CHE Fall 2014 Conventional Fossil Fuels 2X Greyscale

8/9/2019 CHE Fall 2014 Conventional Fossil Fuels 2X Greyscale

1/35

!"!"#$

#

!"#$%#&"#'( *"++,( *-%(+

&'()*+ ,(-.'/0/*+ 1 2/03-+

4)(5 67 8(9-.: 2.7;7

6!"=?$ 1 &&@ =!A: 4900 BC#$

!"!"#$ 6!"=?$ 1 &&@ =!A #

./0/ 1#%234 .+%

!"!"#$ B


2/35

!"!"#$

B

56%2% 72% 8#(4 562%% 82,3,#'( 1#%234 0"-29%+

1'2:6

;-9(%'2


3/35

!"!"#$

=

!"#$%#&"#'( 1#%234

O!"#$%#&"#'(P ,+ #": M%(( ?%K#%?

"Q%# -+%? ,#:%296'#3%'N(4 M,:6 OH"++,( H-%(+P

H-%(+ -+%? H2"= :6% ,#?-+:2,'( 2%$"(-&"# :" :6% N,2:6 "H :6%

%#$,2"#=%#:'( ="$%=%#:

+:'#?'2? H-%(+ H2"= RS:6 !/ .07

M""? '#? 9"M ?-#3 #": :4F,9'((4 ,#9(-?%?

!"#$%#&"#'( *"++,( *-%(+I

T,U-,? F%:2"(%-=B ;':-2'(


4/35

!"!"#$

$

L%#%M'N(% 1#%234

D'+ E/)F /E ('()*+ G.9G 3H )('(N(5-/'M'L900+ /) 9''L900+

&'()*+ E/)FH G.9G 9)( '/G 5(S0(G9K0(

T3'5: H/09): N9G(): M590U

83/V('()*+ W3E LH(5 HLHG93'9K0+X

,(-.'3-900+ 3'-0L5(H 'L-0(9) N3G. K)((5())(9-G/)H

KLG F/HG S(/S0( 5/'YG H(( 3G G.9G N9+

T.9G 9K/LG *(/G.()F90Z

[/F( )(H/L)-(H H((F S()S(GL90: H/F( S09+ /LG

!"!"#$ \


5/35

!"!"#$

>

0-+:',#'N(% 1#%234

D -/FK3'9M/' /E @('(N9K0( 1 a)(('Z

[/F( KLG '/G 900 9b)3KLG(H /E (9-.Z

2().9SH 9 F/)( S)9*F9M- 5(c'3M/'

I/G dL3G( a)((': KLG a)((' ('/L*.

I/G dL3G( @('(N9K0(: KLG 90F/HG H/

!"!"#$ !

!(%'# 1#%234

D '(N G()F 3' G.( ^[ F(539 1 95Q()MH3'*

8(3'* LH(5 S)3F9)30+ 3' )(E()('-( G/ I9GL)90a9H


6/35


7/35

!"!"#$

\

*"++,( *-%(+ 72% [2,='2,(4 .+%? *"2 *-%(+I

\XS ]-'?+ H"2 *-%(+

\Y ]-'?+ H"2 ;"#^*-%(+ E%/3/ F2"?-9:+G

!"!"#$ #=

!"'( 0%9&"#

!"!"#$ #$


8/35

!"!"#$

?

!"!"#$ #>

!"'( V+ [2,='2,(4 .+%? H"2 1(%9:2,9 ["M%2


9/35

!"!"#$

!

56%2% '2% *"-2 L'#_+ "H !"'(

4/L) )9'_Hf 03*'3G(: HLKK3GLF3'/LH: K3GLF3'/LH: 9'G.)9-3G( 5(S('5H /' 9F/L'GH /E -9)K/' 1 .(9G ('()*+

0/N() .(9G g 0/N() )9'_

e3*'3G(f B>V=> S()-('G -9)K/' W0/N(HG )9'_X

F93'0+ KL)'(5 9G S/N() S09'GH G/ *('()9G( (0(-G)3-3G+

0(953'* HG9G(Hf ,(]9H 9'5 I/)G. ;9_/G9

[LKK3GLF3'/LH -/90f =>V$> S()-('G -9)K/'

