HIT-HY 170 - Hilti United Kingdom · PDF fileHIT-HY 170 Safety information for...

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HIT-HY 170 Safety information for 2-Component-products Date of issue: 12/01/2016 Revision date: 12/01/2016 Supersedes: 06/11/2015 Version: 1.2 12/01/2016 EN (English) 1/20 SECTION 1: Kit identification 1.1 Product identifier Name HIT-HY 170 Product code BU Anchor 1.2 Details of the supplier of the Safety information for 2-Component-products Hilti (Gt. Britain) Ltd. 1 Trafford Wharf Road M17 1BY Manchester - Great Britain T +44 161 886 1000 0800 886 100 Toll-free - F +44 161 872 1240 [email protected] SECTION 2: General information Storage Storage temperature: 5 - 25 °C A SDS for each of these components is included. Please do not separate any component SDS from this cover page This Kit should be handled in accordance with good laboratory practices and appropriate personal protective equipment should be used SECTION 3: Kit contents Classification of the Product Classification according to Regulation (EC) No. 1272/2008 [CLP] Eye Irrit. 2 H319 Skin Sens. 1 H317 Aquatic Acute 1 H400 Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) GHS07 GHS09 Signal word (CLP) Warning Hazardous ingredients methacrylates, dibenzoyl peroxide Hazard statements (CLP) H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H400 - Very toxic to aquatic life Precautionary statements (CLP) P262 - Do not get in eyes, on skin, or on clothing P280 - Wear eye protection, protective clothing, protective gloves P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P302+P352 - IF ON SKIN: Wash with plenty of water P333+P313 - If skin irritation or rash occurs: Get medical advice/attention

Transcript of HIT-HY 170 - Hilti United Kingdom · PDF fileHIT-HY 170 Safety information for...

Page 1: HIT-HY 170 - Hilti United Kingdom · PDF fileHIT-HY 170 Safety information for 2-Component-products 12/01/2016 EN (English) 2/20 P337+P313 - If eye irritation persists: Get medical

HIT-HY 170

Safety information for 2-Component-products

Date of issue: 12/01/2016 Revision date: 12/01/2016 Supersedes: 06/11/2015 Version: 1.2

12/01/2016 EN (English) 1/20

SECTION 1: Kit identification

1.1 Product identifier

Name HIT-HY 170

Product code BU Anchor

1.2 Details of the supplier of the Safety information for 2-Component-products

Hilti (Gt. Britain) Ltd. 1 Trafford Wharf Road M17 1BY Manchester - Great Britain T +44 161 886 1000 0800 886 100 Toll-free - F +44 161 872 1240 [email protected]

SECTION 2: General information

Storage Storage temperature: 5 - 25 °C

A SDS for each of these components is included. Please do not separate any component SDS from this cover page

This Kit should be handled in accordance with good laboratory practices and appropriate personal protective equipment should be used

SECTION 3: Kit contents

Classification of the Product

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Eye Irrit. 2 H319 Skin Sens. 1 H317 Aquatic Acute 1 H400

Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]

Hazard pictograms (CLP)

GHS07

GHS09

Signal word (CLP) Warning

Hazardous ingredients methacrylates, dibenzoyl peroxide

Hazard statements (CLP) H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H400 - Very toxic to aquatic life

Precautionary statements (CLP) P262 - Do not get in eyes, on skin, or on clothing P280 - Wear eye protection, protective clothing, protective gloves P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P302+P352 - IF ON SKIN: Wash with plenty of water P333+P313 - If skin irritation or rash occurs: Get medical advice/attention

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HIT-HY 170

Safety information for 2-Component-products

12/01/2016 EN (English) 2/20

P337+P313 - If eye irritation persists: Get medical advice/attention

Additional information

2-Component-foilpack, contains: Component A: Urethane methacrylate resin, inorganic filler Component B: Dibenzoyl peroxide, phlegmatized

Name General description Quantity Unit Classification according to Regulation (EC) No. 1272/2008 [CLP]

