Cumulative Frequency Plots of Species Sensitivity to the ...
Transcript of Cumulative Frequency Plots of Species Sensitivity to the ...
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Cumulative Frequency Plots of Species Sensitivity to the Toxicants in the ANZECC
& ARMCANZ Water Quality Guidelines
This document contains the cumulative frequency plots of species sensitivity for the toxicantsfor which trigger values were derived using the statistical distribution method. The plots weregenerated using the BurrliOZ software (Campbell et al. 2000), included on the CD Rom, thatwas specifically designed for derivation of trigger values.
Each plot contains the geometric means for the most sensitive end-points for each species for which toxicity data were available. Three sample distributions are also plotted. The blue lineis for the Burr Type III distribution estimated from the toxicity data by maximum likelihood.The log-logistic distribution used by Aldenberg and Slob (1993), and adopted in theNetherlands, as well as the normal distribution, are also plotted for comparative purposes. Inthe current version of BurrliOZ contained on the CD Rom, the normal curve is not displayed.This has been replaced by the log-normal curve as used in Denmark, and as developed byWagner and Løkke (1991).
Each plot also contains a purple line, which indicates either the concentration that should protect 95% or 99% of species. The level of protection that is indicated corresponds to the level ofprotection that was used for the trigger value (TV) for that chemical. Where the data weresufficient to derive a high reliability (HR) TV, the blue line denotes/matches the TVconcentration. However, if only a moderate (MR) or low (LR) reliability TV could be derived,the concentrations derived by the BurrliOZ software were further manipulated in order to obtainthe TV. This manipulation involved dividing the concentration by an acute to chronic ratio or bya default assessment factor. The magnitude of the assessment factor varied depending on thetype and amount of toxicity data. The document, ‘Description of how each toxicant triggervalue was derived’ (file ‘TOX-Tvderivation’), indicates what level of protection the blue linecorresponds to or whether the BurrliOZ figure was subject to further manipulation.
BurrliOZ can alternate the scale of the ‘x’ axis between a normal and a logarithm to the base 10 scale (the latter indicated as ‘E’ in the concentration range). Both types of plots arepresented in this document. The type of plot that best presented the distribution of the toxicitydata and the concentration that protects either 95% or 99% of species is presented.Occasionally, both types of plots are presented.
The caption for the ‘x’ axis states the concentration of toxicant in a file name. The file names were chosen to be as self-explanatory as possible. But there were character limitations. Mostfile names end with an ‘F’, ‘M’ or ‘FM’ that indicate the toxicity data were measured infreshwater, marine water, and fresh and marine water respectively. The files referred to in the‘x’ axis are not provided as part of the Water Quality Guidelines.
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ReferencesCampbell E, Palmer MJ, Shao Q, Warne MStJ & Wilson D 2000. BurrliOZ: A computer
program for calculating toxicant trigger values for the ANZECC and ARMCANZ waterquality guidelines. Perth WA.
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Aldenberg T & Slob W 1993. Confidence limits for hazardous concentrations based onlogistically distributed NOEC toxicity data. Ecotoxicology and Environmental Safety 25,48−63.
Wagner C & Løkke H 1991. Estimation of ecotoxicological protection levels from NOECtoxicity data. Water Research 25, 1237−1242.
KEY to line coloursin graphs
Burr Type III
Normal distribution
Log-logistic distribution
95th Percentile
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Arsenic (III)
Freshwater
Arsenic (V)
Freshwater
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Boron
Freshwater
Boron
Freshwater
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Cadmium
Freshwater
Cadmium
Marine
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Chromium (III)
Marine
Chromium (VI)
Freshwater
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Chromium (VI)
Marine
Cobalt
Freshwater
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Cobalt
Marine
Copper
Freshwater
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Copper
Marine
Lead
Freshwater
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Lead
Marine
Manganese
Freshwater
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Mercury
Freshwater
Mercury
Marine
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Nickel
Freshwater
Nickel
Marine
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Nickel
Marine
Total Selenium
Freshwater
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Total Selenium
Freshwater
Silver
Freshwater
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Silver
Marine
Tributyltin
Marine
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Vanadium
Marine
Zinc
Freshwater
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Zinc
Marine
Zinc
Marine
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Ammonia
Freshwater
Ammonia
Marine
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Chlorine
Freshwater
Cyanide
Freshwater
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Cyanide
Freshwater
Cyanide
Marine
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Cyanide
Marine
Nitrate
Freshwater
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Sulfide
Freshwater
Ethanol
Freshwater
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Ethanol
Marine
Dichloromethane
Fresh and Marine
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Chloroform
Fresh and Marine
Carbon Tetrachloride
Fresh and Marine
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1,2-dichloroethane
Fresh and Marine
1,1,1-trichloroethane
Fresh and Marine
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1,1,2-trichloroethane
Freshwater
1,1,2-trichloroethane
Marine
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1,1,2-trichloroethane
Marine
1,1,2,2-tetrachloroethane
Fresh and Marine
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1,1,2,2,2-pentachloroethane
Fresh and Marine
Hexachloroethane
Freshwater
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Hexachloroethane
Marine
Hexachloroethane
Marine
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1,1-dichloropropane
Fresh and Marine