0(953'* HG9G(f T+/F3'*

83GLF3'/LH -/90f $>V?A S()-('G -9)K/' WBV=h .(9G /E 03*'3G(X

i/HG 9KL'59'G )9'_ /E -/90 3' G.( ^'3G(5 [G9G(H W>CjX

@9N F9G()390 E/) G.( HG((0 9'5 3)/' 3'5LHG)3(H7

0(953'* HG9G(Hf T(HG k3)*3'39: l('GL-_+: 9'5 2(''H+0Q9'39

D'G.)9-3G(f ?AV!\ S()-('G -9)K/' W.3*.(HG )9'_X 0/N() .(9M'* Q90L( G.9' K3GLF3'/LH -/90

Q()+ )9)( 3' G.( ^'3G(5 [G9G(H

!"!"#$ #\

56% ./0/ A'+ 7 T": "H !"'(

O,.( '3G(5 [G9G(H .9H G.( N/)05mH 09)*(HG _'/N' -/90 )(H()Q(H: 9K/LG BA\7A K3003/' H./)G G/'H7 ,.3H3H ('/L*. -/90 G/ 09HG 9SS)/]3F9G(0+ B=A +(9)H 9G G/59+mH 0(Q(0 /E LH(7P

,.( 7[7 .9H G.( N/)05YH 09)*(HG )(H()Q(H /E [.90( J30: G//

!"!"#$ #?


10/35

!"!"#$

#C

!"'( A'+ >%2,:+ '#? `2'MN'9_+

i()3GH /E -/90f

DKL'59'G

6.(9S

&9H+ G/ HG/)(

;)9NK9-_H /E -/90f

H3*'3c-9'G 09'5 53HGL)K9'-( E/) 3GH (]G)9-M/'

-9)K/' 3'G('H3Q(

-/90 3H '9GL)(YH 8)3G9 -9)K/' c0G()

KL)'3'* -/90 )(0(9H(H G)9SS(5 S/00LG9'GH HL0EL): F()-L)+: .(9Q+ F(G90H

!"!"#$ #!

!"'( A'+ ' [2,9% 7?$'#:'3%I V: V+ T%++

1aF%#+,$% b T%++ c"('&(% 56'# 8,( '#?


11/35

!"!"#$

##

!"'( !"#+-=F&"# 7#? [2"?-9&"# 72%

!("+%(4 >':96%?

&]S/)GH G/ &L)/S( 1 6.3'9

!"!"#$ B#

!"'( .+% A'+ 06,Q%? *2"= 8:6%2 0%9:"2+

5" 1(%9:2,9 ["M%2

!"!"#$ BB


12/35

!"!"#$

#B

!"'( .+% A'+ 06,Q%? 5" 1(%9:2,9 ["M%2

!"!"#$ B=

56%2% 72% 5M" 54F%+ 8H >,#,#3I 0-2H'9% '#?

.#?%232"-#?

!"!"#$ B$


13/35

!"!"#$

#=

!"'( >,#,#3 ,+ `'#3%2"-+

!"!"#$ B>

>"+: ./0/ !"'( ,+ [2"?-9%? N4 0-2H'9% >,#,#3

!"!"#$ BA


14/35

!"!"#$

#$

799,?%#:+ 0&(( A'FF%#

!"!"#$ B\l(''(-/b 6/90 i3'(: ^G9.: DS)30 BC#=

*"2 09'(%B 56"+% '2% :6% @"2(?+ T'23%+: 52-9_+

!"!"#$ B?


15/35

!"!"#$

#>

>"+: 0-2H'9% >,#,#3 5'_%+ [('9% ,# :6% @%+:

!"!"#$ B!

56% !"'( 0:':%+ 72%#d: ;%9%++'2,(4 @6" [%"F(%

56,#_ 56%4 72%

[/L)-(f D&@ BC##!"!"#$ =C


16/35


17/35

!"!"#$

#\

./0/ !"'( 1aF"2:+

!"!"#$ ==

./0/ !"'( 1aF"2:+

!"!"#$ =$


18/35

!"!"#$

#?


19/35

!"!"#$

#!

