DEGREE OF UNSATURATION EXAMPLE A COMPOUND HAS THE FORMULA C 8 H 7 Br 1.WORK OUT THE DEGREE OF...
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Transcript of DEGREE OF UNSATURATION EXAMPLE A COMPOUND HAS THE FORMULA C 8 H 7 Br 1.WORK OUT THE DEGREE OF...
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DEGREE OF UNSATURATION EXAMPLE
A COMPOUND HAS THE FORMULA C8H7Br
1. WORK OUT THE DEGREE OF UNSATURATION
2. PROPOSE A STRUCTURE FOR THE COMPOUND
Br
CH2
D.U. = 5
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NORMAL MODES OF VIBRATION EXAMPLES
Symmetricalstretch
Asymmetricalstretch
Scissoring
Rocking Wagging Twisting
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UV/VIS LECTURE EXERCISE
SUGGEST ALL POSSIBLE TRANSITIONS (e.g. n *) FOR THE FOLLOWING COMPOUND:
σ σ*
π π*
n σ*
n π*
d d
L M charge transfer
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UV/VIS LECTURE EXERCISE
* transitions of the corrin ring
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UV-VIS LECTURE EXERCISE
THE UV/VIS SPECTRUM OF A SOLUTION (conc. = 2.5 × 10-5 M) HAS TWO PROMINENT PEAKS.
THE FIRST AT 400 nm HAS AN ABSORBANCE OF 0.8, AND THE SECOND AT 550 nm HAS AN ABSORBANCE OF 0.1.
THE MEASUREMENT WAS CONDUCTED IN A CUVETTE WITH A PATHLENGTH OF 0.02 m.
CALCULATE THE EXTINCTION COEFFICIENT FOR BOTH PEAKS.
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UV-VIS LECTURE EXERCISE cont.
A = ε×b×c
ε = A/(c × b)
ε400 = 0.8/(2.5 × 10-5 mol ℓ-1 × 2 cm)
= 16000 mol-1 ℓ cm-1
ε550 = 2000 mol-1 ℓ cm-1
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TYPICAL INSTRUMENT
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TYPICAL INSTRUMENT
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Using only the peak integrals, assign which signals belong to which protons.
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Using peak multiplicities, and prior knowledge about shielding, fully assign the 1H spectrum below.
A
A
B
B
C
C
D
D
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HOW IS J CALCULATED?
THE MAGNITUDE OF J CAN BE CALCULATED BY × THE
SEPARATION OF THE LINES IN δ (ppm) UNITS BY THE
RESONANCE FREQUENCY OF THE SPECTROMETER IN MHz.
J (Hz) = δ (ppm) × ν0 (MHz)
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ab
Jba
Jba
Jab
IF Ha AND Hb ARE COUPLED, THEN THE SPACING BETWEEN THE LINES ARE EQUAL, AND Jab
= Jba
MORE ON J
Jab = Jba = 6.0 Hz