List WHMIS Classification Class C - Oxidizing Material
Class E - Corrosive Material
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR.
SECTION 16: OTHER INFORMATION
Revision date : November 2017 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA
Hazard Communication Standard 29 CFR 1910.1200. GHS Full Text Phrases: ------ Eye Dam. 1 Serious eye damage/eye irritation Category 1 ------ Met. Corr. 1 Corrosive to metals Category 1 ------ Ox. Liq. 3 Oxidizing liquids Category 3 ------ Skin Corr. 1A Skin corrosion/irritation Category 1A ------ H272 May intensify fire; oxidizer ------ H290 May be corrosive to metals ------ H314 Causes severe skin burns and eye damage ------ H318 Causes serious eye damage
NFPA Health Hazard : 3 - Short exposure could cause serious temporary or residual injury even though prompt medical attention was given.
NFPA Fire Hazard : 0 - Materials that will not burn. NFPA Reactivity : 0 - Normally stable, even under fire exposure conditions,
and are not reactive with water. NFPA Specific Hazard : OX - This denotes an oxidizer, a chemical which can greatly
increase the rate of combustion/fire. Party Responsible for the Preparation of This Document El Dorado Chemical Company P.O. Box 231 El Dorado, AR 71731 (870) 863-1400 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
Concentrated Nitric Acid
WHMIS Classification Class E - Corrosive Material Class C - Oxidizing Material
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Sulfuric Acid 1 August 2009
MATERIAL SAFETY DATA SHEET - MSDS
Sulfuric Acid (Concentrated)
Martin Product Sales, LLC Emergency Assistance P.O. Box 191 Chemtrec: (800)424-9300 Kilgore, Texas 75663 1-800-256-6644 Section 1: Product Identification Synonyms: Sulphuric Acid, Hydrogen Sulphate, Oil of Vitriol, Battery Acid Chemical Name: Sulfuric Acid Chemical Family: Inorganic Acid Chemical Formula: H2SO4 CAS Reg. No.: 7664-93-9 Martin can not guarantee the technical analysis and exact chemical composition as it may vary depending on the chemical components of the raw material and are not reflected in this document. Consult analysis sheets for exact chemical composition. Section 2: Hazard Identification PHYSICAL STATE AND APPEARANCE: Odorless, clear to amber, heavy, oily liquid. A pungent odor may exist if certain impurities are present in the acid. EMERGENCY OVERVIEW: Danger! Extremely corrosive. Causes severe burns and / or eye damage. Mist: Causes respiratory irritation. Harmful if inhaled. Harmful or fatal if swallowed. Reacts violently with water. Concentrated Sulfuric Acid will react with many organic materials and may cause fire due to the heat of the reaction. Not flammable, but reacts with most metals to form explosive/flammable hydrogen gas. This product contains ingredients that are considered to be hazardous as defined by the OSHA Hazard Communication Standard 29 CFR 1910.1200, and is listed in the Toxic Substances Control Act (TSCA). Routes of entry: Skin contact. Eye contact. Ingestion. Inhalation. Potential acute health effects EYE CONTACT: Immediate pain, severe burns and corneal damage, which may result in permanent blindness. SKIN CONTACT: Causes burns, and brownish or yellow stains. Concentrated solutions may cause second or third degree burns with severe necrosis. Prolonged and repeated exposure to dilute solutions may cause irritation, redness, pain and drying and cracking of the skin. INHALATION: Causes respiratory irritation and at high concentrations may cause severe injury, burns, or death. Effects of exposure may be delayed. INGESTION: Causes severe irritation or burns of the mouth, throat, and esophagus.
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Sulfuric Acid 2 August 2009
EXISTING MEDICAL CONDITIONS POSSIBLY AGGRAVATED BY EXPOSURE: Skin irritation may be aggravated in individuals with existing skin lesions. Breathing of vapors or sprays (mists) may aggravate acute or chronic asthma and chronic pulmonary disease such as emphysema and bronchitis. See Section 11 for Toxicological Data Section 3: Composition / Information on Ingredients Name CAS # % by weight Sulfuric Acid 7664-93-9 70 – 100% Water 7732-18-5 0-30% Section 4: First Aid Measures Corrosive effects on the skin and eyes may be delayed, and damage may occur without the sensation or onset of pain.
SPEED IS ESSENTIAL. OBTAIN IMMEDIATE MEDICAL ATTENTION. Have emergency eyewash station / safety shower available in work area.
SKIN CONTACT: Immediately flush skin with running water for a minimum of 20 minutes. Start flushing while removing contaminated clothing. If irritation persists, repeat flushing. Obtain medical attention immediately. Do not transport victim unless the recommended flushing period is completed or flushing can be continued during transport. Discard heavily contaminated clothing and shoes in a manner that limits further exposure. EYE CONTACT: Immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during flushing. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY. Do not transport victim until the recommended flushing period is completed unless flushing can be continued during transport. INHALATION: Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Do not use mouth-to-mouth method if victim ingested or inhaled the substance: induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Give Cardiopulmonary Resuscitation (CPR) if there is no pulse AND no breathing. Obtain medical attention IMMEDIATELY. INGESTION: DO NOT INDUCE VOMITING. If victim is alert and not convulsing, rinse mouth and give ½ to 1 glass of water to dilute material. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing in of vomitus, rinse mouth and administer more water. IMMEDIATELY contact local poison control center. Vomiting may need to be induced but should be directed by a physician or a poison control centre. IMMEDIATELY transport victim to an emergency facility. While the patient is being transported to a medical facility apply compresses of iced water. If medical treatment must be delayed, immerse the affected area in iced water or apply compresses of iced water to affected areas. Do not freeze tissue. Continued washing of the affected area with cold or iced water will be helpful in removing the last traces of sulfuric acid. Creams or ointments should not be applied before or during the washing phase of treatment.
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Sulfuric Acid 3 August 2009
NOTE TO PHYSICIANS: This product contains materials that may cause severe pneumonitis if aspirated. If ingestion has occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to prevent aspiration. Observe patient for respiratory difficulty from aspiration pneumonitis. Give artificial resuscitation and appropriate chemotherapy if respiration is depressed. Following exposure the patient should be kept under medical review for at least 48 hours as delayed pneumonitis may occur. DO NOT attempt to neutralize the acid with weak bases since the reaction will produce heat that may extend the corrosive injury
Section 5: Fire Fighting Measures
Flammability of the product: Non-flammable
Flash points: Not applicable
Auto-ignition temperature: Not applicable
Flammable limits: Not applicable
Products of thermal decomposition: Oxides of Sulfur
EXPLOSION HAZARDS:
Not flammable but highly reactive. Reacts violently with water with evolution of heat can react with organic materials explosively (See Section 10). Reacts with many metals to liberate hydrogen gas which can form explosive mixtures with air. Hydrogen can accumulate to explosive concentrations. May ignite other combustible materials. HAZARDOUS REACTIVITY Instability: Stable, but reacts violently with water and organic materials with evolution of heat. Decomposition: Releases sulfur dioxide at extremely high temperatures. Polymerization: Polymerization will not occur. Materials to Avoid: Vigorous reactions with water; alkaline solutions; metals, metal powder; carbides; chlorates; fuminates; nitrates; picrates; strong oxidizing, reducing, or combustible organic materials. Hazardous gases are evolved on contact with chemicals such as cyanides, sulfides, and carbides. FIRE-FIGHTING MEDIA AND INSTRUCTIONS: Wear a NIOSH/MSHA approved self-contained breathing apparatus if vapors or mists are present and full protective clothing. For fighting fires in close proximity to spill or vapors, use acid-resistant personal protective equipment. Evacuate personnel to a safe area. Prevent unauthorized entry to fire area. Dike area to contain runoff and prevent contamination of water sources. Neutralize runoff with lime, soda ash or other suitable neutralizing agents (see Deactivating Chemicals, Section 6). Cool containers that are exposed to flame with streams of water until fire is out.
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Sulfuric Acid 4 August 2009
Section 6: Accidental Release Measures Small Spill: Cover with DRY earth, sand or other non-combustible material or absorb with an inert dry material and place in a loosely covered plastic or other appropriate waste disposal container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate, lime, or other suitable neutralizing agent. Large Spill: Stop leak if possible without risk. Dike with DRY earth, sand or other non-combustible inert material. Prevent entry into sewers or waterways. Consider neutralizing the residue with sodium carbonate, lime, or other suitable neutralizing agent. Ensure adequate decontamination of tools and equipment following clean up. Comply with Federal, Provincial/State and local regulations on reporting releases. Dispose of waste material at an approved waste treatment/disposal facility, in accordance with applicable regulations. Do not dispose of waste with normal garbage or to sewer systems. Section 7: Handling and Storage Good general ventilation should be provided to keep vapor and mist concentrations below the exposure limits. Have available and wear as appropriate: Chemical splash goggles; full-length faceshield/chemical splash goggle combination; acid-proof gauntlet gloves, apron, and boots; acid proof suit and hood; and appropriate NIOSH/MSHA respiratory protection. In case of emergency or where there is a strong possibility of considerable exposure, wear a complete acid suit with hood, boots and gloves. If acid vapor or mist are present and exposure limits may be exceeded, wear appropriate NOISH/MSHA respiratory protection. HANDLING: Wear appropriate Personal Protection Equipment. Do not breathe sprays or mists. Do not ingest. Do not get in eyes, on skin or on clothing. Keep ignition sources away from sulfuric acid storage, handling and transportation equipment. Locate safety shower and eyewash station close to chemical handling area. Use EXTREME care when diluting with water. Always add acid to water never the reverse. CAUTION: Hydrogen, a highly flammable gas, can accumulate to explosive concentrations inside drums, or any types of steel containers or tanks upon storage. Carbon steel storage tanks must be vented. People working with this chemical should be properly trained regarding its hazards and its safe use. STORAGE: If stored in non-reactive container, keep container tightly closed. Metal and, specifically carbon steel, storage tanks must be vented due to hydrogen release as noted above. Section 8: Exposure Control / Personal Protection Engineering controls Use process enclosures, local exhaust ventilation or other engineering controls to keep airborne levels below recommended exposure limits. The most effective measures are the total enclosure of processes and the mechanization of handling procedures to prevent all personal contact with sulfuric acid. Safety showers and eyewash stations should be installed in storage and handling areas.
Personal protection Eyes: Chemical goggles and face shield. Skin: Where there is a danger of spilling or splashing, acid resistant aprons or suits should be worn. Trouser legs should be worn outside (not tucked in) rubber boots.
Hands: Chemical-resistant, impervious gloves (i.e. neoprene) should be worn when handling sulfuric acid.
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Sulfuric Acid 5 August 2009
Respiratory: Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. A NIOSH/MSHA approved air-purifying respirator equipped with acid gas/fume, dust, mist cartridges for concentrations up to 10 mg/m
3. An air-
supplied respirator if concentrations are higher or unknown. NOTE: Personal protection information shown in Section 8 is based upon general information as to normal uses and conditions. Where special or unusual uses or conditions exist, it is suggested that the expert assistance of an industrial hygienist or other qualified professional be sought. Component Exposure limits Sulfuric Acid: ACGIH TLV 1 mg/m
3 (TWA) 8 hours
ACGIH STEL 3 mg/m3 15 minutes
OSHA PEL 1 mg/m3 (TWA) 8 hours
NIOSH REL 1 mg/m3 (TWA) 10 hours
Section 9: Physical and Chemical Properties
Appearance and Odor: Odorless, clear to amber, heavy, oily liquid. A pungent odor may exist if certain impurities are present in the acid. Physical State: Liquid
Molecular Weight: 98.08
Odor Threshold: Not applicable
Boiling Point: 78%: 193°C (380°F) 93%: 276°C (529°F) 98%:330°C (626°F)
Melting/Freezing Point: 78%: -11.2°C (+11.6°F) 93%: -29.5°C (-21.1°F) 98%: -1.1°C (30°F)
Vapor Pressure at 40°C (102°F): 78%: 1.2 mmHg 93%: 0.0016 mmHg 98%: 0.002 mmHg
Specific Gravity at 15°C (60°F): 78%: 1.7059 93%: 1.8354 98%: 1.8437
Vapor Density: (Air=1): 3.4
Evaporation Rate: Not applicable
Solubility: Easily soluble in cold water (with liberation of much heat.) Soluble in ethyl alcohol.
pH: 0.3 (1N solution at 25°C/78°F)
Section 10: Stability and Reactivity Stability: Stable Conditions to Avoid: Keep away from heat and sources of ignition. Avoid temperatures, which may have a negative effect on the materials of construction used in equipment. Materials to Avoid: Contact with organic materials (such as alcohol, acrylonitrile, chlorates, carbides, epichlorohydrin, fulminates, isoprene, nitrates and picrates) may cause fire and explosions. Contact with metals may produce flammable hydrogen gas. When diluting, add acid to water. Do NOT add water to the acid.
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Sulfuric Acid 6 August 2009
Hazardous Decomposition or Combustion Products: Toxic gases and vapors (e.g. sulfur dioxide, sulfuric acid vapors/mists and sulfur trioxide) may be released when sulfuric acid decomposes. Hazardous Polymerization: Will Not Occur. Corrosivity: Extremely corrosive in presence of aluminum, copper, and stainless steel. Highly corrosive in presence of stainless steel (304). Non-corrosive in presence of glass. Section 11: Toxicological Information Toxicity Data LD
50 (oral, rat) = 2140 mg/kg LC
50 (inhalation, rat) = 510 mg/m
3 for 2 hrs
Carcinogenicity Data: The IARC has concluded that occupational exposure to strong inorganic acid mists containing sulfuric acid is carcinogenic to man, causing cancer of the larynx (the voice box). Although no direct link has been established between exposure to sulfuric acid and cancer in man, exposure to any mist or aerosol during the use of this product should be avoided. Reproductive Effects: Slightly embryotoxic in rabbits (a minor, rare skeletal variation). The animals were exposed to 5 and 20 mg/m
3 for 7 hrs/day throughout pregnancy. Slight maternal toxicity was present at the
highest dose in both species. Mutagenicity Data: Cytogenic analysis (hamster) ovaries 4 mmol/L Teratogenicity Data: Not teratogenic in mice and rabbits. Synergistic Materials: None known Special Remarks on other Toxic Effects on Humans: Skin: Causes severe skin irritation and burns. Continued contact can cause tissue necrosis. Eye: Causes severe eye irritation and burns. May cause irreversible eye injury. Ingestion: Harmful if swallowed. May cause permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the stomach, GI bleeding, edema of the glottis, necrosis and scarring, and sudden circulatory collapse (similar to acute inhalation). It may also cause systemic toxicity with acidosis. Inhalation: May cause severe irritation of the respiratory tract and mucous membranes with sore throat, coughing, shortness of breath, and delayed lung edema. Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis, and pulmonary edema. May also affect teeth (changes in teeth and supporting structures - erosion, discoloration).
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Sulfuric Acid 7 August 2009
Chronic Potential Health Effects: Inhalation: Prolonged or repeated inhalation may affect behavior (muscle contraction or spasticity), urinary system (kidney damage), and cardiovascular system, heart (ischemic heart lesions), and respiratory system/lungs (pulmonary edema, lung damage), teeth (dental discoloration, erosion). Skin: Prolonged or repeated skin contact may cause dermatitis, an allergic skin reaction.
Section 12: Ecological Information Ecotoxic Effects: Harmful to aquatic life in very low concentrations. May be dangerous if it enters water intake; Fish toxicity; 2.8 μg/L 96 hrs LC50 Rainbow trout. Products of Degradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. These products are sulphur oxides (SO2, SO3) Toxicity of the Products of Degradation: The products of degradation are more toxic than the original product.
Section 13: Disposal Considerations
Waste disposal: The generation of waste should be avoided or minimized wherever possible. Cleaned up material may be a hazardous waste as defined by Resource Conservation and Recovery Act (RCRA) on disposal due to the corrosivity characteristic. Disposal of this product and any by-products must comply with all local, state, and federal requirements. Consult your local and/or regional authorities. Section 14: Transport Information Shipping Description: Sulfuric Acid Shipping Description: UN 1830, Sulfuric Acid, 8, PG II Packaging References: 49CFR, Sections 172.504, 173.213, 173.247, 172.325 / SP 30 Section 15: Regulatory Information U.S. Federal regulations: TSCA 8(b) inventory: Sulfuric acid SARA 302/304/311/312 extremely hazardous substances: Sulfuric acid SARA 313 toxic chemical notification and release reporting: Sulfuric acid CERCLA: Hazardous Substances: Sulfuric acid: 1000 lbs. (453.6 kg) Reportable Quantity (RQ) under U.S. EPA CERCLA: RQ=1000 lb / 454 kg TSCA Inventory Status: Reported/Included Other Regulations/Legislation which apply to this product: New Jersey Special Health Hazard Substance List and Environmental Hazardous Substance; Minnesota, Florida, Rhode Island Hazardous Substance ; California Director's List of Hazardous Substances; Massachusetts Extraordinarily Hazardous Substance List
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Sulfuric Acid 8 August 2009
Section 16: Other Information
Hazardous Material Information System (HMIS) National Fire Protection Association (NFPA)
References: 29 CFR Part 1910.1200 OSHA MSDS Requirements.
49 CFR 172.101 Table of Hazardous Materials ANSI Z400.1, MSDS Standard, 2004. Hawley’s Condensed Chemical Dictionary, 14th Edition The Merck Index, 12th Edition Supplier Material Safety Data Sheets
LEGAL DISCLAIMER While the information contained in the MSDS is believed to be reliable, no guarantee is made as to its accuracy or completeness. The conditions of use, handling, storage, and disposal, and the suitability of the product for particular uses are beyond our control. Consequently, all risks involving the use of the product are assumed by the user. We expressly disclaim all warranties of every kind and nature, express or implied, including the warranties of merchantability and fitness for a particular purpose.
Health 3
Fire hazard 0
Physical Hazard 2
Personal protection C
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Material Safety Data Sheet
Toluene (MSDS)
Section 1: Chemical Product and Company Identification
Product Name: Toluene
CAS#: 108-88-3
Synonym: Synonyms: Methacide;
Methylbenzene; Phenylmethane; Antisal la;
Benzene, methyl-; Methane, phenyl-;
Methylbenzol; Tolu-Sol; Tolueen; Toluen;
Toluene; Tolueno; Toluol; Toluolo.
Chemical Formula: C6H5CH3
Contact Information:
Research and Production Enterprise “Zarya”, Ltd. Zavodskaya Street, 1g/36, Rubezhnoye, Lugansk reg., Ukraine, 93001 Phone: +380 (6453) 95085, 95026, 95035 Fax: +380 (6453) 95042, 95026, 95035
www.zaryachem.com
Section 2: Composition and Information on Ingredients
Composition:
Name % by Weight
Toluene wt, % min 99,2
Benzene wt, % max 0,02
Sulphur wt, % 0,25
Section 3: Hazards Identification
Potential Acute Health Effects:
Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.
Slightly hazardous in case of skin contact (permeator).
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH, 3 (Not
classifiable for human.) by IARC.
MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to blood, kidneys, the
nervous system, liver, brain, central nervous system (CNS).
Repeated or prolonged exposure to the substance can produce target organs damage.
Section 4: First Aid Measures
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of
water for at least 15 minutes. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an
emollient. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek
immediate medical attention.
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Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt
or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform
mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give
mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek medical
attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: Flammable.
Auto-Ignition Temperature: 552°C
Flammable Limits: LOWER: 1.17% UPPER: 7.1%
Flash Points: 4.4°C
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances:
Flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of
explosion of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions:
Flammable liquid, insoluble in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE:
Use water spray or fog.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards:
Toluene forms explosive reaction with 1,3-dichloro-5,5-dimethyl-2,4-imidazolididione; dinitrogen
tetraoxide; concentrated nitric acid, sulfuric acid + nitric acid; N2O4; AgClO4; BrF3; Uranium
hexafluoride; sulfur dichloride. Also forms an explosive mixture with tetranitromethane.
Section 6: Accidental Release Measures
Small Spill:
Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Large Spill:
Toxic flammable liquid, insoluble or very slightly soluble in water. Keep away from heat. Keep
away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-
combustible material. Do not get water inside container. Do not touch spilled material. Prevent entry
into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be careful
that the product is not present at a concentration level above TLV. Check TLV on the MSDS and
with local authorities.
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Section 7: Handling and Storage
Precautions:
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing
material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In
case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice
immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from
incompatibles such as oxidizing agents.
Storage:
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep
container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark
or flame).
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers
are proximal to the work-station location.
Personal Protection:
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or
equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus
should be used to avoid inhalation of the product. Suggested protective clothing might not be
sufficient; consult a specialist BEFORE handling this product.
Exposure Limits:
TWA: 200 STEL: 500 CEIL: 300 (ppm) from OSHA (PEL) [United States] TWA: 50 (ppm) from
ACGIH (TLV) [United States] SKIN TWA: 100 STEL: 150 from NIOSH [United States] TWA: 375
STEL: 560 (mg/m3) from NIOSH [United States] Consult local authorities for acceptable exposure
limits.
Section 9: Physical and Chemical Properties
Physical State: Liquid
Appearance: colorless
Odor: sweetish odor - pleasant odor - benzene-like
Molecular Weight: 92.14 g/mol
Boiling Point: 110.62 °C
Freezing/Melting Point:-94,99 °C
Vapor Pressure: 36.7 mm Hg @ 30 deg C
Vapor Density: 3.1 (Air=1)
Density (20 ºC): 0,8669 g/cm3
Volatility: Moderate
Water/Oil Dist. Coeff.: The product is more soluble in oil; log(oil/water) = 2.69
Solubility: Soluble in diethyl ether, acetone. Practically insoluble in cold water. Soluble in ethanol,
benzene, chloroform, glacial acetic acid, carbon disulfide.
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Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Heat, ignition sources (flames, sparks, static), incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Incompatible with strong oxidizers, silver perchlorate, sodium difluoride, Tetranitromethane,
Uranium Hexafluoride. Frozen Bromine Trifluoride reacts violently with Toluene at -80 deg. C.
Reacts chemically with nitrogen oxides, or halogens to form nitrotoluene, nitrobenzene, and
nitrophenol and halogenated products, respectively.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur
Section 11: Toxicological Information
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animals:
Acute oral toxicity (LD50): 7530 mg/kg [Rat]. Acute dermal toxicity (LD50): 12400 mg/kg
[Rabbit]. Acute toxicity of the vapor (LC50): 440 24 hours [Mouse].
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH, 3 (Not
classifiable for human.) by IARC.
May cause damage to the following organs: blood, kidneys, the nervous system, liver, brain,
central nervous system (CNS).
Other Toxic Effects on Humans:
Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case
of skin contact (permeator).
Special Remarks on Toxicity to Animals:
Lowest Published Lethal Dose: LDL [Human] - Route: Oral; Dose: 50 mg/kg LCL [Rabbit] -
Route: Inhalation; Dose: 55000 ppm/40min
Special Remarks on Chronic Effects on Humans:
Detected in maternal milk in human. Passes through the placental barrier in human. Embryotoxic
and/or foetotoxic in animal.
May cause adverse reproductive effects and birth defects (teratogenic). May affect genetic material
(mutagenic)
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Causes mild to moderate skin irritation. It can be absorbed to
some extent through the skin. Eyes: Causes mild to moderate eye irritation with a burning
sensation. Splash contact with eyes also causes conjunctivitis, blepharospasm, corneal edema,
corneal abraisons. This usually resolves in 2 days. Inhalation: Inhalation of vapor may cause
respiratory tract irritation causing coughing and wheezing, and nasal discharge. Inhalation of high
concentrations may affect behavior and cause central nervous system effects characterized by
nausea, headache, dizziness, tremors, restlessness, lightheadedness, exhilaration, memory loss,
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insomnia, impaired reaction time, drowsiness, ataxia, hallucinations, somnolence, muscle
contraction or spasticity, unconsciousness and coma. Inhalation of high concentration of vapor may
also affect the cardiovascular system (rapid heart beat, heart palpitations, increased or decreased
blood pressure, dysrhythmia), respiration (acute pulmonary edema, respiratory depression, apnea,
asphyxia), cause vision disturbances and dilated pupils, and cause loss of appetite. Ingestion:
Aspiration hazard. Aspiration of Toluene into the lungs may cause chemical pneumonitis. May
cause irritation of the digestive tract with nausea, vomiting, pain. May have effects similar to that
of acute inhalation. Chronic Potential Health Effects: Inhalation and Ingestion: Prolonged or
repeated exposure via inhalation may cause central nervous system and cardiovascular symptoms
similar to that of acute inhalation and ingestion as well liver damage/failure, kidney damage/failure
(with hematuria, proteinuria, oliguria, renal tubular acidosis), brain damage, weight loss, blood
(pigmented or nucleated red blood cells, changes in white blood cell count), bone marrow changes,
electrolyte imbalances (Hypokalemia, Hypophostatemia), severe, muscle weakness and
Rhabdomyolysis. Skin: Repeated or prolonged skin contact may cause defatting dermatitis.
Section 12: Ecological Information
Ecotoxicity:
Ecotoxicity in water (LC50): 313 mg/l 48 hours [Daphnia (daphnia)]. 17 mg/l 24 hours [Fish (Blue
Gill)]. 13 mg/l 96 hours [Fish (Blue Gill)]. 56 mg/l 24 hours [Fish (Fathead minnow)]. 34 mg/l 96
hours [Fish (Fathead minnow)]. 56.8 ppm any hours [Fish (Goldfish)].
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation
products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the
product itself.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:
Waste must be disposed of in accordance with state and local environmental control regulations.
Section 14: Transport Information
DOT Classification: CLASS 3: Flammable liquid.
Identification: : Toluene UNNA: 1294 PG: II
Special Provisions for Transport: Not available.
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Section 15: Other Information
References: Not available.
Other Special Considerations: Not available.
Created: 15/08/2011 11:00 AM
Last Updated: 14/07/2012 12:00 PM
Futher Information: The information contained in this Material Safety Data Sheet is based upon
available data and believed to be correct; however, as such has been obtained from various
sources, including the manufacturer and independent laboratories, it is given without warranty or
representation that it is complete, accurate, and can be relied upon. Research and Production
Enterpise “Zarya”, Ltd. has not attempted to conceal in any manner the deleterious aspects of
the product listed herein, but makes no warranty as to such. Further, Research and Production
Enterpise “Zarya”, Ltd. cannot anticipate nor control the many situations in which the product or
this information may be used; there is no guarantee that the health and safety precautions suggested
will be proper under all conditions. It is the sole responsibility of each user of the product to
determine and comply with the requirements of all applicable laws and regulations regarding its
use. This information is given solely for the purposes of safety to persons and property. Any other
use of this information is expressly prohibited.
A-110
UNDERTAKING
I], Nishant Patel, Director of Reynish Pharmachem Pvt. Ltd. to be located a t
urvey. no.: 504, 505 and 507, Village: Dabhasa, Ta.: Padra, District:
adodara , Gujarat, do hereby undertake as under:
1 I hereby give an undertaking that, the data & information given in the
application and enclosures are true and we will be responsible for any
1 factual discrepancy in EIA report. The ownership of EIA report remain
with us.
I
A-112
I undertake that, content including information & data of EIA report is
own by us and data or information are not taken from any other EIA
report.
I hereby declare that, what is stated herein above is true to the best of
my knowledge and same I believed to be true.
For Reynish Pharmachem I F y t . - Ltd
= i P*P* D;.rietor
(Stamp & Signature here)
Date: 12.02.2019
Place: Vadodara
For, Reynish Pharmachem Pvt. Ltd.
Nishant Patel
Director
~ W C A N T J. PATEL NOTARY
-.DIST.VADOMM (GOVT. OF INDIA)
A-113
No.IA-J-11011/194/2018-IA-II(I)
Goverment of India
Minister of Enviroment,Forest and Climate Change
Impact Assessment Division
***
Indira Paryavaran Bhavan,
Vayu Wing,3rd Floor,Aliganj,
Jor Bagh Road,New Delhi-110003
13 Jul 2018
To,
M/s REYNISH PHARMACHEM PVT. LTD.