1,2-dichlorpropane
Fresh and Marine
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1,3-dichloropropane
Fresh and Marine
Chloroethylene
Fresh and Marine
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1,1-dichloroethylene
Fresh and Marine
1,1,2-trichloroethylene
Fresh and Marine
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1,1,2,2-tetrachloroethylene
Fresh and Marine
1,1,2,2-tetrachloroethylene
Fresh and Marine
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3-chloropropene
Fresh and Marine
1,3-dichloropropene
Fresh and Marine
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Aniline
Freshwater
Aniline
Freshwater
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2,4-dichloroaniline
Freshwater
2,4-dichloroaniline
Freshwater
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3,4-dichloroaniline
Freshwater
3,4-dichloroaniline
Marine
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Benzene
Freshwater
Benzene
Marine
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Toluene
Fresh and Marine
Ethylbenzene
Fresh and Marine
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o-xylene
Freshwater
m-xylene
Fresh and Marine
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p-xylene
Fresh
Isopropylbenzene
Fresh and Marine
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Naphthalene
Fresh
Naphthalene
Marine
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Anthracene
Fresh and Marine
Anthracene
Fresh and Marine
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Phenanthrene
Fresh and Marine
Fluoranthene
Fresh and Marine
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Fluoranthene
Fresh and Marine
Benzo[a]pyrene
Fresh and Marine
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Nitrobenzene
Freshwater
2,4-dinitrotoluene
Freshwater
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2,4-dinitrotoluene
Freshwater
2,4,6-trinitrotoluene
Freshwater
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Chlorobenzene
Fresh and Marine
1,2-dichlorobenzene
Freshwater
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1,2-dichlorobenzene
Marine
1,3-dichlorobenzene
Freshwater
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1,3-dichlorobenzene
Marine
1,4-dichlorobenzene
Freshwater
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1,4-dichlorobenzene
Marine
1,2,3-trichlorobenzene
Freshwater
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1,2,4-trichlorobenzene
Freshwater
1,2,4-trichlorobenzene
Marine
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1,3,5-trichlorobenzene
Fresh and Marine
1,2,3,4-tetrachlorobenzene
Fresh and Marine
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1,2,3,5-tetrachlorobenzene
Fresh and Marine
1,2,4,5-tetrachlorobenzene
Fresh and Marine
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Pentachlorobenzene
Fresh and Marine
Hexachlorobenzene
Fresh and MarineIn this plot the dark blue line indicates the PC95 50% while the light blue line is the PC9950%.
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Aroclor 1242
Freshwater
Aroclor 1254
Freshwater
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Phenol
Freshwater
Phenol
Marine
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2-chlorophenol
Freshwater
2-chlorophenol
Freshwater
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4-chlorophenol
Freshwater
2,4-dichlorophenol
Freshwater
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2,4,6-trichlorophenol
Freshwater
2,4,6-trichlorophenol
Freshwater
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2,3,4,6-tetrachlorophenol
Freshwater
Pentachlorophenol
Freshwater
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Pentachlorophenol
Freshwater
Pentachlorophenol
Marine
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Pentachlorophenol
Marine
2,4-dinitrophenol
Freshwater
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Dimethylphthalate
Freshwater
Diethylphthalate
Freshwater
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Dibutylphthalate
Freshwater
Dibutylphthalate
Freshwater
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Polyacrylonitrile
Freshwater
Polyacrylonitrile
Marine
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Chlordane
Freshwater
DDT
Freshwater
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DDT
Freshwater
Endosulfan
Freshwater
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Endosulfan
Freshwater
Endosulfan
Marine
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Endosulfan
Marine
Endrin
Freshwater
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Endrin
Freshwater
Endrin
Marine
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Endrin
Marine
Heptachlor
Freshwater
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Heptachlor
Freshwater
Lindane
Freshwater
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Toxaphene
Freshwater
Guthion
Freshwater
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Guthion
Freshwater
Chlorpyrifos
Freshwater
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Chlorpyrifos
Freshwater
Chlorpyrifos
Marine
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Chlorpyrifos
Marine
Diazinon
Freshwater
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Dimethoate
Freshwater
Dimethoate
Freshwater
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Fenitrothion
Freshwater
Malathion
Freshwater
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Parathion
Freshwater
Temphos
Marine
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Temphos
Marine
Carbofuran
Freshwater
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82
Methomyl
Freshwater
Diquat
Freshwater
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83
2,4-D
Freshwater
2,4,5-T
Freshwater
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84
Molinate
Freshwater
Molinate
Freshwater
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85
Thiobencarb
Freshwater
Thiram
Freshwater
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86
Thiram
Freshwater
Atrazine
Freshwater
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87
Simazine
Freshwater
Tebuthiuron
Freshwater
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88
Tebuthiuron
Freshwater
Glyphosate
Freshwater
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89
Glyphosate
Freshwater
Trifluralin
Freshwater
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90
Trifluralin
Freshwater
LAS
Freshwater
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91
AES
Freshwater
AE
Freshwater
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92
Corexit 9527
Marine