HIT-HY 170 - Hilti United Kingdom · PDF fileHIT-HY 170 Safety information for...
Transcript of HIT-HY 170 - Hilti United Kingdom · PDF fileHIT-HY 170 Safety information for...
HIT-HY 170
Safety information for 2-Component-products
Date of issue: 12/01/2016 Revision date: 12/01/2016 Supersedes: 06/11/2015 Version: 1.2
12/01/2016 EN (English) 1/20
SECTION 1: Kit identification
1.1 Product identifier
Name HIT-HY 170
Product code BU Anchor
1.2 Details of the supplier of the Safety information for 2-Component-products
Hilti (Gt. Britain) Ltd. 1 Trafford Wharf Road M17 1BY Manchester - Great Britain T +44 161 886 1000 0800 886 100 Toll-free - F +44 161 872 1240 [email protected]
SECTION 2: General information
Storage Storage temperature: 5 - 25 °C
A SDS for each of these components is included. Please do not separate any component SDS from this cover page
This Kit should be handled in accordance with good laboratory practices and appropriate personal protective equipment should be used
SECTION 3: Kit contents
Classification of the Product
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Eye Irrit. 2 H319 Skin Sens. 1 H317 Aquatic Acute 1 H400
Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP)
GHS07
GHS09
Signal word (CLP) Warning
Hazardous ingredients methacrylates, dibenzoyl peroxide
Hazard statements (CLP) H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H400 - Very toxic to aquatic life
Precautionary statements (CLP) P262 - Do not get in eyes, on skin, or on clothing P280 - Wear eye protection, protective clothing, protective gloves P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P302+P352 - IF ON SKIN: Wash with plenty of water P333+P313 - If skin irritation or rash occurs: Get medical advice/attention
HIT-HY 170
Safety information for 2-Component-products
12/01/2016 EN (English) 2/20
P337+P313 - If eye irritation persists: Get medical advice/attention
Additional information
2-Component-foilpack, contains: Component A: Urethane methacrylate resin, inorganic filler Component B: Dibenzoyl peroxide, phlegmatized
Name General description Quantity Unit Classification according to Regulation (EC) No. 1272/2008 [CLP]
HIT-HY 170, A 1 pcs (pieces) Eye Irrit. 2, H319 Skin Sens. 1, H317
HIT-HY 170, B 1 pcs (pieces) Skin Sens. 1, H317 Aquatic Acute 1, H400
SECTION 4: General information
General advice For professional users only
SECTION 5: Safe handling advice
Environmental precautions Prevent entry to sewers and public waters Notify authorities if liquid enters sewers or public waters
Storage conditions Keep cool. Protect from sunlight
Precautions for safe handling Wear personal protective equipment Avoid contact with skin and eyes Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Provide good ventilation in process area to prevent formation of vapour
Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation Recover mechanically the product Store away from other materials
For containment Collect spillage
Incompatible materials Sources of ignition Direct sunlight
Incompatible products Strong bases Strong acids
SECTION 6: First aid measures
First-aid measures after eye contact Rinse immediately with plenty of water Remove contact lenses, if present and easy to do. Continue rinsing Obtain medical attention if pain, blinking or redness persist
First-aid measures after ingestion Rinse mouth Drink plenty of water Get medical advice/attention Do not induce vomiting Obtain emergency medical attention
First-aid measures after inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing Allow breathing of fresh air Allow the victim to rest
First-aid measures after skin contact Wash contaminated clothing before reuse Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention
HIT-HY 170
Safety information for 2-Component-products
12/01/2016 EN (English) 3/20
First-aid measures general Remove/Take off immediately all contaminated clothing Never give anything by mouth to an unconscious person If you feel unwell, seek medical advice (show the label where possible)
Symptoms/injuries after skin contact May cause an allergic skin reaction
SECTION 7: Fire fighting measures
Firefighting instructions Use water spray or fog for cooling exposed containers Exercise caution when fighting any chemical fire Prevent fire-fighting water from entering environment
Protection during firefighting Self-contained breathing apparatus Do not enter fire area without proper protective equipment, including respiratory protection
Hazardous decomposition products in case of fire