;':-2'(


20/35

!"!"#$

BC

;':-2'(


21/35

!"!"#$

B#

;':-2'( '#4 .+%+ b L%:',( *"2=+

2)3F9)+ LH(Hf -//_3'*".(9M'* (0(-G)3-3G+ E((5HG/-_

DQ9309K0( 3' 9 E(N )(G930 E/)FHf I9GL)90 *9H WIaX 6/FS)(HH(5 '9GL)90 *9H W6IaX e3dL(c(5 '9GL)90 *9H WeIaX

6/FS9MK0( N3G. S3S(03'(H WIaX

-+03'5()H W6IaX H.3SH WeIaX

!"!"#$ $#

;':-2'(


22/35

!"!"#$

BB

;':-2'(


23/35

!"!"#$

B=

./0/ [,F%(,#% V#H2'+:2-9:-2% ,+ 1a:%#+,$%

!"!"#$ $>

;':-2'(


24/35

!"!"#$

B$

;':-2'(


25/35

!"!"#$

B>

;':-2'( C


26/35

!"!"#$

BA

]I @6,96 +:':% F2"?-9%+ :6% ="+: ",(g

D7 ,(]9H

87 D09H_9

67 6903E/)'39

;7 e/L3H39'9

&7 J_09./F9

&RD WBCC?X

!"!"#$

>#

;/ `'_":' 8,( [2"?-9&"# V+ ;"M R#?:" 5h

!"!"#$

>B


27/35

!"!"#$

B\

8,( [2"?-9&"# ,# :6% ./0/ ,+ !6'#3,#3

!"!"#$

>=

[%:2"(%-= V+ .+%? *2"= >'#4 0"-29%+

'#? *"2 >'#4 [-2F"+%+

!"!"#$

>$


28/35

!"!"#$

B?

[%:2"(%-= !"#+-=F&"# A'+ [2,='2,(4


29/35

!"!"#$

B!

!"#$%#&"#'( !2-?% 8,( A'+ 0%$%2'(

`,+: !6'2'9:%2,+&9+

[N((G'(HHf )(E()H G/ HL0EL) -/'G('G

HN((G g 0/N HL0EL) -/'G('G

H/L) g .3*. HL0EL) -/'G('G

e3*.G'(HHf )(E()H G/ Q3H-/H3G+

03*.G g 0/N Q3H-/H3G+

.(9Q+ g .3*. Q3H-/H3G+

i/HG '9M/'H S)(E() 03*.G: HN((G -)L5(

03*.G -)L5(H 9)( (9H3() G/ )(c'(

HN((G -)L5(H .9Q( 0/N() (F3HH3/'H

!"!"#$

>\

[%:2"(%-=^D'+%? *-%(+ A'$% >'#4

7j2'9&$% [64+,9'( !6'2'9:%2,+&9+

&'()*+ 5('H3G+

*)9Q3F(G)3-f 5('H3G+ S() L'3G F9HH

Q/0LF(G)3-f 5('H3G+ S() L'3G Q/0LF(

69' K( S3S(5 G./LH9'5H /E F30(H 3' )9N /)

c'3H.(5 E/)F

6/'Q('3('G K/303'* 9'5 E)((n3'* S/3'GHf HG9+H

03dL35 L'5() F/HG -03F9M- -/'53M/'H

!"!"#$

>?


30/35

!"!"#$

=C

[%:2"(%-= `%2,$%? *-%(+ 72% 7 D(%#? "H

0%$%2'( !"#+&:-%#:+

a9H/03'(: _()/H('(: 53(H(0: (G-7: 9)( IJ, 9 SL)( -.(F3-90

[L0EL) 3H K/G. 9 S/00LG9'G WK95X 9'5 0LK)3-3G+ 9*('G W*//5X

Volume Class Example Species

75-85% Paraffins &

isomers

Methane, ethane, propane, isooctane, n-

pentane, cyclic paraffins (naphthenes)

13-22% aromatics Benzene, toluene, xylene, etc.

'#4 [2"?-9:+

# K0L( K9))(0 W88eX g $B *900/'H K+ Q/0LF(

o3(05H $$ *900/'H /E S)/5L-GH

K(-9LH( /E OHN(00P /) OS)/-(HH3'* *93'P

69' LH( G.()F/-)9-_3'*: -9G90+M- -)9-_3'*: 9'5 .+5)/G)(9M'* G/ LS*)95( .(9Q3()S)/5L-GH G/ 03*.G(): )(c'(5 EL(0H

Product Gallons per BBL of

crude

Gasoline 20

Diesel 10

Jet Fuel 4

Fuel Oil & LPG 4

Other Products 6

!"!"#$

AC


31/35

!"!"#$

=#

56%

1#%234!"#:%#: ,+

`,J%2%#:

H"2

`,J%2%#:

