DTICprocedures fo 'r over .100 potentially hazardous chemical contaminants. The 'A guide contains...

//TG-141

AD-A180 370

NTED STATES ARMYENVIRONMENTAL HYGIENE

AGENCY,ABERDEEN PROVING GROUND, MD 21010-5422

INDUSTRIAL HYGIENE SAMPLING INSTRUCTIONS

DTICELECTE

MAY 20 198714E

i Approved ior public release; distribution is unlimited.

AIW

Users are invited to send comments and suggestedimprovements on DA Form 2028 (Recommended Changesto Publications and Blank Forms) to Commander, U.S.Army Environmental Hygiene Agency, ATTN: HSHB4ML-O,Aberdeen Proving Ground, MD 21010-5422.

"I.

a

UNCLASSIFIED' f SECURITY CLASSIFICATION OF THIS PAGEh 1?0 4

__________________________________________Eap Date Jun 30, 1986laREPORT SECURITY CLASSIFICATION lb RESTRICTIVE MARKINGS

UNCLASSIFIED ______________________

2a SECURITY CLASSIFICATION AUTHORITY 3. DISTRIBUTION /AVAILABILITY Of REPORT

_________________________Approved__ for public release; distribution2b DECLASSIFtCATION /DOWNGRADING SCHEDULEisulmtd

4 PERFORMING OR4jANIZATION REPORT NUMBER(S) Sý MONITORING ORGANIZATION REPORT NUMBER(S)

Techni1cal Guide (TG) 1416a NAME OF PERFORMING ORGANIZATION 16b OFFICE SYMBOL laý NAME OF MONITORING ORGANIZATION

US IArmy Environmental Hygiene j.(if applicableI)

Agency _______________________

c.ADDRESS (City. Statef. anh. ZIPCs.I 7b, ADDRESS (City, State, and ZIP Code)

Aberdeen Proving-Ground, RD 21010-5422

Ba. NAME OF FUNDING /SPONSORING Sb OFICE SYMBOL 9. PROCUREMENT INSTRUME.NT IDENTIFICATION NUMBERORGANIZATION0fAI1ale

Sc. ADDRESS (City, State, and ZIP Code) 10. SOURCE Of FUNDING NUMBERS

ELEMENT NO. NO NO (CESSION NO

I]& TYPE OF andOR 1314E OEE DATE OF REPORT (Yost, Month, Day) S1 PAGE COUNT

Tehia ud RM 1rh1937 58

17COSATI CODES 18 SUBJECT TERMS (Continue on reve'se of naeoesary and identify by bloick inubrnei).

FIELD GROUP SUB-GROUP

A. ~19. ABSTRACT (Continue on neilms of necessary and identify by bilock number)

, P -This technical guide describes air and bulk industrial hygiene samplingprocedures fo 'r over .100 potentially hazardous chemical contaminants. The

'A guide contains air volumes, sampling rates and references for IH airsampling. It addresses the types of containers and amount of samplerequired for bulk sample 's. Procedures fdr submitting samples including alisting of Army laboratories that perform industrial hygiene chemistryanalysis are providpd. The guide lists the expendable monitoring suppl"es

* that~are compatible with the sampling procedures and includes representativecommercial sources.

p. 20 DiSTRIBUT;ON 'AVAILABILITY OF ABSTRACT 121 ABS IRACT SECURITY CLASSIFICATION% MWUNCLASSIFIEDIINLIMITFD 0 SAME AS RPT 0 DTIC USERS UNCLASSIFIEDeA22a NAME 09 RESPONSIBLE NDVIDUAL I22b TELEPHONE (include Area Code) 22c OFFICE SYMBOL

00FREDERIC BELKIN and RICHARD W. CISHOP IAUTOVON 584-2208 HSHB-ML-O

DO FORM 1473,.84 MAR 83 APR 0.',on may be used untIl exhausted SECURITY CLASSIFICATION OF THIS PAGEAll tl~e Cd~I~fl areOb~O~teUNCLASS IFI ED

L ' _

Technical Guide No. 141 March 1987

-) ONTENTS,)

Paragraph *Page

General Sampling Instructions ....................... 1AsbestosS ii p]i ng, ................................... 2 3

!ca. (Quartz) Sampling ............... .3 4FiTter Sampl ng .................................... 4 4kdsor'p~tin Tube Samplln g)........................... 5 6

,?mpTnTer Sampl Ing,................................... 6 8c B TR amp ng ...................................... 7 84..5 1ve _usion eMonttor, ................... 8 9

Radon _ aimp TI ng, ...................................... 9 10' FReTd BTanks, ............................. 10 10"'Procedures for Submitting Samples...... .. ........ 11 11

APPENDIXES

A - TABLES...........................................A-iA-i - Air sampling procedures for chemical

contaminants ............................... A-2A-2 - Bulk sampling procedures for chemicalcontaminants.......... .A-13

A-3 - Documentation of IH air samplingprocedures .................................. A-14

8 - 1IH MONITORING SUPPLIES AND VENDORS ............-C - SUPPORTING LABORATORIES AND AREAS SERVED ...... C-1D - INSTRUCTIONS FOR COMPLETING USAEHA FORM 9-R,

INDUSTRIAL HYGIENE AIR SAMPLE DATA .......... D-1S- INSTRUCTIONS, PO R COMPLETING USAEHA FORM 8-R,1BULK SAMPLE DATA ............................ E-1- REFERENCES .................................... F-1

G - SELECTED BIBLIOGRAPHY........................... G-1GLOSSARY ..... .... .................... ................... GLOSSARY I

DbC TAd L]

"4'0 F.. .. .....D ib ib.tin. .

K..&Jli~Y CIes

fuor

DEPARTMENT OF THE ARMYv. M. aaiv E1v1omNTAI. Umwse Aou0c0

AIREN6N PROVING GROUND. MARYLAND 2101064=2

&lfty TO

HSHB-ML-O March 1987'

USAEHA TECHNICAL GUIDE NO. 141

INDUSTRIAL HYGIENE SAMPLING INSTRUCTIONS

1. GENERAL SAMPLING INSTRUCTIONS

"a. Industrial hygiene (IH) sampling procedures are summarized Intables A-I, A-2. and A-3.