Thermal decomposition generates : Carbon dioxide Carbon monoxide
SECTION 8: Other information
No data available
HIT-HY 170, B Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
Date of issue: 20/11/2015 Revision date: 06/11/2015 Supersedes: 08/01/2015 Version: 1.1
12/01/2016 EN (English) 4/20
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form Mixture
Name HIT-HY 170, B
Product code BU Anchor
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec For professional use only
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
Supplier Hilti (Gt. Britain) Ltd. 1 Trafford Wharf Road M17 1BY Manchester - Great Britain T +44 161 886 1000 0800 886 100 Toll-free - F +44 161 872 1240 [email protected]
Department issuing data specification sheet Hilti Entwicklungsgesellschaft mbH Hiltistrasse 6 86916 Kaufering - Deutschland T +49 8191 906310 - F +49 8191 90176310 [email protected]
1.4. Emergency telephone number
Emergency number Schweizerisches Toxikologisches Informationszentrum – 24h Service
+41 44 251 51 51 (international)
+44 161 886 1000 0800 886 100 Toll-free
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin Sens. 1 H317
Aquatic Acute 1 H400
Full text of hazard classes and H-statements : see section 16
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP)
GHS07
GHS09
Signal word (CLP) Warning
Hazardous ingredients dibenzoyl peroxide
Hazard statements (CLP) H317 - May cause an allergic skin reaction H400 - Very toxic to aquatic life
Precautionary statements (CLP) P280 - Wear eye protection, protective clothing, protective gloves P262 - Do not get in eyes, on skin, or on clothing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
HIT-HY 170, B Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 5/20
contact lenses, if present and easy to do. Continue rinsing P302+P352 - IF ON SKIN: Wash with plenty of water P337+P313 - If eye irritation persists: Get medical advice/attention P333+P313 - If skin irritation or rash occurs: Get medical advice/attention
2.3. Other hazards
No additional information available
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]
dibenzoyl peroxide (CAS No) 94-36-0 (EC no) 202-327-6 (EC index no) 617-008-00-0 (REACH-no) 01-2119511472-50
5 - 10 Org. Perox. B, H241 Eye Irrit. 2, H319 Skin Sens. 1, H317 Aquatic Acute 1, H400 (M=10)
Full text of H-statements: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general Remove/Take off immediately all contaminated clothing. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Allow breathing of fresh air. Allow the victim to rest.
First-aid measures after skin contact Wash contaminated clothing before reuse. Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention.
First-aid measures after eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if pain, blinking or redness persist.
First-aid measures after ingestion Rinse mouth. Drink plenty of water. Get medical advice/attention. Do not induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after skin contact May cause an allergic skin reaction.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media Water spray. Carbon dioxide. Dry powder. Foam. Sand.
Unsuitable extinguishing media Do not use a heavy water stream.
HIT-HY 170, B Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 6/20
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition products in case of fire
Thermal decomposition generates : Carbon dioxide. Carbon monoxide.
5.3. Advice for firefighters
Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection.
Emergency procedures Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment Collect spillage.
Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation. Recover mechanically the product. Store away from other materials.
Other information Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions Keep cool. Protect from sunlight.
Incompatible products Strong bases. Strong acids.
Incompatible materials Sources of ignition. Direct sunlight.
Storage temperature 5 - 25 °C
7.3. Specific end use(s)
No additional information available
HIT-HY 170, B Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 7/20
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
dibenzoyl peroxide (94-36-0)
United Kingdom Local name Dibenzoyl peroxide
United Kingdom WEL TWA (mg/m³) 5 mg/m³
Additional information The product has a pasty consistency. Exposure limit values for respirable dusts ar not relevant for this product.
8.2. Exposure controls
Personal protective equipment Avoid all unnecessary exposure. Safety glasses. Gloves. Protective clothing.