2, Capriana Appartment, 27 Rajnagar Soc., Near Akota Stadium, Vadodara,
Vadodara-391150
Gujarat
Tel.No.079-26583077; Email:[email protected]
Sir/Madam,
This has reference to the proposal submitted in the Ministry of Environment, Forest
and Climate Change to prescribe the Terms of Reference (TOR) for undertaking detailed EIA
study for the purpose of obtaining Environmental Clearance in accordance with the provisions of
the EIA Notification, 2006. For this purpose, the proponent had submitted online information in the
prescribed format (Form-1 ) along with a Pre-feasibility Report. The details of the proposal are
given below:
1. Proposal No.: IA/GJ/IND2/75368/2018
2. Name of the Proposal: REYNISH PHARMACHEM PVT. LTD.
3. Category of the Proposal: Industrial Projects - 2
4. Project/Activity applied for: 5(f) Synthetic organic chemicals industry (dyes
& dye intermediates; bulk
5. Date of submission for TOR: 11 Jun 2018
In this regard, under the provisions of the EIA Notification 2006 as amended, the Standard TOR
for the purpose of preparing environment impact assessment report and environment
management plan for obtaining prior environment clearance is prescribed with public consultation
as follows:
A-114
STANDARD TERMS OF REFERENCE (TOR) FOR EIA/EMP REPORT FOR PROJECTS/ACTIVITIES REQUIRING ENVIRONMENT CLEARANCE
5(f):STANDARD TERMS OF REFERENCE FOR CONDUCTINGENVIRONMENT IMPACT ASSESSMENT STUDY FOR SYNTHETICORGANIC CHEMICALS INDUSTRY (DYES & DYEINTERMEDIATES; BULK DRUGS AND INTERMEDIATESEXCLUDING DRUG FORMULATIONS; SYNTHETIC RUBBERS;BASIC ORGANIC CHEMICALS, OTHER SYNTHETIC ORGANICCHEMICALS AND CHEMICAL INTERMEDIATES) ANDINFORMATION TO BE INCLUDED IN EIA/EMP REPORT
A. STANDARD TERMS OF REFERENCE
1) Executive Summary
2) Introduction
i. Details of the EIA Consultant including NABET accreditation
ii. Information about the project proponent
iii. Importance and benefits of the project
3) Project Description
i. Cost of project and time of completion.
ii. Products with capacities for the proposed project.
iii. If expansion project, details of existing products with capacities and whether adequate landis available for expansion, reference of earlier EC if any.
iv. List of raw materials required and their source along with mode of transportation.
v. Other chemicals and materials required with quantities and storage capacities
vi. Details of Emission, effluents, hazardous waste generation and their management.
vii. Requirement of water, power, with source of supply, status of approval, water balance diagram,man-power requirement (regular and contract)
viii. Process description along with major equipments and machineries, process flow sheet(quantative) from raw material to products to be provided
ix. Hazard identification and details of proposed safety systems.
x. Expansion/modernization proposals:
c. Copy of all the Environmental Clearance(s) including Amendments thereto obtained forthe project from MOEF/SEIAA shall be attached as an Annexure. A certified copy of thelatest Monitoring Report of the Regional Office of the Ministry of Environment and Forestsas per circular dated 30th May, 2012 on the status of compliance of conditions stipulatedin all the existing environmental clearances including Amendments shall be provided. In
A-115
STANDARD TERMS OF REFERENCE (TOR) FOR EIA/EMP REPORT FORPROJECTS/ACTIVITIES REQUIRING ENVIRONMENT CLEARANCE
addition, status of compliance of Consent to Operate for the ongoing Iexisting operationof the project from SPCB shall be attached with the EIA-EMP report.
d. In case the existing project has not obtained environmental clearance, reasons for nottaking EC under the provisions of the EIA Notification 1994 and/or EIA Notification2006 shall be provided. Copies of Consent to Establish/No Objection Certificate andConsent to Operate (in case of units operating prior to EIA Notification 2006, CTE andCTO of FY 2005-2006) obtained from the SPCB shall be submitted. Further, compliancereport to the conditions of consents from the SPCB shall be submitted.
4) Site Details
i. Location of the project site covering village, Taluka/Tehsil, District and State, Justificationfor selecting the site, whether other sites were considered.
ii. A toposheet of the study area of radius of 10km and site location on 1:50,000/1:25,000 scaleon an A3/A2 sheet. (including all eco-sensitive areas and environmentally sensitive places)
iii. Details w.r.t. option analysis for selection of site
iv. Co-ordinates (lat-long) of all four corners of the site.
v. Google map-Earth downloaded of the project site.
vi. Layout maps indicating existing unit as well as proposed unit indicating storage area, plantarea, greenbelt area, utilities etc. If located within an Industrial area/Estate/Complex, layoutof Industrial Area indicating location of unit within the Industrial area/Estate.
vii. Photographs of the proposed and existing (if applicable) plant site. If existing, showphotographs of plantation/greenbelt, in particular.
viii. Landuse break-up of total land of the project site (identified and acquired), government/private - agricultural, forest, wasteland, water bodies, settlements, etc shall be included. (notrequired for industrial area)
ix. A list of major industries with name and type within study area (10km radius) shall beincorporated. Land use details of the study area
x. Geological features and Geo-hydrological status of the study area shall be included.
xi. Details of Drainage of the project upto 5km radius of study area. If the site is within 1 kmradius of any major river, peak and lean season river discharge as well as flood occurrencefrequency based on peak rainfall data of the past 30 years. Details of Flood Level of theproject site and maximum Flood Level of the river shall also be provided. (mega green fieldprojects)
xii. Status of acquisition of land. If acquisition is not complete, stage of the acquisition processand expected time of complete possession of the land.
xiii. R&R details in respect of land in line with state Government policy.
A-116
STANDARD TERMS OF REFERENCE (TOR) FOR EIA/EMP REPORT FOR PROJECTS/ACTIVITIES REQUIRING ENVIRONMENT CLEARANCE
5) Forest and wildlife related issues (if applicable):
i. Permission and approval for the use of forest land (forestry clearance), if any, andrecommendations of the State Forest Department. (if applicable)
ii. Landuse map based on High resolution satellite imagery (GPS) of the proposed site delineatingthe forestland (in case of projects involving forest land more than 40 ha)
iii. Status of Application submitted for obtaining the stage I forestry clearance along with lateststatus shall be submitted.
iv. The projects to be located within 10 km of the National Parks, Sanctuaries, Biosphere Reserves,Migratory Corridors of Wild Animals, the project proponent shall submit the map dulyauthenticated by Chief Wildlife Warden showing these features vis-à-vis the project locationand the recommendations or comments of the Chief Wildlife Warden-thereon.
v. Wildlife Conservation Plan duly authenticated by the Chief Wildlife Warden of the StateGovernment for conservation of Schedule I fauna, if any exists in the study area.
vi. Copy of application submitted for clearance under the Wildlife (Protection) Act, 1972, to theStanding Committee of the National Board for Wildlife.
6) Environmental Status
i. Determination of atmospheric inversion level at the project site and site-specific micro-meteorological data using temperature, relative humidity, hourly wind speed and directionand rainfall.
ii. AAQ data (except monsoon) at 8 locations for PM10, PM2.5, SO2, NOX, CO and otherparameters relevant to the project shall be collected. The monitoring stations shall be basedCPCB guidelines and take into account the pre-dominant wind direction, population zoneand sensitive receptors including reserved forests.
iii. Raw data of all AAQ measurement for 12 weeks of all stations as per frequency given in theNAQQM Notification of Nov. 2009 along with - min., max., average and 98% values foreach of the AAQ parameters from data of all AAQ stations should be provided as an annexureto the EIA Report.
iv. Surface water quality of nearby River (100m upstream and downstream of discharge point)and other surface drains at eight locations as per CPCB/MoEF&CC guidelines.
v. Whether the site falls near to polluted stretch of river identified by the CPCB/MoEF&CC, ifyes give details.
vi. Ground water monitoring at minimum at 8 locations shall be included.
vii. Noise levels monitoring at 8 locations within the study area.
viii. Soil Characteristic as per CPCB guidelines.
ix. Traffic study of the area, type of vehicles, frequency of vehicles for transportation of materials,additional traffic due to proposed project, parking arrangement etc.
A-117
STANDARD TERMS OF REFERENCE (TOR) FOR EIA/EMP REPORT FORPROJECTS/ACTIVITIES REQUIRING ENVIRONMENT CLEARANCE
x. Detailed description of flora and fauna (terrestrial and aquatic) existing in the study areashall be given with special reference to rare, endemic and endangered species. If Schedule-I fauna are found within the study area, a Wildlife Conservation Plan shall be prepared andfurnished.
xi. Socio-economic status of the study area.
7) Impact and Environment Management Plan
i. Assessment of ground level concentration of pollutants from the stack emission based onsite-specific meteorological features. In case the project is located on a hilly terrain, theAQIP Modelling shall be done using inputs of the specific terrain characteristics fordetermining the potential impacts of the project on the AAQ. Cumulative impact of all sourcesof emissions (including transportation) on the AAQ of the area shall be assessed. Details ofthe model used and the input data used for modelling shall also be provided. The air qualitycontours shall be plotted on a location map showing the location of project site, habitationnearby, sensitive receptors, if any.
ii. Water Quality modelling - in case of discharge in water body
iii. Impact of the transport of the raw materials and end products on the surrounding environmenthall be assessed and provided. In this regard, options for transport of raw materials andfinished products and wastes (large quantities) by rail or rail-cum road transport or conveyor-cum-rail transport shall be examined.
iv. A note on treatment of wastewater from different plant operations, extent recycled and reusedfor different purposes shall be included. Complete scheme of effluent treatment. Characteristicsof untreated and treated effluent to meet the prescribed standards of discharge under E(P)Rules.
v. Details of stack emission and action plan for control of emissions to meet standards.
vi. Measures for fugitive emission control
vii. Details of hazardous waste generation and their storage, utilization and management. Copiesof MOU regarding utilization of solid and hazardous waste in cement plant shall also beincluded. EMP shall include the concept of waste-minimization, recycle/reuse/recovertechniques, Energy conservation, and natural resource conservation.
viii. Proper utilization of fly ash shall be ensured as per Fly Ash Notification, 2009. A detailedplan of action shall be provided.
ix. Action plan for the green belt development plan in 33 % area i.e. land with not less than1,500 trees per ha. Giving details of species, width of plantation, planning schedule etc. shallbe included. The green belt shall be around the project boundary and a scheme for greeningof the roads used for the project shall also be incorporated.
x. Action plan for rainwater harvesting measures at plant site shall be submitted to harvestrainwater from the roof tops and storm water drains to recharge the ground water and also to
A-118
STANDARD TERMS OF REFERENCE (TOR) FOR EIA/EMP REPORT FOR PROJECTS/ACTIVITIES REQUIRING ENVIRONMENT CLEARANCE
use for the various activities at the project site to conserve fresh water and reduce the waterrequirement from other sources.
xi. Total capital cost and recurring cost/annum for environmental pollution control measuresshall be included.
xii. Action plan for post-project environmental monitoring shall be submitted.
xiii. Onsite and Offsite Disaster (natural and Man-made) Preparedness and Emergency ManagementPlan including Risk Assessment and damage control. Disaster management plan should belinked with District Disaster Management Plan.
8) Occupational health
i. Plan and fund allocation to ensure the occupational health & safety of all contract and casualworkers
ii. Details of exposure specific health status evaluation of worker. If the workers' health is beingevaluated by pre designed format, chest x rays, Audiometry, Spirometry, Vision testing (Far& Near vision, colour vision and any other ocular defect) ECG, during pre placement andperiodical examinations give the details of the same. Details regarding last month analyzeddata of above mentioned parameters as per age, sex, duration of exposure and departmentwise.
iii. Details of existing Occupational & Safety Hazards. What are the exposure levels of hazardsand whether they are within Permissible Exposure level (PEL). If these are not within PEL,what measures the company has adopted to keep them within PEL so that health of the workerscan be preserved,
iv. Annual report of heath status of workers with special reference to Occupational Health andSafety.
9) Corporate Environment Policy
i. Does the company have a well laid down Environment Policy approved by its Board ofDirectors? If so, it may be detailed in the EIA report.
ii. Does the Environment Policy prescribe for standard operating process / procedures to bringinto focus any infringement / deviation / violation of the environmental or forest norms /conditions? If so, it may be detailed in the EIA.
iii. What is the hierarchical system or Administrative order of the company to deal with theenvironmental issues and for ensuring compliance with the environmental clearanceconditions? Details of this system may be given.
iv. Does the company have system of reporting of non compliances / violations of environmentalnorms to the Board of Directors of the company and / or shareholders or stakeholders atlarge? This reporting mechanism shall be detailed in the EIA report
A-119
STANDARD TERMS OF REFERENCE (TOR) FOR EIA/EMP REPORT FORPROJECTS/ACTIVITIES REQUIRING ENVIRONMENT CLEARANCE
10) Details regarding infrastructure facilities such as sanitation, fuel, restroom etc. to be provided to thelabour force during construction as well as to the casual workers including truck drivers duringoperation phase.
11) Enterprise Social Commitment (ESC)
i. Adequate funds (at least 2.5 % of the project cost) shall be earmarked towards the EnterpriseSocial Commitment based on Public Hearing issues and item-wise details along with timebound action plan shall be included. Socio-economic development activities need to beelaborated upon.
12) Any litigation pending against the project and/or any direction/order passed by any Court of Lawagainst the project, if so, details thereof shall also be included. Has the unit received any noticeunder the Section 5 of Environment (Protection) Act, 1986 or relevant Sections of Air and WaterActs? If so, details thereof and compliance/ATR to the notice(s) and present status of the case.
13) 'A tabular chart with index for point wise compliance of above TOR.
B. SPECIFIC TERMS OF REFERENCEFOREIASTUDIES FOR SYNTHETICORGANIC CHEMICALS INDUSTRY (DYES & DYE INTERMEDIATES;BULK DRUGS AND INTERMEDIATES EXCLUDING DRUGFORMULATIONS; SYNTHETIC RUBBERS; BASIC ORGANICCHEMICALS, OTHER SYNTHETIC ORGANIC CHEMICALS ANDCHEMICAL INTERMEDIATES)
1. Detailsonsolvents to be used,measuresfor solventrecovery and for emissions control.
2. Details of process emissions from the proposed unit and its arrangement to control.
3. Ambient air quality data should include VOC, otherprocess-specificpollutants* like NH3*, chlorine*,HCl*, HBr*, H2S*, HF*,etc.,(*-asapplicable)
4. Work zone monitoring arrangements for hazardous chemicals.
5. Detailed effluent treatment scheme including ssegregation of effluent streams for units adopting'Zero' liquid discharge.
6. Action plan for odour control to be submitted.
7. A copy of the Memorandum of Understanding signed with cement manufacturers indicating clearlythat they co-process organic solid/hazardous waste generated.
8. Authorization/Membership for the disposal of liquid effluent in CETP and solid/hazardous waste inTSDF, if any.
9. Action plan for utilization of MEE/dryers salts.
10. Material Safety Data Sheet for all the Chemicals are being used/will be used.
11. Authorization/Membership for the disposal of solid/hazardous waste in TSDF.
A-120
STANDARD TERMS OF REFERENCE (TOR) FOR EIA/EMP REPORT FOR PROJECTS/ACTIVITIES REQUIRING ENVIRONMENT CLEARANCE
12. Details of incinerator if to be installed.
13. Risk assessment for storage and handling of hazardous chemicals/solvents. Action plan for handling& safety system to be incorporated.
14. Arrangements for ensuring health and safety of workers engaged in handling of toxic materials.
***
A-121
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A-144
Hourly Meteorological data
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 01.10.18 0:00 31.0 80.0 180 9.7 0
2018 01.10.18 1:00 32.6 76.0 171 10.2 0
2018 01.10.18 2:00 34.1 72.0 162 10.7 0
2018 01.10.18 3:00 28.0 80.0 45 0.0 0
2018 01.10.18 4:00 29.4 76.0 43 0.0 0
2018 01.10.18 5:00 30.8 72.0 41 0.0 0
2018 01.10.18 6:00 28.0 77.0 90 3.9 0
2018 01.10.18 7:00 29.4 73.2 86 4.1 0
2018 01.10.18 8:00 30.8 69.3 81 4.3 0
2018 01.10.18 9:00 31.0 70.0 113 15.5 0
2018 01.10.18 10:00 32.6 66.5 107 16.3 0
2018 01.10.18 11:00 34.1 63.0 101 17.1 0
2018 01.10.18 12:00 33.0 59.0 113 21.4 0
2018 01.10.18 13:00 34.7 62.0 118 22.5 0
2018 01.10.18 14:00 36.3 64.9 124 23.5 0
2018 01.10.18 15:00 36.0 51.0 113 19.4 0
2018 01.10.18 16:00 34.2 53.6 118 18.4 0
2018 01.10.18 17:00 32.4 56.1 124 17.5 0
2018 01.10.18 18:00 34.0 58.0 90 15.5 0