"(1) Table A-i lists the chemical ,contaminant, sampling method,recommended sample volume range In liters, and a procedure numbercorresponding to those procedures performed at the U.S. Army EnvironmentalHygiene Agency, Aberdeen Proving' Ground (USAEHA APG). The procedurenumbers are provided as guidance to the 1,ndustrial hygienists serving

,y USAEHA APG, and do not apply to those methods used by USAEHA field supportactivities (FSA). Appearing at the end of table A-I are alternate samplingmethods for several chemical parameters. These methods are to be used whensubmitting samples to the FSA Fitzsimons Army Medical Center (FAMC)laboratory for analysis of these parameters.

(2) The recommended sampling rates and air volumes listed In tableA-I are consistent with documented procedures published by the NationalInstitute for Occupational Safety and He&ath (NIOSH), American Society forTesting and Materials (ASTM), manufacturers of sampling media, etc.Sampling done based on these recommendations will reasonably ensure thatthe accuracy and detection limit requirements of the analytical measurementsystem are met while also minimizing the potential for exceeding kinetic orsaturation capacities of. the sampling device(s). It Is recognized, however,that situations may arise which necessitate deviation from these guidelines.*

Use ot trademarkeo names does not imply endorsement I

I by the U.S. Army, but is intended only to assist inIdentification of a,.specific product.

This technical guide supersedes TG-141, Industrial Hygiene SamplingInstructions, October 1984, and Errata No. 1, 28 June 1985.

¶ ... ,'*

€:

Technical Guide NI. 141 March 1987

For example, a workplace may contain sufficiently high concentrations of acontaminant to require the usage of a "lower-than-recommended" flow rate inorder to meet sampling time requirements, or may warrant a lower totalsample volume; this is not uncommon with filter sampling in dusty areas.Similarly, pump or time constraints could conceivably lead to the neesl tosample a "higher-than-recommended" air volume. Since there Is a safetyfactor built into the volume recommendations, there may be no problem with"breakthrough"; but it should be remembered that high humidity or thepresence of additional adsorbing compounds could significantly reduce thissafety factor. Therefore, whil, deviations from the recommended volumesmay be made, such changes require the exercise of trained'Judgment and.should be made only on an individual case basis.

(3) Table A-2 lists bulk sampling procedures for chemicalcontaminants. Details are given about container and sample sizerequirements.

• <:(4) Table A-k lists the sampling method, analytical method,coefficient of variation (CV), reference, and procedure number for thoseprocedures performed at USAEH APd. Equivalent documentation for theprocedurls pe.formed at the FSA should be obtained from their individuallaboratories. The CVs included In table A-3 are giver, for the measurementsystem which includes the sampling and analytical method. Where 1aipl0ingerrors have not been determined, a 5 percent sampling error has.-ueen

* assumed and included with the analytical measurement error tr,'produce theCV for the procedure. Some procedures listed in table A-? are notvalidated (NV). These procedures are assumed to be state-of-the-art and/orthe most reliable methods available; however, they have not undergonevalidation testing such as outlined by NIOSH in the Manual of AnalyticalMethods, 3rd Edition. The gravimetric procedurec employed at USAEHA APGare not considered validated because they deviate significantly from theNIOSH methods. Many chemical substances in tie tables have the same USAEHAAPG procedure number because they utilize the same analytical procedur( foranalysis.

(5) Appendix B, section I, tables B-I through B-4, contain lists* of monitoring supplies compatible with the procedures given in the sampling

instructions in this guide. The supplies listed in the tables are intendedonly to assist in identifying a specific product. Other sources may beavailable for supplying equivalent items. Appendix B, section II, 1ists

S ,-•.

* U


the addresses and telephone numbers of vendors who supply the items listedin tables B-I through B-4.

b. The supporting laboratory should be contacted prior to sampling forcontaminants whenever assistance is needed or for contaminants not listedin table A-I.

(1) Continential United States (CONUS).

(a) USAEHA APG:

For asbestos, quartz, and metals contact the Radiological and/, Inorganic Chemistry Division (AUTOVON 584-2619)

For organics, solvents, acid mists, and pesticides contact the

Organic Environmental Chemistry Division (AUTOVON 584-2208).

(b) Field Support Activities:

For metals, organics, solvent; contact either -'--, FSA Fort McPherson, GA (AUTUVON 572-3234) or

FSA Fitzsimons Army Medical Center, CO (AUTOVON 943-8288)

(2) Outside Continental United Sates (OCONUS). Consult theappropriate supporting laboratory in appendix C.

c. Swipe, wipe, and swab samples should not generally be submittedexcept by prior approval from the supporting laboratory. The samplecollecting material very often presents interferences in analysis. Contact'the appropriate laboratory for guidance on collecting swipe, wipe,,or swabsamples.

2. ASBESTOS SAMPLING

a. Asbestos samples are collected on 25 mm diameter, 0.8 um pore size,cellulose esters (CE) filters in open face cassettes with 50 mm extensioncowls. Sample with the open end of the sampler facing downward. Do notuse 37 mm filters because sufficiently low detection limits may not beattained.

giJ

"3


b. A sample volume of 360 liters will permit detection of fibers atone-tenth the current permissible exposure limit (i.e., 0.02 fibers percubic centimeter) using phase contrast microscopical counting techniques.A sample volume. of 720 liters is desirable to permit reliable quantitationat this level. Sample at a rate between 0.5 and 2.5 liters per Minute.

c. When positive asbestos fiber concentrations can be anticipated (e.g.,from prior experience), optimal loading of the sample filters for countingpurposes can be achieved.

(1) The range of sample volumes to be collected can be estimated bydividing the anticipated fiber concentration into 'he.constants 40 and 500.For example, if the e,timated concentration is 1 fiber per cc, then collectbetween 40 and 500 liters.