HIT-HY 170, A 1 pcs (pieces) Eye Irrit. 2, H319 Skin Sens. 1, H317

HIT-HY 170, B 1 pcs (pieces) Skin Sens. 1, H317 Aquatic Acute 1, H400

SECTION 4: General information

General advice For professional users only

SECTION 5: Safe handling advice

Environmental precautions Prevent entry to sewers and public waters Notify authorities if liquid enters sewers or public waters

Storage conditions Keep cool. Protect from sunlight

Precautions for safe handling Wear personal protective equipment Avoid contact with skin and eyes Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Provide good ventilation in process area to prevent formation of vapour

Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation Recover mechanically the product Store away from other materials

For containment Collect spillage

Incompatible materials Sources of ignition Direct sunlight

Incompatible products Strong bases Strong acids

SECTION 6: First aid measures

First-aid measures after eye contact Rinse immediately with plenty of water Remove contact lenses, if present and easy to do. Continue rinsing Obtain medical attention if pain, blinking or redness persist

First-aid measures after ingestion Rinse mouth Drink plenty of water Get medical advice/attention Do not induce vomiting Obtain emergency medical attention

First-aid measures after inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing Allow breathing of fresh air Allow the victim to rest

First-aid measures after skin contact Wash contaminated clothing before reuse Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention

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HIT-HY 170

Safety information for 2-Component-products

12/01/2016 EN (English) 3/20

First-aid measures general Remove/Take off immediately all contaminated clothing Never give anything by mouth to an unconscious person If you feel unwell, seek medical advice (show the label where possible)

Symptoms/injuries after skin contact May cause an allergic skin reaction

SECTION 7: Fire fighting measures

Firefighting instructions Use water spray or fog for cooling exposed containers Exercise caution when fighting any chemical fire Prevent fire-fighting water from entering environment

Protection during firefighting Self-contained breathing apparatus Do not enter fire area without proper protective equipment, including respiratory protection

Hazardous decomposition products in case of fire

Thermal decomposition generates : Carbon dioxide Carbon monoxide

SECTION 8: Other information

No data available

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HIT-HY 170, B Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

Date of issue: 20/11/2015 Revision date: 06/11/2015 Supersedes: 08/01/2015 Version: 1.1

12/01/2016 EN (English) 4/20

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form Mixture

Name HIT-HY 170, B

Product code BU Anchor

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identified uses

Industrial/Professional use spec For professional use only

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

Supplier Hilti (Gt. Britain) Ltd. 1 Trafford Wharf Road M17 1BY Manchester - Great Britain T +44 161 886 1000 0800 886 100 Toll-free - F +44 161 872 1240 [email protected]

Department issuing data specification sheet Hilti Entwicklungsgesellschaft mbH Hiltistrasse 6 86916 Kaufering - Deutschland T +49 8191 906310 - F +49 8191 90176310 [email protected]

1.4. Emergency telephone number

Emergency number Schweizerisches Toxikologisches Informationszentrum – 24h Service

+41 44 251 51 51 (international)

+44 161 886 1000 0800 886 100 Toll-free

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Skin Sens. 1 H317

Aquatic Acute 1 H400

Full text of hazard classes and H-statements : see section 16

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display

Hazard pictograms (CLP)

GHS07

GHS09

Signal word (CLP) Warning

Hazardous ingredients dibenzoyl peroxide

Hazard statements (CLP) H317 - May cause an allergic skin reaction H400 - Very toxic to aquatic life

Precautionary statements (CLP) P280 - Wear eye protection, protective clothing, protective gloves P262 - Do not get in eyes, on skin, or on clothing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove

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HIT-HY 170, B Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 5/20

contact lenses, if present and easy to do. Continue rinsing P302+P352 - IF ON SKIN: Wash with plenty of water P337+P313 - If eye irritation persists: Get medical advice/attention P333+P313 - If skin irritation or rash occurs: Get medical advice/attention

2.3. Other hazards

No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance

Not applicable

3.2. Mixture

Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]

dibenzoyl peroxide (CAS No) 94-36-0 (EC no) 202-327-6 (EC index no) 617-008-00-0 (REACH-no) 01-2119511472-50

5 - 10 Org. Perox. B, H241 Eye Irrit. 2, H319 Skin Sens. 1, H317 Aquatic Acute 1, H400 (M=10)

Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general Remove/Take off immediately all contaminated clothing. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

First-aid measures after inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Allow breathing of fresh air. Allow the victim to rest.