2018 01.10.18 19:00 32.3 60.9 95 14.7 0
2018 01.10.18 20:00 30.6 63.8 99 14.0 0
2018 01.10.18 21:00 31.0 65.0 68 11.7 0
2018 01.10.18 22:00 29.5 68.3 71 11.1 0
2018 01.10.18 23:00 27.9 71.5 74 10.5 0
2018 02.10.18 0:00 29.0 72.0 45 3.9 0
2018 02.10.18 1:00 30.5 68.4 43 4.1 0
2018 02.10.18 2:00 31.9 64.8 41 4.3 0
2018 02.10.18 3:00 27.0 80.0 180 9.7 0
2018 02.10.18 4:00 28.4 76.0 171 10.2 0
2018 02.10.18 5:00 29.7 72.0 162 10.7 0
2018 02.10.18 6:00 29.0 78.0 180 9.7 0
2018 02.10.18 7:00 30.5 74.1 171 10.2 0
2018 02.10.18 8:00 31.9 70.2 162 10.7 0
2018 02.10.18 9:00 33.0 64.0 68 9.7 0
2018 02.10.18 10:00 34.7 67.2 64 10.2 0
2018 02.10.18 11:00 36.3 70.4 61 10.7 0
2018 02.10.18 12:00 37.0 50.0 158 3.9 0
2018 02.10.18 13:00 35.2 52.5 165 4.1 0
2018 02.10.18 14:00 33.3 55.0 173 4.3 0
2018 02.10.18 15:00 38.0 46.0 68 0.0 0
2018 02.10.18 16:00 36.1 48.3 71 0.0 0
2018 02.10.18 17:00 34.2 50.6 74 0.0 0
2018 02.10.18 18:00 36.0 53.0 248 0.0 0
2018 02.10.18 19:00 34.2 55.7 260 0.0 0
2018 02.10.18 20:00 32.4 58.3 272 0.0 0
2018 02.10.18 21:00 32.0 66.0 360 13.7 0
2018 02.10.18 22:00 33.6 62.7 378 13.0 0
A-153
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 02.10.18 23:00 35.2 59.4 396 12.3 0
2018 03.10.18 0:00 30.0 76.0 360 13.7 0
2018 03.10.18 1:00 31.5 72.2 342 14.4 0
2018 03.10.18 2:00 33.0 68.4 324 15.1 0
2018 03.10.18 3:00 29.0 80.0 180 9.7 0
2018 03.10.18 4:00 30.5 76.0 171 10.2 0
2018 03.10.18 5:00 31.9 72.0 162 10.7 0
2018 03.10.18 6:00 30.0 79.0 180 9.7 0
2018 03.10.18 7:00 31.5 83.0 171 10.2 0
2018 03.10.18 8:00 33.0 86.9 162 10.7 0
2018 03.10.18 9:00 34.0 67.0 68 3.9 0
2018 03.10.18 10:00 32.3 70.4 64 4.1 0
2018 03.10.18 11:00 30.6 73.7 61 4.3 0
2018 03.10.18 12:00 37.0 51.0 135 0.0 0
2018 03.10.18 13:00 35.2 53.6 142 0.0 0
2018 03.10.18 14:00 33.3 56.1 149 0.0 0
2018 03.10.18 15:00 38.0 49.0 135 0.0 0
2018 03.10.18 16:00 36.1 51.5 142 0.0 0
2018 03.10.18 17:00 34.2 53.9 149 0.0 0
2018 03.10.18 18:00 36.0 62.0 45 13.7 0
2018 03.10.18 19:00 37.8 58.9 47 13.0 0
2018 03.10.18 20:00 39.6 55.8 50 12.3 0
2018 03.10.18 21:00 32.0 76.0 45 13.7 0
2018 03.10.18 22:00 33.6 72.2 47 13.0 0
2018 03.10.18 23:00 35.2 68.4 50 12.3 0
2018 04.10.18 0:00 30.0 77.0 45 11.7 0
2018 04.10.18 1:00 31.5 73.2 43 12.3 0
2018 04.10.18 2:00 33.0 69.3 41 12.9 0
2018 04.10.18 3:00 29.0 77.0 45 9.7 0
2018 04.10.18 4:00 30.5 73.2 43 10.2 0
2018 04.10.18 5:00 31.9 69.3 41 10.7 0
2018 04.10.18 6:00 30.0 79.0 360 11.7 0
2018 04.10.18 7:00 28.5 83.0 342 12.3 0
2018 04.10.18 8:00 27.0 86.9 324 12.9 0
2018 04.10.18 9:00 32.0 73.0 360 11.7 0
2018 04.10.18 10:00 30.4 76.7 342 12.3 0
2018 04.10.18 11:00 28.8 80.3 324 12.9 0
2018 04.10.18 12:00 35.0 61.0 45 3.9 0
2018 04.10.18 13:00 33.3 64.1 47 4.1 0
2018 04.10.18 14:00 31.5 67.1 50 4.3 0
2018 04.10.18 15:00 35.0 60.0 45 9.7 0
2018 04.10.18 16:00 36.8 63.0 47 9.2 0
2018 04.10.18 17:00 38.5 66.0 50 8.7 0
2018 04.10.18 18:00 32.0 71.0 45 11.7 0
2018 04.10.18 19:00 33.6 67.5 47 11.1 0
2018 04.10.18 20:00 35.2 63.9 50 10.5 0
2018 04.10.18 21:00 30.0 78.0 180 9.7 0
2018 04.10.18 22:00 31.5 74.1 189 9.2 0
2018 04.10.18 23:00 33.0 70.2 198 8.7 0
A-154
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 05.10.18 0:00 28.0 82.0 180 9.7 0
2018 05.10.18 1:00 29.4 77.9 171 10.2 0
2018 05.10.18 2:00 30.8 73.8 162 10.7 0
2018 05.10.18 3:00 27.0 84.0 338 13.7 0
2018 05.10.18 4:00 25.7 88.2 321 14.4 0
2018 05.10.18 5:00 24.3 92.4 304 15.1 0
2018 05.10.18 6:00 27.0 84.0 338 15.5 0
2018 05.10.18 7:00 25.7 88.2 321 16.3 0
2018 05.10.18 8:00 24.3 92.4 304 17.1 0
2018 05.10.18 9:00 31.0 71.0 338 17.5 0
2018 05.10.18 10:00 29.5 74.6 321 18.4 0
2018 05.10.18 11:00 27.9 78.1 304 19.3 0
2018 05.10.18 12:00 35.0 55.0 360 19.4 0
2018 05.10.18 13:00 36.8 57.8 378 20.4 0
2018 05.10.18 14:00 38.5 60.5 396 21.3 0
2018 05.10.18 15:00 35.0 57.0 180 21.4 0
2018 05.10.18 16:00 36.8 54.2 189 20.3 0
2018 05.10.18 17:00 38.5 51.3 198 19.3 0
2018 05.10.18 18:00 31.0 72.0 180 17.5 0
2018 05.10.18 19:00 32.6 68.4 189 16.6 0
2018 05.10.18 20:00 34.1 64.8 198 15.8 0
2018 05.10.18 21:00 28.0 83.0 360 11.7 0
2018 05.10.18 22:00 29.4 78.9 378 11.1 0
2018 05.10.18 23:00 30.8 74.7 396 10.5 0
2018 06.10.18 0:00 28.0 83.0 338 11.7 0
2018 06.10.18 1:00 26.6 87.2 321 12.3 0
2018 06.10.18 2:00 25.2 91.3 304 12.9 0
2018 06.10.18 3:00 28.0 81.0 360 3.9 0
2018 06.10.18 4:00 26.6 85.1 342 4.1 0
2018 06.10.18 5:00 25.2 89.1 324 4.3 0
2018 06.10.18 6:00 29.0 80.0 360 3.9 0
2018 06.10.18 7:00 27.6 84.0 342 4.1 0
2018 06.10.18 8:00 26.1 88.0 324 6.4 0
2018 06.10.18 9:00 33.0 68.0 360 11.7 0
2018 06.10.18 10:00 34.7 71.4 342 12.3 0
2018 06.10.18 11:00 36.3 74.8 324 12.9 0
2018 06.10.18 12:00 35.0 57.0 180 17.5 0
2018 06.10.18 13:00 36.8 54.2 189 18.4 0
2018 06.10.18 14:00 38.5 51.3 198 19.3 0
2018 06.10.18 15:00 34.0 60.0 45 21.4 0
2018 06.10.18 16:00 35.7 57.0 47 20.3 0
2018 06.10.18 17:00 37.4 54.0 50 19.3 0
2018 06.10.18 18:00 31.0 72.0 180 17.5 0
2018 06.10.18 19:00 32.6 68.4 189 16.6 0
2018 06.10.18 20:00 34.1 64.8 198 15.8 0
2018 06.10.18 21:00 28.0 80.0 360 17.5 0
2018 06.10.18 22:00 26.6 76.0 378 16.6 0
2018 06.10.18 23:00 25.2 72.0 297 15.8 0
2018 07.10.18 0:00 28.0 81.0 338 15.5 0
A-155
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 07.10.18 1:00 26.6 85.1 321 16.3 0
2018 07.10.18 2:00 25.2 89.1 304 17.1 0
2018 07.10.18 3:00 27.0 84.0 338 15.5 0
2018 07.10.18 4:00 25.7 88.2 321 16.3 0
2018 07.10.18 5:00 24.3 92.4 304 17.1 0
2018 07.10.18 6:00 28.0 84.0 338 17.5 0
2018 07.10.18 7:00 29.4 88.2 321 18.4 0
2018 07.10.18 8:00 30.8 92.4 304 19.3 0
2018 07.10.18 9:00 32.0 73.0 338 15.5 0
2018 07.10.18 10:00 33.6 76.7 321 16.3 0
2018 07.10.18 11:00 35.2 80.3 304 17.1 0
2018 07.10.18 12:00 35.0 59.0 270 9.7 0
2018 07.10.18 13:00 36.8 56.1 284 10.2 0
2018 07.10.18 14:00 38.5 53.1 297 10.7 0
2018 07.10.18 15:00 35.0 60.0 45 9.7 0
2018 07.10.18 16:00 36.8 57.0 47 9.2 0
2018 07.10.18 17:00 38.5 54.0 50 8.7 0
2018 07.10.18 18:00 32.0 73.0 45 11.7 0
2018 07.10.18 19:00 30.4 69.4 47 11.1 0
2018 07.10.18 20:00 28.8 65.7 50 10.5 0
2018 07.10.18 21:00 29.0 82.0 180 13.7 0
2018 07.10.18 22:00 27.6 86.1 189 13.0 0
2018 07.10.18 23:00 26.1 90.2 198 12.3 0
2018 08.10.18 0:00 28.0 84.0 270 13.7 0
2018 08.10.18 1:00 26.6 88.2 257 14.4 0
2018 08.10.18 2:00 25.2 92.4 243 15.1 0
2018 08.10.18 3:00 27.0 84.0 338 11.7 0
2018 08.10.18 4:00 28.4 88.2 321 12.3 0
2018 08.10.18 5:00 29.7 92.4 304 12.9 0
2018 08.10.18 6:00 28.0 84.0 270 11.7 0
2018 08.10.18 7:00 29.4 88.2 257 12.3 0
2018 08.10.18 8:00 30.8 92.4 243 12.9 0
2018 08.10.18 9:00 32.0 71.0 270 9.7 0
2018 08.10.18 10:00 33.6 67.5 257 10.2 0
2018 08.10.18 11:00 35.2 63.9 243 10.7 0
2018 08.10.18 12:00 36.0 53.0 338 0.0 0
2018 08.10.18 13:00 37.8 50.4 354 0.0 0
2018 08.10.18 14:00 39.6 47.7 371 0.0 0
2018 08.10.18 15:00 37.0 47.0 293 0.0 0
2018 08.10.18 16:00 35.2 44.7 307 0.0 0
2018 08.10.18 17:00 33.3 42.3 322 0.0 0
2018 08.10.18 18:00 34.0 61.0 270 9.7 0
2018 08.10.18 19:00 32.3 64.1 284 9.2 0
2018 08.10.18 20:00 30.6 67.1 297 8.7 0
2018 08.10.18 21:00 29.0 79.0 270 15.5 0
2018 08.10.18 22:00 27.6 83.0 284 14.7 0
2018 08.10.18 23:00 26.1 86.9 297 14.0 0
2018 09.10.18 0:00 29.0 82.0 270 13.7 0
2018 09.10.18 1:00 30.5 86.1 257 14.4 0
A-156
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 09.10.18 2:00 31.9 90.2 243 15.1 0
2018 09.10.18 3:00 28.0 84.0 270 13.7 0
2018 09.10.18 4:00 29.4 88.2 257 14.4 0
2018 09.10.18 5:00 30.8 92.4 243 15.1 0
2018 09.10.18 6:00 29.0 84.0 270 11.7 0
2018 09.10.18 7:00 30.5 79.8 257 12.3 0
2018 09.10.18 8:00 31.9 75.6 243 12.9 0
2018 09.10.18 9:00 34.0 68.0 45 11.7 0
2018 09.10.18 10:00 35.7 64.6 43 12.3 0
2018 09.10.18 11:00 37.4 61.2 41 12.9 0
2018 09.10.18 12:00 37.0 50.0 68 11.7 0
2018 09.10.18 13:00 35.2 47.5 71 12.3 0
2018 09.10.18 14:00 33.3 45.0 74 12.9 0
2018 09.10.18 15:00 38.0 49.0 68 13.7 0
2018 09.10.18 16:00 36.1 46.6 71 13.0 0
2018 09.10.18 17:00 34.2 44.1 74 12.3 0
2018 09.10.18 18:00 35.0 64.0 270 15.5 0
2018 09.10.18 19:00 33.3 67.2 284 14.7 0
2018 09.10.18 20:00 31.5 70.4 297 14.0 0
2018 09.10.18 21:00 31.0 80.0 270 15.5 0
2018 09.10.18 22:00 32.6 84.0 284 14.7 0
2018 09.10.18 23:00 34.1 88.0 297 14.0 0
2018 10.10.18 0:00 29.0 81.0 270 15.5 0
2018 10.10.18 1:00 30.5 85.1 257 16.3 0
2018 10.10.18 2:00 31.9 89.1 243 17.1 0
2018 10.10.18 3:00 29.0 83.0 270 9.7 0
2018 10.10.18 4:00 30.5 87.2 257 10.2 0
2018 10.10.18 5:00 31.9 91.3 243 10.7 0
2018 10.10.18 6:00 31.0 77.0 45 5.8 0
2018 10.10.18 7:00 32.6 73.2 257 6.1 0
2018 10.10.18 8:00 34.1 69.3 243 6.4 0
2018 10.10.18 9:00 35.0 60.0 68 9.7 0
2018 10.10.18 10:00 33.3 57.0 64 10.2 0
2018 10.10.18 11:00 31.5 54.0 61 10.7 0
2018 10.10.18 12:00 37.0 45.0 68 15.5 0
2018 10.10.18 13:00 35.2 42.8 71 16.3 0
2018 10.10.18 14:00 33.3 40.5 74 17.1 0
2018 10.10.18 15:00 37.0 46.0 270 17.5 0
2018 10.10.18 16:00 35.2 48.3 284 16.6 0
2018 10.10.18 17:00 33.3 50.6 297 15.8 0
2018 10.10.18 18:00 34.0 62.0 270 15.5 0
2018 10.10.18 19:00 35.7 65.1 284 14.7 0
2018 10.10.18 20:00 37.4 68.2 297 14.0 0
2018 10.10.18 21:00 29.0 77.0 270 17.5 0
2018 10.10.18 22:00 30.5 80.9 284 16.6 0
2018 10.10.18 23:00 31.9 84.7 297 15.8 0
2018 11.10.18 0:00 29.0 81.0 360 13.7 0
2018 11.10.18 1:00 30.5 85.1 342 14.4 0
2018 11.10.18 2:00 31.9 89.1 324 15.1 0
A-157
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 11.10.18 3:00 30.0 84.0 270 5.8 0
2018 11.10.18 4:00 31.5 79.8 257 6.1 0
2018 11.10.18 5:00 33.0 75.6 243 6.4 0
2018 11.10.18 6:00 30.0 81.0 68 0.0 0
2018 11.10.18 7:00 28.5 77.0 64 0.0 0
2018 11.10.18 8:00 27.0 72.9 61 0.0 0
2018 11.10.18 9:00 34.0 62.0 90 5.8 0
2018 11.10.18 10:00 32.3 58.9 86 6.1 0
2018 11.10.18 11:00 30.6 55.8 81 6.4 0
2018 11.10.18 12:00 37.0 45.0 90 11.7 0
2018 11.10.18 13:00 35.2 47.3 95 12.3 0
2018 11.10.18 14:00 33.3 49.5 99 12.9 0
2018 11.10.18 15:00 38.0 41.0 68 11.7 0
2018 11.10.18 16:00 39.9 43.1 71 11.1 0
2018 11.10.18 17:00 41.8 45.1 74 10.5 0
2018 11.10.18 18:00 37.0 52.0 270 11.7 0
2018 11.10.18 19:00 38.9 54.6 284 11.1 0
2018 11.10.18 20:00 40.7 57.2 297 10.5 0
2018 11.10.18 21:00 32.0 65.0 270 13.7 0
2018 11.10.18 22:00 33.6 68.3 284 13.0 0
2018 11.10.18 23:00 35.2 71.5 297 12.3 0
2018 12.10.18 0:00 28.0 77.0 360 11.7 0
2018 12.10.18 1:00 29.4 73.2 342 12.3 0
2018 12.10.18 2:00 30.8 69.3 324 12.9 0
2018 12.10.18 3:00 26.0 87.0 360 11.7 0
2018 12.10.18 4:00 24.7 82.7 342 12.3 0
2018 12.10.18 5:00 23.4 78.3 324 12.9 0
2018 12.10.18 6:00 28.0 84.0 270 5.8 0
2018 12.10.18 7:00 26.6 79.8 257 6.1 0
2018 12.10.18 8:00 25.2 75.6 243 6.4 0
2018 12.10.18 9:00 33.0 65.0 270 5.8 0
2018 12.10.18 10:00 31.4 61.8 257 6.1 0
2018 12.10.18 11:00 29.7 58.5 243 6.4 0
2018 12.10.18 12:00 36.0 46.0 68 9.7 0
2018 12.10.18 13:00 37.8 48.3 71 10.2 0
2018 12.10.18 14:00 39.6 50.6 74 10.7 0
2018 12.10.18 15:00 37.0 42.0 270 13.7 0
2018 12.10.18 16:00 38.9 44.1 284 13.0 0
2018 12.10.18 17:00 40.7 46.2 297 12.3 0
2018 12.10.18 18:00 35.0 55.0 270 11.7 0
2018 12.10.18 19:00 36.8 57.8 284 11.1 0
2018 12.10.18 20:00 38.5 60.5 297 10.5 0
2018 12.10.18 21:00 31.0 68.0 270 11.7 0
2018 12.10.18 22:00 32.6 71.4 284 11.1 0
2018 12.10.18 23:00 34.1 74.8 297 10.5 0
2018 13.10.18 0:00 28.0 76.0 360 13.7 0
2018 13.10.18 1:00 26.6 72.2 342 14.4 0
2018 13.10.18 2:00 25.2 68.4 324 15.1 0
2018 13.10.18 3:00 27.0 84.0 360 13.7 0
A-158
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 13.10.18 4:00 25.7 79.8 342 14.4 0
2018 13.10.18 5:00 24.3 75.6 324 15.1 0
2018 13.10.18 6:00 28.0 82.0 270 5.8 0
2018 13.10.18 7:00 26.6 77.9 257 6.1 0
2018 13.10.18 8:00 25.2 73.8 243 6.4 0
2018 13.10.18 9:00 33.0 64.0 68 0.0 0
2018 13.10.18 10:00 34.7 67.2 64 0.0 0
2018 13.10.18 11:00 36.3 70.4 61 0.0 0
2018 13.10.18 12:00 36.0 44.0 90 0.0 0
2018 13.10.18 13:00 37.8 46.2 95 0.0 0
2018 13.10.18 14:00 39.6 48.4 99 0.0 0
2018 13.10.18 15:00 37.0 40.0 68 0.0 0
2018 13.10.18 16:00 38.9 42.0 71 0.0 0
2018 13.10.18 17:00 40.7 44.0 74 0.0 0
2018 13.10.18 18:00 34.0 51.0 360 0.0 0
2018 13.10.18 19:00 35.7 53.6 378 0.0 0
2018 13.10.18 20:00 37.4 56.1 396 0.0 0
2018 13.10.18 21:00 31.0 58.0 270 5.8 0
2018 13.10.18 22:00 32.6 55.1 284 5.5 0
2018 13.10.18 23:00 34.1 52.2 297 5.2 0
2018 14.10.18 0:00 28.0 60.0 270 9.7 0
2018 14.10.18 1:00 26.6 57.0 257 10.2 0
2018 14.10.18 2:00 25.2 54.0 243 10.7 0
2018 14.10.18 3:00 27.0 65.0 68 9.7 0
2018 14.10.18 4:00 25.7 61.8 64 10.2 0
2018 14.10.18 5:00 24.3 58.5 61 10.7 0
2018 14.10.18 6:00 28.0 70.0 270 5.8 0
2018 14.10.18 7:00 26.6 73.5 257 6.1 0
2018 14.10.18 8:00 25.2 77.0 243 6.4 0
2018 14.10.18 9:00 33.0 54.0 203 0.0 0
2018 14.10.18 10:00 34.7 56.7 192 0.0 0
2018 14.10.18 11:00 36.3 59.4 182 0.0 0
2018 14.10.18 12:00 37.0 38.0 180 0.0 0
2018 14.10.18 13:00 38.9 39.9 189 0.0 0
2018 14.10.18 14:00 40.7 41.8 198 0.0 0
2018 14.10.18 15:00 37.0 36.0 270 5.8 0
2018 14.10.18 16:00 38.9 37.8 284 5.5 0
2018 14.10.18 17:00 40.7 39.6 297 5.2 0
2018 14.10.18 18:00 35.0 46.0 315 0.0 0
2018 14.10.18 19:00 36.8 43.7 331 0.0 0
2018 14.10.18 20:00 38.5 41.4 347 0.0 0
2018 14.10.18 21:00 32.0 52.0 270 0.0 0
2018 14.10.18 22:00 30.4 49.4 284 0.0 0
2018 14.10.18 23:00 28.8 46.8 297 0.0 0
2018 15.10.18 0:00 28.0 54.0 90 5.8 0
2018 15.10.18 1:00 26.6 51.3 86 6.1 0
2018 15.10.18 2:00 25.2 48.6 81 6.4 0
2018 15.10.18 3:00 27.0 62.0 90 0.0 0
2018 15.10.18 4:00 25.7 58.9 86 0.0 0
A-159
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 15.10.18 5:00 24.3 55.8 81 0.0 0
2018 15.10.18 6:00 28.0 59.0 315 0.0 0
2018 15.10.18 7:00 29.4 62.0 299 0.0 0
2018 15.10.18 8:00 30.8 64.9 284 0.0 0
2018 15.10.18 9:00 34.0 44.0 203 0.0 0
2018 15.10.18 10:00 35.7 46.2 192 0.0 0
2018 15.10.18 11:00 37.4 48.4 182 0.0 0
2018 15.10.18 12:00 37.0 34.0 248 0.0 0
2018 15.10.18 13:00 38.9 35.7 260 0.0 0
2018 15.10.18 14:00 40.7 37.4 272 0.0 0
2018 15.10.18 15:00 37.0 34.0 293 0.0 0
2018 15.10.18 16:00 38.9 35.7 307 0.0 0
2018 15.10.18 17:00 40.7 37.4 322 0.0 0
2018 15.10.18 18:00 36.0 44.0 360 0.0 0
2018 15.10.18 19:00 34.2 41.8 378 0.0 0
2018 15.10.18 20:00 32.4 39.6 396 0.0 0
2018 15.10.18 21:00 32.0 44.0 90 5.8 0
2018 15.10.18 22:00 30.4 41.8 95 5.5 0
2018 15.10.18 23:00 28.8 39.6 99 5.2 0
2018 16.10.18 0:00 29.0 42.0 360 5.8 0
2018 16.10.18 1:00 27.6 39.9 342 6.1 0
2018 16.10.18 2:00 26.1 37.8 324 8.5 0
2018 16.10.18 3:00 28.0 41.0 293 0.0 0
2018 16.10.18 4:00 29.4 43.1 278 0.0 0
2018 16.10.18 5:00 30.8 45.1 263 0.0 0
2018 16.10.18 6:00 29.0 41.0 158 0.0 0
2018 16.10.18 7:00 30.5 43.1 150 0.0 0
2018 16.10.18 8:00 31.9 45.1 142 0.0 0
2018 16.10.18 9:00 34.0 35.0 135 0.0 0
2018 16.10.18 10:00 35.7 36.8 128 0.0 0
2018 16.10.18 11:00 37.4 38.5 122 0.0 0
2018 16.10.18 12:00 38.0 28.0 68 0.0 0
2018 16.10.18 13:00 39.9 29.4 71 0.0 0
2018 16.10.18 14:00 41.8 30.8 74 0.0 0
2018 16.10.18 15:00 38.0 31.0 315 0.0 0
2018 16.10.18 16:00 36.1 29.5 331 0.0 0
2018 16.10.18 17:00 34.2 27.9 347 0.0 0
2018 16.10.18 18:00 36.0 41.0 270 0.0 0
2018 16.10.18 19:00 34.2 39.0 284 0.0 0
2018 16.10.18 20:00 32.4 36.9 297 0.0 0
2018 16.10.18 21:00 32.0 36.0 90 9.7 0
2018 16.10.18 22:00 30.4 34.2 95 9.2 0
2018 16.10.18 23:00 28.8 32.4 99 8.7 0
2018 17.10.18 0:00 29.0 37.0 113 9.7 0
2018 17.10.18 1:00 30.5 38.9 107 10.2 0
2018 17.10.18 2:00 31.9 40.7 101 10.7 0
2018 17.10.18 3:00 28.0 44.0 158 7.7 0
2018 17.10.18 4:00 29.4 46.2 150 8.1 0
2018 17.10.18 5:00 30.8 48.4 142 8.5 0
A-160
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 17.10.18 6:00 28.0 44.0 68 7.7 0
2018 17.10.18 7:00 29.4 46.2 64 8.1 0
2018 17.10.18 8:00 30.8 48.4 61 8.5 0
2018 17.10.18 9:00 34.0 38.0 203 7.7 0
2018 17.10.18 10:00 35.7 39.9 192 8.1 0
2018 17.10.18 11:00 37.4 41.8 182 8.5 0
2018 17.10.18 12:00 37.0 30.0 180 11.7 0
2018 17.10.18 13:00 35.2 28.5 189 12.3 0
2018 17.10.18 14:00 33.3 27.0 198 12.9 0
2018 17.10.18 15:00 38.0 30.0 180 9.7 0
2018 17.10.18 16:00 36.1 28.5 189 9.2 0
2018 17.10.18 17:00 34.2 27.0 198 8.7 0
2018 17.10.18 18:00 36.0 39.0 203 7.7 0
2018 17.10.18 19:00 34.2 37.1 213 7.3 0
2018 17.10.18 20:00 32.4 35.1 223 6.9 0
2018 17.10.18 21:00 34.0 43.0 293 0.0 0
2018 17.10.18 22:00 35.7 40.9 307 0.0 0
2018 17.10.18 23:00 37.4 38.7 322 0.0 0
2018 18.10.18 0:00 30.0 47.0 113 0.0 0
2018 18.10.18 1:00 31.5 49.4 107 0.0 0
2018 18.10.18 2:00 33.0 51.7 101 0.0 0
2018 18.10.18 3:00 27.0 46.0 270 9.7 0
2018 18.10.18 4:00 28.4 48.3 257 10.2 0
2018 18.10.18 5:00 29.7 50.6 243 10.7 0
2018 18.10.18 6:00 28.0 47.0 68 0.0 0
2018 18.10.18 7:00 29.4 49.4 64 0.0 0
2018 18.10.18 8:00 30.8 51.7 61 0.0 0
2018 18.10.18 9:00 34.0 36.0 338 0.0 0
2018 18.10.18 10:00 32.3 37.8 321 0.0 0
2018 18.10.18 11:00 30.6 39.6 304 0.0 0
2018 18.10.18 12:00 37.0 29.0 158 7.7 0
2018 18.10.18 13:00 35.2 27.6 165 8.1 0
2018 18.10.18 14:00 33.3 26.1 173 8.5 0
2018 18.10.18 15:00 37.0 31.0 135 7.7 0
2018 18.10.18 16:00 35.2 29.5 142 7.3 0
2018 18.10.18 17:00 33.3 27.9 149 6.9 0
2018 18.10.18 18:00 35.0 42.0 90 0.0 0
2018 18.10.18 19:00 36.8 39.9 95 0.0 0
2018 18.10.18 20:00 38.5 37.8 99 0.0 0
2018 18.10.18 21:00 31.0 44.0 68 0.0 0
2018 18.10.18 22:00 32.6 46.2 71 0.0 0
2018 18.10.18 23:00 34.1 48.4 74 0.0 0
2018 19.10.18 0:00 28.0 42.0 270 7.7 0
2018 19.10.18 1:00 29.4 44.1 257 8.1 0
2018 19.10.18 2:00 30.8 46.2 243 8.5 0
2018 19.10.18 3:00 26.0 42.0 315 7.7 0
2018 19.10.18 4:00 27.3 44.1 299 8.1 0
2018 19.10.18 5:00 28.6 46.2 284 8.5 0
2018 19.10.18 6:00 28.0 42.0 270 0.0 0.5
A-161
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 19.10.18 7:00 26.6 44.1 257 0.0 0.5
2018 19.10.18 8:00 25.2 46.2 243 0.0 0.5
2018 19.10.18 9:00 34.0 33.0 293 0.0 1.6
2018 19.10.18 10:00 32.3 31.4 278 0.0 1.6
2018 19.10.18 11:00 30.6 29.7 263 0.0 1.6
2018 19.10.18 12:00 36.0 28.0 158 9.7 1.1
2018 19.10.18 13:00 34.2 26.6 165 10.2 1.1
2018 19.10.18 14:00 32.4 25.2 173 10.7 1.1
2018 19.10.18 15:00 37.0 32.0 135 7.7 0
2018 19.10.18 16:00 38.9 30.4 142 7.3 0
2018 19.10.18 17:00 40.7 28.8 149 6.9 0
2018 19.10.18 18:00 36.0 44.0 113 0.0 0
2018 19.10.18 19:00 37.8 46.2 118 0.0 0
2018 19.10.18 20:00 39.6 48.4 124 0.0 0
2018 19.10.18 21:00 32.0 45.0 113 0.0 0
2018 19.10.18 22:00 33.6 47.3 118 0.0 0
2018 19.10.18 23:00 35.2 49.5 124 0.0 0
2018 20.10.18 0:00 29.0 45.0 158 0.0 0
2018 20.10.18 1:00 30.5 47.3 150 0.0 0
2018 20.10.18 2:00 31.9 49.5 142 0.0 0
