2012-Small Molecule Semiconductors for High-efficiency Organic Photovoltaics
High-Efficiency, High Concentration Photovoltaics through ......ARPA-E Presentation March 2012 Roger...
Transcript of High-Efficiency, High Concentration Photovoltaics through ......ARPA-E Presentation March 2012 Roger...
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High-Efficiency, High Concentration Photovoltaics through Advanced Optical Systems : System level challenges
ARPA-E Presentation March 2012
Roger Angel
University of Arizona
• Astronomy heritage - UA Mirror Lab
• Spectral splitting, concentration and angular divergence
– Absorption
– Refraction
– Interference
• High concentration system at UA
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First 8.4 m from the Mirror Lab (LBT)
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This mirror making diffraction-limited images - four planets around the star HR 8799
(Hinz, Skemer et al. in preparation)
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Spectral splitting by absorption
• Good at very high concentration
because it is independent of ray angle
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Spectral splitting by refraction • needs to be done at the
entrance pupil - angular divergence ½ degree
• Practical at large aperture with grooves on entrance window
• Grooves can be as narrow as 50 microns without diffraction penalty
• Following lens or mirror will yield a spectrum at the focus
• Pick off different bands • Tracking errors will translate
into spectral errors
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Optical splitting by interference
• Wavelength depends on angle
• Sharpness of splitting depends on angular divergence
• Divergence depends on concentration
• Optical etendue
• Solid angle of divergence increases in proportion with concentration – Sun 10-4 sterad, with pointing errors 10-3 sterad
– At 1000x, increased to 0.1 sterad to 1 sterad
• Upper bound set by second law of thermodynamics – like Carnot cycle – hard limit
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Angular dependence of spectral separation for interference
• As solid angle for near normal incidence
• As square root solid angle for 45 degrees
Difficult to separate bands with near normal incidence reflection
cross coupling of tracking and splitting wavelength
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Example of a very high concentration system
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Early experimental dish made at the U. Arizona Mirror Lab
with Rep Gabrielle Giffords
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good point focus achieved – 15 sec solar exposure on 6 mm steel
– melts a quarter-sized hole
– don’t try this with your own 3-m telescope
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Cells at high concentration?
• At 10,000 x you are working at an image of the sun
• Sensitive to optical errors and tracking errors
• Issue that cells need to see the same flux for series connection
• Idea of entrance and exit pupil
– Telecentric system conserves etendue
– (reaches thermodynamic limit)
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System design
• Separation of large collectors and small cells
• Can afford to replace cells with better ones when they degrade – increase lifetime from 20 – 40 years
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Lowest cost reflector systems use self-supporting glass mirrors on simple steel support structure
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New UA technology used for bending such mirrors in 2-dimensions for high concentration point focus
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Lab test of 10 m2 mirror focusing to 2 cm diameter spot – 30,000 concentration
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A way to spread light concentrated by a big dish uniformly over multiple cells. The ball lens forms a stabilized 400x exit pupil at the funnels
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a unique way to control high power concentrated sunlight
Place the focus
at the center of
a ball lens
The light lands on a concave array of
cooled cells placed immediately behind
The ball puts all the
energy into a sharp
square image of the dish
optical funnels reformat the
image into 36 equal
strength square patches
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Now on-sun, Ball lens at the focus is feeding the light to a concave array of cells
Nearly ready for action –
cells in receiver box with
cover and ball removed
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It works – over 200 hours on-sun
• First end-to-end test (solar flux of 1 kW/m2) yielded 2.2 kW
• Tune up with 37% cells and better optics – expect 2.5 kW
• With 50% efficient cells, projected in a few years 3.5 kW
(35% overall AC conversion efficiency)