First-aid measures after skin contact Wash contaminated clothing before reuse. Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention.

First-aid measures after eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if pain, blinking or redness persist.

First-aid measures after ingestion Rinse mouth. Drink plenty of water. Get medical advice/attention. Do not induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries after skin contact May cause an allergic skin reaction.

4.3. Indication of any immediate medical attention and special treatment needed

No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Water spray. Carbon dioxide. Dry powder. Foam. Sand.

Unsuitable extinguishing media Do not use a heavy water stream.

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HIT-HY 170, B Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 6/20

5.2. Special hazards arising from the substance or mixture

Hazardous decomposition products in case of fire

Thermal decomposition generates : Carbon dioxide. Carbon monoxide.

5.3. Advice for firefighters

Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.

Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Emergency procedures Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection.

Emergency procedures Ventilate area.

6.2. Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning up

For containment Collect spillage.

Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation. Recover mechanically the product. Store away from other materials.

Other information Dispose of materials or solid residues at an authorized site.

6.4. Reference to other sections

For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.

Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions Keep cool. Protect from sunlight.

Incompatible products Strong bases. Strong acids.

Incompatible materials Sources of ignition. Direct sunlight.

Storage temperature 5 - 25 °C

7.3. Specific end use(s)

No additional information available

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HIT-HY 170, B Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 7/20

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

dibenzoyl peroxide (94-36-0)

United Kingdom Local name Dibenzoyl peroxide

United Kingdom WEL TWA (mg/m³) 5 mg/m³

Additional information The product has a pasty consistency. Exposure limit values for respirable dusts ar not relevant for this product.

8.2. Exposure controls

Personal protective equipment Avoid all unnecessary exposure. Safety glasses. Gloves. Protective clothing.

Hand protection Wear protective gloves

Type Material Permeation Thickness (mm) Standard

Disposable gloves Nitrile rubber (NBR) 6 (> 480 minutes) 0,12 EN 374

Eye protection Chemical goggles or safety glasses

Type Use Characteristics Standard

Safety glasses Droplet clear EN 166, EN 170

Skin and body protection Wear suitable protective clothing

Environmental exposure controls Avoid release to the environment.

Consumer exposure controls Avoid contact during pregnancy/while nursing.

Other information Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state Solid

Appearance Thixotropic paste.

Colour white.

Odour characteristic.

Odour threshold Not determined

pH ≈ 6

Relative evaporation rate (butylacetate=1) No data available

Melting point No data available

Freezing point No data available

Boiling point No data available

Flash point No data available

Auto-ignition temperature Not self-igniting

Decomposition temperature No data available

Flammability (solid, gas) Non flammable

Vapour pressure No data available

Relative vapour density at 20 °C No data available

Relative density No data available

Density 1.7 g/cm³ DIN 51757

Solubility Water: Not miscible

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HIT-HY 170, B Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 8/20

Log Pow No data available

Viscosity, kinematic No data available

Viscosity, dynamic 90 Pa.s HN-0333

Explosive properties Product is not explosive.

Oxidising properties No data available

Explosive limits No data available

9.2. Other information

SADT 65 °C

SECTION 10: Stability and reactivity

10.1. Reactivity

No additional information available

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No additional information available.

10.4. Conditions to avoid

Direct sunlight. Extremely high or low temperatures.

10.5. Incompatible materials

Strong acids. Strong bases.

10.6. Hazardous decomposition products

fume. Carbon monoxide. Carbon dioxide. Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity Not classified

dibenzoyl peroxide (94-36-0)

LD50 oral rat > 5000 mg/kg bodyweight (Rat; Equivalent or similar to OECD 401; Weight of evidence)

Skin corrosion/irritation Not classified

Based on available data, the classification criteria are not met

pH: ≈ 6

Serious eye damage/irritation Not classified

Based on available data, the classification criteria are not met

pH: ≈ 6

Respiratory or skin sensitisation May cause an allergic skin reaction.