2018 20.10.18 3:00 27.0 49.0 113 0.0 0
2018 20.10.18 4:00 25.7 51.5 107 0.0 0
2018 20.10.18 5:00 24.3 53.9 101 0.0 0
2018 20.10.18 6:00 28.0 49.0 270 0.0 0
2018 20.10.18 7:00 26.6 46.6 257 0.0 0
2018 20.10.18 8:00 25.2 44.1 243 0.0 0
2018 20.10.18 9:00 33.0 36.0 293 0.0 0
2018 20.10.18 10:00 31.4 34.2 278 0.0 0
2018 20.10.18 11:00 29.7 32.4 263 0.0 0
2018 20.10.18 12:00 36.0 28.0 203 7.7 0
2018 20.10.18 13:00 37.8 26.6 213 8.1 0
2018 20.10.18 14:00 39.6 25.2 223 8.5 0
2018 20.10.18 15:00 37.0 31.0 113 0.0 0
2018 20.10.18 16:00 38.9 29.5 118 0.0 0
2018 20.10.18 17:00 40.7 27.9 124 0.0 0
2018 20.10.18 18:00 35.0 42.0 270 0.0 0
2018 20.10.18 19:00 36.8 44.1 284 0.0 0
2018 20.10.18 20:00 38.5 46.2 297 0.0 0
2018 20.10.18 21:00 30.0 45.0 315 0.0 0
2018 20.10.18 22:00 31.5 47.3 331 0.0 0
2018 20.10.18 23:00 33.0 49.5 347 0.0 0
2018 21.10.18 0:00 27.0 50.0 270 0.0 0
2018 21.10.18 1:00 25.7 52.5 257 0.0 0
2018 21.10.18 2:00 24.3 55.0 243 0.0 0
2018 21.10.18 3:00 27.0 55.0 113 9.7 0
2018 21.10.18 4:00 25.7 57.8 107 10.2 0
2018 21.10.18 5:00 24.3 60.5 101 10.7 0
2018 21.10.18 6:00 28.0 54.0 158 7.7 0
2018 21.10.18 7:00 26.6 51.3 150 8.1 0
A-162
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 21.10.18 8:00 25.2 48.6 142 8.5 0
2018 21.10.18 9:00 33.0 45.0 68 7.7 0
2018 21.10.18 10:00 34.7 42.8 64 8.1 0
2018 21.10.18 11:00 36.3 40.5 243 8.5 0
2018 21.10.18 12:00 36.0 34.0 270 0.0 0
2018 21.10.18 13:00 37.8 32.3 284 0.0 0
2018 21.10.18 14:00 39.6 30.6 297 0.0 0
2018 21.10.18 15:00 36.0 34.0 90 0.0 0
2018 21.10.18 16:00 37.8 35.7 95 0.0 0
2018 21.10.18 17:00 39.6 37.4 99 0.0 0
2018 21.10.18 18:00 34.0 44.0 270 0.0 0
2018 21.10.18 19:00 35.7 46.2 284 0.0 0
2018 21.10.18 20:00 37.4 48.4 297 0.0 0
2018 21.10.18 21:00 31.0 49.0 270 0.0 0
2018 21.10.18 22:00 29.5 51.5 284 0.0 0
2018 21.10.18 23:00 27.9 53.9 297 0.0 0
2018 22.10.18 0:00 29.0 53.0 270 0.0 0
2018 22.10.18 1:00 27.6 55.7 257 0.0 0
2018 22.10.18 2:00 26.1 58.3 243 0.0 0
2018 22.10.18 3:00 26.0 58.0 113 7.7 0
2018 22.10.18 4:00 24.7 55.1 107 8.1 0
2018 22.10.18 5:00 23.4 52.2 101 8.5 0
2018 22.10.18 6:00 28.0 60.0 135 7.7 0
2018 22.10.18 7:00 29.4 57.0 128 8.1 0
2018 22.10.18 8:00 30.8 54.0 122 8.5 0
2018 22.10.18 9:00 34.0 50.0 158 0.0 0
2018 22.10.18 10:00 35.7 47.5 150 0.0 0
2018 22.10.18 11:00 37.4 45.0 142 0.0 0
2018 22.10.18 12:00 37.0 36.0 135 0.0 0
2018 22.10.18 13:00 38.9 37.8 142 0.0 0
2018 22.10.18 14:00 40.7 39.6 149 0.0 0
2018 22.10.18 15:00 36.0 35.0 90 0.0 0
2018 22.10.18 16:00 37.8 36.8 95 0.0 0
2018 22.10.18 17:00 39.6 38.5 99 0.0 0
2018 22.10.18 18:00 34.0 45.0 270 0.0 0
2018 22.10.18 19:00 32.3 47.3 284 0.0 0
2018 22.10.18 20:00 30.6 49.5 297 0.0 0
2018 22.10.18 21:00 30.0 49.0 270 7.7 0
2018 22.10.18 22:00 28.5 51.5 284 7.3 0
2018 22.10.18 23:00 27.0 53.9 297 6.9 0
2018 23.10.18 0:00 27.0 57.0 270 7.7 0
2018 23.10.18 1:00 25.7 54.2 257 8.1 0
2018 23.10.18 2:00 24.3 51.3 243 8.5 0
2018 23.10.18 3:00 26.0 64.0 270 9.7 0
2018 23.10.18 4:00 27.3 60.8 257 10.2 0
2018 23.10.18 5:00 28.6 57.6 243 10.7 0
2018 23.10.18 6:00 27.0 66.0 113 7.7 0
2018 23.10.18 7:00 28.4 62.7 107 8.1 0
2018 23.10.18 8:00 29.7 59.4 101 8.5 0
A-163
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 23.10.18 9:00 32.0 53.0 135 9.7 0
2018 23.10.18 10:00 33.6 50.4 128 10.2 0
2018 23.10.18 11:00 35.2 47.7 122 10.7 0
2018 23.10.18 12:00 36.0 38.0 135 0.0 0
2018 23.10.18 13:00 37.8 39.9 142 0.0 0
2018 23.10.18 14:00 39.6 41.8 149 0.0 0
2018 23.10.18 15:00 36.0 36.0 90 0.0 0
2018 23.10.18 16:00 34.2 37.8 95 0.0 0
2018 23.10.18 17:00 32.4 39.6 99 0.0 0
2018 23.10.18 18:00 34.0 46.0 270 7.7 0
2018 23.10.18 19:00 32.3 48.3 284 7.3 0
2018 23.10.18 20:00 30.6 50.6 297 6.9 0
2018 23.10.18 21:00 32.0 51.0 270 9.7 0
2018 23.10.18 22:00 30.4 53.6 284 9.2 0
2018 23.10.18 23:00 28.8 56.1 297 8.7 0
2018 24.10.18 0:00 29.0 59.0 270 11.7 0
2018 24.10.18 1:00 30.5 56.1 257 12.3 0
2018 24.10.18 2:00 31.9 53.1 243 12.9 0
2018 24.10.18 3:00 26.0 67.0 270 11.7 0
2018 24.10.18 4:00 27.3 63.7 257 12.3 0
2018 24.10.18 5:00 28.6 60.3 243 12.9 0
2018 24.10.18 6:00 27.0 65.0 90 9.7 0
2018 24.10.18 7:00 28.4 61.8 86 10.2 0
2018 24.10.18 8:00 29.7 58.5 81 10.7 0
2018 24.10.18 9:00 31.0 54.0 135 9.7 0
2018 24.10.18 10:00 32.6 56.7 128 10.2 0
2018 24.10.18 11:00 34.1 59.4 122 10.7 0
2018 24.10.18 12:00 34.0 39.0 113 9.7 0
2018 24.10.18 13:00 32.3 41.0 118 10.2 0
2018 24.10.18 14:00 30.6 42.9 124 10.7 0
2018 24.10.18 15:00 35.0 36.0 270 9.7 0
2018 24.10.18 16:00 33.3 37.8 284 9.2 0
2018 24.10.18 17:00 31.5 39.6 297 8.7 0
2018 24.10.18 18:00 32.0 48.0 270 11.7 0
2018 24.10.18 19:00 30.4 50.4 24 11.1 0
2018 24.10.18 20:00 28.8 52.8 25 10.5 0
2018 24.10.18 21:00 28.0 61.0 23 13.7 0
2018 24.10.18 22:00 29.4 58.0 24 13.0 0
2018 24.10.18 23:00 30.8 54.9 25 12.3 0
2018 25.10.18 0:00 26.0 69.0 23 9.7 0
2018 25.10.18 1:00 27.3 65.6 21 10.2 0
2018 25.10.18 2:00 28.6 62.1 20 10.7 0
2018 25.10.18 3:00 26.0 72.0 23 7.7 0
2018 25.10.18 4:00 27.3 68.4 21 8.1 0
2018 25.10.18 5:00 28.6 64.8 20 8.5 0
2018 25.10.18 6:00 28.0 71.0 270 0.0 0
2018 25.10.18 7:00 29.4 74.6 257 0.0 0
2018 25.10.18 8:00 30.8 78.1 243 0.0 0
2018 25.10.18 9:00 32.0 58.0 135 7.7 0
A-164
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 25.10.18 10:00 30.4 60.9 128 8.1 0
2018 25.10.18 11:00 28.8 63.8 122 8.5 0
2018 25.10.18 12:00 35.0 43.0 135 7.7 0
2018 25.10.18 13:00 33.3 45.2 142 8.1 0
2018 25.10.18 14:00 31.5 47.3 149 8.5 0
2018 25.10.18 15:00 35.0 40.0 113 0.0 0
2018 25.10.18 16:00 33.3 42.0 118 0.0 0
2018 25.10.18 17:00 31.5 44.0 124 0.0 0
2018 25.10.18 18:00 33.0 52.0 270 0.0 0
2018 25.10.18 19:00 34.7 49.4 284 0.0 0
2018 25.10.18 20:00 36.3 46.8 297 0.0 0
2018 25.10.18 21:00 29.0 58.0 23 9.7 0
2018 25.10.18 22:00 30.5 55.1 24 9.2 0
2018 25.10.18 23:00 31.9 52.2 25 8.7 0
2018 26.10.18 0:00 27.0 62.0 270 7.7 0
2018 26.10.18 1:00 28.4 58.9 257 8.1 0
2018 26.10.18 2:00 29.7 55.8 243 8.5 0
2018 26.10.18 3:00 26.0 64.0 90 0.0 0
2018 26.10.18 4:00 27.3 60.8 86 0.0 0
2018 26.10.18 5:00 28.6 57.6 81 0.0 0
2018 26.10.18 6:00 27.0 63.0 158 0.0 0
2018 26.10.18 7:00 28.4 66.2 150 0.0 0
2018 26.10.18 8:00 29.7 69.3 142 0.0 0
2018 26.10.18 9:00 32.0 48.0 270 0.0 0
2018 26.10.18 10:00 30.4 50.4 257 0.0 0
2018 26.10.18 11:00 28.8 52.8 243 0.0 0
2018 26.10.18 12:00 35.0 36.0 180 9.7 0
2018 26.10.18 13:00 33.3 37.8 189 10.2 0
2018 26.10.18 14:00 31.5 39.6 198 10.7 0
2018 26.10.18 15:00 36.0 36.0 248 9.7 0
2018 26.10.18 16:00 34.2 37.8 260 9.2 0
2018 26.10.18 17:00 32.4 39.6 272 8.7 0
2018 26.10.18 18:00 34.0 47.0 315 0.0 0
2018 26.10.18 19:00 35.7 44.7 331 0.0 0
2018 26.10.18 20:00 37.4 42.3 347 0.0 0
2018 26.10.18 21:00 30.0 52.0 113 0.0 0
2018 26.10.18 22:00 31.5 49.4 118 0.0 0
2018 26.10.18 23:00 33.0 46.8 124 0.0 0
2018 27.10.18 0:00 27.0 52.0 158 0.0 0
2018 27.10.18 1:00 28.4 49.4 150 0.0 0
2018 27.10.18 2:00 29.7 46.8 142 0.0 0
2018 27.10.18 3:00 26.0 52.0 270 9.7 0
2018 27.10.18 4:00 27.3 54.6 257 10.2 0
2018 27.10.18 5:00 28.6 57.2 243 10.7 0
2018 27.10.18 6:00 28.0 51.0 203 13.7 0
2018 27.10.18 7:00 26.6 53.6 192 14.4 0
2018 27.10.18 8:00 25.2 56.1 182 15.1 0
2018 27.10.18 9:00 34.0 42.0 203 13.7 0
2018 27.10.18 10:00 32.3 44.1 192 14.4 0
A-165
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 27.10.18 11:00 30.6 46.2 182 15.1 0
2018 27.10.18 12:00 37.0 28.0 180 15.5 0
2018 27.10.18 13:00 35.2 29.4 189 16.3 0
2018 27.10.18 14:00 33.3 30.8 198 17.1 0
2018 27.10.18 15:00 37.0 28.0 180 13.7 0
2018 27.10.18 16:00 38.9 26.6 189 13.0 0
2018 27.10.18 17:00 40.7 25.2 198 12.3 0
2018 27.10.18 18:00 35.0 37.0 315 0.0 0
2018 27.10.18 19:00 36.8 35.2 331 0.0 0
2018 27.10.18 20:00 38.5 33.3 347 0.0 0
2018 27.10.18 21:00 33.0 36.0 135 0.0 0
2018 27.10.18 22:00 34.7 34.2 142 0.0 0
2018 27.10.18 23:00 36.3 32.4 149 0.0 0
2018 28.10.18 0:00 30.0 36.0 270 9.7 0
2018 28.10.18 1:00 31.5 37.8 257 10.2 0
2018 28.10.18 2:00 33.0 39.6 243 10.7 0
2018 28.10.18 3:00 27.0 40.0 203 11.7 0
2018 28.10.18 4:00 25.7 42.0 192 12.3 0
2018 28.10.18 5:00 24.3 44.0 182 12.9 0
2018 28.10.18 6:00 28.0 41.0 180 11.7 0
2018 28.10.18 7:00 26.6 43.1 171 12.3 0
2018 28.10.18 8:00 25.2 45.1 162 12.9 0
2018 28.10.18 9:00 33.0 36.0 180 7.7 0
2018 28.10.18 10:00 31.4 37.8 171 8.1 0
2018 28.10.18 11:00 29.7 39.6 162 8.5 0
2018 28.10.18 12:00 38.0 25.0 180 7.7 0
2018 28.10.18 13:00 39.9 23.8 189 8.1 0
2018 28.10.18 14:00 41.8 22.5 198 8.5 0
2018 28.10.18 15:00 39.0 23.0 180 7.7 0
2018 28.10.18 16:00 41.0 21.9 189 7.3 0
2018 28.10.18 17:00 42.9 20.7 198 6.9 0
2018 28.10.18 18:00 36.0 32.0 180 0.0 0
2018 28.10.18 19:00 37.8 30.4 189 0.0 0
2018 28.10.18 20:00 39.6 28.8 198 0.0 0
2018 28.10.18 21:00 32.0 31.0 203 0.0 0
2018 28.10.18 22:00 33.6 29.5 213 0.0 0
2018 28.10.18 23:00 35.2 27.9 223 0.0 0
2018 29.10.18 0:00 29.0 33.0 248 0.0 0
2018 29.10.18 1:00 27.6 34.7 235 0.0 0
2018 29.10.18 2:00 26.1 36.3 223 0.0 0
2018 29.10.18 3:00 27.0 34.0 270 0.0 0
2018 29.10.18 4:00 25.7 35.7 257 0.0 0
2018 29.10.18 5:00 24.3 37.4 243 0.0 0
2018 29.10.18 6:00 29.0 31.0 360 0.0 0
2018 29.10.18 7:00 27.6 32.6 342 0.0 0
2018 29.10.18 8:00 26.1 34.1 324 0.0 0
2018 29.10.18 9:00 35.0 25.0 270 0.0 0
2018 29.10.18 10:00 36.8 26.3 257 0.0 0
2018 29.10.18 11:00 38.5 27.5 243 0.0 0
A-166
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 29.10.18 12:00 38.0 20.0 180 0.0 0
2018 29.10.18 13:00 39.9 19.0 189 0.0 0
2018 29.10.18 14:00 41.8 18.0 198 0.0 0
2018 29.10.18 15:00 38.0 24.0 180 0.0 0
2018 29.10.18 16:00 39.9 22.8 189 0.0 0
2018 29.10.18 17:00 41.8 21.6 198 0.0 0
2018 29.10.18 18:00 36.0 36.0 180 0.0 0
2018 29.10.18 19:00 37.8 34.2 189 0.0 0
2018 29.10.18 20:00 39.6 32.4 198 0.0 0
2018 29.10.18 21:00 34.0 37.0 248 0.0 0
2018 29.10.18 22:00 32.3 38.9 260 0.0 0
2018 29.10.18 23:00 30.6 40.7 272 0.0 0
2018 30.10.18 0:00 30.0 38.0 293 0.0 0
2018 30.10.18 1:00 28.5 39.9 278 0.0 0
2018 30.10.18 2:00 27.0 41.8 263 0.0 0
2018 30.10.18 3:00 27.0 32.0 248 11.7 0
2018 30.10.18 4:00 25.7 33.6 235 12.3 0
2018 30.10.18 5:00 24.3 35.2 223 12.9 0
2018 30.10.18 6:00 27.0 32.0 248 11.7 0
2018 30.10.18 7:00 28.4 33.6 235 12.3 0
2018 30.10.18 8:00 29.7 35.2 223 12.9 0
2018 30.10.18 9:00 32.0 29.0 248 11.7 0
2018 30.10.18 10:00 33.6 27.6 235 12.3 0
2018 30.10.18 11:00 35.2 26.1 223 12.9 0
2018 30.10.18 12:00 36.0 21.0 270 13.7 0
2018 30.10.18 13:00 37.8 20.0 284 14.4 0
2018 30.10.18 14:00 39.6 18.9 297 15.1 0
2018 30.10.18 15:00 37.0 25.0 248 11.7 0
2018 30.10.18 16:00 38.9 23.8 260 11.1 0
2018 30.10.18 17:00 40.7 22.5 272 10.5 0
2018 30.10.18 18:00 34.0 34.0 180 0.0 0
2018 30.10.18 19:00 32.3 35.7 189 0.0 0
2018 30.10.18 20:00 30.6 37.4 198 0.0 0
2018 30.10.18 21:00 31.0 32.0 180 7.7 0
2018 30.10.18 22:00 29.5 33.6 189 7.3 0
2018 30.10.18 23:00 27.9 35.2 198 6.9 0
2018 31.10.18 0:00 28.0 30.0 248 11.7 0
2018 31.10.18 1:00 26.6 31.5 235 12.3 0
2018 31.10.18 2:00 25.2 33.0 223 12.9 0
2018 31.10.18 3:00 26.0 31.0 248 13.7 0
2018 31.10.18 4:00 27.3 32.6 235 14.4 0
2018 31.10.18 5:00 28.6 34.1 223 15.1 0
2018 31.10.18 6:00 26.0 34.0 248 15.5 0
2018 31.10.18 7:00 27.3 32.3 235 16.3 0
2018 31.10.18 8:00 28.6 30.6 223 17.1 0
2018 31.10.18 9:00 31.0 31.0 270 15.5 0
2018 31.10.18 10:00 32.6 29.5 257 16.3 0
2018 31.10.18 11:00 34.1 27.9 243 17.1 0
2018 31.10.18 12:00 35.0 20.0 270 17.5 0
A-167
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 31.10.18 13:00 36.8 19.0 284 18.4 0
2018 31.10.18 14:00 38.5 18.0 297 19.3 0
2018 31.10.18 15:00 36.0 23.0 270 13.7 0
2018 31.10.18 16:00 34.2 21.9 284 13.0 0
2018 31.10.18 17:00 32.4 20.7 297 12.3 0
2018 31.10.18 18:00 35.0 34.0 270 0.0 0
2018 31.10.18 19:00 33.3 35.7 284 0.0 0
2018 31.10.18 20:00 31.5 37.4 297 0.0 0
2018 31.10.18 21:00 32.0 33.0 248 7.7 0
2018 31.10.18 22:00 30.4 34.7 260 7.3 0
2018 31.10.18 23:00 28.8 36.3 272 6.9 0
2018 01.11.18 0:00 28.0 29.0 248 11.7 0
2018 01.11.18 1:00 29.4 30.5 235 12.3 0
2018 01.11.18 2:00 30.8 31.9 223 12.9 0
2018 01.11.18 3:00 26.0 29.0 248 13.7 0
2018 01.11.18 4:00 27.3 30.5 235 14.4 0
2018 01.11.18 5:00 28.6 31.9 223 15.1 0
2018 01.11.18 6:00 26.0 33.0 248 15.5 0
2018 01.11.18 7:00 27.3 31.4 235 16.3 0
2018 01.11.18 8:00 28.6 29.7 223 17.1 0
2018 01.11.18 9:00 31.0 32.0 248 15.5 0
2018 01.11.18 10:00 32.6 30.4 235 16.3 0
2018 01.11.18 11:00 34.1 28.8 223 17.1 0
2018 01.11.18 12:00 35.0 22.0 270 17.5 0
2018 01.11.18 13:00 33.3 20.9 284 18.4 0
2018 01.11.18 14:00 31.5 19.8 297 19.3 0
2018 01.11.18 15:00 35.0 24.0 248 15.5 0
2018 01.11.18 16:00 33.3 25.2 260 14.7 0
2018 01.11.18 17:00 31.5 26.4 272 14.0 0
2018 01.11.18 18:00 33.0 32.0 180 9.7 0
2018 01.11.18 19:00 31.4 33.6 189 9.2 0
2018 01.11.18 20:00 29.7 35.2 198 8.7 0
2018 01.11.18 21:00 29.0 31.0 248 11.7 0
2018 01.11.18 22:00 30.5 32.6 260 11.1 0
2018 01.11.18 23:00 31.9 34.1 272 10.5 0
2018 02.11.18 0:00 27.0 32.0 270 13.7 0
2018 02.11.18 1:00 28.4 33.6 257 14.4 0
2018 02.11.18 2:00 29.7 35.2 243 15.1 0
2018 02.11.18 3:00 24.0 34.0 248 11.7 0
2018 02.11.18 4:00 25.2 32.3 235 12.3 0
2018 02.11.18 5:00 26.4 30.6 223 12.9 0
2018 02.11.18 6:00 26.0 35.0 180 13.7 0
2018 02.11.18 7:00 27.3 33.3 171 14.4 0
2018 02.11.18 8:00 28.6 31.5 162 15.1 0
2018 02.11.18 9:00 31.0 31.0 248 13.7 0
2018 02.11.18 10:00 29.5 29.5 235 14.4 0
2018 02.11.18 11:00 27.9 27.9 223 15.1 0
2018 02.11.18 12:00 35.0 21.0 248 17.5 0
2018 02.11.18 13:00 33.3 22.1 260 18.4 0
A-168
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 02.11.18 14:00 31.5 23.1 272 19.3 0
2018 02.11.18 15:00 35.0 21.0 180 17.5 0
2018 02.11.18 16:00 33.3 22.1 189 16.6 0
2018 02.11.18 17:00 31.5 23.1 198 15.8 0
2018 02.11.18 18:00 31.0 28.0 203 11.7 0
2018 02.11.18 19:00 32.6 29.4 213 11.1 0
2018 02.11.18 20:00 34.1 30.8 223 10.5 0
2018 02.11.18 21:00 27.0 26.0 180 13.7 0
2018 02.11.18 22:00 28.4 27.3 189 13.0 0
2018 02.11.18 23:00 29.7 28.6 198 12.3 0
2018 03.11.18 0:00 24.0 29.0 248 15.5 0
2018 03.11.18 1:00 25.2 27.6 235 16.3 0
2018 03.11.18 2:00 26.4 26.1 223 17.1 0
2018 03.11.18 3:00 23.0 35.0 248 15.5 0
2018 03.11.18 4:00 24.2 33.3 235 16.3 0
2018 03.11.18 5:00 25.3 31.5 223 17.1 0
2018 03.11.18 6:00 23.0 39.0 248 17.5 0
2018 03.11.18 7:00 21.9 37.1 235 18.4 0
2018 03.11.18 8:00 20.7 35.1 223 19.3 0
2018 03.11.18 9:00 29.0 36.0 248 17.5 0
2018 03.11.18 10:00 27.6 34.2 235 18.4 0
2018 03.11.18 11:00 26.1 32.4 223 19.3 0
2018 03.11.18 12:00 35.0 26.0 248 17.5 0
2018 03.11.18 13:00 33.3 27.3 260 18.4 0
2018 03.11.18 14:00 31.5 28.6 272 19.3 0
2018 03.11.18 15:00 36.0 27.0 180 15.5 0
2018 03.11.18 16:00 37.8 28.4 189 14.7 0
2018 03.11.18 17:00 39.6 29.7 198 14.0 0
2018 03.11.18 18:00 33.0 34.0 203 11.7 0
2018 03.11.18 19:00 34.7 35.7 213 11.1 0
2018 03.11.18 20:00 36.3 37.4 223 10.5 0
2018 03.11.18 21:00 29.0 34.0 180 13.7 0
2018 03.11.18 22:00 30.5 35.7 189 13.0 0
2018 03.11.18 23:00 31.9 37.4 198 12.3 0
2018 04.11.18 0:00 26.0 35.0 248 15.5 0
2018 04.11.18 1:00 27.3 33.3 235 16.3 0
2018 04.11.18 2:00 28.6 31.5 223 17.1 0
2018 04.11.18 3:00 24.0 37.0 248 15.5 0
2018 04.11.18 4:00 22.8 35.2 235 16.3 0
2018 04.11.18 5:00 21.6 33.3 223 17.1 0
2018 04.11.18 6:00 24.0 40.0 248 13.7 0
2018 04.11.18 7:00 22.8 38.0 235 14.4 0
2018 04.11.18 8:00 21.6 36.0 223 15.1 0
2018 04.11.18 9:00 30.0 36.0 248 13.7 0
2018 04.11.18 10:00 28.5 37.8 235 14.4 0
2018 04.11.18 11:00 27.0 39.6 223 15.1 0
2018 04.11.18 12:00 35.0 25.0 180 13.7 0
2018 04.11.18 13:00 36.8 26.3 189 14.4 0
2018 04.11.18 14:00 38.5 27.5 198 15.1 0
A-169
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 04.11.18 15:00 35.0 25.0 203 13.7 0
2018 04.11.18 16:00 36.8 26.3 213 13.0 0
2018 04.11.18 17:00 38.5 27.5 223 12.3 0
2018 04.11.18 18:00 32.0 34.0 315 7.7 0
2018 04.11.18 19:00 33.6 35.7 331 7.3 0
2018 04.11.18 20:00 35.2 37.4 347 6.9 0
2018 04.11.18 21:00 28.0 36.0 180 0.0 0
2018 04.11.18 22:00 29.4 34.2 189 0.0 0
2018 04.11.18 23:00 30.8 32.4 198 0.0 0
2018 05.11.18 0:00 26.0 34.0 270 7.7 0
2018 05.11.18 1:00 24.7 32.3 257 8.1 0
2018 05.11.18 2:00 23.4 30.6 243 8.5 0
2018 05.11.18 3:00 24.0 34.0 203 11.7 0
2018 05.11.18 4:00 22.8 32.3 192 12.3 0
2018 05.11.18 5:00 21.6 30.6 182 12.9 0
2018 05.11.18 6:00 26.0 36.0 180 11.7 0
2018 05.11.18 7:00 24.7 37.8 171 12.3 0
2018 05.11.18 8:00 23.4 39.6 243 12.9 0
2018 05.11.18 9:00 32.0 31.0 270 9.7 0
2018 05.11.18 10:00 33.6 32.6 257 10.2 0
2018 05.11.18 11:00 35.2 34.1 243 10.7 0
2018 05.11.18 12:00 36.0 22.0 203 11.7 0
2018 05.11.18 13:00 37.8 23.1 213 12.3 0
2018 05.11.18 14:00 39.6 24.2 223 12.9 0
2018 05.11.18 15:00 36.0 24.0 203 11.7 0
2018 05.11.18 16:00 37.8 25.2 213 11.1 0
2018 05.11.18 17:00 39.6 26.4 223 10.5 0
2018 05.11.18 18:00 33.0 33.0 248 7.7 0
2018 05.11.18 19:00 34.7 31.4 260 7.3 0
2018 05.11.18 20:00 36.3 29.7 272 6.9 0
2018 05.11.18 21:00 29.0 35.0 270 0.0 0
2018 05.11.18 22:00 27.6 33.3 284 0.0 0
2018 05.11.18 23:00 26.1 31.5 297 0.0 0
2018 06.11.18 0:00 27.0 34.0 338 0.0 0
2018 06.11.18 1:00 25.7 32.3 321 0.0 0
2018 06.11.18 2:00 24.3 30.6 304 0.0 0
2018 06.11.18 3:00 26.0 33.0 90 7.7 0
2018 06.11.18 4:00 24.7 31.4 86 8.1 0
2018 06.11.18 5:00 23.4 29.7 81 8.5 0
2018 06.11.18 6:00 28.0 33.0 270 7.7 0
2018 06.11.18 7:00 29.4 34.7 257 8.1 0
2018 06.11.18 8:00 30.8 36.3 243 8.5 0
2018 06.11.18 9:00 34.0 26.0 248 0.0 0
2018 06.11.18 10:00 35.7 27.3 235 0.0 0
2018 06.11.18 11:00 37.4 28.6 223 0.0 0
2018 06.11.18 12:00 37.0 20.0 293 0.0 0
2018 06.11.18 13:00 38.9 21.0 307 2.1 0
2018 06.11.18 14:00 40.7 22.0 322 2.2 0
2018 06.11.18 15:00 37.0 23.0 270 7.7 0
A-170
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 06.11.18 16:00 38.9 24.2 284 7.3 0
2018 06.11.18 17:00 40.7 25.3 297 6.9 0
2018 06.11.18 18:00 34.0 31.0 203 7.7 0
2018 06.11.18 19:00 32.3 29.5 213 7.3 0
2018 06.11.18 20:00 30.6 27.9 223 6.9 0
2018 06.11.18 21:00 32.0 32.0 270 7.7 0
2018 06.11.18 22:00 30.4 30.4 284 7.3 0
2018 06.11.18 23:00 28.8 28.8 297 6.9 0
2018 07.11.18 0:00 29.0 35.0 203 0.0 0
2018 07.11.18 1:00 27.6 33.3 192 0.0 0
2018 07.11.18 2:00 26.1 31.5 182 0.0 0
2018 07.11.18 3:00 26.0 35.0 270 7.7 0
2018 07.11.18 4:00 27.3 36.8 257 8.1 0
2018 07.11.18 5:00 28.6 38.5 243 8.5 0
2018 07.11.18 6:00 27.0 35.0 248 7.7 0
2018 07.11.18 7:00 28.4 36.8 235 8.1 0
2018 07.11.18 8:00 29.7 38.5 223 8.5 0
2018 07.11.18 9:00 34.0 27.0 360 2.0 0
