Biodiesel Basics for the Beginner_VaCC

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    ABC Coalition

    2004 Peer Review Report

    Atlanta-Chicago Regional Peer Review Meeting

    Indianapolis, IndianaAugust 30 September 1, 2004

    Biodiesel Basics for the BeginnerChelsea Jenkins and Al Christopher

    Virginia Clean Cities

    Hampton Roads Clean Cities Coalition

    Biodiesel Public Education Forum

    May 30, 2007

    Hollins University

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    VIRGINIA CLEAN CITIES

    VIRGINIAOverview

    Brief overview what is Clean Cities? Biodiesel Basics

    Advantages/disadvantages

    WVO, SVO, homebrew, commercial, ASTM

    Users, availability

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    VIRGINIA CLEAN CITIES

    VIRGINIAEnergy InSecurity

    THE U.S. IMPORTS OVER ONE-HALF OF ITS PETROLEUM

    Source: EIA AEO 2006

    TRANSPORTATION PETROLEUM

    USE 67% OF OVERALL USE

    TRANSPORTATION IS 97%

    DEPENDENT ON PETROLEUM

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    VIRGINIA CLEAN CITIES

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    Clean Cities

    National US DoE voluntary program to promote energyindependence in transportation

    80 Coalitions nationwide

    One designated Coalition in Virginia (Hampton Roads) Statewide effort ongoing

    DoE Website:

    http://www.eere.energy.gov/cleancities/

    Virginia Clean Cities:

    http://www.hrccc.org

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    VIRGINIA CLEAN CITIES

    VIRGINIABiofuels

    Fossil Fuel: a hydrocarbon fuel, such as petroleum,derived from living matter of a previous geologic time. Coal, Oil, Natural Gas

    Biofuel: Any fuel that derives from biomass recentlyliving organisms or their metabolic byproducts

    Biodiesel, Ethanol

    Primary drivers behind introducing biofuels include: Reduce dependency on fossil-fuels Reduce GHG emissions (reduce impact on health,environment)

    Improve energy security Contribute to rural development through domesticproduction

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    What is Biodiesel

    1. Mono-alkyl esters of fatty acids (i.e. methyl or ethyl esters)2. A diesel replacement fuel produced from vegetable oils, animal fats,recycled cooking grease

    Physical properties very similar to conventional diesel

    Must meet the quality requirements of ASTM D6751

    Biodiesel Blend: mixture of biodiesel and petroleum diesel

    BXX = volume XX% biodiesel

    Most common blends are B5, B20

    http://www.uwyo.edu/plants/AECLclub/biodiesel.jpg
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    Biodiesel is NOT unrefined vegetable oil

    or used cooking oil

    What Is Not Biodiesel?

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    SVO/WVO Vegetable oil can be used in diesel engine Much more viscous Doesnt burn the same Many studies have found SVO can lead to engine carbon deposits,

    reducing engine life or increasing maintenance costs Successful SVO use is documented, but use requires considerable

    modifications to diesel equipment

    SVO has strong following Elsbett single and double tank SVO fuel systems from Germany

    Single tank system seems to get best reviews: The kit includes modifiedinjector nozzles, stronger glow plugs, dual fuel heating, temperaturecontrols and parallel fuel filters.

    ANTICIPATE PROBLEMS AND COSTS ASSOCIATED WITHCONVERSION

    What Is Not Biodiesel?

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    Waste Oil Similar to confusion between biodiesel and WVO Referred to as used motor oil or waste engine oil Used oil can be re-refined into base stock for lubricting oil If you recycle 2 gals of used oil, it can generate enough electricity to run

    average household for almost 24 hours (API, http://www.recycleoil.org/) Waste motor oil furnaces (UL listed, EPA approved)

    www.cleanburn.com

    What Is Not Biodiesel?