Germ cell mutagenicity Not classified

Based on available data, the classification criteria are not met

Carcinogenicity Not classified

Based on available data, the classification criteria are not met

Reproductive toxicity Not classified

Based on available data, the classification criteria are not met

Specific target organ toxicity (single exposure) Not classified

Based on available data, the classification criteria are not met

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HIT-HY 170, B Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 9/20

Specific target organ toxicity (repeated exposure)

Not classified

Based on available data, the classification criteria are not met

Aspiration hazard Not classified

Based on available data, the classification criteria are not met

HIT-HY 170, B

Viscosity, kinematic 52941.17647059 mm²/s

Potential adverse human health effects and symptoms

Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

12.1. Toxicity

dibenzoyl peroxide (94-36-0)

LC50 fish 1 2 mg/l (96 h; Poecilia reticulata)

EC50 Daphnia 1 0.07 mg/l

LC50 fish 2 0.0602 mg/l (96h; Oncorhynchus mykiss; ECHA)

NOEC (acute) 0.0316 mg/l (96h; Oncorhynchus mykiss; ECHA)

12.2. Persistence and degradability

HIT-HY 170, B

Persistence and degradability Not established.

dibenzoyl peroxide (94-36-0)

Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.

12.3. Bioaccumulative potential

HIT-HY 170, B

Bioaccumulative potential Not established.

dibenzoyl peroxide (94-36-0)

Log Pow 3.71 (QSAR; 3.2; Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method; 22 °C)

Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

Additional information Avoid release to the environment

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Regional legislation (waste) Disposal must be done according to official regulations.

Waste disposal recommendations Refer to manufacturer/supplier for information on recovery/recycling. Dispose of contents/container to Avoid release to the environment, Refer to manufacturer/supplier for information on recovery/recycling.

Ecology - waste materials Avoid release to the environment.

European List of Waste (LoW) code 08 04 09* - waste adhesives and sealants containing organic solvents or other dangerous substances 20 01 27* - paint, inks, adhesives and resins containing dangerous substances

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HIT-HY 170, B Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 10/20

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN Other information No supplementary information available

ADR IMDG IATA RID

14.1. UN number Not regulated for transport

14.2. UN proper shipping name Not applicable Not applicable Not applicable Not applicable

14.3. Transport hazard class(es) Not applicable Not applicable Not applicable Not applicable

Not applicable Not applicable Not applicable Not applicable

14.4. Packing group Not applicable Not applicable

Not applicable Not applicable

14.5. Environmental hazards Dangerous for the environment : Yes

Dangerous for the environment : Yes Marine pollutant : Yes

Dangerous for the environment : Yes

Dangerous for the environment : Yes

ADR 5.2.1.8.1 derogation applies (quantity of liquids ≤ 5 litres or net mass of solids ≤ 5 kg)

No supplementary information available

14.6. Special precautions for user

- Overland transport

- Transport by sea

No data available

- Air transport

No data available

- Rail transport

Carriage prohibited (RID) No

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations

Contains no REACH substances with Annex XVII restrictions

Contains no substance on the REACH candidate list

Contains no REACH Annex XIV substances

15.1.2. National regulations

No additional information available

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HIT-HY 170, B Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 11/20

15.2. Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

Other information None.

Full text of H- and EUH-statements:

Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1

Eye Irrit. 2 Serious eye damage/eye irritation, Category 2

Org. Perox. B Organic Peroxides, Type B

Skin Sens. 1 Sensitisation — Skin, Category 1

H241 Heating may cause a fire or explosion

H317 May cause an allergic skin reaction

H319 Causes serious eye irritation

H400 Very toxic to aquatic life

SDS_EU_Hilti

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product

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HIT-HY 170, A Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

Date of issue: 20/11/2015 Revision date: 06/11/2015 Supersedes: 08/01/2015 Version: 1.1