2018 07.11.18 10:00 35.7 28.4 342 2.1 0
2018 07.11.18 11:00 37.4 29.7 324 2.2 0
2018 07.11.18 12:00 37.0 19.0 270 2.0 0
2018 07.11.18 13:00 38.9 20.0 284 2.1 0
2018 07.11.18 14:00 40.7 20.9 297 2.2 0
2018 07.11.18 15:00 37.0 21.0 180 9.7 0
2018 07.11.18 16:00 38.9 20.0 189 9.2 0
2018 07.11.18 17:00 40.7 18.9 198 8.7 0
2018 07.11.18 18:00 33.0 29.0 203 9.7 0
2018 07.11.18 19:00 31.4 27.6 213 9.2 0
2018 07.11.18 20:00 29.7 26.1 223 6.9 0
2018 07.11.18 21:00 30.0 29.0 338 7.7 0
2018 07.11.18 22:00 28.5 27.6 354 7.3 0
2018 07.11.18 23:00 27.0 26.1 371 6.9 0
2018 08.11.18 0:00 26.0 30.0 270 13.7 0
2018 08.11.18 1:00 24.7 31.5 257 14.4 0
2018 08.11.18 2:00 23.4 33.0 243 15.1 0
2018 08.11.18 3:00 23.0 34.0 203 15.5 0
2018 08.11.18 4:00 24.2 35.7 192 16.3 0
2018 08.11.18 5:00 25.3 37.4 182 17.1 0
2018 08.11.18 6:00 24.0 31.0 270 13.7 0
2018 08.11.18 7:00 25.2 32.6 257 14.4 0
2018 08.11.18 8:00 26.4 34.1 243 15.1 0
2018 08.11.18 9:00 30.0 25.0 248 13.7 0
2018 08.11.18 10:00 31.5 26.3 235 14.4 0
2018 08.11.18 11:00 33.0 27.5 223 15.1 0
2018 08.11.18 12:00 36.0 16.0 270 13.7 0
2018 08.11.18 13:00 37.8 15.2 284 14.4 0
2018 08.11.18 14:00 39.6 14.4 297 15.1 0
2018 08.11.18 15:00 36.0 17.0 203 11.7 0
2018 08.11.18 16:00 34.2 16.2 213 11.1 0
A-171
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 08.11.18 17:00 32.4 15.3 223 10.5 0
2018 08.11.18 18:00 32.0 24.0 315 7.7 0
2018 08.11.18 19:00 30.4 22.8 331 7.3 0
2018 08.11.18 20:00 28.8 21.6 347 6.9 0
2018 08.11.18 21:00 29.0 22.0 270 7.7 0
2018 08.11.18 22:00 27.6 20.9 284 7.3 0
2018 08.11.18 23:00 26.1 19.8 297 6.9 0
2018 09.11.18 0:00 26.0 23.0 180 11.7 0
2018 09.11.18 1:00 27.3 24.2 171 12.3 0
2018 09.11.18 2:00 28.6 25.3 162 12.9 0
2018 09.11.18 3:00 23.0 29.0 203 13.7 0
2018 09.11.18 4:00 24.2 30.5 192 14.4 0
2018 09.11.18 5:00 25.3 31.9 182 15.1 0
2018 09.11.18 6:00 24.0 33.0 248 11.7 0
2018 09.11.18 7:00 25.2 34.7 235 12.3 0
2018 09.11.18 8:00 26.4 36.3 223 12.9 0
2018 09.11.18 9:00 31.0 28.0 248 7.7 0
2018 09.11.18 10:00 32.6 29.4 235 8.1 0
2018 09.11.18 11:00 34.1 30.8 223 8.5 0
2018 09.11.18 12:00 37.0 19.0 248 7.7 0
2018 09.11.18 13:00 35.2 18.1 260 8.1 0
2018 09.11.18 14:00 33.3 17.1 272 8.5 0
2018 09.11.18 15:00 37.0 21.0 270 2.0 0
2018 09.11.18 16:00 35.2 20.0 284 1.9 0
2018 09.11.18 17:00 33.3 18.9 297 1.8 0
2018 09.11.18 18:00 34.0 30.0 270 2.0 0
2018 09.11.18 19:00 32.3 28.5 284 1.9 0
2018 09.11.18 20:00 30.6 27.0 297 1.8 0
2018 09.11.18 21:00 32.0 30.0 203 2.0 0
2018 09.11.18 22:00 33.6 31.5 213 1.9 0
2018 09.11.18 23:00 35.2 33.0 223 1.8 0
2018 10.11.18 0:00 29.0 31.0 203 7.7 0
2018 10.11.18 1:00 30.5 32.6 192 8.1 0
2018 10.11.18 2:00 31.9 34.1 182 8.5 0
2018 10.11.18 3:00 23.0 31.0 203 11.7 0
2018 10.11.18 4:00 24.2 32.6 192 12.3 0
2018 10.11.18 5:00 25.3 34.1 182 12.9 0
2018 10.11.18 6:00 24.0 32.0 270 7.7 0
2018 10.11.18 7:00 25.2 33.6 257 8.1 0
2018 10.11.18 8:00 26.4 35.2 243 8.5 0
2018 10.11.18 9:00 31.0 29.0 248 7.7 0
2018 10.11.18 10:00 29.5 27.6 235 8.1 0
2018 10.11.18 11:00 27.9 26.1 223 8.5 0
2018 10.11.18 12:00 37.0 20.0 248 2.0 0
2018 10.11.18 13:00 35.2 19.0 260 4.1 0
2018 10.11.18 14:00 33.3 18.0 272 4.3 0
2018 10.11.18 15:00 38.0 24.0 338 0.0 0
2018 10.11.18 16:00 36.1 22.8 354 0.0 0
2018 10.11.18 17:00 34.2 21.6 371 0.0 0
A-172
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 10.11.18 18:00 34.0 36.0 113 0.0 0
2018 10.11.18 19:00 35.7 37.8 118 0.0 0
2018 10.11.18 20:00 37.4 39.6 124 0.0 0
2018 10.11.18 21:00 32.0 33.0 113 3.9 0
2018 10.11.18 22:00 33.6 34.7 118 3.7 0
2018 10.11.18 23:00 35.2 36.3 124 3.5 0
2018 11.11.18 0:00 28.0 33.0 270 7.7 0
2018 11.11.18 1:00 29.4 34.7 257 8.1 0
2018 11.11.18 2:00 30.8 36.3 243 8.5 0
2018 11.11.18 3:00 23.0 33.0 203 13.7 0
2018 11.11.18 4:00 24.2 34.7 192 14.4 0
2018 11.11.18 5:00 25.3 36.3 182 15.1 0
2018 11.11.18 6:00 24.0 34.0 270 11.7 0
2018 11.11.18 7:00 22.8 32.3 257 12.3 0
2018 11.11.18 8:00 21.6 30.6 243 12.9 0
2018 11.11.18 9:00 31.0 28.0 270 7.7 0
2018 11.11.18 10:00 29.5 26.6 257 8.1 0
2018 11.11.18 11:00 27.9 25.2 243 8.5 0
2018 11.11.18 12:00 36.0 20.0 203 7.7 0
2018 11.11.18 13:00 34.2 19.0 213 8.1 0
2018 11.11.18 14:00 32.4 18.0 223 8.5 0
2018 11.11.18 15:00 37.0 23.0 203 3.9 0
2018 11.11.18 16:00 38.9 21.9 213 3.7 0
2018 11.11.18 17:00 40.7 20.7 223 3.5 0
2018 11.11.18 18:00 32.0 32.0 203 3.9 0
2018 11.11.18 19:00 33.6 33.6 213 3.7 0
2018 11.11.18 20:00 35.2 35.2 223 3.5 0
2018 11.11.18 21:00 29.0 28.0 203 7.7 0
2018 11.11.18 22:00 30.5 29.4 213 7.3 0
2018 11.11.18 23:00 31.9 30.8 223 6.9 0
2018 12.11.18 0:00 26.0 28.0 203 11.7 0
2018 12.11.18 1:00 27.3 29.4 192 12.3 0
2018 12.11.18 2:00 28.6 30.8 182 12.9 0
2018 12.11.18 3:00 23.0 34.0 270 13.7 0
2018 12.11.18 4:00 21.9 35.7 257 14.4 0
2018 12.11.18 5:00 20.7 37.4 243 15.1 0
2018 12.11.18 6:00 23.0 36.0 270 11.7 0
2018 12.11.18 7:00 21.9 34.2 257 12.3 0
2018 12.11.18 8:00 20.7 32.4 243 12.9 0
2018 12.11.18 9:00 30.0 32.0 270 11.7 0
2018 12.11.18 10:00 28.5 30.4 257 12.3 0
2018 12.11.18 11:00 27.0 28.8 243 12.9 0
2018 12.11.18 12:00 36.0 22.0 203 7.7 0
2018 12.11.18 13:00 37.8 20.9 213 8.1 0
2018 12.11.18 14:00 39.6 19.8 223 8.5 0
2018 12.11.18 15:00 36.0 24.0 203 7.7 0
2018 12.11.18 16:00 37.8 25.2 213 7.3 0
2018 12.11.18 17:00 39.6 26.4 223 6.9 0
2018 12.11.18 18:00 32.0 33.0 203 7.7 0
A-173
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 12.11.18 19:00 33.6 34.7 213 7.3 0
2018 12.11.18 20:00 35.2 36.3 223 6.9 0
2018 12.11.18 21:00 29.0 32.0 203 11.7 0
2018 12.11.18 22:00 30.5 33.6 213 11.1 0
2018 12.11.18 23:00 31.9 35.2 223 10.5 0
2018 13.11.18 0:00 24.0 33.0 180 13.7 0
2018 13.11.18 1:00 22.8 34.7 171 14.4 0
2018 13.11.18 2:00 21.6 36.3 162 15.1 0
2018 13.11.18 3:00 23.0 37.0 270 13.7 0
2018 13.11.18 4:00 21.9 35.2 257 14.4 0
2018 13.11.18 5:00 20.7 33.3 243 15.1 0
2018 13.11.18 6:00 24.0 39.0 270 13.7 0
2018 13.11.18 7:00 22.8 37.1 257 14.4 0
2018 13.11.18 8:00 21.6 35.1 243 15.1 0
2018 13.11.18 9:00 30.0 34.0 270 13.7 0
2018 13.11.18 10:00 31.5 32.3 257 14.4 0
2018 13.11.18 11:00 33.0 30.6 243 15.1 0
2018 13.11.18 12:00 35.0 24.0 270 15.5 0
2018 13.11.18 13:00 36.8 25.2 284 16.3 0
2018 13.11.18 14:00 38.5 26.4 297 17.1 0
2018 13.11.18 15:00 35.0 24.0 270 11.7 0
2018 13.11.18 16:00 36.8 25.2 284 11.1 0
2018 13.11.18 17:00 38.5 26.4 297 10.5 0
2018 13.11.18 18:00 31.0 31.0 203 7.7 0
2018 13.11.18 19:00 32.6 32.6 213 7.3 0
2018 13.11.18 20:00 34.1 34.1 223 6.9 0
2018 13.11.18 21:00 27.0 31.0 203 7.7 0
2018 13.11.18 22:00 25.7 32.6 213 7.3 0
2018 13.11.18 23:00 24.3 34.1 223 6.9 0
2018 14.11.18 0:00 26.0 32.0 203 7.7 0
2018 14.11.18 1:00 24.7 30.4 192 8.1 0
2018 14.11.18 2:00 23.4 28.8 182 8.5 0
2018 14.11.18 3:00 23.0 32.0 270 13.7 0
2018 14.11.18 4:00 21.9 30.4 257 14.4 0
2018 14.11.18 5:00 20.7 28.8 243 15.1 0
2018 14.11.18 6:00 23.0 35.0 270 15.5 0
2018 14.11.18 7:00 24.2 33.3 257 16.3 0
2018 14.11.18 8:00 25.3 31.5 243 17.1 0
2018 14.11.18 9:00 29.0 33.0 270 13.7 0
2018 14.11.18 10:00 30.5 31.4 257 14.4 0
2018 14.11.18 11:00 31.9 29.7 243 15.1 0
2018 14.11.18 12:00 35.0 23.0 248 13.7 0
2018 14.11.18 13:00 36.8 24.2 260 14.4 0
2018 14.11.18 14:00 38.5 25.3 272 15.1 0
2018 14.11.18 15:00 35.0 24.0 270 11.7 0
2018 14.11.18 16:00 36.8 25.2 284 11.1 0
2018 14.11.18 17:00 38.5 26.4 297 10.5 0
2018 14.11.18 18:00 32.0 30.0 203 11.7 0
2018 14.11.18 19:00 30.4 31.5 213 11.1 0
A-174
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 14.11.18 20:00 28.8 33.0 223 10.5 0
2018 14.11.18 21:00 28.0 28.0 203 13.7 0
2018 14.11.18 22:00 26.6 29.4 213 13.0 0
2018 14.11.18 23:00 25.2 30.8 223 12.3 0
2018 15.11.18 0:00 24.0 28.0 203 13.7 0
2018 15.11.18 1:00 22.8 26.6 192 14.4 0
2018 15.11.18 2:00 21.6 25.2 182 15.1 0
2018 15.11.18 3:00 22.0 30.0 203 15.5 0
2018 15.11.18 4:00 23.1 28.5 192 16.3 0
2018 15.11.18 5:00 24.2 27.0 182 17.1 0
2018 15.11.18 6:00 22.0 34.0 270 17.5 0
2018 15.11.18 7:00 23.1 32.3 257 18.4 0
2018 15.11.18 8:00 24.2 30.6 243 19.3 0
2018 15.11.18 9:00 28.0 34.0 270 15.5 0
2018 15.11.18 10:00 29.4 35.7 257 16.3 0
2018 15.11.18 11:00 30.8 37.4 243 17.1 0
2018 15.11.18 12:00 34.0 23.0 248 15.5 0
2018 15.11.18 13:00 35.7 24.2 260 16.3 0
2018 15.11.18 14:00 37.4 25.3 272 17.1 0
2018 15.11.18 15:00 35.0 23.0 270 11.7 0
2018 15.11.18 16:00 33.3 24.2 284 11.1 0
2018 15.11.18 17:00 31.5 25.3 297 10.5 0
2018 15.11.18 18:00 32.0 30.0 203 11.7 0
2018 15.11.18 19:00 30.4 31.5 213 11.1 0
2018 15.11.18 20:00 28.8 33.0 223 10.5 0
2018 15.11.18 21:00 29.0 28.0 270 15.5 0
2018 15.11.18 22:00 27.6 26.6 284 14.7 0
2018 15.11.18 23:00 26.1 25.2 297 14.0 0
2018 16.11.18 0:00 26.0 28.0 270 15.5 0
2018 16.11.18 1:00 27.3 26.6 257 16.3 0
2018 16.11.18 2:00 28.6 25.2 243 17.1 0
2018 16.11.18 3:00 22.0 28.0 270 15.5 0
2018 16.11.18 4:00 23.1 26.6 257 16.3 0
2018 16.11.18 5:00 24.2 25.2 243 17.1 0
2018 16.11.18 6:00 22.0 32.0 270 15.5 0
2018 16.11.18 7:00 23.1 33.6 257 16.3 0
2018 16.11.18 8:00 24.2 35.2 243 17.1 0
2018 16.11.18 9:00 28.0 33.0 248 17.5 0
2018 16.11.18 10:00 29.4 34.7 235 18.4 0
2018 16.11.18 11:00 30.8 36.3 223 19.3 0
2018 16.11.18 12:00 34.0 24.0 248 17.5 0
2018 16.11.18 13:00 32.3 25.2 260 18.4 0
2018 16.11.18 14:00 30.6 26.4 223 19.3 0
2018 16.11.18 15:00 35.0 25.0 270 13.7 0
2018 16.11.18 16:00 33.3 26.3 284 13.0 0
2018 16.11.18 17:00 31.5 27.5 297 12.3 0
2018 16.11.18 18:00 31.0 31.0 203 13.7 0
2018 16.11.18 19:00 29.5 29.5 213 13.0 0
2018 16.11.18 20:00 27.9 27.9 223 12.3 0
A-175
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 16.11.18 21:00 29.0 28.0 270 17.5 0
2018 16.11.18 22:00 30.5 26.6 284 16.6 0
2018 16.11.18 23:00 31.9 25.2 297 15.8 0
2018 17.11.18 0:00 24.0 29.0 270 17.5 0
2018 17.11.18 1:00 25.2 27.6 257 18.4 0
2018 17.11.18 2:00 26.4 26.1 243 19.3 0
2018 17.11.18 3:00 22.0 33.0 203 17.5 0
2018 17.11.18 4:00 23.1 31.4 192 18.4 0
2018 17.11.18 5:00 24.2 29.7 182 19.3 0
2018 17.11.18 6:00 22.0 36.0 203 17.5 0
2018 17.11.18 7:00 23.1 37.8 192 18.4 0
2018 17.11.18 8:00 24.2 39.6 182 19.3 0
2018 17.11.18 9:00 28.0 35.0 270 17.5 0
2018 17.11.18 10:00 26.6 36.8 257 18.4 0
2018 17.11.18 11:00 25.2 38.5 243 19.3 0
2018 17.11.18 12:00 34.0 23.0 270 17.5 0
2018 17.11.18 13:00 32.3 24.2 284 18.4 0
2018 17.11.18 14:00 30.6 25.3 297 19.3 0
2018 17.11.18 15:00 34.0 23.0 270 15.5 0
2018 17.11.18 16:00 32.3 24.2 284 14.7 0
2018 17.11.18 17:00 30.6 25.3 297 14.0 0
2018 17.11.18 18:00 32.0 30.0 203 13.7 0
2018 17.11.18 19:00 33.6 28.5 213 13.0 0
2018 17.11.18 20:00 35.2 27.0 223 12.3 0
2018 17.11.18 21:00 28.0 29.0 270 13.7 0
2018 17.11.18 22:00 29.4 27.6 189 13.0 0
2018 17.11.18 23:00 30.8 26.1 198 12.3 0
2018 18.11.18 0:00 23.0 29.0 203 15.5 0
2018 18.11.18 1:00 24.2 27.6 192 16.3 0
2018 18.11.18 2:00 25.3 26.1 182 17.1 0
2018 18.11.18 3:00 22.0 32.0 203 15.5 0
2018 18.11.18 4:00 23.1 33.6 192 16.3 0
2018 18.11.18 5:00 24.2 35.2 182 17.1 0
2018 18.11.18 6:00 22.0 34.0 203 13.7 0
2018 18.11.18 7:00 20.9 35.7 192 14.4 0
2018 18.11.18 8:00 19.8 37.4 182 15.1 0
2018 18.11.18 9:00 29.0 31.0 270 11.7 0
2018 18.11.18 10:00 27.6 32.6 257 12.3 0
2018 18.11.18 11:00 26.1 34.1 243 12.9 0
2018 18.11.18 12:00 35.0 21.0 203 13.7 0
2018 18.11.18 13:00 33.3 22.1 213 14.4 0
2018 18.11.18 14:00 31.5 23.1 223 15.1 0
2018 18.11.18 15:00 35.0 22.0 180 11.7 0
2018 18.11.18 16:00 36.8 20.9 189 11.1 0
2018 18.11.18 17:00 38.5 19.8 198 10.5 0
2018 18.11.18 18:00 32.0 30.0 203 11.7 0
2018 18.11.18 19:00 33.6 28.5 213 11.1 0
2018 18.11.18 20:00 35.2 27.0 223 10.5 0
2018 18.11.18 21:00 29.0 30.0 180 11.7 0
A-176
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 18.11.18 22:00 30.5 28.5 189 11.1 0
2018 18.11.18 23:00 31.9 27.0 198 10.5 0
2018 19.11.18 0:00 26.0 31.0 203 11.7 0
2018 19.11.18 1:00 27.3 32.6 192 12.3 0
2018 19.11.18 2:00 28.6 34.1 182 12.9 0
2018 19.11.18 3:00 20.0 31.0 203 11.7 0
2018 19.11.18 4:00 19.0 32.6 192 12.3 0
2018 19.11.18 5:00 18.0 34.1 182 12.9 0
2018 19.11.18 6:00 21.0 32.0 203 7.7 0
2018 19.11.18 7:00 20.0 33.6 192 8.1 0
2018 19.11.18 8:00 18.9 35.2 182 8.5 0
2018 19.11.18 9:00 29.0 29.0 203 7.7 0
2018 19.11.18 10:00 27.6 30.5 192 8.1 0
2018 19.11.18 11:00 26.1 31.9 182 8.5 0
2018 19.11.18 12:00 35.0 20.0 203 7.7 0
2018 19.11.18 13:00 36.8 19.0 213 8.1 0
2018 19.11.18 14:00 38.5 18.0 223 8.5 0
2018 19.11.18 15:00 36.0 21.0 225 7.7 0
2018 19.11.18 16:00 37.8 20.0 236 7.3 0
2018 19.11.18 17:00 39.6 18.9 248 6.9 0
2018 19.11.18 18:00 32.0 29.0 225 7.7 0
2018 19.11.18 19:00 33.6 27.6 236 7.3 0
2018 19.11.18 20:00 35.2 26.1 248 6.9 0
2018 19.11.18 21:00 29.0 28.0 225 11.7 0
2018 19.11.18 22:00 30.5 26.6 236 11.1 0
2018 19.11.18 23:00 31.9 25.2 248 10.5 0
2018 20.11.18 0:00 24.0 28.0 203 11.7 0
2018 20.11.18 1:00 25.2 29.4 192 12.3 0
2018 20.11.18 2:00 26.4 30.8 182 12.9 0
2018 20.11.18 3:00 22.0 29.0 203 11.7 0
2018 20.11.18 4:00 20.9 30.5 192 12.3 0
2018 20.11.18 5:00 19.8 31.9 182 12.9 0
2018 20.11.18 6:00 26.0 30.0 203 7.7 0
2018 20.11.18 7:00 24.7 31.5 192 8.1 0
2018 20.11.18 8:00 23.4 33.0 182 8.5 0
2018 20.11.18 9:00 32.0 26.0 225 3.9 0
2018 20.11.18 10:00 30.4 27.3 214 4.1 0
2018 20.11.18 11:00 28.8 28.6 203 4.3 0
2018 20.11.18 12:00 36.0 18.0 225 3.9 0
2018 20.11.18 13:00 37.8 17.1 236 4.1 0
2018 20.11.18 14:00 39.6 16.2 248 4.3 0
2018 20.11.18 15:00 35.0 22.0 225 3.9 0
2018 20.11.18 16:00 36.8 20.9 236 3.7 0
2018 20.11.18 17:00 38.5 19.8 248 3.5 0
2018 20.11.18 18:00 29.0 33.0 203 3.9 0
2018 20.11.18 19:00 30.5 31.4 213 3.7 0
2018 20.11.18 20:00 31.9 29.7 223 3.5 0
2018 20.11.18 21:00 26.0 29.0 203 7.7 0
2018 20.11.18 22:00 27.3 30.5 213 7.3 0
A-177
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 20.11.18 23:00 28.6 31.9 223 6.9 0
2018 21.11.18 0:00 22.0 28.0 225 11.7 0
2018 21.11.18 1:00 20.9 29.4 214 12.3 0
2018 21.11.18 2:00 19.8 30.8 203 12.9 0
2018 21.11.18 3:00 22.0 28.0 225 11.7 0
2018 21.11.18 4:00 20.9 29.4 214 12.3 0
2018 21.11.18 5:00 19.8 30.8 203 12.9 0
2018 21.11.18 6:00 23.0 30.0 225 11.7 0
2018 21.11.18 7:00 21.9 31.5 214 12.3 0
2018 21.11.18 8:00 20.7 33.0 203 12.9 0
2018 21.11.18 9:00 31.0 29.0 203 7.7 0
2018 21.11.18 10:00 32.6 27.6 192 8.1 0
2018 21.11.18 11:00 34.1 26.1 182 8.5 0
2018 21.11.18 12:00 35.0 20.0 203 7.7 0
2018 21.11.18 13:00 36.8 19.0 213 8.1 0
2018 21.11.18 14:00 38.5 18.0 223 8.5 0
2018 21.11.18 15:00 35.0 22.0 225 7.7 0
2018 21.11.18 16:00 36.8 20.9 236 7.3 0
2018 21.11.18 17:00 38.5 19.8 248 6.9 0
2018 21.11.18 18:00 30.0 31.0 203 7.7 0
2018 21.11.18 19:00 31.5 32.6 213 7.3 0
2018 21.11.18 20:00 33.0 34.1 223 6.9 0
2018 21.11.18 21:00 27.0 29.0 203 7.7 0
2018 21.11.18 22:00 25.7 30.5 213 7.3 0
2018 21.11.18 23:00 24.3 31.9 223 6.9 0
2018 22.11.18 0:00 26.0 29.0 225 11.7 0
2018 22.11.18 1:00 24.7 30.5 214 12.3 0
2018 22.11.18 2:00 23.4 31.9 203 12.9 0
2018 22.11.18 3:00 23.0 29.0 203 15.5 0
2018 22.11.18 4:00 21.9 30.5 192 16.3 0
2018 22.11.18 5:00 20.7 31.9 182 17.1 0
2018 22.11.18 6:00 24.0 31.0 225 13.7 0
2018 22.11.18 7:00 25.2 29.5 214 14.4 0
2018 22.11.18 8:00 26.4 27.9 203 15.1 0
2018 22.11.18 9:00 30.0 30.0 225 11.7 0
2018 22.11.18 10:00 31.5 28.5 214 12.3 0
2018 22.11.18 11:00 33.0 27.0 203 12.9 0
2018 22.11.18 12:00 36.0 20.0 225 7.7 0
2018 22.11.18 13:00 37.8 19.0 236 8.1 0
2018 22.11.18 14:00 39.6 18.0 248 8.5 0
2018 22.11.18 15:00 36.0 22.0 225 7.7 0
2018 22.11.18 16:00 37.8 20.9 236 7.3 0
2018 22.11.18 17:00 39.6 19.8 248 6.9 0
2018 22.11.18 18:00 32.0 31.0 203 7.7 0
2018 22.11.18 19:00 30.4 32.6 213 7.3 0
2018 22.11.18 20:00 28.8 34.1 223 6.9 0
2018 22.11.18 21:00 29.0 30.0 203 7.7 0
2018 22.11.18 22:00 27.6 31.5 213 7.3 0
2018 22.11.18 23:00 26.1 33.0 223 6.9 0
A-178
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 23.11.18 0:00 26.0 29.0 203 7.7 0
2018 23.11.18 1:00 24.7 30.5 192 10.2 0
2018 23.11.18 2:00 23.4 31.9 182 10.7 0
2018 23.11.18 3:00 23.0 28.0 225 13.7 0
2018 23.11.18 4:00 24.2 29.4 214 14.4 0
2018 23.11.18 5:00 25.3 30.8 203 15.1 0
2018 23.11.18 6:00 23.0 29.0 225 11.7 0
2018 23.11.18 7:00 24.2 27.6 214 12.3 0
2018 23.11.18 8:00 25.3 26.1 203 12.9 0
2018 23.11.18 9:00 30.0 28.0 203 7.7 0
2018 23.11.18 10:00 31.5 26.6 192 8.1 0
2018 23.11.18 11:00 33.0 25.2 182 8.5 0
2018 23.11.18 12:00 35.0 19.0 203 7.7 0
2018 23.11.18 13:00 36.8 18.1 260 8.1 0
2018 23.11.18 14:00 38.5 17.1 272 8.5 0
2018 23.11.18 15:00 35.0 22.0 248 7.7 0
2018 23.11.18 16:00 33.3 23.1 260 7.3 0
2018 23.11.18 17:00 31.5 24.2 272 6.9 0
2018 23.11.18 18:00 30.0 31.0 203 3.9 0
2018 23.11.18 19:00 28.5 32.6 213 3.7 0
2018 23.11.18 20:00 27.0 34.1 223 3.5 0
2018 23.11.18 21:00 27.0 27.0 203 11.7 0
2018 23.11.18 22:00 25.7 28.4 213 11.1 0
2018 23.11.18 23:00 24.3 29.7 223 10.5 0
2018 24.11.18 0:00 26.0 26.0 225 13.7 0
2018 24.11.18 1:00 27.3 27.3 214 14.4 0
2018 24.11.18 2:00 28.6 28.6 203 15.1 0
2018 24.11.18 3:00 23.0 26.0 225 13.7 0
2018 24.11.18 4:00 24.2 24.7 214 14.4 0
2018 24.11.18 5:00 25.3 23.4 203 15.1 0
2018 24.11.18 6:00 23.0 29.0 248 13.7 0
2018 24.11.18 7:00 24.2 27.6 235 14.4 0
2018 24.11.18 8:00 25.3 26.1 223 15.1 0
2018 24.11.18 9:00 29.0 29.0 248 13.7 0
2018 24.11.18 10:00 30.5 27.6 235 14.4 0
2018 24.11.18 11:00 31.9 26.1 223 15.1 0
2018 24.11.18 12:00 34.0 20.0 248 15.5 0
2018 24.11.18 13:00 32.3 21.0 260 16.3 0
2018 24.11.18 14:00 30.6 22.0 272 17.1 0
2018 24.11.18 15:00 34.0 21.0 225 15.5 0
2018 24.11.18 16:00 32.3 22.1 236 14.7 0
2018 24.11.18 17:00 30.6 23.1 248 14.0 0
2018 24.11.18 18:00 30.0 27.0 203 13.7 0
2018 24.11.18 19:00 28.5 28.4 213 13.0 0
2018 24.11.18 20:00 27.0 29.7 223 12.3 0
2018 24.11.18 21:00 28.0 25.0 225 15.5 0
2018 24.11.18 22:00 29.4 26.3 236 14.7 0
2018 24.11.18 23:00 30.8 27.5 248 14.0 0
2018 25.11.18 0:00 24.0 24.0 248 17.5 0
A-179
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 25.11.18 1:00 25.2 22.8 235 18.4 0
2018 25.11.18 2:00 26.4 21.6 223 19.3 0
2018 25.11.18 3:00 21.0 25.0 248 17.5 0
2018 25.11.18 4:00 22.1 23.8 235 18.4 0
2018 25.11.18 5:00 23.1 22.5 223 19.3 0
2018 25.11.18 6:00 22.0 28.0 248 15.5 0
2018 25.11.18 7:00 23.1 26.6 235 16.3 0
2018 25.11.18 8:00 24.2 25.2 223 17.1 0
2018 25.11.18 9:00 29.0 29.0 248 13.7 0
2018 25.11.18 10:00 27.6 27.6 235 14.4 0
2018 25.11.18 11:00 26.1 26.1 223 15.1 0
2018 25.11.18 12:00 35.0 19.0 248 15.5 0
2018 25.11.18 13:00 33.3 20.0 260 16.3 0