Hand protection Wear protective gloves
Type Material Permeation Thickness (mm) Standard
Disposable gloves Nitrile rubber (NBR) 6 (> 480 minutes) 0,12 EN 374
Eye protection Chemical goggles or safety glasses
Type Use Characteristics Standard
Safety glasses Droplet clear EN 166, EN 170
Skin and body protection Wear suitable protective clothing
Environmental exposure controls Avoid release to the environment.
Consumer exposure controls Avoid contact during pregnancy/while nursing.
Other information Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state Solid
Appearance Thixotropic paste.
Colour white.
Odour characteristic.
Odour threshold Not determined
pH ≈ 6
Relative evaporation rate (butylacetate=1) No data available
Melting point No data available
Freezing point No data available
Boiling point No data available
Flash point No data available
Auto-ignition temperature Not self-igniting
Decomposition temperature No data available
Flammability (solid, gas) Non flammable
Vapour pressure No data available
Relative vapour density at 20 °C No data available
Relative density No data available
Density 1.7 g/cm³ DIN 51757
Solubility Water: Not miscible
HIT-HY 170, B Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 8/20
Log Pow No data available
Viscosity, kinematic No data available
Viscosity, dynamic 90 Pa.s HN-0333
Explosive properties Product is not explosive.
Oxidising properties No data available
Explosive limits No data available
9.2. Other information
SADT 65 °C
SECTION 10: Stability and reactivity
10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. Under normal conditions of storage and use, hazardous decomposition products should not be produced.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity Not classified
dibenzoyl peroxide (94-36-0)
LD50 oral rat > 5000 mg/kg bodyweight (Rat; Equivalent or similar to OECD 401; Weight of evidence)
Skin corrosion/irritation Not classified
Based on available data, the classification criteria are not met
pH: ≈ 6
Serious eye damage/irritation Not classified
Based on available data, the classification criteria are not met
pH: ≈ 6
Respiratory or skin sensitisation May cause an allergic skin reaction.
Germ cell mutagenicity Not classified
Based on available data, the classification criteria are not met
Carcinogenicity Not classified
Based on available data, the classification criteria are not met
Reproductive toxicity Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) Not classified
Based on available data, the classification criteria are not met
HIT-HY 170, B Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 9/20
Specific target organ toxicity (repeated exposure)
Not classified
Based on available data, the classification criteria are not met
Aspiration hazard Not classified
Based on available data, the classification criteria are not met
HIT-HY 170, B
Viscosity, kinematic 52941.17647059 mm²/s
Potential adverse human health effects and symptoms
Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
12.1. Toxicity
dibenzoyl peroxide (94-36-0)
LC50 fish 1 2 mg/l (96 h; Poecilia reticulata)
EC50 Daphnia 1 0.07 mg/l
LC50 fish 2 0.0602 mg/l (96h; Oncorhynchus mykiss; ECHA)
NOEC (acute) 0.0316 mg/l (96h; Oncorhynchus mykiss; ECHA)
12.2. Persistence and degradability
HIT-HY 170, B
Persistence and degradability Not established.
dibenzoyl peroxide (94-36-0)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
12.3. Bioaccumulative potential
HIT-HY 170, B
Bioaccumulative potential Not established.
dibenzoyl peroxide (94-36-0)
Log Pow 3.71 (QSAR; 3.2; Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method; 22 °C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
Additional information Avoid release to the environment
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Regional legislation (waste) Disposal must be done according to official regulations.
Waste disposal recommendations Refer to manufacturer/supplier for information on recovery/recycling. Dispose of contents/container to Avoid release to the environment, Refer to manufacturer/supplier for information on recovery/recycling.
Ecology - waste materials Avoid release to the environment.