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    VIRGINIA CLEAN CITIES

    VIRGINIABiodiesel

    Advantages:

    Its Easy: Transparent to end-user, easy toimplement

    LDV/HDV, marine, underground mining

    No increased vehicle equipment cost

    Minimal infrastructure impact (blending, storage,availability, vehicles)

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    VIRGINIA CLEAN CITIES

    VIRGINIABiodiesel

    Advantages:

    Its Domestic (or can be): MADE IN USA

    It Can Stimulate Local Economies andSupport Farmers

    value added product, supports rural economies, protectsfarmland from development pressures

    algae coconut hemp mustard seed

    pumpkin seedavocado coffee jatropha oats

    rapeseedbrazil nuts coriander jojoba oil palm

    safflowercalendula corn (maize) kenaf olives

    sesamecashew nut cotton linseed (flax) opium poppy

    soybeancastor beans euphorbia lupine peanuts

    sunflowerscocoa (cacao) hazelnuts macadamia nuts pecan nuts

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    VIRGINIA CLEAN CITIES

    VIRGINIABiodiesel

    Advantages:

    Its Renewable, Biodegradable, & Nontoxic

    Its Efficient: Very favorable energy balance, ~3.2 to 1 (debatable,but most find more efficient than petroleum)

    Its Engine Friendly: Superior engine performance

    High flash point: 260F v 117F

    Lubricity properties

    Higher cetane rating

    http://www.uwyo.edu/plants/AECLclub/biodiesel.jpg
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    VIRGINIA CLEAN CITIES

    VIRGINIABiodiesel

    Advantages:

    Its Healthier: Lower emissions(Example: DDC Series 50), US DoA, US DoE

    Carbon monoxide: 38% lower

    Unburned HC: 83% lower

    Oxides of Nitrogen: still debated Particulates: 49% lower

    Smoke and odor are much better

    PAH, nPAH, & air toxics lower

    It Contributes less to Greenhouse

    Gases

    Closed carbon cycle in theory

    Still petroleum involved inagriculture process andtransportation, so not entirely

    closed

    BIODIESELDIESEL

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    Disadvantages:

    Increased price relative to diesel

    Petroleum displacement potentialof B20 relatively limited

    Beginning of industry growth has

    caused some commodity priceincreases that are limiting

    Biodiesel

    Retail price calculator for biodiesel blends

    B2 B5 B10 B20

    gallons: 100 100 100 100petro gals: 98 95 90 80

    bio gals: 2 5 10 20

    petro price: 2.430 2.430 2.430 2.430petro total: 238.14 230.85 218.70 194.40

    bio price: 2.830 2.830 2.830 2.830

    bio total: 5.66 14.15 28.30 56.60total cost 243.80 245.00 247.00 251.00

    blend price 2.438 2.450 2.470 2.510

    fed tax 0.244 0.244 0.244 0.244

    va tax 0.160 0.160 0.160 0.160

    total 2.842 2.854 2.874 2.914

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    Disadvantages:

    Cold handling and storage of B100

    soybean based biodiesel start to crystallize at 0C

    Oxidative stability

    old fuel can become acidic and form sediments and varnish

    Excellent solvent

    filter clogging during transition from petrol diesel

    replace natural rubber components

    Supply

    Biodiesel

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    VIRGINIAMaking biodiesel

    The beauty of biodiesel is it can be made on any scale, and by anydespite level of chemical processing experience

    For a great video tutorial on how biodiesel can be made from manyfeedstocks, check out the JMU biodiesel conference website for 2006,

    view webcast at top, and forward to How Biodiesel is Made by ChrisBachmann: http://www.cisat.jmu.edu/biodiesel/conference2006.html

    Or visit the Collaborative Biodiesel Tutorial:http://www.biodieselcommunity.org/howitsmade/ (includes recipes forbeginners with pictures and detailed instructions)

    Make sure you understand the health and safety risks involved!!!

    http://www.cisat.jmu.edu/biodiesel/conference2006.htmlhttp://www.biodieselcommunity.org/howitsmade/http://www.biodieselcommunity.org/howitsmade/http://www.cisat.jmu.edu/biodiesel/conference2006.html
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    VIRGINIA CLEAN CITIES