2018 25.11.18 14:00 31.5 20.9 272 17.1 0
2018 25.11.18 15:00 36.0 19.0 225 13.7 0
2018 25.11.18 16:00 34.2 20.0 236 13.0 0
2018 25.11.18 17:00 32.4 20.9 248 12.3 0
2018 25.11.18 18:00 31.0 25.0 203 11.7 0
2018 25.11.18 19:00 32.6 26.3 213 11.1 0
2018 25.11.18 20:00 34.1 27.5 223 10.5 0
2018 25.11.18 21:00 28.0 22.0 225 15.5 0
2018 25.11.18 22:00 29.4 23.1 236 14.7 0
2018 25.11.18 23:00 30.8 24.2 248 14.0 0
2018 26.11.18 0:00 24.0 22.0 248 13.7 0
2018 26.11.18 1:00 25.2 20.9 235 14.4 0
2018 26.11.18 2:00 26.4 19.8 223 15.1 0
2018 26.11.18 3:00 23.0 23.0 248 15.5 0
2018 26.11.18 4:00 24.2 21.9 235 16.3 0
2018 26.11.18 5:00 25.3 20.7 223 17.1 0
2018 26.11.18 6:00 23.0 27.0 248 13.7 0
2018 26.11.18 7:00 21.9 25.7 235 14.4 0
2018 26.11.18 8:00 20.7 24.3 223 15.1 0
2018 26.11.18 9:00 30.0 27.0 248 11.7 0
2018 26.11.18 10:00 28.5 28.4 235 12.3 0
2018 26.11.18 11:00 27.0 29.7 223 12.9 0
2018 26.11.18 12:00 35.0 18.0 248 13.7 0
2018 26.11.18 13:00 33.3 18.9 260 14.4 0
2018 26.11.18 14:00 31.5 19.8 272 15.1 0
2018 26.11.18 15:00 35.0 20.0 225 13.7 0
2018 26.11.18 16:00 36.8 21.0 236 13.0 0
2018 26.11.18 17:00 38.5 22.0 248 12.3 0
2018 26.11.18 18:00 32.0 27.0 203 13.7 0
2018 26.11.18 19:00 33.6 28.4 213 13.0 0
2018 26.11.18 20:00 35.2 29.7 223 12.3 0
2018 26.11.18 21:00 29.0 25.0 225 13.7 0
2018 26.11.18 22:00 30.5 23.8 236 13.0 0
2018 26.11.18 23:00 31.9 22.5 248 12.3 0
2018 27.11.18 0:00 24.0 25.0 225 13.7 0
2018 27.11.18 1:00 25.2 23.8 214 14.4 0
A-180
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 27.11.18 2:00 26.4 22.5 203 15.1 0
2018 27.11.18 3:00 23.0 28.0 225 13.7 0
2018 27.11.18 4:00 21.9 26.6 214 14.4 0
2018 27.11.18 5:00 20.7 25.2 203 15.1 0
2018 27.11.18 6:00 23.0 31.0 225 13.7 0
2018 27.11.18 7:00 21.9 32.6 214 14.4 0
2018 27.11.18 8:00 20.7 34.1 203 15.1 0
2018 27.11.18 9:00 30.0 29.0 248 11.7 0
2018 27.11.18 10:00 28.5 30.5 235 12.3 0
2018 27.11.18 11:00 27.0 31.9 223 12.9 0
2018 27.11.18 12:00 36.0 19.0 248 11.7 0
2018 27.11.18 13:00 37.8 20.0 260 12.3 0
2018 27.11.18 14:00 39.6 20.9 272 12.9 0
2018 27.11.18 15:00 37.0 20.0 225 11.7 0
2018 27.11.18 16:00 38.9 21.0 236 11.1 0
2018 27.11.18 17:00 40.7 22.0 248 10.5 0
2018 27.11.18 18:00 33.0 26.0 203 11.7 0
2018 27.11.18 19:00 34.7 24.7 213 11.1 0
2018 27.11.18 20:00 36.3 23.4 223 10.5 0
2018 27.11.18 21:00 31.0 24.0 203 11.7 0
2018 27.11.18 22:00 32.6 22.8 213 11.1 0
2018 27.11.18 23:00 34.1 21.6 223 10.5 0
2018 28.11.18 0:00 28.0 23.0 225 11.7 0
2018 28.11.18 1:00 26.6 21.9 214 12.3 0
2018 28.11.18 2:00 25.2 20.7 203 12.9 0
2018 28.11.18 3:00 24.0 24.0 225 13.7 0
2018 28.11.18 4:00 22.8 22.8 214 14.4 0
2018 28.11.18 5:00 21.6 21.6 203 15.1 0
2018 28.11.18 6:00 24.0 26.0 225 13.7 0
2018 28.11.18 7:00 22.8 27.3 214 14.4 0
2018 28.11.18 8:00 21.6 28.6 203 15.1 0
2018 28.11.18 9:00 30.0 24.0 248 11.7 0
2018 28.11.18 10:00 31.5 25.2 235 12.3 0
2018 28.11.18 11:00 33.0 26.4 223 12.9 0
2018 28.11.18 12:00 37.0 17.0 225 11.7 0
2018 28.11.18 13:00 38.9 17.9 236 12.3 0
2018 28.11.18 14:00 40.7 18.7 248 12.9 0
2018 28.11.18 15:00 37.0 19.0 203 11.7 0
2018 28.11.18 16:00 38.9 20.0 213 11.1 0
2018 28.11.18 17:00 40.7 20.9 223 10.5 0
2018 28.11.18 18:00 33.0 26.0 203 11.7 0
2018 28.11.18 19:00 34.7 24.7 213 11.1 0
2018 28.11.18 20:00 36.3 23.4 223 10.5 0
2018 28.11.18 21:00 29.0 26.0 203 11.7 0
2018 28.11.18 22:00 27.6 24.7 213 11.1 0
2018 28.11.18 23:00 26.1 23.4 223 10.5 0
2018 29.11.18 0:00 26.0 28.0 203 9.7 0
2018 29.11.18 1:00 24.7 26.6 192 10.2 0
2018 29.11.18 2:00 23.4 25.2 182 10.7 0
A-181
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 29.11.18 3:00 23.0 29.0 203 9.7 0
2018 29.11.18 4:00 21.9 30.5 192 10.2 0
2018 29.11.18 5:00 20.7 31.9 182 10.7 0
2018 29.11.18 6:00 24.0 29.0 225 9.7 0
2018 29.11.18 7:00 25.2 30.5 214 10.2 0
2018 29.11.18 8:00 26.4 31.9 203 10.7 0
2018 29.11.18 9:00 31.0 24.0 248 9.7 0
2018 29.11.18 10:00 32.6 25.2 235 10.2 0
2018 29.11.18 11:00 34.1 26.4 223 10.7 0
2018 29.11.18 12:00 37.0 17.0 248 7.7 0
2018 29.11.18 13:00 38.9 17.9 260 8.1 0
2018 29.11.18 14:00 40.7 18.7 272 8.5 0
2018 29.11.18 15:00 37.0 19.0 225 7.7 0
2018 29.11.18 16:00 38.9 18.1 236 7.3 0
2018 29.11.18 17:00 40.7 17.1 248 6.9 0
2018 29.11.18 18:00 33.0 26.0 203 9.7 0
2018 29.11.18 19:00 31.4 24.7 213 9.2 0
2018 29.11.18 20:00 29.7 23.4 223 8.7 0
2018 29.11.18 21:00 31.0 25.0 203 11.7 0
2018 29.11.18 22:00 29.5 23.8 213 11.1 0
2018 29.11.18 23:00 27.9 22.5 223 10.5 0
2018 30.11.18 0:00 28.0 26.0 225 11.7 0
2018 30.11.18 1:00 26.6 27.3 214 12.3 0
2018 30.11.18 2:00 25.2 28.6 203 12.9 0
2018 30.11.18 3:00 24.0 27.0 225 13.7 0
2018 30.11.18 4:00 25.2 28.4 214 14.4 0
2018 30.11.18 5:00 26.4 29.7 203 15.1 0
2018 30.11.18 6:00 24.0 29.0 225 11.7 0
2018 30.11.18 7:00 25.2 30.5 214 12.3 0
2018 30.11.18 8:00 26.4 31.9 203 12.9 0
2018 30.11.18 9:00 31.0 28.0 225 3.9 0
2018 30.11.18 10:00 32.6 29.4 214 4.1 0
2018 30.11.18 11:00 34.1 30.8 203 4.3 0
2018 30.11.18 12:00 37.0 18.0 293 0.0 0
2018 30.11.18 13:00 38.9 17.1 307 0.0 0
2018 30.11.18 14:00 40.7 16.2 322 0.0 0
2018 30.11.18 15:00 37.0 20.0 135 3.9 0
2018 30.11.18 16:00 35.2 19.0 142 3.7 0
2018 30.11.18 17:00 33.3 18.0 149 3.5 0
2018 30.11.18 18:00 32.0 28.0 270 7.7 0
2018 30.11.18 19:00 30.4 26.6 284 7.3 0
2018 30.11.18 20:00 28.8 25.2 297 6.9 0
2018 30.11.18 21:00 28.0 27.0 180 11.7 0
2018 30.11.18 22:00 26.6 25.7 189 11.1 0
2018 30.11.18 23:00 25.2 24.3 198 10.5 0
2018 01.12.18 0:00 24.0 28.0 180 13.7 0
2018 01.12.18 1:00 25.2 29.4 171 14.4 0
2018 01.12.18 2:00 26.4 30.8 162 15.1 0
2018 01.12.18 3:00 23.0 32.0 203 13.7 0
A-182
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 01.12.18 4:00 24.2 33.6 192 14.4 0
2018 01.12.18 5:00 25.3 35.2 182 15.1 0
2018 01.12.18 6:00 23.0 34.0 225 11.7 0
2018 01.12.18 7:00 24.2 35.7 214 12.3 0
2018 01.12.18 8:00 25.3 37.4 203 12.9 0
2018 01.12.18 9:00 29.0 28.0 225 11.7 0
2018 01.12.18 10:00 30.5 29.4 214 12.3 0
2018 01.12.18 11:00 31.9 30.8 203 12.9 0
2018 01.12.18 12:00 36.0 19.0 225 7.7 0
2018 01.12.18 13:00 34.2 18.1 236 8.1 0
2018 01.12.18 14:00 32.4 17.1 248 8.5 0
2018 01.12.18 15:00 36.0 20.0 203 7.7 0
2018 01.12.18 16:00 34.2 19.0 213 7.3 0
2018 01.12.18 17:00 32.4 18.0 223 6.9 0
2018 01.12.18 18:00 31.0 26.0 180 11.7 0
2018 01.12.18 19:00 29.5 24.7 189 11.1 0
2018 01.12.18 20:00 27.9 23.4 198 10.5 0
2018 01.12.18 21:00 37.0 26.0 203 13.7 0
2018 01.12.18 22:00 38.9 27.3 213 13.0 0
2018 01.12.18 23:00 40.7 28.6 223 12.3 0
2018 02.12.18 0:00 24.0 28.0 225 13.7 0
2018 02.12.18 1:00 25.2 29.4 214 14.4 0
2018 02.12.18 2:00 26.4 30.8 203 15.1 0
2018 02.12.18 3:00 23.0 32.0 225 15.5 0
2018 02.12.18 4:00 24.2 33.6 214 16.3 0
2018 02.12.18 5:00 25.3 35.2 203 17.1 0
2018 02.12.18 6:00 22.0 35.0 225 17.5 0
2018 02.12.18 7:00 23.1 36.8 214 18.4 0
2018 02.12.18 8:00 24.2 38.5 203 19.3 0
2018 02.12.18 9:00 27.0 34.0 248 19.4 0
2018 02.12.18 10:00 28.4 32.3 235 20.4 0
2018 02.12.18 11:00 29.7 30.6 223 21.3 0
2018 02.12.18 12:00 33.0 24.0 248 21.4 0
2018 02.12.18 13:00 31.4 22.8 260 22.5 0
2018 02.12.18 14:00 29.7 21.6 272 23.5 0
2018 02.12.18 15:00 34.0 25.0 225 19.4 0
2018 02.12.18 16:00 32.3 23.8 236 18.4 0
2018 02.12.18 17:00 30.6 22.5 248 17.5 0
2018 02.12.18 18:00 31.0 32.0 203 15.5 0
2018 02.12.18 19:00 29.5 33.6 213 14.7 0
2018 02.12.18 20:00 27.9 35.2 223 14.0 0
2018 02.12.18 21:00 27.0 33.0 225 17.5 0
2018 02.12.18 22:00 28.4 34.7 236 16.6 0
2018 02.12.18 23:00 29.7 36.3 248 15.8 0
2018 03.12.18 0:00 23.0 36.0 248 19.4 0
2018 03.12.18 1:00 24.2 37.8 235 20.4 0
2018 03.12.18 2:00 25.3 39.6 223 21.3 0
2018 03.12.18 3:00 22.0 38.0 248 17.5 0
2018 03.12.18 4:00 23.1 39.9 235 18.4 0
A-183
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 03.12.18 5:00 24.2 41.8 223 19.3 0
2018 03.12.18 6:00 22.0 41.0 248 19.4 0
2018 03.12.18 7:00 23.1 39.0 235 20.4 0
2018 03.12.18 8:00 24.2 36.9 223 21.3 0
2018 03.12.18 9:00 26.0 39.0 248 21.4 0
2018 03.12.18 10:00 24.7 37.1 235 22.5 0
2018 03.12.18 11:00 23.4 35.1 223 23.5 0
2018 03.12.18 12:00 33.0 28.0 270 21.4 0
2018 03.12.18 13:00 31.4 26.6 284 22.5 0
2018 03.12.18 14:00 29.7 25.2 297 23.5 0
2018 03.12.18 15:00 35.0 27.0 248 15.5 0
2018 03.12.18 16:00 33.3 25.7 260 14.7 0
2018 03.12.18 17:00 31.5 24.3 272 14.0 0
2018 03.12.18 18:00 32.0 34.0 225 13.7 0
2018 03.12.18 19:00 33.6 35.7 236 13.0 0
2018 03.12.18 20:00 35.2 37.4 248 12.3 0
2018 03.12.18 21:00 29.0 35.0 225 17.5 0
2018 03.12.18 22:00 30.5 36.8 236 16.6 0
2018 03.12.18 23:00 31.9 38.5 248 15.8 0
2018 04.12.18 0:00 24.0 37.0 248 19.4 0
2018 04.12.18 1:00 25.2 38.9 235 20.4 0
2018 04.12.18 2:00 26.4 40.7 223 21.3 0
2018 04.12.18 3:00 21.0 41.0 248 19.4 0
2018 04.12.18 4:00 22.1 43.1 235 20.4 0
2018 04.12.18 5:00 23.1 45.1 223 21.3 0
2018 04.12.18 6:00 21.0 46.0 248 19.4 0
2018 04.12.18 7:00 20.0 43.7 235 20.4 0
2018 04.12.18 8:00 18.9 41.4 223 21.3 0
2018 04.12.18 9:00 26.0 46.0 248 19.4 0
2018 04.12.18 10:00 24.7 43.7 235 20.4 0
2018 04.12.18 11:00 23.4 41.4 223 21.3 0
2018 04.12.18 12:00 34.0 32.0 248 15.5 0
2018 04.12.18 13:00 32.3 30.4 260 16.3 0
2018 04.12.18 14:00 30.6 28.8 272 17.1 0
2018 04.12.18 15:00 36.0 30.0 225 11.7 0
2018 04.12.18 16:00 37.8 31.5 236 11.1 0
2018 04.12.18 17:00 39.6 33.0 248 10.5 0
2018 04.12.18 18:00 32.0 36.0 203 13.7 0
2018 04.12.18 19:00 33.6 37.8 213 13.0 0
2018 04.12.18 20:00 35.2 39.6 223 12.3 0
2018 04.12.18 21:00 29.0 36.0 225 17.5 0
2018 04.12.18 22:00 30.5 37.8 236 16.6 0
2018 04.12.18 23:00 31.9 39.6 248 15.8 0
2018 05.12.18 0:00 24.0 38.0 225 17.5 0
2018 05.12.18 1:00 25.2 39.9 214 18.4 0
2018 05.12.18 2:00 26.4 41.8 203 19.3 0
2018 05.12.18 3:00 21.0 42.0 248 17.5 0
2018 05.12.18 4:00 20.0 39.9 235 18.4 0
2018 05.12.18 5:00 18.9 37.8 223 19.3 0
A-184
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 05.12.18 6:00 22.0 45.0 248 17.5 0
2018 05.12.18 7:00 20.9 42.8 235 18.4 0
2018 05.12.18 8:00 19.8 40.5 223 19.3 0
2018 05.12.18 9:00 27.0 41.0 248 13.7 0
2018 05.12.18 10:00 25.7 39.0 235 14.4 0
2018 05.12.18 11:00 24.3 36.9 223 15.1 0
2018 05.12.18 12:00 34.0 28.0 248 11.7 0
2018 05.12.18 13:00 35.7 29.4 260 12.3 0
2018 05.12.18 14:00 37.4 30.8 272 12.9 0
2018 05.12.18 15:00 35.0 25.0 203 9.7 0
2018 05.12.18 16:00 36.8 26.3 213 9.2 0
2018 05.12.18 17:00 38.5 27.5 223 8.7 0
2018 05.12.18 18:00 31.0 32.0 203 13.7 0
2018 05.12.18 19:00 32.6 33.6 213 13.0 0
2018 05.12.18 20:00 34.1 35.2 223 12.3 0
2018 05.12.18 21:00 28.0 29.0 225 15.5 0
2018 05.12.18 22:00 29.4 30.5 236 14.7 0
2018 05.12.18 23:00 30.8 31.9 248 14.0 0
2018 06.12.18 0:00 24.0 25.0 225 13.7 0
2018 06.12.18 1:00 22.8 23.8 214 14.4 0
2018 06.12.18 2:00 21.6 22.5 203 15.1 0
2018 06.12.18 3:00 21.0 25.0 225 13.7 0
2018 06.12.18 4:00 20.0 23.8 214 14.4 0
2018 06.12.18 5:00 18.9 22.5 203 15.1 0
2018 06.12.18 6:00 21.0 30.0 225 15.5 0
2018 06.12.18 7:00 20.0 28.5 214 16.3 0
2018 06.12.18 8:00 18.9 27.0 203 17.1 0
2018 06.12.18 9:00 26.0 30.0 248 17.5 0
2018 06.12.18 10:00 27.3 28.5 235 18.4 0
2018 06.12.18 11:00 28.6 27.0 223 19.3 0
2018 06.12.18 12:00 33.0 19.0 248 17.5 0
2018 06.12.18 13:00 34.7 20.0 260 18.4 0
2018 06.12.18 14:00 36.3 20.9 272 19.3 0
2018 06.12.18 15:00 35.0 20.0 248 13.7 0
2018 06.12.18 16:00 36.8 21.0 260 13.0 0
2018 06.12.18 17:00 38.5 22.0 272 12.3 0
2018 06.12.18 18:00 31.0 27.0 225 11.7 0
2018 06.12.18 19:00 32.6 28.4 236 11.1 0
2018 06.12.18 20:00 34.1 29.7 248 10.5 0
2018 06.12.18 21:00 29.0 26.0 225 13.7 0
2018 06.12.18 22:00 27.6 27.3 236 13.0 0
2018 06.12.18 23:00 26.1 28.6 248 12.3 0
2018 07.12.18 0:00 24.0 27.0 248 15.5 0
2018 07.12.18 1:00 22.8 25.7 235 16.3 0
2018 07.12.18 2:00 21.6 24.3 223 17.1 0
2018 07.12.18 3:00 21.0 29.0 248 17.5 0
2018 07.12.18 4:00 20.0 27.6 235 18.4 0
2018 07.12.18 5:00 18.9 26.1 223 19.3 0
2018 07.12.18 6:00 21.0 33.0 248 17.5 0
A-185
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 07.12.18 7:00 22.1 31.4 235 18.4 0
2018 07.12.18 8:00 23.1 29.7 223 19.3 0
2018 07.12.18 9:00 27.0 31.0 248 15.5 0
2018 07.12.18 10:00 28.4 32.6 235 16.3 0
2018 07.12.18 11:00 29.7 34.1 223 17.1 0
2018 07.12.18 12:00 34.0 21.0 270 15.5 0
2018 07.12.18 13:00 35.7 22.1 284 16.3 0
2018 07.12.18 14:00 37.4 23.1 297 17.1 0
2018 07.12.18 15:00 35.0 22.0 248 11.7 0
2018 07.12.18 16:00 36.8 23.1 260 11.1 0
2018 07.12.18 17:00 38.5 24.2 272 10.5 0
2018 07.12.18 18:00 31.0 30.0 225 9.7 0
2018 07.12.18 19:00 29.5 31.5 236 9.2 0
2018 07.12.18 20:00 27.9 33.0 248 8.7 0
2018 07.12.18 21:00 28.0 29.0 225 13.7 0
2018 07.12.18 22:00 26.6 27.6 236 13.0 0
2018 07.12.18 23:00 25.2 26.1 248 12.3 0
2018 08.12.18 0:00 23.0 29.0 248 13.7 0
2018 08.12.18 1:00 21.9 27.6 235 14.4 0
2018 08.12.18 2:00 20.7 26.1 223 15.1 0
2018 08.12.18 3:00 22.0 31.0 248 13.7 0
2018 08.12.18 4:00 23.1 29.5 235 14.4 0
2018 08.12.18 5:00 24.2 27.9 223 15.1 0
2018 08.12.18 6:00 22.0 33.0 248 13.7 0
2018 08.12.18 7:00 23.1 34.7 235 14.4 0
2018 08.12.18 8:00 24.2 36.3 223 15.1 0
2018 08.12.18 9:00 28.0 30.0 248 11.7 0
2018 08.12.18 10:00 29.4 31.5 235 12.3 0
2018 08.12.18 11:00 30.8 33.0 223 12.9 0
2018 08.12.18 12:00 34.0 20.0 248 11.7 0
2018 08.12.18 13:00 35.7 21.0 260 12.3 0
2018 08.12.18 14:00 37.4 22.0 272 12.9 0
2018 08.12.18 15:00 35.0 21.0 225 11.7 0
2018 08.12.18 16:00 33.3 22.1 236 11.1 0
2018 08.12.18 17:00 31.5 23.1 248 10.5 0
2018 08.12.18 18:00 30.0 28.0 203 11.7 0
2018 08.12.18 19:00 28.5 26.6 213 11.1 0
2018 08.12.18 20:00 27.0 25.2 223 10.5 0
2018 08.12.18 21:00 26.0 28.0 203 11.7 0
2018 08.12.18 22:00 24.7 26.6 213 11.1 0
2018 08.12.18 23:00 23.4 25.2 223 10.5 0
2018 09.12.18 0:00 23.0 29.0 225 11.7 0
2018 09.12.18 1:00 24.2 27.6 214 12.3 0
2018 09.12.18 2:00 25.3 26.1 203 12.9 0
2018 09.12.18 3:00 22.0 30.0 225 11.7 0
2018 09.12.18 4:00 23.1 28.5 214 12.3 0
2018 09.12.18 5:00 24.2 27.0 203 12.9 0
2018 09.12.18 6:00 22.0 31.0 248 11.7 0
2018 09.12.18 7:00 23.1 32.6 235 12.3 0
A-186
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 09.12.18 8:00 24.2 34.1 223 12.9 0
2018 09.12.18 9:00 29.0 27.0 248 9.7 0
2018 09.12.18 10:00 30.5 28.4 235 10.2 0
2018 09.12.18 11:00 31.9 29.7 223 10.7 0
2018 09.12.18 12:00 35.0 18.0 248 7.7 0
2018 09.12.18 13:00 33.3 18.9 260 8.1 0
2018 09.12.18 14:00 31.5 19.8 272 8.5 0
2018 09.12.18 15:00 36.0 21.0 225 3.9 0
2018 09.12.18 16:00 34.2 22.1 236 3.7 0
2018 09.12.18 17:00 32.4 23.1 248 3.5 0
2018 09.12.18 18:00 32.0 30.0 203 7.7 0
2018 09.12.18 19:00 30.4 28.5 213 7.3 0
2018 09.12.18 20:00 28.8 27.0 223 6.9 0
2018 09.12.18 21:00 30.0 34.0 225 7.7 0
2018 09.12.18 22:00 31.5 32.3 236 7.3 0
2018 09.12.18 23:00 33.0 30.6 248 6.9 0
2018 10.12.18 0:00 27.0 37.0 225 7.7 0
2018 10.12.18 1:00 28.4 35.2 214 8.1 0
2018 10.12.18 2:00 29.7 33.3 203 8.5 0
2018 10.12.18 3:00 22.0 34.0 225 11.7 0
2018 10.12.18 4:00 23.1 35.7 214 12.3 0
2018 10.12.18 5:00 24.2 37.4 203 12.9 0
2018 10.12.18 6:00 22.0 35.0 248 11.7 0
2018 10.12.18 7:00 23.1 36.8 235 12.3 0
2018 10.12.18 8:00 24.2 38.5 223 12.9 0
2018 10.12.18 9:00 29.0 31.0 248 3.9 0
2018 10.12.18 10:00 27.6 32.6 235 4.1 0
2018 10.12.18 11:00 26.1 34.1 223 4.3 0
2018 10.12.18 12:00 35.0 20.0 315 0.0 0
2018 10.12.18 13:00 33.3 21.0 331 0.0 0
2018 10.12.18 14:00 31.5 22.0 347 0.0 0
2018 10.12.18 15:00 35.0 22.0 203 3.9 0
2018 10.12.18 16:00 33.3 20.9 213 3.7 0
2018 10.12.18 17:00 31.5 19.8 223 3.5 0
2018 10.12.18 18:00 31.0 32.0 270 7.7 0
2018 10.12.18 19:00 32.6 30.4 284 7.3 0
2018 10.12.18 20:00 34.1 28.8 297 6.9 0
2018 10.12.18 21:00 29.0 34.0 203 9.7 0
2018 10.12.18 22:00 30.5 32.3 213 9.2 0
2018 10.12.18 23:00 31.9 30.6 223 8.7 0
2018 11.12.18 0:00 23.0 36.0 203 11.7 0
2018 11.12.18 1:00 24.2 37.8 192 12.3 0
2018 11.12.18 2:00 25.3 39.6 182 12.9 0
2018 11.12.18 3:00 21.0 39.0 225 13.7 0
2018 11.12.18 4:00 22.1 41.0 214 14.4 0
2018 11.12.18 5:00 23.1 42.9 203 15.1 0
2018 11.12.18 6:00 22.0 40.0 270 11.7 0
2018 11.12.18 7:00 20.9 42.0 257 12.3 0
2018 11.12.18 8:00 19.8 44.0 243 12.9 0
A-187
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 11.12.18 9:00 28.0 31.0 248 11.7 0
2018 11.12.18 10:00 26.6 32.6 235 12.3 0
2018 11.12.18 11:00 25.2 34.1 223 12.9 0
2018 11.12.18 12:00 34.0 19.0 225 11.7 0
2018 11.12.18 13:00 32.3 18.1 236 12.3 0
2018 11.12.18 14:00 30.6 17.1 248 12.9 0
2018 11.12.18 15:00 35.0 21.0 203 11.7 0
2018 11.12.18 16:00 36.8 20.0 213 11.1 0
2018 11.12.18 17:00 38.5 18.9 223 10.5 0
2018 11.12.18 18:00 31.0 32.0 203 11.7 0
2018 11.12.18 19:00 32.6 30.4 213 11.1 0
2018 11.12.18 20:00 34.1 28.8 223 10.5 0
2018 11.12.18 21:00 27.0 37.0 180 11.7 0
2018 11.12.18 22:00 28.4 35.2 189 11.1 0
2018 11.12.18 23:00 29.7 33.3 198 10.5 0
2018 12.12.18 0:00 23.0 44.0 203 13.7 0
2018 12.12.18 1:00 24.2 46.2 192 14.4 0
2018 12.12.18 2:00 25.3 48.4 182 15.1 0
2018 12.12.18 3:00 22.0 51.0 203 15.5 0
2018 12.12.18 4:00 20.9 53.6 192 16.3 0
2018 12.12.18 5:00 19.8 56.1 182 17.1 0
2018 12.12.18 6:00 22.0 53.0 203 13.7 0
2018 12.12.18 7:00 20.9 55.7 192 14.4 0
2018 12.12.18 8:00 19.8 58.3 182 15.1 0
2018 12.12.18 9:00 28.0 45.0 225 13.7 0
2018 12.12.18 10:00 26.6 47.3 214 14.4 0
2018 12.12.18 11:00 25.2 49.5 203 15.1 0
2018 12.12.18 12:00 34.0 30.0 203 13.7 0
2018 12.12.18 13:00 35.7 28.5 213 14.4 0
2018 12.12.18 14:00 37.4 27.0 223 15.1 0
2018 12.12.18 15:00 35.0 28.0 293 11.7 0
2018 12.12.18 16:00 36.8 26.6 307 11.1 0
2018 12.12.18 17:00 38.5 25.2 322 10.5 0
2018 12.12.18 18:00 32.0 35.0 270 11.7 0
2018 12.12.18 19:00 33.6 33.3 284 11.1 0
2018 12.12.18 20:00 35.2 31.5 297 10.5 0
2018 12.12.18 21:00 29.0 36.0 315 13.7 0
2018 12.12.18 22:00 30.5 37.8 331 13.0 0
2018 12.12.18 23:00 31.9 39.6 347 12.3 0
2018 13.12.18 0:00 26.0 37.0 270 13.7 0
2018 13.12.18 1:00 24.7 38.9 257 14.4 0
2018 13.12.18 2:00 23.4 40.7 243 15.1 0
2018 13.12.18 3:00 21.0 37.0 203 13.7 0
2018 13.12.18 4:00 20.0 38.9 192 14.4 0
2018 13.12.18 5:00 18.9 40.7 182 15.1 0
2018 13.12.18 6:00 21.0 39.0 225 13.7 0
2018 13.12.18 7:00 20.0 41.0 214 14.4 0
2018 13.12.18 8:00 18.9 42.9 203 15.1 0
2018 13.12.18 9:00 27.0 35.0 203 13.7 0
A-188
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 13.12.18 10:00 28.4 33.3 192 14.4 0
2018 13.12.18 11:00 29.7 31.5 182 15.1 0
2018 13.12.18 12:00 33.0 24.0 203 13.7 0
2018 13.12.18 13:00 34.7 22.8 213 14.4 0
2018 13.12.18 14:00 36.3 21.6 223 15.1 0
2018 13.12.18 15:00 34.0 24.0 203 11.7 0