European List of Waste (LoW) code 08 04 09* - waste adhesives and sealants containing organic solvents or other dangerous substances 20 01 27* - paint, inks, adhesives and resins containing dangerous substances
HIT-HY 170, B Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 10/20
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN Other information No supplementary information available
ADR IMDG IATA RID
14.1. UN number Not regulated for transport
14.2. UN proper shipping name Not applicable Not applicable Not applicable Not applicable
14.3. Transport hazard class(es) Not applicable Not applicable Not applicable Not applicable
Not applicable Not applicable Not applicable Not applicable
14.4. Packing group Not applicable Not applicable
Not applicable Not applicable
14.5. Environmental hazards Dangerous for the environment : Yes
Dangerous for the environment : Yes Marine pollutant : Yes
Dangerous for the environment : Yes
Dangerous for the environment : Yes
ADR 5.2.1.8.1 derogation applies (quantity of liquids ≤ 5 litres or net mass of solids ≤ 5 kg)
No supplementary information available
14.6. Special precautions for user
- Overland transport
- Transport by sea
No data available
- Air transport
No data available
- Rail transport
Carriage prohibited (RID) No
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2. National regulations
No additional information available
HIT-HY 170, B Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 11/20
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
Other information None.
Full text of H- and EUH-statements:
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Org. Perox. B Organic Peroxides, Type B
Skin Sens. 1 Sensitisation — Skin, Category 1
H241 Heating may cause a fire or explosion
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H400 Very toxic to aquatic life
SDS_EU_Hilti
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product
HIT-HY 170, A Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
Date of issue: 20/11/2015 Revision date: 06/11/2015 Supersedes: 08/01/2015 Version: 1.1
12/01/2016 EN (English) 12/20
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form Mixture
Name HIT-HY 170, A
Product code BU Anchor
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
No additional information available
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
Supplier Hilti (Gt. Britain) Ltd. 1 Trafford Wharf Road M17 1BY Manchester - Great Britain T +44 161 886 1000 0800 886 100 Toll-free - F +44 161 872 1240 [email protected]
Department issuing data specification sheet Hilti Entwicklungsgesellschaft mbH Hiltistrasse 6 86916 Kaufering - Deutschland T +49 8191 906310 - F +49 8191 90176310 [email protected]
1.4. Emergency telephone number
Emergency number Schweizerisches Toxikologisches Informationszentrum – 24h Service
+41 44 251 51 51 (international)
+44 161 886 1000 0800 886 100 Toll-free
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Eye Irrit. 2 H319
Skin Sens. 1 H317
Full text of hazard classes and H-statements : see section 16
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP)
GHS07
Signal word (CLP) Warning
Hazardous ingredients 1,4-Butanediol dimethacrylate, 2-Hydroxypropyl methacrylate
Hazard statements (CLP) H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation
Precautionary statements (CLP) P280 - Wear eye protection, protective clothing, protective gloves P262 - Do not get in eyes, on skin, or on clothing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
HIT-HY 170, A Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 13/20
contact lenses, if present and easy to do. Continue rinsing P302+P352 - IF ON SKIN: Wash with plenty of water P337+P313 - If eye irritation persists: Get medical advice/attention P333+P313 - If skin irritation or rash occurs: Get medical advice/attention
2.3. Other hazards
No additional information available
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]
2-Hydroxypropyl methacrylate (CAS No) 27813-02-1 (EC no) 248-666-3 (EC index no) 607-125-00-5 (REACH-no) 01-2119490226-37
10 - 25 Eye Irrit. 2, H319 Skin Sens. 1, H317
1,4-Butanediol dimethacrylate (CAS No) 2082-81-7 (EC no) 218-218-1 (REACH-no) 01-2119967415-30
1 - 2.5 Skin Sens. 1B, H317
1,1'-(p-tolylimino)dipropan-2-ol (CAS No) 38668-48-3 (EC no) 254-075-1 (REACH-no) 01-2119980937-17
0.1 - 1 Acute Tox. 2 (Oral), H300 Eye Irrit. 2, H319 Aquatic Chronic 3, H412
1,2-dihydroxybenzene, pyrocatechol (CAS No) 120-80-9 (EC no) 204-427-5 (EC index no) 604-016-00-4
0.1 - 1 Acute Tox. 3 (Oral), H301
Acute Tox. 3 (Dermal), H311 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317 Muta. 2, H341
Full text of H-statements: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general Remove/Take off immediately all contaminated clothing. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Allow breathing of fresh air. Allow the victim to rest.
First-aid measures after skin contact Wash contaminated clothing before reuse. Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention.
First-aid measures after eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if pain, blinking or redness persist.