12/01/2016 EN (English) 12/20

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form Mixture

Name HIT-HY 170, A

Product code BU Anchor

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identified uses

No additional information available

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

Supplier Hilti (Gt. Britain) Ltd. 1 Trafford Wharf Road M17 1BY Manchester - Great Britain T +44 161 886 1000 0800 886 100 Toll-free - F +44 161 872 1240 [email protected]

Department issuing data specification sheet Hilti Entwicklungsgesellschaft mbH Hiltistrasse 6 86916 Kaufering - Deutschland T +49 8191 906310 - F +49 8191 90176310 [email protected]

1.4. Emergency telephone number

Emergency number Schweizerisches Toxikologisches Informationszentrum – 24h Service

+41 44 251 51 51 (international)

+44 161 886 1000 0800 886 100 Toll-free

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Eye Irrit. 2 H319

Skin Sens. 1 H317

Full text of hazard classes and H-statements : see section 16

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display

Hazard pictograms (CLP)

GHS07

Signal word (CLP) Warning

Hazardous ingredients 1,4-Butanediol dimethacrylate, 2-Hydroxypropyl methacrylate

Hazard statements (CLP) H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation

Precautionary statements (CLP) P280 - Wear eye protection, protective clothing, protective gloves P262 - Do not get in eyes, on skin, or on clothing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove

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HIT-HY 170, A Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 13/20

contact lenses, if present and easy to do. Continue rinsing P302+P352 - IF ON SKIN: Wash with plenty of water P337+P313 - If eye irritation persists: Get medical advice/attention P333+P313 - If skin irritation or rash occurs: Get medical advice/attention

2.3. Other hazards

No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance

Not applicable

3.2. Mixture

Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]

2-Hydroxypropyl methacrylate (CAS No) 27813-02-1 (EC no) 248-666-3 (EC index no) 607-125-00-5 (REACH-no) 01-2119490226-37

10 - 25 Eye Irrit. 2, H319 Skin Sens. 1, H317

1,4-Butanediol dimethacrylate (CAS No) 2082-81-7 (EC no) 218-218-1 (REACH-no) 01-2119967415-30

1 - 2.5 Skin Sens. 1B, H317

1,1'-(p-tolylimino)dipropan-2-ol (CAS No) 38668-48-3 (EC no) 254-075-1 (REACH-no) 01-2119980937-17

0.1 - 1 Acute Tox. 2 (Oral), H300 Eye Irrit. 2, H319 Aquatic Chronic 3, H412

1,2-dihydroxybenzene, pyrocatechol (CAS No) 120-80-9 (EC no) 204-427-5 (EC index no) 604-016-00-4

0.1 - 1 Acute Tox. 3 (Oral), H301

Acute Tox. 3 (Dermal), H311 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317 Muta. 2, H341

Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general Remove/Take off immediately all contaminated clothing. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

First-aid measures after inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Allow breathing of fresh air. Allow the victim to rest.

First-aid measures after skin contact Wash contaminated clothing before reuse. Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention.

First-aid measures after eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if pain, blinking or redness persist.

First-aid measures after ingestion Rinse mouth. Drink plenty of water. Get medical advice/attention. Do not induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries after skin contact May cause an allergic skin reaction.

4.3. Indication of any immediate medical attention and special treatment needed

No additional information available

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HIT-HY 170, A Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 14/20

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Water spray. Carbon dioxide. Dry powder. Foam. Sand.

Unsuitable extinguishing media Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

Hazardous decomposition products in case of fire

Thermal decomposition generates : Carbon dioxide. Carbon monoxide.

5.3. Advice for firefighters

Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.

Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Emergency procedures Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection.

Emergency procedures Ventilate area.

6.2. Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning up

For containment Collect spillage.

Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation. Recover mechanically the product. Store away from other materials.

Other information Dispose of materials or solid residues at an authorized site.

6.4. Reference to other sections

For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.

Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions Keep cool. Protect from sunlight.

Incompatible products Strong bases. Strong acids.

Incompatible materials Sources of ignition. Direct sunlight.

Storage temperature 5 - 25 °C

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HIT-HY 170, A Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 15/20

7.3. Specific end use(s)

No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Additional information The product has a pasty consistency. Exposure limit values for respirable dusts ar not relevant for this product.