(2) For expected low fiber concentrations (less than 0.1 fiber/cc),excessive volumes are required and optimal loading of the sample filtershould not be attempted.

d. ,For asbestos abatement sampling (after asbestor removal) collect1300 liters (25 mm filters) or 3000 liters (37 mm f4lters) as noted intable A-1.U

e. All asbestos air samples are. analyzed by phase contrastmicroscopy. USAEHA does not perform electron microscopy analyses such asscanning electron microscopy or transmission electron microscopy.

3. CRYSTALLINE SILICA (QUARTZ) SAMPLING

a. Respirable quartz samples are collected on 37 mm diameter, 5 umpore s*ze,, polyvinyl chloride (PVC) membrane filters for x-ray diffractionanalysis for weight of quartz present. Closed-face sample cassettes aremounted in 10 mm nylon cyclones, and a minimum sample volume of 500 litersis collected at a flow rate of 1.7 liters per minute.

b. Crystalline silica samples can be examined oua!itatively by x-raydiffraction for the presence of cristobalite and/or tridymite. However,the lack of suitable laboratory standards for these crystalline silicaspecies precludes quantitative analysis.

4. FILTER SAMPLING

a. Types of filters tased-are:

S(1) CE, which is a mixed cellulose ester fi~ter (the same asX cellulose nitrate.

' .. e . . . . S w , -.. S S . .e e. - - - - .nin..en eii - -


(2) Polyvinyl chloride (PVC).

(3) Glass Fiber (GF).

(A) Polymer of tetrafluoroethylene (PTFE).

b. When sampling for metals, dust, and oil mist, use the maximumsampling rate consistent with good pump operation to meet the minimumrecommended volume for reliable analysis. However, care should be takenwhen collecting air samples for metals during sanding and grindingoperations to avoid filter over-loading, which'may occur due to short-termgeneration of large volumes of material.

c. At least one field blank filter will be submitted with each set ofsamples from the same sampling series; if the number of samples in a setexceeds ten, then submit one blank for each ten samples. Asbestos analysisrequires a minimum of two blanks, and chromium VI,. potassium hydroxide, andsodium hydroxide require at least three blanks. When using preweighedfilters, always use corresponding blank filters from the same lot as thesamples. The lot can be determined from the code on the top of the USAEHApreweigh-3d filter.

d. After sampling, preweighed filters must be returned to thesupporting laboratory that performed the first weighing.

e. Some air contaminants may be collected and analyzed on the samefilter. An example is the simultaneous sampling and analysis for lead andtotal chromium. The following list Includes air contaminants which must becollected and analyzed on an individual basis:

(1) antimony

(2) molybdenum

(3) potassium hydroxide

-. (4) sodium hydroxide

(5) chromic acid mist

(6) chromium VI

p.

5.• m . . . . • . . . .. . . . . . . ? . . .. . .. ... . . . . . . .


f. Some PVC filters, specifica ly catalog number 8SWP from theMillipore Corporat,on, are not acce table for sampling chromitm VI. Thisfilter has been found to reduce a s gnificant amount of the chromatespike. The NIOSH Sampling Method 7 00 suggests use of catalog number FWSB[NSA] or number VM-l (GELMAN] or eq ivalent. The storage stability forchromium VI samples has been valida ed for only a 2-week holding time,therefore, the USAEHA should be not fied of analytical requirements priorto the collection of thE samples.

5. ADSORPTION TUBE SAMPLING

a. Various types of adsorption tubes are used according to thecontaminant being sampled; some of hese are charcoal, Tenax®, silicagel, Florisile and XAD-20. Table AJ1 lIsts the contaminants andcorresponding adsorption tubes. Ap endix B 1ists the sources forconsumable supplies (containers, fI ters, passive monitors, sampler types)detailed in tables A-] and A-2.

b. Smaller type charcoal tubes (150 mg) may be substituted for the 600mg tubes listed in table A-]. (Not : The 600 mg tubes are 200/400 mg twosection tubes.) However, correspon ingly lower air volumes and samplingrates must be used (no more than on -half of the maximum volume andone-half the maximum sampling ra~te isted In table A-l). This also appliesto smaller silica gel tubes for ani mne, cresols or methanol sampling.Chromosorb 102 33/66 mg size tube f r pesticides may be interchanged withthe 50/100 mg size, with no change n the recommended air volume samplebeing required. Size substitution or other adsorption tubes shouldgenerally not be made.

c. Generally, a number of diff rent organic solvents can be analyzedfrom the same charcoal tube, Organ c solvents requiring the sameanalytical procedure can be sampled and analyzed together. However, thefollowing require a separate charcol1 tube for each analysis requested:

0 Tenax is a registered trademark GC-Enka N.V., The Netherlands.0 clorisil is.a registered trademar of Floridin Company, ITT System,Pittsburgh, PA.(9 XAD-2 is a registered trademark f Rohm a;id Haas, Philadelphia, PA.

16-6

AQw

7 - - - - - - - .


(1) 2-butoxyethanol (Butyl cellosolved)

(2) t-butyl alcohol

(3) carbon disulfide

(4) 2-ethoxyethanol (ethyl ce-llosolve)

(5) ethyl alcohol

(6) ethyl other

(7) isopropanol

(8) isobutyl alcohol

(9) 2-methoxyethanol (methyl cellosolve)

(10) methyl bromide

" "" d. The three stage nitrogen dioxide tubes are used both for nitrogendioxide and sulfur dioxide sampling. Both parameters can be analyzed fromthe same tube.

e. The capacity of charcoal tubes and passive monitors may be reducedby either--

(1) High humidity (greater than 50 percen, relative humidity) incombination with high ambient temperatures (greater than 85 *F), or

(2) Very high humidity (greater than 80 percent relative humidity)with normal ambient temperatures.

To reduce the probability of breakthrough and sample loss, do not exceed* one-half of the recommended maximum sample volume under the above

conditions.,

0 Cellosolve is a registered trademark of Uflon Carbide Corp, 270 ParkAve, New York, NY.

7

VITechnical Guide No. 141 Narch 1987

f. The flow rate through an adsorption tube should be determined foreach individual sampling pump before field use. Only one tube need be usedsince all tubes are packed to provide a uniform pressure drop at thepre'cribed flow rate. For field sampling, changes in pressure drop andthus flow rate through the adsorption tube are assumed to be negligiblyaffected by packing and transport.

g. Field blank tubes will be submitted with each set of samples. Ifthe number of samples in a set exceeds 10, then submit at the rate of oneblank for each 10 samples, not to exceed 10 blanks per set. The fieldblank should beopened and capped; no air should be drawn through it.

h; After sampling, snugly relace plastic caps on all adsorption tubes.