First-aid measures after ingestion Rinse mouth. Drink plenty of water. Get medical advice/attention. Do not induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after skin contact May cause an allergic skin reaction.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
HIT-HY 170, A Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 14/20
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media Water spray. Carbon dioxide. Dry powder. Foam. Sand.
Unsuitable extinguishing media Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition products in case of fire
Thermal decomposition generates : Carbon dioxide. Carbon monoxide.
5.3. Advice for firefighters
Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection.
Emergency procedures Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment Collect spillage.
Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation. Recover mechanically the product. Store away from other materials.
Other information Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions Keep cool. Protect from sunlight.
Incompatible products Strong bases. Strong acids.
Incompatible materials Sources of ignition. Direct sunlight.
Storage temperature 5 - 25 °C
HIT-HY 170, A Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 15/20
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Additional information The product has a pasty consistency. Exposure limit values for respirable dusts ar not relevant for this product.
8.2. Exposure controls
Personal protective equipment Avoid all unnecessary exposure. Safety glasses. Gloves. Protective clothing.
Hand protection Wear protective gloves
Type Material Permeation Thickness (mm) Standard
Disposable gloves Nitrile rubber (NBR) 6 (> 480 minutes) 0,12 EN 374
Eye protection Chemical goggles or safety glasses
Type Use Characteristics Standard
Safety glasses Droplet clear EN 166, EN 170
Skin and body protection Wear suitable protective clothing
Environmental exposure controls Avoid release to the environment.
Consumer exposure controls Avoid contact during pregnancy/while nursing.
Other information Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state Solid
Appearance Thixotropic paste.
Colour Light grey.
Odour characteristic.
Odour threshold Not determined
pH No data available
Relative evaporation rate (butylacetate=1) No data available
Melting point No data available
Freezing point No data available
Boiling point No data available
Flash point > 109 °C DIN EN ISO 1523
Auto-ignition temperature Not self-igniting
Decomposition temperature No data available
Flammability (solid, gas) Non flammable
Vapour pressure No data available
Relative vapour density at 20 °C No data available
Relative density No data available
HIT-HY 170, A Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 16/20
Density 1.65 g/ml AW 4.3.23
Solubility Water: Not miscible
Log Pow No data available
Viscosity, kinematic No data available
Viscosity, dynamic 100 Pa.s HN-0333
Explosive properties Product is not explosive.
Oxidising properties No data available
Explosive limits No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. Under normal conditions of storage and use, hazardous decomposition products should not be produced.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity Not classified
1,1'-(p-tolylimino)dipropan-2-ol (38668-48-3)
LD50 oral rat 25 mg/kg
LD50 dermal rat > 2000 mg/kg
1,4-Butanediol dimethacrylate (2082-81-7)
LD50 oral rat 10066 mg/kg
LD50 dermal rat > 3000 mg/kg
2-Hydroxypropyl methacrylate (27813-02-1)
LD50 oral rat > 5000 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Literature study; >=2000 mg/kg bodyweight; Rat; Experimental value)
LD50 dermal rabbit >= 5000 mg/kg bodyweight (Rabbit; Experimental value)
Skin corrosion/irritation Not classified
Based on available data, the classification criteria are not met
Serious eye damage/irritation Causes serious eye irritation.
Based on available data, the classification criteria are not met
Respiratory or skin sensitisation May cause an allergic skin reaction.