2018 13.12.18 16:00 35.7 22.8 213 11.1 0
2018 13.12.18 17:00 37.4 21.6 223 10.5 0
2018 13.12.18 18:00 30.0 31.0 180 11.7 0
2018 13.12.18 19:00 31.5 32.6 189 11.1 0
2018 13.12.18 20:00 33.0 34.1 198 10.5 0
2018 13.12.18 21:00 26.0 31.0 180 13.7 0
2018 13.12.18 22:00 24.7 32.6 189 13.0 0
2018 13.12.18 23:00 23.4 34.1 198 12.3 0
2018 14.12.18 0:00 22.0 31.0 203 15.5 0
2018 14.12.18 1:00 20.9 32.6 192 16.3 0
2018 14.12.18 2:00 19.8 34.1 182 17.1 0
2018 14.12.18 3:00 21.0 32.0 225 15.5 0
2018 14.12.18 4:00 20.0 33.6 214 16.3 0
2018 14.12.18 5:00 18.9 35.2 203 17.1 0
2018 14.12.18 6:00 21.0 36.0 225 17.5 0
2018 14.12.18 7:00 22.1 34.2 214 18.4 0
2018 14.12.18 8:00 23.1 32.4 203 19.3 0
2018 14.12.18 9:00 27.0 36.0 248 15.5 0
2018 14.12.18 10:00 28.4 34.2 235 16.3 0
2018 14.12.18 11:00 29.7 32.4 223 17.1 0
2018 14.12.18 12:00 34.0 23.0 270 15.5 0
2018 14.12.18 13:00 35.7 21.9 284 16.3 0
2018 14.12.18 14:00 37.4 20.7 297 17.1 0
2018 14.12.18 15:00 35.0 23.0 248 11.7 0
2018 14.12.18 16:00 36.8 21.9 260 11.1 0
2018 14.12.18 17:00 38.5 20.7 272 10.5 0
2018 14.12.18 18:00 31.0 30.0 225 11.7 0
2018 14.12.18 19:00 32.6 31.5 236 11.1 0
2018 14.12.18 20:00 34.1 33.0 248 10.5 0
2018 14.12.18 21:00 27.0 29.0 225 15.5 0
2018 14.12.18 22:00 25.7 30.5 236 14.7 0
2018 14.12.18 23:00 24.3 31.9 248 14.0 0
2018 15.12.18 0:00 23.0 32.0 225 17.5 0
2018 15.12.18 1:00 21.9 33.6 214 18.4 0
2018 15.12.18 2:00 20.7 35.2 203 19.3 0
2018 15.12.18 3:00 21.0 34.0 248 17.5 0
2018 15.12.18 4:00 20.0 35.7 235 18.4 0
2018 15.12.18 5:00 18.9 37.4 223 19.3 0
2018 15.12.18 6:00 22.0 36.0 248 15.5 0
2018 15.12.18 7:00 23.1 34.2 235 16.3 0
2018 15.12.18 8:00 24.2 32.4 223 17.1 0
2018 15.12.18 9:00 28.0 34.0 270 11.7 0
2018 15.12.18 10:00 29.4 32.3 257 12.3 0
A-189
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 15.12.18 11:00 30.8 30.6 243 12.9 0
2018 15.12.18 12:00 34.0 23.0 248 7.7 0
2018 15.12.18 13:00 35.7 21.9 260 8.1 0
2018 15.12.18 14:00 37.4 20.7 272 8.5 0
2018 15.12.18 15:00 35.0 24.0 225 7.7 0
2018 15.12.18 16:00 36.8 25.2 236 7.3 0
2018 15.12.18 17:00 38.5 26.4 248 6.9 0
2018 15.12.18 18:00 32.0 31.0 203 9.7 0
2018 15.12.18 19:00 30.4 32.6 213 9.2 0
2018 15.12.18 20:00 28.8 34.1 223 8.7 0
2018 15.12.18 21:00 29.0 30.0 203 13.7 0
2018 15.12.18 22:00 27.6 31.5 213 13.0 0
2018 15.12.18 23:00 26.1 33.0 297 12.3 0
2018 16.12.18 0:00 26.0 30.0 225 15.5 0
2018 16.12.18 1:00 24.7 31.5 214 16.3 0
2018 16.12.18 2:00 23.4 33.0 203 17.1 0
2018 16.12.18 3:00 22.0 32.0 225 13.7 0
2018 16.12.18 4:00 23.1 30.4 214 14.4 0
2018 16.12.18 5:00 24.2 28.8 203 15.1 0
2018 16.12.18 6:00 22.0 36.0 248 13.7 0
2018 16.12.18 7:00 23.1 34.2 235 14.4 0
2018 16.12.18 8:00 24.2 32.4 223 15.1 0
2018 16.12.18 9:00 28.0 35.0 248 11.7 0
2018 16.12.18 10:00 29.4 33.3 235 12.3 0
2018 16.12.18 11:00 30.8 31.5 223 12.9 0
2018 16.12.18 12:00 35.0 25.0 248 7.7 0
2018 16.12.18 13:00 36.8 26.3 260 8.1 0
2018 16.12.18 14:00 38.5 27.5 272 8.5 0
2018 16.12.18 15:00 36.0 27.0 315 3.9 0
2018 16.12.18 16:00 34.2 28.4 331 3.7 0
2018 16.12.18 17:00 32.4 29.7 347 3.5 0
2018 16.12.18 18:00 32.0 33.0 270 11.7 0
2018 16.12.18 19:00 30.4 34.7 284 11.1 0
2018 16.12.18 20:00 28.8 36.3 297 10.5 0
2018 16.12.18 21:00 29.0 31.0 270 13.7 0
2018 16.12.18 22:00 27.6 32.6 284 13.0 0
2018 16.12.18 23:00 26.1 34.1 297 12.3 0
2018 17.12.18 0:00 26.0 31.0 225 13.7 0
2018 17.12.18 1:00 27.3 29.5 214 14.4 0
2018 17.12.18 2:00 28.6 27.9 203 15.1 0
2018 17.12.18 3:00 22.0 33.0 225 13.7 0
2018 17.12.18 4:00 23.1 31.4 214 14.4 0
2018 17.12.18 5:00 24.2 29.7 203 15.1 0
2018 17.12.18 6:00 21.0 36.0 225 13.7 0
2018 17.12.18 7:00 22.1 34.2 214 14.4 0
2018 17.12.18 8:00 23.1 32.4 203 15.1 0
2018 17.12.18 9:00 27.0 33.0 225 15.5 0
2018 17.12.18 10:00 28.4 31.4 214 16.3 0
2018 17.12.18 11:00 29.7 29.7 203 17.1 0
A-190
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 17.12.18 12:00 33.0 23.0 225 17.5 0
2018 17.12.18 13:00 31.4 24.2 236 18.4 0
2018 17.12.18 14:00 29.7 25.3 248 19.3 0
2018 17.12.18 15:00 34.0 25.0 270 15.5 0
2018 17.12.18 16:00 32.3 26.3 284 14.7 0
2018 17.12.18 17:00 30.6 27.5 297 14.0 0
2018 17.12.18 18:00 31.0 35.0 270 9.7 0
2018 17.12.18 19:00 29.5 36.8 284 9.2 0
2018 17.12.18 20:00 27.9 38.5 297 8.7 0
2018 17.12.18 21:00 28.0 37.0 270 9.7 0
2018 17.12.18 22:00 29.4 38.9 284 9.2 0
2018 17.12.18 23:00 30.8 40.7 297 8.7 0
2018 18.12.18 0:00 23.0 39.0 270 11.7 0
2018 18.12.18 1:00 24.2 37.1 257 12.3 0
2018 18.12.18 2:00 25.3 35.1 243 12.9 0
2018 18.12.18 3:00 21.0 42.0 270 13.7 0
2018 18.12.18 4:00 22.1 39.9 257 14.4 0
2018 18.12.18 5:00 23.1 37.8 243 15.1 0
2018 18.12.18 6:00 22.0 44.0 225 11.7 0
2018 18.12.18 7:00 23.1 41.8 214 12.3 0
2018 18.12.18 8:00 24.2 39.6 203 12.9 0
2018 18.12.18 9:00 28.0 37.0 225 9.7 0
2018 18.12.18 10:00 26.6 38.9 214 10.2 0
2018 18.12.18 11:00 25.2 40.7 203 10.7 0
2018 18.12.18 12:00 34.0 26.0 315 7.7 0
2018 18.12.18 13:00 32.3 27.3 331 8.1 0
2018 18.12.18 14:00 30.6 28.6 347 8.5 0
2018 18.12.18 15:00 35.0 27.0 180 7.7 0
2018 18.12.18 16:00 33.3 28.4 189 7.3 0
2018 18.12.18 17:00 31.5 29.7 198 6.9 0
2018 18.12.18 18:00 31.0 36.0 270 9.7 0
2018 18.12.18 19:00 32.6 37.8 284 9.2 0
2018 18.12.18 20:00 34.1 39.6 74 8.7 0
2018 18.12.18 21:00 27.0 37.0 270 11.7 0
2018 18.12.18 22:00 28.4 35.2 284 11.1 0
2018 18.12.18 23:00 29.7 33.3 297 10.5 0
2018 19.12.18 0:00 23.0 38.0 270 11.7 0
2018 19.12.18 1:00 24.2 36.1 257 12.3 0
2018 19.12.18 2:00 25.3 34.2 243 12.9 0
2018 19.12.18 3:00 21.0 39.0 225 11.7 0
2018 19.12.18 4:00 22.1 37.1 214 12.3 0
2018 19.12.18 5:00 23.1 35.1 203 12.9 0
2018 19.12.18 6:00 21.0 42.0 225 11.7 0
2018 19.12.18 7:00 20.0 44.1 214 12.3 0
2018 19.12.18 8:00 18.9 46.2 203 12.9 0
2018 19.12.18 9:00 27.0 36.0 248 9.7 0
2018 19.12.18 10:00 25.7 37.8 235 10.2 0
2018 19.12.18 11:00 24.3 39.6 223 10.7 0
2018 19.12.18 12:00 33.0 25.0 225 9.7 0
A-191
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 19.12.18 13:00 31.4 26.3 236 10.2 0
2018 19.12.18 14:00 29.7 27.5 248 10.7 0
2018 19.12.18 15:00 33.0 25.0 270 11.7 0
2018 19.12.18 16:00 34.7 26.3 284 11.1 0
2018 19.12.18 17:00 36.3 27.5 297 10.5 0
2018 19.12.18 18:00 29.0 33.0 270 11.7 0
2018 19.12.18 19:00 30.5 31.4 284 11.1 0
2018 19.12.18 20:00 31.9 29.7 297 10.5 0
2018 19.12.18 21:00 26.0 36.0 270 13.7 0
2018 19.12.18 22:00 27.3 34.2 284 13.0 0
2018 19.12.18 23:00 28.6 32.4 297 12.3 0
2018 20.12.18 0:00 22.0 38.0 225 13.7 0
2018 20.12.18 1:00 23.1 36.1 214 14.4 0
2018 20.12.18 2:00 24.2 34.2 203 15.1 0
2018 20.12.18 3:00 21.0 38.0 225 13.7 0
2018 20.12.18 4:00 20.0 36.1 214 14.4 0
2018 20.12.18 5:00 18.9 34.2 203 15.1 0
2018 20.12.18 6:00 20.0 38.0 225 13.7 0
2018 20.12.18 7:00 19.0 39.9 214 14.4 0
2018 20.12.18 8:00 18.0 41.8 203 15.1 0
2018 20.12.18 9:00 24.0 33.0 248 15.5 0
2018 20.12.18 10:00 22.8 34.7 235 16.3 0
2018 20.12.18 11:00 21.6 36.3 223 17.1 0
2018 20.12.18 12:00 32.0 21.0 248 17.5 0
2018 20.12.18 13:00 33.6 22.1 260 18.4 0
2018 20.12.18 14:00 35.2 23.1 272 19.3 0
2018 20.12.18 15:00 33.0 20.0 225 15.5 0
2018 20.12.18 16:00 34.7 21.0 236 14.7 0
2018 20.12.18 17:00 36.3 22.0 248 14.0 0
2018 20.12.18 18:00 29.0 27.0 270 13.7 0
2018 20.12.18 19:00 30.5 25.7 284 13.0 0
2018 20.12.18 20:00 31.9 24.3 297 12.3 0
2018 20.12.18 21:00 27.0 27.0 225 15.5 0
2018 20.12.18 22:00 28.4 25.7 236 14.7 0
2018 20.12.18 23:00 29.7 24.3 248 14.0 0
2018 21.12.18 0:00 23.0 28.0 248 15.5 0
2018 21.12.18 1:00 21.9 26.6 235 16.3 0
2018 21.12.18 2:00 20.7 25.2 223 17.1 0
2018 21.12.18 3:00 20.0 30.0 248 13.7 0
2018 21.12.18 4:00 19.0 31.5 235 14.4 0
2018 21.12.18 5:00 18.0 33.0 223 15.1 0
2018 21.12.18 6:00 20.0 35.0 248 11.7 0
2018 21.12.18 7:00 19.0 36.8 235 12.3 0
2018 21.12.18 8:00 18.0 38.5 223 12.9 0
2018 21.12.18 9:00 26.0 32.0 248 9.7 0
2018 21.12.18 10:00 27.3 33.6 235 10.2 0
2018 21.12.18 11:00 28.6 35.2 223 10.7 0
2018 21.12.18 12:00 34.0 20.0 225 9.7 0
2018 21.12.18 13:00 35.7 21.0 236 10.2 0
A-192
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 21.12.18 14:00 37.4 22.0 248 10.7 0
2018 21.12.18 15:00 35.0 20.0 270 9.7 0
2018 21.12.18 16:00 36.8 19.0 284 9.2 0
2018 21.12.18 17:00 38.5 18.0 297 8.7 0
2018 21.12.18 18:00 31.0 28.0 270 9.7 0
2018 21.12.18 19:00 32.6 26.6 284 9.2 0
2018 21.12.18 20:00 34.1 25.2 297 8.7 0
2018 21.12.18 21:00 27.0 29.0 270 11.7 0
2018 21.12.18 22:00 25.7 27.6 284 11.1 0
2018 21.12.18 23:00 24.3 26.1 297 10.5 0
2018 22.12.18 0:00 22.0 30.0 270 11.7 0
2018 22.12.18 1:00 20.9 31.5 257 12.3 0
2018 22.12.18 2:00 19.8 33.0 243 12.9 0
2018 22.12.18 3:00 21.0 33.0 270 11.7 0
2018 22.12.18 4:00 20.0 34.7 257 12.3 0
2018 22.12.18 5:00 18.9 36.3 243 12.9 0
2018 22.12.18 6:00 21.0 34.0 225 11.7 0
2018 22.12.18 7:00 22.1 35.7 214 12.3 0
2018 22.12.18 8:00 23.1 37.4 203 12.9 0
2018 22.12.18 9:00 27.0 25.0 225 11.7 0
2018 22.12.18 10:00 28.4 26.3 214 12.3 0
2018 22.12.18 11:00 29.7 27.5 203 12.9 0
2018 22.12.18 12:00 34.0 16.0 225 11.7 0
2018 22.12.18 13:00 35.7 15.2 236 12.3 0
2018 22.12.18 14:00 37.4 14.4 248 12.9 0
2018 22.12.18 15:00 34.0 17.0 270 11.7 0
2018 22.12.18 16:00 35.7 16.2 284 11.1 0
2018 22.12.18 17:00 37.4 15.3 297 10.5 0
2018 22.12.18 18:00 29.0 23.0 180 11.7 0
2018 22.12.18 19:00 27.6 21.9 189 11.1 0
2018 22.12.18 20:00 26.1 20.7 198 10.5 0
2018 22.12.18 21:00 26.0 24.0 270 11.7 0
2018 22.12.18 22:00 24.7 22.8 284 11.1 0
2018 22.12.18 23:00 23.4 21.6 297 10.5 0
2018 23.12.18 0:00 23.0 25.0 270 11.7 0
2018 23.12.18 1:00 21.9 26.3 257 12.3 0
2018 23.12.18 2:00 20.7 27.5 243 12.9 0
2018 23.12.18 3:00 21.0 26.0 225 11.7 0
2018 23.12.18 4:00 22.1 27.3 214 12.3 0
2018 23.12.18 5:00 23.1 28.6 203 12.9 0
2018 23.12.18 6:00 22.0 27.0 225 9.7 0
2018 23.12.18 7:00 23.1 28.4 214 10.2 0
2018 23.12.18 8:00 24.2 29.7 203 10.7 0
2018 23.12.18 9:00 28.0 24.0 225 7.7 0
2018 23.12.18 10:00 29.4 25.2 214 8.1 0
2018 23.12.18 11:00 30.8 26.4 203 8.5 0
2018 23.12.18 12:00 35.0 15.0 315 3.9 0
2018 23.12.18 13:00 36.8 14.3 331 4.1 0
2018 23.12.18 14:00 38.5 13.5 347 4.3 0
A-193
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 23.12.18 15:00 36.0 17.0 158 7.7 0
2018 23.12.18 16:00 34.2 16.2 165 7.3 0
2018 23.12.18 17:00 32.4 15.3 173 6.9 0
2018 23.12.18 18:00 31.0 25.0 158 9.7 0
2018 23.12.18 19:00 29.5 23.8 165 9.2 0
2018 23.12.18 20:00 27.9 22.5 173 8.7 0
2018 23.12.18 21:00 27.0 26.0 180 11.7 0
2018 23.12.18 22:00 25.7 27.3 189 11.1 0
2018 23.12.18 23:00 24.3 28.6 198 10.5 0
2018 24.12.18 0:00 22.0 27.0 68 13.7 0
2018 24.12.18 1:00 23.1 28.4 64 14.4 0
2018 24.12.18 2:00 24.2 29.7 61 15.1 0
2018 24.12.18 3:00 20.0 29.0 270 11.7 0
2018 24.12.18 4:00 21.0 30.5 257 12.3 0
2018 24.12.18 5:00 22.0 31.9 243 12.9 0
2018 24.12.18 6:00 21.0 31.0 270 9.7 0
2018 24.12.18 7:00 22.1 32.6 257 10.2 0
2018 24.12.18 8:00 23.1 34.1 243 10.7 0
2018 24.12.18 9:00 28.0 27.0 293 7.7 0
2018 24.12.18 10:00 29.4 25.7 278 8.1 0
2018 24.12.18 11:00 30.8 24.3 263 8.5 0
2018 24.12.18 12:00 33.0 16.0 158 9.7 0
2018 24.12.18 13:00 31.4 15.2 165 10.2 0
2018 24.12.18 14:00 29.7 14.4 173 10.7 0
2018 24.12.18 15:00 35.0 18.0 158 7.7 0
2018 24.12.18 16:00 33.3 17.1 165 7.3 0
2018 24.12.18 17:00 31.5 16.2 173 6.9 0
2018 24.12.18 18:00 31.0 27.0 158 7.7 0
2018 24.12.18 19:00 29.5 28.4 165 7.3 0
2018 24.12.18 20:00 27.9 29.7 173 6.9 0
2018 24.12.18 21:00 26.0 34.0 158 9.7 0
2018 24.12.18 22:00 27.3 35.7 165 9.2 0
2018 24.12.18 23:00 28.6 37.4 173 8.7 0
2018 25.12.18 0:00 22.0 47.0 45 11.7 0
2018 25.12.18 1:00 23.1 49.4 43 12.3 0
2018 25.12.18 2:00 24.2 51.7 41 12.9 0
2018 25.12.18 3:00 21.0 53.0 180 11.7 0
2018 25.12.18 4:00 22.1 55.7 171 12.3 0
2018 25.12.18 5:00 23.1 58.3 162 12.9 0
2018 25.12.18 6:00 21.0 50.0 270 11.7 0
2018 25.12.18 7:00 22.1 47.5 257 12.3 0
2018 25.12.18 8:00 23.1 45.0 182 12.9 0
2018 25.12.18 9:00 26.0 44.0 203 13.7 0
2018 25.12.18 10:00 24.7 41.8 192 14.4 0
2018 25.12.18 11:00 23.4 39.6 182 15.1 0
2018 25.12.18 12:00 32.0 23.0 225 21.4 0
2018 25.12.18 13:00 30.4 21.9 236 22.5 0
2018 25.12.18 14:00 28.8 20.7 248 23.5 0
2018 25.12.18 15:00 32.0 18.0 225 21.4 0
A-194
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 25.12.18 16:00 30.4 17.1 236 20.3 0
2018 25.12.18 17:00 28.8 16.2 248 19.3 0
2018 25.12.18 18:00 30.0 20.0 225 15.5 0
2018 25.12.18 19:00 31.5 21.0 236 14.7 0
2018 25.12.18 20:00 33.0 22.0 248 14.0 0
2018 25.12.18 21:00 28.0 16.0 225 17.5 0
2018 25.12.18 22:00 29.4 16.8 236 16.6 0
2018 25.12.18 23:00 30.8 17.6 248 15.8 0
2018 26.12.18 0:00 23.0 16.0 225 21.4 0
2018 26.12.18 1:00 24.2 16.8 214 22.5 0
2018 26.12.18 2:00 25.3 17.6 203 23.5 0
2018 26.12.18 3:00 17.0 19.0 225 21.4 0
2018 26.12.18 4:00 17.9 20.0 214 22.5 0
2018 26.12.18 5:00 18.7 20.9 203 23.5 0
2018 26.12.18 6:00 17.0 20.0 225 23.4 0
2018 26.12.18 7:00 16.2 19.0 214 24.6 0
2018 26.12.18 8:00 15.3 18.0 203 25.7 0
2018 26.12.18 9:00 21.0 21.0 225 25.1 0
2018 26.12.18 10:00 20.0 20.0 214 26.4 0
2018 26.12.18 11:00 18.9 18.9 203 27.6 0
2018 26.12.18 12:00 29.0 14.0 248 25.1 0
2018 26.12.18 13:00 27.6 13.3 260 26.4 0
2018 26.12.18 14:00 26.1 12.6 272 27.6 0
2018 26.12.18 15:00 31.0 15.0 225 17.5 0
2018 26.12.18 16:00 32.6 15.8 236 16.6 0
2018 26.12.18 17:00 34.1 16.5 248 15.8 0
2018 26.12.18 18:00 28.0 21.0 203 15.5 0
2018 26.12.18 19:00 29.4 22.1 213 14.7 0
2018 26.12.18 20:00 30.8 23.1 223 14.0 0
2018 26.12.18 21:00 26.0 23.0 225 15.5 0
2018 26.12.18 22:00 27.3 24.2 236 14.7 0
2018 26.12.18 23:00 28.6 25.3 248 14.0 0
2018 27.12.18 0:00 22.0 28.0 225 15.5 0
2018 27.12.18 1:00 23.1 29.4 214 16.3 0
2018 27.12.18 2:00 24.2 30.8 203 17.1 0
2018 27.12.18 3:00 19.0 34.0 225 15.5 0
2018 27.12.18 4:00 20.0 32.3 214 16.3 0
2018 27.12.18 5:00 20.9 30.6 203 17.1 0
2018 27.12.18 6:00 18.0 38.0 225 17.5 0
2018 27.12.18 7:00 17.1 36.1 214 18.4 0
2018 27.12.18 8:00 16.2 34.2 203 19.3 0
2018 27.12.18 9:00 21.0 35.0 248 21.4 0
2018 27.12.18 10:00 20.0 33.3 235 22.5 0
2018 27.12.18 11:00 18.9 31.5 223 23.5 0
2018 27.12.18 12:00 30.0 20.0 248 21.4 0
2018 27.12.18 13:00 28.5 21.0 260 22.5 0
2018 27.12.18 14:00 27.0 22.0 272 23.5 0
2018 27.12.18 15:00 32.0 20.0 248 17.5 0
2018 27.12.18 16:00 33.6 21.0 260 16.6 0
A-195
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 27.12.18 17:00 35.2 22.0 272 15.8 0
2018 27.12.18 18:00 30.0 27.0 225 13.7 0
2018 27.12.18 19:00 31.5 28.4 236 13.0 0
2018 27.12.18 20:00 33.0 29.7 248 12.3 0
2018 27.12.18 21:00 27.0 29.0 225 15.5 0
2018 27.12.18 22:00 28.4 30.5 236 14.7 0
2018 27.12.18 23:00 29.7 31.9 248 14.0 0
2018 28.12.18 0:00 22.0 31.0 248 17.5 0
2018 28.12.18 1:00 23.1 29.5 235 18.4 0
2018 28.12.18 2:00 24.2 27.9 223 19.3 0
2018 28.12.18 3:00 19.0 36.0 248 17.5 0
2018 28.12.18 4:00 18.1 34.2 235 18.4 0
2018 28.12.18 5:00 17.1 32.4 223 19.3 0
2018 28.12.18 6:00 19.0 43.0 248 15.5 0
2018 28.12.18 7:00 18.1 40.9 235 16.3 0
2018 28.12.18 8:00 17.1 38.7 223 17.1 0
2018 28.12.18 9:00 24.0 41.0 248 15.5 0
2018 28.12.18 10:00 22.8 39.0 235 16.3 0
2018 28.12.18 11:00 21.6 36.9 223 17.1 0
2018 28.12.18 12:00 33.0 24.0 270 15.5 0
2018 28.12.18 13:00 34.7 25.2 284 16.3 0
2018 28.12.18 14:00 36.3 26.4 297 17.1 0
2018 28.12.18 15:00 35.0 22.0 248 11.7 0
2018 28.12.18 16:00 36.8 23.1 260 11.1 0
2018 28.12.18 17:00 38.5 24.2 272 10.5 0
2018 28.12.18 18:00 32.0 29.0 225 11.7 0
2018 28.12.18 19:00 33.6 30.5 236 11.1 0
2018 28.12.18 20:00 35.2 31.9 248 10.5 0
2018 28.12.18 21:00 29.0 30.0 225 15.5 0
2018 28.12.18 22:00 30.5 31.5 236 14.7 0
2018 28.12.18 23:00 31.9 33.0 248 14.0 0
2018 29.12.18 0:00 26.0 31.0 248 13.7 0
2018 29.12.18 1:00 24.7 29.5 235 14.4 0
2018 29.12.18 2:00 23.4 27.9 223 15.1 0
2018 29.12.18 3:00 21.0 34.0 248 11.7 0
2018 29.12.18 4:00 20.0 32.3 235 12.3 0
2018 29.12.18 5:00 18.9 30.6 223 12.9 0
2018 29.12.18 6:00 21.0 37.0 225 9.7 0
2018 29.12.18 7:00 20.0 35.2 214 10.2 0
2018 29.12.18 8:00 18.9 33.3 203 10.7 0
2018 29.12.18 9:00 28.0 33.0 225 9.7 0
2018 29.12.18 10:00 29.4 34.7 214 10.2 0
2018 29.12.18 11:00 30.8 36.3 203 10.7 0
2018 29.12.18 12:00 35.0 21.0 225 9.7 0
2018 29.12.18 13:00 36.8 22.1 236 10.2 0
2018 29.12.18 14:00 38.5 23.1 248 10.7 0
2018 29.12.18 15:00 36.0 20.0 225 7.7 0
2018 29.12.18 16:00 37.8 21.0 236 7.3 0
2018 29.12.18 17:00 39.6 22.0 248 6.9 0
A-196
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 29.12.18 18:00 33.0 28.0 203 9.7 0
2018 29.12.18 19:00 34.7 29.4 213 9.2 0
2018 29.12.18 20:00 36.3 30.8 223 8.7 0
2018 29.12.18 21:00 30.0 28.0 203 13.7 0
2018 29.12.18 22:00 28.5 26.6 213 13.0 0
2018 29.12.18 23:00 27.0 25.2 223 12.3 0
2018 30.12.18 0:00 27.0 29.0 225 13.7 0
2018 30.12.18 1:00 25.7 27.6 214 14.4 0
2018 30.12.18 2:00 24.3 26.1 203 15.1 0
2018 30.12.18 3:00 22.0 30.0 225 11.7 0
2018 30.12.18 4:00 20.9 28.5 214 12.3 0
2018 30.12.18 5:00 19.8 27.0 203 12.9 0
2018 30.12.18 6:00 22.0 33.0 225 9.7 0
2018 30.12.18 7:00 23.1 34.7 214 10.2 0
2018 30.12.18 8:00 24.2 36.3 203 10.7 0
2018 30.12.18 9:00 29.0 32.0 248 7.7 0
2018 30.12.18 10:00 30.5 33.6 235 8.1 0
2018 30.12.18 11:00 31.9 35.2 223 8.5 0
2018 30.12.18 12:00 36.0 19.0 248 0.0 0
2018 30.12.18 13:00 37.8 20.0 260 0.0 0
2018 30.12.18 14:00 39.6 20.9 272 0.0 0
2018 30.12.18 15:00 37.0 21.0 315 0.0 0
2018 30.12.18 16:00 38.9 22.1 331 0.0 0
2018 30.12.18 17:00 40.7 23.1 347 0.0 0
2018 30.12.18 18:00 33.0 31.0 135 7.7 0
2018 30.12.18 19:00 31.4 29.5 142 7.3 0
2018 30.12.18 20:00 29.7 27.9 149 6.9 0
2018 30.12.18 21:00 31.0 30.0 45 11.7 0
2018 30.12.18 22:00 29.5 28.5 47 11.1 0
2018 30.12.18 23:00 27.9 27.0 50 10.5 0
2018 31.12.18 0:00 26.0 31.0 203 13.7 0
2018 31.12.18 1:00 24.7 29.5 192 14.4 0
2018 31.12.18 2:00 23.4 27.9 182 15.1 0
2018 31.12.18 3:00 22.0 33.0 225 13.7 0
2018 31.12.18 4:00 23.1 31.4 214 14.4 0
2018 31.12.18 5:00 24.2 29.7 203 15.1 0
2018 31.12.18 6:00 23.0 36.0 225 11.7 0
2018 31.12.18 7:00 24.2 37.8 214 12.3 0
2018 31.12.18 8:00 25.3 39.6 203 12.9 0
2018 31.12.18 9:00 30.0 34.0 225 3.9 0
2018 31.12.18 10:00 31.5 35.7 214 4.1 0
2018 31.12.18 11:00 33.0 37.4 203 4.3 0
2018 31.12.18 12:00 37.0 21.0 293 0.0 0
2018 31.12.18 13:00 38.9 22.1 307 0.0 0
2018 31.12.18 14:00 40.7 23.1 322 0.0 0
2018 31.12.18 15:00 36.0 22.0 90 7.7 0
2018 31.12.18 16:00 34.2 23.1 95 7.3 0
2018 31.12.18 17:00 32.4 24.2 99 6.9 0
2018 31.12.18 18:00 32.0 31.0 90 9.7 0
A-197
Year Date Time Temp.