6. IMPINGER SAMPLING

a. Impinger sampling, as described in this guide, geoierally refers tothe use of midget impingers fitted with fritted bubbler nozzles. The oneexception it ozone, which requires a standard nozzle with a 1 mm insidediameter opening.

b. Samples collected in glass fritted bubblers shculd be transferred toclean, glass-stoppered bottles with teflon lined caps. Rinse the glass frittedbubblers with a small amount of unused absorbing solution, adding the rinse tothe sample. NotiFS~amples collected for ozone analysis should be transferredto stoppered bottles with teflon septum caps without rinsing.

c. Ground-glass surfaces and fritted bubblers used for sampling withsodium hydroxide absorbent should be thoroughly rinsed or purged with waterafter sampling. This prevents "freezing" or fusion of the ground-glasssurfaces.

Sd. Reagent grade chemicals and high quality deionized or distilledwater must be used in preparation of absorbing solutions.

e. One media blank of unused absorbing solution must be submitted with

each set of samples.

7. BULK SAMPLING.

* a. Bulk sampling procedures for chemical contaminants includingcontainer type and ar.unt of sample. required are specified In table A-2.

+ .-~.

8

10


b. When requestinq an analysis for organic solvents and metals In thesame sample (such as a paint), s,.bmit two portions--one for solvents andone for metals.

c. The composition of bulk "unknowns" can often be Identified, from theinformation in Ma'erial Safety Data Sheets (MSDS). Similar information onproduct composition may be available through the Department of DefenseHazardous Materials Information System (DOD HMIS) [DOD 6050.5L and LetterRequirement (LR)] if the National Stock Number of the item is known. Forthose items not in the listing, obtain the MSDS for a product from itsmanufacturer. If sample analysis is:still required, forward the MSDS,sample, and analytical request to the appropriate supporting laboratory(app C).

8. PASSIVE (DIFFUSION TYPE) MONITORS

a. Organic solvent vapors.

(1) Passive monitors for organic solvent vapors contain anadsorbent charcoal element similar to a charcoal tube and are analyzedsimilarly to a charcoal tube.

(2) The passive monitors should only be used for the contaminantsin table A-I and not for collecting "unknown" organic vapors.

(3) Mixtures of several solvents may be collected only if all thesolvents can be analyzed on the monitor and the sampling times aresimilar.

(4) Manufacturers list many solvents which can be sampled withpassive monitors, however, few of these are validated procedures, andconsequently are not included in this guide.

(5) A blank monitor (open bag, open monitor, then replace monitorin sample bag) is to be submitted with the field samples. -Do notintentionally expose the field blank monitor to the contaminated workplaceenvironment. Passive monitors are not recommended for ceiling or shortterm exposure sampling.

9


b. Ethylene oxide (ETO).

(1) Passive monitors for ETO manufactured by 3146 have beenvalidated.

(2) Passive monitors for organic solvent Vapors cannot be used forETO. ,

9. RADON SAMPLINr. For radon sampling procedures, call the USAEHA HealthPhysics Division, AUTOVON 584-3502.

10. FIELD BLANKS

a. The field blank--

(1) Detects a contaminant in the sorbent.

(2) Detects contamination in shipping and storage.

(3) Aids in determining interferences in the collection media.

(4) Serves as a reference 'in most spectrophotometric methods.Sb. At least one field blank must be-submitted with each set ofimpinger, filter, adsorption tube, or passive monitor samples from the same

sampling series. If the number of samples in a set exceeds ten, thensubmit one blank for each ten samples, or fraction thereof. A set is oneor more samples for the same contaminant(s).

c. Blanks should always bp from the same lot as the sample tubesfilters, or monitors. If two different lot numbers are used In sampling,then two blanks are required, one from each appropriate lot number.

d. All adsorption tubes and passive monitor blanks should be treatedlike samples except they should be opened and resealed immediately. Do not

v ~inte tiona1t1y contaminate the field blank.

(9 3M is a registered trademark of Minnesota Mining and Manufacturing Co.,St. Paul, MN,

10

/I

//


11. PROCEDURES FOR SUBMITTING SAMPLES

a., Air samp'les.

(1) Complete AEHA Form 9-R (Industrial Hygiene Air Sample Data).Instructions for completing AEHA Form 9-R are in appendix' D. AEHA Form 9-Ris located at the back of this technical guide. Copies may be locallyreproduced on 8 1/2-. by 11-inch paper.

(2) The AEHA Form 9-R must accompany all IH samples submitted forair sample analysis.

(3) Field personnel should establish a consecutive numberingsystem for assigning sample numbers. There should be no duplication ofnumbers from batch to batch. Number'all samples including blanks.

(4) A "blank" must accompany all air samples, be numbered, and theword "BLANK" written on the tube, filter, bottle, passive monitor, orimpinger. Indicate on the form the "blank," sample number.

(5) In .CONUS, samples may be forwarded directly to either: theSCommander, USAEHA, ATTN: HSHB-ML-A' Bldg E2100, APG, MD 21010-5422 or tothe appropriate FSA (app. C). OCONUS activities can consult their

supporting laboratory (app C) for sample analysis.

b. Bulk samples.

(1) Complete AEHA Form 8-R (Bulk Sample Data). Instructions forcompleting AEHA Form 8-R are in appendix E. AEHA Form 8-R is located atthe back of this technical guide. Copies may be locally reproduced on8 1/2- by 11-inch paper.

(2) The AEHA Form 8-R must accompany all IH samples submitted forbulk analysis.

(3) 'Include the manufacturer's label information and attach themanufacturer's MSDS when possible.