Germ cell mutagenicity Not classified
Based on available data, the classification criteria are not met
HIT-HY 170, A Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 17/20
Carcinogenicity Not classified
Based on available data, the classification criteria are not met
Reproductive toxicity Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity (repeated exposure)
Not classified
Based on available data, the classification criteria are not met
Aspiration hazard Not classified
Based on available data, the classification criteria are not met
HIT-HY 170, A
Viscosity, kinematic 60606.06060606 mm²/s
Potential adverse human health effects and symptoms
Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
12.1. Toxicity
1,1'-(p-tolylimino)dipropan-2-ol (38668-48-3)
LC50 fish 1 ≈ 17 mg/l
LC50 other aquatic organisms 1 245 mg/l
EC50 Daphnia 1 28.8 mg/l
NOEC (acute) 57.8 mg/l
1,4-Butanediol dimethacrylate (2082-81-7)
LC50 fish 1 32.5 mg/l
LC50 other aquatic organisms 1 9.79 mg/l
NOEC (acute) 7.51 mg/l
NOEC (chronic) 20 mg/l
1,2-dihydroxybenzene, pyrocatechol (120-80-9)
LC50 fish 1 9.22 mg/l
LC50 other aquatic organisms 1 22 mg/l
2-Hydroxypropyl methacrylate (27813-02-1)
LC50 fish 1 493 mg/l (48 h; Leuciscus idus; GLP)
EC50 Daphnia 1 > 143 mg/l (48 h; Daphnia magna; GLP)
Threshold limit algae 1 > 97.2 mg/l (72 h; Pseudokirchneriella subcapitata; GLP)
Threshold limit algae 2 > 97.2 mg/l (72 h; Pseudokirchneriella subcapitata; GLP)
12.2. Persistence and degradability
HIT-HY 170, A
Persistence and degradability Not established.
1,4-Butanediol dimethacrylate (2082-81-7)
Biodegradation 84 %
2-Hydroxypropyl methacrylate (27813-02-1)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
12.3. Bioaccumulative potential
HIT-HY 170, A
Bioaccumulative potential Not established.
1,1'-(p-tolylimino)dipropan-2-ol (38668-48-3)
BCF fish 1 ≈
Log Kow 2.1
1,4-Butanediol dimethacrylate (2082-81-7)
Log Pow 3.1
2-Hydroxypropyl methacrylate (27813-02-1)
BCF fish 1 <= 100 (Pisces)
BCF fish 2 3.2 (Pisces; QSAR)
Log Pow 0.97 (OECD 102: Melting Point/Melting Range)
HIT-HY 170, A Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 18/20
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
Additional information Avoid release to the environment
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Regional legislation (waste) Disposal must be done according to official regulations.
Waste disposal recommendations Refer to manufacturer/supplier for information on recovery/recycling. Dispose of contents/container to Avoid release to the environment, Refer to manufacturer/supplier for information on recovery/recycling.
Ecology - waste materials Avoid release to the environment.
European List of Waste (LoW) code 08 04 09* - waste adhesives and sealants containing organic solvents or other dangerous substances 20 01 27* - paint, inks, adhesives and resins containing dangerous substances
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN Other information No supplementary information available
ADR IMDG IATA RID
14.1. UN number Not regulated for transport
14.2. UN proper shipping name Not applicable Not applicable Not applicable Not applicable
14.3. Transport hazard class(es) Not applicable Not applicable Not applicable Not applicable
Not applicable Not applicable Not applicable Not applicable
14.4. Packing group Not applicable Not applicable
Not applicable Not applicable
14.5. Environmental hazards Dangerous for the environment : No
Dangerous for the environment : No Marine pollutant : No
Dangerous for the environment : No
Dangerous for the environment : No
No supplementary information available
14.6. Special precautions for user
- Overland transport
HIT-HY 170, A Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 19/20
- Transport by sea
No data available
- Air transport
No data available
- Rail transport
Carriage prohibited (RID) No
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2. National regulations
No additional information available
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
Other information None.
Full text of H- and EUH-statements:
Acute Tox. 2 (Oral) Acute toxicity (oral), Category 2
Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4
Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Muta. 2 Germ cell mutagenicity, Category 2
Skin Irrit. 2 Skin corrosion/irritation, Category 2
Skin Sens. 1 Sensitisation — Skin, Category 1
Skin Sens. 1B Sensitisation — Skin, category 1B
H300 Fatal if swallowed
H301 Toxic if swallowed
H311 Toxic in contact with skin
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H319 Causes serious eye irritation
H332 Harmful if inhaled
H341 Suspected of causing genetic defects
H412 Harmful to aquatic life with long lasting effects
HIT-HY 170, A Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EC) No. 453/2010
12/01/2016 EN (English) 20/20
SDS_EU_Hilti
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product