['2:+ "H

:6% D'22%([/L)-(f D&@ BCC\

!"!"#$

A#

./0/ L%K#%24 k,%(?+ !6'#3%? 8$%2 5,=%

^7[7 )(c'()3(Hf /LGSLGH /E 53HM009G(H W3'-0L53'* 53(H(0 9'5

.(9M'* /30X E)/F BBj G/ B?j H3'-( #!!?: p(G EL(0 9'5 )(H35L90

EL(0 /30H W/G.() F3550( 53HM009G(HX .9Q( 5)/SS(57!"!"#$AB


32/35

!"!"#$

=B

8,( V#?-+:24 V+ 0:2-9:-2%? @,:6 *"-2 >'l"2

[,%9%+

!"#$%&'()&]S0/)9M/' 9'5 S)/5L-M/' W&12X:

5(Q(0/SF('G: *9H 1 S/N() F9)_(M'*

*+,#$%&'(! #$#%&$'%(

-./0#$%&'(! )(c'3'*: EL(0H F9)_(M'*: 0LK(H

12&(+3'4#! -.(F3-90H: 3'G()F(539G(H:

H+'G.(M-H: S/0+F()H

!"!"#$

A=

56% 1a,+ [%:2"(%-= V#H2'+:2-9:-2%

L%F2%+%#:+ 0-N+:'#&'( !'F,:'( 7++%:+ ,.( ^7[7 S(G)/0(LF H+HG(F 3'-0L5(H

#$! /30 )(c'()3(H

B:CCC /30 HG/)9*( G()F3'90H

BBC:CCC F30(H /E -)L5( /30 9'5 /30 S)/5L-GH

S3S(03'(H

#\>:CCCq *9H HG9M/'H

[/L)-(Hf

I9M/'90 D-95(F+ /E [-3('-(H: BCC$r

)*+,-%: BCC\

!"!"#$

A$


33/35

!"!"#$

==

L%K#,#3 ,# 7=%2,9' A'+ !6'#3%?

0,3#,K9'#:(4 56% T'+: *%M ?%9'?%+ 2(9_(5 9G =B$ )(c'()3(H 3' #!?#

[3FS0(: HF900: 3'(s-3('G: 3't(]3K0(: )(c'()3(H

,/59+f #$! )(c'()3(H

DQ()9*( -9S9-3G+ .9H */'( LS E/L)VE/05

69' G9_( 3' F/)( -/FS03-9G(5 -)L5(

i/)( (s-3('G /Q()900

I(N )(c'()3(H L'5() -/'HG)L-M/' E/) G.( c)HGMF( 3' 5(-95(H

!"!"#$

A>

@(c'3'* 3' DF()3-9


34/35

!"!"#$

=$

>'#4 L%K#%24 V#$%+:=%#:+ A'$%

*"9-+%? "# !'F'N,(,:4B ;85 !'F'9,:4

2)/5L-G 5(F9'5H W)(c'()+ /LGSLGHX G/L*.('N" MF(

6)L5( W)(c'()+ 3'SLGHX *(GH N/)H( N3G. MF(

./' 0-1%- +0 1%*& 2$+3 1%4*'1 50- 3$637(#%8$98*:0' #-01,8+(; -%9'%-( 3* ?02%B*+3%-; $+ 3*( *C0-1%1 -%9'%-( +3% 8*#*@$&$+A +0

4*D% +01*AE( #-01,8+ (&*+%; *'1 4*D% $+ 5-048-,1%( 05 1%8-%*($'6 =,*&$+A>F GHB/)I -%9'$'6 -%#0-+; J%8%4@%- KLLM

!"!"#$

A\

L%K#%2,%+ A'$% >'#4 !'F'N,(,&%+ 5"?'4

56': @%2%#d: @,?%(4 V#+:'((%? ,# :6%mnoS+

,.()F90 9'5 69G90+M- 6)9-_3'* W69G -)9-_()HX(]G('5 G.( S()-('G9*( +3(05 /E 03*.G S)/5L-GH E)/F.(9Q3() E((5HG/-_


35/35

!"!"#$

L%K#%2,%+ !'# D% `'#3%2"-+ 7+ @%((

!"!"#$

A!

CHE Fall 2014 Conventional Fossil Fuels 2X Greyscale

Documents

Transcript of CHE Fall 2014 Conventional Fossil Fuels 2X Greyscale