(4) In CONUS, samples may be forwarded directly to either: theCommander, UGAEHA, ATTN: HSHB-ML-A, Bldg E2100, APG, MD 21010-5422 or to theapprooriate FSA (app C). OCONUS activities may consult their supporting

laboratory (app C) for sample analysis.

"1 11

Technical No. 141 March 1987

Appendix A

Tables

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/


Appendix BIH Monitoring Supplies and Vendors

Section I., Tables

Table B-1Containers

Sampler Type Vendor CAT No.Glass container (25 mL), Pierce 13074 (Vials)screw cap, Teflon disc 12422 (Teflon Disc)

13219 (Screw Cap)

AlItech 9532 (Vials)95322 (Teflon Disc)95321 (Screw Cap)

Supelco 2-3284 (15 mL)2-3285 (40 mL)

"Plastic bottle 30 mL (1 oz) Most scientific Nalge 2002 or equalsupply houses

B-.1

/


Table 8-2Filters

Size Porosity SuggestedSampler Type (mm) (microns) Vendor CAT No.Cellulose Ester (CE) *25 0.8 Gelman 64677

(For asbestos)* 25 0.8 Millipore AWWP-025-000025 0.8 Nuclepore 322575 (assembled)

Cellulose Ester (CE) 37 0.8 Gelman 64678 (GN-4)37 0.8 Millipore AAWP-037-0000,37 0.8 Nuclepore 321541

(2-piece, assembled)

Glass Fiber (For PCBs) '13 - SKC 225-1637 - Gelman Type AlE

PTFE (Zefluor) 37 2 Gelman PSPJ037(For PAH) 37 2 Membrana' -

PVC 37 5 Gelman 6646737 5 Nuclepore 361850 Filter only

240810 Pad only

Swinnex Cassette 13 - Millipore SX 00-013-0000(For PCBs)

* Use 25 mm monitor with 50 mm conductive extention cowl.

B-2


Table 8-3Passive Monitors

Sampler Type Suggested Vendor CAT No.Ethylene Oxide 3M 3551 (Monitor only)

Organic Vapor Monitor .3M 3500(For selected solvents) 3M 3520 (with backup

section)

Pro-Tek Air Monitoring Badge Dupont Type GAA(For-selected solvents) Dupont Type GBB (with backup

section)

8-3


Table 3-4Tubes

Size SuggestedSaler Tvne (Mo) Vendor CAT No.

Alumina 1650/1650 SKC' ST 226-64

Awmonia 250/500 Supelco ORO 77

Charcoal 200/400 SKC ST 226-09(For solvents) 200/400 Supelco 2-0228 ,

S0/100 SKC ST 226-0150/100 Supelco 2-026750/100 MOA 808101

Charcoal (For methylbromide only) 200/400 SKC ST 226-38-02

Chromosorb 102 50/100 SKC ST 226-49-23-102(For pesticides) -50/100 'Supelco 2-0264

33/66 Supelco 2-0262

Chromosorb P for Acids 165/335 Supelco ORB0-70

(0R80-70)

Ethylene Oxide 200/400 Supelco 0R0-78

Florisil 50/100 SKC ST 226-39

Formaldehyde 50/100 SKP ST 226-45

Hydrazine 200/200 SKC ST 226-42

Inorganic Acids 200/400 Supelco 01R0-53(High KPrity Silica Gel) 200/400 SKC ST 226-10-03'

Nitrogen Dioxide 400/600/400 Supelco 0RGO-76(For K02, S0z)

ORB0-70 See Chromosorb P for Acids

PAN (Polyaromatic 50/100 Supelco ORBO-43Hydrocarbons)

Pesticide. OSHA - Supelcb Custom 0R0-80

Silica Gel 260/520 SKC ST 226-15

Silica Gel. High Purity See Inorganic Acids

Silica Gel, H2 S0 4 treated 100/200 SKC ST 226-10-06

Tenax 50/100 SKC ST 226-35-03

Tenax with built in filter S0,100 Supelco Custom nRBO-79

Thernosorb/N Air Sampler Thermedics 6533

XAO 2 200/400 SKC * ST 226 30 06

84.

n


Section II. Vendors

1. Al1tech Associates, Inc. 7. Nuclepore Corp.Applied Science Labs 7035 Commerce Circle2051 Waukegan Road Pleasanton, CA 94566-3294Deerfield, IL 60015 (415) 463-2530(312) 948-8600 (800) 882-7711(800) 255-8324

2. E.I. Dupont de Nemours & Co., Inc. 8. Pierce Chemical CompanyApplied Technology Division PO Box 117Wilmington, DE 19898 Rockford, IL 61105(215) 444-4035 (815) 968-0747(800).344-4900 (800) 874-3723

1.3 Gelman Sciences 9. SKC Inc.600 South Wagner Road RD 1, 395 Valley View RoadAnn Arbor, Kl '48106 Eighty Four, PA 15330-9614(313) 665-0651 (412) 941-7701(800) 521-1520 (800) 752-8472

4. Membr'ana Inc. 1.0. Supelco7070 Commerce Circle Supelco ParkPleasanton, CA 94566-3294 Bellefonte, PA 16823-0048(415) 846-8270 (800)'247-6628

(814) 359-3441(814) 359-3446

5. Millipore Corp., 11. Thermedics, IncAshby Road 470 Wildwood St.Bedfotd, MA .01730 PO Box 2999(617) 275-9200 Woburn, MA 01888-1799(800) 225-1380 (617) 938-3786

6. Minnesota Mining & Mfg. Co.Occupational Health.& Safety

Products Division3M Center, 220-7W-02St. Paul, MN 55144(612) 733-8465(800) 328-1300

iB-5 ,I


AppendixkCSupporting Laboratories and Areas Served

Supporting laooratory' Areas served

* U.S. Army Environme;ital Hygiene Alabama, Arkansas, Florida, Georgia,Agency Western Kentucky, Louisiana,

Field Support Activity Mississippi, Oklahoma, Panama,Fort McPherson, GA 30330-5000 Puerto Rico, South Carolina,AUTOVON 571-3234 Tennessee, Central & Eastern Texas

U.S. Army Environmental Hygiene Alaska, Arizona, California, Colorado,Agency Idaho, Illinios, Iowa, Kansas,