(0C)
Humidity
(%)
Wind Direction
(Degree)
Wind Speed
(Km/hr.)
Rainfall
(mm)
2018 31.12.18 19:00 30.4 29.5 95 9.2 0
2018 31.12.18 20:00 28.8 27.9 99 8.7 0
2018 31.12.18 21:00 28.0 36.0 113 9.7 0
2018 31.12.18 22:00 26.6 34.2 118 9.2 0
2018 31.12.18 23:00 25.2 32.4 124 8.7 0
A-198
SAN ENVIROTECH PVT, LTD, Acclred3xed QCI-NABET Consultant
MoEF Recogneed Envkronrnentai taborarory Uodcr EP J k t , 1986 GPCB Recognized Schedule43 Auditors
I S 0 900%. 14CK$1& QkjSAS 18002 Certified Company GSTlN: 24AASCS5415CXZR
AMBIENT AIR QUALITY
Analyzed By : B& J
Max . Min
98 Percentile - 75 Percentile
50 Percentile 25 Percentile Average
PM-10 (pg/m3)
74.0 59.9
Phone No. 079-26583O77 Cell: 9825007201/9723766007 4011402{423/424/324* Medicine Market* Opp. Shefali Center, Paldi Cross Road, Ahmdabad.
73.3 70.9 68.3 66.0 67.9 *
PM-2.5 (pg/m3)
44.5 35.0 44.5 41.8 39.6 38.0 39.9
(pg/m3)
18.0 12.5
No2 (p9/m3)
21.4 14.4
18.0 16.8 15.3 14.7 15.5
21.1 19.7 18.1 16.8 18.1
A-199
ENVPROTECH PVT- LTD- A c c ~ d i r e d QCI-NABET Consulant
M o E F Recognized E n w i r o a m e n t a k Labaratory UnUer E P Act. 19S6 GPCB Recognized Schedule-il Auditors
#SO 9001,14<H)1& OHSAS 18001 Cemfied Company GSTIN: 24MGCS5415CZZR
AMBIENT AIR QUALITY
Samplinq Location A3 : Padra Villaqe
Monitorinq 02.10.18 05.10.18 09.10.18
CLOCK HOURS ~ ~ - l O ( p g / r n ~ )
24 HOURS (pg/m3)
67.3 61.6 70.4
Analyzed By : ad Max
CO Date of 1 00-08 1 08-16 ' 1 16-24 1 00-08 1 08-16 1 16-24 / 00-08 1 08-16 1 16-24 / 00-08 1 08-16 1 16-24 ~~-2 . ! i (pg / rn~)
H C
77.4 68.3 76.5
Min 98 Percentile 75 Percentile 50 Percentile 25 Percentile Average
PM-10 (pg/rn3)
74.8
s02(pg/rn3) I ~ 0 2 ( p g / r n ~ )
71.6 65.6 72.4
Phone No. 039-26583077 Cell: 98250~?201/9?23766007 ml/4a2/;123/424/324, Medicine Market, Opp. Shefaii Center, Pal& Cross Rmd, A h m d a b d .
54.3 74.7 71.8 68.1 63.7 67.2
PM-2.5 (pg/m3)
42.7
30.6 27.7 35.1
29.4 41.4 38.8 37.6 35.9 37.0
SO2 (pg/m3)
15.8
NO2 (pg/m3)
20.7
46.1 49.6 43.4
10.8 15.8 14.8 13.9 12.8 13.7
13.3 20.2 18.3 16.8 15.3 16.9
40.8 35.2 37.7
10.7 11.1 8.8
15.4 17.8 14.2
12.8 14.6 10.9
11.8 12.8 10.3
17.7 18.1 16.2
15.0 13.3 14.3
1154 1188 1199
1201 1236 1248
A-201
SAN ENVBROTECH P W T - L T D - Accredited QCI-NABET Consultant
MoEF Recognized Envaronmentaf L a b o r a P o s y Under EP Act, 1986 GPCS Recognized Sched ule-31 Aud itorr
IS0 SOOH, 14009 & OlHSrFIS 18002 Cebtineu Company GSTIM: 2 4 M G CSS15CXZR
AMBIENT AIR QUALITY
I PM-10 (ug/m3) I PM-2.5 (ug/m3) 1 102 (ug/m3) I NO2 (ug/m31
Min 59.0 34.6 12.9 14.4 98 Percentile 75.6 50.0 19.1 21.9 75 Percentile 69.2 44.0 17.6 17.8 50 Percentile 66.9 41.9 16.5 16.9 25 Percentile 64.0 . 38.9 14.8 16.0 Average 67.1 41.8 16.3 17.4
I -. -. - -. - - - - -. -- - -
401/402/423/424/324, Medicine Market. Opp. Shefali Center. Paldi Uoss Road, ~ h k d a b a d .
Max Analyzed By: ,&$a 76.3 51 .? 19.3 3 3 3
A-202
ENVEROTECH PVT, LTD- Accredited QCI-NABET Consultant
MaEF Recognized Enviroslrnental Laboratory Under EP AcZ,
GPCS Recognized Schedulell Auditors I S 8 W O B . 14001 & OHSAS 18001 cCemned Company
GST1N: 24AAGCS5415CXZR
AMBIENT AIR QUALITY
PM-10 (pg/m3) PM-2.5 (pg/m3) (pg/m3) NO2 (v9/m3)
Max 76.2 44.0 15.9 20.5 Analyzed By : r
Mln 64.3 29.4 11.2 12.4 98 Percentile 76.1 42.6 15.8 20.2 75 Percent~le 73.7 38.9 14.9 18.2 50 Percentile 71.6 37.8 13.6 15.7 Authorized by:
25 Percentile 68.8 - 35.9 12.7 i4.0 Averaqe 71.0 37.3 13.6 16.0
Phone No. 079-2fiS83077 Cdl: 98250072~3/97237~07 Ernail: - M3[4Q2f42364241324, Medicine Market, Opp. Shefali Cente~, Pa%& O m s Rwd, Ahanedabad-
A-203
ENVIROTECH PVTl. L T D S Accredfted QCI-MABET Cz;pnsultant
M o E F Recognized Environmental tatxxatory Under EP Act, 1986 GPCS Recognize& Schedule41 Awdirars
I S 0 9001.14001 & OHSAS 1&00P Certified Company CSTIM: 24AAGCS5415C1ZR
AMBIENT AIR QUALITY
Sampling Location A6 : Ranu Village
Analyzed By : C
Authorized by: v,
Phone No. 079-2f583077 - CeU: 98~d1720d~972376W)87 Ernaill: .48%1402/423/424/324, Medicine Market, Cdpp. Shefati Center-, Paldi Cams Road, Ahmdabad.
Max
Min 98 Percentile 75 Percentile 50 Percentile 25 Percentile Average
SO1 (pg/m3)
18.3 10.2 17.4 13.4 12.6 11.4 13.0
NO1 (pg/m3)
23.1 11.6 22.0 16.7 15.3 14.0 15.8
PM-10 (pg/m3)
76.0 61.3 75.7 72.5 68.9 65.6 .
68.9
PM-2.5 (pg/m3)
47.1 31.7 46.3 40.0 37.6 33.7 37.6
A-204
SAN ENVIROTECH PVTill TTD, Accredited QCI-MABET Ca4nsulranZ
MoEF Recognized Environmental LaEwxafckry Under EP Act, 19&6 GPCB Recognized Schedule-ll Auditors
IS0 9009,14001 & Q H S M 1&004. CertifkqZ Company GSTIN: 24AAGCS5rl.15CPZR
AMBIENT AIR QUALITY
Sampling Location A7 : Bhsj Village.
Monitoring 1
Phone Wo. 079-26583077 CeH: 9825007203 /9?23766007
CLOCK HOURS
03.10.18 1 64.4 1 73.3 1 67.1 1 31.5 1 47.9 1 39.6 ( 11.8 1 14.7 1 12.7 1 10.3 / 17.0 1 14.4
Max Min 98 Percentile 75 Percentile 50 Percentile 25 Percentile Average
Analyzed By :,$Ab*
~ ~ - 1 0 ( p g / m ~ ) 24 HOURS
(vg/m3)
1206 1 1167
- 401/402/423/424#32r1. Medicine Market, Opp. Shefali Center. Paldi Crou Road, ~hmedabad.
CO
77.7 61.9 76.4 72.1 69.7 67.0 *
69.6
' Date of 1 00-08 1 08-16 1 16-24 1 00-08 1 08-16 1 '16-24 1 00-08 1 08-16 1 '16-24 1 00-08 1 08-16 1 ' 16-24 PM-2.5(pg/m3)
H C
49.3 35.2 47.0 42.6 41.3 39.6 41.1
S02(pgJm3) N02@gJm3)
16.9 11.4 16.4 14.5 13.7 13.2 13.8
20.8 13.7 19.7 16.8
. 15.3 14.4 15.8
A-205
SAN ENVlROTECH PVT, LTD, Accredixed El--BET Consulrant
MoEF Wecognized Environmental Laboratory Uncfer E P Act, 19&6 GPC5 Recognized Schedule-ll Audttors
158 9a01.140018r OD-ISAS 18001 Certrfcecd Company GSTIN: 24AAGCS5415C1ZR
AMBIENT AIR QUALITY
Sampling Location A8 : Vishrampura Villeqe CLOCK HOURS
~ ~ - l O ( p g / m ~ ) 24 HOURS
(pg/m3)
Analyzed By : &'* J -
Authorized by:
Max
Min 98 Percentile 75 Percent~le 50 Percent~le 25 Percent~le Average
CO
Phne No. 079-26583077 ~ e t f ! : Emaif: &32/4~21423/424f 324, Medicine Market, Opp. Shefali Center' PaMi Crass Rwd, Ahmedabad.
Date of 1 00-08 1 08-16' 1 16-24 1 00-08 1 08-16 1 16-24 1 00-08 1 08-16 1 '16-24 1 00-08 1 08-16 1 ' 16-24 'HC
PM-10 (pg/m3)
76.6 66.2 76.5 72.8 70.6 68.3 - 70.7
N01(pq/m3) ~ ~ - 2 . 5 ( p q / m ~ ) S0z(pq/m3)
NO2 (IJg/m3)
26.5 13.1 23.6 17.8 16.0 15.1 16.7
PM-2.5 (pg/m3)
45.4 34.3 45.0 42.9 38.5 36.2 39.5
So2 (pg/m3)
24.2 11.5 20.8 16.1 14.6 13.5 14.9
A-206
S A M EMVIROTECH PVT- LTD, Accredircd QCI-NASET Consultant
MoEF R e c o g n i z e d EnwironrnentaE Laboratory U n d e r E P Act, 19843 GPC8 R e c o g n i z e d Schedule41 Auditem
IS0 9001,14001 & OHSAS 18001 CertjRa3 Company GSnN: 24AAGCS5Q15CZZR
ANALYSIS REPORT OF GROUND WATER SAMPLE
Description of sample
Sample Collected by
Quantity /No. of Sample
:
:
:
Ground Water
San Envirotech Pvt.Ltd.
3 Lit x 08 Nos.
Lab I D Code Report Issue Date PackingISeal
Test Parameters & Method
: : :
:
SEPL/RPP/GWS (1 t o 8)-201812 26.12.2018 Sealed wi th Proper Identif ication
As per result Table, Method of Test : I S 3025
A-207
S A N ENVIROTECH PVTL LTDI Accredited QGI-MABET Consultant
1 WOEF RecognPzed Environrnesltaf L a h r a t o r y Under EP Pwrt, 19&S
@PCB R e c o g n i z e d Schedule-9i Auditors IS0 900a. 1400P & OHSAS 1 W O E Ce-f ied C o m p a n y
GWEN: 24AAGCS5415tlZR
ANALYSIS REPORT OF SURFACE WATER SAMPLE
Description of sample
Sample Collected by _ Quantity /No. o f Sample
:
: :
Surface Water
San Envirotech Pvt.Ltd. 3 Lit x 08 Nos.
19.12.18 Mahi River
7.8 1225
Lab I D Code Report Issue Date PackingISeal Test Parameters & Method
18.12.18 Dabka Pond 7.1 830
Date of Monitoring 18.12.18 Tajpura
Pond 7.4 '
6 10
18.12.18 Dabhasa
Pond 7.3 755
Parameters
pH Conductivity
: : : :
Unit
pH Unit Micro
SEPL/RPP/GWS (1 to 8)-201812 26.12.2018 Sealed with Proper Identification As per result Table, Method of Test : I S 3025
18.12.18 Padra Pond 7.6 502
19.12.18 Bhoj Pond 7.5 508
19.12.18 Ranu Pond 7.2 630
19.12.18 Luna Pond 7.7 560
A-208
SAN ENVIROTECH PVT, LTDp Accsedircd QCI-NMET Consultant
MoEF Recognized E n v i r o n m e n t a l Labonatow U n d e r E P Act, 19236 GPCB Recognized Schedule-31 Auditors
ISO ~ O Z , 14001 & OHSM 18001 ~ e m ~ e d Company GSTIN: 24AAGCS5415CIZR
: 2 Kg - 8 Nos. Test Parameters & Method : As per result Table, Method of Test : After water and acid leachate preparation followed by the analysis method of APHA AWWA WEF 23'* Edition
ANALYSIS REPORT OF SOIL SAMPLE
Description of sample
Sample Collected by
:
:
Soil Sample
San Envirotech Pvt.Ltd.
Lab I D Code Report Issue Date PackingISeal
: : :
SEPL/RPP/SOI(l to 8)-201812 26.12.2018 Sealed with Proper Identification
A-209
SAN ENVfROTECN PVT. LTD. Accredited QCI-NABET Consultant
MoEF Recognized Envlmnmental Laboratow Under EP Act. 1986 GPCB Recognized ScReduleil Auditors
ISO 9001,1~01& OHSAS ISW)~ ~crhflcd Company emff: 2 4 U G C S 5 4 1 5 C l Z R
Ambient Noise Levels in the Study Area (Date of Sampling: 18 to 19 December, 2018)
Location: Project site (N 1) Unit: dB(A)
5 11:OO AM 3:00 AM 40.1 44.8 - 6 ' 12:OO AM 56.4 57.7 22 4:00 AM 44.7 46.6
Pbne No. 079-26583077 072a1/972376fiMt7 Email: mahendra.sep~~i l .con 401/402/423/424/324, Medicine Market, Opp. Shefali Center, Paldi Cross Road, Ahmedabad
Min
44.7 44.3 41.2 45.9
Reading during Night time
11:OO PM 12:OO PM 1:00 AM 2:00 AM
Max
48.1 45.2 44.7 47.7
Sr. No.
17 18 19 20
Sr. No.
1 2 3 4
Max
50.3 51.8 53.3 54.6
Reading during daytime
7.00 am 8:00 AM 9: 00 AM 10:OO AM
Min
49.2 50.2 52.2 53.6
A-210
EMVkROTECH PVT. ZTD. Accrcd~ted QCI-NAB= Consulrant
MOEF Reerognued Envrronmental Laboratory Under EP Act. 1986 GPCB Recognued Scheduleil Audttors
150 5001,14001 &OH= lLUtO1 CeRtlbed Company GmN: 24AACiCSYIlSClZR
Location: 250 m South from the site (IV3) Unit: dB(A)
13 14 15 16
Max
Location: 500 m North from the site (IV4) Unit: dB(A)
Min
7:00 PM 8:00 PM 9:00 PM 10:OO PM
Sr. No.
11 12 13
Reading during Night time
Sr. No.
14 15 16
46.3 53.8 45.9 43.4
5:00 PM 6:00 PM 7:00 PM 8:00 PM 9:00 PM 40:00 PM
Sr. No.
Reading during daytime
48 56.9 48.7 48.9
Reading during Night time
Sr. No.
Reading during daytime
46.6 52.5 49.9 47.5 44.2 47.5
Min
Leq Night Leq Day & Night
Min Min
54.1 56 53.6
Max
Ln - 40.8 Ldn- 49.9
Max Max
54.8 49.3 50.8
Leq Day Leq Niqht
Ld - 50.9 Ln - 39.2
Leq Day & Night Ldn- 49.0
A-211
SAN ENVIROTECW PVT. LTD. Accred~ted QCI-NAB- Consultant
MoEF Recognrzed Envtronmenml Laboratow Under EPAct. 1986 GPCB RecognuEd Schedule-ll Audrtors
150 9~)1,14a31 &OHSAS lBOO1 Cemlted Cn-mpany GSTIM: 24AAGCS5415ClZR
Location: 1000 m East from the site (NS) Unit: dB(A)
11 12
Phone Mo. 079-2W3077 Cell: 9825007201/9723766007 Email: [email protected] 401/402/423/424/324, Medicine Market, Opp. Shefali Center, Paidi Cross R d , Ahmedabad.
Location: Village Dabhasa (IV6) Unit: dB(A)
Min Reading during Night time
5:00 PM 6:00 PM
Max Sr. No.
Sr. No.
13 7:00 PM 49.2 50.4
Sr. No.
52.6 54.9
14 15
Max Reading during daytime
Max Reading during daytime
53.2 56.8
8:00 PM 9:00 PM
Reading during Night time
Sr. No.
Min
Min
Leq Day
51.8 47.6
Min
Ld - 53.7
Max
52.5 49.8
Leq Day & Night Ldn- 51.9
A-212
SAN ENVBIROTECH PVT. LTD, Accredited QCI-NABET Consultant
MoEF Recognized Environmental Laboratory Under EP,.9cf, 1986 GPCB Recognized Schedule-ll Auditors
ISO 9001,14001 & OHSAS l m l certifies Company GSlfN: 24AACSCS5415ClZR
"
Location: Nr BUS stop Padra (N7) Unit: dB(A) 1 Sr. Reading during 1 Min I Max Sr. Reading during I Min I Max I
P h m No. 079-26583077 Cell: 9825007281/9?2376f3007 Email: [email protected] 4011402/423/424/324, Medicine Market, Opp. Shetali Center, Paldi Crws Road, Ahmedabad.
Location: Village Ranu (N8) Unit: dB(A) Max Sr.
No. Reading during
Night time Sr. No.
Reading during daytime
Min Min Max
A-213
Accredited QCI-NABET Consulrant MOEF Recognized EnvimnmenKal Laboratory Under EP Act. 1986
GPCB Recogn~zed Schedule-11 Auditors I S 0 9001.14001. & OHSAS 18001 CcrMfed Uomoanv
Location: Village Bhoj (N9) Unit: dB(A) Min Max Sr. Reading during
No. Night time
10 11 12
P b n e No. 079-2€i%Ew77 Cell: 9&Z5007201/97237664H177 Emair: [email protected] 4M/402#'423/424/324, Wdicine Market, Opp. SheQli Center, Pal& 005s Road, Ahmedabad.
13
4:00 PM 5:00 PM 6:00 PM
-
7:00 PM
42.1 44.3 43.6 42.8
14
53.0 56.3 59.4
41.7 8:00 PM 56.7
Leq Day I Leq Night I Ln - 40.3
54.8
Ld - 51.8
I Leq Day & Night I Ldn - 49.9
A-214
Conservation Plan for Peacock or Indian Peafowl (Pavo Cristatus)
Schedule – I Bird Species
Protection Status:
As per IUCN: Classified as Least Concern (LC) on the IUCN Red List (1) and listed
on Appendix II of CITES 3.
Population Trend: Stable
Habitat: Terrestrial
Habitat Type: Forest, Scrubland, Artificial/Terrestrial
Generation Length in Year: 6.1
Movement Patterns: Non Migrant
Indian Peafowl (Pavocristatus)
Scientific classification
Kingdom: Animalia
Phylum: Chordata
Class: Aves
Order: Galliformes
Family: Phasianidae
Genus: Pavo
Species: Pavocristatus
Common Name: Indian Peafowl
Vernacular Name: Mor
A-216
Introduction: The Indian Peafowl (Pavo Cristatus) is a resident breeder in the
Indian subcontinent. The bird was declared as the National Bird of and its
widespread distribution in the country. The species is found in dry semi-desert
grasslands, shrub and deciduous forests. It forges and nests on the ground but
roots on top of trees. It eats seeds, insects, fruits, small mammals and reptiles. The
Indian Peafowl is a ground nesting bird and it lays a clutch of 4-8 eggs which take
28 days to hatch. The eggs are light brown and are laid every other day usually in
the afternoon. The male does not assist with the rearing, and is polygamous.
Poaching of Peacock for their feathers and poisoning by feeding on pesticide treated
seeds are known threats to wild birds. Under the law, collection of tail feather is
allowed only when bird sheds them. The Indian peafowl is under various threats
that include the demand for feathers and wild meat, conflict with farmers during
cropping season, increased use of chemical fertilizer and pesticide and habitat
degradation.
Habitat:
The Indian Peafowl is found mainly on the ground in open scrub forest or on land
under cultivation where they forage for berries, grains but will also prey on snakes,
lizards, and small rodents. Their loud calls make them easy to detect, and in forest
areas often indicate the presence of a predator such as a tiger. They forage on the
ground in small groups and will usually try to escape on foot through undergrowth
and avoid flying, though they will fly into tall trees to roost. The bird has a
celebrated status in Indian mythology, and hence protected culturally in India
especially in Gujarat. The Indian Peafowl is listed as Least Concern by IUCN (2014)
Red data.
Photographs of Peafowl
A-217
Appearance: The male, known as a peacock, is a large bird with a length from bill
to tail of 100 to 115 cm (40 to 46 inches) and to the end of a fully grown train as
much as 195 to 225 cm (78 to 90 inches) and weigh 4–6 kg. The females, or
peahens, are smaller at around 95 cm (38 inches) in length and weigh 2.75– 4 kg.
Indian Peafowl are among the largest and heaviest representatives of the
Phasianidae family. Their size, colour and shape of crest make them unmistakable
within their native distribution range. The male is metallic blue on the crown, the
feathers of the head being short and curled. The fan shaped crest on the head is
made of feathers with bare black shafts and tipped with blush-green webbing. A
white stripe above the eye and a crescent shaped white patch below the eye are
formed by bare white skin. The sides of the head have iridescent greenish blue
feathers. The back has scaly bronze-green feathers with black and copper
markings. The scapular and the wings are buff and barred in black, the primaries
are chestnut and the secondaries are black. The tail is dark brown and the "train" is
made up of elongated upper tail coverts (more than 200 feathers, the actual tail
has only 20 feathers) and nearly all of these feathers end with an elaborate eye-
spot. A few of the outer feathers lack the spot and end in a crescent shaped black
tip. The underside is dark glossy green shading into blackish under the tail. The
thighs are buff coloured. The male has a spur on the leg above the hind toe.
Peacocks are polygamous, and the breeding season is spread out but appears to be
dependent on the rains. Several males may congregate at a lek site and these
males are often closely related. Males at lek appear to maintain small territories
next to each other and they allow females to visit them and make no attempt to
guard harems. Females do not appear to favour specific males. Peafowl are
A-218
omnivorous and eat seeds, insects, fruits, and reptiles. A large percentage of their
food is made up of the fallen berries. Around cultivated areas; peafowl feed on a
wide range of crops such as groundnut, tomato, paddy, etc. Around human
habitations, they feed on a variety of food scraps. In the countryside, it is
particularly partial to crops and garden plants.
Status & impact in the Study Area:
No peacock was sighted in the project site. All the direct sightings of the peacock
were located near the human habitats, villages and agriculture field, of study area.
This species is well adapted to natural village environment setting. Day time they
temporarily move towards the surrounding agriculture areas for feeding while
during night time they roost on the trees present in the village and in the
agriculture hedges.
Since Indian Peafowl is a ground nester, several project activities can have adverse
Impact on their nesting grounds such as pollution, degradation of soil and
vegetation from surrounding area and in the forest areas. Direct disturbance by
presence of people, vehicle their noise, vibration, light etc. can potentially disturb
most of the bird species.
Threats in the Study Area:
No perceptible threats were identified in the study region, as
Village residents are against hunting or poaching of the peafowl, due to
culture and mythology reasons.
Majority villagers follow Hinduism in the region, thus they have high respect
towards peacocks due to mythological reasons, and
Literacy levels are greater than 80% in the study region and people are
aware with the significance of the peacock as the national bird.
Conservation: Following actions for the conservation and protection are suggested
in wildlife conservation action plan to reduce impacts of project related activities on
the species. Based on our field observation on the distribution, behavioural ecology,
conservation need, and envisaged impacts of proposed project.
Conservation through Habitat Improvement and Awareness
Habitat improvement programme can be undertaken through plantation of suitable
tree species in the surrounding villages. While selecting the tree/ shrub species care
shall be provided for beery plants which attract these birds. During summer period,
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villagers will be encouraged to use the old earthen pots to fill with water for
drinking these birds.
Seed Distribution among the Villagers:
Summer is the time when these birds are facing shortage of feeds, there by
supplying the feed like Bajri, Juwar, Maize to the surrounding villages with good
population of Indian peafowls will suffix the problem of food shortage.
Conservation Measures with fund allocation:
In consultation of the forest department, following conservation measures will be
adapted for peacock conservation:
1. Increasing the tree cover in the study area which will provide shelter and
roosting to the peacocks. This can be achieved by planting of local tree species
like Neem, Shirish, Khakhro, Haldu, Amli, Banyan, Peepal and Peeper or other
Ficus sp. Vacant places such as edges of agricultural fields, village Gauchar,
Panchayat’s common land, neighbourhood of people inhibiting, road side avenue
tree plantation, open scrubs, ravines, school compounds can be selected for
practicing the plantation activity.
2. School level awareness programmes will be conducted for conservation of
peacocks in the study area by organizing competitions during “Wildlife Week”
and “Van Mahotsav” celebrations by active involvement of local community.
3. Some provision of rewards to informers for the control of poaching and illegal
trade in wildlife.
4. Carrying out census and research projects to know the potential threats and
population status of the species in collaboration of local schools, colleges,
panchayats and forest department.
5. Suggest strategies to minimize negative impacts of changing environment in
nearby area of peacock populations and to promote conservation of peacock
habitats.
6. Another way to help preserve the endangered species is to create society
dedicated to ecological ethics. All the conservation measures will be
implemented with the help of and in the consultation of the district forest
department.
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The proponent has proposed a sum of Rs. 220000/- for the “Peacock”
conservation plan under the following heads:
Sr.
No.
Work or Activity Approximate
Cost. Rs.
Village
1 Plantation-350 tree plants (5 feet height
as per the plant species-Cost of sapling
will be changed per year)
70,000/-(@
200/-per
plant)
Dabhasa, Ranu,
Dhobikuwa and
Mahuvad
2 Small water tank–10 nos. @ 10000/-per
tank
1,00,000/-
3 One awareness programme for “Peacock”
conservation
20,000/- Study area
4 3 cash prizes @ 10000 in a year will be
awarded to the informer of poachers.
30,000/-
Total 2,20,000/-
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