8.2. Exposure controls

Personal protective equipment Avoid all unnecessary exposure. Safety glasses. Gloves. Protective clothing.

Hand protection Wear protective gloves

Type Material Permeation Thickness (mm) Standard

Disposable gloves Nitrile rubber (NBR) 6 (> 480 minutes) 0,12 EN 374

Eye protection Chemical goggles or safety glasses

Type Use Characteristics Standard

Safety glasses Droplet clear EN 166, EN 170

Skin and body protection Wear suitable protective clothing

Environmental exposure controls Avoid release to the environment.

Consumer exposure controls Avoid contact during pregnancy/while nursing.

Other information Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state Solid

Appearance Thixotropic paste.

Colour Light grey.

Odour characteristic.

Odour threshold Not determined

pH No data available

Relative evaporation rate (butylacetate=1) No data available

Melting point No data available

Freezing point No data available

Boiling point No data available

Flash point > 109 °C DIN EN ISO 1523

Auto-ignition temperature Not self-igniting

Decomposition temperature No data available

Flammability (solid, gas) Non flammable

Vapour pressure No data available

Relative vapour density at 20 °C No data available

Relative density No data available

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HIT-HY 170, A Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 16/20

Density 1.65 g/ml AW 4.3.23

Solubility Water: Not miscible

Log Pow No data available

Viscosity, kinematic No data available

Viscosity, dynamic 100 Pa.s HN-0333

Explosive properties Product is not explosive.

Oxidising properties No data available

Explosive limits No data available

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity

No additional information available

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No additional information available.

10.4. Conditions to avoid

Direct sunlight. Extremely high or low temperatures.

10.5. Incompatible materials

Strong acids. Strong bases.

10.6. Hazardous decomposition products

fume. Carbon monoxide. Carbon dioxide. Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity Not classified

1,1'-(p-tolylimino)dipropan-2-ol (38668-48-3)

LD50 oral rat 25 mg/kg

LD50 dermal rat > 2000 mg/kg

1,4-Butanediol dimethacrylate (2082-81-7)

LD50 oral rat 10066 mg/kg

LD50 dermal rat > 3000 mg/kg

2-Hydroxypropyl methacrylate (27813-02-1)

LD50 oral rat > 5000 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Literature study; >=2000 mg/kg bodyweight; Rat; Experimental value)

LD50 dermal rabbit >= 5000 mg/kg bodyweight (Rabbit; Experimental value)

Skin corrosion/irritation Not classified

Based on available data, the classification criteria are not met

Serious eye damage/irritation Causes serious eye irritation.

Based on available data, the classification criteria are not met

Respiratory or skin sensitisation May cause an allergic skin reaction.

Germ cell mutagenicity Not classified

Based on available data, the classification criteria are not met

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HIT-HY 170, A Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 17/20

Carcinogenicity Not classified

Based on available data, the classification criteria are not met

Reproductive toxicity Not classified

Based on available data, the classification criteria are not met

Specific target organ toxicity (single exposure) Not classified

Based on available data, the classification criteria are not met

Specific target organ toxicity (repeated exposure)

Not classified

Based on available data, the classification criteria are not met

Aspiration hazard Not classified

Based on available data, the classification criteria are not met

HIT-HY 170, A

Viscosity, kinematic 60606.06060606 mm²/s

Potential adverse human health effects and symptoms

Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

12.1. Toxicity

1,1'-(p-tolylimino)dipropan-2-ol (38668-48-3)

LC50 fish 1 ≈ 17 mg/l

LC50 other aquatic organisms 1 245 mg/l

EC50 Daphnia 1 28.8 mg/l

NOEC (acute) 57.8 mg/l

1,4-Butanediol dimethacrylate (2082-81-7)

LC50 fish 1 32.5 mg/l

LC50 other aquatic organisms 1 9.79 mg/l

NOEC (acute) 7.51 mg/l

NOEC (chronic) 20 mg/l

1,2-dihydroxybenzene, pyrocatechol (120-80-9)