Field Support Activity Michigan, 'Minnesota, Missouri,Fitzsimons Army Medical Center Montana, Nebraska, Nevada, New Mexico,Aurora, CO 80045-5001 North Dakota, Oregon, South Dakota,

* AUTOVON 943-8288 West Texas, Utah, Washington, Wisconsin,Wyoming

Commander Hawaii, Japan, Korea. Okinawa,' U.S. Army Pacific Environmental Philippines, Thailand, and all other

Health Engineering Agency Far EastSagamiAPO San Francisco 96343Camp Zama 228-4111

Commander Europe, Africa, Middle East, WesternlOth Medical Laboratory Europe, Turkey, Africa, and MiddleATTN: AEMML-PM-LAB EastAPO New York 09180Landstuhl Military (2223-)7272

Commander a. Worldwide support to laboratoriesU.S. Army Environmental Hygiene listed above

Agency b. Connecticut, Delaware, District ofATTN: HSHB-ML-A Columbia, Eastern Kentucky, Indiana,Bldg E2100 Maine, Maryland, Massachusetts, NewAberdeen Proving Ground, MD Hampshire, New Jersey, New York, North21010-5422 Carolina, Ohio, Pennsylvania. RhodeAUTOVON: Island, Vermont, Virginia, West Virginia584-2619 (metals, quartz, asbestos)584-2208 (solvents, organics, acid

mists, pesticides)

C-1

lo D-


Appendix D

Instructions for Completing AEHA Form 9-R, Indus rial Hygiene Air Sample Data

1. Return address: Self explanatory.

2. Point of contact: Name and AUTOVON number of person in charge ofsampling/project.

3. Samples collected by: Self explanatory.

4. Date collected: Self explanatory. m

5. Date shipped: Date samples sent for analysis

6. Associated bulk samples: Indicate whether bu k samples of materials usedin the operation are being submitted along with cOrresponding air samples. Ifso, list the sample numbers which identify these ýulks. Note: Bulk samplesmust be shipped separately from air samples.

7. Project number: For USAEHA and FSA use only.

8. Sampled installation: Self explanatory.

9. ARLOC: Army Location Code: reference - DA P m 525-12 (CONUS) and 525-13(Fqreign).

10. Location (bldg/ared): Self explanatory.

11. Description of operation: Briefly describe he industrial operation(e.g., degreasing metal parts, spray painting, ve icles, etc.)

12. Persons exposed/hrs per day: Self explanatory.

13. Method of collection: Air sampling medium used to collect samples (e.g.,.cha:-coal tube, 0.8 pm CE filter, etc.).

14. Associated complaints: List worker complaints (e.g., dizziness, nausea,skin irritation, etc.) about exposure problems arising from operation.

.D-1


15. Analysis desired: List specific parameters when they are known orsuspected to be present; otherwise, indicate general type of analysisdesired (e.g., unknown solvents, etc.).

16. Sampling data.

a. Sample number: Number assigned to the sample by field personnel.Note: Use a consecutive numbering system so there is no duplication ofnumbers from batch to batch of samples. Number all samples includingblanks.

b. Pump number: Identifying number for sampling pump (if used).

(1) Time on: Start time of pump (e.g., 1430).

(2) Time off: Stop time of pump (e.g., 1615).

(3) Total time: Sampling time in minutes (e.g., 105 min).

c. Flow rate: Sampling. rate of pump in liters per minute."If theinitial and final calibration flow rates are-different, a volume calculatedusing the higher flow rate should be repotted to the laboratory. If anoverexposure can not be established using the higher flow rate, theindustrial hygienist should recalculate the sample concentration using thelower flow rate. If the concentration using the lower flow rate exceedsthe exposuri limits, resampling should be considered.

d. Volume: Air volume sampled in liters.

e. GA/BZ: Enter GA if a general area sample or BZ if a brea-thing zonesample.

f. Employee name/ID: Self explanatory.Note: Name and social security number is considered Privacy Act

information and should be protected.

g. Laboratory number: Leave blank.

I

q


17. Results: Lab will provide results in the common conversion (such asppm, iWj/-rf/cc, etc.).18. Comments to lab: Insert any comments or information necessary on a

particular sample.

19. Lab use only: Leave blank.

20. Calibration'information: Self explanatory.

21. Operation: Self explanatory.

22. Personal protective equipment: Check box if equipment is worn.Specify type if applicable.

23. Field notes/additional comments: Self explanatory.

I)I.

D-3

"p


Appendix EInstructions for Completing AEHA Form 8-R, Bulk Sample Data

1. Return address: Self explanatory.

2. Point of contact: Name and AUTOVON number of person in charge ofsampling/project.

3. Sampled installation': Self explanatory.

4. Project number: For USAEHA and FSA use only.

5. ARLOC: Army location code - reference DA PAN 525-12 (CONUS) and 525-13(Foreign).

6. Samples collected by: Self explanatory.

7. Date collected: Self explanatory.

8. Date shipped: Date samples sent for analysis.

S 9. Description, ofoperation: Brief description of the Industrialoperation (e.g., degrearing metal parts, spray painting vehicles, etc.).

10. Location (bldg/area): Self explanatory.

1!. Associated complaints: Worker complaints about exposure problemsarising from operation (e.g., dizziness, nausea, skin irritation, etc.).

12. Associated air samples: If air samples corresponding to these bulksare submitted for analysis, please so indicate and list the sample numberswhich identify these air samples. Air samples must be shipped separatelyfrom bulk samples.

13. Label information:

a. Trade name: Self explanatory; if unknown, so indicate.

E-1

" 7

S I _ _ Ii• . • . .• •w •.•,.• ., •prm !• I ! • • .,•,l•L~ !•iiT~ •. S


b. NSN:. If available, so indicate.

c. Manufacturer: Self explanatory; if unknown, so indicate.

d. Address: Self explanatory; if unknown, so indicate.

e. MSDS: Attach the MSDS whenever possible and so indicate.

14. Analysis desired: List specific parameters when they are known orsuspected to be present otherwise, fndicate general type of analysisdesired (e.g., unknown solvents, etc.).