    VIRGINIAHomebrew vs Commercial Production

    FuelMeister Biodieselgear 60

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    VIRGINIA CLEAN CITIES

    VIRGINIAHomebrew vs Commercial Production

    JMU Processor I

    Appleseed (w/ standpipe wash tank)

    www.biodieselcommunity.org

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    VIRGINIA CLEAN CITIES

    VIRGINIAHomebrew vs Commercial

    Source:www.jsonline.com/bym/news/j

    an06/389013.asp

    Source:http://www.mnsoy.com/biodiesel_

    pricing.htm

    MN Biodiesel Plants

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    VIRGINIA CLEAN CITIES

    VIRGINIAHomebrew vs Commercial Quality

    Industry organization that defines the consensus on fuels is the AmericanSociety for Testing and Materials (ASTM)

    ASTM fuel standards are the minimum accepted values for properties ofthe fuel to provide adequate customer satisfaction and/or protection.

    Dec 2001 -- ASTM approved the full standard for biodiesel, with the newdesignation of D-6751. Standard covers pure biodiesel (B100), for blendingwith petrodiesel in levels up to 20% by volume. Higher levels on case-by-case basis.

    http://www.biodiesel.org/resources/fuelfactsheets/standards_and_wa

    rranties.shtm

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    VIRGINIA CLEAN CITIES

    VIRGINIAHomebrew vs Commercial

    No matter how its made (backyard or in commercial plant), out-of-specbiodiesel can result

    NREL/NBB fuel quality testing project found at least one-third ofcommercial biodiesel samples pulled between November 2005 and

    July 2006 were out of spec for incomplete processing Many homebrewers/small scale coops are making high quality biodieselall over the US, and some are struggling as well

    QC testing can be $1700 for full ASTM slate tests, and labs are ~$30,000to install, and out of reach for many homebrewers

    QUALITY IS IMPORTANT, SO ENSURE YOU ARE BUYING ASTM

    QUALITY FUEL OR IF PRODUCING FOR SALE THAT IT MEETS ASTM

    SPECS

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    Biodiesel production & use has grown dramatically NBB estimates 75 million gallons in 2005

    Current production capacity is more than 290 million annual gallons

    More than 570 million annual gallons under construction or planned

    Current U.S. avg. rack price $3.20/gal (vs. $2.40 for No. 2 diesel)

    Prices pre-tax, pre-tax credit

    Who Uses Biodiesel?

    Whos using it?

    U.S. Postal Service

    U.S. DoD, DoE, and DoA

    Countless school districts,transit authorities, national

    parks, public utilitycompanies, and garbage

    and recycling companies Credit: Robert McCormick, NREL

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    VIRGINIA CLEAN CITIES

    VIRGINIACommercial Biodiesel Production Plants

    Source: National Biodiesel Board

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    VIRGINIABiodiesel retail locations

    Source: National Biodiesel Board (Retailers and Distributors map)http://www.biodiesel.org/buyingbiodiesel/guide/default.shtm

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    VIRGINIA CLEAN CITIES

    VIRGINIAMarket Development in Virginia B20 Fleets

    VALLEY

    PROTEINS

    US NAVY

    Portsmouth

    Yorktown

    Westmoreland

    Schools

    2004 Fleets

    2005 Fleets

    2006 Fleets

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    Industry Analyses

    MORE INFORMATION National Biodiesel Board: www.biodiesel.org

    Virginia Clean Cities: www.hrccc.org

    US Department of Energy Clean Cities:http://www.eere.energy.gov/cleancities/blends/biodiesel.html

    Iowa State Universitys Biomass Energy Conversion

    Center (BECON): Biodiesel Short Course -

    http://www.me.iastate.edu/biodiesel/Pages/biodiesel1.html

    RESOURCE CD: Included as part of workshopseries

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    www.hrccc.org

    Al Christopher

    804-436-3867

    [email protected]

    Contact Information

    Hampton Roads

    Virginia

    www.hrccc.org

    Chelsea Jenkins

    757-256-8528

    [email protected]