LC50 fish 1 9.22 mg/l

LC50 other aquatic organisms 1 22 mg/l

2-Hydroxypropyl methacrylate (27813-02-1)

LC50 fish 1 493 mg/l (48 h; Leuciscus idus; GLP)

EC50 Daphnia 1 > 143 mg/l (48 h; Daphnia magna; GLP)

Threshold limit algae 1 > 97.2 mg/l (72 h; Pseudokirchneriella subcapitata; GLP)

Threshold limit algae 2 > 97.2 mg/l (72 h; Pseudokirchneriella subcapitata; GLP)

12.2. Persistence and degradability

HIT-HY 170, A

Persistence and degradability Not established.

1,4-Butanediol dimethacrylate (2082-81-7)

Biodegradation 84 %

2-Hydroxypropyl methacrylate (27813-02-1)

Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.

12.3. Bioaccumulative potential

HIT-HY 170, A

Bioaccumulative potential Not established.

1,1'-(p-tolylimino)dipropan-2-ol (38668-48-3)

BCF fish 1 ≈

Log Kow 2.1

1,4-Butanediol dimethacrylate (2082-81-7)

Log Pow 3.1

2-Hydroxypropyl methacrylate (27813-02-1)

BCF fish 1 <= 100 (Pisces)

BCF fish 2 3.2 (Pisces; QSAR)

Log Pow 0.97 (OECD 102: Melting Point/Melting Range)

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HIT-HY 170, A Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 18/20

Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

Additional information Avoid release to the environment

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Regional legislation (waste) Disposal must be done according to official regulations.

Waste disposal recommendations Refer to manufacturer/supplier for information on recovery/recycling. Dispose of contents/container to Avoid release to the environment, Refer to manufacturer/supplier for information on recovery/recycling.

Ecology - waste materials Avoid release to the environment.

European List of Waste (LoW) code 08 04 09* - waste adhesives and sealants containing organic solvents or other dangerous substances 20 01 27* - paint, inks, adhesives and resins containing dangerous substances

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN Other information No supplementary information available

ADR IMDG IATA RID

14.1. UN number Not regulated for transport

14.2. UN proper shipping name Not applicable Not applicable Not applicable Not applicable

14.3. Transport hazard class(es) Not applicable Not applicable Not applicable Not applicable

Not applicable Not applicable Not applicable Not applicable

14.4. Packing group Not applicable Not applicable

Not applicable Not applicable

14.5. Environmental hazards Dangerous for the environment : No

Dangerous for the environment : No Marine pollutant : No

Dangerous for the environment : No

Dangerous for the environment : No

No supplementary information available

14.6. Special precautions for user

- Overland transport

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HIT-HY 170, A Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 19/20

- Transport by sea

No data available

- Air transport

No data available

- Rail transport

Carriage prohibited (RID) No

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations

Contains no REACH substances with Annex XVII restrictions

Contains no substance on the REACH candidate list

Contains no REACH Annex XIV substances

15.1.2. National regulations

No additional information available

15.2. Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

Other information None.

Full text of H- and EUH-statements:

Acute Tox. 2 (Oral) Acute toxicity (oral), Category 2

Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3

Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3

Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4

Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3

Eye Dam. 1 Serious eye damage/eye irritation, Category 1

Eye Irrit. 2 Serious eye damage/eye irritation, Category 2

Muta. 2 Germ cell mutagenicity, Category 2

Skin Irrit. 2 Skin corrosion/irritation, Category 2

Skin Sens. 1 Sensitisation — Skin, Category 1

Skin Sens. 1B Sensitisation — Skin, category 1B

H300 Fatal if swallowed

H301 Toxic if swallowed

H311 Toxic in contact with skin

H315 Causes skin irritation

H317 May cause an allergic skin reaction

H318 Causes serious eye damage

H319 Causes serious eye irritation

H332 Harmful if inhaled

H341 Suspected of causing genetic defects

H412 Harmful to aquatic life with long lasting effects

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HIT-HY 170, A Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010

12/01/2016 EN (English) 20/20

SDS_EU_Hilti

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product