16. Sample number: Number that field personnel assigns is the samplenumber. Use a ccnsecutive numbering system so there Is no duplication ofnumbers from batch to batch of samples.

17. Constituents: Leave blank.

18. Results: Leave blank.

19i Remarks: Leave blank.

20. Comments to lab: Use for any general information or remarks you wishto include.


4

da


Appendix FReferences

Section I.-Required Publications

000 6050.5-L (DOD Hazardous Materials InformationSystem Hazardous Item Listing). Citedin paragraph 7c. (This listing isavailable from the U.S. Army AGPublication Center, 2800 EasternBlvd., Baltimore, NO 21220-2896.

DOD 60O50.5-LR (DO0 Hazardous Materials InformationSystem Hazardous Item Listing). Citedin paragraph 7c. (This l1sting is forU.S. Government use only, limitedbecause it contains proprietary(limited rights) data. Copies areavailable from the U.S.*Army AGPublication Center, 2800 EasternBlvd., Baltimore. MD 21220-2895.)

DA Pamphlet 525-12 (Army Location Codes - CONUS). Citedin appendixes 0 and E.

DA Pamphlet 525-13 (Army Location Codes - CONUS). Citedin appendixes D and E.I Section 11.

Related Publications*

Title 49 CFR Chapter 1, (Hazardous Materials Regulations)Subchapter C

I

SA related publication is merely a source of additional information. The

user does not have to read it to understand this document.'

"F-i

"I,.

- -

I~~ ~ Will....


DHEW (NIOSH) Publication (Criteria for a Recommended Standard:No. 75-120 Occupational Exposure for Crystalline

Silica) (This publication isavailable from PublicationsDissemination, DTS, NIOSH, 4676Columbia Parkway, Cincinnati, OH45226.)

DHEW (NIOSH) Publication (Criteria for a Recommended Standard:No. 76-105 Occupational Exposure toSodium

Hydroxide) (This publication isavailable from PublicationsDissemination, DTS, NIOSH, 4676Columbia Parkway, Cincinnati, OH45226.)

DHEN (NIOSH) Publication (Criteria for a Recommended Standard:No. 77-140 Occupational Exposure to Waste

Anesthetic Gases and Vapors) (Thispublication is available fromPublications Dissemination, DTS,NIOSH, 4676 Columbia Parkway,Cincinnati, OH 45226.)

DOEW (NIOSH) Publication (Manual of Analytical Methods. Vol 1)No. 77-147A (This publication is available from

Publications Dissemination, DTS,NIOSH, 4676 Columbia Parkway,Cincinnati, OH 45226.)

* DHEN (NIOSH) Publication (Manual of Analytical Methods. Vol 2)No. 77-157B (This publication is available from


DHEW (NIOSH) Publication (Manual of Analytical Methods, Vol 3)No. 77-157C (This publication is available from

Publications Dissemination, DTS,NIOSH. 4676 Columbia Parkway,Cincinnati, OH 45226.)

F-2

44

44.


DHEW (NIOSH) Publication (Manual of Analytical Methods, Vol 4)No. 78-175 (This publication is available from

Publications Dissemination, DTS,NIOSH) 4676 Columbia Parkway,Cincinnati, OH 45226.)

DHEW (NIOSH) Publication (Manual of Analytical Methods, Vol 5)No. 79-141 (This publication is available from


DHEW (NIOSH) Publication (Manual of Analytical Methods, Vol 6)No. 80-125 (This puhlication is available from


DHEW tNIOSH) Publication (Manual, of Analytical Methods, Vol 7)A No. 62-100 (This publication is available from

Publications Dissemination, DTS,"NIOSH, 4676 Columbia Parkway,Cinclnnati,-OH 45226.)

CHHS (NIOSH) Publication (NIOSH Manual of Analytical Methods.No. 84-100 3rd Ed., Peter M. Eller, Editor) (This

publication is available fromPublications Dissemination, DTS,NIOSH, 4676 Columbia Parkway,Cincinnati, OH 45226.)

TLVse Booklet (TLVss - Threshold Limit Values andBiological Exposure Indices for thecurrent year.) (This publicationis available from ACGIH, 6500 GlenwayAve., Bldg 0-5, ZCricinnati, OH 45211.)

F-3

,- - - - -

b


APPENDIX GSelected Bibliography '

Belkin, F. and R. W. Bishop. The New U.S. Army's Industrial HygieneSampling Guide. American Society for Testing Materials Special TechnicalPublication 957. To be published (1987).

Bishop, R. W., T. A. Ayers, and D. S. Rinehart. The Use of a SolidSorbent as a Collection Medium for TNT and TDX Vapors. Am. Ind. Hyg.Assoc. J. 42:586-589 (1981).

Bishop, R. W., et al. A Gas Chromatography Procedure for the Determinationof Airborne MDI and TDI. Am. Ind. Assoc. J. 44(3):151-155 (1983).

Bishop, R. W., F. Belkin, and R. J. Gdffney. Evaluation of a New AmmoniaSampling and Analytical Procedure. Am. Ind. Hyg. Assoc, 3. 47:135-137(1986).

Charell, P. R. and R. E. Hawley.. Characteristics of Water Absorption onAir Sampling Filters. Am. Ind. Hyg. Assoc. J. 42:353-60 (1980).

Documentation of TLVs and BEIs. American Conferehce of GovernmentalIndustriel Hygienists, fifth edition (1986).

Dolzine, T. W., G. G. Esposito, and R. 3. Gaffney. Determinatlon ofHydrogen Cyanide in Air by Ion Chromatography. American Society forTesting, Materials Special Publication 786 (1982).

Elskamp, C. J. and G. R. Schultz. An Alternate Sampling'and AnalyticalMethod for 2-Butanone. Am. Ind. Hyg. Assoc. J. 44:201-204 (1983).

Esposito, G. G., and T. W. Dolzine. Determi nation of Airborne1,6-Hexamethylene Dflsocyanate by Gas Chromatography. Anal. Chem. 54:1572-1575 (1982).

Esposito, G. G., et al. Determination of Ethylene Oxide in Air by GasChromatography. Anal. Chem. 56(11):1950-1953 (1984).

Feigley, C. E. and J. B. Chastain. An Experimental Comparison of ThreeDiffusion Samplers Exposed to Concentration Profiles of Organic Vapors.Am. Ind. Hyg. Assoc. 3. 43:227-234 (1982).

G-1

'/ 0


Mazur, J. F., et al. Evaluation of a Passive Dosimeter for Collection of2-bromo-2-chloro-1,l,1-trifluoroethane and 2-chloro-l.1,2-trifluoroethyldifluoromethyl ether in Hospital Operating Rooms. Am. Ind. Hyg. Assoc. J.41:317-321 (1980).

Mazur, J. F., et al. Evaluation of Passive Dosimeters for Monitoring VaporDegreaser Emissions. Am. Ind. Hyg. Assoc. J. 42:752-756 (1981).

Mullins, H. E. Sub-part-per-million Diffusional Sampling for EthyleneOxide with the 3M #3550 Ethylene Oxide Monitor. Am. Ind. Hyg. Assoc. J.46:625-631 (1985).

Organic Methods Evaluation Branch, OSHA Analytical Laboratory, Method No.27: Volatile Nitrosamine Mixture I. Salt Lake City, Utah, Feb 1981.

Roper, E. M. and C. G..Wright. Sampling Efficiency of Five Solid Sorbents-for Trapping Airborne Pesticides. Bulletin of Environmental Contaminationand Toxicology. 33:476-483 (1984).

Rose, V. E. and Perkins, J. L. Passive Dosimetry - State of the ArtReview. Am. Ind. Hyg. Assoc. J. 43:605-621 (1982).

Sax, N. I. Dangerous Properties of Industrial Materials. Van NostrandReinhold Company. 6th edition (1984).

Vinjamoori, D. V. and Chaur-Sun-Ling. Personal Monitoring Method for,,Nitrogen'Dioxide and Sulfur Dioxide with Solid Sorbent Sampling and IonChromatographic Determination. Anal. Chem. 53:1689-1691 (1981).

Williams, K. E., G. G. Esposito, and D. S. Rinehart. Sampling Tubes forthe Collection of Selected Acid Vapors in Air. Am. Ind. Hyg. Assoc. J.42:476-478 (1981).

G-2


GLOSSARY

APG ................ Aberdeen Proving Ground

CE ................. cellulese ester

CONUS .............. continental United States

Cr ................. chromium

CT ................. charcoal tube

CV ................. coefficient of variation

00O ................ Department of Defense

ECO ................ electron capture detector

ETO ................ ethylene oxide

FAIC ............. Fitzsimons Army Medical Center

FID ................ flame ionization detector

FPD ................ flame photometric detector

FSA ................. field support activity

GF ................. glass fiber

HMIS ................ hazardous materials information system

ICP............... inductively coupled plazna

ID ................. inside diameter

IN ................ industr'ial hygiene

LR ................. letter requirement

MSDS ............... material safety data sheets

NIOSH .............. National Institute for Occupational Safety and Health

NPO ................ nitorgen phosphorus detector

NV ................ not validated

OCONUS ............. outside continental United States

PCB ............... polychlorinated biphenyls

PM ................. passive monitor

PTFE ............... polymer of tetrafluoroethylene

PVC ................ polyvinyl chloride

TDI ................ toluene dlisocyanate

TLV ................ threshold limit value

TNT ................ trinitrotoluene

TWA ................ time weighted average

AW~k USAEHA ............. US Army Environmental Hygiene Agency

""' UV ................ ultraviolet

IG

INDUSTRIAL HYGIENE AIR SAMPLE DATA

Flu *. ~ For use of this form see LISAEHA TG 1741; the roponent is HSHB-LO.Return Address (omplete. addres includ=ing Zip Code) Point of Contact (nameIA UTo vol)

Samples Collecte By Date a fecte ate Shp EJYes O]No

- I ý -4-V-s fal I Bulk Sample No(s):t

Metho of Colection[JPersons Exposed Hrs/DayAssociate aomplaints (be specific) (state NONE if ap:)licable)

Analysis Desired.

____________________ Smpli'ng Data ____ ____ ____ ____

Sample No. ________________

Pomrp No. ___

T ime On___ ___

T imre Of f_____ ____ ________

Total rime_(min) ________________

Flow Rate (LFM) ________

V-)Iume (Liters)

GA/BZ ____ ___ ___

Employee Name/ID

1.3boratory No.

_______________________ Results

Comments to Lab:

Lab Use OnlyA'nalyst (initials) ReiwdBy (initials) JDate Received DaeDispatched V

A EHA Form 9-R, 1 Oct84

Replaces AF.HA Form 9, 1 Oct 80 which is obsolete.

/i

Calibration Information

Calibration (L/min) Rotomet3rPump No. Pre-Use T Post-Use Setting Date

...;.....'... . X.... . . Name of Calibrator

....................... ...........................................'I

Operation

r source of Contaminant:

Operat ion Employee(s) Perform:

Ventilation: ' Local Exhaust. General Area N'lone

Personal Protective Equipment (check if worn)

r- Respiratory Protective Equipment Type:

Oi Protective Clothing Type:

[:]Gloves Type:

0( Goggles/Face Shield

[]Ear Protection

[] Other :

Field Notes/Additional Comments

2

Sampled Installation Project Nurnber ARLO~ J 1 1

Samples Collected By Date Collected Date Shipped

Description of Operation Location (BLDG/AREA,)

Associated Complaints (be specific)

Associated Air Samples If yes, list sample numbers

jYes- ONo

Label Information ________________

Trade Name NSN Man~ufacturer

AddressMSDS Attached

EJYes LNo

'D Analysis Desired

LabUs ~rnieConstituents* Results RemarksOnly No. _______________

Comments to Lab:

Lab Use OnlyAnaytiii ) Reiewd By (ntasDteReceived Date Reported

Procedures Performed Commwents:

~' AEHA Form 8-0. 1 Oct 84 'Replaces AEHA Form 8, 1 Oct 80 which is obsolete.

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